ML18022A976

Forwards Application for Renewal of NPDES Permit NC0039586, Submitted to Nc Div of Environ Mgt on 951003

ML18022A976
Person / Time
Site:	Harris
Issue date:	10/03/1995
From:	Robinson W CAROLINA POWER & LIGHT CO.
To:	NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM)
References
HNP-95-091, HNP-95-91, NUDOCS 9510130013
Download: ML18022A976 (329)

Text

PRIORITY (ACCELERATED RIDS PROCESSING)

)

REGULATORY INFORMATION DISTRIBUTION SYSTEM (RIDS)

ACCESSION NBR- 9510130013 DOC. DATE 95/10/03 NOTARIZED- NO DOCKET FACIL:50-400 Shearon Harris Nuclear Power Plant, Unit 1, Carolina 05000400 AUTH. NAME AUTHOR AFFILIATION

-ROBINSON,W.R. Carolina Power & Light Co. R RECIP.NAME RECIPIENT .AFFILIATION Document Control Branch (Document Control Desk)

SUBJECT:

Forwards application for renewal of NPDES permit NC0039586, submitted to NC Div of Environ Mgt on 951003.

DISTRIBUTION CODE'E23D COPIES RECEIVED LTR TITLE: Environmental Event Report (per Tech Specs)

J ENCL 2 BISE ~ SO NOTES:Application for permit renewal filed. 05000400 RECIPIENT COPIES RECIPIENT COPIES ID CODE/NAME LTTR ENCL ID CODE/NAME LTTR ENCL PD2-1 PD 1 1 LE,N 1 1 INTERNAL: ACRS 5 5 FILE CEN 01 1 1 NRR/DISP/PIPB 1 1 OGC/HDS2 1 1 RGN2 1 1 EXTERNAL: NOAC 1 1 NRC PDR 1 1 D

N NOTE TO ALL "RIDS" RECIPIENTS:

PLEASE HELP US TO REDUCE WASTE! CONTACT THE DOCUMENT CONTROL DESK, ROOM OWFN 5D8 (415-2083) TO ELIMINATE YOUR NAME FROM DISTRIBUTION LISTS FOR DOCUMENTS YOU DON'T NEED!

TOTAL NUMBER OF COPIES REQUIRED: LTTR 13 ENCL 13

Carolina Power & Light Company William R. Robinson PO Box 165 Vice President New Hill NC 27562 Harris Nuclear Plant OCT -3 1995 U.S. Nuclear Regulatory Commission Serial: HNP-95-091 ATTN: NRC Document Control Desk Washington, DC 20555

Subject:

Shearon Harris Nuclear Power Plant Docket Number: 50-400 License Number: NPF-63 NPDES Permit Renewal Application Submittal Gentlemen:

On October 3, 1995, Carolina Power A Light Company's Harris Nuclear Plant submitted to the

'North Carolina Division of Environmental Management, an application for renewal of National Pollutant Discharge Ellimination System (NPDES) Permit Number NC0039586. The subject application is provided for your informatin. Ifyou have any questions regarding this application, please contact Mr. T. D. Walt at (919) 362-2711.

Sincerely, MV Attachment c: Mr. S. D. Ebneter (NRC - RII)

Mr. N. B. Le (NRC - PM/NRR)

Mr. S. A. Elrod (NRC - SHNPP)

'95i01300i3 95i003 05000400 PDR ADOCK P PDR State Road 1134 New Hill NC Tel 919362-2502 Fax 919 362-2095

U. S. Nuclear Regulatory Commission HNP-95-089 / Page 2 bc: T. A. Baxter, Esq Ms. P. Brannan Mr. R. K. Buckles (LIS)

Mr. W. R. Campbell (BNP)

Mr. J. W. Donahue Mr. H. W. Habermeyer, Jr.

Ms. T. A. Head (GLS File)

Mr. M. D. Hill Mr. J. W. Hindman Mr. R. M. Krich (RNP)

Mr. R. D. Martin Admiral K. R. McKee Mr. W. S. Orser Mr. G. A. Rolfson Mr. R. S. Stancil Mr. T. D. Walt Nuclear Records File: HI/A-2D ~

File: H-X-503

Carolina Power & Light Company William R. Robinson PO Box 165 Vice President New Hill NC 27562 Harris Nuclear Plant OCT -3 1995 Letter Number: HO-950532 Mr. A. Preston Howard Jr.

Director, N.C. Division of Environmental Management 512 N. Salisbury Street P.O. Box 29535 Raleigh, NC 27626-0535

Subject:

Harris Nuclear Plant and Harris Energy & Environmental Center National Pollutant Discharge Elimination System (NPDES) Permit Numbers NC0039586 and NC0026735 Wake County Application for Renewal

Dear Mr. Howard:

The current NPDES permits for Carolina Power & Light Company's (CP&L) Harris Nuclear Plant (HNP) and Harris Energy and Environmental Center (HE&EC) located near New Hill in Wake County, both expire on March 31, 1996. CP&L respectfully requests that the North Carolina Division of Environmental Management (NCDEM) renew the Harris Nuclear Plant NPDES Permit (Permit No.

NC0039586) in accordance with 15NCAC 2H.0100. Furthermore, CP&L requests that, as previously discussed with Mr. Dave Goodrich of the NCDEM Permits and Engineering Unit during a meeting with Mr. Rick Yates of CP&L's Environmental Services Section on July 26, 1995, the one outfall currently permitted at the HE&EC (Permit No. NC0026735) be included in the renewal of the HNP permit. Also, as discussed with Mr. Goodrich, the HNP stormwater application pursuant to 40CFR Part 122.26 was included in CP&L's Storm Water Group Application No. 286 previously submitted to the U.S.

Environmental Protection Agency (EPA). By reference, CP&L desires that the group application be made part of the HNP renewal application. Copies of the group application correspondence are attached to the enclosed application form (Attachment 8). No stormwater outfalls at the HE&EC are within the scope of the EPA's Phase 1 stormwater regulations.

Enclosed is a check for the $ 400 permit renewal application fee and the "Application for Permit to Discharge Wastewater" (Standard Form C). As required, the application is being submitted in triplicate.

CP&L appreciates the continued cooperation demonstrated by the NCDEM staff in responding to its permitting needs. If you have any questions or require additional information, please contact Mr. R. T. Wilson at (919) 362-%44 or Mr. Rick Yates at (919) 546-7777.

Sincerely, MV Attachments State Road1134 NewHill NC Tel 919362-2502 Fax 919362-2095

Mr. Howard NCDEM Page 2 of 2 bc: Mr. J. W. Cagle Ms. L. L Cooper Mr. M. R. Greeson (w/o enclosures)

Mr. J. W. Griffith (w/o enclosures)

Mr. J. W. Gurganious Mr. W.L. Lohmeyer (w/o enclosures)

Dr. G. J. Oliver (w/o enclosures)

Mr. S. W. Radford (w/o enclosures)

Mr. P. B. Snead (w/o enclosures)

Mr. M. Verrilli Mr. T. C. Walt Mr. B.C. White (w/o enclosures)

Mr. R. T. Wilson Mr. R. C. Yates NLS File: H-X-230

~ a c 4 c ~g>p13pp>3 NORTH CAROLINA DEPT. OF ENVIRONMENT, HEALTH, AND NATURALRESOURCES ENVIRONMEKI'ALMANAGEMENTCOMMISSION NATIONALPOLLUTANTDISCHARGE ELIMINATIONSYSTEM APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER STANDARD FORM C - MANUFACTURING AND COMMERCIAL SECTlON I. APPLlCATION AND FAClLlTY DESCRIPTION Unless oiheiwise specsled on friis Iorm all Rema are lo be completed. If an Rem Is nol applicable Indicate 'NA'.

ADDITIONALINSTRUCTIONS FOR SELECTED ITEMS APPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDiCATED. REFER TO BOOKLET BEFORE FILI.ING OUT THESE ITEMS.

Pfease Print or Type Legal Name of Appficant 101 Carolina Power & Li ht Cori an (see insuuctions)

Maibng Address of Applicant (see Instnictiora)

Number & Street P. 0. Box 1551 City 102b Raleigh

?forth Carolina Zip Code 27602-1551 Appbcant's Authonzed Agent (see Instructions)

Name and bitte Uilliar.: R. Robinson Vice President Harris Nuclear Plant Number & Sbeet P. 0. Box 165 5413 Shearon.Harris Road City New Hill State North Carolina Zip Code 27562-0165 Telephone Number Previous Applicaten ll a preveus abpbcation for a pelmit under lhe Nabonal Pollutant Discharge Elimination System has been maae, give the date of appbcaten. 90 9 26 YA MO OAY I oenity that I am familiar with the infonnaticn contained in this appbcation and that to the best ot my knowledge and befief such information is ttue. complete.

slid accurate.

tlilliara R. Robinson 102e Vice Pres ident - Harr f ar Plant Printed Name of Person Slgrung Title 102f Slgniuure ol Applcsia or Autnonzed Agent Oats Application Signed carolina General statue 143-215.8 (b)(2) provides that Any person wte knowingly makes any false statement repmsentation. or cerbficationin any icabon. record. report. plan. or other document files or required to be maintained unaer Artcte 21 or regulations of the Enviffirrentat Management ommission unoiementing tnat Artcte. or wno falsities. tampers with. or knowingly renders inaccurate any reoxaina or monit r..".c device or memod required to be ooeratea or mmntainea unaer Artide 2'I or regufatens of the Environmen< Management commission imbiemenuna tr at Artcie. shall be guilty af a misaemeanor aunisnable by a fine ret to exceea $ 1 0.000. or by impnsonment not to exceea set months. or by both. I18 U.S.C. Secson 1001 provees a punisnment by a fine or not more tnan $ 10000 or unpnsonment not more than 5 years. or both. for a similar ottense I

Facility (see instrucdons)

Give the name. ownorsnip, and physical beaten of tho plant or other o porattng faa5ty where discharge(s) presently occur(s) or wtll occur.

Name Harris Nuclear Plant/Harris Ener 6 Environnental Center Ovmership (Public. Private or both Pubic and Private) Qtue gtrtv Qos Check block if a Federal facility and give GSA Inventory Controt Number N/A beattcn:

Number 6 Street 5413 Shearon Harris Road and 3932 New Hill/Hollerean Poad City New Hill llake North Carolina Nature of Business State the nature 106a Electric Power Generation of tho business conducted at tho plant or o porabng faabty.

106b AGENCY USE Facility intake Water (see Instrucsons) Indicate water intake volume per day by soutces.

Estimate average volume per day in thousand ga5ons per day.

Municipal or pmrate water system 107a N/A Surface water 28,657 thousand ga5ons por day Groundwater 107c N/A thousand galbns por day 107d N/A thousand gallons per day Total Item 7 107e 28,657 thousand galbns per day

'f thereis intake waterfrom 'other.

spea1y tho source.

107f N/A Facility Water Use Estimate average volume per day in thousand galbns per day for the fo5owing typos of water usaoe at the faatrty.

(See insuucdons)

Nonoontact cooling water 28 405 thousand galbns per day Boiler feed water 106b 41 thousand galbns per day Process water (including contact 108c 251 thousand galbns per day cooling water)

Sanitaty water 1C8d 20 thousand ga5ons por day Othot 108e 1 /A thousand ga5ons per day 108I 28. 717 thousand galbns per day

'l Total Item 8 there are discharoes to 'othe t',

specify 108g If there is 'Sanitary water use, 1CBh w 1000 eopleserved (See Item 12) give the nvmoer of pooolo served.

All FaciTity Dischaiges and other Losses. Number and Discharge (See insauctions)Vcfume Specify tho number of dkchatgo points and the volume of water ('See Item 12) dischamed or lost from Se facility according to the categories below. Estimate average volume per day in thousand gallons per day Number of TotalVoiumeDischaiged, Thousand Discharae Points Gallons Per Da Surface Water Sanitary wastewater transport syste 109)t 20 (HNP Cc HECcHC)

Storm water transpon system 109cl 293 Coinbined sanitary and storm water 109dl N transport system Surface iinpountSnent with no 109el effiuont Underground percolation 8 Well injection 10991 Waste acceptance finn 2 109h2 0.5 (Sludge Disposal)

Evaporaton 109it 21,304 Consumption 109j1 1tskt OSet'acility dischargee and volume Total Item 9 109I1 See Item 12

'lf there aio discharges to 'other', 109m1 specify.

Permits. Licenses and AppticatIons List am existing, pending or denied perinits, licenses and applications related to cfischaigos fmn this facility (see instructions) issuing For Type of Date Date Date Expiration Agency Agency Permit or Filed Issued Doniod Date Ucense ID Numbor YR/MO/DA YR/MO/DA YR/MO/DA YR/MO/DA

".gk?;)>> tj~p>>

ee Atta hnent 2 c@ig+M'gV.'~+~'.

See Attachments 3, 4A, 4B, and 7 Attach all mquirod maps and drawings to the back of this apphcaticn. (see insuuctions)

Addibonal Information Item 112 Number Information Refer to folio@in a e

Carolina Power & Light Company Harris Nuclear Plant NPDES Permit Renewal

12. Additional Information (Section I)

Item Information l

The sanitary wastewater systems serve approximately 1000 permanent employees per day. This number may increase during plant outages. Groups of additional 400 or more people may visit the HE&EC for training or the Visitors Center.

"Surface Water" includes flows from Cooling Tower Blowdown, Low-Volume Waste, and Radwaste.

"Sanitary Wastewater Transport System" includes sanitary wastewater treatment facilities at the HNP and the HE&EC. Both ultimately discharge to surface waters of Harris Lake.

See Attachments 1A and 1B for descriptions of facility discharges.

All discharges from the HNP, except storm drains, are routed to Harris Lake through a common outfall pipe. Individual discharges contributing to this outfall are: Cooling tower blowdown, sewage treatment plant effluent, low-volume waste, metal cleaning waste, and radwaste. The HE&EC wastewater treatment facility discharges to Harris Lake through a separate outfall pipe.

The "Total Volume Used or Discharged" reported in Item 9 does not equal the total for Item 7 because stormwater and sludge are included in Item 9.

STANDARD FORM C - MANUFACTURING AND COMMERCIAL SECTION II. BASIC DISCHARGE DESCRIPTION mpfete this section for each discharge Indicated in Section I. Items 9. that Is to surface wslera This Includes discharges to muncipal sewerage systams bi hich the wasfe water does hot go through a treatment worxs bnor ta beiha discharged la surlace waters. Discharaes to wells must be descrsied where there are also discharges lo surface waters fram lhis facsity. sEpARATE DESCRIPTIONs QF EACH DlscHARGE ARE REQUIRED EYEN IF SEYERAL DlscHARGEs ORIGINATE IN THE SAME FACILITY. All values lar an exisfing discharge should be representative al the twelve previous mahihs ot operauon. Il this Is a proposed discharge. vaiues should rellect best engineenng esliinates.

ADDITIONALINSTRUCTIONS FOR SELECTED ITEMS APPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET BEFORE FILUNG OUT THESE ITEMS.

Discharge Serial No. and Name a Discnarge Serial No. 201a 006 (See Itept 26)

(soe insuuctions)

b. Discharge Name 3)tb Common Outfall Pipe to Harris Lake Give fho name of discharge, if any (soe instrucbons)

c. Previous Discharge Serial No 2Dtc 006 (including 001, 002, 003, 004, 005 If a previous permit in current l1PDHS Pernit )Io. )lC0039586) applcabon was made for this dis charge (Item 4.Section I) provido previous discharge serial number.

Discharge Oporating Datos a Discharge Began Date 85 11 If the oischafge doscribod below is in opofabon, give tho date (within best osbmato) the dischargo began NA Ix Discharge to Begat Date lf the ascharge has never YR MO occurrod but is planned for some futuro date. give the date tho discharge will begin.

c. Discharge to End Date If the NA dischargo is scheduled to be YR MO disccnbnuod within the next 5 years. give the date (within best osbmate) tho dschafgo will ond.

Engineering Report Availablo Check if an enginoonng report is available to reviewing agency upon request (soo instnlcbons) (See Iten 26)

Dischaioe Locabon Name the political boundarie within which the point of dschafge is kcatod: Aaencv Use NC County Wake (If applicable) City or Tovm NA Discharae Point Doscription Isoe instrucbons)

Discharge into (chock ono)

Stream fincbfdes ditches. anayos. P STR and other watofcoursos Lake gj LKE Ocean P OCE Municipal Sanitary Wastewater Q MTS Transport System Municipal Combined Sanitary and Storm Transport System Q MCS

DISCHARGE SERIAL NUMBER 006 Municipal Storm Water Transport Q STS System Well (injection) Q WEL Other Q OTH It'other is checked. specify type

6. Oischanp Point ~ LaAnng.

Give the crease bcason ot tho pont ot dscharge to the nearest Latttude DEG. Gd MIN. 47 SEC Lcngtude DEG. EE MIN. EEC

7. Discharge Receiving Water Name Name tne waterway at the pointof Harris Lake discharge. (see instructions) lt tho discharge is through an outfall that extonds beyond tho snomlle or ts beiow the mean bw water line, complete rtem 8.

Ds Ace kaed

~ aaaas ky~ SJy 207c Near Ace Ued

8. Offshore Discharge a Discharge Distance from Shorn 500 feet

b. Discharge Depth Below Water 40 feet Discharge Type and Occurrence a Type of Discharge Chock whether the discharge is Qx (con) Continuous continuous or intermittent. Q (int) Intormittont (See instmctfons)

b. Discharge Occurrence Days per Week. Enter the average ntsnber of days per week days porweek

'during penods ot dischargo) this discharge occurs.

c. Discharge Occurrence- Months NAQ JAN Q FEB Q MAR It this discharge normally oper. Q APR Q MAY Q JUN ates (either atormittentfy or Q JUL Q AUG Q SEP continuousfy) on krss than a y Q OCT Q NOV Q DEC around basis (exdudng shut-dovms tor rousne maintenance),

check tho months during tho ye when the dischargo rs oporattng (see instructrons)

Canplete Items 10 and 11 if Intermittent's checked in Item 9w Othervytse, proceed to Item 12.

10. Intermittent Discharge Quantity State the average volume por dis. 210 NA thousand galbns por day charge oxvnence in thousands of gatbns

11. Intermittent Discharge Duration and Frequency a Intermittent Discharge Duratbn Per Oay Stas the average 211a noumperday nlnberof hours per day the discharge is ooerating

b. Intemttient Discharge Frequency Setate tho average 211b discharpa occurrences parday number of cscharge occurren per aay cunt oays when cischargtng

12. Maximum Flow period Give the arne oe nod m v amen tho maxtmum 212 From Jen. Io Deo.

flow of this discnarge occurs month mone

8 DISCHARGE SERIAL NUMBER 006

13. Activity Description Give a 213a See Attachment 1A for narrative narrative descnption ot activity descri tion of each source 'of wastewater producing this dscharge (see contributin to the common outfall.

instructions j

14. Actnrity Causing Discharge For each SIC Code which descnbes the activity causing this discharge, supply the type and maximum amount of either the raw matenal consumed (Item 14a) or the product produced (Item 14b) in the units specrtiedin Table I ol the Instmction Booldet..

For SIC Codes not listed in Table I. use raw material or pioducton units normalty used Ior measunng p/oduction (see insuuctions)

a. Raw Materials NA Maximum Unit Shared Discha/ges SIC Code Amount/Dav (See Table I) (Seria Number) 214a i4l Maximum Unit Shared Discharges SIC Code Name Amount/Dav (See Table I) (Serial Number) 21 4911 Electric 0.9 Z-1 Power Services

DISCHARGE SERIAL NUMBER 006 15 Waste Abatement a Waste Abatement Practices 215a NanatNe. See Attachment 1A for descri tions Descnbe the waste abatement of waste abatement ractices pracaces used cn this dis.

charge with a brief nanative (see instructions)

b. Waste Abatement Codes 215b Using the codes listed in Table II of the instructon Booklet, describe the waste abatement (10) CHFUTR processes for this discharge in (16) POTHER the order in which they occur (16) if possible. (19) (21)

(22)

(25)

Items 1 - 2: Cooling Tower Blowdown Items 3 - 6: Sewage Treatment Plant Items 7 - 9i Metal Cleaning Waste Items 10"12: Low-Volume Waste Item 13: Radwaste

DISCHARGE SERIAL NUMBER 006 t6. Wastewater Charactenstics (See I tern 26)

Check the box beside each consstuent which is present in tho effluent (discharge water). This doteimlnation is to based on actual anatysis or best essmate.(see instrucsonsj rarameter resent rarameter resent 216 216 l.oior p per 00060 X 01042 mmonia ron OC610 01045 X rganic nitrogen 00605 01051 X i ate agnes wm 00620 X 00927 itnte anganes8 00615 X 01C65 X nospnorus ercury 00665 71KQ liale o oaenum 00945 X 01062 ullloB ICKOI 00745 X 01067 Ie nwm 00740 01147 fomiae OIIVBf 71870 X 01077 onae otasswm 00940 X 00937 X oaium 00929 iuonao i asium 00951 01C69 uminum wm 01105 01152 mony in 01097 01102 isenic nc 01002 01092 X rysium glclaos 01012 74C61 num onnatea organic corn pounas 01007 X 74C62 ron estci Bs 01022 74C63 aamium i anagmase 01027 OC650 aicium nenes 00916 c 32730 Dali unactants 01037 X 3886 01034 romium Chlorine r ecai costonn oactena aaioactlvity 74065 74C60

' peaty substances. compounds and/or elements in Item 26.

Pesticides (insecscidos. funocides. and todenticides) must be reportedin terms of the acoeotable commonnames specifi<:n Acceptable Ccmmon Names and chemical names lor tne Ingredient statement on Pess'crdo Labels. 2nd Edition. Environmental protection Agency. washl"-:-,n. D.c. 20250, June 1972, as required by subsecaon 162.7(b) ol the Regulations for the Enforcement of the Federal Insocoode. Fungicide. and Rodenticide Act.

8 4

CI'li& bC DISCHARGESERIALNUMBER 006

17. Doscription of lntake and Discharge (See Item 26)

For each of the pa/ametors listed bebw, enter in the appropriat box the value or cods letter answer callod for (see instructions)

In addtion. enter the parametername and code and all required vahos torany ot the tolbwing parameters if they ere checkodin Item 16:

ammonia. cyanido. aluminum, arsenic, boryllium, cadmium, chromium. copper, lead. mercuty... nickel, selenium, nnc, phenofs, oil and grease, and chlorine (resioual).

n nt t uont n ats n. tan aiy mimum aximum requency umoor o pie Parameter and Cods Intake Treated Average Value Value of Analysis Analyses Type Water Intake Observed or Observed or 217 (Daily Water Expected Expected average) (Daily During During average) Discharge Discharge Activity Activity f2) f3) f4) f5) f6) f7) f8) t Iow H Gallons per day

-cess- 50050 4.66 1.3E 9.07 CONT NA NA P

Units 00400 6.3 7.7 1/7 52 mporature twintsr)

OC 74026 22.3 14.5 30.3 1/7 59 emporature (summer]

oc 7402 29.2 18.8 35 ' 1/7 52 acne mc/at xygon Demand (BOD 5.0ay) 3.0 1/365 C mg/I 24-hr IX)310 m/cat xygon Demand (COD) mg/I 30.8 1/365 C 00340 24-hr 0 aspen ooo (nonfilterable) Sohds mg/I 14.8 1/30 12 00530 poet t/c oils c tan co micromhos/cm at 25'C 199 694 365/ 365 G 00095 365 atxe assr (residue) ml/I 00545 ther discharges sharing intake tlow (serial numbers) (see instructions)

DISCHARGE SERIAL NUMBER

'06 (Cont'd) in vent c uont nueatea n iant ally inimum aximum fee u e flcy umoor Parameter and Code Intake Treated Average Value Value of Analysis of Type Water Intake Obseived or ObseNed or Analyses 217 (Daily Water Expected Expected average) (Daily During During ave rago) Discharge Discharge Activity Activity (2) 3) (4) '5)

(6) (7) (8) Units Ammonia 1 6 mg/1 (01105) 0.220 00610'luminum 1/365 C 24h mg/1 Arsenic (01002) 0.005 1/365 C 24h mg/1 Cadmium (01027) 0.005 1/365 C 24h mg/1 Chromium (01034) 0.01 1/365 C 24h mg/1 Copper (01042) 0.011 1/365 C 24h mg/1 Lead (01051) 0.05 1/365 24hr mg/1 (Item 17 continued on next page)

18. Plant Controls Check if the tollowing plant controls are avaitabto (or this dischaigo 218 Alternate powor source for major pumping facility Px APS Alarm or emergency procedure for power or equipment failure Qx ALM Complete Item 19 if discharge is fro cooling and/or steam water generation and water tmatment additNes aio used

19. Water Treatment Additives I( the discharge is ueated with any conaitioner. inhibitor. or algicido.

answer mo folbwing; a Name of Material(s) 219a See Attachment lA

b. Name and address of 219b Chemical su liers var manufacturer Specific supplier information at a given time is available u on re uest.

Quanpty (pounds addod por 219c See Attachment lA million gailons ot water treated)

tv'i v i bc DISCHARGE S" RIAL NUMBER 006 (Cont'dl tnnuent crtluent untroatoa in riant IJaily inimum aximum rreouency urnoer ~txe parameter and Cede Intake Treated Ave raoe Vatue Yalue ol Analysis ol Type Water Intake Obseivea or Observed or Analyses 217 (Daily Water Exoectoa Exooctoa average) (Daily Dunng Dunng average) Discharge Discharge ActNrty Activity I21 I31 I41 (51 I61 I71 I81 Units Nickel (01067) 1/365 1 , 24hr. rng/1 Zinc (01092) 0.141 1/365 1 24hr ntg/1 OiltrGrease(00550) 5.00 1/365 1 24hr ntg/1 Chlorine (50060) n.n<<0.05 (0.05 1/30 12 ng/1

I VI1 DISCHARGE SERIAL NUMBER 006

d. Chemical corn position ot these 219d See Attachrtent 1A additives (see insvvctions)

Complete Items 20-25 if there is a thermal discharge (e.g., associated with a steam and/ar power acne iabon plant, steel milt, petroleum refinery, or any otnor inanufactunng process) and the total d schaigo tlow is 10 million gallons per day or more. (see instivcbons)

Thermal Discharge Source. Check the apprapnate item(s) indcabng the source of the discharge (see instrucbans)

Boiler Blowdovm Q BLBD Boiler Chemical Cleaning P BCCL Ash Pond Overflow Bolor Water Treatment- Q EPBD Evaporatar Blovchwn Oil and Coal Fired Plants-ENuent Q OCFP trom Air Pollution Control Dovicos Condense Cooling Water Q COND Cooling Tower Slowdown Px CTBD Manufactviing Process Q MFPR Other Q OTKR DischargelReceiving Water Temporaturo Difference Give the maximvm tomporaturo ditleience between the discharge and receiving waters tor summor and winter apeiabng cond(bans see instructions) ummor 221a 9 of Winter 221b 32 oF Discharge Temaerature, Rate of Chango Per Hour 'O(((our Give tho maximum possible rate ol temperature change perhourot dischattp undor oporabng conditions (see sisuvcbons)

Water Temperature, Percentile Report(Frequency of Occurrenco)

In the table below. enter the temperature wnich is excooded 10o/o

'of the year, 5% of tho year, 1% ot the year and not at all (maximvm yearly temperature). (see insbvcbans)

NA Frequency ot occurrence 1 /o a/o 1 /o axlmvnl

a. Intake Water Temperature (subject to natural changes oF 'F Of

b. Discharge Water Temperature Of 0F CF Water Intake Velocity 5 (sol(soo.

(see instiuctionsl NA misolos Retenbon Time G ve the length of bme. in minvies. frain start of water tomooiature nse ta discharae of coobng water. 1 see instiucbonsl

FOR AGchCY Uoc DISCHARGE SERIAL NUMBER 006 Additional Information 226 '" rem n ormauon Refer to follovlng page

Carolina Power Ec Light Company Harris Nuclear Plant NPDES Permit Renewal DISCHARGE SERIAL NUMBER 006

26. Additional Information Item Information Discharge Serial No. 006 is specified to maintain consistency with the outfall numbering used in the current NPDES permit.

Engineering drawings, Final Safety Analysis Report, system descriptions, and other related documents are available upon request.

16 Chemical constituents contained in this discharge that may be conveyed to Harris Lake will in part be representative of the naturally occurring chemical quality of the intake water and will also have chemical constitu-ents of such quality and quantity associated with similar discharges for nuclear generating facilities of this size, type, and in this geographical location. Either all or part of the elements listed in the Periodic Table, either singularly or in any combination, may from time to time be contained in the discharge.

16 Constituents checked are either 1) present in the common outfall line as determined by conventionaVpriority pollutants monitoring for this permit application, 2) known to be present in the specific waste streams, or 3) used in a process which could result in discharge to waste streams.

16 Radioactive components of releases are regulated by the Nuclear Regula-tory Commission and, therefore, not addressed in this application.

16 Algicide currently used as needed is the biodispersant "ACTI-BROM 1338". Approval for use was granted June 11, 1990 by the North Carolina Division of Environmental Management. Sodium bromide in other forms may be purchased from other vendors in the future. Also, gluteraldehyde is used in closed cooling systems but it is not normally discharged; however, limited quantities may be discharged due to maintenance or system leakage.

17 The influent data requested is variable in nature and not normally under the control of the applicant. Effluent data are partially derived from Discharge Monitoring Reports previously submitted to DEM. These documents are incorporated by reference in this submittal. Other effluent data reported in this application are from Conventional/Priority Pollutants monitoring conducted at the common outfall during 1995 (Attachment 5).

17 EPA - approved procedures are used for all NPDES required analyses.

STANDARD FORM C - MANUFACTURING AND COMMERCIAL SECTION II, BASIC DISCHARGE DESCRIPTION mpleta this secten for caen aischarge Indicated in Section I. Items 9i that ls to surface waters. This Includes discharges to muniaoal aawarsge systems in ich the waste water aoes not go through a treatment woes onor lo beina discharged to aunace waters. Discharges lo wells must be aescnbed where there are also discharges lo surface waters from this facaity. SEPARATE DESCRIPTIONS OF EACH DISCHARGE ARE REQUIRED EVEN IF SEVERAL DISCHARGES oRIGINATE IN THE SAME FActLITY. All values lor an crusting discharge should bo representative ol tho twelve prewous monlhs of o perauon. It this la a proposed discharge. vaiues should reflect baal engineenng eslsnatea.

ADDITIONALINSTRUCTIONS FOR SELECTED ITEMS APPEAR IN SEPARATE INSTRUCTION BOOKLET AS INDICATED. REFER TO BOOKLET BEFORE FILUNG OUT THESE ITEMS.

Dischatoe Serial No. and Name a Discnarge Serial No. 201a 007 (see insuuctions)

b. Discharge Name 201b Harris Energy 6 Environmental Center hr(fTP Give the name of discharge, if any (see instructions)

c. Previous Discharge Serial No 201c 001 (current ?IPDES Permit ufo. HC0026735)

If a previous permit appiicaircn was made for this dis charge (item 4,Section I) provide previous discharge serial number.

Dischaitx. Operating Dates a Discnargo Began Date 74 7 If the oischarge describod below YR h0 is in operation, give the date (within best osbmato) the discharge began

b. Discharge to Begin Date  ?IA If the aschafgo has never YR MO occurred but is planned for some futuro date, gve Ihe date tho discharge will bogin.

c. Discharge to End Date If tho discharge is scheduled to be YR MO disccncnued within the next 5 years. give the date (within best osbmato) tho dscharge will ond.

Enginoenng Re port Avarlabfo Chock if an ongxteenng report is available to reviewing agency upon roauest (see instnfcfions) (See Iten 26)

Discharge Locascn Name tho political boundaries within which tho point of dschafgo is located: Agoncv Use County Wake (If applicable) City or Town NA Discharae Point Description (soe instruccons)

Discharge into (check one)

Stream tindudos ditches. anoyos, Q STR and other watonxxf rsos Lake g LKE Ocean CI OCE Municipal Sanitary Wastewater 0 MTS Transpon System Municioat Combined Sanitary and Storm Tnms port System g MCS

DISCHARGESERIALNUMBER 007 Municipal Storm Water Transport Q STS System Well (injection) Q WEL Other Q OTH If 'other is checked. specify typo

6. Discharge Point - Latllrsng.

Give the precise bcatron of the pant ol dscharge to the nearest latitude SS DEG. SS MIN. SEC Longruae DEG. SS MIII. 5 SEC

7. Discharge Receiving Water Name Name tne waterway at the point of Harris Lake discharge. (see hstructions)

If the discharge is through an autlall that extends beyond the snorefiire or is below the mean bw water line, complete rtem 8, SC AOS VSS kaaaar ky~ NdD 207c

<C ACS VSS Offshore Discharge a Discharge Distance from Shore 150 feet

b. Discharge Depth Bebw Water 10 feet Discharge Typo and Occurrence a Typo of Discharge Check whether the discharge is Q (con) Continuous continuous or intermittent. Qx (int) Intermittent (See insuuctions)

b. Discharge Occurrence Days per Week. Enter the average nrsnber of days per week days pa mask (during penods of discharge) this discharge accurs.

c. Discharge Occunonco- Months g JAN Qx FEB g] MAR If this discharge normally oper. g APR Ij AUG MAY g JUN ates (either intermittently or continuously) on hss than a ye around basis (exdudng shut-downs forroutrne maintenance),

gj JUL H OCT I Q

NOV gj SEP Ej DEC check the months during tho ye when the discharge is operabng (see instructions)

Com ! ete Items 10 and 11 if 'intermittent's chac ed in Item 9a. Otherwise, proceed to Item 12.

10. Intermittent Discharge Quantity State the average volume per dis- 210 16 thousand galbns por day charge occurrence in thousands of galbns Intermittent Discharge Duration and Frequency

a. Intermittent Discharge Duration Per Day State the average 211a koom par day nrxnborof hours perday tho dMaroe is ooerating

b. Intermittent Discharge Frequency State the average 211b discharge occurrences per day numberof dscharge occurmn per aay dunw aays when "ischarging Maximum Flow period Give tho time oenod in vriicn the maximum 212 From Jan. Io Dec.

flow ol this aiscnarge occurs nlonth manN

DISCHARGE SERIAL NUMBER 007

13. Activity Description Give a 213a See Attachment lB for narrative nanative descnption of activity descri tion of activities'contri-producing this cischaige (see butin to this discharge.

instrucbons)

14. ActivityCausing Discharge For each SIC Code which descnbes the actNIty causIng this discharge, supply the type and maximum amount of either the raw matenal consumed (Item 14a) or the pnxfuct produced (Item 14b) in the units specrliedin Table I of the Insttucbon BookhL For SIC Codes not 5sted in Table I, use raw material or pioducbonnunits normally used for measunng production (see instrucbons) a Raw Matenals Maximum Unit Shared Discharges SIC Cede Amount/Dav (See Table I) (Seria Number) 214a i4 I 4952 Domestic 685w People WA Haste See Attachment 18 Maximum Unit Shared Discharges SIC Code Name Amount/Dav See Table I) ISerial Number) 21 l41 4911 Elect:ric 0.9 Z" 1 NA Power Services

DISCMARGESERIALNUMBER 007 15 Waste Abatement a Waste Abatement practices 215a See Item 26 Describe the waste abatement praceces used on this dis-charge wrth a brief nanative (see rnstnrctions)

b. Waste Abatement Codes 215b Using the codes listed in Table II of the Instnrction Booklet, descnbe the waste abatement (10) BSTABI (11) BACTIV (12) BABPAT processes for this discharge in 15) the order in which they occur (16) 18) if possrbfe. (19) (20) (21)

(24)

(25)

DISCHARGE SERIAL NUMBER 007

16. WastewaterCharactenstics .'.(See'adem 26)

Check the box beside each constituent whichis present in the effluent (discharge water). This determinationis to based on actual analysis or best esumate.(see insuucsons) raremeter resent rarameter resent 216 216 oior pper OCC60 01042 mmonia ron OC610 01045 rganic nitrogen 00605 01051 X i ate agnes iufll 00620 00927 itnte anganeso 00615 01055 elcuiy 719' X I ate yoaenum 00945 01062 lilac ICKeI 00745 01067 Ie nium 00740 X 01147 X romiae oi ver 71870 01077 onae otassium 00940 00937 ium 00929 onae aiiium 'I ~

1 01059 uminum ium 01105 01152 inony in 01097 01102 rsenic c 01002 01092 Iyiiium giciaes 01012 X 74051 num onnatea organic compounas 01C07 74C62 ion esuciaes 01022 74C63 aamium i ana giease 01027 OC650 aicium 00916 c oait 01037 X tomium 01034 Chlorine X recai couiorm oaciena aaloactNIty 74055 X 74050 X

'pecify substances. compounds andlor elements in Item 26.

Pesticides (Insecticides. funacides. androdenticides) mustbe reportedin terms of the acceotable commonnames specified in Acceptable Common Names and chemical names lor rrie lngierient stalemenr on pesrrcr'de Labels. 2nd Edition. Erwironmentai protection Agency, wash.;;"-.n. D.c. 20250, June 1972, as requimdby Subsecuon 16? 7(b) of the Regulations for the Enforcement of the Federal Insecccide, Fungicide. and Rodenticide Act.

CIA M DISCHARGE SERIAL NUMBER 007 4 t7. DescriptionoflntakeandOischargo (See Item 26)

For each of the parameters listed bebw, enterin the appropriate box the value or cods lottor answer calod for(see instructions)

In addtion. enterthe parameter name and code and all required values for any of tho fdbwing parameters if they eie checkodin item 16:

ammonia. cyanide. aluminum, arsenic. beryllium, cadmium, chromium. copper, lead, moicuiy... nickel. selenium. nnc, phends, oil and grease, and chlonne (residual).

n nt n a a n. aiy immum aximum requency um er o pio Parameter and Cods Intake Treated Average Value Value of Analysis Analyses Type Water Intake Obsewed or Obsoivod or 2)7 (Daily Water Expected Expoctod ave rago) (Daily During During average) Discharge Discharge Activity Activity (2) (3) (4) (5) (8) (7) (8)

I low

?f Gallons porday 50050 0.015 > 0 0,023 CONT NA NA p

Units (X)400 6.0 e.s 2/7 mperaturo (winter) emperature (summer)

OF 74027 66 50 1/7 14 iocnemciai xygsn Oo mand (BOD 5-Oay) 7.6 1/7 15 mg/I K310 meat xygen Domand (COD) mgi) 00340 0 hU spoil oso (nonfilterable) Solids mg/I 12 1/7 00530 pociiic oncxictance miciomhos/cm at 25'C 00NS atxo anor (residue) ml/I (0545 er discharges sharing intake (tow (serial numbers) (see instructions)

DISCHARGE SERIAL NUMBER 007 (Cont'd),

n uent uent ntieatea n. iant aliy inimum aximum requency umoer Parameter and Code Intake Treated Average Value Value of Analysis of Type Water Intake Observed or ObseNed or Analyses 217 (Daily Water Expected Expected average) (Daily During During average) Discharge Discharge Activity Actnrity f2) 3) f4) f5) f6) f7) f8) Units 1esidual Chlorine (500 0) <0. 1 <0. 1 <0. 1 2/7 30 mg/1

.otal Nitrogen (00625) 8.07 8.07 8.07 1/90 mg/1

".otal Phos horus (0066 ) <0.05 <0.05 <0.05 1/90 ng/1 unnonia 00610 0.8 <0.02 3.9 1/7 ng/1

18. Phnt Controls Check if the following plant controls are available for this dischaigo 218 Alternate power source for major pumping facility Alarm or emergency procedure for power or equipment failure Qx ALM Complete Item 19 if discharge is fro coding endor steam water generation and water tmatmont additives amused

19. Water Treatment Additives If tho discharge Is treated with any conaitioner, inhibitor, or algicido, answer tno following:

a Name of Material(s) 219a See Item 26

b. Name and address of 219) See Item 26 manufactumr c, Ouantity (pounds addod per 219c See Item 26 million gailons of water treated)

thill C C ss DISCHARGE SERIAL NUMBER 007 s

d. Chemical composition of these 219d See Item 26 additives (see insuuctions)

Complete Items 20-25 if there is a thermal dischatgo (e.g.. associated with a steam and(or power gonoraton plant. steel mill, petroleum refinery, or any otnor inanufactunng piucess) and the total dschaigo tfow is 10 million gallons por day or more. (see instructions)

Thermal Discharge Source. Check tho appiopnato item(s) incfcaung tho source of the discharge (seo instructions) NA Boiler Slowdown Q BLBD Boiler Chemical Cleaning Q BCCL Ash Pond Overhow Q APOF Boiler Water Treatment- Q EPBD Evaporator Blowdown Oil and Coal Fired Phnts.ENuent from Air Pollution Control Devices Q OCFP Condenso Cooling Water Q COND Cooling Tower Blowdown Q CTBD Manufactuifng Process Q MFPR Other Q OTHR Discharge/Receiving Water Temperature Difference Give the maximum tomporaturo dNe rance between the discharge and receiving waters for summer and winter operating conditions see instructions) ummor 221a NA CF Winter 221b 'F Discharge Temperatum, Rate ot Change Per Hour 'Fihuur Give the maximum possible rate of te raturo change perhourot undor operating conditions (soe instructions)

Water Tempeiatuto, Percentile NA Report(Frequency ot Occunonco) ln tho table below. enter tho temperature which is excoecM 10%

of the year, 5% of tho year. 1% of the year andnot at ail (maximum yeaity temperature). (see i~Curn.

instructions)

Frequency of occuimnce 1 lo 1% aximum

a. Intake Water Temperature (subject to natural changes 'F 0F CF 'F

b. Discharge Water Temperature CF 0F OF Water Intake Velocity (see instructions l Retenton Time Give the lenath ot miuuiss time. in minutes. from start of water temoerature nse to discharae of coosng water. (seo insuuctionst

tVh Avcis>'r Ubc DISCHARGE SERIAL NUMBER 007 Adrenal Information

<em rn ormatron Refer to followin a es

Carolina Power & Light Company Harris Nuclear Plant NPDES Permit Renewal DISCHARGE SERIAL NUMBER 007

26. Additional Information Item Information Engineering drawings and other related documents are available upon request.

15 P SCREE: Screening is accomplished at the bar screen and comminutor area to hold or eliminate any large items that may damage the liftstation pumps.

15 PSEDIM: The grit chamber is designed to settle any inorganic solids that flow through its confines ifheavier than water.

15 PSKIMC: Oil & grease separator is used collect oil and grease from laboratory flows.

15 PSANDF: The lagoon system utilizes an upflow sand filter at the effluent area to remove any solids.

15 PDIATO: The radwaste system has a diatomaceous earth filter incorporated in to its design at the holding tank area.

15 CNEUTR: Limestone pit is designed to neutralize acidic influents from the laboratory flows.

15 CPHADJ: Hydrated lime and sodium hydroxide are used to buffer the pH. Lime is used in Lagoon 1 and sodium hydroxide is used in Lagoon 3.

15 CFLOCC: Aluminum sulfate is used in Lagoon 3 to develop flocculation of solids prior to discharge to the sandfilter.

15 CCLDIS: Sodium hypochlorite is blended with effluent from Lagoon 2 prior to entry into Lagoon 3 to remove algae and disinfect any possible disease carrying organisms.

15 BSTABI: Lagoons 1 & 2 are facultative ponds. Biological breakdown of organics is accomplished through both aerobic and anaerobic microorganism activity. The majority of the lagoons contents are aerobic but the sludge at the bottom also assists with breakdown of organics anaerobically.

8 Carolina Power & Light Company Harris Nuclear Plant NPDES Permit Renewal Item Information 15 BACTIV: Lagoon 1 utilizes activated sludge as it main constituent for effective removal or breakdown of introduced wastes.

15 BAERAT: Lagoons I & 2 are aerated lagoons.

15 BDENIT Denitrification and nitrification are accomplished in BNUTRI: Lagoon I by the typical breakdown of the introduced wastes by the activated sludge.

16 Chemical constituents contained in this discharge that may be conveyed to Harris Lake will in part be representative of the naturally occurring chemical quality of the intake water and will also have chemical constituents of such quality and quantity associated with similar discharges for domestic wastewater treatment facilities of this size, type, and in this geographical location. Either all or part of the elements listed in the Periodic Table, either singularly or in any combination, may from time to time be contained in the discharge.

16 Constituents checked are either I) known to be present in the specific waste streams or 2) used in a process which could result in discharge to waste streams.

16 Radioactive components of releases are regulated by the North Carolina Division of Radiation Protection and, therefore, not addressed in this application.

16 The Algicide currently used in the building air conditioning system that may be in the system's blowdown is an aqueous glutaraldehyde solution.

17 The influent data requested is variable in nature and not normally under the control of the applicant. The effluent data provided are derived from the Discharge Monitoring Reports previously submitted to DEM. These documents are incorporated by reference in this submittal.

17 EPA - approved procedures are used for all NPDES - required analyses.

19 Water Treatment Additives l.'. Aluminum sulfate Koch Refining Company Post Office Box 64598 St. Paul, MN 55164 1581 lbs./million gallons Same as la.

Carolina Power & Light Company Harris Nuclear, Plant NPDES Permit Renewal Item Information 19 (cont.) The aluminum sulfate is. added to Lagoon 3 during the discharge of the final one-third of batches of 80,000-100,000 gallons. This material is used to bind the colloidal solids together and create a heavy mass that will readily settle to the bottom of the lagoon.

2. a. Sunny Sol 150 (sodium hypochlorite bleach)

Jones Chemicals, Inc.

80 Munson Street Leroy, NY 14482

c. 5797 lbs./million gallons Sodium hypochlorite Sodium hydroxide Inert ingredients

e. The sodium hypochlorite is blended in the telescoping valve box with the effluent from Lagoon 2 for consistent mixing to control algae. This is performed in the batch process prior to adding aluminum sulfate.

3. a. Liquid caustic soda, 50%

PPG Industries One PPG Place Pittsburgh, PA 15272 C. 1272 lbs./million gallons

d. Sodium hydroxide Used to buffer pH up to acceptable ranges. The aluminum sulfate has a very low pH and typically drops the contents of Lagoon 3 below 6.0.

4. a. Bio-Neutralizer Norweco, Inc.

220 Republic Street Norwalk, Ohio 44857

c. 225 lbs./million gallons

d. Sodium sulfite@35%

Inert ingredients @ 65%

Used at the end of treatment to remove any chlorine that is present in the effluent.

ATTACHMENT1A DESCRIPTION OF WASTE STREAMS HARRIS NUCLEAR PLANT

ATTACHMENT1A PAGE 1 of 7 DESCRIPTION OF WASTE STREAMS HARRIS NUCLEAR PLANT INTRODUCTION The Harris Nuclear Plant (HNP) consists of a 900 MW generating unit and associated facilities. The HNP systems include a Westinghouse pressurized water reactor, three recirculating steam generators, a turbine generator, a one-pass condenser, an open recirculating (cooling tower) cooling water system, and a lake to makeup water lost by evaporation. In a pressurized water reactor design, steam is produced in the secondary system steam generators using hot water from the reactor core. The primary system does not normally come into contact with any other part of the generating system, such as the steam cycle which includes the turbine and the condenser.

COMBINED HNP OUTFALLTO HARRIS LAKE The HNP operates on an open recirculating cooling system using a natural draft cooling tower and 4100 acre makeup water storage reservoir. All five major wastewater discharges at the HNP are combined in a 36-inch diameter common pipe which discharges to the Harris Lake 500 feet offshore at 40 feet below the surface (Discharge Serial No. 006 in this application.) The individual waste streams contributing to the common outfall pipe are: cooling tower blowdown, sanitary waste treatment plant effluent, metal cleaning wastes, low-volume wastes, and radwaste system. (These waste streams are enumerated in the present permit as Discharge Serial Numbers 001, 002, 003, 004, and 005, respectively.) Monthly toxicity testing has been conducted on the combined outfall line since February 1990. Each of the waste streams, as well as miscellaneous discharge points, are described in this narrative. Also included is a list of chemicals which are expected to be in waste streams from the HNP (Attachment 6).

HNP COOLING TOWER BLOWDOWN TO HARRIS LAKE The cooling tower provides the condenser with a supply of water for removing the heat rejected by the condensation of steam. (The recirculating water temperature rise across the condenser is 25 F.)

This heat is dissipated primarily by evaporation as the water falls through the tower. This evaporation is essentially pure water vapor, with the dissolved and suspended solids remaining to concentrate.

