ML20246L334
| ML20246L334 | |
| Person / Time | |
|---|---|
| Site: | Sequoyah  |
| Issue date: | 07/12/1989 |
| From: | Schmierbach M TENNESSEE VALLEY AUTHORITY |
| To: | Cropp J CHATTANOOGA-HAMILTON COUNTY AIR POLLUTION CONTROL |
| Shared Package | |
| ML20246L341 | List: |
| References | |
| NUDOCS 8907180401 | |
| Download: ML20246L334 (126) | |
Text
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>p TENNESSEE VALLEY AUTHORITY -
la 3 _ ,K,NpXVILLE. TENNESSEE 37902 QUh21999
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l Mr. J. Wayne Cropp
' Chattanooga-Hamilton County Air Pollution Control Bureau 3511 Rossville Boulevard Chattanooga, Tennessee 37407
Dear Mr. Cropp:
. TENNESSEE VALLEY AUTHORITY - SEQUOYAH NUCLEAR PLANT (SQN) - PERMIT APPLICATIONS FOR EKISTING AIR POLLUTION SOURCES - SUPPLEMENTAL DATA
REFERENCE:
. LETTER, STEVEN T. COLWELL TO DALE V. WILHELM, APRIL 27, 1989 The following information'is provided in response to the referenced letter which requests additional information regarding the permit applications submitted with my March 1 letter. We apologize for the lateness of this response, but your, incoming letter was misrouted in TVA and was not received by my staff until April.27.. The responses are numbered to correspond with the items in the referenced letter.
- 1. Modifications Carpenter Shop Woodworking Equipment with Transfer System and Storage Bin
- a. The estimated volume of gas discharged from GCE at dry standard conditions is 3800 cubic feet per minute. This estimate is based on the manufacturer's data given in Enclosure 1. The fan is powered by a 1-horsepower motor operating at 1735 revolutions per minute.
- b. A sketch of the storage bin is given in Enclosure 2.
- 2. Modifications Carpenter Shop Radial Arm'Saw Served by Small Dust CollectorL
- a. Input process rate is estimated to be 75 percent of the lumber going through the shop. The shop process rate is 450 pounds per hour:
therefore, input process rate is approximately 340 pounds per hour.
- b. The pressure drop across the baghouse has not been measured; however, the manufacturer stated it to be 4.5 inches of water. A copy of the vendored provided specifications is given in Enclosure 3.
- c. The baghouse filter fabric type is woven.
I I 8907160401 89071? bpOf PDR ADOCK 05000327pdc y
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An Equal Or.portunity Empinvm cm . . .J
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, Mr. J. Wayne Cropp
- 5. Service Building Paint Spray Booth Wash Water Curtain
- a. The dilution ratio used for determining the applied coating reported on the E010B form was 99 parts coating to 1 part thinner. Form E010B was included as'a typical coating applied. Revised E010B forms for those coatings actually applied during the last year are given in Enclosure 4.
- b. A Material Safety Data Sheet (MSDS) for the thinner specified on the E010B form submitted earlier is not provided since revised E010B forms are being submitted.
- c. The usage data and MSDS for the coatings and thinners used for this ,
cource for the past year are given in Enclosure 4.
- 7. Ilydrazine Tank Vent
- a. The tank was installed as part of the original plant equipment sometime around 1975.
- b. A copy of the E106 form for hydrazine that was used to determine the uncontrolled emission values in item 7 of the E104 form is given in Enclosure S.
- 8. Ammonia Tank Vent
- a. The tank was installed as part of the original plant equipment sometime around 1975.
- b. A copy of the E106 form for ammonia that was used to determine the uncontrolled emission values in item 7 of the E104 form is given in Enclosure 6.
- 9. Construction Sandblast and paint Shop with Two Building Roof Exhausters
- a. The process weight (item 12. E001 form) is estimated to be 600 gallons per year (2.3 gallong per day) of coatings and thinners and 3960 pounds per day of black beauty (grit used in sandblasting).
- b. The usage data and MSDS for all coatings and thinners used for this source for the past year are given in Enclosure 7. Revised E010B forms for those coatings actually applied during the last year are also given in Enclosure 7. Also included is a revised form E106 that more accurately reflects the uncontrolled pollutant emission rate.
- c. Attachment I referenced in the E106 form for this facility is given in Enclosure 8.
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Mr. J. Wayne Cropp .M l 21989
- 10. Unit'l Lubricating Oil System Vapor Extractor Vents (4 Vents)
- a. We'do not believe that individual permit applications and associated fcrms for vapor extracter should be required. 'We' view the lubricating; oil system as one system and the four vents as a group of identical.
-(in the sense that they perform the same function) sets of equipment that have a common feed. Therefore, we request that you reconsider your request that individual permit applications be submitted for each vapor extractor,
- b. Drawings of the lubricating oil system, the vapor extractor and the mist eliminator are given in Enclosure 9.
- 11. Unit 2 lubricating 011 System Vapor Extractor Vents (4 Vents)
- a. The comments and information provided in item 10 for Unit I also apply to the Unit 2 system.
If you or your staff have any questions or connents regarding this informa-tion, please contact Dale V. Wilhelm at (615) 632-6693 in Knoxville. Sincerely. Ou .,s O H. Paul Schmierbach, Manager Environmental Quality Enclosures-cc (Enclosures): Ms. S. C. Bisek, Assistant Director for Projects TVA Projects Division Office of Special Projects United States Nuclear Regulatory Commission One White Flint, North 11555 Rockville Pike ' Rockville, Maryland 20852 Mr. F. R. McCoy, Assistant Director for Inspection Programs TVA Projects Division United States Nuclear Regulatory Commission Region 11 101 Marietta Street, NW. Suite 2900 ) 1 Atlanta, Georgia 30323 l l 1
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o' _4_ Mr. J. Wayne Cropp .. JK 121989
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'n Sequoyah Resident Inspector Sequoyah Nuclear Plant 2600 Igou Ferry Road Soddy Daisy. Tennessee 37379
/ Uni t cet nt at oc wiirlent__h -int =*nvy rammtce4ng Attention: Document Control Desk lidtington, D.C. 20555 L e
5 I ENCLOSURE 1 GAS DISCHARGE CdRVE FOR BLOWER ON DUST COLLECTION SYSTEM FOR MODIFICATIONS CARPENTER SilOP WOODWORKING EQUIPMENT F i
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.4 ENCLOSURE 2
SKETCil 0F STORAGE BIN'FOR MODIFICATIONS. CAP.PENTER Sil0P WOODWORKING EQUIPMENT
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. SPECIFICATIONS FOR DUST COLLECTION SYSTEM '
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- Home vacuums provide 100 CFM. design makes it superior to the airoronthefloor. Powered single-stage collectors.
byahigh performance, . Industrial vacuums can heavy-duty indus, trial motor, supply up to 120 CFM. Jobs are done quickly, qu,etly. i . The DustMaster supplies IWo-Stage System It's elficient. The self-350-1100 CFM, many times the power of the heaviest M7reDurable, , , cleaning, cast aluminum radial blade blower draws in duty industrial vacuum. Efficient - the smallest chips and dust. Shop vacuums can't match The two-stagn/ stem is The permanently tubricated, the DustMaster's collection more durable, efficient and I ball beanng motor is totally ! . hor oun n9 safer than competitive single-enclosed and fan-cooled. It's {5-g on p gp um stage collector systems. safe because there are n provides ample waste exposed moving parts. capacity. Final air filtration Single-stage collectors draw area is twenty square feet; dust-laden air directly into the The resultis a cleaner cotton duck filter bagis blower, where contact with ' working environment. The grit and particles causes i DustMaster gets waste as it's equipped with a zippered I clean-out. rapid wear to the wheel and being made, not after the job ' housing. Sparks can also is done. .. The hoses are also designed occur, providing an increased
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hick The Power You Need .. s. The DustMaster's many sizes are well-suited for Five Models Available industrial and commercial applications. A complete line of nozzles, fittings and hoses makes it flexible .. Complete dust collectors with permanently lubricated, ball bearing, continuous-duty, TEFC motor, enough for many varied operations.-
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T pical Applications Stock No. 1Z726 1Z967 1Z863 1ZI64 3Z002 HHP.1PH 1HP.1PH 1HP.3PH 2HP.3PH Molar HHP.1PH 34 2 3450 3450 Des 1 Collecter Horsepower Batings RPM 3450 3450 ac 0 208-2201440 1/3 1/2 1 2 115/206-230 115/208-230 115/208-230 208-220/440 Rany # _
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- - X X ', 60 7.6 60 7.6 Belt / Disc Sar. der 7001100 CFM X X X Jointer 300-800 CFM X .^
static 3"WG 7" WG 4M" WG 4W WG. . 6W WG X X X X Max'swa Pres Grinder 2001100 CFM 700 700 1100 X Mat CFM 355 450
- - X Foundry Mixer 7001100 CFM X X X s 5155 5120 5130 5600 pg 7230 Bag fyling 4001100 CfM X X X X 65 burting/Pollshin0 3001100 CFM 76 78 83 83 dBA @ 51
- - X X Stone Cuttmg 500-800 CrM 3160" 4160" 5460" 5460' 6*x60" Hose llas X X X X 24" Labora*.ory fguipment 3001100 CFM 20" 20' 24* 24*
Drum ud Dia. wds b Drum $118 $5 Gal- 55 Gal- 55 Gal-c P 20-24 Gal. 20 24 Gal-r* men on. . cur.est toon u.o
- e. . *
.n
. , Ship Wt., Ibs. 43 51 73 65 81 Supplied Supplied Wired for Wired for Wired fo,r M.'<? r Electrical 115V; 8' 115V; 8' 115V; 8 rea@ for rea@ for
* #8 s- Hookup cord set and cord set and cord set and g"8 sw d sw m sw M ,,,,,, ,,,,,,
;z:;[ ~ w g ___
d Otiality DistMaster v g.!/ '" ' Accessories Dust Bag: A 20 sq. f t. filtration area cotton duck filter bag comes with the DustMaster. o' Nontes: A front intake nozzle and a side intake f nozzle come with the DustMaster.
~=
Hose Kits (optional): Four hose kits are available.
' , Hose ki'.s contain one hose, two clamps and one
' tubuiar steel connector sleeve. Use for extending hose or replacing original hose.
Model Stock No. Shipping Wt. Hose Size
~
3*x60", - HK 3 1Z891 1.6 lbs. 4'x60" HK 4 1Z890 2.2 lbs. 2Z061 2.5 lbs.
, .- .' , 5"x60" HK 5 2.8 lbs.
s6 ' ' ' 6'x60" HK6 2W449 4> um.:on a e, eney nm +e e. - - _ DustMaster by Cincinnati Fan
~
4 e n Monnq
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ENCLOSURE 4 USAGE DATA AND MATERIAL SAFETY DATA SHEETS FOR COATINGS AND TilINNERS USED IN Ti{E SERVICE BUILDING PAINT Sil0P
'l 1
1 l i i i
~~~-a----- ___ _ _ _ _ _ _ _
1 LISTING OF COATINGS AND TilINNERS USED IN TiiE SERVICE BUILDING PAINT SliOP PRODUCT OUANTITY USED Warren Maintenance and Machinery Enamel 2 gallons Benjamin Moore Satin Finish Varnish 3 gallons 3 gallons Benjamin Poore Sanding Scaler Benjamin Mc re Walnut Stain 3 gallons 1 gallon Phenoline Thinner 1.5 gallons Phenoline 305 Paint 1 gallon carboline Thinner 1.5 gallons Carboline Zine Primer 4 gallons Sherwin Williams Industrial Enamel 5 gallons Sherwin Williams Red Oxide Primer Sign Painting Lettering Enamel One Shot 3 quarts Black 2 quarts Red 2 quarts Blue 1 quart Green Gold 1 quart Gum turpentine 3 gallons Note: Material Safety Data Sheets are attached. l i i 1 i l 4 I I
- .y.
Ferm E010B COATING / THINNER DATA FORM. rompany Name: YrDI10YhF$ YUdLdk (AkIT LN YAlltY Y WlG. Applicable L APCB ' Certificate #:: MM kDdr katr 60MY ) Prodiact ' Name: ' Stier' M) LeT70t tJ6 i EuAmrt .. Product Manufacturer: b//6//F/Exs Pe,ar FIc.rea v .7m Usaae Data-
- Daily.(gal / day): O.dd3 Annual (gal /yr): 2. 2 b Rule 25.43 & 25.44 Analysis or Manufacturers certification Data *: b /77A@ f $D,5
--4u As Received (Concentrated): O Density (1bs/ gal): / Solids % by Weight: 40 % by Volume: 45 VOC % by Weight: 40 %.by Volume: 35 Water % by Weight: Id __ % by Volume: As Applied (Diluted): - $ 9tE~ A.s A p c-Density (lbs/gsi): % tj Jelm,,. ; I solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thiener Data '
/b
/
chemical Composition: Density (1bs/ gal): Mfr. Data Sheet or Certification is attached. Yes o
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true_and plete to the best of my knowledge. -f ', /J g Signature: / /t Ortv4 it'tYA >
Title:
MAh0Got' of &ViPoNMG7DL /Odsmf 11/03/89
' RMP
/y//-
.:c'
.. i
,j g ") < (ffj U.S. DEPARTMEN ' OF L AE.OR o Pl J V 'T .k occupational: Safety and Hethh A: N nistr uion MATERIAL SAFETY DATA SHEET C ::, ' .'. M ! $,------s=h==== i h . diO t
= = = = = = = = = = n =e = ==e-
===============================================I SECTION J Emergency Telephone No.
Manuf acturer's Name . 219-949-1684 Consumers Paint Factory, Inc.
- Address (Number, Street, City, State and Zip Code)
P.O. Box 6398, Gary Indiana 46406 Trace Names and Synonyms Chemica! Name and Synonyms "I Shot" (R) Lettering Enamel . N/A Formula Chemical Family N/A Paints and Coatings
==------ -------- -----------========================
====== =============== ===SE CTION II - H A-* A R DOUS IN GRE DIE NTS See Table I, Section II Attached
- =====================-======
= = = = = = = = = = = = = = = = = = = = == = = = = = =SE C T I O N 111 - P H Y S1 C Al. D A T_A_,
Note: Data Herein (except 9o Vol.) for solvent portion only Specific Gravity (H 0:1) .74 .89 Boiling Point ( F.) 246-385 Percent Volatile by 'ol.(96).. 25% - 35% - Vapor Pf ' - *e (mm H g.)' 2-15 9 -70 3.8 - 4.9 Evaporation Rate (Ether = 1) ' Vapor Demity (AIR = 1) Solubility in Water Ins. . Water white and characteristic petroleum odor. Appearance and Odor
===========================
=== === == ============ SECTIO = IV=====N
- FI RE AN D E X PL OSION H A"" AR D D AT A Le! Uel F.ammabie Limits Flash Pc;nt (method used)
Pensky-Martens closed tester: 84 - 110 F N.E. N.E. Carbon dioxide or dry chemical Extinguishing Media Special Fire Fighting Procedures: fire. Water spray mhy be ineffective. Water spray should be used to cool containers Do not enter the fire area without p oper protective equipment, in:Juding self-conta breathing apparatus. Unusu2 rire and Explosion Hr. cards: Avoid s.ource of ignition, flame, static electricity, heat, electrical spark.
====s======================
==========================Sn.i,.= .: ..-nmm == .. =...nr= = = = = = = = = . = = . = = . .====,=,==.
Threer f Li rP Yahm 5:e Tct.t 1, Section 11. . Ef f ets :f Overexposure See Taole 2, Section V Emerge- y and First A;d Procedures
. See Table 2, Section V
===========================
~ e a
t
'. Form OSH A."'
Page ( ' i
- -. :. = = =====
'~ ==============================- - '
= ====== =-=== === ==== = =S== =====ECTI ON VI - RE A CT WIT Y D AT A*
Stabilit y. L' : stable ' Cor.ditions to Avoid 5 table _X Ex : ssive Heat ... incompatibility (Materies to Avoid) None Hazardous Decor . position Products CO, NOx, Lead, Chromium Fume May occur. Cc .ditions to Avoid ' Hazardous Polymerization Till Not Occur. X
===============- -==-==--===========---===========
== = ====== ==== == ==============N SECTIO VII '- SPILL OR L E A K P R OCEDU R ES '
Steps To Be Taken in Case MaterialIs Released Or Spilled -!
- Eliminate all heat sources, open flames, and other sources of ignition. Absorb with solid absorbent. Shovel into containers. If large quantities are spilled, personal protective equipment may be required.
Waste Disposa! Method
-Dispose as paint waste in accordance w?th Federal, State, and local regulations.
================-==============
=s = = = = == = == === = = ===
SECTION Vill=- SP
= ============ ==E CI AL P R OTE CTIL 1 1 N F OR M ATI O Respiratory Protection (specif y type)
- Organic vapor respirator with particulate filter approved by NIOSH.
Specid
~ Ventilation Local Exhaust None Preferred - Paint Spray Booth,150 f pm f ace velocity Mecha tical (general) Other None Acceptable ior small volume applications Eyp Protection Protective Gloves Spbetacles with side shields.
Butyl rubber or equivalent Other Protective Equipment Norie
=========================----------------
== = === == === = = = = ==SECTION = = == = === == = === = ==I X - S P E CI A L P R EC A UTI O N S Precautions 7: h Ta':e Ir; Handling and Storh; Keep container closed when not in use. See labels ior normal handling caution.
Other Precautiem Handle caref ully in accordance with hazardous prope ties of flammable liquids as suggested by. the National Fire Protection Association. Liability is expressly disclaimed f or any loss or injury crisint out of tM use cf this inf ormation or the use ef any materials designated. Nationa! Paint and Costinp Associat. ion Hazardous Material Information System
======================================
e Form OSHA-20 l Page (2) , t . L E __ _ _ _
- m. - ..... ,. ,
a a r.- . v . 11/35
- p. c h
Table 2 ' Section Y Health Hazard Data Effects of overexposure , May cause dizziness, giddiness, narcosis, central nervous system depression.
~
Prolonged overexposure to solvents may cause kidney, liver, and other systemic damage. ,. Recent reports indicate that prolonged exposure to solvents at moderate levels m affect higher brain f unctions and mental capacity.
. Lead may cause liver, central nervous system and systemic effects on the blood and
. blood-f orming organs af ter high, prolonged exposure.
Exposure to airborne concentrations of chromates has been associated with fung: cancer. Prolonged exposure to high concentrations can cause perforation of the nasal septa. Emergency and First Aid Procedures if overcome by vapors, remove to fresh air. If not breathing, restore breathin&- Get medical help or a physician immediately. If ingested, do not indoce vomiting. Cet medical help or a physician immediately. Eye
Contact:
Flush with large quantities of water for 15 minutes. Get medical help or a physician immediately. 1 Skin
Contact:
Remove excess material with paper towels or rags. Wash with mild soap and warm water. If any redness or swelling persists, get medical attention. s k l ' Page (3) .
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For:n E010B COATING / THINNER DATA FORM _ Company Name: YtDUOYhd YLidLCllR (Abli LNMW YA Al/Tik*lG Applicable APCB Certificate I: M MC# k DG P41#T 60MY Product Name:. IfA OL. 87 ,kED O%tDC , Product Manufacturer: It' h//R#/M- ILL/4Ms 4 Usaae Data Daily (gal / day): O O/9 Annual (gal /yr): 2 N Water % by Weight: 8A % by Volume: As Applied (Diluted): $Atf AS N,oyf Density (1bs/ gal): % 4 'lelom ; Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: A/A Density (lbs/ gal): Mfr. Data Sheet or Certification is attached. Yes o
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true an omplete to the best of my knowledge. , 3 /J Signature:/ t .1 t
Title:
pMerdK of 6%PoNMG7AL_Q@@ 11/03/89 RMP _ _ _ _ _ _ _ . _ _ _ ___ _ i
y U
'E6i'R C21'-
MATERIAL S A F E. T Y DATA FHEET FI . 549 ' 37 FOR CDATINGS. RESINS AND RFtATEh MA1FP]AtS 1 Approved bw U.S. I*epartment of Labor 'Essenttallw Similar' to form 05HA-20) MANUFACTURER'S NAME EMERGENCY TE'LEPHONE Nil .
.THE SHERWIN-WILLIAMS COMPANY (216) 566-2917 101 Prospect Avenue N.W.
Clevelandr- Ohio 44115 DATE 0F PREPARATION INFORMAT30N TELEPHONE NO. 6-Aus-86 . (216) 566-2902 , o.=n===========================r=r===rre====rne-e-rer===r=rr===-=nerenennernen Section I -- PRODUCT IDENTIFICATION .,g --_------- -----
* - Trede Mar'k c.5TC-%
PRODUCT NUMBER -
-E61 R C21 > c t> -
PRODUCT NAME i P risme r Paint, Red Oxide g@ g PRODUCT CLASS - Alkwd Paint , . _ ===============================n=rme=rerncenernner=r===r=r-ranc-ermenenrnere=r., - Section II -- HAZARDOUS INGREDIENTS V.P. by WEIGHT ACGlH-TLV OSHA-PEL UNITS CAS No. INGREDIENT 40
---------- 300
--------------------. PPM 12 0 64742-40-9 V. M. 1 P. Naphtha.
<5 100 500 PPM 20 64742-47-0 Mineral Spirits. Ms/M3
<0.5 0.05 11103-86-9 Potassium Zine Chromate. <I)
< > Ingredient is an.IARC, N1P<N> or OSHATO) listed carcinocen 0.0.' O.05 Ms/M3 Chromium VI (as Cr).
= = = a = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = r = r e n r e. r = r r = = = = = = = = = = = r e r r - r n e n n n Section III --
PHYSICAL DATA -----. EVAPORATION RATE -- Slower than Ether VAPOR DENSITY -- Henvier than Air
% VOL.ATILE VOLUME WT/ GAL BOILING. RANGE (F) 9.62 240'- 395 62 4 su===========================-=ner===r=rer=rme=rrerencenrenenn=========
Section IV -- FIRE AND EXPLOSION HAZARD DATA
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - . - - - - - - - - - - - - - - - - - -0.9 -----.---
Ft. ASH POINT 30 F.PNCC LEL FLAMMABILITY CLASSIFICATION RED LABEL -- Flammable, Flash.below 100 F EXTINGUISHING r1EDI A Carbon Dioxide, Drw Chemical, Foam UNUSUAL FIRE AND EXPLOSION HA7ARDS Keep containers tightIw closed. Isolate frosi heate electriccl couirment, f.r p rks , and open flace. Closed containers nav explode when exposed to extreme heat. Anelication to hot surfrees reavires sPeeial precautions. Durino rectcener conditions overexposure to Sumetams saw not be immediately apparent. ! doe'neosition Products an c'ause a health hazard. f Obtain medical att:ntien. 1 S PE. C I A L F I F.; a l r;Hii p s c R nent:F.E r I Jull Protective eoulement :r4 ludson .c it -c.mtrined breathin[ arrarotus shouldWater be u.may
- d. be Wat2r sern e n be itinf f ective. I f wa te r i' w,cil, foi no: les are preferable. ]
j used to cool clcsed containers to rrevent rrettore build-up and rocsibic cutoinnition or ' l oxPlosion when exposed to extreme heat. , I i ,
)
i i
. . . . . .s n .,. 2 i
[ $ * ]
+ a ne .-
. .- E 61,i N C 21 trsaier Paant, hro 0:.2 m o ===&========= =. . ..=== _ == _ = m = ~ _ ..- ~ ...-- ~ -= - = = _ -
====n...
Section V -- HEALTH HAZARD DATA !' THRESHOLD LIMIT VALUE - See Section II EFFECTS OF OVEREXPOSURE Hav cause nervous cur. ten ACUTE:= OverenFosure causes en , skin and retritatorn irritation. depression accompanied bu headar.he, dizziness, na ur.co , confusion and stssmerins salt. Entreme overenporure meu result in uncont.ciour.ncsc cnd rossibic deeth.
. CHRONIC: 'Prolonsed overexposure to insredient in Section II meu cause rdverse effects so the livere and urinarv systems.
Reports' have associated repected cnd rrolonced overeneor.ute to solvents with eermanent brain and nervous r.>.estem damatte.
. EMERGENCY AND FIRST AID PROCEDURES
.If' INHALED: If affected, remove from eurosure. Rectore breatinc. Keer warm and nulet.
If.on SKIN: Wash affected area thorouchly with socr and water. ' Remove contaminated clothine and 1cunder before re-use. Ifi(EYES: Flush-eves with larse amounts of water for 15 minutet. Get siedicci i attention.
===me============================enr=nrereene-nner===== n-nnr==nrr=nreennrrr===
Section VI -- REACTIVITY DATA STABILITY -- Stable HAZARDOUS DECOMPOSITION PRODUCTS Pv fire: Carbon Dioxide, Carbon Hononsde, 0xidet of Metals in Section II
' HAZARDOUS POLYMERIZATI,0H -- Will Not Occur nr.nnnr=r-
=================================n=nenerenner errron=n=rremenennenener Section VII --
SPILL OR LEAK PROCEDURES STEPS TO BE'TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED R2 move all sources of isnition. Ventilate and remove with inert cbrorbe;nt. WASTE DISPOSAL METHOD Waste from this Product may be hazardous cr. defined under the Recource Conservation and Recoverv Act (RCRA) 40 CFR 261. Waste must be tested for innitability and entreetebilitu to d2termine the applicable EPA hazardout weste numbers. . Incinerate in aPeroved'facilitv. Do not incineret e closed container. DiCPoSe Of in accordance with Federal, State, and Loen1 regulations recardinn Pollution.
= = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = r r = r e r e n e r r e = r e n,r n n e r e n e n e r n e = = = = r = = = n e Section VIII --
PROTECTION INFORMATION PRECAUTIONS TO BE TAKEN IN USE Avoid contact Use only with adeouste ventilation. Avoid breathine veror and screv mist. with skin .and eyes. Wash hands after usins. Protect assinst ha:ardous dust or fumer which sau be senernted bu sendince wirebrushinse
. abrading, burnins, bra: ins or weldins of the dried film.
VENTILATION Local exhaust Preferable. General enhaust accerteble if Refer the excocure to meterials in to DSHA Standards 1910.94, Section 11 is maintained below onelicable extosure limits. 1910 107, 1910.108. RESPIRATORY PROTEf. TION If Personal enromn e c i mot be erntrolled below creliccble limitt be ventilation, waar respirc:ct" om- wr- 4 bu N ' JSH/MF ) to erotect. ion assinst materials in. Sect'lish'.l.I. PROTECTI' 3LU'ES ,
,l ;/. -" -
Wear sicves which are recommended by slove rurrlier for trotection accinct'meterials'in- ' E.~ .,,
- L,' '
Section II. EYE PROTECTION i-C.g "%N . , .
- dear safets specta'eles with unrerforeted tideshieldn. hUr,~.
u, /. .
; ',..M.A . e. q'e
[';'$. E g~. ,N ~ A
< . ;^. .
s {- Continued on pase 3
,_ -_ - _ _ _ - - - _ _ _ _ = _ _ _ _ _ _ - _ - - _ _ _ _ _ _ _ _ _ _ _ _ _ _ .____-- - _ - _ _ - . - _ - _ _ _ _ _ _ - - _ - -
. .+
Par.s 3 1E61 R C21- Pricer Paint, Red 0::inc renemener.e=e
~ n = = ,4 . = = = = = = = = = = = = = = = = = . = = = = = = = = = = = = = e = - a r = n e r r - r r r n e = = - = = = = = r e r =r r '
l Section IX --. PRECAUTIONS , l ____..________________________________________________________________________3
- DOL S10ivauE C ATEGORY 1B
, PRECAUTIONS TO BE TAKENKeep IN-HANDLINGaway fromAND STORING hente secrkne cod oren f1cee. j Centents are' FLAMMABLE. Durins use and until all varors are tone: Kect avec ventileted - Do not smoke - E>:tinsuish all flames, ellot 114htse and heater; - Turn off stovei, electric tools and areliances, and anw other sources of isnition.. , Censult NFPA-Code. Use aperoved.Bondinc rnd Groundinf Procedures. Trencter onh: to arrroved contcinerc'uith complete-Koor container closed when not in use. Keep out of the reach of children.
-and aperorriste labelins. Do not take internallu, DTHER PRECAUTIONS ' ~ '.This'costins contains materials elessified n nuinence torticulatene f or e>:cerle, titanium dios:ider calcium. carbonate, etc. (see ACGIH TLV Listi Preface and Aprendi>: D),
e ich saw be Present at hazardous' levels'only durinc sanding or abrading of>the dried film.- Intentional misuse by deliberetelv concentrations and inhclinn the contente een be hereful or. fatal. s
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.The above information eertains lo this rroduct as currentivyformuleted, and is based on the information available at this time. Addition of reducers or other additives Since to this conditions Product aas substa'ntially alter the compo'sition and ha ards of the Product.
of use are outside our controle wo make no warrantic<;e m: Press or ineliede and assume no ' liability in connection with any use of thit inforectinn.
o . I Form E010B f COATING / THINNER DATA FORM Company Name: YtDt10Yhd Yt)CLdk (AUT EN W YALLly k W IG Applicable APCB Certificate f: MW kDG Pa6tT %Y Product Name: [plDU577d/A L. hd4MEL. , OtyroHC PE C
' Product Manufacturer: IS' 6HFRuf4M - Nf LL/44% b, i -Usaae Data
!.f Dail) (gal / day): O. O /6 Annual (gal /yr): Rule 25.43 & 25.44 Analysis or Manuf acturers Certification Data *: b /77Ac/irb h$$ As Received (Concentrated): Density (lbs/ gal): 8. 8 b Solids % by Weight: b % by Volume: N,9 - VOC % by Weight: 40 % by volume: U. l _. Water % by Weight: O % by volume: O As Applied (Diluted): f & WE _ Density (Ibs/ gal): % ty '/;1mme; Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: Density (1bs/ gal): Mfr..' Data Sheet or certification is attac d. Yes o
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true an ompl te to the best of my knowledge. 4.f] 7 Signature:/ V.1/7u. I nu/J lYv// Tit 1e: h4NMGbt of th'VienNMG9L /~0thuT'f 11/03/89 , RMP
*s7.e4.2s 18:34
.. '. w sss2 er C54 W 102 ~
MATERIAL GAFETY DATA SHEET 12: FOR COATINGS, RESINS AND RELATED MATERIALS ( Approved bw U.S. Derartment of Labor 'Essentis11v Similar' to f orm OSHA-2h SQN MANUFACTURER'S NAME - EMERGENCY.. TELEPHONE NO. T H E 2S H E R W IN--W I Lt5 A PNssC O M PAffjf. $216) ~ 546.;2Rg NEM
'~ " '
- 101 Prospect Avenue N.W.
. Cleveland, Ohio 44115 .
DATE OF J' REPARATION I N {,0 R M A T.I,0 N ,,T.E L E tH.O NE ND . gig 5e,tsaCir.86, K 214 hi54.6 -Mp2,- .
.. . . ..... ...==........ ========.................. =_=====..================= -
Section I -- PRODUCT IDENTIFICATION . _ . . PRODUCT NUMBER * - Trade Mark
,,b54ikRv202g PRODUCT NAME 11ndust rial Enavnel rL.Midtone z.Basse ~
PRODUCT'CLASG Alkvd Er.amel
===a============.=======.............m==========================.......====:
Section II -- HAZARDOUS INGREDIENTSTLV-MG/M3 t.CL V.F. CAS No. INGRDIENT PERCENT M TLV-PPM 64742-47-01Hiner41Srir.ijs.. !AC, 100. 581. 1.0 20 1 -.
....................................=.....=....................................
Section III -- PHYSICAL DATA EVAPORAT10N RATE -- Slower than Ether VAPOR DENSITY -- Heavier than Air
% VOLATILE VOLUME WT/ GAL BOILING RANGE (F) 8 86 (300 "395 T 57.1 anos.........'.s=====...z=.======.....................s.... ass ======.........:
Section IV -- FIRE AND EXPLOSION HAZARD DATA
. F. LASH PO I NT dit,0.1;yF, P MC C LEL 1.0 FLAMMABILITY, CLASSIFICATION ,
Combustible e.. Flash ,abovey 9h'and sbelow 3' ' ' " ' ' 200 aF
- EXTINGUISHING MEDIA Carbon Dioxidee Drw Chemical, Foam UNUSUAL FIRE .AND EXPLOSION HAZARDS l-IKoeP*' containers tishtlw' closed. c. Isolate ~frosl eate electrical'eouirmente, sparkse end.open Closed containers nav' explode when exposed to extreme hest. Application to' hot ^
~
i fla e.
',ourfaces'reoufres specist precautions. Durins emersenew conditions ovetexrosure to deco: Position Products nav cause a health hazard.' Swa> toms mov not be immediately arrarent.
l [Vbtainmedicalattention. I SPECIAL FIRE FIGHTING PROCEDURES l Full Protective en ir.etit includins self-contained breathins spearatus should be used. i l Water sprav may b e i t ' ." ; n . m '.et is esed. 'or no:zles att Preferable. Later sisy be used te ;:eci :1re.oi r.*n n i. $" . vent Pressure build-up and possic.Ie autoffnition or j exp los s en uW . m% e d .a e.c tsie n-s t. > k k I w__m._- _ - _ _ _ . _ _ - _ . .cce.
- e r . e s ..: s seiss,
- N o" 3382 .*.
~ ,
pese 2 B54 W.102 Industrial Enamele Midtone Base ' p a s s a r s. . . . . . . a = . . w . . z . . . e w . m . . s = = = = . . . . . . c = . . . = . z . . . . . . . . . . . . . . W . . . . . . . . Section V -- HEALTH HAZARD DATA _ . . . . . . - - . . . _ _ . THRESHOLD LIMIT VALUE -- See Section II EFFECTS OF OVEREXPOSURE Overexposure saw ACUTE: In;a confir.ed area varors in high concentration are anesthetic. result in lightheadedness and stasserins sait. Irritant to skin'and ureer vesFir.stors,systIm. ~ CHRONIC: Reecris have associated reFeeted and Prolorded overexposure to solvents with i eermanent brain.and nervous swstem dana'se. '
~ '
EMERGENCY AND FIRST AID Pr.0CEDURES ' Mf'Affectedr'temove'frondexrosse.[.R e s t o r e ib r e a thi n s . jKie e MifsMo
~ ~ ~ " n~diub t.
~
If INHALED: ~ If on SKIN: '~S % ,f,, fee,ted,,k're, ]t g pui g"{ Kt'h"goa Q nd h tet. } Remove fontaniinated clothinscend. un'de rrsbeTote mr e-Ys e . If it. EYES: Flush. ewes with"larse amounts of ustef'for'13 'ainutes. Iret medie'll'atfintiori. '
=====.........=====....u....e====e.,,......=========....w...=,==.....===e=
Section VI -- REACTIVITY DATA STABILITY --IStable HAZARDOUS DECOMPOSITION PRODUCTS 9w fire: Carbon Dioxide Carbon Monpxide HAZARDDUS POLYMERIZATION -- Will Not Occur
...=.........................,=====..........m==................
===...........
Section VII -- SPILL OR LEAK PROCEDURES . . - . . _ . . . _ _ . _ . . . . . STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of isnition. Ventilate and remove with inert absorbent. WASTE DISPOSAL METHOD Incinerate in approved facilitv. Do not incinerate closed container. Dispose of in accordance with Federal, States and Local regulations regardins Pollution.
=====.........=====........======......======............e===............... PROTECTION INFORMATION Section VIII --
PRECAUTIONS TO BE TAKEN IN USE Avoid contact Use oniv with adeouste ventilation. Avoid breathins varor and sprav mist. with skin and eyes. Wash hands after usins. Protect against dust which may be senerated by sandins or abrading the dried film. VENTILATION i Local exhaust pref erable. General exhaust seeertable if the exposure to materials in Section II is maintained below arrlicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If Personal exeosure carcot be controlled below applicable Ifmits by ventilation / wear peseiratorvdevicearerovedbvNIOSH/MSHA"forprotectionagainstmaterial,sinSec ' PROTECTIVE GLOVES Wear slaves which are recommended bw slove sueelier for Protection assinst saterists in S etion U Ei' c'
"'1 Lear safety Setectacles with unperfotated sideshields.
