ML20094R672

Forwards Groundwater Monitoring Rept for CNS Conventional Wastewater Treatment Ponds.Samples Collected on 950905,in Accordance W/Sampling & Analysis Plan

ML20094R672
Person / Time
Site:	Catawba
Issue date:	11/29/1995
From:	Carter J DUKE POWER CO.
To:	Aponte H SOUTH CAROLINA, STATE OF
References
NUDOCS 9512050100
Download: ML20094R672 (6)

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!' DUKEPOWER November 29,1995 Mr. Harry Aponte SC Department of Health and Environmental Control Bureau of Water Pollution Control Water Quality Assessment and Enforcement Section 2600 BullStreet Columbia, South Carolina 29201

Subject:

Catawba Nuclear Station - NPDES Permit # S.C0004278 WC Pond Groundwater Monitoring Data

. File Code: CN-705.05 Certified Mail: Z 403 319 227  !

Dear Mr. Aponte:

Please find _ attached a groundwater monitoring report for Catawba Nuclear Station's conventional wastewater treatment ponds. Samples were collected on September 5,1995,in accordance with the sampling and analysis plan. -

All monitoring results met the South Carolina State groundwater standards. The i high sulfate concentration seen in the upgradient well WCMW1 has decreased l from the previous sampling event. i i

Should you have questions or comments regarding this report please feel free to contact John Estridge at (704) 875-5965.

Sincerely, l'

f n Carter, Technical System Manager ,

Environmental Division, Water Protection i

. jte/486 -

Attachments -

xc: Catawba Disteict Hydrologist CNS NRC Distributiss List 05(113 9512050100

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DUKE POWER COMPANY Oct:ber 2,1995 GROUND-WATER MONITORING REPORT Table 1 Facility: Catawba Nuclear Station Conventional Chemical Waste Treatment Ponds Sample Date: September 5,1995 (GEOCIIEMISTRY DATA)

Storet Monitoring Well Identification FIELD SC R6158 Parameter Units Number WCMW1 WCMW2 WCMW3 WCMW4 BLANK MCL  !

lab Certincate No. 00008 99005 99005 99005 99005 99005 - x Top of Well Casing mst-feet mW " 622.06 608.32 600.35 595.42 W e@@

Depth to Water f=t t@ 18.26 19.60 18.32 13.41 M ." #%d M Water Elevation (0.01') ms! feet 12545 603.80 588.72 582.03 582.01 @FMs2 Os e@ -

Well Depth feet x

1. di$n 25.% M5 30.02 30.06 21.52 MMB Field Spec. Conductance umho/cm Fieldpli C0095 1712 418 134 127.6 en x

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Std. Units 00400 6.7 6.7 5.7 6.3 #4 6.5-8.5" Arsenic mg/l 01002 <0.0010 <0.0010 <0.0010 0.0014 <0.0010 0.050 Alkalinity mg/l 57 90 17 49 <

30 45 MSMA 'MMM J Barium mg/l 01007 0.052 0.041 0.044 0.029 <0.0050 2.0 Cadmium ng/i 01027 <0.00010 <0.00010 <0.00010 <0.00010 <0.00010 0.0050 Cidoride mg/l 00s40 35 19 25 6.8 <l .0 250*

Cluomium mg/l 01034 0.0036 0.0086 0.0016 0.0058 <0.0010 0.1G Copper mg/l 01042 0.0065 0.0031 0.0012 0.031 0.0011 1.0

• Iron mg/l 01045 1.5 4.9 2.5 2.0 <0.010 0.3

• Lead mg/l 01051 <0.0020 0.0028 0.017 0.0029 <0.0020 0.050 Manganese mg/l 01055 0.042 0.21 0.18 0.022 <0.0050 0.050*

Msmi mg/l 71900 <0.00010 <0.00010 <0.00010 <0.00010 <0.00010 0.0020 NO3 + NO2" mg/l 00630 0.92 0.60 <0.050 0.22 <0.050 10 Selenium mg/l 01147 0.0022 4).0010 <0.0010 <0.0010 <0.0010 0.050 Silver mg/l 01077 0.00032 0.00023 0.00020 <0.00020 <0.00020 0.10*

Sulfate mg/l 00945 928 75 16 15 1.4 250" Zinc mg/l 01092 0 0070 0 0080 <0.0050 <0.0050 <0.0050 5.0*

• SC R6158.5(O) Secondary Maximum Contaminant level (MCL) for drinking water as reference only.

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Laboratory IEEfers # 7Nrk5($f!^U ANALYSIS REQUEST FORM ' .

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f2sCOENT: Pe'rson or group who is requestingthe~5nal sis. ~

,3. Project Name

Name of station, facility, and/or project (examples - McGuire Landfill #1. Marshall NPDES).

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5. Address / PROFS: Intemal or extemal mailing address / PROFS or FAX # (if desired method of transmittal).

i 6. Matrix /OC Level: (Example - sludge, groundwater, surface water)/OC level requi,d, as follows:

i OC Level 1: Highest level of OC. This level is for samples that must meet regulatory requirements.

i QC Level 11: All nonregulatory in-house and support studies.