ATTACHMENT1A PAGE2of7 To prevent the solids from causing scale and corrosion problems, some of the concentrated cooling water is discharged from the cooling tower basin, i.e., blowdown. During plant operation, the cooling tower basin continuously discharges for optimum performance. Blowdown currently averages approximately 6 MGD. Makeup water for cooling tower evaporative losses and cooling tower blowdown is provided from the main reservoir. The cooling tower also serves as a partial source of service water, which is used for non-contact cooling of.auxiliary equipment throughout the plant. The cooling tower is infrequently drained for maintenance. The normal operating procedure includes draining the residual water to the lake via Discharge Serial No. 006.

Occasionally, the condensers are drained for maintenance and repairs. When the condensers are drained, it is necessary to route the residual water (approximately 60,000 gallons per condenser per event) to area storm drains which discharge to the lake. This water is monitored prior to discharge for appropriate parameters required for cooling tower blowdown in accordance with the NPDES permit. Presently, condenser draining events are reported with relevant monitoring data to DEM on attachments to monthly Discharge Monitoring Reports.

Several chemicals are used (or planned for use) in the treatment ofthe circulating water. Information concerning these chemicals and approximate dosages are provided below. (The chemical supplier is subject to change at any time.)

Chemical Description Approximate Dosage BETZ FOAMTROL 144 Foam control agent 100 gallons/year BETZ CPL-12 Aqueous solution of approximately 40 lbs/million gallons 24% zinc chloride BETZ CPL-09 Aqueous solution of polyacrylic 39 lbs/million gallons acid based copolymer BETZ CPL-08 Aqueous solution of approximately 40 lbs/million gallons 40% sodium tolyltriazole BETZ 3690 Aqueous solution of non-ionic Amount varies depending on surfactant biodispersant biological activity and temperature of makeup water Sodium hypochlorite Approximately 15% solution Amount varies depending on biological activity and temperature of makeup water BETZ CPL-11 Aqueous solution of approximately 112 lbs/million gallons 73% orthophosphate

ATTACHMENT1A PAGE 3 of 7 HNP SEWAGE TREATMENT FACILITY A 0.05 MGD extended aeration sewage treatment facility serves the HNP. The facility consists of dual-path equalization tanks, aeration tanks, sludge holding tanks, clarifiers, and chlorine contact tanks. Disinfected effluent is pumped to the common outfall pipe. Currently, sludge is land applied offsite by a contract disposal firm (Hardee's Septic Tank Service, PgrmitNo.%Q0000584, effective November 9, 1993, expiration September 30, 1998). The contractor adds lime to the sludge for stabilization. Because the HNP sewage treatment facility receives industrial type waste as well as domestic type waste, the land application of the mixed sludge meets the exemption conditions stipulated at 40 CFR Part 503.6.

In addition to sanitary waste, HVAC condensate and organic developers from the microfilm processing laboratory (approximately 52 gallons/year) are discharged to the sewage treatment facility. (Hazardous and ammonia-containing components of developing waste are disposed of as hazardous waste and low-volume waste, respectively.)

Chemicals used (and approximate quantities) in the sewage treatment facility are described below.

The chemical supplier is subject to change at any time. Chemical composition of the Betz products is proprietary information.

Chemical Approximate Quantity Sodium hypochlorite (15%) 2000 gallons/year BETZ FOAMTROL 144 50 gallons/year Sodium hydroxide (50%) 2500 gallons/year BETZ Polymer 1192 600 gallons/year HNP METALCLEANING WASTES Infrequently, cleaning of heat exchanger equipment by chemical solutions may be necessary.

Cleaning solutions would be routed to the waste neutralization basin for pH adjustment (or other chemical neutralization) prior to discharge to the settling basin where further treatment by sedimentation occurs. To date, the only metal cleaning which has been conducted was a preoperational flush. Ifa new system is added in the future, flushing could be necessary again.

Also, metal cleaning may be needed in the future for plant systems (e.g., steam generators, auxiliary boilers, piping, etc.). Chemical solutions used may include phosphates, organic cleaners, citric acid, or oxalic acid.

ATTACHMENT1A PAGE 4 of 7 HNP LOW VOLUMEWASTES In the operation of the HNP, there are many processes which result in intermittent low volumes of various waste streams. Low-volume waste is treated by neutralization (for pH adjustment),

sedimentation, and separation. These wastes may be treated in the oily waste separator and/or neutralization basin as needed prior to routing to the sedimentation basin, which ultimately discharges to the common outfall line. Chemicals present in these systems may include corrosion products (such as copper and iron) corrosion inhibitors (such as nitrites, molybdates, ammonia, hydrazine, carbohydrazide, and ethanolamine), acids and bases from water treatment processes, and wastewater &om ion exchange processes and ammonium bisulfite &om dechlorination. Low-volume waste flow &om the settling basin averages approximately 0.2 MOD. The various low-volume waste sources are described below:

a) Water treatment system wastes from processing of demineralized water and potable water.

(The water treatment system includes coagulation, filtration, disinfection, and ion exchange.

Wastes from treatment include filter backwash and demineralizer regeneration wastes.)

b) Non-radioactive oily waste, floor drains, and chemical tank containment drains.

(Turbine building wastes which could contain oil are routed to the oily waste separator for treatment prior to routing to the neutralization basin. Used oil is collected by a contractor for reclamation.)

c) Steam generator and auxiliary boiler draining following wet layup d) Non-radioactive secondary waste from condensate polishers e) Miscellaneous drains/leaks from condenser, steam generator, and secondary components f) Ammonia-containing wastes from microfilm processing laboratories g) Auxiliary boiler system blowdown h) Miscellaneous waste streams not otherwise identified elsewhere in this application.

HNP RADWASTE TREATMENT SYSTEM

~ ~ ~

The radwaste system is designed to collect, store, process, and release any radioactive or potentially radioactive liquids associated with operation of the nuclear power plant. The waste streams are collected in tanks and sampled for conventional pollutants and radioactivity. The specific batch

~

ATTACHMENT1A PAGE 5 of 7 treatment is selected based on these analytical results. This allows for selection of the proper treatment processes for each individual batch. Most radwaste streams are treated by the Modular Fluidized Transfer Demineralization System (MFTDS) that uses filtration and ion exchange in a manner that minimizes the production of solid wastes. Boric acid is recycled. The secondary waste system (SWS) is for treating radioactively-contaminated water from the secondary steam cycle system; however, since that system is not normally contaminated, those flows are routed to the normal low-volume waste treatment system aAer radiological monitoring.

AAer treatment, the radwaste flows are stored in one of four tanks: the secondary waste sample tank, the treated laundry and hot shower tank, the waste monitor tank, or the waste evaporator condensate tank. After monitoring to verify adequate treatment, the tanks are discharged to the common outfall line.

The cooling tower bypass line provides a flow of lake water for radwaste releases, as regulated by the NRC.

OTHER HNP DISCHARGES

'unoff from parking lots, outside storage areas, roof drains, and other areas on the plant site are collected in storm drains and ultimately routed to release points which discharge to Harris Lake. Flow contributed from those areas is estimated at 8.8 million gallons per month, based on average rainfall of 43 inches per year and a runoff assumption factor of 0.7. Further description of the storm drain system was provided to NCDEM in a copy of the group stormwater application submitted in accordance with the EPA final stormwater regulations.

A diagram and additional description of the stormwater routing system at the HNP is provided with this application in Attachment 7.

In addition to stormwater, a few miscellaneous sources ofwater are also intermittently routed to the storm drains. These sources that have a minor contribution to overall storm drain flows are as follows:

flwfi er I we r The upflow filter clearwell stores filtered lake water which is used in the potable water treatment system. Periodically, some of the water from this tank is drained to the storm drains that discharge to Harris Lake via SW-5 (see Attachment 7). This water may contain low concentrations of chlorine because sodium hypochlorite is added to control biological growth in the tank prior to treatment through the upflow filter.

ATTACHMENT1A PAGE 6 of 7 e exch r he emi ral'r fe dw' During the cold months, it is necessary to heat the source water to the demineralized water treatment system to achieve optimum degassification. To accomplish this, steam is used to heat the feedwater. The condensed steam is discharged to the storm drains that flow to Harris Lake via SW-5 (seq Attachment 7) at approximately 5 - 10 gallons per minute. This steam could contain trace amounts of hydrazine and ammonia used for chemistry control in the auxiliary boiler steam system. Due to the low flow rate and the long retention time, the temperature of the condensed steam should be at ambient temperature upon reaching the lake.

en rwa er dr Prior to condenser maintenance or repairs it is sometimes (approximately twice/year) necessary to drain circulating water to the storm drains (approximately 60,000 gallons per condenser per event) that discharge to Harris Lake via SW-4 (see Attachment 7). This water is monitored for selected cooling tower blowdown parameters.

il edw e r e Water from the upflow filter clearwell is treated with carbon filters for turbidity control and then stored in a tank prior to subsequent filtration and disinfection.

Occasionally, some water from this tank may be drained to the storm drains that discharge to Harris Lake via SW-5 (see Attachment 7). This water may contain trace amounts of chlorine.

're e i Approximately 5000 gallons of lake water used for annual testing of the fire protection system is routed to most of the storm drains that discharge to Harris Lake.

In the event of a fire, additional water could be discharged to storm drains.

o eh wll During outages (approximately once per 1S months) it is necessary to drain the condenser hotwell for condenser maintenance and inspection. Approxmiately 70,000 gallons of this water resulting from condensed steam is drained to storm drains that discharge to Hams Lake via SW-4 (see Attachment 7). It may contain trace amounts of ethanolamine, 100 ppb or less of boron, and 100 ppb or less ammonia.

ATTACHMENT1A PAGE7of7

...g. ~

nden t a an I

Infrequently it is necessary to drain the condensate storage tank for maintenance.

Approximately 400,000 gallons per event is drained to storm drains that discharge to Harris Lake via SW-4 (see Attachment 7). It may contain 200 ppb or less boron, 1000 ppb or less ammonia, and trace hydrazine.

h. 'r c diti nin nden e The condensate from various building air conditioning systems flows to various storm drains to Harris Lake. The volume is generally low and is greatest in the humid summer months.

rvicew r e r in Infrequently, when service water strainers located at the makeup pumps from the cooling tower basin are backwashed to remove biofouling organisms or debris, a small volume of service water overflows the basin and runs to the adjacent storm drain that discharge to Harris Lake via SW-2 (see Attachment 7).

mer e ervice W er e This system primarily provides non-contact cooling water for nuclear safety-related equipment systems and during emergency conditions. The emergency service water system discharges to the auxiliary reservoir which is used as the plant's heat sink during emergency conditions, a feature required by Nuclear Regulatory Commission regulations to provide a reliable supply of cooling water. Under normal operating conditions, the auxiliary and the main reservoirs are isolated from each other; however, the reservoirs may be connected as necessary. In addition to emergency situations, this system is used periodically for testing purposes or for containment cooling as needed. This water may contain traces of chemicals identified for the cooling tower blowdown.

8 ATTACHMENT1B DESCRIPTION OF WASTE STREAMS HARRIS ENERGY & ENVIRONMENTALCENTER

Cl ATTACHMENT1B PAGE10f2 DESCRIPTION OF WASTE STREAMS HARRIS ENERGY 4 ENVIRONMENTALCENTER INTRODUCTION The Harris Energy & Environmental Center (HE&EC) includes facilities that provide support services (laboratories and training classro'oms) for the HNP and other CP&L operations. The sources of wastewater at the HE&EC are domestic waste, conventional laboratory waste, cooling tower blowdown, and potentially radioactive liquid waste from the radiochemistry and metallurgy laboratories. Additionally, floor drains from several shops and storage buildings are routed to the wastewater treatment facility. Allwaste streams, with the exception of the radiological wastewater, receive treatment in the 0.020 MGD wastewater treatment facility.

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Components of the treatment facility include a comminutor and manual bar screen, a submersible pump station as an influent pump station, three treatment ponds, sand filtration, and chlorination and dechlorination (or UV disinfection). The pond treatment system consists of an aerated pond with a minimum retention time of 10 days followed by a stabilization pond, also with a

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minimum retention time of 10 days. The third pond is a polishing pond with a minimum 2-day

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retention time. Effluent from the treatment facility is discharged via the effluent discharge pipe into

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Harris Lake.

The sludge from the treatment facility will be land applied by a contractor (currently, Wallace Woodall Vacuum Pumping, Inc., Permit No. WQ0000506, effective July 8, 1993, expiration September 30, 1997) when necessary. Because the treatment facility receives industrial type waste as well as domestic type waste, the land application of the mixed sludge meets the exemption conditions stipulated at 40 CFR Part 503.6.

DOMESTIC WASTE The maximum domestic waste flow from the HE&EC sanitary facilities is approximately 0.014 MGD. In addition to the 235 permanent employees on site, the HE&EC, serving as a Company training facility and as a visitors'enter for the nearby Harris Nuclear Plant, accommodates a fluctuating population (ranging from 0 to 450 additional people per day).

LABORATORYWASTE Laboratory waste flow, consisting primarily of rinse water from the chemical, metallurgical, and biological laboratories, is approximately 0.001 MGD. HE&EC personnel are educated in the proper disposal of laboratory wastes and are encouraged to minimize the use of laboratory drains for chemical disposal. Most laboratory chemical wastes and virtually all oily wastes are drummed for

ATTACHMENT1B PAGE 2 of 2 off-site disposal. Laboratory-wastes that are not drummed may go to one of two 5,000 gallon holding/neutralization tanks for visual inspection and testing before being discharged to the influent pump station.

COOLING TOWER BLOWDOWN Cooling tower blowdown from the HE&EC air conditioning system averages approximately 0.002 MGD. Chemical additives include an algicide (aqueous glutaraldehyde solution) and a suspension agent. The treatment and extended retention time in the treatment ponds should ensure that no algicide is discharged to Harris Lake.

RADIOLOGICALWASTEWATER The majority of the radiological wastewater results from the cleaning of laboratory glassware. In addition, small quantities of liquid radiochemistry laboratory samples, radioactive metallurgy laboratory wastewater (which is prefiltered with a paper cartridge to remove particulates before disposal), liquids generated from analyses of plant 10 CFR Part 61 samples, and reagents are disposed via the HE&EC radiochemistry laboratory drains to a holding tank. Approximately 5,000 gallons are discharged annually from the holding tank to the effluent discharge line below the sewage treatment plant and into Hams Lake, as allowed by radioactive materials License No. 092-0218-4, issued by the N. C. Divisiori of Radiation Protection.

Radiochemcial analyses are performed prior to release to calculate the total radioactivity in the waste. These analyses include a gamma spectrum analysis using intrinsic germanium gamma spectrometry systems, as well as direct analysis for Tritium, Iron-55, Nickel-63 and Strontium-89/90.

Individual radionuclides have different release limits; however, the total release for all radionuclides may not exceed one curie per calendar year.

Additionally, the pH of the wastewater is determined before release. The pH must be between six and nine and is adjusted, ifnecessary, using 50% sodium hydroxide. The tank is agitated aAer addition of the sodium hydroxide, and an additional sample is analyzed to verify that the appropriate pH adjustment is achieved.

STORMWATER Stormwater runoff from the HE&EC is composed only of parking lot, roof, and lawn drainage. This non-industrial stormwater is not subject to the Phase 1 stormwater regulations at 40 CFR Part 122.

ATTACHMENT2 PERMITS, LICENSES, AND APPLICATIONS HARRIS NUCLEAR PLANT HARRIS ENERGY & ENVIRONMENTALCENTER

CHMENT2 PERMITS, LICEN ND APPLICATIONS (SECTION I, ITEM NO. 10)

DATE DATE ISSUING AGENCY TYPE OF PERMIT ID NUMBER FILED DATE ISSUED EXPIRATION Division of Health Services Main Reservoir 633 2/1 1/74 11/5/80 Division of Health Services Auxiliary Reservoir 633 2/11/74 9/5/79 Division of Environmental Management Well Construction 2497 7/1 1/73 7/14/77 Division of Environmental Management Well Construction 1290 7/11/73 7/16/73 Division of Environmental Management Well Construction 1145 4/4/73 4/17/73 Division of Environmental Management Well Construction 922 11/2/72 11/13/72 Division of Environmental Management 401 Certification WQC-1198 3/7/83 9/4/77 Division of Environmental Management 401 Certification WQC-214 8/8/73 12/20/73 Division of Solid Waste Management Industrial Landfill 92-10 1/27/86 8/28/86 Division of Environmental Management NPDES (HNP) NC0039586 9/27/90 11/1/91 3/31/96 Division of Environmental Management NPDES (HNP Landfill) COC NGG 120032 10/1/92 4/30/93 Division of Environmental Management NPDES (HE&EC) NC0026735 5/26/93 5/1/94

• 3/31/96 Division of Environmental Management Nondischarge WQ0009475 5/19/94 12/21/94 11/30/99 Division of Environmental Management Nondischarge <<*WQ0000584 11/9/93 9/30/98 Division of Environmental Management Nondischarge <<<<WQ0000506 7/8/93 9/30/97 Wake County Planning Land Use 3830 4/1 1/74 ~ 4/11/74 Wake County Planning Land Use 13383 3/20/78 3/20/78 Nuclear Regulatory Commission Facility Operating NP F63 12/22/81 10/24/86 - low power operating license 10/24/2026 License 1/12/87 - full power operating liccnsc Division of Radiation Protection Radioactive Materials 092-0218-4 12/5/94 12/27/94 9/30/98 License (Amendment 39)

No expiration date specified Permits held by contract disposal firms

ATTACHMENT3 HARRIS NUCLEAR PLANT AND HARRIS ENERGY & ENVIRONMENTALCENTER LOCATION MAP

Jack, QS1 Tom Creek

~ " Thomas Creek Harris Plan 1 CO

'EE E3 Little White Oak Creek White Oak Creek Cg 00T Intake Auxiliary Canal Reservoir t

Emergency Service .r Water Intake go ..~

gx Cary Branch

~Holleman's Crossroads Boat Ramp Buckhom Creek 006 NC 42 Boat Ramp 0 1 2

-oi Main Dam Kilometers NC 42 0 1 Buckhorn Miles Creek

', 'arris Nuclear Plant Attachment 3 Carolina Power & Light Company Harris Nuclear Plant NORTH CAROLINA Wake County, NC Location Map Page 1 of 1 September 1995

ATTACHMENT4A HARRIS NUCLEAR PLANT SCHEMATIC OF WATER FLOW

Notes:

1. See attached pages 34 for table of how rates emergency

2. See narrative for description of major Auxiliary Reservoir Fire Protection water 29 waste streams 37 24 make-up Harris Reservoir 3o Storm Drains cooing tower (See Datati A on page 2) ss ine 5 evaporative 58 losses l 25 4

31 Low Volume Waste 26 39 Sanitary Wastewate Cooling Tower Settling Basin Water Pretreatment Potable Water Treatment 32 27 38 40 plant & HEEC Usage 21 16 <oo3 Metal Cleaning Service Water Waste Non-contam. Oily Make-up and Reactor Coolant 42 33 Condenser Waste & Floor Drainsl Polishing System Oily Waste Separator Demineralizers 12 35 43 Radwaste 17 19 Processing System (See Detal7B on Page 2)

Condensate Waste Chemical and 48 Deminera!izers Polishers eutralization Basins Auxiliary Boilers Volume Control 49 S stem 13 10 Steam Generator,5 Reactor Condensate Storage Attachment 4A 45 Carolina Power 8 Light Company Secondary Waste Harris Nuclear Plant-Wake County, NC Holding Tanks Schematic of Water Flow Page 1 of 6 September 1995

25 Treated water tank drains 4~ Yard & roof drains Storm Drains Water treatment steam heater drains Detail A 57 Condenser water box drains 37 Fire protection system 42 00 Secondary Waste Sample Tank I

to 49 Reactor coolant system Boron recyde M 51 Cl Equipment drain Treated Hot a Shower Tank lO to Secondary waste O 52 005) Waste Monitor 0 Floor drain Detail B Q.

Tank O Laundry hot shower CJ Laboratory 005 Waste Evaporator U Condensate Tank C5 Filter back flush Boron recyde to chemical &

To combined outfall (CTB) line volume control system Attachment 4A Carolina Power 8 Light Company Harris Nuclear Plant-Wake County, NC Schematic of Water Flow Page 2 of 6 September 1995

HMENT 4A PAGE 3 of 6 HARRIS NUCLEAR PLANT APPROXIMATE WATER USE UNDER VARIOUS STATION CONDITIONS FLOW@ FLOW @

STREAM MAXIMUMPOWER

• TEMP. SHUTDOWN

• NOTES 21,QQQ gpm 21,000 gpm Emergency/Testing/Intermittant use 510 MGM 0- 5 MGM Varies with dissolved solids 864 MGM 9 MGM Cooling tower makeup 648 MGM 4 MGM Average meteorological conditions 0-14,000 gpm 0-14,000 gpm Cooling tower bypass line 500,000 gpm 0 - 284,000 gpm 500,000 gpm 0 - 284,000 gpm 300 gpm 0 - 176 gpm 20,800 0- 10,000 Intermittant operation 10 300 gpm Q - 176 gpm 1.2 MGM 210,000 Condensate polisher regenerations and rinse (Intermittant operation) 12 24,000 gpm 0 - 16,500 gpm 13 24,000 gpm 0 - 16,500 gpm 14 315,900 gpm 0 - 185,000 gpm 15 315,900 gpm 0 - 185,000 gpm 16 6 MGM 5 MGM

• Units: Gallons per month unless otherwise noted MGM = million gallons per month gpm = gallons per minute

HMENT 4A PAGE 4 of 6 FLOW FLOW@

STREAM MAXIMUMPOWER

• TEMP. SHUTDOWN

• NOTES 17 208,300 208,300 18 Very infrequent operation 19 666,600 666,600 20 500 500 Auxiliary boiler drains 21 50,000 gpm 50,000 Service water system gpm 22 1,220,800 220,000 Secondary waste (Nonradiological), alternate route 23 Secondary waste (Radiological), not normally used 24 0- 1 MGM Make-up as needed 25 7,645,000 7,645,000 26 4,000,000 4,000,000 27 300 lbs/month 300 Ibs/month Settling basin sludge 28 3,033 3,033 Treated water tank drains 29 11,000 11,000 Fire pump test 30 8,786,200 8,876,200 Storm drains includes rainwater and fire water 31 1.2 MGM 1.2 MGM Potable water 32 2,445,000 2,445,000 33 39,000 39,000 Reactor coolant system 34 1,200,000 1,200,000 Demineralized water 35 500 500 Demineralized water to auxiliary boilers

• Units: Gallons per month unless otherwise noted MGM = million gallons per month gpm = gallonsperminute

HMENT 4A PAGE 5 of 6 STREAM FLOW MAXIMUMPOWER

• FLOW I TEMP. SHUTDOWN

• NOTES 36 11,000 11,000 Fire pump test 1,167 1,167 Hydrant and drain tests 38 693,000 693,000 Plant and HE&EC water usage 39 0.2 MGM 0.2 MGM Sanitary waste 40 Sludge removal as necessary 41 8,340,000 8,340,000 Yard and roof drains 42 10,000 10,000 43 33,300 33,300 44 Makeup as required 45 1,220,800 220,000 Makeup for 9 and 11 46 0.2 MGM 0.2 MGM Sanitary waste 413,000 413,000 Rad waste 48 10,000 10,000 gpm Boron recycle 49 67,000 67,000 gpm Boron recycle JCUS letdown 50 30 30 Used oil 51 75,0OO 75,000 Equipment drains 52 316,000 316,0QQ Floor drains 53 7,000 7,000 Decontaminated waste 54 6,000 6,000 Laboratory waste (chemistry)

" Units: Gallons per month unless otherwise noted MGM = million gallons per month gpm = gallons per minute

HMENT 4A PAGE 6 of 6 FLOW@ FLOW STREAM MAXIMUMPOWER

• TEMP. SHUTDOWN

• NOTES 55 4,100 4,100 Varies with number of filter backwashes 56 5- 10 gpm 5- 10 gpm Water treatment steam heater drains 57 120,000 120,000 Condenser water box (approximately two drains/year) 58 6,950,700 6,950,700 Low-volume waste

• Units: Gallons per month unless otherwise noted MGM = million gallons per month gpm = gallons per minute

ATTACHMENT4B HARRIS ENERGY & ENVIRONMENTALCENTER SCHEMATIC OF %'ATER FLO%

Holding Tank TTF Ult Station Ult Station NDE Building (0.00t MGO)

Lab Waste Boat Storage Sump C&OS Building Building Cooling Tower (0.002 MGo)

Blowdown Filter Backwash EOF Building Lift Station Comminutorl influent Pump Aerated Pond Stabilization Pond Polishing Pond Sand Filter By-pass with Station (Lagoon 1) (Lagoon 2) (Lagoon 3)

Bar Screen (0.0 tl MGQ)

Fire Pump Once-through Blowers En ine Coolin (5,000 gatlnns sent) anntlttr)

Radiological Holding Tank Wastewater De-chlorination Chlorination System Oe.chbr Tabtets Attachment 4B Discha e Chlorine Contact Carolina Power 8 Light Company (0.0tl MGo) Tank Harris Energy & Environmental Center Wake County, NC Schematic of Water Flow Page1of1 September 1995

ATTTACHMENT5 CONVENTIONALAND PRIORITY POLLUTANTDATA

Page 1.

Received: /06/95 WEBB TECHNICAL REPORT CAROLINA POWER Ec LIGHT CO.

TO SHNPP 07/10/95 PREPARED Webb BY 4320

12:39

'ork REPORT Technical Grou Delta Lake Drive Inc.

Order 5 9 206 P.O. BOX 165 MAIL ZONE 5 Ralei h NC 27612 NEW HILL NC 27562 CERTIFXED BY ATTEN MR. WILLIAM LOMEYER ATTEN Client Services PHONE 919 787-9171 CONTACT R KARAS CLIENT CPLNH SAMPLES 1 COMPANY CAROLINA POWER &: LIGHT CO. We are leased to rovide this certified re ort of anal sis.

FACILITY SHNPP STATE ROAD 1134 Anal sis sam les will be retained for 30 da s after re ort is NEW HILL NC 27562 issued exce t those submitted for microbiolo ical testin WORK XD WW MONITORING CC CPS'TEVE TAKEN SOLLOD TRANS DELIVERY CLIENT P.O. BOX 1551 CPB3A2 TYPE 03-92-992 RALEIGH NC 27602 P.O. 0 XT10000064-A01 INVOICE under se grate cover SAMPLE IDENTIFICATION TEST CODES and NAMES used on this workorder 01 WW COMBINED OUTFALL 6 6 AG SILVER BY ICP EPA624 GC MS FOR VOLATILE ORGANIC AL ALUMINUM BY ICP FE IRON BY ICP AS ARSENIC BY ICP FLU DI FLUORIDE BY DISTILLATION BORON HG AA MERCURY BY COLD VAPOR BA BARIUM BY ICP MBAS METHYLENE BLUE ACTIVE SUB BE BERYLLIUM BY ICP MG MAGNESIUM BY ICP BOD BIOCHEMICAL OXYGEN DEMAND MN MANGANESE BY ICP CD CADMIUM BY ICP MO MOLYBDENUM BY GFAA CHLO W CHLORIDE - WATER N2 N3W NITRITE AND NITRATE -WATER CN TW CYANIDE TOTAL - WATER NH3 W AMMONIA WATER CO COBALT BY ICP NI NICKEL BY ICP COD CHEMICAL OXYGEN DEMAND NITROG TOTAL NITROGEN COLIF FECAL COLIFORM 0 G W OIL AND GREASE WATER COLOR COLOR WATER PB LEAD BY ICP CR TOTAL CHROMIUM BY ICP PHEW W PHENOLIC CMPDS DIST.-H20 CU COPPER BY ICP SB ANTIMONY BY GFAA E8150W HERBICIDES WASTEWATER SE SELENIUM BY ICP EP625A GC MS SEMIVOL. ACID EXTR. SFID W SULFIDE WATER EP625B GC MS SEMIVOL. BASE NEUT. SI AA SILICON BY ICP EP8140 ORGANOPHOSPHORUS PESTICIDE SN AA TIN BY ICP EPA608 CHLORINATED PEST. AND PCB S02 W SULFITE - WATER

Page 2 Received: /06/95 WEBB TECHNZCAL 07/10/95 REPORT

12:39 Work Order I9 206 TEST CODES and NAMES used on this workorder SO4 W SULFATE - WATER TI TITANIUM BY ICP TKN W TOT.KJELDAHL NIT.-WATER TL AA THALLIUM BY GFAA TOC W TOTAL ORGANIC CARBON -H20 TPHO W PHOSPHORUS TOTAL - WATER ZINC BY ICP

Page 3 WEBB TECHNICAL REPORT Work Order ¹ 9 206 Received: /06/95 -

Results by Sample SAMPLE ID WW COMBINED OUTFALL 6 6 SAMPLE ¹ 01 FRACTIONS: A B C D E P G H IJ K L M N 0 Date & Time Collected 06 06 95 08:00:00 Category AG <<0. 01 AL 0.220 AS <0.005 B 0.114 BA 0.032 BE <0.002 MG/L MG/L MG/L MG/L MG/L MG/L BOD 3.00 CD <0.005 CHLO W 26.6 (O.OQ5 CO <O.Q1 COD 3Q.8 MG/L MG/L MG/L MG/L MG/L MG/L COLIP 33 COLOR 30 CR c0.01 CU 0.011 E8150W SEE EP625A SEE PER 100ML COLOR UNITS MG/L MG/L ATTACHED ATTACHED EP625B SEE EP8140 NEGATIVE EPA608 SEE EPA624 SEE PE 0.518 FLU DI 0.209 ATTACHED PPM ATTACHED ATTACHED MG/L MG/L

<0.2 MBAS 0.133 MG 3. 73 MN 1.55 MO c0.005 N2 N3W 0.222 UG/L MG/L MG/L MG/L MG/L MG/L NH3 W 0.481 NI (0.02 NITROG 1.71 0 G W <5.00 PB <0.05 PHEN W <0.005 MG/L MG/L MG/L MG/L MG/L SB <3.0 SE <0.005 SPID W <1.00 SI AA 1.56 SN AA <0.2 SO2 W c3.00 UG/L MG/L MG/L MG/L MG/L MG/L S04 W 36.9 TI <0.01 TKN W 1.49 TL AA c1.0 TOC W 15.6 TPHO W 0.659 MG/L MG/ L MG/L UG/L MG/L MG/L ZN 0.141 MG/L

I WEBB TECHN CAL GROUP I INC ~

4325 Pleasant Valley Road, Suite 110 Raleigh, NC 27612 (919) 787-9171 CLIENT: CAROLINA POWER & LIGHT SHNPP SAMPLE ID: Combined Outfall 6/6 COLLECTED: 6/6/95; 08:00 RECEIVED FROM: Client Deliver WTG LOG NUMBER: 95-06-206-01 DATE RECEIVED'6/06/95 EPA METHOD: (8140) Com ounds Run b 625/Librar Search Mass S ectrometr DATE EXTRACTED: 06/12/95 DATE ANALYZED: 06/15/95 ANALYST: S. Branch QUANTITATION COMPOUND Demeton-0

~/ LIMIT 20 RESULT

~u/L BQL Demeton-S 20 BQL Ethyl Parathion 20 BQL EPA METHOD: 8150 DATE EXTRACTED'6/12/95 DATE ANALYZED: 06/20/95 ANALYST: K. Rehner

~i QUANTITATION LIMIT RESULT COMPOUND ucC/L 2, 4-D 12.0 BQL 2I4I5 T 2.0 BQL 2, 4, 5- TP (Silvex) 2.0 BQL BQL=Below Quantitation Limit Comments:

CERTIFIED BY: 4,.~Mw~ REPORT DATE: Jul 5, 1995

WEBB TECHNICAL GROUP, INC.

4325 Pleasant Valley Road, Suite 110 Raleigh, NC 27612 (919) 787-9171 CLIENT: CAROLINA POWER & LIGHT SHNPP SAMPLE ID: Wastewater Combined Outfall 6/6 RECEIVED FROM: Client Deliver COLLECTED: 6/6/95; 08:00 DATE RECEIVED: 06/06/95 WTG LOG NUMBER: 95-06-206-01H DATE EXTRACTED: 06/08/95 EPA METHOD: 608 DATE ANALYZED'6/19/95 PESTICIDES/PCB'S QUANTITATION LIMIT RESULT COMPOUND ug/L ug/L ALPHA-BHC 0.05 BQL BETA-BHC 0.05 BQL DELTA-BHC 0.10 BQL GAMMA-BHC (LINDANE) 0.05 BQL HEPTACHLOR 0.05 BQL ALDRIN 0.05 BQL PTACHLOR EPOXIDE 0.80 BQL NDOSULFAN I 0.10 BQL DIELDRIN. 0.02 BQL 4 4'-DDE 0.10 BQL ENDRIN 0.06 BQL ENDOSULFAN II 0.01 BQL 4,4'-DDD 0.10 BQL ENDOSULFAN SULFATE 0.70 BQL 4 4s-DDT 0.10 BQL ENDRIN ALDEHYDE 0.20 BQL CHLORDANE 0.20 BQL TOXAPHENE 2.40 BQL PCB-1016 0.50 BQL PCB-1221 0.50 BQL PCB-1232 0.50 BQL PCB-1242 0.50 BQL PCB-1248 0.50 BQL PCB-1254 0.50 BQL PCB-1260 0.50 BQL BQL=Below Quantitation Limit Comments:

ERTIFIED BY: ~ ~ REPORT DATE: Jul 3, 1995

WEBB TECHNICAL GROUP, INC.

4325 Pleasant Valley Road, Suite 110 Raleigh. NC 27612 (919) 787-9171 CLIENT: CAROLINA POWER & LIGHT SHNPP SAMPLE ID: Wastewater Combined Outfall RECEIVED FROM: Client Deliver COLLECTED: 6/6/95; 08: 00 DATE RECEIVED:

WTG LOG NUMBER: 95-06-206-01I DATE ANALYZED'6/06/95 EXTRACTED: N/A EPA METHOD: 624 DATE 06/13/95 VOLATILE COMPOUND QUANTITATION LIMIT RESULT ug/L ug/L CHLOROMETHANE 10 BQL VINYL CHLORIDE 10 BQL BROMOMETHANE 10 BQL CHLOROETHANE 10 BQL TRICHLOROFLUOROMETHANE 5 BQL 1i1 DICHLOROETHENE 5 BQL METHYLENE CHLORIDE 5 BQL 1I 1 DICHLOROETHANE 5 BQL TRANS-1,2-DICHLOROETHENE 5 BQL CHLOROFORM 5 BQL I 1 I 1 TRICHLOROETHANE 5 BQL ARBON TETRACHLORIDE 5 BQL BENZENE 5 BQL 1I2 DICHLOROETHANE 5 BQL TRICHLOROETHENE 5 BQL 1I2 DICHLOROPROPANE 5 BQL BROMODICHLOROMETHANE 5 BQL 2-CHLOROETHYLVINYL ETHER 10 BQL CIS-1,3-DICHLOROPROPENE 5 BQL TOLUENE 5 BQL TRANS 1I3 DICHLOROPROPENE 5 BQL 1i1g2 TRICHLOROETHANE 5 BQL TETRACHLOROETHENE 5 BQL DIBROMOCHLOROMETHANE 5 BQL CHLOROBENZENE 5 BQL ETHYLBENZENE 5 BQL BROMOFORM 5 BQL 1 i 1 i 2 g 2 TETRACHLOROETHANE 5 BQL 1,3-DICHLOROBENZENE 5 BQL 1,4-DICHLOROBENZENE 5 BQL 1I2 DICHLOROBENZENE 5 BQL BQL= Below Quantitation Limit Comments:

CERTIFIED BY: ~ REPORT DATE: Jul 3, 1995

Webb Technical Group, Inc.

4320 Pleasant Valley Road, Suite 110 Raleigh, NC 27612 (919) 787-9171 CAROLINA POWER & LIGHT SHNPP 'LIENT:

SAMPLE ID: Wastewater Combined Outfall 6/6 RECEIVED FROM: Client Deliver COLLECTED: 6/6/95; 08:00 DATE RECEIVED: 06/06/95 WTG LOG NUMBER: 95-06-206-01D DATE EXTRACTED: 06/12/95 EPA METHOD: 625 DATE ANALYZED: 06/15/95 ACID EXTRACTABLES QUANTITATION LIMIT RESULT COMPOUND ug/L ug/L 4-Chloro-3-methylphenol 10 BQL

. 2-Chlorophenol 10 BQL 2,4-Dichlorophenol 10 BQL 2,4-Dimethylphenol 10 BQL 2,4-Dinitrophenol 50 BQL 2-methyl-4, 6-Dinitrophenol 50 BQL 2-Nitrophenol 10 BQL 4-Nitrophenol 50 BQL Pentachlorophenol 50 BQL Phenol 10 BQL 2, 4, 6-Trichlorophenol 10 BQL BQL = Below Quantitation Limit Comments: This list of corn ounds is re resentative of, but not totall inclusive of, the entire EPA list of corn ounds which can be detected b Method 625.

CERTTFYED BY: ~ '

~~+~REPORT DATE: Jul 35 1995

WEBB TECHNICAL GROUP, INC.

4325 Pleasant Valley Road, Suite -110 Raleigh, NC 27612 (919) 787-9171 CLIENT: CAROLINA POWER 6 LIGHT SHNPP SAMPLE ID: Wastewater Combined Outfall 6/6 RECEIVED FROM: Client Deliver COLLECTED: 6/6/95; 08: 00 DATE RECEIVED: 06/06/95 WTG LOG NUMBER: 95-06-206-01D DATE EXTRACTED: 06/12/95 EPA METHOD: 625 DATE ANALYZED: 06/15/95 BASE NEUTRAL EXTRACTABLES QUANTITATION LIMIT RESULT COMPOUND ug/L ug/L ACENAPHTHENE 10 BQL ACENAPHTHYLENE 10 BQL ANTHRACENE 10 BQL

. BENZIDINE 50 BQL BENZO (A) ANTHRACENE 10 BQL BENZO (A) PYRENE 10 BQL BENZO (B) FLUORANTHENE 10 BQL BENZO (GHI) PERYLENE 10 BQL BENZO (K) FLUORANTHENE 10 BQL BIS (2-CHLOROETHOXY) METHANE 10 BQL BIS (2-CHLOROISOPROPYL) ETHER 10 BQL BIS (2-CHLOROETHYL) ETHER 10 BQL BIS (2-ETHYLHEXYL) PHTHALATE 10 BQL 4-BROMOPHENYL PHENYL ETHER 10 BQL BUTYL BENZYL PHTHALATE 10 BQL 2-CHLORONAPHTHALENE 10 BQL 4-CHLOROPHENYL PHENYL ETHER 10 BQL CHRYSENE 10 BQL DIBENZO (AH) ANTHRACENE 10 BQL 1~2 DICHLOROBENZENE 10 BQL 1,3-DICHLOROBENZENE 10 BQL 1i 4 DICHLOROBENZENE 10 BQL 3i3 DICHLOROBENZIDINE 20 BQL DIETHYL PHTHALATE 10 BQL DIMETHYL PHTHALATE 10 BQL DI-N-BUTYL PHTHALATE 10 BQL 2g 4 DINITROTOLUENE 10 BQL BQL = Below Quantitation Limit Comments: This list of corn ounds is re resentative of, but not totall inclusive of, the entire EPA list of corn ounds which can be detected b Method 625.

CERTIFIED BY: M~M. REPORT DATE: Jul 3, 1995

WEBB TECHNICAL GROUP~ INC ~

4325 Pleasant Valley Road, Suite 110 Raleigh, NC 27612 (919) 787-9171 EPA 625 BASE NEUTRAL EXTRACTABLES Continued...

CLIENT: CAROLINA POWER & LIGHT SHNPP SAMPLE ID: Combined Outfall 6/6 COLLECTED: 6/6/95'8:00 LOG NUMBER: 95-06-206-01D EPA METHOD: 625 QUANTITATION LIMIT RESULT COMPOUND ug/L ug/L 2,6-DINITROTOLUENE 10 BQL

. DI-N-OCTYLPHTHALATE 10 BQL FLUORANTHENE 10 BQL FLUORENE 10 BQL HEXACHLOROBENZENE 10 BQL HEXACHLOROBUTADIENE 10 BQL HEXACHLOROCYCLOPENTADIENE 10 BQL HEXACHLOROETHANE 10 BQL INDENO (1,2g 3-CD) PYRENE 10 BQL ISOPHORONE 10 BQL NAPHTHALENE 10 BQL NITROBENZENE 10 BQL N-NITROSO-DI-N-PROPYLAMINE 10 BQL N-NITROSODIPHENYLAMINE 10 BQL PHENANTHRENE 10 BQL PYRENE 10 BQL 1 f 2 ~ 4 TRICHLOROBENZENE 10 BQL N-NITROSODIMETHYLAMINE 10 BQL BQL = Below Quantitation Limit Comments: This list of corn ounds is re resentative of, but not totall inclusive of, the entire EPA list of corn ounds which can be detected b Method 6 5.

BY: 'ERTIFIED REPORT DATE: Jul 3, 1995

~ ~

ATTACHMENT6 HARRIS NUCLEAR PLANT POSSIBLE CHEMICALWASTE

HMENT 6 PAGE 1 of 3 HARRIS NUCLEAR PLANT POSSIBLE CHEMICALWASTE FROM HNP

':'-'"~

Estimated ~:"':;

':;Co'nc'ei'ifritioi'i;,z,

,:".'-'.', Discharge,'::;,",';"'.,:,

';-':Frequ'ency<".-,"',". ".:;""-.;":;:,Was't'e.'(pp'm)",;:",".:: ","

.';":::.!:::;::,'=:Ã".">'.'-:.Tre'atm'e'nt,'Sy'tem.';':',;.;".'.::";::,.i.,",":=,"h Alum Water Treatment Weekly <20 Settling Basin Ammonia Secondary System & Auxiliary Boilers Daily <50 Waste Neutralization System Ammonium Bisulfite Chlorine Removal Continuous <5 Cooling, Tower, Waste Neutralization System Anti-foaming Agents Sewage Treatment Plant, Waste Evaporator, Cooling As Required <10 Radwaste Processing System, Sewage Tower Treatment Plant, Cooling Tower Boron Secondary System & Waste Processing System Periodically 200 Radwaste Processing System (Reactor Coolant Waste) (Boron Recycle System)

Chlorides Demineralizer Regeneration Periodically <1,000 Waste Neutralization System Citric Acid Chemical Cleaning Periodically <5,000 Radwaste Processing System, Waste Neut?alization System Copper Filter Flushing, System Maintenance, Chemical Periodically <1.0 Waste Neutralization System Cleaning Detergent Waste and Dirt Waste Processing System (Industrial Cleaning) Periodically 1,000 Radwaste Processing System (Floor Drains and Equipment Drains)

Detergent and Waxes Janitorial Cleaning Daily 1,000-1,500 Sewage Treatment Plant Ethanolamine Secondary System Daily <50 Waste Neutralization System Carbohydrazide Secondary System Daily <50 Waste Neutralization System

~ Estimated concentration at point of treatment system discharge.

HMENT 6 PAGE2of3

.'..

,::.:::,;;:,.",,;;:Estiiii'ated ":

,:":;:,Coiicentration:'.;::,.".

!:;;, Dis'charge>:.';:...-  ;'-:"'.;.": Yreate'd.".;;:-.;:";-'.;

.~"::~:.:,.'-';,:! Ch'emical :;.-"',::;::;. "::::-":; ',,'-Fre'q'u'e'n'cy'::;::"-', :,.'-'..',ias'te'(ppm)::.::-.":

Hydrazine Secondary System & Auxiliary Boilers (Chemical Daily <0.06 Waste Neutralization Basin Additive) (5 ppm aAer wet layup)

Iron Filter Flushing, System Maintenance, Chemical Periodically <1.0 Waste Neutralization Basin Cleaning Nickel Filter Flushing, System Maintenance, Chemical Periodically <1.0 Waste Neutralization Basin Cleaning Oil and Grease Waste Processing Systems Daily <20 Radwaste Processing System Phosphates Cooling Tower Treatment, Potable Water, Industrial Daily <5 Cooling Tower, Sewage Treatment (Organic & Inorganic) & Janitorial Cleaning System Phosphoric Acid Chemical Cleaning Periodically <10,000 Radwaste or Waste Neutralization System Photographic Chemicals Microfilm Processing Lab Occasionally <5 Neutralization Basin Polyacrylic Acid Cooling Tower Treatment Daily <10 Cooling Tower Polyelectrolytes Water Treatment, Sewage Treatment Plant, Chemical Weekly <1,000 Settling Basin, Cooling Tower, Cleaning STP, Radwaste Periodically Sewage Treatment Plant Sodium Bromide Biodispersant Daily 0 - 0.5 Cooling Tower Sodium Carbonate or Chemical Cleaning Occasionally <5,000 Radwaste Processing or Waste Bicarbonate Neutralization Basin Sodium Hydroxide Demineralizer Regeneration, pH Adjustment (6-9) Periodically <1,000 Waste Neutralization System

~ Estimated concentration at point of treatment system discharge.

CHMENT 6 PAGE3 of3

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':"ooling Sodium Hypochlorite Biocide <0.2 Tower & Sewage Treatment Chemical Cleaning Periodically Systems Sewage Treatment Daily Sodium or Potassium Closed Cooling Water Corrosion Inhibiter, Possible Occasionally <500 Cooling Tower or Neutralization Molybdate Leakage Basin Sodium EDTA Chemical Cleaning Occasionally <10,000 Radwaste or Waste Neutralization System Sodium or Potassium Closed Cooling Water Corrosion Inhibiter, Possible Occasionally <500 Cooling Tower Basin or Nitrite Leakage Neutralization Basin Sulfates Demineralizer Periodically <1,000 Waste Neutralization System Sulfuric Acid Demineralizer Regeneration, pH Adjustment (6-9) Periodically <1,000 Waste Neutralization System Tolyltriazole Closed Cooling Water Corrosion Inhibiter Leakage Daily <20 Cooling Tower Basin or and Cooling Tower Treatment Neutralization Basin Total Organic Carbons Demineralizer Regeneration Periodically <2,000 Waste Neutralization System Zinc Cooling Tower Treatment Potable Water Daily <1.0 Cooling Tower & Sewage Treatment System

~ Estimated concentration at point of treatment system discharge.

ATTTACHMENT'7 HARRIS NUCLEAR PLANT STORMWATER SYSTEM SCHEMATIC DIAGRAM

I mergencyj"". "-... lconstfuctKNI I I I nrle( ce Wa ter 'Dr'ge; 58 <<PlDE', I I I

I Bldg. Receiving SW4 Warehouse SW-7 I I SW-1 I I I I I I SW-2 I Service I Water 1

I Pumps I I

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I Powers /

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I I I' I Water Treatment, I Service Building I 5 L I rrl I I I. I I Bulk Warehouse e p I 230 KV Che cal I Switchyard Ware use SW-9 SW4

~ t I I I Le end Attachment 7 Emergency Servce Watertc +~

I 'ntake Structure I Q Catch Basin Carolina Power 8 Light Company Intake Channel 2 S I I

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~ Man Hole I Harris Nuclear Ptant-Wake County, NC SW-5 To Harris Lake Emery ncy Service.

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Travel Intake Channel

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Drop Structure Ditches Outraa Stormwater System Schematic Diagram Page 1 of 3 September 1995

Attachment 7 Page 2 of 3 HNP STORMWATER SYSTEM DESCRIPTION Stormwater Outfall No. Description SW-1 This outfall which discharges into the Singer of the lake north of the causeway receives input starting in the plant yard near the diesel fuel oil storage tanks. It receives water from warehouse roof drains, paved and gravel parking lots, and grassed areas before the outfall.

SW-2 This outfall which discharges into the finger of the lake north, of the causeway receives input starting in the plant yard under the plant output transmission lines. It receives input from gravel parking lots and the normal service water pump structure area before the outfall.

SW-3 This outfall which discharges into the finger of the lake north of the causeway receives input from the first few SW-2 inputs as the two are cross tied, the circulating pump intake structure area and paved parking lots before the outfall.

SW-4 This outfall which discharges into the main intake canal at the emergency service water intake structure receives input starting near the turbine building and transformer area. It receives input from plant yard areas both paved and gravel and paved parking lots before the outfall.

