ML18019A696
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ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-3458-1 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:
8/28/2013 5:26:24 PM Ivan Vania, Project Manager I ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-3458-1 Page 2 of 15 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
11 QC Association Summary...................................
14 Tracer Carrier Summary....................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3458-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3458-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-3458-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 08/21/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 5.4 C.
TECHNETIUM-99 (ICPMS)
Sample L050269PUB00 (160-3458-1) was analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 08/22/2013 and analyzed on 08/23/2013.
No difficulties were encountered during the Tc-99 analysis. All quality control parameters were within the acceptance limits.
PERCENT SOLIDS Sample L050269PUB00 (160-3458-1) was analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 08/22/2013.
No difficulties were encountered during the % solids analysis. All quality control parameters were within the acceptance limits.
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3458-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3458-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Sample L050269PUB00 (160-3458-1) was analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R.
The samples were leached on 08/22/2013, prepared on 08/23/2013 and analyzed on 08/28/2013.
Preparation Batch 68361:
Radium-226 is reported in these samples at the clients request. Radium-226 is reported from the 609.31 keV line of Bismuth-214.
Because the samples have not had a 21-day ingrowth, the activity for Radium-226 is an estimated value and may be biased low. This bias is caused by the disruption of secular equilibrium between Radium-226 and Bismuth-214 by the loss of Radon-222 during sample preparation. (160-3435-31 DU), (LCS 160-68361/2-A), (MB 160-68361/1-A), L050268PUB00 (160-3435-31), L050269PUB00 (160-3458-1)
Lead-214 analyzed by gamma spectroscopy was detected above the MDC in the method blank. Variations in Compton backgrounds and statistical analyses allow for small area counts in the ROIs of this nuclide. Other Uranium decay chain products are not present in the blank to support Lead-214 identification. The data is reported. (160-3435-31 DU), (LCS 160-68361/2-A), (MB 160-68361/1-A),
L050268PUB00 (160-3435-31), L050269PUB00 (160-3458-1)
The reporting limit for Thorium-234 was not met due to insufficient sample weight available for analysis. Analytical results are reported with the MDC achieved. L050269PUB00 (160-3458-1)
Radium-226 is reported in these samples at the clients request. Radium-226 is reported from the 609.31 keV line of Bismuth-214.
Because the samples have not had a 21-day ingrowth, the activity for Radium-226 is an estimated value and may be biased low. This bias is caused by the disruption of secular equilibrium between Radium-226 and Bismuth-214 by the loss of Radon-222 during sample preparation. (160-3435-31 DU), (LCS 160-68361/2-A), (MB 160-68361/1-A), L050268PUB00 (160-3435-31), L050269PUB00 (160-3458-1)
Lead-214 analyzed by gamma spectroscopy was detected above the MDC in the method blank. Variations in Compton backgrounds and statistical analyses allow for small area counts in the ROIs of this nuclide. Other Uranium decay chain products are not present in the blank to support Lead-214 identification. The data is reported. (160-3435-31 DU), (LCS 160-68361/2-A), (MB 160-68361/1-A),
L050268PUB00 (160-3435-31), L050269PUB00 (160-3458-1)
No other difficulties were encountered during the Gamma spec analysis. All other quality control parameters were within the acceptance limits.
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10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision* 3 I
Page I ofl Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP_
Chain of Cutodv ID No.
F-082113-01 Pa2:e 1/1 Reauested Analysis Laboratory Na.me:
Project Name:
_(':*
I i TA-MO
\\0 '<'
- -,,\\
N Westinghouse Electric Company I t-N ell Contact Person:
c.::
Laboratory Address:
Gerald Rood
..s 13715 Rider Trail North
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0
'.§ Phone Number:
.-.*- 6h Phone No.
314-810-3382
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" 314-298-8566 8
Sampler Name
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s Laboratory Contact Person:
Scott Jenkins 8
0 Joe Walker s It - i:
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Phone No.
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708-870-8453
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o:l Turn Around Time
- a ' a.. s Rush (7 days) l -~.- -: -* __
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Sample ID Date Time Matrix Q _--
Remarks c:,
"' _E,-<--
c:,
L050269PUB00 8/20/2013 14:40 s C
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L..SA. ()$"' O;l.
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Relinquished~
Date/Time
~;;e~_flQ~
Date/Time Total Cooler Temperature:
?3-;}.\\-1 ~
1 Amhi.-nt t'*~.-'~JD Company Name\\ 1 f'.y_ (..,...
/G,01
~mpanyN~~A Cooler ID: Shipper and Number:
('I_-
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.i; OR20-0l Received by:
Date/Time
~~edbY&?7,Q,
.~at\\/T~b[,
Comments: Please re-analyze sample after 21 day ingrowth
.A 7
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period.
