ML17258A311
| ML17258A311 | |
| Person / Time | |
|---|---|
| Site: | Ginna  |
| Issue date: | 09/28/1981 |
| From: | BRUCE M, GLEASON J P, THOME R WYLE LABORATORIES |
| To: | |
| Shared Package | |
| ML17258A310 | List: |
| References | |
| TASK-06-01, TASK-6-1, TASK-RR 17490-1, NUDOCS 8111130591 | |
| Download: ML17258A311 (31) | |
Text
),!'3r.!,g...I',!>,!,*gv~,'gK!,',yes>'!>,!TAN~!~','*ANALYSISOFTHEDECOMPOSITIONEFFECTSOFINYLCELINSULATIONINADESIGNBASISACCIDENTNUCLEARENYIRtINMENTAL'-QUALIEICATION.::!Il!4!!!811113059181110bPDR@DOCK05000244PPORhD!!!!!!'\'p!
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%PIFLIE'IPGRKBSCIENTIFICSERVICESANDSYSTEMSGROUPHUNTSVILLE,ALABAMAilIRochesterGasandElectricCorporation89EastAvenueRochester,NewYork14649REPORTNO.17490WYLEJOBNO.N-BU-17089YOURP.O.NO.OATESeptember28,1981ANALYSISOFTHEDECOMPOSITIONEFFECTSOFVINYLCELINSULATIONINADESIGNBASISACCIDENTbyJ.F.Gleason,M.Bruce,R.ThomersTATE0FALABAMA$ssCaliforniaProfessional"""'"""""""JEngineeringReg.No.2635JamesF.Gleason.beingdulysworn,ideposesandsays:TheinformationcontainedinthisreportistheresultofcompleteandcarefullyconouctedanalysesandisJothebestofhisknowledgetrueandcorrectinall,19NotaryPublicinar(dfortheS'tatenfrttTabamaatlarge.Mycornmrssrorempires~nWyteshallhavenoliabilityfordarnagcsotanykindtopersonorproperty.includingspecialorconscrtucntiatdamages.resultingfromWyie'sprovidingtheservicescoveredbythisrcporh--.;u'~PREPAREDBYJ.6'leason,M.Bruce,R.Thome~/a..r.//v.Mur'vinJ.Kimbrell ReportNo.17490-1PageNo.ii1.02.03.04.05.06.07.08.0TABLEOFCONTENTSPURPOSESCOPEAPPLICABLEVINYLCELTESTREPORTSTESTRESULTS4.1WaterVaporPermeabilityandHumidAging4.2EffectsofHeatandPressure4.3ResistancetoFlameExposure4.4ThermogravimetricAnalysis4.5RadiationANALYSIS5.1AnalysisIncludingDataforSimilarMaterials.5.2DeterminationofRadiationSensitivityEVALUATIONOFGINNAACCIDENTCONDITIONSCALCULATIONSCORROSIVEEFFECTSPageNumber'68.18.28.3EffectsonRHRComponentsEffectsonCarbonSteelPanelLinerEffectsonthe19-NilStainlessSteelInsulationFacingPanels9.010.0
11.0CONCLUSION
SREFERENCESAPPENDIX12WYLELABORATORIESHuntsvilleFaCility
ReportNo.17490-1PageNo.=11.0PURPOSEThisanalysiswaspreparedbyWyleLaboratoriesforRochesterGasandElectricCompany.ThepurposeofthisreportistoprovideanswerstothefollowingNRCquestions:1.Estimateoftheamountsofeachgas,suchashydrogen,organicgases,andhydrogenchloride,whichwouldbeproducedbyradiationfromthedecompositionofthefoamduringaDBA.2'.TheresultsofananalysisoftheeffectofthehydrogenchloridegeneratedduringaDBA,includingcorrosionofcomponentsinthe,containmentbuilding.2.0SCOPE3.0ThescopeofthisinvestigationincludesliteraturesearchandanalysisofapplicabledataforJohns-ManvilleVinylcelinsulation.TestdataforVinylcel,andforanumberofsimilarpolyvinylchloridematerialsisconsidered.Theeffectsof'the"RobertE.GinnaplantnormalandaccidentenvironmentsonVinylcelareevaluated.APPLICABLEVINYLCELTESTREPORTS4.03.1Johns-ManvilleResearchandEngineeringCenter,"TestReportVinylcel(4PCF)-WaterVaporPermeabilityandHumidAgingTests,"ReportNo.E455-T-268,December20,19673.2'ohns-ManvilleResearchandEngineeringCenter,"TestReport,Vinylcel(4PCF)-EffectofHeatandPressure,"ReportNoE455-T-266,November3,19673.3Johns-ManvilleResearchandEngineeringCenter,"TestReport,Vinylcel-ResistancetoFlameExposure",ReportNo.E455-T-258,September21,1967TESTRESULTS.4.1WaterVaorPermeabilitandHumidAinPerReport3.1,Vinylcelwith4PCFnominaldensitywastestedforwaterpermeabilityat90oF,for50%relativehumidity,andfordimensionalchangesat120oFand100%relativehumidity.Theresultsareasfollows:oResultsindicatethatthewaterpermeabilityofa1-inchthickspecimenwas0.06perm-in.oAftersix(6)monthsat120oFand100%relativehumidity,thevolumechangewasonly1.2%andlengthandwidthchangesonly0.3%.WYLELABORATORlESHuntsvilleFacility ReportNo.17490-1PageNo.24.04.2TESTRESULTS(CONTINUED)EffectofHeatandPressurePerReport3.2,Vinylcelof4PCFnominaldensity,l-l/2inchesthick,wassubjectedtoacombinedheatandcompressiontesttosimulatean"incident"inanuclearreactorcontainmentvessel.Theresultsareasfollows:The30-'minutetestincludedamaximumtemperatureof334oFat90PSI.Eightysix(86)percentofthetesttimewasatatemperaturegreaterthanthe286oFmaximum.accidenttemperatureattheGinnaplant."Maximumpermanentlossofthicknesswas29percent.Weightlosswasnotmeasuredsodecompositioncouldnotbeevaluated.4.34.4ResistancetoFlameExosurePerReport3.3,unfacedandmetal-facedVinylcelweresubjectedtoanumberofflametests,includingbuildingtests,verticalpaneltest,tunneltest,andflamepenetration.'Themetal-facedVinylcelpassedalltests,whereas,theunfacedperformedsatisfactorilyinallbuttheflamepenetration.Attemptsweremadeto'ignite'the'evolvedgases.Onlytracequantitiesofcombustiblegases(possibly'H2orshortchainhydrocarbons)werefound.ThermoavimetricAnalsisThecompletetestreport,Johns-ManvilleTestReportE455-T-142,wasnot.available,butthe.testconditionsandgraphicresultsareprovidedinReport3.3.Theresultsareasfollows:TheVinylcelwassubjectedtoaheatingrateof8oCperminute,andtheairflowwas0.5litersperminute.Initialweightlossoccurredat140oC(284oF),andrapidweightlosswasobservedat"225oC'('437oF).'38percentweightlosswasobservedat300oC(572oF).Decompositionwascontinuedatalowerratebetween300oand600oC(1112oF)toa94.5percentweightloss.Nodirectanalysisofevolvedgaseswasreported(seeFigure2).4.5RadiationExosureReference8,notes"Radiationexposureof8x106Roentgenswithin6hourswillnotchangethephysicalpropertiesofYinylcelsignificantlybut108Roentgenswithin.