ML18152A401

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Responds to Telcons W/Eh Greene of VA Power'S Air Quality E Dept Re Use of Methylene Chloride in Paint Shop of Surry Power Station.Requests Confirmation That Painting Operation Exempt from Toxics Regulations
ML18152A401
Person / Time
Site: Surry  Dominion icon.png
Issue date: 05/11/1995
From: Hadder A
VIRGINIA POWER (VIRGINIA ELECTRIC & POWER CO.)
To: Zoeller J
VIRGINIA, COMMONWEALTH OF
References
NUDOCS 9505190088
Download: ML18152A401 (11)
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Text

  • I Innsbrook Tech11ical Center 5000 Dominion B0ule1*ard Glen Allen, Virginia 23060 May 11, 1995
  • VIRGINIA POWER Ms. Jennifer Zoeller Environmental Engineer, Senior Department of Environmental Quality 4900 Cox Road Glen Allen, Virginia 23060

Dear Ms. Zoeller:

This is in response to your telephone conversations with Mr.

Earnest H. Greene of Virginia Power's* Air Quality Department concerning the use of methylene chloride in the paint shop of the Surry Power Station. Pursuant to your request we have gathered specific information regarding the actual application process of methylene chloride and Epco-Tek 2000. The result of our investigation and subsequent calculations indicate that the emissions from the methylene chloride application project are below the exemption level in Section 120-05-0301 D.1.(c) of the Virginia state Air* Pollution Control Board Regulations, Standard of Performance for Toxic Pollutants. Therefore, Virginia Power is requesting confirmation that the painting operation is exempt from the toxics regulation.

On June 15, 1995, Nuclear Site Services at Surry Power Station is planning to begin painting the Unit 1 high level trash racks on-site with an antifoulant coating system called Epco-Tek 2000. This copper-based epoxy resin is 100% solids, solvent free and toxin free. However, because of the dense formulation of Epco-Tek 2000 it is necessary to thin it with methylene chloride for most applications.

According to preparation and application instructions, up to 1\

quarts of methylene chloride should be mixed with each gallon of Epco-Tek 2000 (assuming an ambient temperature of 70 °F) in order to achieve the desired unif arm consistency and to establish a proper spray pattern. The instructions also recomme~d mixing the coating and the thinner in one gallon batches.

The entire coating project consists of sixteen (16) racks and sixteen (16) beams. Each rack will require no more than seven (7) gallons of Epco-Tek 2000 and each beam will require no more than one ( 1) gallon, therefore, the entire trash rack restoration project will require approximately one-hundred and twenty-eight (128) gallons of Epco-Tek 2000. In accordance*with the preparation instructions for Epco-Tek 2000, station personnel will mix up to 9505190088 950511 PDR ADOCK 05000280 Cft)\ I P PDR

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  • Ms. Jennifer Zoeller Page No. 2 forty-eight (48) fluid ounces of methylene chloride with each gallon of epoxy coating. The entire project will require approximately six thousand one hundred and forty-four (6144) fluid ounces or forty- eight (48) gallons of methylene chloride *

. According to Virginia Power employees involved in this process, only one (1) rack or no more than seven. (7) beams will be coated at any one time. Each rack and each beam will receive 4 coats of Epco-Tek 2000, with at least a 10 minute drying period between coats.

Our conclusion that the methylene chloride emissions from this proposed project will be below the exemption level is based on the attached information and -calculations. Once you have completed your review of this information, please contact me in writing, with your decision.

Thank you for your expeditious review of this matter. If you have any questions or concerns regarding this one time coating project, please do not hesitate to contact me at (804) 273-3023.