4
\
l Cytinue! sn esse 3 __m_._m.m_ _ . _ _ _ _ _ _ _ _ _ _ . . _ _ _ . _ __
'8r.es 21 188S6
.' , ,'r ug sst2 pase 3 C54 W 102 -
Iridusttiol Enowle Midtsne Base -
......d...>.m................e.................w..sona. coon.a.o.....o.ma==..,
Section IX -- PRECAUTIONS DDL STORADE CATEGORY -- 2 PRECAUTIONS TO PE'TAKEN IN HANDLING AND STORING l C:ntents'are COMPUS"IBLE. Keee away f rom heat and ce'en flesie. I C2nsult NFPA Code. pselir~iroved Bonding.and trounding:/ Procedures. Kcer container closed when not in use. Transfer only to'afffoVES containers with coni >1ete and appropriate labelins.- Do not take interns 11w.- Keep'out of the reach of children. OTHER PRECAUTIONS , , This coatins c ontains materials classified es nuisance / Particulate 19 for eMa&Ple- { titaniusi dioxide, calcius carbonate, etc. (see ACGIH TLV List, F ref see and Appendix Die
'whleh mev be rresent at hazardous levels on1w durins sandins or abrading of the dried filei.
Intentional misuse bv deliberstelv concentrations'and inhalins-the contents can be harmful or fatal. l l l The above inforsistion certains to this. Product as current 1w f ormulatede and is based on j the infora atf ori available at this tia e. Addition of reducers or other additives to this product raw substantial 1v alter the composition and ha:ards of the Product. Since conditi'ons of use are outside our controit we aske no warranties, express or inP11ed, and assume no liabilitw in connection with snw use of this information. E__ _ _.____ _ _ _ 0 ..
Form E010B' COATING / THINNER DATA FORM Company Mame: LDYW UC48R. fudT DUFS~ ALLC1 v11 Ott111 Applicable APCB Certificate f: D/C(' dO6 h///7~ bP h9FN) Product Name: __ [/467 27//C Product Manufacturer: M8666/M[ b. Usaae Data Daily (gal / day): O.01 Annual (gal /yr) : 2. b Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: 4 grum 5Ds As Received-(Concentrated): Density (lbs/ gal): OO Solids % by Weight: 38.7 % by Volume: /b VOC % by Weight: _ (b 4 3 % by Volume: OO Water % by Weight: 4 by Volume: As Applied (Diluted): [// /,5) Density (1bs/ gal): b 4 by "ch-e: Solids % by Weight: d7 % by Volume: [n6 VOC % by Weight: % by Volume: b Water % by Weight: /EN % by Volume: Thiliner Data Chemical Composition: O lO9////[ M /A NIE-Density (1bs/ gal): b,b i Mfr. Data Sheet or certification is attached. Yes o l *For USPS Sources Method 24 must be used. This is to certify that this information is true and complete to the best of my knowledge. 2g j/ Signature: M[18d[ w!40'Al l l /V
Title:
ifj huel er GN*a*ER1BL Qatry
'11/03/89 _ _j u_-_m____________ _ _ _ _
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' MATERTAL SAFETY. DATA SHEET *..
e Hil,G,2 5 80 -
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p'350 Henley IndustMal Ct. INFORMATION TELEPHONE NO'. 314-644-1000 EMERGENCY TELEPHONE NO. 318-644-1000 t ' St . Lcuis . T O 63144 4 4.AC.E.S O.AT.E.;
.. .N.E.W..M.SC.S...
. . . . _ PREPARER- r. .lK.at
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. . , --. 08/11/81...... a .
- SECTICW !
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... . .r-- ----.c---- .ODUCT J DENT I F I C AT IO.N -
1 g CARBD ZINC 71 SG p* #
" 910231.GRE.EN S.ECTICH 11 - HAZARDOUS ING.RE.D.IE.N..TS . '
.. ~
vac son te
* (C:UPAflDa' WT. MGT DprJl! tm!TS PELtM $5'E**D (IFA) - (1Lv-$10.) (MI.) seg JtC CAiCWZet 8 - CelCAL NUE CAS Kf@t i 15 L".31Mt noi !!T. W (37, O BT. 41.0 : Io EM AgDcL 64-t?-5 30%
1200k2H m 20.0 smac d
@ 5f. , of Of. 8.0 10 8 pl*.A
. test,TD Actu stLI*ATI .M1.In 135-3H m 10.9 aval W 5f. Cf 5'. 0.0 a0 8 te m W 51 sof Ef. 0.0 . to TrhtfT. MTK5!LICAi! M!rTUIE m 1H.IH $$ agn . ADI 51. @ ". 0.5 10 7-firCff SJTAQ IMH m 10%
400 een .601 BL E L E0 80 15:$iOPAgt IM.0 10 81-%-1 5% ' 250 sg/mi - 80f 51, 807 5 *.
*2 THAM 1 10.0 sg/m) 207 57. sof 51. 0.0 30 '
51 YE'LDs
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...... ........ - - - - - . SEC.T.I.ON..!.!.!.
.. .. ..PH.YS.I.
. . CAL.D.AT.A. .
VAPOR DENSITY ; .!S HEAVIER THAN AIR SOILING RANGEt i TA9-340 F EVAPORATION RATE: 1,5SLOWER THAN ETHER 6a 3% v0LAT1LEBYWEIGHT: V . ..PR.O.D.U.C.T..W.T./.G.AL....i
. . 8. B L...ES w .._ /G.AL.. (U.K.) -
. OLAT . - .LE . BY VOL.U.ME.:
.. . 85. 0.% .
F I RE..AN.D..E.X.PL.C.tS..IC.W..H.A.Z.AR.D.DAT . . .----.. . ... .. A
....... ........ .S.E.C.T.IC.N
. IV.. . .
LEL: 1.1 % FLASn POINT: 56 F FLAPT%E!LITY CLAS$1FICATION: (PENSKY-f%RTENS CLOSED CUP) UEL: 36.0 % OSHA - FLA mABLE LIOUID - CLASS IB DOT - FLAPMABLE LICUID OR SOLID EXTINGU!$HING MEDIA: DRY CHEMICAL CARBON DIOxlDE WATER FOG UNUSUAL FIRE AND EXPLOSIOre HAZAROS: VAPORS ARE HEAVIER THAN A!R AND MAY ACCUMJL&TE. VAPORS MAY BE IGNITED AT LCCATICNS DISTANT FROM THE HANDLING SITE. FLASH 5ACK OF FLAML HANDLING SITE MAY OCCUR.
~~ EVACUATE HAZARD AREA. WEAR PROTECTIVE CLOTHING USE A SPECIAL FIREFIGHTING PROCEt# ES:NIOSH APPkOVED SELF-CCNTAINEC BREA
.A.L.S.C..C.O.O.L S.U.RR.C.U.NDING..E.C.U!PME.NT A.N T.HE..C.ASE
. .----- . OF t AR.G.E . FIRE.S. . . .
....... . . . ..S.E.C.T.I C.N V....H.E A.LT H..HAZ A.R.D DA.T A.
- EFFECT3 OF OVER EXPOSURE: ACUTE Toxit!TY- OVEREXPOSURE CAN LEAD TO CENT
. DEPR lON PROOUCING HEADACHE. ClZZINEE! RRNAUSEAiAT ON P ANDL LOSSANOF CONSCIOUSNESS.
EP D (N1 A T >%Y EYE
>HCS -TED9 MAY RESUL S GHT AN F AIT NG e
M)RE R . SK N CON A ON EP LI I S. jNHALA ILNs H1
- 1 E SKIN WH1 H **Y RESULT N $K!N (RR CN Tl
- YING s [ CONCENTRATIONS OR PROLONGEO EXPOSURE TO LCwER CONCENTRATIONS MA
.M>CCA/S MEMBRANE 3. CAUSES EYE JRR!TATION Hale 1FUL IF ALGOREED THROUGH $ KIN
{;3._ CAUSE BLINDNESS IF SwALLO*ED. CANNOT BE MADE NON-PQlSONOUS. MEDICAL CCNDITIONS PRONE TD AGGRAVATION BY EXPOSURE: NCNE PR!f%RY , ROUTE (S) OF ENTRY:I INHALATIONS DERMAL. <INGESTICW
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! EMERGEN;Y AND RIRST A]D PROCEDURES:' EYE CONTACT: FLUSH.WITH WATER FOR 15 MINUTES wHILE
- 5. MOLDIN EYELIDS OPEN. GET MEDICAL ATTENTION. SK]N C04 TACT: WASH WITH SOAP AND WATER
' 1 REFOVE CONT ANNATED CLOTHING AND SMOES.CLE.AN EE80RE' USING IF PERS! STENT IRRITATIO4 IOCCURG. GET NEDICAL ATTENTION. INHALATION: REPOVE TO FRESE PROVIDE OxYuEN IF
- BREA 1DlFFICULT. GIVE ARTIFICIAL RESPIRATIO4 IF NOT BREATHING. GET MEQlCAL ATTENTION. PO!SOV!!! *
&lF SWALLOWED.!NOUCE VOMIT]NG. GIVE Two GLASSES OF WATEn AND GAG v!CTIM.
- NEVER GI k ==.
%NYTH..I NG..B.Y.M..:X.J.TH.TO..
. . .. .. . . .. AN.U.NCO. . = . . . . . .
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STAE!LITY: THIS PRODUOT IS STAELE UNDER NORMAL STORAGE CONDITIONS. HAZARDOUS POLYMEn!ZATION: WILL NOT OCCUR UNDER NORMAL C04DITIO45. HAZARDOJS DEO>1CT!Du PRODUCTS: CARBON PO40X!DE AND UNIDENTIFIED ORGANIC C04 POUNDS EE FORMED DURING COM6USTION. C04DITIONS TO AVOID: AVOID HEAT. SPARKS, AND OPEN FLAME.
.I.mNC.O .tP AT A.B.I L..I.TY . . - :-AVOID - .
C04 TAC.T WITH STRO4G == Ox!D.l!!NG. AGENTS
..n.... .- ...S.E.;T..I
. C.N a V.l .l .....SP I L.L..O.R
.. . - L.E.AK
. . . PRO.C.E..-. CURE.S.. -
STEPS TO EE TAKEN IN CASE MATERIAL 15 RELL SED OR ALL IGNITION $0)RCES. .HtWOLINC, EQUIPMENT M 57 EE GROUNDED TO PREVENT SPARKING. LA%E SPILLEDs WARNINGt FLAmABLE. ELIM]NATE SplLLS: EVACUATE THE HAZARD AREA OF UNPROTl :TED PERGONNEL. WEAR APPROPRI ATE RESPIRATOR AND PROTECTIVE CLOTHING. DIKE ANO C04TAIN. TRANSFER TO STORAGE / SALVAGE VESSELS. SOAK UP RESIOUAL WITH AN ABSOREENT SUCH AS CLAY OR SAND. FLUSH AREA WITH WATE4 AND DISSCSE OF FLUSet SOLUTICNS AS !NDICATED EELOw. SMALL SPILLS: TAKE UP WITH AN AESORSENT MATERIAL AM SEAL TIGHTLY FOR PROPER DISPOSAL. WASTE DISPOSAL METHOD: PLACE CONTAMINATED MATERI AL IN SUITABLE COJTA]NERS FOR D]SPOSAL. PLACE IN A DISMAL F ACILIT Y APPROVED UNDER RORA RF3JLATIONS Y. FOR NAZAR00US WASTE. USE AND .. . N.O.N-L.S.
.. - . . .S.E.AL..T AKIN.G..C.C.NT
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. . . m .. . .m IO.N RESPIRATORY PROTECTICN IF EXPOSURE MAY OR COES EXCEED 0;CUPATIONf L EXPCSURE LIMITS
- ACOORD WITH 29 (SECTICN 11) 'USE A NIOSH - APPROVED RESP]RATOR TO PREVENT OVEREXPOSURE. IN CFR 191D.134 U$E E]7HER AN ATICaPHERE . SUPPLY]NG RESPIRATOR OR AN AIR - PURIFYlNG RESPIRATOR FOR ORGANIC VAPORS.
VENTILATION: USE EXPLOSICN - PROOF VENTILATION AS RECUIRED TO C04 TROL VAPOR COCENTRAT IO45. PROTEOTIVE CLOVES: WEAR IMPERVlOUS GLOVES. EYE PROTEOTIO4: WEAR CHEMICAL GOGGLES TO PREVENT EYE C04 TACT. OTHER PROTECTIVE ECUIPMENT: WEAR PROTECT!vE CLOTHING AS REQUIRED TO PREVENT SKIN HYGIENIC PRACT]CES: WASH WITH SOAP AND WATER BE: ORE EATING. ORINKING. $h0 KING OR USING ; TO.=ILET
. ===... F AC..ILI.T.IE.E
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.. .m PREC.AUTIONS.
-m. - ._ _ _ _ ,
- - PRECAUTIONS TO DE T AKEN I P. HANDLING AND STORAGE: KEEP AwAY *RCM MEAT . SPARKS ANC' OPEN FLAF E.STRCNG Ox!Dl? :NG GTOAGE O . KEEDTO 4 ICUlpMENT CONTAINERS CLOSED. STORE PPEVENT ACCubutATION IN A COOL.
OF STATIC CHARGE.DRYIFSLACE WlTH ADEi,4>AT! VENTita? !ON. PO)hlNG DR TRANSFERRING l'/ TERI ALS. CONTAINERS MJST BE BO40ED AND GROUNDED. OTHEP O MAUTIOG: CO NOi WELD. HEAT CD DRILL 04 OR NEAR C04TAINER: EVEN EMPT;ED CONT AINilS CAN CCNT AIN t.yPLOSIVE VAPOK. PROVIDE R!DIRATORY PROTECTICN AGAINST SOKE AND FUMES.=
.m mm m GENERATE.D
. .mm D.JR.ING m -mo- CURNING..OR m .m mm.mu m--mm-D.U.3.TI GENERA.TE.Dm. m CU. RIN EffdP/@MWEJSIMM3 NIM 6 -3 $u %m..mue M M E3 m m = =
LR LA4 KO CrJt!DS.E ID n a cm ouT d s o
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1rFORr% TION TELEPHOrE to. (314) - d.1 r l# # DARBOLitE Corf'## (800)-424-9300 1401'S. Henicy Road CFEMTREC EPERGEtCY TELEPHJtE to. f DATE OF PREPARATION: 09/12/86 St. Louis , to 63144 .
? g SECTION 1 - PRODUCT IDENTIFICATION h
\PRODLCT PMtEn CARBOLitE THittER 33 ..
PROOLCT CODE: 01-D533-D 5 J. , 1 PROOLCT CLASS: SOLVENT BLEtO ], W 16
',' ).
SECT 1ON 'Il'- HAZARDOLE INGREDIE.NTS islN rERtDA , DmuE umTS W MMUE (TLW-TE) (PEl.) 2!!*C anMs IfGED!N (UEEL WE IF DIFFDENT) 50 pre MPE 10.0
>11
' # Uni!C ifG0CMD! )lt ilX) pps IDE 12.5
' 1 fEEKY 24RMK1. (FRTILDE E.YCH.100 EML EHR) >1%
!!Eppa 10E 0.5 DifRPitDE E.TCQ. IDDEML EMR SECTION 111 - PHYSICAL DATA ,
WP T ID EITY: 15 ENIER THW A!R. EATILE BY ElH 98 - 1 2 BDILIPGIUNE: 748-363*F EMRRATION RATE: 15 EAER TWIEMR. MLATILE BY EIPE: 99 - 1B MIEDIE!HKA10D 5 - 8 LIE.KA.. (l!.5.) _ . EECTION IV - FIRE Ato EXPLOSION HAZARD DATA FUGl R)1NT(PitI): 91*F LE: 0.9 FUmBILITY QEIFICAT100 (09%): - FUmEE LIED - QE IC (00T) - FUmRE LIED W SLID EXTIM9fifG PEDIA: IRf DO11 CAL. 1Mful. FIE #0 ER5104 H;ZARD: KEEP CORA!ES T1HLY Q.EED. IEIATE FRm EAT, FR3, ELECTRICA. EMPlDA #0 094 FUtES. Q.EE CMAlES MY ERIIE WEN DPEED TO EGEFE EAT. SECIAL FIEEFlHIE f90CEIUES: W mY E (IED TO COL CMAIEPS TO PREN FREEUE MllMP #0 PE51BI ARD-I
'JREED TO EGEE EAT. IF WATER 15 LEED, EPRAT 10Z2LES #E f5EFEREE. ETER 9 HAT MY E If0FECThE.
I EECTION V - FEALTH FMZARD DATA IfHLAT10CillRITAT101 TO E IEFIRAimY TRET,)D00E DlZIIESS, #0 tRIEA #E PE5laf. KIN CHACT ffff ETETS 7 OIR DPOELE: IRRITATlat. EYE CONTE 1:PRl!9RY 1RITAT100 ECA. C00!T106 f90E TO GPAATION BY DPEUE: llectL FRI?fPY RME(5) 7 EMRY: IPHLATIOL EPEEDEY #0 FIRST AlD F90CEUE5r !!MLAT100R90E TO FE91 NR #0 RESTOE BEATHlfG. TREAT SYtPTOMilCAL CORET,E@E C04TIPG VITH ELW. AftEDIATELY l#94 AFFECE #EA WITH SDnP #0 ETER. COGLT A MSIC CORETrF.LEri 1*fEDIATE.Y W!TH LF~ MmRS T WiE fm 1* FE 15 NfUF.. T4I TC A MS IMEES T %G T') Dit' lie. C0 * ;i t ric'3MM M. At i A r ':!Cl#w 5!!DI C0lR2. CENIE. -
---_..~ ~.. _.. - .
ECCT' d - W. CT1.'ITY UAiu ICEIIS RLTERIZATIOC Vit.L POT CCI1R LNER 10ryL C001T106. STA81LITT: MS PRI1ET 15 STABI ttEF. t0ML STOME C0011106. M?MIIS DEC0HSIT104 FRELETS: C#EDI FUCXIE,C#E01010(10E, #0 PO!Ela.Y ALIDifE5 COOli106 TO A010: AS) mi FRI111 fufS MN EAE TO ECOREli!m, A6 IN tELDifG. FlfE3 MY CORAIN OKITS & tETALS L 6 I ~1PC0f%TIBillif (f%iERIAS TO AU010): ,POE IEDIE.Y FTEEEMI.
'. 01-0533-tj - u//12/86 j ,,
PA.iE %
'~
- SECTION Vil - EPILL OR LEAK PROCEDLRES .['@!Y 2 TO E TREN IN DEE 5H14. IS IELDED E Fill.ED: ACID EFEATHIE SUENT WUS. DGE #B1A1E WILATim. ACID )
I ME Wi101 CI11D CAIE FIRE. i@ D!!P54. PETKDi SK LlallIS WiiH sat 1ET E lime #4RDDE. fl191 WITH EU If PEEllLE. A010 ! KIN (INIK.T M Diggg & IN O LKA., STATE #0 IIDOUL REELAT106. p EECTION Vill - SAFE HotOLifG APO UEE Iff0Rf%T ION f ?!IRimi RIOTECTim: N1091A&M NY9tMD REFlRim TE5 SjlTMLE Fm MTERIA.S INECTim 11 IEDf9GD. #9RDAD 0911CA. PEDWICA. FILT9 DfDED UfN WilATlDi IS E51 RICE. Sil.ATIOe SFFICIENT WILATION, IN Mille #0 f% TON, 901D IE 190 VIED TO EEP AIR UNIAftHATIOiIEN Q llENT NTLICN11 (B UlK LIMIT E JCEll'S TLV LIMIT LISU IN ETIQi !!. HECTIE EA6 fEECTIE E.0KS REIDf0ED. 1 PROTECT 104: 09tlCA. EIBES WITH S!E 911EUE m FACE 9(185 IEUTOED. , CD Ml0TECT!E E211Refin 190ETIE ODrS #0 QDiHis REID?OED TO A010 ! KIN CDliACT. [DiltRET!ES: WGi HHE EFGE EATIE 90'IPG W (EIE ilE RESEU1e 901 IN DESIGRE #DS 00. __ _ SECTION IX - SPECIAL PRECAUTIONS IAJT106 TO EE T#'.EN IN HHl.!E #0 SimitG: STOE MTERIA. IN A Cal. CRY #EA W!!H WILATIOl SJIT41E O 19Etall106: FUlDE REPIRATmf f90ET10N EAlET 901 #0 FlfG EEAE OLRIE RRilE OR DLSIS IDOME DRifG 29 CFR PARTS 1915,1916, #01917 IE211RE TFE 19EFARAtlei r THIS mIERIA. SVETY DATA SET. f
Form E010B
~
COATING / THINNER DATA FORM Company name: LUVN d(dBR. f(Jil7~ Dol W YALL.21 v7HOtt14 Applicable APCB Certificate #: D/T b h///7~ NYhM) Product Name: Phnouese s os # < aca.
' Product Manufacturer: [JRh/A/F Oo /AAdNY ..
Usace Data Daily (gal / day): O*OI Annual (gal /yr): -$ Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: N MMM bbb As Received (Concentrated): Density (1bs/ gal): /Ob Solids % by Neight: 72.5 % by volume: 596_ Voc 4 by Weight: 27.5 % by volume: 4a5 Water % by Weight: A/ A % by Volume: ... As Applied (Diluted):
/.* / $)
Density (lbs/ gal): -% by '/clu;r- ,. Solids % by Weight: W % by Volume: bO , _ VOC 4 by Weight: 27 % by Volume: h Water % by Weight: MA % by Volume:
' Thinner Data Chemical Composition: 6etW7/T OCD4D Density (lbs/ gal): [f . b Mfr. Data Sheet or Certification is attached. Yes 40 _
i
*For NSPS Sources Method 24 must be used.
This is to certify that this information is tru_e an4' om ete to the best of my knowledge. gM W /) Signature:/ XFUdd tittfl IL/ T1tle: t/d % d 'er B m n aw I ris c Qatr4 11/03/89 c _-____ _ ___ Ew _ _ ___ _ _ _ __ _ __ _ _ .___ __ _ ._ _ _ _ . _ _ _ _ _ _ _ ____-
p ;; IPNORt% TION TELEPHO E to. .(314,) 644-1000 ,
. CWSOL itE CCFFANY '(BOO)-42t-93DO t 1301 5. Hanlov Road CEMTREC ErERGErCY TELEPHOrE to. ef
. St. Louis, fV 63144 DATE OF' PREPARATION 'D9/i2754 T i y
SECTION I - PROOLCT IDENTIFICATION g7 PRODLCT tMrE:^ PkbOLitE THitfER
^'
#* ' ()/
PRODUCT CODE: 01-0505-0 PRODLCT CLASS: SOLVENT BLEtO SECTION 11 - F%ZARDOUS INGREDIENTS : tE1911 EEDil DPQUE LIMITS WPOR REEUE l (TLWim) (FEL) 20*Cashh l- IfGEDIENT (LAEL NWE !F DIFFUEt#) r - m ,. <m _
- - CON >11 100 m 131 m 21.0 g (O GE)t'
- ffL-24D#0E , >ll 50 pre UE 4.5 1
WitoiY:2-fMR (ROPfLDE E.YUL fD0 FENTL ETE) JUL 6 1987 >1: am POE. .LS. 1
', >1% 131 m !!D m ' 7.5 YlHfL IEMDE JARGRTIC HfUl0CNEDI) 25ppe 50pps i
)l1 0.6 .
1 7tl>0(Y B1140. (ETHrtBE E.YCII. 700 BJTYL ETER) , SELC,T,,l_.ON 11,1,, ,, PHYSIC /L DATA _ WLAlllE BY LElH W - 1001 WPT (D61TY: 15 ENE THH A!R. IDILim R#E: 748-340*F MIKD kElHKAiO4 5 - B tlE./CA., (t!.SJ tu.ATILE BY tu.LfE W - 100L EWTATION RATE: 15 E.061HW ETU. SECTION IV - FIRE ArO EXPLOSION HAZARD DATA FUGi POINT (RTI): Ti'Fk LEL: 1.0 FUm%1LliY CLM51FICAllCN: (03%): ,FIAtWLE LIClllD - 0.#5 IC g (DOT) - FL#fW11 Ll(1]ID 2 SI.!D EXIIG941tG ifDIA: 0RY 001 CAL. LMfDL FIE #0 EE.E101 HORD: KEEP 00NTA!!ES " TIMLY Q.0EED{IS1 ATE FROM EAT, 9WKS, D.ECTRICAL EERDli #0 UNTAltDS mY ERDE 001 EREfffEYisdEAT.~ r 9El#L FIRE:191TlfG IEEE!!ES: LAS MY E LEED TO C03. C0fiAlfERS TO REW FRSELRE MLDW #0 PGElaf AlIO-1
- DFCEED TO EXTEtE iEAT. IF kAE 15 LED, EPRAY PEZL!3 #E REFDi4LE. ETER EPRAY MY E IfEFFECTlW. ~
~
SECTION V,- HEAL 1H f%ZARD DATA , DECTS 7 06 EEEEi !?MLAT10N:lRRITAT104 T0 ilE E!P! RATTY TRET,EDDE,0!ZZIESS, #0 ffLEEA #E PGElEI. ! KIN COUACT FRIN8RY ' EllAi!04. . EYE CetTACT:FRitpRY 1RRiihi!N , fGICAL C00li106 FEFE TO KIFAAT101 BY EEHEi UttD.N. E!TRY R11TE'S) 7 DURY: EINAL #0 IHLAT101. . E*f2DEh #!) F!P5 A]D ROG*1ES: ItWLATD:ESE TO FFai A!R #0 ESTEE EREATHIE. TEAT CDITORODE CCA!!?G W!iH ELWNI. !rtEIATELY t#Gi AFTEtiED #EA W1TH !D4P,#0 kAE. CORLT A RifSICl#i IF. liRilATlDi ERSISTS. EYE T O P.!Sf! Pre:A.ILY VITH 'RE AttufE 7 LTU FT AT LEtST 15 Mif0TES. WE 10 A RifSICl#N fm fEDIC#L
- TEAffD i!.iE 7 A'F TC D!.ifiE. DC 'OT ltDIE vmliffG. COSii A Rf!SICl#1 m PO!!01 C0iiR2. CENE.
SECTION VI - REACTIVIFY DATA HOR)0LE RI.YSZAllCN: V!LL PDT OCQR UCER 70NL CD0lT106. Sis 6LITY: Tril5 IHOOLII 15 STMLE UE4 tum. STmKE C00lt106. HOEG.S ECQfEIT101 PR00LIIS' CARBCN rDOKIE,CNEDI 010XIE, #0 RE51a.Y ALIBES. 401 EATED TO EC0f%lT!Qi, AS IN LELD!$. FUG f%Y EDUA!N OX123 7 ThtS LISTED ,[ CD011106'TO A010: #.5) f%Y FELEE FL i _ _ _ - _ _ _ _ _ - _ - - _ _ - - _ _ _ _ - _ _ a __
m __ SECTION Vll - SPILL OR LEAK PROCEDLRES __ 5
. 595 TO E T#Di IN CNE MU14.15 PSINED E SP!L1D' ACID IREATH!!G ELW wpm 5.INkk'k52 RTE WILAi!E.[ M ..,,#ff1Hl$ HE CnLD C4fE FIE.
w61E Dl! PEA. PETKD: DK4)alllE,W11H SEST.E RE #0 RDDE. FLIBi WITH W4E 1F PO!Ela.E, MID 9;1N CONTET #0 01
- r.k Ji:lH11T.4.sSTATE #0,FEDEk1EihM106. ~ ~ '
SECTION Vill - SAFE IMDLitG AfD LSE INFORMATION
' liDPClarf IHOTECTIGO' N10!H/M #Y904D IEPhlATE TYR5 EllTE FE t%IER14.5 IN Eilai il RECOTOED. NYROA IEC0f0GD MN WILATION 15 IIESTRICE.
Wii. Ail @ 9HICIDG MILA110N, IN RtPE NO PA19% 901D IE 190/IIED TO KEEP AIR COUR11tA1104 IEl.0J CLRRENT #R.lC#LE.09A FERM DRElllE Linli E Gil'5 TLV LIMIT LISE IN ET10N 11. I 1 IROTEtilE E.Cl458.g!EE}N!IdC0h0ED. .
~
E1EFH01ECT104: gl,ChEiUl,E EIE T $1815 W FEE 9tlELDS EQtOED. 018 790ETIE E111PPOR: ilWOTECTIE'CHE#6 #6 CLD1Hl$ llECuff0ED TO MID 9:lN CORETl ffGalt FRETICES: jWiEiiIfMEIEFUIE EA!!!G, 90;ItG W ISitG TW RESTRDOM, 90I IN DESIGME # LEAS QLY. / SECTION IX - SPECIAL PRECAUTIONS . MECulas TO E IMEN IN HW1.ltG #0 STEltG STEE t%B14. IN A C03. EY #EA WiiH MILAT104 SJITE FE STEltG MTE 11. OTE FRECM106: FR0/IT RE!PIRATEY PROTECT!al Git 6190'I #0 FlfE5 GDEPAE OLRitG RINitG E RETS GEER 29 CFR PARTS 1915,1916, #01917 FS231E TE PREPARAT104 7 THIS MUla. SfETY DATA SET. r B 6 8 e ah .
~
. .. j
- . t%TERIAL SAFETY DAT A Sr-EET FOR COATitE5- lu.i
- >116 MJ kcwcu micruA_m
!. . ., t' . ' ' ' ' ~ CARBOLitE Ccrf ANY ltFORt% TION TELEPHDtE to. (314).644-1000 1401 S. Hanicy Road CEMTREC ErERGEtCY TA FPHDrE to. (800)-424-9300 St. Louise to 63144 DATE OF PREPARATION: ,09/12/86 SECTION 1 - PRODUCT IDENTIFICATION l/ PRODUCT tWE P$tOLitE 305 PRirER~ PART A PROOLCT CODE: 01-0606-A. PROOLCT .tWE PEtOLitE 305 PRitER PART 7 PROOLCT CODE: 01-0606-B PROOLCT CLASS: POOlFIED PHEtOLIC SECTION 11 - HAZARDOUS 1rGEDIEr#5 ERSK LIMITS wpm RESUE _ . ElGli PDiGNT P#ii A PETB MIED (TLW-TM) (PEL) 2D*Cus/He IPGEDIENT (LMEL NVE IF DIFFDENT)
>n Y1h >11 50 pre 1El pae 10.0 HETHfL-2-ENT40E (PETHfL lEHJTYL ETOE)
>n >11 >11 231pps PDE 2.0 W L P l#FTm (NYHim)
)3 )11 >11 5 pas 221 pps 3.8 2 ETFUKETHWL (ETHfLEE E.YDL 700 ETHfL ETER)
TQ1.DE )n '01 )n 13)ppe PDE 'B.O 01 )11 >n 23) pre 2 pps 90.0 ISORPNG. 01 >11 )11 1ppe PDE 1.0 DIETHflDE TRIMIE (GL MIE) 131 pro XYlBE . .
>n E >11 15) pre 21.0 01 >11 ).11 IDE PDE 8.0 ' 1:3 DIMiloWF#E (EL M!E)
R90. 01 >11 ).3 5ppe 5 pas 0.2 N N,N' N'-TETiWEiWft-13 BJi#EDim!PE (EL mlE) 01 >11 ).11 10E JDE 2.0 TE F310/IE 11ST DPEUE POTENTIA. 011D EXIST AS tGWL 115T HWE m WEN IDD/ItG QED C04 TIE BY (RY /GF610N fETHDS. R)TMEM AIMDCSILICAE - MICA (MICA) )11 01 )n 6eg/s !!ss/s POE
>11 01 >11 1%/s 1%/s 10E CAfle A1MIM SILICATE-rAllN (QAY) 4 SECTION 111 - PHYSICAL DATA RATILE BY LElH 26 - 2 % W P m (D EITY: 15 EA/IER THH AIR. !!DILIE R#Es 173 - 3D*F VaATILE BY E1FE ?? - 121 EWPmAT!W RAE 15 SDR THH ETER.
MDED LElH/CA.LW 9 - 12 LIS./GoL. (ll.5.) SECTION.IV - FIRE Ato EXPLOSION HAZARD DATA f FUfW61LITY QEBlFICAil@ (GM): PT. A - FUfM8.E LlQJ10 - Q.#5 IC FLA91F0lNit(PMI) FT. A %*F LB.: 0.9 FT. B - FL#WELE L12J10 - OKS IB FT.8: 5t'T (00T) : PT. A - FUrWEE L12J10 m SLID PT. B - FUrWEE Ll2110 m ELID EXT!?GJ1SilfG E!A TY 0911CA.: 28 F0G CR OTER fEDIA SJITMLE Fm SLWNIS IN SEETION !!. LN.SA. FIPE #0 ERISim H47APDr EP CHAltG5 TIGHILY G.0ED. IEl. ATE FEM EAT: SP#!KS: B.ECTRICAL EDJIPPENT #0 CPEN FUfES. U.(EED , CMTADOS mT DPLTE WEN EEIED TO EXTiDE EAT. 9'EE14. FIREFlHIE PPIEDLES: mE MY E LEED 10 C03. (DNTAIPUS TO REWNT REELFE BJ111HP #0 PEElai AJIO-lWITim E D JRIE': TO EXITfE FAT. IF WE 15 l'ED 99AY P0Z2LES #E FEFEPE.E. mE 9: RAT MY E IPEFFEEilW.. f IZ10< 4 V - FrALTH FAZARD DATA EFFETI & OG DP09E IM1ATI@!E! TAT!W TO TrE RSPIRATTY TRlCT E/00E,012ZifES, #0 fMEEA #E PGElaE. E!N CINTET:fRif9RY 1RRITAT134. EE CONIET:RitWRY 1RRITAT104. 2-ETRAY TrWQ. #0 2-ETHKETHWL KETAE CM E MEDEED AFTER OFL: EIN, m MILATICN DRXUE:
- 0 CM CAIE TCKICITY IN 1PUERN4. mG96 SDi /6 EIID LIWRr K10EYS,#0 TE5ES. SPE STLDIES l@CAE LDG-TERM OR0(IC DF 'dE GETHK1ETHWL #0 2-ETt00ETHWL KITATE MY CAE REMGLETIE DIEPJERS. M.KYL ml!E5 (i.e. DIElHfLDE TRimlE) #E EIN !D
" KIN UNTACT #0 IPHLAT!Qi BY kDRitG #RPRIATE FEDIECT!W Q.0THifG, REPIRATUS, #0 EYE FROTECT!m. .
=:....' - -
.: " c em '
ElCA. CD0lT106 RDE TO EGWATION BY ERRE: LiedN FRlfYRT RQJTE(5) 7 ENTRT: IERMIL #0 INMATICN.
iwr. t
. t-01-0606-A/08-0606-B - 09/12/86 ._
SECTION V - FEALTH HAZARD DAT - - e ant .
?
K.Y #0 FIRST A!D f%CHIK5: !!MATim:le0E TO 11E91 AIR #0 RESTEE BEATHIE. TEAT SWTQ%tIW.Y Gr TelO0E CDATIE WITH SLE. IffEDIATE.Y WGi #FECTED MA WITH !DP #0 W.