-10,hours"willcausesomeprogressivedeterioration'."ThisradiationresistancewasapparentlybasedongenericdataforPVC.NoinformationontheradiationresistanceofVinylcelwaslocated.WYLELABORATORIESHuntsvilleFeality QReportNo.17490-1PageNo.35.0ANALYSIS5.1AnalsisIncludinDataforSimilarMaterialsSincenospecificdatawasavailableforirradiatedVinylcel,andsincesynergisticeffectsoftemperature,radiation,andoxidizingconditionsareknownforsomepolyvinylchloride-basedmaterials,thisanalysisisbasedondataforgenericallysimilarmaterials.Thefollowingsignificantinformationisnoted:oAttemperaturesbelow200oC,theonlyvolatileproductfromdegradationofpure,unirradiatedPVCisHCl;neitherH2orC12hasbeendetected,Reference16.oForfoamedorplasticizedPVCbasedmaterials,HC1istheonlyvolatilereleasedinsignificantquantities.Reference6identifiesproductsreleasedinsmallquantities(lessthan1%byweight)fromthree(3)PVC-basedinsulationsatelevatedtemperaturesinair.TheseconstituentswereCO2,CO,aldehydes,ammonia,cyanidesandnitrogenoxides.oIrradiationalsoresultsindehydrochlorinationofPVCmaterials.Thisapparentlyoccursatdosesaslowas5xl05radsforsomePVCmaterials,Reference12.5.2DeterminationofRadiationSensitivitNodatawasfoundforexposureofVinylceltoirradiation.DataavailableforexposureofotherirradiatedPVCmaterialswasthereforeconsidered.IThelowestradiationthresholdvalueindicatedinthereferenceddataforanyPVCmaterialwasSx105rads(References7and12).Thisvalueis20percentgreaterthanthe3x105radsrequirementindicatedfor40yearsnormalserviceatGinna,Reference14.Thenormalradiationdoseof3xl05radsis,therefore,concludedtobeinsignificant.6.0EVALUATIONOFGINNAACCIDENTCONDITIONSTheGinnaaccidentconditionisindicatedas286oF(141.11oC)and60psigfor2.8hours,followedby219oF(103.89oC)forupto24hours,and152oF(66.67C)fortheremainder,'of180days.FromReference6,itwasnotedthatnoneofthethreePVC'stestedevolvedHC1untiltemperaturesexceeded160oC.Theweightlossnotedinallthreesamplesrangedfrom2.1to4%beforeHClwasdetected.AcomparisonofTGAcurvesforthosematerialsandVinylcelindicatesthatVinylcelhassignificantlybettertemperatureresistancesotheGinnaaccidenttemperatureswouldnotbeexpectedtocauseHClevolution.WYLELABORATORIESHuntsvtllaFacility reportNo.i'(68v-lPageNo.46.0EVALUATIONOFGINNAACCIDENTCONDITIONS(CONTINUED)ThenfortheGinnaaccidentscenario,theimportantparameter'withregardtogenerationofHClistheintegratedradiationdose.The180dayaccidentdoseis2x108rads.Theaccumulatedradiationdoseattheendof2.8hourswillbelessthan2x107radsperRegulatoryGuide1.89ProposedRev.1,AppendixD.The19-milstainlesssteelfacingwillprovidesignificantBetashielding,stoppingallBetaradiationwithanenergy'lessthanapproximately1KIEV.Therefore,theradiationdosetotheVinylceliscalculatedtobelessthan5x106radsattheendoftheinitial2.8hourphaseoftheaccident.ReferencellstatesthatnoHC1wasfoundinmassspectrometeranalysisofpolyvinylchlorideirradiatedto5x106rads.Itappearsthattheinitialdesignbasiseventtransientwithinthefirst2.8hoursofhightemperatureregime.wouldnotgenerateHC1.ThisisfurthersupportedbydatafromReference3.PurePVCresinirradiatedto5.8x10"radsandexposedto150oCinapureoxygenatmosphereshowednegligibleweightlossafter3hoursReference,.3.demonstratedthewellrecognizedfactthatoxygenacceler-ateslossofHC1.ItisalsocertainthatelevatedtemperaturesacceleratelossofHCl.ItisapparentthatthetestconditionsweremoreseverethantheaccidentrequirementsatGinna.Reference24.statesthatpurePVCresinsarenotas'resistanttodehydrochlorinationasPVCbasedmaterials.Vinylcelmaybesignificant+moreresistanttolossofHClthanthematerialtested.~Reference.3also'providesusefuldataindeterminingamaximumrateatwhichdecompositionmightproceed.SamplesofPVCirradiatedtovariousdosesinoxygenwereexposedto150oCfordurationsuptoapproximately17hours.Figure1showsthatafterapproximately17hoursat150oC,theweightlossofPVCwasasfollows:RadiationDose(Rads)0"""5.8x10617.4x10629x10652.2x106WeightLossat150Cat17hours(%)2.57111214WYLELABORATORIESHuntsvilleFaciltty portNo.17490-1PageNo.56.04EVALUATIONOFGINNAACCIDENTCONDITIONS(CONTINUED)54TherateofHClevolution,atGinnaaccidenttemperaturesshouldbeslowerthanthevaluesabove.HClcouldbeneutralizedbythecontainmentspraysystemasitisreleasedfromtheVinylcel.ThetotalamountofHClformedisalsoofconcern.Reference12,discussestotalHClgeneratedfromirradiationofPVC.ThegenerationofHClisdefinedbythechemicaltermofGHCI,whichisthenumberofHClmoleculesproducedper100electronvoltsofradiationabsorbedbythePVC.Reference12notesaGHCIof22.6at160OFforPVCexposedto2x107radsinvacuum.Acalculation"'assuminganabsorbeddosetoVinylcelof2x108rads(seeappendix)indicatesthatVinylcelwouldberequiredtohaveGHCL=75.65fortotallossofHCltooccur.Thisismorethanthree(3)timesthehighestvaluefoundbutsincenovaluewasfoundforaradiationdoseof2x108itwasassumedthatthecalculatedvaluewasachievable.Thefollowingcalculationsandtheevaluationofcorrosiveeffectsisbasedontheassumptionthattotal'decompositionoccurs.7.0CALCULATIONStReference13providesanapproximatestructuralformulaforVinylcel.Theweightpercentofthecrosslinkingagentwasnotidentified,butsincethatag'ent,wouldservetoreducethepercentchlorineitisadequate,forthistreatment,tomakethe.assumptionthatthematerialisPVC.Fromtheempiricalformula(CH2CHCL)thematerialis56.8percentchlorinebyweight.ForGinnainsulatedwall,anareaof36,181ftofl-l/4"(4PCF)Vinylcel,thetotalmaterialweightisapproximately6,838,000gms,ofwhichapproximately3,884,000gmsischlorine.TheapplicableparametersforGinna,Reference14,indicatethatthetotaldehydrochlorinationwould,release1.0956x105molesofHCl.If-theHClwereuniformlydistributedinthecontainmentvolume,theconcentrationwouldbe4.22x106moles/cm3,asshownbelow:IConcentration=Moles/volumeConcentrationofHCl=1.0956x105moles/(917,000ft3x28316.847cm3/ft3)ConcentrationofHCl=4.22x106moles/cm3(2)(3)TheHClwillnotremainintheatmosphere,butwillbecondensedanddissolvedintheboratedwatersolutionrecirculatedthroughtheReactorHeatRemoval(RHR)System.WYLELASORATORIESHuntsvilleFacility