ML20206C152

Forwards Application for Renewal of NPDES Permit SC0004278, Per 40CFR122.21

ML20206C152
Person / Time
Site:	Catawba
Issue date:	11/08/1988
From:	Tucker H DUKE POWER CO.
To:	Gibson H SOUTH CAROLINA, STATE OF
References
NUDOCS 8811160120
Download: ML20206C152 (72)

Text

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t .e n Duxs Powna COMPA)nF P.O.BOK 33180 cuAaLorrs. N.c. 38848 1

NALB.TUCEER teLaPWOWs were resseese (704) 37:>4334 e-November 8, 1988 Mr. Ilenry E. Gibson NPDES Administration Section South Carolina Department of Health and Environmental Control

2600 Bull Street i Columbia, S.C. 29201

SUBJECT:

Catawba Nuclear Station l Renewal cf NPDES Permit SCC 004278

, File: CN-702.13 Doar Mr. Gibson:

The subject NPDES permit expires July 30, 1?S9. Federal regulation

{ 40CFR122.21 and South Carolina Regulation 61-9 as well as Part II.B.5 of j the subject permit require the submittal of an application for renewal at least 180 days prior to expiration.

j Please find enclosed the application for renewal of the subject permit.

We request notification that the application is complete. Should you j have any questions or desire additional information, please contact R.T.

i Simril [(704) 373-2310).

i Sincerely,

/k f Hal B. Tucker, Vice Prealdent Nuclear Production ,

W1G/68/Ic1i Enclosures cc Document Control Desk Co \

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8811160120 881108 PDP ADOCK 05000413 p PDC

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in addition to Duke Power Company, the following are joint owners of the Catawba Nuclear Station:

North Carolina Municipal Power Agency Number 1 3100 Smoketree Court - Suite 600 Post Office Box 29513 '

Raleigh, NC 21626-0513  ;

North Carolina Electric Membership Corporation l 3400 Sumner Boulevard i Post Office Box 27306  ;

Raleigh, NC 27611 Saluda River Electric Cooperative, Inc.

Highway 14 Post Office Box 929 Laurens, SC 29360 Piedmont Municipal Power Agency 1 100 Memorial Drive ,

Greer, SC 29651 t

.! T Under the ownership agreement, Duke Power Company, as operator, has owner ,

authority to obtain necessary operating permits.

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Liquid Radwaste 1-U 0.46 MCD Sed ime ntat ion Conventional Wastewater Treat. X-X Ski.-rning 002 ment (WC) System which receivo s 2-C Precipitation input from the follcwing: X-X Co-Precipitation _

service building surp, 2-X Neutralization turbine building surps, Chemical oxidation 2-8 diesel generator catchrent 1-D Mixing surp, sulfuric acid tank 4-A Discharge to surface water containnant drainage surp, yard drain secondary conts' n- -

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• s.... e s.s t<n esseo (hst/ (htll .t.aepses e,c i f y asa eeen past.

005 Chemical metal cleaning Frequerjcy and curation cannot ye predigted from waste as necessary. Various Need based on the thermal-hydr 4ulic perfor:.anec .

l plant systems cleaned / flushed i

using any of the following:

EDTA, hydrazine, citric acid, phosphoric acid, oxalic acid, trisodium phosphate, soda ashi (See description of chemical ind! vidually for nor -routino cleaning.)

002, closed Cooling Systems drain- The sya tems may be drained dividual system vol'me i s 44,000 004 ing. Contains nitrite, borax, mainterance. M.ucicum ir benzotriazole corrosion gallona .

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S. Are the hmetations in the appucsole efffwent gun.tehne espressed in terres of product'on for other measure et w

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C v se tremolete item 111 CJ d C. f you answered"yes"toltemill.S.htt the quentity whe represents an actuat treasurement of vour tev used in tfit appbcable effluent guidehne. and indicate the atf ected outf alls.

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_1,. AVf R AGE D Af(Y PRODUCTION OUTraLke

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an ~ . woo,e4 See instructices before proceedirg - Complete one set of taNeo fot **ch outfeil - Annotate the outf sit number in the space m A.5. O C: NOTE: Tables V.A.V4, and V4 are 6ncluded ori segerete sheets numtered V.1 throvgh V.9.

l D. Use the spece bedow to list any of the pollutants listed 6a Tebte 2c.3 of the instr possespon.

S eOURCe 8.eOURCe I POLLUTANT

s. POLLUTANT s eny pouutant 6.sted m item V C e substance et e component 01' e suostance wneca you currently use or manuf ac.ut Woduct?

DNo ree to Iten Vt3D Qv es ttat eu eme% penetonte botawn N/A CONTINUL ON Rb tH56 P AGE 3 OF 4

\ ""* ***n mig 2C (Rev 2.gp ------._ _________________ _______ ________ _______ _

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0.sceerges or ett a JED pcoM THE f RoNT  ;

te ce caronie tosectry nos coen mece on any of yowf i floGicAL TOXICITY w,. .

f a how any hrwyousedge or reason tod tei ew IA41 eny D otogical teet for ocu '

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' I Qv'se (fdentsfy (Ae f.sa/#J eend densebe (Aev e. recess 6 elder) ,

test. ,

Fathead minnow acute 96-hour flow-through test.Coriodar>hnia 7 f whether the discharqcs were i

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The purpose of both tests was for in-house h knowledge ois no toxicity in the discharg l

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' toxic. The results of the tests indicate that t ere  ;

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.l(803)373-0707 and analysis of j P.O. Box 5207 l sa ples on Dischargy l

) Enwright Laboratories, Inc. Greenville, SC 29607

! 004 (Radwaste).

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endeny et te rerson amyresenment anewvedge endbe es, or o for ha i

essure tet euehnedperservdprope N/ gether end evokere tbe thesepersonesi W./rr%+Phrgetheregthem armi em eneree Pa thet there we signdacent p Q % E N o 'e'es tJde 4 ** A t (704) 373-4531

a. M anns e op p sCiah tot bs f f ppe o* eriets ,

H. B. Tucker, Vice President __

o ceTESIGNED Nuclear Production Department N/e,,ff'E J l

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l 40 DRIFT .

l " EVAPORATION I --*

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" COOLING l

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17,765 TOWER r' s I b.

NSW } }7 REACTOR l I l17,765 DEMIN. Y COND. CIR. 8 WATER

- WATER  : COOLANT WATER RA ASTE 3 b)

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I"INTAKE /

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SYSTEM i, I e OUTF ALL OO4 l ' 3 H LAKE (LAKE x FIRE ,

COND. POLISH U WYLIE WYLIE 1 PROTECTION 8 SKID 4 l

l 74* DEMIN. TURBINE t MOUNTED

-ye RADWASTE

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o FLOOR DRAINS ~ 8LDG. b' I  ; STEAM GEN. SUMP ,

EOUIPMENT i 58,856 LPSW 3856 BLOWDOWN

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4 INTAKE METAL CLEANING  ;

CONV. ,

- CONT. BLDG.

'-* LPSW e CONV. 322 **OUTFALL

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I SCREEN MISC ~ SUMP l TREATMENT I

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SUMP (i.

FILTERED -' 159  : BACKWASH Ci WATER W ~

SYSTEM 26 SEWAGE qOUTFALL SANITARY '

POTABLE TREATMENT jj003 WATER 11 e1 62 g ,

36  ! STORMWATEd RUNOFF - NORMAL FLOW PATH r)'

- -+ ALTERNATE FLOW PATH DUKE POWER COMPANY NOTE: ALL FLOWS ARE IN GPM FOR WATER FLOW SCHEMATIC AVERAGED CONDITIONS CATAWBA NUCLEAR STATION YORK COUNTY, SOUTH CAROLINA Novemt,e r 7, 1988 l

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I Supplemental Information -

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Catawba Nuclear Station

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i TABLE OF CONTENTS, -

? Page

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'i STATION INTAXE 3 Kf/ <  ;

~

.g NUCLEAR FERVICE WATER 1 FIRE PROTECTION 4 ,

e 3 OUTFALL 001 .

.,. 5 Low Pressure Service Water 5  ;

Cooling Towers 3

! Containment Spray' Heat Exchanger Wet Lay-up Syt em 6 Nuclear Service WatercPump Bearing Chemical Cleaning 6 OUTFALL Col. 7 Scritis a Building Sump 7 Water. Treatment Room 8 .

Filtered Water 8 Potable Water 8 -

Demineralized Water 8 Diesel Generator Room Sumps 9

- Turbine Building Sumps 9 Wet Lay-up 9 ,

Auxiliary Building Floor Drain Sumps ~10 '

Turbine Building Floor Drains 10 '

Diesel Generator catchment Sumps 10 Step-up Transformer Base Drainage Sumps 11 Sulf"tic Acid Tank Containment Drainage Sunp 11 Secondary Containment Sumps 11 Miscollaneous 12 t t

OUTFALL 003 12 L

OUTFALL 004 13

)

Floor and Equipment Drains 14  :

Ventilation Unit Drains 14-( OUTFALL 005 14  ;

l Steam Generator Cleaning 15 l Miscellaneous System / Component Cleaning 16  !

l

/SECTION 311 EXEMPTION 17' I APPENDIX: Boron use and Control 18

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The Catawba Nuclear Station is a two (2) unit nuclear fission steam electric generating station. It is owned by Duke Powe r Company, North  ;

Carolina Electric Membarship Corporation, North Carolina Municipal Power Agency Number 1, Piedmont Municipal Power Agency, and the Saluda River Electric Cooperative, Inc. but totally operated by Duka Power Company. Each j unit is a four loop pressurized water reactor. Heactor fuel is :ircaloy clad sintered uranium oxidn pellets. Reactor heat @ sorbed by the Reactor Coolant System produces steam in four (4) steam generators suf ficient to drive a turbine generator unit with a design net electrical rating of 1129

. megawatts.

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The nuclear reaction is controlled by control rods and chemical neutron absorption. Boric acid is used as a chemical neutron absorber and to provide borated water for safety injection. During reactor operation, changes are made in the reactor coolant boron concentration. Appended is a description of the changes in the boron concentration.

A schematic diagram of water use and discharges indicating average rates of flow for individual waste streams of Catawba Nuclear Station is attached.

Actual flows through individual systems may vary significantly d Qending on need to operate and meteorological conditions. The following is a brief description of the major systems.

STATION INTAKE Water used by Catawba Nuclear Station is withdrawn f rom Lake Wylie. There

are two (2) intake structures in Lake Wylie - one for the Nuclear Service Water System and one for the Low Pressure Service Water System. There are a i '

total of six (6) pumps on tho Low Pressure Service Water intake structure -

three (3) for the Low Prescure Service Water System (LPSW) and three (3) for the Fire Prctection System. Each LPSM pump is in a separate bay; the i fire protection system pumps share a bay. Each LPSW bay is equipped with a trash rack and travelling screen. The trash racks and travelling screens remove trash and prr nt debris from entering the pumps. Accumulated trash '

is cleaned from the racks by hand and from the screens by a backwash

! system. The intake screens are backwashed manually, automatically, or as frequently as the differential level alarms on each pump bay indicate the need. Design flow is 560 gpm. Each screen is backwashed every eight hours for 45 minutes per screen. The water is returned to Lcke Wylic at the intake bay. The trash and debris collected from the racks and screens are placed in sanitary containers and transported to a licensed sanitary I

landfill. No chemicals are used in the backwash water, j NUCLEAR SERVICE WATER SYSTEM l

The Nuclear Service Water System is a once-through non-contact p} ant  !

cooling water syster The Nuclear Service Water System supplies coottng water to various heut loads in the Auxiliary and Reactor Buildine nt W r than the se ondary (steam) side of the station. It is served by iro (2)

! bodies of water - Lake Wylie and the Standby Nuclear Service Water Pond (SNSWp) - but only one (1) pump structure. The intake structure in each water body is completely submerged approximately 30 feet below the surface '

of the water. Normal alignment is to Lake Wylie with the SNSWP as an f d8Eured Dack-up in Case of low level 19 the pump structure While aligned to 3

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o the lake. The SNSWP and the pump structure are seismically designed with  ;

suf ficient water to bring the station to a cold shutdown in case of the loss of Lake Wylie Dam. The level of the pond is maintained via an overflow pipe to the lake and pumping capability from the lake. Water from either the pond or the lake is piped to the nuclear cervice water pumn arructura. "

The pump structura consists of two 330,000 gallon pits that serve to provide suction to the pumps. There are two pumps per p it. . In normal Nuclear Service Water System operation, pump suction is from Lake Wylie.

