ML18019A677
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ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-3570-2 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:
9/26/2013 4:20:36 PM Ivan Vania, Project Manager I (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-3570-2 Page 2 of 15 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
14 QC Association Summary...................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3570-2 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3570-2 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-3570-2 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 08/29/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.0 C.
RADIUM-226 BY GAMMA SPEC (21 DAY INGROWTH)
Samples L050101TUB00 (160-3570-1), L050105TUB00 (160-3570-2), L050107TUB00 (160-3570-3), L050109TUB00 (160-3570-4),
L050111TUB00 (160-3570-5), L050113TUB00 (160-3570-6), L050115TUB00 (160-3570-7) and L050117TUB00 (160-3570-8) were analyzed for Radium-226 by gamma spec (21 day ingrowth) in accordance with EPA GA_01_R. The samples were leached on 08/30/2013, prepared on 09/04/2013 and analyzed on 09/25/2013.
Batch 70612:
For gamma spectroscopy batch 70612, insufficient sample was provided for the following sample to fill a tuna can calibrated for Ra-226 analysis by gamma spectroscopy: L050101TUB00 (160-3570-1). Therefore the sample was placed into a 100 mL geometry. The use of a different geometry could potentially bias the results low due to the loss of radon into the headspace of the container.
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3570-2 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3570-2 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
No other difficulties were encountered during the Radium 226 analysis. All other quality control parameters were within the acceptance limits.
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Procedure HDP-PR-QA-006, Chain of Custody Page I ofl Hematite Decommissioning Project !Revision: 3 I
I Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed Coe to HDP.
Chain ofCutody ID No. I F-082913-01 Page 1/1 Laboratory Name:
Project Name:
Westinghouse Electric Company Contact Person:
Gerald Rood Phone Number:
314-810-3382 Sampler Name Scott Jenkins Sample ID L050101TUBOO L050105TUBOO L050107TUBOO L050109TUBOO L050111TUBOO L050113TUBOO L050115TUBOO L050 l l 7TUBOO Company Name:w..t:.L Received by:
Company Name:
Relinquished by:
Comoany Name:
Date Tune 8/23/2013 14:45 8/23/2013 13:40 8/23/2013 14:15 8/23/2013 13:05 8/22/2013 15:40
-8/22/2013 15:20 8/22/2013 15:02 8/22/2013 14:20
!!!10 l~~o Date/Time Date/Time Matrix s
s s
s s
s s
s Date/Time
~
TA-MO Laboratory Address:
13715 Rider Trail North
~--------------------4
- .s PhoneNo.
"' 8 314-298-8566
-:§ Laboratory Contact Person:
~ Joe Walker 1
Phone No.
708-870-8453 Turn Ar1tuJ1d Time Rush (7 days)
Remarks Cooler Temperature:
fl_'1 * ~ I ~
r flllllJICm I
I!) ;
- I ~
.. Cooler ID: Shipper and Number:
V _v,:,_ _
0829-04 Date/Time
!Comments: Please re-analyze samples after 21 day ingrowth i q,A period.
