ML20065N374

Forwards Cooling Water Additive Info & Matl Safety Data Sheet for Facility

ML20065N374
Person / Time
Site:	Perry
Issue date:	04/22/1994
From:	Stratman R CENTERIOR ENERGY
To:	Jackson K OHIO, STATE OF
References
NUDOCS 9404270134
Download: ML20065N374 (5)

Text

. - - _ _ - _ _ _ . - -_

CENTERDOR ENERGY PERRY NUCLEAR POWER PLANT Mail Address: Robert A.Stratmart PO BOX 97 VICE PRESIDENT NUCLEAR

- 10 CENTER ROAD PERW, OWO 4 081 PERRY, OHIO 44081

'(216) 259-3737 April 22, 1994 PY-CEI/0 EPA-0200L Hs. Kim Jackson Ohio Environmental Protection Agency Division of Vater Pollution Control Enforcement and Compliance Section l 1800 Vatermark Drive, P.O. Box 1049 Columbus, Ohio 43266-0149

Dear Hs. Jackson,

The Perry Nuclear Power Plant has enlisted Calgon Corporation to initiate the use of Towerbrom 960 for slime and algae control in the plant Circulating Vater  !

System. The chemical vill be added to the system twice per day. j Attachments 1 and 2 contain the information required in accordance with Ohio _

l EPA procedures. Our intention is to begin use of Towerbrom 960 upon receipt of l your approval. Please contact Donna Tizzano at (216) 280-5514 if you have further questions.

Sincerel , l f // / s _

ff kdl %

RAS:dgt l

cc: NRC Document Control Desk NRC Project Manager ,

NRC Resident Inspector ]

NRC Region III j B. Hall - OEPA District Office 1

-1 l

280073

'I I operonng companies l

e and E ectne muminonng 9404270134 940422 PDR ADOCK 05000440 b

P PDR

]1

r

• 4 , -.

PY-CEI/0 EPA-0200L Attachment 1 Cooling Vater Additive.Information

1. The'name'of the additive to be used and general' product information.

a. MSDS - Attachment 2

b. 89% Sodium Dichloro-S-Triazinetrione 11%' Sodium' Bromide

c. <5% Vater

<3% Sodium Chloride

d. slime control in the plant circulating water system

e. USEPA Registration Number 524-395-10445

2. The concentration of the additive to be used (mg/L)

a. Application 0.2 - 0.5 mg/L, two times per day. e

b. Shock feed for testing

c. Manual addition for testing purposes. A permanent feed system vill be employed if permanent.use of Toverbrom 960 is employed.

3. The expected concentration of the additive contained in the discharge H immediatly prior to entering state surface waters. l

a. 0.0 mg/L 2

b. Dehalogenation vill be accomplished by addition of sodium sulfite'to -l the plant outfall by the existing Plant Discharge Dechlorination .I System.

4. The average flovrate (MGD) and the outfall number of each outfall containing the additive,

a. The average flow rate in the Perry Plant outfall is 82.08 HGD*. .The volume of cooling tower blowdown entering the, discharge is approximately 14.4 HGD. The outfall is No. 3IB00016004.

5. Name of the state surface water (s) that receive the. discharge.

Lake Erie

6. Toxicity and environmental information for the additive.

96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> LC50 - Rainbow Trout .37 mg/L 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> LC50 - Bluegill Sunfish .43 mg/L 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> LC50 - Daphnia Magna - 2.30 mg/L 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> LC50 - Fathead Minnov .70 mg/L

• MGD - Hillion Gallons per Day

MATERIAL SAFETY DATA SHEET

^ '

CALGON CORPORATIOt! -

P.O. Box 134G Pittsburgh, PA 15230-1346 CA.L..G

=e O.N a n.e 1

24 Hour Emergency Tolephone --(412) 777-8000 I. PRODUCT IDENTIFICATION HEDUCT RAPE: Towerbrom 960 CHIMICAL DESCRIPTICW: This product is a sairture of soditas dichlorelsocyanurate (anhydrous) and soditan bromide. When dissolved in water, the mixture produces the disinfectant hypobromous acid.

19fDUCT CLAS3: Microblocide II. HAZARDOUS INGREDIENTS AND EXPOSURE t.1MITS I by Oral LD50 Dermal LD50 ACUIB TLV Chemical Name CAS No. ti.jahl f frat) (rabbit) C6HA PEL Sodisse dichloro-a-triatinatrione 2893-78-9 89 1400 mg/kg Not available TWA 0.5mg/ef*

STEL 1.5 mg/m

• Sodium bromide 7647-15-6 7 3500 mg/kg Not available Not listed

• Suppiter recommandations III. TYPICAL PHYSICAL PROPERTIES BOILING ICINI: Not applicable SOLUBILITY IN WATER: 20 g/100 g 8 25*C VAPOR TRESSUPE: Not available BULK DENSITY: 57 lbs./ cubic it.

