ML20077M605

Forwards Results of Water Supply Performance Evaluation Study 35 (Ws 035) for Lab at Plant

ML20077M605
Person / Time
Site:	Davis Besse
Issue date:	01/03/1995
From:	Percival A, Jeffery Wood TOLEDO EDISON CO.
To:	Murff N ENVIRONMENTAL PROTECTION AGENCY
References
RAOG-94-51, NUDOCS 9501130119
Download: ML20077M605 (9)

Text

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TOLEDO EDISON A Centerior Energy Company T

OH 1

January 3, 1995 RA0G 94-51 Hs. Natalie Hurff, PE Studies Quality Assurance Research Division, EMSL-CI U. S. Environmental Protection Agency 25 West H. L. King Drive, Room 525 Cincinnati, Ohio 45268 Dear Hs. Hurff2 Subj ect: Results of Vater Supply Performance Evaluation Study 35 (VS 035)

Enclosed are the rinsults of the Vater Supply Performance Evaluation Study 35 (VS 035) for the laboratory at the Davis-Besse Nuclear Power Station. The result of the Quality Assurance staple for turbidity le entered on the enclosed survey forms.

Analyses of the remaining analytes are performed by certified off-site laboratories contracted by Toledo Edison. Therefore, their results are not included in this report.

Please contact Mr. Villiam T. O'Connor, Manager - Regulatory Affairs, at (419) 249-2366 ff you have any questions.

Sincerely yours, g

/Mg O k h M2J y6hnK. Wood A. H. Percival Plant Manager 2-90-37 Davis-Besse Nuclear Power Station Class II Operator Vater Supply TKV/lkg Enclosures cc:

Z. A. Clayton, Ohio Environmental Protection Agency Mr. James D. Dolfi, Ohio Department of Health Laboratories U. S.. Nuclear Regulatory Commission Document Control Desk

/oDI 7

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BTAPLE OMB#2080-0021

.HERE (Exp. 7/97)

Page'1 of 8 UATER SUPPLY LABORATORY PERFORMANCE EVALUATION STUDY U.S. ENVIRONMENTAL PROTECTION AGENCY STUDY NO. WS035 i

0 OH 0014 7 DAVIS-BESSE NUCLE A R POWE R STATI ON BOBEHT SCHBAUDER TOLEDO EDISON CO.

5501 N.

ST. HT. 2 AK.HARBOE, OH 43449 Samples:,1-C i

P REPORT APPROVED BY:

1 John K. Wood Plant Manager (419)249-2435 //3/pg~

NAME (Print).

/ SIGNATURE TITLE TELEPHONE

' DKTE This report is authorized by law (Public Laws93-523 and 99-339).

Successful annual participation in a water supply study or its equivalent is mandatory for every analyte or cnalyte group for which a drinking water laboratory is certified to conduct official analyses.

i Paperwork Reduction Act Notice Public reporting burden for this collection of information is estimated to averags 8.35 hours4.050926e-4 days <br />0.00972 hours <br />5.787037e-5 weeks <br />1.33175e-5 months <br /> p*r respondent. The estimate is based on analysis for an average of thirty-four analytes per respondent. The estimate includes time for reading instructions, preparation of the performance camples, analyses, gathering and reporting of the information.

Send comments regarding the burden estimate or any other aspect of this collection of information, including suggestions i

for reducing this burden, to Chief, Information Policy Branch, 2136, U.S.

Environmental Protection Agency, 40~ M. Street, SW, Washington, DC 20460; and to the office of Information and Regulatory Affairs, Office of Management and Budget, hashington, DC 20503.

EPA-359 (Cin) y

CHEMISTRY DATA Page 2 of 8

• E Analyze for Arsenic in Sample 1 using your routine method which obviously should be an pprovsd one. Use USEPA method 200.9 or 206.2 for Sample 3.

If you analyzed the special Sample for Arsenic and yc>u concentrated the sample before analysis, please indicate the concentration actor you used f:.;c~egn

,gggggh'MW~+~g# sus $wnst, %

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et Na e3 m m& W Analyto Number & Name Sample #

MC

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Quantity

%fpjf.%gl

LD$;y...2MM MhMR;9 4, mtia$s i '4 ::+2 ?,TRLC"EBETALS"y

"%';@s u ggM%gg n t**w - n -.-.+

$1%;ifq;y?' /4

mee a:

