ML18019A676
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ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-3570-1 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:
9/8/2013 9:55:09 AM Ivan Vania, Project Manager I ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-3570-1 Page 2 of 23 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
16 QC Association Summary...................................
20 Tracer Carrier Summary....................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3570-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3570-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-3570-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 08/29/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.0 C.
TECHNETIUM-99 (ICPMS)
Samples L050101TUB00 (160-3570-1), L050105TUB00 (160-3570-2), L050107TUB00 (160-3570-3), L050109TUB00 (160-3570-4),
L050111TUB00 (160-3570-5), L050113TUB00 (160-3570-6), L050115TUB00 (160-3570-7) and L050117TUB00 (160-3570-8) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 08/30/2013 and 09/04/2013 and analyzed on 09/03/2013 and 09/04/2013.
Preparation Batch 69983, Analytical Batches 70530 & 70531:
The following sample(s) was diluted to bring the concentration of target analytes within the calibration range: L050107TUB00 (160-3570-3). Elevated reporting limits (RLs) are provided.
The following sample(s) was diluted due to matrix interference indicated by internal standard failure in the undiluted sample:
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3570-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3570-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
L050109TUB00 (160-3570-4). Elevated reporting limits (RLs) are provided.
Preparation Batch 70525:
The associated sample was re-extracted due to a tracer miss-spike in the original batch L050113TUB00 (160-3570-6).
No difficulties were encountered during the Tc-99 analysis. All quality control parameters were within the acceptance limits.
PERCENT SOLIDS Samples L050101TUB00 (160-3570-1), L050105TUB00 (160-3570-2), L050107TUB00 (160-3570-3), L050109TUB00 (160-3570-4),
L050111TUB00 (160-3570-5), L050113TUB00 (160-3570-6), L050115TUB00 (160-3570-7) and L050117TUB00 (160-3570-8) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 09/03/2013.
No difficulties were encountered during the % solids analysis. All quality control parameters were within the acceptance limits.
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Samples L050101TUB00 (160-3570-1), L050105TUB00 (160-3570-2), L050107TUB00 (160-3570-3), L050109TUB00 (160-3570-4),
L050111TUB00 (160-3570-5), L050113TUB00 (160-3570-6), L050115TUB00 (160-3570-7) and L050117TUB00 (160-3570-8) were analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R. The samples were leached on 08/30/2013, and prepared and analyzed on 09/04/2013.
Preparation Batch 70600:
Radium-226 is reported in these samples at the clients request. Radium-226 is reported from the 609.31 keV line of Bismuth-214.
Because the samples have not had a 21-day ingrowth, the activity for Radium-226 is an estimated value and may be biased low. This bias is caused by the disruption of secular equilibrium between Radium-226 and Bismuth-214 by the loss of Radon-222 during sample preparation. (160-3570-8 DU), (LCS 160-70600/2-A), (MB 160-70600/1-A), L050101TUB00 (160-3570-1), L050105TUB00 (160-3570-2),
L050107TUB00 (160-3570-3), L050109TUB00 (160-3570-4), L050111TUB00 (160-3570-5), L050113TUB00 (160-3570-6),
L050115TUB00 (160-3570-7), L050117TUB00 (160-3570-8)
The reporting limit for thorium-234 was not met due to insufficient sample weight available for analysis. Analytical results are reported with the MDC achieved. L050101TUB00 (160-3570-1)
No other difficulties were encountered during the Gamma spec analysis. All other quality control parameters were within the acceptance limits.
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Procedure HDP-PR-QA-006, Chain of Custody Page I ofl Hematite Decommissioning Project !Revision: 3 I
I Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed Coe to HDP.
Chain ofCutody ID No. I F-082913-01 Page 1/1 Laboratory Name:
Project Name:
Westinghouse Electric Company Contact Person:
Gerald Rood Phone Number:
314-810-3382 Sampler Name Scott Jenkins Sample ID L050101TUBOO L050105TUBOO L050107TUBOO L050109TUBOO L050111TUBOO L050113TUBOO L050115TUBOO L050 l l 7TUBOO Company Name:w..t:.L Received by:
Company Name:
Relinquished by:
Comoany Name:
Date Tune 8/23/2013 14:45 8/23/2013 13:40 8/23/2013 14:15 8/23/2013 13:05 8/22/2013 15:40
-8/22/2013 15:20 8/22/2013 15:02 8/22/2013 14:20
!!!10 l~~o Date/Time Date/Time Matrix s
s s
s s
s s
s Date/Time
~
TA-MO Laboratory Address:
13715 Rider Trail North
~--------------------4
- .s PhoneNo.