- TSBi 5 7 IMTER litEDIATELY WITHlla.E TO DIlllTE. 0010T UPE #0. HTS Mrft!T!!G. 7 VIER CDGLT FE AT A M51Cl#1 m PolEN LEE 15 CDER1 MIMITES. CENTER. TV 3Me CR KCIENT CAL DOGE l-SIH24-Y3D DAY T HIGE. ' '
' SECTION VI - REACTIVITY DATA __
M2#UIS KLTrERIZAT104: Will foi OCDR LtER KRM. CD LITY: THIS FRIIIT IS STE INER 10tW. STGUE C00lil06. dab CEIDftSITlDi PfmCTS C# EON FD0KlE,CNB01 DimlEs #0 PElB.Y 4.IDMES. T106 TO MIDI A30 MY fRILE fitES EEN EATED TO EC0fE!Tims Mi IN 1 f'AilBILITY (mTERIAS TO MID): 10E IEEDNLY FUEEEEE. SECTION Vil - SPILL OR LEAK PROCEDLRES MID IFFATHIfG SLW WGS. EEE #E2 ATE WILAT!W. MID EPWS, FL#E5 #0 E TO E TREN IN CME MTERIA. IS IE1DED m EPILLED: klfG H0iCILIS CAEE flE. SX LlQJIDS WITH S40l5T E RE #01904. FLLSI UlTH M lt 802i12I. eld 9;1N C060 #0 I DISPTA. PETE: LKA., STATE #0 FESUL IEllAT106. SECTION Vill - SAFE FWOLitG AhD LISE ItFORP% TION uQ NICSi/0EM #YHWED REPIPATE TtES SJITEE fm MTERIAS IN SEti
- !RAimYf90Eil04:
2f0ED 001 WILAilai IS FESIRICE. I!!AT101: RFFICIDE WILAT104, IN M1.lfE #0 PATEIN, 901D E PR0/IED TO KEEP AIR CDAmila GLE LIMIT E M'S TLV LIMIT LISTED IN ETim !!. ETIE E.045 fROTECT!W E.045 IEDf00ED. f
- FR1TECT104
- #0011CA. GmIS WITH SIE 911EIS E FKE 9418.C5 IE0 feed.
O FEDETIE EMP!OR: F90TECTIE HENS #0 CLOTHIE FEDfDED TO MID 9:lN CDUKT. Wei FWOS tire. EAT!?G !MKIE @ [51E TE REST 2001, SUE IN ESIGATED #ENi OLY. Jalt F9KilES: SECTION IX - SPECIA PRECAUTIONS STGE MTERIA. IN A CCQ. IRY #EA WITH WilATim SJITRE FE ECAli!06 TO EE TWEN IN tWQ.!!G #0 STTitG: IER 19EIM106: fME REPIRAimY fEDEil(N KilET 901 #0 fl1ES BEPATED DLRIE B i 29 7R PETS 17:5:1916 #01917 RB2JIE TrE f9E"#MT10f 7 THIS MTER!A. SY
~
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Form E010B COATING / THINNER DATA FORM Company Name: &ranoYAH nudie 21L LASIT [ENkl&W YAttty lt/Tib'lG Applicable APCB Certificate f:' MCF" f.XIXr' kalTT b@UY ) Product Name: l-VENT ~7IIIA$D S72/N Product Manufacturer: .b46JM/N' NMRE' b llg.gge Data Daily (gal / day): Os O[ isnnual (gal /yr): _6 RuJe 25.43 & 25.44 Analysis or Manufacturers certification Data *: M /7-rAugt) h$$ . As Received (Concentrated): Density (1bs/ gal): 7 Solids % by Weight: 2O % by volume: l1 VOC % by Weight: N % by Volume: M Water % by Weight: ^/A % by Volume: As Applied (Diluted): gA4 c. AMC Density (lbs/ gal): % ty */elmue; Solids % by Weight: % by Volume. VOC % by Weight: % by Volume: Water % by Weight: _ % by Volume: Thinner Data Chemical Composition: A/M Density (1bs/ gal): i Mfr. Data Sheet or certification is attached. Yes i o
*For NSPS Sources Method 24 must be used.
l This is to certify that this information is true and completc *o the ,. best of my knowledge. q A // / ) 1 Signature:/
- bid tut [lM/
Tit 1e: h4MGOL Of thWPnNMLN7DL (Othin'f 11/03/89 RMP
i - HN.0'399 i l MAIIRIAL SAFETY DATA SBEET - NPCA 1-84 mR amDcS, nESDE, 3Ne REtA2ED MATER 1Aw F REPIACES NKA 1-82 MNMFACItJRDt'S NApr fECENED EMERGDCY TELEPHCNE !O. Benjanin ftere & Co. . SON, 51 Ches".ut Ridge ibad - (201) 344-12tn etntuh . tw Jerrey r%i3 ,'jjJ 9 y) EAIT CF PREPAFATICN + July 1987 INFCPMATICN TEIIPHCNE PC. SUPEPr5m March 1986- , !(201).344-1200: SECIICH I - PBOCXJCT IDDCIFICATICN [ -
.f Moor 's nterion ltod ,Pe PPCIIX.T Nt.NBE$2 241 20,21,58,59,60,62,64,65, PIODUCI NMtE:
'67,68,69 'SthE . gf "
- j" ~ . pet'Ar.iggs ' ' '
\. j_ w.m . -
PRODUCT CLASS: Solvent' Thinned Stain SEETICH II - HAZAprIIJS IIGREDIDCF-1 OCCUPATIONAL EXPOSURE LIMITS VAFOR CASI PEPCDC TLV PEL PRESSURE DEREDIDE NAME d 111-76-2 6-14 50 ppn 100 ppn 7.0 m,1t;. e 25* Ethylene Glycol te..ncb.ut.ylf
- s. ... ,
g . ,
'Nineral Spiriti 64742-88-7 67-75 100 ppn SCn ppn ,1 <5'.0 m 112.'. 100
*FFYYHMDJDED BY SUPPLIER.
StruCN III - PHYSICAL DATA POILItG ENCE: l313 - y3,88, F,[ VAFOR DDEITY HEAVIER LIGITER 'DIAN AIR EVAPCRATICN PATE:, FASTER SIfWER THAN E'DIER % VOIATILE VOLIME 88 WT/ GAL 7 lbs. SEXIICN IV - FIRE M4D EXPIDSICH HA2ARD DATA OSHA FIASH POI!C LEL FLM4 ABILITY CIASSIFICATICH: Cotustible liquid DCTr X 110 F 1.0% CO2 ERY CHEMICAL WNIER FCC CIHER , EXTItCUISHI!G MEDIA: FCAM "ALCCHOL" ITAM UNUSUAL FIRE AND EXPLOSICN HAZARIS: tbne SPfrIAL FIREFIGCDG PBOCEUJRES: Eb rot use water streau on burning liquid. Cool exp3 sui containers with water. f SEXIICN V 2 HEALTH HAZARD DATA eft u.m CF OVEREXPOSURE: 1 gestion maypiause, narcosis Eye Contact Primary irritation.... ,. . Animal studies have showo ingestii'oi'6f YtKy'l'sne'4deid, WhigW feddIs'MYcuse 'c' ends 1*,ne'rvou5 ' systen,' kidney'/lbfo6d?ns#possibre[ liver , effects. .m.' ; MEDICAL CCNDITICNS PRCNE TO ACGRAVATICN BY EXPCFURE: Unkrown
- . .+ ,
.. ^
1 PRIMARY ICXJIE(S) OF DERY: ' CERMAL 'ItalAIATICH IICESTICN-t.
...... - .::rs EMEPGDCY NO FIRST AID EM mfRES: If swallowed,. immediately-giyep14fg23 glasses *of water'and { .
call shysician, hospital,.emengency f6 sin'lot[Polidi.'CintrOf. Cente6kcMimpt6Anduce ycznitilFx~gg' i case 'of eye contact, flush with plenty of water cIf"irrithtien persists, consult physiclan~. GEP sk:n centadtyuditieff fwith mild soayandzwater;"- ,. 1
~'.
f Su. A104 VI - FIAL.Ai1ITY DATA STABILITI: (NSTABIE STABLE ' HAZAFrnM FOLYMERIZATICN: MAY CCHIR WIII fur CCCUR , ( HAZARII:US DEEDGCSITIQi PFCD)C'IS: Burning may prcduce carten monoxide and carbon dioxide. CCNCITICNS It hVC:D: tbt Acclicable FECENED SON INCOMPATIBILITY (MATEI,IAJLS 'IO IN II ): 1 J '. t 'lic @'ns gg yoop ; i SELA ACN VII - SPILL OR IIAK PIO.r udRES dan 'IO BE 'DKD1 IN CASE MA'IERIAL IS RELEASED CR SPILIID: Bemove all sources of ignition. Avoid breathing vapors. Use non-sparking tools to return materials to containers. Absoru-residue with Fuller's earth. ~ WASTE DISPCSAL MEIlO0: Conventional procedures in ccttpliance with local, State and Federal Begulation. Ce not incinerate sealed containers. SECTIQ4 VIII - SAFE HN4DLIIG AND USE INFOIEATICN FISPIPA'ICRY FIUr:ITICN: Use NICEH approved respirator specified for protection against paint , sprcy mist and organic vapors in restricted or confined areas. VDtrII.ATICN: Adequate to maintain working atmosphere telow T.L.V. and L.E.L (See Section II fce I irgredient data and concentrations) . Mechanical. exhaust [may be required in confined area. Discharge exhaust: only in area away ftun ignition scurceh. PRCTTECTIVE GIDVES:.i Ecquired durirg re,peated contact. EYE PfutinuCN: Safety glasses to, protect against splashesM CIHER PRCTrDCIT/E D")UImElff: 'Cicthirq rdequate to protect'skiri7 HYGIDlIC PR/CTICES: tot Applicable SECTICN IX - SPECIAL PAfDUTICNS PRIGLTTICNS TO BE 'IAKIN IN HANELI!G hND S'ICRING: Canblutible - Keep away frtzn heat and flame. ~ Harmful or fat.tl if swallowed. , CDIER l'RECAf.TTIQ4S: Use only adequate ventilation. Avoid _ prolonged contact with skin and brasthing of vapor or spray mist. ' Close container af ter ,eacti,,,use! Keep out of the reach of children. Ib not take internally. torICE: Feports have asscciated pemanent brain and nervous system damag$ with repeatedmisuse Intentional prolonged by exposure to solvents moung perscos ergaged in the painting ' trade. f deliberately concentrating ard inhaling the contents may be harmful or fatal. l 1 i - _ . _ . _ - . _ _ . _ _ _ _ _ . _ _ . _ . ~ . . .
Form E010B COATING / THINNER DATA FORM _ Company Name: htOfLQY4l'I t/dLd/E /AAIT h 444&y MlQ Applicable APCB Certificate f: MMCf bCMr kdM 6fkAY Product Name: VA8h'/Sh' Product Manufacturer: YM/74k//M NI b Usaae Data Daily (gal / day): O. O[ Annual (ga2/yr): 3 Rule 25.43 & E5.44 Analysis or Manufacturers Certification Data *: h /7pggtb $$ As Received (Concentrated): Density (1bs/ gal): b solids % by Weight: % by Volume: O VOC % by Weight: b/ % by Volume: 70 Water % by Weight: % by Volume: As Applied (Diluted): $34(r As /ta/F Density (1bs/ gal): % -by */clume ; Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Dalg i Chemical Composition: censity (1ba/ gal): Mfr. Data Sheet or Certification is attached. Yes_ o l
*For NSPS Sources Method 24 must be used.
This is to certify thst. i.his information is true a comp ete to the best of my knowledge. p, / ,) Signature:/ '
. wl>ll/A>
l Tit 1e: MAM46& of Eh%PeNMOITAL Nt.h@ 11/03/89 RMP A
-..~-_-~____._m
7 .iK.~in',C 3 ~ MATERIAL SATETT DATA SHEET NPCA 3 54 TOR COATINGS, RESINS, AND RELATED MATERIALS .f.j!.*.C1303 REPLACES NPCA 3 62 .. E".EkGENCY TE'LEPHONE NO. MANUFACTURER'S NAME Br, w .njarigore MCo.' .f ' MM I.'.lh0?
/ ,s. a.w...
ST*Ehestnut Ri dge Rd. , Hent valt . .E.J. 0761) INFORMATION TELEPHONE NO. LATE OF PREPARAT)ON m. - ...
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.([.14. .f.t.E'._3 2003
.... M. - m %1 ;Lr'5hw.9
- . . . .6. 6.'
SECT 3ON 3 . PRODUCT 2DENTIF3 CATION - - . .1.vsr- - - _ - . .
~.
. ..... . . - O.N 5 Y PRODUCT NAM PRODUCT NUMBE mw PRODUCT CLASS
............ .....v.....................................................
r w.nisnu SECT 3ON II - MAEARDOUS INGRED3ENTS
.. .. .. . .. .. VAPOR-PERCEN't OCCUPATIONAL Ihf GRED I ENT EXPOSDRE L3MITS PRESSURT
# # TLV PEL _-.
6657 100 ppm 500 ppm 4 5.0 m 4 6t.7t.2-BB-7 @ 100 F s 48 iFiEi' k.i. unee.aI ~8 A. W h a .* A PBTSICAL DATA SECf]ON :I3 VAPOR Dl:NSITy H r n'1 r s L* GHTER THAN AIK BO) L 111G rat 1GE N.13.Fg m wrt rum rrwrr % VOLATILL VOLLME 70%
EVAPORAT J ON RATE TASTER Wr/ CAL 7.3 lbs.
- SECTION IV FIRE AND EXPLOSION HAEARD DATA OSHA -
F L ASil POINT LEL
.f.t Aom1ABI: , i s.sSS:TICATION ^
f'"D~ddSTe NqEd' . DO~ ____ h0,1 f -1.0%
*:fDCT1MGt!"!SHI NG MEDI A: DFY CHEM 3 CAL bATER IQG. OTHE*
" ALCOHOL" _CO2 pa w FOAM ,
LIN tlSU AL r3RE AND EXPLOS20N HAZARDS NONE
- De not use water streatn on burning liquid.
SPEci At. rJRErIGHTING PROCEDURES Coo) exposed containers with water.
- SECTION V- IIEA LTH HAZARD DATA _ . . . _ _ _ . . . . . . _ . . . _ . .
Ef7ECTS Or OVERExroScHE - It.halation - Respiratory trritation and :enttal nervous syrter. effect - Anesthe: c. Skin and Eye Contact - Frit ary irrit.::1en. MENCAL, COND113 ONS PRONE TO AGGRAVATION BY EXPOSURE: ..
'M r.ov, Mrt- W [yWHEL'E7jogM 6p'djST.10N'* w PRIMRY FOUTE(SI OE ENTRY: Sn.r .'.sM. e emer 4T PROC ED'JRES . Ir.halation p emoyez weirdMM$76tdareamgaakste'rweverpf njg EgtRGgtJ CY AND FIRS 7 AID - . - - r oggarnp7e 1 er r--- # ' ~ ~
M s... a h El% su rs.M..a..T.
..............~.....................q...................
- i. _.............
SECTIOW VI - REACTIVITY DATA g ,
'7. '
l- - --a - . . .- T Y ' UNSTABLE #STAELE . I ' . EfA26RDOPOLYMER l US 11ATION MAY OCCUR WfLL NOT 00CUl__ H uARD.>trS DECOMPOS 3 T I ON PRODU275- -
--81Nttte ,say produce carbon dioxide and -:arb:n m: nexide .
l "CC)ft Da-CIDNS TO AVOID - i .
- I
.- N:t A;;.lica.tle
. MAT'.. .*J B 3 L I T Y (MATER 1ALS TO AVD1D) -
l ( A'*tS ~,a.d.:wOpr.D Rab 3 e .. SECTlON V31 - SP2LL OR LEAK . PROC EDD R ES
......'...............................................................S.... - - . . . . , m v - c -- - r r..
,,,C 7. .,5 M_.Ol*,9 EIl,7Ah.E.Ed, rig
.. .@.M24M.L.MMMUNEMb S C, ~. . ..r
, m I- M - gE'., .
Remove all sources of ignition. Avoid breathing vapors. Use nen. sparking tools te ret urn materials to cont aintr. Absorb residue with Fuller's e orth. VTAS7E DISPOSAL ME7 HOD Conventional Prc,eedares in co .;1 an:e with Joea), state a.nd feder43 _ regulations. Do not antanerate sealed contaaners. SECT 3ON V111 - SATE HANDLING AND USE INFORMATION .
............................................................................. .ee.---.y..,.,,_,m_
RES P 2 E A70F ). PFO;E. 710N se N:orgre;7. ret ed res;'ir.a*or 'speci fied f or proteet zen s;ainst point spray rr.ist and crger.ic '*vapirTsr.' res t ri ct e doi ~ck. fine d are as . V ENT IL AT I ON Adequat e to rnaint aar. verking atn:, spher e be 3ov 7.L.V. and L.E.L. (Eee Se rt ct. 3: for ingrecsent dat a and < con::e,71.r a ti ons ) fr.sv be ,r eq.:.af.e d . .i n cfr.f a ne d a r e s t PRO 7 EC7 3VE GL0YLS M)sXtarReh%d. hgp Me:ha ical ed.auste'ags{;f Ep[hn,i,, tion' jeu , Required daring repeates cor.t art. t y t P R OT E C T 1 ON ....,,. . m.n re-: n v. . a : - -~. 7 T .s..U. e t[91.a s,st ae s t;0.PI.: "CE'"I* * "* 'N"y* 8 * * .
~
O. H E R - F D E.C,7. 3 E. ,g ,.g 3 p w g g *-- 4,ry.,- - y._.. f.1g"c'*l oth,, , ng; a de - qu. a e.....'s.t .o~pr . ot. .e ct . ski n Hys)ENIC PRACTICES: Not Applicable - ; SECTJON ]I - SPECIAL PRECA07)ONS . PFICA?7) Ore TO EE 1.AFEN 1 N HANDL I NO ANC STOM N*-
~ .. .
Cor.: ;* tit le ' Kee; a 'sy fic.- he'at and fla.e.
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.j 07HIF F REC Aui10m tse only v:th ,ade . ate vent:)atier..
A... . . y:Ed,. ;;.:. 2. e".;e d,. cer t a:t v: th' skin ,and tre ath:r.; c f vart rl c: spray r:rt. .,) 3,%f ***.a4,e 5 . 7. : e. s . . .i ea:! tfe h,t
+" e'e 4,fN.Lp?c'ff thf'"fiUh cf' chsis:er'.
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,.. t . us . rys. e r d a- a pe .v.: t.h...,7
@'in'the papw:wa.* ,:nt :r.:
- g. u.g re- ate.p.ptc.3onced e:e v * *=
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O ) Form E010B COATING / THINNER DATA FORM Conpany Name: LDYY Yld8k (dilT IW All21 UTHOf/14 Applicable APCB. Certificate f- MY/T d46 h///I NY bM)- Product Name: bAF67 blM6N i Product Manufacturer: Wb?$lN Ol8T l lk?(D2 &&MNV Usaae Data Daily (gal / day): _. O.OOA Annual (gal /yr): 1 Rule 25.43-& 25.44 Analysis or Manufacturers certification Data *: N M/wuko MSDS As Received (Concentrated): Density (lbs/ gal): ~7,70 Solids % by Weight: W[/b % by Volume: 3d74-VOC %'by Weight: 6058 % by volume: W. M Water % by Weight: b % by Volume: h As Applied-(Diluted): gr g Ag,ogg Density (lbs/ gal): % by volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: N8/D776 Density (1bs/ gal): 7.l Mfr. Data Sheet or Certification is attached. Yes No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is tr lete to the best of my knowledge. 4 anp' f omp/// Signature: / _ _ d) ' (.f tu4t.M )
Title:
t/ilked 'er Gm w drsu Qatr~r 11/03/89 . _ _ _ _ _ RM_P . _ _
H A T E' R 1 AL SAFETY DATA SHEET
.? ...
DANUVACTURER'S NAME: EHERGENCY TELEPHONE NO. BARREN PA1HT AND COLOR COHPANY (615) 292-6655 ' 900 HEDGEH000 AVENUE EASHVILLE, TN 37203 INFORMATION TELEPHONE NO. $ ATE 'OF PREPARATION: 06/14/89 (615) 292-6655 S_______-_______-.________= _ _ _ _ _ _ - - - - _- --__---_______________-_______ SECTION 1 - PRODUCT IDENTIFICATION p____________ _-_____-____--____-___________________________-__----. ==_______ NRODUCT NUMBER: 2304 Hl11S RATINGS: H F R PP >RODUCT NAME : SAFETY BLACK 1 2 O B ?RODUCT CLASS.: PA1HT y --_______-_____-_____-_______________-_--_ _-- --==__-__---____--__-___-_____- SECTION 11 - HAZARDOUS INGREDIENTS s____________-________________--____-___-__-_________-____________________-_-_ HEIGHT OCCUPATIONAL VAPOR PRESSURE 7NGRE~ilENT CAS HUMBER PERCENT EXPOSURE LIMITS HG G TEMP 21HERAL SPIRITS 64742-88-7 50.38 500.00 PPH 6.2 LOOF GAZARDOUS INGREDIENTS FOLLONED BY AN ASTERISK (*) ARE SUBJECT TO THE REPORTING GEGUIREHENTS OF SECTION 313 OF THE EHERGENCY PLANNING AND COHHUNITY RIGHT TO LNOH ACT OF 1986 AND OF 40 CFR 372. DISTRIBUTION OF THS PRODUCT NUST BE (CCOHPANIED BY A COPY OF THIS HSDS. SECTION 111 - PHYSICAL DATA BOILING POINT - : 307 DEF F VAPOR DENSITY: HEAVIER THAN AIR (VAPORATION RATE : 41.15 (ETHYL ETHER = 1) HT/ GAL: 7,,TO 6 VOLATILE VOLUME: 61.26 VOLATILE ORGANIC COMPOUNDS: 3.91 SECTION IV - FIRE AND EXPLOSION HAZARD DATA YLAHHABILITY CLASSIFICATION: COMBUSTIBLE - CLASS 11A _ _ . , " LASH POINT: 103 DEG F TCC
, >J hW wW~ "
7WMAM' . i l
r__-__...___ _ _ . _ - _ _ _ _ _ s aevat s d e nt -
- Ie a + ,
'y 4 . . . _
'UNVTUAL FIRE fNO Ekfl0510N. IIA 2ARPGs Venera torn sn enplussve'einture sn nsr between
'Nthdie as ce2bustable satersol, "l[ la ff :
~
.1he upper and tousr esplesere Isan ts uhich can ye s end t ed bv seny sources such
' giy as psint lights, open fleees, electrseal metere andlsustchts*
SttCI AL FIRifl0NilNG PROCEVNRt$s
.p. Respir a tor y rous pe*n t 9heuld be ner n t e* evend snhalat son 'ef cenerntr ated Vavers . Water should not be used eucept as tee to L eap nearkv container e evole .t l-L 4........ -.=____
StC110N V - NEAllN NAZARV .. VARA ......--- ..
- LWitCTS OF OVERintOSURLs .
zinhalatsen.Vassvness, breatheno darfneulty, headaches, & less of teerdsnattene Eye contact-Severe errstatten, trarsne e rdness, and blur red visten. fish centact*Can drv and dotat sS sn enus sne er ne As. irrstatsene and dernetstis.
'ineestten.Can cause'enstresntestsnal svrstatten, Venit sne. nausea 4 diarrhea.
'DitVICAL CONVill0NS PRONE 10 A00R AVAllDM CV Ext 0$URL s Anesthestas respar et er y tract st r t t et sen. der e s t a t t e , nausea, ven g t sap.
PRINARY ROUtttSt Of (NtRYs PERHAL. 1NNAlAT20N, INGESTION ENER0ENCY /MV flR$7 AIV PROCEDURE $i if bvrathsne steps, apply inhalatson ever e spesure-Neve ver een in fresh ant, tyr centact. flush ar tif tt sal r espirat ten and seet sneedse*e nedscal atten9 ten e Nath. laver quantiters os water for 15 assutes. $$sn cortact-wash thercuehts utth ) senp and water and ser a doctor. Shoestsun-tse not nr deer s ena t tne, can cause chrancal pheunenstss.and puinenary edron, Centact physsetan tonedsetely. SECTI0li IV . Rt ACTIVITY VAT A
- i i
$1AUltt1Yo STA0Lt NA2ARVOUS rNLYl9tR12Al10Ns NILL NOT OCCUR l
.NAEARV0VS VICuttr0 SIT 20N PROVUCl$s
'Carhan menonsdeo carben dsentdr, ontdes of n s trecen.
l CONV1110NS TO Avoirs I.
- EktesstVe hent e poor Ventilat son, corres see atmospher es , estess ter agine. ,_
RNCOMPAtlBill1Y INAltRI ALS 10 Av010s e Alhalsne enter 5 als. strong ac sds and en tds enne enter sais.
' 6ttil0N Vil ~ $ rill OR ltAh rnoctVURLS' .....
Sitr$ 10 CE 1AltN lis Cast NAllRIAL 15 relia $tV OR FrilitVs titegnate tenttien sources, provide need Ventsisation, dtSe aptli area and add
. abserben t ear th er sandust to sostled isquad, NA$it Visr0 SAL NETHOVs Collect abserbent/bpslied iscusd esnture ente metal containere. .
. Censult let a l, s t a t e 4 s ede r a t ha s ar deu s un s t e s e en t e t ten betere dsspessn9 snte approved hasardous neste f areds s ils. (
Ubes relevant laus.
.... =.... .- ..
s SECTION till - tAtt NANvt!NG ANO U$t 1Nt0RNAtl0N RttrinA10RY PR0ftCil0Ns Nher spravsnp thss entre sal use a Nt0$N appres ed tar te ader resper ator er ens pasa sustable to aeop a g r eer ne ensis and carer concentrafson etlew the tsee-
, nos ekted threshald lees t e alues. Nhen ussse nn peerlv sentilated and conftned spacese use a fresh.ast supplysne respsr eter er a self.centa$ned berething apparatus.
VENtlLAtl0Ns Generel eethenseal eestsistsen er le<al eshaust should er eustable in neep reper contentratsens beten itV. s'en t s f a t sen retenreent should be espierten preef rR0ftCtlVE Cluktse lepereeable threstal handisne cleres f or saen pretecteen. tst PR09ttil0Ns Use cheetcal caret s plasses, ecceles, and f aceshnelds for eye protretsen. 09NtR PR0ttCilVt tuulrNINis
#se sapermeable aprens and pr otec t sve clothene whenecer pesssele to prevent shan tentact, the use er head caps ukeneeer possekte ts strenely reteneended.
Ns0ltNIC TRAC 18ttTe Eve washes and serrts shenera sn the nevnetner ss receeernded.
+
StCTION th . SrtCIAL rRfCAvl10N$ PRECAUtt0NC 30 6t l Ar,t N lN MANVilNQ ANf* $10RlN09 Ose non-spar a sne utens e ls when handis , thus eatersal. Ares 4 het metal surfaces Use so teel, nell-e ent s tated ar eas. reer sentanner s <tered when net en use. Step auav free eseresser heat and open finess. OsNT ECAufl0NSs Faea en seems where this entersal es used shoull be s tr #< t iv prehse s ted. N0tt his enternetsen as a< curate to the best taentedee of Narren rannt and , Celve Co .4 -t u t se fuensshed methout any espressed er sopf sed warr ant aes. _--___.-_i___--_-_---__.._-.-_ - . _ . _ _ . - _ . _ _ . _ _ _ ._ _ _ . - - . . _ _ . . _ __ = _ - . . _ -._.._._a
_1 e e A- .
' ]fs, Y *~ e -64Kuh t.i .e ..o su,tL6_I_E_B_I_&_L__S_o E_E_I_X_ D_0_I_e__S_U_E_E I r
fgMANUFACTLNtER8.KLEAN-STRIP, DIVISION Ol* - DATE PREPARED 8'10/01/05 W.M.~BARR A. COMPANY h ~ 2105 CHANNEL AVENUE P.O..90X 1979 @ ~MEMPHISE TENNESSEE TELEFilONE NUMBERt - (90f) 775-oJA1
. INFORMATION HAN.1 LING SER.
ATTNs KATitLEEN SAMPLE h- . P.O.,90X 1213 - - l ENGLEWOOD CD S0150._l' .- - _ _________________SECIIOU I_=_E80DUCI_IDEUIIEICeIIDW__ ________.._ _ .. . FORMULA f.*UMDER8 1683 lPRIDUCT NUMBER 8-OT-69 PRODUCT NAME- 8 GUM SPIRITS TURPENTINE KLEAN GTRIP
. PRODUCT CLASS 8 THINNER-SOLVENT
~
___: :Z Z:ZZZZZiEEii5s ii:;;:53EEEE50s is5EE5iEsii:ZZZZ:ZZ.~.Z.1 i l 1 l INGREDIENT l CASS 1 PERC l OCCUPATIONAL 1- U ... nk l l WT IEXPOSURE LIMTTRI PRFm.til _____ __ __ __ _ .. . . .._ _ _ _ ____ __.1 _ _ ._ _ _ _ _._ 1_ _ __ __1_ _ILV__ _ _ EE li _1B H .. . . . < l - 1 1 i ~l-1.< TURPENTINE ~ , l 0006-64-21(100 'i100 ppml100 ppmlNE- - ____.. _.SECIION III_=._EU.SIG6L Y Dele ____.______ _ __ __..L _ . 7._____---
;GDILING RANGE 8 309 THRU 330 F VAPUR DENSITY
- Heavier Tha n - A1 r.
g/ EVAPORATION RATE! Slower Than Ether. X UOLATILE! 100 0 :LDB/ Gal t tia-
. __ ___ _ __ __ ____ SECIION_IM_= EIBE_oHD_EXELDSION_UoZe8D_ Dele ____ _ _._.
FLAMMABILITY CLASSt~ OSHA-Class IC' FLASH PDINT! 94F_ Lt?Lt; 0.0. DDT-F1ammable Lituid. N EXTINGUISHING- MEDIAt-Use- Carbon Diexide, Dry Powden or Foam.
- UNUSUAL. FIRE AND EXPLOSION HAZARDGt Keep eontal'ner tit.thtty ctused. Inotaio r r. -
~
hoste : electrical etulpment, sparks, open f tameo and hot surfaces.
.SPECIAL FIREFIGHTING PROCEDURESt Self-contained respiratory protection shnuid provided f otV fIref ichters f ight i ng' f f res I n bu t Ld I ngs . or < conf I ned areau. O t or.s containers exposed to fire should be kept enot with water spray to prevent promourer bulLd-up.
.._______ SEGIIOU_M_.=_lEoLIU_ UoZoBD._DaIe __ - _ _ _ . _ . . _ . . _ . . _ _ . . . . . - .
PRIMARY ROUTES OF ENTRY
- Inhalation _E_ Ingestion ..M Dermal ._X_
EFFECTS.0F OVEREXPOSURE - SHORT TERM EFFECTS!
,INHALATICN m May cause headache, d i n i ness and nausea. )
l , . ' INGESTION - No t determi ned,
~' WIN CONTACT - Not determineu.
g iYE CONTACT ~~ May cause irrit.5 tion.
.EW ECTG OF OVEREXPOSURE - i.GhG TERH GYEtr(at
+ - Pro tonged cr peated cont ac t may cautro derr. a t i t i s. fiep .eri a have o4oc i .s i-a
'ropsoied and alonged overexposure to aolvents ullb neurological a nc! o ttia .
- Phytsi o ien len L da, mage. 4..g ., ,
u=2i--~L- ~ L-_ :_ ""_l_ *~~W __ _ ' _- -_ _-R- _ _ _;; ~_ ;__- . _Q
1
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12co3 39 B Atih IW M) i. 00, 7 /C ' OJO11 . C *i ,
(
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OVEREXPOSURE Nons rocngni zed.
.H.E3ICAL CONDITION 3 PRONE TO AGGRAVATION D) 3 u..
EilERGENCY AND FIRST AID PROCEDURESt 7NifALATICH - If user exper ienceu brea th i ng d if f icu lty, movo to air free of raporo. Admi nister oxygon on ar t i f ic i a l respirat l u n unt i l med ica l en ia,t ana c. ba1rondernd.
. IHOESTION - Ca t t your hosp i ta l emercency roo:n, poison control center or Fhysicien immediately for lustructions.
GKIN CONTACT - Wash'with soap a nd Large quant i t los of uat or and ser-h med ic ;i
'ot tent i on - If irritation from contact persecto. y
' EYE CONTACT - Flush with tarse quantitles of water for at teant 15-minuieu se.d e cxk laced iate medica l at tent i on.
__ ___________________________________________________________________._.._ 1
.. ____ _ __ __.!_SECIIDH_VI_=_SEGCIIVII%_D81G______ _________ ____ ...... _ 1 STADILITYt Stable.
IIAZARDOUS POLYMERIZATION! Will not occur. HAZARDOUS DECOMPOSITION PRODUCTSt None recogni zed. INCOMPATIBILITY-(MATERIAL TO AVOID)t Dirong oxidizing agents. ____ ____ _________ __SECIION_VII._=_SEILL_6ND_LE0!L.EGOCEDURIIS_ _ _ . ___..... . OTEPS TO DE YAKEN IN CASE NATERIAL IS RELEACED OR SPILLED 2 Avoid breaihing 9- vcpors. Vent i late area. Flush large epitin of material into suitchie rstainiwa crca or contal nors wi th large quant i t les of watter. Sma L L spi i to can be absorbei N by appropriate Inert absorbent. 7 WA'2TE DISPOSAL 3 Dispose in accor;Jance wiili applicable locat, state and federal M ,.rc9ulations.
. . __ EEE 150:DIII _ e e E E i s E E E 5 i E 5 i i 5 s ?.I L E 5 s s s i i E s ~_ Z .~.
b RESPIRATORY PROTECTION! For OSHA contro t ted wori: place, use only with adegi2te vsnt i tat i on under engi neered a ir contro l systems designetd t o provide mw imm. cppropriain TLV. For occasionet use whero engineered air eontrot is not r-) . fossib Lee ~ use NIOSN - approved resp irat ors. For: occasi una i co nsumer use, .oue on,L. utth adeguate ventilation.
- o e VENTILAT. ION! Adequate ' vent i la t i o n must be provided. See resp ira tory pro tet. i n .,o D cbove.
PROTECTIVE GLOVES! Use impermeable 91 oven t o prevent sl:1 n irritation. EYE PROTECTION! Safety glasses, chemicat voguten and/or face shlaIdo are recommended t e safeguard aga i not potent Ia I aye contact, irritation or-injury. OTHER PROTECTIVE EQUIPHEHTS Varyi n'a opp iles t l o u methods ca n dic ta te caso o f additional protective safety equipment, auch as impermeab le apr o ns, etc. I \
\
l HYGIE?lIC PRACTICESI Wash hands ihorough ty ofter use. ! ___ __ _____ _________.SECIIGel..IX_=..EEECIGL..ECEC6HIIONS__ ...____......__. - PRECAUTIONS TO DE TAKEN IN HANDLING AND STORAGE 1 Do not s4 ore naar f Iawn e ulevated temperatures. ') THER PRECAUTION 98 Read caret u t ty a t 1 cauf i uns a nd direcieonu on produci i ,i, a l 1 r?oro _ use. Si nce empty c o nta i ner reta i ns residue, follow all tabel war n i n.> .. avon after conuiner is emnty, Dispone of empty container iccording to l or:,s e re;ulotionn.
'~~
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, n .. ;.a; E f. ; L,L e >
'7NC u.,v12- ' (. ti 9 BARA'-(W-MI n u.h , .'126bJ >
- 9.' +,
, l l_ * :d : 4 .
!! ATE 3 0THE INFORMATION CONTAINED .HEREIN :IG FURHISHED UITHOUT- UARRAH rY OF Ain '
L C i KIND. EHFt.OYERS BHOULD USE- TilIG INFORMATIDH ,ONLY AS A 1NFORMATIUM GATHERED BY Tl!EH' AMD itOST MAKE filDEPENDE!!T DETERMINANT 0f t .0F
' 3U1TABILITY ' AND. COMPLETENESS . OF ' INFORMAT10N. FRull' ALL GOURCES ' TO - AGGURE ' PRfi61!
