ML22123A206

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2021 Annual Radiological Environmental Operating Report
ML22123A206
Person / Time
Site: Indian Point  Entergy icon.png
Issue date: 05/03/2022
From: Fleming J
Holtec Decommissioning International
To:
Document Control Desk, Office of Nuclear Material Safety and Safeguards, Office of Nuclear Reactor Regulation
References
HDI-IPEC-22-035
Download: ML22123A206 (123)


Text

Krishna P. Singh Technology Campus, 1 Holtec Blvd., Camden, NJ 08104 Telephone (856) 797-0900 Fax (856) 797-0909 HDI-IPEC-22-035 10 CFR 50.36(a) 10 CFR 50 Appendix I May 3, 2022 ATTN: Document Control Desk U.S. Nuclear Regulatory Commission Washington, DC 20555-0001 Indian Point Energy Center Renewed Facility License No. DPR-05, DPR-26 and DPR-64 NRC Docket Nos. 50-03, 50-247, and 50-286

Subject:

2021 Annual Radiological Environmental Operating Report Enclosed with this cover letter is the Annual Radiological Environmental Operating Report for the calendar year 2021 for the Indian Point Energy Center. This submittal is made in accordance with facility Technical Specifications, Appendix A, Section 5.6.2, Annual Radiological Environmental Operating Report.

This letter contains no new regulatory commitments.

If you have any questions or need further information, please contact Mr. Walter Wittich, IPEC Licensing at 914-254-7212, or me at (856) 797-0900, ext. 3578.

Sincerely, Jean A. Digitally signed by Jean A. Fleming Fleming Date: 2022.05.03 09:25:55 -04'00' Jean A. Fleming Vice President, Licensing, Regulatory Affairs and PSA Holtec Decommissioning International, LLC

Enclosure:

2021 Annual Environmental Protection Plan Report cc: NRC Senior Project Manager, NRC NMSS NRC Region l Regional Administrator NRC Senior Regional Inspector, Indian Point Energy Center New York State Liaison Officer Designee, NYSERDA New York State (NYS) Public Service Commission

Krishna P. Singh Technology Campus, 1 Holtec Blvd., Camden, NJ 08104 Telephone (856) 797-0900 Fax (856) 797-0909 ENCLOSURE TO HDI-IPEC-22-035 2021 Annual Radiological Environmental Operating Report

Page 1 of 121 Plant: Indian Point Energy Center YEAR: 2021 Docket Number: 50-003 (IP1), 50-247 (IP2), 50-286 (IP3)

Annual Radiological Environmental Operating Report

Plant: Indian Point Energy Center Year: 2021 Page 2 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE OF CONTENTS Page 1.0 EXECUTIVE

SUMMARY

7 1.1 Introduction 8 1.2 Sampling and Analysis 8 1.3 Land Use Census 8 1.4 Summary of Results 9 1.5 Conclusions 9

2.0 INTRODUCTION

10 2.1 Overview 11 2.2 Site Description 11 2.3 Program Background 12 2.4 Program Objectives 12 3.0 RADIOLOGICAL ENVIRONMENTAL SAMPLING PROGRAM REQUIREMENTS 13 3.1 Sample Collection 14 3.2 Sample Analysis 14 3.3 Sample Collection and Analysis Methodology 14 3.3.1 Direct Radiation 14 3.3.2 Airborne Particulates and Radioiodine 15 3.3.3 Drinking Water 15 3.3.4 Soil 15 3.3.5 Broad Leaf Vegetation 15 3.3.6 Hudson River Water 15 3.3.7 Hudson River Bottom Sediment 15 3.3.8 Hudson River Shoreline Soil 16 3.3.9 Hudson River Aquatic Vegetation 16 3.3.10 Fish and Invertebrates 16 3.3.11 Land Use Census 16 3.4 Statistical Methodology 17 3.4.1 Lower Limit of Detection (LLD) 17 3.4.2 Table Statistics 18

Plant: Indian Point Energy Center Year: 2021 Page 3 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE OF CONTENTS (continued)

Page 4.0 INTERPRETATION AND TRENDS OF RESULTS 28 4.1 Direct Radiation 30 4.2 Airborne Particulates and Radioiodine 31 4.3 Drinking Water 32 4.4 Soil 32 4.5 Broad Leaf Vegetation 32 4.6 Hudson River Water 32 4.7 Hudson River Bottom Sediment 32 4.8 Hudson River Shoreline Soil 33 4.9 Hudson River Aquatic Vegetation 33 4.10 Fish and Invertebrates 33 4.11 Land Use Census 33 4.12 Conclusion 34 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM 35

SUMMARY

5.1 2021 Annual Radiological Monitoring Program Summary 36 5.2 Land Use Census 36 5.3 Sampling Deviations 36 5.4 Analytical Deviations 36 5.5 Special Reports 36 6.0 HISTORICAL TRENDS 90 7.0 INTERLABORATORY COMPARISON PROGRAM 109 7.1 Program Description - Teledyne Brown Engineering 110 Environmental Services Comparison Programs 7.2 Acceptance Criteria 110 7.2.1 Analytics Sample Results Evaluation 110 7.2.2 ERA and MAPEP Sample Result Evaluation 111 7.3 Program Results Summary 111 7.4 Environmental TLD Quality Assurance 116

8.0 REFERENCES

118

Plant: Indian Point Energy Center Year: 2021 Page 4 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT LIST OF FIGURES FIGURE TITLE Page A-1 Sampling Locations (Within Two Miles) 22 A-2 Sampling Locations (Greater Than Two Miles) 23 A-3 Additional Sampling Locations 24 C-1 Direct Radiation, Annual Summary, 2011 to 2021 93 C-2 Radionuclides in Air - Gross Beta, 2011 to 2021 95 C-3 Radionuclides in Hudson River Water - Tritium 97 2011 to 2021 C-4 Radionuclides in Drinking Water, 99 2011 to 2021 C-5 Radionuclides in Shoreline Soil, 2011 to 2021 101 C-6 Radionuclides in Broad Leaf Vegetation, 2011 to 2021 103 C-7 Radionuclides in Fish & Invertebrates, 2011 to 2021 105 C-9 Radionuclides in Bottom Sediment, 2011 to 2021 108

Plant: Indian Point Energy Center Year: 2021 Page 5 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT LIST OF TABLES TABLE TITLE Page A-1 Indian Point REMP Sampling Station Locations 19 A-2 Lower Limit of Detection (LLD) Requirements for 25 Environmental Samples A-3 Reporting Levels for Radioactivity Concentrations in 27 Environmental Samples B-1 Summary of Sampling Deviations - 2021 37 B-1a 2021 Air Sampling Deviations 38 B-1b 2021 Other Media Deviations 38 B-1c 2021 Changes to the REMP Program 39 B-2 Radiological Environmental Monitoring Program Summary 40 Indian Point Energy Center - 2021 B-3 Direct Radiation, Quarterly Data - 2021 45 B-4 Direct Radiation, 2012 through 2021 Data 46 B-5 Direct Radiation, Inner and Outer Rings - 2021 47 B-6 Gross Beta Activity in Airborne Particulate Samples - 2021 48 B-7 Iodine-131 Activity in Airborne Charcoal Samples - 2021 50 B-8 Gamma Emitters in Airborne Particulate Samples - 2021 52 B-9 Radionuclides in Drinking Water Samples - 2021 56 B-10 Gamma Emitters in Soil Samples - 2021 60 B-11 Gamma Emitters in Broad Leaf Vegetation Samples - 2021 61 B-12 Radionuclides in River Water Samples - 2021 70 B-13 Gamma Emitters in Bottom Sediment Samples - 2021 74 B-14 Radionuclides in Shoreline Soil Samples - 2021 76 B-15 Gamma Emitters in Aquatic Vegetation Samples - 2021 79 B-16 Radionuclides in Fish / Invertebrates - 2021 82 B-17 Land Use Census, Residence & Milch Animal Results 2021 88 B-18 Land Use Census - 2021 - Unrestricted Area Boundary 89 and Nearest Residences

Plant: Indian Point Energy Center Year: 2021 Page 6 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT LIST OF TABLES (Continued)

TABLE TITLE Page C-1 Direct Radiation Annual Summary, 2011 - 2021 92 C-2 Radionuclides in Air, 2011 - 2021 94 C-3 Radionuclides in Hudson River Water - Tritium 96 2011 to 2021 C-4 Radionuclides in Drinking Water, 2011 to 2021 98 C-5 Radionuclides in Shoreline Soil, 2011 to 2021 100 C-6 Radionuclides in Broad Leaf Vegetation, 2011 to 2021 102 C-7 Radionuclides in Fish & Invertebrates, 2011 to 2021 104 C-8 River Water Discharge Area Tritium, REMP vs Effluent 106 C-9 Radionuclides in Bottom Sediment, 2011 to 2021 107 D-2.1 Ratio of Agreement 111 D-3.1 Analytics Interlaboratory Comparison Program 112 and Ratio of Agreement D-3.2 DOE Interlaboratory Comparison Program 114 and Ratio of Agreement D-3.3 ERA Interlaboratory Comparison Program 115 and Ratio of Agreement D-4.1 Percentage of Individual Dosimeters That Passed EDC 116 Internal Criteria, 2021 D-4.2 Mean Dosimeter Analysis (N=6), 2021 117 D-4.3 Summary of Independent Dosimeter Testing, 2021 117

Plant: Indian Point Energy Center Year: 2021 Page 7 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT SECTION 1.0 EXECUTIVE

SUMMARY

Plant: Indian Point Energy Center Year: 2021 Page 8 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT 1.0 EXECUTIVE

SUMMARY

1.1 INTRODUCTION

This report summarizes the results of the Radiological Environmental Monitoring Program (REMP) conducted in the vicinity of Indian Point Energy Center (IPEC) during the period from January 1 to December 31, 2021. The Indian Point site consists of Units 1, 2 and 3, which are operated by Holtec Decommissioning International Unit 1 was retired as a generating facility in 1974, and its reactor is no longer operated. Unit 2 was permanently shutdown on April 30th 2020. Unit 3 ceased operation April 30th 2021.

The REMP has been established to monitor/measure the radiation and radioactivity detectable in the environment that may be attributable to the operation of IPEC. This program, initiated in 1958, includes the collection, analysis, and evaluation of radiological data in order to assess the impact of IPEC on the environment.

1.2 SAMPLING AND ANALYSIS The environmental sampling media collected in the vicinity of IPEC and at distant locations included air particulate filters and charcoal cartridges, soil, drinking water, broad leaf vegetation, river water, shoreline sediment, bottom sediment, aquatic vegetation, fish, and invertebrates.

During 2021 there were 1172 samples collected from the atmospheric, aquatic, and terrestrial environments. This includes 164 exposure measurements which were obtained using environmental thermoluminescent dosimeters (TLDs).

A small number of inadvertent issues were encountered in 2021 in the collection of environmental samples in accordance with the IPEC Offsite Dose Calculation Manual (ODCM). Equipment failures and electrical outages resulted in a small number of instances in which lower than normal sampling volumes were collected at the airborne monitoring stations. A full description of all discrepancies encountered with the environmental monitoring program is presented in the Table B-1 of this report.

There were 1319 analyses performed on the environmental media samples. The analyzes of the 2021 Indian Point environmental samples were performed by several laboratories.

Thermoluminescent dosimeters were analyzed by Environmental Dosimetry Company (formerly Stanford Associates) of Sterling, MA. Teledyne Brown Engineering, Inc. of Knoxville, TN performed all the remaining analyses for 2021. Samples were analyzed as required by the IPEC ODCM.

1.3 LAND USE CENSUS The annual land use census in the vicinity of IPEC was conducted as required by the IPEC ODCM in May through October. No dairy animals whose milk is used for human consumption were identified within 5 miles of the Station during the census. Due to the difficulty of locating individual gardens and determining those having an area greater than 500 square feet, broad leaf sampling was performed. As allowed for in the ODCM, monthly broad leaf sampling may be used in lieu of a garden census.

Plant: Indian Point Energy Center Year: 2021 Page 9 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT 1.4

SUMMARY

OF RESULTS Samples collected as part of the IPEC REMP continued to contain detectable amounts of naturally-occurring and some man-made radioactive materials. Offsite ambient radiation measurements using environmental TLDs beyond the site boundary ranged between 43 and 61 milli-Roentgens (mR) per year. The range of ambient radiation levels observed with the TLDs is consistent with natural background radiation levels for New York.

Monitoring of the aquatic environment in the area of the station indicated the presence of the following potential station related radioactivity, tritium and cesium-137. Tritium was found in river water at the downstream mixing zone of the discharge canal at levels that were expected from routine plant operation, or other sources such as fallout from past weapons testing. Low-levels of cesium-137 were detected in Hudson River bottom sediment samples downstream of the discharge canal, as well as in the Off Verplanck, Lents Cove, and Cold Spring locations.

The levels detected were consistent with historical findings. No other plant related activity was detected in any offsite samples. The predominant radioactivity for all samples was from non-plant related sources, such as fallout from nuclear weapons tests and naturally occurring radionuclides.

1.5 CONCLUSION

S The 2021 Radiological Environmental Monitoring Program for IPEC resulted in the collection and analysis of over a thousand environmental samples and measurements. The data obtained were used to determine the impact of IPECs operation on the environment and on the general public.

In 2021 the only positive detectable plant related activity was three instances of low levels of H-3 detected in river water samples. An evaluation of direct radiation measurements, environmental sample analyses, and dose calculations demonstrates that all applicable federal criteria were met. Furthermore, radiation levels and resulting doses from station operation were a small fraction of those attributed to natural and man-made background radiation.

In summary, the levels of radionuclides in the environment surrounding Indian Point were within the historical ranges, i.e., previous levels resulting from natural and anthropogenic sources for the detected radionuclides. Further, IPEC operations in 2021 did not result in exposure to the public greater than the variability of environmental background levels.

Plant: Indian Point Energy Center Year: 2021 Page 10 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT SECTION

2.0 INTRODUCTION

Plant: Indian Point Energy Center Year: 2021 Page 11 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT

2.0 INTRODUCTION

2.1 Overview The Radiological Environmental Monitoring Program (REMP) for 2021 performed by Holtec for the Indian Point Energy Center (IPEC) is discussed in this report. Since the operation of a nuclear power plant results in the release of small amounts of radioactivity and low levels of radiation, the Nuclear Regulatory Commission (NRC) requires a program to be established to monitor radiation and radioactivity in the environment (Reference 1). This report, which is submitted to the NRC annually per Indian Point Technical Specifications, summarizes the results of measurements of radiation and radioactivity in the environment in the vicinity of the IPEC and at distant locations during the period January 1 to December 31, 2021.

The REMP is used to measure the direct radiation and the airborne and waterborne pathway activity in the vicinity of the Indian Point site. Direct radiation pathways include radiation from buildings and plant structures, airborne and liquid material that might be released from the plant, cosmic radiation, and the naturally occurring radioactive materials in the ground. Analysis of thermoluminescent dosimeters (TLDs), used to measure direct radiation, indicated that there were no increased radiation levels attributable to plant operations.

The airborne pathway includes measurements of air, drinking water, and broad leaf vegetation samples. The airborne pathway measurements indicated that there was no adverse radiological impact to the surrounding environment attributed to Indian Point Station operations.

The waterborne pathway consists of Hudson River water, fish and invertebrates, aquatic vegetation, bottom sediment, and shoreline sediment. Measurements of the media comprising the waterborne pathway indicated that there was no adverse radiological impact to the surrounding environment attributed to Indian Point Station operations.

These results are reviewed by IPEC's staff and have been reported semiannually or annually to the Nuclear Regulatory Commission and others for over 30 years.

This report contains a description of the REMP for IPEC and the conduct of that program in 2021 as required by the IPEC ODCM. Also included are summaries and discussions of the results of the 2021 program, trend analyses (where appropriate), comparison to historical results and evaluation of any potential impact on the environment. Results of the annual land use census, as well as the inter-laboratory comparison program are included, per the ODCM requirements.

2.2 Site Description The Indian Point site occupies 239 acres on the east bank of the Hudson River on a point of land at Mile Point 42.6. The site is located in the Village of Buchanan, Westchester County, New York. Three nuclear reactors, Indian Point Unit Nos. 1, 2 and 3, and associated buildings occupy approximately 35 acres. Unit 1 began operation in 1962 and was retired as a generating facility in 1974. Units 2 and 3 began operation 1974 and 1978. Indian Point

Plant: Indian Point Energy Center Year: 2021 Page 12 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT Units 1 and 2 are owned by Holtec Decommissioning International Indian Point 2, LLC and Unit 3 is owned by Holtec Decommissioning International Indian Point 3 LLC. All three units are no longer in operation.

2.3 Program Background Environmental monitoring and surveillance have been conducted at Indian Point since 1958, four years prior to the start-up of Unit 1. The pre-operational program was designed and implemented to determine the background radioactivity and to measure the variations in activity levels from natural and other sources in the vicinity, as well as fallout from atmospheric nuclear weapons tests. Thus, as used in this report, background levels consist of those resulting from both natural and anthropogenic sources of environmental radioactivity. Accumulation of this background data permits the detection and assessment of environmental activity attributable to plant operations.

2.4 Program Objectives The current environmental monitoring program is designed to meet two primary objectives:

1. To enable the identification and quantification of changes in the radioactivity of the area.
2. To measure radionuclide concentrations in the environment attributable to operations of the Indian Point site.

To identify changes in activity, the environmental sampling schedule requires that analyses be conducted for specific environmental media on a regular basis. The radioactivity profile of the environment is established and monitored through routine evaluation of the analytical results obtained.

The REMP designates sampling locations for the collection of environmental media for analysis. These sample locations are divided into indicator and control locations. Indicator locations are established near the site, where the presence of environmental radioactivity of plant origin is most likely to be detected. Control locations are established farther away (and upwind/upstream, where applicable) from the site, where the level would not generally be affected by plant discharges. The use of indicator and control locations enables the identification of potential sources of detected radioactivity, thus meeting one of the program objectives.

Verification of expected radionuclide concentrations resulting from effluent releases attributable to the site is another objective of the REMP, which is met by meeting the two primary program objectives described above. Verifying projected concentrations through evaluating REMP data can be difficult since the environmental concentrations resulting from plant releases are typically too small to be detected. Plant related radionuclides were detected in 2021 in very low levels; however, residual radioactivity from atmospheric weapons tests and naturally occurring radioactivity were the predominant sources of radioactivity in the samples collected. Analysis of the 2021 REMP sample results confirms that environmental concentrations which could be attributed to radiological effluents were well below regulatory limits.

Plant: Indian Point Energy Center Year: 2021 Page 13 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT SECTION 3.0 RADIOLOGICAL ENVIRONMENTAL SAMPLING PROGRAM REQUIREMENTS

Plant: Indian Point Energy Center Year: 2021 Page 14 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT 3.0 RADIOLOGICAL ENVIRONMENTAL SAMPLING PROGRAM REQUIREMENTS To achieve the objectives of the REMP and ensure compliance with the ODCM, sampling and analysis of environmental media are performed as outlined in Table A-1 and described in section 3.3.

3.1 Sample Collection Holtec personnel perform collection of environmental samples for the Indian Point site, with the exception of fish/invertebrate samples. Collection of fish and invertebrate samples is performed by a contracted environmental vendor, Normandeau Associates, Inc.

Environmental media are sampled at the locations specified in Table A-1 and shown in Figures A-1, A-2, and A-3. The samples are analyzed according to criteria established in the ODCM. These requirements include: methods of sample collection; types of sample analysis; minimum sample size required; lower limit of detection, which must be attained for each medium, sample, or analysis type, and environmental concentrations requiring special reports.

Table A-1 provides the sampling station number, location, sector, and distance from Indian Point, sample designation code, and sample type. This table gives the complete listing of sample locations used in the 2021 REMP.

Three maps are provided to show the locations of REMP sampling. Figure A-1 shows the sampling locations within two miles of Indian Point. Figures A-2 and A-3 show the sampling locations within ten miles of Indian Point.

3.2 Sample Analysis The analysis of the 2021 Indian Point environmental samples was performed by several laboratories. Thermoluminescent dosimeters were analyzed by Environmental Dosimetry Company (formerly Stanford Associates) of Sterling, MA. Teledyne Brown Engineering, Inc.

of Knoxville, TN performed all the remaining analyses.

3.3 Sample Collection and Analysis Methodology 3.3.1 Direct Radiation Direct gamma radiation is measured using integrating calcium sulfate thermoluminescent dosimeters (TLDs), which provide cumulative measurements of radiation exposure (i.e., total integrated exposures in milli-roentgen, mR) for a given period. The area surrounding the Indian Point site is divided into 16 compass sectors. Each sector has two TLD sample locations. The inner ring is located near the site boundary at approximately 1 mile (1.6 km).

The outer ring is located at approximately 5 miles (8 km) from the site (6.7- 8.0 km), see Figures A-1 and A-2. Additional TLD locations include a control location at Roseton (20.7 miles north) and eight locations of special interest. In total, there are 41 TLD sample sites, designated DR-1 through DR-41, with two TLDs placed at each site. TLDs are collected and processed on a quarterly basis. The results are reported as mR per standard quarter (91 days). The data reported is the average of the two TLDs from each sample site.

Plant: Indian Point Energy Center Year: 2021 Page 15 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT 3.3.2 Airborne Particulates and Radioiodine Air samples were taken at eight locations varying in distance from 0.28 to 20.7 miles (0.5 to 33 km) from the plant. These locations represent one control at sampling station 23 (A5) and seven indicator locations. These indicator locations are at sampling stations 4 (A1), 5 (A4),

27, 29, 94 (A2), 95 (A3), and 108. The locations are shown on Figures A-1, A-2, and A-3.

The air samples are collected continuously by means of fixed air particulate filters followed by in-line charcoal cartridges. Both filters and cartridges are changed on a weekly basis. The filters are analyzed for gross beta and the cartridge samples for radioiodine. In addition, gamma spectroscopy analysis (GSA) is performed on quarterly composites of the air particulate filters.

3.3.3 Drinking Water Samples of drinking water are collected monthly from the Camp Field Reservoir (3.4 miles NE, sample station 7, sample designation Wb1) and New Croton Reservoir (6.3 miles SE, sample station 8); see Figure A-2 and Figure A-3. Each monthly sample is approximately 4 liters and is analyzed for gross beta and gamma-emitting radionuclides. Monthly samples are composited quarterly and analyzed for tritium.

3.3.4 Soil Soil samples are collected from two indicator locations (sampling stations 94 and 95), and one control location (23) on an annual basis; see Figure A-3. They are approximately 2 kg in size and consist of about twenty 2-inch deep cores. The soil samples are analyzed by gamma spectroscopy.

3.3.5 Broad Leaf Vegetation Broad Leaf vegetation samples are collected from three locations during the growing season.

The indicator locations are sampling stations 94 (Ic2) and 95 (Ic1), and the control location is at sampling station 23 (Ic3). See Figures A-1 and A-2. The samples are collected monthly, when available, and analyzed by gamma spectroscopy. These samples consist of at least 1 kg of leafy vegetation and are used in the assessment of the food product and milk ingestion pathways.

3.3.6 Hudson River Water Hudson River water sampling is performed continuously at a point exterior to the discharge canal where Hudson River water and water from the discharge canal mix (sampling station 10, Wa2); see Figure A-1. Samples were also collected continuously at a control station 23 Roseton (Figure A-2 and A-3). An automatic composite sampler is used to take representative samples. On a weekly basis, accumulated samples are taken from both sample points. These weekly river water samples are composited for monthly gamma spectroscopy analysis and quarterly for tritium analysis.

3.3.7 Hudson River Bottom Sediment Bottom sediment and benthos are sampled at four locations: three indicator locations (sampling stations 10, 17, and 28) and one control location (84), along the Hudson River, once each spring and summer; see Figure A-3. These samples are obtained using a

Plant: Indian Point Energy Center Year: 2021 Page 16 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT Peterson grab sampler or similar instrument. The bottom sediment samples are analyzed by gamma spectroscopy.

3.3.8 Hudson River Shoreline Soil Shoreline soil samples are collected at three indicator and two control locations along the Hudson River. The indicator locations are at sampling stations 53 (Wc1), 28, and 17. The control locations are at sampling stations 50 (Wc2) and 84. Figures A-1, A-2, and A-3 show these locations. The samples are gathered at a level above low tide and below high tide and are approximately 2-kg grab samples. These samples are collected at greater than 90 days apart and are analyzed by gamma spectroscopy and for strontium-90.

3.3.9 Hudson River Aquatic Vegetation During the spring and summer, aquatic vegetation samples are collected from the Hudson River at two indicator locations (sampling stations 17 and 28) and one control location (84);

see Figure A-3. Samples of aquatic vegetation are obtained depending on sample availability. These samples are analyzed by gamma spectroscopy.

3.3.10 Fish and Invertebrates Fish and invertebrate samples are obtained from the Hudson River at locations upstream and downstream of the plant discharge. The indicator location (downstream sample point) is designated as sampling station 25 (Ib1), and a second sampling station 107 is located further downstream. The control location (upstream) is at sampling station 23 (Ib2). See Figures A-1 and A-2. These samples are collected in season or semiannually if they are not seasonal.

The fish and invertebrates sampled are analyzed by gamma spectroscopy as well as for strontium-90 and for nickel-63.