"' 8 314-298-8566
-:§ Laboratory Contact Person:
~ Joe Walker 1
Phone No.
708-870-8453 Turn Ar1tuJ1d Time Rush (7 days)
Remarks Cooler Temperature:
fl_'1 * ~ I ~
r flllllJICm I
I!) ;
- I ~
.. Cooler ID: Shipper and Number:
V _v,:,_ _
0829-04 Date/Time
!Comments: Please re-analyze samples after 21 day ingrowth i q,A period.
~{
\\<&*'"'
Date/Time IC~mpany.Name:
I ~-c) '1 *I 1
~.G:"\\
(j:l,y Verified By:
c__=-
LlJ LI)
....J
()
Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-3570-1 Login Number: 3570 Question Answer Comment Creator: Daniels, Brian J List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
False Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Metals Qualifier Description J
Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier Rad Qualifier Description U
Indicates the analyte was analyzed for but not detected.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL DOE GA-01-R Cesium-137 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 23 1
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Sample Summary TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-3570-1 L050101TUB00 Solid 08/23/13 14:45 08/29/13 18:38 160-3570-2 L050105TUB00 Solid 08/23/13 13:40 08/29/13 18:38 160-3570-3 L050107TUB00 Solid 08/23/13 14:15 08/29/13 18:38 160-3570-4 L050109TUB00 Solid 08/23/13 13:05 08/29/13 18:38 160-3570-5 L050111TUB00 Solid 08/22/13 15:40 08/29/13 18:38 160-3570-6 L050113TUB00 Solid 08/22/13 15:20 08/29/13 18:38 160-3570-7 L050115TUB00 Solid 08/22/13 15:02 08/29/13 18:38 160-3570-8 L050117TUB00 Solid 08/22/13 14:20 08/29/13 18:38 TestAmerica St. Louis Page 9 of 23 1
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Client Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-1 Client Sample ID: L050101TUB00 Matrix: Solid Date Collected: 08/23/13 14:45 Percent Solids: 97.9 Date Received: 08/29/13 18:38 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 0.0030 0.00053 0.000016 mg/Kg
08/30/13 10:44 09/03/13 20:16 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 51.8 (2+/-)
5.24 (2+/-)
1 09/03/13 20:16 08/30/13 10:44 pCi/g 0.181 1.05 RL MDC 1.64 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/30/13 10:44 09/03/13 20:16 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 96 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.126 U
(2+/-)
0.163 (2+/-)
1 09/04/13 19:11 09/04/13 13:12 pCi/g 0.310 RL MDC 0.163 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 19:11 1
0.149 0.0862 0.0862 U
0.00783 Americium 241 pCi/g 09/04/13 13:12 09/04/13 19:11 1
1.06 0.622 0.621 U
0.321 Bismuth 212 pCi/g 09/04/13 13:12 09/04/13 19:11 1
0.183 0.214 0.188 0.976 Bismuth 214 pCi/g 09/04/13 13:12 09/04/13 19:11 1
0.138 0.104 0.0984 0.263 Lead 212 pCi/g 09/04/13 13:12 09/04/13 19:11 1
0.199 0.212 0.189 0.916 Lead 214 pCi/g 09/04/13 13:12 09/04/13 19:11 1
1.39 0.951 0.912 2.66 Potassium 40 pCi/g 09/04/13 13:12 09/04/13 19:11 1
1.70 0.946 0.946 U
0.0547 Protactinium 231 pCi/g 09/04/13 13:12 09/04/13 19:11 1
0.183 1.00 0.214 0.188 0.976 Radium 226 pCi/g 09/04/13 13:12 09/04/13 19:11 1
1.62 1.00 0.741 0.719 1.73 Thorium 234 pCi/g 09/04/13 13:12 09/04/13 19:11 1
0.360 0.217 0.215 U
0.334 Uranium 235 pCi/g 09/04/13 13:12 09/04/13 19:11 1
10.2 5.12 5.12 U
0.995 Protactinium 234m pCi/g 09/04/13 13:12 09/04/13 19:11 1
0.310 0.163 0.163 U
0.126 Thorium 232 Other Detected Radionuclide None pCi/g 09/04/13 13:12 09/04/13 19:11 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3570-2 Client Sample ID: L050105TUB00 Matrix: Solid Date Collected: 08/23/13 13:40 Percent Solids: 98.8 Date Received: 08/29/13 18:38 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 0.00020 J
0.00052 0.000016 mg/Kg
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Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 3.35 (2+/-)
0.348 (2+/-)
1 09/03/13 20:20 08/30/13 10:44 pCi/g 0.179 1.05 RL MDC 0.142 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/30/13 10:44 09/03/13 20:20 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 97 TestAmerica St. Louis Page 10 of 23 1
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Client Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-2 Client Sample ID: L050105TUB00 Matrix: Solid Date Collected: 08/23/13 13:40 Date Received: 08/29/13 18:38 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.183 (2+/-)
0.0621 (2+/-)
1 09/04/13 23:13 09/04/13 13:12 pCi/g 0.114 RL MDC 0.0592 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0734 0.0433 0.0433 U