SW-S This outfall discharges into a retention pond with an inverted siphon discharge which travels along an open ditch, crosses a road and travels along a gully before reaching the main lake. It starts at the northwest area of the plant yard and receives input from plant roof drains Units 3 & 4 pit areas, water treatment building, auxiliary boiler area, gas yard, neutralization and settling basin areas, water treatment tank area, both gravel, paved and grass plant yard areas, warehouse roof and drain area drains, and vehicle shop area drains before the outfall.

SW-6 This outfall discharges into the emergency service water intake channel from the auxiliary reservoir. It receives input from the gas yard, auxiliary boiler fuel oil storage area, settling basin area, and gravel plant yard before entering a ditch that travels to the outfall.

SW-7&8 These outfalls discharge into the emergency service water discharge channel to the auxiliary reservoir. Both outfall receive input from plant yard areas that are grassy.

Attachment 7 Page 3 of 3 Stormwater Outfall No. Description SW-9 This outfall discharges into the main lake. It receives input from the electrical distribution switchyard and the main road along the switchyard. It travels through some open ditches and along a gully before the outfall. This outfall is not subject to the Phase 1 stormwater regulations because it is associated with the distribution of electricity not the generation of electricity.

ATTACHMENT8 STORMWATER GROUP APPLICATION CORRESPONDENCE

C~L Carolina Power 8 t.tght Company MAR I 4 I99l Director, Office of Water Enforcement and Permits Environmental Protection Agency 401 M. Street, S.W.

Washington, DC 20460 RE: Group Application for Stormwater Discharges

Dear Sir or" Madam:

This letter and enclosures are intended to serve as Part 1 of a group application for a NPDES permit to discharge stormwater associated with industrial activity as specified in 40 CFR 122. Specifically, the industrial facilities addressed herein are six (6) steam electric generating plants owned and operated by Carolina Power & Light Company (CP&L) in North Carolina and South Carolina.

Enclosed is the information required in 40 CFR 122.26(c)(2)(i) for Part 1 of the group application. This includes a list of the participating facilities, a narrative description of their industrial activities and similarities, a list of materials and management practices to minimize stormwater contamination, and an explanation of why the specific facilities chosen to provide quantitative data for Part 2 are representative of the group as a whole.

Also enclosed is a copy of a letter from Mr. James Davis, Senior Vice President, delegating authority to sign NPDES applications to the Manager of the Environmental Services Section, the position that I currently hold.

It is CP&L's understanding that EPA intends to inform the Company within 60 days of the acceptability of these facilities for a group application. If you require any further information, please contact Mr. Cam Wheeler at (919) 546-6725.

Yours very truly, G. J. Oliver Ph.D.

Manager Environmental Services CCW:dcs (91-07.CCW)

Enclosures cc: Mr. George Everett, N.C. Division of Environmental Management Mr. Russ Sherer, S.C. Department of Health and Environmental Control 411 Fayettevitte street ~ p, 0 Sox t55t ~ Rateign, N, c. 2r602

CAROLINA POWER & LIGHT COMPANY GROUP APPLICATION FOR STORM WATER DISCHARGE - PART 1 MARCH 1991 I. Partici atin Facilities Rainfall Zone 2 Electric Plant, Person County, North Carolina Roxboro Steam Lat. 36'9'ong. 79'4'ayo Electric Plant, Person County, North Carolina Steam Lat. 36'2'ong. 78'4'ape Electric Plant, North Carolina Lat. 35'4'ong.

Fear Steam Chatham County, 79'3'arris Nuclear Power Plant, County, North Carolina Lat. 35'4'ong. Wake 78'8'ainfall Zone 3 Brunswick Steam Electric Plant, Brunswick County, North Carolina Lat. 33'7'ong.

78'1'obinson Electric Plant, Darlington County, South Carolina Lat. 34'4'ong.

Steam 80'9'I.

Descri tion of Facilities All of the referenced facilities were built for and are operated by Carolina Power & Light Company (CP&L) for the purpose of generating electricity by using steam to power turbine generators. They are sufficiently similar to have their waste water discharges be covered by a single NPDES Effluent Guideline (40 CFR 423, Electric Power Generating

Facilities). With the exception of the method used to generate steam, the equipment and processes used at each facility is essentially the same.

Heat for steam is generated either by nuclear reactor or by pulverized-coal fired boilers. All are medium to large power plants with similar land use and material handling practices, and storm water management programs. Additional similarities are discussed in the following sections. At every plant except Brunswick, the turbine building, which includes the condenser, turbine-generator, and much of the water treatment equipment, is the "open" design, which means that there is no roof or walls surrounding most of the equipment. For the coal-fired plants, this is also true of the boilers and fuel handling portions of the plants. For the nuclear plants, the reactor building and other nuclear-related buildings are, of course, completely enclosed. At all of CP&L's facilities, but especially at the nuclear power plants, good housekeeping i.s a high priority.

III. Materials and Mana ement Practices Significant materials that may be stored exposed to precipitation:

A. Stored open and directly exposed:

Coal-fueled lants onl All Coal Machinery Coal ash Piping Valves Scrap metal Structural steel B. Stored in open areas, but contained in closed steel or plastic containers:

Hydrazine Sodium Hydroxide Citric Acid Grease Chlorine gas Sodium bicarbonate Lubricating Oil Herbicides Detergents Sulfuric Acid Sodium nitrate Sodium molybdate Sodium Chloride Phosphates Ethylene Glycol

C. Stored in open areas in stationary tanks, usually with secondary containment:

Fuel oil Sulfuric Acid Lubricating Oil Sodium Hydroxide Boric Acid (nuclear only) Aluminum Sulfate Ammonium Hydroxide The material management practices at all CP&L facilities routinely include best management practices to minimize contamination of land or water. With the exception of coal and ash, all material potentially harmful to stormwater and stored outside is kept enclosed or contained to prevent any but accidental contact with precipitation.

Materials stored in bulk are usually in tanks with secondary containment and with valve controlled drains so that stormwater can be routed to treatment facilities if necessary.

Coal at coal-fired plants is kept in a coal pile and runoff from the pile and related areas is subject to NPDES Effluent Guidelines (40 CFR 423). The typical practice is to route all coal pile runoff to a retention pond for equalization and sedimentation. Coal pile runoff is the only storm water discharge from these facilities that is specifically addressed in the Effluent Guidelines for the Steam Electric Power Generating Point Source Category.

Coal ash is typically stored in a sedimentation pond, where the runoff from any exposed ash is drained to the active pond and treated along with the ash transport water. At the one facility (Roxboro Plant) that stores ash by landfill, that component of the facility storm water will be permitted separately as a landfill with an individual application to N.C. Division of Environmental Management, and is not included in this application.

Most significant materials stored exposed to stormwater are stored in their original containers in a fenced and paved or graveled storage yard. These areas

are not easily accessible by vandals or other unauthorized persons and are inspected regularly to minimize the chances of a significant undetected spill or leak.

Various brands of commercial herbicides might be used to control weeds and other unwanted plant growth on active industrial areas of the plant, storage areas, and the plant perimeter for security reasons. Ef so, they are carefully applied by licensed applicators in accordance with manufacturers instructions.

Fertilizers are applied only minimally on any of the active industrial areas of these facilities.

IV. Partici ants to Provide uantitative Data

SUMMARY

QF PLANTS IN GROUP Stormwater4'reated MoItnlaSstem Part 2 Sze ~ Untreated Once Cooling Data Plant ~MWe Fuel ~ee ~Throe h Tower Roxbo ra 2477 Coal 30 70 X X X Mayo 705 Coal 40 60 X X Cape Fear 320 Coal 90 10 X X 24 OI~

Harris 860 Nuclear 10 Brunswick 1580 Nuclear 75 X Robinson 174 Coal 50 665 Nuclear a) Percentages of stormwater treated or untreated prior to discharge are estimated.

b) At virtually all of these plants, stormwater that is treated is also combined with other waste streams such as ash transport water and/or low volume wastes and are treated In a retention/sedimentatlon basin.

c) At the Cape Fear Plant, some steam for electrical generation Is produced by heat recovery boilers using exhaust from oil-fueled internal combustion turbines. This system ls usually operated for only tO15 hours per year.

The above plants that are identified to provide quantitative data for Part 2 of the group application (Mayo, Cape Fear, and Robinson) represent the entire range of stormwater treatment methods of the total group. The storm drains for these facilities drain areas that are very similar to others in the group in respect to industrial activity and material handling practices. The types of other waste streams combined with stormwater prior to discharge are also representative of the group as a whole.

The Mayo Plant was chosen for quantitative data because it represents the plants

where most of the stormwater from the power block (boiler, turbine generator) is discharged directly without treatment, as it also is at the Roxboro and Harris Plants.

Quantitative data from the Cape Fear Plant will provide representative indication of facilities where most stormwater discharges are treated by a retention or sedimentation pond such as at portions of the Roxboro and Brunswick Plants. Mayo and Cape Fear also represent the two-thirds of the group that are in Rainfall Zone 2.

The Robinson Plant will represent the one-third of the group that is in Rainfall Zone 3 and provide the quantitative data for South Carolina. In addition, it represents the nuclear power facilities and those that have untreated stormwater from material storage areas and other industrial activities other than the power block.

(91-06.CCW)

Choline Power 4 Ught ComOaoY P. 0. Box i 551 ~ Raleigh, N. C. 2TSQ2 IIIIR 28 1987 JAMES M DAVIS, JR Senior Vice Presidenl Fossil Generahon 6 Serial No.: ESS-87-272 Power Transmission Mr. R. Paul Milms, Director N. C. Division of Environmental Management P. O. Box 27687 Raleigh, N. C. 27611-?687 RE: NPDES PERMIT APPLICATIONS DELEGATION OF SIGNATURE AUTHORITY

Dear Mr. Mi lms:

As allowed by the North Carolina Mater Pollution Control Regulations, Section .0106, "Filing Aoplications", I hereby designate the Manager of the Environmental Services Section (ESS) as my duly authorized representative for the purpose of signing Carolina Power Im Light Company's (CPEL) NPDES permit applications. The ESS Manager coordinates CP8L's non-radiological environmental programs and directs requlatory, compliance, and monitorinq activities.

Currently, Mr. G. H. Macr incr occupies this position.

This action is in concurrence with a telephone conversation with Mr. Arthur Mouberry of the Permitting & Engineering Unit in which Mr. Mouberry indicated that CPSL could assign this responsibility to the ESS manager.

Should you have any questions oT need additional information, please contact Mr. Marriner at (919) 362-3235.

Yours very truly, O"imlinak SI~~rl Ly JAhKM M. DAVTS, JP~

J. M. Davis, Jr.

Carolina Power dk Light Company Technical Services Department 411 Fayetteville Street Mall - P.O. Box 1551 - 4C3 CPB Raleigh, North Carolina 27602 AUG I 4 I99I Director, Office of Wastewater Enforcement and Compliance U.S. Environmental Protection Agency 401 M Street, S.W.

Washington, DC 20460 ATTENTION: William F. Swietlik (EN-336)

RE: Storm Water Group Application No. 286 Additional Information for Part One

Dear Mr. Swietlik:

As requested in Mr. Ephraim King's letter of June 29, 1991, Carolina Power & Light Company (CP&L) has compiled the additional information EPA requested to evaluate part one of our group application and that information is enclosed.

If ~

you have any questions or require additional information, please contact Mr. Cam Wheeler at (919) 546-6725 in our General Office.

~ ~

Yours very truly, G. J. Oliver, Ph.D.

Manager Environmental Services CCW:dcs (91-14.CCW)

Enclosures

CAROLINA POWER S LIGHT COMPANY STORM WATER DISCHARGE GROUP APPLICATION SUPPLZMENTAL INFORMATIONFOR PART ONE This information was prepared at the request of EPA in a letter to G. J. Oliver dated June 29, 1991, and is intended to supplement information provided in CP&L's original Part One application dated March 14, 1991. This information covered herein addresses only those items specifically requested by EPA on June 29.

Exhibit 1 is a list of group participants that gives the mailing and location address for each participant.

Exhibit 2 is a matrix of significant materials stored outside by each participant. In comparison to CP&L's submittal of March 14, 1991, sodium nitrate and boric acid are no longer identified, as they are now stored inside. Morphaline and PCS's have been added.

Exhibit 3 is a matrix of material and storm water management practices employed by each participant.

Exhibit 4 is an additional explanation of why facilities conducting sampling are representative of the group, specifically in terms of significant materials and management practices.

EXHIBIT I GROUP APPLICATION PARTICIPANTS Roxboro Steam Electric Plant Harris Nuclear Power Plant Person County Road 1377 Wake County Road 1134 P.O. Box 1238 P.O. Box 165 Roxboro, NC 27573 New Hill, NC 27562 Mayo Steam Electric Plant Brunswick Steam Electric Plant Route 5, Highway 501 North N.C. Highway 87 P.O. Drawer C P.O. Box 10429 Roxboro, NC 27573 Southport, NC 28461 Cape Fear Steam Electric Plant Robinson Steam Electric Plant Chatham County, Road 1916 S.C. Highways 151 and 23 P.O. Box 229 P.O. Box 790 Moncure, NC 27559 Hartsville, SC 29550 (91-14.CCW)

EXHIBIT2 SIGNIFICANT MATERIALSSTORED OUTSIDE F ili A B C D E F G H I J K L N 0 P Q R S T U V W g p'xbprp x x x x x x X X X X X X X X X X X Mayo X X X X X X X X X X X Cape Fear x x x x x x x X X X X X X X Harris X X X X X X X X X X X BrunSwick X X X X X X X gpbjIIspg x x x x x x x x x X X X X X X X X A = Coal I = Sodium Hydroxide Q = Sodium Molybdate B = Coal Ash J = Chlorine Gas R = Ethylene Glycol C = Machinery K = Herbicides S = Fuel Oil D = Hydrazine L = Morphaline T = Sodium Hypochlorite E = Grease M = Phosphates U = Aluminum Sulfate F = Lubricating Oil N = Citric Acid V = Ammonium Hydroxide G = Sulfuric Acid 0 = Sodium Bicarbonate W = Polychlorinated Biphenols H = Sodium Chloride P = Detergents (91-14.CCW)

EXHIBIT3 tri)/ ormw rMn mn

~F~ili y A B C D E F G Roxboro X X X X X X Mayo X X X X X X X Cape Fear X X X X X X X Harris X X X X X X Brunswick X X X X X X X Robinson X X X X X X X A = covered storage B = housekeeping of storage areas sealed containers D = secondary containment E = retention/sedimentation basins F = catch basins G = access control

EXHIBIT4 SUBMISSION REQUIREMENTS SIGNIFICANT MATERIALPROPORTIONS Number of Number of Partici ants Sam les Coal 67 100 Coal Ash 67 100 Machine 100 H drazine 67 67 Grease 100 Lubricatin Oil 100 Sulfuric Acid 67 100 Sodium Chloride 67 33 Sodium H droxide 33 33 Chlorine Gas 67 67 Herbicides 67 67 Phos hates 17 Citric Acid 67 100 Sodium Bicarbonate 33 33 Deter ents 100 Sodium Molb date 33 33 Ethe lene Gl col 67 100 Fuel Oil 100 Sodium H ochlorite 17 33 Aluminum Sulfate 50 Ammonium H droxide 50 67 Mo haline 17 33 PCBs 17 33

0 Exhibit 4 (Continued)

Since all facilities in this group are in the same Standard Industrial Category (SIC 4299), and part of the same company, they are very similar in terms of signiQcant materials and storm water management practices. The primary difference in signiQcant materials would be due to the type of fuel used, with coal-Gred plants having the most material stored outside and exposed to storm water. With the exception of retention basins, all facilities in the group have common types of storage and management practices as demonstrated in Exhibit 3. All of the sampling facilities have some outfalls that are treated by retention basins and some that are not. Outfalls that are treated by retention basins and those that are untreated are both represented in the sampling group in approximately the same proportion as the group as a whole. All three of the facilities in the sampling group have coal-Gred generation. The Robinson Plant has both coal and nuclear fueled generation and represents the nuclear facilities. There are no signiQcant materials or management practices that are unique to the nuclear plants as a group. The Cape Fear Plant is the only facility that stores PCB's or morphaline and it is included in the sampling group.

The only facility that stores aluminum sulfate (alum) outside is the Roxboro Plant, which is not an identiQed sampler. The only facility that stores phosphates outside is the Harris Plant, which is not an identiGed sampler. The reasons for this are:

1) Most of the Roxboro Plant's yard drain outfalls (including the ones that drain the area around the alum tank) as well as the inverts of the most downstream manholes, are submerged at all times. This makes accurate sampling and flow measurements extremely difQcult.

2) The Harris Plant has a relatively large number of smaller outfalls that would cause the cost of sampling to greatly exceed that done at other f'acilities. In addition, because the Harris Plant is CP&L's newest facility and a nuclear plant, it is not as likely to have signiQcant quantities of pollutants in its storm water runoff.

3) These materials at both facilities are stored in bulk tanks and deliveries are made by tanker truck; the material is always handled and stored in a closed system. Even though the tank and delivery system are outside, and therefore listed here, the material itself is not directly exposed to storm water.

4) Because of the active nature of the facilities and frequent observations by operations personnel, it is extremely unlikely that any leak or spill of these materials would go undetected or unrepaired. Additionally, it would be even less likely that any such material would Gnd its way to a yard drain during the limited monitoring period of this permit

~

application process.

Because of the sampling difQculty referenced above, the very remote chances of storm water contamination by the single unique material, and the more appropriate choice of sampling at other, more representative facilities, these two facilities (Roxboro and Harris) are not included in the sampling group.

4 Carolina Power R Light Company Technical Services Department 411 Fayetteville Street Mall, CPB 3A2 P.O. Box 1551 Raleigg North Carolina 27602 S P Director, Office of Wastewater Enforcement and Compliance U,S. EPA 401 M Street, S.W.

Washington, DC 20460 ATIN: William F. Swietlik (EN-336)

RE: Storm Water Group Application No. 286 Submittal of Part 2

Dear Mr. Swietlik:

Enclosed is Part 2 of Carolina Power & Light Company's group application for storm water discharge. Included are copies of EPA Forms 1, 2C, and the required portions of 2F for the three facilities that were selected to provide samples for the group of six. The sampling facilities included are:

Sampler ¹1 Mayo Steam Electric Plant Sampler ¹2 Cape Fear Steam Electric Plant Sampler ¹3 Robinson Steam Electric Plant In addition, there is a map of each sampling facility and narrative descriptions of the storm water outfalls, as well as a categorization of outfaHs from these facilities with a discussion of the need for monitoring requirements for each category that may be of use to EPA in preparing a model permit.

William F. Swietlik If you have any questions regarding this application, please contact Mr. Cam Wheeler at (919) 546-6725.

Very truly yours, George J. Oliver, Ph.D.

Manager Environmental Services ABH/

Enclosures cc: Mr. Russ Sherer, SC Department of Health and Environmental Control Ms. Coleen Sullins, NC Division of Environmental Management

CAROLINA POWER 8c LIGHT COMPANY Storm Water Group Application No. 286 PROPOSED MODEL PERMIT REQUIREMENTS OUTFALL CATEGORIES Storm water outfalls from CP&L's steam electric generating plants can be grouped into four distinct categories, as summarized below:

Category I: Runoff Combined with Coolin Water Flow In this case, runoff from power plant site areas of industrial activity is combined with once-through cooling water prior to reaching an outfall to waters of the United States. In such instances, the cooling water flow (typically ranging from 280 to 2000 cubic feet per second) is water essentially unaltered from the receiving stream, except for the addition of heat, and would mask any measurable pollutants that may be added by runoff.

Category II: Runoff Combined with Plant Low Volume Wastes or Ash Trans ort Water and Treated b Retention Ponds Several plant drains collect storm water from selected areas of the site, usually under or immediately surrounding industrial equipment or activities. This storm water is then conveyed, either by gravity or forced main, to a retention/sedimentation facility designed to treat miscellaneous process wastewater from the plant. These "design wastes" usually contain higher levels of any pollutants prior to treatment than the storm water alone, and the range of expected pollutants can be expected to be very similar to any in the storm water; therefore, the treatment facility can be expected to also provide pollutant removal treatment of storm water. The treatment facilities are usually basins such as ash ponds that have several days or months of retention time, even at anticipated maximum flow rates.

Category III: Direct Runoff from Ma'or Industrial Activi Areas Some outfalls drain the main plant yards near major process facilities and, aside from catch basins or swales, receive no other signiGcant treatment prior to discharge to surface waters. Good housekeeping and BMPs are the primary storm water pollution controls.

Cl Catego~ IV: Runoff from Areas of Minimal Industrial Activi Some runoff is produced from areas of a steam electric generating plant site that can be technically considered areas of industrial activity, but represent little or no threat to water quality from storm water runoff because of small surface area, low runoff coefficient, and/or little or no direct exposure of significant material to rainfall (mostly roofs or infrequently used pavement).

The following table identifies the sampled outfalls in the referenced categories:

Plant Outfall No. ~Cate thoro Mayo (sampler 1) II IV III III IV Cape Fear (sampler 2) I (includes II and IV components)

II IV II Robinson (sampler 3) II (includes III and IV components)

The unsampled facilities in this group contain the following categories of outfalls:

Plant ~Cate oriea Harris III and IV Roxboro I, III, and IV Brunswick I (includes II components) and IV PROPOSED SAMPLING RE UIREMENTS CP&L suggests that a storm water pollution prevention plan similar to that specified in EPA's general permit might be the primary component of a model storm water discharge permit, and that any regular sampling of storm water discharges is not necessary. Because

of signi6cant dilution or mixing/retention, sampling of outfalls in Category I and II would not detect any measurable pollutants from storm water runoff, even if they existed.

CertiQcation of an outfall as Category IV by the permittee or by a suitable professional, subject to possible veri6cation by a local or state regulator by site visit, should make any sampling of these outfalls unnecessary because of negligible threat to water quality.

Category III outfalls have the greatest potential for storm water contamination, but normally practiced BMPs, good housekeeping procedures, and other components of a pollution prevention plan should provide acceptable protection for the receiving water body. Nuclear plant sites in particular are exceptionally careful with housekeeping and material handling practices.

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fl efielef Whkh WIN Seats in e dkchelpe tO s X F. Qo you or WIN you infect et this tscility dustriel or E. Doss or will this Iscilitv tress. stole, or dispose ol nenlicipel efnuent bHow the IowerneNt strstum con.

hscsrdous wss't IFORM 3) tshlfnL within one stuertsr mile of ths well bors, undenpoend <<Nsrom of drinldnl wstert (FORM 4) 0 vou ai wi yourn~ s tt. Qo you or wHI you Iniect a thk fscEIty tiuids for nle-wslsr or other iluids which sre broueht to she swfals in connection with oonvsntionet oil ce.nstusei aes pro. .,

ckl plo~

Srocessos assis os miling of ssdfur by the Flsscn solution 15lninp of miner!as in shss duction inject ftuidslsssdAor en!!need sscosecy'ef

.tlosb ef fossa feet or seoosesy of Eeothernlei snerfyt combus',

oil or nsturst csL, oc. Iniscrthslde for,scersaeecthsdd ."'FORM 45 h t IFORM et

~ s is ny s one ot the 28 industnsi nels!ense Iiscsd In the in-ty e ~wn NOT one ot the 2$ induarisl cetsporles listed In ths is structions snd which wiN pocsmkdy emit t00 tons 'nstrucdosa end svhbh wia potemhlly emn 250 tons psr yssr of sny eir poihlcsnL repel!ted under the ~, per Veer of eny eir po¹ucsnt seuietsd under ths Clssn clsen Air Act snd'mev elfecc or be faceted'Inws ~ ~

. Alice end mey effect or be loonsd In en ectshunsnc

".-'leet IFORM at

~ lssinmolrl sleet IFOItMttt 5 ~

IIL NAME OF FACII.ITY

~ ~ s ~ ~ ~ ~ ~ i s"'r!

~ s ~ s ~ ~ ~ s s ELECT s

5 C A P E F E A R S T E A II IV>> FACILITYCONTACT As NANe O TSTLS Il&LIfltLe nrlti e rnoNC (sltetodr e no.I C

2 G. J 0 V 91 5fs6 1 9 V. FACILITYMAILINOADDRESS As STNCCT On r.O eoX P ~ O. BOX 155 1 es ClTT Oll TOWN c $ TAT o. sir conc 4 RALEIGH NC 2 7 6 0 2 Vl. FAClt.lTY LOCATION A. STNSSTs lfOUTC NO. ON 0&en SreolrlC lOCN'rll'leis BOX 229 CHATHAM C TY ROAD 1925 e, COONTT NAMC

~ ~ s s C HATHAM C. ClTT On Towli o,sTATCI C. zlr coos I ' s n NC 2755(

EPA Farm 3510-1 I8.90) CONTINUE ON REVERSE

CONTlNUEO FSIOM THE FRONT Vll. SIC COOKS M Chrft, In Otaer o(pnontrt A F INST e. Secoho (SPtn(> I (sprrffp>

ELECTRIC POWER SERVICES O U TH (SPtn(P( (SPtrI(>V

~ ~%

Vill.OPERATOR INFORMATIOSS A, NAMC I e the nefne Iletea Iff l lofti Vill A oleo CAROLINA POWER 6 LIGHT COMPANY ownetr 8 EYEs ee

+No

c. $ TATU$ oF oreNAToN (Enter tnt epptoptlto lrttrr Iffto tnkenswtk eon If 'ttfkr, sptrtf>'.> 0 FHotf o tefco rock o nat (otnkr tnen feaktet or salk( (SPtnf!'(

S %STATE 0 o OTHER (spkrtfr> p a 1 546 4 8 P  % pRIVATE ~ ~ f~ I~ f> ~

eo STNecT oN F,o ooN.

P. O. BOX 1 5 F. CITT ON TOWtt ILaTA lt. NSF cooc OL tNOtAat LANG le the Ieciiity locslea on I nafen Ienasr RALEIGH NC 27602 I

~ss YES ZR NCI I~ I~ ~ I %%% kk ~

X, EXISTINQ ENVIRONMKNTAI PKRSSSTB A Ifrace (D(sraerrte sneer(eke Setert AIR EMISSION SOURCE 9 N NC0003433 1057R OPERATION

~. U la (unartrtoona lnjtrtlon of pre(asl e, oTHCN (tpkrffr)

(spertfp'I 9 U c, N c N A (Hesen(one Westess c oTIfsN'(spectfp(

9 R 9" I

~ ~ ~ ~ ~ fe ~% f ~ ~

XL MAP Atvch to this application a topoyaphio map of theaeamsndingarecfaestonerniiebeyond property bounderfeL The map muse shoat the outline of the facilitIf, the locedon of. each;of ice exiscfny end proposed intake ancf dleck>arge stttetures, each of its hatardous waste t(eattnenr, storage, or dispossi facBltfee;atef oech sseS~ ic hjechffktkfa.unciasyacrat.'nclude aii springs; rlYera and other surface wavr bodies in the map area. See instructialsfor XII. NATURE OF BUSINESS (pttrnt(eo oner ELECTRIC UTILITY Xlll.CERTIFICATION (ske(nsttvet(one(

I cenify under penalty of Iaw chat I I>ape personeffyaxanfnedand ae farruIIersrAA'the fnforrnatio(r auhnrlrtad In this application and all

~ rtachmpnrs and that, I>asad on my inocaky.og chose peracrm for obtaining che informer(on contained In the application, I balieee that the lnfotmeoion Is trrsr, actxeete and clat~ca I anr aewe chat there ete N'gnff cant penalties for submitting feist>info(marion, inc(ud(ng the pt>rs(Nlity of fine and Inrprfso(anent.

A. IIAMC A GFI'ICIAI CITLC(tppr or pnnt( ~e eIGII ACUNC 4, OACC SIGIfeo GEORGE J. OLIVER HANAGER - ENVIRONMENTAL SERVICES w/~g/ex.

COMMENTS FOR OFFICIAL USK ONLY C

C EPA Form SStc.t (8 90)

vN I HAM RIVER ",:;.", jCIF I

~I I tel AuLsi Ii 5 ce' i'E0 +>1.5

,I CAPE FFAR S. E. PLANT . .

COOLI;IG OISCHARGE ( }

']

' "'.'O//I I / '/i WEST (OLD) ASH PONO DISCHARGE ( ) ) (+'.. i EAST (NEM) ASH POND F

WEST (OLD) ASH POND EAST (IIEN) ASH

)/ j'

~ PS Wl I, We/r

/~Jri,Outfall 001 POND DISCHARGE (

M, ~

> 'i~

'" Shfi I

~

/i

/

'i<'r COOLING MATER DISCHARGE CANAL 5 -TP (to Cape Fear RIver) i ~ ~

//r /

~

~ /p g,4 UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY 0

IOC0 0 1000 2000 XNO iO00 SC00 SX0 '000 FEET I NILOMETER CONTOUR INTERVAl. LO FEET MONCURE QUADRANGLE NORTH CAROLlHA 7.5 MINUTE SERIES (TOPOGRAPHIC)

LOCATION MAP CAPE FEAR S. E. PLANT CAROLINA POWER 8t LIGHT CO.

CHATHAM COUNTY, N.C.

4% FORM,....

'ease onnt or tvoe in Ine unshaded I F~lJR '

areas onlv MFA I U, NUMBCR (COP/

from Item I of Eorm U.s. KNYIRDNMcNTALFRDTccTIDN AGKNcv APPLICATION FOR PERMITTO tf

~ t I ~ gpjlI I IF NIP 0

aafa tyo. 2O4O~8 Apprcvsferpites 74IN8

'..I.

~

DLSCHARGEfyASTEWATER'XISTING 2 MANUFACTURING,COMMERCIAL.MININGAND SILVICULTURALOFERATIONS NPDES ., Consoif'dated PermirK Program I. OUTFALL LOCATION For each outfall, list the latitude end longitude of its location to the neatest 15 seconds and the name of the ecsiving water.

L B. I ATITUDC C, LONGITUDC UMBCR D. RKCKIYINGwATER (nemcf IIISTI I~ 444 L MIN ). SRC I~ Oaa I L MIN, I ) ~ SNC 001 35 35 6 79 I 02 (

30 I CAPE FEAR RIVER TRIBUTARY (UNNAtjED)

II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGiES A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the mora detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operadons, treatment units, and outfalls. If a water balance cannot'be determined (afs, for certain mining actfvfffesJ, provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measutas. -.

B. For eacn outfaii, provide a description of: il) All operations contributing wastewater to the effluent, incfucQng process wastewater, sanitaty wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and (2) The treatment received by the wastewater. Continue on additional sheets if necessary, I. OUT s, otcRATIot4lsl cot4YRIBUTING Fl ow S.TRCATMCNT FALL N S, AVCRAGC FLOW I IST CODCS FRO ftlrtl d, OFCRATION fttrtP" ftnclude unitrl s. DCSCRIFTION'" TASL,C SC I 001 Low volume wastes 0, 142,"jGD Oxidation, sedimentation "= 2B ,1U (see narrative) neutralization 2K Condenser cooling water 180 >IGD Evaporation Ash sluice water 0.56 HGD Oxidation, sedimentation 2B 1U Coal pile runoff .007 >jGD Sedimentation, neutralizati 1U 2K Sanitary waste ~ 002 )jGD Oxidation, sedimentation 2B 1U Yard drains varies Sedimentation 1U oFFIGIAL Usc otILY feffluent euIdenner ruo ccteeonert

'4n1rI '9t ~

ONTINlgED FROM THE FRONT

=..Except for worm runoff, leaks, or spills are any of the discharges described in Items II-A or B intermittent or the(a((oivinsrabtcJ i .~, .'. '" ".',: ~:=::.."..~No(go ra Sacr(an(i(J sessor=..'vss(complete

3. FREQUENCY

~ T

~~

8. PLOW RATS b TOTAI VOI UM6 I. OUTFALL 2. OPERATION($) rL DAYS b..MONTHS "..'(Iis mgd I (spec(fy w(rh units J DURC~

NQI48ER CONTR IBUTINtk'FLPW '- PSIPW66K< P6R TSAR (1(st (spec(fy (rpac(fy ~ LOUO YCOM 4 MAAIMUM i LOUO takM L MAAIMUM ~ATION-~

((is() average J average J AVCOAO~ DAILY 4 Y4 4 A4 4 ~ 4 A I LY (In daycJ III. PRODUCTION A. Does an effluent guideline limitation promulgated by EPA under Section 304 ot ths Clean Water Act apply to youc faciiityP Qg v6s (complete Itcnr IIIB I ~No (lo lo Sect(on IVJ rc B. Are the limitations in the applicable effluent guideline expressed in terms ot production (or odier measure of opersti on J ?

~

Qv6s (comp(cte(rcm-III.GJ--' ~

' -- ~ ~ ~ ~- QQNoggo Io Sacr(on IVJ --- ~ ~ -- - -- ~-

C. Ifyou answered "yes" to Item Ill.B,list the quantity which represents an actual measurement of your level of production. expressed in the termssndunits used in the applicable effluent guideline. and indicate the affected outfaiis.

1. AVERAGE DAILYPRODUCTION 2. APPSCTKD C Okkkktlaki kkOOUCYI MAYCAIAl 45C OUTPAI LS a, OUANYITY k ~ 4 OAY b, Vkltk OI MCAAVOC (list outfall numbcrcJ (spec(fy J IV. IMPROVEMENTS A. Are vou now reouired by any Federal, State or local authority to meet any implementauon schedule forthe construction, upgrading or operation of waste.

water treatment equipincnt or practices or any other environmental programs which Inay affect the discharges described in this applicatlonP This includes, but is not limited to, permit conditions, administrative. or enforcement orders, enforcement compliance schedule lowers, stipulations, court orders, and grant

~VSS lcomPlclc thc falloiv(ng labial a/No lgo Io Item IV.BJ 2, APFSCTSD OUTPALLS 4 FINALCOM Ie IDSN'flPICATION OP CONDITIONo AQR66M6NT, 6TC, SRISP OSSCRIPTION OP PROJECT

~ kc4 tl, aoUkcc ok oikckkkac 4 kc IL kkO OJikko JCCYCO

s. opTloNAL: You may attach additional sheatsdescnbing any additional water pollution control programs, (or orharenvironmenoi( projects Ivhicfsrney el'fear your dischergcsi you now have underway or which you plan. Indicate whether each program is now underway or planned, snd indicate your actual or planned Icneduies for construction. QMARIs ")t" IP D6scRIPTIDN op ADDITIDNALcoNTRDL PRocRAMs Is ATTAcHSD EPA Form 3510-2C IRev. 2-85) PAGE 2 OF 4 CONTINUE ON PAGE 3

Form rsooroverr, apA LO. NUMaKR(copy lrom item l ol Eorm ll Ohf8 lyo. 2040~86 rtpprovel esoires 7>>31 88 CONTINUED FROM PAGE 2 V INTAKEAND EFFLUENT CHARACTERISTICS

, B, & C: See instrucuons oefore proceeding complete one set of tables for each outfall Annotate the outfall number in the space prowded.

NOTE: Tables V A. V B, and V-C are included on seoarate sheets numbered V-I through V-9.

Use the soace below to list any of the pollutants listed in Table 2c.3 of the instructions. which you know or have reason to believe is discharged or may b<

dischargea from any outfail. For every pollutant you list, briefly descnbe the reasons you believe it to be present and reoort any analytical data in you:

ssion i, POLLUTANT  ! S. SOURCE I. POLLUTANT s. sounca Asbestos ,'sed in insulation; trace amounts IIIfIy be washed

'own i

drains in plant area

, during maintenance i activities.

Strontium 'race elements Uranium occasionally present in Vanadium coal or oil used to Zirconium start boilers.

I. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant hstedm Item v.c a substance or a component ot a substance which you currently use or manufacture as an intermediate or final product or byproducts Qg Yes llisr all such pollutants below) +NO (So lo Item VJ BI imony Arsenic Beryllium Cadmium Chromium Copper Lead Mercury Nickel Selenium Silver Thallium Zinc EPA Form 3510-2C IRev. 2 85) PAGE 3 OF 4 CONTINUE ON REVERSE

VII. BI()LOGICALTOXICITYTESTING DATA oi

- .. swuaor ahronia toxicity has assn mwie any your ditdwrgw eton a Oo you have eny knowledge or reason to natives terat any oioiogiaattasator o remivingwswrin reietionto yourdhthargnwtthhrmnhuxdyeawh.

GDYcs ((dent(fy<hc test(s) and describe theirpurposes bcloIe) ~

~ No (So to Sect(on VIII)

Chronic Pass/Fail:

(0% effluent - control and 99% effluent) and observed

.for 7 days to assess adult mortality and reproduction.

There can be no significant inhibition of reproduction or significant mortality in the 99% effluent compared to the control to pass the test.

Results: Nov. 1991 Pass Feb. 1992 Pass May 1992 Fail June 1992 Pass VIII.CONTRACTANALYSIS INFORMATION Were any of tho analyses reported in Item V performed by a contract laboratory or consulting firmP (t(st thc name, address. and telephone number of, and pollutants

't'gyss analyzed by. each such laboratory or firm betoIe)

+ No (So to Sect(on IX)

A. NAMS( O AOORESS A area code db no.i t(st Webb Technical Group, Inc. 4320 Delta Lake Drive  ! (919) 787-9171 Acid extracts, Raleigh, NC 27612 Base/neutral extractables, Volatile organics, Total cyanide, Dioxin, Phenolic Compounds, total Kjeldahl Nitrogen I X. CE RTI F I GATI 0 N Icertify under penalty of law that this document and all attachments were prepared under my direction or supervisionin accordance with a system designed to assure that quali%'ed personnel properly gather end evaluate theinformation submitted. Based on myinquiry of the person or persons who manage the system or those persons directly responsible forgatheringthainformation. (heinformationsubmnredis. to(behest ofmyknowledge andbelief. true, accurate. and complete.

I am aware that there are significant penalties for submitting false informarion, including the possibi%'ty of fine endimprisonment for knowing violations.

A. NAMc st oaaiciAI TITI s (type or prgygii car no i George J. Oliver Manager - Environmental Services Sectitn (919) 546-4189 O. OATS SIGNEO g/Zds/jg EPA Form 3510-2C IRev. 2.86) PAGE 4 OF 4

Sanitary waste treatment 0.560 MGD Pump Sta. East Air healer East side No. 2 ash pond wash ard drains transport s tern Coal pile runoff Pump Sta.

No. 6 Boiler make-u No. 2 oil tank runoff & service wate 0.143 MGD Settling basin drains WE 179.610 MGD Pump Sta. Plant intake No. 9 condenser structure Sandbed ritter ackwash wate M

Parking tot drains North side Make up m~l ~ '

Pe ear River ard drains G2 No. 1 oil tank runoff H West 0.560 MGD Discharge Cape Fear Pump Sta. F cooling No. 1 ash pond 0.142 MGD canal OUTFALL001 Waste oil storage Once-Through Once-Through with Closed-Cycle Cooling Cooling Towers Cooling Towers Oit unloading {M~GD {MGD) area drains Low volum A 180 0 0 Boor drains Pump Sta.

No. 5 retention B 0 9 9 basin C 0 9 9 South side ard drains D 180 0 0 Evaporation E 180 9 9 Demtneralizer r enerate (0.001 MGD) F 180 1 1 G1 0 171 Equip. cooling OVNf G2 171 Units5&e iter blowd Pump Sta.

No. 7 Ash trench Water Flow Diagram Cape Fear Steam Electric Plant Carolina Power L Ught Company VALVES: ~ Normally closed [OC] Normally open Chatham County, NC

CAPE FEAR STEAM ELECTRIC PLANT DESCRIPTION OF WASTE STREAMS The Cape Fear Steam Electric Plant is a coal-Gred electric generating plant with four units rated with a net dependable capacity of 28 MWe (Units 1 & 2 combined), 143 MWe (Unit 5), and 173 MWe (Unit 6). Units 3 & 4 are in cold standby status. Chemical constituents contained in these discharges will in part be representative of the naturally occurring chemical quality of the intake water as well as naturally occurring runoff from the ash pond drainage area and will also have chemical constituents of such quality and quantity associated with similar discharges for fossil generating facilities of this size, type, and in this geographical location. Either all or part of the elements enumerated in the Periodic Table, either singularly or in any combination, may from time to time be contained in this discharge. More detailed descriptions of the individual waste streams are below.

OUTFALL 001 - COMBINED DISCHARGF This outfall is located at a weir in the discharge canal approximately 250 feet below the point where the East Ash Pond Discharge becomes "waters of the state". This discharge contains all waste stream Qows including once-through cooling water, East Ash Pond discharge, and West Ash Pond discharge, which are summarized below.

ONCE-THROUGH COOLING WATER Condenser cooling water for Units 1, 2, 5, & 6 is withdrawn from the Cape Fear River, passed through the condenser, and discharged directly into the discharge canal.

Some cooling is accomplished in the discharge canal. When the temperature at Outfall 001 (weir at the end of the discharge canal) reaches 32 C, cooling towers are placed in service in once-through mode to keep the canal water at or below 32 C. If 32 C or less can not be maintained by once-through mode, operation is shifted to closed cycle cooling tower mode. The once-through flow may range from 58.8 MGD to 385.4 MGD.

EAST ASH POND The East Ash Pond receives ash transport waters (bottom ash and fly ash), runoff from yard drains, and sewage treatment plant efQuent. The ash pond provides treatment by sedimentation, oxidation, neutralization, equalization, and adsorption. The East Ash Pond Qow ranges from 0 to 1.0 MGD.

WEST ASH POND The West Ash Pond receives coal pile runoff; No. 2 fuel oil tank runoff; settling basin drains; sandbed ftlter backwash; parking lot drains; equipment cooling tower blowdown and drain; boiler blowdown; oil unloading area drains; demineralizer regenerate; various yard and floor drains; and ash trench drain. The ash pond provides treatment by sedimentation, oxidation, neutralization, equalization, and adsorption. The West Ash Pond Qow ranges from 0 to 1.0 MGD.

CAPE FEAR STEAM ELECTRIC PLANT CHEMICALS USED IN PROCESS STREAMS Chemical Used/Year ~Fre ueuc Pururose Aluminum sulfate 12,000 gal. Continuous Improve settleability in clarifier Soda ash 500 gal. As required Improve settleability in clarifer Sanuril 800 lb. Continuous Chlorination of treated domestic wastes Sodium hypochlorite 3,000 gal. As required Chlorination of circulating water system Sodium chloride 4,000 lb. As required Softener regenerate Sulfuric acid 9,000 gal. As required Demineralizer regenerate Sodium hydroxide 12,000 gal. As required Demineralizer regenerate iVIorpholine 400 gal. Continuous Condensate pH control Hydrazine 200 gal. Continuous Oxygen scavenger in boilers Trisodium phosphate 800 lb. Continuous Boiler pH & corrosion control Hydroquinone 100 gal. As required Oxygen scavenger Potassium hydroxide 500 gal. Continuous Corrosion control 1-Bromo-3-chloro- 1200 lb. Continuous Biofouling control 5,5-dimethylhydantoin

EFA l.o. NUM eER (COPy (rain Item I uf I'onn I J Iuvn At>t>IOTCII PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may tcl>ott some or al) of OMB Nu 2040 t>OSb this information on separate Sheets (use the same formaCJ instead ol completing these pages. AppruTac espiies 7-3C SS SEE INSTRUCTIONS.

OUT > ALL NO V. INTAKE AND EFFLUENT CHARACTERISTICS (conc(>>ued fron> page3 of Form 2 CJ 001 PART A You must provide the results of at least one analysis for every pollutant in this table. Cocnptete one table for each outfall. See instructions for additional details.

~

2 EFFLUENT

~ 3. UNITS 4. INTAKE l>pti.vu>IJ (tt>CI.(fy If blank)

I. POLI.UTANT a. MAXIMUMOA>LY VALUK MAXI PM 3) giAY VALUE C. ON M P, A UE (t NO. OF a. LONG Tt:RM b tto. OF Isl CONC EN ANALYSES a.TRATION b. MASS A ti A L Y S E S

{s) MA~ $ (sl NA$ $ C 0 H C E N T R A 'T I 0 H Is) j@A$ $ CONCLNTHATIOH III wA$$

a. Biochemical Oxygen Demand (BODJ <10 <1827 mg/1. lbs/day

b. Chemical Oxygen Demand (COD)' <20 <3653 mg/L lbs/day

c. Total Organic Carban fTOCI 6.4 1169 mg/L lbs/day

d. Total Suspended Solids (TSSJ 10 1827 mg/L lbs/day Ammonia

e. (Rs NJ 0.27 49.3 mg/L lbs/day VALUE VALUE VALUK VALUE I. Flow I 198.0 116.1 69.0 kfGD

g. Temp@acute VALUL VALUE VALUE VALIIL OC (ur(>ICar )

f '::

I 20 l2 VALUE VALUE VALUE VA> Ut.

h. Temperature (sutnnterJ t 24 23 'C M>N>MUM MAXIMUM MINIMUM MAXIMUM I.pH ", STANDARD UNITS 6.7 7.7 6.7 7.7 PART 8 Mack "X"in column 2-a for each pollutant you know or have reason to believe Is present. Mark "X-in column 2-b for each pollutant you believe to be absenL If you mark column 2a for any pollutant which is limitedeither directly. or indirectly but expressly, in an effluent limitations guideline,you must provide the resuhs of at least one analysis for that pollutant. For other pollutants for which you mark

t. POLI.UT-ANT AND CAS NO.

2. MARK

a. Rc. b. Rc Iava RC LICVC A~

'X'.EFFLUENT column 2a, youmust provide quantitative date or an explanation of their presence in your discharge. Cocnplete one table for each outfall. See the instructioris lor additional details andrequ>rements.

L MAXIMUMOAILY VALUE b, MAX> JfM 3$ gJAY VALUE C.LONG TPM g$ PP. VALUk IS NO, O a.cONCEtt-ANAL

4. UNITS

b. MASS

5. INTAKE (uptlniiaIJ

a. LON AVERAGE VALUE E

NO. OF ANAL (If auaicab(e I

~

saNT $ $ NT Ia) NA$ $ I III NA$ $ (s) IIAss YSES RATION I II) IAA$$ YSKS CONCCNTRATIOH CONCRNTRATION CONCCNTN ATION CONC CHTN*TIOH

a. Brom)de (24959 It7.9) <183 mg/L lbs/day

b. ChIttt(pe, Total f)es)dual 0 mg/L lbs/day

c. Colo( CPU NA 80 NA

d. Fe~t ColltocIT>

105 col/10

e. FluI>ri liil) lbs/day I I I)PB Pl 0.47 216 0.47 216 .14 62.25 mg/L

~ ~

f. Nitrate Nit>)ce (ai NJ <201 mg/L lbs/day EPA Form 365 0-2C fRev. 2-86) PAGE V I

ITEM V 8 CONTINUED FROM FRONT

1. POLl UT- S. MARK EFFI VENT 4. UNITS 5. INTAKE (optional)

ANT AND S.ILVCI OL- b. I>>c- MAXIMUMIsAIg Y VALUL b. MAXI M sit ItlfAY VALUE C. O /I M glgp. VAL C <I. NO.Or coNcEN-

'.6 CAS NO. IL'VLO A 4.lPA)A EVZLtlE ANAL a.TRATION d

~ HI AO II. MASS ANA~L (Itoooi Ia MoI SCH'I LLNT C O H C C N 'T H A T I O N I ~ I <<As@ CONC ~,NTHATIOH III <<Ass I C O N C L I>> T N A T I O N III <<Ass YSES I' N \' I>> T I I A T I 0 N III <<>>>>I v Ysns

g. Nitrogen, Total Organic 477 2.6 0.86 119.6 (ae NI 477 4 mg/L lbs

h. Oll snd Grease 548 mg/L lbs I. Phosphorus (as P), Total 0.3 0.3 0.

)7723.14-0) 231 231 15 71.5 mg/L lbs J. Radioactivity 'A Il) Alpha, <2.67E+0 Total, pCi/L NA I2) Bets, 496+1.75 Total 0 Ci L I3) Radium, Total. 0.28+0.49 Ci L I4) Radium 225, (otal TESTING AND RE ORTING N T REQUIR D Is. Sulfate fas SO4J 14808.79%) X 170 54218 165 30473 45.6 14435 16 m L lbs I. Sulllda 0.4 ~mL

'>>sl X 73 1 lbs nL Su Ite fas 503) ..