vvssvok~'X4'VJPageNo.6,7.0CALCULATIONS(CONTINUED).Thetotalvolumeofsolutionavailable'fordilutionis1,079,604liters,asshownbelow:SraSstemTank230,000gal(2,000ppmborated):870.5x103liters.ReactorFloodTanks6,250ft3(50-100ppmborated):1',134ft3(2,000ppmborated):Total176.95x1Q3liters32.1x103liters1.08x106litersThefinalmaximumconcentrationinthesolutionrecirculatedthroughtheRHRSystemcouldbe0.105molarinHCl.Ifunbuffered,thepHwouldbeapproximately1.ThesolutionisactuallyadiluteboricacidbufferedwithNaOHtoapHof8.5-1Q.O.A5,100-gallontankof30percentNaOHismaintainedonsite'with'1'."4'476'x'1'05molesofNaOH.ThecapabilitytomonitorandadjustthepHofthesolutionisavailableafteraccidentinitiation.SincetheHC1willbeaddedgradually,thesolutionpHcanbemaintainedintherequiredrangeof8.5-10.0byadditionofNaOHsolution.Thesolutionwouldbecomeabout0.1molar'inNaCl.CorrosiveeffectsfortheRHR,Systemwouldthen'bethoseofsaltsolutions.The'VinylcelstainlesssteelfacingandthecarbonsteellinerwillbeexposedtoHClasitevolvesfromtheinsulation.SomeportionofthisHClwillbeabsorbedbytheinsulationandremainincontactwiththemetalwalls.Moisturemaypenetratetheinsulationalongthepaneljointsinthehumidpost'-accident'enviionment.Thisactionwouldresultinexposureofthecarbonsteellinerand'theinteriorofthestainlesssteelfacingtoaqueousHCl.Itisassumedthatthestainlessfacingwillbeexposedtosignificantmoisture;thecarbonsteellinerwillbepartianyprotectedbytheinsulation.8.0CORROSIONEFFECTSEffectsareconsideredseparatelyfortheRHRSystemcomponents,thecarbonsteellineroftheinsulation,andthe19milstainlessinsulationfacingsincetheywillbe'exposedto"differ'entenvironments,asnotedinParagraph7.0.8.1EffectsForRHRComonentsAsindicatedintheprecedingsection,thesecomponentsmaybeexposedtoa0.1molarsaltsolution(approximately0.6percentsalt).Thecorrosiveeffectsshouldbesimilartothoseofseawaterandthedataforseawaterwillbeassumedapplicable.Componentsinthesystemareallstainlesssteelorstainlesssteelclad.WYLELABORATORIESHuntsvilleFacility
~~OReportNo17490-1PageVio.78.0CORROSIONEFFECTS(CONTINUED)8.1EffectsForRHRComonents(Continued)Reference20indicatesthatamaximumrateforgeneralcorrosionof316stainlesssteelbyseawateris0.00063inchperyear.Lowcarbonandcopper-bearingsteelsshowhighercorrosionratesof0.004-0.005inchperyear.These'owvaluesindicatethatsignificantcorrosionshouldnotoccurinthe180daypost-accidentperiod-Reference19indicatedthatseawaterinducedpittingandcrevicecorrosioncanoccurforstainlesssteels,buttheseactionswouldnotbecome'significantinlessthan1.5-2years.8.2EffectsForCarbonSteelPanelLinerTheentirecarbonsteelliner(bothinsulatedandnoninsulatedsurfaces)isprotectedfromdirectcontactwiththeenvironmentbyaCarboZinc-11/Pheno-line305coatingsystem.ThiswouldretardorpreventdirectcontactbetweenHClandthecarbonsteel.Phenoline305isindicatedbythemanufacturerashaving"verygood"resistancetoacidsplashesandspillsandCarboZinc-llisrated"good".Reference19indicatesgoodacidresistanceforphenoliccoatingsattemperaturesupto300oF.Ifthetopcoatispenetratedthezincbasedprimer(approximately86%zinc)providesanadditionalphysicalbarrierandmaybepreferentiallyattackedbytheHClifitispenetrated.Thoughtheeffectmaybereversedundersomeenvironmentalconditions,temperaturesbelow140oFandthepresenceofClionswouldprobablycausethezinctoactasasacrificialanode(Reference20)providingfurtherprotectionofthesteelliner.EgSinceno'estdatawasavailabletodeterminetheamountofprotectionprovided(orwhetherzincwouldactasasacrificialanodeattheGinnaspecified152oFambient)theeffectsofdirectHCl/carbonsteelcontactwillbeconsidered.Ifmoisturedoesnotpenetratetheinsulationandthelinersothatthecarbonsteelisexposedonlyto~drHClgas,thecorrosioneffectswouldnotbesignificant.Reference21indicatesacorrosionrateof0.00003inchperyearforcarbonsteelexposedtodryHClat500oF.Carbonsteelis,however,sensitivetoaqueousHC1inairenvironments.Ifmoisturepenetratesthedegradedinsulation,orpassesthroughjointsbetweenpanels,corrosionwouldoccur.Reference20indicatescorrosionratesformildsteel(carbonsteel)exposedto0.4percentand4.0percentHClinairatroomtemperatures.Theserateswere0.39inchand0.48inchperyear,respectively.Highertemperatureswouldalsoacceleratecorrosion.AsindicatedinReference19,corrosionratesgreaterthan0.05inchperyear,resultinshortservicelifeforthespecifiedmaterial.WYLELABORATORIESHuntsv>lieFacility ReportNo.17490-1PageNo.88.0CORROSIONEFFECTS(CONTINUED)8.3Effectsforthe19-'MilStainlessSteelInsulationFacinPanelsWhilemoreresistantthancarbonsteel,allstainlesssteelshavepoorresistancetoaqueousHCI.AlsodirectaqueousHCl/stainlesssteelcontactismoreprobable;moisturemaynotpenetratetheinsuIationperparagraph3.1ortheCarboZinc-ll/Phenoline305butcouldpenetratealongpaneljointsandaroundretainingbolts.Corrosioncouldoccuralongpaneljointsandaroundretainingbolts.9,0'ONCI'USIONS'"'.1InresponsetoNRCletter.dated1-17-81,QuestionNo.2:QuestionAnestimateoftheamountsofeachgasashydrogen,organicgasesandhydrogenchloride,whichwouldbeprovidedbyradiationfromthedecompositionofthefoamduringDBA.AnswerTheonlygasproducedinmorethantracequantitieswouldbe,HC1.NoHC1gaswouldbeexpecteduntiltheradiationlevelexceeds5x106rais.ThepostulatedpeaktemperatureduringtheDBAof286oFoccuringwithinthefirst2.8hourswouldprobablynotproduceandHClaslong'astheradiationleveldidnotexceed5x10>radsduringthistime.Thepostulatedtotalintegrateddoseof2x108radswouldresultingenerationofHC1.Thetotalamountgeneratedisuncertain.A'orstcase-"ofotal"dehydrochlorinationisassumedalthoughtheactuallossislikelytobesignificantlyless.9.2InresponsetoNRCletterdated1-17-81;QuestionNo.5:questionTheresultsofananalysisoftheeffectofthehydrogenchloridegeneratedduringaDBAincludingcorrosionofcomponentsinthecontainmentbuilding.AnswerTheHClgaseswhichwouldbereleasedintothecontainmentwouldbecomeneutralizedbythechemicalspray.Minorcorrosiontothereactorheatremovedsystemmayresult.ThecorrosioneffectsofdryHClgasareinsignificant.WYLELABORATORIESHuntsvtlteFacility portNo.17490-1PageNo.99.09.2'ONCLUSIONS(CONTINUED)Answer(Continued)hriCorrosionofthecarbonsteellinercouldoccurifaqueousHCIcontactsitssurface.Thiscontactwillbedelayedandmaynotoccuratall.TheVinylcelprovidesprotectionfromthemoistcontainmentatmosphere.TheCarboZinc11/Phenoline305coatingsystemisabarriertodirectHC1/CarbonSteelContact.Ifpenetrated,theCarboZinc11mayactasasacrificialanodefurtherprotectingthecarbonsteel.Corrosionofthe19-milfacingisexpectedalongpaneljointsandaroundretainingbolts.
