ML072840312

Report for Analysis for Samples from Set Twenty-Four from the Indian Point Power Station, Buchanan, New York. Dtd. July 31, 2007

ML072840312
Person / Time
Site:	Indian Point
Issue date:	07/31/2007
From:	Condra D Oak Ridge Institute for Science & Education
To:	Kottan J NRC Region 1
References
IR-07-003, RFTA 07-001
Download: ML072840312 (10)

Text

4B O R I S E OAK RIDGE INSTITUTE FOR SCIENCE AND EDUCATION I [uly 31. 2007 fir. Jim Kottan J.S.Nuclear Regulatory Commission 1 t?GeLdak Road (Ing of Prussia, PA 19406

SUBJECT:

REPORT FOR ANALYSES FOR SAMPLES FROM SET TWENTY-FOUR, FROM T H E INDIAN POINT POWER STATION, BUCHANAN, NEW I YORK

[INSPECTION REPORT NO. 050-247/2007-0031 [RFTA NO. 07-0011

>ear Mr. Icottan:

The Oak Ridge Institute for Science and Education (ORISE) recrived sct 24, consisting of six water amples, associated with the Indian Point Power Station on May 11, 2007. Sample analysis was initiated lased on your previous direction for handling samples from t h s licrnsee and modified based on a phone

onversation with John \Vhtte on July 3,2007 and an e-mail from Stacie Sakai on July 9, 2007. Sample dentification and collection data for the samples addressed in thts report are presented in Table 1.

>amma spectroscopy, the hard-to-detect beras (iron-55, nickel-63, and tritium), technetium-99, total

.adiostrontium, alpha spectroscopy, plutonium-241, and carbon-14 data are provided in Tables 2 through 3, respectively. The pertinent procedure references are provided in each specific table.

3RISE's Quality Control (QC) requirements were met for these analyses. The QC fdes are available for Tour review upon requrst.

Wy contact information is listed below. You may also contact Wade Ivey at 865.576.9184 with any questions or comments.

Sincerely, Dale Condra, Manager zp

'>aboratory 75 I

RDC:LYTI.at W Znclosures s T. Carter, NRC/FSME/DLVIVIEP 7J8 E. &ox-Davin, NRC/FSME/TWFN SA23 J. \Y.htc, NRC Regiot E . Abelquist, ORISE lg VI S.Roberts, ORISE File 1697 Voice: 865.241.3242 Fax: 865.241.3248 E-mail: Dale.Condra @orau.org

TABLE 1 SAMPLE IDENTIFICATIONS AND COLLECTION DATA INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Collection Date Collection Sample ID Sample ID Time 1697WO142 Mw-54-38'-(00 1) 5/3/2007 16:19 1697W0143 Mw-54-59'-(001) 5/3/2007 16:45 1697W0144 Mw-54-125'-(001) 5/3/2007 14:18 1697W0145 Mw-54-146'-(001) 5/3/2007 1431 1697W0146 Mw-54-174'-(001) 5/3/2007 1443 1697WO147 Mw-54-192'-(001) 5/3/2007 15:OO Indian Point Power Station Projects/l697/Dara Tables/2007-07-31 Interim Data Tables 1697 Set 24

TABLE 2 CONCENTRATIONS OF SELECTED GAMMA EMITTING RADIONUCLIDES I N WATER SAMPLES BY GAMMA SPECTROSCOPY CP1, REVISION 15 INDIAN POINT POWER STATION B U C W A N , NEW YORK Radionuclide Concentrations, ORISE NRC Region I TPUs, and MDCs" @Ci/L)

Sample ID Sample ID CO-58 CO-60 cs-l34 cs-w7 1697YV0142 m-54-38'-(001) O.Ob k 2.0' , 3.5 2.3 k 3.1 , 3.8 0.5 f 2.4 , 3.8 2.4 ? 4.6 , 3.5 1697M0143 m-54-59'-(001) -1.1 2 2.3 , 3.8 -0.2 k 2.2 , 3.9 0.5 2 2.3 , 3.9 -1.0 L 2.2 , 3.6 1697YV0144 m-54-125'-(001) -1.1 k 1.8 , 3.1 -0.6 k 1.8 , 3.2 -2.6 -t 1.9 , 3.0 2.1 ? l>j , 3.0 1697YV0145 m-54-146'-(001) -1.9 k 2.8 , 4.1 2.4 ? 2.4 , 4.3 -0.8 ? 3.5 , 4.1 -1.0 k 2.3 , 3.8

1) 1697W0146 I m-54-174'-(001) I -1.2 ? 2.2 , 3.5 I 1.9  ? 2.1 , 3.81 -1.2 k 2.4 , 3.7) 1.3 k 4.6 , 3.3 I(

TABLE 3

~

Radionuclide Concentrations, ORISE N R C Region I TPUs, and MDCs" @Ci/L)

Sample ID Sample ID Fe-55h Ni-63' H-3*

1697W0142 MW-54-38'-(001) -13 k l g e , 33 6.1 i 4.4 , 7.2 1,000 i 210 , 290 I ,

I 169W0144 Mw-54-125'-(001) -6 f 19 , 33 5.2 ? 4.3 , 7.2 1,390 f 220 , 290

- 1697W0145 MW-54-146'-(001) -4 k 19 , 33 5.7 f 4.3 , 7.2 1,720 k 240 , 290 1697W0146 MW-54-174'-(001) -8 2 19 , 33 8.9 ? 4.4 , 7.2 1,830 ? 240 , 290 1697W0147 Mw-54-192'-(001) -2 k 19 , 33 6.4 k 4.4 , 7.2 1,860 +_ 240 , 290 InlanPmr Power Statlon I n t e r n Data Tables 1697 Set 24 Fra~ectr/l697/DaraTables/2007-07-31

