ML20086L855

Provides Results of Water Supply Performance Evaluation Study 36, for Laboratory at Davis-Besse Nuclear Power Station

ML20086L855
Person / Time
Site:	Davis Besse
Issue date:	07/17/1995
From:	Jeffery Wood TOLEDO EDISON CO.
To:	Murff N ENVIRONMENTAL PROTECTION AGENCY
References
RAOG-95-19, NUDOCS 9507240037
Download: ML20086L855 (9)

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TOLEDO EDISON A Centerior Energy Company 0E 3 1 July 17, 1995 ,

PA0G 95-19 Hs. Natalie Hurff, PE Studies Quality Assurance Research Division, ARD, NERL l U. S. Environmental Pro +.ection Agency j 26 West H. L. King Drive, Room 525 ,

Cincinnati, Ohio 45268  :

Dear Hs. Hurff:

Subj ect: Results of Vater Supply Performance Evaluation Study 36 (US 036)

Enclosed are the results of the Water Supply Performance Eva hation Study 36 (VS 036) for the laboratory at the Davis-Besse Nuclear Power Station. The  ;

result of the Quality Assurance sample for turbidity is entered on the enclosed survey forms. Analyses of the remaining analytes are perforned by certified off-site laboratories contracted by Toledo Edison. Therefore, their. ,

results are not included in this report.

To avoid any confusion, please address all future VS studies to " Environmental-Supervisor" instead of " Robert Schrauder".

Please contact Mr. Villiam T. O'Connor, Manager - Regulatory Affairs, at .

(419) 249-2366 if you have any questions.

Sincerely yours, ,

/ ,

d ht. hn lr$.

J n K. Vood A. M. Percival  !

Plant Manager 2-90-37 Davis-Besse Nuclear Power Station Class II Operator Vater Supply  ;

.TKW/lkg .

1 Enclosures cc: Z. A. Clayton, Ohio Environniental Protection Agency Mr. James D. Dolfi, Ohio Department of Health Laboratories /

U. S; Nuclear Regulatory Commission Document Control ~DesE

. yf a r 9507240037 950717 I )

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4' WATER SUPPtY LABORATORY PERFORMANCE EVALUATION STUDY ..

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FNVIR0fetENTAU PROTECTION. AGENCY .' . ,

, ,  ;.. , 4, . i E,; STUDY No..WS036. ,,- ,3.,. ,, .. . . . . ,

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DAVIS-BESSE ROBERT.SCHRAUDER NUCLEAF PCEER STATION 5-  !

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REPORT APPROVED BY:

John K. Wood Plant Manager (419)249-2435 7/g/pf NAME (Print) / SIGNATURE TITLE TELEPHONE '0 ATE This report is authorized by law (Public Laws93-523 and 99-339). Successful annual  !

participation in a water supply study or its equivalent is mandatory for every analyte or  !

analyte group for which a drinking water laboratory is certified to conduct official analyses. l l

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Paperwork Reduction Act Notice Public reporting burden for this collection of information is estimated to average 8.35 hours4.050926e-4 days <br />0.00972 hours <br />5.787037e-5 weeks <br />1.33175e-5 months <br /> per rcspondent. The estimate is based on analysis for an average of thirty-four analytes per respondent. The estimate includes time for reading instruct, ions, preparation of the performance sampics, analyses, gathering and reporting 'of the information. , Send comments regarding~ the burden estimate or any other aspect of. this collection of inforyation, including suggestions f;r reducing this burden, to Chief, Information Policy Branch, -2I36 U.S. Environmental

,~

' Protection Agency, 40I M. Street,'SW, Washington, DC 20460; and to.the'0ffice of Information

and Regulatory Affairs, Office of Management and Budget, Washington, DC 20503.

! EPA-359 (Cin)' '

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4 CHEMISTRY. DATA

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• • • ' Analyze for' Arsenicfin Samplo I using your routine method shich obviously should .be an, approved one. Use USEPA method 200.9 or 206.2 for Sample 3. If.you analyzed the special Sample 3 for Arsenic and you concentrated the sample before analysis, please indicate the concentration facter yo~u used . . .