W W"p

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%gp%f

~

l l

pg/L 235 Aluminum 1

l l

pg/L 140 Antimony 2

001 Arsenic ***

1 l

l l

l pg/L I

3 l

l l

l l

pg/L i

002 Barium 2

l l

l l

l pg/L 141 Beryllium 1

pg/L i

226 noron 2

l l

l l

g/t l

pg/L 8

003 Cadmium 1

i i

004 Chromium 1

l pg/L 8

091 Copper 1

l l

l l

l pg/L l

l l

pg/L 005 Lead 1

8 236 Manganese 1

l l

l pg/L i

006 Mercury 1

l l

pg/L i

237 Molybdenum 2

l l

pg/L 142 Nickel l

l pg/L 8

i 007 Selenium 1

l pg/L i

008 Silver 2

l l

l l

pg/L l

l pg/L 8

143 Thallium 2

239 Zine 1

l l

l l

pg/L z.

.. ~

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% ?$$Tih yA. mc141TRATE f & i NITRITE : & 4 FLUORIDE ;W '

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l mg/L 009 Nitrate as N 1

l 092 Nitrite as N 1

l l

mg/L 8

8 j

0 l

l I

i e

i mg/L j

l 010 Fluoride 1

l i

.PA t-orm wos (nev. uw; vromus eduons aro ousoieto. (rvote. ine caia repon vori.i is cononue, on une next page.)

i j

O CHEMI;TRY DATA Pags 3 of 8

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MC

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Quantity f

• s l

.a y

>^. ::h

(,.

^

h. kk l' nlu m'su m, :pl:.7,a m:x' & - n',.. -,', a ast' "sa' s'tcross' w'l kI ',' Mp.l,".+

m' wl.(, w a y., a, w a P

/

t,.

5 A.

p l$ l 5

093 Alachlor 5

l l

l l

l pg/L l

l l

l pg/L 256 Aldrin 4

l 094 Atrazine 5

l l

l l

l-pg/L 240 Bromacil 6

l l

l l

l pg/L l

l pg/L 257 Butachlor 6

8 097 Total chlordane 3

l l

l l

l pg/L 258 Dieldrin 4

l l

l l

l pg/L 011 Endrin 1

l l

l l

pg/L 095 Feptachlor 4

l l

pg/L l

l pg/L 096 Heptachlor Epoxide 4

}

l l

l pg/L 172 Hexachlorobenzene 4

112 Hexachlorocyclo-4 l

l l

l l

pg/L pentadiene 012 Lindane 1

l l

l l

pg/L 013 Methoxychlor 1

l l

l pg/L 241 Metolachlor 6

l l

l l

pg/L 8

242 Metribuzin 6

l l

l l

pg/L j

l l

kg/L 8

243 Prometon 6

259 Propachlor 4

l l

l l

l pg/L l

l pg/L 113 Simazine 5

014 Toxaphene 2

l l

l pg/L 244 Trifluralin 4

l l

l l

pg/L

r'sj p gs g

. p.,

TENI'b MA NiNNh $ d' $ t)b' IMhNN s'

W 098 Aldicarb 1

l l

l pg/L 099 Aldicarb Salfone 1

l l

l l

pg/L pg/L 8

100 Aldicarb Sulfoxide 1

101 Carbofuran 1

l l

l l

pg/L 8

i i

245 Methomyl 1

l l

pg/L 114 oxamyl (vydate) 1 l

l l

g/L l

h@fM b di,A W

^

h *. <

<' HERBICIDESI ' [

i; s

l l

l pg/L 045 2,4-D 1

016 2,4,5-TP (Silvex) 1 l

pg/L 115 Dalapon 2

l l

l pg/L i

B 9

0 247 Dicamba 2

i e.

i.

e.

i pg/L Lt'A t orm twv-m (tiov. e-94) t'rovious couona are ousoielo. (Note. inw mia ru;x>rt iorm is co innuoc oo me noxi page.)

CHEMISTRY DATA Page 6 of 8 i*$y~Sh$h hlffk h

N+

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7 0 ;H l i

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' 5 Analyte Number & Name Stunple #

MC

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Quantity h M khDhhfkN N SNNIdhfIN'ONMhN NE$Eds.YNNN$$$8k$$$$$$$2

/M#$$h$NShIENWN+

i l

l l

pg/L 116 Dinoseb 2

t l

l l

pg/L 102 Pentachlorophenol 1

117 Picloram 2

l l

l l

l pg/L k$hhbfhkkMkNY$hhNNkN@hi$hEUk NBkINYb

$NNNUfM)!$$h$@@[bT! hhbh$k f

l l

pg/L 118.