I1428~.3) X 2.1 384 1 mg/L lbs

n. Surtactants

<0. 1 <18 1 m/L lbs

o. Alum num, Total,-

p429.'90-5) X 2.8 2994 2.8 2994 0.94 566.8 8 mg/L lbs p, sr urn>>

Total<,n p445.39.3) X 20.0 36.5 1 u/L lbs

q. oron, . ~

Total f7440-42%) 0.06 1 mg/L lbs

r. Co Total ~

f7440-48.4) X <0.05 <9.1 1 mg/L lbs

s. Iron, Total f74394)9.5) X 2.4 1497 2.4 1497 0.94 431.4 8 mg/L lbs

t. Magnesium, Total (7439.95.4) 3.0 548 1 m/L lbs

u. Molybdenum, Total I7439.98.7) <0. 1 <18. 3 1 mg/L lbs Y snganese, Total I7439.95 5) X 0.12 21.9 :mg/L lbs

w. Tln, Total F7~0-3t.)I) X 0.6 109.6 1 mg/L lbs X. Titan}um, Total <50 91. 3 1 ug/L lbs EPA Form 3610-2C {Rev. 2-86) P V-2 TINUE ON PAGE V ~

KPA I.D. NUMBER (Coptr from fram 1

~ I 1) OUTFALL NUMBER form Appro>>

VMB No. 2040 0086 001 Apprutral e>>pires 7.31 -OI8 CONTINUED FROM PAGE 3 OF FORM 2 C PART C - If you are a primary industry and 1his outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALLtoxic metals, cyanides, and total phenols. If you are not required to mark column 2.a (secondary industries. nonprocess wasrevtreter ourfells. and nonrequired GCIMS fractions/. mark "X"in column 2-b for each pollutant you know or have reason to believe is present. Mark -x" in column 2.c for each pollutant you believe is absent. It you mask column 2a for any pollutant. you must provide the results of at least one analysis for that pollutant. Ifyou mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations ot 10 ppb or greeter. If you mark column 2b for acrolein, acrylonitrile, 2.4 dinitrophenol, or 2-methy).4, 6 dinitrophenol. you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pagesi tor each outfall. See instructions for additional details and requirements.

1 ~ POLLUTANT 2. MARK 3.EFFLUENT 4. UNITS 6. INTAKE fopriorIo)l AND GAS NUMSER ~ NO Ilc Is ~ tt 1%.vs ruu

'X'>>ass c ss E.Islets as a MAXIMUMDAILY IrALUK b. MAXI M QS gj Y VALUE C.LONG T M QP, VALUE (1 NO.OF s. CONCEN ANAL b. MASS

a. LONG TERM b. NO.OI ANAI (ll duct)able) 4 tt I s ~ c tt 1 ~ c It s fs) stsss lt) stsss (I) ~sss YSKS TRATION lt) cot>>catt it) >>>>Ass YSFS

>>I>>A>>ION METALS, CYANIDE, AND TOTAL PHENOLS 1M. Antimony, Total (744q 36 0) 0.05 mg/L lbs 2M. Arsenic, Total (7440.3tI-2) 0.05 2.14 0.05 1.25 0.008 0.79 16 mg/L lbs 3M. Beryllium, Tots)7, 40.41'1) <0.01 <1.83 mg/L lbs 4M. Cadmium, Tots) p440.43 9) 0.004 0.98 0.003 0.63 0.0007 0. 18 16 mg/L lbs 6M. Chrom)urn, Tots) (7/p-47.3) X 0.022 0 '22 1.0 0.004 0.20 16 mg/L lbs i)M. Cocoar, Tout (7440-604)):. r .

X 0.03 29.4 0.03 29.4 0.01 4.8 mg/L, lbs 7M. Loan Total P4>9-92.g:.i X 0.003 1.8 0.003 1.8 0.001 0.5 mg/L lbs BM. Marhury, Total (743/-97. )

0.0001 0.1 0.0001 0.1 0 O.l mg/L lbs BM. Nlcital, Total (74404$ '.0)'-" 0.04 42.8 0.04 42.8 0.007 6.1 mg/L lbs 10M. Salanlilm.

Total f P2t49.2) 0.05 1.07 0.05 0.99 0.007 0.34 16 mg/L lbs f

11M:Sllvar:Total (7440-22+ts:

~ t '..

<5 <913 mg/L lbs 1 2M:Thi ilium, Total (7440.28 0)

<0.01 <1.83 mg/L lbs 13M. Zinc. Total 0.02 9.9 0.02 (7440-66.6), 9.9 0.003 1.2 mg/L lbs 14M. Cyan)do, <0.005 <0.91 lbs Total (67.12.6) mg/L 16M. Phono(s, <0.05 <9.1 mg/L lbs ToRI(IR: Il..l t DIOXIN ~ I.-".. ~ ~ ~ ~ tl s I ~ t I t ~ t' 2,3,7,t).Tatra- DESCRIBE RESULTS crttotodlbanao.P- X Dioxin Screen Negative <0.5 ug/L.

Dioxin (176ILOI.6)

EPA Form 3510-2C (Rev. 2-85) PAGE U 3 rt ~ ~ ~ I~ ~~ ra rrtts

~

CONTINUt.O FROM THE FRONT 1.POLLUTANT Z. MARK 'X' 3.EFFLUENT 4. UNITS 5. INTAKE (upi(on>>If AND CAS M 3$ 'g(AY vALUE c.LoNG T /IM p$ pp. vALUE lt NO.OF LoNG TERM MAXIMUMDAILYvALUE b. MAxl a.

I~ ul I2 4421 C 42$ >>. CONCEN NUMBER ~ H ~ 2 44$ 2 LILVs2 a. ANAI I RATION I). MASS coHCHH A N A3 4'H ~ I~ I YSES fif auullotlr49 Hu 44422A SSHI A ~

SLHI ill 24ASS Il) 24 ASS I~ I I~ I 44ASS 'SES IH AIIOH (2) 24ASS GC/MS FRACTION VOLATILECOMPOUNDS 1V. Acrolein (107 02%) <100 <182.6 lbs 2V. Acrylonitrlie (107-13.1) <100 <182.6 lbs 3V. Benzene (71-43-2) <5 <9 lbs 4V. 8 la (Chloro.

methyl) Ether TESTING AND REPORTIN NOT REQUIRED l4424IS 2 I SV. Bromoform (76 25 2) <5 <9 lbs 6V. Carbon Tetrachloride <5 <9 lbs (56.23.6) 7V. Chlorobenzene (108.90-7) <5 <9 8V. Chlorodi ~

bromomethane (124.48.1) <5 <9 ug/1 lbs 9V. Chloroethane (75 00-3) <10 <18 ug/-1 lbs 10V. 2.Chloro.

~ thylvlnyt Ether (110.76%)

<10 <18 ug/1 lbs 11V. Chloroform (67.6S-3) <5 <9 ug/1 lbs 12V. Dlchloro.

bromomethane (76.27.4

<5 <9 ug/1 lbs 13V. Dlchloro-dllluoromethane (75.714)) .

<5 <9 ug/1 lbs 14V. 1,1 Dlchloro.

~ than>> (76-34.3) <5 <9 ug/1 lbs 15V. 1,2 Dlchloro.

ethane (107-06-2) <5 <9 ug/1 lbs 16V. 1,1-Dlchloro.

ethylene (75.35 4) <5 <9 ug/1 lbs 17V. 1,2 Dlchloro.

propan>> (78 87-5) <5 <9 ug/1 lbs I BV. (.3 Oichioro.

propylene (542.75-5) <5 <9 ug/1 lbs 19V. Ethylbonzene

( I 00 4 1.4) <5 <9 ug/1 lbs

'l 20V. Mattryl Bromide $ 7+83 9) 21V. Methyl iu+I

<10 <18 ug/1 lbs Chloride (74 87.3 <10 <18 ug/1 lbs EPA Form 3610-2C ev. 2-86) NTINUE ON PAGE

III ~~ ~ u EI'A I.D. NUMnER (copy from llem l of Form l) OU I ISALL NuMIIER 0418 lyo. 2040 00dd CONTINUEO FROM n E VX 001 Approval exprres 7 31

1. POLI.UTAN EFFLUE 4. UNITS AKE (optional/

AND CAS NUMBER ARIC

'X'SAO C ~s 3.

MAXIMUMDAILY VALUE o. MAxlM M srI g/A Y v A L .I ONG itrRM AVR ~ VALUE + NO'O.P e LONc YERM h. No.o illaua1loblc) NL II VS SHII LISVSI OVIA SANS SSNt A~

e.

(Il CONC S NSII ASION III SIAss (1) II*S~

auadante (1) SIASS YSES icoNcEN e.

RATION II. MASS (tlS cONCAN NATION (1) NASV ANAL.

VSES GC/MS FRACTION VOLATILECOMPOUNDS (conrlnaed) 22V. Methylene lbs Chloride (76.09.2) <5 <9 ug/1 23V. 1,1,2,2-Tetra.

chloroethane <5 <9 ug/1 lbs (79.34-6) 24V. Tetrachloro-ethylene () 27118.4) <5 <9 ug/1 lbs 25V. Toluene lbs (1084)8.3) <5 <9 ug/1 26V. 1,2.Trans-Dlchloroethylene <9 ug/1 lbs (156 60-5) 1,1,1-Trl.

'7V.

chloroethane <9 ug/1 lbs (71-55-6) 28V. 1,1Q-Trl.

chloroethane (79-00-5) <5 <9 ug/1 lbs 29V. Trlchloro- lbs

~ thylene p9.01.6) ug/1 1

30V. Trlchloro-ftuolotnethane <10 <18 ug/1 lbs (75 69%)

31V. Vinyl lbs Chlorldi 75.0INI) <10 <18 ug/1 GC/MS FRACTION AC D COMPOUNDS 1A. 2-Chloropheno (95 57%) <10 <18 ug/1 lbs 2A. 2.4.Dlchloro.

phenol (120.83.2) <10 <18 ug/1 lbs 3A. 2,4 Dlrnethyl-phenol (105.67 9) <10 <18 ug/1 lbs 4A. 4,6 Dlnltro O.

Cresol (534-52.1) <10 <18 ug/1 lbs 5A. 2,4.Dlnitro. lbs phenol (5).28 6) <10 <18 ug/1 6A. 2.NItrophenol lbs (88-75.6) <10 <18 ug/1 7A. 4 Nitrophenol lbs (100 02.7) <52 <95 ug/1 8A. P.Chloro M. lbs Cresol (69-SO-7) <10 <18 ug/1 9A. Pentechloro. lbs phenol (87.86.5) <52 <95 ug/1 10A. Phenol (108.95.2) <10 <18 1-'g/1 lbs 11 A. 2,4.6-Tri.

chloro phenol <10 <18 ug/1 lbs (88.06-2)

CONTINUED FROM THE FRONT POLLUTANT Z. MARK 'X'. 3. EFFLUENT 4. UNITS 5. INTAKE /up IIunal J AND CAS AT ~ ST IT 4 ~ C ~I a. MAXIMUMOAILY VALUE P. MAXI M 3$ Ig/AY VALUK c.LONG TP/IM (Tf'lIP. vALUK d. NO.OI'NAL a CONCKN

a. LONG TKRM h. No. ey NUMBER Nv I ~ VCI IlA~ VS TRAT I 0 II b. MASS ANALI (if auallabil I

~

4$

OVIR I NN SCNT

~

~ SN'I

~

I~ I CONC S NTRATION Il) SIASS lll HA$5 I~ I III HAS ~ YSKS I~ I

~

CONCCN RA SION Ill HA ~ % YSKS WQ GC/MS FRACTION BASE/NEUTRAL COMPOUNDS

18. Acanaphthono (83.32.9) <10 <18 ug/1 lbs

28. Acanephtylano lbs (208-96.8) <10 <18 ug/1

38. Anthracana lbs (12O12 7) <10 <18 ug/1

48. Benzldlna lbs (924)7 5) .I X <52 <95 ug/1

68. Bonzo (l)J Anthrecane <10 <18 ug/1 lbs 56-55-3

68. Bonzo.fa) .

ug/1 lbs Pyrene (60N32%) X <10 <18

78. 3.4.8enzo-'luoranthene (205-99-'2) <10 <18 ug/1 lbs

88. Bonzo (gh(J Perylene <10 <18 ug/1 lbs (191-24-2)

Qb. Benztt (k)

F luoranthene <10 <18 ug/1 lbs (207 08-9) I 108. Ble (2.Chloro.

e(hoxy) Methane X <10 <18 ug/1 lbs (111-91-1) 118. Bit (2.Chforo.

elhylJ Ether (1 1 1XIS4) X <10 <18 ug/1 lbs 126. Bit )2-(7Ihraiso.

picpr() Ether (102.00.1) <10 <18 ug/1 lbs 138. BI! (2-Elhyl-hexyI) Phthalata <10 <18 ug/1 lbs (11741-7) 4.8romo- '48.

phanylPhenyl <10 <18 ug/1 lbs Ether (101.65.3) 168. Butyl Banzyl Phtha'late (85.68-7 <10 <18 ug/1 lbs 168. 2~loro.

naphthalene <10 <18 ug/1 lbs (91-58.7) 178. 4.Chloro-pheny'IPhanyl <10 <18 ug/1 lbs Ether (7005-72-3) 188. Chrytano (218 01-9) <10 <18 ug/1 lbs 198. Dlbenzo (a, J Anthracane (63-70-3) <10 <18 ug/1 lbs 1,2 plchlo(o-

'08.

benzane (85-60-1) ~ ~ X <10 <18 ug/1 lbs 218. '1,3-Dlchloro.

benzene'(541 l3-1 <10 <18 ug/1 lbs V-6 TINUE ON PAGE I EPA Form 3810-2 w. 2-88)

I VIIIIrll)pfDVCII ERA 1.B. NUMBER APPP I If l) OUTFALL NUMOER Obis iya 2040 008 001 Appraisal expires 7-

1. POLLUTAN . MARK 3.EFFLUENT 4. UNITS 5. INTAKE /IB)rinnall AND CAS

'X'T IlILVA, MAXIMUMOAILy yALUc b. MAXI M g/LY VALUE C.LONG T /tM g$ p . yALUK I NO Oe a LONG TCRM NUMBER ~

IN NL Sl IPNI AL I

C AL ILVLI A~

a ajar s. CONCt:N- 1) MASS T RATION

~wumS W)I)(h I) ANO.O II A I I)/ aI)a) Iabl<<I EEVIA k

'TANT ~ LHT (~ )

CDNCI IETHATIDN ll) HAT~ C DNA ~ H IHA TIDH ll) BI A ~ L t.\PNC R, PBT ~ I A ~ IDN II) BEAT ~ YSKS I ~ I CONC)

)MA TIDH lll BIAAA ysas GC/MS FRACT(ON BASE/NEUTRAL COMPOUNDS (continued) 228. 1.4.Dlchloro.

benzene (106 46.7 X <10 (18 ug/1 lbs 238. 3,3'-Dlchloro benzldlna (91.94.1) <52 <95 ug/1 lbs 248. Diethyl Phthalate (64-66.2) <10 <18 ug/1 lbs 268. Dimethyl Phthalste (131 11-3) <10 <18 ug/1 lbs 268. Dl-N-Butyl Phthslata (84.?4.2) <10 (18 ug/1 lbs 278. 2,4 Olnltro-toluene (121-14-2) <10 <18 ug/1 lbs 288. 2.6-D)nhro.

toluene (606 20.2) X <10 (18 ug/1 lbs 298. D).N-Octyl Phthalsta (1174) 4.0)

<10 <18 ug/1 lbs 308. 1,2.D)phenyl.

hydraslna (as Aso.

()enzene) (122.66.7

<52 <95 ug/1 lbs 318. F luorsnthsne (206 44-0) <10 <18 ug/1 lbs 328. F luorene (86-73-7] <10 <18 ug/1 lbs 336. H~obe <10 <18 ug/1 lbs

() IR.?s. II, 348. Hsxa-chlorobutedlene (87-68A))

<10 <18 ug/1 358. Hexach)oro-cyclopentadlene P7.47P4)

<10 <18 ug/1 lbs 368. Hexechloro-ethane (67-72-1) X <10 <18 ug/1 lbs 378. )ndeno fl,2.3.cd) Pyrans (193<9%) <10 <18 ug/1 lbs 388. Isophorone (78.59-1) X <10 <18 ug/1 lbs 398. Naphthalene (9 1.20-31 (10 <18 ug/1 lbs 408. Nltrobentene lbs (98 95 3) ~ <10 <18 ug/1 418. N Nltro-sodlmathylamlne (62.76.9) <10 <18 ug/1 lbs 428. N-N)uosodl-N+ropy)sm)na 62'l-64.? l X <10 <18 ug/1

CONTINUED FROM THE FRONT 1 POLLUTANT 3. MARK 3. EFFLUENT 4. UNITS 5. INTAKE /up Iianvll AND CAS

'X'l NUMBER til avarfabII I IN

~

IL

~ I IL ~ L OVHI'5NT

~

Ll ~

RHL V ~

C ~5 LI ~ VLI A~

SCNT

e. MAXIMUMOAII Y IIALUp III ITI MA55

. MAXIM M 3g g/ Y VALUL .LONG TPPM $

ITI MAss I~ I

!gg VALOE IT) M*'5~

(I. NO.OI ANAL

.YMS

e. CONCBN 1 RATION II. MASS OY %foal tIl OONCLII-

~t LONG TERM III MA~ 5 I NO,

~

ANAL Ysas COHCLNTRATION ONCL NTNATIUH TNATION GC/MS FRACTION BASE/NEUTRAL COMPOUNDS (continuedl 438. N.Nitro.

sodl phenytarnine (86 304)) <10 <18 ug/1 lbs 448. Phenanthrene (85 01-8) X <10 <18 ug/1 lbs 458. Pyrene (129.00.0) <10 <18 ug/1 lbs 1,2,4 Trl-

'68.

chforobenzine (120-82..1 I <10 <18 lbs GC/MS FRACTION PES TICIDE 1P. Aldrln (309.00-2) 2P. II.BHC (319 84.6) 3P. P BHC, (319.85 7) X 4P. T.BHC (68 t)9 9)

SP. 5.BHC;,

(319 86 II) 6P. Chfordette (57749) .

7P. 4.4'.DDT (60-29-3)

BP. 4,4"DDE (72.55.9) ' X 9P. 4.4'-DDD (72-544)),

10P. Dleldlln (60 67-) ) '..I ~ ~

11P. C.Endosuttan (115.29.7) ~

X 12P. P Endosu)fan (I 16.29-7) 13P. Endosultan Sulfate (I 03f-07%)

14P: Endrin (72.204))

16P. Endrin Aldehyde X (7421-93 4) 16P. Heptachlor (76.444t)

EPA Form 3610-A ev. 2-86) E Vis NTI

Forns ApgIIuvcI(

EPA I.D. NUMBER (COP3s (runt (tern 1 (J OUTFALL NUMOER Oht8 Nu. 2040 0 CONTINUED FRO V8 001 I.POLLUTANT 3. MARK 'X' MAXIM)M 3.EFFLUENT 4. UNITS 5. INTAKE (I>IIIIIsnult AND CAS f NUMBER IT( ussuslubts'I Is IN

~ ss i

ISI ~ IN

~ h. ~ s.

I~

TAN ~

Ve

~ 'ss ~ ~

o u c. e. MAxlMUMDAILY vALUE b.

LICIIAI A~

TAN'I I I"

~

CONC L NTN AT ION lsl NACHT lsl C ON C N I N A

~ ~~ I IN 3g PLY VALUE C.LONG TPPM g$ Pf. VALUF II. NO.Or Isl sAALT I I

~

CONC A NTNA T ION III Is@LA YSES CONCEN ANAL a TRATION b MASS ~ LONG 1 RM YCIILkE VBIIBS I> ATIAL Is) I esse Is.

~

TN A ~ ION I II II AT%

NO.OI YSKS GC(MS FRACTION PESTICIDES (conttnucd) 17P. Hcptechlor 6 pox ldu I 1024 57.3) x 18P. PC8.1242 (53469 21.9) 19P. PCB-1254 (11097.69-1) 20P. PC8.1221 (11104.28 2) 21P. PC8.1232 111141.16-5) 22P. PCB.1248 (12672 29 6) 23P. PCB-1260 (1109$ .82.5) x 24P. PCB.1016 (12674.11.2) 25P. Toxaphene (8001 35 2)

PAGE V-9 ITA FN sss %CATT Nr'n ., N ssrs

0 CAPE F1'TEAM ELECTRIC PLANT SAMPLER ¹2 NARRATIVE DESCRIPTION OF STORM WATER OUTFALLS There are four outfalls associated with storm water runoff from areas of industrial activity at the Cape Fear Plant.

Outfall 1 is the termination of the Plant's discharge canal at the south end of the facility and includes virtually all storm water runoff from active industrial areas of the site, as well as all process wastes, including condenser cooling water when the plant is operating.

In accordance with North Carolina regulations, the waters of the state begin just below the weir at this outfall. The two active ash ponds for this facility, which receive and treat much of the storm water from the industrial areas, discharge by overQow stand pipes into the discharge canal upstream of this outfall. The following areas associated with industrial activity are drained by this outfall:

a) The main plant yard, including generating units and boilers, administrative buildings and parking lots, material storage areas, including the coal pile, and service facilities such as machine shops and vehicle maintenance areas are all within a diked area for protection Rom flooding of the river. All areas within these dikes are drained to sumps where storm water and other low volume plant wastes are pumped to one of the two ash ponds. These ponds provide considerable retention time and treatment.

b) Plant yards outside the diked areas, including cooling towers (used seasonally) and railroad tracks used for coal transportation. Most of these areas drain to the discharge canal by overland Qow or grassed swales.

Outfall 2 is at the southwest corner of the site and is used only to provide severe weather drainage from an abandoned ash pond. There is a small pool of approximately 2 acres of standing water in this pond but due to evaporation and in6ltration, the normal pool level is several feet below the crest of the discharge stand pipe. The pond has probably not discharged for several years and did not discharge during the period when sampling was done for this application.

Outfall 3 drains a small area of the site that discharges via a swale to a stream. The only industrial activity in this area is a portion of railroad tracks that carry coal cars. No loading or unloading of coal takes place in this area. The area is mostly grass and gravel rail bed, and a measurable runoff was not observed during the sampling period.

Outfall 4 is the discharge from an ash pond that was abandoned many (20+) years ago. The area is covered with grass and trees and is surrounded by a dike. The crest of the standpipe outlet structure is more than one foot above the ground surface, and there is no standing water. A storm in excess of 12 inches would be required to produce a discharge, and no measurable discharge was observed for this outfall.

EPAIONumber (copynomnemlotForm rl SXfPLER ll2 CAPE FEAR PL Continued from Paae 2 A.B,c. s, o: see instrucuons oefore oroceeoing. Complete one set ot tables for eacn outlall. Annotate the outfall number tn the space pranced.

Tables Vll A. Vll B. and Vll C are included on seoarate sheets numbered Vll 1 and VII.2.

potenuai discharaes not covered by analysis - Is any pollutant listed in Table 2F.2 a substance or a component of a substance wnich urrenuy use or manulaCture aS an intermediate or final product or byprcduct? you

~1 Yes llisr all such oolluranrs oelowl W No (oorosecrionNI Antimony Mercury Arsenic Nickel Beryllium Selenium Cadimum Silver Chromium Thallium Lead Zinc Copper oo you nave any knovnedge or reason to believe that any biologicsi test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years'P W Yes (list all such oolluranrs be/owl W No ( orosectionN Were any of the analyses teponed in Item V performed by a contract laboratory or consulting firm'7

! Qj] Yes (list the name, address, and telephone number ol, and polluranrs No (go to Section XJ A. Name B. Address C. Area Code B Phone No. O. Pollutants Anatvted Webb Technical Group, Inc. 4320 Delta Lake Dr. (919) 787-9171 Total K~.eldahl N Raleigh, NC 27612 I certl'fy under penalty of law that this document and all attachments were prepared under my direction or suoervision in accordance with a system designed to assure that quail%ed personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible lor gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are signl%cant penalties for submining false information, including the possibility of fine and imprisonment for knowing violations.

A Name 8 Official Title (type or pnn>> B. Area Code ana Phone Ivo.

eorge J. Oliver ~Ltanager, Environmental Services (919) 546-4189 C. Signature Page 3ot 3 2F-3

~

f~ ~ ~

~ I ~

~ ~ ~ ~ ~ ~ 0 ~ ~

~ ~

~ ~ ~ ~

~ ~

~ ~

~ ~ ~

~ ~ ~

~ ~

I I ' I ~ ~ I

~ ~ 0 ~

I ' I~ ~ ~ ~ ~ I ~, ~ I t ~ ~ I ~

~ ~

~ ~

I Part G ~ Utt eaCn Oouutant ShOWn in Tablea 2F 2. 2F.3. ana 2'hat you XnOW Or naVe reason io aoaitiona octans ana reauuements. Complete one taole for eacn outtall.

Oeu~ si i Maamum values Average values Number t

(

Pollutant {include uniisl {include unrrsf I of ana Grab Samol ~ Grab Samole Storm i Taken Ouiing Taken Guring CAS Number First 30 FIow~igntea First 30 Flowwvoighted Evems I (if avruiao{el Minutes Composne Minutes Composite Samoleac Sources of Pollutants Color 80 cpu I 90 cpu I I Coa1 and ash VIIB Al 1400 u /1 l790 u /1 I I I Coal and ash Fe 1.3 m /1 1.0 mg/1 I I Coal and ash Cu 20 utt/1 I 22 ug 1 I ICoa and as As See data I in Section I VIIB I I I Cd I See data in Section I VIIB Cr I See data in Section I VIIB Se I See data in Section I VIIB Chlorine,TRI See data in Section I VIIB

>>rt 0 ~ Proviae aata for the storm event{st which resulted in the maximum values for the flow weiahtea composne sam pie

3. 4. 5. 6. 8.

Oats ot I I

Ouration Total fantail Number of hours between Maximum floe rate Total flow fram Form ot Storm ol Storm storm event begutning of storm mess. during ran event ran event sample was Precipitauon during urea ana ena of previous (gaf{onslminure or (gallons or I (ran{a((.

Event {in minuresl {in incnesl measurable ran event soecrfir units soecirti unirsr taken sir owineltl

/23/ 240 0.35 ., 200 59.5 MGD Winter Rain or 41,320 gal/ 2 x 10 min gallons flow'of "ioviae a aescnotion ol the meinoo of llaw measurement or estimate.

Plant cooling water pumps were operating at tine of sampling, providing 41,000 gallons in discharge canal at outfall weir. Any contribution of this storm to that flow would not be measurable. Flow rates given are from pump rating curves. Total flow from rain event based on total rainfall and U.S. Soil Conservation Service runoff estimation techniques (USSCS Field Manual).

EPA Form 35to 2F {tt gOI Page vu 2 2F-5

Key Drainage Area Po

Boundary 8'esT'a~ Pouo J 0ssryui. i00)IL Outfall p I Sewer Line so Z ~oboS 'L r,C,'IT ~iSC' &ITR+JCC SDM wp>>~ pP / DiS CriARC g, 0 0 Nl~br ARTCC ~ND ) yR4 0 0 Cooi 0 0 T~CSS 0 WAI " QN( f PiSCw+CSC ipi0 Voi 0iit l00m E ~ RS+iJo~ DA $ eSCNARA0 ~ Pos> Pili ltbA <no Abii PS'SO C J4~+ CillitS - 884~0~alEO PoaP (bc4(MFS) S>m PsS~tl<iC4E sr')5c yL + g ty,(~ I P~ ~ i~AiCf. 0 Sia0C.T0RC RiVSR t'AP a. CAROLINA POiVER & LIGHTCO. CAPE FEAR STFAM ELECTRIC PLANT Storm Water Group Application No. 286 Sampler No. 2 'f olrsce oitnl ot cvos ih che uflshsoeo mess ohlv Form Aoproved. OMS IIO. 20f 04086. Aporovat escjna Ifpr-tn crees ere rdececr for erin cvde. Ae.. I2 chsrecrennnchl 54)42. UA CNVINONMCNTALFNOTCCTION AOCNCY I. EFA LtL NUMseft GENERAL INFORMATiON %1/ Consolidated Femcics Frottnam F QSNNRAL riewf rae "cenerel lnsrrnerione" aerdre ererflne.f k 4 INS n T Ole if e pratxcntad bb¹ has bean povs'decL affix I. CFA I.D. NUMSKIS it In cha dasianacsd sosce. Review che eiforrn-III FACILITY ~ NAML'CILITY ~ pprcu~ the printed ~ ~ chn carefuilyl it any ol it h incorrect. croa throuen lt and sneer che correct deca In che cree baiOw. Aise,4t eny of deca ls ebssnc fcha <<w so the tert or the label nance Hsts tice ttrfoinsatfck 'AILINQADDItCSS EASE FLACK KI. If4 THIS SfsAC lhet sfxnitd aoosarft please prcnnde ll itc the pnspar INI-in ereafrt below. If de tab¹ ls FACILITY ~ icloiese and correcL you nsad not oornplcce Items f, ee lll. v. and csscussssscf vl (cconsr rseensesscf. harae If no label hes been orondacL Rater to vM knlcfs Conccste eN 'OCATION ~ ~ he hcsanscdona these for dstaued hsmedsscrfp. for tha local authorfcachxca under. whfabd&dete ls couaccacL IL FOLLUTANTCNAIIACTIRtSTICS INsTRUcTIOIIL Cmaploo A through'e detedefae sahether yestaned ts euhesft eny penpit epplfcetlm feeeee the 8'A. Ifyou ,quadooa, yoo Inutt cobalt th)e fons assd the eeppf~A %ra fhesd IN the'peteetheafe fef)~0 the IettteaL ffeth")I"hi the hox hi the thin) cohpen ~-"oe" ~ ~ yse"-teeny ~~ If the tupplalneritakfotta4 et)ached; If yeu 8e.eath Fsattffea, Test eeecl not eshssit eny ef these fcetsL You facy "no" If your ectfsfty Is excluded from parte)I teqeieeaetDm2ecdeNC ef the Iectrsctfona See efeL ~tel 0 of the hcawtfonc for dcffafthma of heid-faced terna aecccerc csucsTsoks va e Onion seocs stsc ou csysosrs A. I~ ittt.~ ~ watch resuccs in a dbatkeee.so tttttttt~:~~ ~naif sw g,<Doaatar u¹t dde iecNRy labeaF ea2usasr oF Prc2P~dl Itttlttl~ t ttttat tttlttl~ Wtttttttt ii vae ~ A. it tTnens ~ dsa.ILLS IFORM 2AI ~ eueste enhssl pnadsladess fsahhcr svfucrc nsurcs Nl e Naaiaseee>> of dse VS2 IFOftll2$ ) I is a sell ltv wfl curcanclv reslno lil ~ s k~ co waters of che ILs. OQ>>r chan chose oeccnbed in X X fn el or S consist vddch wlu rends Nil e co X or tF M F. Oo you or wiN you inject et this fa¹licy induscnsf or 2, Does or will lhis facility creat, score, or dispose of municipal effluent baukv tl>> lowerncctt stratum Con. hasardoua wmsat IFORM 3) tahdruL whhhs one quarter mNe of the wau bon, undssIround usurces ol drfnQne encert IFORM e) 0 Yoii dr wt vdli Inrecs ~ is wscar or other fluids whch are broutnt soche surface H. Oo you or wIN you Infect et thia fac4hy tiulds tor nso-in connecccNI vnch oonvenchsrcat oil or,necurat eas pro. cf¹ procasan aucfs sa nurdne of scdfur by tha Frasch ducdon, in)ace fluids~ +sr enhanced recovery trf ~ procasat aoludon tnhllne ol nenenda, Nc shu cornbus oil or nacurai eas cc fnfscrfhddsfoeaseraeaotdcsdd .:oorsof

'FOffMfoadt fuaL or noway of eeothann¹ energyt h I IFOIIM4) 4)

I is nv e ty e Oxkae is one of the 28 indunnal oasetknee listed in the in. ffgT one of tha 2S hduttfisf caceeoriss listed In che sccuccions snd which wiN pocssnialty amn t00 tons Inscrcxcions ond csauch wiN pocanclouy emit 250 cons of any air popucenst cwesaasad" under the . par year of any ¹r pouucant ISCFNatad under the Clean Cisen Air Act andirnsy ONacc or be Nscesad ines ~ . Air-Acc snd mey efface or be locecad in en eclair~os ~ccshviwns MwI IFOIIMNt:i -. anat IFORM Sl' IIL NAMN OF FACILITY i fex'o!CAPE FEAR STEAN ELECT ~ ~ ~ ti IV. FACILITYCOIITACT Ai NAMC at TITLC IISS4 IIIVLn IICISI ~ FHONC Serve code e no.r C ~ 2 ~ J 0 V 919 546 1 9 V. FACILITYMAILINQADDRESS A eTkccT ok F.o. eox P. 0. BOX 1551 ~ CITY Ok TOWN c,sTAT o. Cie cooc RALEIGH NC 27602 Vl. FAClt.lTY LOCATION A. STNCCT kOUTC NO Ok OTNCk eecclrtlC IDCNTlrtl~ Sr BOX 229 CHATHAM C TY ROAD 192 t ~ ~ ~, COUNTY NAMC i t CHATHAM C. CITY Olc TOWN o.aTATci c. Slit cooc I NC 27555 EPA Form 3810.1 (8 90) ON RCVERSE I'ONTINUE CONTISIUEO PROM THE FRONT Vll. SIC COOES ldaislt, m oroer or ononryr A. FIRST S. SCCONO rrptrtfpi (tptofpr ELECTRIC POWER SERVICES C THIRO O. FOURTH ftPttlrpr Ifperil pr 7 ~ ~ ~ Vill.OPERATOR INFORMATION A, NAMC I ls Olo nNlle iisteO In Item VillA eteo iherHtr CAROLINA POWER Irt LIGHT COMPANY 8 %YES ~5 DNO I~

c. $ TATU$ oF opeNATQN (Entet tnt oppropnete letter mto tire ontwe oacr tf -otrtrr". tpert+I O. FHONC terre colic 4 nat 0 OTHEII rtpectfyr l

(orner trlell /edetol or toter ' P ItPertfpl a 915 546 4 8 S 0 STATE P 0 PRIVATE ~ ~ I~ 1~ 0 Ie 4 eTNCCT oR F oe NOR ~q P. O. BOX 1 5 Is the reality locstscl on lnolen Ienosr 9 RALEIGH NC 27602 ~ YES SS M NO I~ ~ I ~0 X, EXISTINO ENVIRONMENTALPERMCTS A tleocs rprtcrurresso aerreee seseyt AIR EMISSION SOURCE 9 N NC0003433 9 P 1057R9 OPERATION

s. Ulc rr.'ndtrrround Inlectfon of ptnldtt e. OTHCN lepecti7)

(t¹crfyl 9 U c, RcNA IHctetdoos Wettest 44THCN rspoctipl I 9 R 9'. ~ ~ \~ ~ se e ~ eo ~ ~ ~ XI. MAP Attach to this application a topotyaphio map of the ~mtandinyezatfeeatonecnffeheycnsd property boundaries. The map must shoer tha outline of the facility, the iocadon of eecfLof fte edacious end progxnerflntake encl diecf large structures, each of Its hazardous waste treatment, storage, or disposal facBltfea, andeech araS~ ft ~lfftdde.undosynxesd.'nclude all sprln9r, rivers and other surface XII. NATURE OF BUSINESS(proenseobnor ELECTRIC UTILITY XIII.CERTIFICATION fteo ntttrttctcortcl I certify under penahy of law cher I heeeymNI~ exaninecf end an Aaalfer witfpthe Infonrratiorr auhnrftced In this application and all ~ ttachmrrnrs and char, baaed on my. Inocdry-os thoee peraone for ofrtakrhg the Infonrrarion contained ln rhe application, I brrlieve chat the ln%%dnnarion ie crt'ccrteateand creep&a I an esyere chat there <<e agnifleant penaltiesfor Nrbrrrirrlnli falrrr information,including rhe possr'hilly of fine and Inrprfaorenarr. A, NAMc n oeelcIAI TITcc ItyPt or Pnntr ~ SIONATURC OAT SI HCO GEORGE J. OLIVER ~I'IANAGER - ENVIRONlKNTAL SERVICES ~/~~/P~ COMMENTS FOR OFFICIAL USE ONLY C C ~ ~ ~ ~ EPA Form 3514.1 (S QQ) P ~.'~y ~~~ i '- F DEEP RITE -i Zj E, ~e- I ~ 'OF 1IILSifl 1 CD' ( EO PI'LS >>iI CAPE FFAII S. E P.LANT, COOLI;IG DISCHARGE ( } l ~l I / r1 ',.;::I .

"n;..('r, I ipse EAST (NEH) ASH POND WEST (OLD) ASH

~ q,'.1 POND DISCHARGE ( ~ .; ~ ), ( I (OLD) ASH POND ')P7. WEST EAST (NEH) ASH POND DISCHARGE ( Weir F r~/r',Ou((al( r~' ~(FEE ~ 500 'l hPI ) ~' ) ~ Vg E ~ W~ rP. 'l,M~~)W ~l, I ~ ~ ~' ) S COOLING MATER DISCHARGE CANAL " '~~n i(l, (to Cape Fear River) Pgy j f r QX o++ I qC UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY 1OCO 0 1000 OOOO )O00 4000 SC00 OOOO POCO FEET I NILOFAETEN CONTOUR ENTKRVA(. lO Fed MONCURE QUADRANGLE NORTH CAROLINA 7.5 MINUTE SERlES (TOPOORAPHlC) LOCATiON MAP CAPE FEAR S. E. PLAE'IT CAROLINA POWER 5 LIGHT CO. CHATHAM COUIIITY, N.C. urn l.u. NUM OCR leppy /rom l lcm I bi Fortn I) OAfg iya 3040~g Please ormt or tvoe in the unshaded areas only. Approve(aspires 7 3r4g FORM ~ - --.- --- - ~ V.S. CNVIRONMCNTAI PROTCCTION AGCNCT APPUCATION FOR PERMIT TO DLSCHARGENASTEWATER NPDES iSEPA EXISTING MANUFACTURING,CQMMERCIALrMININGAND SILVICULTURALOPERATIONS Consoii dared Permit g Prograrrr I. OUTFALL LOCATION For each outfall, iist the latitude and longitude of its location to the nearest !5 seconds and the name of the receiving water. A. U 0 LATITUDC ~ C, LONGITUOC NUMOCR o. RccclvING wATCR (ncmcf ilicn L ITIN s Scc ~ ~ ~ OCO ~ L It1N, I ) SCC ~ 001 35 35 79 I 02 I 30 CAPE FEAR RIUER TRIBUTARY (UNTIED) I I II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A, Anach a line drawing showing the water flow through the facility. Indicate sources of intake water, operations comributlng wastewater to the effluent, and treatlnent units labeled to correspond to the more detailed descriptions in Item B. Construct a water balance on the line drawing by showing average flows between intakes, operations, treatnlent units, and outfalls. If a water balance cannot be detertnfned (ag forcenalrr mininp ac&Idasl, provide a pictorial description of the nature and amount ot any sources of water and any collecdon or traattnent Ineacuree. -. B. For eacn outfall, provide e descnption of: II) All operations comnbuting wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and I3) The traatnlent received by the wastewater. continue on additional sheets if necessalV. I ~ OUT s. DPcRATIDNIsl coNTRISUTING PLow S.TRCATMCNT PALL N b. AVCRAGC PLOW b, I IST CODCS PROM (IQII a. DpcRATIDIC llfcrl ~ nncludc unl tel TASI c ac I pp 1 Low vo lume wastes 0. 142 ."IGD Oxidation, sedimentation " 2B (see narrative) neutralization 2K Condenser cooling water 180 51GD Evaporation 1F Ash sluice water 0.56 HGD Oxidation, sedimentation 2B 1U Coal pile runof f .007 ~IIGD Sedimentation, neutrali2ati lU 2K Sanitary waste .002 HGD Oxidation, sedimentation 2B lU Yard drains varies Sedimentation 1U opplclAL Use oNLT rciflucnr culucnncc cub.cctccorlccl 2r'Rnu. Dnr:L-I ~c ONTINUSlD FROM THE FRONT ""' Except for storm runoff, leaks, or spills are any of the discnsrges described in Items.ll-A or 8 intermittent or ssasor~.r ~ VSS (COmPlere ihe fOIIOW(ng(cate) i . ... ~ ".,'."', . -=:., ..~ NO ega IO STCIIOn iiil -'&evaP ll OVAV 3.FREQUENCY 4. FL'Oyy, ~ ~ ' 4, PLOW RATS IL TOTAL VOLUMS ~ ~ ~ I. OUTFALL 2 OPERATION($) A a: D*YS b MDNTNs ((n mgds ,(spec(fy w(lh ulllrel -c. DIS ~ NUMBER CONTRIBIJTINQ FEOyy '- YOtWCSK'spec(fy PSIT-YCAR * (epecjfy l UOVV TCWV 4 VAXlllVV ~ 4444 TCWV 1 VAWIVUV (fig(j (ftar) aiie rage I aveflggeJ AvcwA44 ( Ill. PRODUCTION A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? Qg Yss (complete I(em III.BJ -v -@No Ro Io Sec((on IVI ~ B. Are the limitations in the applicable effluent guideline expressed in terms of producuon (or other measure of operedonj? QVSS (ComPlete I(em-Ill CI '-- - ~ -' -.- -- " ~"- - ~- - ~ - ggNO-(go Io SeC<iOn IV).'-~ - ~ ~ --~ - - ..~.~ ~ ", .-V . C. If you answered "yes" to Item III-B,list the quantity which represents an actual measurement of your level of production. expressed in the termsandunits used in the applicable effluent guideline, and indicate the affected outfalls.

1. AVERAGE DAILYPRODUCTION 2. AFFSCTCD C OACWATIOV ~ WOOUCT~ VATCWIAI CTC OUTFALLS I 4 4UAWTITV ACW OAV b, VWITC OW VCATVWC (Iles outfall numbers)

(ipeel fyl IV. IMPROVEMENTS

• ~

A. Are vou now required by any Federal, State or local authority to meet sny implementation schedule for. the construction, upgrading or operation af waste-water treatment equipment or practices or any other environmental programs which may affect the discharges described in this application) This includes, but is not limited to, permit conditions,administrativsar enforcement orders, enforceinent compliance schedule loners, stipulations, court orders,and grant +vss (complete the follow(wg Iaalel Qg No (go io Item IV.BI 2, AFFSCTCO OUTP'ALLS a. FINALCORI I, IDSNTIFICATION OF CONDITION 2. SRICF DESCRIPTION OF PROJSCT ACRCSMCNT, CTC, 444 b soU444 ow oiccvA444 4 CC OUIWCO Is wwD J 4 CT 4 4

8. OPTIONAL: Yau may attach aaditianel sheets describing any additional water pollution control programs for orner environmental projecD which may effect your dischergesl you now have underway or which you plan. Indicate whether each program is naw underway or planned. and indicate your actual or pieilnea schedules for construcpafl @MARK "X" IF DSSCRIPTION OF AODITIONAI CONTROL PROGRAMS IS ATTACIISD EPA Form 3510-2C ( Rev. 2.85) PAGE 2 OF 4 CONTINUE ON PAGE 3

Form 4 oorovea EpA i.o. NUMseRtcooy Irom Item I or eorm I I ORB IIo. esoires 2D1.88 2040~86'pprovet CONTINUEO FROM PAGE 2 V. INTAICE AND EFFI-UENT CHARACTERISTICS A, B, & C: See instrucuons oefore oroceeaing Complete one set of tables for each outfall Annotate the outfall numoer in the space provided. NOTE: Tables V A. V B, and V.C are included an seoarate sheets numoerea V-t througn V-9.

o. Use the soace below to list anv of the pollutants listed in Table 2c.3 of the instructions. which vou know or have reason to believe is discharged or may be discharqea from any outfall. For every pollutant you list, briefly descnbe the reasons you believe it to be present ana report any analytical data in your possession.

i, POLLUTANT I S. SOURCE 1, POLl UTANT S. SOURCE Asbestos ', Used in insulation; trace amounts IIIny be washed down drains in plant area I ,, durint; maintenance i activities. i s Strontium 'race elements Uranium occasionally present in Vanadium coal or oil used to Zirconium start boilers. ~ VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS ls any pollutant hstedm item V.C a substance or a component of a substance which you currently use or manufacture as anmtermediate or final product or byproduct? Qg ttist ll uch ottsstonts beloirri +NO rgo to Item trl BI Antimony Arsenic Beryllium Cadmium Chromium Copper Lead Mercury Nickel Selenium Silver Thallium Zinc EPA Form 3510.2C IRev. 2 Ss) PAGE 3 OF 4 CONTINUE ON REVERSE VII. BIOLOGICALTOXICITYTESTING OATA on you hms any un oui toga or reeum to heiieea that any uiotogimtmm tor mauaor uuonio toxin ty hst assn mess on ~ y or your aaohsrgat o on ~ raoeieirlguatsr s mretloutuyoeyuhahanmutthhtthutmegymmh ermtuega. megml ~ QQ YISS ttdentlfy Whe tcstlel angl dcscrfbe their purposes belagel ~ +No <so to Section VIIII I (0% effluent - control and 99% effluent) and observed .for 7 days to assess adult mortality and reproduction. There can be no significant inhibition of reproduction or significant mortality in the 99% effluent compared to the control to pass the test. Results: Nov. 1991 Pass Feb. 1992 Pass May 1992 Fail June 1992 Pass 'VIII.CONTRACTANALYSIS INFORMATION Were any of the analyses reponcd in Item V performed by a contract laboratory or consulting firmI GDYcs (I4t lhe name. addrese. and telephone number of, and pollutants analysed by, each such laboratory or firm belogel + No leo to Section IXI frAA VTRD A, NAME Lu AOORCSS area cade

• no. l4t Webb Technical Group, Inc. 4320 Delta Lake Drive I (919) 787-9171 Acid extracts, Raleigh, NC 27612 Base/neutral extractables, Volatile organics, Total cyanide, Dioxin, Phenolic Compounds, total Kjeldahl Nitrogen IX.CERTIFICATION I cent'fy under penalty oflaw that this document and all attachments were prepared under my direction orsupervisionin accordance withe system designed to assure that qualified personnelproperly gather endevaluate theinformation submitted. Based onmyinquiry of the person or persons who manage the system or those persons directlyresponsible forgatheringthainformation. theinformation submrltedis. to the best ofmyknowladga endbeliaf. true. accurate. andcomplate.