Pump suction can be switched to the Standby Nuclear Service Water Pond (SNSWP) and discharge be back to the SNSWP. Additionally, during testing required by the NRC and in order to verify flow balance, the SNSWP system is aligned to discharge to the pond approxir.ately 48 hours5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> per year at an estimated rate of 18,000 gpm. The duration of such alignments is typically

, 8 hours9.259259e-5 days <br />0.00222 hours <br />1.322751e-5 weeks <br />3.044e-6 months <br />. The typical tentaragure change of the water removed from and returned to the SNSWP is 2 F. The temperaturo change is greater if

! dlignment to the SNSWP occurs during the process of shutdown. This i alignment may also be required periodically during times when a diesel l generator is inoperable. The discharge line to the SNSWP splits and discharges flow to each "finger" of the SNSWP to assure that surface cooling will occur in all areas of the pond.

As a result of accelerated corrosion, a corrosion inhibitor program is

being considered to be used in the duelcar Service Water System. Inhibitors

' under evaluation include zinc, nitrites, polyphosphates, phosphates, borax,  ;

I polysilicates, molybdates, benzotriazole (BZT), toyltriazole (TT), and mercaptobonzothiazolt. (MBT). Biocidos aro being conal krad f:" biofouling control. Those biocides would be dis" m ed at an agreed :mn concentration.

Biocides used to control clam growth in the safety related nuclear service water system can be discharged to the SHSWP during the required testing described above. Also, low concentrations of biocides may be discharged to the SNSWP during unintentional swapovers of discharges to the SNSWP.

However, product biodegradation and system demand would minimize the discharge concentration.

FfRR PROTECT M Water supply for fire Protection is provided by three (3) full capacity (2500 gpm) firo pumps. In addition, two 25 gpm and ono 200 gpm jockey pumps (supplied by tho Piltered Water System) are provided to prevent frequent starting of the main fire pumps to maintain pressure in the yard mains. If system needs cannot be met with the jockey pumps, the main fire pumps start in sequence as the pressure in the yard mains drop. The system is chlorinated to provent the survival of Corbicula within the system.

Chlorine is added automatically whenever the main firo pumps are on, i System operability is demonstrated by periodically performing specific tests on the system as described in the March 4,1906 correspondence

, (Attachment 1).

l l Testing is performed in such a mannor as to minimize the discharge of l chlorine to Lake Wylie as described in the Department of Health and Environmental Control lotter dated May 2, 1986 (Attachment 2).

4

e OUTFALI, 001 outfall 001 is comprised of low pressure service water, cooling tower blowdown, nuclear service water, and liquid radioactive waste (radwaste).

Radwaste is reguluted as NPDES Discharge 004. atscharge is subsurface through a concrete discharge structure into the uig hilison Creek arm of Lake Wylie. As a result of macroinvertebrutes (Corbievia: Asietic clams) and microbiologically influenced corrosion (MIC), chemical addition is anticipated. Chemicals anticipated to be added to control Corbicula and MIC include chlorine, biocidea, dispersants, and corrosion inhibitors that include zinc, nitrite, silicates,'molybdates, phosphates, polyphosphates, and borates. Chbrine addition at a level necessary to maintain a low level discharge concentration of total residual chlorino (TRC) is under evaluation. Discharges to Lake Wylie would be maintained at an approved discharge concentration.

Low Pressure Service Water, The low pres uro service water system (LpSW) is a once-through non-contact plant cooling water system. Three (3) pumps take suction from Lake Wylie via the LPSW intake structure. These pumps also supply .nake-up to the cooling towers for fill, blowdown, drift, and evaporative losses.

Cooling Towers The cooling towers are a closed cycle mechanical draf t system (3 towers! unit) which supply cooling water to the condensers to conde% e turbino exhaust steam. Total system capacity per unit is approximately 7.5 x 10 gallons. part or all of this can be drained to Outfall 001 and/or the Conventional Wastewater Treatment (WC) System via the turbine building sumps during major outage '*ork.

Chemical treatment of the cooling tower system consists of sulfuric acid, sodium hypochlorite, an organic biocide, and a polyacrylate dispersant. Sulfuric acid is added to maintain a pH between 6 and 9. A polyacrylato dispersant, such as Calgon PCL-20GO, is added for solids deposition control. Sodium hypochlorite is addad intermittently for biofouling control.

Normal chlorine (hypochlorito) additions are to the towers every other day. It is anticipated that during those times when blowdown is necessary to prevent scaling, when chlorine concentrations exceed discharge specifications, and when the WC eystem cannot handle the additional volume, it may becomo necessary to add either sodium sulfito or sodium nitrite to the cooling towers in stoichiometric proportions for dochlorination.

Additionally, because of restrictions on and of chlorine, an organic biocide is also added for biofouling control. Currently approved biocidec are Calgon H640, Drew Biosperse 288, Bet::

S11micide C79, Buckmaa Bulab 6002, Calgon H-130, and Drew Biosperse 216. Only one biocide is used at a tire. Multiple approvals have been obtained for bidding purposes.

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~O Blowdown is initiated through outfall 001 to maintain silica and calcium levels below scaling concentrations. This will average approximately 6 times the concentration of the intako water.

Blowdown averages 5000 gpm/ unit except during the periods of addition and decay of chlorine (hypochlorite) and organic biocidos. Blowdown can be diverted to the WC System when necessary for additional treatment. The discharge of chlorine in the blowdown is in compliance with offluent limitations guidelines. The biocido and dispersant are discharged at previously approved concontrations of less than the 96-hour LC 50 concentration values for general fish populations af ter mixing with other waste streams prior to Lake Wylie.

Containment Spray Heat Exchanger Wet Lay-up System Currently two systems exist. both on Unit 2, with 4000 gallons per system. part or all of this can be flushed through outfall 001 due to testing requirements, system leakage, or system actuation. The testing is required to verify minimum flow and pressure differential. Due to stagnant conditions and subsequent fouling and dopoaition problems, a wot lay-up system was designed specifically around the containment spray heat exchangers.

Organic phorphonates are currently used as a corrosion inhibitor at a concentrat . :n of approximatoly 50 mg/1. If the contents of the heat exchangor were instantaneously discharged directly to the lake, the concentration of the organic phosphonate in the system before mixing with other wasto streams, is well below the lowest reported 96LC50.

Other corrosion inhibitors are being considered to enhance the effectiveness of the wet lay-up program. These include zinc, nitritos, polysilicates, polyphosphates, phosphates, molybdates, and borates. Those formulations would be used in conjunction with a dispe sant and penetrant for deposit control and a biocido for biofouting control. Thoso products would be used so that release concontrations would be below the 96LC50 values for general fish populations af ter mixing with other waste streams prior to dischargo to Lako Wylio.

Nuclear Sorvice Water Pump Boarinq Chemical Cleaning Annually to ensure opornoility, the nuclear service water pump bearings are chemically cleaned to remove silt and sedimont depositn which restrict purp cooling water flod. Approximately fif ty gallons of cleaning solution (7,5) sulfuric acid /0.5% annonium bifluorido) are injected into tho bearing cooling water flow path for each pwrp. A 1.0% soda ash (Na C0 ) solution is used for rinsing the pump bearings.

7 3 The cleaning solutions overflow to the oit where they mix with the volumo of water in the pit. The pit is isolated during the pump cleaning whereby sampling and analysis for copper and iron are performed prior to release. Additionally, the pit volume will ultimately mix with low pressuro service water for a total flow of approximately 35,000 gpm, minimum, beforo discharging through outfall 001.

6

OUYFALL 002 Outfall 002 discharges flow from the conventional Wastewater Treatment (WC) system through a parshall flume into the Big Allison Creek arm of Lake Wylie. The WC system consists of a concrete initial holdup pond (IHp, 300,000 gallons), two (2) parallel clay-lined settling ponds (5 million gallons each), and a polymer lined final holdup pond (FHp, 1.5 million gallons). Normally, inputs are received in the initial holdup pond but can ,

be directed to the in-service settling pond. The IHP serves a surge-damp-ening function to the settling ponds and also allows heavy solids to settle for periodic removal. Solids removed from the IHp are dowatered and disposed of in the on-site licensed landfill. Flow is directed to the in-service settling pond where chemical treatment, mixing, and aeration take place. Sulfuric acid and Jodium hydroxide are added for pH contrel.

coagulants can also be added to facilitate the settling of small particles.

Additionally, it may be necessary infrequently to oxidize persistent chemicals. Approval is therefore requested to add hypochlorite (sodium or -

calcium) or hydrogen peroxide to the settling ponds as oxidation agents as necessary. When hypochlorite is used, TRC will be verified below detection i prior to discharge. The settling ponds can discharge directly to Lake Wylie via Outfall 002, or directed to the FHP for additional treatment or holdup capacity. Treatment in the WC System is on a batch basis. Discharge is normally by gravity at approximately 900 gpm but can be pumped at a rate of 1500 gpm. .

a

! Recirculation capability is available for recirculation intra- or inter-basin. Approval is requested to use an algicide, such as CUTRINE-PLUS, as needed to control algae growth in the system.

The WC System receives inputs directly from the service building sump, turbine building sumps, diesel generator catchment sumps, step-up trans- ,

former base drainage sumps, sulfuric acid tank containment drainage sump, cooling tower blowdown, secondary containment sumps, and rainwater from the initial holdup pond valve pit and cooling tower blowdown valve pit sumps.

At least annually, the plant Heating Water System must be replenished with othylene glycol. This is accomplished by bleeding the system to drums and

, replenishing it with new glycol. This waste glycol, along with glycol collected from leaks and spills, is periodically discharged into the WC System for treatment. j Service Buildino Sump i

The Service Building Sump receives inputs from the water treatment room, diesel generator room sumps, and the service building floor ,

~

drains. The sump has an approximate holding volume of 26,500 gallons l

. and two (2) pumps, each with a capacity of 1350 gpm. Normal alignment is to the WC system directly, but can be through the turbine building l

! cump.

The service building floor drains receive miscellaneous leakage and f

l drainage. Chemical inputs include:

r i

hydrazine I

trisodiu.n phosphato l ,

i i

l

) - - . - - , - - - - . - . , - - - - - - - . . , _ - . _ - . - - - , - - - - - . -

1 o'

amonia morpholine (planned for future use) sodium hydroxide sulfuric acid cationic polyelectrolytes alum ei.hylene glycol Calgon CS (comercially prepared sodium nitrite / borax / "

sodium benzotriazole (BZT) corrosion inhibitor) sodlum benzotriazole (BZT)- ,

blocides (Calgon H-303, Calgon H-130) '

industrial cleaning products laboratory chemicals citric acid Water Treatment Room The Water Treatment Room produces filtered water, potable water, and demineralized water. All chemicals used, all leakage and drainage, and all wastes produced go directly to the sump.