0.00981 Americium 241 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.355 0.204 0.204 U
0.0869 Bismuth 212 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0579 0.0962 0.0775 0.548 Bismuth 214 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0443 0.0489 0.0393 0.225 Lead 212 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0570 0.0952 0.0698 0.623 Lead 214 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.394 1.02 0.749 6.75 Potassium 40 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.700 0.207 0.207 U
0.116 Protactinium 231 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0579 1.00 0.0962 0.0775 0.548 Radium 226 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.733 1.00 0.642 0.626 1.35 Thorium 234 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.165 0.109 0.109 U
0.118 Uranium 235 pCi/g 09/04/13 13:12 09/04/13 23:13 1
4.48 0.674 0.674 U
0.200 Protactinium 234m pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.114 0.0621 0.0592 0.183 Thorium 232 Tl-208 0.0770 0.0256 0.0268 0.0266 pCi/g 09/04/13 13:12 09/04/13 23:13 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3570-3 Client Sample ID: L050107TUB00 Matrix: Solid Date Collected: 08/23/13 14:15 Percent Solids: 94.4 Date Received: 08/29/13 18:38 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 0.011 0.0016 0.000049 mg/Kg
08/30/13 10:44 09/04/13 07:53 2
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 188 (2+/-)
29.3 (2+/-)
2 09/04/13 07:53 08/30/13 10:44 pCi/g 0.562 3.28 RL MDC 7.85 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/30/13 10:44 09/04/13 07:53 2
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 65 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.146 (2+/-)
0.0680 (2+/-)
1 09/04/13 23:12 09/04/13 13:12 pCi/g 0.0640 RL MDC 0.0663 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0716 0.0423 0.0423 U
0.00267 Americium 241 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.258 0.142 0.142 U
0.0127 Bismuth 212 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0382 0.0963 0.0672 0.664 Bismuth 214 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0414 0.0316 0.0289 0.0985 Lead 212 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0521 0.101 0.0609 0.775 Lead 214 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.208 0.516 0.408 3.08 Potassium 40 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.510 0.155 0.155 U
0.0845 Protactinium 231 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0382 1.00 0.0963 0.0672 0.664 Radium 226 TestAmerica St. Louis Page 11 of 23 1
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Client Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-3 Client Sample ID: L050107TUB00 Matrix: Solid Date Collected: 08/23/13 14:15 Date Received: 08/29/13 18:38 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 234 1.29 (2+/-)
0.312 (2+/-)
1 09/04/13 23:12 09/04/13 13:12 pCi/g 0.632 1.00 RL MDC 0.281 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.123 0.0894 0.0843 0.291 Uranium 235 pCi/g 09/04/13 13:12 09/04/13 23:12 1
2.83 1.82 1.82 U
0.911 Protactinium 234m pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0640 0.0680 0.0663 0.146 Thorium 232 Tl-208 0.0312 0.0154 0.0157 0.0227 pCi/g 09/04/13 13:12 09/04/13 23:12 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3570-4 Client Sample ID: L050109TUB00 Matrix: Solid Date Collected: 08/23/13 13:05 Percent Solids: 98.2 Date Received: 08/29/13 18:38 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 0.0015 0.0010 0.000031 mg/Kg
08/30/13 10:44 09/04/13 07:57 2
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 25.4 (2+/-)
2.52 (2+/-)
2 09/04/13 07:57 08/30/13 10:44 pCi/g 0.356 2.08 RL MDC 0.748 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/30/13 10:44 09/04/13 07:57 2
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 97 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.145 (2+/-)
0.0521 (2+/-)
1 09/04/13 23:12 09/04/13 13:12 pCi/g 0.0730 RL MDC 0.0499 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0643 0.0376 0.0376 U
0.00460 Americium 241 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.266 0.143 0.143 U
0.0140 Bismuth 212 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0436 0.115 0.0815 0.786 Bismuth 214 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0394 0.0329 0.0294 0.113 Lead 212 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0525 0.114 0.0697 0.867 Lead 214 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.290 0.472 0.423 2.05 Potassium 40 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.647 0.272 0.272 U
