ML20237K824

Forwards Results of Nonradiological Chemistry Water Stds Insps Activities Conducted During 1985 - 1986 Including Results of Measurements Made by Bnl.Licensee Identified by Code 16

ML20237K824
Person / Time
Site:	Hope Creek
Issue date:	08/12/1987
From:	Martin T NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION I)
To:	Corbin McNeil Public Service Enterprise Group
References
NUDOCS 8708190418
Download: ML20237K824 (2)

Text

.

12 AUG 1987 Docket No. 50-354 Public Service Electric & Gas Company ATTN:

Mr. C. A. McNeill, Jr.

Senior Vice President - Nuclear Post Office Box 236 Hancocks Bridge, New Jersey 08038 Gentlemen:

Subject:

Results of Non-Radiological Chemistry Standards Inspection Activities for All Region I Licensees Routine safety inspections were conducted by this office during the period 1985 to 1986 at USNRC Region I licensees in the area of non radiological water chemistry laboratory operations.

The purpose of this report is to present results of all licensees 1tispected, as well as results of measurements made by Brookhaven National Laboratory.

Each licensee is identified by a code.

Your code is 16.

No reply to this letter is required.

Sincerely, l

OriFJ 1 signed By 3

()

0W Thomas T. Martin, Director Division of Radiation Safety and Safeguards l

Enclosure:

Combined Results of Non-radiological Standards Comparison Inspection Activities for Region I Licensees cc w/ encl:

S. LaBruna, General Manager, Hope Creek Operations W. H. Hirst, Manager, Joint Generation Projects Department, Atlantic Electric Company L. A. Reiter, General Manager - Licensing and Reliability Rebecca A. Green, Bureau of Rasiation Protection Public Document Room (PDR)

Local Public Document Room (LPDR)

Nuclear Safety Information Center (NSIC)

NRC Resident Inspector State of New Jersey 0FFICIAL RECORD COPY LTR RAD RESULTS - 3008.0.0

-@ h/

isT 06/09/87 B708190410$h$o354 PDR ADOCK PDR I i

Public Service Electric & Gas Company 2

j2 gg bec w/ enc 1:

Region I Docket Room (with concurrences)

Management Assistant, DRMA (w/o encl)

DRP Section Chief Robert J. Bores, DRSS S

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.. RSS RI:DRSS RLt S'S DRSS RI:

SS Kottan/geb Zibulsky Pasc ak Bellamy Mar yp[/87 6/17/87

/1/87 G/3/87 6/ /87 OFFICIAL RECORD COPY LTR RAD RESULTS - 0008.0.1 06/09/87 I

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9 U.S. NUCLEAR REGULATORY COMMISSION REGION I Combined Results of Non-Radiological Standards.

Comparison Inspection Activities for l

Region I Licensees Ik w l

Inspectors:

ky, tFemist, Ef flue 6ts Radiation Harv'ey Zibuls,Secti l

,JP&RPB,DRSS Protection T.Q. /WP I

James J. Kottan', Radiation Laboratory Specialist, Effluents Radiation otection Section, EP&RPB, DRSS i

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(N Approved By:

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e Wale 6r J. Pascial, M ief, Effluents Radiation Protection Sect ion, EP&RPB, DRSS l

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l Details 1.

Introduction Region I has implemented an inspection program in the area of ner.-radio-logical water chemistry.

As part of this inspection program, if censees are required to analyze test standards prepared by Brookhaven National Laboratory (BNL) for NRC Region I.

The data from the first rourd of this part of the inspection pregram are now available from all power reactors in Region I and are presented here.

The data as presented perrits each Region I nuclear power plant chemistry laboratory to compare its performance with all other Region I nuclear power plant laboratories.

The data for the BNL known values are also presented so that comparison of the average from all Region I sites to the known value may be mace.

The data were taken from inspecticn reports, but are coded he-e.

The letter transmitting this repc-:

identified the individual code (s) for each addressee.

Section 3.0 lists the inspection reports data were taken from.

The data are presented in Appendix B.

I 2.

Data Analysis The data were analyzed as follows.

1.

The analytical data from all Region I sites were entered irto a data base at BNL. Tre analytical data consisted of each ifcensee's result for each analyte at each analyzed concentration.

2.