I am aware that there are significant penalties for submitting lalseinformation, including the possibi%'ty ol line andimprisonmant for knowing violation* A. NAMC ct OFFICIAL TITLE Itypc Or pg'lggti George J. Oliver Manager - Environmental Services Secticn (919) 546-4189 O. DATE SICNCO g/assr y-z EPA Form 3510e2C IRev. 2-85) PAGE 4 OF 4 Sanitary waste treatment 0.560 MGD Pump Sta. East East side No. 2 ash pond Ash yard drains transport s tern Coal pile runoff Pump Sta. No. 6 Sailor makew No. 2 oil tank runoff 8 service wate O.t43 MGD j basin ns Stu. 179.610 MGD ~Pump Intake Sandbed filter ndenser structure ackwash wats Parking lot drains North side Make up ~ Cape Fear afd drains No. 1 oil tank runoll WE-Pump Sta. West 0.560 MGD Discharge F Capo Fear No. 1 ash pond canal River Equip. cooling tower drain kE- 0.142 MGD ouTFALL 001 Waste oil blowdown stora e Once-Through Once-Through with Closed-Cycle Cooling Cooling Towers Cooling Towers Oil unloading {MGD) area drains low volum A 180 0 0 Hoor drains Pump Sta. No. 5 retention 8 0 9 9 basin C 0 9 9 South side ard drains D 180 0 0 Evaporation E 180 9 9 Oeminerabzer r enerate {0.001 MGD) F 180 1 1 G1 0 171 Equip. cooling ower bl G2 171 Units 54 6 ler blowd Pump Sta. No. 7 Ash trench Water Flow Diagram Cape Fear Steam Electric Plant Carolina Power 8 Light Company VALVES: ~ Normally closed pCj Normally open Chatham County, NC CAPE FEAR STEAM ELECTRIC PLANT DESCRIPTION OF WASTE STREAMS The Cape Fear Steam Electric Plant is a coal-fired electric generating plant with four units rated with a net dependable capacity of 28 MWe (Units 1 & 2 combined), 143 MWe (Unit 5), and 173 MWe (Unit 6). Uaits 3 & 4 are in cold standby status. Chemical constituents contained in these discharges will in part be representative of the naturally occurriag chemical quality of the intake water as well as naturally occurring runoff from the ash pond drainage area and will also have chemical constituents of such quality and quantity associated with similar discharges for fossil generating facilities of this size, type, and in this geographical location. Either all or part of the elements enumerated in the Periodic Table, either siagularly or in any combination, may from time to time be contained in this discharge. More detailed descriptions of the individual waste streams are below. OUTFALL 001 - COMBINED DISCHARGE This outfall is located at a weir in the discharge canal approximately 250 feet below the point where the East Ash Pond Discharge becomes "waters of the state". This discharge contains all waste stream Qows including once-through cooling water, East Ash Pond discharge, and West Ash Pond discharge, which are summarized below. ONCE-THROUGH COOLING WATER Condenser cooling water for Units 1, 2, 5, & 6 is withdrawn from the Cape Fear River, passed through the condenser, and discharged directly into the discharge canal. Some cooling is accomplished in the discharge canal. When the temperature at Outfall 001 (weir at the end of the discharge canal) reaches 32', cooling towers are placed in service in once-through mode to keep the canal water at or below 32'. If32 C or less can not be maintained by once-through mode, operation is shifted to closed cycle cooling tower mode. The once-through flow may range from 58.8 MGD to 385.4 MGD. EAST ASH POND The East Ash Pond receives ash transport waters (bottom ash and fly ash), runoff from yard drains, and sewage treatment plant effiuent. The ash pond provides treatment by sedimentation, oxidation, neutralization, equalization, and adsorption. The East Ash .Pond Qow ranges from 0 to 1.0 MGD. WEST ASH POND The West Ash Pond receives coal pile runoff; No. 2 fuel oil tank runoff; settling basin drains; sandbed Qlter backwash; parking lot draias; equipment cooling tower blowdown and drain; boiler blowdown; oil unloading area drains; demineralizer regenerate; various yard and fioor drains; and ash trench drain, The ash pond provides treatment by sedimentation, oxidation, neutralization, equalization, and adsorption. The West Ash Pond flow ranges from 0 to 1.0 MGD. CAPE FEAR STEAM ELECTRIC PLANT CHEMICALS USED IN PROCESS STREAMS Chemical Used/Year ~Fre uencv Puruose Aluminum sulfate 12,000 gal. Continuous Improve settleability in clarifier u Soda ash 500 gal. As rcquircd Improve settleability in clarifer Sanuril 800 lb. Continuous Chlorination of treated domestic wastes Sodium hypochlorite 3,000 gal. As required Chlorination of circulating water system Sodium chloride 4,000 lb. As required Softener regenerate Sulfuric acid 9,000 gal. As required Dcmineralizcr regenerate Sodium hydroxide 12,000 ga). As rcquircd Demineralizer regenerate Morpholine 400 gal. Continuous Condensate pH control Hydrazine 200 gal. Continuous Oxygen scavenger in boilers Trisodium phosphate 800 lb. Continuous Boiler pH & corrosion control Hydroquinone 100 gal. As required Oxygen scavenger Potassium hydroxide 500 gal. Continuous Corrosion control 1-Bromo-3-chloro- 1200 lb. Continuous Biofouling control 5,5-dimethylhydantoin EPA I.D. NUMOLR (cupy from Item I uf I ann I I Iu>n>>II>I>>u>>c.d PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. Ynu muy report some or alt o( Oft(a iyu 2040 II08h this information on separate sheets fuse the same formerJ instead ol completing these pages. Appruual esp>i es >T 3I aid SEE INSTRUCTIONS. OU I r>ALL trO V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2 CJ 001 PART A - You ntust provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3. UNITS 4 INTAKE I>priI>nuIJ .VAL L (sprrifx If hlanhJ

1. POLLUTANT a. MAXIMUMDAILYVALUK . MAXI illM ao DAY VAt.UE C.

I cuailahiel N h ovu ra e a. LONG TLRM b NO, Ot> IL NO. OF CONCCN. 'lI) NA$5 ANAI YSCS e. b. MASS Atr ALTSES COHCSHTHAI>OH ts) NA55 CO>>CCHTNATION III N 455 TRATION Ir) NAI'5

a. Biochemical OCVOen Demand fBODJ <10 <1827 mg/1, lbs/day

b. Chemical Ocysen Demand (COD) <20 <3653 mg/t. lbs/day Total Oroanlc Carbon fTOCJ 6.4 1169 mg/L lbs/day

d. Total Suspended Solids (TSSJ 1Q 1827 mg/L lbs/day

e. Ammonia (as IIJ I 0.27 49.3 mg/L lbs/day VALUE VALUE VALUE VAI UC I. Flow 198.0 116.1 69.0 HGD

o. Temppature VALUt: VALUE V ALIIC VALUL'AI OC (su(riser) f I'; 20 12

h. Temperature UC VALUE VALUE vALIII (turne)erJ.; 24 23 23 C MrttlMUM MAXIMUM MINIMUM MAXIMUM I.PH", STANDARD UNITS 6.7 7.7 6.7 7.7 PAAT 8 ~ Mark 'x" in column 2 a for each pollutant you know or have reason to believe is present. Mark "xH ln column 2 b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectlybut expressly, in an effluent limitations guldel! ne,youmust provide the results of at least one analysis for that pollutant. For other pollutants forwhich youmark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. complete one table for each outfall. See the instructions lor additional details and requirements.

t. POLLUT- a. MARK 'X'. 3. EFFLUENT 4. UNITS S. INTAKE fuprlirnu)J ANT AND sc b. Nc MAxIMUMDAILYvALUE b. MAxr PM aII g/IY vALUK c.LDNG T /tM P Itif'>. vAI Uc Ii NO 0 a. LON E NO OF

a. AVERAGE VAt UE CAS NO. L>cuc Lic>>c SHC A~ ANAL C.LONCKNRA'TION b. MASS I ANAI (Ifavalfaa(CJ $ CHT 55NT I CONCCNTHATION lt) NA@$ C O N C S N T ffA 'T I 0 N III NA$ $ I CONCCN'fffATION lr) NA%$ YSES CONCCHTH*TION Ir) NA55 YSES

~. Bromide I24gagff g) <183 mg/L lbs/day

b. Chlnr(rre, Total pet)dual X 0 0 mg/L lbs/day

c. Catar- CPU 8Q NA

d. Fecql I Coll(or@ 105 col/10 NA

e. Flue(i >li)

I togs 0.47 216 0.47 216 .14 62.25 mg/L lbs/day '. Nitrate-I '- Nitrite (ai NJ <201 rag/L lbs/day EPA Form 36'.2C iRev. 2-861 PAGE V I '

1. POLLUT- 2. MARK ANT AND S.IAVCI CAS NO.

(tf ovaItoblo)

g. Nitrogen, Total Organic (os Grease

)r)

h. Oll and OI.

WHC %%HI ~ %%NT 'X'. ITEM V.B CONTINUED FROM FRONT U.IIc- a. MAxIMUMITAILYVALUE b. MAXI L TAO A~ I COHCCNTHATION 2.6 lsl HAT~ 477 548 M CONCANTHATIOH 2.6 EF'FLUENT 3)g)AY VALUE C.LON III HA%% 477 I CONCANTNATION 0.86 f /I pig . VALUE III H*%% 119.6 YSES 4 mg/L mg/L

4. UNITS a.CONCEN TRATION IL MASS lbs lbs

~I S. V IR INTAKE (optional) "LCM".bE CVNI' .NI IATIOH ~ III HA%% ANAL( YSES I. Iihosphorus (os P), Total 0.3 0.3 0. 15 71.5 (7723.14.0) 231 231 mg/L lbs ). Radioactivity (1) Alpha, Total <2.67E+0 pCi/L NA (2) Beta, 496+1.75 Total 0 NA l3) Radium, Total. ' 0.28+0.49 NA Ci L NA (4) Radium 226, /otal TESTING AND RE ORTING N T REQUIR IL Sutfata (os SO4) l48 08-79%) X 170 54218 165 30473 45.6 14435 16 m L lbs

t. Sutfkre (os 9)

m. Suttlte 0.4 73 I ~AL (as SOS) ..

(14266-46-3) X 2.1 384 1 mg/L lbs

n. Burt actsnts

<0. 1 <18 1 m/L lbs

o. Alum num, Totslct (1429.90.6) 2.8 2994 2.8 2994 0.94 566.8 8 mg/L lbs

p. ar um, TotalI'44 0.39-3) ofonI I 20.0 36 ~ 5 1 u/L lbs n.

Total (7440.424)) 0.06 1 mg/L lbs

r. Co t,.

Total (7440-48 4) <0.05 <9.1 1 mg/L lbs L Iron, Total (74394)9 6) 2.4 1497 2.4 1497 0.94 431.4 8 mg/L lbs

t. Magnesium, Total (7439-96-4) 3.0 548 1 mg/L lbs

u. Molybdenum, Total (1439.98 7) <0. 1 <18.3 1 mg/L lbs

v. snganess, To'tel (7439.96.6) 0.12 21.9 m /L Ibs

w. Tln, Total (f440.3 f.(t) 0.6 109.6 1 mg/L lbs X. Tltanlum, Total 7440-32.6) <50 91.3 1 ug/L lbs EPA Form 361D- ~ Rav. 2H86) PAG CON N PAGE V ~

EPA I.O. NUMBER (COPy fram Item ) Ol Funn )) OUTFAI.L NUMOER Farm Appruved OMB eru. 2040 0066 001 Appruvar aspires 7-3I ee CONTINUED FROM PAGE 3 OF FORM 2 C PART C - ((you area primary industry and thisoutfall contains processwastewater. refer toTable2c-2lntheinstructionstodeterminewhichof theGC/MS fractionsyou must test for. Mark-X-incolumn 2.a for all such GCIMS fractions that apply to your industry and for A( L toxic metals, cyanides, and total phenols. If you are not required to mark column 2.a fseconderyindoslrics, nenprocess wesresverer orrrfells. endnonrer)rrired GC/MS frecrionsf. mark "X"in column 2-b for each pollutant you know or have reason to believe is present. Mark-X" in column 2 c for each pollutant you believe is absent. Ifyou mark column 2a for any pollutant, you must provide the results ot at least one analysis for that pollutant. Ifyou mark column 2b for any pollutant. you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations ot 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrile. 2,4 dinitrophenol. or 2.methy).4, 6 dinitrophenol. you must provide the results of at least one analysis for each of those pollutants which you know or have reason to believe that you discharge in concentrationso(100ppbor greater.Otherwise. for pollutantsforwhichyoumarkcolumn2b,youmusteithersubmitatleastoneanalysisor brieflydescribethereasonsthe pollutantisexpectedto be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table fell 7 pages) for each outfall. See instructions for additional details and requirements.

1. POLLUTANT 2. MARK 3. EFFLUENT 4. UNITS 5. INTAKE ioprional)

AND CAS 'X'$ NU)48ER $ $ tX as C ~s s. MAXIMUMOAILY VALUE b. MAxl M Qs g(AY vALUE ou o c C.LoNc T M pigc ouo 0 . vALUE d NO.OF s. LONC TERM tL NO OI so $ vs ursus a. CONCEN- ANAL (Il ouortsble) ~ ~ rs ~ pHO $$ ANAL TRATION b. MASS c D rr c s tt Quu) ~ CNT $ $ NT (\) NA$$ (I) ar$ $ $ I~ I (I) rr$ $ $ YSES (I I vuAvloN I\) $ $ 1 ~$ YSKS METALS, CYANIDE, AND TOTAL PHE NOLS 1M. Aattmony, Total (744q.36 0) 0. 05 mg/L lbs 2M. Arsenic, Total (7440+ 2l 0.05 2.14 0.05 1.25 0.008 0. 79 mg/L lbs 3M. Beryllium, Tots), 7. 40-41'7) <0.01 <1. 83 mg/L lbs r >I'M. Cadmium, Total )74r(0%3 9) 0.004 0.98 0.003 0.63 0.0007 0.18 16 mg/L lbs SM. ChromIum, Tots) f7QP.47.3) 0.022 0.022 1.0 0.004 0.20 16 mg/I. lbs (7440M) ',; . 0. 03 29.4 0.03 29.4 0.01 4.8 mg/L lbs 7LL Lead. Tata) (74394)3.g ,:-" X 0.003 1.8 0.003 1.8 0.001 0.5 mg/L lbs BM. Mercury. Total (743$ .97+) ' 0.0001 0.1 0.0001 0.1 0 0.1 mg/I. lbs 9M. Nickel, Total (744'-Ogrg'): " 0. 04 42.8 0.04 42.8 0.007 6.1 mg/L lbs IOM. Satan)urn,, Total f P2i49.2) f 0.05 1.07 0.05 0.99 0.007 0 '4 mg/L lbs 11M:Sliver. Total 1744022y f'-:; ~ <5 <913 mg/L 12M. Thillium, <0.01 <1.83 Total (744(429 0) mg/L lbs 13M. Zinc. Total 0.02 9.9 (7440-66.6) . 0.02 9.9 0.003 1.2 mg/I. lbs ')4M. Cysntds, <0.005 Total (57.12-5) <0.91 mg/L lbs 16M. )'hsno) a., <0.05

11) 0 rt; lb..l

<9. 1 mg/L lbs DIOXIN ( .. ~ ' ~, .I. ~:I ~ ~ r I, ~ . n ~ I i' '.t 2,3,7.B-Tstrs- OKSCRIKK RESULTS chlorodibsnso P X Dioxin Screen Negative <0.5 ug/L Dioxin (176+0).6) EPA Form 3510<<2C (Rev. 2-88) PAGE V 3 I rINTINIIFrIN IIFIIFR~F CONTINUt.O FROM THE FRONT

1. POLLUTANT 3. MARK 'X' 3. EFFLUENT 4. UNITS 5. INTAKE (optional)

AND CAS L I II NL' MAXIMUM OAILY VALUE b. MAXIM M 30 OAY VALUE C.LoNG T /IM gQIIP. YALUE a. LONG TERM II. NO. C NUMBER ~ ~ ~ N ~ I VIL'I LILV NL ~ I

e. auoiraoie) a. CONCEN'RATION II. MA&9 6Y ANAL RL ANL A ~ ( ~ I CONCCN (I) YSES (if auuIlabi<<i LOIN'L'Nl ~ LNT CONCL'NTIIATIOI III NAos I~ I (Ii LIATS (Il LIAN YSES TAATION LI AS ~

GC/MS FRACTION VOLATILECOMPOUNDS 1V. Acrolein (107.024I) <100 <182.6 1 ~u/1 lbs 2V. Acrylonitrll~ (107 13-1) <100 <182.6 u /1 lbs 3V. Benzene (71 43.2) <5 <9 ug/1 lbs 4V. 8ls (Chloro. methyl) Ether TESTING AND REPORTIN NOT REQUIRED (542%8.1) 5V. Bromoform (75 25-2) <5 <9 I ~u/I lbs 6V. Carbon Tetrachloride (56-23-6) <5 <9 ug/I lbs 7V. Chlorobenxene (108.90-7) <5 <9 1 ~tt /I lbs BV. Chlorodi. bromomethane (124.48.1 ) <5 <9 ug/1 lbs 9V. Chloroethane (75 00.3) <10 <18 ug/1 lbs 10V. 2.Chloro. ~ thylvlnyl Ether (110.7$ B): <10 <18 ug/1 lbs 11V. Chloroform (61.66-3) <5 <9 ug/1 lbs 12V. Dlchloro. bromomethene (16.21.4 <5 <9 ug/1 lbs 13V. Olchloro-dlfIuoromethane (76.714)) . <5 <9 ug/1 lbs 14V. ],1 Olchloro- ~ thane (76-34.3) <5 <9 ug/1 lbs 15V. 1,2.0ichloro-ethane (101-06.2) <5 <9 ug/1 lbs 16V. 1 I Olchloro. ~ ethylone (75 35 4l <5 <9 ug/1 lbs 17V. 1,2 Oichloro propane (78 87 5) <5 <9 1 ug/1 lbs 18V. 1,3 0ichioro. propyhsae (542 75 6) <5 <9 ug/1 lbs 'l9V. 6 thylbunteno (100 41 4) <5 <9 1 . - ug/1 lbs 20V. Methyl Bromide $ 74-83.9) el,r <10 <18 ug/1 lbs 21V. Methyl Chloride (74.87.3) <10 <18 ug/1 lbs EPA Form 3610-2C PA .CO JE ON PAGE ov. 2-86) I IV~ IL I ~ cPA I D. NUMouR fcuPy from item I of k tI I'I'ALLNUMIILII OAl8 tyu. A'040 ttttWI 001 Approvat aspirer 7 3I 88 I.POLLUTANT .MARK'X'ND 3.EFFLUENT 4. UNITS 5. INTAKE foptloncI~J CAS vA UP C.LDNQ 'r NUMBER I ~ sI IL RL' INV II Rt LIL VS I

e. MAxIMUMDAlLY VALUE o. MAltl M alt 'gtAY /IM gott, vALUE P a. CONCCN.

~ LONG YLRM h, NO.O IL V~ RNII A~ TRATION h. MASS ANAL ltt OacltebtCJ ~ OVHI ~ SNT $ $ HT CONC III C HTR ATION CI) SIASS (RI HA$ ~ I ~ I CONCAIITNATION (Ii HAss IIITRATION CONC ~ H ( ~) IIA$$ YSES GC/MS FRACTION VOLATILECOMPOUNDS fcontinuedl 22 V. Methy lane lbs Chloride p6 09.2) <5 <9 ug/1 23V. 1,1,2,2-Tetra. chloroethane <5 <9 ug/1 lbs (79%44) 24V. Tetrachloro-. ug/1 lbs ethylene ()27tf 6-4) <5 <9 25V. Toluene lbs (1084)s.l)) <5 <9 ug/1 26V. 1,2-Ttans-Dlchloroethylene <5 <9 ug/1 lbs (1 56-604)) 1,1,1-Trl- '7V. chloroethane <5 <9 ug/1 lbs (71.55-6) 28V. 1,1,2-TII. chloroethane (79-00-5) <5 <9 ug/1 lbs 29V. Trlchloco. ~ thylene (79-0 1.6) <5 <9 ug/1 lbs I 30V. Trlchloro-lluoromethane <10 <18 ug/1 lbs PS.69-4) ~ 31V. Vinyl lbs Chloride (15-01 NI) <10 <18 ug/1 GClN(S F R ACT(ON AC D COMPOUNDS IA. 2-Chlorophano lbs (95 57.8) <10 <18 ug/1 2A. 2,4 Dichloro. phenol (120.83.2) <10 <18 ug/1 lbs 3A. 2.4.Dimethyl phenol (105 67-9) ~ <10 <18 ug/1 lbs 4A. 4.6 Dinltro O. lbs Cresol (534.52-1) <10 <18 ug/1 SA. 2.4 Dinitro. lbs phenol (6 (.28 5) <10 <18 ug/1 6A. 2 Nltcophenol (88-1 5.6) X <10 <18 ug/1 lbs 7A. 4 Nltrophenol (100 02.7) <52 <95 ug/1 lbs SA. P.Chloro M. lbs Ceasel (69 50-7) <10 <18 ug/1 9A. Pentachloro- lbs phenol (87.86.5) <52 <95 ug/1 10A. Phenol (108 95 2) <10 <18 ug/1 lbs 11A. 2,4,6 Trl. chlocophenol <10 <18 ug/1 lbs (88 06-2) CONTINUED FROM THE FRONT

1. POLLUTANT Z. MARK 3. EFFLUENT 4. UNITS 5. INTAKE fupriunol)

C.LONG TP/IM ggtIF). VALUE It NO.OF LONG TERM 'X'T AND CAS TT IA ~ I os a. MAXIMUMDAILYVALUE cISVSI D MAXI M 3$ 'gPY VALU e. NUMBER ~ INN ~ I VCI I ANAL e. CONCs:N TRATIO~ II. MASS III CONCHA iiiouoItobtI'I NL OVIN' ANI, TNT \A~~NT III II) MASS III N@ss III II AS ~ YSF.S I N A SION III ISA ~ s ~Q CONTI NTN ATION GC/MS FRACTION BASE/NEUTRAL COMPOUNDS

18. Acensphthene (83 32-9) <10 <18 ug/1 lbs

28. Acenephtyleno lbs (208-96-8) X <10 <18 ug/1

38. Anthracene ug/1 lbs (120.12.7) <10 <18

48. BenzlTIlne lbs (924)7.5) . X <52 <95 ug/1

68. Bonzo (TIJ Anthrocene <10 <18 ug/1 lbs 56-65-3

68. Bonzo.fo) lbs Pyrene (60 324)) <10 <18 ug/1

78. 3.4.8enzo-'uorenthene (205 99-'2) X <10 <18 ug/1 lbs

88. Bonzo (ghi)

Perylene <10 <18 ug/1 lbs (191.24.2

98. Benztt (tr)

F luorenthene <10 <18 ug/1 lbs (207 08-9) I 108. Bls (2 Chforo. ethoxy) Mothene <10 <18 ug/1 lbs (111.91-1 118. Bls (2-Chloro. ethyl) Ether (111NI44) X <10 <18 ug/1 lbs 126. Bis (2 CSorotro-prcp)0 Ether (102 00 I) <10 <18 ug/1 lbs 138. Bls (2.Ethyl. hexyt) Phthslote " X <10 <18 ug/1 lbs (1174) 1-7) 148. 4.8romo-phenylPhenyl Ether (101.55.3) <10 <18 ug/1 lbs 1SB. Butyl Benzyl Phthelete (86 68.7 <10 <18 ug/1 lbs 16$ . Z.Chloro. nophthslene <10 <18 ug/1 lbs (91.58 7) 178. 4 Chloro-phenylPhenyl Ether (7005-72.3) <10 <18 ug/1 lbs 188. Chrysene (218.01.9) <10 <18 ug/1 lbs 198. Dlbenzo (o, Anthrscone (63 70-3) <10 <18 ug/1 lbs 1.2 (3I hio(~ '0S. benzene (95-50.1) <10 <18 ug/1 lbs 218. 1,3 Dlchloro. benzene (641-73.1 <10 <18 ug/1 lbs PA ON PAGE 1 EPA Form 3S10-2 2-86) I <>>>>I >It>I>I<>v<>>r CPA t.o. NtIMDER (coPy from Item I of outfALLNUMuER OIII8 Na. 2040 0086 CONTINUED FROIT< E V4) 001 Appr<wal aspires 7>>31 88

1. POLLUTANT Z. MARK 'X' 3. EFFLUENT 4. UNITS 5 INTAKE f>>prinnalf ANO CAS VAt LIE NUMBER T~ s> IL ~ L ~ c ~ L' a MAXIMtIMtsAtt Y V*Ltsg b. MAXIM M Sa gpy VALUE C LONG TPPN gott ~

<t NO OP a ~R~f<(rl.ONG TCRM I> NO.O 4 NL>>N< >LVS< L<LVL< AA ANAL. a.7 CONCtiN RATION I>. MASS A N >S l. tlf a<>a>labl>'I 44>A" SLNT ~ TNT C <> I<l N C N T>> A T D N ~ > II) MASS IT) M>>ss <. ~ >NC I~ I L NTN>> T>DN I>ss YSSS I<l cDNC< TN AT>DN N I~ I YSS.S Q GC/MS FRACTION BASE/NEUTRAL COMPOUNDS (continued'28. 1,4 Dichloro. bonzene (106.46 7 <10 (18 ug/1 lbs 238. 3,3'-Dichloro benz)dine (91.94.1) <52 <95 ug/1 lb6 248. Diethyl Phthslste (8466-2) <10 <18 ug/1 lbs 268. Dimethyl Phthslste (131.11-3) <10 <18 ug/1 lbs 268. DI-N.Butyl Phthslsto (84.74 2) <10 <18 ug/1 lbs 278. 2,4-0irdts. toluene (121-14.'2) <10 <18 ug/1 lb 6 268. 2,6 Dinitco-toluene (606 20 2l <10 <18 ug/1 lbs 298. DI.N-Octyl Phthslste (1174)40) X <10 <18 ug/1 lbs 308. 1,2 Diphenyl. hydrazine fas Azo. <52 <95 ug/1 lbB bsarch e) (122-66-7 318. F luoronthone (206 44-0) <10 <18 ug/1 lbs 328. Fluorona (86-73 ZI <10 <18 ug/1 lbs 338. Hezscnbr 819.7L.tl <10 <18 ug/1 lbs 348. Mexa-chlorobutsdlene (87.684) <10 <18 ug/1 lb6 358. Hexochloro-cyclopentsdleno <10 <18 ug/1 lbs (77 47NI) 368. Mexschloro. stheno (67-72-1) <10 <18 ug/1 lbs 378. Indeno ff,2, J.cd) Pyrene (193<9%) <10 <18 ug/1 1bs 388. Ilophorone (78.59-1) <10 <18 ug/1 lbs 398. Naphthalene (91.20-3) (10 <18 'g/1 lb8 408. Nttrobenzene lbs (98.95 3) X <10 <18 ug/1 418. N-Nltro-sodlmethylsmlne (10 <18 ug/l lbs (62-75 9) 428. N.N ltrosodl. N4<ropylsmtns <10 <18 ug/1 lb8 621.64.7 P4 Fnr<TL %61ft Ot IR>>- n nr< CONTINUED FROM THE FRONT

1. POLLUTANT 2. MARK 'X' 3. EFFLUENT= 4. UNITS 5. INTAKE ioprioucli AND CAS NUMBER I sl IL ss c sc

~ IN I~ VC ~ ISVL ~

e. MAXIMUMOAII Y VALUE C.LoNo TRIM

)gal fi. vALUE d ' CONCLN II. MASS 0 LONG TERM I iiieverlabh I HL ouIS'sNT AHL AO III A TISH LSHT C OHC L NTN !s) NAss I~ ) II) Hrrss I~ ) I ~ ) HALL .YSES yRATION I ) CONC%M ~ )I) IIAss YSES CONL ~ I TNATION C TINCT N Ter A THIN TN A TISH GC /MS F R ACTION BASE/NEUTRAL COMPOUNDS icon tinu ed) 438. N Nltro-sodlphenylamlne (86 30%) X <10 <18 ug/1 lbs 448. Phenenthrene f85-014)) <10 <18 ug/1 lbs 468. Pyrene (129.00.0) er X <10 <18 ug/1 lbs 468. 1,2, 0 Trl. chtorobensqne (1204)2.1 ~ <10 <18 Ibs GCIMS FRACTION - PESTICIDE 1P. Aldrln (309 00.2) 2P. Q.BHC (319.84-6) 3P. P-BHC (319-86 7) 4P. 7.8HC (58 89.9) 5P. () BHCI . (319 BB-W 6P. Chtordepe (57-74 9) . X 7P. 4,4'.ODT (60-29-3) BP. 4.4'OE (72 S5.9) 'P. 4,4'-DO D (72-64.8) 10P. Dletdttn (6067.)f 1 .. X 11P. II.Endosulfan (115 29 7) I 12P. P Endosu)fen (115-29.7) 13P. Endosulfan Sulfate X () 03)4)74)) 14P: Ends tn (72.204) ) X 16P. Endrin Aldehyde X (7421 93 4) 16P. Heptechlor (76.444)) EPA Form 3610- v. 2-BS) .8 CO ON PAGE 1 FOTTTI Appruvcd KpA t.D. NUM06R (cop)l from (tern 3 of Form l) DUTPALL NUMoBR OM8 No. 2040 0086 CONTINUED FROM PAGE V.B Appruval es pircs Z.3l 88 001 !. POLLUTANT 3. MARK 'X AND CAS

3. Ef fLULNT 4. UNITS 5. INTAKf (<<pl<<<<Ivll NUMBER a ~ ~

IN T~ ~ II. NI ~ C Ns ~ e. I ~ ua v ~ TVTI f. MAXIMUMDAILYVALUE b. MAXIMItM3g gP Y VALUE C.LONG TPPM g$ P VALUF II NO.OF e,CONCCN ANAL TRATION b MAS5 a I.ONG tCRM 6 YfJIB(c h)ILB II rIO.Or Att AI NI TI~ I Aa lt( u IvIlubl<'l I<<IIN SSN ~ SANT I I ~ CONC I ITTNA' IuN (Tl <<Ass I I ~ CONT ~ NINA~ NIN IT) NAss OONCAN ~ NATIIIN ITI IIAbv YSFS II I T 0 Nc T N TNATION III NA ~I Y5e5 GC(MS F RACTION PESTICIDES (cont(nnecf) 11P. Hcptachtor Eqo'xlde ( I024 51.3) 18P. PCB.1242 (53469.21 9) 19P. PCB.1254 (11091 69.1) 20P. PCB-1221 (11104 28.2) 2'IP. PCB 1232 (11141 16.5) X 22P. PCB 1248 (12612.29.6) 23P. PCB 1260 (I )099.82 5) 24P. PCB 1016 (12614 11.21 X 25P. Toxaq)Iene (8001.35 2) PAGP. V-9 'tt Fnrm BBT1(t-'Pt. IRP II-RBII CAPE FEAR STEAM ELECTRIC PLANT SAMPLER 42 NARRATIVE DESCRIFHON OF STORM WATER OUTFALLS There are four outfalls associated with storm water runoff f'rom areas of industrial activity at the Cape Fear Plant. Outfall 1 is the termination of the Plant's discharge canal at the south end of the facility and includes virtually all storm water runoff from active industrial areas of the site, as well as all process wastes, including condenser cooling water when the plant is operating. In accordance with North Carolina regulations, the waters of the state begin just below the weir at this outfall. The two active ash ponds for this facility, which receive,and treat much of the storm water from the industrial areas, discharge by overflow stand pipes into the discharge canal upstream of this outfall. The following areas associated with industrial activity are drained by this outfall: a) Ae main plant yard, including generating units and boilers, administrative buildings and parking lots, material storage areas, including the coal pile, and service facilities such as machine shops and vehicle maintenance areas are all within a diked area for protection Rom Qooding of the river. All areas within these dikes are drained to sumps where storm water and other low volume plant wastes are pumped to one of the two ash ponds. These ponds provide considerable retention time and treatment. b} Plant yards outside the diked areas, including cooling towers (used seasonally) and railroad tracks used for coal transportation. Most of these areas drain to the discharge canal by overland flow or grassed swales. Outfall 2 is at the southwest corner of the site and is used only to provide severe weather drainage f'rom an abandoned ash pond. There is a small pool of approximately 2 acres of standing water in this pond but due to evaporation and infiltration, the normal pool level is several feet below the crest of the discharge stand pipe. The pond has probably not discharged for several years and did not discharge during the period when sampling was done for this application. Outfall 3 drains a small area of the site that discharges via a swale to a stream. The only industrial activity in this area is a portion of railroad tracks that carry coal cars. No loading or unloading of coal takes place in this area. The area is mostly grass and gravel rail bed, and a measurable runoff was not observed during the sampling period. Outfall 4 is the discharge from an ash pond that was abandoned many (20+) years ago. The area is covered with grass and trees and is surrounded by a dike. The crest of the standpipe outlet structure is more than one foot above the ground surface, and there is no standing water. A storm in excess of 12 inches would be required to produce a discharge, and no measurable discharge was observed for this outfall. 'PA IO Number (copy from hem I ol Form It SMtPLER lr'2 CAPE PEAR PLAi Continued from Pace 2 A.B,C, E, O: See instrucuons before oroceeoing. Complete one set ot tables for eacn outfall. Annotate tne outfall number in the soace provided. Tables vll A. Vll B. ana Vll C are included on seoarate sheets numbered vll 1 ana vll-2. ~ E: potenual discnaraes not covered by analysis - Is any pollutant listed in Table 2F 2 a substance or a component at a suostance wnch you cunenuy use or manuiacture as an intermeaiate or tmal proauct or byproauct? i fil Yes llisr all such bollutanis oelowl W No (aatoSecrionNI Antimony Mercury Arsenic Nickel Beryllium Selenium Cadimum Silver Chroniun Thallium Lead Zinc Copper Qa yau nave any anowiedge ar reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? W Yea (liSt all SuCh ballutanrS belawi W No ( ataSecrlonlle Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? I + Yes (list the name, address, and telephone number of, and polluranrs + No (gotoSecdontg B. Address C. Area Code 8 Phone No. O. Pollutants Anahrred Webb Technical Group, Inc. 4320 Delta Lake Dr. (919) 787-9171 Total Kj.eldahl N Raleigh, NC 27612 l certify under penalty of law that this document and all artachments were prepared under my direcrion or supervision in accordance with a sysrem designed to assure that qualified personnel properly garher and evaluate theinformation submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible lor garhering the informarion, the informarion submirred is, to the besr of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting lalse information, including the possibility of fine and imprisonment for knowing violations. Name 8 Olliciar Title (gee or pnml B.Area Code ana phone No. George J. Oliver Manager, Environmental Services (919) 546-4189 C. Signature Page 3 at 3 2F-3 (I ~ ~ ~ I ' l ~ ~ ~ ~ ~ f ~ ~ ~ ~ 0 ~ ~ ~ ~ ~ ~ II ~ ~ ~ ~ ~ ~ ~ I ~ II ~ 'I O I ~ ~ ~ ~ I ~ ~ . ~ ~ ~ ~ OI ~ ~ ' part C ~ Ust each ooeutant snown in Tables 2F 2. 2F.3, ana 2F< that you <<now or nave re<<ac.i io oeiie~ ii ~. eaaitronai octans ana reauuements. Complete one table tor eacn outtall. Maumurn vauee Average Values Number i l i Pollutam (include uncsl (inctucte I ot uncs'rab 9 ana Grab Samoie Samoi ~ Storm i Taken Outing Taken Our ing CAS Number First 30 Fiowwreigntea First 30 Flow~ighted Events l (i( svalaor el Minutes Combosne Minutes Combosne S areal Sources of Pollutsms Color 80 cbu I 90 cbu I I I Coal and ash Sulfate 'ee data lin Section I VIIB I i Coal and ash Al 1400 ue/1 I790 ug/1 I I Fe 1.3 n /1 1.0 mg/1 I I Coa 1 and as Cu 20 ug/1 I 22 ug/1 I ICoa and as As See data I in Section I VXIB l I' C<I I See data I in Section I VIIB Cr I See data I in Section I VXIB I See data I in Section I VIIB Chlorine,TRI See data in Section I VERB Part 0 ~ Provide data for the storm eventlsl which resulted in the maximum vUues for the flaw weiahtect comoosne samoie.

l. 2. 3. 4. 5. 6. T. 6.

Date at Ourauon Total fantail Number of hours between Maxunum floe rate Total flow from Season Form ot Storm of Storm beginning ot storm mess. during ran event ran event during starm event ufed arid end Of previous (gaf(onslmintce or (gallons or sampie was t (rain(arl, Event (in minuresl (in incnesl measurable rain event soecr(V uncs soecA'ncst taken snowmecr /23/ 240 0.35 200 59.5 HGD Vinter Rain or 41<320 gal/ 2x10 min gallons >>ovine a aescriohon ot the meinoa of flow measurement or estimate. Plant cooling water punps were operating at tine of sampling, providing flow of 41,000 gallons in discharge canal at outfall weir. Any contribution of this storm to that flow would not be measurable. Flow rates given are from pump rating curves. Total flow from rain event based on total rainfall and U.S. Soil Conservation Service runoff estimation techniques (USSCS Field JIanual). EPA Form 3510-2F (11.901 Page v<<2 ZF-5 Key poets DiSCHACCC ~ 'ic+ Drainage Area e Boundary etc PcscsO 00t CSi tD Sewer Line /1 ~V ,~/ ~lt csltCO04CC CDSCS Do J pedro >S~RSC ~ 0 sere>t'Stt p3ND 0 0 0 c&le 0 P$ 0 0 cwcco QsCADOOX Qttb IC &AC PK C I D,SCWCCC 000~ evl Coc4~C. ~ CctteJTi~ tSA P04> pssbccct'4E \ ~ 88gccycccs btS Po Atts Sstc ltb4<bocrab S OS/45tcs Fb) t))c A 0 ps tttkc'P DM<ts t.4 StS fc PkdcPc ts To 0 PcalTsS 0 ~ wTAKC 4 5t04ctucC CAP a. <<A< ,.ca CAROLINAPOWER & LIGHTCO. CAPE FEAR STEAM ELECTRIC PLANT Storm Water Group Application No. 286 Sampler No. 2 altair of int or Ivor ln Inr llnlnsoso sf sat oav Form ApprovwL OIJS No. 20t0408S. Approval estates S4I4I2. fhlf sn rfrffrfr IOKrffrof rflfr Ivor. ar.. 12chaffcrtffnncff J. 5 lf s CNVINONIACNTAI PIOTCCTION A4CNC'r I. KFA IJL NUMSSR GENERAL INFORMATION ..., iSEPA ~ ~ ~ ~ CfvuoJNatsfr A nenes Jffaffwn F D IRroc fffr "cfnrfof Jnffnfrnono" arrofo ~ Infant.f AL lna I IONS I. KFA I.O. NUMSKR ll e ofaonnwd Ides Iws bean orowdNL atfbl it In the osntnecad ntece. Review Iha olfofm. ation cafetuay: it any ol it is inconect. crow III. FAclLITYNAatc approonate tia-tn ~ Ihfouen i! snd enter dw correct dots in dw behnt. A4o,JI any ot dw praonnted dsw ls absent lthe arm <<5 dw ' ACIL,ITY Irft of the Jahsf eadw JJJra the Jafofnasttafs AIL IN 6 A 0 OR Spa, EASE PLACE that ehxftd aooearJ, places ofoytta it In tiw proper fili~ sfeerJJ below. It the label ls l ~cofnoww snd corrects you Iwad not ooffessw items l. Ul. v. snd't rouwN vr.s nnfta W cewetswd JsseMatst. Contacts SN F AC'ILITY herse if no label hes assn prowdsf1 Refer to 'OCATION the heenscthma for dswilsd Itamodecato. tksw oad tor ths Ised.autholiletlona under. wh~dete lscoascted. I L FOLLUTANTCIIARIecyshlsTlcs ~-"yse" IffyRUCTIOIIR Ceaolee A thtertyk J to dstetaha atfteoer yea steed ta eabatie aay parfait NI04cetiea fatate&Os EPA If you fQQQINNtL you Itlutt sdbttdt sf'ptta ~ ~ tbs tttppfi~g fetla llwd Ia ths patsattlle foiatabss tbs tetttatL delft "If"bt the bps ia tba olgti softpaa ~-"pa" m ts eay ~ , If the atpptstnectetfotat Is etseoed. If yea e ecch cteetiitL yea peed aet atbtafe af these fottaL Yoa tcey "no If your ectitity is excfuded froth ptttsit tetptieaeatcm Sectisa I: pf the btsaactiea Se eistL Qctiaa 0 of tba lattntctiota for dsfinltkea af be~seal tetaN. spccfpfa avcsytone ~~~ ~ Yon no Yas ~ on A II 0 A&II WSW~'~~l wnfch rafufa nl a ftiaataeee to ~aooa ahe~t I, <oats~ auna dds taoNity fsAaet ecafonp or p~cJ ~ aeede INHNI waalaa &edesssan fasaau wrcst felufts ul e oF arran n IFORM 1AI caeaheree so et dw US2 IFORM 2$ ) 4 a Iacllllv wflKn cuffanllv fwants ln XI ~ ~ ne alar mow IO Waters ol the LLL odwr Iiwn Vwae Oeacnhad CI hr Je or d effoleJ wtdctt wta Iseult Ifl ~ dboharee to A Of atfoYat F M F. Oo you or wHI you Iniact et thft taoiity indutufsl or g, Qost or wlu Ihit lacili\v treat, store, Or dbpsaa ol munlcfpel effhtsnt asatw dw lowsnnast toetum can hacerdous wenwt IFORM 3I talldnsf within ofw Quarter IIule ot tlw waN bore~ X  ! Icctarpround etwas ot drlntdneawtsrt IFORM CI 4 vou of lwl Toll Infect ~ ls ocl walsf of othsf fluids whfcrl afe bausllt eatlw surface tf. oo you or wNI you infect ct this tecNIty fluids for Nw. ih cofuwcuon with oofwenfonwl oll or natural esa pnp cist pracawsa such os mifdne of efifur by tiw fesdl ptooees, eoMIOI <<dfdnp ot mhwnda, In situ coneus. f ducdon, inject fluids~ Aor enhanced tecoeafy wt ~ ~,thta ot toads tuaL or reaoeery ot seodmnwt enargyt od or natural eaL m IAWct thdds for eaereeeoLtkssid fFORSS dl n I IFOflM41 5 4 IIV e e swee wfllcn 4 one ot the 28 iffduanai ceasesnee Nwadln <<>> fn-Ifuucfont snd which wiN oacantwny <<on 'IOO tons psr yasr ot any ~ ff poihcana Ieeuwswt Ntsh ~ Caen Alf Act and nwy effect.ar be4oaaasd in <<5 wmt IFOIIMet.. ~ ths NOT one of the 2S lAdudrisf Catepaftas Iktsd in the InstllsCChxw end whhh will ptentisliy emit 2SO tons psr year ot eny ea txdhxant fesuhgsd under trw clash " Air"Act end Ioay effect at bs kxetat in en ettahutwnt creat IFOftMSt IIL NAMS OF FACII.ITY I sxf ~ i H.B. ROBINSON STEAM ELECTFIC PLANT IV. FACILITYCONTACT A NAlnc 4 TITLc INft Rfvt, 4 IIIlfI ~ i PNONC ferro coot O no.f 2 G.J. OLIVER  ? [GR. ENV VI E 6 I V. FACILITYMAILINGAOORSSS A, STIccT on p.o. Cox P.O. BOX 1551 e clTY on TowN C STAT O. CIP COOC 4 I H 2 0 f Vl. ACILITYI.OCATION A, STICCT, IOVTC NO. OI OTNCI SPCCIPIC IOCNTIPICI HUNTSVILLE SC HIGHWAY 151 + 23 BOX 790 ~ COVIIYY NANC ~ ~ ~ ~ I 1 D RLIVGTOV C. CITY an TOWN 0 STATCI c, zip coot I f 6I IISC ~ 29550 SPA Form 35IO I le 90l CONTINut ON RSVSRSS CONTINUEO PROM THE FRONT Vll. SIC COOES /4%itic. In orotr ot ononryr A. rlntT ~. stcOHcr /Spttlf)V 7 4911. I ELECTRIC POWER SERVICES C, THINO 0, rOUN'TH (ISPCCI/)'/ /SPCCI))'/ 7 ~ ~ Vill.OPERATOR INFORMATION A, HAaet Is cno nemo liecao Ill C 1 1 ~ ~ I cern owner) V III'HN 8 CAROLINA POWER & LIGHT COHPANY KXYES i NO ee

c. $ TATU% or opt NAvoN /EsNt rst eppropnect scrrcr Itlfo lst ensartt oos 'f "Orner", spfctf)',) CI PHont Ieicn coot 1 no.l n /ociatt csea /trlerol or react). ISPtCI f)')

S 0 STATE 0 n OTHER /rpttc/p) p 919 546 41 9 P r PRIVATE ~1 '1 r ~~ ~ ~ 4 STNCCT oN r.cr nore .O. 0 551 ra 1.r 1

r. ccw cr N Tow a ILSTA ir. acr coot IX.

1 Ia Oao iaceICC locacao on Inoian Ianosr B RALEIGH NC 27602 Cl YES Zg NO sa I~ la a ri <<1 a ~ H X. EXISTINQ ENVIRONMENTALFeruNT>> A. H Pc) to locrcnerrtt ro anlareo Weetlr r ~ -1 9NI I 6 SC LANDFILL PERtKT ~. Ulc I uslsclrloosct /slccrfon of Hwds) t oTHtN rcptcrp7) 0820-0002 SC STATE PEIQIIT FOR OPE ATION OF UNIT BOILER + PRECIP TC c rccNA I//eseroooe wereass 4 DTHCN iNON/) / 1 9 A 9' . -195 ~ 1 ~ 1~ ~ ~ ~ ~ ~ ~ XL MAP the outline of the facHity, the locedors of ecch:of.ifoeeded>>send proposed intake end dischergesttmnaes, each of its hazardous e/est>> treatment, storage, or disposai facBitfse,~each>>edf~ it ~I%ddt.undec~end.'ndude eN springs; rieers end other surface water bodies in the met) area. See uaut)cdortefot XII. NATURE OF BUSlhlESS /protsrt pano/ Orat~ ELECTRIC UTILITY XIII.CERTIFICATION /sto OHcrucciost/ I cert) fy under penalty of Iarp d)et I here pe/ate)aVy ex<<rrinedand <<rr f<<ndfst reisfpthe Inforrnationasbnritted ln this eppIicat attacfrments and that, based on my ~ter those peaoow for ob~ tf)e Inforn)stion confined In the application, I brrliere that the Infonnadorr is trt/w, acctwate and crt))t)fst>>, I <<n aver@ that there<<>> signific<<)t penalties for submittIng falseinfonnr lion, induding tha possibility of fine and Imp/iso/er)<<IC, A. HAarc 4 ol ticiAa. viva.t/rypcor pnnr) oe al4H AvU II t C OAVt Si IIC4 GEORGE J. OLIVER KsaNAGER - ENVIROAIEtiTAL SERVICES ~/w/F~ COMMENTS FOR OFFICIAL USE ONLY C C EPA Form 3510.1 \9 90) ~ match line sheet 2 PIPIEEINE ~I ~I p nn P+ S Oischarge Cava) ~P PS SS Vhvg 's ( si' h I Ash pond 4I gsO' 4 'I ?i4. pcs o I c I I .;:~ ~ ~ SI ~ TIP lcrncp c', ~ <4 41 rl h ~ ~ ~ ' 'nv ci; / ~ 74 ':' P S PP44 s / ~'wecplnnc,. lJ ss r urn ~ ~ PPS V ~ ISS ., -."~ OUTFALL. '002 4P ~4 ~ ~ ~ ~ '4 ~ ~ ~ ~1 I/ ~ 44 'i4 r P~ ~h I 's E! II ~ 4 s w  ! Ii' ' pv Is 'o4+~II P ~ ' ~ I." P'-.; ' ! .. An csoc Isr ~ ' ~ I ~J ' ~ P ,o/ ~ ~~ ~ ) I~ ' ~ P 4 o-., P P EBII s r a. ~ Sh~ I ~ ~ ( I ~ ~~ I ~ I PPPP vrcnr44 Q .--" r~~r 10'I!8 LAKE ROBINSON, S. C. II4rr. .Isoor.srr.s P ~~'~)P . H. B. ROBINSOI'I STEAll ELECTRIC PLANT l968 CQ., S. C. '-,>~C',OARLINGTOli sheet 1 of 2 ~ ~55 'L ~v 'i (I ) ~ 'r, it.- -,,~ 7' h gee. ~ r j I J>5 OUTFALL QOj d50 ~ . ~ r j r r ~ ~ d ~ ~ i ~ d  %~ 5 N C Oischarge CanaI 'match 1ine sheet ] '. SCALE 1:24000 0 'i lOCO 0 l 000 %00 !000 d000 !000 SXO 1000 ftET CAROLINA POWER ANO LIGHT CO I NLOKDKR ROBINSON STEAM ELECTRIC PLANT CONTOUR INTERVAL 10 FEET OARLINGTON CO., S. C. OATUM IS MEAN SEA LEVEL 'heet 2 of 2 l'Cfit> V>PPfOVed. cpA I.o. NUMBER>copy lrom Item I ol I orm II OiAB hto, 204OMBB Please onnt or tvoe in the unshaded areas onlv. Applovel ceo>les 7CI WB FORM U,s CNv>RGNMSNTAL FRGTscTIGN AGSNcv ' APPLICATION FOR PERMIT TO OLSCHARGE WASTEWATER NPDES ~%EPA- EXISTING MANUFACTURING,COMMERCIAL,MININGANO SILVICULTURALOPERATIONS l Consolidated Perlnirs Program I. OUTFALL LOCATiON For each outfall. list the latitude and longitude of ils location to the nearest 15 seconds and the name of the recesvinq water. A. A O. LATITUOC C. I ONGITUOC NUMSCR o, RccclvING w*TER (>u>ttlcl >lbfl t, sett> I t ecc 001 34 27 30 80 09 45 LAKE ROBINSON 002 34 24 00 80 09 07 BLACK CREEK II. FLOWS. SOURCES OF POLLUTION, ANO TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate sources of Intake water, operations contributing wastewater to the effluent, and treatment units labeled to correspond to the more detailed descriptions in Item 8. Construct a water balance on the line drawing by showing average flows between intakas, operations, treaunent units, and outfalls. If a water balance cannot be determined (alt, forcerraln mining acdrldesl, provide a pictorial descnption of the nature and amount of any sources of water end any collection or treatment measures.-r 8, For each outfall, provide a description of: Ill All operations contributing wastewater to the effluent, lnduding process wastewater, sanitary wastewater, cooling water, and storm water runoff; (2) The average flow contributed by each operation; and I31 The treatment received by the wastewater. Continue on additional sheets lf necessaly. I~UT 2. OI CRATIONISI CONTRIBUTING FLOW 2.TRCATMSNT FALI N Ill>I) c, OPCRATION IIIIII AVCRAGC FLOW llnclude un>Ie> ~. OCSCRIPTION', I IST COOKS FROM TASI C 2C.I ONCE-THRU COOLING MATER 820 HGD EVAPORATION I DXSCIIARGE TO 1F 4A SURFACE MATER 001 COAL PILE RUNOFF SEDIIKNTATXON 1U ASH SLUICE MATER 0 SEDIHENTATXONs OXIDATION 1U 2B CHEN. HETAL CLEANING WASTES 75,000 gal/eve t NEUTRALIZATION, PRECIPITATE N 2K 2C SANITARY WASTES 42.5 GPD SEDXIKNTATXONs ACTIVATED 1U 3A SLUDGE DISINFECTION, DISCHAR E 4A 2F TO SURFACE HATERS LOW VOLUME WASTES 30 gpm NEUTRALIZATION 2K RADMASTE LOM VOL'BK 8000 GPD ION EXCHANGE, EVAPORATIONs 2J DISCHARGE TO SURFACE WATERS 4A 002 SANITARY WASTES 15,000 GPD ACTIVATED SLUDGE, SEDI?KNTA-'U 3A TION, DISINFECTIONs DISCHAPGE 4A 2F TO SURFACE WATERS LOW VOL'tBK WASTES 0 30 HGD NEUTRALIZATION, SEDDKNTATIO> I 2K 1U OXL/WATER SEPARATION STORI1 WATER RUNOFF 0.11 HGD SEDDKNTATION INTAKE SCREEN MAS11 WATER 300 GPD DXSCHARGE TO SURFACE MATER 4A oFF tc>AL Usa oteLv Iernucnl cu>ucl>t>ee eundo>ceo>Ice> 3510-2C PAI-P I nC ONTINUED FROIVt I Nb PNuiV I ~Yes (comp(etc the folloie(ng table) ~ '...,';-,,~

.Except for storm runoff, leaks, or spills, are any of the discharges described in Items II A or 8 intermittent or teste."..if No rgo ro Section IIII "4 FLOW 3.FREQUENCY

e. FLOW RATC IL TOTAi VOL VMC

..OUTFA Ll 2. OPERATION(gJ e, DAYs b. MDNTHS (Ill mgdJ "(rpcclfy ullth unircl c. DU NUMBER CONTRIBUTING Fl'OW ~ 'PtrsWCCK'CR YtAR ATi (rpccify (rpccffy ~, I onv TOOM 4 MAIIIMvM I l.oN4 TOOM 4 MAAIMOM (llsrl flight/ aecrcgci avcrcgcI >><<AOc (I da 001 INTAKE SCREEN WASH 12 0.04 0.1 NA NA 0.02 002 RADWASTES 12 0.086 0.086 8000 10,000 0.1 gal gal 002 CHEMICAL IKTAL CLEANING ONCE VERY 5- YEARS, 75,000 GAL. E H EVENT v e ~ III. PRODUCTION A, Does an eRluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility) KXYCS (comp(etc Item IIIBI ~ND Ro io Section IV)

8. Ate the liinitations in the applicsbls effluent guideline expressed in terms of producuon (or other measure oi'persrionl I Q vcs (complete Item-III Cl- .-QN o (go ro Sec((on IVI k~ Am C. Ifyou answered "yes" to Item ill-8, list the quantity which represents an actual measurement of your level of production. expressed in the termsandunils used m the applicable effluent guideline, and indicate the affected oudalls.

