ML20235R696

Forwards EPA Forms 3510-1 & 3510-2C for Renewal of NPDES Permit TN0026450,including Description of Boron Sources & Discharge Points,List of Chemicals Added to Each Discharge & Description of Program to Control Microbiological Corrosion

ML20235R696
Person / Time
Site:	Sequoyah
Issue date:	10/01/1987
From:	Rivers M TENNESSEE VALLEY AUTHORITY
To:	Sinclair R TENNESSEE, STATE OF
References
NUDOCS 8710080159
Download: ML20235R696 (130)

Text

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f.s 14 TENNESSEE VALLEY AUTHORITY KNOXVILLE. TENNESSEE 37902 OCT}11987 x

Nr. Ralph N. Sinclair l

Nanager, Permits Section-Division of Water Pollution Control Tennessee Department of Health and Environment 1

TERRA Building 150 Ninth Avenue, North Washv111e, Tennessee 37219-5404

Dear Mr. Sinclair:

SEQUOYAH NUCLEAR PLANT (SQN) - NPDES PERNIT NO. TN0026450 - RENEWAL APPLICATION Enclosed are two copies of '.ironmental Protection Agency forms t

3510-1 and 3510-2C for renewal of the SQN permit (Enclosure 1).

Also j

enclosed for your use in renewing the permit are:

a description of

{

the ' raw water systems and chlorine injection and discharge points (Enclosure 2); a description of the boron sources and discharges (Enclosure 3);

a list of chemicals added to each discharge 1

l-(Enclocure 4); a description of a program to control microbiological 1y influenced corrosion (Enclosure 5); and a description of the quality program for verification of the thermal computed compliance system l

(Enclosure 6).

The permit application package reflects the current l

permit except for the changes requested in Enclosure 7.

l If you have any questions regarding the enclosures, please call Madonna E.

Martin of 'my staff at (615) 632-6695 in Knoxville, Tennessee.

. Sincerely, j

b artin E. Rivers, Director Environmental Quality Enclosures 1

l 8710000159 071001 ADOCK0500g7 PDR P

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N An Equal Opportunity Employer

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1

. 1 OCT}11987 Mr. Ralph M. Sinclair l

cc (Enclosures):

I

~Mr. Bruce R. Barrett, Director i

Water Management Division U.S. Environmental Protection

. Agency, Region IV 345 Courtland Street, NE.

Atlanta, Georgia 30365 Mr. Philip L. Stewart, Manager Chattanooga Field Office Division of Water Pollution Control 2501 Milne Street Chattanooga, Tennessee 37406-3399 1

l U.S. Nuclear Regulatory Commission Attention: Document Control Dest Washington, D.C.

20555 Mr. G. G. Zech, Assistant Director Regional Inspections Division of TVA Projects Office of Special Projects U.S. Nuclear Regulatory Commission i

Region II 101 Marietta Street, NW., Suite 2900 Atlanta,-Georgia 30323 i

Mr. J. A. Zwolinski, Assistant Director for Projects l

Division of TVA Projects Office of Special Projects U.S. Nuclear Regulatory Commission 4350 East West Highway EWW 322 Bethesda, Maryland 20814 4

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ENCLOSURE 1 EPA FORM 3510-1 EPA FORM 3510-20

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Please print or type in the unshaded areas only form Acoroved OMB No.158.RC175 (fdi-in areas are spaced for elite rype. i.e. 12 charactershncht 1

U.S. E NVIRONM ENT AL PROTECT 6ON AG E N CY

1. EPA 1.D. NUMBE R FORM

^C GENERAL INFORMATION 2

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&G Consolidated 1%rmits Program p TN5640020504 0

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G ENE H A L INSTR UCTIONb L A BL L iTE M5

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If a preprinted label has been provided, affix

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($ (k it in the designated space. Review the inform-etion carefully; if any of it is incorrect, cross through it and enter the correct data in the silA F A'CIL)TYM AfAE \\

appropriate fill-in area below. Also, if any of

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the preprinted data is absent (the area to tfie N\\\\\\\\\\

left of the label space lists the information Y' VACILITY that should appear), please provide it in the

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Pl EASE PLACE LABEL IN THIS SPACE M Al4.lNQ ADDR{SS proper fill-in areals) below, if the label is s

complete and correct, you need not complete NNN g

ltems I, lil, V, and VI (except V/-8 which must be completed regardless). Cornplete all ltems if no label has been provided. Refer to y* FACILITY the instructions for detailed item descrip-LOC ATIO tions and for the legal authorizations under which this data is collected,

11. POLLUTANT CHARACTERISTICS INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. lf you answer "yes"to any questions, you must submit this form and the supplemental form listed in the parenthesis following the question. Mark "X"in the box in the third column if the supplemental form is attached. If you answer "no" to each question, you need not submit any of these forms. You may answer "no"if your activity" is excluded from permit requirements; see Section C of the instructions. See also, Section D of the instructions for definitions of bold-f aced terms.

W A R K ' A' I

WANK

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SPECIFIC QUESTIONS was no srEcBr C OUcSTlONS vs, B. Does or will this facility (either entsring or proposed)

A. Is thes facihty a publicly owned treatment works y

h ch r its in a dischstge to waters of the U.S.?

equatic animal production facility which results in a discharge to waters of the U.S.? (FORM 28)

C. Is this a f acility which currently results in discharges i

D. Is this a proposed facility (other than those described to waters of the U.S. other than those described in X l X

in A or O above) which will result in a discharge to X

waters of the U.S.7 (FORM 2D)

A or B ebove? (FORM 2C) ni n

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F. Do you or will you inject at this facility industrial or E. Does or will this facility treat, store, or dispose of X

municipal effluent below the lowermost stratum con-X l

hazardous wastes? (FORM 3) teining, within one quarter mile of the well bore, underground sources of drinking water? (FORM 4) u G. Do you or Wdi you inject at this f acehty any produced g

water or other fluids which are brought to the surface X

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m connection with conventional oil or natural gas pro-duction, inject fluids used for enhanced recovery of g gg,on mining of minerMs, in situ combus-rocess soluti g

g,g oil or natural gas. or inject fluids for storage of liquid (FO N O hydrocarbons? IF OR M 4) a u

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Is this f actisfy a proposed stationary source which as J. is this facihty a proposed sta6obry source which is one of the 28 industrial categories listed in the in-X NOT one of the 28 industrial categories listed in the structions and which will potentially emit 100 tons instructions and which will potentially emit 250 tons X

per year of any air pollutant regulated under the per year of any air pollutant regulated under the Clean Clean Air Act and may affect or be located in on

- Air Act and may affect or be located in en attainment attainment eree? (FORM M eree? (FORM 5) e T "."-n.

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8 T U N,N E S S E E VALLEY A U T,H 0,R I T Y, DO YES D N a

C. 8T ATus Ov ovE N ATO R (Enter the appropriate letter into the enswer box; tf "Other". spectfy.).

D. FHON E (areo code a no.) _

F = FEDERAL M = PUB LlO (other than federal or state) 1 i

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Yl. MA3 Attach to this application a topographic map of the area extending to at least one mile beyond property bounderies. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste trestrnent, storage, or disposal facilities, and each well where it injects fluids underground include all springs, rivers and other surface -

water bodies in the map area. See instructions for precise requirements.

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4 Kii. F.ATURE OF BUSINESS forovsde a brief descnption Production of electric power by thermonuclear fission and other associated operations.

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" lit. CE RATIFICATION (see instructions /

X I certify under penalty of law that I have personally examinedandam familiar with the Information submittedin this application andall:.

Attachments and that, based on my Inquiry of those persons immediately responsible for obtaining the Information contained in the ':

application, I believe that the information is true, accurate and complete. I am aware that thers are significantpenalties forsubmitting false information, including the possibility of fine andimprisonment.

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A. N A M E & O f F IG a A L T I T L E (ty pt or prin t)

Is. SIGN AT U R E C. D AT E SaGNLD Martin E. River'. Director, Original signed by OCT 1 1987 Fnv4 vormn r,1 Onnfirv vn ruch 2

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gPA g.O. N uM" nu tcupy from lum ) of Form jj a Plus.3 print or type in the unshadtd areas only. TN5640020504 ronn Aeroved ous No.158-Rott3 FORM u.w. EN VenONM EN T A4 PRuT4C Ylw N AWNC Y APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER gh 2C g EXtSTING MANUFACTURING, COMMERCI AL, MINING AND SILVICULTURAL OPER ATIONS NFDEs is Consolidated Permits Program l For each outfall, het the latitude and longstude of its location to the nearest 16 seconds and the name of the rReiving water. l A.,0,ug,q u

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,,,,,m,,,,,,,, riarj 101 35 12 35 85 35 14 Tennessee Rivnr 110 35 13 23 85 35 09 Intake Forebay 1 112 35 13 28 85 35 11 Intake Forebay i I 116s 35 13 33 85 35 13 Tennessee River I 117 35 13 32 85 35 03 TennenacTo River l l 09 hh Note: A ll othet outfalls d

11. FLOWS. SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach e line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing westowster to the effluent, i

d and trestrnent units labeled to correspond to the more detailed descriptions in Itern 8. Construct a water belence oc fu line drowing by showing overage flows between intakes. operations, treatment units, and outfalls. If a water balance cannot be determined leAy.r Wr1s/n mht!ng actMeisel, provide e pictorial description of the nature and amount of any sources of water and any collection or treettnent eneseures.. V M ' q

8. For each outfall, provide e description of: (1) All operations contributing westewater to the effluent, including process weetoweter, sanitary westowster, cooling water, and storm water runoff; (2) The everage flow contributed by each operation; and Ol The trootment received by the westewater.,Continus I

df ] on oddstional sheets if necessary.

