ML18010A312
| ML18010A312 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 01/31/2014 |
| From: | Swanson M, Vania I TestAmerica Labs - St. Louis, Westinghouse |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| ML18010A247 | List:
|
| References | |
| HEM-17-72 160-5313-1 | |
| Download: ML18010A312 (21) | |
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-5313-1 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:
1/31/2014 4:49:15 PM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-5313-1 Page 2 of 21 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
7 Definitions/Glossary.......................................
8 Method Summary.........................................
9 Sample Summary.........................................
10 Client Sample Results......................................
11 QC Sample Results........................................
17 QC Association Summary...................................
19 Tracer Carrier Summary....................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-5313-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-5313-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-5313-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 01/27/2014; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 17.0 C.
TECHNETIUM-99 (ICPMS)
Samples L101017BRS00 (160-5313-1), L101018BES00 (160-5313-2), L101019BSS00 (160-5313-3), L101020BRS00 (160-5313-4),
L101021BRS00 (160-5313-5), L101023BRS00 (160-5313-6), L101025BRS00 (160-5313-7), L101026BES00 (160-5313-8),
L101027BSS00 (160-5313-9), L101028BRQ00 (160-5313-10), L101028BRS00 (160-5313-11), L101029BSS00 (160-5313-12),
L101030BRS00 (160-5313-13), L101031BES00 (160-5313-14), L101032BUB00 (160-5313-15) and L101033BUB00 (160-5313-16) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 01/29/2014 and analyzed on 01/31/2014.
No difficulties were encountered during the Tc-99 analysis. All quality control parameters were within the acceptance limits.
PERCENT SOLIDS TestAmerica St. Louis Page 3 of 21 1
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-5313-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-5313-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
Samples L101017BRS00 (160-5313-1), L101018BES00 (160-5313-2), L101019BSS00 (160-5313-3), L101020BRS00 (160-5313-4),
L101021BRS00 (160-5313-5), L101023BRS00 (160-5313-6), L101025BRS00 (160-5313-7), L101026BES00 (160-5313-8),
L101027BSS00 (160-5313-9), L101028BRQ00 (160-5313-10), L101028BRS00 (160-5313-11), L101029BSS00 (160-5313-12),
L101030BRS00 (160-5313-13), L101031BES00 (160-5313-14), L101032BUB00 (160-5313-15) and L101033BUB00 (160-5313-16) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 01/28/2014.
No difficulties were encountered during the % solids analysis. All quality control parameters were within the acceptance limits.
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10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Page 1 ofl Hematite Decommissioning Project !Revision: 3 I
I Westingl,ouse Non-Proprietny Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.
Chain of Cutody ID No. I F-012714-01 Page 1/2 Project Name:
Westinghouse Electric Company Contact Person:
Gerald Rood Phone Number:
314-810-3382 Sampler Name Scott Jenkins Sample ID L1010 l 7BRSOO Ll01018BESOO L101019BSSOO L101020BRSOO L10102 lBRSOO L101023BRSOO L101025BRSOO Ll O 1026BESOO Ll01027BSSOO Ll O 1028BRQOO Ll O 1028BRSOO L101029BSSOO Relinquished by:
Company Name: u) £:.L Received by:
Company Name:
Relinquished by:
Company Name:
Date Time
!Matrix 1/25/2014 8:401 S
1/25/2014 8:451 S
1/25/2014 8:501 S
1/25/2014 9:001 S
1/25/2014 9:201 S
1/25/2014 14:301 S
1/25/2014 10:001 s 1/25/2014 10:051 S
1/25/2014 10:151 S
1/25/2014 10:251 S
1/25/2014 10:251 S
1/25/2014 10:40 r
Date/Time Company Name:
--.i4-Laboratory Name:
TA-MO Laboratory Address:
13715 Rider Trail North
~ =-------------------
- g PhoneNo.
=
8 314-298-8566
'I§ Laboratory Contact Person:
~ foe Walker Phone No.
