ML18019A722
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-16777-1 Client Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Mr. Martin Swanson Authorized for release by:
4/11/2016 11:50:58 AM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
1 2
3 4
5 6
7 8
9 10 11 12
Table of Contents Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-16777-1 Page 2 of 19 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
14 QC Association Summary...................................
17 Tracer Carrier Summary....................................
19 1
2 3
4 5
6 7
8 9
10 11 12
Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-16777-1 Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Job ID: 160-16777-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: HDP RFP-CBA-022 (7 DAY TAT)
Report Number: 160-16777-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 4/4/2016 11:00 AM; the samples arrived in good condition, properly preserved and, where required, on ice.
The temperature of the cooler at receipt was 20.0º C.
TECHNETIUM-99 (ICPMS)
Samples L05-04-23-T-R-B-00 (160-16777-1), L05-04-24-T-S-B-00 (160-16777-2), L05-04-25-T-S-B-00 (160-16777-3) and L05-04-26-T-S-B-00 (160-16777-4) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 04/05/2016 and analyzed on 04/07/2016.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
PERCENT SOLIDS Samples L05-04-23-T-R-B-00 (160-16777-1), L05-04-24-T-S-B-00 (160-16777-2), L05-04-25-T-S-B-00 (160-16777-3) and L05-04-26-T-S-B-00 (160-16777-4) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 04/05/2016.
TestAmerica St. Louis Page 3 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-16777-1 Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Job ID: 160-16777-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Samples L05-04-23-T-R-B-00 (160-16777-1), L05-04-24-T-S-B-00 (160-16777-2), L05-04-25-T-S-B-00 (160-16777-3) and L05-04-26-T-S-B-00 (160-16777-4) were analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R. The samples were leached on 04/04/2016, prepared on 04/06/2016 and analyzed on 04/07/2016.
Preparation Batch 160-244600:
Radium-226 is reported in these samples at the client's request. Radium-226 is reported from the 609.31 keV line of bismuth-214.
Because the samples have not had 21-days of ingrowth, the activity for radium-226 is an estimated value and may be biased low. This bias is caused by the disruption of secular equilibrium between radium-226 and bismuth-214 by the loss of radon-222 during sample preparation. The samples are reported with the MDC achieved. L05-04-23-T-R-B-00 (160-16777-1), L05-04-24-T-S-B-00 (160-16777-2),
L05-04-25-T-S-B-00 (160-16777-3), L05-04-26-T-S-B-00 (160-16777-4), (LCS 160-244600/2-A), (MB 160-244600/1-A) and (160-16777-A-1-G DU)
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
TestAmerica St. Louis Page 4 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Page 5 of 19 1
2 3
4 5
6 7
8 9
10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision: 4 I
Page 1 ofl Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the C::::oC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed Coe lo HDP.
Chain of Cutodv ID No.
F-040216-01 Pa2e 1/l
.-** R~m'lested:.A:nal'~sk Laboratorv Name:
Project Name:
i'f c.'\\ ;\\
"'C-j.
TA-MO
.. G' Westinghouse Electric Company N
l"c.
N
- ~
(
'.:-: ' b Contact Person:
..... \\
/'. '
Laboratory Address:
Clark Evers J:l
('
13715 Rider Trail North
~r,;11
~
I r'{r1 i'.? "
2
=
Phone Number:
oJl C *..
".§ Phone No.
.5
~
. =
314-810-3336 0
314-298-8566 u
Sampler Name,.-
.r~
~
"' Laboratory Contact Person:
t.*
-0 I{. '
0 Donte Love 8
6 l -
b Ivan Vania
.D
- s
~
- i. '
- Phone No.
~ t*:,.: -~
u I\\
- 0)
- i 708-870-8453 5
- i
- 0..
r, *.
00 r:n '
!<i \\ it Turn Around Time Q
u
. ro
- ),.* 1
- a 6 :
Rush (7 days)
- 0. :<!!
0
- ~
~)**-
Sample ID Date Time Matrix =
0 0
~
0 C
~:,
- \\.' *;,
Remarks u
L05-04-23-T-R-B-OO 4/2/2016 9:15 s
G ext,, 'X'. X
\\
I LSA 05-04 Sidewall Bias L05-04-24-T-S-B-OO 4/2/2016 8:55 s
G,-xit \\ /:X:
X l LSA 05-04 Bias L05-04-25-T-S-B-OO 4/2/2016 9:00 s
G \\~ ;:;.-11._!f *x. X i
\\
1 LSA 05-04 Bias LOS-04-26-T-S-B-OO 4/2/2016 9:10 s
G tIX'\\ L :x X..