• • • i*

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a. OPE R ATtON(S) CONTRIBUTING f%Cw

8. T R E ATM ENT-N I

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e. OPER ATlON (lisi) lh^[ unit

e. DESCRIPT80N o '

W N. E g l l Diffuser discharge 2033.7 MGD Mixinn by submerced 4 A which receives flow multiport diffusers 1 0 i 1 101 from the following: 4 i A A. Condenser cooline 2030 MCD Nong water (open mode _) l ) l B. Condenser coolina 1J55 MGD Cooline by natural draft 4 A water (helper mode) cooling towers 1 --.w---.--.--. C. Essential raw cooling I60 MGD 4 A ,i l water I D. Yard drainage pond l_.8.51 MGD 9.5 MG nond which nrovides 1 U I (outfall number 102) _ sedimentation and oil 4 A which receives flow skimn.}}sg I from the following: !Y 1. Service BM 1 ding Sump ___1_0.,000 GPD Skimminn X 2. Office Building floor 10 GFD Skimming X l X and equipment drains .,5. Diesiil Generator 10 GPD Skimmina X X Building-sump 4. Security diesel 10 GPD Skimminn X X generator building sump we rics AL usk oNLv tr/fl ene sumchnes sub.categoriess LP A F orm 3510L2C (6,80) PAGE 1 OF 4 cQNilNUL ON HLVERSI

gr,. s.D. NuM.E s(copy frores Nm J of form J) TN5640-020504 ronn AcorovedousNo. rcs.norra Plusi print or type in the unshaded areas only. U.w. E N W h.ON M E N T A L PawT EC T h.iN Aw N G V FCRM APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER,- g% g EXtSTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS k For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the nome of the rRelving water. >c N u"NEQL

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11. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOG A. Attact a line drawing showing the water flow through the faciisty. Indicate sources of intake water, operations contributing westeweter to the effluent, i

and treatment units labeled to correspond to the mora detailed descriptions in item B. Construct a water belance on the line drowing by sfoving awrege j i I flows between intakes. operations, treatment units, and outfalls, if a water betence cannot be determined (e. A for perful# (n/nksg yetMdes), provide a j pictorial description of the nature end amount of any sources of water and any collection or treatment maneures. . WtNas,4 qss ;,,. 3

8. For each outfall, provide e description of: (f) All operations contributing westewater to the effluent, including procoes westoweser, eenitary win :er,.

cooling water, and storm water runoff; (2) The everage flow contributed by each operation; and (3) The treatment received trif the westoweter. Continus on addrtional sheets if necessary. W k".M M999f C,. 1 s. OUT.

2. OPE R ATIONfS) CONTRIBUTING Flow

' 9. TREATpeEstTm iM AWeAl'+ (list)

n. 09ER AT90N (list)

' inel unit )

8. DEScREFTION * 'f gf f.f 101 cont.

5. Solar Building Sump 10 GrD Skimming X X 6. Sodium hypochlorite 10 GPD Skimming X X building sump 7. Miscellaneous air 632,000 GPD None conditioner cooling waters 8. Switchyard bus cooling 200,000 GPD None water 9. Storm water runoff from. 310,000 GPD None 72.5 acres l Based on .iiannual average rainfall

10. Auxiliary Building 700 000 GPD None heat load l

4 ._E. Low volume wast;e 1.534 MGD 10 jig _nnlined nond 1 0 l 1 U treatment pond _ (outfall number 103) 2 K ] i which receives flow 4 A J from the following: l i l ~ l or r sca AL us e. oNb Y (gff]ggag guadgjmeg gug.cggggongg) l LPA Form 3510 2C (6401 PAGE 1 OF 4 l m

wAe.o.nuunnu tcopy from Jew J of Eorm J) Pizase ormt or tvoe in the unshe&d awes only. TN5640020504 Fann Approved OMB No.158-R0173 FORM u.s. anve omuswT AL rawT cTe# M A4.sacV APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER. . g3 p th i 4Lu Q - EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS OUTFALL LOCA For each outfall, het the letetude and longitude of 6ts location to the neerest 15 'econds and the name of the ratelving wateir. s E.DUTF'sLL e, L ATITU Dg C. LuMGITUDE g,,, gg gy ggg g gg gg [ygggg) (1 ) 4.one. s, as so.

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e i a. II. FLOWS, SOURCES O ] A. Attach a line drawing showing the vaster flow through the f acility. Indicate sources of intake water, operations contributing westoweter to the effluent, l and treatment units labeled to correspond to the more detailed descriptions in item 8. Construct a water balance on the line drawing by showing everage flows between intakes, operations, treatment units, and outfalls. If a water betence cannot he determined (e4, for certain {ninirgy pe$ friar s/, provide a e pictorial descr6ption of the nature and enviunt of any sources of water and any collection or tractment meneures, - '/4 1 % 4...g % B. For each outfall, provide e description of: (1) All operations contributing westewater to the effluent, includirig process westoweser, eerdtary vuestoweter, j cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment pseulved W the westeeseter. Continue on additionet sheets if necessary.

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a. ora m ATecNisi CONTRIBUTING FLOW

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s. OPE R ATIO N (Ilsf) knh

e. DESCRIPTION 8 (-

Ap ^ 1 n d 1. Metal cleaning See II.C 1 MG lined pond and 1 MG 1 U 101 waste ponds 22,000 GPD unlined pond which provide 2 K cont. (DSN 107 ) sedimentation, neutralization,3 G aeration, chemical precipita-2 C tion l l 2. Demineralized regener-12,000 GPD 2 lK ation f rom make-up_ w!Lter treatment plant 2 demineralized 3. Turbine Building sump 1.5 MGD

211_ skimming provided by X

X which receives waste pump suction being set below from the following: gl._ constant water level n. Fil ter hnrkwach 0 - O LMGD --.~._Mone-from make-up water treatment plant 1 b. Supernatant from 0.024 MCD Pond provides sedimentation 1 U alum sludge pond and sludge thickening 5 L (includes filter 5 l0 back wash from plant 2) ~ c. Regeneration wastes 0.012 MGD 4eutralized before release 2 K from make-up water treatment plant I demineralized wF F 8C4 AL USE ONLY (effluent gwadehnes sub-categories) iF'A Form 35142C (6 80) PAGE 1 OF 4 CONTINUL ON REVER5E

Eps e.o. NumeE.4tcopy from km 1 of Form 1) TN5640020504 porm Aggme,d Ous No. fss.nofis PkMs1 print or type in the unshaded Erers oniv. U.W. E N V is.O NM E N T A4. Pub 7 ECT 6.N Au R NC Y FORM APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER - A 2p g EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS g UTF ALL LOCATION . For each outfall, list the totitude and longitude of its location to the nearvst 15 seconds and the name of the Teeiving water, g6

e. L ATITU DE C. LONGITUDE mrn t

] II. FLOWS, SOURCES OF POLLUTION. AND THE ATMENT TECHNOLOGIES] A. Attach a line drawing showing the water flow through the facility. Indicate sotices of intake water, operations contributing westoweter to the effluent, and trestrient units labeled to correspond to the more detailed descriptions in item B. Construct a water belance on the line diewing by showing awroge i flows between intakes, operations, treatment units, and outfalls. If a water belance cannot be determined (e.g. for certs/n min /ng artMfes/, provide e /,, A..;i > :A pictorial description of the noture and amount of any sources of water and any collection or treatment measures. s S. For each outfall, provide e description of: (1) All operations contributing wasteweter to the effluent, including process westoweter, sendtery or, cooling water, and storm water runoff; (2) The eterage flow contributed by each operation; and (3) The treetment received try.the westoweter. Continue on additional sheets if necessary. '(' M P V F M *i W 4 s. OUT. R. OPER AT80M(el CONTRheUTfMO FLOW

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4. OPE R ATION Sist) d.

Regeneration wastes O OR MCD Nauernli7nd 7 K 101 from condensate cont. demineralized system e. Turbine Building 1.374 MGD None X X floor and equipment l drains which can contain system leakage F. Cooling tower blowdown 45 MGD None 4 A which receives flow from l the following: ^l \\

1. ' Essential raw 6Q BG Chl o ri nntert fnr Aninric 2

F cooling water clam control j l 2. Liquid radwaste 1 0.21 MGD Radwaste system provides 1 F_ ___ treatment system treatment by demineralize-2 J (DSN 104) which tion and evaporation as receives flow from needed the following: l ~ ) i l i 1 Or r ecs AL uss ONLv qaffluent sworknen eub.rategoriest l l COWM M MEW EPA Form 3bl42C (6 80) PAGE 1 OF 4

ge,s n.o. Nuns acopy from kns J of Foms 1) TN5640020504 pom, Acomved Ous uA iss.nof 73 Pirsi print or typs in ths unshIded areas only. u.w. aN V8 ONM E NT AL PHOTecTle N Ao,Nc Y F6RM APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER. J. . gg g ph Lb g EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVI'?JLTURAL OPERATIONS ouirALL LOCATION .. For each otrtfeH, het the latitude and longitude of its location to the nearest 15 seconds and the name of the rTealving water. A.QuT A b D. L ATITUDE _

c. LON GtTUDE (llrry s.eso.

a, u.se, s.sec.

s. osa.

a. u ne, s.sec.

1 J t II. FLOWS, SOURCES OF POLLUTION, AND THE ATMENT TECHNOLOGIES] A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing westoweter to the effluent, and treatment units labeled to correspond to the more detailed descriptions in item B. Construct a water balance on the line drawing try showing everage flows between intakes, operations, trestrnent units, and outfalls. If a water belance cannot be determined (e.A or coreslo m/n/ng,artMeles/, provide a f pictorial description of the nature end amount of any sources of water and any cohection or treatment meneures.. > l1(tV9p wm:sg ;,-t., B. For each outfall, provide a description of: (1) All operations contributing westoweter to the effluent, including process westownter, _ Lp westoweter,, cooling water, and storm water runoff; (2) The everage flow contributed by each operation; and (3) The treatment recelyed trir the vesseeegator. Continue A 9 @d 4W ft $# ##M ' ' ' on additional sheets if necessary. g, pyy.

a. OPFR AT80N(e) CONTRIBUTf MG FLOW

h. TRE ATeAEN7%. ai*vt Waei c #

o e 09:RAr ON0u0

• • y,",35,*ft,$ *

e. ossem, Teen Qeju,$Y'y,@.j a* **

'^ Yo" a. Laundry and hot 0.0003 MCD shower drains 101 cont b. Radioactive floor 0.014 MGD drains and sumps l c. Chemical drains 0.1737 MGD d. System leakage 0.018 MCD l 3. Regeneration wastes _0.08 MGD Neutralized 2 K from condensate l 4 A demineralizerJ / stem ' (DSN 105) 4. Steam generator 0.86 MGD None 4 A blowdown (DSN 106) 5. Condenser cooling 1600 MGD Cooling by naturM drnfe Y Y water (helper and .,g. poling towers 4 A closed modes) G. Raw cooling water Rone 4 A (open mode) wrraca AL use oNov w/fiuent guanhnes sus.coregonen CONTINUE ON REVERSE EPA Form 351@2C l640) PAGE 1 OF 4

EPA s.O. Num ER tcopy from itsm J of form Al w Pinse pnnt or woe en th3 unsh&ded arets oniv. TN5640020504 form Approved aus No. f ss.nof 73 u.s. EN V tuCNMENT AL PMeT EC TluN Am E NC Y FORM APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER th 2 g EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPERATIONS OUTFALL LOCATION, For each outfall, list the latitude and longitude o* its loration to the nearest 15 seconds and the narne of the seeiving water. A-u A L g, Laygygog c, Longgygog Nu flarr)

e. one, s....

a.ess,

s. oss.

a. es m.