10.0REFERENCES
1.LetterfromV.S.Noonan,AssistantDirectorforMaterialandQualification,DivisionofEngineering,U.S.NuclearRegulatoryCommission,
Subject:
GinnaSEPonOrganicMaterials,January17,1981(Enclosed)2e3.')"TheUseofPlasticsandElastomers,"W.W.ParkinsonandO.Sisman,NuclearEnineerinandDesin,Vol.17(1971),pp.247-280,WyleLibraryCode438-81I"Thermal'AnalysisofPolyvinylChloride,"R.SaloveyandR.G.Badger,JournalofAliedPolmerScience,Vol.16(1972),WyleLibraryCode430-814,5.6."RadiationResistanceofCable-InsulatingMaterialforNuclearPower"GeneratingStations,"S.Kawata,J.Ogura,K.Kasai,andT.Onishi,IEEETransaction,ElectricalInsulation,Vol.EI-13,No.3,pp.164-171,June,1978,WyleLibraryCode214-79"EffectsofRadiationonElectricalInsulatingMaterials,"C.L.HanksandD.J.Hammon,REICReportNo.46,WyleLibraryCode299-80s"TestReport',ThermalDecompositionProductsandBurningCharacteristics'fSomeSyhntheticLow-DensityCellularMaterial,"BureauofMinesInvestigation04777,January,19517e"GammaRayDosimetrywithPolyvinylChlorideFilms,"ErnestJ.HenleyandArthurMiller,Nucleonics,Vol.9,No.6,pp.62-66,December,19518.LetterfromC.E.Ernst,ChiefEngineer,Johns-ManvilleIndus-trialInsulationsDivision,toGilbertAssociates,Inc.,Reading,Pennsylvania,
Subject:
BMContainmentInsulation,SP-5290GinnaPlant,December22,1967(Enclosed)WYLELABORATORIESHuntsvilleFacility aeporr.No.iv~~u-iPageNo.10REFERENCES(Continued)9.LetterfromJackMiner,Manager,EngineeringandTechnicalServices,Johns-ManvilleSalesCorporation,Denver,Colorado,
Subject:
VinylcelPhysicalPropertiesandRadiationResistance,April7,198110.ContactReports,RayThometoJ.Richardson,Johns-ManvilleProductCoordinator,datedJuly31,1981,
Subject:
VinylcelInsulationTechnicalDataandReports(Enclosed)11.'Effects'f'adiationonMaterialandComponents,"J-F.KircherandR.E.Bowman,ReinholdPublishingCorporation12.RadiationChemistrofPolmericSstems,A.Chapiro,JohnWiley4Sons,Chapter713."RigidPVCFoamProcessAttractsPhillips,"ArticlefromInternational,notdated(Enclosed)14.<t,Contact~Report,M.BrucetoG.Wrobel,RochesterGasdcElectricCorporation,datedAugust7,1981,
Subject:
ObtainContainmentInformation(Enclosed)15.-ContactReport,RayThometoG.Eichele,Johns-ManvilleSalesCoordinator,datedJuly30,1981,
Subject:
VinylcelInsulation(Enclosed)16.,"Mechanism'fPVCDegradation,"W.C.Giddes,RubberChemistrandTechnolo,164,pp.177-21617."ThermalDecompositionofPoly(VinylChloride),"R.Stromberg;S:Straus,andB.G.Achkammer,JournalofPolmerScience,Vol.35,pp.355-368(1959)18."VinylcelStructuralCoreRigidCrosslinkedPVCFoamPhysicalProperties(AverageValues),"Johns-Manville(Enclosed)19.20...e21.NACEBasicCorrosionCourse,NationalAssociationofCorro-sionEngineers,Houston,Texas,EighthPrinting,1977CorrosionandCorrosionControl,H.H.Unlig,JohnWileyttt:Sons,Inc.,SecondEdition,1971"PropertiesandSelectionofMetals,"MetalsHandbook,Ameri-canSocietyforMetals,8thEdition,Vol.I,196122.RadioloicalHealthHandbook,U.S.DepartmentofHealth,Education,andWelfare,Rockville,Maryland,RevisedEdition,p.122,January,1970WYLELABORATORIE5HuntsvilleFeetttty eportNo.17490-1~~PageNo.11REFERENCES(CONTINUED)23.24.CarbolineProductDataSheets,CarbolineCompany,St.Louis,MissouriEnclosed"DeterminationoftheStabilityofPVCCompoundsAgainstHighTemperature",J.Novak,AmericanChemistrySeries,AdvancesinChemistry,Vol85,pp45-46.WYLELABORATORIESHunlswllaFacility ReportNo.17490-1PageNo.12APPENDIXThetheoreticalyieldofHClis56.8%byweightor1.5S83x10-2moles/gmPVCsubstitutingthisvalueintheequationbelowandsolvingforGHCLidentifiestheGvaluerequiredfortotaldehydrochlorination.MolesHCl=GmolesHCl/100eVx2x1010ergs/gmPVCx6.2x1011eV/ergx1moleHCL/6.02x10moleculesTherfore,11G=1.5583"x10-2"'x100x2x1010x6.2x1011x6.02x1023G,=7.5.65.Where,G=moleculeHCl/100eVRadiationDose=2x108radsor2x1010ergs/gmPVC1erg=6.2x1011eVAvogardoConstant=6.02x1023molecules/moleWYLELABORATORIESHuntsvilleFacility QReportNo.17490-1PageNo.13lBBADlATl'.Dl'OLY(VINYLCllLORID:-.3267O6ÃIRI/~'llA'EMd4llTKS40FIGUREl.ISOTHERMALTHERMOGRAVIMETRYOFIRRADIATEDPVC-150'COXYGENATMOSPHERE:(0)CONTROL;(<)5.8MRADS;(D)17.4MRADS;(9)29.0MRADS;(X)52.2NRADS;(~)52.2NRADSINNITRDGEN ReportNo.17490-1PageNo.14TGACurveof'INYLCELTemperature(oP)6oo8oo8o70503020103oo4ooTemperature(C)-FIGURE2