Filtered Water Filtered water is made by taking lake water, adding a coagulant, filtering up through one of two gravel-to-sand i

beds and chlorinating with chlorine gas to approximately 1.5 mg/l FAC. When solids are elevated in the lake, alum (aluminum sulfate) may also be used. The beds are flushed on pressure buildup with high velocity lake water.

Approximately quarterly, or when necessary, each bed is cleaned with approximately 200 gallons of 35% hydrogen 2

peroxide and a surfactant. The peroxide and surfactant is added, tho bed is air mixed, allowed to soak, and flushed.

The peroxide / surfactant cleaning dissolves mud balls that

may have formed. Yearly, approximately 1000 pounds of sand '

are replaced in each bed a a result of normal losses from backwash carryover.

Potable Water potable water is made by passing filtered water through one of two carbon beds and rechlorinating to apgroximately 1.5 mg/l FAC. Both carbon beds contain 110 ft each and are replenished yearly. The waste carbon is sluiced to the ' WC l 4 Ilip.

Denineralized Water Domineralized water is made by passing filtered water through a. carbon bed and then through a regenerative resin l bed. There are two (2) carbon da and two (2) resin beds.

Each carbon bed contains 270 f and is replenished yearly.

Each resin bed contains 510 ft and is replenished every 3 j

to 5 years. To regenerate the resin, sulfuric acid and  !

i 0 (

t i

e sodium hydroxide are flushed through the bed. Each . normal regeneration, at the present time, takes approximately 98 gallons of 93% sulfuric acid and 330 gallons of 50% sodium hydroxide. Regeneration occurs approximately every three

. (3) days. The amounts of ra<pired acid and caustic will vary as dictated by operational requirements.

Approximately quarterly, each bed is surfactant cleaned to remove organic film on the resin.

-Diesel Generator Room Stnpr.

The diesel generator room sumps receive inputs from leakage or draining the diesel generator engine cooling water, fuel oil, and lubrication systems. Each of the four (4) sumps has a volume of approximately 470 gallons and two (2) pumps, each with a capacity of 50 gpm.

The diesel generator engine cooling water systems have a volume of 2240 gallons cach. The systems are treated with a mixture of sodium nitrite, borax (sodium tetraborate), sodium bicarbonate ,

and sodium mercaptobenzothiazole (MBT) to maintain a minimum conc stration of 2000 mg/l as nitrite. To control bacteria, an approved blocide is added.

The diesel generator fuel oil and lubricatior systems can drain l to the sumps, but administrative controls block intentional draining. For emergency spills, an oil coalescing unit is installed between the sumps and the service building sump.

Additionally, the fuel oil contains residual blocide to reduce bacterial breakdown of the oil.

Turbine Building Sumps The turbine building sumps reenjve inputs from steam generator wet  :

lay-up chemicals, cooling tower drainage (unwatering), auxiliary building floor drain sumps, and the turbine building floor drains.

Each sump has an approximate capacity of 12,000 gallons and three purps, oach witn a capacity of 1350 gpm. Normal alignment is directly to the WC system. However, hose connections on the discharge of the pumps allow rerouting to other sumps for unusual circumstances.

Wet Lay-up During shutdowns, the steam generators and hotwell are placed in wet lay-up to prevent corrosion. Prior to start-up, the solution is drained. Each unit is currently shutdown on a 14 month cycle for refueling. Steam generator and betwell wet hy-up con be diverted to the turbine building sump. Each of the four steam generators per unit has a maximum volume of 50,000 gallons.

Maximum chemical concentrations should be 200-300 mg/l hydrazine for corrosion control with the pH adjusted to 10.5 with ammonium hydroxide. The hotwell per unit will contain approximately j 200,000 gallons. Maximum ehemical concentrations should be [,

9

approximately 40 mg/l hydrazine with the pH adjusted to 10.5 with ammonium hydroxide.

Auxiliary Building Floor Drain Sumps Auxiliary building floor drain sumps can be diverted to the turbine building sumps. Each sump has an approximate capacity of 500 gallons and two pumps, each with a capacity of 50 gpm. Inputs consist of equipment drainage, air handling unit condensate, sample line purge, floor wash water and lab drains. Chemicals that may be present include:

arrrnonia boric acid borax (sodium tetraborate) hydrazine sodium carbonate sodium metasilicate sodium hydroxide morpholine (planned for future use) phosphate nitrate nitrite lithium hydroxide ethylene glycol leh chemicals dispersants blocidos industrial cleaning products Turbine Building Floor Drains The turbine building floor drains receive miscellaneous leakage and drainage. Inputs include:

laboratory samples industrial cleaning pro.iucts powdered or bead resin oli hydrazine amonia morpholine (planned for future use) service building sump Diesel Generator Catchment Sumpn The diesel generator catchment sumps receive inputs f rom the fuel oil unloading pads, containment mechanical equipment building (CMEB) sumps, contaminated drum s*.orage area sump, hydrogen / oxygen generator, standby shutdown facility, and rainwater. The Unit 2 sump pumps to the Unit 1 sump with each sump having two (2) pumps. Each pump has a capacity of 250/110 qpm, Unit 1 and 2, respect ively . Unit 1 sump consists of two separate volumes -

one to receive all flow ano the other to house the pumps. A partial concrete wall separates the 10

. 1 I

volumes, allowing flow under the wall only, which minimizon oil from getting to the pump suction.

Additional chemical inputs include a sodium nitrito/ borax / sodium bicarbonate corrosion inhibitor (approximatoly 2000 mg/1) from loakage ,

or drainage in the CMEB, drainage f rom the hydrogon/ oxygen generator '

of 25% potassium hydroxide, ethylene glycol and nitrite / borax /

hydroxide corrosion inhibitor from the standby shutdown facility (SSF) cooling system, and residual biocide in the fuel oil. The SSF has currently not been drained. However, it is conceivable that it would be necessary to drain the system for non-routine maintenance.

Stop-up Transformer Base Drainago Samps The stop-up transformor base drainage pumps receive rainwater and oil leakage from the curbed bases under the main step-up, auxiliary step-up, and auxiliary electric boiler trans fo rmers . Each sump consists of two separate volumes, one to receive all flow and the other to house the pumps. A partial concrete wall separates the volumos, allowing flow under the wall only which should minimize the possibility of oil getting to the cuction of the pumps.

The required minimum fluid capacity in the oil holdup section in 12,716 gallons. The required minimum holding capacity in the water pump section is 6,358 gallons. Each sump has two (2) pumps with a capacity of 800 gpm each.

Sulfuric Acid Tank Containment Drainage Sump The sulfuric acid tank containment drainage sump receives inputs from rainwater, laboratory drains, industrial strength cleaning chomicals, and tank containments. The approximate holding capacity is 225 gallons with pump capacity of 35 gpm.

Tank contairments includo:

15% sodium hypochlorite 16,000 gallons 50% sodium hydroxide 1,500 gallons blocide 3,000 gallons dispersant 7,600 gallons 93% sulfuric acid 30,000 gallons Curbing provides secondary containment for each of these tanks. This curbing is sufficient to contain the entire contonts of each tank in caso of a leak.

In addition, the hypochlorite generator and the waste anolyte system could input to the aump. The hypochlorito generator, which has never operated, would produco an aqueous waste solution of sodium hypochlorito. This waste would be reduced with sodium sulfite in the wasto anolyte treatment system to produco salts before dischargo to the sump.

Secondary containment Sumps Secondary containment sumps receive input from the yard drains. Three 11

10,000 gallon cumps are available for spills or rainf alls less than 10,000 gallons. The numps can pump to the initial or final holdup pond. By design, greater than 10,000 gallons will put the sump in overflow directly to Lake Wylie.

Other than spills or rainfall, actuation or testing of the chlorinated fire protection system in the yard could overflow a sump.

Additionally, the groundwater drainage system for the plant discharges to the yard drains.

Miscellaneous A 2% solution of glutaraldehyde is used in cleaning respirators. This cleaning generates approximately 250 gallons of waste per year. In addition, the motorpool - wash water is collected in a tanker truck and discarded directly to the basins.

There are approximately 25 to 30 closed cooling systems within the station. The largest system has a volume of approximately 44,000 gallons. The main portions of these systems are constructed of carbon steel. A sodium nitrite / borax (sodium tatraborate)/ sodium benzotriazole (BZT) corrosion inhibitor (2000 mg/l nitrite) is added to control corrosion. An organic blocide is added to control biofouling. To date, the systems have not been drained. However, it is conceivable that the systems may need to be drained, individually, for non-routine maintenance. Should this occur, the systems would be drained to the WC system or the Radwaste system if contaminated by radioactivity.

OtfrFALL 003 Outf all 003 discharges flow f rom the Sewage Treatment (WT) System into the Big Allison Creek ann of Lake Wylie. The sewage treatment system consista of a 1.28 million gallon aeration basin that is divided into four sections and a 0.525 million gallon effluent polishing basin. Design flow is 0.080 MGD. Inputs pass through a grit chamber which allow heavy solids to settle out and a bar screen to remove large non-sewage objects and to break large particles. It then passes through a coccinutor which cuts and shreds large solids into smaller particles which are more easily digested. Fro:n the ccmminutor, the sewage enters the aeration lagoon where the sewage is decomposed by aerobic bacteria. Aeration is provided by air compressors.

From the fourth section, the sewage enters the effluent polishing basin or can be directly discharged to Lake Wylie through outfall 003 if of accept-able quality. The effluent polishing bssin (also aerated by air ccmpres-sors) reduces suspended solids, nitrogen, and phosphorous levels. The effluent flows through a parshall flume to record discharge flow, through a Sanuril chlorinator, and a chlorine contact chamber before discharge to Lake Wylie.

The WT System receives raw sewage f rom Catawba Nuclear Station, the Catawba Training Contor, sink drains, shower drains, and drinking water fountains.

A soda ash solution is added to the effluent of the polishing pond as necessary for pH control. The aeration tubes are replaced and/or cleaned 12 l

-7 D

with hydrogen chloride gas as necessary. Approval is requested to use an digicide such as CUTRINE-pLUS to control algae as well ns chemicals for odor control as necessary.

It may be necessary to periodically remove sludge fron the system. The ciudge will either be tanked to a municipal sewage treatment system or dewatered and disposed of in a State licensed landfill or landfarm.

All sinks, showers, toilets, and water foantains carry wastewater and industrial cleaning products to the WT system.

During approximately 10 hours1.157407e-4 days <br />0.00278 hours <br />1.653439e-5 weeks <br />3.805e-6 months <br /> per calendar quarter, small amounts of

photographic wastes (developer and rinse) are disposed of in the WT system.

The volume discharged to the WT system is approximately 180 gallons per hour. The components of these substances include:

acetic acid potassium sulfite potassium hydroxide

• hydroquinono

, 1-phenyl-3-pyrozolidione l glutaraldehyde bisulfite l glutaraldehyde

< l j OUTFALL 004

! Outfall 004 discharges flow from the liquid radwaste system. This flow ~

f L

combines with plant once through cooling water (service water) befor6 discharging through the concreto discharge structure (outfall 001) into the i Big Allison Creek arm of Lake Wylie. ,

The liquid radwaste system collects waste in three (3) sub-systems (floor f

'. and equipment drains, laundry waste, and ventilation unit drains). All r waste is processed to Nuclear Regulatory Commission (NRC) requirements (10 CFR part 20 and 10 CFR part 50) prior to release with the type of processing depending on the type of waste. The maximum discharge rate from

radwaste is 250 gpm. Chemicals that may be present in the liquid radwaste

' system include: [

l l

boric acid i l  ;

borax nitrate [

ammonia ',

norpholine (planned for future use) {

1*thium hydroxide j l

ethylene glycol benzotriazole (BZT) [

nitrito/ borax corrosion inhibitor hydrazine f' chlorine /hypochlorite hydrogen peroxide i ethylene diamine tetracetic acid (EDTA) I I

containment spray heat exchanger lay-up chemicals i

puttp bearing cleaning chemicals t

13 I i

I_ -

- __,....._,, _ _ __ ___._ _ _ _ __.. _ _J

4 i ..

laboratory chemicals dotorgents surfactants polyelectrolytes industrial cleaning produern chemical metals cleaning waste The Turbine Building Sump can become contaminated with radioactivity. When this occurs, it can be pumped to the Floor Drain Tank (FDT) or treated with skid-mounted radwante equipment. The -decision on the method of treatment depends on the amount of waste needing treatment and the quality of , the water being treated. When the sump is diverted to the radwaste equipment, it is considered a part of Radwaste. Chemicals listed as being in the Turbine Building Sump (in Section Outfall' 002) will be in Raddaste (Outfall 004) when it is routed to this path. Solids or concentrated radioactive by-product generated in the treatment process are solidified and transported to a State and NRC licensed low level radioactive waste disposal facility.