Very truly yours, A. W. Hadder Manager Air Quality cc: u. s. Nuclear Regulatory Commission Attention: Document Control Desk Washington, D.* c. 20555 Surry Power Station Units 1 and 2 Docket Nos. 50-280 and 50-281 License Nos. DPR-32 and DPR-37

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  • Surry Power Station I

Methylene Chloride Usage Calculations Preparation Instructions:

  • 1\ gallons or 48 fluid ounces of methylene chloride per gallon of Epco-Tek 2000 (see attached information)
  • 48 gallons or 6, 144 ounces of methylene chloride for the entire project Project Information:
  • 16 racks
  • 7 gallons of Epco-Tek 2000 per rack
  • 16 beams
  • 1 gallon of Epco-Tek 2000 per beam
  • . 128 gallons of Epco-Tek 2000 for the entire project Regulatory Exemption Level:

For toxic pollutants with only a TLV-TWA, the following exemption formula applies, provided that the potential to emit does not exceed 22.8 pounds per hour or 100 tons per year:

Exempt Emission Rates (pounds per hour) 3 TLV-TWA (mg/m ) X 0.066 174 X 0.066 = 11.48 pounds per hour

e Application process:

  • Epco-Tek 2000 (E-T) & Methylene Chloride (MC)
  • 7 gals/4 coats= 1.75 gals/coat
  • Maximum application rate of E-T = 1.75 gals/hr
  • At least 10 minutes drying time between each coat
  • 1.75 gals of E-T/hr X 48 fluid oz. of MC/gal of E-T = 84 _fluid oz MC/hr
  • 84 fluid oz of MC/128 fluid oz per gal= 0.656 gals of MC/hr
  • Density of water@ 25°C = 0.99707 gm/ml
  • 1.31 X 0.99707 gm/ml= 1.306 gm/ml of-MC
  • Conversion factor for gm/ml to_ lbs/gal= 8.345
  • Density of MC= 1.306 gm/ml X 8.345 = 10.9 lbs/gal
  • 10.9 lbs of MC X 0.656 hr of MC= 7.15 lbs/hr
  • Maximum emission rate of MC= 7.15 lbs/hr

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2000 iE CHEMICAL CORPORATION 100% Solids Solvent Free Toxin Free, Foul Free Epoxy Coating Recommended Use D For protection of surface against marine growth in seawater service D Ship hulls, props, bow thrusters, support struts D Barges, floats, off shore platforms D Marine structures Features Two component epoxy systems, cures to a dry hard. finish.

Releases no toxins or heavy materials to environment.

After three years testing in saltwater, does not support Macro-Fouling.

Provides protection against abrasion form suspended solids, and maintains corrosion resistance.

Specifications Pot Life .........2 hrs.@ 77° F. 25°C. Dry time ..... 12.0 hrs.@ 77° F. 25°C.

Recommended film thickness 8-12 mils Ratio by weight .................. .

Flexural strength ............... psi Tensile strength ................ psi Terisile shear W' ............... psi Coverage sq. ft./gal @ IOmil OFT~ lC.O T.AJo....<.pply EPCO-TEK 300 over EPCO-TEK 225 within the 8 hour9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br /> window (as soon as the EPCO-TEK 225 becomes tacky). Spray 0.006 inch thick application in one coat Coverage will be approximately 250 SQuare feet per gallon. Apply EPCO-TEK 2000 over EPCO-TEK 300 when EPCO-TEK 300 becomes tacky (3-4 hours).

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EPCO-TEK 2000: Coverace 94.2 sQuare feet per gallon @0.017"; 160 square feet per gallon~ The heavy (0.017" thick) coating is established to give a finish resistant to severe mechanical abuse. Do not use less than 0.01 O". The copper contained (71 % by weight) settles to the bottom of the Part A package CQntainer. Preliminary mixing of Part A container facilitates transfer of the material. An agitator having no burrs or sharp edces is necessary to prevent shavinc plastic particles from the container. Mix in 1 gallon batches.