(For LS Use Only) Work order number generated by SAM. ,

[! 7. _ SAM No.:

8. FRAC: (For LS Use Only) Sample fraction # generated by SAM.

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SECTIONS 9-12: MAY USE TWO LINES FOR EACH SAMPLE TO ALLOW FOR LARGER HANDWRITING OR FEWER SAMPLES-i j ~ 9.~ CHEMPLOT #: Assigned by staN.

1_0. Sample Description or ID: Brier description of sample type or origin (example - Monitoring well #2B), or sample ID series (Plant-l ,Date-Collector-#). c . ._._; _

[11. Collected using sampling instructions: Verification of proper sampling techniques. Dat:, and time of sample collection and name of

person who collected each sample (NO Initials).

[12. ANALYSES REQUESTED: (Write sideways)

Muslinclude ANALYSES REQUESTED, one column for each type of bottle (examples -[ COLUMN 1] Metals: Ca, Mg, Na, Pb, Cu, Cd, [ COLUMN 2] Nutrients: Nitrate + nitrite, orthophosphate, chloride, [ COLUMN 3] FECALS). Muslinclude type of preservation (examples -[ COLUMN 1] Metals: 5% HNOa. [ COLUMN 2] Nutrients: ICE, [ COLUMN 3] FECALS: treated bottles, ICE)

!13. May include preferred method of analysis or desired detection limit (DL) (if known or if attempting to compare numbers to previous data) (examples - ICP: Ca, Mg, Na. FURNACE: Pb, Cu, Cd). Otherwise, lab will choose de most appropriate method and

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l14. Sample Preserved /Name: Check appropriate box. Name of person who added preservative or placed samples on ice (NO Initials).

[15. Total # of samples: Sum of columns which have number of bottles for each analysis requested.

116. Delivered by, DateAlme, Received by: One section must be filled out by the person who delivers samples to Laboratory Services

! and by the person who received the samples. Other sections should be filled out if the samples are distributed among several labs.

l17. Comments: Any unusual circumstances of sample collection or handling.

l 18. Original WHITE COPY is kept on file in the LS Client Contact's active files. CANARY - Client Contact Copy. PINK - Client Copy.

1 19.-Tumaround Requested: Time frame client needs analyses to be complete and date results should be received by client.

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Form 35226(me05) g I

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$StructionS For Filling Out CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM -

1. PES CLIENT CONTACT / Phone: (For LS Use Only) LS contact handling the request. ,

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'~2ZCllENT: Person or group who is requesting theianalysis.

_3. Project Name

Name of station, facility, and/or project (examples - McGuire Landfill #1. Marshall NPDES). -

--4. Results to/ Phone: Person (s)/ phone # to directly receive analytical results.

5. ' Address / PROFS: Intemal or extemal mailing address / PROFS or FAX # (if desired method of transmittal).

! ' 6.. Matrix /QC Level: (Example - sludge, groundwater, surface water)/OC level required, as follows:

! QC Level 1: Highest level of OC. This level is for samples that must meet regulatory requirements.

, j OC Levelll: All nonregulatory in-house and support studies.

! i 7. SAM No.: (For LS Use Only) Work order number generated by SAM.

, 'L8. FRAC: (For LS Use Only) 9 ample fraction # generated by SAM.

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! -SECTIONS 9-12: MAY USE1 WO LINES FOR EACH SAMPLE TO ALLOW FOR LARGER HANDWRITING OR FEWER SAMPLES-

[ 9. ,CHEMPLOT #: Assigned by station.

i 10. Sample Description or ID: Brief description of sample type or origin (example - Monitoring well #2B), or sample ID series (Plant-i ,Date-Collector-#). r . .- . ; .

[ 11. Collected using sampling instructions: Verification of proper sampling techniques. Date and time of sample collection and name of l person who collected each sample (NO Initials).

j 12. ANALYSES REQUESTED: (Write sideways)

Must include ANALYSES REQUESTED, one column for each type of bottle (examples - [ COLUMN 1] Metals: Ca, Mg, Na, Pb, Cu, Cd, [ COLUMN 2] Nutrients: Nitrate + nitrite, orthophosphate, chloride, [ COLUMN 3] FECALS). Must include type of preservation (examples - [ COLUMN 1] Metals: 5% HNOs, [ COLUMN 2] Nutrients: ICE, [ COLUMN 3] FECALS: treated bottles, ICE) i13. May include preferred method of analysis or desired detection limit (DL) (if known or if attempting to compare numbers to previous data) (examples - ICP: Ca, Mg, Na. FURNACE: Pb, Cu, Cd). Otherwise, lab will choose the most appropriate method and

. detection limit.

114. Sample Preserved /Name: Check appropriate box. Name of person who added preservative or placed samples on ice (NO initials).

[15. Total # of samples: Sum of columns which have number of bottles for each analysis requested.

116. Delivered by, Date/ Time, Received by: One section must be filled out by the person who delivers samples to Laboratory Services L and by the person who received the samples. Other sections should be filled out if the samples are distributed among several labs.

! 17. Comments: Any unusual circumstances of sample collection or handling.

118. Original WHITE COPY is kept on file in th'e LS Client Contact's active files. CANARY - Client Contact Copy. PINK - Client Copy.

19. Tumaround Requested

Time frame client needs analyses to be complete and date results should be received by client.

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