3.see. l l 4 i II. FLOWS, SOURCES UUOLLUTION. AND TREATMENT TECHNOLOGIES] A. Attach a hne drawing showing the water flow through the facility. Indicate sources of Intake water, operations contributing westoweter to the effluent, and treatment units labeled to correspond to the more detailed descriptions in item 8. Construct a water belance on the line drawing by showing everage i flows between intakes, opere. ions. treatment units, and outfalls, if a water belance cannot be determined (sp, for cordelspletng pqMWes/, provide a pictorial description of the nature and amount of any sources of water and any collection or tnestment measures. ~ ' Wedw wpp;,q

8. For each outfall, provide e description of: (1) All operetsons contributing westeweter to the effluent, including process westoweter, eerdtery As. ster, cooling water, and storm water runoff; (2) The everage flow contributed by each operation; and (3) The treatment received trir.ths wesesequier. Continue 8

~ ' >*'d* N L W M W W/ % ' on additional sheets if neccesery. f. OUT.

2. OPER AT4CNISI CoNTRiouf f 84G PLOW

$. TR E AyM ENT54 i,W6U M " j L I N. a B Mita)

8. DESCRIPTION

• rg

( f)

3. OPE R ATION (ljsf)

Recycled cooling water 1607 MGD Cooling by natural draft X X (closed mode) would receive cooling towers 4 A flow from the following: l .A. Condenser coolinn water 1510 MGD Cooling by natural draft l l cooling towers l l B. Essential raw cooling 60 MGD None 4 l A water C. Raw cooling water 37 MGD Mixinn with CCW coolinn 1 0 by towers X X 4 A 7 i Sewage treatmentylant ^l85,000GPD 25,000 and septic tank sand 1 T __ filter system: two 1 U 30,000 gpd extended aeration 1 y plants: chlorination sludge l 2 F disposal by contractor 3 A 3 C 5 l A 5 B 4 A 116 CCW intake trash sluice 100,000 GPD None 4 A W raCs AL uss oNLY (tf[jutnf guldthnte sub categongs) EPA Form 3510 2C (6 80) PAGE 1 OF 4 CONTINUE ON REVERSE u_-__--_-_-___-___________

EPA s.o. NumaLatcopy from item J of form )) TN5640020504 porrn Agoroved aus No. rss.nor73 Plus2 pr,nt or type in the unshadtd arsas oniv. u.s. uM veMs NM ENT A L PROT EC TION Ag E NCY FORM APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER A

2p g EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURAL OPER ATIONS g

Neoss 1s Consolidated Permits Program For each outfell,hst the latitude end longitude of its location to the neerest 16 seconds and the nome of the (WCeiving water. A. ou A L

e. L A YgTuDE C. LONGITUDE flirr) s.ose,

s. w ise.

a.sec.

e. oss.

s, m m. e, se c. 4

11. FLOWS, SOURCES OF POLLUTION, AND 78 A. Attach a line drowing showing the water flow through the facility, indicate sources of intake water, operations contributing vestoweter to the effluent, i

and treatment units labeled to correspond to the enore detailed descriptions in item 8. Construct a water balance on the line drawing by showing everage flows between intakes, operations, trestrnent units, and outfalls if a water balance cannot be determined (e.g, for certain fnlidng MIMeisef, provide a pictoriel description of the nature end amoun.' of any sources of water and any collection or treatment measures, i M W cy., m *rn ++ B. For each outfall, provios a description of: it) All operetsons contributing westoweter to the effluent, including process westenuter, sanitary westoweter,, cooling water, and storm water runoff; (2) T se everage flow contributed by each operation; and (3) The treatment received by the weseenster. Continus - ' W*~ t.NVi *% . on additionel sheets if necessary. 9.007

1. OPE R AttoNIS) con) BleUTING FLOW

3. TRE ATMENT~ s NNAsl4Laf 4 4

'[- lb Ah c.$

e. DESCRIPTION (list)

. a. OPER ATioH (!!st) '

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ERCW screen and strainer 43,000 GPD None 4 A backwash 117 l .p.. - brF F4GI AL uSL OHLY (effluent Fundeimes sub eategorses) CO E ON MME EPA Form 3b10-2C 66 80) PAGE 1 OF 4

CONTINUFO FRoM THE FRONT 'C. Except for storm runoff, leeks, or epitis, are any af the discharges described in items li A or B intermittent or seasonel? @YEs'teomplete the fo%nning te>Je) D HO tee to Beetion !!!)

1. FREQU ENCY

4. FLOW 8

5.OUTFALL }, ' 3, SPER ATION[#) '

s. Dave b.MO'NTNS

( eI C D U R* g, g NUMBER CONTRIBUTING FLOW PER wEtn PERvtAR 3 7,,, [fuf) [l&f) tspeelfy .'specify a "s ma.s am s.mamem.eu

s. mamem,.as (I days)

L o

g. bone.som oversteJ overess) v ss omst avanaam e

man 107 Metal cleaning waste as Frequency and duration cannot e pred eted necessary; various plant from past. Ra inwater 'ollect in the ponds systems are cleaned / flushed and muut be di scharged approxi ately times using any of the following: per year. hydrazine, citric acid, EDTA, ammonium bifluoride, phosphoric acid, oxalic acid, hydroxyacetic formic acid, corrosion inhibitors, sodium permanganate, nitric acid, hydrochloric acid and hydrofluoric acid. lit. MAXIMUM PRODUCTI A. Does an effluent guideline limitotion promulgated by EPA under section 304 of the Clean Water Act apply to your facility?, ~> ~' ' " < ' ' ~ ' ONO tta to 8ection !V) Y,$},h ? $; f @ v ns (complete llem Hi-R) B. Are the omitations in the appliable affluent guideline expreened in terms of production (orodpermeasure of sperysdonJF ,Q B NO too to Baetton IV).; isY s &"' %; V ';h_ q. 1 Ih'

• Qvts (complete item !!! C).,' l.T..,

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c. if you en.ws,ed ves to item iii-8,iisi the ou.ntity which represents on.ctuoi measurement o, you, me imum ie,ei of p,oduction...,,sessa in tre te,me,

.nd unas uesd en the.ppn ebis offiueni guiden,.nd indicate the effectad outf.n..

8. M AMIMUM QU ANT 87Y

g - n ~

lu,, *, eve',,^=e,,, j ... A m. -.e.... g.m e.e u.a i N/A I IV. IMPROVEMENTS] I A. Are you now recit red by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operation of waste-i water treatment equipment or practices oct any other environmental programs which may effect the discharges described in this application? This includes. l but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipuistions, court orders, and grant

• 'I*****"d****

QvEs tcomplete the folloiving table) 3 NO too to item IV B)

1. 8DENTIFIC ATION OF CONDITION,

2. AFFECTED OUTP ALLS sk@$lPN[l AO RE EM EN Y. ETC.

g,,,,,,,,,,,,,,,,, _og. N/A 1 1 B. OPTIONAL: You may attach additional sheets describing any additional water ponution control programs (or other environments / pro / sea swhkh may affect l your discharpet) you now have underway or which you plan, indicate whether each program is now underway or planned, and indicot. your actual or ] pionned schedu'es for construction. @M Anet ax" IF DESCRIPTION OF ADDITION AL CONTROL PROGR AMS IS ATTACNED 1 l EPA Form 3510 2C (6-80) PAGE 2 OF 4 CONTINUE ON PAGE i

IV.B.' Additional Control-Programs 1 l'. The existing sewage treatment facilities'are being consolidated and the treatment capacity. expanded to 85,000 gpd.- The discharge is being rerouted from the yard. drainage pond to the intake forebay. These changes:should be c'ompleted before the existing NPDES permit expires.- This permit application was prepared accordingly.- - - - - - -. - - -. - - - - - _ - ~. - - _ _

I ._. -.m LP,k $.D. NuMLE HlC091 frVM lihm J Of EOrm 1) TN5640020504 ,,,, pop,,,,g o ug y,ggg.gogy3 CONTINUEo MOM PAGE 2 j r A, B, & C: 1 See instructions before proceeding - Complete one set of tables for each outfoli - Annotate the outfall purnber in the spece provkied. I NOTE: Tobles V A,V 0, and V C are included on sep$ne sheets numbered V 1 through V4 9f

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] 8 D. Use the space below to list any of the pollutants listed in Table 2c 3 of the instructions, which you know or have reason to believe is discherged or mey be discharged from any outfelt. For every pollutsnt you list, briefly describe the reasons you believe it tobe present and report eng anstytical dato in your possessson. e, POLLUT ANT 1.bOURCE

s. POLLUTANT o.oOURCE I

Asbestos -Wet laundry of worker's clothing involved in }l asbestos stripping / i handling ope. rations. Discharge would be -l' through radwaste system. (note: currently use 't dry cleaning contract) a I -Shower fecilities (insulator shovers) provided for workers involved in asbestos i stripping / handling operations. Discharge .~ approximately 100 gpd to vard drainn VI. POTENTIAL DIRCHARGES NOT COVsERED BY ANALYSIS A. is arty pollutant listed in item VC e substance or a component of a substena whichi you do or expect that you will over **ie next 5 years ues or manufacture - -- b-,* v% h mka m e w + ~Zfr(*. w v T't. W.~ + +'-- $e&y n:n intermediate or firsi product or byproduct ( .. &a e n? Y v.. m *e ' w fV 4 )'*sf:Qor.< > es o