Transfer the contents of Part A Base container into to the pressure pot using a metal spatula. Agitate to a uniform consistency and add the Part B Hardener while agitating. Mix to uniform mixture. Add 1*1/3 quarts (use Part B container for measuring) of measured methylene chloride (assuming an ambient temperature of 80 degrees F) and mix to uniform consistency. Note: Unttormitv Pl the mb; ;s yery important If the ambient temperature falls to 70 degrees F, 1-1/2 quarts of methylene chloride will be necessary to establish a proper spray pattern.

A 2 gallon Binks agitating pressure pot combined with a 68PB X 68 nozzle with a 568 needle is recommended for applying EPCO-TEK 2000. A rough finish is obtained, but you will have increased application rates and fewer problems with line and gun clogging. Other nozzle combinations may be used. The cun should be held about 12 Inches from the surface to allow the methylene chloride to escape and not be trapped in the surface. Check spray pattern and adjust to obtain a uniform atomization. Run the agitator at about 800 rpm initially cutting back to about 300 rpm as the liQuid level drops. Do not beat air Into the mixture. The first pass over the EPCO-TEK 300 should be 0.001 "-0.002" thick. A second pass should be 0.003* thick. Additional passes should be about 0.004* thick. EPCO-TEK 2000 can be over-passed every 15-20 minutes. Afinal coating thickness of 18-22 mils is desired.

Curing time: EPCO-TEK 2000 must cure for 24 to 48 hours5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> (dependent on ambient conditions) before activation.

ACTIVATION: Note: When EPCO-TEK 2000 cures an epoxy blush forms over the copper particles. This blush must be removed to expose the copper or the material will not be antifoulant The entire coated surface must be activated; fouling will occur on unactivated surfaces.

Lightly sandblast eithe"r (wet or dry); Use 40F grit or finer to activate surface or Armex Blast System using Arm & Hammer baking soda; or wet sand with random orbital or by hand with 220 wet/dry sandpaper.

The longer cure time is before activating the easier it will be to successfully activate (EPCO-TEK 2000 will continue to cure for a week

@70 degrees F). EPCD-TEK 2000 is formulated for highly moist environments, it will cure under water. It should not be applied to damp surfaces.

MAINTENANCE: Periodic inspections of the EPCO-TEK 2000 installation are necessary no less than once annually, preferably Quarterly. If an area of the coating is found to contain marine growth, the surface should be cleaned and reactivated by lightly sanding or otherwise abrading. If an area is found where the coating is missing, repairs can be made by applying the necessary amounts of undercoating and EPCO-TEK 2000 to fill that area. Installation of repair coatings must follow the manufacturer's recommended procedure for EPCO-TEK 2000 application.

NOTICE: Before using this product, read the entire Directions for Use, Spill Information, Storage & Disposal, Precautionary Statements, Specification Statement of Practical Treatment, Environmental Hazards, and Physical and Chemical Hazards appearing on the container label.

CONDITIONS OF SALE AND WARRANTY:

Hi-Tek Chemical Corporation warrants that the product conforms to its chemical description and is reasonably fit for the purpose stated on the label only when used in accordance with label directions under normal conditions of use. HI-TEK CHEMICAL MAKES NO OTHER EXPRESS OR IMPLIED WARRANTIES EITHER OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE. Handling, storage and use of the product by Buyer or User are beyond the control of Hi-Tek Chemical and Seller: Risks such as ineffectiveness or other unintended consequences resulting from, but not limited to weather conditions, presence of other materials or failure to follow. label directions will be assumed by the Buyer or User. IN NO CASE WILL Hl*TEK CHEMICAL OR SELLER BE HELD LIABLE FOR CONSEQUENTIAL SPECIAL OR INDIRECT DAMAGES RESULTING FROM THE HANDLING, STORAGE OR USE OF THIS PRODUCT.

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CHEMICAL CORPORATION 106 Taft Avenue Hempstead, NY 11550

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MATERIAL SAFETY DATA SHEET CHEMICAL CORPORATION 106 Taft Avenue Hempstead, New York i l 5SO 516-538..0400 I - IDENTIFICATION CHEMICAL FORMULA--**---* - MOL.ECUL.AR Wl!IOHT CH2CJ.2.---------~84g,,a.;19t::14~-~

Grade 001 IPENTIFICW"ION NO.