3.3.11 Land Use Census In addition to the sampling outlined in Table A-1, there is an environmental surveillance requirement that an annual land use census be performed. Each year a land use census consisting of milch animal and residence surveys is conducted during the growing season to determine the current utilization of land within 5 miles (8 km) of the site. These surveys are used to determine whether there are changes in existing conditions that warrant changing the sampling program. The results of the census are discussed in Section 4.11.

For example, the milch animal census is used to identify animals producing milk for human consumption within 5 miles (8 km) of Indian Point. This census consists of visual field surveys of the areas where a high probability of milch animals exists and confirmation through New York State records or with personnel such as feed suppliers who deal with farm animals and dairy associations.

Visual inspections are made of the 5-mile area around the Indian Point Site during routine sample collections and emergency plan equipment inspections in the area throughout the year. An extensive land survey is conducted of the 5-mile area in an attempt to identify new residential areas, commercial developments and to identify milch animals in pasture.

Plant: Indian Point Energy Center Year: 2021 Page 17 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT A garden census is not required, since the ODCM allows sampling of vegetation in two sectors near the site boundary in lieu of a garden census. The sectors are chosen to be in the pre-dominant wind directions with the highest predicted deposition rates.

3.4 Statistical Methodology There are several statistical calculation methodologies used in evaluating the data from the Indian Point REMP. These methods include determination of Lower Limits of Detection (LLD) and the Minimum Detectable Concentration (MDC), and estimation of the mean and associated propagated error.

3.4.1 Lower Limit of Detection (LLD)

The LLD is the smallest concentration of radioactive material in a sample that will yield a net count above system background, and be detected with 95% probability, with a 5% probability of falsely concluding that a blank observation represents a "real" signal.

For a particular measurement system (which may include radiochemical separation):

2.71

+ 3.29 sb

  • 1 + ( T b )

T Ts LLD = s E*V

  • k* Y
  • e - t Where:

LLD = The lower limit of detection as defined above (as picocurie per unit mass or volume)

Ts = The sample counting time in minutes sb = The standard deviation of the background counting rate or of the counting rate of a blank sample as appropriate (as counts per minute)

Tb = The background count time in minutes E= The counting efficiency (as counts per transformation)

V= The sample size (in units of mass or volume) k= A constant for the number of transformations per minute per unit of activity (normally, 2.22E+6 dpm per uCi)

Y= The fractional radiochemical yield (when applicable)

= The radioactive decay constant for the particular radionuclide t= The elapsed time between midpoint of sample collection and time of counting Note: The above LLD formula accounts for differing background and sample count times.

The Radiological Environmental Monitoring Program, REMP, may use an LLD formula that assumes equal background and sample count times, when appropriate.

The constants 2.71 and 3.29 and the general LLD equation were derived from References 2 and 3.

Plant: Indian Point Energy Center Year: 2021 Page 18 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT The value of Sb used in the calculation of the LLD for a detection system shall be based on the actual observed variance of the background counting rate or of the counting rate of the blank samples (as appropriate) rather than on an unverified theoretically predicted variance.

In calculating the LLD for a radionuclide determined by gamma ray spectrometry, the background shall include the typical contributions of other radionuclides normally present in the samples. Typical values of E, V, Y, and t shall be used in the calculation. The background count rate is calculated from the background counts that are determined by a separate background count or in the case of gamma ray spectroscopy, from adjacent channels of the energy band of the gamma ray peak used for the quantitative analysis for that radionuclide.

It should be recognized that the LLD is defined as an a priori (before the fact) limit representing the capability of a measurement process and not as an a posteriori (after the fact) limit for a particular measurement. To document the post priori (after the fact) measurement statistics, the MDC is calculated after the measurement using the same equation as above.

To handle the a posteriori problem, a decision level must be defined. To minimize the number of false positives, a value is not considered positive unless it is greater than the MDC or 3 times the total standard deviation of the post priori measurement, where MDC is the post priori (after the fact) measurement statistic calculated similar to the LLD equation listed above (for Tb = Ts, the term 3.29 sb * [(1 + ( Tb / Ts ))1/2] = 4.66 sb).

The ODCM required lower limits of detection (LLD) for Indian Point sample analyses are presented in Table A-2. These required lower limits of detection are not the same as the lower limits of detection or critical levels actually achieved by the laboratory. The laboratory's lower limits of detection and critical levels must be equal to or lower than the required levels presented in Table A-2.

Table A-3 provides the reporting level for radioactivity in various media. Sample results that exceed these levels and are due to plant operations require that a special report be submitted to the NRC.

3.4.2 Table Statistics The averages shown in the summary table (Table B-2) are the averages of the positive values in accordance with the NRC's Branch Technical Position (BTP) to Regulatory Guide 4.8 (Reference 4). Samples with "<" values are not included in the averages.

It should be noted that this statistic for the mean using only positive values tends to strongly bias the average high, particularly when only a few of the data are measurably positive. The REMP data show few positive values; thus the corresponding means are biased high.

Exceptions to this include direct radiation measured by TLDs and gross beta radioactivity in air, which show positive monitoring results throughout the year.

The historical data tables contain the annual averages of the positive values for each year for 2011 through 2021. The historical averages are calculated using only the positive values presented for 2011 through 2020. The 2021 average values are included in these historic tables for purposes of comparison.

Plant: Indian Point Energy Center Year: 2021 Page 19 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE A-1 INDIAN POINT REMP SAMPLING STATION LOCATIONS SAMPLING SAMPLE LOCATION DISTANCE SAMPLE TYPES STATION DESIGNATION Onsite - 0.35 Mi (SSE) at 3 DR8 Service Center Building Direct Gamma 158° A1 Onsite - 0.28 Mi (SW) at Air Particulate 4 Algonquin Gas Line A1 234° Radioiodine A4 Air Particulate Onsite - 0.88 Mi (SSW) 5 A4 NYU Tower Radioiodine at 208° DR10 Direct Gamma 7 Wb1 Camp Field Reservoir 3.4 Mi (NE) at 51° Drinking Water 8 ** Croton Reservoir 6.3 Mi (SE) at 124° Drinking Water Wa2 Onsite - 0.3 Mi (WSW) at HR Water 10 Discharge Canal (Mixing Zone)

    • 249° HR Bottom Sediment Onsite - 0.3 Mi (SE) at 14 DR7 Water Meter House Direct Gamma 133°
    • HR Aquatic Vegetation 17 ** Off Verplanck 1.5 Mi (SSW) at 202.5° HR Shoreline Soil
    • HR Bottom Sediment Cortlandt Yacht Club 20 DR38 1.5 Mi (S) at 180° Direct Gamma (AKA Montrose Marina) 23 HR Water A5 Air Particulate A5 Radioiodine 23 DR40 Roseton* 20.7 Mi (N) at 357° Direct Gamma Ic3 Broad Leaf Vegetation
    • Soil Ib2 Fish & Invertebrates 25 Ib1 Downstream Downstream Fish & Invertebrates
    • Air Particulate 27 ** Croton Point 6.36 Mi (SSE) at 156° Radioiodine DR41 Direct Gamma
    • HR Shoreline Soil DR4 Direct Gamma 28 Lent's Cove 0.45 Mi (ENE) at 069°
    • HR Bottom Sediment
    • HR Aquatic Vegetation
    • Air Particulate 29 ** Grassy Point 3.37 Mi (SSW) at 196° Radioiodine DR39 Direct Gamma 33 DR33 Hamilton Street (Substation) 2.88 Mi (NE) at 053° Direct Gamma Onsite - 0.52 Mi (S) at 34 DR9 South East Corner of Site Direct Gamma 179° Onsite - 0.37 Mi (E) at 35 DR5 Broadway & Bleakley Avenue Direct Gamma 092° 38 DR34 Furnace Dock (Substation) 3.43 Mi (SE) at 141° Direct Gamma
  • = Control location
    • = Locations listed do not have sample designation locations specified in the ODCM HR = Hudson River
      • = In 2021 Air sampler station 44 Peekskill was relocated to 108 Telcom. Bldg.
        • = In 2021 River water station 9 Plant Inlet (Hudson River Intake) was moved to Roseton.

Plant: Indian Point Energy Center Year: 2021 Page 20 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE A-1 INDIAN POINT REMP SAMPLING STATION LOCATIONS SAMPLING SAMPLE LOCATION DISTANCE SAMPLE TYPES STATION DESIGNATION

    • Air Particulate 44** Peekskill Gas Holder Bldg 1.84 Mi (NE) at 052°
    • Radioiodine 50 Wc2 Manitou Inlet* 4.48 Mi (NNW) at 347° HR Shoreline Soil Wc1 HR Shoreline Soil 53 White Beach 0.92 Mi (SW) at 226° DR11 Direct Gamma 56 DR37 Verplanck - Broadway & 6th Street 1.25 Mi (SSW) at 202° Direct Gamma 57 DR1 Roa Hook 2 Mi (N) at 005° Direct Gamma 58 DR17 Route 9D - Garrison 5.41 Mi (N) at 358° Direct Gamma 59 DR2 Old Pemart Avenue 1.8 Mi (NNE) at 032° Direct Gamma Gallows Hill Road & Sprout Brook 60 DR18 5.02 Mi (NNE) at 029° Direct Gamma Road 61 DR36 Lower South Street & Franklin Street 1.3 Mi (NE) at 052° Direct Gamma Westbrook Drive 62 DR19 5.03 Mi (NE) at 062° Direct Gamma (near the Community Center)

Lincoln Road - Cortlandt 64 DR20 4.6 Mi (ENE) at 067° Direct Gamma (School Parking Lot) 66 DR21 Croton Avenue - Cortlandt 4.87 Mi (E) at 083° Direct Gamma 67 DR22 Colabaugh Pond Road - Cortlandt 4.5 Mi (ESE) at 114° Direct Gamma 69 DR23 Mt. Airy & Windsor Road 4.97 Mi (SE) at 127° Direct Gamma 71 DR25 Warren Ave - Haverstraw 4.83 Mi (S) at 188° Direct Gamma 72 DR26 Railroad Avenue & 9W - Haverstraw 4.53 Mi (SSW) at 203° Direct Gamma Willow Grove Road & Captain 73 DR27 4.97 Mi (SW) at 226° Direct Gamma Faldermeyer Drive 74 DR12 West Shore Drive - South 1.59 Mi (WSW) at 252° Direct Gamma 75 DR31 Palisades Parkway 4.65 Mi (NW) at 225° Direct Gamma 76 DR13 West Shore Drive - North 1.21 Mi (W) at 276° Direct Gamma 77 DR29 Palisades Parkway 4.15 Mi (W) at 272° Direct Gamma 78 DR14 Rt. 9W across from R/S #14 1.2 Mi (WNW) at 295° Direct Gamma 79 DR30 Anthony Wayne Park 4.57 Mi (WNW) at 296° Direct Gamma 80 DR15 Route 9W South of Ayers Road 1.02 Mi (NW) at 317° Direct Gamma 81 DR-28 Palisades Pkwy - Lake Welch Exit 4.96 Mi (WSW) at 310° Direct Gamma 82 DR16 Ayers Road 1.01 Mi (NNW) at 334° Direct Gamma 83 DR32 Route 9W - Fort Montgomery 4.82 Mi (NNW) at 339° Direct Gamma

    • HR Aquatic Vegetation 84 ** Cold Spring
  • 10.88 Mi (N) at 356° HR Shoreline Soil
    • HR Bottom Sediment 88 DR6 Reuter Stokes Pole #6 0.32 Mi (ESE) at 118° Direct Gamma Highland Ave & Sprout Brook Road 89 DR35 2.89 Mi (NNE) at 025° Direct Gamma (near rock cut)
  • = Control location
    • = Locations listed do not have sample designation locations specified in the ODCM HR = Hudson River
      • = In 2021 Air sampler station 44 Peekskill was relocated to 108 Telcom. Bldg.
        • = In 2021 River water station 9 Plant Inlet (Hudson River Intake) was moved to Roseton.

Plant: Indian Point Energy Center Year: 2021 Page 21 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE A-1 INDIAN POINT REMP SAMPLING STATION LOCATIONS SAMPLING SAMPLE LOCATION DISTANCE SAMPLE TYPES STATION DESIGNATION 90 DR3 Charles Point 0.88 Mi (NE) at 047° Direct Gamma 92 DR24 Warren Road - Cortlandt 3.84 Mi (SSE) at 149° Direct Gamma A2 Air Particulate A2 Onsite- 0.39 Mi (S) at Radioiodine 94 IPEC Training Center Ic2 193° Broad Leaf Vegetation

    • Soil A3 Air Particulate A3 Onsite - 0.46 Mi (SSW) at Radioiodine 95 Meteorological Tower Ic1 208° Broad Leaf Vegetation
    • Soil 2.5 mi SSW 107 ** Vicinity of Haverstraw Bay Fish & Invertebrates (downstream)
    • Air Particulate 108*** Telecomm Bldg. 0.36 mi ESE
    • Radioiodine
  • = Control location
    • = Locations listed do not have sample designation locations specified in the ODCM HR = Hudson River
      • = In 2021 Air sampler station 44 Peekskill was relocated to 108 Telcom. Bldg.
        • = In 2021 River water station 9 Plant Inlet (Hudson River Intake) was moved to Roseton.

Plant: Indian Point Energy Center Year: 2021 Page 22 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT FIGURE A-1 SAMPLING LOCATIONS Within Two Miles of Indian Point

Plant: Indian Point Energy Center Year: 2021 Page 23 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT FIGURE A-2 SAMPLING LOCATIONS Greater than Two Miles from Indian Point

Plant: Indian Point Energy Center Year: 2021 Page 24 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT FIGURE A-3 SAMPLING LOCATIONS Additional Sampling Locations

Plant: Indian Point Energy Center Year: 2021 Page 25 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE A-2 LOWER LIMIT OF DETECTION (LLD) REQUIREMENTS FOR ENVIRONMENTAL SAMPLES FOOD SOIL or AIRBORNE FISH RADIONUCLIDE WATER MILK PRODUCTS SEDIMENT PARTIUCLATE OR (pCi/kg, ANALYSIS (pCi/L) (pCi/L) (pCi/kg, wet) (pCi/kg, dry)

GASES (pCi/m3) wet)

Gross Beta 4 0.01 H-3 2,000 (d)

Mn-54 15 130 Fe-59 30 260 Co-58 15 130 Co-60 15 130 Ni-63 (f) 30 100 Zn-65 30 260 Sr-90 (f) 1 5 50 Zr-95 30 Nb-95 15 I-131 1 (d) 0.07 1 60 Cs-134 15 0.05 130 15 60 150 Cs-137 18 0.06 150 18 80 180 Ba-140 60 60 La-140 15 15

Plant: Indian Point Energy Center Year: 2021 Page 26 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE A-2 LOWER LIMIT OF DETECTION (LLD) REQUIREMENTS FOR ENVIRONMENTAL SAMPLES Table Notation (a) This list does not mean that only these nuclides are to be considered. Other peaks that are identifiable, together with those of the above nuclides, shall also be analyzed and reported in the Annual Radiological Environmental Operating Report pursuant to the ODCM.

(b) Required detection capabilities for thermoluminescent dosimeters used for environmental measurements are given in Regulatory Guide 4.13.

(c) The LLD is defined as the smallest concentration of radioactive material in a sample that will yield a net count, above system background, that will be detected with 95% probability with only 5% probability of falsely concluding that a blank observation represents a real signal.

It should be recognized that the LLD is defined as an a priori (before the fact) limit representing the capability of a measurement system and not as an a posteriori (after the fact) limit for a particular measurement.

Analyses shall be performed in such a manner that the stated LLDs will be achieved under routine conditions. Occasionally background fluctuations, unavoidable small sample sizes, the presence of interfering nuclides, or other uncontrollable circumstances may render these LLDs unachievable.

In such cases, the contributing factors shall be identified and described in the Annual Radiological Environmental Operating Report pursuant to the ODCM.

(d) These LLDs are for drinking water samples. If no drinking water pathway exists, the LLDs may be increased to 3,000 pCi/liter for H-3 and 15 pCi/liter for I-131.

(e) These required lower limits of detection are associated only with the REMP requirements. The Radiological Ground Water Monitoring Program may involve unique reporting level criteria, independent of the REMP, and defined in station procedures.

(f) Sr-90 and Ni-63 are included in this table due to their historical presence in ground water and possible migration to the environment.

Plant: Indian Point Energy Center Year: 2021 Page 27 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE A-3 REPORTING LEVELS FOR RADIOACTIVITY CONCENTRATIONS IN ENVIRONMENTAL SAMPLES AIRBORNE FOOD RADIONUCLIDE WATER FISH MILK PARTIUCLATE OR PRODUCTS ANALYSIS (pCi/L) (pCi/kg, wet) (pCi/L)

GASES (pCi/m3) (pCi/kg, wet)

H-3 20,000

  • Mn-54 1,000 30,000 Fe-59 400 10,000 Co-58 1,000 30,000 Co-60 300 10,000 Ni-63 *** 300 1,000 Zn-65 300 20,000 Sr-90 *** 8* 40 Zr-95 400 Nb-95 400 I-131 2* 0.9 3 100 Cs-134 30 10 1,000 60 1,000 Cs-137 50 20 2,000 70 2,000 Ba-140 200 300 La-140 200 300
  • Values provided are for drinking water pathways. If no drinking water pathway exists, higher values are allowed, as follows:

H-3 30,000 pCi/L (This is a 40 CFR 141 value)

Sr-90 12 pCi/L I-131 20 pCi/L

    • These reporting levels are associated only with the REMP requirements. The Radiological Ground Water Monitoring Program may involve unique reporting level criteria, independent of the REMP, and defined in station procedures.
      • Sr-90 and Ni-63 are included in this table due to their historical presence in ground water and possible migration to the environment

Plant: Indian Point Energy Center Year: 2021 Page 28 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT SECTION 4.0 INTERPRETATION AND TRENDS OF RESULTS

Plant: Indian Point Energy Center Year: 2021 Page 29 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT 4.0 INTERPRETATION AND TRENDS OF RESULTS The 2021 Radiological Environmental Monitoring Program (REMP) was conducted in accordance with Indian Point's Offsite Dose Calculation Manual ODCM. The ODCM contains requirements for the number and distribution of sampling locations, the types of samples to be collected, and the types of analyses to be performed for measurement of radioactivity.

The REMP at Indian Point includes measurements of radioactivity levels in the following environmental pathways.

Direct Gamma Radiation Drinking Water Broad Leaf Vegetation Hudson River Water Bottom Sediment Shoreline Soil Aquatic Vegetation Fish and Invertebrates Airborne Particulates and Radioiodine Soil An annual land use and milch animal census is also part of the REMP.

To evaluate the contribution of plant operations to environmental radioactivity levels, other man-made and natural sources of environmental radioactivity, as well as the aggregate of past monitoring data, must be considered. It is not merely the detection of a radionuclide, but the evaluation of the location, magnitude, source, and history of its detection that determines its significance. Therefore, we have reported the data collected in 2021 and assessed the significance of the findings.

A summary of the results of the 2021 REMP is presented in Table B-2. This Table lists the mean and range of all positive results obtained for each of the media sampled at ODCM indicator and control locations. Discussions of these results and their evaluations are provided below.

The radionuclides detected in the environment can be grouped into three categories: (1) naturally occurring radionuclides; (2) radionuclides resulting from weapons testing and other non-plant related, anthropogenic sources; and (3) radionuclides that could be related to plant operations.

The environment contains a broad inventory of naturally occurring radionuclides which can be classified as, cosmic ray induced (e.g., Be-7) or geologically derived (e.g., Ra-226 and progeny, Th-228 and progeny, and K-40.) These radionuclides constitute the majority of the background radiation source and thus account for a majority of the annual background dose detected. Since the detected concentrations of these radionuclides were consistent at indicator and control locations, and unrelated to plant operations, their presence is noted only in the data tables and will not be discussed further.

The second group of radionuclides detected in 2021 consists of those resulting from past weapons testing in the earth's atmosphere. The more recent contamination events resulting from the Chernobyl and Fukushima accidents only indicated detectable activity shortly after their occurrences (Reference 5). However, weapons testing in the 1950's and 1960's resulted in a significant atmospheric radionuclide inventory, which, in turn, still contributes to the

Plant: Indian Point Energy Center Year: 2021 Page 30 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT concentrations in the ecological systems. Although reduced in frequency, atmospheric weapons testing continued into the 1980's. The resultant radionuclide inventory of some radionuclides, although diminishing with time (e.g., through radioactive decay and natural dispersion processes), remains detectable.

In 2021, the detected radionuclides that may be attributable to past atmospheric weapons testing consisted of Cs-137 in several media. The levels detected were consistent with the historical levels of radionuclides resulting from weapons tests as measured in previous years.

The final group of radionuclides detected by the 2021 REMP comprises those that may be attributable to current plant operations. During 2021, Cs-137 and Tritium were the only potentially plant-related radionuclides detected in any environmental samples.

H-3 may be present in the local environment due to either natural occurrence, other man-made sources, or as a result of plant operations. Natural occurrence is very low (on the order of approximately 5 pCi/liter - well below typical detectable levels). The major source of H-3 is typically from above ground nuclear weapons testing, in the range of 50 to 150 pCi/liter).

Other sources include weapons production and industrial uses where levels are highly dependent on the release rates and distance from the source term. One such industrial source is nuclear power plant operation. In 2021, very low levels of H-3 were detected in three river water samples.

Cs-137 is ubiquitous in the environment from atmospheric testing debris and a lesser amount from the Chernobyl accident. In 2021, there were six detections of Cs-137 in bottom sediment at indicator and control locations. In all cases, the Cs-137 concentrations, when detected, were consistent with historical values.

Strontium-90 (Sr-90) may also be present in the environment from atmospheric testing debris. Sr-90 was not detected in any of the fish, invertebrate, or shoreline soil.

I-131 is also produced in fission reactors, but can result from non-plant related anthropogenic sources, e.g., medical administrations, such as has been noted in previous years. I-131 was not detected in 2021 in aquatic or terrestrial vegetation indicator and control locations.

Co-58 and Co-60 are activation/corrosion products also related to plant operations. They are produced by neutron activation in the reactor core. Co-58 has a much shorter half-life than Co-60. If Co-58 and Co-60 are concurrently detected in environmental samples, then the source of these radionuclides is more likely the result of recent releases. When significant concentrations of Co-60 are detected but no Co-58, there is an increased likelihood that the Co-60 is due to residual Co-60 from past operations. There was no Co-58 or Co-60 detected in the 2021 REMP, although they were observed in historical data.

In the following sections, a summary of the results of the 2021 REMP is presented by sample medium and the significance of any positive findings discussed. As previously mentioned, Table B-2 provides an annual summary of the following media.

4.1 Direct Radiation The environmental TLDs used to measure the direct radiation were TLDs supplied and processed by Environmental Dosimetry Company. In 2021, the TLD program produced a

Plant: Indian Point Energy Center Year: 2021 Page 31 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT consistent picture of ambient background radiation levels in the vicinity of the Indian Point Station. A summary of the annual TLD data is provided in Table B-2 and all the TLD data are presented in Tables B-3, B-4 and B-5. TLD sample site DR-40 is the control site for the direct radiation (DR) series of measurements.

Table B-3 provides the quarterly and annual average reported doses in mR per standard quarter for each of the direct radiation sample points, DR-1 through DR-41. Table B-4 provides the mean, standard deviation, minimum and maximum values in mR per year for the years 2012 through 2020. The 2021 means are also presented in Table B-4. Table B-5 presents the 2021 TLD data for the inner ring and outer ring of TLDs. The table also provides the sector for each of the DR sample points.

The 2021 mean value for the indicator direct radiation sample points was 13.2 mR per standard quarter - which is consistent with historical values. At those locations where the 2021 mean value was higher than historical means, they are within historical bounds for the respective locations.

The DR sample locations are arranged so that there are two concentric rings of TLDs around the Indian Point site. The inner ring (DR-1 to DR-16) is close to the site boundary. The outer ring (DR-17 to DR-32) has a radius of approximately 5 miles from the three Indian Point units.

The results of the annual totals for these two rings of TLDs are provided in Table B-5. The annual average for the inner ring was 13.2 mR per standard quarter and also average for the outer ring was 13.3 mR per standard quarter. The control location average for 2021 was 14.1 mR per standard quarter.

Table C-1 and Figure C-1 present the 10-year historical averages for the inner and outer rings of TLDs. The 2021 averages are consistent with the historical data. The 2021 and previous years' data show that there is no measurable direct radiation in the environment due to the operation of the Indian Point site.

4.2 Airborne Particulates and Radioiodine The results of the analyses of weekly air particulate filter samples for gross beta activity are presented in Table B-6 and the weekly charcoal cartridge analytical results are presented in Table B-7.

Gross beta activity was found in air particulate samples throughout the year at all indicator and control locations. The average gross beta activity for the seven indicator air sample locations was 0.014 pCi/m3 and the average for the control location was 0.014 pCi/m3. The activities detected were consistent for all locations, with no significant differences in gross beta activity in any sample due to location.

The results of the gamma spectral analyses (GSA) of the quarterly composites of these samples are shown in Table B-8. These quarterly composite air samples indicate that no reactor-related radionuclides were detected and that only Be-7, a naturally-occurring radionuclide was present at detectable levels.