LUBE:OF TilESE!HATERIALS AND Tl4E;BAFETY AND HEALT11;OF EMPLOYEES. ANYc t)Sti n.7 : Tlit0 ~
-DNTA'MID INFORMATION"HUST DE DCTERMINED .DY< THE < USER TO BE. IN ACCORDANfjE U11111
' APPLICABLE FEDERALT GTATE AND LOCAL LAUS AllD ret,ULATIDMS. ,
~ 00000(!G00006 3
.e h
8' - '? p asse - a : O - e Q i l: l l. b
& .ah pass == . g P ad {jh l g, Pl II /t $4 4 'jj
____.m_____.__._ . _ . _ _ . _ _ . _ _ _ _ _ _ , __ _ __
l ENCLO50RE 5 E106 FORM FOR llYDRAZINE TANK VENT f f l f u____..
i f ! .' E106 ' r. POLLUTION ESTIMATION ~ FORM [ORMs y 7 e
- 1. Name of Company (as shown on Line 1, Form E001): $>ED OD'/Atd OOC LEAR TEDMESSM \/ ALLEY b OTW o etiT y' '
kADT s
- 2. l Equipment Name (as shown on Line 10, Form E001): YDRA ZiSJ6 / AO tt YErI.)T NllAZis)E -' '
- 3. Type of pollutant for which estimation is made:
O,087 /bs # ~ is . Pollutant Emission Factor (PEF): /' (Give value & unith in 1bs/ ton, lbs/lbs, lbs/ gal.gr/ft3 ,etc.) Source of Emission Factor: 5 Uncontrolled Pollution Emis ion Rate:
- a. 0 8 % & M (Give
. c c b operating rate
.-/
for Qt is equipment 2/Wh (a7 SAD (PEF from Iteni 4) and the appropriate units in either , ibs/hr, tons /hr, gal /hr or CPN) 2 Uncontrolled '
- 6. Pollution Emission Rate: 2. Ibs emitted /hr (from Item 5 convert to lbs/hr)
This is to certify that I am familiar with the operations concerning this equipaent and that the information provided on this application is true and complete to the best of agr knowledge. This form must be completely filled out before acceptable.
/
~
Mall To: Company Official: /14 (Aw.i /
.c w-l ( Signature CHATTANOOGA-HAMILTON COUNTY AIR POLLUTION CONTROL BUREAU
Title:
/M444rr o/- EM4(ad4/a/r4(, &L/TV 'l 3511 Rossville Boulevard Chattanooga, Tennessee 37407 Date: y/ '/bj:o s/ DO NOT WRITE BELOW THIS LINE , Engineer Approval This form corresponds to permit number: Special Notations: -- I
p~ v,w-
's 4
ENCLOSURE 6 fi E106 FORM FOR AHMONIA TANK VENT
o
.FORMr E106 ,
POLLUTION ESTIMATION FORM e 1, Name of Company (as shown on Line 1, Form E001): M c:7?OcVAu tlGC. LEYht 3 MT fr/kk5m: s/hur V AomeTv Equipment Name (as shown on Line 10, Form E001): Aust<o.3,A. Ts>< Vemy 2. 3, Type of pollutant for which estimation is made: 7// # 19 d.
- h. Pollutant Emission Factor (PEF): O, O f f /bs!ch (Give value & units in lbs/ ton, lbs/lbs, lbs/ gal.gr/ft ,3 etc.)
Source of _ Emission Factor: bdOE S6E/4L/Tn/ d,45c5 - $AFeTy Mo t'*. M Ei2AcutV Prdo eevanf s , 5 Uncontrolled Pollution Emission Rate: i 04 llbr CF x {& 24CFstV40inhs) - O,44 lbbe (PEF from Idem h) (Give operating rate for this equipment (Give value Is' units) and the appropriate units in either lbs/hr, tons /hr, gal /hr or CFM) Uncontrolled //
- 6. Pollution Emission Rate: , d> Y /Ss/Ar Ibs emitted /hr (from Item 5 convert' to lbs/hr)
This is to certify that I am familiar with the operations concerning this equipment and that the information provided on this application is true and complete to the best cf my knowledge. This form must be completely filled out before acceptable. Mail To: Company Official: >. ,// Avid b CHATTANOOGA-HAMILTON COUNTY / Signature AIR POLLUTION CONTROL BUREAU
Title:
/,///,)fggr of M,444Wrd/At_ MJiL/TV 3511 Rossville Boulevard Chattanoots, Tennessee 37407 Date: 7/'l-[f'E ! DO NOT WRITE BELOW THIS LINE Engineer Approval This form corresponds to permit number: Special Notations: t______________ /
m b e ENCI,0SURE 7 i l' l l USAGE DATA AND MATERIAL SAFETY DATA SHEETS FOR COATINGS AND TilINNERS USED AT Ti!E CONSTRUCTION SANDBI.AST AND PAINT S110P l l l i I l 1 l l l l l l r l l a_-_-_-______ _ _ _ _ _ _ . . _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ - - - - - - - - - - - - __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
. 9
> a
- li I U
- e. LISTING OF COATINGS AND THINNERS.
USED AT THE CONSTRUCTION SANDBLAST AND PAINT SHOP
'i ;
PRODUCT-JOUANTITY USED. 260 gallons
- Carboline Number 33 Thinner 220 gallons Carboline Carbo-Zine 5 gallons
- Nutec 6
- Nutec,1201: 5 gallons 30 gallons
- Enamel Paint (PPG Industries and Sherwin-hfilliams Co.).
Varsol 50 mellons TOTAL 600 gallons Note: Material Safety Data Sheets are attached except for Carboline - carbo-Zine which was,provided earlier. l l l'
FORM E106 POLLUTION ESTIMATION FORM Name of Company (as shown on Line 1, Form E001): 6/:7P U O M M //ClFJR 4:/A/f 1.
$1/Nf GSGT \/ ALLS 1 )t /;1kgi ni
- 2. Equipment Name (as, shown on Line 10, Form E001): M5R[f77#[ //D bW ///h Pw-r Site wirn no summ Pa2a Kvihusras
- 3. Type of pollutant for which estimation is made:
Is . Pollutant Emission Factor (PEF): 6,) YM 6/M MO (Give value & unita in 1bs/ ton, 1bs/lbs,1bs/ gal gr/ft3 ,etc.) Source of Emission Factor: N M(//M/MT I 5 Uncontrolled Pollution Emission Rate: b$ ML xfbO0 / 0 ll =b (PEF frcm Item 14) (Give operating rate for this equipment (Give value & units) and the appropriate units in either lbs/hr, tons /hr, gal /hr or CFM) Uncontrolled /_gS /
- 6. Pollution Emission Rate: ///f lbs emitted /hr (from Item 5 convert to lbs/hr)
This is to certify that I am familiar with the operations concerning this equipment and that the information provided on this application is true and complete to the best of my knowledge. This form must be complete]y filled out before acceptable. Mall To: Company Official: M
/ Signature CHATTANOOGA-HAMILTON COUNTY AIR POLLUTION CONTROL BUREAU k
Title:
M / d66Z #A br/AM/A////TJL h84L//f/ 35ll Rossville Boulevard Ch:ttanooga, Tennessee 37407 Date: "}'l 7 'If DO NOT WRITE BELOW THIS LINE Engineer Approval This form corresponds to permit number: Special Notations: _ J
mr Form E010B COATING / THINNER DATA FORM Company Name: UD YA W Y lClliC RUN kWW blANY VIkkYlW Applicable APCB Certificate f: hMM MT///d /MIM Product Name: hMM MC Product Manufacturer: [MMLIN L- b MAMY Usaae Data Daily (gal / day): 4 68 ~ Annual (gal /yr): 2 7/s = Z 2 0 t O'4MF O rp src 00NUOL-Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: M [Tfgc4MD M Cf {El ore " Paossato As Received (Concentrated): pgj fpgy gffgj7,g} Density (lbs/ gal): E la I Solids % by Weight: N % by Volume: N VOC % by Weight: M % by Volume: 6O Water % by Weight: O % by Volume: O As Applied (Diluted): I[4 Density (lbs/ gal): /2.,3 4_by "cl=c : Solids % by Weight: 67 % by Volume: 30 VOC % by Weight: O % by Volume: 7b Water % by Weight: O % by Volume: O Thinner Data Chemical Composition: EudtTIC. it rcaernd , YUNi~(LWelkgyrgyffL-Density (Ibs/ gal): 7N #Nb Mfr. Data Sheet or Certification is attached. Yes / No
*For NSPS Sources Method 24 must be usel.
1 i This is to certify that this information is true co le e to the best of my knowledge. A f) l - Signature: I J/de (#'u 1
Title:
@JMR W~ lkV/ttMuGL O.Auq l 11/03/89 RMP _ _ _ _ - - _ _ _ _ _ _ _ _ _ . _ _ _ _ _ . . . _ _ _ _ . _ --- ._. _ _ _ _ _ _ - - - - . _ _ - -_ a
I I Form E010B
~
COATING / THINNER DATA FORM Company Name: LDV$ UCA4WL ffAllT DIfW Y)Ll.21 Ot/111 QNSr 2006)47 ? g!WT affef ,, _,, Applicable-APCB Certificate #: T /! T 4 rswt WYCPFrTI) Product Name: &^wDun AleAg a 33 -wr##a Product Manufacturer: MdO6/4/f b/L/MM
.Usaae Data Daily (gal / day): !Z. b'O C , b-Annual (gal /yr): (240 -5$ c M5 Cts />-vP SW4WT Rule 25.43 & 25.44 7 # M W *D */ M*WM M 777^M Analysis cr . Manufacturers Certification Data *: "Im h4e /45DS As Received (Concentrated): h Density (lbs/ gal):
Solids % by Weight: % by Volume: VOC % by Weight: % by volume: Water % by Weight: % by volume: As Applied (Diluted): g Density (Ibs/ gal): % by volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by volume: Thinner Data g7ggg g.-g gg ggyg (7;g Chemical composition: [7//VlWi~ hL V60L. NOA/PN/TVL kTl#A Density (1bs/ gal): 7[ Yes o Mfr. Data Sheet or Certification is attached.
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true a d omp e to the best of my knowledge. e, ;/ / /,/ - Signature: dlIfr /I. j Ars
Title:
t/J & ed # BNmessm o d a/r1 11/03/89 - - Jut ___
~ '
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MATERIAL SAFETY DATA SHEET A '.
~.. . '
FOR COATINGS, RESINS AND RELATED MATERIALS .
.(Approved by U.S. Department of Labor as " Essentially Similar" to Form <0SHA' 20) .
b REPLACES: 12/82 l4 DATE OF PREP.: 1/84 ~ Section I hf)'Et23'l ' ' MANUFACTURER'S NAME: '. ar NeCosp'any . , STREET ADDRESS: 350 Hanley Industrial Couet Q CITY, STATE AND ZIP CODE: St. Louis, MO 63144 EMEP';ENCY TELEPHONE NO. 314-644-1000 __ A , INFORMATION TELEPHONE NO.: 314-644-10 _-y . f./ q PRODUCT CLASS: Solvent Blend p . ) D MANUFACTURER'S CODE IDENTIFICATION
,,.,,.s...,v-. -
TRADENAMEs,',q,,..lineThinner#33k,%vj.y , Carbo 533/4A75
- Seetion- II'-+ HAZARDOUS INGREDIENTS d- w, OCCUPATIONAL VAPOR
,'l a 7'? I-L
. EXPOSURE LIMITS PRESSURE'- T0XICITY-M, a ..w.W '
INGREDIENT- A f"- T 'O'>f PERCENT (TLV8-TWA) am/Nr DATA J / Af? .;h.kI . 50 Aromatic Hydrocarbon , _ 100 ppm 3.0 , ; Ethylene Glycol Monobutyl' Ether ' ,7C 25' 50 ppm - ,,0.6 : 1(il Ethylene Glycol.Monethyl Ether =A 25 l5 ppm .,. 3.8 ,. i .; - g..g , .
, }_ ,
~M
% . *v k N. )
~-
~
. .%..g Q i
> N%
w S . Section III -- PHYSICAL DATA '
. BOILING RANGE: .275-340*T ' . , ,~ - 1 VAPOR DENSITY: s HEAVIER, O LIGHTER, THAN AIR EVAPORATION RATE:DFASTER,jeSLOWER,jTlfANETHER' PERCENT VOLATILE WEIGHT PER ,
Ng L') BY VOLUME: 100 GALLON: 7.4 1 0. ?F
.g
I 4Section..IV'-- FIRE AND EXPLOSION HAZARD DATA
. ~=
TLAMMADILITT CLASSITICATIOD'r--< 8 4 ' TLASH POINT 1.0
- (OSHA)
- Combustible Liquid - Class II (PMCC): 101'T LEL:, ;
EXTINGUISHING MEDIA: User. dry,n ch emical.or chemical foam suitable for. solvents shown. W :i
'? j}_
- c. ,, 3 .c .- ._.
9 h i % 31 M' I'Um ' ; if A '.l,' ,
- ~? .
. o;;f n 1 ' Uifil , ~ TIGllCM A M .
. .r . -
4 UNUSUAL FIRE AND EXPLOSION HAZARDS: Isolate from heat, electrical equipc2nt, sparks and g. g,..gg,;,' - open flame. Closed containers may explode when exposed to extreme heat. Water may be used to coolf elosed i:antainers to prevent pressure build-up and possible autoignition or
. explosion when exposure to 'extrame heat is present. 1 id'. . .
s .
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s l
s a
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=
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&6QLlU6 -
[A2lXWN/G YNO/A/6/(
- ' CODE: $33/4A75 % '
Section V -- KEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE - 4 Inhalation: Irritation to respiratory tract; headache, dizziness and nausea. Skin or Eye Contact': Primary irritation. EMERGENCY AND FIRST AID PROCEDURES 1 , r,* ujgj[ Inhalation: Remove to fresh air. Restore breathing. Consult a physician. } Eye
Contact:
Flush immediately with large amounts.of water. Consult a physician. Skin
Contact:
Remove coating with solvent. Immediately wash affected area with soap - and water. Consult a physician if 1rritation persists. Section VI -- REACTIVITY DATA STABILITY: O UNSTABLE e STABLE CONDITIONS TO AVOID: Unknown INCOMPATIBILITY (Materials to avoid): None reasonably foreseeable HAZARDOUS DECOMPOSITION PRODUCTS: CD, CO 2 , Possibly aldehydes HAZARDOUS POLYMERIZATION: D MAY OCCUR 2 WILL NOT OCCUR , k :. uni
- Section VII -- SPILL OR LEAK PROCEDURES 3 STEPS TO BE TAKEN IN CASE MATERIAL RELEASED OR SPILLED: Avoid breathing solvent vapors. g Ensure adequate ventilation. Avoid sparks, flames and anything which could cause fire. , ,
WASTE DISPOSAL METHOD: Soak liquids with sawdust or rags. Remove. Flush with water if possible. Avoid skin contact. Disposal should be in accordance with local, state and
- federal regulations.
Section VIII -- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: NIOSH/ OSHA approved respirator types suitable for materials in 4 ,( &* "Mf." Section II recommended. Approved chemical / mechanical filter recommended when ventilation, , is restricted. Approved air line type respirators or hoods recommended in confined areas. # ,
, VENTILATION: Sufficient ventilation, in vulume and pattern, should be provided to keep air '
contamination below current applicable OSHA permissible exposure limit or ACCHI',s .TLV@ limit. ; FROTECTIVE GLOVES: Protective gloves recommended. j EYE PROTECTION: : Chemical ' goggles with side shields "or face ' shields recommended. ',,, , ' QTHER PROTECTIVE EQUIPMENT: Protective creams and clothing recommended to avoid skin contact.
}L
. (Y ,
t h e.3) Section IX -- SPECIAL PRECAUTIONS & '8 PRECAUTIONS TO BE TAKEN IN HANDLING'AND SiORING: Store in a cool, dry area with ventilation f suitable for storing materials shown in Section II. , OTHER PRECAUTIONS: Provide respiratory protection against smoke and fumes generated during burning or dusts generated during : removal of dry coatings. l
* ~
29- CTR Tarts 1915, 1916 and 1917 require the preparation of this Mate ~ial Safety Data Sheet. . . . F~
- N
_ - _ _ . -- ~
Form E010B i COATING /TIIINNER DATA FORM Company Name: YUDVAd/V/ClBIR flJMT TD4/26fM- VALLEY bri1kttTY Applicable APCB Certificate #: hMM SLAT 7//d /h/MTOD Product Name: v7FC. [/UX7 6 77 /7 h///(It Product Manufacturer: INI'6' K/4l- [A477A/66 h 8,, 5 h , 11gf ae Data Daily (gal / day): Ab8 O < Ob Annual (gal /yr): b Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: M [7/ch@D M SIDJ As Received'(Concentrated): Density (1bs/ gal): _._, 3 Solids % by Weight: 7O % by Volume: 78. b VOC % by Weight: N % by Volume: 24.2 Water % by Weight: 6 % by Volume: As Applied (Diluted): 544W /5 /SOM Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: TManemW cuts:~ chemical Composition: D1LO;0L VG- bCY'7TTf. YVWL .SYAMi , hqlMI% stLIcarv Density (1bs/ gal): Mfr. Data Sheet or Certification is attached. Yes /No
*For NSPS Scurces Method 24 must be used.
This is to certify that this information is true an' omp et to the best of my knowledge. Signature: < [I 3]0"}(I. /w)J /
Title:
M4/R OF EWV/&//LVDL OJur1 11/03/89 RMP _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ J
h "" ^ " MATERIAL SAFETY DATA SHEET dd3/fd, FOR COATINGS, RESINS AND RELATED MATERIALS
* "' U *
- He.iE OF PREP.
hO ' . ' w.03-3178 k Section i L L
' MANUFACTURER'S NAME IMPERI.AL COATINGS CORPORATION,_INC.
CITY, STAT E, AND ZIP CODE , STREET ADDflESS l'16362ChefMonteurHighway, New Orleans, Iouisiana 70129 l EuEnGE NCY T ELE rwooNE No. i l-(504) 254-1433 PRODUCT CLASS MANUFACTURERS CODE IDENTIFICATION Epoxy Polyamide #6 TR@c N AME Nutec _#6 Epoxy LSteel Primer Section 11 - HAZARDOUS INGREDIENTS' f 4GRE 0lEN T PERCENT LEL PRESSURE PPM mg/mS B7sar Epoxy 25 - 11.4 g/kg - - 0 Oral LD 3 Micaccous P.igment 10 - 176mp/m - - 3 Strontium Yellow 5 - 176mp/m - 3 g Magnesium Silicate 30 - 176mp/m - - Xylol . 10 100 435 1.0 9.5 P Cellosolve 5 100 740 2.6 3.7
.* MIBK 10 100 410 1.2 15.2 Aromatic Naphtha _S 200 -
1.0 4.4 Cure : Cellosolve Acetate 15 100 540 1.7 1.2 g 9.5 Xylol 15 100 435 1.0 t Polyamido 30 - - 3
~ ~
Magnesium silicate 40 - 176mp/m - - Y 9 Section lli - PHYSICAL DATA VAPOR DENSIT Y HE AVIE R. {__l LIGHTER,THAN AIR g nolLING RANGE 237 F to 277 F. PERCENT Vot ATILE 24.2 WEIGHT PER 12.3 lbs. g tvAPonAToN nAtE U rASTED l X l SLOWER.THAN ETHER DY VOLUME GALLON Section IV - FIRE AND EXPLOSION HAZARD DATA dot cAf toonY FLAMMABLE - Less than 100 F. r tASH PotNT 68 F. LE6 1.1 CXilNGUISHING ME DIA Use National Fire Protection Class B extinguisher, CO2, dry chemical or foam designed to extinguish Class IB liquid fires. UNDSUAlf mE AND f xFooSfoN HAZARDS Keep containers tightly Closed. Isolate from heat, electrical equipmen t, spark, and open flame. Closed containers may explode when exposed to extreme heat. Do not apply to hot surfaces. Paint vapors can cause violent explosion. When applying in r - 7 closed area, supply sufficient ventilation te keep vapors below LEL level. 'siECiAt r inE r eGnt NG PnocEDunrs Water spray may be ineffective. Water may be used to cool closed containers to prevent pressure buildup and possible autoignitior or explosion who posed to extreme heat. If water is used, fog nozzles are required. _ _ _ - _ - - - _ - . _ - . _ _ _ . _ _ _ . _ _ _ . _ - _ . _ _ - _ - . _ - _ _ _ _ _ _ _ _ . . _ . - - _ . . . - _ _ _ - _ _ _ _ _ - _ _ . - _ _.__-w
Section V - HEALTH HAZARD DATA . P
+ THREssotD uMr VALUE See Section II. . ' EFFECTS oF oVERExt 7SURE - / Inhalations ' Anesthetic . irritation of the respiratory tract or acute nervous system depressio characterized by headache, dizziness, staggering gait, confusion, unconsciousness or coma. ? Skin cnd Eye Contacts primary irritation.
EMERGENCV AND ifRST AfD PROCEDURES Fumes: Remove from exposure.
' Restore breathing. Keep warm and quiet. Notify a physician.
Splash - (Eyes) - Flush innediately with copious quantities of running water for at least 15 min-utos.' Take to a physician for definitive medical treatment. Splash (Skin,) :' Wash affected areas with water. Remove contaminated clothing. Consult a physician. Section VI - REACTIVITY DATA 3rAssuTY uNSTAste O ".ADLE CoNDtiloNS To Avolo Flame, high' heat and moisture. INCoMPATABluf Y (Materials fo svDW) .. HAZARDOUS DECOMPOSITION PRODUCTS ':CO,'CO , Aldehydes, NO ' ""id 2 2 HAZARDOUS PoLYMEnt2ATioN M AY OCCUR @ WILL NoT OCCUR l - CONDITIONS to AVotD Excessive heat af ter mixina cohanent may ennem ra e:t nni ymor4 *nH nn . g) + Section Vil - SPILL OR LEAK PROCEDURES Remove all sources of ignition (flames, hot surfaces, STE PS To DE TAKE N IN CASE MA1EmAL IS RELE ASED oR SPlLLED - r and electrical, static, or frictional sparks) . Avoid breathing vapors, ventilate area.- Remove q with inert absorbent and non-sparking tools. WAST E DISPOSAL METHOD Dispose he accordance with Local, State, and Federal regulations. pIncinerateinapprovedfacility. Do not incinerate closed containers. [ I. Section Vill - SPECI AL PROTECTION IN FORM ATION (' In Outdoor or open areas, use Bureau of Mines, approved mechanical filter In h REsemAf oRY PHo1ECTioNrespirator to remove solid or airborne particles or overspray durin prestricted ventilation areas, use Bureau of Mines approved chemical-mechanical filters designed ! to remove a combination of particles, gas and vapor. In confined areas, use Bureau of Mines approved airline type respirators or hoods. VENTILATION provide general dilution or local exhaust ventilation in volume and pattern to keep bTLV of most hazardous ingredient in Section II below acceptable limit, LEL in Section IV below
. stated limit and to remove decomposition products during welding or flame cutting on surfaces acoated with thi's product.
. PnotECTIVE GLOVES Required for prolonged or repeated contact.
EVE PROTECTION Use safety eye wear designed to protect against splash of liquids. OTHE R PRoTECilVE EoutPMENT prevent prolonged skin contact to contaminated clothing. Section IX - SPECIAL PRECAUTIONS PRECAUiloNS To DE TAKE N IN HANDuNG AND SiohlNG Do not store above 120 F. Store large quantities in buildings designed and protected for storage of NFPA Class I combustible liquids. oiHER PRECAU11oNS Do not take internally. Do not flame cut, braze, or weld without U.S. Bureau of Mines approved respirator or appropriate ventilation. mW _ . - - - _ - . _ - . _ - _ = _ _ - - . _ . _ _ _ . - _ _ _ _ _ _ _ _ _ _ _ _ _ . _ ~ _ . - _ - _ - , . _ - . - _ _ - - _ _ - - _ _ _ - - _ . - _ _ _ .- . _ _ _ _ _ _ . ._-__
Form E010B COATING /TIIINNER DATA FORM - Company Name: Y UDYAN $/Cib6R ?/JM NUK6TA~~ Y)llsv bt/ilkttQ Applicable APCB Certificate #: hA/SF M 8/#T//# h/%/MTSDM Product Name: />7tc & /zo/ PApr- A N PAWB Product Manufacturer: _T/ APER /dL 60M7N6 d%tf Usaae Data Daily (gal / day): 5/460 = o. 0 2-Annual (gal /yr) : b l Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: M [Tfgc/hD M Cf As Received (Concentrated): Density.(lbs/ gal): Solids % by Weight: 74.5 % by vo1ume: 555 VOC'% by Weight: E6. 5 % by volume: 44.5 Water % by Weight: % by Volume: O As Applied (Diluted): g4Ar /$ /@f Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volun.e: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Dat6 Chemical Composition: [M Density (lbs/ gal): Mfr. Data Sheet or Certification is attached. Yes / No i
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true an mp1 e to the best of my Knowledge. <yp3 '/'/M Signature: /ylb A I
Title:
MSR OF INV/tWlurJL oueur'1 l { 11/03/89 j nnP !
.. . a
" FATERIAL SAFETY DATA SHEET.FOR .COATitGS RESITE [ Ato RELATED MATERIALS INFORMATION TELEPH0rd NO. '(314) 644.-1000 .
IPNRI'AL COATItGS (800)-424-9300-CHEMTREC EtERGENCY TELEP)CE NO. C'1401 S. Hanlev Road 09/22/86- . St. Louis, MO 63144 DATE OF PREPARATION: SECTION I - PRODLCT IDENTIFICATION. m ( - PRODUCT CODE: 09-5903-A(L)- PRODUCT NAME: 'rdTEC #1201 PART A . PRODUCT CODE: 09-5903-B(L) PRODUCT NAME' PUTEC #1201 PART B PRODUCT CLASS: E"' OXY POLYAMIDE bh{ ? .h ' ? SECTION 11 - HAZARODUS INGREDIENTS wpm f5 ESSE LEIGif EP.CEAT DPOSE LittliS (ILWik'A) (EL) 20'Cse/Hg PET A PMTB filXED ItGED!ENT (LMEL PFtE IF DIFFERENT) 0% >17. 0.05mg/m l 1.Oss/s PDE
. >1%
i LEta OR3* ATE 100pos 100 pos 21.0
>1% > 17. >1%
- X1LEtE 0.!mg/m ' NIE
> 17. 0% >1% . 0.IEng/s 1 LDO fu.YEDATE 0?#E (1D0 C0f'Clf0) ZD one- 400 oon 90.0
>17. - 07. Sif.
(SBKF#0. 70E 38.0 1
>17. 07. 11% -100one
- UlfE - 5 pas 200Pos 3.8 *
>17. 0% >1%
2 ETHAE1410. (ETHYLBE G.YCOL t00 ETHYL EDE) > 17, 50 pas 100 pas 10.0
>11 0%
14ETHfL-2-f9I#0E (tETHYL ISDEJIYl. KETOE) '10.0
>1% 01 >1% 50 on FUE
- #D'ATIC PEIR:1.E!t1IUPIM (AMTIC HYORotta) 100pos 100pos - 7.5
),1% )1% >17.
ETHYL E012BE (ARTATIC HYDROCM90N)
- 07. >1% ).1% taE POE . 0.01 2 f. 6-TRl(OltETHYLA91tDETHYL)PF00. (UYL #tifE) 20E 1.0
- 07. > 17. . )1% 1one
. OIETHYLBE TRIA11tE (UYL AiltE)
TFE FOL.LOJitG RET DP09fE POTEtHIM. C0t1J) EXIST AS taWL OGi >1% HA2MOS 6sva ' m 001 15mg/m RatNitGIDE OED C0AT!?G
> 17. 0%
SD75 TOE SILICATE (TE) mE
> 17. 07. >11 an9s / 6 sin
[ I - MIS R/G t'ATER14.15 A CMC!tHEN m A SEPECTED CIRCitaDI. _ EECTION III - Pl#51 CAL DATA VV T 09 61TY: 15 LIGiiER THW A!R.
\0.ATILE BY LEIGiD 24 - 27%
3)!LItG RNE: 199 - 3I.6'F
\0ATILE BY VOL.ttE &3-167. EVMTAi!01 RAIE: 15 3.05 THW EDE.
tiled LE!H/CA.LO : 10 - 13 LES./GL. (U.S.) -. _ SECTION IV - FIRE AND EXPLOSION HAZARD DATA
~~
FLA94 POINii(PtCC) FT.M"E LEL: 0.9 4., FL#f'/a!LITY CL451FICAT101: (EM): PT. A - FLATA3.E L10J10 - CLASS IB FT. B - FLATA1E L13J1D - CL/5 IC (IDT) : PT. A - FLAW 8.E L!MD E SLIO PT.BE80'F
,.. ,s.'yfisiD
{'M PT. B - FLATELE LluD m 31.10
'ljG 251987., %d\
. t, w-ORY 00:1C4., VAER FOG CR OiG PEDIA SJITA3I FOR El.VEtHS IN ECT!Di l-(1. ; .
., $6 ~ 9h,j Exf!UJISiltG TEDIA: '
,. -gen O.";'
I titSFL FIE #D ERCS 101 HAZMD: KEEP CORAltES 11MLY CLCED. ISlAE F101lEAT 5 MKS, ELECTRICAL EMPt d A-! C0!TAyEE RAY EE.00E 401 EPRD TO EXIEtE FEAT. ' w* M/
. . , ., j SEC!ti FIET19filfG FREEDLES: miER PAY BE LED TO C03. CORAlfES TO FEE 1T F~.EESE MLD 'P #D P - . X' ZED TO EXIPSE EAT. IF.mtER 15 LED, STAT t0Z2LES ME PREFFA1E. MTER EPRAY rAf1.BE IfEFFEtil\E. - .. _ , .
SECTION V - HEALTH HAZARD DATA _ _ _ 7 Da DP03E ltinAllai:1RRilAT101 TO TE REPIRAITT TRKTJE/0AO-E,0!ZZl!E55, #0 t# LEA #5 POS!al. SKIN COHKDPRIPAtY l
.301 EE CaliKT61r/Rf IEllA1101.~ LEt0 0RQrATE IS A SFECTED CtJCitHDI. LEM VRTRIAE ESP 7 05-97AY #D MPo0'RIATE 190TECil\E CLODil!G 10 RENENT 9:lN C04TKI. DCESSitE ODIC LO 171 T.E tDRH, LCSS 7 IFEllIE, !fDIESI!O4. t; LEA, \UYilil!Gi CO6ilPAT101, taRit#L CP#P3,.SE.5LIEtESS #U LEMtEES. UT O!EF5LBE TEIA*lfE) /PE 9:!N EtSiil2ERS. A0iG 9:lN COUKi t 0 ItMAi!01 BY '.EtRitG AP R:PR!AE ROTECiltE CLOTHit GECT101.' MiWYEiWia. tid MT}DXYETWia. KETAlE C#1 EE ESHED /FIER CE/Le 9'!N, E ltWIN101 EXP0 ELE, #D CA*
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i,s 09-5903-A/09-5903-a - 09/22/86 , PAGE - SECTICN V - HEALTH HAZARD OATd - cont... , . 4-. 3 EDIIS 8.0CD, liter, K10EYS,#0 TESTES. mE SilDIES lt01CATE LOG-TERM OFU11C ENE TO 2GCOEima. #0 2{RTEiSU. KETATE t%f
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E C00!T105 FRGE 10 IGFAVAT101 BY EXF011B UUU.N. W RJJIEG) T ENTRT: KWIL#0ItmAT(DL 3CY A'O FIRST A10 FF0CHIES: Irm.AT101:RDUE 10 FE91 AIR #0 ESITE BEATHitG. TEAT SYtFT0FAllC/LLY #0 COSI.T A FHYSIC ST:Et0E C0AlltG U11H SLtENT lifEDIATELY u01 #TECTED ATA WITH !DP #0 mTER. COELT A FHEIC1/N IF 1RRITAllm PERSISTS. ETE @FUDI IttfDIATELY WITH UEE #RNIS T WTER fm AT LEAST 15 tiltUE. TNI TO A RiYSICIAN F01 PEDIC/L TEAitD#. ItG31101:0RitK 53 7 mTER TO DIt!JIE. 00 tai ItDIE V0111TitG. 00 ALT A RiYSICl#101 F013N C0iTRQ. ENIER. fm Det!CA. EtEDCY - EPILLs LE/K" f!E @l01, m EC10ENT CALL 001TEC 1-E10424-9303 CAY m NIGii. , SECTION VI - REACTIVITY DATA CLITY: THIS MmET IS Sital U001 fUm. STOME C00lT!05. HAZMDQlE FQ.YLlAT101: WILL ICT ECLR tt002 iDM. C00lT105. 015 EC7 POSIT 10J RmET5: CMB01 PDCX1ErCM801010X10E, #0 FOSSla.Y ttD91YDES. 8T106 TO AW10: /L!D t%Y F900LCE FUES 001 FEAE TO DEC0f0 SIT!W,16 IN LEl.DItG. FlfES t%Y C06AIN OX10ES 7 tEitLS LISE Ill ECTI%il. FAllBilllY (PATER!tLS TO AW10): t0E ESara.Y F0HEABLE. m SECTION Vil - SPILL OR LEAK PROCEDLRES @ 10 E WDi IN CAI t%TERl/L 15 ELENED m FILLED AY010 WEATHitG SLVENT VtPTS. EtBRE #0E0JATE vet #!LATIOL AW10 FtrTS, FLATS #0 P.101 C0J 0 C8E FPE. nO!5FFit.fEi@s HN. LIQJ!DS WITH SULST m FXS #0 EVE. FLlDi WITH mIER If POSSISI. AV010 EKIN CalTKT #0 OlEF0E LCC#L, STATE #0 FEEP/L ERLAT105. SECTION Vill - SAFE HANDLING AND LJSE INFORMATION BIPalmYR20Eilm: N!0 EMS % #PROED RETIRATE TES SJlital fm FATERitLS IN ECTim 11 RECGTBED. #TWiD ODilC#L tEO ItCED UEN VENil!Allm IS ESTRICE. FilAllm: Sff!CIEN! WallAT101, IN'ta trE #0 FATEci, 90LLD EE FROVIDED 10 KEP AIR CQatnit%ilm EELOW QEDA #itlttaI (SM RR11SSlai 03E L!till m ACG11'S TLV Littli tlSE IN ECT10111. $11tE DAES: FHOETM E.045 Etat 00ED. , fE0ET101: ODi!C4. GELIS WITH SIDE 9118.05 01 FRE SilEDS ECGTBCED. BROTECT!tEEEFtD4: PROTECiltE CRE#5 #0 0.0iHitG EC0;DCED TO AW10 SKIN C00/4T. 5 EICW!E11CES: WSi MOS EEFEE EA11tG, 5 u b Ut LSitG i s ESIRom, SEE IN CESIG%E MEAS OLY. SECTICN 1X - SPEC 1 AL PRECAUT1ONS - LU110510 BE It(IN IN MD.ItG #0 SimitGi SITE PATERiti IN A C00. EY MEA WlIH tEtHILAT10! SJITNLE FG STmitG t%IER LUT!GS: FED /IT EEFIRATmf PR0iECT101 KAl!ST SUI NO FJES ETEATED DmitG actitG CR QJSTS E'ERAE Cml!G 29 UR FtRIS 1915,1916, #01917 E3J1E TE FEPGAT1017 THIS FATER14L SVETY DATA SET. -~m____.____ . _ _ _ _ _ . . _ _ . _._ _
Form E010B COATING / THINNER DATA FORM
- Company Name: .bflDt}tWAN UMR MY BIAltK5([ Llf)' y_
Applicable APCB Certificate f: $ DST 9$ddf7 f MA/7d/k F W/-{VD M M b i' Product Name: IDSTf2/4 L b4AAEl-Product Manufacturer:'((fE bNDillld 'OlL4(AMS b Usaae Data Daily (gal / day): [/5h O M 80b Annual (gal /yr): J W/5 = 7-Rule 25.43 & 25.44 Analysis or Manufacturers-Certification Data *: h 772 M
-As Received (Concentrated):
Density (1bs/ gal): b, bb ;_ Solids % by Weight: bO % by Volume: 2e9 VOC % by Weight: 4O % by Volume: '! ., Water % by Weight: O t by volume: O As Applied (Diluted): ,j. g p g3 A ggg Density (lbs/ga1): bymhe . Solids % by Weight: t by Volume: VOC % by Weight: % by Volume: Water % by Weight: t by Volume: Thinner Data chemical Composition: ,A Density (lbs/ gal): / Mfr. Data Sheet or Certification is attached. Yes No i
*For NSPS Sources Method 24 must be used. 4 j
l This is to certify that this information is tr anp com lete to the best of my knowledge. Signature: " . [W2 } Tit 1e: Adh'Htt a=[W%fAm46. Oulu7v ' j 11/03/89 RMP
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l B54 W.102 i l. M ATERI AL. SAF'ETY DATA SHEET 12 FOR CDATINGSe RESINS AND RELATED MATERIALS. (Ap. roved bw U.S. Derartment of Labor ' Essentially Slatiar' to. form MHA-Ph SC*.8 MANUFACTURER'S NA1E -EMERGENCY TELE 7H0NE No. THE SHERWIN-tJILL I AMS COMPANY (216) 366-2917 E D EII' i L t-101 Prospect' Avenue N.W. Cleveland, Ohio 44115
. MTE OF PREP ARATION IrlFO RM AT I ON - T EL EPHONE.140.
