ML20054N090

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Forwards CA Regional Water Quality Control Board Order 82-54 Amending NPDES Permit,Order 82-24
ML20054N090
Person / Time
Site: Diablo Canyon  Pacific Gas & Electric icon.png
Issue date: 07/12/1982
From: Crane P
PACIFIC GAS & ELECTRIC CO.
To: Engelken R
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION V)
References
82-24, NUDOCS 8207150338
Download: ML20054N090 (31)


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PACIFIC GAS AND E LE C T RI C C O'M PANY 77 BE4LE STREET, SAN FR ANCISCO, C ALIFORNI A 94106 P H O N E ( 415 ) 781 4211

~" ~ ' P. O. B O x 14 4 2, S A N FR A N CISC O, C ALIFO R NI A 94120 T E LECO PIE R (415) 543 7813 July 12, 1982 Mr. R. H. Engelken, Regional Administrator U.S. Nuclear llegulatory Commission, Region V 1450 Maria Lane, Suite 210 Halnut Creek, CA 94596-5368 Re: Docket No. 50-275, OL-DPR-76 Docket No. 50-323 Diablo Canyon Units 1 and 2 Changes to NPDES Permit Daar Mr. Engelken:

The .iational Pollutant Discharge Elimination System (NPDES)

Permit, Order No. 82-24 of the California Regional Water Quality Control Board, Central Coast Region, was amended on June 11, 1982 by Order No. 82-54. In accordance with the requirements of Section 3.2 of Appendix B (Environmental Protection Plan) of the Facility Operating License, enclosed is a copy of Cruer No. 82-24 along with Order No. 82-54.

Kindly acknowledge receipt of this material on the enclosed copy of this letter and return it in the enclosed addressed envelope.

Very truly yours, s

8207150338 820712 .

Philip A. Crane, Jr.

PDR ADOCK 05000275 PDR p

Enclosures cc w/ encl:

Document Control Desk U.S. Nuclear Regulatory Commission Washington, DC 20555 Service List DS D3

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CALI!OWIA RD3IONAL MTER QUALITY (IXiTPOL IDARD CENTRAL COAST REGION ,; 't 9 :(/

1102-A Laurel Lane ,j San Luis Obispo, California 93401 //W ;

s-I ORDER NO. 82-54 '"

l Amending NPDES Permit No. CA0003751 I

WASTE DISCHARGE REQUIREMDTIS FOR PACIFIC GAS AND ELECTRIC COMPANY DIABID CANYCN POWER PIANT UNI'IS 1 AND 2 '

SAN IDIS OBISPO COUNTY The California Regional Water Quality Control Board, Central Coast Region, (hereafter Board), finds:

1. On January 14, 1982, the Board adopted Order No. 82-24 NPDES Permit CA0003751, Waste Discharge Requirements for Pacific Gas aM Electric Company, Diablo Canyon Power Plant, Units 1 and 2, San Luis Obispo County.
2. Discharge Prohibition A.6., Order No. 82-24, provides as follows:.

[ Discharge of elevated temperature wastes exceeding ambient L temperatures is prohibited until July 1,1982, except for discharge from safety equipment required for non-power production cperations and for low power testing provided the te:gerature increase shall not exceed 2*F. Prior to July 1,1982, the Board will consider rrodification of this prohibition in accordance with provisions of this order. If this Board has not concluded its deliberation on this prohibition by July 1,1982, it shall remain in effect until the Board acts on this prohibition.

3. Provision D.2., Order No. 82-24, provides as follows:
  • In order for the Ibard to consider r:odification of Discharge Prohibition A.6., the discharger shall subnit prior to April 1,1982, a technical report which includes the following:

i (a) Information on and evaluation of alternative plans ~

to reduce the heat and volume of the cooling water l discharge which nuy include alternative coling systems or teneficial use of waste heat.

(b) further information regarding anticipated and passible thermal and volume effects, including heat treatment, on the beneficial use of ocean waters.

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4.

'Ihat Pacific Gas and Electric Company subnitted on March 30, 1982, the technical reports required by the Board entitled " Thermal Discharge AssessTent Report" and " Assessment of Alternatives to the Existing Cooling Water System".

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CALIFORNIA REGIONAL MTER CUALI'IY CDNTEL IDARD CENTRAL COAST REGICN 1102-A Iaurel Lane San Luis Obispo, California 93401 l

l AME!OED ORDER NO. 82-24 NPDES NO. CA0003751 WASTE DISCHARGE REQUIRDEN'rS FOR 1 PACIFIC GAS AND ELECTRIC COMPANY I DIABID CANYON POWER PLA.NT UNITS 1 AND 2 .

SAN LUIS OBISPO COUN'IY The California Regional Water Quality Control Board, Central Coast Re-gion (hereafter Board), finds that:

1. We Pacific Gas and Electric Compary (hereafter discharger) appli-i ed for waste discharge requirements ard a permit to discharge wastes under the National Pollutant Discharge Elimination System ard was issued a Permit on April 9,1976 Order No. 76-11. The Discharger applied for reissuance of the permit by subnission of a preliminarf Report of Waste Discharge dated January 27, 1981. The

(' NPDES Permit application form 2. C. Part V; A, B, & C. , was crxn-pleted June 26, 1981. An analysis for toxic constitutents of the discharge was subnitted to the Regional Board on June 26, 1981.

Further analyses will be conducted after commercial operation be-l gins. Additional factual information was subnitted by the dis-l charger throughout the public hearirg process. We Board has re-quested a$ditional information on alternative nethods of reducing heat ard volume of the discharge.