At each concentration, a grand average and standard deviaticn were calculated using the data from all sites, i

3.

A range consisting of the grand average plus or minus two standard deviations was established. Any values outside of this rar.ge were considered outliers.

4.

A new grand average and standard deviation were calculated excluding the outliers determined in step 3.

I 5.

A range consisting of the grand average plus or minus two standard i

deviations was again established.

Any values outside this range were considered outliers.

6.

The above process was repeated until a range was obtained with no outliers.

This range was used for the data comparison.

A sample calculation is presented in Appendix A.

l

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e It must be. recognized that the data used to generate the averages are not of equal weight.

For example, some ' laboratories were permitted to reanalyze the standards if problems could be identified and corrected during the inspection. Also some of the BNL standards were diluted to different final concentrations by the licensees prior to analysis to allow them to analyze within their calibration range. The results were then normalized back to the original dilution in order to enable comparison.

.In addition, all methods of analysis for a particular. analyte were grouped together.

3.

References:

Site Docket No.

Inspection No.

Beaver Valley #1 50-334 85-07 Beaver Valley #2 50-412 86-14 Calvert Cliffs #1 50-317 86-08 Calvert Cliffs #2 50-318 86-08 FitzPatrick 50-333 85-23 Ginna 50-244 85-14 Ct Yankee 50-213 85-24 Hope Creek 50-354 85-59 Indian Pt. #2 50-247 86-07 Indian Pt. #3 50-286 86-04 Limerick 50-352 86-10 Maine Yankee 50-309 85-33 Millstone #1 50-245 86-04 Millstone #2 50-336 86-04 Millstone #3 50-423 86-13 Nine Mile Pt. #1 50-220 85-10 Dyster Creek 50-219 86-16 Peach Bottom #2 50-277 85-28 Peach Bottom #3 50-278 85-26 Pilgrim 50-293 85-23 Salem #1 50-272 86-03 Salem #2 50-311 86-03 Seabrook 50-443 86-22 Shoreham 50-322 86-11 Susquehanna #1 50-387 85-27 Susquehanna #2 50-388 85-22 Three Mile Island #1 50-289 85-17 Vermont Yankee 50-271 85-38 Yankee Atomic 50-29 85-21 i...........i.m.

m..

e Appendix A Sample Calculation The chloride measurements at approximately 30 ppb were chosen for this example.

Step 1 The following data were in the BNL data base for chloride at approximately 30 ppb.

Site No.

Value (ppb) Site No.

Value (ppb)

Site No.

Value (ppb) 1 30.7 16 27.1 31*

26.7 2

30 17 39.3 32*

71 l --

3 30.2 18 28.8 33 not analyzed L.

4 24.3 19 28 5

30.9 20 29.3 6

30.9 21 23.3 7

32.7 22 28.9 8

38.3 23 not aralyzed 9

32 24 30.7 10 34.2 25 not analyzed 11 37 26*

41.3 12 28.7 27 33 13 not analyzed 28 14 30.7 29 52

• normalized data 15*

43.35 30 29.7 Step 2 A grand average and standard deviation were calculated for all 28 values:

Grand average = 33.6804 I xi n

Standard deviation = 9.5116 I (xi-x)2 _gg n-1 Step 3 From step two above, a range of 52.7036 - 14.6572 was established.

The value from site 32 was determined to be an outlier.

Step 4 A new grand average and standard deviation were calculated excluding the outlier determined in Step 3.

grand average = 32.2981 (n=27) standard deviation - 6.1966 t

'I Appendix A Sample Calculation (continued)

Step 5 From step 4 above a range of 44.6914 - 19.9048 was established.

The value from site 29 was determined to be an outlier.

Step 6 j

1 I

The above process was completed through seven more iterations as follows:

n x

s range outlier sites j

26 31.5404-4.8796 41.2996 - 21.7812 26, 15

.24 30.6417 3.8514 38.3444 - 22.9390 17 23 30.2652 3.4571 37.1794 - 23.3510 8, 21 21 30.2143 2.7368 35.6880 - 24.7406 4, 11 19 30.1684 1.9542 34.0768 - 26.2600 10 l

18 29.9444 1.7419 33.4283 - 26,4605 None Thus out of a total of 28 values 10 were outliers. The range of 33.4283 -

26.4605, which contained no outliers, was used for final comparison.

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