~IVReportNo.17490-1PaqeNo.1520$.7a=-res.its,of.an,ana>ysisoftheeffectofthehydr~enchloride~arete"chris.aQBA,inc)udinacorrosionofccvconants$rthecoo-iMn~ibU'l1dlny~~4ecancxo1eteourrevi~QfTop.icV5-1.,Orw~ic4;richfourweeksafterxereceivetherequse"informiian.A5sEQT.Mt&>,rector'm"KxEeriats6Qaa3i4icatiorIsEnginermgOivisian.ofinain~ring-CZrQ'ELYiJ~8EC.REFERENCE1g).'.Q{ÃS,iiUi'<~La'loas~,P4'5>st&:~Zfzrew;.~~gfar5afetyAssm~t..'"'.crtRVISLMGfL'fcBAS(np~~.:~~QQJQQp-gpf4j'~~FisLYz.'gncen+<g~~.gjs~zar~Qire'c.Qr,P~~.forNateriaQs4~'3H'zcaticersKnq'.reer>r~>gP<g7CP~<-OivisimofB'gineeringSURJz.l:T"."'"Giga'A'KPMQRcQtICFATERNI.SCI~~~~eru,Sp:stmatic.""va3uat$cnProc.rm,mare'~ie"in"Tcpic,.VK-0"0;.oxidic~aerials"fortheBiminiP4~~Thisylang'h.s.~uzi~feats.hattheinnerso~faceofthe'ontairaxnthxHd<ng:.is.>nat$aM:.>.in.'thickshmtscrfY<qRce>2'famenc'psulatednc'0.039in."=aio$esssteel.Toc~'1eteej.renew,weneedtfsefoHming'nfot~J'.The:cuba)we..ch".o.insu1atfmferninthe.etc;tain~CbuHding.':-.'aestimateoftheamountse,ca%gas,soda.s,hyiroa&,aria.ic~>se:andhydro~~n6;3oride,'shich~ldbepea~uced-~.ractia4te:fro-,'.hedecepcsi+ionoftheEM'uringa.KA.octqs~lfMp'shp'hlcf'c'eseoa5esRig5teschpfpoR,Uccstp)nlesssbŽ3Boxesa&~enterthecajMi~ntund~.aci~t;~(time.~,J'.~bez-esu1ts'o.'anana1ysisoftheccetribu0ionuf.hyaromandotherasksgnera0-.remthe:.feartothe.scentsof@~Rib'legases.~duce~fr~otserscarcerduringaD'"'4.cc:h'ex'ageEXHIBITA REFERENCE8PACiE1of2iRePortNo.1749Q-~.PageNo.16JOHNS-MANVILLESAl.ESCORPORATlOHINDUSTRIALINSULATIONSDIVISION~'EA5T4Q<h5TREET~NEWYORK,N.Y.10016'E.Y,10016'ELEPHONE:532.MSAREA'CODEDE212~wDecember22,1967lGi"lber't"'A'ssoc'i'ates,Inc~.525LancasterAvenueReading,Pa.19603.Attention:Mr.K.T.MomoseRe:BMContainmentInsulationSP-5290'irmaPlant
DearMr.Momose:
.OnNovemb~oeber29,atyourrenuestMr.'hefollowingreports'.I~'LReportE455-T-258Vinylcel.eparrE4$$-T-266",vinylcelSubseouenttothi'hi'ourqueseengnyl'ce1similartothatpreviouslyThisisasfollows:EDCoxsenttoyourattentionccesistancetoFlameExposure(4pcf)EffectofHeatandPressureineeringdataonthe4pcffurnishedfor6pcfVinylce1.2:0'7.2Basedon.pressure"cyclingtestsof'om('RtS455-T-238)astiemoduliof6pcfamdeflee'oofpc~,andtheresidualdeformationtobe0.8+c.3:01.2na.Thermalconductivity(BTU/hrsqftHeatFlowMe,ter.cali'bratedea'aedperASTNC>>177GuardedgotPlate.MeanTemperature,F.100~12~100~220~230250~27'-Compressiveyield-.strenth-g-perASTMD1621---E0psiatthenonstress-straincurve.c.Maximumoperatingtt175F,bQtmayvarywithsemperatureforcontinuousservicespecificapplicationreuirequrementsd.Maximumallowabletemperaturef'rsecifitthdRotNoEl45--266U"CbidHtdPe'aanressureTest.53-2 ReportNo.17490-1PageNo.17REFERENCE8Page2of2e.Moisturevapo'rpermeabilityperASTh!C-355.SeeattachedReportNo.E455-T-268,AppendixI,Table3.f.'ShearstrengthperASTMC-273-68ps'iultimate.Shear'modulusperASTMC-Z73-3510psi.h,.CompressivemodulusnerASTM~-1621-2300osi.DensityperASTMD-1622-4.0lbs/cuft.nominal,3.7lbs/cuft.minimum.Averagecoefficientoflinearexpansion-9.4x10in/in/F.k.CurvesfortheCaseIXIsho~ingtemperature.beforeandafteraccidentplottedagainst.time.SeeReportNo.E455-T-266,AnalogueStudyofVinylcelusedasContainment'nsulation.1.TestresultsofpermeabilitytestsperASTMC-355~See,.attachedReport'E455-T-268Predictedcurve,for6monthtestasreauirodunder2:07.9.SeeattachedReportNo.E455-T-268.DimensionalratherthanweightchangeisgivenasexplainedunderHumidAging(Results)ofthereport.m.Radiation,exposureof'8x10roentgenswithin6hourswillnotchane'hehig'yscalpropertiesofVinylcelsignificantlybut'0roentgenswithin10hourswillcausesomeprogressivedeterioration..-',rThe4p:fVinylcelwillbesupplied44'84"x1-1/4"thick.Lenthand,.wid.th~,tolerancewillbe+1/32"x-ck.LengthVery,tru3y~ours,r~~CEE/caC~E~ERNST-Chief=%ngincerP.S.AsIadvisedyoursecretaryon4'ednesday,Researchissending6copiesofreportE455T238directlytoyou.5B-3 ContactReportOf:RePovtHo.17e)0-1~YNDKRCONTACTREPORTREFERENCE10TelephoneRDateofContact:L-8lFollowUpDate'gencyOrCompanyandAddreaaPhonePcraon(a}ContactedandTitleuctrfAj+rararLLEJPua~iipHA/e'tran+~~reDEUTER'iCOt4e~~<o~-0l't-boo48o4W~E'&~4~,Pr~;<~M!tern(s)and'Part,Number(a)a'Rod~~++8A/0i74Q0lnfonnationrrceded0TemperatureLimita0HcyabiltyOata(MilSpec)0Time/TemperatureOcta~diction0Catalogue0Ltatcrlai'Oissuaaion+Aire"pi+art~~~M1.EreViE~,~er4d.rcWuicAgree,~e..cornrei~we~~+L4iU~~a~Aro.Ccgss'-7=a.eB'Zp,.~~e~M+.L~)'ps.,Qo(aa1e~.t4+p~.gAMMunDM~HenAction'O<g~Reer.ad'~reeor;Ibloc.~Qnp~aliLQa(-m(dree,denCopicaToD.SNi45a4R~By-<c.q6I/r"P-I=r~..~>>.J,'.tr,>j.,-..