L.-.......1~"'4¥,l,lo,l,llio,,,),all,,W,i,~ola...----*~----~~--~~---~---~~---*---*--Witf"'-"1..,59,..l'-------~~~------~___.J

~ N l ' i l ) CHEMIC>,1.. N~I -- Ii- PRODUCT .......

AND COMPONENT DATA CA.8 f\e{.)IVTRY NO, Ill>~ ACGIIH Ti,.Y,TWA fr Ilichlbrmetham 75-09-2 >98  !() ~

"' Prq,yi.n.t aclda 75--SH 20 PCl!S

  • ~~~to rtPOl11ftQ rHjU!rem1n11 ol kcillotl 3\3 or Tlllt In QI ltw 1860

~ ~ a n d ~ , I o l i Ao! {8.'.M) AN 40 Cl'!'\ Pan :1711 111- PHYSJCAL DATA APP~~OOOR - SPiOill'IO GRAVITY Cl.aa.r, colorl.M1 liquid; nd.ldly eweet cdor 1.31 @ 25/~°C DOIUNG POltff *-- VAPcm OiNlmY l"'l ,tJ" (Air

  • 1) 103.1*11 (39.s*c> 2.9 V,V>Cf\ PAESSURi
    • -----.... -. VOi.ATILE, llY VOLUME_, .*** -***--

352 nn Hi I 20*c 100

£\'APORATlON MTI SOLUBILITY IN WATER (eder

  • l)t 0.7 1.32 ~100 ~@ 2.5*c IV - R&ACTIVITV DA l A STABILITY CONDITIONS TO Alr'OID -"* ------*-

Stahle Avoid contact: with cpen f ~ . ~trle m-es, or cthar hot liP.lt'face:&

~licll mn cawi,a thez:mal deo~1t1on.

INOOM.PATI81UTY (Malerialt IO avoid')

Strcrg alkalle.i

  • oxygan, n.tt~n perc>>ddt. eooim., t>Qta&sium, an:! other addiztra M:f reaetiv~

mtals. Refsr to Sect:ion VIII for additional Wormation M alll'Ttin..rn.

~~G OEOOMPOStTtON PRODUCTS j

H~an chl.ortde. ph:)sgene, chlorine.

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HAZAADOUSI POL YMeA!ZAT10N Will rot ocwr.

  • V - FIRE AND EXPLOSION HA%ARP tlATA FIJ.MMADL..E Ul,UTS 0
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EXTJNQWSHINCI NJ.ENTB

. , .- 12 *- 19% !Vol.) @ 100°c Wstc f ~. dry chemical~ foam, c::arbon di o:,d.dct UNVSOO.FJA!ANOlXPI.O&IONKUAAOI Cci=ttteted vapors ~ ~ l i d by ~--intermty ign1ticn ~ * ----**-**

Pinfiahtan ah::w.d wttr aeli-contained poe1t1ve presr.Jre 1re.a.thifl? app&NC:u8 due to t:r.'mll s o:>ntact, VI - TOXICITY ANO FIRST AlD 1-EXPOIU--~Ai~UM~IT8~(W~'*.'"".""""':""~':":IO~lt\ll'l~~:-:ll'l::7it:-P'Od:::::::::ll0!::"".,~nd:-'.:'::L'llhe:=:-:rCheml:::::;:o.::i1,:""i.i:'::~rren1. lht IXpOSUr-. hmlt fll~be delin.d ill the ~°'.J **-- ***

.AQllRz SO J>?'6 '.I.WA (8 hr) !NU1 500 p~ lWA (8 hr) la'OXI p~ ~ (29 CFR lSllO,loo:.1)

(O:br thtesh:ild appMdnst:aly 200-30:) pr:m; causes olfactory fat~).