1. AVERAGE DAILYPRODUCTION s. ArrccTSD C, OTCNATIONo YNOOVCT, MATCAIAh ATC, OUTFAI LS 4VANTITY YON OAY b, VNITT OY MOATVIla (flitoutfall numbcreI (rpcc(fyl IV. IMPROVEMENTS A. Are you now required by any Federal, State. or local authority to meet any implementauon schedule for the construction, upgrading or operation of waste.

water ireaiinent equipment or pracuces or any other environmental programs which may affect the discharges described in this applicationt This includes, but is not limited to, permit conditions, adminittrativsor enforcement orders, enforcement coinpliance schedule lenert, ttipulationL court orders, and grant + YCS (compicrc the foliole(ng rabici No (go ro Item IV.BI 4 FINALcorn

t. tDCNTtt icATiorc or coND(TtoN, S, Al FCCTCD OUTFALLS s, $ Rltr DcscRipTioN or FRosccT CC AORCCMCNTo CTC ~ .No b.covncc oc oiccNA444 ~ II4 b, ANO OIIINOO TACT\4

8. QpTloNAL: You mav anacn aaditional sheets describing any additional water pollution control programs.(or orfier environmental proiecrg which mcy ciyccr your dischersesi you now have underway or which you plan. Indicate whether each program is now unaerway or plannea, ana indicate your actual or ir plannea Schedulet fer ccmtfucticn. @MARK "XN DCsCRIPTioN DF ADDiTIONALCDNTROL PROCRAMS is ATTACNCD EPA Form 3510-2C (Rev. 2.85) PAGE 2 Of 4 CONTINUE ON PAGE 3

Farm Aooroveo. [apA l.a. rsUNssRtcoptr tram item I ot I orm li I QiM8 lya. 20404088 I Aptirovet cholres 1.3I <8 CONTINUED FROM PAGE 2 ) V. INTAKE ANO EFFLUENT CHARACTERISTICS I A, 8, Si C: See - instructions oerore oroceeoinq Comoiete one set or taoles tor eacn ounall Annotate tne outtall numoer m tne space orovioed. ~ ROTE: Tables V.A. V.8. ano v.C are included on seoarate enacts numoered v.l througn VH. o, Use tne soace oeiow to list anv oi tne ooilutants listed in Table 2c 3 of the instructions. wnicn vou Know or nave reason to oeheve is oiscnarrted or may o oiscnaraeo rrorn anv outsail. For every ooiiutant vau list, bristly oescrioe tne reasons vou oeheve it to oe present ano reoort any analytical data in you oossession. ~ POLLUTANT S.SDURCS i POLLUTAriT I 2.5OURCC ASBESTOS USED IN INSIILATION, TRACE AIIOUNTS ifAY BE NASHED DOMN DRAINS id PLANT AREA 'DURING ~iIAINTENANCE ACTIVITIES VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS is any pollutant hated in item v-Ca suosta neo or s component of a substance wnicn you currently usa or manufacture as an intermediate or tmal product or byproduct) ~as Iiur all such polluranre eeloia> +leo rgo lo Item vf BI IMONY ENIC ERYLLIUM ADMIUiI ROMIUiI OPPER EAD IERCURY NICKEL ELEiNIUSI ELVER LLIUiI INC EPA Farm 3610.2C IRev. 2.851 PACsg 3 OF 4 CONTINUE ON REVERSE I ~ uIUI trIel4HI I VAI4ll ~ I an ~ nrQ Mslh 3o you nave anv xnowieuge Or reason ta believe that any oioiogicaL tate tor acute or cnromc toxICIty haa been maoa on anV of Your oiscnargaa or on a ~ngwarer m raianonto yourdfschargessfthhrtbirfasc3;ycatat-4n vcc ttdenrffy the reetret and deecnbe rhetrourpoeee befoIer' WHO rao to Section Vfttf 48-HOUR ACUTE TEST USING Ceriodaohnia dubia WAS FEPZOIQED AT BOTH OUTFALLS IN JULY 1990. THIS TEST WAS A j~HJLTI-DILUTION SERIES TESTING FIVE EFFLUENT CONCENTRATIONS AGAINST A, CONTROL (Oio EFFLUENT) USING A DILUTION FACTOR OF 0.5. THE LC50 WAS GREATER THAN 99% EFFLUENT IN BOTH TESTS. 'III.CONTRACTANALYSIS INFORMATION Were anv af the anaivtas reported in Item V oarformeo by a contract laboratory or consulting firmf vcc filet the name. address. and telephone number of. and pollutants @ rIO ICO tO Seatfan fX) IKBI anaiysed by. each swn laboratory or linn betoiei A. IeAMC 6 Aooncsa A iaeeacode er no.i itQt WEBB TECHNICAL GROUP, INC. 4320 DELTA LAKE DRIVE (919) 787-9171 ACID EXTRACTSr RALEIGH, NC 27612 BASE/NEUTRAL EXTRACTABLES, VOLATILE ORGANICS, TOTAL CYANIDE, DIOXIN, PHENOLSr NITRATE-NITRITE N, TOTAL N, TOTAL KJELDAHL N IX. CERTIFICATION l certify under oenalty of law that this document and all attachments ware prepared under my direction or suparvisionin accordance with a system designadto > assure thar qualified personnel properly gather and evaluate theinformation submirted. Based onmyinquiry of the person or persons who manage the system or 'hose persons directly responsible for garhering rhainformarion. thainfarmationsubmnradis. to thebasr ofmyknowledgeandbelief true. accurate. and compfata .'m aware tnat there are signrlicant panaltias lor submirting false information including the possibility of fine andimpnsonmant for knowing violations.

• . NAMc 4k oeeicIAI TITI.C iivpe or prinII 6. eIIoivc eio. iarea coae a na.i GEORGE J. OLIVER, ~fGR ENVIRON1KNTAL SERVICES (919) 546-4189

o. oATC siorico e/m/gg F PA Form 3510-2C f Rev. 2-86) PAGE 4 OF 4

L EVAPORATION LAKE A FIRE WATER MISC. ASH DRAINS HANDUNG ASH POND ROBINSON SYSTEM SYSTEM F CHEMICAL METALCLN. LAKE WASTES INFILTRATION UNIT 1 ROBINSON CONDENSER COAL PILE RUNOFF UNIT 1 WELLS - LOW VOLUME INFILTRATION SOURCES OUTFALL RAINFALL X 001 SERV. WATER SYSTEM HEAT RUNDFF DRAINS DISCHARGE CANAL ROBINSON EXCHANGER LAKE UNIT 2 SLUDGE ROBINSON CONDENSER R (coNTRACTJ D ONTAMINATED RAINFALL METALCLN. RUNOFF SANITARY WELLS MAKE UP WATER TREATMENT NEUTRAL. TANKS WASTES SOUD I TREATMENT PLANTS 1&2 WASTES PLANT RADWASTE DRAINS I PRIMARY 8 UNIT 2 TREATMENT FROM SECONDARY LOW VOLUME T H SEE NOTE 1 SANITARY SYSTEMS SOURCES SYSTEMS SLUDGE <coNTRAGT)~ SANITARY UNIT 2 UNIT 1 COUNTY TREATMENT GROUND ~ RETENTION RETENTION POTABLE SANITARY PLANT k3 wATER WATER WATER POND POND WATER OUTFALL SYSTEM SYSTEM SYSTEM R W U BLACK CREEK TO SANITARY YARD RAINFALL INTAKE PLANTS 1 a 2 RUNOFF SCREEN DRAINS WASH V NOTE 1. Flow to retention pond is normally

• Regeneration wastes from SCHEMATIC OF WATER FLOW unit specific. However, flow from ion exchange CAROLINAPOWER 8 UGHT COMPANY both units can be routed to either ROBINSON STEAM ELECTRIC PLANT pond for maintenance. DARUNGTON CO., S.C.

ROBINSON STEAM ELECTRIC PLANT WASTEWATER FLOW Stream Average e Flow 106 GPH (4500 gpm max.) 88,000 gpm 0.08 MGD D 482,000 gpm 1.2 MGD 0.02 MGD H 150 gpm 20,000 gpm 5 gpm 60 gpm (approx. 2 today) 50 gpm 0 5 gpm 1 gpm Q 4000 gpd (15,000 gpd max.) R 7000 gpd (42,500 gpd max.) 0.37 MGD 0.16 MGD U 0.18 MGD V 800 gpd 0.07 MGD 570,000 gpm 25 gpm 40,000 gpm ROBINSON STEAM ELECTRIC PLANT DESCRIPTION OF WASTE STREAMS OUTFALL 001 - DISCHARGF CANAL TO LAKE ROBINSON ONCE-THROUGH COOLING WATER This Qow provides cooling water for electric power generation by 2 units: Net Condenser Electrical Condenser Temperature Unit ~Ca )acita Fuel Flow Rate Rise 185 MWe Coal 116 MGD 22.4' 665 MWe Nuclear 694 MGD 21 F Service water is used to supply the water needed to cool the component cooling water and a 14 F temperature rise occurs before the water is discharged to the canal. Control of biological fouling on heat-exchanger surfaces is accomplished by the addition of sodium hypochlorite as required, which is usually less than 2 hours2.314815e-5 days <br />5.555556e-4 hours <br />3.306878e-6 weeks <br />7.61e-7 months <br /> per day per unit, with a net total residual chlorine of less than 0.2 ppm discharged during that period. Cooling is accomplished by evaporation from the surface of Lake Robinson and mixing and convection with lake waters. COAL PILE RUNOFF The coal pile area encompasses approximately 8 acres and is surrounded by a drainage ditch that is routed to a retention basin. The retention basin has a vertical stand pipe to allow sedimentation of suspended solids prior to discharge. Due to the sandy soils and resulting infiltration of rainfall, this retention basin is expected to discharge only during rare severe storm events. No known discharge has occurred to date. ASH SLUICE WATER Unit 1 fly ash and bottom ash are conveyed to the ash pond via a water slurry pipeline. A stand pipe with a skimmer allows for overQow release from the ash pond to the discharge canal. Due to the sandy soil conditions and negligible amounts of stormwater inflow, no known discharge has occurred to date. CHFMICAL MFTAI. CLEANING WASTFS Chemical metal cleaning wastes are disposed of in the ash pond where sedimentation pond chemical (neutralization, oxidation, etc.) and physical (absorption) reactions with ash provide treatment. Metal cleaning wastes are not disposed of in the ash pond at any time when the ash pond is discharging to surface waters. It has not been necessary to use chemical metal cleaning on Unit 2 but any such non-radiological waste would be disposed of in a like manner. The Unit 1 boiler is cleaned approximately every 5-7 years using a mild solution of hydrochloric acid and approximately 75,000 gallons of waste is generated during each cleaning. Under certain conditions, metal cleaning wastes may be incinerated in the Unit 1 boiler after obtaining appropriate regulatory approval. SANITARY WASTES DISCHARGED TO THE DISCHARGE CANAL There are two extended aeration-type sanitary waste treatment plants with treatment capacities of 30,000 gal/day and 12,500 gal/day, respectively, that share an efQuent pipe to the discharge canal near the plant. Flow from these plants is dependent upon Quctuating demands due to variations in numbers of personnel on site. The efQuent is disinfected with sodium hypochlorite just prior to discharge. Sludge is disposed of off-site by a contract disposal Qrm. MISCELLANEOUS LOW-VOI.UMF WASTES - UNIT 2 In the operation of Unit 2, some chemical wastes are produced in the processing of high quality feedwater and in the operation of certain auxiliary systems. These chemicals include corrosion products such as iron; corrosion inhibitors such as chromates, ammonia, and hydrazine; acids and bases (neutralized prior to discharge) such as boric acid, sulfuric acid, sodium hydroxide, and lithium hydroxide; and small quantities of various chemicals used in the plant laboratory. A summary of process chemicals used is included with this application. The turbine and reactor cycles are supplied by well water that has been demineralized by the makeup water demineralizers. Under normal plant operation, some leakage of reactor coolant, secondary coolant, and turbine steam water escapes from the system through valve seals, packing, and pump seals. Steam generator blowdown is processed through the liquid radioactive waste processing system or discharged from a Qash tank to the circulating water system in the absence of radioactive contamination. The steam generator blowdown water (normally 150 gpm) also contains some very low levels (<I ppm) of ammonia and hydrazine which are used to control corrosion. Some chromate waste may be evolved through valve leakage and maintenance activities. This waste is usually collected and processed in the radwaste disposal system. Occasionally during an extended outage Unit 2 will use "wet lay-up" to protect heat exchangers from corrosion. This involves filling the equipment with water and adding hydrazine to a concentration of approximately 75-200 ppm to remove oxygen. Normally, upon return to service of the system, the equipment is heated up sufficiently to convert the hydrazine to ammonia and most of the water is recycled in the operating system. A relatively small quantity of lay-up water is released prior to complete heating of the system and is discharged at 350 gpm to the circulating water system. S Occasionally it may also be necessary to drain a portion of the secondary cooling systems to the circulating water system for maintenance purposes. Hydrazine would be present in this water at wet lay-up concentrations or less. There may be approximately 30,000 gallons of water from each of three steam generators (discharged at 350-1050 gpm) and up to 150,000 gallons from the balance of the plant (at 500 gpm). Dilution and turbulence from the 167,000 gpm or greater cooling water Qow are such that the unstable hydrazine is not expected to survive at detectable levels to the end of the discharge canal. RADWASTE SYSTEM Liquid radioactive waste treatment consists of collecting, storing, and processing radioactive or potentially radioactive waste (gases, liquids, and solids) for disposal or off-site shipment. The waste processing system enables the plant to comply with all applicable regulations for the release of radioactivity to the environment. Radioactive Quids entering the waste processing system are collected in tanks until determination of subsequent treatment can be made. The fluids are analyzed to determine the quantity of radioactivity and for isotopic identiGcation. Liquids are processed through the evaporators or ion exchange demineralization beds. The ion exchange beds in radwaste treatment are not regenerated. When the demineralizing capacity of these resins is depleted, they are shipped off-site for disposal at a federal and state-approved disposal facility (such as Chem-Nuclear in Barnwell, S.C.). Processed waste water from radwaste disposal is discharged through a radiation monitor into the circulating water discharge system. OUTFALL 002 - BLACK CREEK BELOW DAM SANITARY WASTE An extended aeration treatment plant, rated at 15,000 gallons per day, with chlorine disinfection discharges to the storm drainage system serving the west side of the site which discharges to Black Creek. Sludge is disposed of off-site by a contract disposal Qrm. LOW-VOLUME STORMWATER RETENTION PONDS The various low-volume flows from each unit, comprised primarily of plant drains, are usually routed to the west retention pond and east retention pond for Units 2 and 1, respectively. During times of maintenance or similar work on these ponds, there are provisions to combine the Qows from each unit and route them to either pond. Each pond has a storage volume of approximately 800,000 gallons, an overflow weir with a skimmer bafQe to prevent release of Qoating solids, and a rope-type oil and grease skimmer. Normal discharge is to Black Creek via the yard drain pipe but an alternate discharge route is provided that allows operators to pump the retention pond efQuent to the discharge canal and then to Lake Robinson (Outfall 001). The ponds can also be isolated at the discharge to retain any spills that may occur. This discharge canal routing is primarily intended for rare occasions when sampling detects a low level of radioactivity which could require routing to the discharge canal for dilution. The water from Unit 2 consists of waste Qows from such systems as water coolers, sampling streams, minor leaks and seal water, washing of machinery, and rainfall runoff from the immediate plant area. The water from Unit 1 consists of waste Qows from such sources as boiler blowdown, non-chemical metal cleaning, seal water, minor leaks, and rainfall runoff form the immediate plant area. A summary of chemicals used and discharged is included with this application. During outages if it is necessary to drain the Unit 1 steam cycle water, which may contain up to 0.05 ppm hydrazine and 1.0 ppm ammonia, most of the water is stored in tanks for reuse. Approximately 10,000 gallons below the pump intakes may be drained to the low-volume retention ponds. Wet lay-up water is recycled within the plant and there is virtually no discharge due to that process. STORMWATER RUNOFF The primary source of runoff is the yard drains serving areas on the west side of the plant site including parking lots, outside storage areas, off'ice areas, and roof drains. The flow contributed from these areas during a 10-year, 24-hour storm is estimated at 1.8 x 10 gallons. The stormwater runoff from the plant area (routed through the retention ponds) for the same storm is estimated to be 2.2 x 10'allons. The average annual Qow for these two areas is estimated to be 0.07 million gallons per day (mgd) and 0.04 mgd, respectively, based on an average annual rainfall of 49 inches. INTAKE SCREEN WASH WATER The intake screens are washed for approximately 10-30 minutes per day with a combined Qow of 27 gallons/minute. The water contains small lake debris that is impinged on the screens during normal operation. H.B. Robinson Steam Electric Plant Chemicals Vsed in Process Streams Compound Total Quantity Unit Chemical Use ~Used Ycsr ~Prc uccc ~Pur csc 1&2 Amine Hydrazine 1320 gallons (35%) Continuous Oxygen scavenger 1&2 Ammonia Same N/A produced as a Continuous pH control by-product of hydrazine 2 Sodium Caustic soda 435,000 I bs. Daily Dcnllncrallzcf rcgcncf:Itlon hydroxide 50% 2 Sulfuric Sulfate 346,000 I bs. Daily Dcmincralizcr rcgcncration acid salts 1&2 Chlorine Sodium 45,000 gallons (15%) Daily Prcvcnt algae buildup on heat hypochlorite exchanges & sewage treatment disinfection 'STP Calcium Same 540 lbs. Continuous Sewage treatment disinfection hypochlorite 2 Lithium Same 15 Kg. Continuous p I I control hydroxide 2 Sodium Same 9 Kg. 'As required Corrosion control chromate 2 Potassium Same 15 Kg. As required Corrosion control chromate 2 Ammonium Same 9,000 gallons Continuous pH control hydroxide 2 Boric acid Same 75,000 gallons As rcquircd Reactivity control 1&2 Dctcrgcnts Various As required Surfactant 'STP Powdered Same 1,000 lbs. As required IVa ter trca t ment activated carbon 'STP I lydratcd Same 2,000 lbs. As required pH control lime 'STP Sewage Treatment Plants ROBINSON STEAM ELECTRIC PLANT NPDES SC0002925 Outfall 001 was not sampled for Form 2C of the Stormwater Group Application because it does not contain any storm water runoff from Industrial Activity areas, and was therefore not relevant. Sampling results from the last NPDES renewal effort (May 25, 1988) are available upon request. ark PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or al) ol this informatiOn on SeParate sheets (ore (became formac) instead of compieiing chase pages. SEE INSTRUCTIONS, a. e. V. INTAKE AND EFFLUENT CHARACTERISTICS (conrinved fran page 8 of Form 2.CJ pH ~ Biochemicai Oxysen Demand (BOD)

b. Chemical Oxygen Demand (CODJ

c. Total Oceanic Carbon (TOCJ

d. Tote) Suspended Solids (TSSJ

e. Ammonia (os NJ CF low

9. Temperature (vrrnrer)

Temperature (summer) t POLLUT-ANT AND CAS NO. (Ifavailable) Bromide )24959.87.9)

b. Chlorine, Total Res)duet

c. Color

d. Fecal Coliform 2.

VRC VALUL VALUL VALUE c10 <20 MINIMUM SANT Yi AS 'X'. Rs. b. Rs I,ISVS LISVSI I N'I 2.0 0.06 0.g4 15.2 4.05 e. lc) IIAss c140 <70 MAXIMUM I CONCSNTRATION .10 15 14 0.42 4.05 MAXIMUMOAII Y VAI UC VALUE VALUE VALUE MINIMUM PART B - Mark -X- ln column 2-a for each pollutant youknow or have lc) IIAss 0.70 III HA ~ s MAXIMUM MAXI PM I 3. CONC ~ NTRATION VALUE'g/L VAI UC VALUE 3P g)AY VAI.UE II) IIAss aaa C0NCSNTRATI0N c.L N I TP/aM CONCSNTRATION EFA II) HAss I.p. NUMIIER (cop)r from )rem ) of Form I) PART A - You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 'I.POLLUTANT e. MAXIMUMOAILY VALUE,MAXI pM 3Q(AY VALUE C.L 2.EFFLUENT A gpss, vA ci. NO. OF ANALYSCS a.CONCCN III HAss Uc dNO. O ANAL YSES TRATION mg/L mg/L mg/L mg/L I IGD e.

3. UNITS (specify If blank)

'C Oc STANDARD UNITS I ONCCN RATION mg/L mg/L col/100 M Is MASS lbs/day lbs/day lbs/day lbs/da lbs/da

b. MASS lbs/day lbs/day NA VALUL VALUE VALUL'.

) RI nI Are)craved OhIB iya 2040 0088 Appruval esprrc:S 7.8I 88 I I ~

4. INTAKE oprkuiur)

a. LONG TERM l\I HA ~

ceason to believe Is prtoenL Mack "XN In column 2-b for each pollutant you believe to be absent. If you mark column 2a for any pollutant which is limited either directly, or indirectfy but expressly, in an efAuent limitational)uideline.youmust pIOvide the cesuhs of at least one analysis for that pollutant. For other pollutants for which column 2a, you must provide quantitative data or an explanation of their presence in your dischart)e. Complete one table foc each outfall. See the instructions for additional details and requirements. MARK EFFLUENT 4. UNITS I OCI I

5. INTAKE (IIpriccn.ci) s AVERAGE VAI UE C 0 N C II N 'T N AT I 0 N III MA$ %

I'ALI NO I)02

b. No. Or ANALYSES yourn A NO. OF AHAL YSES ITt L

~. Fluoride f1 6994-48%) 0.11 0.77 mg/L lbs/day

f. Nlcrate-Nitrite (os )fJ 1.5 10.5 mg/L lbs/day EPA Form 3510-2C (Rev. 2-85) PAGE V I

ITEM V 8 CONTINUED FROM FRONT

3. EFFLUENT 4. UNITS 5. INTAKE (oprinnuli

1. POLLUT- 3.

MARK ANT AND a.acvca Os: ~ I>. NC. s. MAXIMUMDAILY VALUe b. MAXI M 3$ g(AY VALUe c.LON /IM pgttp. VALUe sl. rIO.Or e.CONCeN. A5'LlrADLAIUe >. NO.OI ANA aa'va as ANAL TRATION la. MASS CAS NO. v k ss AO'X'oHcsHT>a*T>oss Yses I CONCSHTHATsOH (>) MASS Yses~ (Ifavai fable) ~ CHT SANT (>) HASS a C 0 N C C SS T H A I0 S SS (>) a>Ass CONCCHTHATSON (>I HAST

g. Nitrogen, Total Orpe>>ic (OI NI X 1.9 13.3 mg/L lbs/day

h. Oll snd Grease X 3.4 23.3 mg/L lbs/day I. Phosphorus (ae PL Total (7723-14-0) 0.12 0.84 mg/L lbs/day

). Radioactivity (1) Alpha, Total 4.6+2.18 NA pCi/L NA (2) Beta, Total 7.2+1.47 NA pCi/L NA (3) Radium, Total X 2.08+0.8 NA pCi/L NA (4) Radium 226, Total TESTING AND REPO ING NOT REQUIRED

k. Sulfate (ar SO4) X 59 413 mg/L lbs/day (1 48 08-79.8 I. Sulfkl~

(ae SJ 3.2 22.4 mg/L lbs/day

m. Sulfite (ar SOS)

(14266-46.3) X 3.1 21.7 mg/L lbs/day

n. Surfsctsnts X CO. 1 (0.7 mg/L lbs/day

o. Alum num, Total (7429.90-6) 5' 39.9 mg/L lbs/day p sr ums Total (7440-39 3) X 6.0 0. 04 ug/L lbs/day

q. aron, Total X 0.05 0.35 mg/L lbs/day (7440-42-8)

r. Co Total X <0.05 (0.35 mg/L lbs/day (7440-48 4)

s. Iron, Total mg/L lbs/day (74394)9.6) 0.52 3.6 t Magnesium, mg/L lbs/day Total 1.7 11.9 (7439 96 4)

u. MOlybdenum, Total X <Oa 1 %0.7 mg/L lbs/day P439.98.7) v snganete Total 0. 13 0. 91 mg/L lbs/day (7439 96.6)

w. Tln, Total lbs/day (7440-31.6) +0. 1 ~0. 7 mg/L

x. Titanium, Total 70 0.5 ug/L lbs/day PAG CONT N PAGc V EPA Form 3610- ev. 2.86)

EpA I.o. NUMOER (copy from ttem ) of Form )) oUTF*LLNUMBER fund Appluvud OM8 Nu. 2040 0086 002 Appruval esrllrus 7.3l atr CONTINUED FROM PAGE 3 OF FORM 2 C PART C - If you are a primary industry and this outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALLtoxic metals, cyanides, and total phenols. If you are not required to mark column 2-a isecondaryindustries. nanprocess wastewater ourfalls. end nonrequired GC/MS fractions), mark-X" in column 2-b for each pollutant you know or have reason to believe is present. Mark "X- in column 2-c for each pollutant you believeisabsent. Ityoumarkcolumn2a foranypollutant.youmustprovide theresultsofatleastoneanalysisforthatpollutant. Ifyoumarkcolumn 2bforanypollutant,youmust provide Ihe results ot at least one analysis for that pollutant if you know or have reason to believe it willbe discharged in concentrations of 10 ppb or greater. It you mark column 2b for acrolein. aery(onitr(to. 2.4 dinitrophenol, or 2-methyl.4, 6 dinitrophenol, you must provide the results of at least one analysis for each of those pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise. for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this pan; please review each carefully. Complete one table faff 7 pagesf for each outfall. See Instructions for additional details and requirements. 1.POLLUTANT S. MARK 3. EFFLUENT 4. UNITS 5. INTAKE faprional) AND CAS 'X'EST

b. MAXI M Js gIAY YALUC C,LONG T M VALUE d NO.OF a. LONG YCRM NUMBER ts EE c QE ~, MAXIMUM OAILY VALUE /gP b. No.op UIQ ISVE LIEVE . CONCCN.

ANAL ~YRATION b. MASS II) coUEEQ- AHAI AE SHI Ae (if auatktble) QUIlt ~ EIIT SEIIT (I) SI*i~ (I) SIASS (S) IIASS YSCS T AA 7 I 0 II (I) II ASS YSES METALS. CYANIDE, AND TOTAL PHE NOLS I M. Antimony, Total (7440.36.0) c0.05 < 0.35 mg/L lbs/day 2M. Arsenic, Total (7440 38 2) 0.007 lbs/day X ug/L 3M. Beryllium, TOIat, 7440.41.7) (5 c35 mg/L lbs/day 4M. Cadmlurn, Tot ~ I (7440 43 9) 0.3 0.002 lbs/day ug/L 5M. Chromium, Total ('7440.47-3) C2 4 0. 014 ug/L lbs/da 6M. Copper. Total P44060-8) (20 c-OA14 118/L lbs/da 7M. leaL Total P438-93. I) 1.6 0.01 ug/L lbs/da 8M. Mercury, Total P439 97-6) < 0.05 0 ug/L lbs/da 9M. Nickel, Total P440.02 0) X (50 <0.35 ug/L lbs/da 10M. Selenium, Total (7782-49 2) 0.007 ug/L lbs/da 11M. Silver, Total (7440-22 4) c,5 ~0. 035 ug/L lbs/da '12M. Thallium, Total P440 28 0) 30 0.2 ug/L lbs/da 13M. Zinc, Total (7440.66 6) 40 0.20 ug/L lbs/da 14M. Cyanide. Total (57-12 5) (0.005 co. 035 mg/L lbs/da 16M. Phenois, Total (0. 05 (0. 35 mg/L lbs/da DIOXIN 2,3.7.8 Tetra. OESCRIBC RESULTS chforodibenzo P. 0.5 Dioxin (1764.01 6) < ug/L EPA Form 3510-2C IRev. 2.85) PAGE V.3 CONTINUE ON REVERSE CONTINUEU FROM Tl(E FRONT I.POLLUTANT 2. MARK 'X' 3. EFFLUENT 4. UNITS 5. INTAKE (0>PRI>null ANO CAS I>. SL' b. MAXIM M 3,ct p/LY VALUE C.LONG T M gott fs. VALUE >t. NO.OF a c ONG TERM IL NO. ~ NUMBER ~ ~ $1 SL a. MAXIMUMDAILYVALUE I ur>ui u c a. CONCEN. 5Y LY INN >~ 0>S I'NI ~ ~ 1$ 0>$ 0 ANAL TRATroN I>. MASS ANAI l>l u>>u>lul>l> I ~ NL >0>IN'$ ,N1 AS (~ I jLNT CONC L NTNATIO> (I) NA$$ I~ I III AIA$$ (I) $ >A$ $ vses IIITNCONCLN A ION (>) IIA$ $ YSt)! CONC L NI>>ATION ~ GC/MS FRACTION VOLATILECOMPOUNDS 1V. Acrolein (107.02 8) <100 CO. 7 ug/L lbs/day 2V. Acrylonitrlle (107-13.1) <100 (0.7 ug/L lbs/day 3V. Benzene (71 43 2) (0. 035 ug/L lbs/day 4V. Bla (Chloro. melhyll Ether TESTING AND REPOR ING NOT R QUIRED (S42B8.1) SV. Bro>nolorm (75 25.2) (0. 035 ug/L lbs/da 6V. Carbon Tetrachloride (56 23.5) (5 ( 0. 035 ug/L lbs/da 7V. Chlocobenzene (108.90.7) (0.035 ug/L lbs/da t BV. Chlorodi ~ bromomethane C0.035 ug/L lbs/da l124.48.1) 9V. Chloroethane lbs/da (75 00.3) (10 (0.07 ug/L IOV. 2 Chloco- ~ thylvinyl Ether ('I 10-75B) c-10 (0.07 ug/L lbs/da 11V. Chlorofoccn lbs/da (67.66.3) (0.035 ug/L 12V. Olchloro bromomethene (75.27 4) (5 (0.035 ug/L lbs/da 13V. Dlchloro-difluoromethane TESTING AND REPOR ING NOT R QUIRED (75 71B) 14V. 1,1.0ichloro. lbs/da> ~ thane (75-34.3) (0.035 ug/L ISV. 1,2.Dichloco-ethane (107.06 2) c-0.035 ug/L lbs/day 16V. 1,1 Oichloro. ug/L 1bs/da> ethylene (75 35 4) C5 K 0.035 17V. 1,2 Oichloro propane (78 87 5) (5 (0 035 ug/L lbs/da> 18V.(.3 BicNoro-propylene (542.75.6) X (0. 035 ug/L lbs/day t 19V. thyll>0:nzena (10 C,0.07 ug/L lbs/da (100 41 4) 20V. Methyl Bromide (74 83 9) X +10 ( 0.07 ug/L lbs/da 21V. Methyl Chloride (74 87 3) C10 <0.07 ug/L lbs/da EPA Form 3510- 2.86) E ON PAGE LFA I.O. IIUMIILII(I OPy ifunl (tern l uf l UIe ALI- IIIII'IIIIlr ~ OhlIS*l..'IIAIII,ldr. CONTINUEO FROM 002 Apprurel erppes /.3 I 6'8 I. POLLUTANT 2. MARK 'X' 3. EFFLUENT 4. UN)TS S. )NTAKE Jupriorra)) ANO CAS NUMBER I ~ 11 IL SL C SL' vs LILvs nI'HC IL MAXIM M lt g/t

• c.LoNC T /IM rf tg ~ vALUE It NO.OF LONG TERM I NO.OI

~ H RL AS

e. CONC ANAL TRATION EN ti. MASS L)hh. ANAL lrl uvolloblI I QVNI 'ILNT SLNT CONC L STRATI ON CONC L HTNATIOH (I) ~ Ass I~ )

CONC S H TN A TISH (I) HAss YSES (IlTRATION COHCLN (I) AIA~ ' YSES GC/MS FRACTION VOLATILECOMPOUNDS <continued) 22V. Methylene Chloride (75.09 2) 23V. 1.1,2,2-Tetra-( 5 <0 ~ 035 ug/L lbs/day chluroethene (79 34.5) + 10 Ar 0 ~ 07 ug/L lbs/day 24V. Tetrachloro-ethylene (127.18.4) IA 10 cr 0 ~ 07 ug/L lbs/day 25V. Toluene (108.88 3) 26V. 1,2 Trans. A I ( 0. 035 ug/L lbs/day Olchloroethylene (156.60-5) 27V. 1 ~ 1,1.Trl. ( 0 ~ 035 ug/L - lbs/day chloroethane (7 1-56.6) < 0. 035 ug/L lbs/day 28V. 1.1,2.Trl-chloroethane (79.00-5) (0 ~ 035 ug/L lbs/day 29V. Trlchloro-ethylene (79-01.6) (0 ~ 035 ug/L lbs/day 30V. Trlchloro. lluoromethane TESTING At<D PZPOPL ING NOT P QVIRHD (75-69.4)

3) V. Vinyl Chloride (15 01 4) X ( 0.07 ug/L lbs/da GC/MS FRACTION ACIO COMFOUN OS 1 A. 2.Chloropheno (95 57.8) X 10 <0 ~ 07 ug/L lbs/da 2A. 2.4 Olchloro phenol (120 83 2) V TI ( 10 4r'

~ 07 ug/L lbs/da 3A. 2,4 Olmethyl phenol (105.67.9) ~ ( 10 (0. 07 ug/L lbs/da 4A. 4,6 Olnitro 0 Cresol (534.52. 1) X ( lO (0 ~ 07 ug/L lbs/da 5A. 2.4 Olnltro. phenol (51.28 5) ( 10 (0 ~ 07 ug/L lbs/da 6A. 2 Nltrophenol (68 15-5) ( 10 ( 0 07 ~ ug/L lbs/da) 7A. 4 Nltrophenol (100 02.7) ( 52 cr 0. 36 ug/L lbs/da BA. P Chloro M. Cresol (59.50.7) ( 10 Q 0.07 ug/L lbs/da SA. Pentachloro. phenol (87 86 5) < 52 (0 ~ 36 ug/L lbs/da 10A. Phenol [108 95.2) I 1A. 2,4,6.T<l-( 10 (' ~ 07 ug/L lbs/da

hlorophenol 88.06.2)

< 10 (0 ~ 07 ' ~ I rsrl I 1t' TI H tr CONTINUED FROM THE FRONT I.POLLUTANT Z. MARK AND CAS NUMBER llfuIiuIruble I 4 I~ HI HA HHHI 1 ~ 11SI ~ 'HI ~A~ I GC/MS FRACTION BASE/NEUTRAL COMPOUNDS

18. Acenaphthene (83 32.1J)

'X'. CH1 I ~ VA ~ ~ ~ VAI ~ AO ~ 1 Hl

a. MAXIMUMOAII Y VALUf b. MAXIM M clo I I

~ Ill HA%+ <0.07 1 IHI H HA I ~ ~ ~ EFFLUENT 3$u P/tY dl'el CI III HA%\ I I ~ (Il HA\A YSf S ug/L

4. UNITS VALUE C.LONG TP/IM ggttf. VALUf It NO OF CONCf N' ANAI s, RATION II. MASS lbs/day

~ a ~

5. IN T A K E fuplnruul I IIIHI AOHCHH LONI Tf RM BYLIfb(c ~

I OH Id'II IIA~ I IINOO AllA)

28. Acensphtylene (208 96 8) Clp 0.07 ug/L lbs/day

38. Anthracene (120.12.7) (10 <0. 07 ug/L lbs/day

48. Benz)dine (92.87 5) (52 0.36 ug/L lbs/day

68. Benzo (dl Anthracene 56-55.3)

(10 , 0.07 ug/L lbs/day

68. Benzo (d)

Pyrene (50.324)) (10 0.07 ug/L lbs/day

78. 3,4 Benzo.

ftuoranthene (205-99.2) (10 0.07 ug/L lbs/day

88. Benzo fghlJ Perylene (191 24.2)

(10 0.07 ug/L lbs/day

98. Banco fkJ F luoranthene (207 08 9) (,10 0. 07 ug/L lbs/day 108. Bls f2.Chloro.

clhoxy) Methane (111.91 1)~ <10 0.07 ug/L lbs/day 118. Bls (2.Chloro. prep(0(ther clhyl) Ether (111-44HI) (Io 0.07 ug/L lbs/day l26. Bit/2 Chkydlso. (102 60-1) (10 (0.07 ug/L lbs/day 138. Bls (2.sibyl. kczyl) Phthalate <10 (0.07 ug/L 31 'day ( I 174) 1-7) 148. 4 Bromo. phenylPhenyl Ether (101 55.3) C10 Cp Pj ug/L lbs/day 158. Butyl Benzyl Phthalate (85 68-7 ('0 ~0.07 ug/L lbs/day 168. 2.Chloro. naphthalene (91-58 7) (10 0.07 ug/L lbs/day 178. 4 Chloro. phenylPhenyl Ether l 7005 72.3) Clp (0. 07 ug/L lbs/day 188. Chrysene (218. 01.9) (10 40.07 ug/L lbs/day 198. Dlbento fd,hJ Anthracene (53 70.3) (10 0. 07 ug/L lbs/day 208. 1,2.Dlchloro-benzene (95.50-1) (10 (0.07 uog/L lbs/day 2'IB. 1,3 Dlchloro. (10 0. 07 benzene (641 73.1 EPA Form 3510-2 .. 2.85) PA u /L lhs d CO ON PAGE I .>>>>>'>1 >H I~ ~ E pA I.D. N UM u Err (copy /rom Item I o/ Fo UTFAI L NUMULII OS ttt tyx> 2040 Ol>4( ~ CONTINUED FROM PAGE V-6 002 Apprx>vsl cxp>rus / 3I 68

1. POLLUTANT 3. EFFLUENT 4. UNITS 5. INTAKE (>>pre>>>el)

ANO CAS NUMBER l>/4>>4>lebt>V 4 >N'xvx ~~ HL ~ Nu>H' > IXH> VH> x Nx ~ Cnx 1>exx H~ ~ 4 Nx ~

e. MAXIMUMDAILY VALUE b. MAXI M CDNc>

IN>HA>>nN ~ I !1! Hiss enN>> ~ ~ >Hex>n>> 4>>4>$4 g/sY e (>) VALUE C.LONG T ex>u NH> ~ I I ~ M Cn>>x x Nl >>ax)NN tt)P 4 4 . VALUE l>l N@1 ~ YSE S

4. CON CS:N TRATIXSN I ~, MASS ~

(~ I I cnNcvN ONG TERM st Klt/s(r I Itf I ~ I >xaev ta NO.O> ANAL YSES GC/MS FRACTION BASE/NEUTRAL COMPOUNDS (continued'28. 1,4 Oichloro. benzene (106 46.7 X (10 <0.07 1 ug/L lbs/day 238. 3.3'.Dichloro benzidlne (91-94 1) (52 CO. 36 1 ug/L lbs/day 248. Diethyl Phthalate (84.66.2) (10 <0.07 1 ug/L lbs/day 2S8. Dimethyl Phthalate (131.11 3) <0.07 1 ug/L lbs/day 268. Dl N.Butyl Phthal4te (84-74 2) (10 c 0.07 1 ug/L lbs/da 278. 2,4 Dlnltro. toluene (121 ~ 'l4 2) (10 c,0.07 1 ug/I. lbs/da) 298. 2,6 Olnltro. toluene (606.20.2) X (10 c,0.07 1 ug/L lbs/da 298. Oi.N.Octyl Phthalate ((174)4.0) X 410 (0.07 1 ug/L lbs/da 308. 1.2.Diphenyl. hydrazine (as >(so. benzene) I 122-66.7 <52 <0.36 1 ug/L lbs/da 318. Fluoranthene (206 44.0) <10 (0.07 1 ug/L lbs/da 328. F luorene (96.73-7) (10 + 0.07 1 ug/L lbs/da) 335. HcsscNcrcbenz (11974 .ts <10 <0.07 ug/I, lbs/da) 348. Hexa. chlorobutsdiene (87-68D) (10 +0.07 ug/L lbs/da 358. Hexschloro-cyclopentsdlene (7 7.47-4) C10 <0.07 1 ug/L lbs/da 368. Hexschloro- ~ thsne (67.72-1) (10 (0. 07 1 ug/L lbs/da 378. Indeno ((,2.3-cd) Pyrene (10 < 0.07 1 ug/L lbs/da (193~.5) 388. Isophorone (78 59.1) (10 <0.07 1 ug/L lbs/da 398. Naphthalene (91 20.3) (10 (0.07 ug/L lbs/da 408. Nltrobenzene ug/L" lbs/da (98.96 3) 410 (0. 07 418. N Nitro-sodlmethylsmine (62 75.9) 410 (0.07 1 ug/L lbs/da 428. N Nltrosodl. N4>ropytamlne 62 1. 64-7 I (10 (0. 07 tsx> /1 CONTINUED FROM THE FRONT