WhiW W)Ch@I WW 2L'G

^)Y c 1 > G y. w, 2, uqu. ,yg gg y gg.ggyy; N/A -] l B. Are your operations such that your row meternels, processes, or products an 6eesonebiy be expected to very so that your discharges of poHutants rney deraq the next 5 years exceeJ tw;o times the mounc.m weaues reported in tsam VF i. D v ns (compiere item VIC below) @Ho too to Sections V5) ~ ' C. If you enswomd "Yes" to f tem VI.0, explain below and describe in detail the sources eral expected levels of such poitutents whitti vou enticipate will be Axterged from each outfelt ovrr the rext 5 years to the best of your abstity at this time. Continue on addstional sheets if you need more space. _ -7.u: N/A l { l l l CONTINUE ON REV EPA Form 35142C (6-80) PAGE 3 OF 4 I 1 ]

. i CONTINUED FROM THE FRONT - Vll. ClOLOGICAL TOXICITY TESTING DATA 9 Do you have any knowledge er reason to believe that e.1y biologic t test for acuts or chronic thicity has been made on entry your discharges or a e g" l receiving water in ' elation to your tuscharge within the last 3 years?. '"-d# '., ."Z l ^ i r 1+5, ...A P i Q YEs (identify the test (s) and desenbe thelqurposes belowl D No (se to Bection Vi!!) h4 l t i l i J J l j i i t 1 i l J l 1 l 1 1 e' k * ' I VillCONTRACT ANALYhtSINFORMATION I i ~ l t%sre any of the snelyses reported in item V performed oy a contract laboratory or cois/ ting firm? 22 a. v ,,,, ;.f. 44 ~Y. N Q v Es (list the name, address, and telephone num ber of, and pollutants Q NO (so to Bsat6on EX) analysed by, each such leboratory or firm below) 1 "c$ [n A. N AM E B. A DDRES5 ( J Analytical Industrial 153 Warehouse Mart. (615) 894-8102 Total phenol Research Laboratory Chattanooga, TN 37421 cyanide IX.CF. RATIFICATION 9', s aN l certify under penalty of law that I haw permnally examined and am familiar with the information submitted in this applicatiert udaRf attachments and that, based on my inquiry of those individuals immediately responsible for obtaining the informatiott, I believe that the W formation is ttve, accurate and complete. I am aware that there are sigr'ificant penetties for submitting false information, incluksq the) possibility of fine and imprisonment. ~u[*{ A. N AM E ik OF FICI Al. 78 TLE (type or print; S. PHON E NO. forea code a no.) Martin E. Rivers Director of Environmental Quality (615) 632-6578-s C. SIGN ATU RE D. D ATE SIGNED 1"ng'* OCT 1 1987 EPA Form 35104C (6-80) P AGE 4 OF 4 4

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_ l TVA Laboratory Branch Chattanooga, TennerreeJl l 09/15,'87 FINAL DATA REPORT 14:28 l

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l ' Lab' Sample-Number i.87/10577 Project Leader David M, Verne11 Sample ID Information BLAltK-IC, NPDES' PRIORITY Sample commentz

SOH HPDES PERMIT REHEWAL Sample type / matrix WATER Sample collected by

F0E Sample collection date 870820 Sample.togin date

870821 Sample account number

234G-765071-11 l

Alt..IDC l Analysis Performed j reruit l units l 34694 Phenol <5 ug/L-34586 2-Chlorophenol <5 ug/L 34283 Bis (2-C11sopropyl>cther <5 ug/L' 34591 2-Nitrophenol .< 5 ug/L l 34606 2,4-Dianthylphenol <5 ug/L 34601 2,4-Dichlorophenol <5 ug/L 34452 4-Chloro-3-methylphenol < 30 ug/L 34621 2,4,6-Trichlorophenol < 20 ug/L i 34616 2,4-Dinitrophenol < 20 ug/L 34646 4-Nitrophenol < 30 ug/L 34657 4,6-Dinitro-o-cresol < 30 ug/L 34433 N-Nitrosodiphenylamine < 5 ug/L 39032 Pentachlorophenol <.30 ug/L 34566 1,3-Dichlorobenzenc <5 ug/L 34571 1,4-Dichlorobenzene <5 ug/L 34536 1,2-Dichlorobenzenc <5 ug/L 34273 Bis (2-chloroethyl> ether <5 ug/L 34396 Hexachloroethane <5 ug/L' 34447 Hitrobenzene <5 ug/L 34428 N-Hitrosodipropylamine <5 ug/L 34408 Isophorone <5 ug/L 34278 Dis ( 2-Clethoxy >methanc <5 ug/L 34551 1,2,4-Trichlorobenzene <5 ug/L~ 34696 Naphthalene <5 ug/L 39702 Hexachlorobutadiene <5 ug/L 34386 HexaC1cyclopentadiene <5 ug/L 34581 2-Chloronephthalenc <5 ug/L 34200 .Acenaphthylene <5 ug/L 34341 Dimethyl phthalate <5 ug/L 34626 2,6-Dinitrotoluenc < 5 ug/L 34205 Acenaphthene <5 ug/L 34611 2,4-Di n i t. roto l ucne <5 ug/L 34381 Fluorene <5 ug/L 34641 4-Chlorodiphenyl ether <5 ug/L 34336 Dicthyl phthalate <5 ug/L 34636 4-Bromediphenyl cther <5 ug/L 39700 Hexachlorobenzene < 5 up/L 34461 Phenanthrene <5 ug/L '34220 Anthracene <.5 ug/L 4

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l: TV4 Laboratory Branch Chattanooga, Tcnnessec l l 09/15/87 FIHAL DATA REPORT 14: 29 l

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39110 Dibutyl phthalate < 5 ug/L 34376 Flucranthene < 5 ug/L 34469 Pyrene < 5 ug/L 39120 Benzidine < 50 ug/L 34292 Benry1buty1phthalate <-5 ug/L 34526 Benzo < a ) anthracene < 5 ug/L 34320 Chrysene < 10 ug/L 34631 3,3'-Dichlorobenridine < 25 ug/L 39100 Bis (2cthylhexpl)phtblate 6 ug/L 34596 Dioctyl phthalate < 10 ug/L 34230 Benzo fluoranthene < 10 ug/L 34242 Benzo < k )fluoranthenc < 10 ug/L 34247 Benro< a > pyrene < 10 ug/L 34403 Indeno( 1,2,3-cd > pyrene < 10 ug/L 34556 Dibenro<a,h) anthracene < 10 ug/L 34521 Benro< ghi >perpienc < 10 ug/L 34438 N-Nitrosodimethylamine < 5 ug/L 34030 Denrenc < 10 ug/L 32101 Bromotrichloromethane < 10 ug/L 32104 Bromoform < 10 ug/L 34413 Bromomethane < 10 ug/L 32102 Carbon tetrachloride < 10 ug/L 34301 Chlorobenzene < 10 ug/L 34311 Chloroethane < 10 ug/L 34576 2-Chloroethylvinyl ether < 10 ug/L 32106 Chloroform < 10 ug/L 34418 Chloromethane < 10 ug/L 32105 Dibromochloromethane < 10 ug/L 34496 1,1-Dichloroethane < 10 ug/L 34531 1,2-Dichloroethane < 10 ug/L 34501 1,1-Dichloroethylene < 10 ug/L 34546 transt,2Dichloroethylenc < 10 ug/L 34541 1,2-Dichloropropanc < 10 ug/L 34704 cis-1,3-Dichloropropene < 10 ug/L 34699 trans-1,3Dichloropropene < 10 ug/L 34371 Ethylbenzene < 10 ug/L 34516 1,1,2,2-TetraClethane < 10 ug/L 34423 Methylene chloride 19 ug/L 34475 Tetrachloroethylene < 10 ug/L 34010 Toluene < 10 ug/L 34506 1,1,1-Trichloroethanc < 10 ug/L 34511 1,1,2-Trichloroethanc < 10 ug/L 34488 Trichlorofluoromethane < 10. ug/L 39175 Vinyl chloride < 10 ug/L 39180 Trichlorethylene < 10 ug/L 24210 Acrolein < 100 'ug/L 34215 Acrylonitrile < 100 ug/L l l l 1 _-_--______a

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~ ATTACHMENT I -musammmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmmm 9 . -j 1 c ..jiTVA' Laboratory Branch) ' Chattanooga, TennesseeLl j ~' l:09/15/87L FINAL DATALREPORT 14:29Jl ammmmmmmmmmmmmmmmmmmmmmmmmmmmmmmma'ammmmmmmmmmmmmmma Page -1'm======== .LabSample. Number. 87/10570' . Pro, ject Leader 11: David M; Varnelli ? Sample ~ID Information

SLANK-101, NPDES PRIORITY

.i . Sample comments

JSQH'HPDES.PERNITIREHEWAL;

) d .Sampleftype/matrixf

' WATER

. Sample' collected by JF0E: j . Sample collectionLdate-870820L L 'i Sample login date.

T670821

~ Sample account number.