708-870-8453 Ium Around Time Rush (7 days)
Remarks 1 LSA-10-10 Sys. Samples 1 LSA-10-10 Sys. Samples 1 LSA-10-10 Sys. Samples 1 LSA-10-10 Sys. Samples 1 LSA-10-10 Sys. Samples 1 LSA-10-10 Sys. Samples 1 LSA-10-10 Sys. Samples 1 LSA-10-10 Sys_ Samples 1 LSA-10-10 Sys. Samples 1 LSA-10-10 QC Sample I LSA-10-10 Sys. Samples 1 LSA-10-10 Sys. Samples Cooler Temperature:
Cooler ID: !Shipper and Number:
127-Date/Time
!Comments: Please analyze samples for Tc-99 on a 7 day TAT.
qate!yime t(v11rif l 'O'l;)
Please analyze samples for gamma spec after a 21 day in growth period.
Verified By:
C--V'-t-:-S w~f d.J-r
~
(j\\J uJ
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10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Page 1 ofl Hematite Decommissioning Project !Revision: :3 I
I Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.
Chain of Cutody ID No. I F-012714-01 Page 2/2 Project Name:
Westinghouse Electric Company Contact Person:
Gerald Rood Phone Number:
314-810-3382 Sampler Name Scott Jenkins Sample ID Ll O 1030BRSOO Ll 0103 lBESOO Ll01032BUBOO Ll01033BUBOO Received bv:
Company Name:
Relinquished by:
Company Name:
Date Time 1/25/2014 11:00 1/25/2014 8:30 1/25/2014 14:00 1/25/2014 14:10 Date/fime Date/Time Matrix s
s s
s Compan.lc-~e:
Date/fime
\\"'i ~~30 Date/fime v,i11qJP Dfte/fjme i/ 1---,, {,y 1.,bU)
Laboratory Name:
TA-MO Laboratory Address:
13715 Rider Trail North
- ~-------------------
".§ PhoneNo.
8 314-298-8566
~ Laboratory Contact Person:
~ Joe Walker Phone No.
708-870-8453 Turn Around Time Rush (7 days)
Remarks LSA-10-10 Sys. Samples 1 ILSA-10-10 Sys. Samples LSA-10-10 Bias Samples 1 ILSA-10-10 Bias Samples Cooler Temperature:
Ambient Cooler ID: I Shipper and Number:
27-02 Comments: Please analyze samples for Tc-99 on a 7 day TAT.
Please analyze samples for gamma spec after a 21 day in growth period.
Verified By: C,.0,-,-h~
~~ I J...t.-,,---
~
Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-5313-1 Login Number: 5313 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
False Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
Thermal preservation not required.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Rad Qualifier Description U
Result is less than the sample detection limit.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL Protocol
References:
EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 9 of 21 1
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Sample Summary TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-5313-1 L101017BRS00 Solid 01/25/14 08:40 01/27/14 18:00 160-5313-2 L101018BES00 Solid 01/25/14 08:45 01/27/14 18:00 160-5313-3 L101019BSS00 Solid 01/25/14 08:50 01/27/14 18:00 160-5313-4 L101020BRS00 Solid 01/25/14 09:00 01/27/14 18:00 160-5313-5 L101021BRS00 Solid 01/25/14 09:20 01/27/14 18:00 160-5313-6 L101023BRS00 Solid 01/25/14 14:30 01/27/14 18:00 160-5313-7 L101025BRS00 Solid 01/25/14 10:00 01/27/14 18:00 160-5313-8 L101026BES00 Solid 01/25/14 10:05 01/27/14 18:00 160-5313-9 L101027BSS00 Solid 01/25/14 10:15 01/27/14 18:00 160-5313-10 L101028BRQ00 Solid 01/25/14 10:25 01/27/14 18:00 160-5313-11 L101028BRS00 Solid 01/25/14 10:25 01/27/14 18:00 160-5313-12 L101029BSS00 Solid 01/25/14 10:40 01/27/14 18:00 160-5313-13 L101030BRS00 Solid 01/25/14 11:00 01/27/14 18:00 160-5313-14 L101031BES00 Solid 01/25/14 08:30 01/27/14 18:00 160-5313-15 L101032BUB00 Solid 01/25/14 14:00 01/27/14 18:00 160-5313-16 L101033BUB00 Solid 01/25/14 14:10 01/27/14 18:00 TestAmerica St. Louis Page 10 of 21 1
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Client Sample Results TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-5313-1 Client Sample ID: L101017BRS00 Matrix: Solid Date Collected: 01/25/14 08:40 Percent Solids: 72.7 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000073 0.000022 mg/Kg