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2. We discharger proposes to discharge wastes from Diablo Canyon Nu-

' clear Power Plant into the Pacific Ocean at Diablo Cove, a water of the United States, at pints 12 miles southwest of San Luis Obispo (Latitude 35* 12', Iongitude 120' 51') and as shown on At-tachnent "A" included with this Order.

3. We potential 2.67 billion gallon per day discharge consists pri-marily of heated seawater. 'Ib this flow are a3ded smaller amounts of in-plant chemical wastes and low-level radioactive wastes.
4. Waste discharges are shown schematically on Attachment "B" includ-ed with this Order and described as follows:

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1 Order No. 82-24 )

Discharce 001 D-Licuid Padioactive Waste Treatment System Effluent, 3 x 10' GPD (Intermittent)

Radioactive liquid wastes fran the reactor system will be col-lected, treated, and nonitored in a radioactive liquid waste treatment system. This system includes storage tanks to per-mit radioactive decay, ion exchangers, and filters to renove radioactive matter frcm the waste streams. High-level wastes prcduced by these processes (evaporator concentrates, ion-exchange resins, filter media) will be collected and packaged for ultimate off-site shipment to an approved burial site. -

After decay and/or treatment, individual batches of low level liquid waste will te sampled and analyzed to determine compliance with discharge limits. The batch will then be discharged through a 5-micron filter into the cooling water discharge. Wastes fran other plant systems discharged into this system include baric acid, lithium hydroxide, sodium hy-droxide, anmonium hydroxide, hydrazine, scdium sulfate, chemi-cal laboratory drains, hot shower and laundry wastes, metal cleaning wastes, and a portion of the firewater system flush water. Treatment includes distillation and filtration. .

J Discharge 001 E-Service Cooling Water 5.62 x 106 GPD

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'Ihis system prcnides once-through cooling water for the ser-vice cooling water system.

Discharge 001 F-Turbine Building Sump, 9.8 x 104 GPD (Intermittent)

Floor drainage from the turbine building and reverse osnosis l

equipment room, as well as a portico of the firewater system flush, will be callected in sumps and treated in an oil-water

( separator prior to discharge.

Discharge 001 G-Reverse Osmosis Blowdown, 7.2 x 10 4 GPD Waste frcm a reverse osmosis demineralizaticn systen contain-ing dissolved solids, sulfuric acid, sodium hexametaphosphate, sodiun hypochlorite an3 sodium bisulfite (for dechlorination) will be discharged to the cooling water stream.

! Discharge 001 H-Condensate Demineralizer and Seawater Evacorator D2mineralizer Recenerant, 5.2 x 104 GFD (Intermittent) l a.) Waste regenerant solution fran the steam-cycle condensate demineralizer will normally te discharged once per day for each unit.

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' The discharge constituents are salts present in seawater whi6 enter the steam cycle through main condenser leak-age, iron and copper corrosion products with added sul-furic acid (1,700 paunds per regeneration), sodium hy-droxide (850 pounds per regeneration) and calcium 61o .

ride (65 pounds per regeneration).

Order No. 82-24 -

Discharge 002 - Intake Structure Buildino Floor Drains, 3 x

) 103 GPD (Intermittent)

Drainage from within the cooling water intake structure, as well as a porticn of the firewater systen flush, will be col-lected in sumps and discharged inside the breakwater adjacent to the intake racks.

Discharge 003 - Intake Screen Wash, 5.62 x 105 cpo Solid material collected on the intake screens that is native to the ocean will be peped back to the ocean at a point lo-cated at the foot of the west breakwater of the intake cove.

Discharge 004 - Thermal Effects Laboratory Discharge 1.44 x 100 GPD Seawater is pumped through tanks used for observation of, and experimentaticn with, marine organisms aM discharged to the intake cove.

Discharge 005 - Yard Storm Drains, Flow Not Determined.

Stormwater runoff is collected in a drainage systen and dis-charged to the ocean near the plant cooling water intake.

This discharge al:o contains a portion of the firewater system

( ) flush.

5. 7bqx:rature of cooling water is proposed to be raised approximate-ly 20*F during nonnal thermal operation. The cooling water temp-erature increase tray be greater than 20*F during condenser heat treatment or transient conditions due to load rejection, steam dump,' generator trip, conditions resulting from cperation of en-gineered safety features, or during periods of reduced flow re-sulting from condenser tube sheet plugging or loss of the circu-lating water pump (s) flow. Tariodic thermal treatment of each cooling water system (about once per nonth for each of the four systems or about once per week) is proposed to demussel aM mini-mize growth of marine organisms in the piping and heat exchangers.

The required frequency of this operation varies seasonally but will normally have a duration of rot nore than a few hours per

. month. The maximum temperature difference between intake and dis-charge during demusseling is expected to be 50*F. if pt r.ps of cnly

'one unit are operating.

6. A chlorination system is proposed to ccytrol slime ard algae in the once-through condenser cooling water.
7. Evidence presented at the hearings indicates that if dilorination is used, the concentration of chlorine allowed in the discharge will minimize degradation of beneficial uses.

I 8. Sewage will receive treatment in septic tanks prior to discharge to leachfields.

Order No. 82-24 )

15. Effluent limitation guidelines for the Steam Electric Power Gener-ating Point Source Category have been promulgated by the United States Environmental Protection Agency (EPA) requirirg the appli-cation of the best practicable control technology currently avail-able (BPT) . Additional effluent limitation guidelines have been proposed, but rot promulgated, by the EPA, including effluent lim-its for best available technology econanically achievable (BAT).

Some effluent limitations contained in this order are chrived frm the promulgated federal guidelines, scrne from the proposed guide-lines, and others are based on the " Ocean Plan". 'Ibgether, they '

are considered the best available technology in the judgment of the Board. Limits are subject to reconsideration when the final guidelines are promulgated.