\\
1 LSA 05-04 Bias i(
,~.-
~
1:.-,.,.:_.\\;
,.*.;)'
~
11111111 111111111 r---.
LJi li"
~ >c
~~ t--
~
r--
r Ir--
1:
-i-160-167771Chain of Custo_dy
...,,~
- .*,,
- -c~,
I i
Relinquished by: -:7 Date/fime Rt~ti~1 3 o Ir*
Date/fime Total Cooler Temperature:
µ, -~0'..'£-vSvt- -
tf-4' J(,p
"' ~ 'i, - (J.
4 Ambient Company Name:
OC,oD
~~1R'f~A,'=- i O Cf o.t, Cooler ID: Shipper and Number:
W6-C..
0401-02 Received by:
Date/fime Relinquished by:
Date/Ti.me Comments: NIA Company Name:
Company Name:
1'~~~ iedb~ t l ~
Date/fime,,..- ~eceiv~{ ULA* (),I~
v,rifo!By /h.-,Y,r.+-/~
w.. - ~ - l-jo o_ --
Com~ IN~: 7$"'
~..
~
'~~
Name:,
C. *
- S S 0 11
(/ *
\\ 'I I,l """"I 11 A l.(-3~/b
Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-16777-1 Login Number: 16777 Question Answer Comment Creator: Dedner, Connie L List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
N/A Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time (excluding tests with immediate HTs)
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
TestAmerica St. Louis Page 6 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Definitions/Glossary TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Qualifiers Rad Qualifier Description U
Result is less than the sample detection limit.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CFL Contains Free Liquid CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica St. Louis Page 7 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Method Summary TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL DOE GA-01-R Cesium-137 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Sample Summary TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-16777-1 L05-04-23-T-R-B-00 Solid 04/02/16 09:15 04/04/16 11:00 160-16777-2 L05-04-24-T-S-B-00 Solid 04/02/16 08:55 04/04/16 11:00 160-16777-3 L05-04-25-T-S-B-00 Solid 04/02/16 09:00 04/04/16 11:00 160-16777-4 L05-04-26-T-S-B-00 Solid 04/02/16 09:10 04/04/16 11:00 TestAmerica St. Louis Page 9 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Client Sample Results TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-16777-1 Client Sample ID: L05-04-23-T-R-B-00 Matrix: Solid Date Collected: 04/02/16 09:15 Date Received: 04/04/16 11:00 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.11 (2+/-)
0.164 (2+/-)
1 04/07/16 17:15 04/06/16 10:38 pCi/g 0.109 RL MDC 0.119 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.106 0.0643 0.0642 U
-0.0381 Americium 241 pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.264 0.328 0.302 1.23 Bismuth 212 pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.0709 0.133 0.0979 0.861 Bismuth 214 pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.0639 0.154 0.0742 1.04 Lead 212 pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.0657 0.130 0.0859 0.939 Lead 214 pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.353 2.30 1.09 19.7 Potassium 40 pCi/g 04/06/16 10:38 04/07/16 17:15 1
1.07 0.175 0.171 U
0.303 Protactinium 231 pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.0709 1.00 0.133 0.0979 0.861 Radium 226 pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.792 1.00 0.525 0.506 1.36 Thorium 234 pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.238 0.139 0.139 U
0.108 Uranium 235 pCi/g 04/06/16 10:38 04/07/16 17:15 1
4.77 2.68 2.68 U
0.243 Protactinium 234m pCi/g 04/06/16 10:38 04/07/16 17:15 1
0.109 0.164 0.119 1.11 Thorium 232 Tl-208 0.367 0.0427 0.0572 0.0293 pCi/g 04/06/16 10:38 04/07/16 17:15 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-16777-1 Client Sample ID: L05-04-23-T-R-B-00 Matrix: Solid Date Collected: 04/02/16 09:15 Percent Solids: 80.4 Date Received: 04/04/16 11:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000068 0.000020 mg/Kg
04/05/16 02:58 04/07/16 09:43 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0952 U (2+/-)
0.0752 (2+/-)