5-Mar-86 (216) 566-2902-
.. .........c......................................................... .......s '
Section I -- PRODUCT IDENTIFICATION PRODUCT NUMBER * - Trade Mark B54 W 102 PRODUCT NAME Industrial Enamel, Midtone Base PRODUCT CLASS-Al k w d Er.asie l ,
................................ 4............................................
Section II -- HAZARDOUS INGREDIENTS ING G IENi FERCENT TLV-PPM TLV-MG/P.3 LEL Y.P. CAS No. 6a7a2-47-9 Mineral Spirits. 40 100. 581. 1.0- 2.0 s Section III -- PHYSICAL DATA EVAPORATIDH RATE -- Slower than Ether VAPOR DENSITY -- Heavier than Air BOILING RANGE (F) % VOLATILE VOLUME WT/ GAL 300 - 395 57.1 8.A4
....................................................................... 2.....
Section IV -- FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION FLASH.FOINT 101 F PMCC LEL 10 Cosbustiblee Flash above 99 and below 200 F EXTINGUISHING MEDIA Carbon Dioxidee Drw Chemical,e Foam UNUSUAL FIRE AND EXPT.0SIO4 HAZARDS Keer containers tishtlw riosed. Isolate from heste electrical eautreente seerkse and o*en flane. C1ssed containers uaw explode when exposed to extreme heet. Apel! cation to hot surfaces reoutres special precautions. Durins emersonew conditions overexposure to ; decomposition Products asw cause a hest th hara+d. Svastons saw not be insediatelv apparent. j Obtain medical attention. SPECIAL FIRE FIGHTIN" FRCCEDURES : Full Protective eculp 2nt includins self-contained treathins areeratus should be usec. If water is usede fos no:=les are preferable. Water siaw be Water sprav nav be ineff. Tive. used to cool closed contantsets to prevent Pressure build-up and possible avtalsnition or explosion uner. exposed to extresie heat. l
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6 *sr.se.:s toisa ) B54 W 102 Industrial Enamele Midtone Base rase 3-l
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S tet.iors IX ~- PRECAUTIONS DOL STORAGE Ct.TE00RY -- 2 ] FRCCAt!T!ONS TO PE TAKEN IN HAN3 LING AND STORING .
- cntents art COMBUST *BLE. .t.eer aut.'* rom acat end open flame. i Consult tjFPA Code. . Use artroved Pondino and iroiannins *coesdures.
Keep container closed when not in use. Transfer only to a>> roved containers with comples arid aper aeriate labelins. Do not'take internallw. Keep out of the resen of children. ~ ' i
. OTHER PRECAUTIONS This coatins Contains materials classified as> nuisance /particulatese for exa4Ple titanium dioxideo caletus carbonater etc. (see ACGIH TLV i.ifite Pr4 face and Appendix Die which me:w be s resent at hazardous levels onlw durins sandinsi or abradins of the dried film.
Intentional misuse bw deliberate 1w concentrations and 'inhalins the contents can be harmful , or fatal. . l 1 The abcve ir.fors.ation Pertains to tht? acoduct as currentiv'. Formulated. and is based on the iriforsistior. available at this time. Addittors of reducers or other additives to this
- aroduct sow substantia!1w alter the ecorostiton and hazards of the protuet. Since conditto*,s of use art! outside our controle we aske no warrantiese exp ress- or ie*1:ed e and assume no
'( liability tr. eennection with anw use of this information. _-.:_-_--___ _ _ - . _ _ . _ _ ._-__s
'i 1
Form E010B -I l COATING / THINNER DATA FORM l
- f Company Name: . 12D)D/AA UOfAR MT* LWA/EK5tC LLS)! v2Ettj7"f Applicable APCB Certificate f: $NST.I$E47f MA/7d/bf W/71*/0M N b.
I Product Name: 1]I'1)$#/ dL. IA M Ll Product Manufacturer: %M TIbRVJIN' VL(L//M 6 b Usaae DA.tA Daily (gal / day): 8M C 0808 Annual (gal /yr) : //6# D f Rule 25.43 & 25.44 Analysis or Manufacturers Certific6 tion Data *: h TTA M As Received (Concentrated): Density (1bs/ gal): ) Solids % by Weight: 55 % by votome: 4 z_ VOC % by Weight: 45 % by Volume: GF; Water % by Weight: O % by Volume', h As Applied (Diluted): 7 g jggyp-Density (1bs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: Density (1bs/ gal): / Mfr. Data Sheet or Certification is attached. Yes No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true an{ omplete to the best of my knowledge. Signature: /J[li.J),.M I' tt'>4 Y[d Tit 1e: MJUMit azEWytwrAvra. Curt 7y 11/03/89 RMP L______________
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Form E010B COATING / THINNER DATA FORM. Company Name: bb7Q)tWAll $U6'18K MT* hA/ESSLC LLfy irgfjff Applicable APCB Certificate #: {$ 85T.N $ # M f M A/7 d /h>P W / 7W O M N b Product Name: bel /72oc kWT [LL bW-ThCE bJh4tC , Product Manufacturer:'70t_' 6I(hiRpJO ' kle LC,/AMs de Usaae Data Daily (gal / day): 8hO E O'OOb Annua 1 (gal /yr): 38 d5 0 7- "
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Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *:h 775M As' Received (Concentrated): , Density-(lbs/ gal): 9 Solids % by Weight: 6O % by volume: IO 60 l VOC 4 by Weight: 50 % by vo1ume: 0 Water % by Weight: O % by Volume: i As Applied (Diiuted): g ig Aj Agg/r-Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: i Water % by Weight: - % by volume: Thinner Data Chemical Composition: Density (lbs/ gal): / Mfr. Data Sheet or Certification is attached. Yes No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true and mplete to the best of my knowledge. Signature: } yb, }SA }d, h'd'#U / Tit 1e: AlhWit 'LPENV/khsurk OVkIDI ' i 11/03/89 ! RMP
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Form E010B _ COATING / THINNER DATA FORM
) fly BJA/A'SG~ LLfy' trgifffY Company Name: 0GO)O/AA l d'JC8R Applicable APCB Certificate f: NA/ST NAUX4f7f MA/Td/bf W/71a/0 M N Product Name: b31M/l A - NOO MTF% Nail -655 h61s Product Manufacturer: Y"' $/W$$ NILLlAM S p_saae Data Daily (gal / day): 7-/240 # Or 88[]
Annual (gal /yr): $ // s c Z_ Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *:h TTJ@ As Received (Concentrated): Density (lbs/ gal): /h solids % by Weight: 30 % by volume: 30 VOC % by Weight: /O % by Volume: 70 Water % by Weight: b % by Volume: O As Applied (Diluted): gg g gj g-Density (lbs/ gal): % by Volume: . Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water 4 by Weight: % by Volume: Thinner Data Chemical Composition: MA i Density (1bs/ gal): Mfr. Data Sheet or Certification is attached. Yes Io
*For NSPS Sources Method 24 must be used.
This best of is my to knowledge, certify that this information is true al,f_comleetothe f;, { Signature:[
- Oh U//n>J1 l
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l Form E0108. j _ COATING / THINNER DATA' FORM. l
' Company; Name: b23Jo/Aa Nuo<i21a Bar 42im dia.yAi,2, airy i Applicable'APCB. Certificate-l: MT $$gET f MA/Td/b/* W 71e/0 M Nbi
~
Product Name:- M}{TE dlf>55 6 //JI'- [AJA Af R Product Manufacturer: PPG $sJt::veres , Tac Usaae Data ;
' Daily. (gal / day) :- -
566 8*O M Annual (gal /yr):
>W/ 6 ;- b I
Rule 25.43-& 25.44 Analysis 'or Manuf acturers certification Data *:b TTJfMD W
.. 'l As Received (Concentrated):
Density (1bs/ gal): h h f~ Solids % by Weight: bI 2.- % by Volume: 43'7 VOC % by Weight: 3d b % by Volume: Id 3M Water % by Weight: O % by Volume: O' As Applied.(Diluted): sW AS 46o C Density (1bs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: j, Thinner Data l Chemical Composition: A/M Density-(1bs/ gal): / Mfr. Data Sheet or certification is attached. Yes No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is t e com le e to the
~
best of my knowledge. Signature: .
'u NIL 5 T1t1e: AJk'Jdt , LP FIN /t>aAmurk. Oukt7y 11/03/89 i
- _RMP.._______
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HATI* RIAL SAI'ETY DATA SHEET COATI) lgs AND RESINS GROUP (. SECTION I - PRODUCT INFORMATION namufACfuttR'S NAMil PPC IN0usf a stl .lwC. C00s /10t N ti f f 6-252 - t0130aa0) . PACouCf SAf tff LOC.: 260 EAPPA CalVf 3 f ta05 mant s Wullt GLOSS ttf/lNI ENAMEL e Pif f 5tueGN, sa 4238 CNEnlCAL f antLf t Altt0/Of L . mIOS CONF aCf 3 MAsAGla, lh0u5 fat AL #ff.!ENE ' U$'00f sPaluf, Consu$figLt (10ule . Am0 oaf t 03 PREPA8Afl0NI f/14/6F - id (412)PRODUCf 9d,313*2 tast {*V- CusicMat PAaf se initCENCf TELtPMouti - (306) 643'13C0 - -* SECTION II - INGREDIENTS. j = APPRON . . t W P O 8 414 i ACClu TLV , OSMA PEL L1ni13 PPG IPfL ,.s.. hf . CAS No. 3
. Attselmun $1LICAff 1 1335 30 4 ' sof 657. m0f t$f. mot ist. '
fifAnlun DIDXIDE s 30 13463 67 7 10.00ns/m3 15.00Mg/m3 10.00ng/n3 NY0a0fatAff0 stavf maputnA I$ OAF 42 68 9 : 801 851 . NOT tsf. Not ist. Nf0f0f atatt0 a100Lt etst!LLAf ts - 5 e4742 66 7 m0f 851 mot ist. mOf tsf. ntplun AtlPmallC $0tytut mAPufMA 20 647&2 68 7 ' bOf $$1. WOf fif. NCE ($f. fitn 80sutas, ansl#s, A=0 A00lf tvts 30 Pe0Pattfatt =0f tst. NOT asf. m0f: Est. CAaCINeatstC AcCcnol=G 10 Calife:A E tf ant isat0 en *.=fP ** . T Asc 0 = csua ' e = Of ate 'j SECTION III - PHYSICAL / CHEMICAL CHARACTERISTICS i [ BOLLING RANGt f 100
- 273 MG.C sotusltiff in heaf tas 0.1 E 1
\- WAPOR P8ttsuet: 0.5 anW9 WT/ CAL (L31)1 0.84 (u.$.) l i v4POR Otu$lff i NEAvlta TNAN Alt PM U/l !
-1 WOL/v0Lunt 54.30 % 50Ll0 sf wilGut 64.2 .{(
EVAP Raf t($sCAes1001: 10 SPicif fC C#Aviff f 1.18 SECTION IV - FIRE AND EXPLOSION HAIARD DATA I ul 00f CAftCCRit Contulf f BLE l ILAINPolmf g TC6 CCG. 7 PnCC f tAnMASLt L4mif 5: LtL 0.8 bfL u/l j fvf fwCtrifwf wC W'h l Lst gallonAL f!ag # A0ffCflou AHOCI AfION InsPal CLASS $ (IllNC4fl$Htal (CAttes 010M108. Off J 1 ChinlCAt. Ce univtatat Acutcus fitn foentuG f0amt Of 5icut0 f0 taflucullA #7PA CLAtt il CCP%31.8Lt LIC.tIO flats. UwU5Unt t eet a=0 esetotten mataeM;
*' sitP CChialatal fli.af t? Ctott0. Isos.Aff f aen utAf Etttf afCAL E0ulPntsf. spaars, amo Opts FLAmtl. Clott0 C*6f altitt naf S apt (21 WatN ERPOSf 0 to f attant NE Af. DO NOT APPLf Ou N'If -
Suaf ACil. TCxlC CAttl MAY 90an wwtu PRODUCT l$ CCNT ACit0 SY f TAME 011 nOf tunf ACES. -.
- PEC T st a lef
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.Alta SpaAf naf $4 ;htef ECf!vt. waff t 5P#af aaf 68 USE0 fD COOL Ct05tp Conf AINttl 10 ;
Petvtel petttt.At 4.*tD up ANO sussisti autotCulf104 08 taPLOllCW Wats tup 05t010 tuteent 1 at AI . If WAf f a 15 .,$tc. 706 n0Z*Lt$ Age PRtitta8Lt. fif t flChitBS Shout 0 WEAS SELF CCatalmtp Sat Atuta APsamatus. SECTION V - REACTIVITY DATA stattt f f v STA8LE **f **0071 89"f'f f af f 0*' =0f S APECit0 TO OCCus encomen tief t tf' rea f tef ats n=0 ry,e: ocus ?O avolgy,;,, Avol0 CDest ACI wt f e slacmG ALLAtiti. STRONG NINf 944 ACI0t. 01 Sta0=G ONI0111NG AGehf $.
*afisecus ett>*esi1ie we0Utf,13.
MAT Pa0 Duct na2AaCDf5 CICOMpollflos Pe00uCf t uwid at Atto, utLDING. samtlNG, ce PLAaf Cuf fluG CN SL 87 Acts CCalte Witte Thil PRODUCI nAf PRODUCI funti INCLUDluGt Carcon nonossee, SECTION VI - SPILL OR LEAK PROCEDURES titP1 f0 8E 'aste f4 Calt maff else f ett f eefft no qPf tt t0;
- etevlDi masis.un visi!Las 60s. Out t plas0sentt (GUIPPip WlfM PEOPIB RitPf RAf 0Rf AND lale ANO ETt Pa0f tCilCW IaCL.C Et Pt4Mif f t0 lu tut Aata, etnovt Att 50usCEt 08 BCwf f l0N. Tatt up SPfLito eartas AL .;'s SAM)ust , '.tBMICJLif t. 08 Otute Asscastat matrelat awo PLACt into t
+
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- 4t Ol tf t,:,LO Cf la aCCf.aCahCE wif N FlotaAL. $1 Af t. AND LOCAL anvisDeemEnf at Cte,te . s t GVl a l!LN$ . EMPf 7 CONtalktal Shout 0 ti stCYCito 08 Ollposto of ,
ImacuGM As Appec.d asit MAnactuined f ACittf.
- SECTION VII - HEALTH HA"ARD DATA tretets os evest.Pesuet ww.
===
InGI 5 f lcm: nA&mf ut Oh # At At l a WAi t tat u , CAusil 4 f t thall At 4:m. SCN sala CcNi ACfi ra f CAvst ='At aA*t o ;n ;ssi! Af ten. 4
$Jb b k h lNWAL All0N l uros a.0 tema, n. a f .. . Ci .a. .ut i f; te..At to . I Ctait ths t0 Ch Pact 2
r-r l a 1 acGius v nciALin nAZAriD OAl'A f
- I vaatswouo s mer_vatwa 400 com for solvent (iscoropyl alcohol) u tcis o, ovensoosvas f111d dizziness wnen continuously inhaled. !1icht be irritating to skin of sensitive
/
persons. ( tTgnog=cv t amo reasT aso PooctDvatsskin contact, wash witn soap and . water. If swallowed, do not induce vomiting. Call physician immediately. 1
- e. ,I . ,
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.# !4 ~ SECTION VI REACTIVITY OATA ih(
- g-
"a a " v~na.c.
l co~o'm~"a av**
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encou** t a miss Tv se,annes so s*mer gb' Cr,3 h , 41amoovs oscoucosettoH PADNACTs None f(q ts coNoITIONs To Avolo Q*yma .4 paraaOOUS
" poLyug allaTION * *g,/
- W8LL NOT OCCUR l y l
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%"g SECTION Vil . SPILL OR LEAK PROCEDURES g -
I stres To et r**tm i~ cast marsaias is asutasto on saiu to
- /'l.4
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' Wipe up with rags. Wash of f with alkaline detercent. *
%y 4 *:'
.asts oiseosaw ust" Discose of in accordance with local, state and federal 75 7 - renul a tions.
$l' b <
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Ja*N .i {.f n I SECTION Vill . SPECIAL PROTECTION INFORMATION
.4 asseinar on < eao r sc: o~ ,3,,cif, '7P'I Not requi red
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- . (; ,,,,,,,,,, socaw sx-awn i seccias
unenan,cau scena n o,nnn.
' 5 C*" not required naosactiva ocovas flot required ;
l E'E '" otrca emotscrive sowinusar . l. I
- SECTION IX - SPECIAL PRECAUTIONS [
, s cau tio~s t o er. v ana~ . - ~ow.~5 a~o s t oa ~o -l Store in cool, dry place, of e.tn PatCavisons
/ aus PAGE (2) Form OSHA.20 TT:smi 8-5-80
_ _ _ _ ____ .l
Form E010B COATING / THINNER DATA FORM Company Nane: .0flDtJOMA YUMK !JT AflKSC LLF/ tygf/fy ' Applicable APCBsCertificate #: d1 Alit.NX/>EST f MA/7d/bf W/71a/o % Nbi Product Name: V0b (l/STiG L. GJ/wl FL iYal'lMD { clot,5 Product Manufacturer: If h/6FWM/" M/1/Alf b> 11 gage Data Daily (gal / day): k[2 60
- O O Ch'$
Annual (gal /yr): 3 #l5 Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: N ITTJf8DN As Received (Concentrated): Density (1bs/ gal): O. b Solids ~% by Weight: b 4 by volume: b6 VOC % by Weight: 7h _ % by Volume: 65 Water % by Weight: O % by Volume: O As Applied (Diluted): g plp A$ pype-Density (1bs/ gal): % by volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: Density (1bs/ gal): / Mfr. Data Sheet or Certification is attached. Yes No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is tr e an omplet to the best of my knowledge. /r / Signature: [ yJO> d W M -
Title:
A/Af1 W ocliN % @swfk. Dukl77 11/03/89 RMP
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Form E010B COATING / THINNER DATA JORM Company Name: .bfD)OM A YlE/12IK MN" fBIAl65G" LLE)' (TALTJO' Applicable APCB Certificate,i: ' ,f214/ST.N$#47 f MA/7d/bf W/71*/0 M N bi Product Name: GK DY bdNIhl' l
' Product Manufacturer: bk fd D t/ S T7'l C Luc- ,
Usaae Data Daily (gal / day): !7dd = . OC b Annual (gal /yr): Y/ 6: 2 Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: h O As Received-(Concentrated): Density (1bs/ gal): b, b Solids % by Weight: h,3 % dy vo1ome: 4.9 VOC % by Weight: N7 % by Volume: 63,/0 Water % by Weight: 4 by Volume: k As Applied (Diluted): $4W A5 /llioVF Density (1bs/ gal): % by Volume Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by volume: Thinner Data i Chemical Composition: i Density (1bs/ gal): / Mfr. Data Sheet or certification is attached. Yes No , I
*For NSPS Sources Method 24 must be used.
This is to certify that this information is tr:ve ; com le e to the best of my knowledge. Signature: lun,, t.tntU Of L, Tit 1e: 4/Jh'Mit LP EW/MthsvTK Cukl77 11/03/89 ]' RMP
- 4 %//M ' -
f gx y Mb i MATERIAL SAFETY DATA SHEl-1 M1C '
' COATINGS AND RESINS GROOP
( SECTION I - PRODUCT INFORMATION CODE / IDENTITY M __ (111885E) MANUFACTURER'S NAME:Q LEL TR AD E NAME : -- - ~.mt---- -T PRODUCT ISAFETY .6p,j,AffA,, PIJTSBURGH fg,1558 LDC.:)fjMN.D,ilS.E,g[Rivg]d CHEMICAL FAtiist2: tat dd" MSDS CONTACT: MANAGER"tND115THXLPAINT. HYGIEffE'}. COMBUSTIBLE LIOut000T CLS: A.tjD P.EQRUfJ,5 ETY DATE OF PREPARATION: ** T4'/UT/8Q LM @ $ 922 5 , EMERGENCY TELEPHONE: (304,)18,13-13#d i . SECTION 11 - INGREDIENTS , E X P O 3 U A E L 1M 1 Y S ( APPROK.
% Wf. CAS NO. ACCtH TLv OSHA PEL PPG IPEL INESED/ENTS a isss-se-4 Not Est. Nof Esf. N6f Esf.
f%Tsu r Nbu'.s t L t ca r ry to 13463-67-f is.seugius ts.eeugius to.eeug/W3
,, set.f =:J uu=crorspET 'M%^1*-- -.,, to sest-32-4 Nof.Esf. Not Esf. Not Esf. ,
gooor. cts s8pppgmAMts P tst rf r NOT E$T. NOT EST. Not $57. NOT EST.
. .H I GN [ 8 0 ! L I NO,, A L I PN A T 1C,1 'E K '[ s Not E57. NOf EST. NOT EST.
'uRtppg sPlarfs;iULT es80pW - is aest-22-4 NOT EST. NOT EST.
N f ulEJa nufMMMI AMA,NY ti filjlN AM 35 Poorn1ETARY NOT E31.
"'***"%L..I,.mC.sL
- D f h.'A 1at* 5"* O L SECTION !!! - PHYSICAL / CHEMICAL CHARACTERISTICS SOLUBILITY IN WATER: 0.0 % RECEIVED BOILING RANGE : 136 - 273 DEG.C CC!N VAPOR PRESSURE: 0.5 mmHg WT/ GAL (LBS): 9.15 I VAPOR DENSITY : HEAVIER THAN AIR pH: U/I
% VOL/ VOLUME : 53.10 % SOLIO BY WEIGHT: 62.3 MAY 6 1988 9
4 (EVAPRATE(BuGAC=IOO):SECTION IV - FIRE AND EXPLOSI 00T CATEGORY:TclitiffuSTlBLE FLASHPOINT:IID4TDEGr F PMCC FLAMMABLE LIMITS: LEL 0.8 UEL U/I EXTINGUISHING MEDIA: USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS B EXTINGUISHERS (CARBON DIOX1DE. DRY CHEMICAL OR UNIVERSAL AOUEOUS FILM FORMING FOAMI DESIGNED TO EXTINGUISH NFPA CLASS titB COMBUSTIBLE LIQUID FIRES. UNUSUAL FIRE AND EXPLOSION HAZARDS: ~~
~
TRlE760tdXUJEM5"fiGHiLir u.vstu.5150EATE LE C MEN r.' 5 par- v ==8MDM S 3 wyfs.msr4 VFEADETF'CEOSEDCOTTAINE'RT
,; SURF ACESS.TOXtC GASES MAY. FORM _ _ , . . . _ _ .
D.BY.F ~ - URFACEw - Q i SPECIAL FIRE FIGHTING PROCEDURES: WATER SPRAY M AY BE INEFFECTIVE. WATER SPRAY M AY BE USEDTO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BufLD-UP AND POSSIBLE AUTOlGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HE AT. IF wpTER IS USED. FOG NOZZLES ARE PREFERABLE. FIRE-FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. . s SECTION V - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR I N C OMP, AT I B I !.,LI,X,. GEE R I, ALJ,,,Mg,,,q,QfjQQJ.QJ15 T O AV O_I,0J: AvNiTACT W TH STRONG ALRAL ES. STRONG '4 MINERAL
"
- ACIDS.ORMS.GT7XOZMAGERI'SO{
a" ^"
~ HAZARDQU,5 DECOMPOSITION PRODUGS;" "~'"fWHENHEATED.I WELDING. BRAZING. OR M AY 5dDLTCE HK2 ARDOO$DE66uPOSITION PR'ODUCT FLAME-CffTTING ON SURFACES COATEDwtTH THtS PRODUCT MAY PRODUCE FUMES INCLUDING: ]
Carton Monoxide. SECTION VI - SPILL OR LEAK PROCEDURES k 5TEPS. TO BE TAKEN IN CASE MATERI AL 15 RELEASED OR SPILLED: _ Continued on Back of Page
~.. - _ .
. ' I 4' .C:ntinuitiol of Manufacturer's Code 110 DATE OF PREP: 4/01/86 .
I _
~
- 'PROfiCf MAXiiiUU VtNTICATION ONLY~PRRSONNEl EQUIPPED
~ ~ ~~ ~ ~ ~~
y' , EYE PROTECTION SHOUT D BE, PERM'TTED INJNE*AREMREMOV ~ SPILf.EDMATtRIAlbwiTHSAWOUST7VERMICUtfTE'.'060TNER ABSORBE i, CONTAINE RS FOR' DISPOS Ati P/ "'"'~~ '~~ ~ ~" ~"**"*"* """*'*-"* ** "'" "*** ** *~~"' L WASTE DISPOSAL METHOD: . W ASTE MATERIAL MUST BE OtSPOSED OF IN ACCORDANCE WITH FEDERAL. STATE. AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVEDWASTE MANAGEMENT FACILTY. SECTION Vll - HEALTH HAZARD DATA ~ EFFECTS OF OVEREXPOSURE FRON: , INGESTION:..- ~ ,, - HARMFUL OR FATAL IF SWALLOWED.V , EY.,E. CONTACT: ',. i
. CAUSES EYE IRRITATION.
SKIN. CONTACT:..... . . . . . . . . . . . . _ , I I MAY CAUSE MODERATE SKIN IRRITATION. . INHALATION: '
- VAPOR *ANCTSPRAfMISTM AY BE HARstTJETFT#M . . _
'3 /
REPEATED EXPO.SURE TO HIGH VAPOR CONCENT5thT)CASMAVC AUmmarraw%_ rMmnoi '
.5YSTEM ANQPERMANENT. BRAIN A70 NERVOUS SiSTEMDAMA'GE.Y@MtMNMMtg ,,,.q INTENTIONALTi1SUSE BY DEL 18ERATELY CONCENTRATING AND INHALING - - -~..s.,7,y,,U.L[*,',
THE CONTENTS CAN BE HARM..F OR FATAL. CHRONIC OVEREXPOSURE AVOID LONG-TERM AND REPEATED CONTACT. ]
/
SIGNS AND SYMPTONS OF OVEREXPOSURE EYE WATERING. HEADACHES. NAUSEA. DIZZINESS. AND LOSS OF COORO! NATION ARE INDICATIONS THAT
- SOLVENT LEVELS ARE TOO HIGH.
REDNESS. :TCHING. BURNING SENSATIONS AND VISUAL DISTURBANCES MAY BE !NDICATIONS THAT EXCESSIVE EYE CONTACT HAS OCCURED. DRYNESS. ITCHING CRACKING, BURNING REDNESS. ANDSWELLING ARE CONDITIONS ASSOO.,TEDWITH EXCESSIVE SKIN CONTACT. NOT APPLICABLE { MEDICAL CONDITIONS SECTION Vill- AGGRAVATED FIRST AfD PROCEDURES BY EXPOSURE: INGEST. ION:--- . _ IF SWALLOWED. DO NOT INDUCE VOMITING. , EYE.p0NTACT.: , . ... , . . . . . _ . .
,1N CASE OF, EYE CONTACT. FLUSH EYES IMMEDIATELY ~ "' ' ' 'WITH ' " " PL5NTY
" ' CF WATER FOR AT LEAST MINUTEST '~
SKIfLCDNTACT.: ._,.._ . . . .. . - . , . _ _ '
. IN CASE.OE. SKIN CtMTACT. REMOVE PROMPTLY BY WIPING;FOLLOWED BY.WATERLtSSIHARCLEAm" -W
' " *~'""'"'**#'"
SOAP AND WATER *- INHALATI0N n ,_.._,. _._ .
" .lF AFFECTED BY.lNHALATION OF, VAPOR,ORSPMYJAIST..REMOVgOggR. AP,PLYgT!,FICIALy ' ' * "
RESPIRATION AND OTHER SUPPORTIVE MEASURES AS REQUIRED. ,a - 1 1 OTHER: ..-%. l. } IE.ANY 0F.TMEQLLOWING OCCUR DURING OR FOLLOWING USE OF THIS PRODUCT.. CONTACT A pod 2f'Q ] 7'CC,NTROL CENTEGMERGENCY ROOM OR PP"/SICIAle IMMEDIATELY; HAVE MATERIAL' SAFETY DATA SHEET
" j
'INFORMATION AVAILAtsLE. *lNGESTION.
- EXCESSIVE EXPOSURE TO A CORROSIVE MATERIAL.
l j
- PERSISTENT SKIN / EYE 1RRITATION OR BREATHING DIFFICULTIES.
SECTION IX - PROTECTION INFORMATION ,
' PERSONAL PROTECTIVE EQUIPMENT FOR:
EYE PR0TECT10N: ;... . ....__ _ _ __ _ _ _ , , ,, WEAR CHEMICAL-TYPE SPLASH GOGGLES OR FULL FACE SHIELD. ' 4 j SK,1N. PROTECT. ION: -.~~.* WEAR PROTECTtvE CLOTHING, INCLUDING IMP.ERMEABLE APRON AND NITRILE RUBBER. NEOPRENE RUBBER OR PO!'YMNYL' ALCOHOL *" ' l RESPIRATORY PROTECTION: i Continued on Page 2 . ; ; \ Q - i ! 1 l 1 Uh ___ - _ _ _ _ - - . _ _ _ _ _ _ _ _ _ _ _ _ _
- - - .. .I
. 1,
'o ,
I ; , PAGE 2 ; i Continuation of Manufacturer's Code 110 , OATE OF PREP: 4/01/86 OVEREXPOSURE TGVAPORS MAY.BE PREVENTED BY ENSURING. VENTILATION CONTEOLS., VAPOR EXHAUST OR FRESH AIR ENT11Y. MOSHIMSHA APPROVED (TC-13C-) PAINT SPRAY OR AIR SUPPLIED (TC.'9C-l? 1 RESPIRATOR $ MAY ALSO REDUCE EXPOSURE. IN ALL CASES. READ RESPIRATOR MANUF ACTURER'S INSTRUCTIONS AND LITERATURE CAREFULLY TO DETERWNE THE TYPE OF AIRBQRNE CONTAMINANTS AGAINST WHICH THE RESPIR ATOR IS EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED. ' 071}ER,EQUIEMEN.T.: - m a . - - - ,-._. .-. _.., CLE AN OR DISC ARD CONT AMINATED CLOTHING AND SHOES. - VENTILATION REQUIREMENTS: _ _. ._._.. ....... .... PROVIDE GENERAL Dit.UTION OR LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP THE CONCENTRATION OF INGREDIENTS LISTED IN SECTrON il BELOW THE LOWEST SUGCTSTED EXPOSURE LIMITS. THE LEL IN SECTION iv BELOW THE STATED LIMIT. AND TO REMOVE DECOMPOSITION PRODUCTS , DURtNG WELDING OR FLAME CUTTING ON SURFACES COATED WITH THIS PROOUCT. SECTION X - SPECIAL PRECAUTIONS HANDL.!]LG_AND. 5T,0 RAGE. PRECAUTIONS: . . r - -em--- rem - = , . ,,-, y YDO NOT STORE ABOVEd20 DEGREES ,%STORELARGE,00AN{lTICMPLDUf LDING$ DESIGNED,ANO ,1
' . PROTECTED FOR STORAGE "'""' OF WPA CLASS ~1118
~ "'COMBUSTIBLE
" " ~ ~ ~ ~ LIQUIDS.
~'""
OTHER PRECAUTIO.f5: IF THIS M ATERI AL 15 PART OF A MULTIPLE COMPONENT COATING SYSTEM. READ THE MATERIAL SAFETY DATA SHEET (S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS THE RESULTING pMIXTURE MAV HAVE.THE. HAZARDS.0F ALL.0F,1,TS PARTS.
' ' CONTAINERS SHOULD BE GROUNDED WHEN POURING.' AVOID FREE FALL OF LtOUIDS IN EXCESS OF A FEW
' INCHES.
'- I ALL CHEMICAL SUBSTANCES IN THl3 PRODUCT COMPLY WITH ALL APPLICABLE RULES OR THE ENVIRONMENTAL PROTECTION AGENCY'S TOXIC SUBSTANCE CONTROL ACT.
THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA HAZARD - COMMUNICATION STANDARD (29 CFR 1910.1200) Ull = UNKNOWN INFORMATION N/A = NOT APPUCABLE NOT EST.* NOT ESTADUSHED 9 g L e .:; P L . 1 u__
4 Form E010B _ COATING / THINNER DATA FORM CompanyKame:.6/13JOMN U$lAR NT* BIA/E55G~ LLE'Y tyMT)fY Applicable i APCB- Certificate f :. MA/ST.N$#457 f MA/Td/DP W!7WO M N I Product Name: IhRl LLMllT ND cf LOSf_ [-f44 /447 I Product Manufacturer: bDd3772/4"E Usace Data Daily (gal / day): ~/-[84C L Or b 8 . Annual (gal /yr): Sf// 6
- L l
Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: h h @ As Received (Concentrated): Density (lbs/ gal): 8 25 c ' ids % by Weight: M;b Y % by Volume: 5/.4 4 1 by Weight: 3 3. / % by voiume: (4tio Water % by Weight: O % by volume: C As Applied (Diluted): <jgp A5 /ADVe Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: ( Density (lbs/ gal): / Mfr. Data Sheet or certification is attached. Yes No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true an com le e to the f best of my knowledge, qf Signature:/ . _ Ill/ 44' 4 , t/ Tit 1e: //h' int LF[W/kghsntLt. Oukt77 11/03/89 RMP
. . d 4 / /.U f...' m,/9 w
. . 1 i f
D /M M1 l , MATERIAL SAFETY DATA SHEET l '( COATINGS AND RESINS GROUP SECTION I - PRODUCT INFORMATION MANUFACTURER'S NAME: PPG INDUST,RIE5' INC. CODE / IDENTITY :054'506I (1115840). ' PRODUCT SAFETY LOC.: 260 KAPPA DRIVE , TRADE NAME: 881udrii'REO GLOSS ENAMELT.! PITTSBURGH, PA 16238 CHEMICAL FAMILY: ALxYo : MSDS CONTACT: MANAGER. INDUSTRIAL HYGIENE 00T CLS: PAINT. COMBUSTIBLE LIQUID
- AND PRODUCT SAFETY DATE OF PREPARATION: 3/06/86 '
EMERGENCY TELEPHONE: )(4 IE).,963,,5822 j(304)- 843-1300 ;,y SECTION ll - INGREDIENTS APPROE. EI P O S U R E L 2M I' T 3 INGREDIENTS % WT. CAS NO. ACO:H TLV OSHA PEL PPO 2PEL ALUMINUM SILICATE 18 1315-38-4 N/A N/A N/A
@C3hLESS MINERAL SPIR 373 20 S.32-32-4 M/A N/A N/A
, P20 PYL E NE CARSONATE- % <1 198 32=f N/A N/A N/A
, METNYL EINYL MEf011ME <1 96-19=F N/A N/A N/A '
f ',MI NERAL . S PI R I T 3N* 29 64742-40*f N#A N/A N/A r,ETNYL,9ENZENE, 41 100-41-4 199.99PPW 100.9ePPM tes.eePPu
.m eNE . u ; r . m. . . .. ....-,.-, ...... P. ......, - ...... P.
.g r tM r o E a s . .E : N.. .A N . Af o n i,v E s .. P.. P. i n. Nor nr. No, ist. Not nr.