VAKR DENSITY (air =1): Not available p!!: 6.0 (11 soln 8 25'C) 2 WJLATILE BY WEICHT: Nil MELTING POINT: 240-250*C (decomposes)

APPEARANCE AND OIOR: White to offwhite granules with slight bromine odor.

IV. FIRE AND EXPLOSION HAZARD DATA II.ASil ICIFT: This product is not 11astnable or combustible, howeve,r, it .4 an oxidi Ana and chlorinating agent, Ccmtect wit.h most foreign materials, organic matter or sessly chlorinated or oxidized materials may result in fire, While this informatico and recommendations set forth herein are believed to be accurat.e as of the date hereof, CA1 DON LGRPORATION HAKM NO WARRANTY WITil RESP!rf HERETO AND DISCLAltti ALL LIABILITY FROM RELIANCE THERE,0N (CDS No. E2C6-02-02-93-0B79 Page 1 of 5 Date: 7/27/93 J

t IV. FIRE AND EXPLOSION HAZARD DATA (continued)

Use water sprsy to cool containers exposed to fire and massive Do not use ABCquantities dry of water to EXTIM]UISHING MEDIA: dilute material involved in a fire or spilled from containers. il or Halon chassical fire extinguishers, other dry chemical fire extinguishers or mater a s fire extirguishers.

A self-contained breathing Exercise caution when fighting any chemical fire. Chlorine containing gases with traces

$FICIAL TIREFIQlTING FROCEDURES:n;,paratus and protective clothing era Thoroughly of 400*F. essential.. 4 7-*

of phosgene can be liberated at ty .i.u..deconteninate equipeent including wearing appare followir.4 the incident.

In a fire, as a result of decomposition or contacthwith small amounts oftoxic gases will iMUSUAL FIPI AND EXFiDSICri EAZARDS:

water, be evolved.

extremely dense and roxious fumes containingHisture chlorine and ot erConsact hi contain nitrogen may form nitrogen trichloride, a highly explosive ition andcompound.

container with hydrated salta may result in an erothermic reaction, deccuposMixture with non-lonic surfa Decomposition can be initiated rupt.ure due to pressure.

highly azothermic reactions causing fire or explosim. l i f dense with itsnes .

a heat source and can propagate throughout the mass with the evo ut m o wet.

Reactivity = 2 Special Bazard = OKY Flannability = 0 EFPA RATINGS: Uselth = 3 V. REACTIVITY DATA CHDtICAL STABILITY s Stable HAZARDOUS 10LYMERIZATION: Will not, occur (DNDITIONS TO AVOID: Overheating Avoid contact wit.h easily oxidizable inorganic INCt2fATIBILI TY: Avoid contact wit.h water while in the container.

organic material; anzonia, urea, or similar nitrogen cont.alning compounds; reducing ccapounds; calcitan hypochlorite; alkalls.

Chlorine (released in presence of sciature) and other chlorine containing BAZARDOUS DECI2f0SITION FRODUCTS:coupounds. Hypobremous acid, hypochlorous acid, and cyanuric acid (released Oxides of nitrogen, disodium oxide, brornine, and when dissolved in water).

traces of t hossene.

VI. HEALTH HAZARD DATA inhalation, ingestion E'ye and skin contact, FRIMARY ROUTES OF ENTRY:

TARCET OMANS: Eye, skin, respiratory tract, gastrointestinal t.rects DANGERt May cause severe eye and skin damage.

Hay be harmful if swallowed.

Hay cause respirat.ory tract, irritation.

Contact wit.h water slowly liberates irritating and hazardous chlorine containing gases.

Decomposes at 460-480*F with release of harmful gases.

I Date: 7/27/93 I Page 2 of 5 K;DS No, 0B79-02-02-93

m .

]

VI. HEALTH HAZARD DATA (continued)

EyTECTS & tm.u.uuiURE:

d26%

EYE CONTACT: This product may produce severe eye damage upon contact with the eye, SEIN CatfTACT: This product may be irritating sad demasing to the skin upon contact. In dry fone, the product is not appreciably irritating to dry skin. However, on contact, with moist,ure, sodites dichlorcisocyanurete readily hydrolyses to form hypochlorous acid which may cause t,1aeus damage. This proaact is not expected to be absorbed through t.he skin in harinful moounts or t.o sauce akin sensitisat.icea. ' The acute dermal iS$0 (rabbit) of a similar product,was found to be > S000 mg/kg.