Decachlorobiphenyl 1

@ M h$$ [S N $kQ ds k @ ff M 'N $N)@ % %MyW35$ M h h sN $ $ 23di h ! W M / N b,".*D EfN$$$$f 119 Acenaphthylene 1

l l

l pg/L l

l pg/L 8

120 Anthracene 1

121 Benzo (A) Anthracene 1

l pg/L 122 Benzo (A) Pyrene 1

l l

pg/L 8

l l

l pg/L 8

123 Benzo (B) Fluoranthene 1

124 Benzo (K) Fluoranthene 1

l l

l pg/L 8

125 Benzo (G,H,I) Perylene 1

l l

l l

l pg/L l

l l

l pg/L 126 Chrysene 1

l l

l pg/L 8

127 Dibenzo (A,H) Anthracene 1

l l

Kg/L 8

8 133 Flucranthene 1

l l

l l

pg/L 8

128 Fluorene 1

l l

pg/L 8

8 129 Indeno (1,2,3-C,D) Pyrene 1

5 5

1 l

l l

l pg/L

_ 33 Naphthalene 1

130 Phenanthrene 1

l l

l l

pg/L 131 Pyrene 1

l l

l pg/L

$M8333??@y@!yjh3.eu.$j.@[n. - u na.gs%3q(h:-...._y$e p?

wm

pa

@Mw idiT M.

M[ff h (f12g$ i NI)n[ u:.. g@ d,!, q$%q.y4kp% w _M 8)gg k, e

< w,... wwen

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$Ni g.

M m._.

8 pg/L 134 Di (2-Ethylhexyl) Adipate 1

I I

pg/L 136 Di (2-Ethylhexyl) 1 i

Phthalate l

l l

g/L 135 Butyl Benzyl Phthalate 1

149 Di-n-Butyl Phthalate 1

l l

l pg/L 8

8 i

150 Diethyl Phthalate 1

l l

l l

pg/L 151 Dimethyl Phthalate 1

l l

l l

pg/L I

1 a

A t.PA r orm (ovu-os (Hev. e-vej Prwods osuons are ousoaote. groote: ino mia n gort norm is co innuea on me next page ;

1 l

I l

CHEKIETRY DATA Page 5 of 8 ff M$kP Th$.$'ki!

g Y

fr N

YN f'

s W lS l0 l 3 l 5 0l Hl 0'

Ol 1

'4

'7 ff*4WI@6bM @4@N4WN5wn#b}thE#d$0? c '

Analyte Number & Name Sample #

MC.

</>

Quantity

. h.hkkhkh MhNhhbkihbk5IhkfhhhhhhhIhkk

[Nhh[bhhfifkkhhlkhfkh.Ik!

k I

i 8

137 Diquat 1

l l

l pg/L i

i l

l l

l pg/L 138 Endothall 1

i i

i 139 Glyphosate 1

l l

l l

pg/L 8

k:N hNbkkkhkd$h b kbkhN$Ih$8J2Mbh hNk@s5d

$ h2 h $$

k hi,hhhhhh h

5 019 Bromodichloromethane 1

l l

l l

pg/L 8

8 8

018 Bromofortn 1

l l

pg/L 020 Chlorodibromomethane 1

8 8

pg/L 017 Chloroform 1

l l

l l

l pg/L Mk,$NN$dOkMh$$ilkh$jkkhiff$${[ANQ (IjkkN}$fhhkkhh}$$$$$

Nhhh 039 Benzene 1

l l

l pg/L 8

8 pg/L 037 Carbon Tetrachloride 1

049 Chlorobenzene 2

l l

l l

l pg/L 054 1,2-Dichlorobenzene 2

pg/L 8

8 pg/L 041 1,4-Dichlorobenzene 1

pg/L 035 1,2-Dichloroethane 1

pg/L 034 1,1-Dichloroethylene 1

043 Cis-1,2-Dich1.oroethylene 2

8 pg/L 042 Trans-1,2-Dichloro-2 I

pg/L ethylene 055 Dichloromethane 1

l l

l l

pg/L 8

pg/L 044 1,2-Dichloropropane 2

l l

pg/L 048 Ethylbenzene 2

053 Styrene 2

l l

pg/L pg/L 040 Tetrachloroethylene 2

047 Toluene 2

l l

l l

pg/L 8

i 8

pg/L 036 1,1,1-Trichloroethane 1

l l

pg/L 061 1,1,2-Trichloroethane 1

038 Trichloroethylene 1

l pg/L 076 1,2,4-Trichic,robenzene 2

l pg/L 032 Vinyl Chloride 1

l pg/L 8

i 090 Total Xylenes 2

l l

l l

l pg/L EPA Form 7500-55 (Hev. B-94) Previous edbons are obsolete. GJote: I he data report fonn is continued on the next page.)