The mean annual gross beta concentrations and Cs-137 concentrations in air for the past 10 years are presented in Table C-2. From this table and Figure C-2, it can be seen that the

Plant: Indian Point Energy Center Year: 2021 Page 32 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT average 2021 gross beta concentration was consistent with historical levels. Cs-137 has not been detected since 1987. This is consistent with the trend of decreasing ambient Cs-137 concentrations in recent years.

From the data, it can be seen that no airborne radioactivity attributable to the operation of Indian Point was detected in 2021.

4.3 Drinking Water Results of the gross beta, tritium and gamma spectroscopy analyses of the monthly drinking water samples are in Table B-9. Other than Gross Beta activity consistent with historical values, no radioactivity was detected in drinking water samples. This has historically been the case for the radionuclide results for this media. Operation of the Indian Point units had no detectable radiological impact on drinking water.

4.4 Soil Table B-10 contains the results of the soil samples for 2021. There were no plant related nuclides detected in the 2021 samples.

4.5 Broad Leaf Vegetation Data from analysis of the 2021 samples are presented in Table B-11. Table C-6 contains an historical summary and Figure C-6 is an illustration of the broad leaf vegetation analysis results. There were no plant related nuclides detected in the 2021 samples. The detection of low levels of Cs-137 has occurred sporadically at indicator locations at relatively low concentrations for the past ten years, most likely the result of previous atmospheric weapons testing.

4.6 Hudson River Water Data resulting from analysis of monthly Hudson River water samples for gamma emitters and quarterly composites of H-3 are presented in Tables B-12.

The only plant related activity detected was H-3; detected at low levels in three indicator samples. The levels are consistent with occasional historical detection of H-3 related to plant operation. Table C-3 shows historical H-3 concentrations at the plant inlet and discharge points. Table C-8 contains a comparison of H-3 detected at the plant discharge (Hudson River Water mixing point) versus calculated quarterly average effluents concentrations. The data in table C-8 provides assurance that the REMP is indeed providing verification of the calculated radionuclide concentrations resulting from effluent releases attributable to the site.

4.7 Hudson River Bottom Sediment Table B-13 contains the results of the analysis of bottom sediment samples for 2021.

Cesium-137 was detected in five of six indicator station samples, and one of two control location samples. Detection of positive levels of Cs-137 in river bottom sediment is not unusual. Cs-137 is often detected in the control location sediments and therefore not likely due to plant releases.

Plant: Indian Point Energy Center Year: 2021 Page 33 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT Historical levels of Cs-137 in bottom sediment samples are shown in table C-9 and figure C-

9. This data shows the continued detection of Cs-137 in bottom sediment samples at varying levels, and demonstrates that the levels observed during 2021 sampling are within the range of levels identified in historical samples.

4.8 Hudson River Shoreline Soil Table B-14 contains the results of the gamma spectroscopic and strontium-90 analyses of the shoreline soil samples. Naturally occurring radionuclides were detected in the shoreline soil samples. There were no plant related nuclides detected in the 2021 samples.

An historical look at Cs-137 detected in shoreline soil at indicator and control locations can be viewed in Table C-5 and Figure C-5. Cesium-137 has been present in this media, both at indicator and occasionally at the control location, at a consistent level over the past ten years.

Cesium-134 and Cs-137 are both discharged from the plant in similar quantities. The lack of Cs-134 activity is an indication that the primary source of the Cs-137 in the shoreline soil is legacy contamination from weapons fallout.

Strontium-90 (Sr-90) was not detected in any of the six indicator location samples or any of the control location samples.

4.9 Hudson River Aquatic Vegetation Table B-15 results show no plant related radionuclides were detected in any indicator or control aquatic vegetation samples in 2021. This is consistent with historical findings.

4.10 Fish and Invertebrates Table B-16 contains the results of the analysis of fish and invertebrate samples for 2021.

No plant related radionuclides were detected. This is consistent with historical results which are shown in Table and Figure C-7.

4.11 Land Use Census A census was performed in the vicinity of Indian Point in 2021. This census consisted of a milch animal and a residence census. Results of this census are presented in Tables B-17 and B-18.

The results of the 2021 census were generally same as the 2020 census results. In 2020 the presence of goats was noted on a property located less than 5.0 miles of IPEC, discussions with the owner of the property indicated that the goats did not produce milk for human consumption. Similar to 2020, it was noted in 2021 that no animals were producing milk for human consumption at this location or any other location within 5 miles to IPEC.

However, discussions with the owner for the 2021 land use surveys confirmed that the goats did not produce milk for human consumption and are therefore not milch animals.

The 2021 land use census indicated there were no new residences that were closer in proximity to IPEC.

Plant: Indian Point Energy Center Year: 2021 Page 34 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT The ODCM allows the sampling of broad leaf vegetation in two sectors at the site boundary in lieu of performing a garden census. Analysis results for these two sectors are discussed in Section 4.5 and presented in Table B-11, Table C-6 and Figure C-6.

4.12 Conclusion The Radiological Environmental Monitoring Program is conducted each year to determine the radiological impact of Indian Point operations on the environment. The preceding discussions of the results of the 2021 REMP reveal that operations at the station did not result in an impact on the environment.

The 2021 REMP results demonstrate the relative contributions of different radionuclide sources, both natural and anthropogenic, to the environmental concentrations. The results indicate that the fallout from previous atmospheric weapons testing continues to contribute to detection of Cs-137 in some environmental samples. There are infrequent detections of plant related activity in the environs; however, the radiological levels are very low and are significantly less than those from natural background and other anthropogenic sources.

Plant: Indian Point Energy Center Year: 2021 Page 35 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT SECTION 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

Plant: Indian Point Energy Center Year: 2021 Page 36 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT 5.0 RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

5.1 2021 Annual Radiological Environmental Monitoring Program Summary The results of the 2021 radiological environmental sampling program are presented in Tables B-2 through B-16. Table B-2 is a summary table of the sample results for 2021.

The format of this summary table conforms to the reporting requirements of the ODCM, NRC Regulatory Guide 4.8, and NRC Branch Technical Position to Regulatory Guide 4.8 (Reference 4). In addition, the data obtained from the analysis of samples are provided in Tables B-3 through B-16.

REMP samples were analyzed by various counting methods as appropriate. The methods are; gross beta, gamma spectroscopy analysis, liquid scintillation, radiochemical analysis, and TLD processing. Gamma spectroscopy analysis was performed for gamma emitting nuclides, including the following: Be-7, K-40, Mn-54, Co-58, Co-60, Fe-59, Zn-65, Zr-95, Nb-95, Ru-103, Ru-106, I-131, Cs-134, Cs-137, Ba/La-140, Ce-141, Ce-144, Ra-226 and Ac/Th-228. Radiochemical analyses were performed for H-3, Ni-63, Sr-90 and I-131 for specific media and locations as required in the ODCM.

5.2 Land Use Census In accordance with Sections IP2-D3.5.2 and IP3-2.8 of the ODCM, a land use census was conducted to identify the nearest milch animal and the nearest residence. The results of the milch animal and land use census are presented in Tables B-17 and B-18, respectively. In lieu of identifying and sampling the nearest garden of greater than 50 m2, at least three kinds of broad leaf vegetation were sampled near the site boundary in two sectors and at a designated control location (results are presented in Table B-11).

5.3 Sampling Deviations During 2021, environmental sampling was performed for 10 unique media types addressed in the ODCM and for direct radiation. A total of 1172 samples of 1177 scheduled were obtained. Of the scheduled samples, 99.6% were collected and analyzed for the program. Sampling deviations are summarized in Table B-1.

Discussions of the reasons for the deviations are provided in Table B-1a for the air samples, Table B-1b for other media, and Table B-1c for changes to the REMP program. Analytical deviations noted in Table B-6 and B-7 due to insufficient sample volumes as noted in Table B-1a.

5.4 Analytical Deviations No analytical deviations were found in 2021.

5.5 Special Reports No special reports were required under the REMP.

Plant: Indian Point Energy Center Year: 2021 Page 37 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-1 Summary of Sampling Deviations - 2021 TOTAL NUMBER OF SAMPLING NUMBER OF REASON FOR MEDIA SCHEDULED DEVIATIONS* EFFICIENCY % ANALYSES** DEVIATION SAMPLES MEDIA TLD 164 0 100% 164 N/A PARTICULATES IN AIR 424 0 100% 456 N/A CHARCOAL FILTER 424 0 100% 424 N/A DRINKING WATER 24 0 100% 56 N/A SOIL 3 0 100% 3 N/A BROAD LEAF 54 0 100% 54 N/A VEGETATION HUDSON RIVER WATER 24 0 100% 32 N/A SHORELINE SOIL 10 0 100% 20 N/A HUDSON RIVER BOTTOM 8 0 100% 8 N/A SEDIMENT AQUATIC VEGETATION 6 2 67% 4 See Table B-1b FISH & INVERTEBRATES 36 3 94% 98 See Table B-1b TOTALS 1177 5 99.6% 1319 TOTAL NUMBER OF SAMPLES COLLECTED = 1172

  • Samples not collected or unable to be analyzed.
    • Several sample types require more than one analysis

Plant: Indian Point Energy Center Year: 2021 Page 38 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-1a 2021 Air Sampling Deviations LOCATION DATE PROBLEM / ACTIONS TO PREVENT RECURRENCE Air sampler collection frequency exceeded 7 days + 25%. CPR-04 Algonquin 2/4/2021 IP3-2021-00333. Cb.

Air sampler collection frequency exceeded 7 days + 25%. CPR-05 NYC Tower 2/4/2021 IP3-2021-00333. Cb.

Air sampler collection frequency exceeded 7 days + 25%. CPR-29 Grassy Point 2/4/2021 IP3-2021-00333. Cb.

Air sampler collection frequency exceeded 7 days + 25%. CPR-108 Telecomm 2/4/2021 IP3-2021-00333. Cb.

Air sampler lost 22 hours2.546296e-4 days <br />0.00611 hours <br />3.637566e-5 weeks <br />8.371e-6 months <br /> of run time due to hour meter repair. IR-27 Croton Point 10/4/2021 IP3-2021-00229.

TABLE B-1b 2021 Other Media Deviations LOCATION DATE PROBLEM / ACTIONS TO PREVENT RECURRENCE During collection of 1st Quarter REMP TLDs it was discovered 38 Furnace Dock 1/7/2021 that the TLD was missing from the Cortlandt Yacht Club location. CR-IP2-2021-00017.

10 Hudson River Sample was not able to be obtained due to pump failure. Grab 2/4/2021 Discharge sample was collected. CR-IP2-2021-00058.

Sample was not able to be obtained due to the pump being in 23 Roseton Hudson 5/3/2021 pause mode. Grab sample was collected. CR-IP2-2021-River 00237.

Aquatic Vegetation samples were not available in the riverbed 17 Verplanck Spring areas designated for these samples during the Spring sampling event.

Crab samples were not available during the Spring sampling 25 Indian Point Spring event.

Crab samples were not available during the Spring sampling 23 Poughkeepsie Spring event.

Aquatic Vegetation samples were not available in the riverbed 17 Verplanck Summer areas designated for these samples during the Summer sampling event.

Striped Bass samples were not available during the Spring 107 Croton - Haverstraw Summer sampling event Stripped Bass samples had limited amount of sample.

25 Downstream 9/15/21 Strontium-90 was unable to be performed.

Plant: Indian Point Energy Center Year: 2021 Page 39 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-1c 2021 Changes to the REMP Program LOCATION DATE Discussion of REMP Change No changes to the REMP program in 2021.

Plant: Indian Point Energy Center Year: 2021 Page 40 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-2 RADIOLOGICIAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

INDIAN POINT ENERGY CENTER - 2021 Dockets50-003, 50-247 & 50-286 Medium or Indicator Control Pathway Analysis Total LLD* Locations Location with Highest Mean Locations Non-Routine Sampled Type Number Mean ** Location Distance Mean** Mean** Reported (Units) (Range) Number Direction (Range) (Range) Measurements Direct Radiation TLD-Quarterly 164 13.2 (160/160) DR-13 1.21 Mi. 15.5 (4/4) 14.1 (4/4) 0 (mR/Standard Quarter) (9.4/16.6) W (14.8/16.6) (13.1/15.6)

Air Particulate Gr-B 424 0.01 .014 (371/371) 4 0.28 Mi. .015 (53/53) .014 (53/53) 0 (pCi/m3) (.005/.026) SW (.006/.026) (.005/.023)

Air Iodine GAMMA 424 3

(pCi/m ) I-131 0.07 <LLD - <LLD 0 Air Particulate GAMMA 32 (10-3 pCi/m3) Be-7 NA 112.9 (28/28) 94 0.39 Mi. 117.1 (4/4) 95.0 (4/4) 0 (84.5/151.6) S (99.7/131.1) (77.8/124.2)

K-40 NA <LLD - <LLD 0 Cs-134 0.05 <LLD - <LLD 0 Cs-137 0.06 <LLD - <LLD 0 Th-228 NA <LLD - <LLD 0 Drinking Water Gr-B 24 4 3.16 (9/24) 8 6.3 Mi. 3.47 (5/12) NA 0 (pCi/L) (2.49/5.38) SE (2.54/5.38)

H-3 8 200 <LLD - NA 0 GAMMA 24 Mn-54 15 <LLD - NA 0 Co-58 15 <LLD - NA 0 Fe-59 30 <LLD - NA 0 Co-60 15 <LLD - NA 0 Zn-65 30 <LLD - NA 0 Nb-95 15 <LLD - NA 0 Zr-95 30 <LLD - NA 0 I-131 15 <LLD - NA 0 Cs-134 15 <LLD - NA 0

Plant: Indian Point Energy Center Year: 2021 Page 41 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-2 RADIOLOGICIAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

INDIAN POINT ENERGY CENTER - 2021 Dockets50-003, 50-247 & 50-286 Medium or Indicator Control Pathway Analysis Total LLD* Locations Location with Highest Mean Locations Non-Routine Sampled Type Number Mean ** Location Distance Mean** Mean** Reported (Units) (Range) Number Direction (Range) (Range) Measurements Drinking Water (cont'd) Cs-137 18 <LLD - NA 0 (pCi/L)

Ba-140 60 <LLD - NA 0 La-140 15 <LLD - NA 0 Soil GAMMA 3 (pCi/kg dry) Be-7 NA <LLD - <LLD 0 K-40 NA 10320 (2/2) 23 20.7 Mi. 14750 (1/1) 14750 (1/1) 0 (8669/11970) N Co-60 NA <LLD - <LLD 0 Cs-134 150 <LLD - <LLD 0 Cs-137 180 <LLD - <LLD 0 Ra-226 NA <LLD - <LLD 0 Th-228 NA 589 (1/2) 23 20.7 Mi. 715 (1/1) 715 (1/1) 0 N

Broad leaf Vegetation GAMMA 54 (pCi/kg wet) Be-7 NA 2133 (36/36) 23 20.7 Mi. 2486 (17/18) 2486 (17/18) 0 (758.2/5935) N (1009/5319) (1009/5319)

K-40 NA 4814 (36/36) 95 0.46 Mi. 5638 (18/18) 4637 (18/18) 0 (2224/10050) SSW (3285/10050) (2381/7444)

Co-60 NA <LLD - <LLD 0 I-131 60 <LLD - <LLD 0 Cs-134 60 <LLD - <LLD 0 Cs-137 80 <LLD - <LLD 0 Th-228 NA 127 (3/36) 95 0.46 Mi. 141.8 (2/18) <LLD 0 (98.5/169.4) SSW (114.2/169.4)

Plant: Indian Point Energy Center Year: 2021 Page 42 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-2 RADIOLOGICIAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

INDIAN POINT ENERGY CENTER - 2021 Dockets50-003, 50-247 & 50-286 Medium or Indicator Control Pathway Analysis Total LLD* Locations Location with Highest Mean Locations Non-Routine Sampled Type Number Mean ** Location Distance Mean** Mean** Reported (Units) (Range) Number Direction (Range) (Range) Measurements River Water H-3 8 200 380.0 (3/4) 10 0.3 Mi. 380.0 (3/4) <LLD 0 (pCi/L) (214/483) WSW (214/483)

GAMMA 24 Mn-54 15 <LLD - <LLD 0 Co-58 15 <LLD - <LLD 0 Fe-59 30 <LLD - <LLD 0 Co-60 15 <LLD - <LLD 0 Zn-65 30 <LLD - <LLD 0 Nb-95 15 <LLD - <LLD 0 Zr-95 30 <LLD - <LLD 0 Cs-134 15 <LLD - <LLD 0 I-131 15 <LLD - <LLD 0 Cs-137 18 <LLD - <LLD 0 Ba-140 60 <LLD - <LLD 0 La-140 15 <LLD - <LLD 0 Th-228 NA 9.974 (1/12) 10 0.3 Mi. 9.974 (1/12) <LLD 0 WSW Bottom Sediment GAMMA 8 (pCi/kg dry) K-40 NA 16472 (6/6) 84 10.88 Mi. 19885 (2/2) 19885 (2/2) 0 (13790/21400) N (19560/20210) (19560/20210)

Co-60 NA <LLD - <LLD 0 Cs-134 150 <LLD - <LLD 0 Cs-137 180 182.5 (5/6) 84 10.88 Mi. 256.9 (1/2) 256.9 (1/2) 0 (94.4/321.4) N

Plant: Indian Point Energy Center Year: 2021 Page 43 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-2 RADIOLOGICIAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

INDIAN POINT ENERGY CENTER - 2021 Dockets50-003, 50-247 & 50-286 Medium or Indicator Control Pathway Analysis Total LLD* Locations Location with Highest Mean Locations Non-Routine Sampled Type Number Mean ** Location Distance Mean** Mean** Reported (Units) (Range) Number Direction (Range) (Range) Measurements Bottom Sediment (cont'd) Ra-226 NA 2270 (2/6) 17 1.5 Mi. 2270 (2/2) <LLD 0 (pCi/kg dry) (1962/2578) SSW (1962/2578)

Th-228 NA 718.6 (6/6) 84 10.88 Mi. 1027.4 (2/2) 1027.4 (2/2) 0 (244/900) N (970/1085) (970/1085)

Shoreline Soil Sr-90 10 50 <LLD - <LLD 0 (pCi/kg dry)

GAMMA 10 K-40 NA 11083 (6/6) 84 10.88 Mi. 31200 (2/2) 21160 (4/4) 0 (8047/13410) N (30250/32150) (9070/32150)

Cs-134 150 <LLD - <LLD 0 Cs-137 180 <LLD - <LLD 0 Ra-226 NA <LLD 50 4.48 Mi. 2435 (1/4) 2435 (1/4) 0 NNW Ac-228 NA <LLD - <LLD 0 Th-228 NA 368.0 (4/6) 50 4.48 Mi. 613.7 (2/2) 512.0 (4/4) 0 (203/493) NNW (577/650) (335/650)

Aquatic Vegetation GAMMA 4 (pCi/kg wet) Be-7 NA 385.5 (1/2) 28 0.45 Mi. 385.5 (1/2) <LLD 0 ENE K-40 NA 2173 (2/2) 84 10.88 Mi. 2688 (2/2) 2688 (2/2) 0 (2134/2212) N (2405/2971) (2405/2971)

Co-60 NA <LLD - <LLD 0 I-131 60 <LLD - <LLD 0 Cs-134 60 <LLD - <LLD 0 Cs-137 80 <LLD - <LLD 0 Ra-226 NA <LLD - <LLD 0 Ac-228 NA <LLD - <LLD 0 Th-228 NA <LLD - <LLD 0

Plant: Indian Point Energy Center Year: 2021 Page 44 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-2 RADIOLOGICIAL ENVIRONMENTAL MONITORING PROGRAM

SUMMARY

INDIAN POINT ENERGY CENTER - 2021 Dockets50-003, 50-247 & 50-286 Medium or Indicator Control Pathway Analysis Total LLD* Locations Location with Highest Mean Locations Non-Routine Sampled Type Number Mean ** Location Distance Mean** Mean** Reported (Units) (Range) Number Direction (Range) (Range) Measurements Fish Ni-63 33 100 <LLD - <LLD 0 (pCi/kg wet)

Sr-90 32 5 <LLD - <LLD 0 GAMMA 33 K-40 NA 2422 (22/22) 23 20.7 Mi. 2780 (11/11) 2780 (11/11) 0 (1185/3573) N (1827/4154) (1827/4154)

Mn-54 130 <LLD - <LLD 0 Co-58 130 <LLD - <LLD 0 Fe-59 260 <LLD - <LLD 0 Co-60 130 <LLD - <LLD 0 Zn-65 260 <LLD - <LLD 0 Cs-134 130 <LLD - <LLD 0 Cs-137 150 <LLD - <LLD 0 Th-228 NA 212.1 (1/22) 25 Downstream 212.1 (1/22) <LLD 0 Environment Samples 1172 Analysis 1319

  • LLD IS THE LOWER LIMIT OF DETECTION
    • THE MEAN VALUES ARE CALCULATED USING THE POSITIVE VALUES

Plant: Indian Point Energy Center Year: 2021 Page 45 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-3 DIRECT RADIATION, QUARTERLY DATA - 2021 mR/Quarter +/- 1 sigma Sample Station First Quarter Second Quarter Third Quarter Fourth Quarter Annual Annual Nuclide Number 01/01-03/31 04/01-06/30 07/01-09/30 10/01-01/01 Average Total TLD DR-01 14.1 +/- 0.5 15.8 +/- 0.6 15.7 +/- 1.0 15.0 +/- 1.1 15.1 +/- 0.8 60.6 DR-02 13.5 +/- 0.6 14.6 +/- 0.6 14.9 +/- 1.0 14.3 +/- 0.6 14.3 +/- 0.6 57.3 DR-03 11.8 +/- 0.8 12.8 +/- 0.5 12.6 +/- 0.9 12.2 +/- 0.7 12.4 +/- 0.4 49.4 DR-04 12.1 +/- 0.6 14.0 +/- 0.5 13.6 +/- 0.9 12.9 +/- 0.6 13.2 +/- 0.8 52.6 DR-05 12.2 +/- 0.5 13.9 +/- 0.7 13.7 +/- 0.8 12.6 +/- 0.6 13.1 +/- 0.8 52.3 DR-06 12.9 +/- 0.8 14.0 +/- 0.7 13.8 +/- 0.9 13.7 +/- 0.6 13.6 +/- 0.5 54.4 DR-07 13.7 +/- 0.5 15.7 +/- 0.5 15.6 +/- 1.1 14.4 +/- 0.7 14.8 +/- 0.9 59.3 DR-08 10.9 +/- 0.6 11.9 +/- 0.4 12.3 +/- 0.8 11.6 +/- 0.5 11.7 +/- 0.6 46.6 DR-09 12.2 +/- 0.6 13.3 +/- 0.6 12.8 +/- 0.8 12.7 +/- 0.7 12.7 +/- 0.5 50.9 DR-10 11.4 +/- 0.6 12.5 +/- 0.5 13.5 +/- 1.0 12.7 +/- 0.6 12.5 +/- 0.8 50.1 DR-11 9.9 +/- 0.5 11.2 +/- 0.4 9.4 +/- 0.7 9.9 +/- 0.5 10.1 +/- 0.8 40.4 DR-12 14.0 +/- 0.8 16.2 +/- 0.7 14.7 +/- 0.9 14.5 +/- 0.6 14.8 +/- 0.9 59.3 DR-13 14.8 +/- 0.9 16.6 +/- 0.6 15.4 +/- 1.0 15.2 +/- 0.7 15.5 +/- 0.8 62.0 DR-14 11.7 +/- 0.8 13.3 +/- 0.5 12.3 +/- 0.8 12.3 +/- 0.7 12.4 +/- 0.7 49.5 DR-15 11.4 +/- 0.7 13.2 +/- 0.5 12.0 +/- 0.8 12.3 +/- 0.5 12.2 +/- 0.7 49.0 DR-16 12.5 +/- 0.6 14.9 +/- 0.6 13.2 +/- 0.9 13.7 +/- 0.6 13.6 +/- 1.0 54.3 DR-17 12.4 +/- 0.5 14.0 +/- 0.7 13.7 +/- 0.9 13.5 +/- 0.7 13.4 +/- 0.7 53.5 DR-18 12.4 +/- 0.7 14.4 +/- 0.6 13.3 +/- 0.8 13.7 +/- 0.6 13.4 +/- 0.8 53.8 DR-19 12.7 +/- 0.6 14.7 +/- 0.5 13.7 +/- 0.9 13.2 +/- 0.6 13.6 +/- 0.8 54.3 DR-20 12.2 +/- 0.5 14.0 +/- 0.7 13.3 +/- 0.8 13.3 +/- 0.6 13.2 +/- 0.8 52.8 DR-21 12.6 +/- 0.7 14.2 +/- 0.5 13.2 +/- 0.9 13.4 +/- 0.6 13.3 +/- 0.6 53.4 DR-22 10.0 +/- 0.4 11.7 +/- 0.4 10.4 +/- 0.7 10.5 +/- 0.5 10.6 +/- 0.7 42.5 DR-23 12.6 +/- 0.6 13.8 +/- 0.5 12.4 +/- 0.8 13.4 +/- 0.7 13.1 +/- 0.6 52.3 DR-24 12.8 +/- 0.6 14.3 +/- 0.9 14.1 +/- 0.7 13.7 +/- 0.7 13.7 +/- 0.6 54.9 DR-25 10.8 +/- 0.5 12.0 +/- 0.8 12.1 +/- 0.7 11.2 +/- 0.6 11.5 +/- 0.6 46.1 DR-26 12.4 +/- 0.4 13.6 +/- 0.5 12.7 +/- 0.7 12.6 +/- 0.5 12.8 +/- 0.5 51.2 DR-27 12.0 +/- 0.7 13.6 +/- 0.8 13.0 +/- 0.6 12.6 +/- 0.6 12.8 +/- 0.7 51.3 DR-28 13.7 +/- 0.6 15.3 +/- 0.5 14.6 +/- 0.5 14.2 +/- 0.7 14.4 +/- 0.7 57.8 DR-29 12.1 +/- 0.5 13.8 +/- 0.6 13.6 +/- 0.7 13.1 +/- 0.7 13.2 +/- 0.8 52.6 DR-30 12.3 +/- 0.5 13.9 +/- 0.9 13.7 +/- 0.7 13.1 +/- 0.8 13.3 +/- 0.7 53.1 DR-31 14.4 +/- 0.7 15.9 +/- 0.7 15.4 +/- 0.9 15.0 +/- 0.6 15.2 +/- 0.7 60.7 DR-32 13.6 +/- 0.5 15.3 +/- 0.8 15.5 +/- 0.9 14.7 +/- 0.7 14.8 +/- 0.9 59.1 DR-33 12.1 +/- 0.7 13.1 +/- 0.6 13.0 +/- 0.7 12.6 +/- 0.7 12.7 +/- 0.4 50.7 DR-34 11.6 +/- 0.4 13.0 +/- 0.5 12.6 +/- 0.6 12.4 +/- 0.6 12.4 +/- 0.6 49.5 DR-35 11.9 +/- 0.5 14.1 +/- 0.7 14.2 +/- 0.5 15.0 +/- 0.7 13.8 +/- 1.3 55.2 DR-36 13.5 +/- 0.6 14.5 +/- 0.6 14.1 +/- 0.6 13.8 +/- 0.7 14.0 +/- 0.4 55.8 DR-37 12.1 +/- 0.5 13.4 +/- 0.6 13.1 +/- 0.5 12.2 +/- 0.6 12.7 +/- 0.6 50.8 DR-38 11.2 +/- 0.5 12.1 +/- 0.6 11.8 +/- 0.6 11.3 +/- 0.7 11.6 +/- 0.4 46.4 DR-39 13.1 +/- 0.4 14.5 +/- 0.7 14.3 +/- 0.6 13.9 +/- 0.6 13.9 +/- 0.6 55.8 DR-40* 13.1 +/- 0.5 13.7 +/- 0.4 15.6 +/- 0.7 13.9 +/- 0.7 14.1 +/- 1.0 56.3 DR-41 11.5 +/- 0.6 13.4 +/- 0.8 12.6 +/- 0.5 11.6 +/- 0.6 12.3 +/- 0.9 49.1 AVERAGE 12.4 +/- 1.1 13.9 +/- 1.2 13.4 +/- 1.3 13.1 +/- 1.2 13.2 +/- 1.2 52.8 (Indicator Locations)