1 04/07/16 09:43 04/05/16 02:58 pCi/g 0.232 1.36 RL MDC 0.0747 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 04/05/16 02:58 04/07/16 09:43 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 92 Lab Sample ID: 160-16777-2 Client Sample ID: L05-04-24-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 08:55 Date Received: 04/04/16 11:00 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.13 (2+/-)
0.172 (2+/-)
1 04/07/16 17:16 04/06/16 10:38 pCi/g 0.136 RL MDC 0.127 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.0740 0.0443 0.0443 U
0.0201 Americium 241 pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.468 0.535 0.515 1.40 Bismuth 212 pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.0687 0.127 0.0979 0.774 Bismuth 214 pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.0682 0.152 0.0793 1.00 Lead 212 TestAmerica St. Louis Page 10 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Client Sample Results TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-16777-2 Client Sample ID: L05-04-24-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 08:55 Date Received: 04/04/16 11:00 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Lead 214 0.827 (2+/-)
0.122 (2+/-)
1 04/07/16 17:16 04/06/16 10:38 pCi/g 0.0600 RL MDC 0.0864 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.232 2.20 1.16 18.3 Potassium 40 pCi/g 04/06/16 10:38 04/07/16 17:16 1
1.04 0.283 0.280 U
0.417 Protactinium 231 pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.0687 1.00 0.127 0.0979 0.774 Radium 226 pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.745 1.00 0.275 0.262 0.828 Thorium 234 pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.215 0.124 0.124 U
0.0588 Uranium 235 pCi/g 04/06/16 10:38 04/07/16 17:16 1
5.59 3.31 3.30 U
1.78 Protactinium 234m pCi/g 04/06/16 10:38 04/07/16 17:16 1
0.136 0.172 0.127 1.13 Thorium 232 Tl-208 0.382 0.0504 0.0642 0.0356 pCi/g 04/06/16 10:38 04/07/16 17:16 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-16777-2 Client Sample ID: L05-04-24-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 08:55 Percent Solids: 81.4 Date Received: 04/04/16 11:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000068 0.000020 mg/Kg
04/05/16 02:58 04/07/16 09:56 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.110 U (2+/-)
0.107 (2+/-)
1 04/07/16 09:56 04/05/16 02:58 pCi/g 0.233 1.36 RL MDC 0.107 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 04/05/16 02:58 04/07/16 09:56 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 90 Lab Sample ID: 160-16777-3 Client Sample ID: L05-04-25-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 09:00 Date Received: 04/04/16 11:00 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.08 (2+/-)
0.161 (2+/-)
1 04/07/16 17:17 04/06/16 10:38 pCi/g 0.0961 RL MDC 0.118 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.0825 0.0486 0.0486 U
0.000549 Americium 241 pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.342 0.399 0.374 1.32 Bismuth 212 pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.0704 0.112 0.0876 0.674 Bismuth 214 pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.0627 0.153 0.0770 1.02 Lead 212 pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.0625 0.121 0.0831 0.845 Lead 214 pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.362 2.29 1.15 19.3 Potassium 40 pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.974 0.254 0.249 U
0.448 Protactinium 231 pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.0704 1.00 0.112 0.0876 0.674 Radium 226 pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.816 1.00 0.517 0.507 0.984 Thorium 234 TestAmerica St. Louis Page 11 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Client Sample Results TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-16777-3 Client Sample ID: L05-04-25-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 09:00 Date Received: 04/04/16 11:00 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Uranium 235 0.0856 U (2+/-)
0.112 (2+/-)
1 04/07/16 17:17 04/06/16 10:38 pCi/g 0.171 RL MDC 0.112 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/06/16 10:38 04/07/16 17:17 1
4.64 2.79 2.79 U
