ML18019A707
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ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-3530-1 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:
8/30/2013 4:25:39 PM Ivan Vania, Project Manager I ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-3530-1 Page 2 of 22 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
17 QC Association Summary...................................
20 Tracer Carrier Summary....................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3530-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3530-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-3530-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 08/26/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.0 C.
TECHNETIUM-99 (ICPMS)
Samples L050328PUI01 (160-3530-1), L050328PUI02 (160-3530-2), L050328PUI03 (160-3530-3), L050328PUI04 (160-3530-4),
L050328PUI05 (160-3530-5), L050328PUI06 (160-3530-6), L050328PUI07 (160-3530-7), L050341PUB00 (160-3530-8) and L050342PUB00 (160-3530-9) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 08/28/2013 and analyzed on 08/29/2013.
No difficulties were encountered during the Tc-99 analysis. All quality control parameters were within the acceptance limits.
PERCENT SOLIDS Samples L050328PUI01 (160-3530-1), L050328PUI02 (160-3530-2), L050328PUI03 (160-3530-3), L050328PUI04 (160-3530-4),
L050328PUI05 (160-3530-5), L050328PUI06 (160-3530-6), L050328PUI07 (160-3530-7), L050341PUB00 (160-3530-8) and TestAmerica St. Louis Page 3 of 22 1
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3530-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3530-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
L050342PUB00 (160-3530-9) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 08/28/2013.
No difficulties were encountered during the % solids analysis. All quality control parameters were within the acceptance limits.
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Samples L050328PUI01 (160-3530-1), L050328PUI02 (160-3530-2), L050328PUI03 (160-3530-3), L050328PUI04 (160-3530-4),
L050328PUI05 (160-3530-5), L050328PUI06 (160-3530-6), L050328PUI07 (160-3530-7), L050341PUB00 (160-3530-8) and L050342PUB00 (160-3530-9) were analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R. The samples were leached on 08/27/2013, and prepared and analyzed on 08/29/2013.
Preparation Batch 69554:
Radium-226 is reported in these samples at the clients request. Radium-226 is reported from the 609.31 keV line of Bismuth-214.
Because the samples have not had a 21-day ingrowth, the activity for Radium-226 is an estimated value and may be biased low. This bias is caused by the disruption of secular equilibrium between Radium-226 and Bismuth-214 by the loss of Radon-222 during sample preparation. (160-3530-9 DU), (LCS 160-69554/2-A), (MB 160-69554/1-A),
L050328PUI01 (160-3530-1), L050328PUI02 (160-3530-2), L050328PUI03 (160-3530-3), L050328PUI04 (160-3530-4), L050328PUI05 (160-3530-5), L050328PUI06 (160-3530-6), L050328PUI07 (160-3530-7), L050341PUB00 (160-3530-8), L050342PUB00 (160-3530-9)
The reporting limit for Thorium-234 was not met due to insufficient sample weight available for analysis. Analytical results are reported with the MDC achieved. (160-3530-9 DU), L050328PUI01 (160-3530-1), L050328PUI02 (160-3530-2), L050328PUI03 (160-3530-3),
L050328PUI04 (160-3530-4), L050328PUI05 (160-3530-5), L050328PUI06 (160-3530-6), L050328PUI07 (160-3530-7), L050341PUB00 (160-3530-8), L050342PUB00 (160-3530-9)
No other difficulties were encountered during the Gamma spec analysis. All other quality control parameters were within the acceptance limits.
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10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision: 3 I
Page I of J Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the conuriner is transferred to another organization, a person from each organization should sign the Coe. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.
Chain of Cutodv ID No.
F-082613-01 Pa2e 1/1 Reauested Analysis Laboratorv Name:
Project Name:
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Westinghouse Electric Company I *
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1 Contact Person:
- ljt, Laboratory Address:
Gerald Rood
'8 13715 Rider Trail North
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Phone Number:
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314-810-3382
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Laboratory Contact Person:
Scott Jenkins 8
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Joe Walker
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0 L050328PUI01 8/23/2013 10:30 s C.. x X x*
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L050328PUI02 8/23/2013 10:50 s
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L050328PUI03 8/23/2013 11:05 s
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I L050328PUI04 8/23/2013 14:10 s C x **.