l

CHEMIETRY DATA Paga 6 of 8 h

f W !S 0

g Analyte Number & Name Sample #

MC

</>

Quantity

- h{h h... kkb [j -

f h.k l

.e i

i 8

067 Bromobenzene 3

l pg/L 089 Bromochloromethane 3

8 pg/L l

l pg/L 108 Bromodichloromethane 3

pg/L 062 Bromoform 3

pg/L 069 Bromomethane 3

pg/L 079 n-Butylbenzene 3

086 Sec-Butylbenzene 3

pg/L 085. Tert-Buty1 benzene 3

pg/L 109 Chlorodibromomethane 3

pg/L 070 Chloroethane 3

pg/L l

l l

kg/L 110 Chloroform 3

068 Chloromethane 3

l pg/L l

pg/L 071 2-Chlorotoluene 3

8 8

pg/L 072 4-Chlorotoluene 3

045 1,2-Dibromo 4 pg/L Chloropropane (DBCP)

By Method 504 pg/L 057 Dibromomethane 3

066 1,3-Dichlorobenzene 3

pg/L 088 Dichlorodifluoromethane 3

8 kg/L 8

]

pg/L 056 1,1-Dichloroethane 3

8 059 1,3-Dichloropropane 3

pg/L 060 2,2-Dichloropropane 3

8 kg/L 058 1,1-Dichloropropene 3

8 pg/L 152 Cis-1,3-Dichloropropene 3

pg/L 153 Trans-1,3-Dichloropropene 3

pg/L 046 Ethylene Dibromide (EDB) 4 l

l l

l l

pg/L By Method 504 8

i 087 Fluorotrichloromethane 3

8 pg/L 081 Hexachlorobutadiene 3

pg/L i

i i

i i

pg/L 084 Isopropy1 benzene 3

i i

trA torm idw-do (nev. u-v4) VmvioUF5511555Te ousoeoto. (reom; a ne caIa rprt vorm as co ianuoa w ino next page.)

\\~ 1 NintISTRY DATA Pegs 7 of 8 b/h [hfkf$$f dkh $Nhbbh hhAh h

hhhdk)hkhhh Tshhh 9{'kegdf%%5RewgsvgM~ W $ $ N e g g p t. y % b /

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MC

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Quantity W

((

_) NkhbbbhhkhhhNh I

hhShh!hk hb h!

l l

l l

gg/L 083 4-Isopropy1 toluene 3

078 'n-Propy1 benzene 3

l l

pg/L 8

8 063 1,1,1,2-Tetrachloro-3 l

l l

l l

pg/L 8

ethane l

Hg/L 065 1,1,2,2-Tetrachloro-3 f

et:vne l

077 1,2,3-Trichlorobenzene 3

l l

l MG/L 075 1,2,4-Trimethylbenzene 3

l l

l 40/L 064 1,2,3-Trichloropropane 3

l l

l l

MG/L 8

pg/L 082 1,3,5-Trimethylbenzene 3

I i

.hc;h bbb

' [kk Nk 250 Bromochloroacetic Acid 1

pg/L l

pg/L 165 Chloral Hydrate 2

I 8

8 8

8 8

kg/L 157 Dibr m eetic Acid 1

8 8

8 8

8 pg/L _

158 Dichlosoacetic Acid 1

160 Monobromoacetic Acid '

1 l

pg/L 8

161 Monochloroacetic Acid 1

pg/L 8

pg/L 162 Trichloroacetic Acid 1

E INi $Id

$ Nh$kk

$5$8 M / M !

i 193 Bromate 2

l l

[

pg/L a

260 Bromide l

l l

l l

pg/L 194 Chlorate 1

l l

l l

pg/L 195 Chlorite 1

l l

l l

pg/L M r@i$l M S M E5s}$ $ $ $ M e d yS$ M $in M E M f @ @ M S@ $4f $ $fsid$$!idpb LIM $$

022 Residual Free Chlorine 1

l l

l l

l mg/L 023 Turbidity 1

2l 2 i3 l.

l3 i5 NTU 1

024 Total Filterable Residue 1

l mg/L (at 1800 C) l l

l l

l mg/L 025 Calcium Hardness 1

(as Calcium Carbonate) i 026 pH 1-l l

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l Units j

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027 Alkalinity 1

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