INTEAfJ~TIOnIAL~I~~~~~i~IRepottNo.17490-1.PageNo.19REFERENCE13PI-IdPVCfoam.processat'Irac<sPhijllipsjMinorityinterestinFrerichplasticsfirmgivesitacaptiveoutletforjointventure'sresinproductionPhiBipsPetroleumdoesn'tproducepolyvi>>ylchlorideintheU.SirbutinwesternEurope,thecompanyshowskeen"interestintliatlarge-volumeplas-~tic.Earlierthisyear,PhillipsteameduptvithWestGermany'sBASFtoformIIadischePhillipsPetroleum,N.V.'(Badiphil)",inAntwerpinitsfirstventuretomakePVCresins(ChEN,June20,page23).Itfol-lowedthatmovelastmonthby'acquir-inga35%interestintheParis-basedKleber-.cojombespicturesbridgesofamidegroupsbetweenchainsF'Vc",-i-tooc-'(-cooH,:.1Boo(;-Y-co-ZniH1NHOC'-'(-'oop'lHoOC-'(-COSH-IxPVCXIssegmeniofuinyridenicmonomerinIholaIerallygratledchainv(wiihI~oearbosylgroups)Issagmenioi~tnylenicanhydrideallerhydrolysisinIhoI~le>allygralledchainZI~carriergroupingofisoeyanaletunclionslndlorpo>yisocyana>eusedurC~iU.S.Pa>ant3,90O,OS9plasticfabricatorKl>cber-ColombesPia'stiques,S.A.TheminorityholdinginKlcber-Co-lombesPlastiquesgivesPhillipsacap-tiveoutletforBadiphil'sPVC.KI>c-her-ColombesPlastiqueshasapartic-ularlystrongpositioninrigidPVCfoams.Itsprocessforproducingacross-linkedPVCfoamhasbeenli-censedby14companiesin12.coun-tries(includingB.F.GoodrichandJohns-hfanvilleintheU.S.).AtthesametimethatPhillipsbought,35%ofKleber-ColombesPlas-tiques,theWestGermanBnn',Reno-lit-lVcrke,GmbH,Worms,acquired14%.Thislefta51%interestinthehandsoftheparenttireandrubbergoodsmanufacturer,Klcber-colombes,S.A.PhillipsandRenolitarelinkedintheU.S.WithNationJDistdierstheyownAmericanRenolit,whichproducesPVCcalenderedgoods.Kll':ber-ColombesPlastiqueswillpost'alesofabout$15millionthisyear.IRIgidPVCfoamhasbeenoneofitsmajorproductsfor15years.Butthecross-linkedznaterial,KlegecellG300,hasonlybeenofferedforaboutayearandahaIE..KII':bcr-ColombcsPlas-tiquespinsitshopesforincreasedsalesonbetterdimensionalstabilityatteinpcraturesto120C.andIughermechanicalstrengthsforthecross-linkedfoams.'nitsolderprocess(U.S.Patent2,578,749),Kllcbcr-Colombcsusedatwo-stepprocess,i>>ivliiclitllcrcac:tio>>ofwiitcrwithadiiso<<y;matcprociui~dcarbondioiidetogiveahardened,cel-lularstructure.Thisproducthastcicsrelativelyseriousdrawbacks,.accord-ingtoDr.YvanLa>>dier,manageroftheParisresearchcenterofKleber-Co-lombes.Itcoststoomuch,sincetheprocesscaii'tprodurero:imswirthden-sitiesbcloiv2.5poundspcrcu.ft.Secondly,ithaspoortliernialdimen-sionalstability.At90sC.thefoamshrinksabout40c.At150to160C.,tliesefoamscollapse.Cross-linking,lioii'c'vcr,makespos-sibleaI'oainivhidiI>asadensityof1.5poundcpercu.ft.withcorrespond-inglyloivcr'osti.Also,temperaturestabilit>isimprc>v<<d.At904C.,shrinkage'conly5":r.At150'o160C.,criyis-linkedrn:imsrrt;iint)icircellularsiriicture.Inliddit'ion,inc-Kleber-Colombes'andier14licensees,12countrieschanicalstrengthsandsolveiitresistanceareImproved.Thenewprocess(U.S.Paten3,200,089),issuedtoDr.LandIcrimcPierreLebel,alsohastivosteps.Additionofavinylidcnicmonomer,aiethylcnicanhydride,a>>dafree-raclic".icatalysttoPVCrcsi>>anilisocmil>viteiitliefirstormoldi>>gstep.I>>tliescc.ondstep,areactionwithiv:iterproducestheBnishedcross-linkedfoam.Dr.La>>dierproposesameclianisntoexplaintheformationoftilecioislinkedfo:mi(secciriiivi>>g).Iic.iirscl'll)cistllcproc:essleso>><<111ivlll<<lamidegroup~fromtliciso<<yon;>I<<bridgegraftedPVCmacrumol<<cuiesIntheheatandpressureofmoldingi:thefirststep,theeth>'Icnic:>>Ihydrid:andvinvlidenicmonomercc>poly>nerize.Tilecopolymerthc>>grartco>>tcthePVCmolecule.Intlicscelniistep,tileanhydrideunitsontilegr:ihydrolyzetoacidsimdre>i<<tivitliicvcyanatemolcculestocross.li>>kI1i.PVC.Solubilitystudieshearoiittliisliy-pothesis.Accordi>>gtoDr.L:inilll'I'U:S.patent,tlicKlcher-Ci>li>:>>L<<-productsarcinsol>>blcindimctliyi~form:imide,v.hiclicani7iccolvcnilirltypesorPVC-Losecle<<lliil:irni:il<<ri.ils.TiiceonclucionistliatIiieKli'lll>-Co.ion>liesproductsarcdiitin<<ilydiiiclin!andni:iyI>avearciie>>IairrIciru<>leivjtli:iIridiincnsion.iii>l'Iivuik.
ContactReportOf:DateOfContact:8--8lReportNo.17490-1CONTACTREPORTPageNo.20REFERENCE14TelephoneQVisitQPage1of3FollowUpDate:AgencyOrCompanyandAddressPhonePerson(s)ContactedandTitlePogeS~QkSfCMcZR<C(.~if)rl4-~ooPurpose~F0RAIL6.~~+~~~egapgyearDiscussionH,v.mcnab1~c.~H~ft(owingoCmv+~~0b44ws&Qdpace)t5gl7ohio.(coAlsirdchiisfl'M~'ol-vck~csM're505)hauC.hatP,~2.~~4.gg;tli8*.,<p~.B.+a~<.vid~Iv~ging~~<Ru.RHI2s.~i~l4A~~I,S'XIoCg~>>~i%~~3>mW+(~tswed.'"F~e.~gy.gD~sgtqeP'~Qcfll~oL~4GCC~~/iM~~~~(~g0-'op(80~gAction.CopiesTo:549Rev.