Floor and Equipment Drains All floor drains in the auxiliary building, all equipment (pumps, tanks, heat exchangers, etc.) drains, laundry equipment drains, and waste from ths Unit 1 and Unit 2 containment floor and equipment sumps are collected in the Floor Drain Tank (FDT), Steam Generator Drain Tanks (EGDTs), Laundry and Hot Shower Tank (LHST), and Waste Evaporator Feed Tank (WEFT). The total tank capacity is 125,000 gallons.

Ventilation Unit Drains The Ventilation Unit condonsate Drain Tanks (VUCDTs) collect condensate fro.n air handling units f rom each reactor building. Each VUCDT has a volume of 10,000 gallons.

This waste typically has little radionuclide contamination and no chemical contamination. The waste is transferred from the VUCDT to one of two 5,000 gallon Recycle Monitor Tanks (RNT). The waste is then sampled for radionuclides and chemical contamination and discharged the same as other 11guld radwaste. If the samples indicate the need for processing, the RMT contents may be transferred -to the FDT for processing.

Waste from the collection tanks is then processed using filters and/or ion exchangers. The processed ef fluent is collected in waste monitor tanks for sampling and analysis prior to release f rom one (1) of two (2) points.

Waste Monitor Tanks and Recycle Monitor Tanks are discharged to the low pressure service water system via the nuclear service water system.

Auxiliary Monitor Tanks discharge directly to the Low Pressure Service Water System through a radiation monitor and into Lake Wylie via Outfall 001. All releases are made in compliance with NRC requirements.

OUTFALI. 005 Outfall 005 discharges chemical metal cicaning waste to Lake Wylie via the 14

o WC System (Outfall 002). Any chemical metal cleaning waste that is contaminated with radioactivity is processed in the liquid radwaste system

, and discharged through Outfall 004 (Outfall 001).

Currently, the only chemical metal cleaning done routir.aly ic the cicaning of the four (4) containment spray heat exchangers. All wastowat ar is returned to the turbine building sump and finally to the WC system.

Chemicals used when cleaning the containment spray heat exchangers, or other components, include:

surfactants trisodium phosphato sodium carbonate organic phosphonato anti-foaming agents polyphosphates sodium metasilicate sodium nitrite sodium tetraborate sodium hydroxido hydrogen peroxido chlorino polyelectrolytes dispersants organic biocidos cleaning of condensato polishing domineralizor filter elements may begin on a regular basis in the next several years. This cleaning consists of soaking the filtor elements in an acid solution f 61 owed by rinsing with demineralized water. Acids being considered for use includo, but are not limited, to the following:

phosphoric citric sulfamic oxalic nitric steam Generator cleaning Each olectrical generating unit contains four (4) steam generators that have a capacity of approximately 50,000 gallons each. There has been no chemical cleaning of the ateam generators to date. However, whenever a chemical cloaning is performod, all four steam generators will be cleaned based on need as detennined by the thormal-hydraulic performance. One possible cloaning solution, based on previous experience, consists of 15% ammoniated ethylene diamine tetracetic acid (EDTA), 1% CCI 80/1 ( .s proprietary corrosion inhibitor), it hydrazino and annonium hydroxide for pH adjustment. The spent solvent may contain radioactivity, iron, and other metals in trace quantities.

Treatment will possibly be by domineralization and noutralization/

precipitation doponding on the characteristics of the waste and/or whethor contract vendors aro used to perform tho treatment. Treatment 15

will be either performed in Radwaste or the WC System depending on tne level of radioactivity. Additionally, rinse / passivation water will be required. The rinse water will be processed followed by neutral-ization/ precipitation in the WC System. The process may be modified for each cleaning depending on the ::cale deposited within the steam generators. Other solutions may be utilized in the cleaning.

Niscellaneous System /Cemoonent Cleaning other systems may need to be cleaned periodically because of scaling or plugging. Other components will be cleaned as necessary for various fouling problems. Solutions utilized will be standard chemical cleaning methodologien. Chemicals utilized by these methodologies, alone or in combination, include the following:

Alkaline Boilout Solutions non-ionic surfactants anionic surfactants cationic surfactants sodium hydroxide soda ash trisodium phosphate sodium metasilicate disodium phosphate nonosodium phosphate sodium bicarbonate i Acid Solutions hydrochloric acid sulfuric acid phosphoric acid formic acid hydroxyacetic acid sulfamic acid citric acid nitric acid Acid Solution Additivos thiourea antnonium bifluoride oxalic acid EDTA Corrpounds and HEDTA pH adjusted tetra-ammonium EDTA tetra-amonium EDTA di-ammonium EDTA hydroxyethylenediaminetriacetic acid tetra-sodium EDTA 16

Hiscellaneous Compounds chlorotheno sodium chlorido chlorino (hypochlorito) potassiun permanganate agua amponia remonium persulf ate codium nitrite antifoam sodium sulfite corrosion inhibitors (e.g., phosphates, borax-nitrite, silicates, etc.)

organic blocidos These solutions are described in the Development Document for Effluent Limitations Guidelinos and New Source Performance Standards for the Stoam Electric Power Generatinq Point Source Category (Dovelop: dent Document).

The spent solvents from these cleanings will be treated in the WC System or the Radwaste System. The acid compounds will be neutralized; the other compounds will be mixed, oxidized, and/or precipitated as necessary for troatmont.

SECTION 311 EXEMPTION The legislative / regulatory history of the Clean Wator Act, Section 311, indicatus that an exemption would be allowed where an on-sito spill is processed through a treatment system capable of eliminating or abating the spill. A Section 311 exemption is thereforo requested for the five (5) substances discuaned under the Sulfuric Acid Containment Drainago Sump section of this document. In addition to these five (5) substances, a Section 311 exemption is requested for the 5,000 gallons of caustic in a storage tank that in located in the Service Building. Curbing sufficient to contain the entiro contents cf the tank is provided. Drainage from the curbed area is to the WC system via the Service Building Sump.

As discussed, tho entiro contents of these tanks are contained and are routed to an existing treatment f acility (WC System). The treatment system is capable of containing the spilled material along with normal process waste flows and of mitigating / abating the of fects on the receiving water sinco the system

- treats the wastes by batch,

- treatment capacity is 5 million gallons por batch - much greator than any of the tank volumes, and

- has procedural safeguards to restrict inputs to a discharging basin.

Thorofore, in accordance with 40 CFR 117.12 and with the legislative /

regulatory history, a section 311 exemption is requested for these substancos.

17

APPENDIX Boron use and Control Boric acid is used as a chemical neutron absorber in the reactor ecolant system for reactivity control and to provide water for safety injection.

During reactor operation, changes are made in the reactor coolant boron concentration for the following conditions:

Reactor start-up - boron concentration must be decreased from shutdown concentration.

Load follow - boron concentration must be either increased or decreased following a chango in load.

Fuel burn-up - boron concentration must be decreased to compensate for fuel burn-up and the buildup of fission products in the fuel.

Cold shutdown - boron concentration must be increased to the cold shutdown concentration.

The concentration of boron in the Reactor Coolant System varies from 0 to 2500 ppm depending on core life.

The baron concentration is controlled through the Chemical and Volume control System. The boric acid is stored in the Concentrated Boric Acid Storage Tank at a concentration of 7000 ppm boron. The boron concentration in the Peactor coolant System is varied by blonding reactor makeup water from the Reactor Makeup Water Storage Tank and boric acid f rom the Boric Acid Tank as needed to reach the desired concentration. Excess liquid effluents from the reactor coolant system which contains 0 to 2500 ppm boron are diverted (or letdown) to the Recycle Holdup Tanks in the Boron Rocycle System. Water from the Recycle Holdup Tanks can be processed as a batch through the boric acid evaporators whero the boron is recovered and recycled to the boric acid tanku. Any beric acid that is not of suf ficient quality to be recycled is processed further in the Radwasto System. It is further concontrated, solidified, and transported to a Stato and Nuclear Regulatory Commission (NRC) licensed low lovel radioactive landfill. The distillate f rom the ovaporators is either returned to the Reactor Makeup Water Storage Tank or treated further in the Liquid Radwasto System for releasa to Lake Wylie as part of the Lignid Radwaste Dischargo (Discharge 004). Water from the Recycle Holdup Tanks may bypass the boric acid evaporators and be released to the monitor tanks. The decision to byp'ss a the boric acid ovaporators depends on the atomgo capacity available for the concentrated boric acid and the condition of the boron.

Water containing boron can also be released to the monitor tanks for dischargo as a result of system leakage and flushing operations. The maximum concontration of boron that can be present in the liquid radwasto system dischargo is estimated to be 200 ppm. The maximum release rate f rom the liquid radwaste system is 250 gpm. The liquid radwaste systen discharges through a valve which is controlled by a radiation monitor and flow meter. This valve is designed as an interlocking device which will not 10

operi unless the radioactivity is within limits specified by the Nuclear Regulatory Comission in 10 CFR part 20 and a minimum flow rate is established in the Low Pressure Service Water System so that the of f site dose will be within limits specified in 10 CFR Part 50. The resulting concentration in Lake Wylie is loss than 12 ppm. Results of monitoring for boron in Lake Wylie over the last five (5) years have been less than 10 ppm. In most cases, the results have been less than 1 ppm.

l 19

4 e Attachment 1 DUKE POWER GOMPANY NUCLEAH PRODUGTION DEPARTMENT P.O. DOX 33189,499 NOUTH ClfUMCH 37 MEN canz.orre. .v.c. asa4a (704) ora-40s:

March 4, 1986 Nancy Weatherup, Engineer Industrial & Agricultural Wastewater Div.

Bureau of Water Follution Control South Carolina Department of Health &

Environmental Control 2600 Bull Street Columbia, SC 29201

SUBJECT:

Catawba Nuclear Station Fire Protection System Chlorination File CN-271.45, 724.30

Dear Ms. Weatherupt During our December 6, 1985 discussion concerning chlorinating the Catawbs Nuclear Station fire protec-tion system, you requested written information concern-ing our system testing requirements.