  • Control location

Plant: Indian Point Energy Center Year: 2021 Page 46 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-4 DIRECT RADIATION, 2012 THROUGH 2021 DATA mR per Year Station Mean Standard Deviation Minimum Value Maximum Value 2021 Annual Number (2012-2020) (2012-2020) (2012-2020) (2012-2020) Total DR-01 62.0 3.0 55.6 65.6 60.6 DR-02 58.3 1.7 55.9 60.4 57.3 DR-03 46.9 5.0 35.0 50.9 49.4 DR-04 53.3 1.0 52.1 54.8 52.6 DR-05 54.9 1.6 53.3 58.2 52.3 DR-06 56.2 1.4 54.7 58.0 54.4 DR-07 62.6 1.4 60.7 64.6 59.3 DR-08 47.4 1.6 45.1 49.5 46.6 DR-09 53.4 2.1 50.0 55.8 50.9 DR-10 56.9 4.7 53.0 67.7 50.1 DR-11 43.2 1.1 41.4 44.6 40.4 DR-12 60.6 4.5 49.2 64.8 59.3 DR-13 64.7 1.9 62.3 67.6 62.0 DR-14 52.3 1.2 50.5 54.0 49.5 DR-15 52.2 1.3 50.3 53.8 49.0 DR-16 57.6 1.6 55.1 59.3 54.3 DR-17 57.8 1.7 55.6 60.1 53.5 DR-18 56.4 1.3 54.4 58.2 53.8 DR-19 58.3 1.5 55.9 60.4 54.3 DR-20 55.5 1.3 53.4 57.5 52.8 DR-21 55.2 2.5 51.9 58.4 53.4 DR-22 45.1 1.7 42.6 47.7 42.5 DR-23 55.6 1.4 53.6 57.4 52.3 DR-24 58.2 1.6 55.8 60.2 54.9 DR-25 48.3 1.3 45.7 50.0 46.1 DR-26 55.0 1.2 53.0 56.5 51.2 DR-27 54.0 1.6 51.5 56.5 51.3 DR-28 69.5 11.3 51.3 80.6 57.8 DR-29 56.3 1.2 54.8 58.3 52.6 DR-30 57.0 1.4 54.7 59.3 53.1 DR-31 64.7 1.9 61.5 67.4 60.7 DR-32 54.9 5.2 48.7 63.3 59.1 DR-33 53.7 1.1 52.3 55.6 50.7 DR-34 52.6 1.8 50.2 55.0 49.5 DR-35 52.9 2.6 49.9 56.3 55.2 DR-36 57.6 1.3 55.9 59.6 55.8 DR-37 54.8 1.2 53.3 56.8 50.8 DR-38 47.5 3.7 38.5 50.9 46.4 DR-39 57.8 1.8 54.8 59.4 55.8 DR-40* 58.7 4.2 49.3 62.4 56.3 DR-41 52.0 1.7 49.7 53.9 49.1 AVERAGE 55.3 52.8 (Indicator Locations)

  • Control location

Plant: Indian Point Energy Center Year: 2021 Page 47 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-5 DIRECT RADIATION, INNER AND OUTER RINGS - 2021 (mR per Year)

Inner Ring Outer Ring Sector Inner Ring Outer Ring ID ID Annual Total Annual Total DR-01 DR-17 N 60.57 53.54 DR-02 DR-18 NNE 57.26 53.78 DR-03 DR-19 NE 49.43 54.29 DR-04 DR-20 ENE 52.62 52.78 DR-05 DR-21 E 52.29 53.38 DR-06 DR-22 ESE 54.37 42.50 DR-07 DR-23 SE 59.32 52.25 DR-08 DR-24 SSE 46.63 54.93 DR-09 DR-25 S 50.91 46.10 DR-10 DR-26 SSW 50.08 51.21 DR-11 DR-27 SW 40.36 51.27 DR-12 DR-28 WSW 59.33 57.79 DR-13 DR-29 W 61.95 52.63 DR-14 DR-30 WNW 49.54 53.06 DR-15 DR-31 NW 48.95 60.71 DR-16 DR-32 NNW 54.33 59.07 Average 53.00 53.08

Plant: Indian Point Energy Center Year: 2021 Page 48 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-6 GROSS BETA ACTIVITY IN AIRBORNE PARTICULATE SAMPLES - 2021 pCi/m3 +/- 2 Sigma PERIOD Algonquin NYU Tower Roseton Croton Point Grassy Point Training Building Met Tower Telcom Bldg.

ENDING 4 5 23* 27 29 94 95 108 01/05/21 0.009 +/- 0.002 0.008 +/- 0.002 0.008 +/- 0.002 0.012 +/- 0.002 0.009 +/- 0.002 0.010 +/- 0.002 0.009 +/- 0.002 0.011 +/- 0.002 01/11/21 0.009 +/- 0.002 0.006 +/- 0.002 0.008 +/- 0.002 0.009 +/- 0.002 0.008 +/- 0.002 0.007 +/- 0.002 0.008 +/- 0.002 0.010 +/- 0.002 01/19/21 0.026 +/- 0.003 0.025 +/- 0.003 0.019 +/- 0.002 0.018 +/- 0.003 0.022 +/- 0.003 0.021 +/- 0.003 0.023 +/- 0.003 0.022 +/- 0.003 01/25/21 0.011 +/- 0.002 0.010 +/- 0.002 0.009 +/- 0.002 0.011 +/- 0.003 0.009 +/- 0.002 0.010 +/- 0.002 0.010 +/- 0.002 0.011 +/- 0.002 02/04/21 0.006 +/- 0.001 0.008 +/- 0.002 0.007 +/- 0.002 0.009 +/- 0.002 0.008 +/- 0.002 0.007 +/- 0.002 0.007 +/- 0.002 0.007 +/- 0.001 02/08/21 0.021 +/- 0.004 0.018 +/- 0.004 0.016 +/- 0.003 0.013 +/- 0.003 0.020 +/- 0.004 0.014 +/- 0.003 0.015 +/- 0.003 0.020 +/- 0.004 02/16/21 0.019 +/- 0.003 0.021 +/- 0.003 0.017 +/- 0.002 0.021 +/- 0.003 0.018 +/- 0.002 0.020 +/- 0.003 0.016 +/- 0.002 0.020 +/- 0.002 02/22/21 0.016 +/- 0.003 0.016 +/- 0.003 0.015 +/- 0.003 0.014 +/- 0.003 0.014 +/- 0.003 0.017 +/- 0.003 0.013 +/- 0.003 0.014 +/- 0.003 03/01/21 0.013 +/- 0.003 0.014 +/- 0.003 0.012 +/- 0.002 0.012 +/- 0.002 0.014 +/- 0.002 0.011 +/- 0.002 0.012 +/- 0.002 0.014 +/- 0.002 03/08/21 0.013 +/- 0.002 0.015 +/- 0.002 0.012 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.002 0.014 +/- 0.002 0.011 +/- 0.002 0.012 +/- 0.002 03/15/21 0.022 +/- 0.003 0.021 +/- 0.003 0.023 +/- 0.003 0.021 +/- 0.003 0.023 +/- 0.003 0.019 +/- 0.003 0.020 +/- 0.003 0.022 +/- 0.003 03/22/21 0.018 +/- 0.003 0.019 +/- 0.003 0.016 +/- 0.002 0.016 +/- 0.002 0.018 +/- 0.003 0.020 +/- 0.003 0.018 +/- 0.003 0.019 +/- 0.003 03/29/21 0.013 +/- 0.002 0.012 +/- 0.002 0.012 +/- 0.002 0.011 +/- 0.002 0.011 +/- 0.002 0.013 +/- 0.002 0.009 +/- 0.002 0.011 +/- 0.002 04/05/21 0.017 +/- 0.003 0.015 +/- 0.003 0.015 +/- 0.003 0.016 +/- 0.003 0.014 +/- 0.003 0.016 +/- 0.003 0.014 +/- 0.002 0.016 +/- 0.003 04/12/21 0.010 +/- 0.002 0.011 +/- 0.002 0.009 +/- 0.002 0.009 +/- 0.002 0.009 +/- 0.002 0.011 +/- 0.002 0.010 +/- 0.002 0.010 +/- 0.002 04/19/21 0.006 +/- 0.002 0.006 +/- 0.002 0.007 +/- 0.002 0.006 +/- 0.002 0.006 +/- 0.002 0.006 +/- 0.002 0.005 +/- 0.002 0.006 +/- 0.002 04/27/21 0.020 +/- 0.003 0.015 +/- 0.002 0.016 +/- 0.003 0.018 +/- 0.003 0.018 +/- 0.003 0.018 +/- 0.002 0.017 +/- 0.003 0.018 +/- 0.003 05/03/21 0.016 +/- 0.003 0.015 +/- 0.003 0.015 +/- 0.003 0.019 +/- 0.003 0.017 +/- 0.003 0.017 +/- 0.003 0.018 +/- 0.003 0.020 +/- 0.003 05/10/21 0.009 +/- 0.002 0.009 +/- 0.002 0.008 +/- 0.002 0.007 +/- 0.002 0.007 +/- 0.002 0.007 +/- 0.002 0.008 +/- 0.002 0.010 +/- 0.002 05/17/21 0.011 +/- 0.002 0.012 +/- 0.002 0.012 +/- 0.002 0.013 +/- 0.002 0.013 +/- 0.002 0.012 +/- 0.002 0.013 +/- 0.002 0.012 +/- 0.002 05/24/21 0.020 +/- 0.003 0.017 +/- 0.003 0.017 +/- 0.003 0.017 +/- 0.003 0.017 +/- 0.003 0.018 +/- 0.003 0.018 +/- 0.003 0.018 +/- 0.003 06/01/21 0.010 +/- 0.002 0.010 +/- 0.002 0.009 +/- 0.002 0.009 +/- 0.002 0.009 +/- 0.002 0.008 +/- 0.002 0.011 +/- 0.002 0.010 +/- 0.002 06/07/21 0.015 +/- 0.003 0.015 +/- 0.003 0.017 +/- 0.003 0.015 +/- 0.003 0.022 +/- 0.003 0.019 +/- 0.003 0.019 +/- 0.003 0.019 +/- 0.003 06/14/21 0.010 +/- 0.002 0.010 +/- 0.002 0.010 +/- 0.002 0.009 +/- 0.002 0.011 +/- 0.002 0.010 +/- 0.002 0.009 +/- 0.002 0.010 +/- 0.002 06/21/21 0.012 +/- 0.002 0.016 +/- 0.002 0.014 +/- 0.002 0.017 +/- 0.003 0.015 +/- 0.002 0.014 +/- 0.003 0.013 +/- 0.002 0.015 +/- 0.003 06/28/21 0.009 +/- 0.002 0.009 +/- 0.002 0.011 +/- 0.002 0.010 +/- 0.002 0.012 +/- 0.002 0.011 +/- 0.002 0.010 +/- 0.002 0.009 +/- 0.002

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 49 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-6 GROSS BETA ACTIVITY IN AIRBORNE PARTICULATE SAMPLES - 2021 pCi/m3 +/- 2 Sigma PERIOD Algonquin NYU Tower Roseton Croton Point Grassy Point Training Building Met Tower Telcom Bldg.

ENDING 4 5 23* 27 29 94 95 108 07/06/21 0.010 +/- 0.002 0.009 +/- 0.002 0.010 +/- 0.002 0.010 +/- 0.002 0.009 +/- 0.002 0.012 +/- 0.002 0.010 +/- 0.002 0.010 +/- 0.002 07/12/21 0.014 +/- 0.003 0.013 +/- 0.003 0.014 +/- 0.003 0.016 +/- 0.003 0.016 +/- 0.003 0.015 +/- 0.003 0.016 +/- 0.003 0.014 +/- 0.003 07/19/21 0.014 +/- 0.002 0.012 +/- 0.002 0.012 +/- 0.002 0.014 +/- 0.002 0.012 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.003 0.012 +/- 0.002 07/26/21 0.016 +/- 0.002 0.015 +/- 0.002 0.013 +/- 0.002 0.017 +/- 0.003 0.016 +/- 0.002 0.014 +/- 0.002 0.012 +/- 0.002 0.015 +/- 0.002 08/02/21 0.014 +/- 0.003 0.015 +/- 0.003 0.015 +/- 0.003 0.013 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.002 08/09/21 0.018 +/- 0.003 0.019 +/- 0.003 0.021 +/- 0.003 0.019 +/- 0.003 0.016 +/- 0.002 0.017 +/- 0.003 0.017 +/- 0.003 0.019 +/- 0.003 08/16/21 0.016 +/- 0.002 0.011 +/- 0.002 0.013 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.002 0.014 +/- 0.002 0.013 +/- 0.002 0.013 +/- 0.002 08/23/21 0.011 +/- 0.002 0.012 +/- 0.002 0.011 +/- 0.002 0.013 +/- 0.002 0.011 +/- 0.002 0.010 +/- 0.002 0.012 +/- 0.002 0.011 +/- 0.002 08/30/21 0.020 +/- 0.003 0.019 +/- 0.003 0.021 +/- 0.003 0.020 +/- 0.003 0.020 +/- 0.003 0.020 +/- 0.003 0.019 +/- 0.003 0.020 +/- 0.003 09/07/21 0.010 +/- 0.002 0.011 +/- 0.002 0.011 +/- 0.002 0.011 +/- 0.002 0.012 +/- 0.002 0.011 +/- 0.002 0.011 +/- 0.002 0.011 +/- 0.002 09/13/21 0.017 +/- 0.003 0.017 +/- 0.003 0.018 +/- 0.003 0.017 +/- 0.003 0.019 +/- 0.003 0.019 +/- 0.003 0.017 +/- 0.003 0.017 +/- 0.003 09/20/21 0.021 +/- 0.003 0.021 +/- 0.003 0.021 +/- 0.003 0.020 +/- 0.003 0.023 +/- 0.003 0.019 +/- 0.003 0.019 +/- 0.003 0.021 +/- 0.003 09/27/21 0.010 +/- 0.002 0.010 +/- 0.002 0.013 +/- 0.002 0.013 +/- 0.002 0.011 +/- 0.002 0.012 +/- 0.002 0.013 +/- 0.002 0.012 +/- 0.002 10/04/21 0.015 +/- 0.002 0.017 +/- 0.003 0.015 +/- 0.002 0.017 +/- 0.003 0.016 +/- 0.003 0.017 +/- 0.003 0.014 +/- 0.002 0.016 +/- 0.002 10/12/21 0.007 +/- 0.002 0.007 +/- 0.002 0.005 +/- 0.002 0.008 +/- 0.002 0.008 +/- 0.003 0.005 +/- 0.002 0.006 +/- 0.002 0.008 +/- 0.002 10/18/21 0.016 +/- 0.002 0.016 +/- 0.003 0.015 +/- 0.002 0.017 +/- 0.003 0.016 +/- 0.003 0.014 +/- 0.002 0.013 +/- 0.002 0.016 +/- 0.002 10/25/21 0.021 +/- 0.003 0.020 +/- 0.003 0.018 +/- 0.003 0.019 +/- 0.003 0.021 +/- 0.003 0.021 +/- 0.003 0.022 +/- 0.003 0.021 +/- 0.003 11/01/21 0.014 +/- 0.002 0.012 +/- 0.002 0.013 +/- 0.002 0.012 +/- 0.002 0.014 +/- 0.003 0.016 +/- 0.003 0.014 +/- 0.002 0.015 +/- 0.002 11/08/21 0.014 +/- 0.002 0.012 +/- 0.002 0.012 +/- 0.002 0.014 +/- 0.002 0.013 +/- 0.002 0.013 +/- 0.002 0.013 +/- 0.002 0.014 +/- 0.002 11/15/21 0.025 +/- 0.003 0.021 +/- 0.003 0.022 +/- 0.003 0.024 +/- 0.003 0.023 +/- 0.003 0.018 +/- 0.003 0.023 +/- 0.003 0.023 +/- 0.003 11/22/21 0.011 +/- 0.002 0.010 +/- 0.002 0.011 +/- 0.002 0.013 +/- 0.002 0.009 +/- 0.002 0.011 +/- 0.002 0.009 +/- 0.002 0.011 +/- 0.002 11/29/21 0.011 +/- 0.002 0.011 +/- 0.002 0.010 +/- 0.002 0.010 +/- 0.002 0.012 +/- 0.002 0.012 +/- 0.002 0.010 +/- 0.002 0.011 +/- 0.002 12/06/21 0.020 +/- 0.003 0.015 +/- 0.002 0.017 +/- 0.003 0.015 +/- 0.002 0.016 +/- 0.002 0.017 +/- 0.003 0.018 +/- 0.003 0.018 +/- 0.003 12/13/21 0.018 +/- 0.003 0.019 +/- 0.003 0.016 +/- 0.003 0.017 +/- 0.003 0.020 +/- 0.003 0.020 +/- 0.003 0.017 +/- 0.003 0.019 +/- 0.003 12/20/21 0.017 +/- 0.003 0.015 +/- 0.003 0.016 +/- 0.003 0.017 +/- 0.003 0.016 +/- 0.003 0.016 +/- 0.003 0.015 +/- 0.002 0.016 +/- 0.002 12/28/21 0.016 +/- 0.002 0.016 +/- 0.002 0.016 +/- 0.002 0.017 +/- 0.002 0.018 +/- 0.002 0.016 +/- 0.002 0.016 +/- 0.002 0.017 +/- 0.002 01/03/22 0.024 +/- 0.003 0.016 +/- 0.003 0.020 +/- 0.003 0.018 +/- 0.003 0.020 +/- 0.003 0.019 +/- 0.003 0.021 +/- 0.003 0.020 +/- 0.003

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Plant: Indian Point Energy Center Year: 2021 Page 50 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-7 IODINE-131 ACTIVITY IN AIRBORNE CHARCOAL SAMPLES - 2021 pCi/m3 +/- 2 Sigma PERIOD Algonquin NYU Tower Roseton Croton Point Grassy Point Training Building Met Tower Telcom Bldg.

ENDING 4 5 23* 27 29 94 95 108 01/05/21 < 0.038 < 0.040 < 0.035 < 0.039 < 0.036 < 0.037 < 0.042 < 0.040 01/11/21 < 0.034 < 0.035 < 0.018 < 0.035 < 0.022 < 0.033 < 0.024 < 0.025 01/19/21 < 0.015 < 0.016 < 0.016 < 0.015 < 0.017 < 0.015 < 0.018 < 0.018 01/25/21 < 0.023 < 0.024 < 0.021 < 0.023 < 0.022 < 0.021 < 0.024 < 0.021 02/04/21 < 0.028 < 0.028 < 0.019 < 0.038 < 0.015 < 0.036 < 0.024 < 0.014 02/08/21 < 0.030 < 0.030 < 0.030 < 0.021 < 0.042 < 0.020 < 0.033 < 0.043 02/16/21 < 0.031 < 0.031 < 0.029 < 0.031 < 0.031 < 0.029 < 0.032 < 0.030 02/22/21 < 0.020 < 0.018 < 0.008 < 0.020 < 0.019 < 0.018 < 0.020 < 0.019 03/01/21 < 0.025 < 0.024 < 0.015 < 0.023 < 0.019 < 0.024 < 0.020 < 0.019 03/08/21 < 0.021 < 0.022 < 0.027 < 0.021 < 0.027 < 0.021 < 0.029 < 0.027 03/15/21 < 0.026 < 0.026 < 0.024 < 0.027 < 0.025 < 0.025 < 0.026 < 0.025 03/22/21 < 0.019 < 0.020 < 0.021 < 0.020 < 0.022 < 0.008 < 0.022 < 0.021 03/29/21 < 0.016 < 0.017 < 0.016 < 0.017 < 0.016 < 0.015 < 0.015 < 0.016 04/05/21 < 0.037 < 0.038 < 0.049 < 0.037 < 0.051 < 0.039 < 0.049 < 0.052 04/12/21 < 0.022 < 0.023 < 0.019 < 0.022 < 0.019 < 0.021 < 0.018 < 0.019 04/19/21 < 0.018 < 0.018 < 0.018 < 0.018 < 0.019 < 0.008 < 0.017 < 0.018 04/27/21 < 0.016 < 0.016 < 0.017 < 0.016 < 0.016 < 0.015 < 0.014 < 0.017 05/03/21 < 0.029 < 0.029 < 0.019 < 0.029 < 0.018 < 0.028 < 0.022 < 0.020 05/10/21 < 0.021 < 0.022 < 0.021 < 0.021 < 0.010 < 0.021 < 0.022 < 0.020 05/17/21 < 0.036 < 0.036 < 0.022 < 0.036 < 0.021 < 0.034 < 0.023 < 0.021 05/24/21 < 0.015 < 0.016 < 0.014 < 0.016 < 0.016 < 0.016 < 0.016 < 0.016 06/01/21 < 0.022 < 0.024 < 0.032 < 0.025 < 0.035 < 0.024 < 0.036 < 0.034 06/07/21 < 0.023 < 0.011 < 0.031 < 0.026 < 0.030 < 0.026 < 0.026 < 0.030 06/14/21 < 0.027 < 0.025 < 0.017 < 0.027 < 0.017 < 0.027 < 0.017 < 0.018 06/21/21 < 0.029 < 0.028 < 0.024 < 0.029 < 0.024 < 0.029 < 0.024 < 0.026 06/28/21 < 0.020 < 0.020 < 0.030 < 0.020 < 0.030 < 0.021 < 0.031 < 0.030

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Plant: Indian Point Energy Center Year: 2021 Page 51 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-7 IODINE-131 ACTIVITY IN AIRBORNE CHARCOAL SAMPLES - 2021 pCi/m3 +/- 2 Sigma PERIOD Algonquin NYU Tower Roseton Croton Point Grassy Point Training Building Met Tower Telcom Bldg.