Prcpyllw ad.de: Nmlir ~0 Pt:m lWA (8 hr) CffiA: lOO pµn (8 hr) 7WA

~ i o n c4 IUCOOOlia bA~rages may in~l"E!8'1$ th. potent:!.Al. tor de'11!!1.opttlnt: of cCDd.c effaec11 NeW.~ frm ~ r e to thU product,

~ ,11 G1-..o' In 1h11 leCC*'1 art ~ not IO COOIJr K ~ I N Mt l!\llr,tall'\.o ll 61 btlow 11pprt>Priate TL~.

e.oai.. ~ 1M ll'idt 'AlnllOM In indiYldllA( w.oeptlbllhy. I ~ ~ l ' I ~l'llllt l'l\o\y ~ be a?l)IICM4blt IO 1111 pol"IOl\t tiod lhOM wllll IMd\cal DC>Milionl lilll8'0 belo,II.

MfDIQAL. QOHDITlONS MI0"4111ED rrf E><fll'OIURE A.l.echoJJ.lm, aaJt:a llld c:hraUc liver and ld.dno)' cli.aease, chrcmc luQg disease, armi&, eor~ disaase or ~ clUorders of the blart:,

  • AOUTI '1'Qll(ICITV Pt1m1tY IOIMl(IJ tit llepaeU19: ijJ lnt\f.lallon -- tk111 ~ 0 lnpmk>n * .

l.rhu.atialr Major rwte of sx,tential e<<po8t.1r6. I-Ethylene chlod.dt depres$eit t:~ c:n:ral oor-voua 9)"Stem. ~ n t t a t ~ between 900-1,000 pµn my cause. d11:d.r.ess. NaJMa, haar;i&.che, and

\,m1.t~ can ocQ.lt' at a:iocent~tions ~ 2,0CX) pµn. At 7 ,rxtJ Pl'.al, nmim11et and tireting 1n atma a! legs ft! ~ heartb&At: h!ve occurred. Losa of COtl3.c.1wsress ad des.th hQV$ ~rrad at UYUJS abave 9 ,CIXJ p~, ;fl cq.iosure is prol~.

~ o b 1 n .1..eval.l cmt te el1;Nat:ed 1n peraons a,q:>.'.)800 tc, ntlthyleni, chl.oride a"ld can ~ e

.a aubs~a.l. "tt"eBs on tha. oetrdiCNasCl.tl.ar BYBtem* This elev&tico can 1::.e ~t1ve eo the 1neNB:Be caused ~ ~ an:! ott.!r es,r\.,oo ~ d e SOUl:'CJ!So Sld..n: Liquid m3thyl.e,n& chloride u. PA1nful aoo im.tat~ if oonf:1.ned to ddil ey g ~ .

ciothing, etc. ~ Ctr repeated contact may C81.J$e 1nitation 1 de.fatttll; of ildn, an:! der-mat1t1a. Ab,orption t:hro.¢ .1nt:act skin :is ):IOSSible 1f c:ontact with liquid u p:t'()J.o~.

Propylana (>>Cide SI a J.lJI'8 9..l'tst&'OI, has c.aus&d Allergic naar.tioo if N~t:ed ~e.ct ccwn;.

~ : IJ.q_ui.d ll'Bj' caw1e te.cpOiar)' 1rtitation w.l.th ~mtY come.al injury. Vtq>ON ms)' irri-tate e::,w,

!!E;et1tioo1 Si.fw.e cbae ta>d..d.ty lcu to UPderate, lf van!.t~ oorurs, nethylene chlorlds can ba asllinted into J.urltS, wch can cause cnemil"Al. pne.JD:>nia an:! systemic affects.

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Imal.at1au Ra,ve to fresh ab*. If breath.i.re has 8tor,pod 1 &dlllinister axt1f1cl.al tupiration.

eait a ifo,sic1ao.