1. POLLUTANT AND CAS NUMBER d I~

N

3. MARK

\I I>>'I.ANI ~ ~ A I VC ~ ~ ~ X'.EFFLUENT c ~C SISVS ~

a. MAXIMUMDAILY VALUE b. MAxl M 3$ g(AY vALUE C.LDNG TfpM )QItp. vALUK II NO. OP ANAL

4. UNITS

a. CONCBN 3 RATION

~ II M ASS

5. INTAKE (IIPRINrul/

LONG TCRM .~ Y LI(4I(CI IIIIE Ij NO AN A I ir( uuuIlo(IIIU ~ NC OI A ~ I I SSNI ~ SNI CONC I NTNAIION ~ (tl AI ASS I~ I III NASs III NASA .YSKS I ~ I CONC ~ N 'IN A SION I ~ I HA ~ s Ysat ~ CNI I ~ NTNAI IN ~~ GC/MS FRACTION BASE/NEUTRAL COMPOUNDS (conlinurd) 438. N Nitro. sodlphonylamlna C10 (0.07 ug/L lbs/da (86 30.6) 448. Phenanthrene (85 01.8) C10 C0.07 ug/L ibs/da 458. Pyrene (129.00.0) C.10 (0.07 ug/L lbs/da 468. 1,2,4 Trl-chlorobenxene C10 <0. 07 ug/L lbs/da (120-82 1) GC/MS FRACTION PES TICIDES 1P. Aldrln (309 00 2) 2P.G BHC (319.84-6) 3P. P BHC (319 85.7) 4P. 7 BHC (58 89.9) SP. 6 BHC (319 86 8) 6P. Chlordane (57 74.9) 7P. 4.4'.OOT (6029 3) BP. 4,4'.DOE (12 55-9) 9P. 4.4'.DDD (72 54.8) 10P. Dieldrin. I (6057 I) I IP. C.Endosullan (1 I 5.29-7) 12P. P Endosullan (116 29.7) 13P. Endosulran Sulfate ((03(.074)) 14P. Endrin (12 208) 16P. Endrin Aldehyde (7421-93 4) 16P. Heptachlor (76. 448) EPA Form 3610-2 . 2-86) -8 CON ON PACE i Fc>>u> Appn>veil fPA I D. NUM OER (Cope feonl I(eiil I Of Polin I J OUTfAI L NUM[I)R Oh(() No 2040 002 e>pries 7.3( a8 0()8o'ppi>IVal CONTINUED FROM PAGE V 8 I.POLLUTANT X. MARK 'X 3.EFFLUENT 4. UNITS 5 I N T A K C fi>Pii>>u>>ll AN[) GAS VALUE TfPM gTfig. VALUE Il SIO.OF MAXIM 'AY AlN Sl IC V~ I C>>A b. M 5P C.LONG I.ONG 7 EAM I ~ ICO.OI NUMBER ~ ~ I~ I N~ ~ I II>VS ~ A~ il. MAXIMUMDAILY VALUE ANAI >>. rOIirf TRATION >4 I> IIIA55 6 Y td(b[C < Wh(II(S= ASIA I, iif>>II>>>l>>IIII) H~ QIIIN SANI SI H1 C>>HC Nr>>A1 >>H (I) >>ASS li) NASA (II >>ASS YSE 5 ( ~ I I OHC ~ N. (I) AIA~ 1 V555 ~IL. ~ ~ I. >IN C ~ H I N A ~ ~ II ~ . IHC ~ ~ A I@ ~ N A 1 ~ IIN \ N A II>IN GC/MS F RACTION PESTICIDES feo> >(inued) 17P. Hcplachlor 6 pox(do (1024 57 3) IBP. PCB 1242 (53469 21-9) 19P. PCB 1254 (11097 69-'I) 20P. PCB 1221 (11104 28 2) 21P. PCB 1232 ( I 114'I ~ 16.5) 22P. PCB.1248 (12672-29 6) 23P. PCB.1260 ([109682.5) 24P. PCB IO'(6 ()2674 11.2) X 25P. To>caphl>ni> (8001 35 2) PAGE V 9 pn pnrin '\I(1(I OI IRm O nnl ROBINSON STEAM ELECTRIC PLANT SAMPLER 43 NARRATIVE DESCRIPTION OF STORM WATER OUTFALLS There is one outfall associated with storm water runoff at this facility. All industrial areas of the facility that have a point source discharge drain to a common point through a system of storm sewers and then discharge to a creek just below the reservoir dam. The coal pile runoff is already included in the current NPDES permit and is not included here. Outfall 1, in addition to storm water, also contains discharges from a small sewage treatment plant and effluent from the low volume waste treatment ponds, which receive and treat discharge from virtually all of the plant drains, both equipment and yard storm water. Also noteworthy is the fact that this site has a very high groundwater table and therefore a great deal of infiltration to the storm water sewers.. The groundwater and surface waters in this area are naturally low pH, usually ranging from about 4.2 to 6.0. The following areas associated with industrial activity are drained by this outfall: a) Runoff from the main "power block" of Unit 1, a coal fired steam electric generating unit, including boiler, turbine/generator, precipitator, machine shops, warehouse, and electrical transformers. Neither the boiler nor the turbine structures have a roof, as typical with CP&L coal-Gred plants. This area drains to a retention pond with an oil skimmer prior to routing to Outfall 1. b) Runof'f from Unit 2, a nuclear powered steam electric generating unit, including reactor building roof, an open (no roof or walls) turbine building, the roofs of various shops, laboratories, and administrative buildings. Material is stored in this area usually only on a temporary basis. This area drains to a retention pond with an oil skimmer prior to routing to Outfall 1. c) Runoff f'rom areas that provide support facilities for the nuclear powered unit, including administrative and support services buildings, warehouse roofs, service roads, and material storage areas. Continued from Page 2 I x,8.c, S 0: See insuucuons before oroceeaing. Ccmpiete one set ot tables for eacn outfall. Annotate tne outfall number in the space provided. he ts umbered Vlht ana Vll.2. E: Potenuat discharaes nct coveiea by anaiysis - is any pollutant listed in Table 2F.2 a substance or a component of a substanCe wmcn you ufrentiy use or manuiacture as an intermediate or tin'ai product or byproauct? ".Q(i YeS (litt ail SuCh bOiiutanrS beiawi ko ( orosecrion(N ANTIHONY THALLIUH ARSENIC ZINC BERYLLIUH CHRONlUN CADHIUH COPPER LEAD HERCURY NICKEL SELENIUH SILVER oo you have any trnowiedge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your aischarge wnhin the last 3 years? ~ Yea (liSt all SuCh bOiiutanrS belaw) ko (ao to Section 80 V(ere any of the analyses teported in Item V performed by a conttact laboratory or consulting firm'? ~ Yes (list the nane, address, and telephone number of, ahd pollutants kame + ko (gotosectioni(l 6 Phone ko. O. Pollutants AnsNTed A. 8. Address C. Area Code I DAVIS AND BROW%i, INC. P.O. BOX 15038 (803) 665-6746 QUINBY, SC 29501 I certify under penally of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qua(i%ed personnel properly gather and evaluate the information submitted. Based on myinquiry of the person or persons who manage the system or those persons directly responsible for gathenng the information, the information submitted is, to the best of my knowledge and belief, frue, accurate, and complete. l am aware that there are signi%cant penalties for submitting false information, including the possibility of fine andimprisonment for knowing violations. Name rt Otticial Title (type or pnnri 8. Area Code ana Phone No. GEORGE J. OLIVER HGR ENVIR018fENTAL SERVICES (919) 546-4189 C. Signature O. Date Signea Page 3ot 3 2F-3 0 SAIIPLER rorm Aop 2'."3 - ROBINSON PLANT EPA lo Number Icooyfmm ~m I Of Fo~ rl I ea. OM8 No. 20404066 I Approves excgres ~ I.gp II. OIscnar e tntorrnaston rt-ontfnuea trom oa e J ol Form ZFI pars A You must ptovide the results ot at least ofl~ analysis lof every poilutarlt in Inis table. Complete one taot ~ tof eacn oudatt. See I >nstructrons tor additional aetaus. values !Maximum Average values Number I (inctucfe unrfst (inCtude unrfxt  ! ot and Grab Samole Grab Samoi ~ Stortn Taken Ounng Taken Ounng Row~rgmea CAS Number Rfst 30 Row~igntsa Fiat 30 Events I rir avariaofet Minutes Comoosrt ~ Minutes Composite Samoteat Sources ot Potlufafits Oilaaa &aaaa I I 2.1 mg/1 vehicle/equipment leaks 20 g/1  ! 20 g/1 below detection level Chemical Oxygen gas/oil from vehicles, isc. leaks s ills of ma eri I Oemand ICOOI  ! 30 mg/1  ! 28 mg/1 Total Suspended mm,anggi I 22 0 mg/1! 22.2 mg/1 erosion settled dust Total Kjeldaht Nilrooen 1.1 mg/1 4.5 mg/1 decomposing vegetation Nitrate pius Nitflte Nrtrooen c1.0 mg/1 $ 1.0 mg/1 elow detection level )%0.10 mg/1 !C0.10 mg/1 elow detection level 'hnrmurn 4 73 Maximum 4 Minimum Maximum 1 natura y ow pn groun w ter art tt ~ t.rst eacn pouutant inst a umitea in an eiuuent guiaeune mvnrcn tne facrrrty is suoiect to or any pouulant uslea in the tacuuy s N pQ permil tor ils process wastewater lit the tacrtrty rs operating undet an existing NPOES permiil Complete one table tor eacn outtail. c a i Maximum Values Awrage Values Numosr Pollutant 'include unrrst  ! (include unrrst ot and Grab Samoi ~ Grab Samote Slorm Taken Ounng Taken Ounng ROwwreighted Events CAS Number Rowmrverg hied First 30 First 30 (r(avartapteI Minutes Composite Minutes Composite Samplea Sources ol Pouutants SEE DATA IN SECTION VIIIA. D TA Ia SECTION VII'. SECTION u T. I<50 u" L VII'+50 I below detection level O 25 I 1.24 mg/L I I 1 i corrosion of pipes and I disinf ection of treated I e ow detection level I I ~ I EPA Form 3610-1F It t.eoI Page vu 1 Conunue on Reverse Contfnuec( from tne Front Part C ~ tist eacn oouutant snown in Tables 2F.2. 2F.3, ana 2F< that you know or nave reason to believe is Present. See tne insuucuons ior saaitionaf octans ana reauuements. Compiete one table for eacn outtall. Maximum values Average Values Nurriber I ~ Pollutant (inclucre vnrrsf (include unrrsl  ! oi ana Grab Samoi ~ Grab Sampf ~ Storm f Taken Outing I Taken During I CAS Number First 30 Rowwreigntea First 30 rqow~eignted Events (i(avfu(a ore) Minutes Composne Minutes j Composne Sam pisa Sources of Pollutants TRC I SEE DATA IN SECTION VIKB I I i I I I I I I I I I Sulfate I (.50 m /l I 1.83 mg I I I 1 I coal dust Al 3.1 mg/I I 3.6 mg 1 1 coal dust, corrosion l I I Barium f .024 mg/l .034 mg coal dust l i I 1 Ng I 1350 t" 1265 mg 1 1 coal dust r I <20 ug/L 420 ug 1 e ui ment corrosion, coal e I SEE DATA IN SECTION VI B Part 0 ~ Provide data for the storm eventfs) whicn resulted in the maximum values for the flaw we hted comoosite samoie.

t. 2. 3. " 4, 5. 6. 8.

Oats of Duration Totalrainfall Number of hours between Maximum floe rate Total flow from Form ot Storm of Storm during storm event beginmng ol storm meas- during rain event ran event sempre was Precipitation urea ana end of previous (gallons /minute or (gallons or (rainfall. Event (in rninvres) (ininches) measurable rain event spec% units specdv unfrsf taken snowmenf 1/13/ 2 270 0.27 240 2.78 ft3/se 12,550 winter rain ft3 Provide a description at the method of flow measurement or estimate. FLOW RATE WAS ESTIHATED BY I'IEASURING THE DEPTH OF FLOW IN A LINED CHANNEL APPROZIifATEL EVERY 20 MINUTES DURING THE RAIN EVENT AND USING MANNING'S EQUATION FOR FLOW IN OPEN CHANNELS. EPA Form 35ta-2F {11-90) page vll 2 ZF-5 Key Drainage Area Boundary / = Outfall IC IIAISIN Sewer Line EIRC r 8LDG DOCuNENT CON lROL CXPIIAPNKNT T STOR RLDG ROBINSON IhlPOUNOME22T RCA SNOP/ 5IOCA PIIT5/PC CNE INCAL FID> 0 00 II Q3 srv4hbt srCRAGE SEQI IANT l g l0 i P5 IUABINE DLDG PAP. EAST IESEL p CO OO RIEN STORAGE NARE NOIASE PAP NE5T 0 KE 0LOG PI Tur } IPAT PIIur 0 IJNl I SNI ICNTARO s~ lsd(F GET TRAPANG T RAIIENE DLDG IPAT 2 SWI TCN TARO gC lr NIJL A IAPLDING ll!E~Q 8UL NG PADX OIAIPKL TEST 1 \, RETENTOH ~) ~~* 0> g CAROLINA POWER & LIGHTCO. ROBINSON STEAM ELECTRIC PLANT Storm Water Group Application No. 286 Sampler No. 3 94...9403070328 t'arolina Power & Light Shearon Harris Nuclear Power Plant License No. NPP-063 SE AOANNUALRADtOACTTVE EPltLtlENT RELEASE REPORT July 1, 1993 to December 31, 1993 Prepared by: -/$ -9'y Speci 1 t - E&C Reviewed by: /g Manager - E&RC S pport Reviewed by: Mana r - B&C Reviewed by: ~ ugly,~ ager - vironmental & Radiation Control Approved by: General Manager - Harris Plant K l V '1 5 Table of Contents Page No. Introduction i Discussion Appendix 1. Supplemental Information Appendix 2. Effluent and Waste Disposal Report

1. Lower Limits of Detection (LLDs) 2/1

2. Effluents Released 2/3

3. Solid Waste Disposal 2/10 Appendix 3. Changes to Process Control Program (PLP) 3/1 Appendix 4. Changes to Offsite Dose Calculation Manual (ODCM) 4/1 Appendix 5. Changes to the Environmental Monitoring Program

1. Environmental Monitoring Program 5/1

2. Land Use Census 5/2 Appendix 6. Additional Technical Specification Responsibilities

1. Inoperability of Liquid Effluent Monitors 6/1

2. Inoperability of Gaseous Effluent Monitors 6/2

3. Unprotected Outdoor Tanks Exceeding Limits 6/3 4, Gas Storage Tanks Exceeding Limits, 6/4 Appendix 7. Major Modifications to Radwaste System 7/1 Appendix 8. Meteorological Data 8/1 Appendix 9. Assessment of Radiation Doses for Calendar Year 1993

1. Population Doses outside Site Boundary due to Effluent Releases 9/1

2. Doses to the General Public Due to Activities Inside the Site Boundary 9/2

3. Doses to the Likely Most Exposed Member of the Public 9/4

4. Major Assumptions used to Calculate Radiation Doses 9/8

C g, t I I 4l Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Introduction This Semiannual Radioactive Effluent Release Report is in accordance with Technical Specification 6.9.1.4 to the Shearon Harris Nuclear Power Plant (SHNPP) Operating -License No. NPF-63. It provides effluent monitoring information obtained in fulfillment of the plant's Radiological Effluent Technical Specifications (RETS) . The Shearon Harris Nuclear Power Plant achieved initial criticality on January 3, 1987. This Report covers the period from July 1, 1993 to December 31, 1993. During this period, the plant continued in Cycle 5 operation. For calculation of doses in Appendix 9, this Report covers the period from January 1, 1993 to December 31, 1993. Discussion Appendices 1 and 2: The information on gaseous and liquid effluents and solid waste is given in accordance with Regulatory Guide 1.21 (Rev. 1) Appendix B format. As required by Technical Specification 6 '.1.4, the solid waste table has been supplemented to include 10CFR61 class, type of container and solidification agent or absorbent. Except for continuous noble gas releases, liquid and gaseous average concentrations (pCi/cc) and total curies released are for only those nuclides that were positively identified. If no activity for a nuclide is reported for a quarter, the Lower Limit of Detection (LLD) tables show a typical sensitivity level for detection of the nuclide. Continuous noble gas effluent activities were based on hourly average stack monitor readings (in pCi/cc) and stack flow rate estimates based on fan flow rates, and are apportioned as per the GALE code (NUREG 0017) nuclide assumptions as given in the ODCM. When specific noble gas nuclides were identified in the stack gas grab samples, their activity was added to the activity based on stack monitor readings. Nuclides reported in gaseous batch releases are determined from the isotopic analysis for each batch release. The "Percent of Technical Specification Limit" is calculated using ODCM default methodology and parameters. A total of 43.14 m~ of solid waste, containing 183.86 Ci of radioactivity, was,shipped for burial during this Report period, compared with 21.94 m'nd 189.97 Ci shipped during the previous Report period. '4 h Eq 4 Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Discussion (continued) Appendix 3: The Process Control Program (PCP) was changed to delete the requirements for the plant installed Solid Radwaste System. The complete description of the change is in Appendix 3. Appendix 4: One change to the Off-Site Dose Calculation Manual (ODCM) was made during this Report period. The change is described as ODCM Change 3/8. Appendix 5: As a result of the 1993 annual Land Use Census, a new sample location for food crops was established in the Environmental Monitoring Program. Appendix 6: One instance of effluent monitoring instrumentation inoperable for greater than 30 days during this Report period has been listed. No unprotected outdoor tank or gas storage tank exceeded Tech Spec limits during this Report period. Appendix 7: No major modifications to the Radwaste System were made during this Report period. Appendix 8: The 1993 annual summary of meteorological data is available to the NRC upon request. This summary is also used in the NRC approved program XOQDOQ, which is used in the Appendix 9 dose calculations. f ~ 4 t Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Discussion (continued) Appendix 9: The effluent quantities reported for both semiannual periods in 1993 were combined for determining the annual dose impact from plant operations. The doses were calculated by the programs LADTAP II (for liquid effluents) and GASPAR (for gaseous effluents). LADTAP and II GASPAR are NRC approved programs for implementing Reg. Guide 1.109 methodology, which is also the basis of the ODCM calculations. When appropriate, the doses are also broken down by age group (adult, teen, etc.) and organ (bone, thyroid, etc.) . Enclosure 1 shows the integrated population doses within the 50-mile ingestion zone (in man-rem) due to liquid and gaseous releases for the various applicable pathways. Also, the tritium contribution to the hydrosphere is shown. Enclosure 2 shows the doses (in mrem/yr) to a hypothetical individual member of the general public due to activities inside the site boundary. Since portions of Harris lake are within the site boundary, these doses result from the recreational usage of the lake. The highest whole body doses any individual could have received in this area were 0.093 mrem due to liquid effluents and 0.004 mrem due to gaseous effluents. The corresponding values for CY 1992 were 0.015 and 0.011 mrem respectively. Enclosure 3 shows the hypothetical doses (in mrem/yr) for the "Likely Most Exposed Individual". For the liquid pathways, this calculation assumes that the Harnett County water supply intake (formerly Lillington), the closest downstream public water supply, is the source of drinking water and Harris Lake is the source of all other liquid exposure. The highest whole body and organ doses any individual could . have received due to liquid effluents were 0.093 and 0.116 mrem respectively. Corresponding values for CY 1992 were 0.055 and 0.060 mrem respectively. For the airborne pathways, the gaseous dose considers two types of individuals: (1) the "Maximum Hypothetical, Individual", who resides at the site boundary in the sector of highest plume exposure, and (2), the "Maximum Real Individual" who, based on the Land Use Census, had the highest combined dose from his actual exposure pathways, e.g. plume, ground, etc. In 1993, the "Maximum Real Individual" is located at 4667 meters ("2.9 miles) in the SW sector. This is a change from 1992, in which the "Maximum Real Individual" was located in the NNW sector at a distance of 1.5 miles. Previous to 1992, the "Maximum Real Individual" was located in the NNE sector at a distance of 1.8 miles. '.q iy pX 4 'I 4 '4 v n yt I Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Discussion (continued) Appendix 9 (Continued) For the <<Maximum Hypothetical Individual", the highest whole body dose was 0.127 mrem, and the highest organ dose was 0.191 mrem. Beta and gamma annual air doses were 0.114 and 0.069 mrad respectively. Corresponding values for CY 1992 were 0.155 whole body, 0.330 organ, 0.348 beta, and 0.238 gamma, respectively. For the "Maximum Real Individual", the highest whole body dose was 0.021 mrem, and the highest organ dose was 0.033 mrem. Beta and gamma annual air doses were 0.022 and 0.012 mrad respectively. Corresponding values for CY 1992 were 0.037 whole body, 0.038 organ, 0.090 beta, and 0.058 gamma, respectively. Enclosure 4 lists the major assumptions associated with the liquid and gaseous effluent doses. Where available, site specific information is used to derive these values. In other cases, parameter values or derivations are as given in Reg. Guide 1.109 ' l I V '1 4 Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 1: Supplemental Information Regulatory Limits Fission and activation gases (1) Calendar Quarter

a. 5 mrad gamma

b. 10 mrad beta (2) Calendar Year

a. 10 mrad gamma

b. 20 mrad beta B. I-131, I-133, I-135, H-3 and particulates with half-lives greater than eight days (1) Calendar Quarter

a. 7.5 mrem to any organ (2) Calendar Year

a. 15 mrem to any organ C. Liquid effluents (1) Calendar Quarter

a. 1.5 mrem to total body 5 mrem to any organ (2) Calendar Year

a. 3 mrem to total body

b. 10 mrem to any organ

I tg I' Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 1 (Continued): Supplemental Information

2. Maximum permissible concentrations and dose rates which determine maximum instantaneous release rates.

A. Fission and activation gases (1) 500 mrem/year to total body (2) 3000 mrem/year to the skin I-131, I-133, I-135, H-3 and particulates with half-lives greater than eight days. 1500 mrem/year to any organ C. Liquid effluents The annual average concentration of radioactive material released in liquid effluents to unrestricted areas after dilution shall be limited to the concentration specified in 10CFR20, Appendix B, Table 2, Column 2, for radionuclides other than dissolved or entrained noble gases. For dissolved and entrained noble gases, the EC shall be equal to 2.08-4 pCi/ml. Beginning 01-01-93, SHNPP began using Effluent Concentrations (ECs) instead of MPCs.

3. Average Energy (E)

N/A an SHNPP. SHNPP determines doses and dose rate based on actual releases, not on an average energy value. 4 ~ Measurements and Approximations of Total Radioactivity A. Fission and activation gases Measurements by continuous monitors of activity concentrations times total stack flow, and analysis by gamma spectroscopy and liquid scintillation counting for specific radionuclides in representative grab samples. B. Iodines Continuous charcoal cartridge sampling and analysis by gamma spectroscopy for specific radionuclides times total stack flow. C. Particulates Continuous particulate sampling and analysis by gamma spectroscopy, alpha counting and radiochemical analysis for specific radionuclides times total stack flow. D. Liquid Effluents Pre-release representative sampling and analysis by gamma spectroscopy and liquid scintillation counting for specific radionuclides times total release volume. if J 1 ~ Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 1 (Continued): Supplemental Information Batch Releases Liquid Batch Releases (1) Number of batch releases 8.00 E+01 (2) Total time period for batch releases 6.10 E+04 min (3) Maximum time of a batch release 1.90 E+03 min (4) Average time for a batch release 7.63 E+02 min (5) Minimum Time for a batch release 2.62 E+02 min (6) Average stream flow during periods of release 1.45 E+04 gpm B. Gaseous Batch Releases (1) Number of batch releases 1.00 E+00 (2) Total time period for batch releases 8.07 E+02 min (3) Maximum time of a batch release 8.07 E+02 min (4) Average time for a batch release 8.07 E+02 min (5) Minimum Time for a batch release 8.07 E+02 min Abnormal Releases A. Liquid No abnormal liquid releases were made in this period. B. Gaseous No abnormal gaseous releases were made in this period. 4 'I g '1 j Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2: Effluent and Waste Disposal Report Bnclosure 1: LOWER LIMITS OP DETECTION (LLDs)

1. LLDs for Gaseous Effluents Nuclide ~ci cc Gross Alpha 1.80 E-15 H-3 7.97 E-09 Ar-41 3.79 E-OS Kr-85 6.09 E-,06 Kr-85m 2.12 E-OS Kr-87 8.88 E-08 Kr-88 2.32 E-08 Xe-131m 6.21 E-07 Xe-133 6.96 E-08 Xe-133m 4.65 E-07 Xe-135 2.07 E-08 Xe-135m 4.65 B-07 Xe-138 5.94 E-07 I-131 3.22 B-14 I-133 2. 73 E-14 I-135 7.97 E-14 Cr-51 1.17 E-13 Mn-54 1.66 E-14 Co-58 1.33 E-14 Pe-59 3.87 E-14 Co-60 1.86 E-14 Zn-65 7 ~ 55 E-14 Sr-89 3.00 B-15 Sr-90 1.00 E-15 Mo-99 1.48 E-13 Cs-134 1. 01 E-14 Cs-137 2.63 E-14 Ba-140 4. 13 E-14 La-140 2.41 E-14 Ce-141 1.26 E-14 Ce-144 3.89 E-14

'k'" I I \ l i V ~ I' (I 4 'I '1 f.i 0 Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 1: LOWER LIMITS OF DETECTION (LLDs)

2. LLDs for Liquid Effluents Nuclide ~Ci ml Nuclide Ci ml Gross Alpha 4.10 E-08 Sb-122 5.06 E-08 H- 3 2.55 E-06 Sb-124 1.68 E-08 Be- 7 2.24 B-07 Sb-125 9.36 E-08 Na-24 3.15 E-08 I-131 2.67 E-08 Cr-51 2.61 E-07 I-132 3.31 E-08 Mn-54 2.01 E-08 I-133 1.33 E-07 Fe-55 2.00 E-07 I-135 1.25 E-07 Co-57 1.73 E-08 Te-132 2.31 E-08 Co-58 1.98 E-08 Xe-131m 9.21 B-07 Fe-59 4.64 E-08 Xe-133 5.36 E-08 Co-60 3.89 E-08 Xe-133m 1.91 E-07 Ni-63 2.00 E-07 Xe-135 2.59 E-08 Zn-65 8.67 E-08 Cs-134 3.08 E-08 Sr-89 1.50 E"08 Cs-137 3.38 E-08 Sr-90 5.00 E"09 Cs-138 5.62 E-07 Sr-92 4.52 B-08 Ba-140 9.60 E-08 Y-93 1.34 E-07 La-140 3.02 E-08 Nb-95 3.26 E-08 Ce-141 4.84 E-08 Zr-95 3.36 E-08 Ce-143 6.07 E-08 Mo-99 2.04 E-07 Ce-144 2.04 E-07 Tc-99m 2.46 E-08 Pr-144 1.17 E-06 RQ- 103 2.51 E-08 Hf-181 2.62 B-08 Ag-110m 5.93 E-08 2/2

Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 2 : Effluents Released Table 1A  : GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES Units Quarter Quarter . Est.Total 3 4 Error

1. Fission & Activation Gases A. Total Release Ci 9.29 E+01 8.10 E+01 4.50 E+01 B. Average Release Rate for Period pCi/sec 1.17 E+01 1.02 C. Percent, of Technical E+01'.84 Specification Limit E-01 4.74 E-01

2. Zodines (Z-131, I-133, I-135)

A. Total Iodines Ci 0.00 E+00 0.00 E+00 2.00 E+01 B. Average Release Rate for Period <<pCi/sec 0.00 E+00 0.00 E+00 C. Percent of Technical Specification Limit See the Footnote Below

3. Particulates A. Particulates with B.

T1/2) 8 days Average Release Ci 0.00 E+00 1 '7 E-04 2.00 E+01 Rate for Period pCi/sec 0.00 E+00, 1.72 E-05 C. Percent of Technical Specification Limit See the Footnote Below D. Gross Alpha Radioactivity Ci ( LLD ( LLD

4. Tritium A. Total Release Ci 4.50 E+01 3.29 E-03 3.00 E+01 B. Average Release Rate for Period pCi/sec 5. 66 E+00 4. 14 E-04 CD Percent of Technical Specification Limit 8.13 E-01 1.87 E-02 The Percent of Technical Specification limit applies to Zodines, Particulates and Tritium combined, and is calculated using ODCM default methodology and parameters. The value for Zodines and Particulates is included in the Tritium summation.

2/3 af ~l C / h lp Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste-Disposal Report Enclosure 2 : Bffluents Released Table 1B : GASEOUS BFFLUENTS - ELEVATED RBLEASES All releases at Shearon Harris are made as ground releases. 2/4 L n 0 4 '4 P d ~l' Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 2 : Effluents Released Table 1C : GASEOUS EPPLUENTS - GROUND LEVEL RELEASES CONTINUOUS BATCH NUCLIDES Units Q3 Q4 Q3 Q4

1. Fission and Activation Gases H-3 Ci 4 . SOE+Ol 3.298-03 No Batch 5.608-06 Xe-131m Ci 2.00E-01 2.578-01 Releases < LLD Xe-133 Ci 2 . 42E+01 5. 148+01 made in 4.398-04 Xe-133m Ci 3.01E-01 7.998-01 Period LLD Xe-135 Ci 7.998+00 6.658+00 LLD Xe-135m Ci LLD LLD LLD Xe-138 Ci 1.508-01 3.988-01 LLD Ar-41 Ci < LLD LLD LLD Kr-85 Ci 1 . 408+01 1. 808+01 6. 808-01 Kr-85m Ci 4.528-01 1.208+00 LLD Kr-87 Ci 1.508-01 3 . 988-01 LLD Kr-88 Ci 7.53E-01 1.99E+00 LLD Totals Ci 9. 298+01 8. 108+01 6.808-01

2. lodines

~ ~ I-131 Ci LLD < LLD No Batch < LLD I-133 Ci LLD LLD Releases LLD I-135 Ci LLD LLD made in LLD Totals Ci < LLD LLD Period LLD

3. Particulates Gr. Alpha Ci < LLD LLD No Batch LLD Sr-89 Ci LLD LLD Releases LLD Sr-90 Ci LLD < LLD made in LLD Cr-51 Ci LLD LLD Period LLD Mn-54 Ci LLD LLD LLD Co-58 Ci < LLD < LLD LLD Pe-59 Ci LLD LLD LLD Co-60 Ci LLD 1.37E-04 LLD Zn-65 Ci LLD LLD LLD Mo-99 Ci LLD LLD < LLD Cs-134 Ci LLD LLD LLD Cs-137 Ci LLD ( LLD LLD Ce-141 Ci LLD LLD LLD Ce-144 Ci LLD LLD < LLD Ba-140 Ci LLD ( LLD LLD La-140 Ci < LLD LLD < LLD Totals Ci < LLD 1.378-04 LLD 2/5

I , n wt gJ 'h l Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 2 : Effluents Released Table 2A  : LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES Units Quarter Quarter Est. Total 3 4 Error

1. Fission &, Activation Products A. Total Release (not including tritium, Ci 8.25 8-03 5.68 E-03 3.50 8+01 gases, or alpha)

B. Average Diluted Concentration during Period pCi/ml 1.18 8-09 7.52 8-10 C. Percent of Technical Specification Limit 1.64 8-02 1.21 E-02

2. Tritium Total Release Ci 1.23 8+02 3.48 8+02 3.50 8+01 B. Average Diluted Concentration during Period pCi/ml 1.76 8-05 4.60 8-05 C. Percent of Technical Specification Limit 1.76 8+00 4.60 8+00

3. Dissolved and Entrained Gases A. Total Release Ci 3.17 8-04 1 ~ 06 8-02 3.50 8+01 B. Average Diluted Concentration during Period pCi/ml 4.54 E-11 1.40 8-09 C. Percent of Technical Specification Limit 2.27 8-05 7 '1 8-04

4. Gross Alpha Radioactivity Total Release Ci c LLD 3.50 E+01 2/6

e J'I I Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued):, Effluent and Waste Disposal. Report Enclosure 2 : Effluents Released Table 2A  : LIQUID EFFLUBNTS - SUMMATION OF ALL RELEASES Units Quarter Quarter Bst. Total 3 4 Error

5. Volume of water released prior to dilution A. Batch Release liters 3.60 E+06 2.07 E+06 1.00 E+01 B. Continuous Release ,liters 2.13 E+07 1.07 E+07 1.00 B+Ol C. Total Effluent Released liters 2.49 E+07 1.28 E+07 1.00 E+01

6. Volume of dilution water liters 6.96 E+09 7.54 E+09 1.00 B+01 used during period

7. Total Volume Released (Releases + Dilution) liters 6.99 E+09 7.56 E+09 2/7

lg II $l Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 2 : Effluents Released Table 2B : LIQUID EFFLUENTS

1. Fission and V

Activation Products CONTINUOUS BATCH Nuolides Released Units Q3 Q4 Q3 Gr. Alpha Ci LLD < LLD LLD LLD H-3 Ci 2.938-01 3.75E-02 1.23E+02 3.488+02 Fe-55 Ci c LLD LLD 3.068-03 9.46E-04 Ni-63 Ci LLD LLD < LLD I LD Sr-89 Ci LLD LLD LLD LLD Sr-90 Ci < LLD LLD LLD ( LLD Cr-51 Ci LLD < LLD c LLD < LLD Mn-54 Ci c LLD c LLD LLD 9.108-05 Co-58 Ci LLD c LLD 2.278-04 9.008-05 Pe-59 Ci LLD LLD c LLD LLD Co-60 Ci LLD LLD 4.398-04 2.108-03 Zn-65 Ci LLD LLD c LLD LLD Y-93 Ci LLD LLD << LLD LLD Zr-95 Ci LLD ( LLD LLD c LLD Nb-95 Ci LLD LLD LLD << LLD Tc-99m Ci LLD ~ < LLD LLD LLD Mo-99 Ci c LLD LLD < LLD LLD Sb-125 Ci LLD LLD 3.718-03 2.348-03 Te-132 Ci LLD LLD LLD < LLD I"131 Ci LLD c LLD 4.538-04 1.178-04 I-133 Ci LLD LLD c LLD < LLD Cs-134 Ci LLD c LLD 1.70E-04 LLD Cs-137 Ci LLD LLD 1.94E-04 LLD Cs-138 Ci LLD LLD LLD LLD Ce-141 Ci LLD LLD LLD LLD Ce-144 Ci LLD LLD LLD c LLD Ba-140 Ci LLD LLD LLD LLD La-140 Ci LLD < LLD LLD LLD Totals Ci 2.93E"01 3.758-02 1.23E+01 3.488+02 rp I 'k Pj Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 2 : Effluents Released Table 2B : LIQUID EFFLUENTS (Continued)

2. Dissolved and Entrained Gases CONTINUOUS BATCH Nuclides Released Units Q3 Q4 Q3 Q4 Xe-131m Ci < LLD LLD < LLD 4.10E-05 Xe-133 Ci < LLD LLD 3.038-04 1.018-02 Xe-133m Ci LLD < LLD LLD 1.178-04 Xe-135 Ci LLD LLD 1.408-05 3.078-04 Totals Ci LLD < LLD 3.178-04 1.068-02 2/9

4 ra4 +C W4 Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and'Waste Disposal Report Enclosure 3 : Solid Waste Disposal Table 3  : SOLID WASTE AND IRRADIATED FUEL SHIPMENTS Solid Waste Shipped for Burial or Disposal ( WASTE CLASS A ) A. Type of Waste

a. Spent Resin, filter sludge, evaporator bottoms, etc.

Number of Shipments 2 Activity Shipped 1.85 E+01 Ci Estimated Total Error 10%'.37 Quantity Shipped E+00 m~ Solidification Agent N/A Container Type Strong Tight Package NRC-Approved Package Shipment Form Dewatered

b. Dry Compressible Waste, Contaminated Equipment, etc. ( DAW, )

Number of Shipments 61 Activity Shipped 3.63 E-01 Ci Estimated Total Error 10% Quantity Shipped 2.44 E+01 m~ Solidification Agent N/A Container Type Strong Tight Package Shipment Form Dewatered C. Irradiated Components, Control Rods, etc. No waste of this type shipped

d. Other (Describe)

No waste of this type shipped 2/10 "li p I P 4 \- C4 Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 3 : Solid Waste Disposal Table 3  : SOLID WASTE AND IRRADIATED FUEL SHIPMENTS Solid Waste Shipped for Burial or Disposal ( WASTE CLASS A ) B. Estimate of Major Nuclide Composition (by type of Waste) Spent Resin, filter sludge, evaporator bottoms, etc. Percent Total Activity Nuclide Composition Ci H-3 4.30 8-02 7.96 8-03 C-14 2.13 8-03 3.95 E-04 Mn-54 5.95 8+00 1.10 8+00 Fe-55 1.71 8+01 3.16 8+00 Co-58 5.93 8+00 1.10 8+00 Ni-59 3.85 E-01 7.13 8-02 Co-60 2.03 E+01 3.76 8+00 Ni-63 2. 13 E+01 3.95 8+00 Sr-90 2.22 E-02 4.12 8-03 Nb-94 4.15 8-04 7.68 8-05 Tc-99 3.13 E-04 5.79 8-05 Cd-109 3.81 8+00 7.06 8-01 Sb-125 1 '5 E+00 2.32 8-01 Cs-134 1.30 8+01 2.40 8+00 Cs-137 1.10 8+01 2.02 8+00 Pu-241 6.86 8-03 1.27 8-03 Cm-242 1.49 8-04 2.76 8-05 7t f 4y 'r r 'i '1 I fl Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 3 : Solid Waste Disposal Table 3  : SOLID WASTE AND IRRADIATED FUEL SHIPMENTS

1. Solid Waste Shipped for Burial or Disposal ( WASTE CLASS A )

B. Estimate of Major Nuclide Composition (by type of Waste)

b. Dry Compressible Waste, Contaminated Equipment, etc. ( DAW )

Percent Total Activity Nuclide Composition Ci H-3 1.93 E-01 7.05 8-04 C-14 7.21 E-02 2.62 E-04 Fe-55 6. 67 E+01 2.42 E-01 Co-58 4.61 8+00 1.68 8-02 Co-60 2.22 8+01 8.09 8-02 Ni-63 4.30 8+00 1.56 E-02 Mn-54 5.61 E-01 2.04 E-03 Cs-137 5. 89 8-01 2.14 8-03 Ce-144 4.54 E-01 1.65 8-03 Am-241 2.64 8-01 9.59 E-04 Np-237 1.60 8-07 5.90 8-10 Pu-238 5.10 8-05 1.86 E-07 Pu-239 2.80 E-05 1.03 8-07 Pu-240 1.60 8-06 5.70 E-09 Pu-241 1.10 8-04 4.00 8-07 Pu-242 4.30 8-11 1.60 8-13 Am-243 2.80 8-11 1.00 E-13 Cm-242 1.40 8-07 5.10 8-10 Cm-243 7.40 8-12 2.70 8-14 Cm-244 3.00 8-10 1.10 8-12 These values include the activity of ten Special Nuclear Material in-core detectors which were disposed of during the report period. C. Irradiated Components, Control Rods, etc. No waste of this type shipped

d. Other (Describe)

No waste of this type shipped 2/12 i 4I 8 5, 4 I Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 3 : Solid Waste Disposal Table 3  : SOLID WASTE AND IRRADIATED FUEL SHIPMENTS Solid Waste Shipped for Burial or Disposal ( WASTE CLASS A ) C. Solid Waste Disposal Number of Shipments

• 63 Mode of Transportation Truck Destination Barnwel1, S.C.

) The two type 1.A.a shipments were made from the Harris Site. All 61 of the type 1.A.b shipments were made from the Scientific Ecology Group (SEG) processing facility in Oak Ridge, Tennessee. 2/13 h li J , ~5 j4 rf 'l Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued).: Effluent and Waste Disposal Report Enclosure 3 : Solid Waste Disposal Table 3  : SOLID WASTE AND IRRADIATED FUEL SHIPMENTS Solid Waste Shipped for Burial or Disposal ( WASTE CLASS B ) Type of Waste

a. Spent Resin, filter sludge, evaporator bottoms, etc.

Number of Shipments 2 Activity Shipped 1.65 E+02 Ci Estimated Total Error 10%'.37 Quantity Shipped E+00 m~ Solidification Agent N/A Container Type NRC Approved Package Shipment Form Dewatered

b. Dry Compressible Waste, Contaminated Equipment, etc. ( DAW )

No waste of this type shipped C. Irradiated Components, Control Rods, etc. No waste of this type shipped

d. Other (Describe)

No waste of this type shipped 'H f I C-fbi Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 3 : Solid Waste Disposal Table 3  : SOLID WASTE AND IRRADIATED FUEL SHIPMENTS Solid Waste Shipped for Burial or Disposal ( WASTE CLASS B ) B. Estimate of Major Nuclide Composition (by type of Waste) a o Spent Resin, filter sludge, evaporator bottoms, etc. Percent Total Activity Nuclide Composition Ci H-3 6.58 E-02 1.08 E-01 C-14 4.75 E-03 7.84 E-03 Mn-54 5.78 E+00 9.52 E+00 Fe-55 1.87 E+01 3.08 E+01 Co-58 5.91 E+00 9.74 E+00 Co-60 2.15 E+01 3.55 E+01 Ni-59 1.12 E-01 1.85 E-01 Ni-63 2.16 E+01 3.57 E+01 Sr-90 2. 11 E-02 3.48 E-02 Nb-94 1.21 E-04 2.00 E-04 Tc-99 2.98 E-04 4.91 E-04 Cd-109 3.18 E+00 5.24 E+00 Sb-125 1.77 E+00 2.92 E+00 Cs-134 1.05 E+01 1.73 E+01 Cs-137 1.06 E+01 1. 74 E+01 Ce-144 2.03 E-01 3.34 E-01 Pu-238 3.37 E-04 5.55 E-04 PU-239/240 2.32 E-04 3.82 E-04 Am-241 1.49 E-04 2.45 E-04 Pu-241 5.83 E-02 9.61 E-02 Cm-242 6.40 E-OS 1.06 E-04 Cm-243/244 1.92 E-04 3.16 E-04 2/15 J tf >>I p p1 r Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 3 : Solid Waste Disposal Table 3  : SOLID WASTE AND IRRADIATED FUEL SHIPMENTS Solid Waste Shipped for Burial or Disposal ( WASTE CLASS B ) B. Estimate of Major Nuclide Composition (by type of Waste)

b. Dry Compressible Waste, Contaminated Equipment, etc. ( DAW )

No waste of this typed shipped C. Irradiated Components, Control Rods, etc. No waste of this type shipped Other (Describe) No waste of this type shipped C. Solid Waste Disposal Number of Shipments 2 Mode of Transportation Truck Destination Barnwell, S.C. 2/16 tk If V ff k t.f V Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 2 (Continued): Effluent and Waste Disposal Report Enclosure 3 : Solid Waste Disposal Table 3  : SOLID WASTE AND IRRADIATED FUEL SHIPMENTS

3. Solid Waste Shipped for Burial or Disposal ( WASTE CLASS C )

No waste of this type was shipped during this Report Period.

4. Irradiated Fuel Shipments (Disposition)

No irradiated fuel was shipped during this Report Period. 2/17 I

4 gl ij

Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 3  : Changes to Process Control Program (PCP) Technical Specification 6.13 The SHNPP Process Control Program (PCP) was changed on October 14, 1993 to delete the requirements for the plant installed Solid Radwaste System. This system failed to meet the requirements of 10 CFR 61 and has been abandoned. Vendor services are used for solidification and dewatering of radioactive waste. The revised PCP contains the management responsibilities and controls to provide reasonable assurance of complete vendor dewatering and solidification of various radioactive waste. The change did not reduce the overall conformance of the solidified waste product to existing criteria for solid waste. The PCP was reviewed and accepted by the Plant Nuclear Safety Committee on October 6, 1993. Documentation of review and approval is attached. Revision 1 of PLP-300, Process Control Program, is attached. i ~ 'PA REVZBZON 3 10CPR50 ~ 59 PROGRAM A 37 RAHU'TTACHMENT CP&L SAFETY REVIEW PACKAGE Page 7 af PART V: PNSC REVIEW DOCUMENT NO. REV. NO. Determination/Evaluation: ~ p~ oP Ic9-6 c 3 /4z u 'i Action Taken: Basis 'NSC Chaixman: D t'Form AP-01.1-6-A-l) OS2 CAROLINA POWER 6: LIGHT COMPANY SHEARON HARRIS NUCLEAR POWER PLANT PLANT OPERATING MANUAL VOLUME 1 PART 2 PROCEDURE TYPE: PLANT PROGRAM (PLP) NUMBER: PLP-300 TITLE: PROCESS CONTROL PROGRAM REVISION 1 EFFECTS. OCT 1 4 f995 Lo g. go/As~ APPROVED: Signature Date TITLE: GENERAL MANAGER - HARRIS PLANT .i9 I j Q jl OCTO@ 1993 fly DQCU!AR'T CGNTROL HNP CONTROLLED COPY 8~~ Page 1 of 15 OS2 Table of Contents Section ~Pa e 1.0 PURPOSE 4

2. 0 REFERENCES 4 3.0 DEFINITIONS/ABBREVIATIONS 4.0 GENERAL ~ 5 4.1 Review, Approval, and Changes ~ ~ ~ ~ 6 4.2 General Requirements ~... 6 5.0 IMPLEMENTATION 0 7 5.1 Management Responsibilities ~ ~ ~ 7 5.2 Waste Streams 8 5.3 Vendor SolidificationgDewatering Requirements 9 5.4 High Integrity Containers 10 5.5 Reporting of Mishaps 5.6 10 CFR 61 Implementation 12 5.6.1 Waste Classification 10 CFR 61 '5 ~ ~ 12 5.6.2 Radioactive Waste Characteristics 10 CFR 61.56 . . . . . 13 5.6.3 Labeling 10 CFR 61.57 14 5.7 10 CFR 20.2006 Implementation 14 5.7.1 Shipment Manifest 14 5.7.2 Quality Control Program 14 6.0 DIAGRAMS/ATTACHMENTS 14 Attachment 1 - Vendor Process Control Programs 15 PLP-300 Rev. 1 Page 2 of 15

OS2 List of Effective Pa es ~Pa e Revision 1 - 15 ~ ~ ~ ~ ~ ~ 1 PLP-300 Rev. 1 Page 3 of 15 OS2

1. 0 s PURPOSE The pur pose of the Process Control Program (PCP) is to establish the management responsibilities and controls used at Shearon Harris Nuclear Power Plant (SHNPP) to provide reasonable assurance of complete dewatering and solidification of various radioactive waste. This procedure demonstrates compliance with 10 CFR 20, 10 CFR 61, Plant Technical Specifications, Federal and State regulation, burial site requirements and other requirements governing the disposal of radioactive waste. 'he Process Control Program is a requirement of Technical Specification 3/4.11.3 and 6.13.

2.0 REFERENCES

Shearon Harris Nuclear Power Plant Technical Specifications, 3/4 11.3 Solid Radioactive Waste, 6.5.2 Plant Nuclear Safety Committee and 6.13 Process Control Program.

Code of Federal Regulations, Title 10 Part 61, "Licensing Requirements for Land Disposal of Radioactive Waste."

3. Code of Federal Regulations, Title 10 Part 20.2006, "Transfer for Disposal and Manifests."

NUREG-0472, "Radiological Effluent Technical Specification for PWR" - July 1979 NUREG-0133, "Preparation of Radiological Effluent Technical Specification for Nuclear Power Plants."

6. Technical Position on Waste Form (Revision 1) - January 1991

7. HPP-810, Radioactive Material Shipping Manual SHNP-PCP-03-003, SEG Mobile Incontainer Dewatering and Solidification Process Control Program STD-P-05-029, SEG Process Control Program for Incontainer Solidification of Filter Sludge

10. STD-P-05-004, SEG Process Control Program for Incontainer Solidification of Bead Resin 3.0 DEFINITIONS ABBREVIATIONS

1. Batch"= A specific quantity of waste material which can be isolated from further inputs.

2. ~Dewaterin - The process of removing water prom a hed og solid waste. Dewatering processes can also be used to prepare solid waste for shipment without solidification using cement or other chemical agents. Dewatered waste must meet NRC and burial site conditions on maximum drainable liquid content.

PLP-300 Rev. 1 Page 4 of 15

OS2 3.0 DEFINITIONS ABBREVIATIONS (continued)

3. Hi h Inte rit Containers HICs - Container certified by the burial state to meet the stability requirements for wastes requiring stability for disposal.

Liner - A container into which radioactive waste is placed for shipment to the burial site.

ualified Process Control Pro ram - A Process Control Program which the testing to meet 10 CFR 61 requirements is underway or test results have been transmitted to the NRC for approval.

6. Scalin Factor - A scaling factor is the ratio of a hard to

-measure=isotope to an isotope that is easily measured through techniques such as gamma-spectral analysis.

Solidification - The process of mixing waste, pretreatment chemicals, cement and the appropriate additives together to

.produce a free standing solidified material.

Solidification Formulation - The quantities of waste, pretreatment chemicals, cement and additives required to affect solidification.

Also referred to as the recipe.

Stable Waste - Wastes that, by virtue of their radionuclide content, have been dewatered in high integrity containers or solidified using a solidification formulation that results in a solidified product that meets the performance requirements of 10 CFR 61.56, Waste Characteristics.

10. Unstable Waste - Wastes that, by virtue of their radionuclide content, have been dewatered in steel liners or solidified to meet the minimum requirements of 10 CFR 61.56(a).

11. Waste Classification - The determination of a waste class as outlined in 10 CFR 61 by radionuclide isotopic analysis and/or correlation with other measured nuclides.

12. Waste Streams - Radioactive wastes are divt.ded into separate waste streams categories based on scaling factors and characteristics of

'the waste.

4.0 GENERAL The installed plant solidi.fication system at HNP fai,led to meet the requirements of 10 CFR 61 and has been abandoned. Vendor services are used for solidification and dewatering of radioactive waste.

PLP-300 Rev. 1 Page 5 of 15

~ ~

OS2 4.0 GENERAL (continued)

Plant Technical Specification 3/4 11.3 requires the Solid Radwaste System to be used in accordance with a Process Control Program to meet shipping and transportation requirements and disposal site criteria. It is the objective of the HNP Process Control Program to provide reasonable assurance of meeting the applicable shipping, transportation and,disposal site requirements by:

Requiring solidification, dewatering, packaging, waste classification and transportation to be'one in accordance with the HNP Process Control Program and approved plant procedures and/or plant approved vendor procedures.

2. Defining the various solid radwaste waste streams at HNP.

3. Providing management programmatic controls for vendor solidification and dewatering of these waste streams.

4. Implementing the burial site disposal criteria.

5 Implementing a sampling and waste classification system in accordance with 10 CFR 61.55 and 10 CFR 20.2006 Appendix F to 20.1001-20.2401.

6. Providing a quality control program, required by 10 CFR 20.2006 Appendix F to 20.1001-20.2401.

Review A royal and Chan es The HNP Process Control Program shall be reviewed by the PNSC and approved by the NRC prior to implementation. Revision 0 of the HNP Process Control Program was submitted to the NRC in September 1985 and approved in the Shearon Harris SSER.

Changes to the Process Control Program shall be reviewed by the PNSC in accordance with Technical Specification 6.5.2 and 6.13.

Vendor Process Control Programs shall be incorporated into the HNP Process Control Program as an attachment and are subject to the same review by the PNSC as changes to this program.

Changes shall be submitted to the Nuclear Regulatory Commission in the Semiannual Radioactive Effluent Release Report for the period in which the change was made in accordance with Technical Specification 6.13.

Radwaste Dewatering/Solidificat'ion Coordinator shall be responsible for ensuring changes to the Process Control Program are provided to the Manager E&RC or his designee for inclusion in the Semiannual Report.

4.2 General Re uirements All radioactive waste shall be processed, packaged, classified, and shipped to the burial site in accordance with the requirements of the HNP Process Control Program.