ENDING 4 5 23* 27 29 94 95 108 07/06/21 < 0.017 < 0.017 < 0.018 < 0.017 < 0.009 < 0.019 < 0.019 < 0.018 07/12/21 < 0.031 < 0.032 < 0.019 < 0.031 < 0.018 < 0.033 < 0.020 < 0.019 07/19/21 < 0.026 < 0.027 < 0.024 < 0.026 < 0.023 < 0.028 < 0.026 < 0.011 07/26/21 < 0.017 < 0.018 < 0.019 < 0.017 < 0.018 < 0.017 < 0.019 < 0.019 08/02/21 < 0.022 < 0.022 < 0.022 < 0.022 < 0.021 < 0.022 < 0.021 < 0.021 08/09/21 < 0.025 < 0.025 < 0.017 < 0.025 < 0.016 < 0.026 < 0.017 < 0.014 08/16/21 < 0.014 < 0.015 < 0.015 < 0.014 < 0.015 < 0.015 < 0.015 < 0.015 08/23/21 < 0.016 < 0.016 < 0.012 < 0.016 < 0.012 < 0.016 < 0.013 < 0.012 08/30/21 < 0.027 < 0.028 < 0.043 < 0.027 < 0.042 < 0.028 < 0.043 < 0.042 09/07/21 < 0.017 < 0.017 < 0.017 < 0.017 < 0.017 < 0.017 < 0.017 < 0.017 09/13/21 < 0.014 < 0.014 < 0.028 < 0.014 < 0.027 < 0.014 < 0.027 < 0.026 09/20/21 < 0.021 < 0.022 < 0.021 < 0.021 < 0.020 < 0.021 < 0.021 < 0.020 09/27/21 < 0.033 < 0.034 < 0.019 < 0.033 < 0.019 < 0.034 < 0.019 < 0.015 10/04/21 < 0.030 < 0.032 < 0.026 < 0.029 < 0.027 < 0.030 < 0.026 < 0.011 10/12/21 < 0.022 < 0.019 < 0.039 < 0.022 < 0.039 < 0.022 < 0.009 < 0.037 10/18/21 < 0.028 < 0.031 < 0.027 < 0.031 < 0.028 < 0.029 < 0.027 < 0.027 10/25/21 < 0.026 < 0.026 < 0.019 < 0.025 < 0.019 < 0.026 < 0.018 < 0.018 11/01/21 < 0.019 < 0.019 < 0.015 < 0.019 < 0.016 < 0.020 < 0.015 < 0.010 11/08/21 < 0.064 < 0.064 < 0.018 < 0.063 < 0.019 < 0.065 < 0.018 < 0.008 11/15/21 < 0.024 < 0.024 < 0.021 < 0.023 < 0.022 < 0.025 < 0.020 < 0.009 11/22/21 < 0.017 < 0.017 < 0.020 < 0.016 < 0.020 < 0.018 < 0.020 < 0.020 11/29/21 < 0.025 < 0.025 < 0.018 < 0.025 < 0.018 < 0.025 < 0.018 < 0.018 12/06/21 < 0.021 < 0.021 < 0.021 < 0.021 < 0.021 < 0.023 < 0.021 < 0.021 12/13/21 < 0.014 < 0.014 < 0.013 < 0.013 < 0.013 < 0.015 < 0.013 < 0.013 12/20/21 < 0.018 < 0.018 < 0.017 < 0.018 < 0.018 < 0.019 < 0.017 < 0.017 12/28/21 < 0.019 < 0.019 < 0.017 < 0.019 < 0.017 < 0.021 < 0.017 < 0.016 01/03/22 < 0.047 < 0.048 < 0.029 < 0.046 < 0.029 < 0.046 < 0.031 < 0.024

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Plant: Indian Point Energy Center Year: 2021 Page 52 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-8 GAMMA EMITTERS IN AIRBORNE PARTICULATE SAMPLES - 2021

-3 3 10 pCi/m +/- 2 Sigma Algonquin NYU Tower 4 5 DATE 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Be-7 110 +/- 21 133 +/- 27 85 +/- 28 85 +/- 19 122 +/- 23 121 +/- 21 94 +/- 19 91 +/- 19 K-40 < 19 < 27 < 22 < 13 < 24 < 16 < 15 < 15 Mn-54 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 Co-58 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2 Fe-59 < 5 < 7 < 6 < 6 < 4 < 4 < 5 < 4 Co-60 < 1 < 2 < 1 < 1 < 1 < 1 < 1 < 1 Zn-65 < 2 < 3 < 4 < 3 < 4 < 2 < 3 < 3 Nb-95 < 2 < 3 < 3 < 2 < 2 < 1 < 2 < 1 Zr-95 < 3 < 4 < 5 < 3 < 4 < 4 < 4 < 3 Ru-103 < 2 < 3 < 4 < 2 < 3 < 2 < 3 < 2 Ru-106 < 9 < 16 < 11 < 9 < 13 < 9 < 9 < 9 I-131 < 118 < 222 < 410 < 386 < 184 < 149 < 302 < 405 Cs-134 < 1 < 2 < 1 < 1 < 1 < 1 < 1 < 1 Cs-137 < 1 < 2 < 1 < 1 < 1 < 1 < 1 < 1 Ba-140 < 71 < 138 < 147 < 152 < 113 < 61 < 131 < 109 La-140 < 2 < 65 < 54 < 70 < 33 < 18 < 50 < 39 Ce-141 < 4 < 5 < 6 < 4 < 5 < 3 < 4 < 4 Ce-144 < 5 < 7 < 6 < 5 < 7 < 4 < 5 < 4 Ra-226 < 17 < 22 < 20 < 15 < 22 < 15 < 17 < 14 Ac-228 < 4 < 6 < 5 < 4 < 4 < 4 < 4 < 4 Th-228 < 2 < 2 < 2 < 1 < 2 < 1 < 1 < 1

Plant: Indian Point Energy Center Year: 2021 Page 53 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-8 GAMMA EMITTERS IN AIRBORNE PARTICULATE SAMPLES - 2021

-3 3 10 pCi/m +/- 2 Sigma Roseton Croton Point 23* 27 DATE 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Be-7 79 +/- 24 124 +/- 21 100 +/- 23 78 +/- 24 121 +/- 20 137 +/- 25 105 +/- 22 101 +/- 22 K-40 < 26 < 16 < 17 < 25 < 19 < 21 < 18 < 19 Mn-54 < 2 < 0 < 1 < 2 < 1 < 2 < 1 < 1 Co-58 < 2 < 1 < 2 < 3 < 2 < 2 < 2 < 2 Fe-59 < 7 < 3 < 6 < 8 < 5 < 6 < 5 < 5 Co-60 < 1 < 1 < 1 < 2 < 1 < 2 < 1 < 1 Zn-65 < 5 < 2 < 2 < 3 < 3 < 3 < 3 < 3 Nb-95 < 2 < 1 < 2 < 3 < 2 < 2 < 2 < 2 Zr-95 < 4 < 2 < 4 < 6 < 4 < 4 < 4 < 4 Ru-103 < 3 < 1 < 2 < 4 < 2 < 3 < 3 < 3 Ru-106 < 13 < 8 < 8 < 14 < 8 < 9 < 10 < 10 I-131 < 195 < 83 < 266 < 534 < 117 < 218 < 326 < 465 Cs-134 < 2 < 1 < 1 < 2 < 1 < 1 < 1 < 2 Cs-137 < 2 < 1 < 1 < 2 < 1 < 1 < 1 < 1 Ba-140 < 120 < 47 < 102 < 233 < 56 < 102 < 117 < 181 La-140 < 61 < 27 < 27 < 101 < 41 < 46 < 39 < 57 Ce-141 < 5 < 3 < 4 < 6 < 3 < 4 < 4 < 5 Ce-144 < 7 < 3 < 4 < 7 < 5 < 6 < 5 < 6 Ra-226 < 23 < 14 < 14 < 26 < 17 < 20 < 17 < 19 Ac-228 < 6 < 4 < 4 < 7 < 4 < 5 < 4 < 5 Th-228 < 2 < 1 < 1 < 2 < 1 < 2 < 1 < 2

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Plant: Indian Point Energy Center Year: 2021 Page 54 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-8 GAMMA EMITTERS IN AIRBORNE PARTICULATE SAMPLES - 2021

-3 3 10 pCi/m +/- 2 Sigma Grassy Point Training Building 29 94 DATE 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Be-7 117 +/- 21 135 +/- 23 120 +/- 23 94 +/- 22 131 +/- 25 130 +/- 22 100 +/- 28 107 +/- 23 K-40 < 22 < 21 < 24 < 26 < 30 < 13 < 27 < 26 Mn-54 < 1 < 1 < 1 < 2 < 2 < 1 < 2 < 2 Co-58 < 2 < 2 < 2 < 2 < 2 < 1 < 3 < 2 Fe-59 < 5 < 4 < 8 < 7 < 5 < 5 < 8 < 8 Co-60 < 2 < 1 < 1 < 1 < 1 < 1 < 2 < 1 Zn-65 < 3 < 2 < 3 < 3 < 4 < 2 < 4 < 4 Nb-95 < 2 < 2 < 2 < 3 < 3 < 1 < 3 < 3 Zr-95 < 4 < 3 < 4 < 4 < 5 < 3 < 4 < 5 Ru-103 < 2 < 3 < 4 < 3 < 4 < 2 < 5 < 5 Ru-106 < 12 < 11 < 14 < 12 < 11 < 8 < 17 < 13 I-131 < 120 < 147 < 378 < 686 < 200 < 138 < 491 < 626 Cs-134 < 1 < 1 < 1 < 1 < 2 < 1 < 2 < 2 Cs-137 < 1 < 1 < 1 < 1 < 1 < 1 < 1 < 1 Ba-140 < 86 < 77 < 170 < 224 < 114 < 56 < 207 < 198 La-140 < 27 < 25 < 58 < 84 < 48 < 25 < 66 < 92 Ce-141 < 3 < 3 < 5 < 5 < 5 < 3 < 6 < 6 Ce-144 < 5 < 4 < 6 < 6 < 7 < 4 < 8 < 8 Ra-226 < 16 < 16 < 18 < 19 < 24 < 15 < 26 < 22 Ac-228 < 5 < 4 < 4 < 5 < 6 < 3 < 7 < 6 Th-228 < 2 < 2 < 2 < 2 < 2 < 2 < 2 < 2

Plant: Indian Point Energy Center Year: 2021 Page 55 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-8 GAMMA EMITTERS IN AIRBORNE PARTICULATE SAMPLES - 2021

-3 3 10 pCi/m +/- 2 Sigma Met Tower Telecomm Bldg 95 108 DATE 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter 1st Quarter 2nd Quarter 3rd Quarter 4th Quarter Be-7 98 +/- 20 152 +/- 23 121 +/- 19 92 +/- 19 102 +/- 20 124 +/- 29 135 +/- 23 101 +/- 17 K-40 < 22 < 16 < 10 < 17 < 25 < 32 < 29 < 17 Mn-54 < 1 < 1 < 1 < 1 < 1 < 2 < 2 < 1 Co-58 < 2 < 2 < 1 < 2 < 2 < 3 < 3 < 1 Fe-59 < 5 < 6 < 5 < 5 < 6 < 4 < 10 < 6 Co-60 < 1 < 1 < 1 < 1 < 2 < 2 < 2 < 1 Zn-65 < 3 < 3 < 2 < 3 < 3 < 3 < 5 < 2 Nb-95 < 1 < 2 < 2 < 2 < 2 < 3 < 3 < 2 Zr-95 < 4 < 4 < 3 < 3 < 4 < 5 < 4 < 3 Ru-103 < 2 < 3 < 2 < 2 < 3 < 4 < 5 < 2 Ru-106 < 8 < 11 < 8 < 6 < 13 < 13 < 17 < 8 I-131 < 132 < 220 < 296 < 404 < 179 < 198 < 522 < 406 Cs-134 < 1 < 1 < 1 < 1 < 1 < 1 < 2 < 1 Cs-137 < 1 < 1 < 1 < 1 < 2 < 1 < 2 < 1 Ba-140 < 67 < 100 < 101 < 146 < 98 < 96 < 203 < 128 La-140 < 33 < 52 < 44 < 40 < 29 < 49 < 85 < 45 Ce-141 < 3 < 5 < 4 < 4 < 4 < 6 < 7 < 4 Ce-144 < 4 < 5 < 4 < 4 < 6 < 7 < 7 < 4 Ra-226 < 14 < 21 < 13 < 13 < 21 < 24 < 26 < 16 Ac-228 < 4 < 4 < 2 < 4 < 5 < 5 < 7 < 3 Th-228 < 1 < 2 < 1 < 1 < 2 < 2 < 2 < 1

Plant: Indian Point Energy Center Year: 2021 Page 56 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-9 RADIONUCLIDES IN DRINKING WATER SAMPLES - 2021 pCi/L +/- 2 Sigma Camp Field 7

DATE 01/12/21 02/17/21 03/17/21 04/05/21 5/11/2021 06/07/21 RADIOCHEMICAL Gr-B 3 +/- 1 < 3 < 2 < 2 < 3 < 2 H-3 (a) < 177 < 184 GAMMA Be-7 < 54 < 42 < 60 < 56 < 52 < 49 K-40 < 145 < 75 < 68 < 119 < 110 < 110 Mn-54 < 9 < 4 < 8 < 6 < 6 < 5 Co-58 < 7 < 4 < 7 < 7 < 6 < 6 Fe-59 < 12 < 9 < 15 < 13 < 13 < 12 Co-60 < 7 < 4 < 6 < 9 < 7 < 6 Zn-65 < 14 < 8 < 11 < 14 < 11 < 14 Nb-95 < 8 < 4 < 7 < 6 < 5 < 4 Zr-95 < 13 < 6 < 13 < 15 < 10 < 9 Ru-103 < 7 < 5 < 7 < 7 < 5 < 6 Ru-106 < 59 < 42 < 56 < 48 < 64 < 52 I-131 < 9 < 7 < 9 < 7 < 6 < 8 Cs-134 < 7 < 6 < 9 < 9 < 8 < 7 Cs-137 < 8 < 5 < 7 < 7 < 6 < 6 Ba-140 < 27 < 26 < 32 < 29 < 22 < 20 La-140 < 8 < 9 < 9 < 9 < 11 < 9 Ce-141 < 13 < 7 < 11 < 11 < 11 < 9 Ce-144 < 53 < 30 < 43 < 46 < 43 < 43 Ra-226 < 166 < 110 < 162 < 153 < 182 < 153 Ac-228 < 27 < 17 < 25 < 27 < 30 < 19 Th-228 < 14 < 8 < 11 < 11 < 12 < 10 (a) Quarterly Composite

Plant: Indian Point Energy Center Year: 2021 Page 57 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-9 RADIONUCLIDES IN DRINKING WATER SAMPLES - 2021 pCi/L +/- 2 Sigma Camp Field 7

DATE 07/12/21 08/10/21 09/14/21 10/11/21 11/08/21 12/14/21 RADIOCHEMICAL Gr-B 2 +/- 2 < 3 < 2 < 2 3 +/- 2 3 +/- 2 H-3 (a) < 187 < 187 GAMMA Be-7 < 46 < 39 < 44 < 33 < 46 < 30 K-40 < 101 < 79 < 142 < 74 < 93 < 73 Mn-54 < 7 < 4 < 5 < 3 < 5 < 4 Co-58 < 7 < 3 < 5 < 4 < 4 < 4 Fe-59 < 12 < 8 < 13 < 8 < 10 < 7 Co-60 < 7 < 5 < 7 < 5 < 5 < 4 Zn-65 < 13 < 9 < 15 < 11 < 13 < 9 Nb-95 < 5 < 4 < 5 < 4 < 5 < 4 Zr-95 < 12 < 9 < 12 < 7 < 10 < 7 Ru-103 < 6 < 5 < 6 < 4 < 5 < 4 Ru-106 < 68 < 40 < 56 < 32 < 52 < 35 I-131 < 7 < 5 < 7 < 5 < 6 < 4 Cs-134 < 8 < 5 < 7 < 5 < 6 < 4 Cs-137 < 7 < 5 < 7 < 5 < 4 < 4 Ba-140 < 23 < 16 < 22 < 15 < 26 < 16 La-140 < 9 < 7 < 8 < 7 < 7 < 5 Ce-141 < 9 < 7 < 9 < 7 < 10 < 6 Ce-144 < 40 < 29 < 41 < 28 < 42 < 23 Ra-226 < 167 < 114 < 142 < 108 < 139 < 100 Ac-228 < 30 < 19 < 29 < 17 < 21 < 16 Th-228 < 12 < 12 < 12 < 8 < 10 < 7 (a) Quarterly Composite

Plant: Indian Point Energy Center Year: 2021 Page 58 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-9 RADIONUCLIDES IN DRINKING WATER SAMPLES - 2021 pCi/L +/- 2 Sigma Croton 8

DATE 01/12/21 02/17/21 03/17/21 04/05/21 05/11/21 06/07/21 RADIOCHEMICAL Gr-B 3 +/- 1 < 2 < 2 5 +/- 2 < 3 < 2 H-3 (a) < 182 GAMMA Be-7 < 46 < 39 < 54 < 57 < 48 < 38 K-40 < 133 < 93 < 101 < 104 < 120 < 83 Mn-54 < 6 < 5 < 8 < 7 < 5 < 5 Co-58 < 8 < 5 < 7 < 7 < 5 < 5 Fe-59 < 14 < 9 < 15 < 9 < 12 < 10 Co-60 < 6 < 5 < 8 < 6 < 5 < 7 Zn-65 < 12 < 12 < 11 < 10 < 12 < 10 Nb-95 < 8 < 5 < 7 < 7 < 6 < 5 Zr-95 < 9 < 9 < 13 < 12 < 12 < 7 Ru-103 < 7 < 6 < 5 < 6 < 5 < 5 Ru-106 < 67 < 46 < 49 < 61 < 53 < 38 I-131 < 8 < 9 < 9 < 8 < 6 < 5 Cs-134 < 8 < 5 < 7 < 7 < 7 < 5 Cs-137 < 8 < 5 < 7 < 6 < 6 < 6 Ba-140 < 19 < 21 < 27 < 26 < 20 < 14 La-140 < 6 < 8 < 7 < 5 < 9 < 8 Ce-141 < 9 < 7 < 12 < 9 < 11 < 8 Ce-144 < 47 < 30 < 40 < 41 < 49 < 27 Ra-226 < 160 < 105 < 159 < 148 < 160 < 117 Ac-228 < 31 < 18 < 23 < 25 < 28 < 18 Th-228 < 12 < 8 < 13 < 10 < 13 < 8 (a) Quarterly Composite

Plant: Indian Point Energy Center Year: 2021 Page 59 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-9 RADIONUCLIDES IN DRINKING WATER SAMPLES - 2021 pCi/L +/- 2 Sigma Croton 8

DATE 07/12/21 08/10/21 09/14/21 10/11/21 11/08/21 12/14/21 RADIOCHEMICAL Gr-B 3 +/- 2 < 2 < 2 < 2 3 +/- 1 4 +/- 2 H-3 (a) < 183 < 193 GAMMA Be-7 < 51 < 48 < 59 < 31 < 33 < 43 K-40 < 136 < 87 < 132 < 64 < 67 < 101 Mn-54 < 6 < 4 < 7 < 4 < 4 < 4 Co-58 < 6 < 5 < 6 < 3 < 4 < 5 Fe-59 < 14 < 10 < 14 < 7 < 8 < 10 Co-60 < 6 < 6 < 8 < 4 < 4 < 4 Zn-65 < 13 < 12 < 8 < 7 < 9 < 11 Nb-95 < 6 < 6 < 7 < 4 < 4 < 5 Zr-95 < 7 < 9 < 11 < 6 < 7 < 7 Ru-103 < 5 < 6 < 6 < 3 < 4 < 5 Ru-106 < 55 < 56 < 63 < 33 < 47 < 43 I-131 < 7 < 7 < 7 < 4 < 5 < 6 Cs-134 < 6 < 5 < 5 < 4 < 5 < 5 Cs-137 < 6 < 7 < 5 < 4 < 5 < 5 Ba-140 < 22 < 15 < 22 < 14 < 18 < 20 La-140 < 9 < 5 < 8 < 5 < 5 < 6 Ce-141 < 9 < 10 < 10 < 7 < 7 < 8 Ce-144 < 43 < 45 < 45 < 27 < 28 < 36 Ra-226 < 160 < 155 < 164 < 103 < 99 < 129 Ac-228 < 35 < 23 < 22 < 14 < 15 < 17 Th-228 < 13 < 10 < 11 < 7 < 7 < 9 (a) Quarterly Composite

Plant: Indian Point Energy Center Year: 2021 Page 60 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-10 GAMMA EMITTERS IN SOIL SAMPLES - 2021 pCi/kg dry +/- 2 Sigma Roseton Training Building Met Tower 23* 94 95 DATE 09/13/21 09/13/21 09/13/21 Be-7 < 793 < 739 < 613 K-40 14750 +/- 1948 11970 +/- 1713 8669 +/- 1253 Mn-54 < 87 < 79 < 66 Co-58 < 84 < 80 < 55 Fe-59 < 151 < 149 < 129 Co-60 < 92 < 84 < 60 Zn-65 < 198 < 178 < 153 Nb-95 < 97 < 78 < 56 Zr-95 < 151 < 136 < 97 Ru-103 < 81 < 62 < 49 Ru-106 < 866 < 603 < 572 I-131 < 96 < 79 < 69 Cs-134 < 96 < 102 < 67 Cs-137 < 103 < 94 < 70 Ba-140 < 317 < 292 < 257 La-140 < 127 < 122 < 67 Ce-141 < 110 < 85 < 90 Ce-144 < 434 < 316 < 361 Ra-226 < 1944 < 1684 < 1263 Th-228 715 +/- 189 589 +/- 116 < 103

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Plant: Indian Point Energy Center Year: 2021 Page 61 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Roseton 23*

DATE 05/17/21 05/17/21 05/17/21 06/21/21 06/21/21 06/21/21 GAMMA Be-7 1152 +/- 258 < 322 1052 +/- 274 2324 +/- 419 1009 +/- 305 1640 +/- 272 K-40 7444 +/- 760 3426 +/- 606 4446 +/- 618 5838 +/- 823 5048 +/- 660 4256 +/- 506 Mn-54 < 29 < 27 < 23 < 35 < 26 < 18 Co-58 < 26 < 19 < 19 < 31 < 22 < 14 Fe-59 < 59 < 50 < 54 < 59 < 51 < 36 Co-60 < 28 < 30 < 26 < 36 < 30 < 22 Zn-65 < 72 < 63 < 65 < 79 < 60 < 54 Nb-95 < 25 < 33 < 24 < 30 < 25 < 16 Zr-95 < 51 < 42 < 43 < 49 < 44 < 35 Ru-103 < 23 < 25 < 26 < 29 < 22 < 19 Ru-106 < 230 < 236 < 193 < 318 < 197 < 179 I-131 < 31 < 30 < 31 < 30 < 29 < 19 Cs-134 < 33 < 26 < 27 < 37 < 32 < 24 Cs-137 < 26 < 26 < 29 < 30 < 25 < 22 Ba-140 < 79 < 95 < 90 < 122 < 108 < 80 La-140 < 31 < 7 < 28 < 31 < 34 < 13 Ce-141 < 42 < 34 < 39 < 33 < 38 < 27 Ce-144 < 191 < 131 < 177 < 153 < 158 < 109 Ra-226 < 694 < 440 < 654 < 685 < 655 < 473 Th-228 < 53 < 42 < 53 < 50 < 48 < 37

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 62 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Roseton 23*

DATE 07/19/21 07/19/21 07/19/21 08/16/21 08/16/21 08/16/21 GAMMA Be-7 2857 +/- 346 4521 +/- 444 1119 +/- 339 1989 +/- 321 1154 +/- 309 4092 +/- 362 K-40 5559 +/- 617 4640 +/- 674 4731 +/- 748 4817 +/- 577 5655 +/- 700 4470 +/- 565 Mn-54 < 20 < 27 < 29 < 22 < 26 < 24 Co-58 < 25 < 19 < 29 < 22 < 26 < 21 Fe-59 < 54 < 48 < 65 < 49 < 51 < 60 Co-60 < 26 < 25 < 33 < 30 < 28 < 29 Zn-65 < 67 < 57 < 61 < 61 < 63 < 60 Nb-95 < 21 < 24 < 27 < 24 < 31 < 25 Zr-95 < 44 < 48 < 47 < 40 < 48 < 32 Ru-103 < 26 < 27 < 21 < 19 < 22 < 23 Ru-106 < 217 < 261 < 257 < 196 < 254 < 250 I-131 < 33 < 33 < 36 < 28 < 33 < 25 Cs-134 < 27 < 26 < 30 < 26 < 34 < 26 Cs-137 < 25 < 32 < 29 < 25 < 34 < 22 Ba-140 < 92 < 112 < 98 < 84 < 110 < 97 La-140 < 14 < 30 < 35 < 23 < 25 < 33 Ce-141 < 40 < 48 < 33 < 32 < 39 < 36 Ce-144 < 158 < 191 < 143 < 127 < 183 < 138 Ra-226 < 640 < 689 < 574 < 538 < 761 < 565 Th-228 < 50 < 53 < 39 < 59 < 55 < 53

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 63 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Roseton 23*