We are required by Tachnical Specifications. Appendix A of the Operacing License, and fire insurance to insure that the fire protection systen is operable at all times. Operability is demonstrated by periodically

' performing specific tests on the system. Semi- i annually, each of the hose connection shut off valves on all hydrants are manipulated. At this same time, with the hydrant valve open, the hose connection shutoff valves are opened 1-1-1/2 turns for a few I minutes to flush rusty water from the hydrants. Only

one (1) valve is opened at a time to prevent starting the nata fire pumps. Until a main fire pump starts,  ;

fire protection water is supplied by the filtered water  ;

systen which is essentially drinking water. This part '

of the system consists of three (3) jockey pumps, ranging in size from 25 spa to 200 spa, and a 5500 .

gallon pressuriser tank. Based on previous tests, estimates of water discharge for each hydrant range from 1200 to 5000 gallons. There are approximately 60 hydrants of which about half are in paved areas and the remainder in dirt areas. Based on previous observa- ,

tions of this testing, a maximum of about 3-5 gallons '

, reach yard drains. This portion of the testing should j have no adveroe environiental impact. '

1

-- - ~ - , , _ . - - , . . , . _ - , - _ - - . . - - ._ _ -, ,,,---- -.,. - - ,_ _ - -,,..---,-- - _._- .

j _. . _ _ __ _ .

t

. j 4

Nancy Weatherup, Engineer March 4 1986  !'

Page Two 4

4 Once each hydrant has been tested, one (1) main fire I pump is turned on and the hydrant that is the '

fartherest from the pumps is fully opened and flushed for 15 minutes. If any debris is present, the hydrant is flushed again. The flow rate for the flush is estimated to be 1500 spa. This hydrant must be open a miniaua of 15 minutes.

] Annually, the pumping capacity must be verified by testing three points on the pump performance curve.

Also annually, the pump starting point must be verified by testing at what pressure each pump starta. These '

tests should have no e nv iror.me n t al effect since they I are performed totally prior to the chlorine injection  !

point. Check valves have been installed prior to the chlorine injection point.

Every two (2) yeara. full flow testing of the system is required. Every loop in the system must be tested to  :

) ensure adequate flow is maintained. The auxillary (

building and P.u rbin e /s e rvic e building loops discharge ~

out the test header at the intake structure. The auxiliary building loops (2 loops) takes approximately 15 minutes to test while the t u rbin e / s e rv ic e building loops (8-10 loops) takes approximately 3 hours3.472222e-5 days <br />8.333333e-4 hours <br />4.960317e-6 weeks <br />1.1415e-6 months <br />. The cooling tower yard loops (3 loops) takes approximately  :

45 minutes to test. Th e flow rates range between 1500  ;

to 2500 spa.

~

l The stated times are the maximum times l that water will be flowing. Several hours can be [

expected to elapse between testing each loop for [

l aligning the valves to establish the flow pt.th. All of I l the performance tests combined rcquire about three days  !

to complete. It may lie possible to conduct these tests  :

during the winter when chlorination may not be needed. l l

other uses include safety / fire brigade training, I backwashing cooling tower screens, and a supply of  !

water for the Bethel Volunteer Fire Department. Each i l of these uses approximately 1000-3000 gallons each l time. There should be no adverse environmental impact.

The travel path for the cooling tower screen backwash after it reaches the ground is across dirt / grass to a ,

yard drain and then to a swampy area beside the WC  :

discharge point. Water in the swampy area seeps l through rock into the lake over an extended time .

period. The Bethel Volunteer Fire Department has two  !

(2) tankers that are approximately 2500 gallons each. l

, It takes approminately 20-30 minutes to fill each -

! tanker with most of the water coming from the filtered *

{  !

1

-- , - - - . . - , - - - - - . -~

. i Nancy Weatherup, Engineer March 4, 1986 I Page Three l water system. The level of chlorination, at the present time is unknown. To control Corbicu31a. a minimum of 0.5 ppa TRC muJe be maintaine[ for a period of not less than 108 hours0.00125 days <br />0.03 hours <br />1.785714e-4 weeks <br />4.1094e-5 months <br /> following the time the main fire pumps are turned off after each use. Chlorination is needed anytime the intake water temperature is greater than 60 degrees F. The chorination system is designed to inject up to 10 ppa at design flow at the injection point. The actual amount injected will be determined by trial and error to ensure that 0.5 ppa TRC is maintained for the 108 hours0.00125 days <br />0.03 hours <br />1.785714e-4 weeks <br />4.1094e-5 months <br />. The level of chlorination may vary depending on the chlorine demand of the lake water. The recommendation has been made to begin with 2-5 ppa TRC at the injection point. Th e chlorination system has been completely installed.

Any of the chlorinated water reaching the lake should have no adverse environmental impact. Assuming (1) each hydrant discharge is 1500 gym, (2) each test with flow reaching the lake is for 15 minutes, (3) all the chlorinated water reaches the lake at the maximum chlorine level. (4) chlorine is 5.0 ppa TRC, and (5) the low pressure service water system is 59000 spa, the maximum level of chlorine after mixing will be 0.13 TRC the total amount of chlorine will be less than one (1) pound.

We are waiting for your response on impact on the environnent and/or recommendations prior to connecting the chlorine cylinders and testing the system. Should you desire additional information, please call me at (704) 373-5764.

Sincerely.

R. T. Simril, System Engineer Nuclear Envi on ntal Campliance by G.1T. fin Environmental Engineer WTG t hj p cet W.A. Haller R.R. Wylie R. Maynard D.C. Gooleby CN-3000.02-11, 5030.00, 5030.00-01

Attachment 2 South Carolina Dcpertment of Health and Environmental Control Eosed 2600 Buu Strese j[rp. Moses H. Clark.on Jr . Chairman Columw. S.C. 29201 m),f/, g \ Gerald A Kamard. %ce Chairman Oren L. Brady Jr . Secretary

" + (

Barbara P %essle Commodedeaw James A. Sorw11. Jr.

Robert S. Jackson. M D. %1 ham H. Hester. M D Euta M. Colun, M D May 2, 1986 R. T. Simril. System Engineer Nuclear Environmental Compliance Duke Power Company P. O. Box 33189 Charlotte, NC 28242 Attn: W. T. Griffin Re: Catawba Nuclear Station Fire Protection System Chlorination York County

Dear Mr. Simril:

Per your March 4,1986 communication, this office has reviewed your dis-cussion on the possible discharges of chlorinated water to the environment through the testing of the fire protection system at the above referenced f acil i ty. While we can appreciate the need for this type of testing, we are concerned with the possible environment impact from the discharge of water that has a total residual chlorine concentration of 0.5 ppm to 5.0 ppm.

We, therefore, request that you minimize the impact of discharged chori-nated water. It appears that this may be done in the following ways:

1 Discharge to dirt / grass areas whenever possible.

2. Conduct the tests, whenever possible, during the winter (<60' temp.)

when chlorination may not be needed.

3. Conservatively space the testing of each system and the testing of each hydrant in each system.

4. Do not discharge directly into the lake. Aim hoses away from the lake and storm drain systems.

We request that you incorporate these suggestions in your operating procedures for testing the fire protection system. However, as you are aware, the final responsibility rests with Duke Power Company to protect the waters of the State and the envirorsent.

As always, please contact me if you have any questions of if this office ray be of further assistance.

Sincerely, '

pt co% t .

• I

-c

[y"'***" ,k Nancy Weatherup, Engineer

= r Industrial & Agricultural NW/sgr a MAY A 196p Wastewater Division E d' 4,, v SCR

e RL DISCHARGE .

CNS EFA s.o. Musn etne (copy frone itenue i of Form s p

, PLE A'E Pftt*iT G64 TYPE B74 THE UNSHADED ARE AS CNLY. You may eepoet some or all of a,e,,

.. .ao. i.o p.,aie.r ..t~ v.es,ein a1.aue

osco.m e.mu.m p.rs. SC0004278 ., . .,, ,,, i 3 , ,,

,3 f ter.Y f tt s(* T stM

v. BPel AKL A*.D E f f LULP.T CesA P.4flT A - You enust suuvuk time- eewstss of at least or e an styus lo. cuery gaullutant en ttus table. Cornplete one table for ca:h outf all. See instructions for additiona; details.

3. UNITS I e INT AKE (opslam. alp f' 2 [FFLUENT **dhH a m e t y w a tu a ' be.ama j sy g,w w atut ' c a4NUp g m d eeO OF A EHA E 4 #F th N O OF i n. POLLU T Ard T . .e a .a.u

" " * " ^ " * ' " ' '

.....'.V.... N - --

^ " ^ ' " * ' 'Oa"EE".' ...t.'... 1.i --..

.._t.'...._ s . 8 -- - . 01. .._ s 8 -- -

1.5 1100 1 mg/L lb/ Day 2.8 1.928 1 f C,",*~~'

L-10269 1 mg/L lb/ Day 15 10,327 1 I ggf;- "-~-' 14

( I e4 4 O*g c-t - .1.>c,

.C 4.6 3374 1 ag/L lb/ Day 4.8 3,305 1

, - 16 11736 1 fng/L lb/ Day <4 <2,754 1

-seu

• ^ - ='***' .1 73 1 mg/L lb/ Day .06 41 1 l _

watuk watae LaLua watus

' '

• 37.9 102.1 82.5 CR MGD X 82.5 CR VALug

't W A4 ut wALuk waLug 15 CR 10 CR

'~ '"8 22 VALuL g w A L 68 E WALUE l

I- .

wALu& .C 32 CR 8--~' 32 28 CR i

' ...=u. ...u w a - .= u-

..u ST AND ARD UNITS j ( e se 6.7 7.5 52 _/

l 7n _

PAlli 8 Mask ~X .n column 2 a f.sr eacf. po8*.utant y2u know or have reason to bolagve as pr esent. Mesk ~X" en columrt 2-b lot sech poilutant l you For beheve of has to be absent.

pollutants If you for wwhich youme masrkk colum wtuch as Ramsted eethes des ectly.Os .ndesectly b I empressly. en an effluent lametations guedelene, you must provide the f etutts ofthe See et least one analysis instruCInons for 2nsi for eddata that detaals pol utnt.ead ieques ements.

Cotorrin 2a. you su.aest prow.de quantitatsve data os an eaptanatson of the t presence in yous descitargo. Complete one tet.le for 6och outta11.

4. UNITS S B N T A K C ( sgs .oen.st) 3 3_. E FF LU EN T

3. t*Ot.LU T- A E VALug A td T A re D **

..: * "". '.". a n s e. u n a .L v V a t u t ' """'MMM,* " ^'"' " "' MMNI,'f * ^ # 4 NO, Of m ee m t.

. L ONC E N. ta -ags A L la a N,O, a.g.

Of C AS NO.

. a

- -*- ~ ~ * * '

.r1.. i.i -- .. vus .a ~ " . .th. .. e i - - .. vu.

i a mu,, =. c. .. .

,11... i.-... . ._. . t.i. . . i .e -- . .

. e. -.

<.2 <147 1 mg/L lb/ Day <.2 <138 1 i2e m u +> X

,uC w (73 1 fug/L lb/ Day <.1 <S9 1

! T .a n 1-. X <.1 c*'** 1 pcu X 15 X 1 1

• X 15 X _

1 No./ X 5 X 1  ;

i C.

X <2 X innm1 l _ _ _ . _. . _ . _ _ _ _ _ . __.. ---_ _. -

1 mg/L lb/ Day .11 76 1

" .%"Jo i I

X .13 95 _

.n....... 1 mg/L lb/ day .07 48 1 u . . .v . X  : .23 169 s* A G a. V - t CONTINUE ON REVLIISL 1 - . - - ,a. wu > u.a l

CNS-001 .

e fF as VM CC9dTINtif D FIOM F FONY WLkN T 3 MTS 5.iNTAKC(.ets. M s.rOLLUT. a u n w es m '-

coaca . *C. MMS 'S*".c ," J' "c",'3 7l* . ri' :. . -- = .=u= n a.'v v a tue * " *A"".'f" JJ.B^7 " * '"' * " " N'.".f.'If f " " "' "a. a '

= ~ ~ . . " ,- T.C ~..., o. "- - . t.' . . -u- ' " ' ' " ' "

. .- . t! . . oi - -

..s . Js .