9 SECTION 111 - PHYSICAL / CHEMICAL CHARACTERISTICS
~
BOU,ING RANGE : 100 - 242 DEG.C S0LUBILITY IN WATER: 0.1 % VAPOR PRESSURE: 2.0 mmHg WT/ GAL (LBS): 8.25 ( VAPOR DENSITY : HEAVIER THAN AIR pH: N/A
% VOL/ VOLUME : 48.60 % SGLID BY WEIGHT: 61.9 EVAP RATE (BuoAC=100): 4 SECTION IV - FIRE AND EXPLOS!ON HAZARD DATA DOT CATEQ RY: COMBUSTIBLE ....
FLASHPOINT: 101 DEG. F PM6C FLAMMABLE LIMITS: LEL Q.9,, US N/A EXTINGUISHING MEDIA: USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS B EXTINGUISHERS (CARBON DIOXICE. DRY CHEMICAL OR UNIVERS AL AQUEOUS FILM FOAMING FOAMI DESIGNED TO EXTINGUISH NFPA CLASS lilB COMBUSTIBLE UQUID FIRES. * ~ UNUSUAL FIRE AND EXPLOSION., HAZARDS: .. . . . gMEEPCONTAINERSTIG@lkU , ISOLATEffilOMMEATs ELECTRICAL E . B6 BKS.AM10P ENEXPOSEDTO EXTREMEHE DOM' APPLY.ONpOTS*7 FLAMES.LCLOSED QQPfTAINERS SUFtFACES.*TOXId GASsShAVF'd .EN PRdOUCT IS CONTACTED BY M FLA' E'~ ~URFACES.
' "~ g" " ' "}f SPECIAL FIRE FIGHTING"PROCEDUREST * " " " '
p'a ~.i WATER SPRAY M AY BE INEFFECTIVE. WATER SPRAY MAY BE USED TO COOL CLOSED CONTAINERS TO
. PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTO!GNITION OR EXPLOSION WHF.N EXPOSED TO EXTREME HE AT. IF WATER IS USED. FOG NOZZLES ARE PREFERABLE. FIRE-FIGHTERS SHOULO WEAR SELF COMTAINED BREATHING APPARARIS, SECTION V - REACTIVITY DATA I
STABILITY: STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR INCOMPATIBILITY (MATERIALS AND. CONDITIONS TO AVOID):..- - . . _ . . . . . . . AVOID CONTACT WITH STRONG ALKALIES. STRONG MINERAL ACIDS. OR STRONG OXIDIZlNG AGENTS. / HAZARDOUS DECOMPOSITION PRODUCTS: . ... M AY PRCOUCE HAZARDOUS DECOMPOSITION PRODUCTS WHEN HE ATED. WELDrNG. BRAZlNG. OR FLAME-CtrTTING ON SURFACES CO ATED WITH THIS PROCUCT MAY PRCOUCE FUMES INCLUDING: Careon Monoxide. * - SECTION VI - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN NSE MATERIAL IS RELEASED OR SPILLED: Continued on Back of Page *
.p '
y ; 4 ., ,
- j {
.- ,; ,z j
F :ntinuation C of & nufacturer's Code 306 OATE OF. PREP: 4 3/06/86 . . . y~ .. s -- < ~
. ..... . .. ....,....._A. ,
f PROVCE MAxlMUM VENO sTION. ONLY PERSONNEL EQU!PPED WITH PROPER RESPIR ATORY, AND S N , 4
.' ; EYE PROTECTION SHOULL ' 'ERMITTEDIN THE AREA. REMOVE ALL SOURCES OF,lGNITION.'TAK.E P '
j SPILLED MATERIAL WITH SAWDUST. VERMICULITE. OR OTHER ABSORBENT MATERIAL /ND PLACE INTO'y 3
' COMTAINERS FOR DISPOSAL. .
. WASTE: DISPOSAL METHOD:
. WASTE M ATERI AL MUST BE DISPOSED OF IN ACCCRGANCE WITH FEDERAL. STATE. AND LCCAL ENVIRONMENTAL COWTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR,DtSPOSED OF THROUGH AN APPROVEDWASTE MANAGEMENT F#CILTY.
SECTION Vil - HEALTH-HAZARD DATA . . . EFFECTS OF OVEREXPOSURE FROM: INGESTION: , HARMFUL OR FATAL IF SWALLOWED. . , , DRIED FILM OF THIS PAINT MA// SE HARMFUL IF EATEN OR CHEWED.; S EYE CONTACT: CAUSES SEVERE EYPRRITATION. ' ' i SKIN CONTACT: .
. MAY CAUSE MODERATE SKIN IRRITATIOtt
- MAY BE ABSORBED THROUGH THE SKfN2.; .
' PROLONCED OR REPEATED CONTACT MAY CAUSE AN ALLERGIC SKIN REACTICN.
INHALATION: VAPOR AND SPRAY MIST M AY BE HARMFUL.lF INHALSD... ,, MAY CAUSE i UNG IRRITATION AND ALLERGIC' RESPIRATORY REACTION. REPEATED EXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY CAUSE IRRITATION OF THE RESPIR ATORY?' , SYSTEM AND PFPMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. '. . . . ! nf.k.. 9 INTENTIONAL L.10SE SY DELIBERATELY CONCENTRAT&NG APO INHALING THE CONTENTS C.AN. BE HARMFt,L). !
, . nn y,,,c,. . ....<.-...
REPEATED EXPOSURE: AVolD LONG. TERM APO REPEATED CONTACT. SIGNS AND SYMPTONS OF OVEREXPOSURE: . EYE WATERING. HEADACHES. NAUSEA DIZZINESS. AND LOSS OF COORDINATION ARE IPOICATIONS THAT.I
. ' ~~ ' ' " "'" ? "' '
- T [ * #
SOLVENT LEVELS ARE TOO HIGH.n NN *"**'~ . .
, REDNESS. ITCHIN3 BURNING SENSATIONS AND VISUAL DISTURBI.;CES MAY BE Ito CATIONS THAT' I !
' EXCESS 1B EYE CONTACT.HAS OCCURED.M l' '~
DRYNESS.tTCHING. CRACKING l BURNING. PIEDNESS. AND SWELLfkG ARE CONDITIONS ASSOCIATED WITHiJP,t EXCESSIVE SKIN COMTACT. * ! i.4. MEDICAL CONDITIONS AGGRAYATED BY EXPOSURE: NOT APPUCABLE SECTION Vill - FIRST AlD PROCEDURES , 1 INGESTION: IF SWALLOWED. DO NOT itOUCE VQMITING. EYE CONTACT: .. .. . , . . . . . . . IN CASE OF EYE CONTACT. FLUSH EYES IMMEDIATELY WITH PLENTY OF WATER FOR*^"#'~~~ AT LEAST 15'
. MINI]TES. '
~
' - ^
' SKIN CONTACT: . .
w r~ w ., IN CASE OF SKIN CONTACT, REMOVE PROMPTLY BY WIPING. FOLt. OWED BY WATERLESS HAPO CLEANER ' ' SOAP APOWATER. 4 -- <a "* * " ~ ' ' " INHALATION: . .sm.,,..... , , IF AFFECTED BY INHALATION OF VAPOR OR. SPRAY MtST. REMOVETO FRESH AIR. APPLY ARTI
. RESPIRATION AND OTHER SUPPORTIVE MEASURES' AS REOdlRE'D*.T" -~' ~~"****** *** I
" ~ " " ' ' l
*OTHER*
. h ANY OF THE FOLLOWING OCCUR DURING OR FOLt.OWING USE OF THIS PRODUCT) N j CONTROL CENTER. EMERGENCY ROOM GR PHYSICIAN IMMEDIATELY: HAVE MATERIAEMFETYDATA'SHIET
. INFORMATION AVAILABLE. *lNGESTION
- EXCESSIVE EXS'OSURE TO A CORROSIVE MATERIAL.
- PERSISTEMT SK!NIEYE IRRITATION OR EREATHING DIFFICULTIES.
[ Continued on Page 2 \ i L_______ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ . _ _ . _ _
t j ,pE P <2' . I 5 Continuation of Manufacturer's Code - 54 DATE OF PREP: 3/06/86 b06 o SECTION IX - PROTECTION INFORMATION l { PERSONAL PROTECTIVE EQUIPMENT FOR: EYLH PROTECTION: WE AR CHEMICAL-TYPE SPLASH GOGGLES OR FULL FACE SHIELD. f 1 SKIN PROTECTION: .
. t WEAR PROTECTIVE CLOTMNG. INCLUDING IMPERME ABLE APRON AND GLOVES CONSTRUCTED OF:
NITRILE RUBBER'.' NEOPRENE RUBBER OR POLYVINYL ALCOHOL"' f RESPIRATORY PROTECTION: OVEREXPOSURE TO VAPORS M AY BE PREVENTED BY ENSURING VENTILATION CONTROLS.
- VAPOR EXHAUST OR *
. FRESH AIR ENTRY, NIOSH/MSHA APPROVED (TC 23C-) PAINT SPRAY OR AIR SUPPLIED (TC 19Cs) * ~ .
.' RESPIRATORS MAY ALSO REDUCE EXPOSURE. IN ALL CASES. READ RESPIRATOR MANUFACTURER'S 8 INSTRUCTIONS'AND LITER ATURE CAREFULLY TO DETERM1NE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THE RESPIRATOR IS EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED.
.OTHER EQUIPMENT: .
CLEAN OR DISCARD CONTAMINATED CLOTHING AND SHOES. ' ' > VENTILATION REQUIREMENTS: ., . . . . .. . . . ._ .. PROVIDE GENERAL DILLITION OR LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP THE CONCENTRATION OF INGREDIENTS LISTED IN SECTION !! BELOW THE LOWEST SUGE.ESTED EXPOSURE LIMITS.THE LEL IN SECTION TV BELOW THE STATED LIMIT. AND TO REuoVE DECOMPOSITION PRODUCTS DURING WELDING OR FLAME CUTTING ON SURF ACES COATED WITH THIS PRODUCT. SECTION X - SPECIAL PRECAUTIONS HANDL.ING AND STORAGE..PJtECAUIIJMS:
. DO NOT STORE'ABOVE 120 DEGREES F/ STORE LARGE QUANTITIES IN BU LDINGS DESIGNED AND PROTECTED FOR STORAGE OF NF PA CLASS 1818 COMBUSTIBLE LIQUIDS.
OTHER PRECAUTIONS: IF THIS M ATERIAL IS PART OF A MULTIPLE COMPONENT COATING SYSTEM RE AD THE MATERI AL SAFETY DATA SHEET (S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS THE RESULTING
.1 .. . . - , .
MIXTURE M AY HAVE THE HAZARDS OF ALL OF ITS PARTS. . ,. ( j '... ',.COMTAINERS<
INCHES.
SHOULD BE GROUNDED WHEN POURING.' ' ~ ' * ' ' " ' ?M JAVolo
" ~' FREE FALL OF LIQ
.' ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPL'Y WITH ALL APPLICABLE RULES OR ORDERS UNDER THE ENVIRONMENTAL PROTECTION AGENCY'S TOXIC SLESTANCE CONTROL ACT.
THIS M ATERI AL S ArETY DATA SHEET HAS BEEN PREDARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STAiJDARD (29 CFR 1910.1200) 9 4 4 l l \L l i -_
- - _ _ - - ___ _________m_ , _,m y,% ,
Form.E010B COATING / THINNER DATA FORM Company Name: b20)rJMik l$[C$lt LAMT EllAIESS/K LLEY v71}TJ7~){ Applicable APCB Certificate f: [d9NST 9//>EMT f MA/7d/6/' W/7WoM Mf Product Name: b 'b b AiF7_ f 9867'Y YG.L,DjA/ Product Manufacturer: W( TsJDOSTRIGS T_tdc Usac:e Data Daily (gal / day): ~2 60 C O NO ._ Annual (gal /yr): < b6 5% '2 Rulo 25.43 & 25.44 Analysis or Manufacturers Certification Data *: h 72 O As Received (Concentrated): Density (lbs/ gal): 879 Solids % by Weight: Ne b _ % by volume: O. 2 - VOC %'by Weight: hb.1 % by Volume: N.hO Water % by height: O % by volume: O' As Applied (Diluted): 9 jg g e vg-- Density (lbs/ gal): _ % by volume: Solids % by. Weight: .. % by volume: VOC % by Weight: % by volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: Density (1bs/ gal): _
/
Mfr. Data Sheet or Certification is attached. Yes No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true a ompl te to the best of my knowledge. ep . - Signature:/ ~ ) l>Adll u Tit 1e: NJA'HtCa=EWVinsr /retra__ pujury 11/03/89
.RMP
- _ - _-____ -_________ ___- _ _ _ _ _ _ _ _ _ - _ __ . _ - _ _ _ _-. ._ _a
N ,
'l
' h,) bh ..
1 I . M i
- s, f ' *, " '
. MATERIAL SAFETY DATA SNEET l COATINGS AND RESINS GROUP i
SECTION I - PRODUCT INFOR*tATION
- ni CODE /IDENitTY : 54-308 (0129865)
MANUFACTURER'S NAMES PPG INDUSTRIES INC.
-TRADE NAME: 0 0 ENAMEL, SAFETY YELLOW PatsuCT SAFETY LOC.: 260 KAPPA DRIVE PITT!9URGN, PA 15238 CHEMICAL FAMitTs ALKYD p %
yh e MSDS CONTACTS MANAGER, INDUSTRIAL NYCIENE DOT CLStPAINT, CONSULTIBLE LIQUID g/ AND PRODUCT SAFETY DATE OF PREPARAfl0Ns 9/11/86 ~
- 4.-
(412) 963 5822 CU$f0MER PART #
-l EMERGENCY TELEPHnNE: (3041 843 1300 WSON SECTION II - INGREDIENTS
, APPROX. E 1: P 0 .5 u R E LIMITS
' 5 WT . CAS NO. ACCIN TLV OSHA PEL PPG IPEL INGREDIENTS.
$ 13463 67 7 10.00Mg/M3 15.0(>g/M3 10.00Me/M3 f!TAAllst DIDXIDE ALUMINLM SILICAff 10 1335 30 4 NOT EST. M0f Elf. NOT EST.
NOT EST. SEP 15 M 15 64742 48 9 NOT EST. NOT EST. HYDROTREATED HEAVY NAPNTHA 20 64742 88 7 NOT EST. NOT EST. NOT EST. MEDfUM ALIPuATIC SOLVENT NAPNTHA 40 PROPRIETARY NOT EST. NOT FST. NOT EST.
*" a ypg FILM FORMERS, RES!NS, AND ADDITIVES SECTION III - PHYSICAL / CHEMICAL CHARACTERISTICS SDILING RANGE 100 a 242 DEG.C SOLUSILITY IN WATER: 0.1 % 4 *y*
=
VAPOR PRESSURE: 0.5 mHg WT/ GAL (LIS)* 8.79 ' I ' 4 pNt U/I , g, VAPOR DER $liY t HEA71ER THAN AIR ' 1 VOL/ VOLUME : 51.80 % SOLID sY utlGNis 61.8 . t
/
EVAP Rete (SAAcet001: 11 SECTION IV - FIRE AND EXPLOSION HAZARD DATA 007 PATEGORT.: COM9UST18tE FLAfAPOINis 103 REG, F PMCC FLAMMA8LE LIMITS: LEL 0.8 UEL U/t EXIINGUfSNfkB MEDfar USE NAi!ONAL FIRE PROTECTION ASSOCIAfl0N (NFPA) CLASS S EXTINGUISHERS (CARBON DIDXIDE DRY , CHEMICAL, OR UNIVER$AL AQUEDUS FILM 70'tMING FOAM) DESIGNED TO EFTINGUISH NFPA CLASS !! COMBUSTIBLE tt0UID FIRES. UNUSUAL FIRE AND !QtPLOS10N HAZARD $t EEEP CDNTAINERS flGNTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND UPEN FLAMES. CLOSED CONTAINERS MAY EXPLCDE WHEN EXPOSED TO EXTREME NEAf. DO NOT APPLY ON NOT
-(' SUHFACER. TOMIC CASES MRY TORM WHEN PRODUCT lt CONTACTED BY FLAME,OR NOT SURFACES.
SPECTAl FfRE Q QH3NG PROC *DURESr WAIER SPRAY MAT BE INEFFECTIVE. WATER SPRAY MAY BE USED TO COOL CLOSED CONTAINERS TO PREWNT PRES $URE BUILD +UP AND POS$lBLE AUT0lGNIfl0N OR EXPLOSION WHEN EMPOSED TO EXTREME sfEAT. IF WATER IS USED, 700 -N0ZZLES AAE PREFERABLE. FIRE + FIGHTERS SHOULD WEAR SELF CONTAINED SREATNING APPARAfUS.
- SECTION V - REACTIVITY DATA STABILITYf. STABLE A M RDOUS POLYMERIZAllQN,[,LNOT EXPECTED TO OCCUR INCOMPAf f 81L17Y (MATERI ALS Aho CONDf fl0NS TO A lQ AvotD CONTACT WifH STRONG ALKALIES, STR0h4 NINERAL ACIDS, OR STRONG OXIDIZING AGENTS.
NAIARDOUS OFCOMoosifTON 'RODUCTS L MAV PR(OUCE NAIARDmJS DECOMPOSITION PRODUCTS WHEN HEATED. WELDING, ORAllNG, OR FLAME CUTTING ON SURFACES COATED WITH THIS PRODUCT MAY PRODUCE FUMES INCLLDING: Carbon Monom1de, SECTION VI - SPILL OR LEAK PROCEDURES STEPS TO 9E T&rEN IN CAtt MAYERIAL 13 RfLEAS2D 09 SPfLLED? I PROVIDE MAAIMUM VENilLAfl0N. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRATORY AND SKIN AND ETE PROTECTION $NaA.D BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP SPILLED MATERI AL Wl'h SAWUni, VERMICULlif, OR OTHER ASSORSENT MATERIAL AND PLACE INTC
- CONTAINERS 'OR DISPOSAL. ,
WAffE DISPOSAt MEfMODt { ' WASTE MATERIAL r ei SE IISPOSED OF IN ACCO2 DANCE WITN FEDERAL. St. TE, AND LCCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY COKfA!NERS SNCULD DE RE <TCLED OR DISPOSED OF ikRGUGN AN APPROVED WASTE MANAGEMEhf F AC.!LTY. 4Q f1ECTION VII - HEALTH HAZARD MTA M EfECff 0F C'VEPEVPOSUPLM . e- ntMSTIONs 7 NA M UL DR FATAL 1F SWALLOWED.
- CAUSU EVE !RRITAfl0N.
SKIN CONTACTS MAY CAUSE MODTRATE SKIN IRRITAf!DN. , , gg. INNALAT10N VAPOR AND SPRAY MIST MAY BE NA2MFUL 17 INHALED. REPEATED EXPOSURE TO MICH VAP.R CONCENTRAf10MS MAY ~ * *CAUSE
* " " '1RRITi fl0N OF THE RE3PIRATORY a
CONTINUED CN PAGE 2 _ __ - __ ~
1 e 4 D 4: - PAGE 2 Datt 07 PaEP: 9/11/a6 Cont 1riustion of Manuf acturer's Code 54-30 8
+' SYS7EN AND PERMANENT '8 RAIN .tMD NERVOUS
- SYSTEM CAMAGE.
' !NTENil0NAL MISUSE OY DELIBERATELY CONCENTRATING AND $WHAllNG THE CONTENTS CAM SE NARMFUL OR FATAL.
+ CHRON!C OVEREXPOSURE:
AVQl0 LONG fERM AND REPEATED CONIACT. ffCNt AND fvwPYONS OF OVEREXPOSURE 2 EYE WATERING. NEADACHES, NAUSEA, DIZZINESS, AND LOSS OF COORDINATION ARE INDICATIONS THAT SOLVENT LEVELS ARG ?CO NQN. REDNESS, ifCHING, SURNING SENSAfl0NS AND VISUA'. DISTURBANCES MAY SE INDfCAi!0NS THAT EXCESS;VE EYE CONTAC1 NAS OCCURES.
, ' DRYNESS.1TCHING, CRACKING, SURNING, RLMESS, AND SWELLING ARE CONDITIONS ASSOCIATED Vlfil EXCESSIVE ' KIN CONTACY.
MEDICAL CONDf f f 0NS AGGRAVATED BY er>0 sin, sOf APPt1 CABLE SECHON VIII
- FIRST AID PROCEDURES
-fMGESTf0Nt IF SWALLOWED, DO NOT INDUCE V0Mlf!NG.
* ,,,, q fYE CONTACTr IN CASE OF EYE CONTACT, FLUSN EYES IMMEDIATELY WITN PLENTY OF WATER FOR AT LEAST 1$
MINUTES. ErfN CONTAC7f IN CASE OF SKIN CONTACT, REMOVE PROMPTLY BY WIPING, FOLLOWED SY WATERLESS MAND CLEANER AND SOAP AND WATER. fMMALAff0NT IF AFFECTED BY INHALAfl0N OF VAPOR OR SP#AY MIST, REMOVE TO FRESN AIR. APPL 7 ARilFICIAL RESPIRAfl0N AND 0iMER SUPPORTIVE F;EASURES AS REQUIRED. OfNER! 1F ANY OF THE FOL LOWING OCCUR DURING OR TOLLOWING USE OF THIS PRODUCT, CONTACT A P0150N . CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATEITT HAVE NATERIAL SAFETY CATA SNEET INFORMAlllli AVAILASLE. *lNGEtil0N *EXCES$1VE EXPOSURL TO A CORROSIVE MATERIAL.
- PER$1 STENT SKIN / EYE IRRITAil0N OR BREATHING DIFFICUL 'ES.
SECTION IX - PROTECIION INFORn ATION
@0NAL 900fECTIVE EQUIPMENT FOR!
EVE PRolECTION: WEAR CNEMICAL fYPE SPLASH GOGGLES OR FULL FACE $NIELD. SEIN PROJECTIONS WEAR PROTECTIVE CLOTHING, INCLUDING IMPERMEABLE APRON AND CLOVES CONSTRUCTED OFs f-fg, NITRILE RUBBER, NEOPRENE RUBBLR OR POLTVINYL ALCONQL RESPIRA10RY PROTECTION: OVEREXPOSURE TO VAPOKS MAY BE PREVENTED 8? ENSURING VENTILAfl0N CONTROLS, VAPOR EXNAUST OR FRESH AIR ENTRY. N'OSM/MSHA APPROVED (TC 23C-) PAINT SPRAY OR AIR SUPPLIED (TC 19C-) RESPIRAf0RS MAY ALSO REDUCE ENPOSURE. IN ALL CASEE, REAPS RESPIRATOR MANUFACTURER'S INSTRUC110NS AND LITERATURE CAREFULLY TO DETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WNICH THE RESPIE;.iOR IS EFFECTIVE find NOW If IS TO BE PROPERLY FITTED, OTHER EQUlPMENT:
. CLEAN OR DISCARD CONTAMINATED CLOTHING ANO' SHOES.
VENTfLAf10W REQUl#EMENTSt. PROVIDE GENERAL DILUTION OR LOCAL EXNAUST hlNitLATION IN VOLUME AND PaffERN TO KEEP THE CONCENTRATION OF INGREDIENTS LISTED IN SECTION Il BELOW THE LOWEST SUGGESTED EXPOSURE LIMifS, THE LEL !!! SECTION IV 8ELOW THE STATED tlMIT, AND TO REMOVE DECOMPOSITION PRODUCTS DURING VELDING OR FLAME CUT 1tNG ON SURFACES COATED WITH THIS PR(ElUCT. SECTION X - SPECIAL PRECAUTIONS NANDlfNG AND STCRACg *eECAyT1pNgy,, 00 301 STORE AeovE 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS CESIGNED AND PROTECTED FOR $70 RAGE OF NFPA CLASS Il COMBUSTIBLE LIQUIDS. OTHER **EtAUTIONS IF 1915 MATERIAL IS PART OF A MULilPLE COMPONENT C0AflNG SYSTEM, READ TMF MATERIAL SAFETY DATA SHEEtlS) FOR TPE CTHER COMPONENT OR COMPONCNTS BEFORE BLENDING AS THE RESULilNG MIXfURE MY NAYE THE NAZARDS OF 1LL OF ITS parit. CONTAINERS SHOULD SE GROUNDED WF(N POURING. AVOID FEEE FALL Of LIQUIDS IN EXCESS OF A FEV
=j INCHES.
e ALL CNC.WICAL SUSSTANCES (. ."1f 8 PRODUCT COMPtY WITt ALL APPLICABLE RULES OR ORDERS UNDER f*fE sNVIRON* ENTAL PROTECTION AGENCY'S T0XIC TUBSTANCE CONTROL ACT. TNil MATERIAL SAFETY CATA SHEET PAS SEEN PREPgRED IN ACCORDANCE WITN THE OSHA HAZARD 1 COMMUNICAflDN STANDARD (29_CFR 1910.120C1 U/t a UNKNOWN INFORMAllVN N/A e NOT APPLICA8LE N0f (ST. s NOT ESTABLISHED PPIC 1120 (CUSTOMfR NO.) LOCAT!0N : 0809 86M/308/////911
. _ _ . . _ _ _ . _ _ - - _ -__ . _ = _ _ _ _ _ _ _ _ _ _ _ _ _ _ -
Form E010B I COATING / THINNER DATA FORM _ Company 'Name:h0DYM /V/CilMR ?tJMT TD4/ESfE" Y4LLE1 bnikt. TTY Applicable APCB Certificate #: hMM [MX774/4 /M7~MD b MFh,l Product Name: UlCl< l {hf4AfVl YA ("~t'T 4 Product Manufacturer: ?{N $lbDUSTAlNS TtJC 1 Useae Data Daily (gal / day): O'
- _
Annual (gal /yr): 30/I552-- Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: h [Tfgc4/6D M TI.)[ As Received (Concentrated): Density (1bs/ gal): b. 3 _ Solids % by Weight: 57,I9 % by volume: #53 VOC % by Weight: b bl % by Volume: 6 M,70 Water.% by Weight: O % by Volume: C As Applied (Diluted): g g f 45 A0M Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: Density (Ibs/ gal): Mfr. Data Sheet or Certification is attached. Yes / No
*For NSPS Sources Method 24 must be used.
complete to the This best ofismyto certify that this information kisowledge. , S true is 7 an j/jduf 7(4ttt(t(/ 4t Signature:
Title:
W4t!#/Al f OF /WV/tW/tNOL OEJT"1 ,, 11/03/89 RMP
*/
An9 (MATERIAL SW p COATINGS SAFETY DATAGROUP SHEET
/
AND RESINS SECTION I - PRODUCT INFnnwamTnN MANUFACTURER'S NAME: PPG' INDUSTRIES 71tCe CODE / IDENTITY , 31413M *0526870) PRODUCT SAFETY LOC.: 260<RAPPA-DR1VE. sed *,g TRADE NAME: CUIw vu . uuw=q~sATEDjRg
'PITTSBURGH,' PA 15238 CHEMICAL FAMtEYf AL M ' <
MSDS CONTACT: MANAGER 71NDUSTRIAI'~HYCIENE'"j US DOT: PAINT, COMBUST! LE.L.layp' d 9 ANDJRODUCT SAFETY DATE OF PREPARATION: /28/88 F p.
- 412),963;5tfD CUSTOMER PART f: M""" y{1 ( ' **
EMERGENCY TELEPHONE: (304) 843 1300 SECTION II - INGREDIENTS APPROX. EXPOSURE LIMITS WT. CAS NO. ACGIH TLV OSHA PEL PPQ IPEL 5 13463 67 7 10.00Mg/M3 15.00Mg/M3 10.00Mg/M3 NM Uh!3bDE.# iTMINupti r 5 1335 30-4 10.00Mg/M3 NOT EST. 10.00Mg/M3 CiSotVENP?NAPWTHA! 30 64742 88 7 NOT EST. NOT EST. NOT EST.
. 10 64742-48 9 NOT EST. NOT EST. NOT EST. .
40 PROPRIETARY NOT EST. NOT EST. NOT EST.
..- . 2... _ ADDIT. _.S C RCINOGENIC ACCORDING TO CRITERIA ESTABLISHED BY: * = NTP ** = IARC 3 = OSHA # = OTHER SECTION III 3 PHYSICAL / CHEMICAL CHARACTERISTICS BOILING RANGE : 136 242 DEG.C SOLUBILITY IN WATER: D.0 %
VAPOR PRESSURE: 1.7 mHg
- WT/ GAL (LBS): 8.30 (U.S.)
VAPOR DENSITY : HEAVIER THAN AIR pH: U/I
% VOL/ VOLUME 54.70 % SOLID BY WElGHT: 57.19 EVAP PATE(BuoAc=100): 17 SPECIFIC GRAVITY: 1.00 SECTION IV - FIRE AND EXPLOSION HAZARD DATA -
I kQAI,, CATEGORY:,C USTIBLE LASHPCINIIT12~DEG.FPMCC FLAMMABLE LIMITS: LEL 0.9 UEL U/I EXTINGUISHING MEDIA: USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS B EXTINGU!$HERS (CARBON DIDXIDE. DRY CHEMICAL, OR UNIVERSAL AQUEOUS FILM FORMING T0AM) DESIGNED TO EXTINGUISH NFPA CLASS !! COMBUST!BLE LIQUID FIRES. UNUSUAL YlRE AND EXPLOSION MA7ARDS: _ _ _ . _ g KEE TAINER$t}lGHTLY CLOSED"7190 LATE
- FROW HEAT,'"ELEl TRICAt-"EQUTPMENT75 g if ' CONT A INE R b MAT = EXPLODES WHElen EXPOSEIM10gElQREMEg[EEg4bNQg SURTACESwita;;1C_ GASESJY
- FCAN
~ "WHEN
* *PRODUCT
~ ~ " ~IS ~ CONTACTED ~""
Bf" FLAME OR HOT " SURFACES SPECIAL FIRE FIGHTING PROCEDURES: WATER SPRAY MAT BL INEFFECTIVE. WATER SPRAY MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP AND POSSIBLE AUT0!GNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF VATER IS USED, FOG N0ZZLES ARE PREFERABLE. FIRE FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. ' SECTION V - REACTIVITY DATA STABILITY: STABLE HA7ARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR INCOMPATIBILITY ' MATERIALS AND COADITIONS TO AVotD): AVOID CONTACT WITH STRONG ALKALIES, STR NfMINERAt'ACf0$""TifISTRONG OXIDIZING' AGENTS.
^ * - u'A h HA7ARDOUS DEC0" POSIT 10N PRODUCTS: * . - . - - . . - . -
MAY PRODUC6 HAZAPCOUS DECOMPOSITION PRODUCTS WHEN HEATED. WELDING, BRAZING, OR FLAME CUTTING ON SURFACES COATED WITH THIS PRODUCT MAY PRODUCE FUMES INCLUDING: Carbon Monoxide, SECTION VI - SPILL OR LEAK PROCEDURES JTEPS 70 BE TAKEN IN CASE MATERI AL IS DELEASED OR SPf LLED: TROVIDE MAXIMUM VENilLATION. ONLY PERSONNEC'E00!'PPETUITH7it'0PETRElflRTUFAN!F,51 , f.YE; PROTECT ION *SHOULF BE*PE RMI TTED- I N* THE*AREr.'TREMOVEP Akkp* tit lerF hM- ' eu t e v r- _-
?
KPJLLEIL. MATER 1}LMIN t SAWDUS,T(,, VERMICULITE,,,0ILOTHER ABSORBENT. MATERIAL AND' PLACEllNTGd 3CONTA!NE'RIFDRDILPOSAL. VASTE 01SPOSAL WETH00&- WASTE MATERIAL MVST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL INV!kONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECTCLED 04 DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT FACILTY. 1 SECTION VII - HEALTH HAZARD. DATA i EFFECTS OF OVEREXPOSU#E FROM: INGESTION: '
..FA"T@rdJALLOWED ETE CONTACT: ,.; .. ,.4 _._? T r . P ~ * ~j
. '*W SKINCONTACT:{CAUSESEYE,.!kRITAI!ONN* 'M HAY cat %E MODERATE SKIN IRRITATION.j INHALATION: p. _ _ _ _ 7 ;t ; , - . . . . , ,
' l VAPORf,AND,' SPRAT,M!st MAY BE HARMFUL IF JNHALED. '~'
.I VAPOR *1RRITATES ETES,, NOSE,=ANF THROAT. -
~ ~
CONTINUED ON PAGE 2 l
.I
,e e
p p*
- PAGE 2
'g# f-Continuation of ' Manufacturer's Code - 5 4-311 DATE OF PREP: 1/28/88 i
f
'I
- Pl lRE#EATED EXPOSURE To HICN VAPOR CONCENTRATIONS HAY CAUSE SYSTEM AND PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGEe-- c n..r _ 4 :--( -
f- IRRITATION
+
1NTENT10NAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE NARM
,0R FATALa 3
CHRONIC OVEREXPOSURE: AVOID DONG TERM AND REPEATED CONTACT. . THIS PROD 0CT CONTAINS TATAN!UM DIOXIDE.- ANIMALS.!NHALING MAS $!VE QUANTITIES OF TITAN!UM DIOX:DE DUST IN A LONG TERM STUDY DEVELOPED. LUNG TUMORS.' STUDIES WITH HUMANS INVOLVED IN PJLNUFACTURE OF THIS P!GMEhT INDICATE N0' INCREASED RISK OF CANCER FROM EXPOSURE. POTENTIAL FOR INHALATION CF TITAN!UM DIOXIDE DUSTS FROM COATINGS IS VERY LIMITED. SINCE OVE1 EXPOS".2f 3 ARE NOT EXPECTED, THERE IS No $1GN"FICANT MAZARD FOR MAN.
.$!GNS $ND SYMPTOMS OF CVEPEXPCSU4E:
UE WATERING, HEADACHES, 4AUSEA, DIZZINESS, AND LOSS OF COORDINATION ARE INDICATIONS THAT SOLVENT LEVELS ARE TOO HIGH. REDNESS, ITCHING, BURNING SENSATION AND VISUAL DISTURBANCES MAY INDICATE EXCESSIVE EYE _ CONTACT.
.' 'DRTNESS, ITCHING, CRACKING, BURNING, REDNESS; AND SWELLING'ARE CONDlil0NS ASSOCIATED WITil EXCESSIVE SKIN CUNTACT. ,
HEDICAL CONDITIONS ACCRAVATED BY EXPOSURE: NOT APPLICABLE SECTION VITE - FIRST AID PROCEDURES
~ ' * ' '^
INCESTION: . , ~ -
~-l IF SWALLOWED, 00.ECT !NDUCE VOMITING.l EYF CONTACT: J T m.* R - ._ ...
IQ0',. .ETE fo{Afhf,L{3,X E,Y,E$ ,IMMEDIATELy,1M, P,,1;Q,,,,pFJA Ayg@g SKIN CONTACT: . +. .. ... - - - - - - . . . . . . . . ~ . - - - ._ I.INCASEOF$KINCONTACT,REMOVEPROMPTLYBYWIPING,FO;.0WEDBYWATERLESSHANDCLEANER.AND)
"" ~ ' " ' * " ' " * " * * * - " "
fNHALAff0N: l SOAP *ANDWATER.*
.. ._ . , , . _ . . J
.4.--
TF' FFECTED'BY' INHALATION OF VAPOR OR SPRAY MIST, REMOVE TO FRESH AIR. APPLY ARTIFICIALJ RESPIRATION AND OTHER SUPPORTIVE MEASURES AS REQUIRED.
- - .' w - *M*= '-%
pTHgR; IF ANY OF THE FOLLOWING OCCUR DURING OR FOLLCVING USE OF THIS PRODUCT, CONTACT A POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE MATERIAL SAFETY DATA SHEET INFORMATION AVAILABLE. *lNGESTION
- EXCESSIVE EXPOSURE TO A CORROSIVE MATERIAL.
- PERSISTENT SK!h/ EYE IRRITAfl0N OR BREATHING DIFFICULTIES.