DATE 09/20/21 09/20/21 09/20/21 10/18/21 10/18/21 10/18/21 GAMMA Be-7 2068 +/- 454 3834 +/- 545 5319 +/- 497 3146 +/- 399 1632 +/- 282 3355 +/- 358 K-40 4042 +/- 654 2925 +/- 640 4307 +/- 686 2381 +/- 570 4113 +/- 562 5372 +/- 644 Mn-54 < 26 < 37 < 28 < 23 < 24 < 20 Co-58 < 27 < 34 < 28 < 29 < 27 < 17 Fe-59 < 55 < 65 < 58 < 52 < 55 < 52 Co-60 < 33 < 33 < 21 < 33 < 27 < 29 Zn-65 < 51 < 49 < 51 < 62 < 49 < 48 Nb-95 < 30 < 31 < 25 < 31 < 19 < 19 Zr-95 < 45 < 71 < 46 < 39 < 37 < 30 Ru-103 < 31 < 31 < 29 < 28 < 19 < 21 Ru-106 < 235 < 252 < 214 < 303 < 208 < 197 I-131 < 36 < 36 < 37 < 38 < 26 < 30 Cs-134 < 32 < 37 < 24 < 30 < 27 < 22 Cs-137 < 26 < 38 < 31 < 31 < 25 < 20 Ba-140 < 114 < 126 < 87 < 123 < 92 < 82 La-140 < 30 < 37 < 33 < 38 < 30 < 17 Ce-141 < 44 < 45 < 47 < 42 < 36 < 38 Ce-144 < 195 < 180 < 198 < 185 < 176 < 157 Ra-226 < 698 < 877 < 687 < 688 < 583 < 536 Th-228 < 54 < 64 < 60 < 52 < 45 < 43

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 64 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Training Center 94 DATE 05/18/21 05/18/21 05/18/21 06/22/21 06/22/21 06/22/21 GAMMA Be-7 886 +/- 245 1076 +/- 279 758 +/- 328 1574 +/- 208 779 +/- 232 763 +/- 244 K-40 5587 +/- 586 2858 +/- 519 4094 +/- 564 6101 +/- 506 3136 +/- 440 2224 +/- 467 Mn-54 < 27 < 20 < 26 < 19 < 23 < 25 Co-58 < 23 < 18 < 27 < 21 < 19 < 26 Fe-59 < 46 < 56 < 59 < 44 < 38 < 44 Co-60 < 33 < 27 < 17 < 23 < 19 < 24 Zn-65 < 54 < 59 < 54 < 52 < 35 < 45 Nb-95 < 25 < 21 < 25 < 20 < 20 < 25 Zr-95 < 38 < 34 < 44 < 38 < 30 < 33 Ru-103 < 24 < 20 < 25 < 18 < 23 < 23 Ru-106 < 183 < 201 < 217 < 151 < 193 < 191 I-131 < 26 < 29 < 26 < 21 < 26 < 26 Cs-134 < 30 < 30 < 25 < 22 < 24 < 26 Cs-137 < 22 < 24 < 23 < 21 < 19 < 22 Ba-140 < 67 < 78 < 94 < 67 < 85 < 95 La-140 < 20 < 28 < 24 < 18 < 26 < 24 Ce-141 < 36 < 35 < 33 < 26 < 29 < 35 Ce-144 < 138 < 153 < 150 < 103 < 115 < 142 Ra-226 < 571 < 587 < 512 < 432 < 500 < 548 Th-228 < 39 < 50 < 46 < 40 < 37 < 54

Plant: Indian Point Energy Center Year: 2021 Page 65 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Training Center 94 DATE 07/20/21 07/20/21 07/20/21 08/17/21 08/17/21 08/17/21 GAMMA Be-7 1358 +/- 280 3719 +/- 431 1498 +/- 284 2056 +/- 339 1549 +/- 384 2668 +/- 391 K-40 3114 +/- 547 2758 +/- 447 2872 +/- 423 3121 +/- 637 3473 +/- 568 5876 +/- 732 Mn-54 < 26 < 26 < 23 < 22 < 25 < 29 Co-58 < 18 < 22 < 22 < 26 < 28 < 24 Fe-59 < 51 < 34 < 48 < 56 < 60 < 45 Co-60 < 21 < 21 < 30 < 33 < 25 < 21 Zn-65 < 48 < 51 < 55 < 51 < 58 < 54 Nb-95 < 27 < 25 < 26 < 24 < 25 < 25 Zr-95 < 43 < 42 < 39 < 48 < 36 < 42 Ru-103 < 23 < 24 < 20 < 27 < 22 < 24 Ru-106 < 185 < 204 < 214 < 257 < 265 < 231 I-131 < 26 < 28 < 26 < 29 < 28 < 29 Cs-134 < 28 < 17 < 27 < 30 < 33 < 29 Cs-137 < 23 < 26 < 26 < 29 < 30 < 32 Ba-140 < 94 < 88 < 81 < 121 < 102 < 104 La-140 < 17 < 23 < 31 < 24 < 36 < 28 Ce-141 < 33 < 37 < 35 < 38 < 39 < 44 Ce-144 < 142 < 168 < 136 < 155 < 179 < 198 Ra-226 < 537 < 627 < 558 < 745 < 678 < 692 Th-228 < 46 < 49 < 42 < 68 < 66 99 +/- 46

Plant: Indian Point Energy Center Year: 2021 Page 66 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Training Center 94 DATE 09/21/21 09/21/21 09/21/21 10/19/21 10/19/21 10/19/21 GAMMA Be-7 1472 +/- 356 2908 +/- 543 4129 +/- 541 2315 +/- 302 1597 +/- 370 5935 +/- 537 K-40 3048 +/- 710 4275 +/- 716 5496 +/- 816 5134 +/- 604 2959 +/- 551 5677 +/- 764 Mn-54 < 37 < 48 < 34 < 31 < 31 < 28 Co-58 < 26 < 42 < 26 < 23 < 31 < 28 Fe-59 < 53 < 86 < 75 < 60 < 52 < 61 Co-60 < 42 < 43 < 44 < 27 < 32 < 40 Zn-65 < 75 < 75 < 81 < 56 < 64 < 62 Nb-95 < 27 < 35 < 30 < 21 < 33 < 20 Zr-95 < 48 < 67 < 62 < 44 < 55 < 51 Ru-103 < 28 < 35 < 33 < 24 < 30 < 25 Ru-106 < 295 < 324 < 260 < 252 < 227 < 255 I-131 < 35 < 41 < 41 < 30 < 39 < 27 Cs-134 < 45 < 52 < 41 < 25 < 33 < 24 Cs-137 < 40 < 38 < 36 < 27 < 29 < 25 Ba-140 < 112 < 167 < 137 < 87 < 95 < 107 La-140 < 50 < 49 < 30 < 23 < 33 < 32 Ce-141 < 43 < 53 < 53 < 40 < 40 < 43 Ce-144 < 184 < 235 < 236 < 168 < 210 < 175 Ra-226 < 726 < 957 < 802 < 649 < 686 < 650 Th-228 < 68 < 77 < 73 < 52 < 63 < 52

Plant: Indian Point Energy Center Year: 2021 Page 67 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Met Tower 95 DATE 05/18/21 05/18/21 05/18/21 06/22/21 06/22/21 06/22/21 GAMMA Be-7 1153 +/- 204 764 +/- 252 892 +/- 225 1107 +/- 230 868 +/- 198 1331 +/- 264 K-40 3620 +/- 451 6815 +/- 859 6840 +/- 640 6201 +/- 597 3633 +/- 439 3843 +/- 586 Mn-54 < 18 < 29 < 22 < 23 < 19 < 21 Co-58 < 19 < 24 < 21 < 25 < 18 < 20 Fe-59 < 32 < 56 < 49 < 50 < 37 < 38 Co-60 < 21 < 25 < 25 < 23 < 22 < 25 Zn-65 < 41 < 58 < 51 < 54 < 47 < 40 Nb-95 < 19 < 28 < 17 < 28 < 18 < 22 Zr-95 < 33 < 45 < 30 < 42 < 32 < 41 Ru-103 < 14 < 25 < 23 < 26 < 20 < 20 Ru-106 < 197 < 190 < 180 < 198 < 164 < 204 I-131 < 20 < 25 < 24 < 25 < 21 < 16 Cs-134 < 15 < 30 < 26 < 26 < 22 < 22 Cs-137 < 17 < 26 < 25 < 26 < 21 < 19 Ba-140 < 68 < 94 < 82 < 96 < 67 < 73 La-140 < 16 < 23 < 19 < 21 < 21 < 19 Ce-141 < 26 < 34 < 31 < 33 < 29 < 27 Ce-144 < 101 < 134 < 143 < 152 < 132 < 112 Ra-226 < 420 < 507 < 479 < 550 < 496 < 470 Th-228 < 30 < 43 < 45 < 46 < 40 < 38

Plant: Indian Point Energy Center Year: 2021 Page 68 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Met Tower 95 DATE 07/19/21 07/19/21 07/19/21 08/17/21 08/17/21 08/17/21 GAMMA Be-7 4524 +/- 382 1306 +/- 321 2884 +/- 396 2376 +/- 319 1987 +/- 424 1460 +/- 341 K-40 6970 +/- 649 6118 +/- 781 3285 +/- 549 6274 +/- 769 6249 +/- 804 4640 +/- 846 Mn-54 < 21 < 23 < 27 < 34 < 33 < 33 Co-58 < 19 < 26 < 25 < 21 < 32 < 33 Fe-59 < 47 < 53 < 49 < 41 < 63 < 74 Co-60 < 27 < 24 < 24 < 33 < 39 < 46 Zn-65 < 48 < 72 < 64 < 64 < 54 < 64 Nb-95 < 20 < 26 < 28 < 28 < 34 < 30 Zr-95 < 34 < 50 < 43 < 39 < 53 < 51 Ru-103 < 22 < 26 < 25 < 23 < 28 < 34 Ru-106 < 222 < 254 < 257 < 233 < 311 < 253 I-131 < 27 < 32 < 35 < 33 < 31 < 31 Cs-134 < 28 < 26 < 29 < 28 < 36 < 38 Cs-137 < 25 < 30 < 30 < 30 < 35 < 37 Ba-140 < 89 < 96 < 115 < 74 < 110 < 87 La-140 < 19 < 37 < 31 < 27 < 36 < 27 Ce-141 < 28 < 40 < 42 < 31 < 47 < 40 Ce-144 < 131 < 172 < 166 < 142 < 189 < 165 Ra-226 < 524 < 614 < 649 < 605 < 614 < 665 Th-228 < 37 < 49 < 51 < 39 < 70 114 +/- 66

Plant: Indian Point Energy Center Year: 2021 Page 69 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-11 GAMMA EMITTERS IN BROAD LEAF VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Met Tower 95 DATE 09/20/21 09/20/21 09/20/21 10/19/21 10/19/21 10/19/21 GAMMA Be-7 4266 +/- 568 3871 +/- 565 4224 +/- 600 964 +/- 239 3496 +/- 269 2277 +/- 354 K-40 10050 +/- 993 6231 +/- 854 3565 +/- 720 4309 +/- 544 6634 +/- 488 6209 +/- 773 Mn-54 < 32 < 37 < 34 < 22 < 16 < 32 Co-58 < 39 < 41 < 40 < 18 < 19 < 30 Fe-59 < 87 < 62 < 95 < 42 < 40 < 66 Co-60 < 44 < 48 < 44 < 19 < 20 < 36 Zn-65 < 92 < 84 < 88 < 47 < 43 < 74 Nb-95 < 39 < 34 < 44 < 22 < 18 < 25 Zr-95 < 75 < 73 < 71 < 36 < 32 < 54 Ru-103 < 41 < 33 < 35 < 18 < 17 < 32 Ru-106 < 347 < 358 < 391 < 185 < 172 < 236 I-131 < 47 < 36 < 51 < 25 < 22 < 33 Cs-134 < 41 < 47 < 37 < 24 < 21 < 35 Cs-137 < 43 < 41 < 33 < 22 < 18 < 29 Ba-140 < 150 < 127 < 145 < 83 < 74 < 100 La-140 < 29 < 37 < 39 < 20 < 19 < 34 Ce-141 < 64 < 52 < 66 < 29 < 29 < 39 Ce-144 < 251 < 192 < 279 < 136 < 127 < 184 Ra-226 < 1040 < 826 < 1093 < 495 < 475 < 689 Th-228 169 +/- 69 < 62 < 76 < 43 < 38 < 61

Plant: Indian Point Energy Center Year: 2021 Page 70 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-12 RADIONUCLIDES IN RIVER WATER SAMPLES - 2021 pCi/L +/- 2 Sigma Discharge Canal 10 DATE 01/26/21 02/23/21 03/30/21 04/27/21 06/02/21 07/07/21 RADIOCHEMICAL H-3 (a) 483 +/- 128 214 +/- 122 GAMMA K-40 < 23 < 24 < 38 < 60 < 27 27 +/- 16 Mn-54 < 1 < 2 < 2 < 5 < 1 < 1 Co-58 < 2 < 3 < 2 < 4 < 2 < 1 Fe-59 < 3 < 6 < 5 < 10 < 4 < 3 Co-60 < 2 < 3 < 2 < 4 < 2 < 1 Zn-65 < 3 < 6 < 4 < 8 < 4 < 2 Nb-95 < 2 < 2 < 2 < 4 < 2 < 1 Zr-95 < 3 < 5 < 4 < 7 < 4 < 2 Ru-103 < 2 < 3 < 3 < 5 < 2 < 2 Ru-106 < 13 < 22 < 18 < 39 < 15 < 12 I-131 < 5 < 9 < 11 < 15 < 11 < 6 Cs-134 < 2 < 3 < 2 < 5 < 2 < 1 Cs-137 < 2 < 3 < 2 < 4 < 2 < 1 Ba-140 < 11 < 21 < 19 < 32 < 19 < 12 La-140 < 4 < 7 < 7 < 12 < 7 < 4 Ce-141 < 3 < 5 < 5 < 10 < 4 < 3 Ce-144 < 11 < 16 < 16 < 31 < 11 < 9 Ra-226 < 32 < 56 < 52 < 109 < 39 < 26 Ac-228 < 6 < 9 < 8 < 16 < 6 < 4 Th-228 < 3 < 4 < 4 < 8 < 3 < 3 (a) Quarterly Composite

Plant: Indian Point Energy Center Year: 2021 Page 71 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-12 RADIONUCLIDES IN RIVER WATER SAMPLES - 2021 pCi/L +/- 2 Sigma Discharge Canal 10 DATE 08/03/21 08/31/21 09/28/21 10/26/21 11/30/21 12/29/21 RADIOCHEMICAL H-3 (a) 442 +/- 129 < 170 GAMMA K-40 < 21 < 30 < 27 < 90 < 15 < 15 Mn-54 < 1 < 2 < 2 < 4 < 1 < 1 Co-58 < 1 < 2 < 2 < 5 < 2 < 2 Fe-59 < 3 < 4 < 4 < 12 < 4 < 4 Co-60 < 1 < 2 < 2 < 5 < 2 < 1 Zn-65 < 3 < 3 < 4 < 10 < 3 < 3 Nb-95 < 2 < 2 < 2 < 5 < 2 < 2 Zr-95 < 3 < 3 < 3 < 9 < 3 < 3 Ru-103 < 2 < 2 < 2 < 5 < 2 < 2 Ru-106 < 13 < 15 < 16 < 38 < 15 < 14 I-131 < 5 < 7 < 6 < 15 < 8 < 8 Cs-134 < 2 < 2 < 2 < 4 < 2 < 2 Cs-137 < 1 < 2 < 2 < 4 < 2 < 2 Ba-140 < 10 < 14 < 14 < 36 < 15 < 15 La-140 < 4 < 4 < 4 < 13 < 5 < 5 Ce-141 < 3 < 4 < 4 < 9 < 4 < 4 Ce-144 < 9 < 12 < 12 < 31 < 11 < 11 Ra-226 < 28 < 41 < 39 < 111 < 33 < 40 Ac-228 < 5 < 7 < 7 < 18 < 6 < 5 Th-228 < 2 < 3 10 +/- 3 < 8 < 3 < 3 (a) Quarterly Composite

Plant: Indian Point Energy Center Year: 2021 Page 72 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-12 RADIONUCLIDES IN RIVER WATER SAMPLES - 2021 pCi/L +/- 2 Sigma Roseton 23*

DATE 01/25/21 02/22/21 03/29/21 04/26/21 06/01/21 07/06/21 RADIOCHEMICAL H-3 (a) < 175 < 180 GAMMA K-40 < 16 < 35 < 14 < 46 < 15 < 15 Mn-54 < 1 < 2 < 2 < 3 < 2 < 2 Co-58 < 1 < 2 < 2 < 3 < 2 < 2 Fe-59 < 3 < 5 < 4 < 8 < 5 < 4 Co-60 < 1 < 2 < 2 < 3 < 2 < 2 Zn-65 < 2 < 5 < 3 < 6 < 3 < 3 Nb-95 < 1 < 3 < 2 < 3 < 2 < 2 Zr-95 < 2 < 4 < 3 < 7 < 3 < 3 Ru-103 < 1 < 3 < 2 < 4 < 2 < 2 Ru-106 < 9 < 18 < 14 < 23 < 15 < 15 I-131 < 4 < 9 < 10 < 13 < 12 < 9 Cs-134 < 1 < 2 < 2 < 4 < 2 < 2 Cs-137 < 1 < 2 < 2 < 4 < 2 < 2 Ba-140 < 9 < 17 < 16 < 26 < 19 < 16 La-140 < 3 < 7 < 5 < 9 < 6 < 6 Ce-141 < 2 < 4 < 4 < 7 < 4 < 4 Ce-144 < 5 < 14 < 12 < 22 < 10 < 13 Ra-226 < 16 < 54 < 43 < 79 < 33 < 39 Ac-228 < 4 < 7 < 6 < 11 < 7 < 6 Th-228 < 3 < 6 < 3 < 6 < 3 < 3

  • Control Location (a) Quarterly Composite

Plant: Indian Point Energy Center Year: 2021 Page 73 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-12 RADIONUCLIDES IN RIVER WATER SAMPLES - 2021 pCi/L +/- 2 Sigma Roseton 23*

DATE 08/02/21 08/30/21 09/27/21 10/25/21 11/29/21 12/28/21 RADIOCHEMICAL H-3 (a) < 173 < 173 GAMMA K-40 < 14 < 14 < 38 < 41 < 16 < 29 Mn-54 < 1 < 1 < 2 < 3 < 1 < 2 Co-58 < 2 < 2 < 2 < 3 < 1 < 2 Fe-59 < 3 < 4 < 6 < 6 < 3 < 4 Co-60 < 2 < 2 < 2 < 2 < 1 < 2 Zn-65 < 3 < 3 < 4 < 6 < 2 < 4 Nb-95 < 2 < 2 < 2 < 3 < 1 < 2 Zr-95 < 3 < 3 < 5 < 5 < 2 < 3 Ru-103 < 2 < 2 < 3 < 3 < 1 < 2 Ru-106 < 14 < 14 < 21 < 25 < 10 < 16 I-131 < 6 < 7 < 8 < 11 < 6 < 9 Cs-134 < 2 < 2 < 3 < 3 < 1 < 2 Cs-137 < 2 < 2 < 2 < 3 < 1 < 2 Ba-140 < 12 < 14 < 19 < 21 < 11 < 17 La-140 < 4 < 5 < 6 < 8 < 4 < 5 Ce-141 < 4 < 4 < 5 < 6 < 2 < 4 Ce-144 < 12 < 12 < 15 < 19 < 7 < 11 Ra-226 < 35 < 41 < 57 < 67 < 27 < 41 Ac-228 < 5 < 6 < 8 < 10 < 4 < 6 Th-228 < 3 < 3 < 4 < 5 < 3 < 3

  • Control Location (a) Quarterly Composite

Plant: Indian Point Energy Center Year: 2021 Page 74 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-13 GAMMA EMITTERS IN BOTTOM SEDIMENT SAMPLES - 2021 pCi/kg dry +/- 2 Sigma Discharge Canal Off Verplanck 10 17 DATE 06/15/21 08/30/21 06/15/21 08/30/21 GAMMA Be-7 < 355 < 612 < 561 < 476 K-40 14330 +/- 1303 21400 +/- 2042 16460 +/- 1784 18130 +/- 1411 Mn-54 < 45 < 65 < 69 < 52 Co-58 < 45 < 60 < 59 < 48 Fe-59 < 86 < 124 < 138 < 112 Co-60 < 55 < 92 < 76 < 56 Zn-65 < 106 < 175 < 151 < 137 Nb-95 < 41 < 65 < 73 < 51 Zr-95 < 78 < 114 < 117 < 90 Ru-103 < 40 < 63 < 60 < 50 Ru-106 < 423 < 566 < 600 < 509 I-131 < 43 < 102 < 72 < 100 Cs-134 < 61 < 84 < 79 < 70 Cs-137 94 +/- 55 321 +/- 118 < 108 141 +/- 54 Ba-140 < 159 < 305 < 250 < 252 Ce-141 < 52 < 80 < 79 < 67 Ce-144 < 239 < 305 < 336 < 246 Ra-226 < 982 < 1578 2578 +/- 1241 1962 +/- 984 Th-228 244 +/- 71 864 +/- 107 776 +/- 100 803 +/- 88

Plant: Indian Point Energy Center Year: 2021 Page 75 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-13 GAMMA EMITTERS IN BOTTOM SEDIMENT SAMPLES - 2021 pCi/kg dry +/- 2 Sigma Lent's Cove Cold Spring 28 84*

DATE 06/15/21 08/30/21 06/15/21 08/30/21 GAMMA Be-7 < 684 < 1074 < 690 < 980 K-40 13790 +/- 1874 14720 +/- 1999 20210 +/- 2075 19560 +/- 2036 Mn-54 < 107 < 119 < 97 < 104 Co-58 < 81 < 108 < 82 < 114 Fe-59 < 190 < 240 < 195 < 211 Co-60 < 107 < 115 < 91 < 110 Zn-65 < 202 < 228 < 207 < 215 Nb-95 < 81 < 131 < 98 < 138 Zr-95 < 153 < 211 < 168 < 200 Ru-103 < 87 < 116 < 89 < 108 Ru-106 < 624 < 906 < 836 < 936 I-131 < 84 < 187 < 97 < 187 Cs-134 < 109 < 143 < 111 < 124 Cs-137 142 +/- 78 214 +/- 109 < 131 257 +/- 107 Ba-140 < 308 < 564 < 330 < 528 Ce-141 < 88 < 177 < 138 < 155 Ce-144 < 398 < 642 < 518 < 624 Ra-226 < 1850 < 2667 < 2229 < 1913 Th-228 724 +/- 144 900 +/- 197 970 +/- 232 1085 +/- 153

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 76 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-14 RADIONUCLIDES IN SHORELINE SOIL SAMPLES - 2021 pCi/kg dry +/- 2 Sigma Off Verplanck Lent's Cove 17 28 DATE 06/02/21 09/08/21 06/02/21 09/08/21 RADIOCHEMICAL Sr-90 < 45 < 42 < 45 < 49 GAMMA Be-7 < 431 < 524 < 396 < 439 K-40 13410 +/- 1311 12060 +/- 1219 11950 +/- 1238 12390 +/- 1287 Mn-54 < 52 < 52 < 57 < 52 Co-58 < 53 < 51 < 56 < 49 Fe-59 < 117 < 97 < 106 < 94 Co-60 < 54 < 51 < 48 < 43 Zn-65 < 82 < 114 < 113 < 120 Nb-95 < 66 < 58 < 53 < 53 Zr-95 < 89 < 88 < 92 < 94 Ru-103 < 46 < 52 < 50 < 42 Ru-106 < 348 < 488 < 388 < 422 I-131 < 74 < 53 < 75 < 60 Cs-134 < 61 < 68 < 57 < 57 Cs-137 < 64 < 75 < 53 < 53 Ba-140 < 220 < 191 < 208 < 177 La-140 < 69 < 66 < 73 < 34 Ce-141 < 72 < 70 < 69 < 66 Ce-144 < 279 < 260 < 262 < 281 Ra-226 < 1226 < 1263 < 1127 < 1185 Ac-228 < 336 < 349 < 277 < 280 Th-228 384 +/- 115 493 +/- 97 392 +/- 97 203 +/- 73

Plant: Indian Point Energy Center Year: 2021 Page 77 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-14 RADIONUCLIDES IN SHORELINE SOIL SAMPLES - 2021 pCi/kg dry +/- 2 Sigma Manitou Inlet White Beach 50* 53 DATE 06/02/21 09/07/21 06/02/21 09/07/21 RADIOCHEMICAL Sr-90 < 43 < 44 < 43 < 47 GAMMA Be-7 < 867 < 516 < 273 < 572 K-40 9070 +/- 1502 13170 +/- 1507 8047 +/- 974 8639 +/- 1145 Mn-54 < 81 < 54 < 36 < 66 Co-58 < 75 < 54 < 43 < 65 Fe-59 < 164 < 122 < 81 < 136 Co-60 < 80 < 61 < 45 < 66 Zn-65 < 185 < 141 < 91 < 139 Nb-95 < 103 < 69 < 38 < 69 Zr-95 < 137 < 111 < 60 < 108 Ru-103 < 78 < 60 < 29 < 48 Ru-106 < 656 < 470 < 296 < 517 I-131 < 112 < 65 < 45 < 64 Cs-134 < 112 < 68 < 41 < 69 Cs-137 < 125 < 65 < 40 < 65 Ba-140 < 362 < 213 < 161 < 198 La-140 < 108 < 68 < 42 < 75 Ce-141 < 109 < 76 < 44 < 69 Ce-144 < 412 < 301 < 171 < 288 Ra-226 2435 +/- 1596 < 1114 < 786 < 1275 Ac-228 < 601 < 387 < 195 < 266 Th-228 650 +/- 152 577 +/- 97 < 57 < 116

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 78 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-14 RADIONUCLIDES IN SHORELINE SOIL SAMPLES - 2021 pCi/kg dry +/- 2 Sigma Cold Spring 84*