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.T. uf , T Analyte Number & Name Sample # MC </> Quantity g;.> W *3;g fi f g ?': id6 M Y TRACE METALS? Y '

'C '

i i i i 235 Aluminum 1 l  !  !  ! pg/L i i i i 140 Antimony 2 1  !  !  ! gg/L i -i i e i pg/L 4

001 Arsenic *** 1  !  !  !  !  !

i i i i i 3  !  ! L  !  ! pg/L i

i i 002 Barium 2 '

! t pg/L i e i i pg/L i

141 Beryllium 1  ! t I t I i

i i i i

226 Boron 2  !  !  !  ! gg/L 003 Cadmium 1 l  ! l  !  ! pg/L 004 Chromium 1  !'

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!l i i i

pg/L i e j 091 Copper 1 1 1  !  !  ! gg/L i i i l i 005 Lead I  ! l

! gg/L i e i i 236 Manganese 1 1  !  !  ! pg/L i i i e i 006 Mercury 1 l  !  !  !  ! gg/L i i i i i 237 Molybdenum 2 l t  !  !  ! gg/L i i i i i 142 Nickel 1 l  ! j  !  ! pg/L i . .

007 Selenium 1 l  ! t g/L i i i i 008 Silver 2 i

1  ! l t i gg/L 143 Thallium 2 l l l  !!i pg/L i i i .i 239 Zine 1  ! ,

!  !  ! I gg/L

?MITRAIE&MITRITEL& FLU 0 RIDE' 009 Nitrate as N 1 l l  !!l mg/L 092 Nitrite as N 1  ! !l l  ! mg/L' 010 Fluoride 1 l l l l l mg/L EPA Fem ww55 PWW. M PWous A are otmokh im The data report kwm W e ;;i.md on the next page.)

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CHEMISTRY DATA Page 3 of 8

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.Results

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Analyte Number & Name Sample # MC </> Quantity l

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PESTICIDEN -

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'5' 093'- ' 'Al~achlor ~

.!'. 4g/L

!. . . t.  : t.

Aldrin 256 4  !'  ! l gg/L

. i . .

094 Atrazine 5 t  !  !  ! pg/L i i i Bromacil 240 6 ug/L i i i 257 Butachlor 6  ! l l

! 49/L 097 258 Total Chlordane Dieldrin 3

4 i

t t pg/L i pg/L 011 Endrin 1  !

49/L i

095 Heptachlor 4 1  !

t pg/L t

i  ; i . i 096 Heptachlor Epoxide 4 i  ?  !  ! 1 pg/L Hexachlorobenzene 172 4  !  ! '

49/L i . i . .

112 Hexachlorocyclo- 4 l 49/l l l l l pentadiene  !  !

012 Lindane 1 1 49/L 013 Methoxychlor \ \ I .

1 '

! pg/L 241 Metolachlor 6  !  ! '

! gg/L 242 Metribuzin 6  !  !!  !  ! kg/L 243 Prometon i iii

_6 t t i  ! ng/L 259 Propachlor 4  !

'ii ng/L 113 Simazine 5 t l

I t ug/L 014 Toxaphene 2 g/L 244 Trifluralin 4 l l l  !  ! g/L CARBAMATES 1'YYDATE i i i 098 Aldicarb I 1 i

!  !  !  ! 49/L l 099 Aldicarb Sulfone 1 i

i1 i

49/L t 100 Aldicarb Sulfoxide 1  ;

!  ! 49/L 101 Carbofuran  !  !

, 1  !  ! 49/L 245 Methomyl 1  !

! 49/L 114 0xamyl (Vydate) 1 l pg/L t  ! l l EPA Form 7500 55 (Bev. Mr$) Previous editions are obsolete. (Note: The data toport form is continued on the next page.)

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1 CHEMISTRY DATA - Page 4 of 8

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• Analyte Number & Name Sample '# MC </> Quantity N ,

- ;:y 77

, HERBICIDES H -

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'l gg/L-1 3 '

015 2 4-D  !- ,

.- il i i 016 2,4,5-TP (Silvex) 1  ! t-  !  ! pg/L-l i i i i 115 Dalapon 2 I t  !  ! gg/L 247 Dicamba 2 l l  !  ! pg/L 116 Dinoseb 2 l l l gg/L Pentachlorophenol I gg/L 102 1 l i i i i i 117 Picloram 2 1  !  !  !  ! gg/L

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+ : :FCBsi -

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i i i i i 118 Decachlorobiphenyl 1  !  !  !  ! t pg/L

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119 Acenaphthylene - 1  ! pg/ L___

i i 120 Anthracene 1 i

1  !

pg/L

. i 121 Benzo (A) Anthracene 1 1 I pg/L i e i i 122 Benzo (A) Pyrene 1 I t  ! gg/L i i i F 123 Benzo (B) Fluoranthene 1  !  !  !

gg/L i i i 124 Benzo (K) Fluoranthene 1  !  !  ! gg/L 125 Benzo (G,H,1) Perylene 1  !  ! gg/L i l . i i 126 Chrysene 1 pg/L 127 Dibenzo (A,H) Anthracene 1 l l gg/L 132 Fluoranthene 1 l l l gg/L i i F 128 Fluorene 1 i

!  ! t ug/L i e i i 129 Indeno (1,2,3-C,D) Pyrene 1 l l t  ! pg/L i F i i F 133 Naphthalene 1 l t 1 pg/L i F i 130 Phenanthrene 1  !  ! gg/L i

l i i gg/L i

131 Pyrene 1 l l l t M >m ~

i ADIPATES &lPHTHALATES-i i i i i 134 Di (2-Ethylhexyl) Adipate I t  !  !  ! t pg/L i i i i i 136 Di (2-Ethylhexyl) 1 l l l l l gg/L Phthalate  ! I  !  !  !