ContactReportOf:fA~cue@DateOfContact:8-7-8lONk'5CIR50RTPageNo.21REFERENCE14Page2Of3Telephone~VisitgFollowUpDate:IAgencyOrCompanyandAddressPhonePerson(s)ContactedandTitle6Cf(&mrg~~p'/MjicPurposeDiscussionAction.o@~~~~~on~>>~~R.D~aazgyyo8(~4l((~(s~~ISc((s(Q)gc/,~r~~Ma(((~+P~@e~M~~s.,'W]g~~)d]~~~:(e~MLtd'~c5el~~~r//<~~~~~o/zooceps(&mgw((~~o~~~)pB&y8I4~~~~~~g'g+~I(~hajji~~~~c~(75gw(s~+pM(s'loor-(((rrwi'ooIcs(lc~rzc~Q~o((rgWAh~Hwpe<+~~~+f>f~-(depp~So@aM,,~mo~~ls)3WPigaOoaWp~r(lEcrec((cu(~-pg~g~h~~~+~~~PH~~~~e~~(a~CopiesTo:549Rev.
ContactReportOf:RePilrtNo.'l7$90-1~CONTACTREPORTREFERENCE14Page3of3Telephone~VisitQDateOfContact:FollowUpDate:AgencyOrCompanyandAddresslPhonePerson(s)ContactedandTitle.epochu5v"Cp/rs-M>Purpose.VlA)pence~yQSg~dA3QQP4O/7MfdDiscussiono~~imps~~~&(~),,4-mCpa~5~pcecl+~~QtfM~Cog(PAy(4.-der-/d~~l+9A~~giaXo.bed'~o~~~~~.Action.hgu-~+a<~~C'~4~NdckcNK~~s~+anC~CopiesTo:549Rev.
0~~-~~~~~~~~II~~~a0.(~e~Pg.~f ReportNo.17490-1':i-"..lqt..JJgfl/I,/!Qi:j<<~'"REFERENCE18RIGIDCROSS-IINKEDPVCI=0AMUINXLCELFiiYSZCALPROPERTIES"(averagevalues)TEST1KTHODNORMALDENSlTX,PCFCompressiveStrength(ultimate)~psiRt70Fat175Fat212FLaminarTensileStrength,psiShearStrength(ultimate),psiFlexuralStrength-';.Modulusof.Rupture,psi'"'.Fodulusof,Elasticity,psiCoefficidntofLingarExpansionin/in/Fx10(upto110F)Linear,Shrinkage,,C100days175Fdrysoa3d.ngheat100days158F,100$RH63days120F,100+~RHWaterVaporPermeability,perm-inchWater.,Absorption,~volume48hrsat10'ead."Pl~bili.ty,1",thick..-.TunnelFlameSpreadSmokeDevelopedThermalConductivity(Btuin.persqftperFperhr)75FmeBI1OFmeanASTMD1621&4ASTM.0297-61ASTMC273&1ASTMC203-58.ASTM0355-64HHI-524ASTME84-61ASTM05183T453833503070300082$3$g1$0.12080-100.20.16158113106165'75.1907000101.7$2$<1$0.04.'ANA'-22.1826518517512331090000.5$0.5$(1%0.00136(3/4~tk.)P200-23.19TestData.valuesshownareaveragesastestedbystandardmethods.Thesevalues.are,provided.asguidesforproductevaluationandaregivenwithoutliabilitytoJ'ohns->~ville.
0.,,.~RePoI<"0U4go+(aC:,LtC'~~=-"I.'a=."..'etPageNo.25gpRgoz)NQttREFERENCE23rC=~I,thCZfll(I~f'350HANLEYINDUSTRIALCOURT~ST.LOUIS,MO.63144~314-644-1000SELECTIONDATAGENERICTYPE:Selfcuring,inorganiczincprimer.Thecoatingconsistsofabasiczincsilicatecomplex.Baseand~zittcfillermixedpriortoapplication.GENERALPROPERTIES:Aninorganiczincbasecoatthatprotectssteelgalvanically,eliminatingsub-filmcorrosion.Hasoutstandingapplicationproperties.Canbeappliedattherecommendedthicknessinonecoat.RECOMMENDEDUSES:CarboZinc11(thefirstselfeur-inginorganiczincprimer)isusedasasinglecoatprotectionofsteelstructuresinweatheringexposureandasabasecoatfororganicandinorganictopcoatsinmoresevereservices.Excellentfortheinteriorsandexteriorsofstoragetankscontainingfuelsandorganicsolvents.Hasmanyusesasamaintenanceprimer,withorwithouttopcoats,dependingonexposure.Usedwidelyinchemicalplants,papermills,refineriesandcoastalorsaltatmospheresincludingoffshorestructures.CarboZinc11meetsthestringentperformancerequirementsoftheAmericanNationalStandardsInstitute,ANSIN101.2-1972andANSIN5.12.1974.NOTRECOMMENDEDFOR:Immersionorindirectex-'osuretoacidsoralkalieswithoutsuitabletopcoat.CHEMICALRESISTANCEGUIDE:(withpropertopcoat)HeavyFumesorOutsideLightSplashWeatheringExposureimmersion,~andSpiiioeorMiidFumesAcidsNRVeryGoodExcellentAlkaliesNRVeryGoodExcellentSolventsExcellentExcellentExcellentSaltExcellentExcellentExcellentWater-ExcellentExcellentExcellentTEMPERATURERESISTANCE:(non-immersion)Continuous:750'(399'C)Non.continuous:800F(427'C)FLEXIBILITY:Fair.GoodWEATHERING:ExcellentABRASIONRESISTANCE:Excellent.Abrasionresistanceincreaseswithage.SUBSTRATES:Applyoverproperlypreparedsteel,castiron,orothersurfacesasrecommended.TOPCOATREQUIRED:Maybetopcoatedwithepoxies,phenolics,vinyls,acrylics,silicones,chlorinatedrubbersorothersasrecommended.NOTE:Undercertainconditionsamistcoatortiecoatmaybedesirabletopreventtopcoatbubbling.COMPATIBILITYWITHOTHERCOATINGS:Applydi-rectlyoversubstrate,CarboWeld11orotherinorganiczincsasrecommended.SPECIFICATIONDATATHEORETICALSOLIDSCONTENTOFMIXEDMA.TERIAL:~BWrihsCarboZinc117%k~2%Percentzincindryfilm86%RECOMMENDEDDRYFILMTHICKNESSPERCOAT:2-3mils(50to75microns)THEORETICALCOVERAGEPERMIXEDGALLON:1000milsq.ft.(24.5sq.m/1925microns)333sq.ft.at3mits(8.2sq.m/1875microns)'NOTE:Materiallossesduringmixingandapplicationwillvaryandmustbetakenintoconsiderationwhenestimatingjobrequirements.SHELFLIFE:Base:12monthsminimumZincFiller:24monthsminimumCOLORS:GrayorGreenonly.GLOSS:Manefinish.ORDERINGINFORMATIONPricesmaybeobtainedfromCarbolineSalesRepresentativeorMainOffice.Terms-Net30days.SHIPPINGWEIGHT:1'$5'sCarboZinc1123lbs.{10.4kg)113lbs.(51.3kg)CarbolineThinnert",339lbs.(4.1kg)41lbs.(18.6kg)CarbolineThinner~218lbs.{3,6kg)36lbs.(16.3kg)FLASHPOINT:(Pensky.MartensClosedCup)CarboZinc11Base56F(13C)CarbolineThinner433101F(38C)CarbolineThinnern2153F(12C)Feb.81ReplacesJan.80Tothebestofouiknowledgethetechnicaldatacontainedhereinwetrueandaccurateatthedateof'Issuanceandaresublecttochangewithoutpnornotice.Usermustconlactcarbolinetoveritycorrectnessbeforesoecifyingorordering.Noguaranteeofaccuracyisgivenorimolied.weguwanteeourproductstoconformtocarbolinedualitycontrol.weassumenoresoonsibilityforcoverage,performanceorinluries~esultingfromuse.Liability.itany,islimrcedcoreolacementofnroducts.Pricesandcost'dataitshown,aresublectlochangewithoutnriornotice.NOQTHERWARRAN'ryQRQUARANTFFOFANYKINDISMADE=BYTfsESELLER,ExPRESSQRIMPLIED.STATUTORY.eyOPERATIONQRLAW,QRQTHERWISE,INCLUDINGMERCHANTAOILITYANDFITNESSFORAPARTICULARPURPOSE.