0.0938 Protactinium 231 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0436 1.00 0.115 0.0815 0.786 Radium 226 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.612 1.00 0.376 0.304 2.11 Thorium 234 pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.158 0.132 0.122 0.487 Uranium 235 pCi/g 09/04/13 13:12 09/04/13 23:12 1
3.21 2.02 2.01 U
1.65 Protactinium 234m pCi/g 09/04/13 13:12 09/04/13 23:12 1
0.0730 0.0521 0.0499 0.145 Thorium 232 Tl-208 0.0407 0.0152 0.0158 0.0177 pCi/g 09/04/13 13:12 09/04/13 23:12 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
TestAmerica St. Louis Page 12 of 23 1
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Client Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-5 Client Sample ID: L050111TUB00 Matrix: Solid Date Collected: 08/22/13 15:40 Percent Solids: 96.3 Date Received: 08/29/13 18:38 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 0.0015 0.00056 0.000017 mg/Kg
08/30/13 10:44 09/03/13 20:39 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 25.4 (2+/-)
2.52 (2+/-)
1 09/03/13 20:39 08/30/13 10:44 pCi/g 0.193 1.13 RL MDC 0.160 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/30/13 10:44 09/03/13 20:39 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 93 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.154 (2+/-)
0.0658 (2+/-)
1 09/04/13 23:13 09/04/13 13:12 pCi/g 0.113 RL MDC 0.0639 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0718 0.0425 0.0425 U
0.00994 Americium 241 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.353 0.205 0.205 U
0.100 Bismuth 212 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0372 0.106 0.0774 0.694 Bismuth 214 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0411 0.0441 0.0357 0.200 Lead 212 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0554 0.0942 0.0653 0.654 Lead 214 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.226 0.828 0.630 5.25 Potassium 40 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.767 0.119 0.119 U
0.0860 Protactinium 231 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0372 1.00 0.106 0.0774 0.694 Radium 226 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.633 1.00 0.352 0.326 1.27 Thorium 234 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.167 0.162 0.155 0.463 Uranium 235 pCi/g 09/04/13 13:12 09/04/13 23:13 1
4.08 2.47 2.47 U
1.83 Protactinium 234m pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.113 0.0658 0.0639 0.154 Thorium 232 Tl-208 0.0747 0.0290 0.0300 0.0276 pCi/g 09/04/13 13:12 09/04/13 23:13 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3570-6 Client Sample ID: L050113TUB00 Matrix: Solid Date Collected: 08/22/13 15:20 Percent Solids: 96.1 Date Received: 08/29/13 18:38 Method: 6020A - Metals (ICP/MS), Tc RE RL MDL Technetium 99 0.0015 0.000054 0.000016 mg/Kg
09/04/13 09:58 09/04/13 16:03 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity - RE Analyte Technetium 99 25.0 (2+/-)
2.44 (2+/-)
1 09/04/13 16:03 09/04/13 09:58 pCi/g 0.186 1.09 RL MDC 0.390 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/04/13 09:58 09/04/13 16:03 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 96 TestAmerica St. Louis Page 13 of 23 1
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Client Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-6 Client Sample ID: L050113TUB00 Matrix: Solid Date Collected: 08/22/13 15:20 Date Received: 08/29/13 18:38 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.163 (2+/-)
0.0555 (2+/-)
1 09/04/13 23:50 09/04/13 13:12 pCi/g 0.0761 RL MDC 0.0529 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.0669 0.0395 0.0395 U
0.00157 Americium 241 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.233 0.147 0.147 U
0.149 Bismuth 212 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.0358 0.0822 0.0591 0.550 Bismuth 214 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.0307 0.0355 0.0277 0.173 Lead 212 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.0499 0.0895 0.0559 0.673 Lead 214 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.261 0.670 0.494 4.42 Potassium 40 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.630 0.279 0.279 U
0.137 Protactinium 231 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.0358 1.00 0.0822 0.0591 0.550 Radium 226 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.533 1.00 0.313 0.265 1.58 Thorium 234 pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.106 0.0813 0.0767 0.265 Uranium 235 pCi/g 09/04/13 13:12 09/04/13 23:50 1