234G-765071-11 i

.l - Alt. IDC l . Analysis. Pert'ormed l' ' result' ll Lunits; 'li -34586 2-Chlorophenol <.5 ug/L 34601: 2,4-Dichlorophenol:

< 5' ug/L R

.34606-2,4-Dimethylphenol. <.5. Jug /L 'd 34657 14,6-Dinitro-o-cresol. E< 30 ug/La j 34616 2,4-Dinitrophenol < 20 .ug/L: W '34591 '2-Nitrophenol .< 5: ug/L ~ l! l 34646' '4-Hitrophen'o11 .< 30: ug/L' lj 34452 4-Chloro-3-methylphenol <L30 ug/L: l <.30 Lug /Ll 39032 Pentachlorophenol. 7< 20 ug/L-g 34621 2,4,6-Trichlorophenol 34694 Phenol. <5 'ug/L j 34566 1,3-Dichlorobenzene < :5 ug/L' 34571 1,4-Dichlorobenzene- <5 ug/L 34396 HexachloroethaneL .<'5 .ug/L 34273 Bi s( 2-chloroethyl > ether _ <5

ug/L' 34536 1,2-Dichlorobenzene

<'5-ug/L 34283 Bis ( 2-Clisopropy1 > ether < 5-ug/L. j 34428 H-Hitrosodipropylamine <. 5 ug/L j 34408 Isophorone <5; ug/L 4 34447 Hitrobenzene <5 ug/L; 39702 Hexachlorobutadiene. < 5-

ug/L j

1 34551 ~1,2,4-Trichlorobenzene <5 ug/L. 34696 Naphthalene <5 ug/L .5 ug/L. 34278 Bi s( 2-Clethoxy > methane 34386 HexaC1cyclopentadiene < 5 ug/L 1 34581 2-Chloronaphthalene. <5-og/L 1 34200' Acanaphthylene- <5 ug/L l l 34205 Acenaphthene < 5 -ug/L) ') .34341 Dimethyl phthalate -< 5 og/L 34626 2,6-Dinitrotoluene <5 Lug /L 34361 Fluorene- < 5 ug/L-34641 4-Chlorodiphenyl ether < 5_ .ug/L 't 34611 2,4-Dinitrotoluene. <5 Lug /L' 1 34336 Diethyl phthalate < 5 ug/L' l 34433 H-Nitrosodiphenylamine < 5 ug/L 39700 Hexachlorobenzene < 5 ug/L. l 34636 4-Bromodiphenyl ether <5 ug/L 34461 Phenanthrene <.5 ug/L 347:20 Anthracene <5 ug/L i 1' f = -

1 ATTAQWENT I

===u===============================an======n==u===========

s l TV4 Laboratory Branch Chattanooga, Tennessee l l 09/15/87 FINAL DATA REPORT 14:29 l

=================================================== Page 2

====e

39110 Dibutyl phthalate < 5 ug/L 04376 Fluoranthene < 5 ug/L 34469 Pyrene < 5 ug/L 39120 Benzidine < 50 vg/L 34292 Benzylbuty1phthalate < 5 ug/L 39100-Bis (2cthylhexy1)phtblate < 5 ug/L 34320 Chrysene < 10 ug/L 34526 Benzo < a) anthracene < 5 ug/L 34631 3,3 '-D i chl orobenzi d ine < 25 ug/L 34596 Dioctyl phthalate < 10 ug/L i 34230 Benzo < b )fluoranthene < 10 ug/L 1 34242 Benzo <k)fluoranthene < 10 ug/L 34247 Benzo <a> pyrene < 10 ug/L 34403 Indeno( 1,2,3-cd > pyrene < 10 ug/L 34556 Dibenzo<a,h> anthracene < 10 ug/L 34521 Benzo <ghi>peryiene < 10 ug/L 34438 H-Nitrosodimethylamine < 5 ug/L 34030 Benzene < 10 ug/L 32101 Bromotrichloromethane < 10 ug/L f 32104 Bromoform < 10 ug/L 34413 Bromomethane < 10 ug/L 32102 Carbon tetrachloride < 10 ug/L l 34576-2-Chloroethylvinyl ether < 10 ug/L I 32106 Chloroform < 10 ug/L ] 34418 Chloromethanc < 10 ug/L 1 32105 Dibromochloromethane < 10 ug/L 34496 1,1-Dichloroethane < 10 ug.'L 34531 1,2-Dichloroethane < 19 ug/L 34501 1,1-Dichloroethylene < 10 ug/L 34546 transt,2Dienloroethylene < 10 ug/L 34541 1,2-Dichloropropane < 1 'O ug/L 34704 cis-1,3-Dichloropropene < 10 ug/L 34699 trans-1,3Dichloropropene < 10 ug/L 34371 Ethylbenzene < 10 ug/L 34423 Methylene chloride 14 ug/L 34516 1,1,2,2-TetraClethane < 10 ug/L 34506 1,1,1-Trichloromethane < 10 ug/L' 34301 Chlorobenzene < 10 ug/L i 34311 Chloroethane < 10 ug/L 34475 Tetrachloroethylene < 10 ug/L 34010 Toluene < 10 ug/L 34511 1,1,2-Trichloromethane < 10 ug/L 34488 Trichlorofluoromethane < 10 og/L 39175 Vinyl chloride < 10 ug/L 39100 Trichlorethylene < 10 ug/L 34210 Acrolein ( 100 ug/L 34215 Acrylonitrile < 100 vg/L

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.i 1 1mmmmmmmm=====m==na=mmmmmmmmmm==mummma==umesmannammmmmacammmmmmmmmumuna lcTV41 Laboratory:Becrich Chattanooga, Tconessee 1 l l' 09/15/87 FINAL DATA REPORT -14:30 ):

============================================= Page' 1-===

j Lab Sampic Number : 87/10579 Project Leader 11' David N'. Varn(11 1 1 ' Sample'ID Inf~ormation i BLANK 112, HPDES PRIORITY. Sampic commentz i SSQH'HPDES PERMIT RENEWAL Sample typc/ matrix

WATER q

Sample. collected-by ..: F0E R Sample" collection date i 870820 l Sample login_date'

870821 Sample? account number

234G-765071-11 l

Alt..IDC l Analysis Performed l result' l: units l l 34596 2-Chlorophenol < 5 ug/L .j l 34601 2,4-Dichlorophenol < 5 ug/L j 34606 2,4-Dimethylphenol 5' 'ug/L 34657 4,6-Dinitro-o-cresol < 30, ug/L 34616 2,4-Dinitrophenol < 20 ug/L l 34591 2-Nitrophenol <5 ug/L l 34646 4-Hibrophenol < 30 ug/L j 34452 4-Chlore-3-methylphenol < 30 ug/L 39032 Pentachlorophenol < 30 ug/L-34621 2,4,6-Trichlorophenol' < 20 ug/L-34694 Phenot <5 ug/L 34566 1,3-Dichlorobenzene- < 5' ug/L l 34571 1,4-Dichlorobenzenc <5 ug/L 34396 Hexachloroethane <5 ug/L 34536 1,2-Dichlorobenzenc < 5 ug/L 34428 N-Nitrosodipropylamine <5 ug/L 34447 Hitrobenzene 5' ug/L [ 34696 Naphthalene <5 ug/L 34200 Acanaphthylene. <5 .ug/L-L 34273 Bis ( 2-chloroethyl > ether < 5 ug/L 34283 Bis (2-C11sopropyl>cther <5 ug/L i 39702 Hexachlorobutadienc <5 og/L 34551 1,2 4-Trichlorobenzene < 5 ug/L ) l 34408 Isophorone methanc <5 .ug/L l 34386 HexaC1cyclopentadiene <5 ug/L 34581 2-Chloronaphthalene < 5 ug/L 34341 , Dimethyl phthalate < 5 ug/L 34641 4-Chlorodiphenyl ether < 5 ug/L 34611 2,4-Dinitrotoluene < 5 -ug/L 34336 Dicthyl phthalate < 5 ug/L 34433 N-Nitrosodiphenylamine < 5 ug/L 39700 Hexachlorobenzene < 5 vg/L 34636 4-Bromodiphenyl ether < 5 ug/L 34461 Phenanthrene < 5 ug/L 34220 Anthracene < 5 ug/L 34376 Fluoranthene < 5 vg/L 39100 Dis ( 2e thylhexp1 >phthl ute < 5 ug/L 34526 Bento<a> anthracene < 5 ug>L y,. -e ._.--.-_.a

=,.: u = = a e m n a a = = = n a a - - - - - a = = n m 6 w = n = = = = = n a u = = a n a n a m a a e a w a a

l TVA L4boratory E: ranch-Chattanooga,.Tennserve l' l 09/15/97, fit 4AL DATA REPORT 14i30fI

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Page-2========= 1 34205 Acenophthene. t 5 ug/L 34626' 2,6-Dinitrotoluene f 5 ug/L 34381 Fluorene i 5 .vg/L; 39110 D1 butyl phthalate < 15 .ug/L .34469 Pyrene' < 5 ug/L 39120 ' Benzidine < 50 'ug/L 1 34292 Senzylbutp1phthalate < 5f -ug/L-34320 Chr ysene < 10 ug/L 34631 3,3'-Dichlorobenzidine < 25' .ug/L 34596 Dioctyl phthalate <- 10. og/L j 34230 Benzo (b>Clucranthenc < 10 ug/L' H 34030 Benzene < 10 ug/L-32101 Bromodichloromethanc' < 10 ug/L 34418 Chloromethane < 10 ag/L' 34501 1,1-Di bloroethylene- <: 10 vg/L. < 10 ug/L- .34699 trans-1:,3Dich1cropropene , < 10 ug/L 34010 Toluene 34210 Acrolein <.1001 ug/L. 34215 . Acrylonitrile < 100 ug/L 34242 Benzo <k)flueranthene < 10 ug/L 34247 Benzo ( a ) pyrene < 10 ug/L ' ) 3 34403 Indeno( 1,2,3-cd > pyrene - < 10 ug/L 34436 H-Nitrosodimethylamine <5 ug/L 32104 Bromoform .< 10 ug/L 1 34413 Bromomethane