... i .i -- . . i. i --.-

i.". 7o*.*.*."/ , X .37 271 1 mg/L 1b/ Day .46 317 1

a. oa =-* X .35 257 1 mg/L lb/ Day <.1 <69 1 a.

X .07 51 1 mg/L lb/ Day .04 28 1

[.,W.,23

.e. ,

I_

o it dn.wis.se, s X (.4 X  ! I pCi/L X <.S X 1 sv.o.cie

.: g s28 **. X 4.51 .8 X 1 pCi/L X 2.71.7 X 1 T .e asi a.4 . X <.S X 1 pCi/L i X <.S X 1

, re a tei a- X <.5 X 1 pCi/L X <.5 X 1 2 >e.1 s' s . X 38 27874 1 mg/L lb/ Day 18 12,392 1 ges 304p

( B 48018- F* 8 D

.s eu. X <1 <734 1 mg/L lb/ Day <1 <688 1 c,

'" d X <2 <1467 1 mg/L lb/ Day <2 i <1,377 1

,;i3y t14266 46 31 X .3 220 1 mg/L lb/ Day <.1 <69 1

,t *,- X .5 367 1 mg/L lb/ Day <.3 <206 1 i ren .a si ~

.02 15 1 mg/L lb/ Day .01 7 1 7,87"'"- X ar o n si mg/L lb/ Day .07 48 1 y,*~. X .11 81 1 i14 0c2 ei _

,-y'. X <.1 <73 1 mg/L lb/ Day .1 69 1 i,... 4i L _ _ __

X . '.3 425 1 mg/L lb/ Day .19 131 1

. w. . vu

, ir:n ee si _

1 mg/L lb/ Day 1.9 1,308 1 t

r. u e.

X 2.8 2054 e van es 4 A u=*****a-"' X <.02 f.15 1 mg/L lb/ Day <.02 <14 1 e sen se 2i ._ ____ .._ _ __

1 mg/L ib/ Day .01 7 1

{,",-- X .03 22 inca a si 1 mg/L 1b/ Day <.5 <344 1

.u . v.=o.

2 .. v .'

T <.S <367 1 mg/L 1b/ Day <.006 4 1

.ae '

s.e.e T .02 15 i F44o 32 41 CONTINUE ON PAGE V . *

~- PAGE V-2 s es s win.7c an,w 7 ns.4

l .

I .

tra a o_ seuaestse f..,s.y f e sia e i of Forno f) ouv r mLa. eeues es a 0"8 * * *88 SC0004278 001 re. o..e .. no ae

' ctweiet.ut o e etoma ru.t 3 OF eonu 7 C o

PAtti C . is yo .se a pe.many n.suvvy and u s ountast cunaa r.s psuc. s.wastewai.e. setes to imble 2c-2.n the mstrucs.uns todeteam.no which oi ttw GC/MS isect.ons v u must test for Mask "X~ en column 2 . Sw 34 th GC/ WIS hatt.ons thes as.piy to yous .she y ami Los All. no..c eneesta, cyamdes. and toast phenols. If you are nos sequw.d to mas k column 2 a (secon f.sy sadusstset, nonproces s

.sse .ss ovat as. enfia.svevow ?4,C/MS /s.csus>J. mm k T n casumn 2 as sur e.ch postut ns you know or have reason to ben. eve ee psesens Mask ~X"in column 2 er astprovidetheresuits toe each pollutant you s

t s.ee. .bsene et you n sek cos a 2.tw .ny l-. . a you muse peovede the se.uats ut at lease one analyses for that po sutant. If you mank casumn 2b los any pollutant. vuu t see.s on m #rs.s sw sh.ss pussusana f y know v. ha s. ass.n to bra we ;* will t,e d sct.aaged n concenivat.uns of 10 psa ur ere see af you mask coaumn 2b for acrose.n. acsytosussile. 2.4 s 4. a. c_c :_.v c.at. you n.uss sno..d eh se>uais ut .? se43: un. en.lys.s fue each of these putsuvanas wNch you know o' 'save sessun to bet eve that you d scharge in

. .% # .ne. en 2- neu.y m u..s ...I IOopge<w gee.s.r Osbarwese, f** s.ussue.nas tu, e h you n k cuausi n 2b. you must e.shes subm.: at isass one anatys.s us te erfly descs.be it e ee sons the pollutant .s e=pecie.,to to, u , a huse ism.s shees es 7 pages to sNs swt. ps.:ase se.. w *h c.setutsy Complete one table (m# 7 pegent for each outtast See anstruct.ons tus ado.s.onal de s.ts and requwemenss

4. uteiTS 5. t N T A M C (..p.fa.m.f A s . 9-OLLUT AN T 2 ne n .e s. a- 3 L s ra.u t teT 4 ed sst s * * * * *

• • , C

. a a.asuas pass.Y Lu YMQ N .eo m A 9e A a/

. roseCr se

'"^" " IsDeAss a mIpe A A UE h

A pe A L

!!.- .':-- s.: -- -

5t= v5**

68- --

o'-'*' @"- " ,h~' , ~~~ 3

. '.L.*

85 n _' m . .;.8 . . _

• .8----

_ . . f.' . . .

sat T Ats CirAfdsDE At40 701 AL PIst NOt s _

<.6 <440 1 mg/L lb/ Day. <.6 <413 1

".^."I."L'"Ao, X

<1 <.73 1 pg/L lb/ Day <1 <.7 1

, l"a$'3.'s'*** X

<.001 <.73 1 mg/L lb/ Day <.001 <.7 1 7',.',";;aW, ,, X

<2.9 1 mg/L lb/ Day <.004 <3 1 l '" .'. Oh X

<.004 1

<22 1 mg/L lb/ Day <.03 <21 1 i

r O.'.'",.ao.,3,' X (.03 1 og/L lb/ Day <.03 <21 1 l ,*"g '**' X <.03 <22

<.08 1 mg/Lllb/ Day <.08 <S5 1 j $g ,'* X <S9 i

<.1 <.07 1 pg/L lb/ Day <.1 <.07 1 X

l 7". g ;"* __._ _.

(29 1 mg/L lb/ Day <.04 <28 1 l *" jg";, '"" X <.04 X <2 <1.5 1 pg/L lb/ Day <2 <1 1 Tes.4 (,FS2 49 23

""5**'"" <29 1 mg/L lb/ Day <.04 <28 1

- X . 04 g,440 22 44 1 mg/L lb/ Day <.5 <344 1 l ""

im ':'*e."o-r e oi X <.5 <367 a __ _ . .

) 1 ag/L lb/ Day .02 14 1

'2 N '"" X .02 15 t i.".a e. 5

~

A.02 (15 1 mg/b IblUh <.02 < 14 1 iao i-.e c., is u se X

1 1 ag/L lb/ Day <.005 <3 1 X <.005 3.7

.m r -.- .

l .Ye1 -.. I

~

.asz.r.a .suais a

.. . s u < u X*t NEGAT1VE CD84 Int 4L3L Ord &tLVLl45L e* A(.4. V - s

CNS-001 .

CONTINtK) FROa4 THE FRONT O. UNITS 5. 8N TCM C ppsesm elp ,

i. pot.LUT(2NT a so m mes an- 2. E rrLUCe4T peUMBER annataeues pasLv waLuc * ** "" 'M ** Nf

" MSd.N' # d am - a CONCEN

- ' a-

,,,,,,, Ahah NA m

" * [,'

m.

"l***'M -.

.=. =*;,".;=,*,*._ ,,_..e.... _t it.:.<:-

,.,- m, .

.e .. ...... . . . . . . , . . . . , _

GCAss FILACTBOed - VOLATILE COMPOUNDS iv. Aen.a.in

) <20 <15 1 pg/L lb/ Day <S <3 1 isere2e . - s.e __

2v. a.+ehieiw - <20 <15 1 pg/L lb/ Day (S <3 1 sist4.>irp e - )

2v:e A.' -

) <20 <15 1 pg/L lb/ Day <S <3 1 cric23 - ~

ev.ai. gens X X X X X X

- ad8 e *=' X N/A X GS42 46-il

<20 <15 1 pg/L lb/ Day <S <3 1

[7.'2Y5 X s' ~~ ev. c <20 <15 1 pg/L lb/ Day <S <3 1

!'&&21ft t

X _ l 1 pg/L lb/ Day <S <3 1 7V.

sio. c.h.eerebenaeae ri X' <20 <15

~

v. cna 1 pg/L lb/ Day <S <3 1

= - - - -m-- X (20 <15 1 2143 it

'7, o'."If'""*** X <20 <15 1 pg/L 1b/ Day <S <3 1 iOV. 2 Consere-

~~******' X <20 <15 1 pg/L lb/ Day <S <3 1 (ii4 7& C'8

.. - 1 pg/L lb/ Day <S <3 1 i.,v.micmi X <20 <15 irv. oira -

1 pg/L lb/ Day <S <3 1

.6= - - - --- X <20 <15 (FS27 43 3 2V. Oechtero-^ - - - X X X X X X

• ^ - X N/A X i re-rici 1 pg/L lb/ Day <S <3 1 EYS$Y X <20 <15 1 pg/L lb/ Day <S <3 1 Efi 73 X <20 <15 1*gdWli v' <20 <15 1 pg/L lb/ Day <S <3 1 1 pg/L lb/ Day <S <3 1 "7*/? 7.%I i X <20 <15 -

irt u m 1 pg/L lb/ Day <S <3 1

,, s.2 n ei X <20 <l5 1 pg/L lb/ Day <S <3 1

,'ik 'i* f'****** X <20 <15 1 pg/L lb/ Day <S <3 1

'0EIle'es si X <20 <15 1 pg/L lb/ Day <S <3 1

• ' '.J.",**7,'.' s , ., . y <20 <15 ,

CONilNUL ON PAGE \

racc v.4

. . . . - w m. >c . . 3..u

~in's olv .i a ~#<.,y trv.= ss<=. 8 1 Fer.= a s ou

• 0 a u awa*.* **

001

^

SCOOGl.? 7:;

omrewur' t Rou Pact v4 c. UNIT 3 O O M T C. M E (*P8=.**Is 3,rotsUTANT s ..een a- 3. EFFLUEN T *

"a~'

'gr" a urs .**--.*'."" 4,~,,

.g- .co-c. __d na".%"" z._ .".'J '

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OC/MS F R ACT BON - VOt.AYILE COMPOUNOS is

,2. _

X 1 <20 <15 t 1 pg/L lb/ Day <S <3 1 c = irs o.2, ,

J J w. 9.9.2.2 T.e.. lb/ Day

'"1 ,2.ca "* IX <20 <l5 1 pg/L <5 <3 1 __

n.1

.,. 2,

..., X <20 <15 1 pg/L -1b/ Day ' <5 <3 __L l% ,',*'7"* X <20 <15 .

1 pg/L lb/ Day <5 <3 1_

2;v 5.2 T..a.

==- x= X <20 < 15 1 pg/L- - - ~ lb/ Day

<5 < 3_ __ __1 _

i 9S4 SO SB _ . _ _ _ _ _ . . __ _ _ _ _ - . , - -

2Fw H .1;.1 1i T.b X <20 <lS - - - - -

1 pg/L

-lb/ Day <5 <3 _1_

uisi ss a _ _ -- . - -

25 Y. B. S.2 f.4- pg/L lb/ Day <5 <3 1

. X <20 < lS 1 m oo ci .. _ _ _ . ._ _. . . _ _ _ -__ _ _ _ . _ _ _ . - _

8 ',';, '.",*;'77, , X <20 (15 - - - -

1 pg/L--

lb/ Day

<5 <3 1 mov s.u ..