16. Best available technology economically achievable (BAT) for Diablo Canyon Power Plant should result in minimal discharge of heavy metals which result frcm dissolution of metal in the plant piping system and frcm other sources. Such quantities in many cases may be sirnificantly less than State Ocean Plan allowable concentra-tions. Discharge requirement fourd in Paragraph B.l.b. are based 3 on limits aimed at maintaining discharges of metal as low as rea .

sonably achievable.

17. Section 316 (b) of the Clean Water Act requires that the location, design, construction, and capacity of coolirg water intake struc-l tures reflect the best technology available for minimizing adverse

! environmental impact. 'Ihe large volume of this discharge may re-quire special procedures to minimize entrainment and impingment of marine organisms.

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18. 'Ihere are difficulties in neasuring constituents listed in B.l.b.

at low levels. Many of the low volum streams have the potential

! for contributing significant concentrations of heavy metals and other toxic constituents ard for diversion to further treatment if necessary. Since analytical procedures are nore reliable at high-er concentrations, the Board considers internal monitorire of var-l ious waste streams to ba reasonable, desirable and necessary.

l l . 19. 'Ibe presently available method for calculation of toxicity in Sea-water does not allow for masurement of lower limits than that given in B.l.b.

20. Waste discharge requirements for this discharge are exempt frcm the prcuisions of the California Environmental Quality Act (Public Resources Code, Section 21000 et seq.) in accordance with Section 13389 of the California Water Code.

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Order No. 82-24 '

(c) Sorre chemicals will be added to the water used for cooling; s however, the c:ncentration of these chemicals in Diablo Cove is not expected to have adverse effects on aquatic life.

(FES) S e NEC staff will require that, during heat treat-ment, ro chemicals that can te controlled te added to the effluent stream (FES, p. 3-50). Se NRC staff will require that the effluent be monitored for total available chlorine and the cove, for acute and chronic effects (FES ) and that total available chlorine be limited to 0.1 ppn in the dis-charged cooling water (FES, p. 3-46).

(d) Sere will be very little, if any decline in the concentra-tion of dissolved oxygen in' the discharged cooling water.

(FES) .

(e) %e ES stated: the thermal discharge from the plant will cause an ecological shift in benthic organisms and fish that will result in an increase in the nurrber of warmwater- tol-erant forms. The higher temperatures in Diablo Cove may cause those parts of the bull kelp that are near the surface to degenerate earlier in the year thrn they normally do; at raast, 2 or 3 acres will be affected. h e higher temperatures will also increase the feeding activity of the giant sea urchin, which competes with the abalone for the existing food supply (mainly kelp); this may letd to a decline in the e abalone population unless measures are taken to control the

( urchin. A total of 110,000 abalone may be lost as a result of the staticn operation.

(f) The Mdendum predicted loss of 10-20 acres of bull kelp, but concluded that this will not be a serious impact to those aquatic species that depend on kelp for food cr habitat. (p.

5-4). Because the populations of abalone ard sea urchins within D.C. have been reduced to a small fraction of their former abundance primarily due to factors unrelated to the plant (including sea otter predation, copper discharge from the plant ard a red tide (Mdendum, p. 2-21), the additional t

l impact of the thermal plume will be small (Mdendum). How-ever, the Cove will not afford a viable habitat for abalone in those areas where the thermal plume remains in constant contact with the bottom. (Mdendum p. 5-5)

(g) No adverse effect on phytoplankton populations is expected, because of the rapid regeneration times ard large stocks available for recruittrent from outside Diablo Cove. A mor-tality of as much as 8.5% of the zepplankton passing through the cooling system rray occur, but the generation times for California zcoplankton are generally 24 hours2.777778e-4 days <br />0.00667 hours <br />3.968254e-5 weeks <br />9.132e-6 months <br /> to 8 weeks, and recruitment from the cpen ocean will be copious; therefore, the impact on the local ecosysten is believed to be insigni-

! ficant. (FES) l Some jellyfish will be killed in the intake structures as a

( (h) result of impingement. The ecological consequences of this loss are expected to te s:rall. (FES) i i

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4 Order No. 82-24 (q) We issm of alternative coolirg syste:rs will be decided by the California Regional Water Quality Control Board in connee-tion with the applicant's request for an exemption fran appli-cable thermal discharge prohibitions under Section 316(a) of the EKPCA. (Addendum)

22. Testirrony received by the Board during the hearing shows that the large volume of the proposed discharge combined with the tempera-ture increases in the proposed discharge may not assure protection of some beneficial uses of water within Diablo Cove. Temperature ,

levels in Diablo Cove, especially during demusseling operations, may cause stress of ard increase mortality rates of marine organisms.

23. Wat Pacific Gas and Electric Company subnitted on March 30, 1982, the technical reports required by the Board entitled " Thermal Discharge Assessment Report" and " Assessment of Alternatives to the Existing Ccoling Water System". -
24. Implemntation Provisior.s of the " Water Quality Control Plan for Control of Temperature; in the Coastal and Interstate Waters and .

Enclosed Bays and Ltuaries of California" state that " Existing y" ard future dischargers of thermal waste shall conduct a study to define the effect of the discharge on beneficial uses and, for ex-istirg discharges, determine design and operatirg changes which would be necessary to achieve compliance with the provisions of this plan."