3.28 1.91 1.90 U
1.23 Protactinium 234m pCi/g 09/04/13 13:12 09/04/13 23:50 1
0.0761 0.0555 0.0529 0.163 Thorium 232 Tl-208 0.0685 0.0169 0.0183 0.0149 pCi/g 09/04/13 13:12 09/04/13 23:50 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3570-7 Client Sample ID: L050115TUB00 Matrix: Solid Date Collected: 08/22/13 15:02 Percent Solids: 95.5 Date Received: 08/29/13 18:38 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 0.0022 0.00054 0.000016 mg/Kg
08/30/13 10:44 09/03/13 20:47 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 38.3 (2+/-)
3.96 (2+/-)
1 09/03/13 20:47 08/30/13 10:44 pCi/g 0.186 1.08 RL MDC 1.43 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/30/13 10:44 09/03/13 20:47 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 96 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.185 (2+/-)
0.0644 (2+/-)
1 09/04/13 23:51 09/04/13 13:12 pCi/g 0.0809 RL MDC 0.0616 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.0716 0.0424 0.0424 U
-0.00337 Americium 241 pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.255 0.173 0.171 0.268 Bismuth 212 pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.0370 0.0955 0.0657 0.667 Bismuth 214 pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.0443 0.0430 0.0344 0.199 Lead 212 pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.0467 0.0976 0.0590 0.748 Lead 214 pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.185 0.639 0.457 4.37 Potassium 40 pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.672 0.127 0.126 U
0.101 Protactinium 231 pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.0370 1.00 0.0955 0.0657 0.667 Radium 226 TestAmerica St. Louis Page 14 of 23 1
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Client Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3570-7 Client Sample ID: L050115TUB00 Matrix: Solid Date Collected: 08/22/13 15:02 Date Received: 08/29/13 18:38 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 234 1.79 (2+/-)
0.365 (2+/-)
1 09/04/13 23:51 09/04/13 13:12 pCi/g 0.609 1.00 RL MDC 0.313 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.147 0.123 0.111 0.533 Uranium 235 pCi/g 09/04/13 13:12 09/04/13 23:51 1
2.89 2.14 2.11 3.79 Protactinium 234m pCi/g 09/04/13 13:12 09/04/13 23:51 1
0.0809 0.0644 0.0616 0.185 Thorium 232 Tl-208 0.0878 0.0220 0.0238 0.0200 pCi/g 09/04/13 13:12 09/04/13 23:51 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3570-8 Client Sample ID: L050117TUB00 Matrix: Solid Date Collected: 08/22/13 14:20 Percent Solids: 88.3 Date Received: 08/29/13 18:38 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 0.00049 J
0.00061 0.000018 mg/Kg
08/30/13 10:44 09/03/13 20:51 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 8.45 (2+/-)
0.892 (2+/-)
1 09/03/13 20:51 08/30/13 10:44 pCi/g 0.209 1.22 RL MDC 0.275 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 08/30/13 10:44 09/03/13 20:51 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 92 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.746 (2+/-)
0.131 (2+/-)
1 09/04/13 23:13 09/04/13 13:12 pCi/g 0.0884 RL MDC 0.107 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0845 0.0499 0.0499 U
0.00169 Americium 241 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.287 0.356 0.338 1.07 Bismuth 212 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0560 0.101 0.0772 0.632 Bismuth 214 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0538 0.109 0.0587 0.714 Lead 212 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0582 0.109 0.0773 0.746 Lead 214 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.335 1.78 0.983 14.5 Potassium 40 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.953 0.248 0.244 U
0.383 Protactinium 231 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0560 1.00 0.101 0.0772 0.632 Radium 226 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.769 1.00 0.661 0.626 2.02 Thorium 234 pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.194 0.133 0.127 0.403 Uranium 235 pCi/g 09/04/13 13:12 09/04/13 23:13 1
4.23 2.76 2.75 U
1.97 Protactinium 234m pCi/g 09/04/13 13:12 09/04/13 23:13 1