SECTION IX - PROTECTION INFORMATION PERSONAL PROTECT!VE E0VIPMENT FOR I ETE PROTECTIONAL,- --
?*"~~~~--=~.~_,,_,,,,,,,
WEAR CHEMICAL TYPE SPLASH GOGGLES OR FULL FACE SHIELD.' SKIN PROTECTION; . -- w e =- . ... _ _ Gl.0yES, CONSTRUCTED OF WEAR PROTECTjVE '(N!TRILE RUBBER, CLOTHING,. NEOPRENE INCLUDING. RUBBER'ORIMPERMEABLE, POLYVINYC APRON,AND,, ALCOH 0t**'"~'"***g RESPIRATORY PROTECTION: 4 -%~-- - -m .4 R #
, OVEREXPOSURE TO VAPORS.MAY.BE PEEVENTED BY. ENSURING VENTILATION. CONTROLS,.. VAPOR-EX T OR
. FRESH AIR. ENTRY. NIOSH/MSHA APPROVEDr(TC 23C-) PAINT SPRAY OR AIR SUPPLIED (TC 19C-RESPIRATOR $ MAY ALSO' REDUCE'EXPOSI".s. 5 READ RESPIRATOR MANUFACTURER'S INSTRUCTIONS AN LITERATURE CAREFULLY TO DETERMINE 'HE TYPE Of AIRBORNE CONTAMINANTS AGAINST WHICH THE RESPIRATOR IS EFFECTIVE AND HOW IT S TO BE P2OPERLY FITTED.
OTHER EQUIPMENT (- , . . . . _ . .... - - - -. , e CLEAN OR DISCARD CONTAMINATED CLOTH,NG AND SHOES. ' VENTILAff0N REQUIR'EMENTS: -. PROVIDE GENERAL CILUTION OitTOCAL EXHAUST VENTILATION!!N VOLUME AND PATTERN TO KEEP THE. . CONCENTRATION OF INGRIDIENTSiLISTED IN SECTION !! BELOW THE LOWEST SUGGESTED EXPOSURE LIMITS, THE LEL IN SECTION IV BELOW THE STATED LIMIT, AND TO REMOVE DECOMPOSITION PRODUCTS DURING WELDING OR FLAME CUTTING ON SURFACES COATED blTH THIS PRODUCT. SECTION X - SPECIAL PRECAUTIONS HANDLING AND STORACE PRECAUTIONS: . % . - . O NOT STORE ABOVE 120 DEGREES F.~ STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND ROTECTE0*FOR STORAGE'0F*NFPA CLASS Il COMBUSTIBLE LIQUIDS. OTHER PRECAUTIONS: IF THl$ MATERIAL IS PART OF A MULTIPLE CCMPONENT COATING SYSTEM, READ THE MATERIAL SAFETY I DATA SHEET (S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE .N.ENDING AS THE RESULTING M1XTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES. ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH ALL APPLICABLE RULES OR ORDERS UNDER THE' ENVIRONMENTAL PROTECTION AGENCY'S T0XIC SUS $7ANCES CONTROL ACT. THIS MATERIAL SAFETY DATA SHEET NAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)
; U/I a UNKNOWN INFORMAfl0N N/A = NOT APPLICABLE NOT EST. = NOT ESTABLISHED CERT. LTR.m CHEMIC4L 0.K. ON TSCA INVENTORYT CAS WO. NOT AVAILABLE PPlc 5635 (CUSTOMER NO.) LOCATION : 0809 8854/311/////128
l l
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Form E010B COATING / THINNER DATA FORM Company Name:$VoVAd $/CIMR ?LJAT 194/W VALLEY bril'tttT1 Applicab'le'APCB Certificate #: MF D //d /MIM - Product Name: 17$ - PT5 h t)I Cl< I) R 4 V71/M fl blU h/dMIL Produ'ct Manufacturer: MhuS'772/5 MC - Usaae Da.t;A l Daily (gal / day): 36O
- Oh Annual (gal /yr): 80//6 5 7-Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: M [Tfgc4BD M TDf As Received (Concentrated):
Density (lbs/ gal): Of /. Solids % by Weight: 54.M % by volume: 43. / VOC % by Weight: 452 % by vo1ume: FA 90 Water % by Weight: O ,% by Volume: O As Applied (Diluted): , j$ ggyF Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by volume: Thinner Data Chemical Composition: ,A/ Density (lbs/ gal): Mfr. Data Sheet or Certification is attached. Yes / No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true a com e e to the best of my knowledge. '}- j Signature (. '/d L (WI
Title:
$ALMdfL DF LWVitWHNDL CLDUM 11/03/89 RMP
i r . - . .
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.0 %1-/ /$t y_,
gd3y .
.,. A ~f'
~
r MATERIAL SAFETY D.ATA SHEET COATINGS AND RESINS GROUP h kC b C SECTION I - PRODUCT INFORM ATION. MANUFACTURER'S NAME:y e w ..~.. ,d..o4 JPGoINDUSTRIES IliC; CODE / IDENTITY (,100j84E) { PRODUCT SAFETY LOC.: 260 KAPRALO3QE4. -.. . TRADE .NAME: P Df d: g _ tem ex_DRvAuTUMjgsaOW ' ~ ~ ~ ~ j PITTSBURGH, PA 15238 CHEMICAL FAMILY:'itsy0
' MSDS CONTACT: MANAGER *, INDUSTRI AL HYGIENE- 00T CLS: PAINT. COMBUSTIBLE LIOUID m . , .
AND. PRODUCT. SAFETY DATE OF PF.EPARATION: I3/06/86;j ' ~ ~ " j (412)3963 5822j :
- EMERGENCY TELEPHONE: (30,4)J.43;-1300.s SECTION 11 - INGREDIENTS APPROK. t X P o3 yag Lgy g y 3 1HOREo!ENr3 % wr. CAS NO. ACCIN rLV OSNA PEL PPO IPEL 5 1309-3F-1 ts.eeMg/M3 N/A 1$..gMg/M3 TRON OX10E (S.SOMg/M3
$ NOT,E3r. 10.00Mg/M3 N/A 1AON CAIDE N/A N/A 1333-30*4 N/A ALUM 1NUM stL! cart 5 N/A N/A ODORLESS MINERAL SPIR!rs 15 0932-32-4 N/A (1 148-J2-7 N/A N/A N/A PROPYLENE CmRSONAf(
M(rHvL ErNyt MEr0XIME <t 18-29-7 N/A N/A N/A AvLENE <t 1336-29-r t;*.99 PPM 199.99 PPM 199.8SPPM 30 8032-32-4 N / .' N/A N/A MINERAL SPIR!rs* RULE $4 , t..-4,-4 ......,PM i..... PPM i.....P,M l eruvL seNzeNe Nor PitM ro=McRs. REsrNs. ANo Aoortives 4e PRoPRrerARv Not est. Not est. r. / SECTION 111 - PHYSICAL / CHEMICAL CHARACTERISTICS BOILING RANGE : 100 - 242 DEG.C SOLUBILITY IN WATER: 0.2 %
- VAPOR PRESSURE: 1.8 mmHg WT/ GAL (LBS): 8.19 VAPOR DENSITY : HEAVIER THAN AIR pH: N/A
( % VOL/ VOLUME : 56.90 % SOLID BY WEIGHT: 54.8 EVAP RATE (Bu0AC=100): 12 SECTION IV - FIRE AND EXPLOSION HAZARD DATA DOT CATEGORY 1._0,0t1Q5TIBLE FLAMMABLE LIMITS: LEL ._0;9, , q:1 UEL N/A FLASHPOINT:y10DEGGFPMCC EXTINGUISHING MEDIA: USE NATIONAL FIRE PROT ECTION ASSOCIATION (NFPAl CLASS B EXTINGUISHERS (CARBCN D10XIDE. DRY CHEMICAL OR UNIVERS AL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA CLASS ll COMBUSTIBLE LiCUID FIRES.
- UNUSUAL FIRE AND EXPLOSI,0]LilAZA.RD,5.:. _ _ . . . . _ _ ' . _ .,_ _ _ .
KEEP,.CONTAINERiTLM ,M MEMT, S P A% $ CONTACTED.ELECTRfCAl EIQ1EMTAfW9tE EQUtP317dhtgARKS.ANDAPffy, fLAMESJCLOSEDCONTA] 8tFEAMOM5$RlI,cw__U tu-SURFACES.MOXIC GA5ES ohm. _ fBODUC.. SPECIAL' FIRE" FIGHTING PROCEDURES:
- '- WATER SPRAY M AY BE INEFFECTIVE. WATER SPRAY MAY BE USED TO COOL CLOSED COMTAINERS TO
~ A PREVENT PRESSURE BUILD.UP AND POSSIBLE AUTOlGNITION OR f.XPLOSION WHEN EXPOSED TO EXTREME HEAT. IF W ATER IS USED. FOG NOZZLES ARE PREF ERABLE. FIRE. FIGHTERS SHOULD WEAR SELF
- CONTAINED BREATHING APPARATUS.
SECTION V - REACTIVITY DATA
- STABli#d : STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR INCOMP ATIBILITY (MATERI ALS AND. CONDITIONS TO AVOID )a---...-. m.--_..-., %
AVOID CONTACTWITH STRONG ALKAttES. STRONG MINERAL ACIDS. OR STRONG OXIDtZING AGENTS. ~ ~ " " "c *.a HAZARDOUS DECOMPOSITION. PRODUCTS:.1.~.".Zl,7..,....... ,' ' 4 i M AY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS WHEN HEATED.' WELDING. BRAZING. OR FLAME-CUTTING ON SURF ACES COATED WITH THIS PRODUCT M AY PRODUCE FUMES INCLUDING: - { Cart >on Monoxide. l Continued on Back of Page l
~
i .
- ~ * , , .
\ .,, , [ Continuation of Manufacturer's Code 321 DATE OF PREP: 3/06/86 : 7 I i SECTIOA VI - SPILL OR LEAK PROCEDURES l( STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
' PROVICE max 1 MUM VENT'lLATION."ONLY PERSONNEL EQUIPPEDWITH PROPER RESPIRATORY AND SKIN ANO j
I EYE PROTECTION SPILLED M ATERI SHOULD AL WITH BE PERuiTTED SAWOU.ST. IN THE AREA.i REMOVE ALL SOURCES VERMICULITE. OR OTHER OFplGNITION.T.TAKE.UPM. ABSORBENT M ATsR l
~ ~ ' ' ' ' ' " ;
3 CONTAINERS FOR OfSPOSAL. ' , I WASTE DISPOSAL METHOD: . WASTE M ATERI AL MU6,T BE DISPOSED OF IN ACCORDANCE WITH FEEERAL, STATE. AND LCCAL
- l ENVIRCNMEN~AL CCUTROL REGULATIONS. EMPTY CONTAINERS SFOULD BE RECYCLED OR DISPOSED OF
~
.HROUGH AN APPROVED WASTE MANACEMENT FACILTY. g SECTION Vil - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE FP.0M:
INGESTION: . .. HARMFUL OR FATAL IF SWALLOWED. DRIED FILM OF THIS PAINT MAY BE HARMFUL IF EATEN OR CHEWED. ' EYE CONTACT: ._. g CAUSES EYE IRRITATION. g SKIN CONTACT: . MAY CAUSE MODERATE SKIN IRRITATION. MAY BE ABSORBED THROUGH THE SKIN. - .. . PROLONGED OR REPEATED CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION. , f INHALATION: . . _ _ _ . , 4 VAPOR AND SPRAY MIST M AY BE HARMFUL IF INHALED. . MAY CAUSE LUNG IRRITATION AND ALLERGIC RESPIRATORY,RFACTION).. ... . , . , .. . , , _ - REPEATED EXPOSURE TO HIGH VAPOR CONCENTRATIONS M AY CAUSE IRRIT TION OF THE RESPIRATORY: l, . f-. -
.SYSTEM AND PERMANENT BAAIN AND NERVOUS SYSTEM DANAGEtMM ^
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING E CONTENTS CAN B
" " ' ' " " * ' * ' " ~
ANOINHALINGTA. #@W3 OR FATAL. REPEATED EXPOSURE: g AVO10 LCNG-TERM AND REPEATED CONTACT. SIGNS AND SYMPTONS OF OVEREXPOSURE:
" EYE 9/ATER'NG. HEADACHES. NAUSEA. OlZZINESS. AND LOSS OFO COORDINATION ARE I o SOLVENT LEVELS ARE TOO HIGH. 0 6"m'**~" N - ' ~ r e ' ^ t. .as or r w.a*ti REDNESS. lTCHING. BURNING SENSATIONS ANO VISUAL olSTURBANCES MAY BE INDICATIONS THAT ,' f EXCESSIVE EYE CCNTACT HAS OCCURED. ,' .. . . . . . . . - . . .. ...,.3..c, ;
. DRYNESS. ITCHING? CRACK!NG',' BURNING. REDNESS. ANO SWELLING ARE CONDITIONS ASSOCIATED WITH EXCESSIVE SKIN CONTACT."
HEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NOT APPLICABLE r SECTION Vill - FIRST AlD PROCEDURES INGESTION:
. IF SWALLOWED. DO NOT INDUCE VOMITING.)
EYE CGNTACT: .
. . . . , r .
.r., e. , . , % .
,, , , IN CASE OF EYE '- CONTACT," FLUSH EYE"S IMMEDIATELYyllTH PLENTY OF. WATER FOWAJ' LEA T'R
r e '"-
MINUTES.
~
" ~
* ~Fr SKIN CONTACT:
. YA A DWATE , ',l e* . ' INHALATION: , ~
l IF AFFECTEQB4INHAIATION OFhAPOR,OR SPjlAY,MI'$Y,,eR5MOVFkTO'F)dH' lR.9'APPE 'ARTIElbk
* 'RESPIRAYlON AN6 OTHER SUPPORTIVE MEASURES AS HEOulRED. ' - !
~ '
IF ANY OF THE FOLLOWING OCCUR DURING OR FOLLOWING USE OF THIS PRODUCT. botiT CT1 NI55 bontinuedonPage2 8
}
i Ll ( , i. I
-_ -- h
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; PAGE 2 ,
Continuation of Manufacturer's Code .54-321- DATE OF PREP: 3/06/8'S
" CONTROL CENTER. EMERGENCY RO7M OR PHYSICIAN IMMEDI ATELY: HAVE MATERt AL $ AFETY DATA SHEET C INFORMATION AVAILABLE. *tNGEST10M.
- EXCESSIVE EXPOSURE TO A CORROS!VE M ATERIAL.
- PERStSTENT SKINIEYE IRRITATION OR BREATHING DIFFICULTIES. '
SECTION IX - PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPMENT FOR:
' EYE PROTECTION: , .
WEAR CHEMICAL. TYPE SPLASH GOGGLES OR FULL FACE SHIELD. SKIN PROTECTION: WEAR PROTECTIVE CLOTHING. INCLUDING IMPERMEABLE APRON AND GLOVES CONSTRUCTED OF: .' 3 NITRILE RUBBER.NEOPitENE RUBBEA OR POLYVINYL ALCOHOL RESPIRATORY PROTECTION: OVEREXPOSURE TO VAPORS M AY BE PREVENTED BY ENSURING VErmLATION CCNTROLS. VAPCR EXHAUST OR FRESH AIR ENTRY. NIOSH/MSHA APPROVED (TC-23C-) PAINT SPRAY OR AIR SUPPLIED (TC-190-1 RESPIRATORS MAY ALSO REDUCE EXPOSURE. IN ALL CASES. READ RESPIRATOR MANUFACTURER'S INSTRUCTIONS AND LITERATURE CAREFULLY TO DETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AG AINST WHICH THE RESPIRATOR IS EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED. OTHER EQUIPMENT:
. CLEAN OR DISCARO CONTAMINATED CLOTHING AND SHOES.
VENTILATION REQUIREMENTS: ., PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP THE CCNCENTR ATION OF INGREDIENTS LISTED IN SECTION 11 BELOW THE LOWEST SUGGESTED EXPCSURE LIMITS. THE LEL IN SECTION IV BELOW THE STATED LIMIT. AND TO REMOVE DECOMPOSITION PRODUCTS DURING WELDNG OR FLAME CUTTING ON SURF ACES COATED WITH THIS PRODUCT. SECTION X - SPECIAL PRECAUTIONS HANDLING AND STORAGE PRECAUTIONS: . . . . . . . . . . , . . . DO h JT STORE ABOVE,t2O DEGREES F, STORE LARGE OUANTITIES IN* BUILDINGS DESIGNED ' PROTECTED FOR STORAGE OF NFPA CLASS 11 COMBUSTIBLE LIOUtDS. / ( OTHER PRECAUTIONS: IF THIS M ATERI AL IS PART OF A MULTIPLE COMPONENT CCATING SYSTEM. READ THE M ATERIAL S AFETY DATA SHEET (S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS THE RESULTING
- MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS.
CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE F ALL OF LIOUIDS IN EXCESS OF A FEW INCHES. ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH ALL APPLICABLE RULES CR ORDERS UNDER THE ENVIRONMENTAL PROTECTION AGENCY'S TOXIC SUBSTANCE CONTROL ACT. THis M ATERI AL S AFETY OATA SHEET HAS BEEN PAEPARED IN ACCCRDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)
~.
i
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e ( .
-- i
4 Form E010B COATING / THINNER DATA FORM Company Name: Y UDYA4 $/CtBIR ?tJMT' 194/M6EN" YALLEy bstilkfdTY Applicable APCB Certificate.#: hM8T~ M 8/AT/4/( A/MTSD Product Name: h(llCl4 by h44i$LS Product Manufacturer: PN ridovsvieres Jrs c._ Usaae Data Daily (gal / day): L /2[ad ~~ O-(M O Annual (gal /yr): 30 /I E 2. - Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: h [Tfgdd!DMSD[_ As Received (Concentrated): Density (lbs/ gal): Solids % by Weight: 56 % by Volume: IO VOC % by' Weight: b % by Volume: [O Water % by Weight: O % by Volume: O As Applied (Diluted): 9c AJ d COVE Density (lbs/ gal): ,_ % by Volume: Solids % by Weight: ,_ % by Volume: f VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data chemical Composition: A/A Density (lbs/ gal): Mfr. Data Sheet or Certification is attached. Yes / No (
*For NSPS Sources Method 24 must be used.
This is to certify that this information is tru a . omp t to the best of my knowledge. j Signature: '
> f MM Tit 1e: ph11#/K # ENV/&//INDL_dML(lq 11/03/89 RMP
h
MATERIAL SAFETY DATA SHEET
,W COATINGS AND RESINS GROUP
+ _
l SECTION I - PRODUCT INFORMATION "4 MANUFACTURER'S NAME: PPG INDUSTRIES INC. CODE /I'DENTITY : 54-B u' TRADE NAME: CUICK DRY ENAMELS p,g, 94,p,g p g 1 PRODUCT SAFETY LOC. 260 KAPPA DRIVE PITTSBURGH, PA 15238 CHEMICAL FAMILY: ALKYD H M H.31t H-!!c H-13K MSDS CONTACT: MANAGER, INDUSTRIAL HYGIENE US DOT: PAINT, COMBUSilBLE LIQUID H 200C H+313 H-!!0C H 200 AND PRODUCT SAFETY DATE OF PREPARATION: 11/09/87 H-101 H 321 H lTOC
' (412) 963 5822 CUSTOMER PART #: p.3,, .e 132 H !T4C
' EMERGENCY TELEPHC(JE: (304) 843 1300 SECTION II -
INGREDIENTS MAXIMUM E.X P 0 $ U R E L IMi iS ACGlH TLV OSHA PEL PSC 'IPEL
%WT. CASNO.l
( 15 51274 00 1 5.00Mg/M3 NOT EST. 5.00Mg/M3 IRON OXfDE NOT EST. NOT EST. 10 NOT EST NOT EST. I PIGMENTS 0.00 tag /M3 30 13463 67 7 , 10.00Mg/M3 15.00Mg/M3
- firANIUM DIOX10E # ! 10.00Mg/M3 NOT EST. U.00Mg/M3 ALUMINUM SILICATE 10 1335 30 4 50 6(.742 88 7 NOT EST. Not EST. > Noi EST. ,
MEDIUM AllPHATIC SotNINT NAPHIHA 100.00 PPM *!3.00 PPM a
- XYLENE .
1 1330 20 7 100.00 PPM 100.00 PPM
- 3.00PpH ETHYL BENZENE 1 100 41 4 100.00PFM ,
40 PROPRIETARY NOT EST. NOT ES.T. NOT EST.
, FILM FORMERS, RESIE3, AND ADDITIVES g
' l l
' * = NTP "
- TARC Q = OSHA
- s OTHER C, CARCINOGENIC SECTION ACCORDINGIII - TO CRITERIA ESTABLISHED %
BY: PHYSICAL / CHEMICAL C l[0ILINGRANCE: 136 '242 DEC.C SOLUGILITY IN WATER: <1 VAPOR PRESSURE: <3 mHf WT/ GAL (LBS): 8 10 (U.S.) SON VAPOR DENSITY : HEAVIER THAN AIR , pH: U/1
/ % SOLID BY WEIGHT: 46-63
% VOLfVOLUME : 48 72 (VAP RATE (BUCAes100): 420 SPECIFIC GRAVITY: 1.0
- 1.2 $(616: M SECTION IV - FIRE AND EXPLOSION HAZARD DATA US DOT CATEGORY: COMBUST!BLE FLASHP0lNT: 102 DEG. F PMCC FLAMMABLE LIMITS. LEL 0.9 UEL U/1 EXTINGUISHING MEDIAt USE NATIONAL FIRE PROTECTION ASSOCI AT10N (NFPA) CLASS B EXTINGUISHERS (CAR $0N D10X1DE, DRY CHEMjCAL, OR UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA CLASS 11 COMBUSTIBLE L10UlD FIRES.
U f5UAL FIRE AND ExPLOS10N untsRDS: ISCLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND OPEN KEEP CONTAINERS TIGHTLY CLOSED. FLAMES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NCT ANPLY ON HOT SURFACES. T0XIC CASES MAY FORM VHEN PRODUCT IS CONTACTED BY FLAME OR HOT S'.RFACES. ; SPECIAL FIRE FIGHilNG PROCEDURES: WAIER SPRAY MAY BE INEFFECTIVE. WATER SPR AY MAY BE USED TO COOL CLOSED COATAINERS TO - PREVENT PRESSURE BUILD UP AND POSSIBLE AUT0!GNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NO22LES ARE PREFERABLE. FIRE FIGHTERS SHOULD WEAR SELF ;
~
CONTAINED BREATHING APPARATUS. SECTION V - REACTIVITY DATA STABftlTY: STABLE HAZARDOUS POLYMERIZAft0N: NOT EXPECTED to OCCUR INCOMPAff81LITY (NATERI ALS AND CONDIT10NS TO AVotD) AVO!D CONI ACT WITH STRONG ALKAllES,. STRONG MINERAL ACIDS, oil , STRONG OXIDIZING AGENTS. HA{ARDOUS DECOMPOSITION PRODUCTS: MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS WHEN HEATED. WELDING, BRAZING, OR FLAME CUTTING ON SURFACES CCATED WITH THIS PRODUCT MAY PRODUCE FUMES,1NCLUDING: Carbon Monoxide, SECTION VI - SPILL OR LEAK PROCEDURES . I STEDS TO BE TAKEN IN CASE MAT'ERI AL IS RELE ASEC OR SPitLEDs PROVIDE MAXIMUM VENilLATION. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRAICRY AND SKIN AND EYE PROTECTION SHOULD BE PERMITTED IN THE AREA. RE' HOVE ALL SOURCES OF IGNITION. TAKE UP SPILLED MATERIAL WITH SAWDU17, VERMICULITE, OR OTHEa ABSORBENT MATERIAL AkD, PLACE INTO' CCNTAINERS FOR DISPOSAL. WA$ff DISPOSAL METHODt_ WASTE MATERI AL MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULAfl0NS. EMPTY CONTAINERS SHOULD EE RECYCLED GR DISPOSED OF , THROUGH AN t.PPROVED WASTE MANAGEMF.NT FACILfY. - i SECTION VII - HEALTH HAZARD DATA M CTSTOF OVEREXPOSt>RE FROMt (NGESil0N: ( HARMFUL OR FAIAL IF SWALLOWED. IN. PLANT HAZARD RAYING EYE CONTACT: HEALTH 2 CAUSES EYE IRRITATION. FL AMMAS :L I TY :
/
SKIN Cf)NTACT: R O f% "AT CAUSE MODERATE SK]N IRRITAT10N. p INHALATION: EOUIPmfMT CONilkUED CN PAGt 2 4 5 1
[ , ' K .. ,, , y p' ' f., . g .PAGE 2 :9 f'
'4 stTou t en ofWriefprursr's Code
- 5 4-B 'DATE OF PREP 11/09/87. $l[*. $$h I 4 * '9 j .
) VAPOR AND SPRAT. MIST MAY BE HARMFUL IF. INHALED.
VAPOR 1RR!TATES EYES, NOSE,'AND THROAT. .,
' i /.
1L c.-c :
- REPEATED EXPOSURE 70 MIGN VAPOR CONCENTRATIONS MAY CAUSE IRRITATION OF THE RESPIRATORY
' SYSTEM AND PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
(. INTENil0NAL MISUSE BY DELIBERATELY; CONCENTRATING' AND INHALING THE CONTENTS CAN BE HARMFUL' L -' LOR FATAL. l CHRONIC OVEREXPOSURE: AVO!D LONG TERM AND REPEATED CONTACT. THis PRODUCT CONTAINS TITANjuM 010XfDE. ANIMALS INHALING MASSIVE QUANTITIES OF. TITANIUM. OldlDE OUST IN A 'LONG TERM TUDY DEVELOPED LUNG TUMORS. - STUDIES WITH HUMANS INVOLVED IN
. - MANUFACTURE OF THl5 PIGMENT : WDICATE NO INCREASED RISK OF CANCER ROM EXPOSURE. POTENil AL -
FOR INHAt.AT!ON OF T; TAN!UM DIDXIDE DUSTS FROMI COATINGS IS VERY LlHITED..AND CVEREXPOSURES ? ' '
- AREs NOT llXPECTED.
SfGNS AND SYMPTOMS OF OVEREXPOSURE: . ETE WATERING, HEADACHES, NAUSEA, Dl2ZINESS, AND LOSS OF COORDINATION ARE tlNDICAfl0NS THAT SOLVENT LEVELS ARE TOO HIGH. j REDNESS, ITCHINQ, BURNING SENSATION ANO VISUAL DISTURBANCES MAY ,1N01CATE EXCESSIVE EYE
- CONT,ACT.
L I DRYNESS, ITCHING,' CRACKING, BURNING,. REDNESS, AND SWELLING *ARE CONDPTIONS ASSOC!ATED WITH. EXCES$1VE SKlH CONTACT.
- MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE; NOT APPLICABLE i SECTION VIII -
FIRST AID PROCEDURES
- I l q
.INCESTf0Nt ,
r . IF SWALLOWED, DO NOT INDUCE VOMITING. EVE CONTACT:
!N CASE OF EYE CONTACT, FLUSN EYES :MMEDIATELY WITH PLENTY OF VATER FOR AT LEAST 15
.l: *
$ KIN CONTACT:
IN CASE OF SKIN CONTACT, REMOVE PROMPTLY 87 WIP!NG, .FDLLOWED BY WATERI.ESS HAND CLE ANER AND . SOAP AND WATER.
.lNNALATTONt
- IF AFFECTED BY INHALAfl0N OF VAPOR OR SPRAY HIST, REMOVE 10 FRESH A!R. APPLY ARTIFICIAL
, RESPIRAfl0N AND OTHER.SUPPORilvE MEASURES AS REQUIRED.
{ OTHER! 4 IF ANY OF THE FOLLOWTNG OCCUR DURING OR FOLloWING USE OF THIS PRODUCT, CONTACT A PolSON CONTROL CENTER, EMERGENCY RCOM OR PHYSICI AN IMMEDI ATELY; HAVE MATERI AL SAFETY DATA SHEET
. INFORMATION AVAILABLE. *lNCESTION
- EXCESSIVE EXPOSURE 70 A CORROSIVC MATERIAL. ['
- PER$1 STENT SKIN / EYE IRRITATION OR BREATHING DIFFICULTIES.
SECTION IX - PROTECTION INFORMATION PERSONAL PROTECTIVE E00fpMENT FOR; EYE PROTECTION! . WEAR CHEMICAL TYPE SPLASH COGGLES OR FULL FACE SHIELD.
- SKIN PROTECTION: . .
WEAR PROTECTIVE CLOTHING, INCLUDING !MPERMEABLE APRON AND GLOVES CONSTRUCTED OF: NITRILE RUBBER NEOPRENE RUBBER OR POLYVINYL ALCOHOL RESPIRATORY PROTECTION: OVEREXPO URE 10 VAPORS MAY BE PREVENTED BY ENSURING VENilLAfl0N CONTROLS, VAPOR EXHAUST OR FRESH AIR ENTRY. NIOSH/MShA* APPROVED (TC 23C ) PAINT SPRAY OR AIR SUPPLIED (TC 19C') RESPIRATORS MAY ALSO REDUCE EXPOSURE. READ RESPIRATOR MANUFACTURER'S INSTRUCTIONS AWQ
, LITERATURE CAREFULLY TO DETERMINE THE TYPE OF' AIRBORNE CONTAMINANTS AGAINST UNICH THE RESPIRATOR IS EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED. !
OTHER EQUIPMENT: , s . CLEAN OR DISCARO CONTAMINATED CLOTHING AND SHOES. . VENilLATION REQUIREMENT A PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP THE CONCENTRATION OF INGREDIENTS LISTED IN SECT 10N !! BELOW THE LOVEST SUGGESTED EXPOSURE . LIMITS, THE LEL IN SECTION IV BELOW THE STATED LIMIT, AND TO REMOVE DECOMP 051110N PRODUCTS
' DURING WELBING OR FLAME CUTTING ON SURFACES COATED WITh THis PRODUCT.
+
SECTION,X - SPECIAL PRECAUTIONS
- u HANDtlNG AND STORAGE PRECAUTIONS!
DO NOT STORE ABOVE 120 DEGREES F. STORE LARG( OUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS 11 COMBUS]1BLE LIQUIDS. I OTHER PRECAUTIONS: . 1 IF TH15 MATERIAL IS PART OF A HULTIPLE COMPONENT COATING SYSTEM, READ THE MATERI AL SAFETY DATA SHEET (S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORil BLENDING AS THE RESULT!NG' MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS. , 8 CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVotD FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES. r
. ALL CHEMICAL SUBSTANCES IN THl$ PRODUCT COMPLY WITH ALL APPLICABLE RULES OR ORDERS UNDER
[ THE ENVIRONMENTAL PROTECTION AGENCY'S T0XIC SUBSTANCES CONTROL ACT. .! I' THIS MATERI AL SAFETY DATA SHEET MAS BEEN PREPARED IN ACCORDANCE WITH THE OSNA HAZARD COMMUNICAfl0N STANDARD (29 CFR 1910.1200) U/1 a UNKNOWN INFORMATION N/A = NOT APPLICABLE NOT EST = NOT ESTABLISHED 4 (CUSTOMER No.) LOCAfl0N 8754/8//////1109 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ . _ . _ _ _ _ _ _ _ __ . . . Y
Form E010B ) COATING /TIIINNER DATA FORM Company Name:_ UDVA// $ /CitA R flJ/1' 194/W Y4ttsy }ynkgiry Applicable'APCB Certificate #: h4/5T /$l#77//6 /MTMk Product Name: IW GPE4t/ EN/JAEL Product Manufacturer: b, IfdDSTM il'3 hbd C Usaae Data' Daily'(gal / day): 2 /2 h 6 ~-- d 0 0 8 Annual (gal /yr) : 3 /6 Z-Rulo 25.43 & 25.44 Analysis or Manufacturers Ce..;ification Data *: M [TffcdtDMSDf As Received (Concentrated): Density (lbs/ gal): 136 Solids % by Weight: D % by Volume: /7 VOC.%~by Weight: 7b % by Volume: b3 O % by volume: O Water % by Weight: As Applied (Diluted): g y\p y Agf Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data chemical Composition: Density (lbs/ gal): Mfr. Data Sheet or Certification is attached. Yes / No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true ar com e to the
/
best of my knowledge. Signature-[1{' A3.f 2 4 WNd Tit 1e: piAllMfL DF 87NIttMINDL_DALIG 11/03/89 RMP t- - _ _ _ _ _ _ _ _ _ _ - _
. MX i CninL Cn:'C i i un i n OnCC i /(p %
o a. J FORC0ATINGSi,RESINSANDRELATEDMATERIALS NPCA.1-72 Date of PREP: 09/28/82 (Similar to Form OSHA-20) S'dCTION 1 ' H 2 C-16 46
~
~
Manufacturer's Name: PPG Industries, Inc. Coatings & Resins Group
~-Address: <- 260 Kappa Drive Pittsburgh, Pa 15238 Attn: Manager, Industrial Hygiene and Product Safety
{.. . Emergency -Telephone : (304) 843-1300 Product Class: AEROSOL SPRAY PAINT Manufacturer Code: 55-305 ( ) Trade Name: IVY GREEN ENAMEL SECTION 11 - HAZARDOUS INGREDIENTS
% W7. *f LYl lS44 ) ** PPG IPEL CASNO LEL V.P.
INGREDIENTS , 3$ F59.90 PPu , 67-84-1 2.6 136.3 2-PROPANONE .NE N.E. 2.2 Sg 25 . HYGROCARDON PROPfLLANf3 to 9009.00 Pru . . 64-17-5 3.3 de ETMvt ALCOHOL $ $8.89 PPM 123-42-2 1.4 9.3 4-Hv Dm o s y-4-ut f My L PEN T ANONE . 1330-29-7 9.9 S.3
~ < 5 100.00 PPu .
svLENE 499.pf PPu 441-78-6 2.$ fg (TMyt AC(TATE < $ .
< s see.se **u . Fa-o3-3 9.s ri.2 -
2-surANoNE c""*"'"*""'**'"**""
"9.". M,',*, ,. ),"',','fg7,13T4"*' '" C*"'*" '
SECTION 111 - PHYSICAL DATA Boiling Range: 56-164 DEG.C. Vapor Density - HEAVIER THAN AIR Evaporation Rate = SLOWER THAN ETHER s Volatile /Vol: . 83 Wt/ Gal: 7.35 SECTION IV - FIRE AND EXPLOSION HAZARD DATA 00T Category: EXTREMELY FLAMMABLE F.lashpoint: -156 DEG.F. TOC LEL: 1.8 REC 8VED SCN Extinguishing Media: ,g[ y MO USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CL ASS B EXTINGUISHERS (C ARBON DIOxlDE. DRY CHEMIC AL OR FO AM) DE SIGNED TO EXTINGUISH NF PA CLASS lA F LAMM ABLE LfQUID FIRES. Unusual Fire & Explosion Hazards: AEROSOL CONTAINERS HOLDING EXTREuELY FLAMM ABLE GAS AfD FLAMMABLE LIQUID. CONTENTS UFOER PRESSURE. CONTAINERS SHOULD BE ISOLATED FROu HEAT. SPARKS. AtO OPEN FL AME. CLOSED CONT AINERS M AY EXPLODE WHEN EXPOSED TO EXTREME HE AT. DO NOT APPLY TO HOT SURF ACES. Special Fire Fighting Procedures:WATE R SPR AY M AY BE INEFF ECTIVE. W ATER M AY BE USED TO ' COO CONT AINERS TO PREVENT PRESSURE BUILD-UP AND POSStBLE AUTOlGNITION OA EXPLOSION WHEN EXPOSED TO EXTREME HE AT. lF WATER IS USED. FOG NOZZLES ARE PREFERABLE. SECTION V - HEALTH HAZARD DATA 7hr e.s cid Limit Value: SEE SEC. 11 Effects of t erexposure: INHAL ATION: ANESTHETIC. IRRITATION OF THE RESPIRATORY TRACT OR ACUTE NERVOU$ Sv5 TEM DEPRESSION CHAR ACTERIZED BY THE FOLLOWING PROGRESSIVE STEPS: ME ADACHE. OlZZINE SS. ST AGGERING G AIT. CONrUSION. UPOONSC10VSNE SS. OR COM A. SKIN OR EYE CCNT ACT: PRIMARY lRRiT ATION. REPE ATED OVE AE XPOSUAE TO SOLVENT VAPORS M AY C AUSE PERM ANEMT B A AIN APO NE RVOUS SYSTEu D AM AGE. INTENTION AL MISUSE BY DELIBERATELY CONCENTR ATING APO INHAllNG THE CONT ENTS C AN BE HARMFUL OR F ATAL. EYE WATERING. HE ADACHES. NAUSE A. DIZZINESS.