!kinr P.a,ve o:xltani.n&too clot~ &\n:1 sroes, Wa..h expoee:i aru th::>rrughly With soap c-d

'wiiter for at least 15 miwtes. Waah cont~ted clothing oo£ot1, reuse.

~1 Flush e:,,m il=idiately with wa~er for at leatJt l5 miootefJ, If irrJ.tat:iQl.'I peraist.t, C<'lll a i:cyrld.-i,

'fm'est1'xlr ~ roe Wuce vcmiting. ~'lt61.Ct 7X1Ysician or emargen::y lnilclical f&c111ty itmadj,ateJ,y.

N~ ID FHYSICTANr ~ n should rever 'tx. givan to person ~ e d to nstt\Yl~ chloride,

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pH~IO-n:,)(IO!TY 'lhe og e~ c tad.c eff6Cts in

~ ~ te avoided, failure to cb AO ca.ild tWUlt 1n iajury, 1lltte8a or wen death.

ChrcXlie ~ t:o o:ethylere d\loride have 03uaed JJvt,>r m:f kidney tClldc rifect1:s in experi.ir)c>rJ.tal boratory e:ums.Ja.1My miicste tOJCicit:y to h~.

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~ c i t y l Mtt~lene chloride twi teen evaluatEd tor JX:)8s1ble <YJncer calJ$t~ effr:ct:s :in ..u1ooni.tory a.n1Jl:els, Ima.lation seudies at ~ n t r a t ~ of 2,000 1 aru It ,ocn P?Tl increased the inc.1.dence of ma.U.gnant liver sn.i l.ur6 tlffl)I"B in mice. Three .inhalation atud.{~ of ntta have sh::,..,n 1nc't'&a9ed ind.dl'U'lee o( benign ITlln'mlIY g ~ bln:>rs 1n frmale ~t.* at conccncratiOM of 500 p~ ~ above ar"d i n c ~ .1n bar'dgn DIOOIJllry gla[)j t:uiors 1n ma.lM at OOllCentratiot'N of 1,500 ppu an:3 aoovu. RAt.9 ~ a d c:o .SO an:f 200 pµn via inhklation ~ rx> inc:ree.iaed 1.ncideriee of t:11:trors. Mi.CJ:! ar-.;r rats ~ by ingestion Rt levels up to 250 ~ d a y llf1t~ soo ha:mtQrs axposed via :1.nhalll.t:ion to oonolillltratiOM Up to 3,500 PJ:ll\ llf,-

t1- d1d tt>t eb:u an increased facide~ o£ wn::i~. .

Prq>ylena ad.de ms caua~ 1n~reased ir1clcieni::e of nasal b.Jrlon; 1n rnca ex;')('lied by inhaliition, forestoo.(lch tw;ite in mt* expose:! )!,, gavage (for.md-foo in ail) b.1-rl 1.rt1ect1.011 site ttmors ii.ten injected ;urd&r the skin of rats.

The lntQmat.ional ~ for Rese.at'Ch a1 c.a.ncei- (!ARC) hna ~lud.ad that there is &i.fficlent evidallOO for the aireincg'80iclty of net11Ylene cillor.Lde to ~d:ment:al anirtels, sn:f ina:i~uate Mden:e for Chi car~c.1.ty of irethylenQ i:hloride to ~ . re!tUlti~ in .o. el.assifkation as a 2B animal card.negen.

Tre NIP has ide?ltie1ed rrethylel'w;I d\loridt a;i an arwM.J. a i r ~ . tut it :is rot en t:ht). ~ or NIP lists* as of Sep!:tnlber 30, l9$B., Prq,ylane .Did.de raa l:oon 1dent1£11d ~ an aniratl eardn~ian by !ARC aoo NIP, b.lt 1s tr:><: oo tba ~ list, Epi.dmd.logy atud.1.es c.if 7SI h..J!mns ch.rlxlic11.lly expo$ed t:u rmteylene chtotide, in ~ ~rlcpl..aoe of ~ch 2.52 ware expooerJ for a mln1m.w of 20 years did 'l'Dt d~t:nit~ ~* inc~e 1r1 dBat:hs c.tuaed ~ ~ r or am.tiac prob).emg. A secoo:l. study cir 2 .227 ~rlcel'$ confirm=:! t ~ ?:eSults.