DATE 06/02/21 09/07/21 RADIOCHEMICAL Sr-90 < 45 < 46 GAMMA Be-7 < 450 < 413 K-40 32150 +/- 2225 30250 +/- 2163 Mn-54 < 67 < 62 Co-58 < 60 < 57 Fe-59 < 158 < 130 Co-60 < 62 < 75 Zn-65 < 166 < 148 Nb-95 < 64 < 70 Zr-95 < 112 < 113 Ru-103 < 48 < 55 Ru-106 < 438 < 561 I-131 < 73 < 57 Cs-134 < 84 < 70 Cs-137 < 60 < 63 Ba-140 < 249 < 231 La-140 < 68 < 45 Ce-141 < 67 < 71 Ce-144 < 274 < 279 Ra-226 < 1060 < 1203 Ac-228 < 333 < 432 Th-228 335 +/- 81 486 +/- 94

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 79 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-15 GAMMA EMITTERS IN AQUATIC VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Lent's Cove 28 DATE 06/15/21 08/30/21 Peltandra Virginica Peltandra Virginica Be-7 < 169 386 +/- 233 K-40 2212 +/- 328 2134 +/- 457 Mn-54 < 17 < 30 Co-58 < 14 < 31 Fe-59 < 41 < 52 Co-60 < 21 < 36 Zn-65 < 35 < 69 Nb-95 < 16 < 30 Zr-95 < 28 < 49 Ru-103 < 16 < 30 Ru-106 < 159 < 277 I-131 < 17 < 38 Cs-134 < 19 < 36 Cs-137 < 18 < 29 Ba-140 < 53 < 127 La-140 < 19 < 22 Ce-141 < 20 < 48 Ce-144 < 87 < 205 Ra-226 < 345 < 708 Ac-228 < 64 < 106 Th-228 < 29 < 60

Plant: Indian Point Energy Center Year: 2021 Page 80 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-15 GAMMA EMITTERS IN AQUATIC VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Off Verplanck 17 DATE 06/17/21 08/30/21 Be-7 (a) (a)

K-40 Mn-54 Co-58 Fe-59 Co-60 Zn-65 Nb-95 Zr-95 Ru-103 Ru-106 I-131 Cs-134 Cs-137 Ba-140 La-140 Ce-141 Ce-144 Ra-226 Ac-228 Th-228 (a) Refer to deviation table B-1b

Plant: Indian Point Energy Center Year: 2021 Page 81 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-15 GAMMA EMITTERS IN AQUATIC VEGETATION SAMPLES - 2021 pCi/kg wet +/- 2 Sigma Cold Spring 84*

DATE 06/15/21 08/30/21 Peltandra Virginica Peltandra Virginica Be-7 < 200 < 374 K-40 2971 +/- 446 2405 +/- 528 Mn-54 < 17 < 36 Co-58 < 20 < 37 Fe-59 < 32 < 67 Co-60 < 20 < 28 Zn-65 < 40 < 55 Nb-95 < 18 < 34 Zr-95 < 30 < 47 Ru-103 < 18 < 29 Ru-106 < 137 < 246 I-131 < 24 < 43 Cs-134 < 19 < 36 Cs-137 < 18 < 29 Ba-140 < 73 < 142 La-140 < 13 < 34 Ce-141 < 23 < 51 Ce-144 < 105 < 231 Ra-226 < 329 < 844 Ac-228 < 80 < 158 Th-228 < 35 < 69

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 82 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-16 RADIONUCLIDES IN FISH / INVERTEBRATES - 2021 pCi/kg wet +/- 2 Sigma Downstream 107 DATE 06/01/21 06/01/21 06/01/21 06/01/21 06/01/21 06/16/21 Striped Bass Sunfish Perch Catfish Eel Blue Crab RADIOCHEMICAL Ni-63 < 63 < 56 < 80 < 87 < 83 < 80 Sr-90 < 5 < 5 < 4 < 4 < 4 < 5 GAMMA Be-7 < 420 < 353 < 503 < 487 < 419 < 400 K-40 2505 +/- 959 2209 +/- 707 2424 +/- 775 2426 +/- 911 2605 +/- 895 2713 +/- 717 Mn-54 < 59 < 49 < 44 < 47 < 52 < 61 Co-58 < 53 < 46 < 54 < 53 < 38 < 58 Fe-59 < 114 < 86 < 139 < 120 < 112 < 87 Co-60 < 76 < 51 < 57 < 57 < 58 < 54 Zn-65 < 59 < 83 < 94 < 145 < 63 < 106 Nb-95 < 52 < 35 < 64 < 58 < 47 < 52 Zr-95 < 75 < 103 < 129 < 117 < 84 < 89 Ru-103 < 37 < 38 < 67 < 52 < 48 < 52 Ru-106 < 465 < 376 < 356 < 537 < 366 < 459 I-131 < 86 < 69 < 93 < 96 < 80 < 156 Cs-134 < 45 < 42 < 41 < 60 < 55 < 46 Cs-137 < 46 < 41 < 52 < 54 < 51 < 44 Ba-140 < 243 < 226 < 252 < 247 < 217 < 348 La-140 < 72 < 68 < 104 < 59 < 89 < 136 Ce-141 < 55 < 73 < 64 < 77 < 67 < 77 Ce-144 < 248 < 263 < 245 < 256 < 221 < 239 Ra-226 < 875 < 1125 < 1035 < 1186 < 949 < 896 Th-228 < 89 < 89 < 91 < 92 < 89 < 73

Plant: Indian Point Energy Center Year: 2021 Page 83 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-16 RADIONUCLIDES IN FISH / INVERTEBRATES - 2021 pCi/kg wet +/- 2 Sigma Downstream 107 DATE 08/23/21 08/26/21 09/01/21 09/01/21 09/08/21 09/08/21 Sunfish Eel Catfish Perch Blue Crab Stripped Bass RADIOCHEMICAL Ni-63 < 82 < 38 < 70 < 89 < 96 (a)

Sr-90 < 4 < 4 < 4 < 5 < 4 GAMMA Be-7 < 472 < 511 < 443 < 743 < 343 K-40 3251 +/- 988 1970 +/- 797 1466 +/- 617 3169 +/- 1087 2193 +/- 936 Mn-54 < 75 < 60 < 70 < 86 < 50 Co-58 < 52 < 61 < 66 < 90 < 44 Fe-59 < 118 < 109 < 134 < 138 < 110 Co-60 < 73 < 68 < 51 < 77 < 59 Zn-65 < 186 < 114 < 143 < 180 < 106 Nb-95 < 71 < 61 < 67 < 106 < 51 Zr-95 < 84 < 122 < 85 < 157 < 65 Ru-103 < 65 < 53 < 59 < 74 < 43 Ru-106 < 480 < 456 < 515 < 691 < 480 I-131 < 167 < 103 < 208 < 260 < 103 Cs-134 < 54 < 76 < 65 < 85 < 54 Cs-137 < 76 < 56 < 66 < 81 < 50 Ba-140 < 294 < 290 < 352 < 654 < 232 La-140 < 114 < 99 < 104 < 173 < 86 Ce-141 < 80 < 71 < 92 < 134 < 61 Ce-144 < 338 < 271 < 307 < 464 < 225 Ra-226 < 1393 < 1097 < 1016 < 1592 < 976 Th-228 < 89 < 78 < 77 < 144 < 80 (a) Refer to deviation table B-1b

Plant: Indian Point Energy Center Year: 2021 Page 84 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-16 RADIONUCLIDES IN FISH / INVERTEBRATES - 2021 pCi/kg wet +/- 2 Sigma Roseton 23*

DATE 06/01/21 06/01/21 06/01/21 06/01/21 06/01/21 06/01/21 Striped Bass Sunfish Catfish Perch Eel Blue Crabs RADIOCHEMICAL Ni-63 < 98 < 63 < 74 < 89 < 93 (a)

Sr-90 < 4 < 4 < 4 < 4 < 4 GAMMA Be-7 < 532 < 410 < 577 < 512 < 550 K-40 2203 +/- 1252 2570 +/- 871 4154 +/- 973 2635 +/- 1035 3037 +/- 902 Mn-54 < 76 < 60 < 72 < 56 < 61 Co-58 < 84 < 55 < 67 < 59 < 63 Fe-59 < 136 < 73 < 131 < 139 < 156 Co-60 < 76 < 61 < 70 < 64 < 52 Zn-65 < 135 < 105 < 146 < 112 < 137 Nb-95 < 76 < 55 < 72 < 65 < 70 Zr-95 < 119 < 96 < 125 < 146 < 122 Ru-103 < 82 < 50 < 78 < 53 < 61 Ru-106 < 650 < 497 < 644 < 419 < 671 I-131 < 138 < 64 < 116 < 107 < 117 Cs-134 < 84 < 46 < 84 < 66 < 79 Cs-137 < 72 < 51 < 73 < 52 < 64 Ba-140 < 361 < 310 < 378 < 264 < 323 La-140 < 131 < 109 < 104 < 109 < 102 Ce-141 < 97 < 63 < 96 < 66 < 97 Ce-144 < 418 < 212 < 373 < 234 < 361 Ra-226 < 1523 < 1017 < 1502 < 1032 < 1503 Th-228 < 120 < 86 < 127 < 86 < 122

  • Control Location (a) Refer to deviation table B-1b

Plant: Indian Point Energy Center Year: 2021 Page 85 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-16 RADIONUCLIDES IN FISH / INVERTEBRATES - 2021 pCi/kg wet +/- 2 Sigma Roseton 23*

DATE 08/23/21 08/26/21 09/01/21 09/01/21 09/08/21 09/15/21 Sunfish Eel Catfish Perch Blue Crab Striped Bass RADIOCHEMICAL Ni-63 < 84 < 49 < 65 < 99 < 94 < 91 Sr-90 < 4 < 4 < 4 < 5 < 4 < 5 GAMMA Be-7 < 589 < 641 < 478 < 436 < 592 < 502 K-40 2235 +/- 937 1827 +/- 1013 3072 +/- 875 2287 +/- 676 2780 +/- 752 3784 +/- 1106 Mn-54 < 73 < 82 < 50 < 48 < 62 < 57 Co-58 < 60 < 73 < 51 < 44 < 56 < 60 Fe-59 < 105 < 120 < 133 < 94 < 141 < 132 Co-60 < 69 < 74 < 29 < 47 < 68 < 67 Zn-65 < 147 < 191 < 102 < 108 < 108 < 110 Nb-95 < 57 < 77 < 58 < 45 < 47 < 74 Zr-95 < 108 < 161 < 93 < 83 < 102 < 104 Ru-103 < 54 < 70 < 71 < 50 < 61 < 52 Ru-106 < 433 < 606 < 453 < 326 < 551 < 500 I-131 < 176 < 149 < 169 < 139 < 97 < 128 Cs-134 < 69 < 74 < 63 < 39 < 73 < 71 Cs-137 < 55 < 67 < 47 < 44 < 57 < 65 Ba-140 < 405 < 344 < 381 < 322 < 322 < 404 La-140 < 139 < 131 < 119 < 127 < 117 < 133 Ce-141 < 82 < 108 < 83 < 64 < 90 < 96 Ce-144 < 271 < 412 < 244 < 203 < 298 < 312 Ra-226 < 950 < 1674 < 1065 < 954 < 1438 < 1297 Th-228 < 94 < 138 < 116 < 102 < 110 < 89

  • Control Location

Plant: Indian Point Energy Center Year: 2021 Page 86 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-16 RADIONUCLIDES IN FISH / INVERTEBRATES - 2021 pCi/kg wet +/- 2 Sigma Downstream 25 DATE 06/01/21 06/01/21 06/01/21 06/01/21 06/01/21 06/01/21 Striped Bass Perch Sunfish Catfish Eel Blue Crabs RADIOCHEMICAL Ni-63 < 97 < 93 < 86 < 71 < 79 (a)

Sr-90 < 4 < 4 < 4 < 5 < 4 GAMMA Be-7 < 722 < 483 < 442 < 422 < 441 K-40 2253 +/- 967 1959 +/- 854 3044 +/- 937 2341 +/- 666 2903 +/- 1014 Mn-54 < 81 < 64 < 48 < 52 < 52 Co-58 < 77 < 50 < 64 < 41 < 42 Fe-59 < 133 < 116 < 141 < 110 < 124 Co-60 < 71 < 46 < 68 < 45 < 62 Zn-65 < 188 < 108 < 84 < 104 < 156 Nb-95 < 80 < 68 < 70 < 52 < 49 Zr-95 < 118 < 109 < 105 < 68 < 110 Ru-103 < 64 < 59 < 54 < 53 < 47 Ru-106 < 852 < 458 < 467 < 476 < 504 I-131 < 140 < 85 < 88 < 79 < 95 Cs-134 < 80 < 43 < 73 < 47 < 65 Cs-137 < 88 < 55 < 64 < 44 < 56 Ba-140 < 443 < 329 < 275 < 229 < 270 La-140 < 87 < 88 < 68 < 64 < 76 Ce-141 < 118 < 68 < 74 < 51 < 68 Ce-144 < 450 < 252 < 256 < 211 < 248 Ra-226 < 1555 < 897 < 1212 < 927 < 1084 Th-228 < 133 < 85 < 86 < 67 < 86 (a) Refer to deviation table B-1b

Plant: Indian Point Energy Center Year: 2021 Page 87 of 121 Annual Radiological Environmental Operating Report INDIAN POINT ENERGY CENTER TABLE B-16 RADIONUCLIDES IN FISH / INVERTEBRATES - 2021 pCi/kg wet +/- 2 Sigma Downstream 25 DATE 08/23/21 08/26/21 09/01/21 09/01/21 09/08/21 09/15/21 Sunfish Eel Catfish Perch Blue Crab Striped Bass RADIOCHEMICAL Ni-63 < 97 < 66 < 57 < 98 < 86 < 68 Sr-90 < 4 < 4 < 4 < 5 < 4 (a)

GAMMA Be-7 < 643 < 490 < 585 < 460 < 424 < 810 K-40 2691 +/- 1054 2593 +/- 1005 2116 +/- 988 1688 +/- 591 1185 +/- 741 3573 +/- 1298 Mn-54 < 62 < 75 < 91 < 55 < 48 < 91 Co-58 < 82 < 28 < 51 < 46 < 45 < 90 Fe-59 < 156 < 116 < 151 < 99 < 101 < 248 Co-60 < 84 < 49 < 51 < 47 < 61 < 122 Zn-65 < 139 < 148 < 149 < 97 < 120 < 205 Nb-95 < 80 < 72 < 55 < 58 < 47 < 115 Zr-95 < 142 < 97 < 151 < 98 < 68 < 158 Ru-103 < 85 < 63 < 75 < 51 < 36 < 108 Ru-106 < 682 < 513 < 531 < 467 < 380 < 809 I-131 < 249 < 150 < 266 < 190 < 78 < 235 Cs-134 < 74 < 51 < 65 < 48 < 64 < 101 Cs-137 < 82 < 48 < 58 < 45 < 43 < 89 Ba-140 < 492 < 398 < 556 < 371 < 209 < 541 La-140 < 125 < 99 < 207 < 63 < 85 < 260 Ce-141 < 115 < 87 < 105 < 86 < 55 < 145 Ce-144 < 416 < 276 < 339 < 263 < 223 < 454 Ra-226 < 1602 < 1075 < 1352 < 1081 < 851 < 2023 Th-228 < 135 < 98 < 104 < 79 < 85 212 +/- 119 (a) Refer to deviation table B1-b

Plant: Indian Point Energy Center Year: 2021 Page 88 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-17 LAND USE CENSUS - RESIDENCE AND MILCH ANIMAL RESULTS 2021 The 2021 land use census indicated there were no new residences that were closer in proximity to IPEC.

IPEC maintains a complete nearest residence survey with updated distances.

No milch animals were observed during this reporting period within the 5-mile zone. There are no animals producing milk for human consumption within five miles of Indian Point.

Plant: Indian Point Energy Center Year: 2021 Page 89 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE B-18 LAND USE CENSUS 2021 UNRESTRICTED AREA BOUNDARY AND NEAREST RESIDENCES Distance to site Distance to site Distance to nearest Boundary from Unit 2 Boundary from Unit 3 resident, from Unit 1 Plant Vent (meters) Plant Vent (meters) superheater (meters)

Sector Compass Point Address of nearest resident, Last Census 1 N RIVER RIVER 1788 41 River Road Tomkins Cove 2 NNE RIVER RIVER 3111 Chateau Rive Apts. John St. Peekskill 3 NE 550 636 1907 211 Viewpoint Terrace, Peekskill 4 ENE 600 775 1478 1018 Lower South St. Peekskill 5 E 662 785 1371 1103 Lower South St. Peekskill 6 ESE 569 622 715 461 Broadway Buchanan 7 SE 553 564 1168 223 First St. Buchanan 8 SSE 569 551 1240 5 Pheasant's Run Buchanan 9 S 700 566 1133 320 Broadway Verplanck 10 SSW 755 480 1574 240 Eleventh St. Verplanck 11 SW 544 350 3016 8 Spring St. Tomkins Cove 12 WSW RIVER RIVER 2170 9 West Shore Dr. Tomkins Cove 13 W RIVER RIVER 1919 712 Rt. 9W Tomkins Cove 14 WNW RIVER RIVER 1752 770 Rt. 9W Tomkins Cove 15 NW RIVER RIVER 1693 807 Rt. 9W Tomkins Cove 16 NNW RIVER RIVER 1609 4 River Rd. Tomkins Cove

Plant: Indian Point Energy Center Year: 2021 Page 90 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT SECTION 6.0 HISTORICAL TRENDS

Plant: Indian Point Energy Center Year: 2021 Page 91 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT HISTORICAL TRENDS The past ten years of historical data for various radionuclides and media are presented both in tabular form and graphical form to facilitate the comparison of 2021 data with historical values. Although other samples were taken and analyzed, values were only tabulated and plotted where positive indications were present.

Averaging the positive values in these tables can result in a biased high value, especially, when the radionuclide is detected in only one or two quarters for the year.

Plant: Indian Point Energy Center Year: 2021 Page 92 of 121 Annual Radiological Environmental Operating Report TABLE C-1 DIRECT RADIATION, ANNUAL

SUMMARY

2011-2021 Average Quarterly Dose (mR/Quarter)

Control Year Inner Ring Outer Ring Location 2011 13.6 14.4 13.4 2012 13.2 13.5 12.5 2013 13.4 13.8 14.2 2014 13.7 13.6 14.2 2015 13.8 14.0 14.3 2016 14.3 14.2 15.6 2017 14.3 14.7 15.6 2018 14.0 14.4 15.3 2019 13.7 13.9 15.0 2020 14.0 14.2 15.4 2021 13.2 13.3 14.1 Historical Average 13.8 14.1 14.6 2011-2020

Plant: Indian Point Energy Center Year: 2021 Page 93 of 121 Annual Radiological Environmental Operating Report Figure C-1 DIRECT RADIATION, ANNUAL

SUMMARY

2011-2021 40.0 Inner Ring Outer Ring Control Location 35.0 30.0 25.0 (Mean) mR / Quarter 20.0 15.0 10.0 5.0 0.0 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021

Plant: Indian Point Energy Center Year: 2021 Page 94 of 121 Annual Radiological Environmental Operating Report TABLE C-2 RADIONUCLIDES IN AIR 2011-2021 (pCi/m3)

Gross Beta Cs-137 All Indicator Control All Indicator Control Year Locations Location Locations Location 2011 0.014 0.014 < Lc < Lc 2012 0.014 0.014 < Lc < Lc 2013 0.014 0.014 < Lc < Lc 2014 0.013 0.013 < Lc < Lc 2015 0.016 0.015 < Lc < Lc 2016 0.015 0.015 < Lc < Lc 2017 0.013 0.012 < Lc < Lc 2018 0.013 0.012 < Lc < Lc 2019 0.012 0.012 < Lc < Lc 2020 0.013 0.013 < Lc < Lc 2021 0.014 0.014 < Lc < Lc Historical Average 0.01 0.01 < Lc < Lc 2011-2020 Critical Level (Lc) is less than the ODCM required LLD.

<Lc indicates no positive values above sample critical level.

Plant: Indian Point Energy Center Year: 2021 Page 95 of 121 Annual Radiological Environmental Operating Report Figure C-2 RADIONUCLIDES IN AIR - GROSS BETA 2011-2021 0.05 All Indicator Locations Control Location 0.04 0.03 pCi/m3 0.02 0.01 0

2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021

Plant: Indian Point Energy Center Year: 2021 Page 96 of 121 Annual Radiological Environmental Operating Report TABLE C-3 RADIONUCLIDES IN HUDSON RIVER WATER-TRITIUM 2011-2021 (pCi/L)

Tritium (H-3) Cs-137 Year Inlet Discharge Inlet Discharge 2011 < Lc 661 < Lc < Lc 2012 < Lc 539 < Lc < Lc 2013 241 462 < Lc < Lc 2014 224 253 < Lc < Lc 2015 188 341 < Lc < Lc 2016 < Lc 415 < Lc < Lc 2017 < Lc 299 < Lc < Lc 2018 236 266 < Lc < Lc 2019 273 295 < Lc < Lc 2020 (b) < Lc 288 < Lc < Lc 2021 < Lc 380 < Lc < Lc Historical Average 232 382 < Lc < Lc 2011-2020 Critical Level (Lc) is less than the ODCM required LLD.

<Lc indicates no positive values above sample critical level.

(b) Refer REMP changes table B-1c

Plant: Indian Point Energy Center Year: 2021 Page 97 of 121 Annual Radiological Environmental Operating Report Figure C-3 RADIONUCLIDES IN HUDSON RIVER WATER - TRITIUM 2011-2021 2000 Inlet (H-3) Discharge (H-3) 1800 1600 1400 1200 pCi/L 1000 800 600 400 200 0

2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 (b) 2021

Plant: Indian Point Energy Center Year: 2021 Page 98 of 121 Annual Radiological Environmental Operating Report TABLE C-4 RADIONUCLIDES IN DRINKING WATER 2011-2021 (pCi/L)

Year Tritium (H-3) Cs-137

< Lc < Lc 2011

< Lc < Lc 2012

< Lc < Lc 2013

< Lc < Lc 2014

< Lc < Lc 2015

< Lc < Lc 2016

< Lc < Lc 2017

< Lc < Lc 2018

< Lc < Lc 2019

< Lc < Lc 2020 2021 < Lc < Lc Historical Average

< Lc < Lc 2011-2020 Critical Level (Lc) is less than the ODCM required LLD.

<Lc indicates no positive values above sample critical level.

Plant: Indian Point Energy Center Year: 2021 Page 99 of 121 Annual Radiological Environmental Operating Report Figure C-4 RADIONUCLIDES IN DRINKING WATER 2011-2021 2000 1800 1600 1400 1200 pCi/L 1000 NO IDENTIFIED NUCLIDES IN PREVIOUS TEN YEARS HISTORY 800 600 400 200 0

2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021

Plant: Indian Point Energy Center Year: 2021 Page 100 of 121 Annual Radiological Environmental Operating Report TABLE C-5 RADIONUCLIDES IN SHORELINE SOIL 2011-2021 (pCi/Kg, dry)

Cs-134 Cs-137 Year Indicator Control Indicator Control 2011 < Lc < Lc 108 < Lc 2012 < Lc < Lc 141 < Lc 2013 < Lc < Lc 133 < Lc 2014 < Lc < Lc 327 < Lc 2015 < Lc < Lc 110 < Lc 2016 < Lc < Lc < Lc < Lc 2017 < Lc < Lc 151 < Lc 2018 < Lc < Lc 129 < Lc 2019 < Lc < Lc 104 < Lc 2020 < Lc < Lc 96 < Lc 2021 < Lc < Lc < Lc < Lc Historical Average

< Lc < Lc 144 < Lc 2011-2020 Critical Level (Lc) is less than the ODCM required LLD.

<Lc indicates no positive values above sample critical level.

Plant: Indian Point Energy Center Year: 2021 Page 101 of 121 Annual Radiological Environmental Operating Report Figure C-5 RADIONUCLIDES IN SHORELINE SOIL 2011-2021 The picture can't be displayed.

Indicator (Cs-134) 700 The picture can't be displayed.

Control (Cs-134)

Indicator (Cs-137) 600 Control (Cs-137) 500 pCi/Kg, dry 400 300 200 100 0

2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021

Plant: Indian Point Energy Center Year: 2021 Page 102 of 121 Annual Radiological Environmental Operating Report TABLE C-6 RADIONUCLIDES IN BROAD LEAF VEGETATION 2011-2021 (pCi/Kg, wet)

Cs-137 Year Indicator Control 2011 < Lc < Lc 2012 44 < Lc 2013 < Lc < Lc 2014 < Lc < Lc 2015 < Lc < Lc 2016 < Lc < Lc 2017 < Lc < Lc 2018 < Lc < Lc 2019 < Lc < Lc 2020 < Lc < Lc 2021 < Lc < Lc Historical Average 44 < Lc 2011-2020 Critical Level (Lc) is less than the ODCM required LLD.

<Lc indicates no positive values above sample critical level.