. . . . i 135 Butyl Benzyl Phthalate 1 1  !  !  !  ! gg/L EPA Form 750>55 FHov. 3-95) Previous editions are ottsolete. (Note: The data report form is continued on the next page.)

CHEMISTRY DATA Page 5 of 8

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'ni l S l 0 !'. 3. l 's - d.!H O ' 'O 1 4l 7 Analyte Number a Name Sample # HC </> Quantity i

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• M IPATES N HTHALATESS i

i- i 149' Di-n-Butyl Phthalate 1  !  !

!- gg/L l

'150

. Diethyl "Pht'hal ate' 1 'l '

l '! ' l. gg/L' i

l 151 Dimethyl Phthalate 1  !  !  !  ! l g/L l W

s nMISCELLANEOUS2SOCss -

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137 Diquat 1 l l pg/L l l

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138 Endothall 1 !I l gg/L l Glyphosate 139 1  !  !  !! l gg/L

/AS1TRIHALOMETHANES-  !

019 i i i Bromodichloromethane 1 1 gg/L 018 Bromoform 1 l gg/L

. i 020 Chlorodibromomethane 1  !  !

! gg/L i

017 Chloroform 1  ! gg/L i . . i i 021 Total Trihalomethanes 1  !  !  !  !  ! gg/L 1

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iAiREGULATED$VOCs1 I 039 i i i Benzene 1  ! pg/L i 037 i i i Carbon Tetrachloride 1  !

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!  ! g9/L 049 Chlorobenzene 2 '

!  ! gg/L 045 1,2-Dibromo 4 E Chloropropane (DBCP) f 49/L By Method 504 054 1,2-Dichlorobenzene 2  ;

pg/L 041 1,4-Dichlorobenzene i 1 i i 1  !  !

! gg/L 035 1,2-Dichloroethane 1

!. l gg/L 034 1,1-Dichloroethylene 1 l

! 49/L i i i i 043 Cis-1,2-Dichloroethylene 2  !  !  !

gg/L 042 Trans-1,2-Dichloro- i i i e i 2 gg/L ethylene l l l l l 055 i i i i Dichloromethane 1  ! gg/L 044 1,2-Dichloropropane i i i i 2  !  ! gg/L 048 Ethylbenzene 2 6 i i i i

!  !  !  !  ! gg/L 046

. 6 i Ethylene Dibromide (EDB) 4 i  ;  !  ! I pg/L By Method 504 l I I EPA Form 7500 55 (Rev. 3-95) Previous editsons are obsolete. (Note: The data report form is continued on tne next page.)

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. i CHEMISTRY DATA Page 6 of 8,

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Results". * 'l .

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Analyte Humber & Name Sample # MC </> Quantity  !

' * + M AS REGULATED VOCs? e

• v m  !

i i i 053 Styren'e 2- , ~.  !  ! gg/L i i i -

040 Tetrachloroethylene 2 {J  !  !  !

gg/L 047 Toluene 2 l  ! gg/L i l 036 1,1,1-Trichloroethane 1  !

! gg/L i i 061 1,1,2-Trichloroethane 1  ! t pg/L i i i 038 Trichloroethylene 1  !  !  ! pg/L 076 1,2,4-Trichlorobenzene 2  ! l 49/L gg/L 032 Vinyl Chloride -

1 090 Total Xylenes 2  !  !  !  !  ! gg/L JAS-UNREGULATED VOCs Bromobenzene 3 l gg/L 067 f

089 Bromochloromethane 3 '

gg/L i i i 108 Bromodichloromethane 3  !  ! I gg/L 062 Bromoform 3  ! pg/L 069 Bromomethane 3  !  !  ! pg/L i i i i 079 n-Butylbenzene 3  !  !  !  ! gg/L 086 Sec-Butylbenzene 3 l l

!, pg/L 085 Tert-Butylbenzene 3 l I gg/L

. i i 109 Chlorodibromomethane 3  !  !  ! gg/L 070 Chloroethane 3  ! gg/L i i ,

i 110 Chloroform . 3  !  !  ! pg/L 068 Chloromethane 3  ! gg/L 071 2-Chlorotoluene 3  ! gg/L i e i i .