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I L050328PUI05 8/23/2013 14:00 s C x..
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L050328PUI06 8/23/2013 14:40 s C ** x i X X 1
I L050328PUI07 8/23/2013 15:00 s C
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1 L050341 PUBOO 8/23/2013 15:30 s
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'11..1 V L050342PUBOO 8/23/2013 15:35 s
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Date/rime Total Cooler Temperature:
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q AmhiPcnt CompanyName: l.()C,(__..,
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Cooler ID: Shipper and Number:
c; OR?h-01 Received by:
Date/Time
~ill.9JEJ~"2.. j
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Date/Time Comments: Please re-analyze the samples after 21-day ingrowth
~ D period.
Company Name:
~ompan~~:c' _ ti -~\\3 Relinquished by:
Date/Time Received ~µ Date/Time 1..-A.
Verified By:
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Company Name:
Company Name:
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Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-3530-1 Login Number: 3530 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
False Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Rad Qualifier Description U
Indicates the analyte was analyzed for but not detected.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL DOE GA-01-R Cesium-137 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 22 1
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Sample Summary TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-3530-1 L050328PUI01 Solid 08/23/13 10:30 08/26/13 18:30 160-3530-2 L050328PUI02 Solid 08/23/13 10:50 08/26/13 18:30 160-3530-3 L050328PUI03 Solid 08/23/13 11:05 08/26/13 18:30 160-3530-4 L050328PUI04 Solid 08/23/13 14:10 08/26/13 18:30 160-3530-5 L050328PUI05 Solid 08/23/13 14:00 08/26/13 18:30 160-3530-6 L050328PUI06 Solid 08/23/13 14:40 08/26/13 18:30 160-3530-7 L050328PUI07 Solid 08/23/13 15:00 08/26/13 18:30 160-3530-8 L050341PUB00 Solid 08/23/13 15:30 08/26/13 18:30 160-3530-9 L050342PUB00 Solid 08/23/13 15:35 08/26/13 18:30 TestAmerica St. Louis Page 9 of 22 1
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Client Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3530-1 Client Sample ID: L050328PUI01 Matrix: Solid Date Collected: 08/23/13 10:30 Percent Solids: 82.2 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00067 0.000020 mg/Kg
08/28/13 13:17 08/29/13 15:29 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0403 U
(2+/-)
0.0378 (2+/-)
1 08/29/13 15:29 08/28/13 13:17 pCi/g 0.230 1.35 RL MDC
-0.0338 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 15:29 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 90 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.987 (2+/-)
0.175 (2+/-)
1 08/29/13 18:38 08/29/13 12:01 pCi/g 0.114 RL MDC 0.143 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.121 0.350 0.350 U
-0.0105 Americium 241 pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.468 0.519 0.501 1.28 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.0786 0.142 0.111 0.844 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.0703 0.180 0.0862 1.22 Lead 212 pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.0755 0.127 0.0957 0.802 Lead 214 pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.305 2.67 1.44 22.0 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 18:38 1
1.37 0.213 0.209 U
0.388 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.0786 1.00 0.142 0.111 0.844 Radium 226 pCi/g 08/29/13 12:01 08/29/13 18:38 1
1.12 1.00 1.03 0.961 3.48 Thorium 234 pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.233 0.210 0.200 0.639 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 18:38 1
6.23 2.35 2.32 U
3.05 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 18:38 1
0.114 0.175 0.143 0.987 Thorium 232 Tl-208 0.359 0.0540 0.0656 0.0405 pCi/g 08/29/13 12:01 08/29/13 18:38 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3530-2 Client Sample ID: L050328PUI02 Matrix: Solid Date Collected: 08/23/13 10:50 Percent Solids: 82.1 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00069 0.000021 mg/Kg