~roductive ¥,cl.tr: Re;:>ror.luctive to>ct.c"Lty tests hiV6 b:!cm wnductoo t:o evaluate too potentuil ~rse effects methylene chloride PJaY him! oo repro::!uc:tion errl offspti;r.g of labol'l!lrocy an.tmus. 'lbe results ;u,-

d1cata c:hat m!:hyl.ere chloride &>es Mt cause birth defects :In labotat:ozy ~ .

VII - PERSONAL PROT!!CTION AND CONTROLS RESPIRATO~ PROTEc;noN

~re v~r concentration ma::ee::ls ot if, likely to excee::! ~ ?FOi !!Ethy~ chloride, Ml approved full fact respirator with organic W{)Or m.onister ifJ acceptable. Appt'We(f 9e.lf-c0l.'¢~ m-eathityz ,ipparat:us 01" All' line respirator, With full facepiooo, 18 tequired for nethyl.ere chloride o:,ncentraUom above l ,CXXJ ?JD .rurl VSNTILATION for B?1U. ttn'l/or erm:rgardes, Foll.o.r arty aµplicahle resr,1rator use stSMU'ds 8[}d regul.at:ialS.

Do not use 1n cl.o.it.d or ronfined ~~ce. O;:en c:bors 11M./or ~ , Uiie ventil.5tioi\ to mtlntain ~ n ,

levrJ.11 of rrethylene chloride t61ow 50 Pllh (TWA). ..

SKIN PRc,rECnON Wear &ol..vwrit-resist&lt glO'VOil such m Viton, polyvinyl alc(Yiol, or equivalent. Solvent-res b t ant 1:x>ots, apron, ~ strl/or faoe,ihicld sh:w.d l::e ~m where splashirg

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.. ___possible, EYE PAOTECTICN Wear BAfciey gwlK!6. Contat.:t ler~ shr:uld rQr,; be worn. Ol!r.d.w goggles anct/or f&M shielda "mud be wom where gplashing is ~ii1ble.

HVl)liNi AV¢id o:xtt.act with ekin c'd &V'Clid treathill; VllpOrs.

h.srds pr.1.or to eat~, dr.tnlci.ng, or using restroan.

!xi rot oat, drink, or ~ in work area. Wuh .

~OTHEP. CONTR~ l,le,MV111\H To detemdne ~ leval(s), nonf.tor.f:r~ stn.i.l.d b2 perfotm'=d regularly. Safety ah:Mer e:r-.:1 eyewash station sl'oJl.d bi! available.,

NOI'.E: Protectiw equ4iacnt m)j clor.lttr~ Bh:uld t:e selected, iNed, sn:I muntained according to ~pl.ioabl.e.

S tania.rdJ; ~ regulatioos I For furtter Wo~t1on, contACt. t'.ha cJ.ot~ ~ equ:ipu3nt msrufacturer or tht Vulc:sn Chmrl.oals Te:mical Servic:e depart'.rreC'lt,

  • VIII* STO~AGE AND HANDLING PRECAUTIONS FollcM ptQtoct1YI control.a Bet forth :l.n Sact1on VII ~ h8n:lllng thia pro:foc;t.

Store labeled sealed c.,:ttainers .tn ii c:ooi, dry. ~U.-..entil8~ area rut of aunllght. l>revent we.ter or ir:oiit air frcn ent.eritw storage t&i(..e or c:ont:ainet'&. lb ll')t c:ut er weld i:r:'I Gapt)' or !ul.l ~ .