IICESTICH: The acute oral LD50 (rat) of a stallar formulat,lon was found t.o be 1350 mg/kg.

Ingestion of soditen dichloroisocyanurate has been reported to cause ulceration or bleeding from the stanach, gastrointestinal irritetion, salivation, tearing, shortness of breath, weakness, emociat,lon, lethargy, diarrhea, and ccma.

INBALATION: Inhalation of soditan dichloroisocyanurat,e chaat has been reprted to produce nose, thtoat, and respiratory tract irritetton and in some individuals bronchospasa may result. Chlorine gas from decomposition of the product has been reported to cause burning of the nose and mouth and irritaticas of the lining of the respiratory tract with coughing, a choking sensation, chest pain, vessiting. nausea, headache, distiness and fainting. The onset of severe respiratory symptans following exposure to chlorine, 4 including pulmmary edene end poumonitis, may be delayed.

SUDCHRONIC. CITRONIC Rats were exposed by inhalation to dust of soditse di$hloroisocyanurate 'et exposure levels of 0, 3.2, 10.4, and 32.8 as/m3 for 6 hours6.944444e-5 days <br />0.00167 hours <br />9.920635e-6 weeks <br />2.283e-6 months <br /> / day, 5 days / week for 4 weeks. Signs of irritation including lacrimation, salivat. ion and labored breet.hing were observed at, the mid- and high-orposure levels, Decreased body and/or liver weights, and hematological parameter alterations were also noted in the mida and high-exposure groups. No adverse histopathological effects were observed. The no effect level is considered to be 3.2 mg/m3.

No teratogenic or fototoxic effects were observed in the offspring of mice maninistered sodium dichloroloocyanurate, by gavage, et, dosage levels of 0, 25,100, .and 400 e6/kg/ day on days 6 through 15 of gest,ation. Nrtality and signs of t.oricity were observed in t.he high-dose group dams, Decreased maternal body weight gain was observed in all treatment, groups.

Repeated oral ingestion of soditsa broaside produces sedation and central nervous system (CNS) depression with possible effects such as headache, irritability, agitation, deliritan, vertigo, marory loss, muscular incoordinet. ion and increased action of the reflexes, decreased appetite, hallucinations, acne-like rash, st,upor and come.

Following repeated exposures (4-12 weeks) t.o soditas bromide in their feed, signs of muscular incoordination and depressed grooming, changes in body weight and behavior, and endocrine (horame) ,

system effects were reported in laboratory animals. Reduced fertility and viability of offspring were '

noted in rat.a fed sodium bromide for three successive generations. These effects on the ability of rats to reproduce were reported to be reversible upon withdrawal of the bromide. Results of another study suggest that learning ability was reduced in offspring of rats given soditse bromide during pregnancy.

CARCINOGENICITY: ,

2 NTP No ingredient.s listed 1 ARC: No ingredients listed 0:llA t No ingredients listed It1IS RATINCGt Bealt.h = 3* Flammability = 0 Reactivity = 2 Personal Protective Equipment. = to be supplied by user depending on use conditions.

• There are pot.ential chronic health effects to consider.

E DS No. 0879-02-02-93 Page 3 of 5 Date: 7/27/93

- ~ . ~ , , - . - .~ . . , , . ._

B n

. VII. APPLICABLE CONTROL HEASUBES Do not get in eyes, on skin, or on clothing.

AFISDPILIATE ETUIENIC PRETICES: Avoid breathing dust or vapor.

FDtSONAL 1%DTECTIVE IQUIPHENT:'

Chanical splash goggles ETF. PROTICTICN:

, Qaealcal restatant gloves, fece shield and protective clothing SKIN FROTECTION:

If airborne concentratione exceed rec-aded esposure Limits, use(29 a CTR RESPIRATGLY 790TICTION:

N10GB eiproved respirator in accordence with C6BA roepiratory protection requirements 1910,134).

An eye wash station and safety shower abould be accessible in the immediate area.

1 G K PRACTICE 3r It is a violation of Tederal Lew to use this product in a menner inconsistent BANDLING AND STORACE PR*: CAUTIONS: with its labeling.

Use with adequate ventilatice.

Do not odd this product to any dispensing device containing resusants of any othar produtt. Such use may cause a violent reaction leading to fire or explosion.

Keep frees contact with clothing or other combustible materials.