08/28/13 13:17 08/29/13 15:49 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.00916 U
(2+/-)
0.0432 (2+/-)
1 08/29/13 15:49 08/28/13 13:17 pCi/g 0.235 1.37 RL MDC
-0.0382 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 15:49 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 88 TestAmerica St. Louis Page 10 of 22 1
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Client Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3530-2 Client Sample ID: L050328PUI02 Matrix: Solid Date Collected: 08/23/13 10:50 Date Received: 08/26/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.19 (2+/-)
0.177 (2+/-)
1 08/29/13 18:39 08/29/13 12:01 pCi/g 0.124 RL MDC 0.135 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.110 0.397 0.397 U
-0.0485 Americium 241 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.444 0.550 0.529 1.55 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0674 0.124 0.0973 0.790 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0695 0.151 0.0830 1.17 Lead 212 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0772 0.140 0.102 0.993 Lead 214 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.298 2.75 1.43 24.3 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 18:39 1
1.18 0.311 0.307 U
0.458 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0674 1.00 0.124 0.0973 0.790 Radium 226 pCi/g 08/29/13 12:01 08/29/13 18:39 1
1.02 1.00 0.976 0.892 4.04 Thorium 234 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.215 0.213 0.198 0.811 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 18:39 1
5.81 3.67 3.65 U
4.01 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.124 0.177 0.135 1.19 Thorium 232 Tl-208 0.386 0.0529 0.0649 0.0391 pCi/g 08/29/13 12:01 08/29/13 18:39 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3530-3 Client Sample ID: L050328PUI03 Matrix: Solid Date Collected: 08/23/13 11:05 Percent Solids: 83.6 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00068 0.000021 mg/Kg
08/28/13 13:17 08/29/13 15:52 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0324 U
(2+/-)
0.0387 (2+/-)
1 08/29/13 15:52 08/28/13 13:17 pCi/g 0.235 1.37 RL MDC
-0.0335 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 15:52 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 87 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.08 (2+/-)
0.184 (2+/-)
1 08/29/13 18:39 08/29/13 12:01 pCi/g 0.144 RL MDC 0.148 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.149 0.0902 0.0900 U
0.0599 Americium 241 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.550 0.422 0.410 0.983 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0878 0.136 0.113 0.725 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0789 0.158 0.0863 1.02 Lead 212 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0795 0.125 0.0951 0.778 Lead 214 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.337 2.70 1.53 21.7 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 18:39 1
1.27 0.447 0.438 U
0.816 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0878 1.00 0.136 0.113 0.725 Radium 226 TestAmerica St. Louis Page 11 of 22 1
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Client Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3530-3 Client Sample ID: L050328PUI03 Matrix: Solid Date Collected: 08/23/13 11:05 Date Received: 08/26/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 234 8.02 (2+/-)
1.50 (2+/-)
1 08/29/13 18:39 08/29/13 12:01 pCi/g 1.31 1.00 RL MDC 1.24 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.312 0.336 0.284 1.76 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 18:39 1
6.87 4.60 4.54 6.98 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.144 0.184 0.148 1.08 Thorium 232 Tl-208 0.361 0.0623 0.0727 0.0477 pCi/g 08/29/13 12:01 08/29/13 18:39 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3530-4 Client Sample ID: L050328PUI04 Matrix: Solid Date Collected: 08/23/13 14:10 Percent Solids: 83.5 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00069 0.000021 mg/Kg
08/28/13 13:17 08/29/13 15:56 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0420 U
(2+/-)
0.0564 (2+/-)
1 08/29/13 15:56 08/28/13 13:17 pCi/g 0.238 1.39 RL MDC