01/29/14 12:15 01/31/14 12:24 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.283 (2+/-)
0.111 (2+/-)
1 01/31/14 12:24 01/29/14 12:15 pCi/g 0.249 1.46 RL MDC 0.102 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 12:24 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 95 Lab Sample ID: 160-5313-2 Client Sample ID: L101018BES00 Matrix: Solid Date Collected: 01/25/14 08:45 Percent Solids: 75.4 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000076 0.000023 mg/Kg
01/29/14 12:15 01/31/14 12:44 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0375 U
(2+/-)
0.0340 (2+/-)
1 01/31/14 12:44 01/29/14 12:15 pCi/g 0.261 1.52 RL MDC 0.0292 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 12:44 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 87 Lab Sample ID: 160-5313-3 Client Sample ID: L101019BSS00 Matrix: Solid Date Collected: 01/25/14 08:50 Percent Solids: 80.8 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000019 mg/Kg
01/29/14 12:15 01/31/14 12:47 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.207 U
(2+/-)
0.0878 (2+/-)
1 01/31/14 12:47 01/29/14 12:15 pCi/g 0.221 1.29 RL MDC 0.0824 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 12:47 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 96 TestAmerica St. Louis Page 11 of 21 1
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Client Sample Results TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-5313-4 Client Sample ID: L101020BRS00 Matrix: Solid Date Collected: 01/25/14 09:00 Percent Solids: 82.0 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
01/29/14 12:15 01/31/14 12:51 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.124 U
(2+/-)
0.0746 (2+/-)
1 01/31/14 12:51 01/29/14 12:15 pCi/g 0.220 1.29 RL MDC 0.0693 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 12:51 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Lab Sample ID: 160-5313-5 Client Sample ID: L101021BRS00 Matrix: Solid Date Collected: 01/25/14 09:20 Percent Solids: 79.1 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg
01/29/14 12:15 01/31/14 12:55 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0495 U
(2+/-)
0.00605 (2+/-)
1 01/31/14 12:55 01/29/14 12:15 pCi/g 0.229 1.34 RL MDC 0.00341 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 12:55 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Lab Sample ID: 160-5313-6 Client Sample ID: L101023BRS00 Matrix: Solid Date Collected: 01/25/14 14:30 Percent Solids: 80.2 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg
01/29/14 12:15 01/31/14 12:59 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.320 (2+/-)
0.0436 (2+/-)
1 01/31/14 12:59 01/29/14 12:15 pCi/g 0.225 1.31 RL MDC 0.0290 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 12:59 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 95 Lab Sample ID: 160-5313-7 Client Sample ID: L101025BRS00 Matrix: Solid Date Collected: 01/25/14 10:00 Percent Solids: 88.0 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000060 0.000018 mg/Kg
01/29/14 12:15 01/31/14 13:03 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier TestAmerica St. Louis Page 12 of 21 1
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Client Sample Results TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-5313-7 Client Sample ID: L101025BRS00 Matrix: Solid Date Collected: 01/25/14 10:00 Percent Solids: 88.0 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0428 U
(2+/-)
0.0390 (2+/-)
1 01/31/14 13:03 01/29/14 12:15 pCi/g 0.207 1.21 RL MDC 0.0366 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:03 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Lab Sample ID: 160-5313-8 Client Sample ID: L101026BES00 Matrix: Solid Date Collected: 01/25/14 10:05 Percent Solids: 81.8 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000020 mg/Kg
