ML072840312

Report for Analysis for Samples from Set Twenty-Four from the Indian Point Power Station, Buchanan, New York. Dtd. July 31, 2007

ML072840312
Person / Time
Site:	Indian Point
Issue date:	07/31/2007
From:	Condra D Oak Ridge Institute for Science & Education
To:	Kottan J J NRC Region 1
References
IR-07-003, RFTA 07-001
Download: ML072840312 (10)

Text

4B ORISE OAK RIDGE INSTITUTE FOR SCIENCE AND EDUCATION I [uly 31. 2007 fir. Jim Kottan J.S. Nuclear Regulatory Commission 1 t?GeLdak Road (Ing of Prussia, PA 19406

SUBJECT:

REPORT FOR ANALYSES FOR SAMPLES FROM SET TWENTY-FOUR, FROM THE INDIAN POINT POWER STATION, BUCHANAN, NEW

[INSPECTION REPORT NO. 050-247/2007-0031

[RFTA NO. 07-0011 I YORK >ear Mr. Icottan: The Oak Ridge Institute for Science and Education (ORISE) recrived sct 24, consisting of six water amples, associated with the Indian Point Power Station on May 11, 2007. Sample analysis was initiated lased on your previous direction for handling samples from ths licrnsee and modified based on a phone :onversation with John \Vhtte on July 3,2007 and an e-mail from Stacie Sakai on July 9, 2007. Sample dentification and collection data for the samples addressed in thts report are presented in Table 1.

>amma spectroscopy, the hard-to-detect beras (iron-55, nickel-63, and tritium), technetium-99, total .adiostrontium, alpha spectroscopy, plutonium-241, and carbon-14 data are provided in Tables 2 through 3, respectively.

The pertinent procedure references are provided in each specific table.

3RISE's Quality Control (QC) requirements were met for these analyses.

The QC fdes are available for Tour review upon requrst. Wy contact information is listed below. You may also contact Wade Ivey at 865.576.9184 with any questions or comments.

Sincerely, Dale Condra, Manager '>aboratory RDC:LYTI.at Znclosures T. Carter, NRC/FSME/DLVIVIEP 7J8 E. &ox-Davin, NRC/FSME/TWFN S. Roberts, ORISE File 1697 SA23 J. E \Y.htc, NRC Regiot . Abelquist, ORISE zp 75 I W s lg VI Voice: 865.241.3242 Fax: 865.241.3248 E-mail: Dale.Condra

@orau.org TABLE 1 - ORISE NRC Region I Collection Collection Date Sample ID Sample ID Time 1 697WO 142 Mw-54-38'-

(00 1) 5/3/2007 16:19 1697W0143 Mw-54-59'-(001) 5/3/2007 16:45 1697W0144 Mw-54-125'-(001) 5/3/2007 14:18 1697W0145 Mw-54-146'-(001) 5/3/2007 1431 1697W0146 Mw-54-174'-(001) 5/3/2007 1443 1697WO147 Mw-54-192'-(001) 5/3/2007 15:OO SAMPLE IDENTIFICATIONS AND COLLECTION DATA INDIAN POINT POWER STATION BUCHANAN, NEW YORK Indian Point Power Station Projects/l697/Dara Tables/2007-07-31 Interim Data Tables 1697 Set 24 TABLE 2 ORISE Sample ID 1697YV0142 1697M0143 1697YV0144 1697YV0145 CONCENTRATIONS OF SELECTED GAMMA EMITTING RADIONUCLIDES IN WATER SAMPLES BY GAMMA SPECTROSCOPY CP1, REVISION 15 INDIAN POINT POWER STATION BUCWAN, NEW YORK Radionuclide Concentrations, TPUs, and MDCs" @Ci/L)

CO-58 CO-60 cs-l34 cs-w7 NRC Region I Sample ID m-54-38'-(001)

O.Ob k 2.0' , 3.5 2.3 k 3.1 , 3.8 0.5 f 2.4 , 3.8 2.4 ? 4.6 , 3.5 m-54-59'-(001)

-1.1 2 2.3 , 3.8 -0.2 k 2.2 , 3.9 0.5 2 2.3 , 3.9 -1.0 L 2.2 , 3.6 m-54-125'-(001)

-1.1 k 1.8 , 3.1 -0.6 k 1.8 , 3.2 -2.6 -t 1.9 , 3.0 2.1 ? l>j , 3.0 m-54-146'-(001)

-1.9 k 2.8 , 4.1 2.4 ? 2.4 , 4.3 -0.8 ? 3.5 , 4.1 -1.0 k 2.3 , 3.8 1) 1697W0146 I m-54-174'-(001)

I -1.2 ? 2.2 , 3.5 I 1.9 ? 2.1 , 3.81 -1.2 k 2.4 , 3.7) 1.3 k 4.6 , 3.3 I(

TABLE 3 ORISE Sample ID ~ Radionuclide Concentrations, TPUs, and MDCs" @Ci/L)

NRC Region I Sample ID Fe-55h Ni-63' H-3* 1697W0142 MW-54-38'-(001)

-13 k lge , 33 6.1 i 4.4 , 7.2 1,000 i 210 , 290 InlanPmr Power Statlon 169W0144 1697W0145 1697W0146 1697W0147 - Fra~ectr/l697/DaraTables/2007-07-31 Intern Data Tables 1697 Set 24 I, I Mw-54-125'-(001)

-6 f 19 , 33 5.2 ? 4.3 , 7.2 1,390 f 220 , 290 MW-54-146'-(001)

-4 k 19 , 33 5.7 f 4.3 , 7.2 1,720 k 240 , 290 MW-54-174'-(001)