1.94 Protactinium 234m pCi/g 04/06/16 10:38 04/07/16 17:17 1
0.0961 0.161 0.118 1.08 Thorium 232 Pb-210 1.54 0.637 0.663 0.789 pCi/g 04/06/16 10:38 04/07/16 17:17 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Tl-208 0.299 0.0419 0.0521 0.0324 pCi/g 04/06/16 10:38 04/07/16 17:17 1
Lab Sample ID: 160-16777-3 Client Sample ID: L05-04-25-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 09:00 Percent Solids: 80.1 Date Received: 04/04/16 11:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000069 0.000021 mg/Kg
04/05/16 02:58 04/07/16 10:01 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.00947 U (2+/-)
0.0401 (2+/-)
1 04/07/16 10:01 04/05/16 02:58 pCi/g 0.237 1.38 RL MDC 0.0401 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 04/05/16 02:58 04/07/16 10:01 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 90 Lab Sample ID: 160-16777-4 Client Sample ID: L05-04-26-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 09:10 Date Received: 04/04/16 11:00 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.891 (2+/-)
0.158 (2+/-)
1 04/07/16 17:50 04/06/16 10:38 pCi/g 0.113 RL MDC 0.129 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.0900 0.0539 0.0539 U
0.0189 Americium 241 pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.325 0.402 0.376 1.37 Bismuth 212 pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.0590 0.117 0.0853 0.773 Bismuth 214 pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.0543 0.158 0.0727 1.08 Lead 212 pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.0613 0.118 0.0761 0.872 Lead 214 pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.318 2.23 1.08 19.0 Potassium 40 pCi/g 04/06/16 10:38 04/07/16 17:50 1
1.07 0.218 0.212 U
0.452 Protactinium 231 pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.0590 1.00 0.117 0.0853 0.773 Radium 226 pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.760 1.00 0.300 0.289 0.761 Thorium 234 pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.157 0.121 0.119 0.212 Uranium 235 pCi/g 04/06/16 10:38 04/07/16 17:50 1
4.79 2.75 2.75 U
0.599 Protactinium 234m pCi/g 04/06/16 10:38 04/07/16 17:50 1
0.113 0.158 0.129 0.891 Thorium 232 TestAmerica St. Louis Page 12 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Client Sample Results TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-16777-4 Client Sample ID: L05-04-26-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 09:10 Date Received: 04/04/16 11:00 Pb-210 1.58 0.599 0.627 0.736 pCi/g 04/06/16 10:38 04/07/16 17:50 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Tl-208 0.314 0.0390 0.0509 0.0286 pCi/g 04/06/16 10:38 04/07/16 17:50 1
Lab Sample ID: 160-16777-4 Client Sample ID: L05-04-26-T-S-B-00 Matrix: Solid Date Collected: 04/02/16 09:10 Percent Solids: 77.2 Date Received: 04/04/16 11:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000071 0.000021 mg/Kg
04/05/16 02:58 04/07/16 10:05 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0195 U (2+/-)
0.0909 (2+/-)
1 04/07/16 10:05 04/05/16 02:58 pCi/g 0.244 1.42 RL MDC 0.0909 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 04/05/16 02:58 04/07/16 10:05 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 91 TestAmerica St. Louis Page 13 of 19 1
2 3
4 5
6 7
8 9
10 11 12
QC Sample Results TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-244121/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 244891 Prep Batch: 244121 RL MDL Technetium 99 ND 0.000051 0.000015 mg/Kg 04/05/16 02:58 04/07/16 09:35 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-244121/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 244891 Prep Batch: 244121 Technetium 99 0.00119 0.00118 mg/Kg 99 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: L05-04-23-T-R-B-00 Lab Sample ID: 160-16777-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 244891 Prep Batch: 244121 Technetium 99 ND 0.00148 0.00150 mg/Kg 102 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: L05-04-23-T-R-B-00 Lab Sample ID: 160-16777-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 244891 Prep Batch: 244121 Technetium 99 ND 0.00148 0.00146 mg/Kg 99 75 - 125 3