-0.0484 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 15:56 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 86 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.12 (2+/-)
0.180 (2+/-)
1 08/29/13 18:39 08/29/13 12:01 pCi/g 0.108 RL MDC 0.140 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.115 0.0681 0.0681 U
0.000611 Americium 241 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.428 0.466 0.444 1.36 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0780 0.125 0.101 0.708 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0641 0.168 0.0780 1.15 Lead 212 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0695 0.116 0.0741 0.856 Lead 214 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.254 2.63 1.27 22.5 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 18:39 1
1.24 0.230 0.223 U
0.514 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.0780 1.00 0.125 0.101 0.708 Radium 226 pCi/g 08/29/13 12:01 08/29/13 18:39 1
1.21 1.00 1.34 1.11 7.15 Thorium 234 pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.223 0.244 0.213 1.17 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 18:39 1
5.07 3.63 3.56 7.21 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 18:39 1
0.108 0.180 0.140 1.12 Thorium 232 Tl-208 0.332 0.0461 0.0575 0.0351 pCi/g 08/29/13 12:01 08/29/13 18:39 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
TestAmerica St. Louis Page 12 of 22 1
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Client Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3530-5 Client Sample ID: L050328PUI05 Matrix: Solid Date Collected: 08/23/13 14:00 Percent Solids: 81.7 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00067 0.000020 mg/Kg
08/28/13 13:17 08/29/13 16:00 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0477 U
(2+/-)
0.0677 (2+/-)
1 08/29/13 16:00 08/28/13 13:17 pCi/g 0.230 1.35 RL MDC
-0.0611 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 16:00 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 91 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.17 (2+/-)
0.206 (2+/-)
1 08/29/13 20:12 08/29/13 12:01 pCi/g 0.190 RL MDC 0.168 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.141 0.0834 0.0833 U
-0.00731 Americium 241 pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.706 0.448 0.445 U
0.496 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.0969 0.164 0.137 0.862 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.0764 0.182 0.0956 1.20 Lead 212 pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.0825 0.152 0.115 0.949 Lead 214 pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.373 2.82 1.66 22.3 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 20:12 1
1.55 0.257 0.253 U
0.407 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.0969 1.00 0.164 0.137 0.862 Radium 226 pCi/g 08/29/13 12:01 08/29/13 20:12 1
1.15 1.00 1.07 0.975 4.16 Thorium 234 pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.236 0.194 0.177 0.769 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 20:12 1
7.88 4.71 4.70 U
3.07 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 20:12 1
0.190 0.206 0.168 1.17 Thorium 232 Tl-208 0.367 0.0684 0.0782 0.0527 pCi/g 08/29/13 12:01 08/29/13 20:12 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3530-6 Client Sample ID: L050328PUI06 Matrix: Solid Date Collected: 08/23/13 14:40 Percent Solids: 82.7 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00070 0.000021 mg/Kg
08/28/13 13:17 08/29/13 16:04 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0167 U
(2+/-)
0.0400 (2+/-)
1 08/29/13 16:04 08/28/13 13:17 pCi/g 0.238 1.39 RL MDC
-0.0345 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 16:04 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 86 TestAmerica St. Louis Page 13 of 22 1
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Client Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3530-6 Client Sample ID: L050328PUI06 Matrix: Solid Date Collected: 08/23/13 14:40 Date Received: 08/26/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.08 (2+/-)
0.157 (2+/-)
1 08/29/13 20:10 08/29/13 12:01 pCi/g 0.122 RL MDC 0.112 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.112 0.0672 0.0672 U