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Date/Time IC~mpany.Name:
I ~-c) '1 *I 1
~.G:"\\
(j:l,y Verified By:
c__=-
LlJ LI)
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Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-3570-2 Login Number: 3570 Question Answer Comment Creator: Daniels, Brian J List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
False Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Rad Qualifier Description U
Indicates the analyte was analyzed for but not detected.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol DOE GA-01-R Radium-226 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 15 1
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Sample Summary TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-3570-1 L050101TUB00 Solid 08/23/13 14:45 08/29/13 18:38 160-3570-2 L050105TUB00 Solid 08/23/13 13:40 08/29/13 18:38 160-3570-3 L050107TUB00 Solid 08/23/13 14:15 08/29/13 18:38 160-3570-4 L050109TUB00 Solid 08/23/13 13:05 08/29/13 18:38 160-3570-5 L050111TUB00 Solid 08/22/13 15:40 08/29/13 18:38 160-3570-6 L050113TUB00 Solid 08/22/13 15:20 08/29/13 18:38 160-3570-7 L050115TUB00 Solid 08/22/13 15:02 08/29/13 18:38 160-3570-8 L050117TUB00 Solid 08/22/13 14:20 08/29/13 18:38 TestAmerica St. Louis Page 9 of 15 1
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Client Sample Results TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-1 Client Sample ID: L050101TUB00 Matrix: Solid Date Collected: 08/23/13 14:45 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.159 U
(2+/-)
0.171 (2+/-)
1 09/25/13 03:50 09/04/13 14:28 pCi/g 0.358 RL MDC 0.171 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 03:50 1
1.07 0.591 0.591 U
-0.0842 Bismuth 212 pCi/g 09/04/13 14:28 09/25/13 03:50 1
0.197 0.240 0.212 1.08 Bismuth 214 pCi/g 09/04/13 14:28 09/25/13 03:50 1
0.146 0.104 0.102 0.147 Lead 212 pCi/g 09/04/13 14:28 09/25/13 03:50 1
0.198 0.231 0.196 1.17 Lead 214 pCi/g 09/04/13 14:28 09/25/13 03:50 1
1.39 0.772 0.767 U
0.885 Potassium 40 pCi/g 09/04/13 14:28 09/25/13 03:50 1
2.33 1.35 1.35 U
-0.436 Protactinium 231 pCi/g 09/04/13 14:28 09/25/13 03:50 1
0.197 1.00 0.240 0.212 1.08 Radium 226 pCi/g 09/04/13 14:28 09/25/13 03:50 1
0.358 0.171 0.171 U
0.159 Thorium 232 pCi/g 09/04/13 14:28 09/25/13 03:50 1
1.57 1.34 1.30 3.23 Thorium 234 pCi/g 09/04/13 14:28 09/25/13 03:50 1
0.406 0.363 0.353 0.829 Uranium 235 pCi/g 09/04/13 14:28 09/25/13 03:50 1
0.172 0.102 0.102 U
0.0429 Americium 241 pCi/g 09/04/13 14:28 09/25/13 03:50 1
11.5 6.43 6.43 U
1.72 Protactinium 234m Lab Sample ID: 160-3570-2 Client Sample ID: L050105TUB00 Matrix: Solid Date Collected: 08/23/13 13:40 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.204 (2+/-)
0.0840 (2+/-)
1 09/25/13 08:37 09/04/13 14:28 pCi/g 0.127 RL MDC 0.0814 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.391 0.232 0.231 U
0.143 Bismuth 212 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0445 0.115 0.0885 0.707 Bismuth 214 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0488 0.0512 0.0425 0.221 Lead 212 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0619 0.109 0.0779 0.732 Lead 214 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.308 1.08 0.823 6.85 Potassium 40 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.796 0.0669 0.0669 U
0.0189 Protactinium 231 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0445 1.00 0.115 0.0885 0.707 Radium 226 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.127 0.0840 0.0814 0.204 Thorium 232 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.665 0.339 0.310 1.31 Thorium 234 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.200 0.102 0.102 U
0.115 Uranium 235 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0692 0.0486 0.0486 U
-0.000848 Americium 241 pCi/g 09/04/13 14:28 09/25/13 08:37 1
5.09 3.24 3.23 U
2.05 Protactinium 234m Lab Sample ID: 160-3570-3 Client Sample ID: L050107TUB00 Matrix: Solid Date Collected: 08/23/13 14:15 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.136 (2+/-)
0.0595 (2+/-)
1 09/25/13 08:37 09/04/13 14:28 pCi/g 0.102 RL MDC 0.0578 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.359 0.196 0.195 U