'6ReportNo.17490-'t.'ageNo.26PHENOL!IIEo305FINISHREFERENCE23350HANLEYINDUSTRIALCOURT~ST.LOUIS,MO.63144~314-644-1095ELECTI0NDATAGENERICTYPE:Modifiedphenolic.PartAandPartBmixedpriortoapplication.GENERALPROPERTIES:Aheavydutytopcoat,Phenoline305Finishsetstoahard,tough;smoothfinishhavingverygdodabrasionresistance.Thesurfaceisglossyandeasilycleaned.Hasexcellentresistancetoawiderangeofsolvents,caustics,cleaningsolutionsandacidentrainedvaporsofhighconcentration.Phenoline305Finishhasoutstandingchemical,physicalandapplicationproperties.Phenoline305-Finishiseasilyrepaired,hasexcellentresistancetohydraulicfluidsandmeetstheapplicableperformancecriteriaoftheAmericanNationalStandardsInstituteANSI101.2-1972andANSINS.12-1974.Ithasperformedsatis.factorilyinradiationresistanceanddecontaminationtestingatOakRidgeNationalLaboratory.RECOMMENDEDUSES:Phenoline305Finishisanex.cellentcoatingfortheprotectionofsteelandconcretesur.facesin-nuclearpowerplants:"Becauseofitsglossyappear-'anceandexcellentphysicalproperties,Phenoline305Finishisanexcellenttopcoatforusebymanufacturersofindustrialequipmentandcomponents.Alsousedinchem-icalprocessingplants,pulpandpapermillsfortheprotec.tionofstructuralsteelandconcreteagainstseveresplash,spillageandfumes.Makesanexcellentfloorcoating,addi~tionofSpecialSilican2providesanon.skidsurface.NOT.RECOMMENDEDFOR:Immersionserviceorcon-tinuousspillageofhotorconcentratedacids.CHEMICALRESISTANCEGUIDE:COMPATIBILITYWITHOTHERCOATINGS:Maybegappliedoverinorganiczincs,catalyzedepoxies,modifiedphenolicsorothersasrecommended.AcceptableprimersareCarboZinc11,CarboZinc12,Carboline195Sur.facer,Carboline295WBSurfacer,Phenoline305Primer,Phenoline305ConcretePrimer,Phenoline307orothersasrecommended.Amistcoatmayberequiredwhenappliedoverinorganiczinc.SPECIFICATIONDATATHEORETICALSOLIDSCONTENTOFMIXEDMA-TERIAL:ByVolume64+2~oPhenoline305FinishRECOMMENDEDDRYFILMTHICKNESSPERCOAT:46mils(100-150microns)THEORETICALCOVERAGEPERMIXEDKIT':1gal.kit(yields1.25gal.)1283milsq.ft.(25.6sq.m/I925microns)320sq.ft.at4mils(6.4sq.m/I8100microns)5gal.kit(yields6.25gal.)6416milsq.ft.(25.6sq.m/I825microns)1603sq.ft.at4mils(6.4sq.m/I8100microns)NOTE:Materiallossesduringmixingandapplicationwillvaryandmustbetakenintoconsiderationwhenestimatingjobrequirements.SHELFLIFE:2yearsminimumExposureAcidsAlkaliesSolventsSaltWaterSplashandSpillageVerygoodExcellentExcellentExcellentExcellentFumesExcellentExcellentExcellentExcellentExcellentCOLORS:Phenoline305Finish:StandardcolorsareWhiteC800,GrayC705,GrayC703.ConsultCarbolineColorChart.IGLOSS:GlossyORDERINGINFORMATIONTEMPERATURERESISTANCE:Continuous:200F(93.3C)Noncontinuous:250F(121C)FLEXIBILITY:FairWEATHERING:VerygoodABRASIONRESISTANCE:VerygoodSUBSTRATES:Applyoversuitablyprimedmetalorce.mentitioussurfaces.Surfacernormallyrequiredforpouredverticalsurfaces.TOPCOATREQUIRED:NormallynoneSHIPPINGWEIGHT:1Gal.Kit~i).26~I.)17lbs.(7.7kg)9lbs.(4.1kg)9lbs.(4.1kg)Phenoline305FinishPhenolineThinnerCaibolifteThinnerQ5Gal.Kit(6.26isl.)66iki.(36.326)~45lbs.(20.5kg)45lbs.(20.5kg)FLASHPOINT:(Pensky.MartensClosedCup)Phenoline305FinishPartA68'F(20.0C)Phenoline305FinishPartB60F(15.6C)PhenolineThinner77'F(25C)CarbolineThinnerW30'F(~1C)PricesmaybeobtainedfromCarbolineSalesRepresentativeorMainOffice.Terms-Net30days.May80ReplacesJan.80Tothebestofourknow)edgethetechnicaldatacontainedhereinaretrueandaccuratestthedateofissiianceandaie5ubleotIOChangew'thoutpriornotice.Usermustcontactcarbolinetoverilycotrectno55beforo5oecifyingorordering.Noguaranteeofaccuracyi5gwenor'molted.weguaranteeourproductstoconfotmlocstbolineuuaiitycontrol.weassumenoresponsibilityforcoverage,perlotmsnceorinlutie5re~ultingfromuse.Liability,ifsny.)slimitedtoreplacementoforoducts,pticossndco52daleifshown,sresub)acttochangowithoutpr'otnett<<,NoOTHFRWaRRANTYORGUARANTEEOFANYKINOISVADEBVTHESELLER.EXPRESSORlltPLIEO.STATUTORY.BYOPERATIONORLAWOROTHERWISEINCIUOINGxERCHANTABILITYANOFITNESSFORAPARTICULARPURPOSF~