01/29/14 12:15 01/31/14 13:07 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0499 U
(2+/-)
0.0674 (2+/-)
1 01/31/14 13:07 01/29/14 12:15 pCi/g 0.224 1.31 RL MDC 0.0630 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:07 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Lab Sample ID: 160-5313-9 Client Sample ID: L101027BSS00 Matrix: Solid Date Collected: 01/25/14 10:15 Percent Solids: 83.9 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000063 0.000019 mg/Kg
01/29/14 12:15 01/31/14 13:11 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.303 (2+/-)
0.0909 (2+/-)
1 01/31/14 13:11 01/29/14 12:15 pCi/g 0.217 1.27 RL MDC 0.0799 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:11 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 93 Lab Sample ID: 160-5313-10 Client Sample ID: L101028BRQ00 Matrix: Solid Date Collected: 01/25/14 10:25 Percent Solids: 82.7 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
01/29/14 12:15 01/31/14 13:14 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier TestAmerica St. Louis Page 13 of 21 1
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Client Sample Results TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-5313-10 Client Sample ID: L101028BRQ00 Matrix: Solid Date Collected: 01/25/14 10:25 Percent Solids: 82.7 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.160 U
(2+/-)
0.0678 (2+/-)
1 01/31/14 13:14 01/29/14 12:15 pCi/g 0.219 1.28 RL MDC 0.0622 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:14 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Lab Sample ID: 160-5313-11 Client Sample ID: L101028BRS00 Matrix: Solid Date Collected: 01/25/14 10:25 Percent Solids: 83.2 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000063 0.000019 mg/Kg
01/29/14 12:15 01/31/14 13:26 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.283 (2+/-)
0.150 (2+/-)
1 01/31/14 13:26 01/29/14 12:15 pCi/g 0.217 1.27 RL MDC 0.139 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:26 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Lab Sample ID: 160-5313-12 Client Sample ID: L101029BSS00 Matrix: Solid Date Collected: 01/25/14 10:40 Percent Solids: 82.9 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
01/29/14 12:15 01/31/14 13:30 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.193 U
(2+/-)
0.106 (2+/-)
1 01/31/14 13:30 01/29/14 12:15 pCi/g 0.220 1.29 RL MDC 0.0968 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:30 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 93 Lab Sample ID: 160-5313-13 Client Sample ID: L101030BRS00 Matrix: Solid Date Collected: 01/25/14 11:00 Percent Solids: 83.2 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000062 0.000019 mg/Kg
01/29/14 12:15 01/31/14 13:34 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier TestAmerica St. Louis Page 14 of 21 1
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Client Sample Results TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-5313-13 Client Sample ID: L101030BRS00 Matrix: Solid Date Collected: 01/25/14 11:00 Percent Solids: 83.2 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0119 U
(2+/-)
0.0331 (2+/-)
1 01/31/14 13:34 01/29/14 12:15 pCi/g 0.213 1.25 RL MDC
-0.0318 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:34 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 96 Lab Sample ID: 160-5313-14 Client Sample ID: L101031BES00 Matrix: Solid Date Collected: 01/25/14 08:30 Percent Solids: 80.0 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg
01/29/14 12:15 01/31/14 13:38 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0173 U
(2+/-)
0.0167 (2+/-)