Plant: Indian Point Energy Center Year: 2021 Page 103 of 121 Annual Radiological Environmental Operating Report Figure C-6 RADIONUCLIDES IN BROAD LEAF VEGETATION 2011-2021 100 Indicator (Cs-137) Control (Cs-137) 80 60 pCi/Kg, wet 40 20 0

2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021

Plant: Indian Point Energy Center Year: 2021 Page 104 of 121 Annual Radiological Environmental Operating Report TABLE C-7 RADIONUCLIDE IN FISH AND INVERTEBRATES 2011-2021 (pCi/Kg, Wet)

Cs-137 Year Indicator Control 2011 < Lc < Lc 2012 < Lc < Lc 2013 < Lc < Lc 2014 < Lc < Lc 2015 < Lc < Lc 2016 < Lc < Lc 2017 < Lc < Lc 2018 < Lc < Lc 2019 < Lc < Lc 2020 < Lc < Lc 2021 < Lc < Lc Historical Average < Lc < Lc 2011-2020 Critical Level (Lc) is less than the ODCM required LLD.

<Lc indicates no positive values above sample critical level.

Plant: Indian Point Energy Center Year: 2021 Page 105 of 121 Annual Radiological Environmental Operating Report Figure C-7 RADIONUCLIDES IN FISH AND INVERTEBRATES 2011-2021 200 Indicator (Cs-137) Control (Cs-137) 180 160 140 120 pCi/Kg, wet 100 80 NO IDENTIFIED Cs-137 IN PREVIOUS TEN YEARS HISTORY 60 40 20 0

2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021

Plant: Indian Point Energy Center Year: 2021 Page 106 of 121 Annual Radiological Environmental Operating Report TABLE C-8 RIVER WATER - Discharge Area - Tritium REMP vs. EFFLUENT (pCi/L)

Year REMP* EFFLUENT **

1Q 2018 273 659 2Q 2018 326 439 3Q 2018 <197 332 4Q 2018 199 418 1Q 2019 296 484 2Q 2019 294 602 3Q 2019 <187 74 4Q 2019 <181 7.68 1Q 2020 347 1021 2Q 2020 <176 470 3Q 2020 <177 188 4Q 2020 229 866 1Q 2021 483 4.95 2Q 2021 214 115 3Q 2021 442 737 4Q 2021 <170 174 Four Year Average, by 310 412 Quarter, 2018 - 2021

  • Sample from mixing zone, expected to be less than average activity in the discharge canal.
    • Based upon Effluent Report data, average activity in the discharge canal calculated from the total H-3 discharged divided by the total dilution volume for the quarter.

Plant: Indian Point Energy Center Year: 2021 Page 107 of 121 Annual Radiological Environmental Operating Report TABLE C-9 RADIONUCLIDES IN BOTTOM SEDIMENT 2011-2021 (pCi/Kg, dry)

Cs-137 Year Indicator Control 2011 287 238 2012 284 < Lc 2013 2738 264 2014 327 < Lc 2015 876 < Lc 2016 224 < Lc 2017 350 < Lc 2018 741 198 2019 190 176 2020 167 207 2021 183 257 Historical Average 618 217 2011-2020 Critical Level (Lc) is less than the RETS required LLD.

<Lc indicates no positive values above sample critical level.

Plant: Indian Point Energy Center Year: 2021 Page 108 of 121 Annual Radiological Environmental Operating Report Figure C-9 RADIONUCLIDES IN BOTTOM SEDIMENT 2011-2021 2800 Indicator Control 2600 2400 2200 2000 1800 1600 1400 pCi/Kg, dry 1200 1000 800 600 400 200 0

2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021

Plant: Indian Point Energy Center Year: 2021 Page 109 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT SECTION 7.0 INTERLABORATORY COMPARISON PROGRAM

Plant: Indian Point Energy Center Year: 2021 Page 110 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT INTERLABORATORY COMPARISON PROGRAM This section presents the results of the interlaboratory comparison program for the Teledyne Brown Engineering Environmental Services and Environmental Dosimetry Company.

7.1 Program Description - Teledyne Brown Engineering Environmental Services Comparison Programs The Teledyne Brown Engineering Environmental Services participates in several interlaboratory comparison programs. These programs include sample media for which samples are routinely collected and for which comparison samples are commercially available. Participation in these interlaboratory comparison programs ensure that independent checks on the precision and accuracy of the measurement of radioactive material in the environmental samples are performed as part of the Quality Assurance Program for environmental monitoring. To fulfill the requirement for an Interlaboratory Comparison Program, Teledyne Brown Engineering Environmental Services has engaged the following programs:

  • Eckert & Ziegler Analytics Environmental Radioactivity Cross Check Program
  • Department of Energy (DOE) Mixed Analyte Performance Evaluation Program (MAPEP)
  • Environmental Resource Associates (ERA) Cross Check Program These programs supply sample media as blind samples (typically spikes), which contain certified levels of radioactivity unknown to the analysis laboratory. These samples are prepared and analyzed by the Teledyne Brown Engineering Environmental Services using standard laboratory procedures. Each program issues a statistical summary report of the results. Teledyne Brown Engineering Environmental Services uses predetermined acceptance criteria methodology for evaluating its laboratory performance.

Teledyne Brown Engineering Environmental Services also analyzes laboratory blanks. The analysis of laboratory blanks provides a means to detect and measure radioactive contamination of analytical samples. The analysis of analytical blanks also provides information on the adequacy of background subtraction. Laboratory blank results are analyzed using control charts.

7.2 Acceptance Criteria Each sample result is evaluated to determine the accuracy and precision of the laboratorys analysis result. The sample evaluation method is discussed below.

7.2.1 Analytics Sample Results Evaluation Samples provided by Analytics are evaluated using what is specified as the NRC method.

This method is based on the calculation of the ratio of results reported by the participating laboratory (QC result) to the Vendor Laboratory Known value (reference result).

Plant: Indian Point Energy Center Year: 2021 Page 111 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT An Environmental Laboratory analytical result is evaluated using the following calculation:

The value for the error resolution is calculated.

Error Resolution = Reference Result_______

Reference Results Error (1 sigma)

Using the appropriate row under the Error Resolution column in Table D-2.1, a corresponding Ratio of Agreement interval is given for use in Tables D-3.1, D-3.2, and D-3.3 The value for the ratio is then calculated.

Ratio of agreement = QC Result Reference Result If the value falls within the agreement interval, the result is acceptable.

TABLE D-2.1 Ratio of Agreement ERROR RESOLUTION RATIO OF AGREEMENT

<4 No Comparison 4 to 7 0.5-2.0 8 to 15 0.6-1.66 16 to 50 0.75-1.33 51 to 200 0.8-1.25

>200 0.85-1.18 This acceptance test is generally referred to as the NRC method. The acceptance criteria are contained in Procedure EN-CY-102. The NRC method generally results in an acceptance range of approximately +/- 25% of the Known value when applied to sample results from the Eckert & Ziegler Analytics Interlaboratory Comparison Program. This method is used as the procedurally required assessment method and requires the generation of a deviation from QA/QC program report when results are unacceptable.

7.2.2 ERA and MAPEP Sample Result Evaluation Both these programs supply an acceptance range for evaluating the results.

7.3 Program Results Summary The Interlaboratory Comparison Program numerical results are summarized in the following tables.

Plant: Indian Point Energy Center Year: 2021 Page 112 of 121 Annual Radiological Environmental Operating Report TABLE D-3.1 Analytics Environmental Radioactivity Cross Check Program Teledyne Brown Engineering Environmental Services TBE Identification Known Ratio of TBE to (b)

Month/Year Matrix Nuclide Units Reported (a) Evaluation Number Value Analytics Result Value March 2021 E13466 Milk Sr-89 pCi/L 84.6 87.1 0.97 A Sr-90 pCi/L 11.5 12.6 0.91 A E13467 Milk Ce-141 pCi/L 111 125 0.89 A Co-58 pCi/L 123 128 0.96 A Co-60 pCi/L 140 154 0.91 A Cr-51 pCi/L 252 242 1.04 A Cs-134 pCi/L 130 151 0.86 A Cs-137 pCi/L 110 110 1.00 A Fe-59 pCi/L 105 109 0.96 A I-131 pCi/L 77.6 86.9 0.89 A Mn-54 pCi/L 111 112 0.99 A Zn-65 pCi/L 200 211 0.95 A E13468 Charcoal I-131 pCi 83.5 88.5 0.94 A E13469 AP Ce-141 pCi 103.0 103 1.00 A Co-58 pCi 93.3 105 0.89 A Co-60 pCi 136 126 1.08 A Cr-51 pCi 213 198 1.07 A Cs-134 pCi 123.0 124 0.99 A Cs-137 pCi 86.3 90.1 0.96 A Fe-59 pCi 81.3 89.6 0.91 A Mn-54 pCi 93.5 92.0 1.02 A Zn-65 pCi 166 173 0.96 A E13470 Soil Ce-141 pCi/g 0.232 0.262 0.89 A Co-58 pCi/g 0.251 0.268 0.94 A Co-60 pCi/g 0.306 0.322 0.95 A Cr-51 pCi/g 0.517 0.506 1.02 A Cs-134 pCi/g 0.263 0.317 0.83 A Cs-137 pCi/g 0.278 0.301 0.92 A Fe-59 pCi/g 0.228 0.229 1.00 A Mn-54 pCi/g 0.221 0.235 0.94 A Zn-65 pCi/g 0.448 0.441 1.02 A E13471 AP Sr-89 pCi 92.2 95.5 0.97 A Sr-90 pCi 11.7 13.9 0.84 A (a) The Analytics known value is equal to 100% of the parameter present in the standard as determined by gravimetric and/or volumetric measurements made during standard preparation (b) Analytics evaluation based on TBE internal QC limits:

A = Acceptable - reported result falls within ratio limits of 0.80-1.20 W = Acceptable with warning - reported result falls within 0.70-0.80 or 1.20-1.30 N = Not Acceptable - reported result falls outside the ratio limits of < 0.70 and > 1.30 (Page 1 of 4)

Plant: Indian Point Energy Center Year: 2021 Page 113 of 121 Annual Radiological Environmental Operating Report TABLE D-3.1 Analytics Environmental Radioactivity Cross Check Program Teledyne Brown Engineering Environmental Services TBE Identification Known Ratio of TBE to Month/Year Matrix Nuclide Units Reported (a) Evaluation (b)

Number Value Known Result Value September 2021 E13472 Milk Sr-89 pCi/L 66.4 85.4 0.78 W Sr-90 pCi/L 11.9 14.0 0.85 A E13473 Milk Ce-141 pCi/L 118 114 1.03 A Co-58 pCi/L 116 118 0.98 A Co-60 pCi/L 142 145 0.98 A Cr-51 pCi/L 244 236 1.03 A Cs-134 pCi/L 81 93.1 0.87 A Cs-137 pCi/L 105 112 0.94 A Fe-59 pCi/L 105 102 1.03 A I-131 pCi/L 65.1 85.6 0.76 W Mn-54 pCi/L 128 128 1.00 A Zn-65 pCi/L 158 153 1.03 A E13474 Charcoal I-131 pCi 85.2 90.9 0.94 A E13475 AP Ce-141 pCi 126 135 0.94 A Co-58 pCi 148 139 1.07 A Co-60 pCi 183 171 1.07 A Cr-51 pCi 322 278 1.16 A Cs-134 pCi 118 110 1.08 A Cs-137 pCi 147 132 1.12 A Fe-59 pCi 131 120 1.09 A Mn-54 pCi 161 151 1.06 A Zn-65 pCi 202 180 1.12 A E13476 Soil Ce-141 pCi/g 0.215 0.219 0.98 A Co-58 pCi/g 0.208 0.226 0.92 A Co-60 pCi/g 0.277 0.277 1.00 A Cr-51 pCi/g 0.388 0.452 0.86 A Cs-134 pCi/g 0.157 0.178 0.88 A Cs-137 pCi/g 0.270 0.284 0.95 A Fe-59 pCi/g 0.218 0.195 1.12 A Mn-54 pCi/g 0.239 0.246 0.97 A Zn-65 pCi/g 0.312 0.293 1.06 A E13477 AP Sr-89 pCi 85.6 68.3 1.25 W Sr-90 pCi 12.6 11.2 1.13 A (a) The Analytics known value is equal to 100% of the parameter present in the standard as determined by gravimetric and/or volumetric measurements made during standard preparation (b) Analytics evaluation based on TBE internal QC limits:

A = Acceptable - reported result falls within ratio limits of 0.80-1.20 W = Acceptable with warning - reported result falls within 0.70-0.80 or 1.20-1.30 N = Not Acceptable - reported result falls outside the ratio limits of < 0.70 and > 1.30 (Page 2 of 4)

Plant: Indian Point Energy Center Year: 2021 Page 114 of 121 Annual Radiological Environmental Operating Report TABLE D-3.2 DOE's Mixed Analyte Performance Evaluation Program (MAPEP)

Teledyne Brown Engineering Environmental Services TBE Identification Known Acceptance (b)

Month/Year Matrix Nuclide Units Reported Evaluation Number Value (a) Range Value (3)

February 2021 21-GrF44 AP Gross Alpha Bq/sample 0.371 1.77 0.53 - 3.01 N Gross Beta Bq/sample 0.731 0.65 0.325 - 0.974 A (4) 21-MaS44 Soil Ni-63 Bq/kg 310 689.0 482 - 896 N Tc-99 Bq/kg 457 638 447 - 829 W 21-MaSU44 Urine Cs-134 Bq/L 2.34 2.73 1.91 - 3.55 A Cs-137 Bq/L 2.54 2.71 1.90 - 3.52 A Co-57 Bq/L 0.4100 (1) A Co-60 Bq/L 2.24 2.44 1.71 - 3.17 A Mn-54 Bq/L 2.03 2.03 1.42 - 2.64 A K-40 Bq/L 52.8 54.0 38 - 70 A U-234 Bq/L 0.108 0.0877 0.0614 - 0.114 W U-238 Bq/L 0.101 0.091 0.064 - 0.118 A Zn-65 Bq/L 1.06 1.34 (2) A 21-MaW44 Water Ni-63 Bq/L 6.7 8.2 5.7 - 10.7 A Tc-99 Bq/L 3.850 4.01 2.81 - 5.21 A 21-RdV44 Vegetation Cs-134 Bq/sample 3.13 3.60 2.5 - 4.7 A Cs-137 Bq/sample 4.64 4.69 3.28 - 6.10 A Co-57 Bq/sample 5.25 5.05 3.54 - 6.57 A Co-60 Bq/sample 2.86 2.99 2.09 - 3.89 A Mn-54 Bq/sample 5.02 5.25 3.68 - 6.83 A Sr-90 Bq/sample 0.631 0.673 0.471 - 0.875 A Zn-65 Bq/sample -0.233 (1) A August 2021 21-GrF45 AP Gross Alpha Bq/sample 0.368 0.960 0.288 - 1.632 A Gross Beta Bq/sample 0.595 0.553 0.277 - 0.830 A (5) 21-MaS45 Soil Ni-63 Bq/kg 546 1280 896 - 1664 N Tc-99 Bq/kg 453 777 544 - 1010 N(6) 21-MaSU45 Urine Cs-134 Bq/L 3.10 3.62 2.53 - 4.71 A Cs-137 Bq/L 0.083 (1) A Co-57 Bq/L 0.844 0.87 0.606 - 1.125 A Co-60 Bq/L 0.0535 (1) A Mn-54 Bq/L 0.459 0.417 (2) A K-40 Bq/L 48.8 54.0 38 - 70 A U-234 Bq/L 0.133 0.116 0.081 - 0.151 A U-238 Bq/L 0.137 0.121 0.085 - 0.157 A Zn-65 Bq/L 0.339 0.420 (2) A 21-MaW45 Water Ni-63 Bq/L 33.5 39.5 27.7 - 51.4 A Tc-99 Bq/L 3.5 3.7 2.60 - 4.82 A 21-RdV45 Vegetation Cs-134 Bq/sample 3.42 4.34 3.04 - 5.64 W Cs-137 Bq/sample 2.14 2.21 1.55 - 2.87 A Co-57 Bq/sample 4.08 4.66 3.26 - 6.06 A Co-60 Bq/sample 2.81 3.51 2.46 - 4.56 A Mn-54 Bq/sample 0.035 (1) A Sr-90 Bq/sample 1.15 1.320 0.92 - 1.72 A Zn-65 Bq/sample 2.05 2.43 1.70 - 3.16 A (a) The MAPEP known value is equal to 100% of the parameter present in the standard as determined by gravimetric and/or volumetric measurements made during standard preparation (b) DOE/MAPEP evaluation:

A = Acceptable - reported result falls within ratio limits of 0.80-1.20 W = Acceptable with warning - reported result falls within 0.70-0.80 or 1.20-1.30 N = Not Acceptable - reported result falls outside the ratio limits of < 0.70 and > 1.30 (1) False positive test (2) Sensitivity evaluation (3) See NCR 21-02 (4) See NCR 21-03 (5) See NCR 21-13 (6) Tc-99 cross-checks done for TBE information only - not required (Page 3 of 4)

Plant: Indian Point Energy Center Year: 2021 Page 115 of 121 Annual Radiological Environmental Operating Report TABLE D-3.3 ERA Environmental Radioactivity Cross Check Program Teledyne Brown Engineering Environmental Services TBE Identification Known Acceptance (b)

Month/Year Matrix Nuclide Units Reported (a) Evaluation Number Value Limits Value March 2021 MRAD-34 Water Am-241 pCi/L 175 157 108 - 201 A (1)

Fe-55 pCi/L 579 275 162 - 400 N Pu-238 pCi/L 181 171 103 - 222 A Pu-239 pCi/L 153 142 87.9 - 175 A Soil Sr-90 pCi/kg 6570 9190 2860 - 14,300 A AP Fe-55 pCi/filter 107 121 44.2 - 193 A U-234 pCi/filter 25.99 25.5 18.9 - 29.9 A U-238 pCi/filter 24.7 25.3 19.1 - 30.2 A April 2021 RAD-125 Water Ba-133 pCi/L 92.3 90.5 76.2 - 99.6 A Cs-134 pCi/L 62.9 70.5 57.5 - 77.6 A Cs-137 pCi/L 161 168 151 - 187 A Co-60 pCi/L 22.5 20.9 17.7 - 25.8 A Zn-65 pCi/L 183 177.0 159 - 208 A GR-A pCi/L 30.8 30.2 15.4 - 39.4 A GR-B pCi/L 60.1 67.5 46.8 - 74.2 A U-Nat pCi/L 36.45 36.9 30.0 - 40.8 A H-3 pCi/L 13,400 14,600 12,800 - 16,100 A Sr-89 pCi/L 64.5 63.5 51.4 - 71.5 A Sr-90 pCi/L 22.8 23.0 16.5 - 27.0 A I-131 pCi/L 28.2 26.7 22.2 - 31.4 A September 2021 MRAD-35 Water Am-241 pCi/L 68 63.7 43.7 - 81.5 A Fe-55 pCi/L 179 246 145 - 358 A Pu-238 pCi/L 102 114 68.5 - 148 A Pu-239 pCi/L 32 34.3 21.2 - 42.3 A Soil Sr-90 pCi/kg 6160 6090 1,900 - 9,490 A AP Fe-55 pCi/filter 493 548 200 - 874 A Pu-238 pCi/filter 28 28.5 21.5 - 35.0 A Pu-239 pCi/filter 21 21.6 16.1 - 26.1 A U-234 pCi/filter 7.95 7.76 5.75 - 9.09 A U-238 pCi/filter 8.0 7.69 5.81 - 9.17 A October 2021 RAD-127 Water Ba-133 pCi/L 82.8 87.5 73.6 - 96.2 A Cs-134 pCi/L 64.0 70.1 57.1 - 77.1 A Cs-137 pCi/L 145 156 140 - 174 A Co-60 pCi/L 83.2 85.9 77.3 - 96.8 A Zn-65 pCi/L 133 145 130 - 171 A GR-A pCi/L 76.0 66.7 35.0 - 82.5 A GR-B pCi/L 63.0 55.7 38.1 - 62.6 N(2)

U-Nat pCi/L 52.88 55.5 45.3 - 61.1 A H-3 pCi/L 13,800 17,200 15,000 - 18,900 N(3)

Sr-89 pCi/L 54.9 61.0 49.1 - 68.9 A Sr-90 pCi/L 24.8 29.3 21.3 - 34.0 A I-131 pCi/L 27.4 26.4 21.9 - 31.1 A December 2021 QR 120121Y Water GR-B pCi/L 47.6 39.8 26.4 - 47.3 N(4)

H-3 pCi/L 17,500 17,800 15,600 - 19,600 A (a) The ERA known value is equal to 100% of the parameter present in the standard as determined by gravimetric and/or volumetric measurements made during standard preparation.

(b) ERA evaluation: A = Acceptable - Reported value falls within the Acceptance Limits N = Not Acceptable - Reported value falls outside of the Acceptance Limits (1) See NCR 21-01 (2) See NCR 21-10 (3) See NCR 21-11 (4) See NCR 21-14 (Page 4 of 4)

Plant: Indian Point Energy Center Year: 2021 Page 116 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT 7.4 Environmental TLD Quality Assurance Environmental dosimetry services for the reporting period of January - December, 2021 were provided by the Environmental Dosimetry Company (EDC), Sterling, Massachusetts. The TLD systems at the Environmental Dosimetry Company (EDC) are calibrated and operated to ensure consistent and accurate evaluation of TLDs. The quality of the dosimetric results reported to EDC clients is ensured by in house performance testing and independent performance testing by EDC clients.

The purpose of the dosimetry quality assurance program is to provide performance documentation of the routine processing of EDC dosimeters. Performance testing provides a statistical measure of the bias and precision of dosimetry processing against a reliable standard, which in turn points out any trends or performance changes.

Dosimetry quality control tests are performed on EDC Panasonic 814 Environmental dosimeters. These tests include: (1) the in house testing program conducted by the EDC QA Officer and (2) independent test perform by EDC clients.

Excluded from this report are instrumentation checks. Although instrumentation checks represent an important aspect of the quality assurance program, they are not included as process checks in this report. Instrumentation checks represent between 5-10% of the TLDs processed.

Table D-4.1 provides a summary of individual dosimeter results evaluated against the EDC internal acceptance criteria for high-energy photons (Cs-137) only. The internal acceptance (tolerance) criteria for the Panasonic Environmental dosimeters are: +/- 15%

for bias and +/- 12.8% for precision. During this period, 100% (72/72) of the individual dosimeters, evaluated against these criteria met the tolerance limits for accuracy and 100% (72/72) met the criterion for precision.

Table D-4.2 provides the Bias + Standard deviation results for each group (N=6) of dosimeters evaluated against the internal tolerance criteria. Overall, 100% (12/12) of the dosimeter sets evaluated against the internal tolerance performance criteria met these criteria.

Table D-4.3 presents the independent blind spike results for irradiated dosimeters provided by client utilities during this annual period. All results passed the performance acceptance criterion.

TABLE D-4.1 PERCENTAGE OF INDIVIDUAL DOSIMETERS THAT PASSED EDC INTERNAL CRITERIA JANUARY - DECEMBER 2021 (1), (2)

Number  % Passed Precision Dosimeter Type  % Passed Bias Criteria Tested Criteria Panasonic Environmental 72 100 100 (1)

This table summarizes results of tests conducted by EDC.

(2)

Environmental dosimeter results are free in air.

Plant: Indian Point Energy Center Year: 2021 Page 117 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT TABLE D-4.2 MEAN DOSIMETER ANALYSES (N=6)

JANUARY - DECEMBER 2021 (1), (2)

Standard Tolerance Process Date Mean Bias %

Deviation % Limit +/-15%

5/04/2021 0.6 0.9 Pass 5/06/2021 -0.2 1.4 Pass 5/26/2021 -3.8 1.6 Pass 7/27/2021 2.8 1.4 Pass 8/04/2021 -1.8 2.3 Pass 9/14/2021 -0.2 2.3 Pass 11/01/2021 3.7 0.6 Pass 11/03/2021 1.9 1.9 Pass 11/09/2021 1.1 1.1 Pass 01/26/2022 2.6 1.9 Pass 01/30/2022 -4.2 1.1 Pass 02/06/2022 2.9 1.2 Pass (1)

This table summarizes results of tests conducted by EDC for TLDs issued in 2021.

(2)

Environmental dosimeter results are free in air.

TABLE D-4.3

SUMMARY

OF INDEPENDENT DOSIMETER TESTING JANUARY - DECEMBER 2021 (1), (2)

Standard Pass / Fail Issuance Period Client Mean Bias %

Deviation %

1st Qtr. 2021 SONGS -3.8 1.4 Pass 1st Qtr. 2021 SONGS -4.7 1.1 Pass 2nd Qtr.2021 Seabrook 3.1 1.0 Pass 3rd Qtr. 2021 Millstone -4.7 1.4 Pass 4th Qtr.2021 PSEG(PNNL) 50mR 1.3 0.8 Pass 4th Qtr.2021 PSEG(PNNL) 100mR 1.8 0.8 Pass 4th Qtr.2021 PSEG(PNNL) 150mR -0.6 0.5 Pass 4th Qtr.2021 PSEG(PNNL) 200mR -2.6 2.0 Pass 4th Qtr.2021 Seabrook 2.6 1.4 Pass (1)

Performance criteria are +/- 30%.

(2)

Blind spike irradiations using Cs-137

Plant: Indian Point Energy Center Year: 2021 Page 118 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT SECTION

8.0 REFERENCES

Plant: Indian Point Energy Center Year: 2021 Page 119 of 121 ANNUAL RADIOLOGICAL ENVIRONMENTAL OPERATING REPORT

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