25. We Ocean Plan states that "The Regional Board shall require dis-chargers to conduct self-rronitorirg progrars and submit reports necessary to determine compliance with the waste discharge re-quirements, and may require dischargers to contract with agencies or persons acceptable to the Regional Board to provide conitoring reports. Such nonitority programs shall comply with Guidelines for Mcnitoring the Effects of Waste Discharges on the Ocean which shall be issued by the Executive Director of the State Board."
26. On July 13, 1981, the Board notified the discharger and interested agencies ard persons of its intent to revise waste discharge re-quirements for the proposed discharge and has provided them with an opportunity for a public hearity ard an opportunity to subnit their written views and reconrnendations.
27. We Board in public rneetings on Sept.11 & 24, Oct. 9, 29 & 30,

!bv.11 & 14,1981, Jan.14, May 14, and June 11, 1982 considered all con =ents prtainirg to the discharge.

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Order No. 82-24 l

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Instan-6-Month Daily taneous Median Maximum Maximum Grease and Oil 5.0 10.0 20.

A::enia (expressed 0.1 0.2 0.3 as nitrogen)

Toxicity Concen- 0.7 tu - -

l tration l l

, Total Chlorinated 0.002 0.004 0.006 Pesticides .

Radioactivity Not to exceed limits specified in Title 17, Chapter 5, subchapter 4, Group 3, Article 3, Section 30269 of the Cali-fornia Administrative Code. In addi-tion the Provisions of 10 CFR20 and 10CFR50 shall apply.

c. We daily maximum total chlorine residual concentration in Effluent Limitation B.l.b. shall not ba maintained for longer than 30 minutes per day per generating unit. Icnger priods of l

chlorination may be used as lorg as the maximum concentration is reduced to comply with the time-concentration relationship contained in the California Ocean Plan. Chlorination periods shall rot exceed two hours per day per generating unit at any time. At least thirty minutes must separate the chlorine dis-charged from each one-half condenser unit.

d. Durirg any Six-Month period, the effluent mass emission rate for each constituent listed in Effluent Limitation B.l.b. shall not exceed the " Maximum Allowable Six-Month Median Mass Emis-sion Rate" as calculated from the total waste flow occuring on the day of the Median effluent concentration ard the constit-uent concentration specified in the "Six-Month Median" column of Effluent Limitation B.l.b.

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e. We discharge shall contain a minimum dissolved oxygen concen-tration of 5.0 ng/l at all times.
f. We discharge shall not exceed 2.67 billion gallons per day.

l g. We temperature measured at the poind of discharge shall not

exceed 20*F. over that of the intake except during heat treat-ment.
h. During discharge of heat treatment effluent from Unit 1, Unit 2 circulating water pump shall be operated at full capacity with

! no comercial load. Temperature measured at the point of discharge of Unit 1 shall not exceed 100*F.

Order No. 82-24 9. Discharce 001, 002, 003, 004, and 005:

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a. We discharge of waste shall not cause a pollution as defined in Section 13050(1) of the California Water Code.
b. We discharge of waste shall not cause a nuisance as defined in Section 13050(m) of the California Water Code.

C. Receiving Water Limitations (Receiving water quality is a result of many factors, some unrelated to the discharge. mis permit considers these other factors, and is designed to minimize the adverse in-fluence of the discharge in the receivirg water).

1. Elevated temperature wastes shall not a3versely affect beneficial uses.

Waste discharges shall not individually or collectively cause:

2. Floatirg particulates or grease and oil to te visible.
3. Esthetically undesirable discoloration of the ocean surface.

. 4. Significant reduction in transmittance of natural light in

( ocean waters which muld cause mrine cocmunities to be & grad-ed.

5. Change in the rate of cbposition of inert solids and the char-acteristics of inert solids in ocean sediments such that ten-thic comunities are degraded. Degradation shall be determined by analysis of the effects of waste discharge on species diver-sity, population density, contamination, growth anomalies, de-bility, er supplantirg of normal species by undesirable plant and animal species.
6. We dissolved oxygen concentration in the ocean waters to te depressed more than 10 percent frcm that which occurs naturally.
7. We pH in the ocean waters to be changed nore than 0.2 units

- frcm that which occurs naturally.

8. Dissolved sulfide concentrations of waters in and near sedi-ments to increase significantly above those present under na-tural conditions.
9. Foam and froth that causes marine comunities to te degraded.
10. Objectionable aquatic growth.
11. Concentrations of materials in marine sediments to increase to

! a level which would degrach marire life.

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Order No. 82-24 7. Within 36 nonths after beginning commercial operation, the discharger shall sutmit results of:

(a) Thermal Effects Study to determine whether a thermal dis-charge in compliance with this Order adequately protects a beneficial uses of receivirg waters.

3 (b) Studies necessary to denonstrate mmpliance with Section

?. 316 (b) of the Clean Water Act.

0 8. %e permit is subject to revision if any of the above studies demonstrate different effects than those estimated prior to -

plant operation.

9. We terms "significant difference" and " degradation" used in this permit are defined in footnotes 5 and 7, respectively, of the 1978 Water Quality Control Plan for Ocean Waters of Cali-fornia.
10. All facilities used for containment, transporting or holding waste on site shall be adequately protected against overflow, flooding or washout occurring as a result of a 100 year fre-quency storm.

( 11. Eis Order does rot alleviate the responsibility to obtain other necessary local, state, and federal permits to construct facilities necessary for compliance with this Order, ror does this Order preclude imposition of additional standards, re-quirements, or mnditions by any other regulatory agency.

12. Requirements prescribed by this Order supersede requirements prescribed by Order No. 76-11 adopted by the Board on April 9, 1976. Order No. 76-11 is hereby rescinded.
13. Eis Order expires January 1,1986. 2e discharger must file a report of waste discharge in accordance with Title 23, Chapter 3, Subchapter 9 of the California khinistrative Code, not later than 180 days in advance of such expiration date as ap-plication for issuance of new waste discharge requirements.