0.0884 0.131 0.107 0.746 Thorium 232 Tl-208 0.217 0.0354 0.0420 0.0278 pCi/g 09/04/13 13:12 09/04/13 23:13 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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QC Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-69983/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70530 Prep Batch: 69983 RL MDL Technetium 99 ND 0.00050 0.000015 mg/Kg 08/30/13 10:44 09/03/13 19:22 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-69983/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70530 Prep Batch: 69983 Technetium 99 0.00237 0.00248 mg/Kg 104 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: Matrix Spike Lab Sample ID: 160-3571-A-21-C MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 70530 Prep Batch: 69983 Technetium 99 0.000025 J
0.00316 0.00298 mg/Kg 93 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-3571-A-21-D MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 70530 Prep Batch: 69983 Technetium 99 0.000025 J
0.00311 0.00292 mg/Kg 93 75 - 125 2
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Client Sample ID: Method Blank Lab Sample ID: MB 160-70525/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70773 Prep Batch: 70525 RL MDL Technetium 99 ND 0.000051 0.000015 mg/Kg 09/04/13 07:26 09/04/13 13:26 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-70525/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70773 Prep Batch: 70525 Technetium 99 0.00236 0.00251 mg/Kg 106 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: Matrix Spike Lab Sample ID: 160-3600-A-1-B MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 70773 Prep Batch: 70525 Technetium 99 ND 0.00295 0.00286 mg/Kg 97 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-3600-A-1-C MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 70773 Prep Batch: 70525 Technetium 99 ND 0.00306 0.00286 mg/Kg 93 75 - 125 0
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD TestAmerica St. Louis Page 16 of 23 1
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QC Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-69983/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70531 Prep Batch: 69983 Technetium 99 Analyte U
1 09/03/13 19:22 08/30/13 10:44 pCi/g 0.170 MDC 0.991 RL 0.0456 0.0449 (2+/-)
(2+/-)
MB 0.1284 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 08/30/13 10:44 09/03/13 19:22 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 102 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-69983/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70531 Prep Batch: 69983 Technetium 99 Analyte 120 80 104 42.40 40.7 3.96 1.02 0.174 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 99 LCS Client Sample ID: Matrix Spike Lab Sample ID: 160-3571-A-21-C MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 70531 Prep Batch: 69983 Technetium 99 Analyte 125 75 93 50.98 54.1 0.435 5.57 1.35 0.231 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 90 MS Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-3571-A-21-D MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 70531 Prep Batch: 69983 Technetium 99 Analyte 1
0.09 125 75 93 49.98 53.3 0.435 5.13 1.33 0.228 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 90 MSD Client Sample ID: Method Blank Lab Sample ID: MB 160-70525/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70774 Prep Batch: 70525 Technetium 99 Analyte U
1 09/04/13 13:26 09/04/13 07:26 pCi/g 0.174 MDC 1.01 RL 0.0296 0.0290 (2+/-)
(2+/-)
MB 0.04320 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total TestAmerica St. Louis Page 17 of 23 1
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QC Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: Method Blank Lab Sample ID: MB 160-70525/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70774 Prep Batch: 70525 Carrier Re 30 - 110 09/04/13 07:26 09/04/13 13:26 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 99 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-70525/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70774 Prep Batch: 70525 Technetium 99 Analyte 120 80 106 42.90 40.3 3.99 1.01 0.173 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 99 LCS Client Sample ID: Matrix Spike Lab Sample ID: 160-3600-A-1-B MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 70774 Prep Batch: 70525 Technetium 99 Analyte 125 75 97 49.02 50.4 0.0647 U
5.31 1.26 0.216 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 91 MS Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-3600-A-1-C MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 70774 Prep Batch: 70525 Technetium 99 Analyte 1
0.01 125 75 93 48.96 52.5 0.0647 U
5.44 1.31 0.224 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 88 MSD Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-70600/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70572 Prep Batch: 70600 Actinium 228 Analyte U