0.0238 Bismuth 212 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0463 0.116 0.0868 0.745 Bismuth 214 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0412 0.0392 0.0340 0.151 Lead 212 TestAmerica St. Louis Page 10 of 15 1
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Client Sample Results TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-3 Client Sample ID: L050107TUB00 Matrix: Solid Date Collected: 08/23/13 14:15 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)
Analyte Lead 214 0.843 (2+/-)
0.119 (2+/-)
1 09/25/13 08:37 09/04/13 14:28 pCi/g 0.0591 RL MDC 0.0798 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.258 0.544 0.476 2.58 Potassium 40 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.714 0.420 0.419 U
-0.191 Protactinium 231 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0463 1.00 0.116 0.0868 0.745 Radium 226 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.102 0.0595 0.0578 0.136 Thorium 232 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.634 0.304 0.271 1.32 Thorium 234 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.175 0.138 0.134 0.334 Uranium 235 pCi/g 09/04/13 14:28 09/25/13 08:37 1
0.0745 0.0436 0.0436 U
-0.00119 Americium 241 pCi/g 09/04/13 14:28 09/25/13 08:37 1
4.33 2.25 2.21 U
3.75 Protactinium 234m Lab Sample ID: 160-3570-4 Client Sample ID: L050109TUB00 Matrix: Solid Date Collected: 08/23/13 13:05 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.221 (2+/-)
0.0501 (2+/-)
1 09/25/13 08:38 09/04/13 14:28 pCi/g 0.0237 RL MDC 0.0447 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.229 0.142 0.142 U
0.126 Bismuth 212 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.0364 0.122 0.0769 0.914 Bismuth 214 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.0419 0.0341 0.0304 0.120 Lead 212 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.0414 0.133 0.0774 1.04 Lead 214 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.170 0.402 0.339 2.11 Potassium 40 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.520 0.198 0.198 U
0.0572 Protactinium 231 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.0364 1.00 0.122 0.0769 0.914 Radium 226 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.0237 0.0501 0.0447 0.221 Thorium 232 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.644 0.615 0.563 2.37 Thorium 234 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.162 0.130 0.122 0.457 Uranium 235 pCi/g 09/04/13 14:28 09/25/13 08:38 1
0.0630 0.0370 0.0370 U
0.000275 Americium 241 pCi/g 09/04/13 14:28 09/25/13 08:38 1
3.19 2.36 2.34 3.57 Protactinium 234m Lab Sample ID: 160-3570-5 Client Sample ID: L050111TUB00 Matrix: Solid Date Collected: 08/22/13 15:40 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.264 (2+/-)
0.0596 (2+/-)
1 09/25/13 09:33 09/04/13 14:28 pCi/g 0.0590 RL MDC 0.0531 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.295 0.190 0.189 U
0.235 Bismuth 212 pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.0401 0.0977 0.0669 0.685 Bismuth 214 pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.0377 0.0404 0.0316 0.195 Lead 212 pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.0460 0.101 0.0609 0.779 Lead 214 pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.263 0.790 0.549 5.56 Potassium 40 pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.488 0.244 0.243 U
0.227 Protactinium 231 pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.0401 1.00 0.0977 0.0669 0.685 Radium 226 TestAmerica St. Louis Page 11 of 15 1
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Client Sample Results TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-5 Client Sample ID: L050111TUB00 Matrix: Solid Date Collected: 08/22/13 15:40 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 232 0.264 (2+/-)
0.0596 (2+/-)
1 09/25/13 09:33 09/04/13 14:28 pCi/g 0.0590 RL MDC 0.0531 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.531 0.466 0.433 1.64 Thorium 234 pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.116 0.106 0.101 0.318 Uranium 235 pCi/g 09/04/13 14:28 09/25/13 09:33 1
0.0649 0.0387 0.0387 U
0.0131 Americium 241 pCi/g 09/04/13 14:28 09/25/13 09:33 1
3.61 1.21 1.19 U