This Order shall serve as a National Pollutant Discharge Elimination System permit pursuant to Section 402 of the Act, or amendments there-to, ard shall take effect January 25, 1982.

I, KENNDH R. dCNES, Executive Officer, do hereby certify the foregoing is a full, true, ard correct copy of an Order adopted by the California Regional Water Quality Control Board, Central Coast Region, on January 14, 1982 ard amended on June 11, 1982.

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/ o 001 A 1. 2. A 3 WASTE STREAMS Dischargs D e scelpilen Weewme (g el/d e r)

D!acha r g e D e sceiptioei Veleme rg eudet) Diechesco De weepuen, Volume {ge,g)

$ 1,20 u00 00 t L 5:eem Geneestoe 3Hoodoen 432 000 001 Onc e lhsough Cocha0 Water 2.540 000 000 Don t See .ce Cooung Waics I **** Teeb me 0wid'a0 5 ump 08000 002 Inlake Situctuee Ou sed.ng Fioor 300 000 001 F 8:aterreutients Deasas tinteem nieng 001 A.t Fle eaatee System Flush SC 000 I'"""'"'*N F2 000 003 blat e Scenen Wash 582 000 00l G Reverse osmosis oscadoan 001 A.2 Fhowanee System Flow iest 24.000 $2 000 004 T hes mal E llecia leboe stoey 1.440000 00th Condensaie Demiaeealise* ead ginie,m.ueny Soaaates !vapoealue Dr** Discharge Col A.3 Fase Hose Test (intermittent) 1.400 etatsses negelseans liniesm.nenil Verteble 005 Yeed ssoem Deelns Availtary 5ait Walee Coohag 31.700 000 cost sea Watee Evepoealot oio*down 430 000 001 8 .

Make up wate System Wa ste 19 000 00tJ Condensare Pomps D.scharge 36J 000 00t C Elliveni ginicemiit enti lieado Overt,osed tialeem.stenil 30 000 00tst Coadcasee fut.e sheat lesk 8000 001 0 16av.et Ra's.cartive Waste

M & R Progr o No. 82-24 ,

Minimum Frequency

) Parameter Units Discharge Type of Samole of Analysis Turbidity tm] 001 Grab Monthly Grease & Oil ng/l 001 & 001F Grab Monthly Grease & Oil ng/l 001C,001D,00lG, Grab Qtrly(Jan,Apr, July,0ct) 001H,00lI,00lJ, 00lK,00lL,002,&

005 Total Non-Filtrable mg/l 001&O0lI Grab Monthly Residue * (Suspended Solids)

Total Non-Filtrable ng/l 001C,001D,001F, Grab Monthly Residue (Suspended Solids) 00lG,00lH,00lJ, 001K&O0lL Arsenic ng/l 001 Grab Annually (Oct.)

Cadmium ng/l 001 Grab Annually (Oct.)

'Ittal Chromium mg/l 001 Grab Qtrly(Jan,Apr, July,0ct)

Copper ng/l 001 Grab Monthly Copper ng/l 001D,001F, 24-Hr. Durirg metal cleaning 001I,&O0lL Cm.posite operations Lead ng/l 001 Grab Annually (Oct.)

Mercury ng/l 001 Grab Annually (Oct.)

f Nickel mg/l 001 Grab Qtrly(Jan,Apr, July,0ct)

(' Silver ng/l 001 Grab Annually (Oct.)

Zine ng/l 001 Grab Monthly Cyanide ng/l 001 Grab Annually (Oct.)

Phenolic Compounds ng/l 001 Grab Annually (Oct.)

'Ibtal Chlorine Residual ng/l 001 Grab At least twice during eadi chlorination cycle Chlorine Used Ibs/ day 001 Record of Actual Monthly amount used.

Anmonia (as N) mg/l 001 Grab Qtrly(Jan,Acr, July,0ct)

'Ibxicity Concentration ** tu 001 Grab Qtrly(Jan,Apr, July,0ct)

Total Chlorinated mg/l 001 Grab Annually (Oct.)

l Pesticides & PCB's***

l Iron ng/l 001D,001F 24-Hr. During metal cleaning 00lI&O0lL Composite operations Titanium ng/l 001 Grab Qtrly(Jan,Apr, July,0ct)

. Boron mg/l 001 Grab Qtrly(Jan,Apr, July,0ct)

Dissolved Oxygen ng/l 001 Grab Qtrly(Jan,Apr, July,0ct)

Lithium -

mg/l 001D Grab Qtrly(Jan,Apr, July,0ct)

Hydrazine ng/l 001 Grab Qtrly. when discharging Cadmium, chrcraium, copper, 1ead, mercury, nickel 001D, 00lH Quarterly silver, ard zine mg/l & 00lL Ca posite Qtrly(Jan,Apr, July,0ct)

Cadmium, chromium, lead, copper, mercury, nickel, Weekly i silver, ard zinc mg/l 00lF Catposite Qtrly(Jan,Apr, July,0ct)

r M & R Program No. 82-24 .

2. Sediment sa.ples shall be analyzed annually at two stations inside ard tw stations adjacent to Diablo Cove for constituents listed in paragraph B.6. on page 9 of Order No. 81-76.
3. Aerial photographs of the existing kelp beds from Pecho Pock to Point Buchon shall be taken three times per year, during February, June and October, for a pericd of at least two years after comer-cial operation begins.
4. Surface water temperatures shall be determined at two-month inter-vals from Point Buchon to Pecho Rock for at least two. years after cc:miercial cperation b2 gins. Isotherms shall be determined'in 2*F -

intervals.