PLP-300 Rev. 1 Page 6 of 15

7 OS2 4.2 General Re uirements (continued)

Class A Unstable waste products need only demonstrate that the product is a free standing monolith with no more than 0.5 percent of the waste volume as free liquid. Class A Stable, Class 8 and Class C waste shall meet the stability requirements of 10 CFR 61 or be packaged in a High Integrity Container approved by the burial site.

Solidification and/or dewatering shall be done by qualified individuals who have completed a solidification and/or dewatering training and qualification program.

If solidification does not meet disposal site and shipping/transportation requirements, immediately suspend shipment of inadequately processed-waste and correct the Process Control Program, the implementing procedures, and/or the Solid Waste Processing System to prevent recurrence.

If solidification is not performed in accordance with the HNP Process Control Program, test the processed waste in each container to ensure it meets burial site and shipping requirements and take appropriate actions to prevent recurrence.

With the installed Solid Waste Processing equipment incapable of meeting requirements of Technical Specification 3.11.3 or declared inoperable, restore the equipment to operable status or provide for contract capability to process waste as necessary to satisfy applicable transportation and disposal requirements.

5.0 IMPLEMENTATION The HNP Process Control Program shall be implemented by use of approved plant procedures and plant approved vendor procedures. These procedures shall provide step by step direction for the operation of solidification and dewatering systems and for transportation/disposal of waste at a licensed burial facility. All plant procedures and vendor procedures which implement the Process Control Program shall be reviewed and approved in accordance with Technical Specification 6.5.1.

5.1 Mana ement Res onsibilities

.The General. Manager,- Harris Plant is responsible for ensuring that radioactive waste are processed and shipped in accordance with the appropriate state and federal regulations.

The Manager - Operations is responsible for operations to assure spent resin, radwaste filters, radwaste sludge, and radwaste evaporator concentrates are processed and packaged in accordance with Technical Specification 3/4.11.3, the process control program and plant procedures.

The Manager - E&RC is responsible for assuring:

Y 0 a Other radioactive wastes are processed and packaged in accordance with Technical Specification 3/4.11.3, the process control program and plant procedures.

PLP-300 Rev. 1 Page 7 of 15

OS2 5.1 Mana ement Res onsibilities (continued)

Radioactive wastes are stored and shipped in accordance with plant procedures; and the state, burial site and federal regulations.

c Radioactive wastes are sampled and classified in accordance with 10 CFR 61.

The Radwaste Dewatering/Solidification Coordinator is responsible for:

a Advising the General Manager, Manager Operations, and Manager E&RC on the appropriate technical standards, regulations, and requirements as related to solidification and dewatering of radioactive waste.

b. Ensuring the vendor's Process Control Program and solidification/dewatering procedures are reviewed and approved as required.

c, Retaining vendor supplied documentation for NRC inspection and review.

Ensuring changes to the Process Control Program are provided to Manager E&RC for inclusion in the Semiannual Report.

5. The Manager E&RC Support is responsible for advising the General Manager and Manager E&RC on the appropriate technical standards, regulations, and requirements as related to storage and shipment of radioactive waste.

5.2 Waste Streams Radioactive wastes are divided into separate waste stream categories based on scaling factors and characteristics of the

"'"waste. Waste streams at HNP include, but are not limited to:

a Dry Active Waste (DAW)

Radwaste Filters c, Radwaste Resin/Charcoal CVCS Resin/BTRS Resin/Spent Fuel Pool Resin Sludge Evaporator Concentrates Spent Fuel Pool Charcoal Spent Fuel Pool Filters PLP-300 Rev. 1 Page 8 of 15

OS2 5.2 Waste Stream (continued)

i. Decontamination Waste j . Oil For the purpose of the HNP Process Control Program, a batch is a specific quantity of a particular waste stream which can be isolated from further inputs. This may be the volume in a tank or in a liner.

5.3 Vendor Solidification Dewaterin Re uirements Prior to performing solidificationgdewatering services at HNP, the vendor shall provide documentation on the following for CP&L review, evaluation, and retention:

a A qualified process control program or a program approved by the NRC. For each low-level radioactive waste formulation, the PCP should address the boundary conditions for processing the waste to provide reasonable assurance that the final waste form will meet 10 CFR 61 stability requirements.

b. Topical Report for SolidificationgDewatering including review and acceptance letter from the NRC.

Copy of the 10 CFR 61 Testing Program to meet stability requirements including submittal letter or NRC approval letter. This is not required if the vendor only performs dewatering service or solidification of waste not requiring stability.

d. Sketch or drawing of the solidificationgdewatering process system.

Detailed procedures for operation of the solidificationgdewatering equipment and inspection and use of containers.

Documentation that the operator has been qualified in accordance with the vendor's solidificationgdewatering training and qualification program.

Identification of solidification agent(s) and formulation used by the process.

Copies of chemical fact sheet(s) for all chemicals that will be used by the vendor.

Certificate of Compliance for any High Integrity Containers and a list of incompatible waste.

PLP-300 Rev. 1 Page 9 of 15

OS2 5.3 Vendor Solidification Dewaterin Re uirements (continued)

2. The vendor is accountable to the Radwaste Dewatering/Solidification Coordinator for the solidification and/or dewatering of liquid waste, The E&RC unit is responsible for shipping of solidified and dewatered wastes. The vendor and the E&RC Shipping Supervisor may communicate on these matters as necessary.

Solidification and/or dewatering shall be done by qualified individuals who have completed a solidification and/or dewatering training and qualification program. Certification shall be provided by the vendor for vendor operators and shall be on file prior to any solidification/dewatering work performed by the individual.

As required by Technical Specification surveillance requirement 4.11.3, a test solidification of at least every tenth batch of each type of wet radioactive waste shall be performed.

Test solidification of every batch may be performed if desired.

5. If any test specimen fails to verify solidification, the solidification of the batch under test shall not be performed until such time as additional test specimens can be obtained, alternative solidification parameters can be determined, and a subsequent test verifies solidification. Solidification of the batch may then be resumed using the alternative solidification parameters.

If the initial test specimen from a batch of waste fails to verify solidification, then representative test samples shall be collected from each consecutive batch of the same type of wet waste until at least three consecutive initial test specimens demonstrate solidification.

For high activity waste, where handling samples could result in personnel radiation exposures which are inconsistent with ALARA principles, representative non-radioactive samples may be test solidified. These samples shall be as close to the actual ~aste and chemical properties as possible. For resins, the resin beads shall be depleted prior to test solidification.

=-The quality of the solidified and/or dewatered product shall meet or exceed regulatory requirements and the disposal 'site criteria prior to release from the HNP site. Copies of the site disposal criteria shall be maintained by the Radwaste Dewatering/Solidification. Coordinator and Radwaste Shipping. This site disposal criteria requirements are implemented as requirements by reference from this Process Control Program.

5' Hi h Inte rit Containers With the approval from the land disposal facility, ~astes may be disposed of in approved high integrity containers (HICs).

Certificate of Compliance from the disposal facility shall be on file prior to use of any high integrity containers.

PLP-300 Rev. Page 10 of 15

OS2 5.4 Hi h'Inte ri Containers (continued)

2. The maximum allowable free liquid in a high integrity container shall be less than one percent of the waste volume.

3. Corrosion and chemical tests should be performed to confirm the suitability of the proposed container. List of prohibited contents should be available. If it is suspected that the waste may contain any of the prohibited chemicals, chemical tests shall be run to verify the absence of the chemical. As a minimum, the waste pH shall be determined to be within the acceptable range for the HIC.

4, Written procedures or documentation for use, inspection and storage of HIC shall be provided by the manufacturer/supplier.

5. The length of on-site storage of HICs may vary depending on the type of container. Procedures for use and storage of HICs should contain maximum storage times. Photosensitive containers shall be kept out of direct sunlight and away from any other sources of ultraviolet radiation.

6. HICs shall be inspected prior to use.

5.5 Re ortin of Misha s Any knowledge of misuse or failure of waste forms and containers shall be reported to the NRC's Director of the Division of Low Level Waste Management and Decommissioning and the designated State disposal site regulatory authority within 30 days of the knowledge of the incident.

Adverse Condition Report shall be completed and sent to Regulatory Compliance Unit. For any such waste form mishap occurrence, the affected waste. form should not be shipped off-site until approval is obtained from the. disposal site regulatory authority. Such mishaps include, but are not necessarily limited to:

The failure of high integrity containers used to ensure structural stability. Such failure may be evidenced by changed container dimensions, cracking, or injury from mishandling.

2. The misuse of high integrity containers, as evidenced by a quantity of free liquid greater than one percent of container volume, or an excessive void space within the container.

The production of solidified Class A Stable, Class B or C waste form that has any of the, following characteristics:

a. Greater than 0.5 percent volume of free liquid.

b. Concentrations of radionuclides greater than the concentrations demonstrated to be stable in the waste form in qualification testing accepted by the regulatory agency.

Greater or lesser amounts of solidification media than were used in qualification testing accepted by the regulatory agency.

PLP-300 Rev. 1 Page ll of 15

OS2 5.5 Re ortin of Misha s (continued)

d. Contains chemical ingredients not present or accounted for in qualification testing accepted by the regulatory agency.

Shows instability evidenced by crumbling, cracking, spalling, voids, softening, disintegration, non homogeneity, or change in dimensions.

Evidences processing phenomena that exceed the limiting processing conditions identified in applicable topical reports or process control programs, such as foaming, excessive temperature, premature or slow hardening, production of volatile material.

5.6 10 CFR 61 Im lementation Solidified radioactive waste packaged for disposal at a licensed burial facility shall meet the requirements of Title 10 Code of Federal Regulations Part 61.

5'.6.1 Waste Classification 10 CFR 61.55 is determined to for near-surface it contains anygenerally Waste be unacceptable disposal if of the radionuclides listed in Table 1 and 2 of 10 CFR 61.55 in concentrations exceeding the limits.

established for the radionuclides. Compliance with these limits shall be determined prior to shipment.

2. Waste transported for disposal must be classified as Class A, Class B, or Class C for the purpose of segregation at the disposal site. The waste class is based on the concentration of certain radionuclides-in the waste form as given in 10 CFR 61.55.

3. Waste shall be classified based on isotopic analysis and the use of scaling factors for hard to measure isotopes. Initially, generic scaling factors will be used for waste, classification.

Each waste stream shall then be sampled after the first three months of commercial operation or prior to the first shipment if generated after the first three months of commercial operation.

4. Confirmatory sampling for Class A waste shall be performed on a bi-annual basis. Class B and Class C wastes shall be sampled for confirmation of scaling factors at least on an annual basis.

These frequencies may be extended based on fuel performance factors influencing the affected waste stream. Samples shall not be required if the waste stream is not generated during the sampling frequency. These infrequently generated waste stream shall be sampled and the scaling factors updated prior to shipment. In addition, a waste stream shall be sampled determined that a factor of 10 shift in any scaling factor has if it is occurred in that waste stream.

PLP-300 Rev. 1 Page 12 of 15

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OS2 5.6.1 Waste Classification 10 CFR 61.55 (continued)

5. If the plant is in an outage period at the same time the sampling period is due, the sampling period may be delayed until after the outage period. Resampling should not be completed until after two months at full power operation, to allow the reactor water chemistry and waste stream characteristics to stabilize.

6. A'omputerized waste classification and shipping program is normally used to determine waste classification from isotopic analysis and the scaling factors. Manual methods may be used if computer system is not available. Waste Classification is

'he controlled by plant procedure HPP-810, Radioactive Material Manual. 'hipping 5 '.2 Radioactive Waste Characteristics 10 CFR 61.56

1. The eight minimum waste characteristic identified in 10 CFR 61.56(a) and listed below shall apply to any waste solidified or dewatered at HNP.

a0 Waste must not be packaged for disposal in cardboard or fiberboard boxes.

b. Liquid waste must be solidified or packaged in sufficient absorbent material to absorb twice the volume of the liquid.

c, ~ Solid waste containing liquid shall contain as little free standing and noncorrosive liquid as is reasonably achievable, but in no case shall the liquid exceed 1% of the volume.

d. Waste must not be readily capable of detonation or of explosive decompensation or reaction at normal pressures and temperatures, or of explosive reaction with water.

e. Waste must not contain, or be capable of generating, quantities of toxic gases, vapors, or fumes harmful to persons transporting, handling, or disposing of the waste.

Waste must not be pyrophoric. Pyrophoric materials contained in waste shall be treated, prepared, and package to be nonflammable.

ge Waste in a gaseous form must be packaged at a piessure that does not exceed 1.5 atmospheres at 20'C. Total Activity must not exceed 100 curies per container.

h. Waste containing hazardous, biological, pathogenic, or infectious material must be treated to reduce to the maximum extent practicable the potential hazard from the non-radiological materials.

Waste stability requirements are assured by the requirement in section 5.3 for the vendor to provide a copy of the 10 CFR 61 Testing Program for Waste Stability.

PLP-300 Rev. 1 Page 13 of 15

t OS2 5.6.3 Labelin 5.7 10 CFR 61.57 Each package of waste shall be clearly labeled to identify the appropriate waste classification in accordance with Section 5.6.1.

10 CFR 20.2006 Im lementation Radioactive waste transferred for disposal by Shearon Harris Nuclear Power Plant shall meet the requirements of 10 CFR 20.2006 and Appendix F'o 20.1001-20.2401.

5.7.1 Shi ment Manifest The requirements of 10 CFR 20.2006 and Appendix F to 20.1001-20.2401.for shipment manifest and record keeping shall be included in the appropriate E&RC shipping procedures.

5.7.2 uali Control Pro ram I The quality control program consists of required use of plant procedures which implement the Process Control Program and audits",~'-

by personnel independent of the activities. I

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2. The Process Control Program and implementing procedures for processing and packaging radioactive wastes are audited once per 24 months by the Nuclear As.essment Department in accordance with Plant Technical Specification 6.5.4.1. These audits shall be

'eviewed by E&RC Manager.

6,0 DIAGRAMS ATTACHMENTS Attachment 1 - Vendor Process Control Programs PLP-300 Rev. 1 Page 14 of 15

OS2 Attachment 1 Vendor Process Control Pro rams SEG Mobile Incontainer Dewatering and Solidification Process Control Program (SHNP-PCP-03-003)

SEG Process Control Program for Incontainer Solidification of Filter Sludge (STD-P-05-029)

SEG Process Control Program for Incontainer Solidification of Bead Resin (STD-P-05-004)

These procedures contain vendor proprietary information and access is controlled. For access to procedures, contact Radwaste Dewatering/Solidification Coordinator or Manager Radwaste.

PLP-300 Rev. 1 Page 15 of 15

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 4  : Changes to the Offsite Dose Calculation Manual (ODCM)

Technical Specification 6.14 The following change to the Off-Site Dose Calculation Manual (ODCM) was made during this Report period.

ODCM Change 3/8 incorporated the 1993 Land Use Census into the ODCM document and also increased the permitted release concentration to 10 times the 10 CFR 20 Effluent Concentration (EC) limits (Appendix B, Tablemadel' 2, Column 2) for individual releases. This change was authorized by SHNPP License Amendment No. 40.

The ODCM change is attached and includes a full description of the changes that were

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ODCM Change AC 3/8 Impact of Changes The change to Table 3.2-2 is a routine change to update information and will have no impact on the ODCM.

A Technical Specification Change to T.S. 3.11.1.1 to increase the release rate to 10 times the 10CFR20 limit has been submitted to the NRC for review and approval. Since NRC approved change to the Technical Specifications are not unreviewed safety questions, this change to the ODCM cannot be an unreviewed safety question.

The ODCM is an administrative program set up to control the release of radioactive effluents to the environment. Nothing in the ODCM is concerned with the safe shutdown of the plant or the mitigation of any analyzed accident. These- changes to the ODCM do not:have any affect on the probability of occurrence or the consequences of any analyzed accident. No equipment important to safety is affected in any way, nor is any possibility of a different accident created. This change does not have any impact any Technical Specification margin of, safety since there will

'n be no change to the effluent mix or quantity.

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Description of Changes to the ODCM ODCM Change 3/8 Section Page 3-18 Update Table 3.2-2 to reflect the results of the 1993 Land Use Census.

Section 2.0 Page 2-1, 2-4, 2-5, 2-6 Revise the wording to say that the release rate for licpxid effluents is ten times (10x) the limit specified in 10 CFR 20, Appendix B, Table 2, Column 2. The annual average limit, which is what the Appendix B values are based on, will not change and we are still limited to this value on an annual average basis.

ODCM Software EC Data Table The values in the EC data table have increased by a factor of 10, except for dissolved and entrained gases, which will remain at 2E-04 uCi/ml. As these values are data. in a table, they are not included in this package.

OS2 SHEARON HARRIS NUCLEAR POWER PLANT OFF-SITE DOSE CALCULATIONMANUAL (ODCM)

Revision 3 Advance Change 3/8 Docket No. STN-50-400 CAROLINA POWER 6c LIGHT COMPANY PNSC Chairman's Approval Effective Dete

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OS2 2.0 LI UID EFFLUENTS Radioactive materials released in liquid effluents from SHNPP to unrestricted areas are required to implement 10 CFR 50 Appendix I (Technical Specification 3.11.1.2) and, on an annual average basis, be limited to the concentrations specified in 10 CFR 20, Appendix B, Table 2, Column 2 (Technical Specification 3.11.1.1). For dissolved or en-trained noble gases the concentration shall be limited to 2E-4 pCi/ml total activity. On an individual release basis, the release concentration for liquid effluents will be limited to ten times (10x) the concentrations specified in 10 CFR 20, Appendix B, Table 2, Column

2. The liquid effluent release point is at the point of discharge from the Cooling Tower Blowdown Line into Harris Lake (see Figure 2.1-3 and T/S Figure 5.1-3). As of January 1, 1993, these values are EC values.

Radioactive liquids are routinely released as batches from the Waste Monitor Tank (WMT), Waste Evaporator Condensate Tank (WECT), and Treated Laundry and Hot Shower Tank (TLGHST);- Batch releases may also originate from the Secondary Waste Sample Tank (SWST). These tanks are shown in Figures 2,1-1 and 2.1-2. Effluent monitor identification numbers are provided in Appendix C. Liquid effluent dilution prior to release to Harris Lake is provided by the Cooling Tower Blowdown Line. Con'current batch releases should not normally occur at SHNPP.

Continuous releases are routinely permitted from the SWST and the Normal Service Water (NSW) system because a low potential for radioactive contamination exists. These releases are checked by effluent monitors on the SWST (Figure 2.1-2) and the NSW lines (Figure 2.1-3).

The turbine building floor drains and the outside tank area drains (Figure 2.1-4) are monitored effluent lines with low probability of radioactive contamination.

The radioactive liquid waste sampling and analysis required for batch and continuous releases are found in Table 4.11-1 of the Technical Specifications.

DCM/ODC-2 2-1 Rev. 3.0

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OS2 2.1.1 Batch Releases (continued)

Radioactivity concentration of radionuclides in the liquid effluent prior to dilution (pCi/ml) from analysis of the liquid effluent to be released or from composite sample analysis.

MPC MPC~, MPC MPC MPC~, and MPH, zz are 10 times the most restrictive values for the appropriate gamma (g)- and alpha (a)-

emitting, and strontium (s) radionuclides, and for tritium (t), and Fe-55, from 10 CFR 20, Appendix B, Table 2, Column 2.

As of January 1, 1993, these values are EC values.

The measured concentration of each gamma-emitting radionuclide observed by gamma spectroscopy including noble gases, pCi/ml. If no gamma activity is pe detectable then assume a Cs-134 activity s/~

of 9E-07 pCi/ml and proceed to the Set Point Calculation Method: Cs-134.

The measured concentration of alpha-emitting radionuclides as determined by gross alpha analysis of the previous monthly composite sample, pCi/ml.

Cs The measured concentration of Sr-89 and Sr-90 as determined by analysis of the previous quarterly composite sample, pCi/ml.

DCM/ODC-2 2-4 Rev. 3.0

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OS2

.2.1.1 Batch Releases (continued)

C, The measured concentration of H-3 as determined by analysis of the liquid effluent or previous monthly composite sample, pCi/ml.

Cpe-55 The measured concentration of Fe-55 as determined by analysis of the previous quarterly composite sample, pCi/ml.

'A spfety factor used to assure that the radionuclide concentrations are approximately 50% of 10 times the limits specified in 10 CFR 20, Appendix B, Table 2, Column 2 at the point of discharge.

3. Maximum Batch Release R'ate (2.1-5) where:

MRR Maximum release rate of the tank batch, gpm B Cooling tower blowdown dilution flow rate. The minimum dilution flow rate for each setting is shown in Table 2.1-2.

4.7E+03 gpm nominal average flow rate based on measured release rate data during January 1989.

Do Minimum acceptable dilution factor DCM/ODC-2 2-5 Rev. 3.0

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OS2 2.1.1 Batch Releases (continued)

Fraction of the available dilution volume which may be assigned to a particular release to ensure discharge point limits are not exceeded by simultaneous radioactive liquid releases.

The value of T~ is based on assumed operational considerations for simultaneous releases but normally will be 0.8 for a batch release and 0.2 for a continuous release.

Available Dilution Factor The Available Dilution Factor, D,l, represents the cooling tower blowdown flow rate available during the t:ime of a batch release to dilute the tank activities to or below the Technical Specification limit:s.

B + RR avl (2.1-6) where:

Davl Available dilution factor Tank release rate, gpm The lower. value between the calculated MRR and the pump discharge capacity in 'Table 2.1-1.

5. Prerelease Criteria For Permitting Batch Releases Compliance with 10 CFR 20 - Based Technical Specifications Technical Specification 3.11.1.1 requires that 10 times the values of 10 CFR 20, Appendix B, Table 2, Column 2 are not exceeded at the point of discharge for any radionuclide in a release. Therefore, DCM/ODC-2 2-6 Rev. 3'

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OS2 Table 3.2-2 Distance to the Nearest Special Locations for the Shearon Harris Nuclear Power Plant (miles)~

(Comparison of 1992/1993 Data)

Residence Milk Animal Garden Meat Animal Exclusion Sector Boundary 1992 1993 1992 1993 1992 1993 1992 1993 N 1.32 2.2 2.2 2.2 2.2 2.2 2.8 2.2 2.2 1.33 1.8 1.7 1.7 3.1 2.2 NE 1.33 2.3 2.3 2.3 2.'3 '2.3 2' ENE 1.33 3.6 1.8 3.8 3.6 1.33 1.9 1.8 4.7 2.0 2;2 2.0 ESE 1.33 2.7 2.6 4.7 4.4 4.2 SE 1.33 4.3. 2.6 4. 4" 4'..1=. 4. 3 4.1 SSE 1.33 4.4 4.2 ,4.6 4.3 1.36 5.3 5.3 ~

-5.3 SSW 1.33 3.9 3.9 3.9 3.9 SW 1.33 2.8 2.9 2.8 2.9 WSW 1.33 4.3 4.3 1.33 2.8 3.0 2' 3.1 2.9 3.1 1.33 2.1 2.3 2.1 2.3- '.6 1.26 2.4 3.8 2.7 3.8 3.7 NNW 1.26 1.5 1.6 1.7 2.0 1.7 2' As of June, 1993.

Distance estimates are + 0.1 miles except at the exclusion boundary.

Distances and sectors determined by Global Positioning System.

DCM/ODC-3 3-18 Rev. 3.0

il Semiannual Radioactive Effluent Release Report Guly 1, 1993 to December 31, 1993 Appendix 5 : Changes to the Environmental Monitoring Program Enclosure 1 : Environmental Monitoring Program Technical Specifications 3.11.2.3 3.12.1 3.12.1.c The Land Use Census observed a new garden in the NE sector. The position of the garden was determined using a global positioning system (GPS) . When the location of the garden was processed by the XOQDOQ program, value greater than that for the it produced a D/Q garden currently being sampled in the NNW sector.

A new food crop Location 462 was created and sampling began in August, 1993.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 5 : Changes to the Environmental Monitoring Program Enclosure 2 : Land Use Census Technical Specifications 3.12.2.a

3. 12.2.b No changes were made to the Land Use Census during this Report period.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 6 : Additional Technical Specification Responsibilities Enclosure 1 : Inoperability of Liquid Effluent Monitors Technical Specification 3.3.3.10, Action b Monitors Out-of-Service ),30 Days During this Report Period No liquid effluent monitoring instrumentation specified in Technical Specification Table 3.3-12 was inoperable for greater than 30 Days during this Report period.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 6 (Continued): Additional Technical Specification Responsibilities Enclosure 2 : Inoperability of Gaseous Effluent Monitors Technical Specification 3.3.3.11, Action a Monitors Out-of-Service > 30 Days During this Report Period HAIC-21WG-1118AW, the A-train Hydrogen recombiner H~ monitor, was out of service for greater than 30 days during this report period. The monitor was inoperable due to the successive failures of several components. One of the components was obsolete, so an evaluation had to be performed on its replacement. During the time that this monitor was inoperable, the B-train monitor was operable and providing all required monitoring for all but 13 days.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 6 '(Continued): Additional Technical Specification Responsibilities.

Enclosure 3 : Unprotected Outdoor Tanks Exceeding Limits Technical Specification 3.11.1.4, Action a No unprotected outdoor tank exceeded the Technical Specification limit during this Report period.

6/3

Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 6 (Continued): Additional Technical Specification Responsibilities-4 : Gas Storage Tanks Exceeding Limits 'nclosure Technical Specification 3.11.2.6, Action a No gas storage tank exceeded the Technical Specification limit during this Report period.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 7 : Major Modifications to Radwaste System Technical Specification 6.15.1 No major modifications were made to the Radwaste System during this Report period.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 8 : Meteorological Data Technical Specification 6.9.1.4 As allowed by the Footnote to Technical Specification 6.9.1.4, the annual summary of meteorological data will be retained in a filch This data will be provided to the NRC upon request.

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Semiannual Radioactive Bffluent Release Report July 1, 1993 to December 31, 1993 Appendix 9  : Assessment of Radiation Doses Enclosure 1: Population Doses Outside Site Boundary Due to Effluent Releases

1. Integrated Population Dose Due to Liquid Effluents (man-rem)

A. 50 mile Ingestion Zone 1993 Bone Liver W. Body Thyroid Kidney Lung GZ-LLI Skin Sport Fish 4.17 E-02 8. 17 E-02 5.65 E-02 2.02 8-02 3.98 8-02 2.75 8-02 2.72 E-02 0 F 00 8+00 Com Fish 0.00 8+00 0.00 8+00 0.00 Ejoo 0.00 8+00 0.00 8+00 0.00 8+00 0.00 8+00 0.00 E+00 Sport Invert 0.00 8+00 0.00 8+00 0.00 8+00 0.00 E+00 0.00 8+00 0.00 8+00 0.00 8+00 0.00 8+00 Com Invert 0.00 8+00 0.00 8+00 0.00 Bj00 0.00 E+00 0.00 8+00 0.00 8+00 0.00 8+00 0.00 E+00 Drinking water 3.31 E-03 1.30 E+00 1.30 8+00 1.30 E+00 1.30 8+00 1.30 8+00 1.31 8+00 0.00 8+00 Shoreline 2.01 E-02 2.01 8-02 2.01 8-02 2.01 8-02 2.01 8-02 2.01 E-02 2.01 E-02 2.35 8-02 Swimming 1.23 8-04 1.23 E-04 1.23 8-04 1.23 8-04 1.23 8-04 1.23 E-04 1.23 E-04 0.00 E+00 Boating 6.16 E-05 6.16 E-05 6.16 E-05 6.16 8-05 6.16 8-05 6.16 E-05 6.16 8-05 0.00 8+00 Zrri Veg 0.00 E+00 0 F 00 E+00 0.00 E+00 0.00 8+00 0.00 E+00 0.00 8+00 0.00 8+00 0.00 8+00 Irri Leafy veg Irri Milk 0.00 0.00 8+00 0.00 0.00 8+00 0.00 E+00 0.00 8+00 0.00 E+00 0.00 8+00 0.00 E+00 0.00 8+00 8+00 E+00 0.00 8+00 0.00 8+00 0.00 E+00 0.00 8+00 0.00 8+00 0.00 E+00 Irri Meat 0.00 E+00 0.00 8+00 0.00 8+00 0.00 8+00 0.00 8+00 0.00 8+00 0.00 8+00 0.00 8+00 All Pathways 6.54 8-02 1.41 E+00 1 '8 8+00 1.34 E+00 1.36 E+00 1.35 E+00 1.36 8+00 2.35 8-02 B. Tritium (Hydrosphere)

Bone Liver W. Body Thyroid Kidney Lung GZ-LLZ Total 0.00 E+00 7.41 8-03 7.41 8-03 7.41 E-03 7.41 8-03 7.41 8-03 7 '1 8-03

2. Integrated Population Dose Due to Gaseous Effluents (man-rem) 50 mile Ingestion Zone W. Body GZ-LLZ Bone Liver Kidney Thyroid Lung Skin Plume 6.873E-02 6.873E-02 6.873E-02 6.8738-02 6.8738-02 6.8738-02 .3438-02 . 7978-01 Ground Plane 3.754E>>03 3.7548-03 3.7548-03 3.7548-03 3.7548-03 3.7548-03 .754E-03 .4168-03 Inhalation 8.6408-02 8.6458-02 2.3998-07 8.6408-02 8.640E-02 8.650E-02 .7668-02 .6408-02 Vegetation 3.0098-'02 3. 016E-02 1 '09E-07 3.0088-02 3.0078-02 3. 0128-02 .0078-02 .0078-02 Cow Milk 1.0618-02 1.062E-02 1.8188-07 1. 0618-02 1.061E-02 1.068E-02 .0618-02 .0618-02 Meat R Poultry 1.3608-02 1.3688-02 1.350E-08 1.3608-02 1.359E-02 1.3608-02 .359E-02 .3598-02 2.1328-01 2.1348-01 7.248E-02 2.1328-01 2.1328-01 2.1348-01 2.1918-01 4.2488-01

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 9 : Assessment of Radiation Doses Enclosure 2:-Doses to General Public Due to Activities Inside Site Boundary

1. Individual Dose Due to Liquid Effluents (mrem/yr.)

Bone Liver W. Body Thyroid Kidney Lung Gi-LLI Skin ADULT Pish 4.608-02 9.898-02 7.808-02 2.628-02 4. 948-02 3.43E-02 3.59E-02 Drinking 2.408-05 1.228-02 1.228-02 1.228-02 1. 218-02 1.218-02 1.23E-02 Shoreline 2.138-03 2. 138-03 2. 13E-03 2.138-03 2.13E-03 2.138-03 2.13E-03 2.488-03 Swimming 1.348-04 1.348-04 1.348-04 1.348-04 1.348-04 1.34E-04 1.34E-04 Boating 1.538-04 1.538-04 1.538-04 1.538-04 1.538-04 1 '38-04 1.53E-04 4.848-02 1. 138-01 9.25E-02 4.088-02 6.398-02 4.898-02 5.06E-02 2.488-03 TEEN Fish 4.868-02 9.53E-02 4.988-02 2.03E-02 4.418-02 3. 018-02 2.70E-02 Drinking 2.318-05 8.588-03 8.588-03 8.588-03 8.578-03 8.578-03 8.648-03 Shoreline 1.198-02 1.198-02 1. 198-02 1.198-02 1.19E-02 1.19E-02 1.19E-02 1.398-02 Swimming 2.008-04 2.008-04 2.008-04 2.008-04 2.008-04 2.00E-04 2.00E-04 Boating 2.238-04 2.23E-04 2.238-04 2.238-04 2.238-04 2.23E-04 2.238-04

6. 108-02 1.168-01 7 '68-02 4.118-02 6.498-02 5.10E-02 4.79E-02 1.39E-02 CHILD Fish 6.078-02 8.318-02 2.878-02 1.698-02 3.708-02 2.468-02 1.898-02 Drinking 6.828-05 1.64E-02 1.648-02 1.64E-02 1.64E-02 1.648-02 1.65E-02 Shoreline 2.488-03 2.488-03 2.488-03 2.488-03 2.488-03 2.488-03 2.488-03 2.908-03 Swimming 6.688-05 6.688-05 6.688-05 6.688-05 6.688-05 6.688-05 6.688-05 Boating 8.358-05 8.358-05 8.358-05 8.358-05 8.358-05 8.358-05 8.358-05 6.348-02 1. 028-01 4.788-02 3.598-02 5.608-02 4.368-02 3.808-02 2.90E-03 INFANTS are assumed to have no exposure via this pathway.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 9  : Assessment of Radiation Doses Enclosure 2 (Continued): Doses to General Public Due to Activities Inside Site Boundary

2. Individual Dose Due to Gaseous BfFluents (mrem/yr.)

W. Body GZ-LLZ Bone Liver Kidney Thyroid Lung Skin ADULT Plume 2.8368-03 2.8368-03 2.8368-03 2. 8368-03 2.8368-03 2.8368-03 2.9028-03 6.6008-03 Ground Plane 2 . 1198-04 2. 1198-04 2.1198-04 2. 1198-04 2.1198-04 2. 119E-04 2. 1198-04 2.493E-04 Inhalation 9. 0658-04 9.0738-04 2.7078-09 9.0658-04 9.064E-04 9.0778-04 9.2518-04 9.0648-04 3.9548-03 3.955E-03 3.0488-03 3.954E-03 3.954E-03 3.9558-03 4.0398-03 7.7568-03 TEENAGER Plume 2.8368-03 2.8368-03 2.8368-03 2.8368-03 2.8368-03 2.8368-03 2.9028-03 6.6008-03 Ground Plane 2.1198-04 2.119E-04 2.1198-04 2.1198-04 2.1198-04 2.1198-04 2.1198-04 2.4938-04 Inhalation 9.1228-04 9.1308-04 3.8078-09 9.1228-04 9.122E-04 9.137E-04 9.394E-04 9.1228-04 3.9608-03 3.9618-03 3.0488-03 3.960E-03 3.9608-03 3.9618-03 4.053E-03 7.7628-03 CHILD Plume 2.8368-03 2.8368-03 2. 8368-03 2. 8368-03 2. 8368-03 2.8368-03 2.9028-03 6.6008-03 Ground Plane 2.1198-04 2.1198-04 2.1198-04 2.1198-04 2.1198-04 2.119E-04 2. 1198-04 2.493E-04 Inhalation 8.0678-04 8.0698-04 5.1698-09 8.0678-04 8.0668-04 8.0838-04 8.2878-04 8.0668-04 3.8548-03 3.8558-03 3.0488-03 3.8548-03 3.8548-03 3.8568-03 3.943E-03 7.6568-03 INFANT Plume 2 . 8368-03 2.8368-03 2.8368-03 2.8368-03 2.8368-03 2.8368-03 2.9028-03 6.6008-03 Ground Plane 2 . 1198-04 2.1198-04 2. 1198-04 2.1198-04 2. 119E-04 2. 1198-04 2. 1198-04 2.4938-04 Inhalation 4 . 6398-04 4.6398-04 4.0828-09 4.6398-04 4.6388-04 4.6548-04 4. 7798-04 4.6388-04 3.5118-03 3.512E-03 3.0488-03 3.511E-03 3.5118-03 3.5138-03 3.5928-03 7.3148-03 9/3

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 9 : Assessment of Radiation Doses Enclosure 3: Doses to Likely Most Exposed Member of the Public

1. Individual Dose Due to Licpxid Effluents (mrem/yr.)

ADULT Bone I iver W. Body Thyroid Kidney Lung GI-LLI Skin Fish 4.608-02 9.898-02 7.80E-02 2.628-02 4.948-02 3.438-02 3.598-02 Drinking 2.408-05 1.228-02 1.22E-02 1.228-02 1.21E-02 1.218-02 1.23E-02 Shoreline 2. 138-03 2.138-03 2.13E-03 2.13E-03 2.138-03 2.138-03 2. 138-03 2.488-03 Swimming 1.348-04 1.348-04 1.34E-04 1.348-04 1.348-04 1.348-04 1.348-04 Boating 1.53E-04 1.538-04 1.538-04 1.538-04 1.538-04 1.538-04 1.538-04 4 . 848-02 1.138-01 9.258-02 4.088-02 6.39E-02 4 . 898-02 5.06E-02 2.488+03 TBEN Fish 4.86E-02 9.53E-02 4.988-02 2.038-02 4.418-02 3.01E-02 2.70E-02 Drinking 2.31E-05 8.588-03 8.588-03 8.58E-03 8.578-03 8.578-03 8.648-03 Shoreline 1.198-02 1.198-02 1.19E-02 1. 19E-02 1.198-02 1. 198-02 1.198-02 1.398-02 Swimming 2.008-04 2.008-04 2.008-04 2.008-04 2.008-04 2.008-04 2.008-04 Boating 2.238-04 2.23E-04 2.238-04 2.238-04 2.238-04 2.238-04 2.238-04 6.108-02 1. 16E-01 7.068-02 4.118-02 6.49E-02 5.108-02 4.798-02 1.398-02 CHILD Fish 6.078-02 8.31E-02 2.878-02 1.698-02 3.708-02 2.46E-02 1.89E-02 Drinking 6.828-05 1.64E-02 1.648-02 1.648-02 1.648-02 1.64E-02 1.658-02 Shoreline 2 '88-03 2.488-03 2.48E-03 2.48E-03 2.488-03 2.48E-03 2.48E-03 2.908-03 Swimming 6.688-05 6.688-05 6.688-05 6.688-05 6.688-05 6.68E-05 6.688-05 Boating 8.358-05 8.35E-OS 8.358-05 8.358-05 8.358-05 8.358-05 8.358-05 6.348-02 1. 028-01 4.78E-02 3.598-02 5.60E-02 4.368-02 3-.808-02 2.908-03 INFANT Drinking 6.498-05 1.628-02 1.618-02 1.628-02 1.618-02 1.618-02 1. 618-02 6.49E-OS 1.628-02 1. 618-02 1.628-02 1 '1E-02 1.618-02 1.618-02 9/4

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 9 : Assessment of Radiation Doses Enclosure 3 (Continued): Doses to Likely Most Exposed Member of the Public

2. Individual Dose Due to Gaseous Effluents (mrem/yr.)

A. Maximum Hypothetical Individual - Bxposure from Noble Gases, Particulates, Zodines, and Tritium W. Body GZ-LLZ Bone Liver Kidney Thyroid Skin ADULT Plume 4.4498-02 4.449E-02 4.449E-02 4.449E-02 4.4498-02 4.4498-02 4 . 5648-02 1. 0748-01 Ground Plane 1. 8118-03 1. 8118-03 1. 8118-03 1. 8118-03 1.8118-03 1.8118-03 1.8118-03 2.1318-03 Inhalation 1.6338-02 1.6358-02 4.7658-08 1.6338-02 1.6338-02 1.6358-02 1.6658-02 1.6338-02 Vegetation 2.7788-02 2.7988-02 5.5628-08 2.7768-02 2.7758-02 2.7788-02 2.775E-02 2.7758-02 Cow Milk 6.5688-03 6.577E-03 1.5528-07 6.5678-03 6.5678-03 6.6398-03 6.5678-03 6.5678-03 Meat 6 Poultry 2.8028-03 2.8438-03 5.615E-09 2.7998-03 2.796E-03 2.7998-03 2.796E-03 2.7968-03 9.9788-02 1.0018-01 4.630E-02 9.9768-02 9.9758-02 9.9878-02 1.0128-01 1.6308-01 TEENAGER Plume 4.449E-02 4.4498-02 4.4498-02 4.4498-02 4.4498-02 4.449E-02 4.5648-02 1. 074E-01 Ground Plane 1. 8118-03 1.8118-03 1. 8118-03 1.8118-03 1.8118-03 1. 8118-03 1. 8118-03 2.131E-03 Inhalation 1.643E-02 1.6458-02 6.7028-08 1.6438-02 1.6438-02 1.6468-02 1.6918-02 1.643E-02 Vegetation 3.2658-02 3.2858-02 5.3998-08 3.2628-02 3.2618-02 3.2638-02 3 . 2618-02 3.261E-02 Cow Milk 8.5568-03 8.5668-03 2.8158-07 8.5558-03 8.5548-03 8.6698-03 8.5548-03 8.5548-03 Meat & Poultry 1.6728-03 1.6938-03 4.666E-09 1.6708-03 1.6688-03 1.6708-03 1.6688-03 1.6688-03 1.0568-01 1.059E-01 4.6308-02 1.0568-01 1.056E-01 1.0578-01 1.0728-01 1.6888-01 CHILD Plume 4.4498-02 4.4498-02 4.4498-02 4.4498-02 4.449E-02 4.449E-02 4.564E-02 1. 0748-01 Ground Plane 1.8118-03 1. 8118-03 1.8118-03 1. 8118-03 1.8118-03 1.8118-03 1.8118-03 2.1318-03 Inhalation 1.4538-02 1.454E-02 9.1008-08 1.4538-02 1.4538-02 1.4568-02 1 . 4918-02 1.4538-02 Vegetation 5.1008-02 5.1088-02 1.0188-07 5.094E-02 5.0928-02 5.0958-02 5.0928-02 5.0928-02 Cow Milk 1.3528-02 1.3528-02 6.8298-07 1.3528-02 1.3528-02 1.374E-02 1.351E-02 1.3518-02 Meat 6 Poultry 2.0228-03 2.0288-03 8.6548-09 2.0178-03 2. 0158-03 2.0188-03 2 . 0158-03 2.0158-03 1.2748-01 1.2758-01 4.6308-02 1.273E-01 1.273E-01 1.2768-01 1.2888-01 1.9058-01 INFANT Plume 4.4498-02 4.4498-02 4 .4498-02 4 '49E-02 4.4498-02 4.4498-02 4 . 564E-02 1. 0748-01 Ground Plane 1. 8118-03 1.8118-03 1.8118-03 1.8118-03 1.8118-03 1.8118-03 1.8118-03 2.1318-03 Inhalation 8.3578-03 8.3588-03 7. 1868-08 8.3578-03 8.3568-03 8.3848-03 8.6018-03 8.3568-03 Cow Milk 2. 0518-02 2.0518-02 1.4268-06 2. 0518-02 2. 051E-02 2.1068-02 2.0508-02 2.050E-02 7.5178-02 7.517E-02 4.6318-02 7.517E-02 7.5178-02 7.5748-02 7.655E-02 1.3848-01 9/5

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 9  : Assessment of Radiation Doses Enclosure 3 (Continued): Doses to Likely Most Exposed Member of the Public

2. Individual Dose Due to Gaseous Effluents (mrem/yr.)

B. Maximum Real Individual - Exposure from Noble Gases, Particulates, Iodines, and Tritium W. Body GI-LLZ Bone Liver Kidney Thyroid Skin ADULT Plume 7.549E-03 7.5498-03 7.5498-03 7.5498-03 7.5498-03 7.5498-03 7.7728-03 1.9298-02 Ground Plane 2.6158-04 2.615E-04 2.6158-04 2.615E-04 2.6158-04 2.615E-04 2. 615E-04 3.0778-04 Inhalation 3.3808-03 3.3828-03 9.456E-09 3.3808-03 3.3798-03 3.3848-03 3.442E-03 3.3798-03 Vegetation 5.7478-03 5.7768-03 7.9868-09 5.745E-03 5.7438-03 5.7478-03 5.743E-03 5 '438-03 1.694E-02 1.697E-02 7.8108-03 1.6938-02 1.6938-02 1.6948-02 1.7228-02 2.8728-02 TEENAGER Plume 7.5498-03 7.549E-03 7.549E-03 7.5498-03 7.549E-03 7.5498-03 7.7728-03 1 '29E-02 Ground Plane 2.6158-04 2. 6158-04 2.6158-04 2. 6158-04 2. 6158-04 2. 6158-04 2.6158-04 3.0778-04 Inhalation 3. 4018-03 3.4048-03 1.3308-08 3 '018-03 3.401E-03 3.4068-03 3.4928-03 3.4018-03 Vegetation 6.7548-03 6.7838-03 7.7528-09 6.750E-03 6.7488-03 6.7518-03 6.7488-03 6.7488-03 1.7978-02 1.8008-02 7.8108-03 1.796E-02 1.7968-02 1.797E-02 1.8278-02 2.9758-02 CHILD Plume 7.5498-03 7.549E-03 7.5498-03 7.5498-03 7.549E-03 7.5498-03 7.7728-03 1.929E-02 Ground Plane 2.6158-04 2.615E-04 2.6158-04 2.6158-04 2. 615E-04 2.6158-04 2.6158-04 3.0778-04 Inhalation 3.0088-03 3.0088-03 1.8068-08 3.007E-03 3.0078-03 3. 0138-03 3 . 0818-03 3.0078-03 Vegetation 1.0558-02 1.0568-02 1.4628-08 1.054E-02 1.054E-02 1.054E-02 1.0548-02 1.0548-02 2.1378-02 2.1388-02 7.8108-03 2.1368-02 2.1358-02 2.1378-02 2.1658-02 3.314E-02 INFANT Plume 7.5498-03 7.549E-03 7.549E-03 7.5498-03 7.5498-03 7.549E-03 7.772E-03 1.9298-02 Ground Plane 2. 6158-04 2. 6158-04 2. 6158-04 2.6158-04 2.6158-04 2.615E-04 2.6158-04 3.0778-04 Inhalation 1.729E-03 1.7308-03 1.4268-08 1.7298-03 1.7298-03 1.735E-03 1.776E-03 1.7298-03 9.5408-03 9.5408-03 7.8108-03 9.5408-03 9.5408-03 9.5458-03 9.8108-03 2.1338-02 9/6

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 9  : Assessment of Radiation Doses Enclosure 3 (Continued): Doses to Likely Most Exposed Member of the Public

3. Annual Air Dose (mrad)

A. Maximum Hypothetical Individual: Beta = 1.14 E-01 Gamma = 6.94 E-02 B. Maximum Real Individual: Beta = 2.23 E-02. Gamma = 1.19 E-02 4

4. Doses Due to Direct Radiation from the Harris Plant On-going environmental TLD dose measurements show that the offsite Direct Radiation Dose is negligible.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 9  : Assessment of Radiation Doses Enclosure 4 : Major Assumptions Used to Calculate Radiation Doses

1. Doses Due to Liquid Effluents A. Dilution Factors Location Value E osure Pathwa s Harris Lake 1.00 E+00 Shoreline, Swimming, Boating, Fish Consumption Cape Fear River 8.28 E+01* Shoreline, Drinking Water (for Harnett County, Lillington, Dunn, and Fayetteville)

Cape Fear River/

Raven Rock Park 8 '8 E+01* Boating

• The dilution of 8.28 E+01 is calculated using the FSAR value for average blowdown of the lake (43 CFS) and the average flow of the Cape Fear River as measured at the gauging station at Lillington. The average flow of the Cape Fear River at this location is 3495 cfs (1981-1992 average flow of the Cape fear River as provided by the United States Geological Service).

BE Populations Affected Location Value E osure Pathwa s Harris Lake 1.10 E+05 person-hours Shoreline, Swimming, Boating Harris Lake 1.20 E+03 persons Drinking Water Harnett County 4.53 E+04 persons Drinking Water Dunn Intake 1.67 E+04 persons Drinking Water Fayetteville Area 1.40 E+05 persons Drinking Water Fuquay-Varina 2.68 E+03 persons Drinking Water Holly Springs 2.27 E+02 persons Drinking Water Harris Lake/

Cape Fear River 7.84 E+03 person-hours Fishing Cape Fear River/

Raven Rock Park 5.00 E+04 person-hours Boatinq Raven Rock Park 4.40 E+05 person-hours Shoreline C. Doses for "Activities Inside the Site Boundary" and the "Likely Most Exposed Member of the Public" use the Cape Fear River as the Drinking Water supply and Harris Lake as the source of all other liquid pathway doses.

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Semiannual Radioactive Effluent Release Report July 1, 1993 to December 31, 1993 Appendix 9 : Assessment of Radiation Doses Enclosure 4 (Continued): Major Assumptions Used to Calculate Radiation Doses

2. Doses Due to Gaseous Effluents The 50 mile Ingestion Zone population is 1.47 E+06 persons.

B. The Maximum Real Individual is located at 4667 meters (-2.9 miles) in the SW sector.

C. The Maximum Hypothetical Individual is located on the site boundary at 2140 meters in the SSW sector.

D. For the Inside Site Boundary Individual, access time is assumed to be 400 hour0.00463 days <br />0.111 hours <br />6.613757e-4 weeks <br />1.522e-4 months <br />s/yr at 1207 meters (3/4 mile) in the NE sector from the plant, which is the closest accessible lake location.

Concurrent meteorology is applied separately to batch and continuous release source terms. The dose commitment from each mode was summed to obtain annual dose.

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