0.0268 Americium 241 pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.505 0.601 0.585 1.35 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.0787 0.136 0.106 0.815 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.0587 0.175 0.0770 1.21 Lead 212 pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.0696 0.128 0.0862 0.908 Lead 214 pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.305 2.46 1.21 21.0 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 20:10 1
1.16 0.234 0.228 U
0.483 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.0787 1.00 0.136 0.106 0.815 Radium 226 pCi/g 08/29/13 12:01 08/29/13 20:10 1
1.04 1.00 0.964 0.918 2.79 Thorium 234 pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.225 0.195 0.190 0.455 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 20:10 1
5.28 3.32 3.27 5.34 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 20:10 1
0.122 0.157 0.112 1.08 Thorium 232 Tl-208 0.387 0.0475 0.0622 0.0322 pCi/g 08/29/13 12:01 08/29/13 20:10 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3530-7 Client Sample ID: L050328PUI07 Matrix: Solid Date Collected: 08/23/13 15:00 Percent Solids: 82.7 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00069 0.000021 mg/Kg
08/28/13 13:17 08/29/13 16:08 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0219 U
(2+/-)
0.0812 (2+/-)
1 08/29/13 16:08 08/28/13 13:17 pCi/g 0.235 1.37 RL MDC
-0.0717 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 16:08 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 88 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.05 (2+/-)
0.188 (2+/-)
1 08/29/13 20:11 08/29/13 12:01 pCi/g 0.0998 RL MDC 0.154 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.188 0.114 0.114 U
-0.0899 Americium 241 pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.412 0.421 0.406 1.07 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.0733 0.119 0.0937 0.709 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.0884 0.142 0.0793 0.913 Lead 212 pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.0776 0.131 0.0971 0.852 Lead 214 pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.306 2.71 1.28 23.4 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 20:11 1
1.24 0.236 0.232 U
0.394 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.0733 1.00 0.119 0.0937 0.709 Radium 226 TestAmerica St. Louis Page 14 of 22 1
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Client Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3530-7 Client Sample ID: L050328PUI07 Matrix: Solid Date Collected: 08/23/13 15:00 Date Received: 08/26/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 234 19.4 (2+/-)
2.59 (2+/-)
1 08/29/13 20:11 08/29/13 12:01 pCi/g 1.59 1.00 RL MDC 1.61 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.337 0.381 0.265 2.69 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 20:11 1
3.30 6.09 5.30 29.7 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 20:11 1
0.0998 0.188 0.154 1.05 Thorium 232 Tl-208 0.355 0.0500 0.0621 0.0392 pCi/g 08/29/13 12:01 08/29/13 20:11 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3530-8 Client Sample ID: L050341PUB00 Matrix: Solid Date Collected: 08/23/13 15:30 Percent Solids: 85.4 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00078 0.000023 mg/Kg
08/28/13 13:17 08/29/13 16:12 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0388 U
(2+/-)
0.0900 (2+/-)
1 08/29/13 16:12 08/28/13 13:17 pCi/g 0.266 1.55 RL MDC 0.0681 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 16:12 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 76 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.25 (2+/-)
0.198 (2+/-)
1 08/29/13 23:57 08/29/13 12:01 pCi/g 0.0977 RL MDC 0.152 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.130 0.0791 0.0789 U
0.0614 Americium 241 pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.365 0.408 0.387 1.26 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.0621 0.113 0.0802 0.764 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.0494 0.155 0.0594 1.10 Lead 212 pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.0615 0.113 0.0755 0.813 Lead 214 pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.246 2.14 0.914 18.9 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.967 0.595 0.592 U