< 10 ug/L j

32102 Carbon tetrachloride . < IG .ug/L 34301 Chlorobenzene < 10 ug/L 34311 Chloroethane <.10 ug/L' 34576 2-Chloroethylvinyl. ether < 10 ug/L 32106 Chloroform < 10 u g,'L. 32105 Dibromochloromethane .<- 10 ug/L-34496 1,1-Dichloroethane < 10 ug/L 34531 1,2-Dichloroethane < 10 ug/L 34546 trans1,2Dichloroethylenc < 10 ug/L 34541 1,2-Dichloropropane < 10 ug/L 34704 cis-1,3-Dichloropropene < 10 ug/L 34371 .Ethylbenzene < 10. ug/L 34423 ~ Methylene chloride: 23 'ug/L 34556 Dib'enzo(a,h) anthracene < 10 ug/L 34521 Benzo (ghi>pery1ene < 10 ug/L 34516 1,1,2,2-TetraClethane- < 10-ug/L i 34475 . Tetrachloroethylene < 10 ug/L' 34506 1,1,1-Trichloromethane < 10 ug/L l _ 1,1,2-Trichloromethane < 10

ug/L 34511 34488 Trichlorofluoromethane

< 10 -ug/L i 39175 Viny 11 chloride < 10 ug/L 39180 Trichlorethylene < 10 vg/L 4 4 4 0 - _ _. _ _ _ _ _ _. _ _. _ _.. - _ _. _ - _ _ _. - -. _ _ _ _ _ _ _ _ _ _ _ _ _. - - _ _ _ _ _ _ _ - _ _. - _ ~. _ _.-_.-._--,.-----__--J

i ENCLOSURE 2 DESCRIPTION OF RAW WATER SYSTEMS AND CHLORINE INJECTION AND DISCHARGE POINTS AT SEQUOYAH NUCLEAR PLANT Essential Raw Cooling Water (ERCW) System The ERCW system provides cooling to various safety-related components and systems required for safe shutdown of the plant in the case of an accident._ l Examples of components for which the ERCW system provides cooling include the ] control rod drive cooling water heat exchangers and emergency diesel generator i heat exchangers. The ERCW system is once-through and then discharged to the cold water return channel This system is chlorinated continuously for Asiatic clam control when the river temperature exceeds 600F. Chlorine is injected in the pump pits; therefore,. chlorine can be present in the screen and strainer backwash. 1 1 Raw Cooling Water (RCW) System I The RCW system is designed to remove waste heat (i.e., cool) from j i turbogenerator auxiliary equipment and miscellaneous features in the turbine building. The RCW does not serve a nuclear safety function. Examples of l equipment the RCW cools include turbine lube oil coolers, hotwell pump motor bearing oil coolers, and nitrogen compressor coolers. The RCW is a once-through system. Water is withdrawn from the condenser circulating water I system upstream of the condenser and is returned to the plant condenser circulating water system downstream of the condensers but upstream of the i condenser cooling water discharge channel. This system is chlorinated continuously when the river temperature exceeds 600F, l Condenser Circulating Water System The condenser circulating water system is designed to remove heat from the main plant condensers. The condenser cooling water (CCW) flows to the CCW discharge channel, then depending on the mode of operation is discharged. In open mode, discharge is to the diffuser pond then to the river via the diffuser system. In helper mode, the CCW is pumped over the cooling towers and through the cold water return channel to the diffuser pond for discharge to the river as in open mode. In closed mode, the CCW is pumped over the cooling towers and through the cold water return channel to the intake forebay. In closed mode, water is also discharged from the CCW discharge channel via cooling tower blowdown. (Note: In open mode the ERCW discharges from the CCW discharge channel via the blowdown line.) Blowdown is discharged to the diffuser pool then to the river via the diffuser. Makeup to the CCW system must be provided to compensate for the water loss associated with evaporation from the cooling towers and blowdown. The CCW is not a safety-related system. This system is not chlorinated at this time, but provisions are available in case chlorination should be needed in the future.

] o l Raw Service Water (RSW) System The.RSW system provides water for the high-pressure fire protection; system, the makeup water filtration plants, and miscellaneous nonpotable uses within

l the plant, such as hose connections for floor washdown, etc.

It'is not a j 8 safety-related cooling system. RSW generally is. routed through floor drains to building sumps _where it.is then discharged to either the low volume waste treatment: pond or the yard drainage pond..This. system'is not chlorinated directly but is supplied by the raw cooling water system'which is' chlorinated. 1 );i High Pressure Fire Protection System This system provides fire protection'for the site. -This' system is' supplied by -) a line from'the CCW intake pumping station and.the'RCW system. The.line from ] the CCW pumping station is chlorinated continuously when the river temperature exceeds 600F. The system is' pressurized.at all. times by.the RCW system. System pressure is boosted during' emergencies and testing by starting a fire i pump in the CCW pumping station..This usually results in an overflow lwhich discharges to the CCW trash sluice. This. overflow can have a chlorine residual. 1 1 i 0140D l i h____.__m.m.____m_..- ...-_,.m,__._

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) ENCLOSURE 3 BORON SOURCES AND DISCHARGES Boric acid is used as a chemical neutron absorber in the reactor coolant system for reactivity control and to provide borated water for safety injection. During reactor operation, changes are made in the reactor coolant boron concentration for the following conditions: 1. Reactor startup - boron concentration must be decreased from shutdown concentration. 2. Load follow - boron concentration must be either increased or decreased following a change in load. 3. Fuel burnup - boron concentration must be decreased to compensate for fuel burnup and the buildup of fission products in the fuel. 4. Cold shutdown - boron concentration must be increased to the cold shutdown concentration. 1 The concentration of boron in the reactor coolant system varies from 0 to 2300 parts per million (ppm) depending on core life. j x The boron concentration is controlled through the Chemical and Volume Control l System (CVCS). The CVCS consists of several subsystems: the charging, letdown, and seal water system; the chemical control, purification, and makeup system; and the baron recovery system. The major components of these systems as they relate to the potential boron release paths are show in the attached I figure. The boric acid is stored in boric acid tanks at a concentration between 20,000 and 22,000 ppm boron. The boron concentration in the reactor coolant system is varied by feeding makeup water from the primary water storage tank and the boric acid tanks as needed to reach the desired concentration. Excess liquid effluents from the reactor coolant system which can contain 0 to 2300 ppm boron are diverted (referred to as letdown) to the CVCS holdup tanks. Water from the CVCS holdup tanks can be processed as a batch through the boric acid evaporators, where the boron is recovered and returned to the boric acid tanks. The distillate from the evaporators which can contain 10 to 100 ppm boron is either: (1) returned to the primary water storagt tank; (2) treated in the condensate demineralized waste evaporator; or (3) released to CVCS monitor tank for release to the cooling tower blowdown line as part of liquid radwaste discharge (DSN 104). Water from the CVCS holdup tanks may bypass the boric acid evaporators and be released to the CVCS monitor tank by routing it to the tritiated drain collector tank. The decision to bypass the boric acid evaporators depends on the storage capacity available for the concentrated boric acid and the condition of the boron. With time, the capacity of the boron to absorb neutrons is consumed and it must be removed from the system. Water containing boron can also be released to the CVCS monitoring tank for release to the cooling tower blowdown as a result of system leakage and flushing operations which are directed to either the tritiated drain collector tank or the floor drain collector tank. The steam generator blowdown can also contain up to 10 ppm boron.

k' 'The maximum concentration of boron that can be present in the liquid radwaste system release is estimated to be 200 ppm. For the NPDES permit, TVA requests that no effluent limitation or monitoring requirements be placed on boron dischage from SQN. The maximum release rate from the liquid radwaste system (LRS) is 125 gallons per minute (gpm). The LRS releases through a valve which is controlled by a radiation monitor and flow meter. This valve is designed as an interlocking device which will not open unless the radiation activity is within limits specified by the Nuclear Regulatory Commission and the flow rate of the receiving waste stream (cooling tower blowdown) is at least 15,000 gpm. This will result in a boron concentration of less than 2.0 ppm in the cooling tower blowdown. l l 1 1

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i l ENCLOSURE 4 CHEMICAL ADDITIONS BY DISCHARGE l r l Discharge Chemicals Added DSN 101, Diffuser Chlorine, hydrar.ine, boron, lithiun, sodium and phosphate cleaning agenhs DSN 102, Yard Drainage Pond Chlorine, hydrazine, horon, ifthium, oil and grease DSN 103, Low Volume Waste Treatment Chlorine, hydrazine, boron, lithium, oil and grease 4 DSN 104, Liquid Radwaste Boron, lithium, oil and grease, phosphate l DSN 105, Condensate Demineralized Boron, lithium Regeneration Water DSN 106, Steam Generator Blowdown DSN 107, Metal O'eaning We.Vte All metals, mdinly Fe, Cu; caustic and acid; sodium, phosphate, hydrazine (See form 2C, page 2, part II.C for f additional chemicals that may be added.) l l DSN 110, Recycled Cooling Water Chlorite l s DSN 112, Sewage Treatment Plant Chlorine, organic matter l DSN 116, CCW Intake Trash Sluice Chlorine DSN 117, ERCW Screen and Strainer Chlorine Backwash l Additional Chemical Usage Ethylene glycol is used as a heat transfer medium in the ice condenser system j and in the diesel generators. Small quantities may be leaked to DSNs 101-104. Most leakage is drummed and transported out for use as a dust suppressant on roads or disposed of in the sewage system. Hydrazine, ammonia, sodium molybdate, sodium tolyltriazole, and lithium hydroxide are added to the primary and secondary water systems to control pH and corrosion. These could end up via leakage or blowdown in DSNs 101-107. Culligan C-321 and M-3008 are added to the Office and Power Stores Building cooling system which can end up in DSN 102 (and 101) via leakage and blowdown. These are trade compounds for pH and algae control. i' 1 .__ _--_ f

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'u (/ [< 'b 6' } a is q f.' ) ( l sNCL0St!hX 5 + i l'. '& 7/ / BESCRTY7 ION OF PROGRAM ./ TO CONTROL 0 MICROB;AdE INFLUENCED CdRROSION / { s Microbially Influenced Corrosion (MIC) has beet. identified in the raw" water systems piping for Sequoyah Nuclear Plant. Microbially influencedscorde/d ( z damage in the stainless steel portions of the piping systems has resuited in N thru-wall leaks. At the present time, the only water treatment prycticed is the use of sodium hypochlorite basically for control of Asiatic c3am or Corbicula (sea enclosure 2). This treatir.ent is not suf ficient for[diowth '1 inhibition c'i the microbial populations in the raw water systems. TVA is investigating'vethods for treating the various water. systems to control MIC. l One method Jthat.f apper.rs promising is the use of a bromine / chlorine i biodispersant. ( 3 s c 4 Biocide efficacy studies performed on the biological sprtrum in ';be, raw water systema have} indicated that a biodispersant, which coad ins brominc, mdy b m the capab'ility to prevent growth of the microbial p.>pulation and f rednt the spread of sessile corrosive hacteria to other sensiti.cd areas..The( l biodispersant would also coatain sodium hypochlorite. It would be fed cia continuous basis the year taand. Organics and pH of I V water suppress the effectiveness of sodiutr hypochlorite s. lone. The brotrih# mte;:erial af fords higher effectiveness at higher pH. / l l TVA requests that the new permit allow for the use anJI discharge of bromine. l / 6 l l i Tf t 3 l i 't Ii A n 'l I, - ) j