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-244121/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 244892 Prep Batch: 244121 Technetium 99 Analyte U
1 04/07/16 09:35 04/05/16 02:58 pCi/g 0.176 MDC 1.03 RL 0.0747 0.0746 (2+/-)
(2+/-)
MB 0.03870 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 04/05/16 02:58 04/07/16 09:35 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 97 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-244121/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 244892 Prep Batch: 244121 Technetium 99 Analyte 120 80 99 20.16 20.4 1.87 1.01 0.173 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 99 LCS TestAmerica St. Louis Page 14 of 19 1
2 3
4 5
6 7
8 9
10 11 12
QC Sample Results TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: L05-04-23-T-R-B-00 Lab Sample ID: 160-16777-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 244892 Prep Batch: 244121 Technetium 99 Analyte 125 75 102 25.72 25.3 0.0952 U 2.45 1.41 0.241 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 88 MS Client Sample ID: L05-04-23-T-R-B-00 Lab Sample ID: 160-16777-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 244892 Prep Batch: 244121 Technetium 99 Analyte 1
0.14 125 75 99 25.05 25.4 0.0952 U 2.43 1.39 0.238 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 90 MSD Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-244600/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 244918 Prep Batch: 244600 Actinium 228 Analyte U
1 04/07/16 17:19 04/06/16 10:38 pCi/g 0.0740 MDC RL 0.0387 0.0387 (2+/-)
(2+/-)
MB 0.009973 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.0242 0.0132 0.0132 U
-0.001706 Americium 241 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.230 0.127 0.127 U
0.05427 Bismuth 212 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.0408 0.250 0.250 U
-0.006250 Bismuth 214 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.0275 2.02 2.02 U
-0.009291 Lead 212 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.0403 0.0818 0.0818 U
-0.01484 Lead 214 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.243 2.48 2.48 U
-0.06207 Potassium 40 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.351 0.0606 0.0606 U
0.0000 Protactinium 231 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.0408 1.00 0.250 0.250 U
-0.006250 Radium 226 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.233 1.00 0.0727 0.0721 U
0.08676 Thorium 234 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.0858 0.525 0.525 U
-0.01312 Uranium 235 1
04/07/16 17:19 04/06/16 10:38 pCi/g 4.00 15.2 15.2 U
-0.3801 Protactinium 234m 1
04/07/16 17:19 04/06/16 10:38 pCi/g 0.0740 0.0387 0.0387 U
0.009973 Thorium 232 Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 04/06/16 10:38 04/07/16 17:19 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected TestAmerica St. Louis Page 15 of 19 1
2 3
4 5
6 7
8 9
10 11 12
QC Sample Results TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-244600/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 244920 Prep Batch: 244600 Americium 241 Analyte 116 87 103 103.4 101 10.8 0.385 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 34.1 37.96 3.92 0.200 0.161 pCi/g 111 87 - 120 Cobalt 60 31.6 34.34 3.40 0.0840 pCi/g 109 87 - 115 Client Sample ID: L05-04-23-T-R-B-00 Lab Sample ID: 160-16777-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 244919 Prep Batch: 244600 Actinium 228 Analyte 1
0.15 1.163 1.11 0.180 0.104 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Americium 241
-0.0381 U 0.01722 U 0.0570 0.0955 pCi/g 0.46 1
Bismuth 212 1.23 1.686 0.532 0.409 pCi/g 0.53 1
Bismuth 214 0.861 0.8411 0.133 0.0702 pCi/g 0.08 1
Lead 212 1.04 1.082 0.162 0.0669 pCi/g 0.13 1
Lead 214 0.939 1.045 0.139 0.0593 pCi/g 0.39 1
Potassium 40 19.7 20.69 2.46 0.241 pCi/g 0.20 1
Protactinium 231 0.303 U 0.6265 U 0.278 1.09 pCi/g 0.71 1
Radium 226 0.861 0.8411 0.133 1.00 0.0702 pCi/g 0.08 1