AJ.'I.Ci.Iuu oqui~ sb;iuld tx>t be UBed for c,torage ~/or ttanSfar, Q:ttact With &l.l.rninJli ~ e :tn a presl!alril!&bla fluil! 11}'Stem tllllJI' CAUSe violent ~tions, Consult e q ~ 9..1ppl.1et tor further infonna.tion.

Vapors are heavim- tMI'I air and will collect 1n low areaA. Do rot ent:&r c:>nfined spaoas 9..lch

  • t4nks or pits "'1.thoot f o l ~ proper Anet>' procedures a.1ch as ASIH I>-427 6.

Do n:>t nmwe Qt" daf'aoa label, Do n,t tsJBe drum withcx.it recycling r:,r 1'lleot'd.1.t1~ 1n acrordw}oe with E6TY applicable tederal. ,ui:e or local J.aww, .

IX - 8,,JLL, LEAK ANO DISPOSAL f'AACTICES BTEl"S TO BE T~KEN IN CA8-E! MA'lcFUAL IS RliLEl.81:D OR 8_.ll.LEO *-*

M ~ tht at'8&, vam:il.etet *aoo awid lre,at:hlrig W,P0I'lh D!kfl 8t'M to coota.1n ap:Lll, CJ.esn

\JP are.a (wu.r protective eguiJm!lnt "." t'Afer to S6e.t1oo VII) by nopp~ '1t with abaorl'ent tnater1al .id pl.&ol 1n eloaed ccntaineni for di5posal, Avoid oont!minat1on of grour'ld arrl aurfaoa watera. Oo n)t flush to ~ r .

If spill ~ :tncbors. turn off resting ar-4/or air cxntit:iooing ayste:e, to prevent vapors f ran contazd.nati%lR' entixe '- ,I 1,U .......

WASTE DliPO&\I. MITHOD

' -****-****** *~-

~ r e d liquids tll!Y bt ~ to a l l ~ ~ r or ~ration .facility. Cootmninlll:ed astetlal mJat be dinJX)eed of .in a )*lllitted waste ~ n t : facility. c<<iiiul.t federal. *cat., or looal

~JX)641 att.l'Crttiee f o r ~ pJ:'OOlaldures.

X- TRANSPORTATION oar KAZ.ARD cuss1F10Af10N

}b:)e trJ' l..arrl ar water ttansµ,rtatiet1 when oontainera are. lefle thnn 1000 11:a each. ~when eoot.tlneni ~ m:>re ~ 1000 lbs each or \oiOO.n transported ~ a1r 1ri ~ size o:ntaina?'*

PL..'C,4.RO RilOIJIJllllt)

~

L.Aal!L ?.eo(Jll'IED

.... ~.

wbal M required ~ 09:l.\ Huard Camunioation St.mint'CI* 8Q:i itny 4pplioa.blci at4te mid l.oca1

-regul..t.t .i~' Uee H!!IDllful label whan transµ,rted ~ air.

for any oth,r Information contact:

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CHEMICAL CORPORATION 106 Taft Avenue Hempstead, New York 11550 L-------------------*----------------------------..1 NOTICE.! \lulc&.I\ Ch*mio.!9 o.!1WH 111&1 111a lnfO<TT1atiQn DOl\la1r,ec, o~ thi* 1.4e1onat S&l*ty Dal.I S'-1

  • lltlfXll'aia. rne au~.o p~~ an t>uea on lll!P4lr'otnot aa of v-,. ~ al ?UbliO*!JOtl. They a,1 l'IOI r,~rl~ ,11-1r.ch.1,1Yt ~ lully ~ ~ I
  • In twry 04rcurnt1a110e. ~ . !hi 1~i0nl ~ nQ( bt oonl.iMO wilh nor ~ Ill vlo!&I iot, ol ~IO&blit lewt, 19gulatlon. Ni.. 0t lr\llurance r.qultem anta.

NO WARMM'tl', t.Xl"~l!JUI OR IMPUEO, 01' Ml!ROHANTABIUT't', ftl'rNl!SS OR OTHEAWISI: II MAC>e,

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