X X X X X X e -a.-- X N/A X

- s m *' a _. _._ . . _ _ _ _ _ _ _ _ . -- . _ _ _ - -

S".OI's o, ,, X <20 <15 1 pg/L lb/ Day <5 <3 1 oc;us e RAcnou - Ac.o courounos X <10 <7.3 1 pg/L 1b/ Day <10 <7 1

((. ![c"******'*

2A 2.0 Dste *e X <10 <7.3 1 pg/L 1b/ Day (10 <7 1

.+ site si 2:

in 2-..eeom . ,.,., X <10 <7.3 1 pg/L 1b/ Day <10 <7 1 CA O G D*a.e.e c.W m. ,, ,O ,

X <10 <7.3 1 pg/L lb/ Day <10 <7 1

=a 2 a o s .

o n 2. . , X <10 <7.3 1 pg/L 1b/ Day <10 <7 1

<10 <7.3 1 pg/L 1b/ Day <10 <7 1

$^.***,7**'*"** X

[ ^e[cU,****-*' X <10 <7.3 1 pg/L 1b/ Day <10 <7 1

[^M *.0, X <10 <7.3 1 pg/L lb/ Day <10 <7 1 1 pg/L lb/ Day <10 <7 1

..L*".7,7*. X (10 <7.3 X <10 <7.3 1 pg/L lb/ Day <10 <7 1

. . [7

..a 2 4 6 f ee

. ~ . - - X <10 <7.3 1 pg/L lb/ Day <10 <7 1 s'd DN IINut UN 04L Vt. 04:.

c:s-co:

• CONTINUTO FROM Ytti FnONY 0.POLLUTCNT ees-ma .- 2 t e s Lut.N T O. UN BY % 5 SN Tf,6(E (wgesumeis l,

""8.55$ =

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OC/MS F RACT$ON BASE /NE UTRAL COMPOUNDS s^1 As-_ _.:

582 22 Ce X <10 <7.3 1 pg/L lb/ Day <10 <7 1 2.. Ae - - - - - - -

mS ** 'X <10 <7.3 1 pg/L lb/ Day <10 <7 1 3..A ~-

i2* o n X (10 <7.3 1 pg/L IL/ Day (10 (7 1

' *2 *TEI e X <20 <15 1 pg/L lb/ Day <20 <14 1_

se s . t.n 75 j;"* "

X <10 < 7. 3 1 pg/L lb/ Day <10 <7 1

" " A <10 <7.3 __

1 _y g/,L_ __lb/ Day <10 <7 _ 1 1 1 2.c

[is,fai "~

X (10 <7.3 1 1 pg/L 1b/ Day <10 <7 1 e.. . . sms

',*',72,

, X <10 <7.3 1 pg/L 1b/ Day (10 <7 1 g..' . .. ,

pg/L lb/ Day <10 <7

'2 %*"'*" X <10 (7. 3 i 1 1 304. Se (2 Ch8w

<10 <7.3 1 pg/L lb/ Day (10 <7 1

$ d E****** X s i .. .. .uu

' <7.3 j 1 pg/L lb/ Day <10 <7 1

• 0'i . ET' X <10 _.__ _ _ .._ _

32s s.Oh '

• ta-se'8 X <10 <7.3 1 pg/L lb/ Day <10 (7 1 3 2.. . e2 na,&

U;fjC'3'**" X <10 <7.3 1 pg/L lb/ Day <10 <7 1 u.. o -

@M'5 23 '

X <10 (7.3 1 pg/L lb/ Day <10 <7 1 is. . .. ~ ..

. pg/L _ _ _ _ _ _lb/ Day <10 <7 1

• • • • • "'"S**X .__ ( 10 _ ._ _<7.3 is 2<=

<10 <7.3 1 pg/L Ib/ Day (10 <7 I

• • ?'T X I F3. O cme.e-C'l,%','2 2i x <10 (7.3 1 pg/L lb/ Day <10 <7 1

... c r

'Ci*' X <10 <7.3 1 pg/L lb/ Day <10 <7 1

... o . T ,

(10 <7.3 1 pg/L 1b/ Day <10 <7 1

^WT33

. X l t 2e. i .2 o= .

-- t ** ** s i < i <10 <7.3 1 pg/L lb/ Day <10 <7 1

, _ _s__ __ . . - _ - - -

2 I O. i.) O*r M .

~~ <Sai n

• 1A <10 <7.3 1 pg/L lb/ Day (10 <7 1 l CONTINLIE. ON 5'At;8

[PA forre 3 510 2C (Hew 2 ftti FAGt' V -6

r - as ~ * .

• 'ra s.o. esuneesse (2.py fre.se Assaus A of Feries JJ ouTVALL cousnesse i 0A88 Are 2040 0086 SC000427a 001 l e- s. .. i ar-ss .

CC-ifI s E 7 F 540M PAGE V4 S. IN T A MC f. p,4ase.3) ,l

4. 4.N 8YS btY[dITANT a . .* a se se s- 3.CFrLUCAT

. 0 A","a 'v ' y,a.g C.4SN '.::.J.:n ..=a - u= =arva'u=

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OC/MS F RACT80N - SASE/ NEUTRAL COMPOUNDS (c.an.=ed- ,

it',ft$2'i,

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1 pg/L IMD: / (20} (14 1 i _ _ _ _

is i.e+ u .

245. D6.thyt chu w. X <10 <7.3 1 pg/L lb/ Day <10 <7 1 ms ss 3s __ _ _ . .

25s. Darse.thyl Pheh.6. X <10 <7.3 1 pg/L lb/Daf <10 <7 1 (128 11 3) 24st. D6 N-Swtvi r~ h... . X <10 <7.3 1 pg/L lb/ Day <10 <7 1 (L e F'r2) 2rg.2po,qa';,,T <10 <7.3 1 pg/L lb/Da;, <

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<10 <7.3 1 pg/L ib/ Day <10 <7 1 2*d,'fgg",*2, X

NI ?.'," "

X <10 <7.3 1 pg/L 1b/ Day <10 <7 1 siirms ___ __ __ _____ ____ _ _ _ _ _ _ _ _ _ _ _ _ .

308.1.2 Diph.avF X <10 <7.3 1 pg/L lb/ Day <10 <7 '

I hvo. . 4,.

sanr- o s n22 wi: __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ . _ _ . __

3'0.*6 = - "'.~ X <10 <7.3 1 pg/L !b/ Day (10 <7 1 (206 44 Cl X <10 (7.3 1 pg/L lb/ Day <10 <7 1

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%5 WC DISCliARGE sen s.o .uuan ne g<.py from Isame 8 et Forme ay g,,,

t E ASE PRIN T OH TYPE IN YttE UNSHADED arf'AS ONLY You may report some or au of OA88 Are JudJ 0086

• 6 8u.m.s.un on seperate sfueu (**** 88 ad"* #8***'l ***'**d of comptes y shete p*'e'-

SC0004278 * * 'a *^J'**

4 e ensIissit'TsONS

% I 4% FIT A - Yuu most issovide ti e results of at Icast sne analysis 8or every p>llutant in this tat >!e. Complete one tatste for each outf all. See instructions for additional details.

2. CFFLUENT 3. UNITS 4. INT AKE foras mal /

8

e. POLLUT ArdT . es a m eamuna .'s .a.w w a s.uc k ^ '"i .'/ "d.i.D ' ' ^ '""

MM.Rf V AN as wo. or a tons va avewar.t u.sua tnr a6een or

_L',, . . . 8 8 ---- . . . t1. . ..- t i ---- .

. P1. . . ,.. bi -- - ^ " ^ * ' " ' *EIfvE"' " " * "

. . . t!. . . .  : t --+.

" " ^ ' ' " *

....-.a

,'~',,"~~'" 5 54 1 mo/L lb/ Day 2.8 1.928 1

"-"",*"***'-' 26 282 1 mg/L lb/ Day 15 10,327 1

. t . o. .

c . t 1. >c, 8.1 88 1 mg/L lb/ Day 4.8 3,305 1

.. . .. s a ,

~*-"" 17.8 159 10 73 24 mg/L lb/ Day .4

. <2.75e 1

- ^~~-~*'-** 2,7 29 1 mg/L lb/ Day .06 41 1 wmLug waLut waL e w a t. u k 1.3 1.07 .88 188 MGb l X 82.5 CR a '~ wALuE wmLua wmLuc wALut

< - ,. 10 CR vmLug v s u s. watut bakut

, C CR

'---~8 23 32

....u. - a . .. .;-

.r. . . . u. -

-...o-

. 4e ST ANDARD UNITS 6.7 7.5 53 i 6.9 _

l'AHI 6 Mark "X" en column ?-a los each p,cutant you know or t+ ave season to twel. eve es present. Mask ~)C* an column 2-b for each pollutant y>u bel. ewe to t,e stesent. If you mas k column 2a los any pollutant wh.ch es t.m.ted eethen dis ectly.or snderectly but esgwessly. an an of fluent ismasations guidelene.you must provide the resuiss ol at least one ssalysas ica that pollutant. f os othor pollut ant s tor which you mar k (caosan 2a. you muse p.ovede quentatatewe dsta or an emplanation of theer presence an yous d scharQe. Complete one tat >Le for esch outfall. See the enstsuctions fos edd.t.unaldata.fs end requisements.

4. UNITS S. SeeT AKE / esJo 4fp

1. *'***"*' 3 EFF'UENT s f OLLU T-

..":1/1. ::.. ~ - "-- a a n a '--

" " ^ " "Ul".

• tM * ^ '" =

" ""#'" /M.P " ^ = y,o,gy- .,Lo.ca. ,,,,,,

a .' FJ.","u, y,og,

^c " S,' a.s.,,

^la" , _. . r.i. . .._ =^naa wo.

,.r =. .=. ... i... _ i..... . _. . t1. . .._ i . t . . .. i.i ... wu. , _. .t!.. .._ t .i . . ..

o n '> <a 'ei y <2

. <2 1 mo/L lb/ Day <.2 < 138 1 c .. lb/ Day < .1 t o. a ~io. X <.1 .: 1 1 mg/L <69 1

< c*'** X 25 X 1 pcu X 15 X 1

' 'T. *' X 16 ~X 2 " dO0ml X 5 X 1 mg/*. Ib/ Day .11 76 X i O~ ate ~u t X .14 2 1 .

.n....... mg/L lb/ Day .07 48 1 1 ...........vi X ,

.36 4 1 r A G a. v - t CONTINUE ON REVE HSE t t' A t ue.. 3'210 2C (H v. 2 ts's)

CNS-002 .

STFM VA CONTINtfFn FCOM FCO*dT 9. 8 N T A K3 g.f- _ *) *I

4. U NITS 3.EFFLbENT

3. POLLU T. 8 * * * ' ' " * * '

a0e' tam D V ."e$.c la

,N_O O ..

S,d[a d'$* j ***** 7 8 *

• ." m e_.'. Coosca se- g ,,,,g C Sa

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. s e - :. " '__

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es ==n-ws ~- ~

.__e ..

. . _ _ < u -... .

e..

• o. ~ . 1 mgl L lb/ Day _ . 4 6 _ __ 317 __ 1

..m X 3.5 38 ____

. Oil .a.

.3 2 24 mg/L lb/ Day .1 < 69 1

.u- X ,3 _ 7

. c X .22 2 1 mg/L lb/ Day .04 28. I

• • ,$'i ,' **4'

, n . ..

. i aie .

X <.5 <S 1 pCi/L X < .5 X 1 en ns X 1.3t.7 X 1 pCi/L X  ?.7 + .7 X 1 1

is n ma' X <.5 X 1 pCi/L X <.5 X 1 i<a n 223 v e'=' X < .5 X 1 pCi/L X <.S X 1 m.SmAfsue 4,122 1 mg/L lb/ Day 18 12,392 1

'",,',*f,,,,, X 380

8. Cao.4

'~ o < 1 < 11 1 mg/L lb/ Day <1 < 688 1 X

. s m..