2.24 Protactinium 234m Lab Sample ID: 160-3570-6 Client Sample ID: L050113TUB00 Matrix: Solid Date Collected: 08/22/13 15:20 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.197 (2+/-)
0.0627 (2+/-)
1 09/25/13 09:34 09/04/13 14:28 pCi/g 0.0482 RL MDC 0.0594 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.242 0.159 0.158 U
0.209 Bismuth 212 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.0313 0.0980 0.0635 0.718 Bismuth 214 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.0392 0.0360 0.0300 0.154 Lead 212 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.0401 0.0988 0.0580 0.770 Lead 214 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.234 0.704 0.501 4.84 Potassium 40 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.605 0.154 0.153 U
0.146 Protactinium 231 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.0313 1.00 0.0980 0.0635 0.718 Radium 226 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.0482 0.0627 0.0594 0.197 Thorium 232 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.559 0.530 0.494 1.83 Thorium 234 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.167 0.0952 0.0915 0.256 Uranium 235 pCi/g 09/04/13 14:28 09/25/13 09:34 1
0.0473 0.0344 0.0342 U
0.0332 Americium 241 pCi/g 09/04/13 14:28 09/25/13 09:34 1
2.96 1.88 1.85 U
2.81 Protactinium 234m Lab Sample ID: 160-3570-7 Client Sample ID: L050115TUB00 Matrix: Solid Date Collected: 08/22/13 15:02 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.267 (2+/-)
0.0805 (2+/-)
1 09/25/13 09:35 09/04/13 14:28 pCi/g 0.0727 RL MDC 0.0758 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.303 0.187 0.187 U
0.165 Bismuth 212 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0482 0.138 0.0929 0.985 Bismuth 214 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0414 0.0507 0.0376 0.263 Lead 212 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0507 0.130 0.0712 1.05 Lead 214 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.203 0.752 0.564 4.87 Potassium 40 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.639 0.209 0.208 U
0.210 Protactinium 231 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0482 1.00 0.138 0.0929 0.985 Radium 226 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0727 0.0805 0.0758 0.267 Thorium 232 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.698 0.630 0.591 2.10 Thorium 234 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.195 0.164 0.148 0.684 Uranium 235 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0744 0.0443 0.0443 U
0.0167 Americium 241 TestAmerica St. Louis Page 12 of 15 1
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Client Sample Results TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-7 Client Sample ID: L050115TUB00 Matrix: Solid Date Collected: 08/22/13 15:02 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)
Analyte Protactinium 234m 1.98 U
(2+/-)
2.15 (2+/-)
1 09/25/13 09:35 09/04/13 14:28 pCi/g 3.76 RL MDC 2.14 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Lab Sample ID: 160-3570-8 Client Sample ID: L050117TUB00 Matrix: Solid Date Collected: 08/22/13 14:20 Date Received: 08/29/13 18:38 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.851 (2+/-)
0.154 (2+/-)
1 09/25/13 09:35 09/04/13 14:28 pCi/g 0.0406 RL MDC 0.127 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.302 0.389 0.368 1.21 Bismuth 212 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0831 0.132 0.107 0.752 Bismuth 214 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0594 0.119 0.0682 0.750 Lead 212 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0743 0.134 0.0924 0.938 Lead 214 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.279 1.78 1.12 13.5 Potassium 40 pCi/g 09/04/13 14:28 09/25/13 09:35 1
1.13 0.367 0.366 U
0.196 Protactinium 231 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0831 1.00 0.132 0.107 0.752 Radium 226 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.0406 0.154 0.127 0.851 Thorium 232 pCi/g 09/04/13 14:28 09/25/13 09:35 1
1.03 0.937 0.913 2.02 Thorium 234 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.191 0.169 0.163 0.433 Uranium 235 pCi/g 09/04/13 14:28 09/25/13 09:35 1
0.108 0.0638 0.0638 U
-0.000734 Americium 241 pCi/g 09/04/13 14:28 09/25/13 09:35 1
6.03 2.71 2.70 U