-0.599 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.0621 1.00 0.113 0.0802 0.764 Radium 226 pCi/g 08/29/13 12:01 08/29/13 23:57 1
1.20 1.00 3.98 1.30 36.0 Thorium 234 pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.217 0.274 0.205 1.78 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 23:57 1
3.40 6.26 4.91 38.4 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 23:57 1
0.0977 0.198 0.152 1.25 Thorium 232 Tl-208 0.342 0.0480 0.0598 0.0379 pCi/g 08/29/13 12:01 08/29/13 23:57 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
TestAmerica St. Louis Page 15 of 22 1
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Client Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3530-9 Client Sample ID: L050342PUB00 Matrix: Solid Date Collected: 08/23/13 15:35 Percent Solids: 84.7 Date Received: 08/26/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00075 0.000022 mg/Kg
08/28/13 13:17 08/29/13 16:16 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0716 U
(2+/-)
0.0554 (2+/-)
1 08/29/13 16:16 08/28/13 13:17 pCi/g 0.257 1.50 RL MDC
-0.0428 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/28/13 13:17 08/29/13 16:16 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 78 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.02 (2+/-)
0.174 (2+/-)
1 08/29/13 21:17 08/29/13 12:01 pCi/g 0.112 RL MDC 0.139 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.195 0.117 0.117 U
0.0126 Americium 241 pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.441 0.515 0.494 1.43 Bismuth 212 pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.0713 0.139 0.108 0.836 Bismuth 214 pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.0707 0.151 0.0818 0.980 Lead 212 pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.0855 0.129 0.104 0.737 Lead 214 pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.187 2.52 1.44 20.3 Potassium 40 pCi/g 08/29/13 12:01 08/29/13 21:17 1
1.02 0.461 0.442 1.17 Protactinium 231 pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.0713 1.00 0.139 0.108 0.836 Radium 226 pCi/g 08/29/13 12:01 08/29/13 21:17 1
1.69 1.00 2.52 1.67 18.0 Thorium 234 pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.431 0.577 0.352 4.50 Uranium 235 pCi/g 08/29/13 12:01 08/29/13 21:17 1
5.70 7.77 7.30 26.3 Protactinium 234m pCi/g 08/29/13 12:01 08/29/13 21:17 1
0.112 0.174 0.139 1.02 Thorium 232 Tl-208 0.313 0.0513 0.0607 0.0399 pCi/g 08/29/13 12:01 08/29/13 21:17 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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QC Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-69128/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 69867 Prep Batch: 69128 RL MDL Technetium 99 ND 0.00053 0.000016 mg/Kg 08/28/13 13:17 08/29/13 15:21 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-69128/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 69867 Prep Batch: 69128 Technetium 99 0.00260 0.00252 mg/Kg 97 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: L050328PUI01 Lab Sample ID: 160-3530-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 69867 Prep Batch: 69128 Technetium 99 ND 0.00308 0.00308 mg/Kg 100 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: L050328PUI01 Lab Sample ID: 160-3530-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 69867 Prep Batch: 69128 Technetium 99 ND 0.00320 0.00308 mg/Kg 96 75 - 125 0
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-69128/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 69868 Prep Batch: 69128 Technetium 99 Analyte U
1 08/29/13 15:21 08/28/13 13:17 pCi/g 0.180 MDC 1.05 RL 0.0598 0.0563 (2+/-)
(2+/-)
MB 0.08124 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 08/28/13 13:17 08/29/13 15:21 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 95 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-69128/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 69868 Prep Batch: 69128 Technetium 99 Analyte 120 80 97 43.20 44.5 4.49 1.11 0.190 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 90 LCS TestAmerica St. Louis Page 17 of 22 1