1 09/04/13 21:58 09/04/13 13:12 pCi/g 0.0465 MDC RL 0.0191 0.0191 (2+/-)
(2+/-)
MB 0.008675 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.0189 0.0114 0.0114 U
0.008474 Americium 241 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.122 0.0575 0.0575 U
0.001267 Bismuth 212 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.0396 0.0879 0.0879 U
-0.01059 Bismuth 214 TestAmerica St. Louis Page 18 of 23 1
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QC Sample Results TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: Method Blank Lab Sample ID: MB 160-70600/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70572 Prep Batch: 70600 Lead 212 Analyte U
1 09/04/13 21:58 09/04/13 13:12 pCi/g 0.0188 MDC RL 0.00978 0.00975 (2+/-)
(2+/-)
MB 0.006140 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.0346 0.470 0.470 U
-0.01411 Lead 214 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.239 0.180 0.180 U
-0.03629 Potassium 40 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.299 0.159 0.159 U
-0.0007753 Protactinium 231 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.0396 1.00 0.0879 0.0879 U
-0.01059 Radium 226 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.224 1.00 0.107 0.107 U
0.01706 Thorium 234 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.0675 0.000412 0.000412 U
0.0001144 Uranium 235 1
09/04/13 21:58 09/04/13 13:12 pCi/g 2.00 0.923 0.923 U
0.1530 Protactinium 234m 1
09/04/13 21:58 09/04/13 13:12 pCi/g 0.0465 0.0191 0.0191 U
0.008675 Thorium 232 Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 09/04/13 13:12 09/04/13 21:58 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-70600/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 70581 Prep Batch: 70600 Americium 241 Analyte 116 87 95 92.66 97.7 9.64 0.473 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 31.6 30.45 3.19 0.200 0.151 pCi/g 96 87 - 120 Cobalt 60 24.7 23.85 2.41 0.0926 pCi/g 97 87 - 115 Client Sample ID: L050117TUB00 Lab Sample ID: 160-3570-8 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 70581 Prep Batch: 70600 Actinium 228 Analyte 1
0.07 0.7632 0.746 0.131 0.0839 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Americium 241 0.00169 U
-0.00281 7
U 0.133 0.0903 pCi/g 0.02 1
Bismuth 212 1.07 1.003 0.418 0.377 pCi/g 0.09 1
Bismuth 214 0.632 0.6603 0.114 0.0643 pCi/g 0.13 1
Lead 212 0.714 0.6978 0.109 0.0519 pCi/g 0.07 1
Lead 214 0.746 0.6657 0.0985 0.0592 pCi/g 0.39 1
Potassium 40 14.5 13.92 1.77 0.247 pCi/g 0.15 1
Protactinium 231 0.383 U
0.1268 U
0.117 1.06 pCi/g 0.70 1
Radium 226 0.632 0.6603 0.114 1.00 0.0643 pCi/g 0.13 1
Thorium 234 2.02 1.647 0.373 1.00 0.779 pCi/g 0.36 1
Uranium 235 0.403 0.4261 0.169 0.189 pCi/g 0.08 1
Protactinium 234m 1.97 U
3.462 U
2.95 4.55 pCi/g 0.26 1
Thorium 232 0.746 0.7632 0.131 0.0839 pCi/g 0.07 1
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QC Association Summary TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Metals Prep Batch: 69983 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3570-1 L050101TUB00 Total/NA Solid None 160-3570-2 L050105TUB00 Total/NA Solid None 160-3570-3 L050107TUB00 Total/NA Solid None 160-3570-4 L050109TUB00 Total/NA Solid None 160-3570-5 L050111TUB00 Total/NA Solid None 160-3570-7 L050115TUB00 Total/NA Solid None 160-3570-8 L050117TUB00 Total/NA Solid None 160-3571-A-21-C MS Matrix Spike Total/NA Solid None 160-3571-A-21-D MSD Matrix Spike Duplicate Total/NA Solid None LCS 160-69983/2-A Lab Control Sample Total/NA Solid None MB 160-69983/1-A Method Blank Total/NA Prep Batch: 70525 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3570 RE L050113TUB00 Total/NA Solid None 160-3600-A-1-B MS Matrix Spike Total/NA Solid None 160-3600-A-1-C MSD Matrix Spike Duplicate Total/NA Solid None LCS 160-70525/2-A Lab Control Sample Total/NA Solid None MB 160-70525/1-A Method Blank Total/NA Analysis Batch: 70530 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 69983 160-3570-1 L050101TUB00 Total/NA Solid 6020A 69983 160-3570-2 L050105TUB00 Total/NA Solid 6020A 69983 160-3570-3 L050107TUB00 Total/NA Solid 6020A 69983 160-3570-4 L050109TUB00 Total/NA Solid 6020A 69983 160-3570-5 L050111TUB00 Total/NA Solid 6020A 69983 160-3570-7 L050115TUB00 Total/NA Solid 6020A 69983 160-3570-8 L050117TUB00 Total/NA Solid 6020A 69983 160-3571-A-21-C MS Matrix Spike Total/NA Solid 6020A 69983 160-3571-A-21-D MSD Matrix