5. Water temperatures shall be neasured at cne metcr intervals from the surface to the bottan at twelve stations inside and adjacent to Diablo Cove. Measurements shall be taken in February, June aM October after comercial operation begins. Precision of measure-nents shall te within _+0.2*F.
6. pH and dissolved oxygen content of the receiving water in February, June, and October (including Pacific Gas & Electric stations 3a through c, 4a through c, Sa through c, as well as three stations in

[ Diablo Cove). Dissolved oxygen and pH samples shall te grab samp-N. , les.

7. Incident light neasurements shall be taken at three neter intervals fran the surface to the bottcm at 6 stations approved by the Execu-tive Officer. Measurements shall be taken on a nonthly basis after ccanercial operation begins ard during times of discharge. Mea-surement shall be with a photometer cell.
8. Radiological monitorirg of seawater ard bull kelp at stations lo-cated at the middle and unnediately rorth and south of Diablo Cove shall be conducted monthly. Radiological monitorirg of the follow-ing animals shall be conducted quarterly at the same locations:

I Black Abalone Red Abalone Perch Rockfish ,

9. An in situ bicassay nonitoring program approved by the Executive l

Officer shall be instituted.

Reporting

'Ibe followirg information shall te reported to the Board:

l/ 1. Results of Influent, Effluent and Receiving Water Monitoring.

l l 2. Details of any bypass or damage of the 5 micron filters in the li-quid radwaste system.

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1 LIGHT METER LOCATIONS FIGURE 3

CALIFORNIA REGIO::AL !!ATER QUALITY CC:! TROL BOARD CE:! TRAL COAST REGIO !

J'LY , 1981 ST.CY.R3 PROVISIO::S A"3 REPORTI;:9 REQ'JIRE'!Ei'TS for

'ATIO:'?L POLL'JT.'.:!! JISCHARGE ELI"I?.*.TIO.': SYSTE" PER:11TS C0:!TE:!TS:

A. Senaral Pernit Conditions U. General :;onitoring Requirements ,

C. General Reporting Requirements

3. Oeneral Pretreatment Provisions E. Cypasses or Upsets F. Enforcement C. Ocfinitions A. General Pernit Conditions:

Prohi bitions :

1. Introduction of " incompatible wastes" to the treatnent syster.1 c is prohibited.

\- 2 Discharge of high-level radiological wasta and of radiolo:icci, chcaical, and biological warfare agents is prnhibited.

3. 31scharge of " toxic pollutants" in violation of effluent standarc's and prohibitions establis5ed under Section 307(a) of the Clean "ater f.ct is prohibited.

. " Bypass" and "overflou" of untreated and partially treated uaste is prohibited.

5. Jischar;e of uaste slud]e, sludge dijester supernatant, an: sludge drying bed leachate to drainagelays, surface waters and the ocean is prohibited.

G. Introduction of pollutants into the collection, treatlent, or disposal system by an " indirect.dischar;er" that:

a. inhibit or disrupt the treatment process, systen operation, or the eventual use or disposal of slud,;c.; or,
b. flou through the systen to tse receivin.; water untreated; and,
c. cause or "significantly contribute" to a violation of any requirement of this Order, is prohibited.
7. Introduction of " pollutant free" wastewater to the collection,

( treatment, and disposal systen is prohibited.

(

c. a change in any condition'or endangement to human health or environment that requires c temporary or peraanent reduction or eliaination of the authorized discharge; and,
d. a caterial change in character, location, or volume of tha discharge.
15. This pemit does not authorize commission of any act causing injury to the property of another, does not convey any property rights of any sort, does not recove liability unjer Federal, State, or local laus, and does not guarantee a capacity right in re-ceiving uaters.
17. The "pemittee" shall take all reasonable steps to ninimize or correct adverse impacts on the environment resultin- from non-compliance with this pemit.

i

10. provisions of this pemit are severable. . If any provision of the pomit is found invalid, the remainder of the pemit shall not be affseted.
19. If an applicable effluent standard or linitation is promulgated w under Section 301 (b) (2) (C) and (3), 304 (b) (2), and 307 (a) and that effluent standard or limitation is more stringent than any l

effluent limitation in the pemit, or controls pollutants not limited in t5e pemit, the pemit shall be moJified or reissued to confom to that effluent standard or lioitation.

( 23. The "pemittee" shall furnish, uithin a reasonable tiae, any infor-I mation the P,egional Soard nay request to detemine whether cause exists for nodifying, revoking, and reissuing or teminating this pemit, or to detemine compliance with this pemit.

21. Safeguards shall be provided to assure maxinal compliance with I

all terns and conditions of this pemit. Safequards shall include I preventative and contingency plans and may also include alternative power sources, stan:!-by generators, retention capacity, operatin1 procedures, or other precautions. Preventative and contingency plans for controlling and nininizing the effect of accidental i

discharges shall:

a. identify possible situations that could cause " upset",

! "overflou" or " bypass", or other noncompliance. (Loading and storage areas, power outa ;e, vaste treatnent unit outage, ant failure of process equipment, tanks and pipes should be considered.)

b. cvaluate the effectiveness of present facilitics and proce-li l

dures and describe procedures and steps to mininire or correct any adverse environmental fopact resulting froa noncompliance with tha pemit.

8

5 l

7. The "parnittaa" shall naintain records of all nonitoring information, includin; all calibration and naintenance records; all original )

strip chart recordings for continuous monitoring instruacntation; the date, exact place, and time of samplinJ; the individual who .

parformed tho sampling; the date analysis was perforned; the laboratory and individual who performed the analysis; thc analytical techniques used; and results. Records shall be main-tained for a nininun of three years. This period asy ba extended during tha course of any unresolved litijation or when requested

y the Board. -

C. Snoral 2aporting Requirements:

1. .lonitoring results shall bc reported at intervals and in a manner specified in the "::onitorin<j ani Reporting Prograa" of tMs parait.
2. .!onitorinj reports shall be subnitted on State '!atar ."esource Control 30ard Fora QR, which will be supplind by the ",cgional "oard upon request.