Remove and wesh ccataminated clothing prceptly.

Store in a cool, dry, well-ventilated place away frcus flamanable 11gulds, combustible materials, and oxidisable materials.

Dzuns should be pallatised to prevent wetting from floor washings or drainage.

Avoid prolonged storage in unventilated areas at stanner temperatures.

Wash thoroughly after handling.

Keep container closed when not in use. e Provide detural or mechanical ventilation to control exposure levels below airborne DIGINEERING CONTEOLS' Use local mechanical otheust ventilation at sources of air exposure limits. Consult NTPA Standard 91 for design of erhaust systems.

containinetton.

VIII. FIRST AID Seek imusediately flush eyes with plenty of water for at least 15 minutes.

EYE CDNTACT:medical In caseaid of contact.

inmediately.

SKIN CONTACT:

In case of contact., inmediately Seek flush skinand smilcal wit. plenty of inmediately.

Wash water forbefore clothing at least 15 minute removing contaminated clothing and shoes.

reuse.

Give large quantities of water. Seek medical eid If swallowed. do NOT induce vaniting.

inmediet.ely. Never give anything by unut.h to an unconscious perison.

INGESTION:

Probable anacosal damage may contraindicat.e the use of gestric lavage.

NOTE TO ITYSICI AN:

If not breathing, give artificial respiration. ~ If breatlaing is INilA1ATION:

If inhaled, remove to fresh air.

• difficult, give oxygen. Seek medical aid.

I Datei 7/27/93' Page 4 of $ I tCDS No.t CB79-02-02-93

. . _ _ _ _ _ _ . . . , _ , -_ ,, - .i

. -I

, l

<l i . . II * - s. I j

}

t IX.' SPILL'OR LEAK PROCEDURES / WASTE DISPOSAL 4 1

STEPS 70 BE TAKDf IF HATERIAL IS RELEASED OR SPILLED: Contain spilled material.~ Any spillage of this product I should be cleaned up imamediately to avoid contact with other materials with which it may react. I Keep spilled product dry. Contact with water releases irritating and baserdous chlorine containing .~ l gases. Sweep, scoop, or vacuun up all spilled material, contaminated soil, and other contaminated material and piece in a clean, dry container for disposal. Complete cleanup ce a dry basis if possible. Floor sweeping compounds should not be used in the removal as finning, fire and emplosion may result. Keep tumeutralised product out of sewers, watersheds and water systems.

Wu!TE DIS 10 SAL: Festicide wastes are acutely basardous. Improper disposal of excess poeticide, sprey mixture, or rinsate la a violation of Federal law. If these westes cannot be disposed of by use according to label instructions, contact your State Festicide or Ihvircemental Control Agency, or the Basardous Weste representative at the nearest EPA Regional office for

< guidance.

fry 1MICAL DATA 4

On staller formulation:

Selenastrum EC50 0.6 mg/l Daphnia magna 4 8-hr , 1f 50 2.5 mg/l Fathead Hinnow 48-hr.1450 - 0.7 mg/l On Sodium dichloroisocyanurate Rainbow Trout 964a.1r50 . 0.37 pia Bluegill Sunfish 96-hr. 1C50 0.43 ppa Hallard Duck Orni 1350 1916 mg/kg Hallard Duck Dietary 8-day 1C50 > 10,000 ppa Bobwhite Quail Dietary 8-day 1450 > 10,000 ppe X, REGULATORY STATUS TT4A STATUS: The ingredient.s of this product are listed on the Toxic Substances Control Act (TT4A)

Chemical Substances Inventory.

RCRA STATUSr This product as sold would be considered a RCRA Bazardous Waste based on the characteristics of ignitability and reactivity. The EPA Hazardous Waste Ntanbers are D001'and D003.

CERCLA reportable quantity of EPA hazardous substances in product None SARA TITLE III:

Section 302 Extremely !!arardous Substances: None Section 311 and 312 Health and I'bysical Hazarda r ,

Imsediate Delayed Fire Pressure Reactivity (yes) (yes) lyes) (no 1 (yes)

Section 313 Toxic Chemicolas None

, DOT CLASSITICATICel: ,

Class: 5.1 Proper Shipping Nane; Dichloroisocyanuric acid salts, mixture i ID Number: UN 2465 .l Label Oxidis er  !

Packing Group: II ]

1 I

, IHETARED BY: P.J. Helonev ,,

1HP-0B79/AN ICDS No. CB79-02-02-93 Page 5 of 5 Date: 7/27/93 1

1 w -4 -- 1 er ,a ~ s'