. A'O LOSS OF CCORDINATO! ARE IPOICATOJS THAT SOLVENT LEVELS ARE TOO HIGH. ,
Emergency and First Aid Procedures: l - l Continued on Back of Page 1(
VAgo j - ,
- p. .., .
Date of Frep: 09/28/82* L,.;,. C'ontinuatiton of: Manuf acturer's code 305!
~
.. H. A C-J 6%
TOWARO HE AT, . '.RKS OR OPEN FLAME. LE AKING CC)(TAINER$ WILL PERMIT T>E ACCUMULATION OF AN EXPLOS i f. ' CONCEMTRATON OF VAPORS. '/ ' INCOMP ATIBILITY: Av00 CONT ACT WITH STRONG OKOZING AGENTS. 4 e
' e 1
e e e g t
@ d e
EP i . g 6 hi_.__'._______ _ . . . _ . . ._ _ 4 ,
Form E010B COATING / THINNER DATA FORM . Company Name: YUDYM N/CtBIR ' IJAIT iMW Y4l.LE1AvilkttW Applicable APCB certificate #: hMST M 8/#T/A/( b/MTSY Product Name: b/jlA- bA44 EL
. Product Manufacturer: W6 ' N D$TilIFS E R Usaae Data ,1 Daily (gal / day): 700 = O.OOb Annual (gal /yr) : N!I b L 2- i Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: h [ 7gcMLD M 6D[ f
]
As Received (Concentrated): Density (lbs/ gal): Solids % by Weight: b % by Volume: /5.5 VOC~% by Weight: bb % by Volume: bY,5 Water % by Weight: % by Volume: . As Applied (Diluted): SW AS ,dEcrM Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: _ Thinner Data Chemical Composition: p/A Density (lbs/ gal): , Mfr. Data Sheet or certification is attached. Yes / No i *For NSPS Sources Method 24 must be used. l l This is to certify that this information is true an comp te to the ! best of my knowledge. Signature: _b ht'A -
Title:
$ALMCfK DF BNIdil9GL O.AUT1 11/03/89 RMP 1 \
H & C - 6 0'J . 4 . i .<... .. ... . 000601 N 64 FOR C0ATING5.Rt51R5 AND RELATED MATERIALS 4 RPCA142' -
~
. t ,
Date of PREF: 07/20/83
'f- ,.--
SeCTicm ,,
- ~
.(5imilar
~ v- to--Fern .
05HA RG Industries, Inc. Coat ings & Resins GrovP . ;
- Mt NF ~~
Manufacturer's Name: 260 Kappa Drive Pittsburgh, Pa 15238 . M . r'
** 7, ,
- - Address: Atta: Manager. Industrial Hygiene and Product safety -
Emergency Telephone: (304)843-1300 Product Class: AIAAMky*1f 7AINT y 11 manufacturer Code: .65-310 ( ) Trade Name: WW W W DRMll
- r. . .
SECTION 11 - HAZARDOUS INGREDIENTS
,f_ . m. .nYi in. i a,.. i,n u . .. in ....
s.....n.T. ..
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...... ,~ . ...., .
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UP AW OSS18LE AUTOtG
^
OR EXPLOSON WEN EXPOSED TO EXTREME R AT. lF W ATER IS USED NOZZLES ARE PREFERABLE. MAY 27 M SECTION V - HEALTH HAZARD DATA Threshold Limit Value: SEE SEC. 11 ,,. , Effects of Overexposure: DJHALATON: AESIMTIC. lRRITATION OF THE RESPIRATORY TRACT OR
*
- ACUTE WRvDLis SYSTEM DEPRE SSION CHAR ACTERIZED BY THE FOLLO PROGRESSIVE STEPS: E ADACE.DZZINESS. ST AOGERING GAIT.
CCNFUSCN, UNCONSC80USNESS. OR COM A. SkW OR EYE CONT ACT: PRiu ARY IRRrf Ate 0N. RE PE ATED OVERE XPOSURE TO SOLVENT V APORS M AY CAUSE PERM BRAIN AW NERVOUS SYSTEM DauAGE. NTENTCNAL utSUSE BY DELf8E RATELY CONCENTRATING A@ p*4AlfNG TE CONTENTS CAN SE
- HARurUL 04 F AT AL. EYE W ATE RlW. E ADACHES. NAUSE A, DZZINESS.
i ' Am LOSS Or COORDWATON ARE DOCATIONS THAT SOLVENT LEVFLS ARE TOO HGH. Erergency and First Aid Procedures:FUuES: RiuoVE FROM EXPOSURE. RESTORE BRE ATHrNG. K QUIET. NOTIFY A PHYSCIAN. SPLASH (EWSI: FLUSH auuEDATELYWITH COPtous ouANT TsE$ Or RUNNtWGWATER FOR AT LE AST 15 uNUTES.TA
-a* TO A PHYSICIANFORDEFNT vE utDCAt TRE ATutNT 5 PLASH (SKIN):
l WASH AF F ECTED ARE A$ WITH W AT ER. REMOVE CONT AMINATED CLO j, . Continued on Back of Page N __ __ _-_- __ 1
. .i U d C U U ~ O SUti A,,uSeta .
m . . . , SECTION VI- REACTIVITY DATA . . a'I STABILITY: STABLE C'enditions to Aveld: UNEN0Wti
- n3 .
. Incompatibility,-(Materials to Avsid): ,, ,{ ).
onorNoAoENTs , . .
- i
- f. Natardous becompositten Products: - 1 h- '
=* *
- May prodwee hare *Wous fwnes when heetoqi to secDmpoolinen as in wel6 tag.
Fwnes sney coatein: Camon Monoslae . ' Hazardous Polymerization - Will 10T OCCUR . CONDITIONS T0.AV0'ID: UNUiCVN
. SECTION Vil - SPILL OR LEAK PRCCEDURES
' Steps to be aken in Case Material is Release or Spilled: i REMOVE ALL SOURCES Or 10MTION (FLAMES.HDT SURF ACES, A>c
., ,,; ,. ,. ELECTRCAL.'siATC ORFRCTIONAL SPARKSt. AVOSO BREATHING ~
VAPORS. VENTsLATE AREA. REMOVE WITH #ERT ASSORRENT Aec
~ - NON SPARKNG TOOLS.
Waste Disposal flethod: - . 7 , , . DSPOSE N ACCOscANCE WITH LOCAL. STATE. APC FEDERAL. REGULATIONS. + DO NOT PUNCTURE OR NCNERATE CONTANERS. SECTION Vill - SPECIAL PROTECTION INFORMATION
~
Respiratory Protection: .- OUTDOOR /OPEN ARE AS: USE FILTER TYPE RESPIRATOR $(NIOSHIMSHA TC21C) -
. ' N.i TO REMOVE SOLO AIRBOR>E PARTICUL ATES FROM OVERSPRAY. RESTRICTED
.*c *-
.
- 1, . VENTIL ATION ARE AS: USE COMBINATION ORGANIC VAPOR. FILTER TYPE RESP
' ~ '
IRATORS INIOSHIMSHA TC23CI DFStGNED TO PVRIFY T4 AIR BY REMOVING SOLO AtRBORNE PARTICULATE Am ORGANICVAPORS.CONFWED AREAS:
- US: SUPPLIED AIR RESPIRATORS OR HOOOS INIOSHIMSHA TC19'Cl. N ALL C ASES. PLE ASE RE AD M ARS ACTURE R*5 INSTRUCTIONS CAREFULLY TO DETERMNE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHCHTE
," _, RESPIRATOR IS EFFECTIVE.'~ A C HOW IT IS TO BE PROPERLY
~ ~ ' ~ ~ ~ - FITTED.
r<.
. ~ ~
Ventilation: PROVCE GENE RAL DLLTTION 04 LOC AL EXH AUST VENTILATION IN VOLUuE , APO PATTERN TO KEEP THE CONCENTRATION OF HAZ ARCOUS NGREDENTS l-8
. LISTED W SECTIONil BELOW THE LOWEST SUGGESTED EXPOSURE Leu TS. l THE LEL M SECTIONIV BELOW THE ST ATED LiutT. APO TO REMOVE g DECOMPo$rfloN PRODUCTS DURNG WELDNG OR FLAME CUTTING ON SURF ACE $ COATED WITH THl5 PRODUCT.
. Protective Gloves:
REOUIRED FOR PROLONGED OR REPE ATED CCHT. ACT. [ye Protection: .
..~ USE SAFETY EYEWE AR DESIGNED TO PROTECT AGAINST SPLASH OF Lt0VIOS.
Other Protective Cquipment: PREVENI PROLCNGED SKN C04T ACT TO COMTAuIN ATED CLOTHINO. ' SECTION IX - SPECIAL PRECAUTIONS Precautions to be Taken in Handling and Storing: .
. CANGER' EXTREuELY FLAuM ABLE. DO NOT STORE NE AR FIRE OR OPEN
. FLAME. 00 NOT STORE ABOVE 120 F. WARNNG' COP.TTENTS UDOEM
, PRESSURE.DO NOT PUNCTURE OR INCINERATE CCNT AfNER. EXPOSURE TO HE AT OR PROLONGED EXPOSURE TO SUN MAY CAUSE YlOLENT BURSTING OF CCNTANER Other Precautions: .
. D3 NOT T ave evrERN ALLY. AVotD PROLONGED OR RE PE ATED CCNT ACT WITH SKIN APO BRE ATHNG OF VAPOR OR SPRAY MIST. DO NOT WE AR
- CONT AulN ATED CLOTHNG. $>CES OR GLOVES. DO NOT SPRAY NE AR OR TOWARD FC A1.SPAh5 OR OPEN FLAME. -
LE AxtNG CONT AtNE RS WILL PERU!T THE ACCUuutATION OF AN EXPLOSfvE CONCENTRAT80N OF VAPOR.
\
I Form E010B COATING / THINNER DATA FORM Company Name:$0bYM $/CilAR ftJdT bdW Y4l111 bu71kttTY Applicable APCB Certificate f: hM57' M 8 TAT 7/M b/MTSDb b d7 M/k Y bM h4415L Product'Name: Product Manufacturer: N6 bDOSNI 6 bC Usaae Data Daily (gal / day): /250
- 6. @8
-Annual (gal /yr): !lb
- 2-Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: M [ Tfgcj M D M S D S As Received (Concentrated):
Density (1bs/ gal): 7. Solids % by Weight: 23* % by Volume: VOC % by Weight: 7b,Y % by Volume: N,[O Water % by Weight: % by volume: D As Applied (Diluted): QME A5 dScM' Density (lbs/ gal): % by Volume: Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: I I Thinner Data Chemical Composition: i Density (Ibs/ gal): i Mfr. Data Sheet or Certification is attached. Yes / No f
*For NSPS Sources Method 24 must be used.
I This is to certify that this information is true an complete to the best of my knowledge. Signature . JL 'MWildTit 1e: iW 4LIMK DF ENVilWUQL CLAUT' 11/03/89 i RMP 1
p . S
*q MATERIAL SAFETY DATA SHEET .
f COATINGS AND RESINS GROUP 1 l SECTION I - PRODUCT INFORMATION .4 MANUFACTURER'S NAME: PPG INDUSTRIES INC. CODE / IDENTITY : 55-317 (030587M) PRODUCT SAFETY LOC.: 260 KAPPA DRIVE TRADE NAME: FLAT UHITE SPRAY ENAMEL PITTSBURGH, PA 15238 CHEMICAL FAMILY: ALKYD
' p US DOT: COMPRESSED GAS, N.O.S.
MSDS CONTACT: MANAGER, INDUSTRIAL HYGIENE -E AND PRODUCT SAFETY DATE OF PREPARATION: 1/28/88 j] j (412) 963 5822 CUSTOMER PART # , u
=* 4 EMERGENCY TELEPHONE: (304) 843 1300 SECTION II - INGREDIENTS APPROX. EXPO $URE LIMITS
%WT. CAS 40. ACCIH TLV OSHA PEL PPG IPEL TjiANIUM DIOXIDE # 10 13463-67 7 10.00Mg/M3 15.00Mg/M3 10.00Mg/M3 CALCIUM CARBONATE 10 1317 65 3 10.00Mg/M3 NOT EST, 10.00Mg/M3 NETHYL ETHYL KETONE 10 78933 200.00 PPM 200.00 PPM 200.00 PPM ACETONE 20 67 64-1 750.00 PPM 1000.00 PPM 750.00 PPM XYLENE 20 1330 20 7 100.00 PPM 100.00 PPM 100.00 PPM PROPANE 15 74 98 6 NOT EST. NOT EST. NOT EST.
ISOBUTANE 15 75 28 5 NOT EST. NOT EST. NOT EST. FILM FORMERS, RESINS, AND ADDITIVES 5 PROPRIETARY NOT EST. NOT EST. NOT EST. CARCINOGENIC ACCORDING TO CRITERI A EST ABLISHED BY:
- e NTP ** = IARC D = OSHA # s OTHER SECTION III - PHYSICAL / CHEMICAL CHARACTERISTICS BOILING RANCE : 56 145 DEG.C SOLUBILITY IN WATER: 20.6 %
VAPOR PRESSURE: 57.4 NrnHg WT/ CAL (LBS): 7.06 (U.S.) VAPOR DENSITY : HEAVIER THAN AIR pH: U/I
% VOL/ VOLUME : 91.10 % SOLID BY WEIGHT: 23.6 i DAP RATE (BuGAes100): 380 SPECIFIC CRAVITY: .85 SECTION IV - FIRE AND EXPLOSION HAZARD DATA
- US DOT CATEGORY: EXTREMELY FLAMMABLE FLASHPOINT: 15 DEG. F PMCC FLAMMABLE LIMITS: LEL 2.3 UEL U/I
?
EXTINGUISHING MEDIAf USE NATIONAL FIRE PROTECT:0N ASSOCI ATION (NFPA) CLASS B EXTINGUISHERS (CARBON DIDX1DE, DRY CHEMICAL, OR UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA CLASS IA FLAMMA8LE LIQUID FIRES. UNUTUAL FIPE AND EXPLOSION HAZARDS: KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND OPEN FLAMES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. 00 NOT APPLY ON HOT SURFACES. T0XIC GASES MAY FORM WHEN PRODUCT IS CONTACTED BY FLAME OR HOT SURFACES. AEROSOL-CONTAINERS HOLD EXTREMELY FLAMMABLE GAS AND FLAMMABLE LIQUID UNDER PRESSURE. SPECIAL FIPE F10HilNG PROCEDURES: WATER SPRAY MAY ES INEFFECTIVE. WATER SPRAY MAY BE USED 10 COOL CLOSED CONTAINERS TO PREVENT PRESSURE FUliD-UP AND POSSIBLE AUTolGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS LSED, FOG N0ZZLES ARE PREFERABLE. FIRE FIGHTERS SHOULD WEAR SELF CONTAINED BREATHibG APPARAlUS. SECTION V - REACTIVITY DATA STABILITY: STADLE HA7ARDOUS PotVMERi?ATION: NOT EXPECTED TO OCCUR INCOMPATIBILITY (MATERI ALS AND Co@lTIONS TO AVOID): AVotD CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS, OR STRONG OXIDlZING AGENTS. HAZAPDOUS DECOMPostilow PRODUCTS: . MAY PRODUCE HAZAPDOUS DECOMPOSITION PRODUCTS WHErr HEATED. WELDING, BRAZING, OR FLAME CUTTING ON SURFACES COATED WITH THIS PRODU';T MAY PRODUCE FUMES INCLUDING: Carbon Monoxide, SECTION VI - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERI AL 1$ RELE ASED OR SPILLED: PROVIDE MAXIMUM VENilLATION. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRATORY AND SKIN AND EYE PROTECTION SHOULD BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP SPILLED MATERIAL WITH SAWDUST, VERMICULITE, OR OTHER ABSORBENT MATERIAL AND PLACE INTO CONTAINERS FOR DISPOSAL. WASTE DISPOSAL METHOD: WASTE MATERIAL MUOT BE DISPOSED OF IN ACCORDANCE WITH. FEDERAL, STATE, AND LOCt.L ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS $HOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT FACILif. SECTION VII - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSLfRE FROM: INGESTION: HARMFUL OR FATAL IF SWALLOWED. EYE CONTACT: CAUSES EYE !RRITATION. SC1N CONTACT: MAY CAUSE MODERATF SKIN 1RRITATION. I INHALATION: CONTINUED ON PAGE 2 L____-______- $
r
.*
- L Q p.
I_ j PAGE 2 I f Continuetton of Manuf acturer's Code . 55-317 s* ATE OF PREP 2 1/28/88 0' VAPOR AND SPRAY MIST MAY BE HARMFUL IF INHALED. VAPOR 1RRITATES EYES, NOSE, AND THROAT. REPEATED EXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY FAUSE IRRITATION OF THE RESPIRATORY SYSTEM AND PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INH /. LING THE CONTENTS CAN BE. HARMFUL OR FATAL. CHRONIC OVEREXPOSURE: AVolD LONG TkRM AND REPEATED CONTACT, THIS PRCDUCT CONTAINS TITAN!UM D10X1DE. ANIMALS INHALING MASSIVE QUANTITIES OF TITAN!UM DIDXIDE DUST IN A LONG TERM STUDY DEVELOPED '.UNG TUMCAS. < STUDIES WITH HUMANS INVOLVED IN MANUFACTURE OF THIS PIGMENT INDICATE NO INCREASED .tISK OF CANCER FROM EXPOSURE. POTENTIAL FOR INHALATION OF TITAN!UM DIDXIDE DUSTC FROM COATINGS IS VERY LIMITED. SINCE OVEREXPOSURE ARE NOT EXFECTED, THERE IS 40 $1CNIFICANT HAZARD FOR MAN. SIGNS AND SYMPTOMS OF OVEREXPOSURE EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, AND *0SS OF COORDINATION ARE.!NDICATIONS THAT" SOLVENT LEVELS ARE TOO HIGH. REDNESS, ITCHING, BURNING SENSATION AND VISUAL DISTURBANCES MAY INDICATE EXCESSIVE EYE, CONTACT. DRYNESS, ITCHING, CRACKING, BURNING, REDNESS, AND SWELLING ARE CONDITIONS ASSOCIATED WITH: EXCESSIVE SKIN CONTACT. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURFt NOT APPLICABLE
~SECTIMI VIII - FIRST AID PROCEDURES ,
INCESTION!_ IF SWALLOWED, DO NOT INDUCE VOMITING. EYE CONTACit IN CASE OF EYE CONTACT, FLUSH EYES IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN CONTACTS . IN CASE OF SKIN CONTACT, REMOVE PROMPTLY BY WIPING, FOLLOWED BY WATERLESS HAND CLEANER AND SOAP AND WATER. INHALATIONS _ 1F AFFECTED BY INHALATION OF VAPOR OR SPRAI MIST, REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION AND OTHER SUPPORTIVE MEASURES AS REQUIRED. OTHERt IF ANY OF THE FOLLOWING OCCUR DURING OR FOLLOWING USE CF THIS PRODUCT, CONTACT A PolSON CONTROL' CENTER, EFERGENCY ROOM OR PHYSICIAN IMMEDIATELY HAVE MATERIAL SAFETY DATA SHEET ' INFORMATION AVAILABLE.
- INGESTION *EXCES$1VE EXPOSURE TO A CORROSIVE MATERI AL.
- PERSISTENT SKIN / EYE IRRITATION OR BREATHING DIFFICULTIES.
SECTION IX - PROTECTION INFORMATION - PERSONAL PROTECTIVE EQUIPMENT FORT EYE PROJECTIONS WEAR CHEMICAL TYPE SPLASH COGGLES OR FULL FACE SHIELD. SKIN PROTECTIONt WEAR PROTECTIVE CLOTHING, INCLUDING IMPERMEABLE APRON AND CLOVES CONSTRUCTED OF l POL 1 VINYL ALCOHOL, NEOPREG NBBER,' NITRILE RUBBER OR LATEX RUBBER l' RESPIRATORY PROTECTION: OVEREXPOSURE TO VAPORS MAY BE PREVENTED BY ENSURING VENTILATION CONTRCLS, VAPOR EXHAUST OR FRESH AIR ENTRY. NIOSH/MSHA APPROVED (TC 23C-) PAINT SPRAY OR AIR SUPPLIED (TC 19C-) RESPIRATORS MAY ALSD REDUCE EXPOSURE. READ RESPIRATOR MANUFACTURER'S INSTRUCTIONS AND LITERATURE CAREFblLY TO DETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THE ' RESPIRATOR IS EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED. OTHER EQU1PMENT: CLEAN OR DISCARD CONTAMINATED CLOTHING AND SHOES. . VENTILATION REQUIREMENTS j PROVIDE GENERAL DILUTION OR toCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP THE J CONCENTRATION OF INGREDIENTS LISTED IN SECTION 11 BELOW THE LOWEST SUGGESTED EXPOSURE LIMITS, THE LEL IN SECTION IV BELOW THE STATED LIMIT, AND TO REMOVE DECOMPOSITION PRODUCTS DURING WELDING OR FLAME CUTTING ON SURFACES COATED WITH THIS PRODUCT. SECTION X - SPECIAL PRECAUTIONS HANDLING AND STORAGE PRECAUTIONS DO NOT STORE ABOVI: 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS IA FLAMMABLE LIQUIDS. OTHER PRECAUTIONS F THIS MATERIAL IS PART OF A MULTIPLE COMPONENT COATING SYSTEM, READ THE MATERIAL SAFETY DATA SHEET (S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS THE RESULTING l MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS. ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH ALL APPLICABLE RULES OR ORDERS UNDER T,iE ENVIRONMENTAL PROTECTION AGENCY'S T0XIC SUBSTANCES CONTROL ACT. TH15 MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) U/l = UNKNOWN INFORMATION N/A = NOT APPLICABLE NOT EST. = NOT ESTABLISHED CERT. LTR.= CHEMICAL 0.K. ON TSCA INVENTORY; CAS No. NOT AVAILABLE PP!C 5635 (CUSTOMER NO.) LOCATION : 0809 8855/317/////128 _ _ . _ _ _ . _ _ . _ _ -..._u __..-.m__ _
Form E010B COATING /TIIINNER DATA FORM Company Name:$0bYA// $/CilidR f/1/IT 15} Jill 55fA- YALLEV britkttT)! Applicable APCB Certificate #: 0//57: M 8t#'r/A/4 MA/NMbM Product Name: YAR50 L /8 Product Manufacturer: bO A/ b/fMfM7 j h.5A Usaae Dara Daily (gal / day): 50/24>O :- //)7 Annual (gal /yr) : So Rule 25.43 & 25.44 Analysis or Manufacturers Certification Data *: M [Tf/ct/CD M Cf As Receive'. (Concentrated): Density (lbs/ gal): 6,5 Solids % by Weight: O % by Volume: O VOC % by Weight _
/OO % by Volume: /Oh Water % by Weight: O % by volume: O As Applied (Diluted): '6N /II / 60VI Density (lbs/ gal): % by Volume:
Solids % by Weight: % by Volume: VOC % by Weight: % by Volume: Water % by Weight: % by Volume: Thinner Data Chemical Composition: Density (1bs/ gal): Mir. Data Sheet or Certification is attached. Yes / No
*For NSPS Sources Method 24 must be used.
This is to certify that this information is true an omplet to the ! best of my knowledge.
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Signature: Mwl f Tit 1e: &LlLd6f1C W fN~ Vitth'lUEbL ODUT"1 11/03/89 RMP
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I y . . . f v5 .e.80L ,. HM C. 417 a@wcoumm usa a omana er seman senpensnow , DATE ISSLED 4/10/88 MATERIAL SAFETY DATA SFEET '#
- EMION C00sP ANY. U.S. A. P.O. 90K Sito Mp'JSTON. TM ??$32-2100 A., IDENTIFICATION ABD ENERGENCY lif0RMATION PRDOUCT 90AIE PMIOUCT COct WADSOL 18 131824
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s CHEMICAL 9easit CAS lasSER Petroleum Selvent 8032-33-4 PRODUCT APPEAAANCE Af8 000R C t eer wa tee-wnt te l eisu te
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'EMERSt8E;T TELEPetBE ItBSER *
(713) 666-3424 B. COMPONENTS AND HAZARD INFORMATION CORIPONENTS CAS 80. OF APPROXIMATE COMPONtefts CDMCENTRATION This peemset een t>e oefened ses meneral optrtte 8032-32-4 100% it constets precomenantly of CT-Ct0 hyerocarbone. This secouet containe: CT-Cto esturates nyorocereone utsture Approutsetely 92*5 Teluone 100*88*3 Approstmately 0.8% Xylene 1930-20-7 Apprestaately 0.3% t thylbenzens tro-at-4 Appeosteetely 0.3% Ce+ Aromatico perture Approutmetely e5 See Section E for Health one eterers Information W 7AR00US MATERIALS IDttff!PICATION 37378W (98115)
><% I th Flesmettllty Rasettelty BASIS 1 3 0 becommenood by tumon
, ERPOSURE Lief!T FOR TOTAL EdODUCT SASIS 900 ope (seo mg/m3) for en pocommenced by tes Amortcon Conference of Governmental e-noue worecoy 1 Inasstetal Mystentate ( ACGIM) for SteOGerW Solvent C EMERGENCY AND FIRST AfD PROCEDURES ,
ETE (XpffACT If soleshed into the eyes. fluen wtth clear water for is etnutes or tmtti terttation subesses. If erettet ton pees tete. call e pnyeteten. SKIN CONTACT i / In case of shen contact, remove any contaminates clothing ents woeft ektn thoro @ly with soap j ( ens vetee.
!DetALATION If e.eecome by vapor, esmove f rom e=ooeure ena cat'. e onys teten tamediately. If Deestning to treeouter or mee stoppeo, start resuscitet ton, samentater orygen, if evelleole.
ees estummmee
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1 stegn vence concentrat tone igeester than soprowsmately 1000 pou) are terstating 'te TNe ens ! ano the recogretory tract, may cause heeemenos one strtfnees. are onestnettc. And may rowe other central nervous system effects. I senivu 0F HAZARD AND TOK! CITY INFORmAT!cN
). Pro.tonges.or i.. tng e terleet repeates ton .ne en enm.utt.:
contacthow.w. with thee product
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on human remove .nemin et te ie ev.ne gees.tely temicological esta, this product te judged to be netthee a *cerecetwe* fuer en *trettent' by 0$ne artterte. Praguet contacting the eyes may cause eye irritetton, seowets of entmal stuates using both eemos of several toectos have snown that htuney semage .! 1 can occue in mole rots of tse prolonged and repeated innelation orposures to t egnt hvorecertson wooors 'of the general type present en this proouct. While the comePo to of a los ocaer of severity in antaals, the tr.iolteettons of these results for humans have not yet been seternenea. Product has a low orsser of acute oral ena cereal toutetiv. Dut minute amouste esotretes into the sunge curing ingestion may cause alltf to tevere pulmonary injury and sessibly seeth, fess product is jusged to have an acute oes) LDSO (ret) greater tre.n 5 g/kg e8 Doey wetent. end en acute norme! LD50 (recett) greater then 3.18 g/kg of booy wetent. a
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- l F. PHYSICAL DATA
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Th. ,onautng aet. are approint. .r tv,6cei v.it ene snevia not .o ..e e.r ts. enstgn purposes. BOILING RANGE VM*0R PRESEURE Approutmately 183-202' c (308-3t&* F ) toes wa= eC m Hg e SS*C A$fM 0 2577 i
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SPtC3FIC ORAVITY itt.S C/tS.S C) VAPOR DfWt!TY ( AIA e 1) 0.78 emormatmetely S.s ICttCULAR WEIED47 PERCENT VOLATILE ST YOLUME 145 100 e t sta, one 2S'C (7T*F) EVAPORATION RATE 9 1 ATW. Ape 25 C (77 F) Pet . (n-SUTTL ActTATE e 1) (seenstally neutral 0.1 PDUP CDNQtALING OR MELTING POINT $@WBILITY IN WATER 91 ATM. Ape 25 C (77 F) Lees then +10'C (O'F) seegitetDiet less tnen 0.1% Pour Point oy 457m D 37 i i VISC0517Y l 0.80 cp
- 25'C Astm O 445 1 4
G REACTIVITY ! i Tht. pro.uct t. .teoi. en. wi n not r..ei vioienc y with wet. . = ar us a>orym.rtrett.n wtIl Awold Contact wt Sucn et Itoute chlortne. concentrated org.n. not,oCCue.=.ium v a poenioru. or c.th Streng ictum osloantB n,pocniert .
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.erto or otner eut tooie so.oro.nt to OD*in . tii .e... inimir. .re thing v. or.. ment.it .msn contact. Wentt88te Confine 8 90eces. all winOOws one ocoPS. Meep Dreduct out of semert ens meteetourset by Othing or imoound t r.g . Aove9e eutnorttlet if proeuct age entseed oP may enteP I
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ertterte ensupilauf Dy the sewelope*e of these rating systems, together 1sttn $seman's - 7mtergeretstlen of the ovellehte Wats. POR ADDITIONAL INFORB4ATION Sue HEALTH < POR STHER PRODUCT SBIPolutAff0BIIXptfACTs RFftCTS EcoffACT OletCT0e CF INDUSTEl&L MYGIENE. $1AN&4(t. IIARKETING TfC64djCAL SERYtCE$ tzXON CuefPANV, U.S.A. EXE0er CDsIPANY. U.S. A. P, D. BOX 3100 N00M 2737 P. O. Box 2140 WOON 3493 MOUSTON. TX 77252=3190 ' MOUSTON, TX 77292*2100 (713) 894-2443 (183) Sd4-Stat 9 9 e w 9 t 3 a w h e D
1 ENCLOSURE 8 ATTACllMENT 1 REFERENCED ON Ti(E E106 FORM FOR Ti(E CONSTRUCTION SANDBLAST AND PAINT Sil0P l I i 1 l l l
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ATTACHMENT 1 POLLUTANT ESTIMATION CALCULATIONS j FOR SEQUOYAit NUCLEAR PLANT CONSTRUCTION SANDBLAST AND PAINT Sil0F WITH .TW") BUILDING ROOF EKHAUSTERS _. ) l Material: Carbo Zinc l Material Composition (as applied)_: I Pounds in Percent by weight .'l
-Ingredient Fraction of. Density 1 cellon Ibs/ mal ~1 Gallon i 2.25 18.4 Thinner 0.25 9 57 1~
Solido 0.30 .23- T-6.5 3 24.5 Ethanol 0.45 12.25; 100.0
. Total 1.00
' Density of paint as applied': 12.25 lbs/ gallon RACT (1bs VOC/ gallon) = (Solvent fraction by weihht)(Paint Density)
= (18.4% + 24.5 %)(12.25 lbs/ gallon) l
= 5.26 lbs VOC/ gallon !
Use 5.3 lbs VOC/ gallon 1
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- ENCLOSURE 9 DRAWINGS OF LUBRICATING OIL SYSTEM AND ASSOCIATED VENTS The following drawings are included as part of enclosure 9.
- 1. Flow Disgram Turbine Drains and Miscellaneous Piping 4 7W807 - 1
- 2. Flow Diagram Lubricating 011 Systems 47W816 - 1 ,
- 3. Description and Diagram of Vapor Extractor System I.L. 1250-3743 l l
1
1 ( VAPOR EXTRACTION SYSTEM f I 1.L.1250-3743 m M Figure I is a diagrammatic illustration of the poset is formed. As the . flowing. gas is 04 system used to remove oil vapor from the oH subjected to multiple changes of direction in its reservoir and the oil piping system. It also path through the demister, a semi-turbulence shows the system by which entrained hydrogen develops by the rolling of the vapors against gas is removed to atmosphere. Two vapor- the . vane walls. As the entrained droplets extractors are used in this system. carried in the gas contact the vane walls, they. En impinge and adhere to them. This liquid then
- p. The first vapor extractor is a motor-driven moves to the vane pockets and is drained by p gas blower mounted on the oil reservoir. Its gravity to the liquid reservoir.
Eip - suction pipe is connected to the area above the oil level where vapors accumulate and are The other blower may be installed either withdrawn by means of the blower. The above or below the loop seal tank as shown in volume of gas discharged by the blower can be varied by changing the opening of the butterfly the illustration. This installation is to remove valve installed in the discharge line. This is any hydrogen which may be entrained in the -
-m-lubricating oil leaving the generator bearing
- 5 usually adjusted for continuous operation . housing. .In this system, a check valve is 2- under normal conditions. mounted in the discharge line to prevent any M
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The discharge from the blower, which is back-Ilow from the pump discharge.. The mounted on the reservoir,is passed through a check-valve in this line is also arranged to allow condensing type of apparatus, identified on the for natural draf t when the vapor extractors are illustration as a "Demister." This is used to out of service. (' . extract entrained liquid from the gas by a condensing principle, whereby the gas passes A flexible connection is used between the across a series of verticall' installed, V shaped, customer's connection to the vapor extractors, corrugated vanes of thm s eel. g ,,, At each point where the individual vane The vapor extractor must be in service when changes the direction of the gas flow, a vane starting and operating the unit. m-um ss D Q '"l* Q9, S*2 S e4 GT'E 4 3 ES oE BY G2 1 (1-I)
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TO ATMOSPHERE I DEMISTER Q7
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+ DISCHARGE ADJUSTABLE BUTTERFLY VALVE l
VAPOR EXTRACTOR SUCTION TffeMOTOR j l u . I + CONDENSED Otl DRAIN - MAKE-UP FROM FILTER OVERFLOW TO FILTER
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O ! DRAIN TO TRAP ; Y VAPOR EXTRACTOR MOUNTED ON RESERVOIR , j VANE WALL O \ VANE POCKET e g FLOW hpfj '
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- .j VANE UNIT NONDENSED OIL 1
Y# DEMISTER _ _ _ _ _ _ ___ _ _ _ .i
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- CHECK VALVE
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(\- W-p ._ _jb [lQ' FLEXIBLE _ - CONNECTION ," j VAPOR EXTRACTOR . l ADJUSTABLE BUTTERFLY I( #g SUCTION GENERATOR 64#l i VALVE LOOP SEAL TANK MgG
~~~ DR AIN ' )) l FILLING CONNECTION g
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. ORIFICE A. MAKE-UP TO
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SEAL Olt UNITMI II ; I V - {TOWASTE VAPOR EXTRACTOR LOCATION ABOVE LOOP SEAL TANK
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GENERATOR Cn'ECK VALVE %___ LOOP SEAL TANK ( UIbh ARGE . FLEXIBLE CONNECTION 79 l 6 'b i i ' ADJUSTABLE ( I BUTTERFLY I ( 4N f f
!j VALVE SUCTION
!, -- DRAIN J) MAKE-UP#= \V DRAIN L&~
TO SEAL Oil UNIT %)
' FILLING CONNECTION s 7 ORIFICE
' VAPOR EXTRACTOR
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fTOWASTEh VAPOR EXTRA _CTOR LOCATED BELOW LOOP SEAL TANK Figure I f.t. I 250-3743 - _ _ _ _ - _ _ _ - _ _ _ - _ . _ _ - _ _ - _ _ _ . . _- ._ _ ~.
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v .. LOVERSIZE .
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SOCUMENT PAGE PULLED ~ SEE APERTURE CARDS L NUMBER OF OVERSIZE PAGCS FILMED ON- APERTUR'E CARDS' - I l
. APERTURE CARD /MARD COPY AVAILABLE FROM QECORDS ~ AND REPORTS MANAGEMENT BRANCH .i l
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