- 3. "aports of narine monitoring surycys conductej tc meat receiving s uator monitorin) reluirements of the ""onitoring and Reportin]

Program" shall inclui; the followin] ainimun information:

c. A dcscription of clinatic and receivinj water charact:ristics at tha time of sanpling (weather observations, floatin; debris, discoloration, wind speed and direction, suo11 or wave action, tina of samplinj, tido height, otc.).
b. A <!cscription of sampling stations, includin; differences unique to each station (e.g., station location, grain size, rocks, shell litter, calcarious nora tubes, evident life, etc.).
c. A description of the sampling procedures cnl preservation sequence used in the survoy.
d. A description of the exact method used for laboratory

. analysis. In ganaral, analysis shall be conducted according to paragraph B.I. Houavar, variations in pro-cedure arc acceptable to acconmodate the special rcquire-nonts of sediment analysis. All sbch variations nast be reported with the tcst results.

c. A brief discussion of the results of the survey. The Dis-cussion shall conpare data from the control station with data from th2 outfall stations. All tabulations and compu-tations shall bc explaincd.

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I b. a schedulo for studios, design, and other stops nooded to provido additional capacity for wasto treatment and/or disposal facilitics before the wasto flow rato equals the capacity of present units. ,

l

) In addition to complying with paragraphs C.14.c and C.15, the f report must certify that the policy-making body is infomcd

, about the report's contents.

[ 10. All "pomittoos" shall submit reports to tho: -

j California Regional llator Quality Control Board Contral Coast Region 1102-A Laurel Lane San Luis Obispo, California 93401 a

I In addition, "pemittoos" with designated major dischargos shall submit a copy of cach document to:

Regional Administrator Environmental Protection Agency, Region IX .

I 215 Fremont Stroot I San Francisco, California 94105

' Attention: ENC"R 1

11. Transfer of control or ownership of a waste discharge facility must be preceded by a notico to the Regional Board at least 30 days in advance of the proposed transfer dato. The notico must includc a writton agreccent betwcon the existing "pcmittoo" and proposad "pomittoo" containing specific date for transfer of responsibility, coverago, and liability between them. Ehether a permit may be transferred without modification or revocation and reissuance is at the descretion of the Board. If pomit modification or revocation and reissuance is necessary, transfer may be delayed 180 days after the Regional Board's receipt of a complete pamit application.
12. .Execpt for data datomined to be confidential under Section 303 of the Clean !!ator Act (excludes efflucnt data and pomit appli-cations), all reports prepared in accordance with this pomit shall be available for public inspection at the office of thc Regional Board or Regional Administrator of EPA.
13. Should the "permittoo" discover that it failed to subnit any relevant facts or that it submitted incorrect information in a report, it shall promptly submit the missing or correct infoma-l tion. ,
t. 14 All reports shall be signed as follows:

. g.

Hotice shall include information on tha quality and quantity of waste bcing introduced to the system and the anticipated impact of the wasto upon the quantity and quality of the aggregato discharge.

18. The "pcmittoo" must notify the Regional Coard as soon as it knows l or has reason to believo:

i a. That a dischargo of a toxic pollutant not limited by tho pomit has occurrod, or will occur, in concentrations that l exceed the highest of the following: -

(1 ) 100 pg/1 ;

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(2) if acrolein or acrylonitrile, 200 pg/1; if 2,4-dinitrophenol or 2-mathyl-4,6 dinitrophonol, 500 )lg/1; and if antimony,1 mg/1; and, (3) Fivo times the maximum concentration value reported for the toxic pollutant in the pcmit application.

b. That they havc begun, nr expcct to begin, use or manu-facture of a toxic pollutant not reported in the pemit

( application.

D. Gonaral Protreatment Provisions

1. Discharga of pollutants by " indirect dischargers" in spacific industrial sub-categories (appendix C, 40CFR Part 403), where categorical protreatment standards have been established, or are to be established, (according to 40CFR Chapter 1, Sub-Chapter H),

shall comply with the appropriate protreatment standards:

a. By the dato specified therein;
b.  !!ithin threo (3) years of the effective date spccified therein, but in no case later than July 1,1984; or,
c. If a new " indirect dischargor", upon commenccment of discharge.
2. Unless the "Pomittee's" Prctreatment Program has bcon approved by the Environmental Protection Agency, affected " indirect dischargers"

' must submit a report, a certification, and a proposed schedulo for complying with prohibition paragraph D.l., above, to the "Pomittoc",

the Regional Board, and the Environmen;al Protection Agency. This report shall be submitted uithin 180 days after the cffective date of a categorical prctreatmcnt standard or after a categorical dctomin-ation decision. The report and cortification shall meet the requiro-ments of 40CFR Part 403, paragraphs 403.12 (b) (1) - (7) and (c)

(1) and (2). Thercafter, progress reports shall be submitted to the "PomittGo", the Regional Board, and the Environmental Protection Agency within fourtoon (14) days of cach date in the approved com-pliancc time schedule mentioned above until cither full compliance with paragraph number D.l. or until the "Pcmittee's" Prctreatment Program is approved.