TABLE 4 CONCENTRATIONS OF TECHNETIUM-99

, I N WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP5, REVISION 17; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide ORISE NRC Region I Concentrations, Sample ID Sample ID TPUs, and MDCs"

@Q/L) 1697W0142 I MW-54-38'-(001) I 3.1  ? 7.6b , 13.0 (1 1697W0143 1 MW-54-59'-(001) I -1.2  ? 7.5 , 13.0 1 1 I 11I) 1697W0144 1697W0145 1697W0146 1

i MW-54-125'-(001)

MW-54-146'-(001)

Mw-54-174'-(001)

I 1

3.5

-0.3 4.5 i 7.7 k 7.5 k 7.7

, 13.0 13.0 13.0 1I 11 1697W0147 I MW-54-192'-1001) I -8.2  ? 7.4 , 13.0 (1 Indlan Point Power stauon Prqetcs/l697/Dara Tabler/Z007-07-31 I n t e r n Data Tables 1697 Set 24

TABLE 5 Radionuclide ORISE NRC Region I Concentrations, TPUs, and Sample ID Sample ID MDCS" @Ci/L) 1697W0142 Mw-54-38'-(001) 12.2 rt l.lb , 0.9 1697W0143 m-54-59'-(001) 3.09 i 0.67 , 0.84 1697W0144 m-54-125'-(001) 21.3 i 1.5 , 0.8 1697W0145 MW-54-146'-(001) 16.9 rt 1.3 , 0.9 1697W0146 MW-54-174'-(001) 19.4 rt 1.4 , 0.9 1697W0147 Mw-54-192'-(001) 22.5

• 1 6 , 0.9 Indian Point Power Station Pr4ects/l697/Data Tables/2007~07-31Inte- Data Tables 1697 Set 24

TABLE 6 ORISE NRC Region I Radionuclide Concentrations' (pCi/L for water)

Sample ID Sample ID Am-241 Cm-242 Cm-243/244 Np-237 1697W0142 Mw-54-38'-(001) 0.11 ? 0.15Ib , 0.32 -0.23 ? 0.19 , 0.41 0.02  ? 0.23 , 0.43 0.05 k 0.08 , 0.14 1697W0143 MW-54-59'-(001) 0.41 t 0.27 , 0.39 -0.02 ? 0.11 , 0.25 -0.07  ? 0.20 , 0.41 0.04 ? 0.08 , 0.16 1697W0144 MW-54-125'-(001) 0.09 0.13 , 0.22 0.00'  ? 0.05 , 0.14 0.12  ? 0.09 , 0.05 -0.02 t 0.04 , 0.16 1697W0145 MW-54-146'-(001) 0.21 ? 0.22 , 0.36 0.05 2 0.09 , 0.15 -0.03  ? 0.16 , 0.32 0.02 2 0.09 , 0.19 1697W0146 MW-54-174'-(001) 0.07 ? 0.21 , 0.38 0.00 k 0.10 , 0.22 0.02  ? 0.16 , 0.32 -0.06 ? 0.09 , 0.24 1697W0147 MW-54-192'-(001) -0.04 ? 0.24 , 0.46 -0.08 ? 0.08 , 0.23 0.00 2 0.19 , 0.38 -0.08 ? 0.13 , 0.32 t

B

TABLE 6 (Continued)

CONCENTRATIONS OF SELECTED ALPHA EMITTING RADIONUCLIDES IN DISSOLVED FRACTIONS OF WATER SAMPLES AP11, REVISION 3; CP2, REVISION 12 INDIAN POINT POWER STATION BUCHANAN, NEW YORK i

TABLE 7 CONCENTRATIONS OF PLUTONIUM-241 I N DISSOLVED FRACTIONS OF WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS APlO, REVISION 3; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK ORISE NRC Region I Radionuclide Concentrations, Sample ID SampleID TPUs, and MDCs" @Ci/L) 1697W0142 Mw-54-38'-(001) -2

• 37b 63 1697W0143 Mw-54-59'-(001) 8

• 34 59 Mw-54-125'-(001) 9 i 35 1697W0145 Mw-54-146'-(001) 5

• 34 59 1697W0146 Mw-54-174'-(001) 3

• 37 63 1697W0147 Mw-54-192'-(001) -6 t 36 62 T h e MDCS are afrer the comma.

bUn~ercmoesrepresmr h e 9594 confidence lwd, bascd on total propagated uncertainties Indian Point Power Station Prqlects/l697/Data Tables/2007-07-31 Inte-Data Tables 1697 Set 24

TABLE 8 ORISE NRC Region I Radionuclide Concentrations, Sample ID Sample ID TPUs, and MDCs' @Ci/L) 1697W0142 MW-54-38'-(001) -0.8 f 9.4b , 16.1 1697W0143 MW-54-59'-(001) -7.2 k 9.4 , 16.1 -

1697W0144 MW-54-125'-(001) -6.0 f 9.4 , 16.1 1697W0145 MW-54-146'-(001) 0.3 f 9.5 , 16.1 1697W0146 MW-54-174'-(001) -1.7 f 9.4 , 16.1 1697W0147 ME-54-192'-(001) -5.3 i 9.4 , 16.1 m e m c s are after the c o m a .

bUncertmties reprerent the 959b confidence level, based on totdpropagated uncert&mes.

In&m Pomr Power stauon Pr~ects/lG9l/DataTabler/2007-07-31 InteMl DataTables 1697 Set 24