-8 2 19 , 33 8.9 ? 4.4 , 7.2 1,830 ? 240 , 290 Mw-54-192'-(001)

-2 k 19 , 33 6.4 k 4.4 , 7.2 1,860 +_ 240 , 290 TABLE 4 ORISE Sample ID CONCENTRATIONS OF TECHNETIUM-99 , IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP5, REVISION 17; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide NRC Region I Concentrations, Sample ID TPUs, and MDCs" @Q/L) b 1697W0142 I MW-54-38'-(001)

I 3.1 ? 7.6 , 13.0 (1 1697W0143 1 MW-54-59'-(001)

I -1.2 ? 7.5 , 13.0 11 1697W0144 1 MW-54-125'-(001)

I 3.5 i 7.7 , 13.0 1) 1697W0145 1 MW-54-146'-(001)

I -0.3 k 7.5 . 13.0 I1 .. I1 1697W0146 i Mw-54-174'-(001) 1 4.5 k 7.7 . 13.0 11 1697W0147 I MW-54-192'-1001)

I -8.2 ? 7.4 , 13.0 (1 Indlan Point Power stauon Prqetcs/l697/Dara Tabler/Z007-07-31 Intern Data Tables 1697 Set 24 TABLE 5 ORISE Sample ID 1697W0142 1697W0143 1697W0144

1697W0145 1697W0146 1697W0147 Radionuclide Concentrations, TPUs, and MDCS" @Ci/L) NRC Region I Sample ID Mw-54-38'-(001) 12.2 rt l.lb , 0.9 m-54-59'-(001) 3.09 i 0.67 , 0.84 m-54-125'-(001) 21.3 i 1.5 , 0.8 MW-54-146'-(001) 16.9 rt 1.3 , 0.9 MW-54-174'-(001) 19.4 rt 1.4 , 0.9 Mw-54-192'-(001) 22.5

• 16 , 0.9 Indian Point Power Station Pr4ects/l697/Data Tables/2007~07-31 Inte- Data Tables 1697 Set 24 TABLE 6 ORISE NRC Region I Sample ID Sample ID 1697W0142 Mw-54-38'-(001) 1697W0143 MW-54-59'-(001) 1697W0144 MW-54-125'-(001) 1697W0145 MW-54-146'-(001) 1697W0146 MW-54-174'-(001) 1697W0147 MW-54-192'-(001)

Radionuclide Concentrations' (pCi/L for water) Am-241 Cm-242 Cm-243/244 Np-237 0.11 ? 0.15Ib , 0.32 -0.23 ? 0.19 , 0.41 0.02 ? 0.23 , 0.43 0.05 k 0.08 , 0.14 0.41 t 0.27 , 0.39 -0.02 ? 0.11 , 0.25 -0.07 ? 0.20 , 0.41 0.04 ? 0.08 , 0.16 0.09 0.13 , 0.22 0.00' ? 0.05 , 0.14 0.12 ? 0.09 , 0.05 -0.02 t 0.04 , 0.16 0.21 ? 0.22 , 0.36 0.05 2 0.09 , 0.15 -0.03 ? 0.16 , 0.32 0.02 2 0.09 , 0.19 0.07 ? 0.21 , 0.38 0.00 k 0.10 , 0.22 0.02 ? 0.16 , 0.32 -0.06 ? 0.09 , 0.24 -0.04 ? 0.24 , 0.46 -0.08 ? 0.08 , 0.23 0.00 2 0.19 , 0.38 -0.08 ? 0.13 , 0.32 t B TABLE 6 (Continued)

CONCENTRATIONS OF SELECTED ALPHA EMITTING RADIONUCLIDES IN DISSOLVED FRACTIONS OF WATER SAMPLES AP11, REVISION 3; CP2, REVISION 12 INDIAN POINT POWER STATION BUCHANAN, NEW YORK i TABLE 7 ORISE NRC Region I CONCENTRATIONS OF PLUTONIUM-241 IN DISSOLVED FRACTIONS OF WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS APlO, REVISION 3; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide Concentrations, Sample ID 1697W0142 1697W0143 SampleID TPUs, and MDCs" @Ci/L)

Mw-54-38'-(001)

-2

• 37b 63 Mw-54-59'-(001) 8

• 34 59 Mw-54-125'-(001) 9 i 35 The MDCS are afrer the comma. bUn~ercmoes represmr he 9594 confidence lwd, bascd on total propagated uncertainties 1697W0145 Mw-54-146'-(001)

Indian Point Power Station 5

• 34 59 Prqlects/l697/Data Tables/2007-07-31 Inte-Data Tables 1697 Set 24 1697W0146 Mw-54-174'-(001) 3

• 37 63 1697W0147 Mw-54-192'-(001)

-6 t 36 62 TABLE 8 ORISE NRC Region I Sample ID Sample ID Radionuclide Concentrations, TPUs, and MDCs' @Ci/L) 1697W0142 1697W0143 1697W0144 1697W0145 1697W0146 1697W0147 me mcs are after the coma. bUncertmties reprerent the 959b confidence level, based on totdpropagated uncert&mes.

MW-54-38'-(001)

-0.8 f 9.4b , 16.1 MW-54-59'-(001)

-7.2 k 9.4 , 16.1 MW-54-125'-(001)

-6.0 f 9.4 , 16.1 MW-54-146'-(001) 0.3 f 9.5 , 16.1 MW-54-174'-(001)

-1.7 f 9.4 , 16.1 ME-54-1 92'-(001)

-5.3 i 9.4 , 16.1 - In&m Pomr Power stauon Pr~ects/lG9l/Data Tabler/2007-07-31 InteMl DataTables 1697 Set 24