1 01/31/14 13:38 01/29/14 12:15 pCi/g 0.228 1.33 RL MDC 0.0156 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:38 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Lab Sample ID: 160-5313-15 Client Sample ID: L101032BUB00 Matrix: Solid Date Collected: 01/25/14 14:00 Percent Solids: 81.3 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
01/29/14 12:15 01/31/14 13:42 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0157 U
(2+/-)
0.0121 (2+/-)
1 01/31/14 13:42 01/29/14 12:15 pCi/g 0.218 1.27 RL MDC 0.0117 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:42 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 97 Lab Sample ID: 160-5313-16 Client Sample ID: L101033BUB00 Matrix: Solid Date Collected: 01/25/14 14:10 Percent Solids: 83.8 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
01/29/14 12:15 01/31/14 13:45 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier TestAmerica St. Louis Page 15 of 21 1
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Client Sample Results TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-5313-16 Client Sample ID: L101033BUB00 Matrix: Solid Date Collected: 01/25/14 14:10 Percent Solids: 83.8 Date Received: 01/27/14 18:00 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.222 (2+/-)
0.0456 (2+/-)
1 01/31/14 13:45 01/29/14 12:15 pCi/g 0.220 1.28 RL MDC 0.0374 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 01/29/14 12:15 01/31/14 13:45 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 93 TestAmerica St. Louis Page 16 of 21 1
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QC Sample Results TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-102058/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 102652 Prep Batch: 102058 RL MDL Technetium 99 ND 0.000048 0.000015 mg/Kg 01/29/14 12:15 01/31/14 12:16 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-102058/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 102652 Prep Batch: 102058 Technetium 99 0.00240 0.00238 mg/Kg 99 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: L101017BRS00 Lab Sample ID: 160-5313-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 102652 Prep Batch: 102058 Technetium 99 ND 0.00328 0.00331 mg/Kg 101 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: L101017BRS00 Lab Sample ID: 160-5313-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 102652 Prep Batch: 102058 Technetium 99 ND 0.00331 0.00334 mg/Kg 101 75 - 125 1
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-102058/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 102653 Prep Batch: 102058 Technetium 99 Analyte U
1 01/31/14 12:16 01/29/14 12:15 pCi/g 0.166 MDC 0.967 RL 0.0389 0.0398 (2+/-)
(2+/-)
MB 0.05943 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 01/29/14 12:15 01/31/14 12:16 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 103 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-102058/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 102653 Prep Batch: 102058 Technetium 99 Analyte 120 80 99 40.82 41.2 4.12 0.999 0.171 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 100 LCS TestAmerica St. Louis Page 17 of 21 1
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QC Sample Results TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: L101017BRS00 Lab Sample ID: 160-5313-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 102653 Prep Batch: 102058 Technetium 99 Analyte 125 75 100 56.70 56.2 0.283 5.53 1.44 0.247 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 95 MS Client Sample ID: L101017BRS00 Lab Sample ID: 160-5313-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 102653 Prep Batch: 102058 Technetium 99 Analyte 1
0.05 125 75 101 57.27 56.6 0.283 5.85 1.47 0.252 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 94 MSD TestAmerica St. Louis Page 18 of 21 1