Company Name:
, ~9mpanyNamr t><ll i,
'tcc:.S'COd.C! 5 Relinauished by:
Date/Time Recej,ved~~
Date/Time
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Verified By:
Company Name:
Company Name:
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Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-3458-1 Login Number: 3458 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
True Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Rad Qualifier Description U
Indicates the analyte was analyzed for but not detected.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL DOE GA-01-R Cesium-137 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 15 1
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Sample Summary TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-3458-1 L050269PUB00 Solid 08/20/13 14:40 08/21/13 18:48 TestAmerica St. Louis Page 9 of 15 1
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Client Sample Results TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3458-1 Client Sample ID: L050269PUB00 Matrix: Solid Date Collected: 08/20/13 14:40 Percent Solids: 66.0 Date Received: 08/21/13 18:48 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.00084 0.000025 mg/Kg
08/22/13 17:17 08/23/13 20:35 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0324 U
(2+/-)
0.0657 (2+/-)
1 08/23/13 20:35 08/22/13 17:17 pCi/g 0.289 1.69 RL MDC 0.0586 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/22/13 17:17 08/23/13 20:35 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 89 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.10 (2+/-)
0.206 (2+/-)
1 08/28/13 11:06 08/23/13 11:50 pCi/g 0.107 RL MDC 0.173 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.120 0.0710 0.0710 U
-0.00714 Americium 241 pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.510 0.402 0.384 1.13 Bismuth 212 pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.0928 0.160 0.124 0.980 Bismuth 214 pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.0642 0.183 0.0827 1.26 Lead 212 pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.0666 0.166 0.107 1.23 Lead 214 pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.335 2.44 1.25 20.5 Potassium 40 pCi/g 08/23/13 11:50 08/28/13 11:06 1
1.21 0.384 0.367 U
1.02 Protactinium 231 pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.0928 1.00 0.160 0.124 0.980 Radium 226 pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.888 1.00 0.345 0.332 0.907 Thorium 234 pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.253 0.0298 0.0297 U
0.0143 Uranium 235 pCi/g 08/23/13 11:50 08/28/13 11:06 1
5.66 3.28 3.27 U
1.14 Protactinium 234m pCi/g 08/23/13 11:50 08/28/13 11:06 1
0.107 0.206 0.173 1.10 Thorium 232 Tl-208 0.380 0.0534 0.0664 0.0419 pCi/g 08/23/13 11:50 08/28/13 11:06 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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QC Sample Results TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-67951/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 68435 Prep Batch: 67951 RL MDL Technetium 99 ND 0.00053 0.000016 mg/Kg 08/22/13 08:38 08/23/13 19:29 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-67951/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 68435 Prep Batch: 67951 Technetium 99 0.00247 0.00245 mg/Kg 99 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: Matrix Spike Lab Sample ID: 160-3435-A-21-D MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 68435 Prep Batch: 67951 Technetium 99 ND 0.00321 0.00304 mg/Kg 95 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-3435-A-21-E MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 68435 Prep Batch: 67951 Technetium 99 ND 0.00320 0.00298 mg/Kg 93 75 - 125 2
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-67951/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 68436 Prep Batch: 67951 Technetium 99 Analyte U
1 08/23/13 19:29 08/22/13 08:38 pCi/g 0.181 MDC 1.06 RL 0.0144 0.0131 (2+/-)
(2+/-)
MB 0.04180 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 08/22/13 08:38 08/23/13 19:29 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 94 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-67951/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 68436 Prep Batch: 67951 Technetium 99 Analyte 120 80 99 41.92 42.3 4.13 1.06 0.181 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 95 LCS TestAmerica St. Louis Page 11 of 15 1
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QC Sample Results TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: Matrix Spike Lab Sample ID: 160-3435-A-21-D MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 68436 Prep Batch: 67951 Technetium 99 Analyte 125 75 95 52.13 55.0 0.112 U
5.61 1.37 0.235 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 90 MS Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-3435-A-21-E MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 68436 Prep Batch: 67951 Technetium 99 Analyte 1
0.10 125 75 93 50.99 54.8 0.112 U
5.39 1.37 0.235 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 90 MSD Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-68361/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 68418 Prep Batch: 68361 Actinium 228 Analyte U