Spike Duplicate Total/NA Solid 6020A 69983 LCS 160-69983/2-A Lab Control Sample Total/NA Solid 6020A 69983 MB 160-69983/1-A Method Blank Total/NA Analysis Batch: 70773 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 70525 160-3570 RE L050113TUB00 Total/NA Solid 6020A 70525 160-3600-A-1-B MS Matrix Spike Total/NA Solid 6020A 70525 160-3600-A-1-C MSD Matrix Spike Duplicate Total/NA Solid 6020A 70525 LCS 160-70525/2-A Lab Control Sample Total/NA Solid 6020A 70525 MB 160-70525/1-A Method Blank Total/NA General Chemistry Analysis Batch: 70086 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-3570-1 L050101TUB00 Total/NA Solid Moisture 160-3570-1 DU L050101TUB00 Total/NA Solid Moisture 160-3570-2 L050105TUB00 Total/NA Solid Moisture 160-3570-3 L050107TUB00 Total/NA TestAmerica St. Louis Page 20 of 23 1
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QC Association Summary TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
General Chemistry (Continued)
Analysis Batch: 70086 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-3570-4 L050109TUB00 Total/NA Solid Moisture 160-3570-5 L050111TUB00 Total/NA Solid Moisture 160-3570-6 L050113TUB00 Total/NA Solid Moisture 160-3570-7 L050115TUB00 Total/NA Solid Moisture 160-3570-8 L050117TUB00 Total/NA Rad Leach Batch: 69978 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-3570-1 L050101TUB00 Total/NA Solid Dry and Grind 160-3570-2 L050105TUB00 Total/NA Solid Dry and Grind 160-3570-3 L050107TUB00 Total/NA Solid Dry and Grind 160-3570-4 L050109TUB00 Total/NA Solid Dry and Grind 160-3570-5 L050111TUB00 Total/NA Solid Dry and Grind 160-3570-6 L050113TUB00 Total/NA Solid Dry and Grind 160-3570-7 L050115TUB00 Total/NA Solid Dry and Grind 160-3570-8 L050117TUB00 Total/NA Solid Dry and Grind 160-3570-8 DU L050117TUB00 Total/NA Prep Batch: 69983 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3570-1 L050101TUB00 Total/NA Solid None 160-3570-2 L050105TUB00 Total/NA Solid None 160-3570-3 L050107TUB00 Total/NA Solid None 160-3570-4 L050109TUB00 Total/NA Solid None 160-3570-5 L050111TUB00 Total/NA Solid None 160-3570-7 L050115TUB00 Total/NA Solid None 160-3570-8 L050117TUB00 Total/NA Solid None 160-3571-A-21-C MS Matrix Spike Total/NA Solid None 160-3571-A-21-D MSD Matrix Spike Duplicate Total/NA Solid None LCS 160-69983/2-A Lab Control Sample Total/NA Solid None MB 160-69983/1-A Method Blank Total/NA Prep Batch: 70525 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3570 RE L050113TUB00 Total/NA Solid None 160-3600-A-1-B MS Matrix Spike Total/NA Solid None 160-3600-A-1-C MSD Matrix Spike Duplicate Total/NA Solid None LCS 160-70525/2-A Lab Control Sample Total/NA Solid None MB 160-70525/1-A Method Blank Total/NA Prep Batch: 70600 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 69978 160-3570-1 L050101TUB00 Total/NA Solid Fill_Geo-0 69978 160-3570-2 L050105TUB00 Total/NA Solid Fill_Geo-0 69978 160-3570-3 L050107TUB00 Total/NA Solid Fill_Geo-0 69978 160-3570-4 L050109TUB00 Total/NA Solid Fill_Geo-0 69978 160-3570-5 L050111TUB00 Total/NA Solid Fill_Geo-0 69978 160-3570-6 L050113TUB00 Total/NA TestAmerica St. Louis Page 21 of 23 1
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QC Association Summary TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Rad (Continued)
Prep Batch: 70600 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 69978 160-3570-7 L050115TUB00 Total/NA Solid Fill_Geo-0 69978 160-3570-8 L050117TUB00 Total/NA Solid Fill_Geo-0 69978 160-3570-8 DU L050117TUB00 Total/NA Solid Fill_Geo-0 LCS 160-70600/2-A Lab Control Sample Total/NA Solid Fill_Geo-0 MB 160-70600/1-A Method Blank Total/NA TestAmerica St. Louis Page 22 of 23 1
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Tracer/Carrier Summary TestAmerica Job ID: 160-3570-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 96 160-3570-1 Percent Yield (Acceptance Limits)
L050101TUB00 97 160-3570-2 L050105TUB00 65 160-3570-3 L050107TUB00 97 160-3570-4 L050109TUB00 93 160-3570-5 L050111TUB00 96 160-3570 RE L050113TUB00 96 160-3570-7 L050115TUB00 92 160-3570-8 L050117TUB00 90 160-3571-A-21-C MS Matrix Spike 90 160-3571-A-21-D MSD Matrix Spike Duplicate 91 160-3600-A-1-B MS Matrix Spike 88 160-3600-A-1-C MSD Matrix Spike Duplicate 99 LCS 160-69983/2-A Lab Control Sample 99 LCS 160-70525/2-A Lab Control Sample 102 MB 160-69983/1-A Method Blank 99 MB 160-70525/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 23 of 23 1
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