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QC Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: L050328PUI01 Lab Sample ID: 160-3530-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 69868 Prep Batch: 69128 Technetium 99 Analyte 125 75 100 52.67 52.7
-0.0403 U
5.31 1.32 0.226 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 92 MS Client Sample ID: L050328PUI01 Lab Sample ID: 160-3530-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 69868 Prep Batch: 69128 Technetium 99 Analyte 1
0 125 75 96 52.66 54.7
-0.0403 U
5.59 1.37 0.234 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 89 MSD Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-69554/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 69583 Prep Batch: 69554 Actinium 228 Analyte U
1 08/29/13 18:38 08/29/13 12:01 pCi/g 0.0446 MDC RL 0.0248 0.0248 (2+/-)
(2+/-)
MB 0.01444 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.0238 0.0133 0.0133 U
-0.001515 Americium 241 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.205 0.108 0.108 U
-0.005444 Bismuth 212 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.0369 0.0233 0.0233 U
-0.002905 Bismuth 214 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.0240 0.0119 0.0118 U
0.002391 Lead 212 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.0322 0.0242 0.0242 U
-0.003482 Lead 214 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.280 0.128 0.128 U
-0.009401 Potassium 40 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.394 0.0914 0.0914 U
0.02744 Protactinium 231 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.0369 1.00 0.0233 0.0233 U
-0.002905 Radium 226 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.245 1.00 0.153 0.152 U
0.09096 Thorium 234 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.0641 0.0359 0.0359 U
0.006568 Uranium 235 1
08/29/13 18:38 08/29/13 12:01 pCi/g 1.86 1.04 1.04 U
0.4895 Protactinium 234m 1
08/29/13 18:38 08/29/13 12:01 pCi/g 0.0446 0.0248 0.0248 U
0.01444 Thorium 232 Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 08/29/13 12:01 08/29/13 18:38 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected TestAmerica St. Louis Page 18 of 22 1
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QC Sample Results TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-69554/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 69584 Prep Batch: 69554 Americium 241 Analyte 116 87 93 90.84 97.7 9.45 0.483 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 31.6 29.85 3.12 0.200 0.141 pCi/g 94 87 - 120 Cobalt 60 24.8 23.24 2.35 0.104 pCi/g 94 87 - 115 Client Sample ID: L050342PUB00 Lab Sample ID: 160-3530-9 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 69590 Prep Batch: 69554 Actinium 228 Analyte 1
0.36 1.150 1.02 0.197 0.0915 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Americium 241 0.0126 U
0.05083 U
0.107 0.177 pCi/g 0.17 1
Bismuth 212 1.43 0.8832 0.449 0.627 pCi/g 0.56 1
Bismuth 214 0.836 0.9046 0.163 0.0905 pCi/g 0.23 1
Lead 212 0.980 0.9992 0.154 0.0714 pCi/g 0.06 1
Lead 214 0.737 0.8648 0.141 0.0987 pCi/g 0.48 1
Potassium 40 20.3 18.88 2.49 0.679 pCi/g 0.28 1
Protactinium 231 1.17 0.3256 U
0.539 0.902 pCi/g 0.85 1
Radium 226 0.836 0.9046 0.163 1.00 0.0905 pCi/g 0.23 1
Thorium 234 18.0 21.36 2.91 1.00 1.85 pCi/g 0.61 1
Uranium 235 4.50 4.616 0.586 0.368 pCi/g 0.1 1
Protactinium 234m 26.3 25.62 7.60 5.90 pCi/g 0.05 1
Thorium 232 1.02 1.150 0.197 0.0915 pCi/g 0.36 1
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QC Association Summary TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Metals Prep Batch: 69128 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3530-1 L050328PUI01 Total/NA Solid None 160-3530-1 MS L050328PUI01 Total/NA Solid None 160-3530-1 MSD L050328PUI01 Total/NA Solid None 160-3530-2 L050328PUI02 Total/NA Solid None 160-3530-3 L050328PUI03 Total/NA Solid None 160-3530-4 L050328PUI04 Total/NA Solid None 160-3530-5 L050328PUI05 Total/NA Solid None 160-3530-6 L050328PUI06 Total/NA Solid None 160-3530-7 L050328PUI07 Total/NA Solid None 160-3530-8 L050341PUB00 Total/NA Solid None 160-3530-9 L050342PUB00 Total/NA Solid None LCS 160-69128/2-A Lab Control Sample Total/NA Solid None MB 160-69128/1-A Method Blank Total/NA Analysis Batch: 69867 