1 08/25/13 20:14 08/23/13 11:49 pCi/g 0.0662 MDC RL 0.00790 0.00789 (2+/-)
(2+/-)
MB 0.004165 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.0257 0.0147 0.0147 U
0.003463 Americium 241 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.158 0.0859 0.0858 U
0.02943 Bismuth 212 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.0401 0.0223 0.0223 U
-0.001347 Bismuth 214 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.0219 0.0131 0.0130 U
0.01034 Lead 212 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.0285 0.0171 0.0168 0.03187 Lead 214 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.315 0.158 0.158 U
-0.009079 Potassium 40 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.358 0.197 0.197 U
-0.02795 Protactinium 231 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.0401 1.00 0.0223 0.0223 U
-0.001347 Radium 226 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.278 1.00 0.144 0.144 U
0.03659 Thorium 234 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.0627 0.0348 0.0348 U
0.004433 Uranium 235 1
08/25/13 20:14 08/23/13 11:49 pCi/g 1.68 1.05 1.05 U
0.8453 Protactinium 234m 1
08/25/13 20:14 08/23/13 11:49 pCi/g 0.0662 0.00790 0.00789 U
0.004165 Thorium 232 Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 08/23/13 11:49 08/25/13 20:14 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected TestAmerica St. Louis Page 12 of 15 1
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QC Sample Results TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-68361/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 68419 Prep Batch: 68361 Americium 241 Analyte 116 87 97 94.58 97.7 9.84 0.491 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 31.7 31.34 3.28 0.200 0.129 pCi/g 99 87 - 120 Cobalt 60 24.8 24.45 2.47 0.109 pCi/g 99 87 - 115 Client Sample ID: Duplicate Lab Sample ID: 160-3435-A-31-E DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 68414 Prep Batch: 68361 Actinium 228 Analyte 1
0.89 0.3328 0.207 0.0729 0.0386 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Americium 241
-0.00170 U
-0.01717 U
0.0401 0.0671 pCi/g 0.19 1
Bismuth 212 0.130 U
0.3056 0.152 0.153 pCi/g 0.50 1
Bismuth 214 0.417 0.5197 0.0835 0.0401 pCi/g 0.62 1
Lead 212 0.269 0.3239 0.0557 0.0346 pCi/g 0.51 1
Lead 214 0.532 0.4982 0.0739 0.0395 pCi/g 0.22 1
Potassium 40 5.35 5.186 0.748 0.187 pCi/g 0.10 1
Protactinium 231
-0.0624 U
0.1583 U
0.121 0.560 pCi/g 0.44 1
Radium 226 0.417 0.5197 0.0835 1.00 0.0401 pCi/g 0.62 1
Thorium 234 0.690 1.292 0.501 1.00 0.576 pCi/g 0.80 1
Uranium 235 0.200 0.2728 0.0966 0.112 pCi/g 0.36 1
Protactinium 234m 1.99 U
0.9806 U
1.56 2.89 pCi/g 0.24 1
Thorium 232 0.207 0.3328 0.0729 0.0386 pCi/g 0.89 1
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QC Association Summary TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Metals Prep Batch: 67951 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3435-A-21-D MS Matrix Spike Total/NA Solid None 160-3435-A-21-E MSD Matrix Spike Duplicate Total/NA Solid None 160-3458-1 L050269PUB00 Total/NA Solid None LCS 160-67951/2-A Lab Control Sample Total/NA Solid None MB 160-67951/1-A Method Blank Total/NA Analysis Batch: 68435 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 67951 160-3435-A-21-D MS Matrix Spike Total/NA Solid 6020A 67951 160-3435-A-21-E MSD Matrix Spike Duplicate Total/NA Solid 6020A 67951 160-3458-1 L050269PUB00 Total/NA Solid 6020A 67951 LCS 160-67951/2-A Lab Control Sample Total/NA Solid 6020A 67951 MB 160-67951/1-A Method Blank Total/NA General Chemistry Analysis Batch: 67957 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-3448-D-1 DU Duplicate Total/NA Solid Moisture 160-3458-1 L050269PUB00 Total/NA Rad Leach Batch: 67776 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-3435-A-31-E DU Duplicate Total/NA Prep Batch: 67951 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3435-A-21-D MS Matrix Spike Total/NA Solid None 160-3435-A-21-E MSD Matrix Spike Duplicate Total/NA Solid None 160-3458-1 L050269PUB00 Total/NA Solid None LCS 160-67951/2-A Lab Control Sample Total/NA Solid None MB 160-67951/1-A Method Blank Total/NA Leach Batch: 67978 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-3458-1 L050269PUB00 Total/NA Prep Batch: 68361 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 67776 160-3435-A-31-E DU Duplicate Total/NA Solid Fill_Geo-0 67978 160-3458-1 L050269PUB00 Total/NA Solid Fill_Geo-0 LCS 160-68361/2-A Lab Control Sample Total/NA Solid Fill_Geo-0 MB 160-68361/1-A Method Blank Total/NA TestAmerica St. Louis Page 14 of 15 1
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Tracer/Carrier Summary TestAmerica Job ID: 160-3458-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 90 160-3435-A-21-D MS Percent Yield (Acceptance Limits)
Matrix Spike 90 160-3435-A-21-E MSD Matrix Spike Duplicate 89 160-3458-1 L050269PUB00 95 LCS 160-67951/2-A Lab Control Sample 94 MB 160-67951/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 15 of 15 1
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