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,si ) i 1 / j N ENCLOSURE 6 ey. '(- -QUALITY PROGRAM FOR VERIFICATION OF j ( SEQUOYAH NUCLEAR PLANT THERMAL COMPUTED COMPLIANCE SYSTEM l ) l

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Tennessee Valley Authority Office of Natural Resources and Economic Development Division of Air and Water Resources Engineering. Laboratory QUALITY PROGRAM FOR VERIFICATION OF SEQUOYAH NUCLEAR PLANT THERMAL COMPUTED COMPLIANCE SYSTEM Report No. WR28-3-45-134 I l I l 1 1 Prepared by Peter Ostrowski, Jr. and Ming C. Shiao i Norris, Tennessee September 1987 1 1

EXECUTIVE

SUMMARY

) A system of real-time measurements and computer models is used at Sequoyah Nuclear Plant to verify compliance with the instream thermal limits contained in the National Pollutant Discharge Elimination System permit. Seven field studies were used to validate the diffuser mixing model used in the computed compliance system. The field surveys covered a range of ambient conditions (reservoir flowrate and thermal stratification), seasons, and plant operation. These studies showed that the system adequately reproduces laterally-averaged temperatures in the cross section at the downstream edge of the mixing zone. The State of Tennessee has requested a quality assurance program to include further field verification tests to add confidence to the computed compliance system. Quarterly field surveys are required during the first year af ter st.artup and annually thereaf ter. A quality program has been developed to meet the State's request. The program identifies a variety of possible combinations of ambient reservoir flowrate and seksonal conditions that can exist and l sets priorities for future studies. Additional field surveys are planned that add to the data already taken. The status of Sequoyah Nuclear Plant startup remains uncertain. Therefore, the field verifications cannot be scheduled at this time. Only one unit may operate for the first year. Because the most significant effects of plant operation occur at full two-unit loads, only one survey is suggested during initial one-unit operation. Quarterly studies for a year will be planned after two units are on line. Additional annual field testing will be determined by field l and plant conditions and the established priorities. All field measurement equipment will be calibrated using standard procedures. l l l l ~ _ _ _. _.. _ _ _. _. _ _ _ _ _ - _. _. _

1.0 INTRODUCTION

The thermal discharge from Sequoyah Nuclea-Plant (SQN) is regulated by the water quality standards of the State of Tennessee as 1 implemented in the National Pollutant Discharge Elimination System (NPDES) Permit No. TN0026450. The specific instream permit limitations on the. thermal discharge require that: the plant-induced temperature ] rise should not exceed 5.4'F (3.0*C), the maximum downstream plant-induced water temperature should not exceed 86.9'F (30.5'C), and the maximum rate of water temperature change should not exceed 3.6'F (2.0*C) per hour. These limits are applied at the 5-foot depth outside a mixing zone which is large enough to essentially complete the diffuser-induced mixing. There are several methods that could be used to verify l compliance with the NPDES limits. The effects of power plant thermal l discharges can best be studied using a combination of modeling, ] i monitoring and field study techniques. The studies usually concentrate 1 on past operating data (if available) or evaluations of worst-case conditions. Worst-case modeling studies are later validated using field j studies. The instream temperature limits are converted to a discharge limit that always keeps the plant below the worst-case instream condition ) ever studied. Some power utilities continue to conduct periodic field j studies to check thermal and biological effects in lieu of real-time l monitoring. j Real-time instream monitoring or computed modeling methods for verifying compliance provide flexibility to operate a power plant more in line with the natural ability of a water body to dissipate heat. A l discharge limit that is determined by the worst-case conditions ever seen will significantly affect plant operation during periods when the water body can accept more heat without detrimental effects. The ability to change cooling systems (use of cooling towers) provides added plant efficiency by using supplemental cooling only when it is needed. Instream temperature monitoring has often been used to determine thermal compliance on a real-time basis. There are however several problems with this method. Locating monitors in representative locations

is often difficult due to navigation and recreation constraints. For example, no monitors can be located in the navigation channel on the Tennessee River. This can significantly hamper measurements that are needed in the center of a channel, where most of the thermal' effluent -plume normally goes. The instream monitors can also be significantly affected by natural heating or cooling processes in the water body that produce hotter or cooler temperatures than are actually attributable to the power plant thermal discharge. Natural statistical temperature l variations in time and space also require numerous averaging techniques to make sure the measured data is not catching spurious peaks that are not indicative of actual conditions. In an effort to provide better real-time assessment of the effects of a thermal discharge, a computed compliance method was proposed for SQN. The computed compliance method was seen as providing a more realistic evaluation of the impact of the thermal discharge on downstream temperatures (cross-sectional averages) than a series of instream monitors. The computed compliance method can also be integrated with scheduling needs. The model can be used to schedule plant cooling tower operation and upstream and downstream dam releases as well as used to j verify compliance. This improves the comparison between scheduling and actual operation, and minimizes the number and duration of thermal noncompliance. The remaining sections briefly describe the present thermal I compliance system, the previous field verification of the system, and the { quality program requested by the State of Tennessee. In the State of Tennessee letter (Stewart, 1987), a " quality assurance" program was I required. It was decided not to title this document as " quality assurance" since this connotation implies a program with specific strict requirements that are aimed at nuclear safety applications. This document spells out the steps that will be taken to assure a quality thermal compliance system without the level of detail that a nuclear l safety " quality assurance" program entails. l l i i

2.0 THERMAL COMPLIANCE SYSTEM DESCRIPTION The computed compliance method is the primary system at SQN for verifying compliance with instream limits on the thermal discharge. The system uses a series of measurements as input to reservoir routing and diffuser mixing computer models that calculate the river flow past SQN and the downstream mixed river temperature. Measurements used as input include: releases from the upstream and downstream dams, the amount of heat being discharged (discharge temperature and flowrate), and the ambient temperature as a function of depth. The calculated downstream i mixed river temperature is used to determine compliance with the maximum l temperature limit and rate of temperature change limit. The calculated l mixed river temperature is also used with the measured ambient 1 l temperature at the 5-foot depth to determine compliance with the temperature rise limit. The measurement and calculation process is repeated every 15 minutes for a quasi-continuous real-time demonstration of thermal compliance. A flowchart detailing the thermal compliance I system is shown in Figure 1. In the event the primary computed compliance system is not 1 working, SQN utilizes measured temperature data taken 1,500 feet ) 1 downstream on the left river bank for the downstream mixed river temperature. This data is also measured ever 15 minutes. If both primary and secondary systems fail, field personnel manually collect ) 1 l upstream and/or downstream reservoir temperatures to demonstrate thermal compliance on a once per day basis. Figure 2 shows the layout of monitoring at SQN. 3.0 PREVTOUS VERIFICATIONS A number of field studies were done to validate the computed thermal compliance system. The first field verification of one-unit operation occurred during July 1981 (McIntosh, et al., 1982). The study was done at full unit load during a reservoir flowrate of about 27,000 cubic feet per second (cfs). The reservoir was thermally stratified

q [7 j j i -l during the field survey. The results showed reasonable agreement betweenL the diffuser model and the field data.- Any' differences-showed that the' model'was conservative. That is, measured dilutions-in the river'were ] greater.than the model predicted. Further field studies were done in 1982 and'.1983 to' characterize-two-unit cperation (McIntosh, et al., 1983).. The studies covered a-L number of' seasons and flow conditions as shown in Table 1. The further surveys indicated that'under the conditions studied.' d the instream monitoring or the computed complianc'e. method was adequate for obtaining a~ representative temperature at the edge of the mixing zone. Ilowever, the computed compliance. method more favorably compared i with laterally-averaged temperatures measured'in the' reservoir. The added advantages of using the computed compliance method made.it the system of choice. I Additional data comparing the instream monitoring with the-computed compliance method is available-for the period after installation of the computer system until the plant went offline in 1985. This data has been evaluated and a report is in' preparation (Ostrowski and Carpenter, in preparation). Comparisons between computed and: measured data show good agreement over a wide range of environmental and plant operating conditions. Differences that occur are believed to be primarily due to natural heating and cooling.that influences the measured-data. The report will also evaluate the years when SQN was not operating (1986 and 1987) to look at differences between upstream and downstream temperature measurements without plant effects. After a series of meetings with the State of Tennessee, it was agreed that further field studies be done to. provide additional-confidence in the computed compliance system. As part of the NPDES permit renewal application, the State of Tennessee requested that a " quality assurance" program be submitted which included quarterly field verification during the first year after start-up and annually thereafter (Stewart, 1987). l-ll ______E____________________________..__._.______

4.0 ADDITIONAL VERIFICATIONS As described in Section 3.0, seven field surveys were performed during the period from July 1981 to May 1983. These field verifications were done under different ambient conditions, at different times of the year, and with either one or both units in operation. Figure 3 summarizes the background characteristics associated with each field study. The conditions corresponding to each of the previous seven field studies are marked as numbers in the figure. Field studies under'this quality program will be arranged in such a way so that each will have different characteristics from those of the previous field studies. The selection of a fie19 study is based on ambient conditions-(reservoir stratification and flow) as well as operational constraints of the hydropower system and unit availability of the plant. Figure 3 makes the selection of a field study easier by ensuring that the previous field tests are not duplicated. Priorities for future field studies are listed as letters in Figure 3, with "A" as the highest priority. Because two-unit operation is more significant than one-unit operation, several one-unit tests are not deemed necessary where two-unit data exists. Conditions which are not planned appear as blanks in the figure. The status of SQN startup remains uncertain. Therefore, the field verifications cannot be scheduled at this time. Only one unit may operate for the first year. Because the most significant effects of. plant operation occur at full two-unit loads, it is suggested that only l one field turvey be done during initial one-unit operation. Quarterly l studies for a year would be planned after two units are on line. Additional annual field testing would be determined by field and plant conditions and the established priorities. The field studies will be selected with the aim of filling the remaining spots in Figure 3. An end to the field testing will be proposed when adequate data has been gathered. I r I l ______________._.________m