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 69128 160-3530-1 L050328PUI01 Total/NA Solid 6020A 69128 160-3530-1 MS L050328PUI01 Total/NA Solid 6020A 69128 160-3530-1 MSD L050328PUI01 Total/NA Solid 6020A 69128 160-3530-2 L050328PUI02 Total/NA Solid 6020A 69128 160-3530-3 L050328PUI03 Total/NA Solid 6020A 69128 160-3530-4 L050328PUI04 Total/NA Solid 6020A 69128 160-3530-5 L050328PUI05 Total/NA Solid 6020A 69128 160-3530-6 L050328PUI06 Total/NA Solid 6020A 69128 160-3530-7 L050328PUI07 Total/NA Solid 6020A 69128 160-3530-8 L050341PUB00 Total/NA Solid 6020A 69128 160-3530-9 L050342PUB00 Total/NA Solid 6020A 69128 LCS 160-69128/2-A Lab Control Sample Total/NA Solid 6020A 69128 MB 160-69128/1-A Method Blank Total/NA General Chemistry Analysis Batch: 68961 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-3530-1 L050328PUI01 Total/NA Solid Moisture 160-3530-2 L050328PUI02 Total/NA Solid Moisture 160-3530-3 L050328PUI03 Total/NA Solid Moisture 160-3530-4 L050328PUI04 Total/NA Solid Moisture 160-3530-5 L050328PUI05 Total/NA Solid Moisture 160-3530-6 L050328PUI06 Total/NA Solid Moisture 160-3530-7 L050328PUI07 Total/NA Solid Moisture 160-3530-8 L050341PUB00 Total/NA Solid Moisture 160-3530-9 L050342PUB00 Total/NA Solid Moisture 160-3530-9 DU L050342PUB00 Total/NA Rad Leach Batch: 68914 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-3530-1 L050328PUI01 Total/NA TestAmerica St. Louis Page 20 of 22 1
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QC Association Summary TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Rad (Continued)
Leach Batch: 68914 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-3530-2 L050328PUI02 Total/NA Solid Dry and Grind 160-3530-3 L050328PUI03 Total/NA Solid Dry and Grind 160-3530-4 L050328PUI04 Total/NA Solid Dry and Grind 160-3530-5 L050328PUI05 Total/NA Solid Dry and Grind 160-3530-6 L050328PUI06 Total/NA Solid Dry and Grind 160-3530-7 L050328PUI07 Total/NA Solid Dry and Grind 160-3530-8 L050341PUB00 Total/NA Solid Dry and Grind 160-3530-9 L050342PUB00 Total/NA Solid Dry and Grind 160-3530-9 DU L050342PUB00 Total/NA Prep Batch: 69128 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3530-1 L050328PUI01 Total/NA Solid None 160-3530-1 MS L050328PUI01 Total/NA Solid None 160-3530-1 MSD L050328PUI01 Total/NA Solid None 160-3530-2 L050328PUI02 Total/NA Solid None 160-3530-3 L050328PUI03 Total/NA Solid None 160-3530-4 L050328PUI04 Total/NA Solid None 160-3530-5 L050328PUI05 Total/NA Solid None 160-3530-6 L050328PUI06 Total/NA Solid None 160-3530-7 L050328PUI07 Total/NA Solid None 160-3530-8 L050341PUB00 Total/NA Solid None 160-3530-9 L050342PUB00 Total/NA Solid None LCS 160-69128/2-A Lab Control Sample Total/NA Solid None MB 160-69128/1-A Method Blank Total/NA Prep Batch: 69554 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 68914 160-3530-1 L050328PUI01 Total/NA Solid Fill_Geo-0 68914 160-3530-2 L050328PUI02 Total/NA Solid Fill_Geo-0 68914 160-3530-3 L050328PUI03 Total/NA Solid Fill_Geo-0 68914 160-3530-4 L050328PUI04 Total/NA Solid Fill_Geo-0 68914 160-3530-5 L050328PUI05 Total/NA Solid Fill_Geo-0 68914 160-3530-6 L050328PUI06 Total/NA Solid Fill_Geo-0 68914 160-3530-7 L050328PUI07 Total/NA Solid Fill_Geo-0 68914 160-3530-8 L050341PUB00 Total/NA Solid Fill_Geo-0 68914 160-3530-9 L050342PUB00 Total/NA Solid Fill_Geo-0 68914 160-3530-9 DU L050342PUB00 Total/NA Solid Fill_Geo-0 LCS 160-69554/2-A Lab Control Sample Total/NA Solid Fill_Geo-0 MB 160-69554/1-A Method Blank Total/NA TestAmerica St. Louis Page 21 of 22 1
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Tracer/Carrier Summary TestAmerica Job ID: 160-3530-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 90 160-3530-1 Percent Yield (Acceptance Limits)
L050328PUI01 92 160-3530-1 MS L050328PUI01 89 160-3530-1 MSD L050328PUI01 88 160-3530-2 L050328PUI02 87 160-3530-3 L050328PUI03 86 160-3530-4 L050328PUI04 91 160-3530-5 L050328PUI05 86 160-3530-6 L050328PUI06 88 160-3530-7 L050328PUI07 76 160-3530-8 L050341PUB00 78 160-3530-9 L050342PUB00 90 LCS 160-69128/2-A Lab Control Sample 95 MB 160-69128/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 22 of 22 1
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