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a. an " upset" occurred and that the pemittte can identify the specific cause(s) of tha " upset"; and,
b. the pomitted facility was at the tiac of " upset" being properly operated; the '"pomittac" subnitted notice of " upset" within 21 hours2.430556e-4 days <br />0.00583 hours <br />3.472222e-5 weeks <br />7.9905e-6 months <br />; and the "pemittoc" took all reasonablo stcps to minimize or correct any adverso impact on the environment. (q F. Enforconent:
1. The "pomittec" must comply with all conditions of this permit. Pomit noncompliance violates state and federal law and is grounds for enforec-ment action, for permit revocation, reissuance, or modification, or q for denial of a pamit renewal application.
2. Any person who falsifias, tampers with, or knowingly rcndors inaccurate any monitoring device or method required to bc maintained in this pomit may, upon conviction, be punished by a finc of not morc than $10,000 por violation, or by imprisonmcnt for not more than six months pcr violation, or both.

,r 3. Any person who knowingly makes any f also statement, represcntation, or

(~ cortification of any record or other document submitted or required to be maintained under this permit, including monitoring reports or reports of compliance or noncompliance, may, upon conviction, be punished by a fine of not more than $10,000 pcr violation, or by imprisonment of not mora than six months par violation, or by both. >

0. Any person causing violation of this permit shall bc subject to a civil pencity not to exceed $10,000 per day of violation. fny parson who willfully or negligently causes violation of this pomit is sub-ject to a fine of not less than $2,500 nor more than $25,000 por' day of violation, cnd by imprisonment for not more than one year.
5. Upon reduction, loss, or failure of the troatnent facility, the " par-mittac" shall, to the extcnt necessary to maintain complianco with this <

permit, control production or all dischargas, or both, until thc facility is restored or an altornativo method of treatment is provided. Should enforcemcnt action be brought against the "pormittoo", the necess My to halt or reduce the parmitted activity in order to obt in compliance with the conditions of this permit shall not be a defensc.

G. Definitions:

1. " Bypass" mcans the diversion of waste streams from any portion of a treatmcnt facility.

, 2. A " composite sample" is a combination of no fewer than cight (8)

\ individual sampics obtained at equal time intervals (usually hourly) over the specified sampling (composito) period. The volume o f cy.h individual sample is proportional to the flow r;tc at tha time of sampling. The period shall be specified in the '"'onitoring and Reporting Program" ordered by the Executive Officer.

e. Heat in amounts that inhibit or disrupt biological activity in thgtreat 40 C (10f, gent works or that raise influent teaparatures aboveF) unle such heat.
9. " Indirect Discharger" means a nondonostic discharger introducing pollutants into a publicly owned treatment and disposal system.
10. " Log :1aan" is the geometric acan. Used for determining ' compliance of focal or total coliform populations, it is calculated with the following equation: .

Log *1can = (C) 2 xC x...xC) q ,

in which "ii" is the number of days samplos werc analyzed during the period and any "C" is the concentration of bactoria (*1?N/100 al) found on each day of sampling. To be valid, "1" must bc fivc or more.

11. ":k.ss camission rate" is a daily rato dcfined by the follcuing equations:

mass cmie 4.to (1bs/ day) = 0.31 x Q x C; and, cass cmmission rate (kg/ day) = 3.78 x Q x C, .

wharc "C" (in mg/1) is the naasured daily constitucnt concentration or the average of measured daily constituent concentrations and ,

"Q" (in ngd) is the naasured da$1y_ floe rata or the averagc of acasured daily flow rates over tha' period of intorast.

'12. Tha " iaxiaum Allowabic *1 css Emission Rate," whath;r for a month, wack, day, or six-month period, is a daily rato dotarained with the formulas

,in paragraph G.11, abova_, ut,ing tha cffluent concentration limit specified in the parait for.the period and thc averag: of measurci daily flows (up to t% allopbic flow) over th: p0riod.

13. ":'aximua Allowable Six 'ionth '*adian : lass Emission F.ato" is a daily rata determined 'iith the fornulas in paragraph G.ll, abovo, using tha "Six-:lonth ilsdian" cffluent limit specified in the pomit, and the avcragc of naasured daily flows (up to the allow:ble flow) ovtr a lE0-day pericd.

. c i f, . "1adian'"is th0 value b: lou which half the samplis (rankad progress- '

ively by increasing value) fall. It nav be considcred the niddic valuc, or the average of two niddic vallcs. Toscvalid,thrscor, nor0 valucs are required.

15. ";1onthly Avaragc" (or "Ucakly Averago," as the casa may be) is th arithnetic coan of daily concentrations or of daily mass caission rat:s over the specified 30-day (or 7-day) period:

Averagc = 1 (X) +X 2+ . +X;g),

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d. Dischargo pollutants, cither alone or in conjunction with pollutants from other sources, that incrocsc the acanitudo or duration of p:rmit violations.
25. "Six.rlonth lodian" m:ans a " median" of results from sampics taken over any periad of 180 consecutive dcys.

2G. " Toxic Pollutant" means any pollutant listed as toxic under Section 307(a) (1) of the Clean Ihter f.ct or under 40 CFR Part 122, Appendix D. ,

Violction of r.aximum daily dischcrgo limitations cro subject to 20- /

hour rcperting (Paragraph C.4.). 3 .

27. " Upset" means an cxceptienc1 incident causing r.onconpiiance with technology-based parmit offluent limitation:. because of factors beyond th: rocsoncblo control of the permittoa. It'does not include non-complianco caused by operational crror, improperly designed treat-mont facilities, inadequato treatmant facilit(cs,1cck of preventative maintenanco, or carelass or improper op;r: tion.

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28. "Zonc of Initial Dilution" means the rogfin surrounding or adj: cent to tha and of an outfall pipa or diffusar ports whose boundaries arc defined through calculation of plume modal verified by the "

Stata "1tcr Rasourcos Control Board.

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