1.99 Protactinium 234m TestAmerica St. Louis Page 13 of 15 1
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QC Sample Results TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-70612/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 74703 Prep Batch: 70612 Actinium 228 Analyte U
1 09/25/13 03:49 09/04/13 14:28 pCi/g 0.0952 MDC RL 0.00987 0.00986 (2+/-)
(2+/-)
MB 0.004445 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.332 0.186 0.186 U
-0.06747 Bismuth 212 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.0291 0.0235 0.0234 U
0.02140 Bismuth 214 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.0280 0.0215 0.0215 U
-0.001932 Lead 212 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.0302 0.292 0.292 U
-0.007306 Lead 214 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.174 0.0473 0.0473 U
0.0000 Potassium 40 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.339 0.146 0.146 U
0.08279 Protactinium 231 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.0291 1.00 0.0235 0.0234 U
0.02140 Radium 226 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.0952 0.00987 0.00986 U
0.004445 Thorium 232 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.285 0.0573 0.0572 U
0.03776 Thorium 234 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.0677 0.0284 0.0284 U
0.01283 Uranium 235 1
09/25/13 03:49 09/04/13 14:28 pCi/g 0.0208 0.0117 0.0117 U
0.004500 Americium 241 1
09/25/13 03:49 09/04/13 14:28 pCi/g 1.56 0.811 0.809 U
0.5413 Protactinium 234m Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-70612/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 74707 Prep Batch: 70612 Americium 241 Analyte 116 87 95 92.60 97.7 9.63 0.458 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 31.6 30.41 3.18 0.131 pCi/g 96 87 - 120 Cobalt 60 24.5 22.88 2.31 0.0618 pCi/g 93 87 - 115 Client Sample ID: L050117TUB00 Lab Sample ID: 160-3570-8 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 74707 Prep Batch: 70612 Actinium 228 Analyte 1
0.21 0.7913 0.851 0.130 0.103 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Bismuth 212 1.21 1.043 0.334 0.289 pCi/g 0.23 1
Bismuth 214 0.752 0.8573 0.125 0.0571 pCi/g 0.41 1
Lead 212 0.750 0.7399 0.112 0.0487 pCi/g 0.05 1
Lead 214 0.938 0.8971 0.124 0.0540 pCi/g 0.16 1
Potassium 40 13.5 15.53 1.86 0.270 pCi/g 0.55 1
Protactinium 231 0.196 U
0.3272 U
0.226 0.963 pCi/g 0.22 1
Radium 226 0.752 0.8573 0.125 1.00 0.0571 pCi/g 0.41 1
Thorium 232 0.851 0.7913 0.130 0.103 pCi/g 0.21 1
Thorium 234 2.02 2.480 0.720 0.796 pCi/g 0.28 1
Uranium 235 0.433 0.4744 0.150 0.162 pCi/g 0.13 1
-0.00073 4
U
-0.00114 3
U 0.0607 0.102 pCi/g 0
1 Protactinium 234m 1.99 U
0.4194 U
1.11 5.08 pCi/g 0.41 1
TestAmerica St. Louis Page 14 of 15 1
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QC Association Summary TestAmerica Job ID: 160-3570-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Rad Leach Batch: 69978 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-3570-1 L050101TUB00 Total/NA Solid Dry and Grind 160-3570-2 L050105TUB00 Total/NA Solid Dry and Grind 160-3570-3 L050107TUB00 Total/NA Solid Dry and Grind 160-3570-4 L050109TUB00 Total/NA Solid Dry and Grind 160-3570-5 L050111TUB00 Total/NA Solid Dry and Grind 160-3570-6 L050113TUB00 Total/NA Solid Dry and Grind 160-3570-7 L050115TUB00 Total/NA Solid Dry and Grind 160-3570-8 L050117TUB00 Total/NA Solid Dry and Grind 160-3570-8 DU L050117TUB00 Total/NA Prep Batch: 70612 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-21 69978 160-3570-1 L050101TUB00 Total/NA Solid Fill_Geo-21 69978 160-3570-2 L050105TUB00 Total/NA Solid Fill_Geo-21 69978 160-3570-3 L050107TUB00 Total/NA Solid Fill_Geo-21 69978 160-3570-4 L050109TUB00 Total/NA Solid Fill_Geo-21 69978 160-3570-5 L050111TUB00 Total/NA Solid Fill_Geo-21 69978 160-3570-6 L050113TUB00 Total/NA Solid Fill_Geo-21 69978 160-3570-7 L050115TUB00 Total/NA Solid Fill_Geo-21 69978 160-3570-8 L050117TUB00 Total/NA Solid Fill_Geo-21 69978 160-3570-8 DU L050117TUB00 Total/NA Solid Fill_Geo-21 LCS 160-70612/2-A Lab Control Sample Total/NA Solid Fill_Geo-21 MB 160-70612/1-A Method Blank Total/NA TestAmerica St. Louis Page 15 of 15 1
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