X <2 < 22 1 mg/L lb/ Day <2 < 1.377 1

'".$.".#. 3, c +.a-.. .2 2 1 ng/L lb / Day <.I < 69 1 l X i .. Si ia 1 mg/L lb/ Day <.3 < 206 1 j v ...

euess' es si X <3 3

', ias 1 mg/L lb/ Day .01 7 1

,',)$3.3, X .02 .2 1

4. e lb/ Day .07 48

.19 1 mg/L 1 l l,*ja.43 , X, 2 _

.. c.i..i.. mg/L lb/Dhy .1 69 1

<1 1 l,*ja ., X < .1

. . . v .. 1 mg/L lb/ Day .19 131 1 ir42e ce si X .15 2

n. ue . 1 mg/L lb/ Day 1.9 1,308 1

,m,,,,' e. . , X 1.9 21

...u.-. 1 mg/L lb/ Day <.02 < 14 1 n ,a n X < .02 < .2 _____

.m.v 1 mg/L lb/ Day .01 7 1 l,*);.' ., X .02 .2

. i i v ...a 1 mg/L lo/ Day < .5 344 1

< >.40 2 ' 5 > >

X s .S <S

. . u. u.

1 ng/L lb/ Day <006 4 1 l,*;& ,, ,, X .006

• 06 .

P AGE. V Z cot 4TINUE ON PAGE V

- - - . - ~ _ _ _ _ . . _ - . ~ . .~_ . . . . - . . . . . . . _ _ _ . - . . - . . _ .. . _ _ - - . ._ .- - _ _ .

. e tra e o. numeos a tse.py fr.no 8sene 2 el fanse 8> ou y sv a Ls. ee uen en se

!aree Aarr.eedt d 5C0004278 002 Oa., ., ma ,ou Aos ee.8e.pnes7 39 38 CteedTItatJE D FPOaA f' ACE 3 OF f Of1M 7 C i

1 I"AN T C . si vuw ere a fw unary moussay end et.es eustan centa.ns process wanew.see. neter so Tehse 2c.2 m aree instrucceens so desermene wruch ot :8 GC/ MS tr ecteons vou musi ness ser . Mee k -)c" an column 2 a fue ,se th GC/MS to aos ons shes apps, se your omsw.ts y and leer ALL tonic enetafs. cyerudes, and totas pnenois If you are not regisesed se mask column 2.a lseconderr aredussraet. aceprocess evastee,eser euttm#s. andssvareguumet(rC/ AfS tracts.urst mark ~M'sa coluenn 2-0 los each pollutens you knoiar or have reason se temaseve es psesene Mark ~X

• en column 2-c for each pollutens you s.orteeve e. etssent sf you nnash column 2a los any gee,ti tans, yo e nn.se smovede she #esults of at feats one anahus for that pollutant . If you metk coluenn 2b los any gNoslutant. you must psowede the seeulta

.,8.es inens une ennsynes $ws thas pattestans of you kreasov se 2.%s e. awn se be swe se emil be desci svgod en caencentsatwns of 10 ppt,or grossee. H you meek col emn 21. for acroleen. acsylonetrale 2.4

.a eseosAseeerst, os 2.esiothys 4, to eser Jarenehenot, yees ee wse smeowease stees s eermee es of as least eene analyses for eacts set thebe postutants whsch you heteve es have see;,e se beleeve that yons deactierge en c.4w.e u.esen.asof I00ps.hsw ge..ser. O-herwese. 8.= s.o.isusens Ian e=re to ye.u eenan a ceause.ri 2tn. yoes muss sher submes at seass one analyses.s sere.ft,desce et, sh.esasans the pealueens se ==pecsed su t,. st.wh y 8 Nese sau these ere 7 pages se thes gsmet. pt.ase see ew era (f. ceae8.sMy Complete one table (a# 7 popesp for each outtait See anstructions tus me t.e.onal detaeas and sequeemensa

3. Lgr Ft.UCNT 4. UN4 TS 3. s>sT A K C g pre swis

9. 0-08.8.0 Y A N T 4.esneeen a-

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se uass t "L~*.. g.g , . a,s,e a, a,nssai,n.- Y n aT son ,,,,,,,

• . ..'. _ , {* 8,,, ,,,,, iel =. g,,,, , s .,1,,, , g,g.... , I.,l, , g.g ..

sef **=_et.8.8 .. 8.. es . .-

F_A& I ALS C_VANIOf A_NC. .T_OT At. f* lit NOLS - -

.a a e ag/L <.6 lb/ Day i '"**'"***'*' X <.6 <6 .

I <413 I su see a. v.s.e j " ** '8 2 '

X <1 <.01 1 pn/L lb/ Day <1 <.7 1 au.e .

<.001 <.7

' '-*'***'" X .002_ .02 1 mg/L lb/ Day 1 au c o .

'-'-'"***'* X* <.004 <.04 1 mg/L lb/ Day <.004 <3 1 c.

'""***'* 1 sig/L lu/ Day <.03 <21 1 X . _. -. <s 03 <3_ . - - . -.

MA casese.Iasel 8"***' _j( . <_03 <.3 1 mo/L lb/ Day <.03 <21 1 1 Pu need. Teens

! *"*3" JL ( na eq 1 mo/L . Ib/ Day <.08 <SS 1 r

=u u.e y. Y.i

"*' < 001 1 un/L lb/ Day <.1 <.07 1 l _1 _

< .1 . I' e.a v.e.e lb/ Day. <28

"***'*' c 04 1 mq/L <.04 _ 1 l

_jl _ __c4 4

suu. s a e..

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• c o? 1 uo/L I lb/ Day <2 <1 1 l 1 to Sd ee. T e.a

"***2*'

<_o4 <_4 1 ma/L lb/ Day <.04 <28 1

.x 9 Ju. Y a e*H

'*

• 8'** " S a' 6 1 sq/L lb/ Day <.5 <344 1 l <h

. w z e.. T.e

"***6 -1 sq/L lb/Dav.. .02 14 1

.X .. .03-- . ., , 3- . . . - - _ -._ u

.. c. .

. -.g/L m lb/ Day _ <.02 <14 1

_.i -u n ' ' 2 $ '. .. . X. . .< 02 -. - < . 2 . .- . - - . _ -.- - - . .

1

.w r mo/L elb/ Day <.005 <3 1

- y noci < oc, 1

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x MGTIVE = a r. r se . , CONI 4NUL ON HLVLetak

__ _ _ _ _ - _m

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s

. 5 .-

CNS-002 f*ONYtNt1f D FftOa4 THE f'.70NT

• 4, aJ NIT 3 O. IN T A M"C despedame.fi

3. POLLUTANT a.e.amse m* 3. E fhLU E N T

....e- h e.- c..- e. .a a m teau.e p ast.T wm Luz

• N ** I.S.)[

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i_ ...... ,,,,,p,,,,,,,

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GCM Fft ACTION -v0LATILE COMPOUNDS X <S <.05 1 pg/L lb/ Day <S <3 1 l7ir^c"aU},.sj,

' <.05 1 pg/L lb/ Day <S <3 1

,'75,%7',*! X <S

<S < 05 1 pg/L lb/ Day <S <3 1

7/**" X .

cv X X X X X X

-.. <=,n ci. rchw r ee.- X N/A X suz e..,s

"*" (S <.05 1 pg/L lb/ Day <S <3 1 l7; *'*2 X

<.05 1 pg/L lb/ Day <S <3 1 X <S

'i.

es

'23 5,."n7

< 05 1 pg/t 1b/ Day <S <3 1

, c76.*."$"f'*"* X <S .

ev.cea .ar <.05 1 pg/L 1b/ Day <S <3 1 X <S

( i 2. -

<.05 1 pg/L lb/ Day <S <3 1

, 77gg'"****** Xf <S l -

nov.2 c= ., <.05 1 pg/L lb/ Day <S <3 1 1

.a r .. t m. X <S

( 31 & F3 Cp

<.05 1 pg/L lb/ Day <S <3 1 l37d$'"*'*** X 1 <S 3 2v. owni-.- 1 pg/L lb/ Day <S <3 1 i : : m == X (S <.05 1F&27 )

13V. 08thi.e.- X X X X X X aan - X N/A X t 73-71 Cl 1 pg/t Ib/ Day <S <3 1

'*il

,, ,',$$7'***~ X <S <.05 1 pg/L lb/ Day <S <3 1 l,*,";,l fit,"II"27 X <S <.05

'*** 1 pg/L 1b/ Day <S <3 1

!*,";2",%"2s .,~ X -:S <.05 1 pg/L 1b/ Day <S <3 1

,'., ,'.;' 7.*E7'7 3 X <S <.OS ire u o.a .- 1 pg/L lb/ Day <S <3 1

! co isu nei X <S <.05

• 1 pg/L lb/ Day <S <3 1

,'[7d7i. '***** X <S <.to a

I 1 pg/L lb/ Day <S <3 1

• *'f.**il

., es es X <S <.05 . _ _ _

1 pg/L 1b/ Day <S <3 1

'a,,;,"*7ll ei s i X <S <.05 CONI 8NUE ON FAGE

<=*. r-.- 3s.a *<*.e. ,ese P Act; v.4

s.--.,w... ,

ou 8 ia' Ones 4 2040 aus.1 -

a ea e o. nu215KH* ir ** A&ra a of f.,

si feUr n a ..- n, ,,

'ON T sNi[D F ~ OM P AC F V 4 C. UNIT 3 D. INT A KE fortsos J1 m- 3. E r e LL,E N T l

8. PO LLU T A N T l 3 em a n sa

• " ^ ^ *" 'l". ' LG* " ^ '" ' " "' W'"J 1,P " ^'"' 4gt.' m M,i ."a 'v**""o e g r?

E", Mfd :f -- ". :i' . ~ . . - a = u" => = ' v a 'u t .co-c

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.- L!-- -- --" ' -"' " ' ' ' *- ~~'r ' ' ' - " - " ' '

_ _ ' ' ' * * * * " .-iE " E M _*.s r L!-- - Is.eds' ' ' - " - --<l'----

OC/MS F.JACTION - VOLATILE COMPOUNDS s<

22v.u a X <S <.05 1 pg/L 1b/Daj <S <3 1 Cha.a 4.s. ( ,.}c9 23 2 2 d. 3.i .2.2 -1 e.

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V ON I Ast i AND E r r LLJf NT CHARACTE i, PAllT A You n.us suovale the ses.. tis of at least oeic an.1vs.s fue ever, p.Aloi nt m thes tatale. Complete one table for each outf all. See aristructions for addit.onal detaifs.

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you bot. eve se the streect if you mark M-a 2a (w any y ' ant t*Atti 8 - Me h ~~X" en toten a 2 -a be sects po81utans yee. 6 nauw or have esasen se beheve .e present Mark ~X en colossue 2 -t. ler each M'-< Fer other pollutanta for wwhich you mas k a

) wi ch .s 8 r.rted e sher d.recity, or andeactly t>d e.pressly, an se offnuent limatetaans g'ad=8% you must provide the resules of at least one snahs.s for that podsr.an*

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"^" 02 CONTINUE ON PAGE V .

1 en t asio 2c in . r es:

O 5 s o e..o.een a 4. ra fr.no 8s. t */ Fene 8o oui e ALs. eeu.* es se Fer.e appre.ed 3C0004218 004 Osu n 20*o con A '.se.eae r 2rn

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i s -2.-2: X , <100 <.004 1 pg/L PAGE V-9

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