. ] 4'.1 Description of Field Testing .j In the previous field studies (McIntosh, et al.,-1983)', b . longitudinal water temperature profiles:of the mixing zone were measured: -at depths of- 0.5, 3.0, 4.75, and 6.25 feet (0.15, 1.0, 1.5, and 2 meters)T below the water surfac'e. The NPDES permit for.SQN defines the mixing. { zone as follows: "(1) a maximum length of 1500 feet' downstream of the diffuserst, j (2) a maximum width of 750. feet; and.'(3) a maximum length of 275-feet upstream of.the. diffusers. The depth ~of-the mixing zone measured from the surface varies linearly from the surface 275-feet upstream of the. diffusers to'the top of the: diffuser pipes and. extends to the bottom downstream of'the diffusers.,-The thermal mixing zone also includes the entire: Intake Basin ~ (during closed mode)'and' Diffuser Pond."- Future field testings will be similar.to.those of~the previous field studies.- The longitudinal temperature distribution at midehannel will be measured from the upstream edge'of the mixing zone ~(275 feet upstream of the diffusers) to about 1,500-feet downstream of the ~ diffusers'at depths of 0.5, 3.0, 4.75, and 6.25 feet (0.15, 1.0,-1.5, and: 2 meters) below the water surface. The.results of' previous ~ field studies' indicated that the thermal plume reached the surface very close to the diffusers. Depending.on reservoir conditions,'this distance varied between about 50 to 500 feet. A vertical string of-thermistors.is mounted on a rigid frame and towed by a survey. boat for these measurements. In additien to the longitudinal temperature distribution, lateral temperature distributions within the mixing' zone will also be measured during the field studies. Cross-sectional'(lateral) measurements of temperature distributions will be made at five longitudinal locations (L1, L2 'L3, L4, L5) in the mixing zone at the l same depths as for the longitudinal surveys. Station L1 is about 50 feet downstream of the diffusers, L2 is approximately 100 feet downstream of the diffusers, L3 is roughly 250 feet downstream of the diffusers, L4 is about 500 feet downstream of the diffusers, and L5 is about 1500 feet downstream (at the location of the fixed monitor on the left river ~ bank). The lateral average of the temperatures.at the 3.0, 4.75, and 6.25-foot (1.0, 1.5, and 2.0-meter) depths is considered,to be j representative of-downstream temperature conditions and is used as the measured downstream mixed river temperature. I 4 4 _..m.__

1 ) I j Because of the crucial role of temperature stratification on interpreting field data, vertical temperature profiles will be collected j at mid-channel at Stations L1, L2, L3, L4, and L5 as well'as at the upstream edge of the mixing zone (275 feet upstream'of the diffusers). These data, in conjunction with the longitudinal and lateral temperature { l profiles, will provide information on.the vertical extent of the thermal plume as it moves through the mixing zone. Measurements of plant intake water temperatures and discharge 1 temperatures into the diffuser pond will also be made to check previous estimates of the temperature rise of cooling water across the condenser. 4.2 Equipment Calibration Procedures To ensure the reliability of the data taken during field surveys, the instrumentation is calibrated prior to and following each i i field trip. The procedures for calibrating the equipment are described in j the following paragraphs. I Temperature sensors are calibrated using a constant-temperature bath. The temperature sensors, along with a traceable precalibrated quartz theacmeter, are inserted into the bath and the temperature of the l i bath allowed to reach a steady state. The output voltage from the thermistors circuit and the temperatures measured by the quartz thermometer are used to generate the calibration curves which are l inputted to the bor.t data acquisition system. Overall temperature measurement system accuracies are within 1 F (0.5 C). The depth measuring sensor is calibrated at Norris Lake since laboratory facilities are not available for calibrating to depths of 60 feet. Prior to calibration, a steel measuring tape is connected to the cable supporting the sensor. Therefore, as the sensor is lowered into the water, known depths could be read from the measuring tape and these values related to the output from the sensor / circuit. This calibration is input directly to the data acquisition system on the boats to be used during field tests.

5.0 REFERENCES

McIntosh, Dave A., Billy E. Johnson, and Ellen B.. Speaks, October 1982, "A Field Verification of Sequoyah Nuclear Plant Diffuser Performance-Model: One-Unit Operation," TVA Division of Air and Water Resources, Water Systems Development Branch, Report No. WR28-1-45-110. McIntosh, Dave A., Billy E. Johnson, and Ellen B. Speaks, August 1983, " Validation of Computerized Thermal Compliance and Plume Development at Sequoyah Nuclear Plant " TVA Division of Air and Water Resources, Water Systems Development Branch, Report No. RR28-1-45-115. Ostrowski, Peter, Jr., and Wallace G. Carpenter, In Preparation. " Evaluation of Computed Thermal Compliance at Sequoyah Nuclear Plant," TVA Division of Air and Water Resources, Engineering Laboratory, Report No. WR28-1-45-124 l Stewart, Philip L., January 12, 1987, Letter from the Department of i Health and Environment, State of Tennessee, to Martin E. Rivers, Environmental Quality Staff Tennessee Valley Authority. i 4 L--_..-.__._...

TABLE 1 Summary of Previous Field Studies of Thermal Compliance at Sequoyah Nuclear Plant Units in Reservoir Thermal Date Operation Flowrate (cfs) Stratification 1. 7/24/81 1 27,000-Yes 2. 4/4/82 2 20,000 Yes 3. 5/14/82 2 8,000 Yes 4. 9/2/82 2 37,000 No 5. 11/10/82 1 35,000 No 6. 3/31/83. 2 9,000 Yes 7. 5/11/83 2 25,000 Yes ENG LAB 9/22/87 0140D l l l l l 1 l 1

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~= + 1 l Figure 3. Summary of Priorities for Field Verification' of the Computed Compliance System at-Sequoy'ah Nuclear Plant. 1 1 Chickamauga Dam Annual Average Flow Rate (1975-1965): 33,800 cfs' i RESERVOIR I FLOW RATE (cfs)' j i 6* 3 D** < 10,000 A ) 10,000-2&7 C 'H E 25,000 F l 25,000-35,000 1-5 B G 4 J l > 35,000 SPRING SUMMER FALL WINTER (3-5) (6-8) (9-11) (12-2). MONTHS 2 units 1 unit Note.

• Numbers identify a previous field survey as used in Table 1.
  • Letters list priority for further field etudies.

ENG LAB 9/23/87 C_______ .m__..

g ENCLOSURE 7 PROPOSED CHANGES TO EXISTING NPDES PERMIT FOR SEQUOYAH NUCLEAR PLANT 1. DSN 101 Change the monitoring frequency for pH to three times per week i in accordance with request in DSN 102. 2. DSN 102 Delete requirements for pH. The discharge has experienced pH excursions over 9.0 due to algal activity. The yard holding pond discharges into the diffuser pond, DSN 101. DSN 102 has a maximum dry weather flow of 1 million gallons per day (MGD). DSN 101 has a minimum flow of 20 MGD and a normal flow of over 2000 MGD. This means that the ratio of DSN 101 to DSN 102 is 20 to 1 and is normally over 2000 to 1. The maximum pH recorded at . j DSN 102 to date due to algal activitiy has been 9.4. Therefore, H because of the mixing ratios, there is no potential for DSN 102 to raise the pH of DSN 101 by a detectable amount because of algal activity. 3. DSN 103 Change flow measurement location from Turbine Building sums to pond discharge. This will allow all flows to the low volume waste treatment pond to be accounted for. 4. DSN 108 This discharge has been eliminated. Page should be eliminated. 5. DSN 109 The generator is cooled by the ERCW system and the discharge is routed to the cold water return channel instead of the intake basin. Page should be eliminated. 6. DSN 111 This discharge will be tiiminated before the new permit is issued. DSN 111 should be eliminated from page. 7. DSN 112 The treatment facility is being expanded to 85,000 gallons per day and the discharge rerouted from the yard drainage pond to the intake forebay. Discharge limitations should be revised i accordingly. l l' l i e

8. DSN 113 and 114 DSN 113 will be eliminated before the new permit is issued. DSN 114 has already been eliminated. Page should be eliminated. 9. DSN 115 This discharge has been eliminated. Page should be eliminated. 10. DSN 116 In accordance with Part III.J. add a new page for DSN 116, CCW intake trash sluice to Tennessee River that states discharge may be made without limitation or monitoring requirements. 11. DSN 117 l In accordance with Part III.J. add a new page for DSN 117, ERCW screen ] l and strainer backwash to Tennessee River that states discharge may be l made without limitation or monitoring requirements. 12. Parts I.B.1.c and III.F In 1985 TVA completed comprehensive aquatic biological and water quality monitoring requirements of the.SQN NPDES permit. TVA requested and received concurrence to modify the program to include the following: (1) cove rotenone fish samples annually at five locations in Chickamauga Reservoir (letters from R. M. Sinclair to M. E. Rivers, May 14, 1987, and from F. M. Pointer to M. E. Rivers, July 9, 1987), (2) modified plankton ) studies to assess effects of plant operation during certain low reservoir flow conditions (letter from M. E. Rivers to R. M. Sinclair, May 27 I 1987), and (3) a special investigation to determine if SQN impacts the I dissolved oxygen regime in Chickamauga Reservoir (letter from M. E. Rivers to P. L. Stewart. April 30, 1987). Parts I.B and III.F l should be rsvised to reflect the commitments and agreements made in the above letters. 13. Parts I.B.1.b and III.E Parts I.B.1.b and III.E should be revised to reflect the requirement for field verification tests for the thermal computed compliance methodology. 14. Part III.J Delete in accordance with requests for DSNs 116 and 117. l 0140D 4 i j !}}