072 4-Chlorotoluene 3  !  !  !  !  ! ug/L 057 Dibromomethane 3 '

gg/L 066 1,3-Dichlorobenzene 3  !  !  ! gg/L 088 Dichlorodifluoromethane 3 l l l l gg/L 056 1,1-Dichloroethane 3 l l l gg/L 059 1,3-Dichloropropane 3  !

i i i i gg/L 060 2,2-Dichloropropane 3  !  !  !  !  ! gg/L E' PA Form 760}$$ @ev.195) Previous editions are obsolete. (Note: The data report form is continued on the next page.)

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CHEMISTRY' DATA Page 7 of.8 ki ' '

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.; dStudy. Number EPA Lab'I.D.- -

~Rssults- -

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W'!S!0 '3 6 lo H !O ! O !1 !4 !7 '

Analyte Number & Name Sample # MC </> Quantity 1AS: UNREGULATED:VOCs6 - N 058 1,1-Dichloropropene 3 I

'49/L t

152 C'is-1,3-Dichloropropene 3 l pg/L 153 Trans-1,3- 3 l l l l l Ag/L Dichloropropene  !  !  !  !  !

{

087 Fluorotrichloromethane 3  !  !  ! Eg/L {

081 Hexachlorobutadiene 3  !  ! Eg/L i . i Isopropylbenzene

• l 084 3 .

!  !  ! 49/L

. i 4-Isopropyltoluene 083 3  !  !  ! 49/L

. i i 078 n-Propylbenzene 3  !  !  ! pg/L i 063 1,1,1,2-Tetrachloro-ethane 3

l l

l Ag/L 065 1,1,2,2-Tetrachloro- 3 l l l l l Ag/L

, ethane  !, 1  !

077 1,2,3-Trichlorobenzene 3  ! 49/L i I I i 075 1,2,4-Trimethylbenzene 3  ! 49/L 064 1,2,3-Trichloropropane 3 ' '

! gg/L 082 1,3,5-Trimethylbenzene 3 l  !  !  !  ! 4g/L ORGANIC-DISINFECTION BY-PRODUCTS--

250 Bromochloroacetic Acid 1 ' '

!  ! 49/L 165 Chloral Hydrate .ii 2  !  !  ! pg/L 157 Dibromoacetic Acid 1  !  !  ! Ag/L 158 Dichloroacetic Acid I  !  !  ! Eg/L 160 Monobromoacetic Acid 1  !  ! 49/L 161 Monochloroacetic Acid 1  ! l 4g/L 162 Trichloroacetic Acid 1  !  !  !  ! 49/L ilNORGANIC DISINFECTION BY-PRODUCTS.

193 Bromate 2 l l l

l 49/L l l

260 Bromide 2  ! '

gg/L l 194 Chlorate 1  !  !  !  !  ! g/L 195 Chlorite 1 l  !  !  !  !  ! gg/L 7A Form 76D553 ( Hev. 3-95) Previous editions are casolete. (Note: The data rvport form is continued on the next page.)

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CHENISTRY DATA Page 8 of 8 .

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f Study Number::-  ? EPA'.LabillD; lRe~sults. 5,Ib - .

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Analyte Number & Name Sample # MC </> Quantity

, ,  % 1MISCELLANE00S? -+ '

1 022 Residual Free Chlorine 1 l l  ! mg/L i 023 Turbidity 1 2 !2 l6

.l6 l0 NTU 024 Total Filterable Residue 1 l l l l l mg/L  ;

(at 180* C)  !  !  !  !  ! l i i i i i 025 Calcium Hardness 1  ; j  ; l mg/L l (as Calcium Carbonate)  !  !  !  !  !  ;

i i i l 026 pH . 1  :  ! Units 027 Alkalinity mg/L 1

l l l l l (as Calcium Carbonate) l l l  ! l 028 Corrosivity (Langelier 1 l l l l l Units Index at 20' C) l l

l l

144 Corrosivity (Aggressive 1 l l l- l l Units Index at 20' C)  !  !  !  !  !

029 Sodium I 1 l l l l mg/L 145 Sulfate 1  ! I l l mg/L 146 Total Cyanide 1 l l l l mg/L 251 Ethylene Thiourea 1 l l l l gg/L 252 Dioxin 1 l I

! l pg/L 253 Asbestos 1  !  ! l l l MFL EPA Form 7500 55 (Rev. 3-95) Previous editions are o ssolete.

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