Thorium 234 1.36 0.9928 0.499 1.00 0.778 pCi/g 0.36 1
Uranium 235 0.108 U 0.1567 U 0.113 0.219 pCi/g 0.19 1
Protactinium 234m 0.243 U 2.429 U 3.06 5.81 pCi/g 0.38 1
Thorium 232 1.11 1.163 0.180 0.104 pCi/g 0.15 1
Tl-208 1
0.07 0.3588 0.367 0.0610 0.0356 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
RER RER Total Other Detected Radionuclides TestAmerica St. Louis Page 16 of 19 1
2 3
4 5
6 7
8 9
10 11 12
QC Association Summary TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Metals Prep Batch: 244121 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-16777-1 L05-04-23-T-R-B-00 Total/NA Solid None 160-16777-1 MS L05-04-23-T-R-B-00 Total/NA Solid None 160-16777-1 MSD L05-04-23-T-R-B-00 Total/NA Solid None 160-16777-2 L05-04-24-T-S-B-00 Total/NA Solid None 160-16777-3 L05-04-25-T-S-B-00 Total/NA Solid None 160-16777-4 L05-04-26-T-S-B-00 Total/NA Solid None LCS 160-244121/2-A Lab Control Sample Total/NA Solid None MB 160-244121/1-A Method Blank Total/NA Analysis Batch: 244891 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 244121 160-16777-1 L05-04-23-T-R-B-00 Total/NA Solid 6020A 244121 160-16777-1 MS L05-04-23-T-R-B-00 Total/NA Solid 6020A 244121 160-16777-1 MSD L05-04-23-T-R-B-00 Total/NA Solid 6020A 244121 160-16777-2 L05-04-24-T-S-B-00 Total/NA Solid 6020A 244121 160-16777-3 L05-04-25-T-S-B-00 Total/NA Solid 6020A 244121 160-16777-4 L05-04-26-T-S-B-00 Total/NA Solid 6020A 244121 LCS 160-244121/2-A Lab Control Sample Total/NA Solid 6020A 244121 MB 160-244121/1-A Method Blank Total/NA General Chemistry Analysis Batch: 244119 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-16768-A-1 DU Duplicate Total/NA Solid Moisture 160-16777-1 L05-04-23-T-R-B-00 Total/NA Solid Moisture 160-16777-2 L05-04-24-T-S-B-00 Total/NA Solid Moisture 160-16777-3 L05-04-25-T-S-B-00 Total/NA Solid Moisture 160-16777-4 L05-04-26-T-S-B-00 Total/NA Rad Leach Batch: 244065 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-16777-1 L05-04-23-T-R-B-00 Total/NA Solid Dry and Grind 160-16777-1 DU L05-04-23-T-R-B-00 Total/NA Solid Dry and Grind 160-16777-2 L05-04-24-T-S-B-00 Total/NA Solid Dry and Grind 160-16777-3 L05-04-25-T-S-B-00 Total/NA Solid Dry and Grind 160-16777-4 L05-04-26-T-S-B-00 Total/NA Prep Batch: 244121 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-16777-1 L05-04-23-T-R-B-00 Total/NA Solid None 160-16777-1 MS L05-04-23-T-R-B-00 Total/NA Solid None 160-16777-1 MSD L05-04-23-T-R-B-00 Total/NA Solid None 160-16777-2 L05-04-24-T-S-B-00 Total/NA Solid None 160-16777-3 L05-04-25-T-S-B-00 Total/NA Solid None 160-16777-4 L05-04-26-T-S-B-00 Total/NA Solid None LCS 160-244121/2-A Lab Control Sample Total/NA Solid None MB 160-244121/1-A Method Blank Total/NA TestAmerica St. Louis Page 17 of 19 1
2 3
4 5
6 7
8 9
10 11 12
QC Association Summary TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Rad (Continued)
Prep Batch: 244600 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 244065 160-16777-1 L05-04-23-T-R-B-00 Total/NA Solid Fill_Geo-0 244065 160-16777-1 DU L05-04-23-T-R-B-00 Total/NA Solid Fill_Geo-0 244065 160-16777-2 L05-04-24-T-S-B-00 Total/NA Solid Fill_Geo-0 244065 160-16777-3 L05-04-25-T-S-B-00 Total/NA Solid Fill_Geo-0 244065 160-16777-4 L05-04-26-T-S-B-00 Total/NA Solid Fill_Geo-0 LCS 160-244600/2-A Lab Control Sample Total/NA Solid Fill_Geo-0 MB 160-244600/1-A Method Blank Total/NA TestAmerica St. Louis Page 18 of 19 1
2 3
4 5
6 7
8 9
10 11 12
Tracer/Carrier Summary TestAmerica Job ID: 160-16777-1 Client: Westinghouse Electric Company LLC Project/Site: HDP RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 92 160-16777-1 Percent Yield (Acceptance Limits)
L05-04-23-T-R-B-00 88 160-16777-1 MS L05-04-23-T-R-B-00 90 160-16777-1 MSD L05-04-23-T-R-B-00 90 160-16777-2 L05-04-24-T-S-B-00 90 160-16777-3 L05-04-25-T-S-B-00 91 160-16777-4 L05-04-26-T-S-B-00 99 LCS 160-244121/2-A Lab Control Sample 97 MB 160-244121/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 19 of 19 1
2 3
4 5
6 7
8 9
10 11 12