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QC Association Summary TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Metals Prep Batch: 102058 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-5313-1 L101017BRS00 Total/NA Solid None 160-5313-1 MS L101017BRS00 Total/NA Solid None 160-5313-1 MSD L101017BRS00 Total/NA Solid None 160-5313-2 L101018BES00 Total/NA Solid None 160-5313-3 L101019BSS00 Total/NA Solid None 160-5313-4 L101020BRS00 Total/NA Solid None 160-5313-5 L101021BRS00 Total/NA Solid None 160-5313-6 L101023BRS00 Total/NA Solid None 160-5313-7 L101025BRS00 Total/NA Solid None 160-5313-8 L101026BES00 Total/NA Solid None 160-5313-9 L101027BSS00 Total/NA Solid None 160-5313-10 L101028BRQ00 Total/NA Solid None 160-5313-11 L101028BRS00 Total/NA Solid None 160-5313-12 L101029BSS00 Total/NA Solid None 160-5313-13 L101030BRS00 Total/NA Solid None 160-5313-14 L101031BES00 Total/NA Solid None 160-5313-15 L101032BUB00 Total/NA Solid None 160-5313-16 L101033BUB00 Total/NA Solid None LCS 160-102058/2-A Lab Control Sample Total/NA Solid None MB 160-102058/1-A Method Blank Total/NA Analysis Batch: 102652 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 102058 160-5313-1 L101017BRS00 Total/NA Solid 6020A 102058 160-5313-1 MS L101017BRS00 Total/NA Solid 6020A 102058 160-5313-1 MSD L101017BRS00 Total/NA Solid 6020A 102058 160-5313-2 L101018BES00 Total/NA Solid 6020A 102058 160-5313-3 L101019BSS00 Total/NA Solid 6020A 102058 160-5313-4 L101020BRS00 Total/NA Solid 6020A 102058 160-5313-5 L101021BRS00 Total/NA Solid 6020A 102058 160-5313-6 L101023BRS00 Total/NA Solid 6020A 102058 160-5313-7 L101025BRS00 Total/NA Solid 6020A 102058 160-5313-8 L101026BES00 Total/NA Solid 6020A 102058 160-5313-9 L101027BSS00 Total/NA Solid 6020A 102058 160-5313-10 L101028BRQ00 Total/NA Solid 6020A 102058 160-5313-11 L101028BRS00 Total/NA Solid 6020A 102058 160-5313-12 L101029BSS00 Total/NA Solid 6020A 102058 160-5313-13 L101030BRS00 Total/NA Solid 6020A 102058 160-5313-14 L101031BES00 Total/NA Solid 6020A 102058 160-5313-15 L101032BUB00 Total/NA Solid 6020A 102058 160-5313-16 L101033BUB00 Total/NA Solid 6020A 102058 LCS 160-102058/2-A Lab Control Sample Total/NA Solid 6020A 102058 MB 160-102058/1-A Method Blank Total/NA General Chemistry Analysis Batch: 101585 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-5313-1 L101017BRS00 Total/NA Solid Moisture 160-5313-2 L101018BES00 Total/NA TestAmerica St. Louis Page 19 of 21 1
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QC Association Summary TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
General Chemistry (Continued)
Analysis Batch: 101585 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-5313-3 L101019BSS00 Total/NA Solid Moisture 160-5313-3 DU L101019BSS00 Total/NA Solid Moisture 160-5313-4 L101020BRS00 Total/NA Solid Moisture 160-5313-5 L101021BRS00 Total/NA Solid Moisture 160-5313-6 L101023BRS00 Total/NA Solid Moisture 160-5313-7 L101025BRS00 Total/NA Solid Moisture 160-5313-8 L101026BES00 Total/NA Solid Moisture 160-5313-9 L101027BSS00 Total/NA Solid Moisture 160-5313-10 L101028BRQ00 Total/NA Solid Moisture 160-5313-11 L101028BRS00 Total/NA Solid Moisture 160-5313-12 L101029BSS00 Total/NA Solid Moisture 160-5313-13 L101030BRS00 Total/NA Solid Moisture 160-5313-14 L101031BES00 Total/NA Solid Moisture 160-5313-15 L101032BUB00 Total/NA Solid Moisture 160-5313-16 L101033BUB00 Total/NA Solid Moisture 160-5313-16 DU L101033BUB00 Total/NA Rad Prep Batch: 102058 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-5313-1 L101017BRS00 Total/NA Solid None 160-5313-1 MS L101017BRS00 Total/NA Solid None 160-5313-1 MSD L101017BRS00 Total/NA Solid None 160-5313-2 L101018BES00 Total/NA Solid None 160-5313-3 L101019BSS00 Total/NA Solid None 160-5313-4 L101020BRS00 Total/NA Solid None 160-5313-5 L101021BRS00 Total/NA Solid None 160-5313-6 L101023BRS00 Total/NA Solid None 160-5313-7 L101025BRS00 Total/NA Solid None 160-5313-8 L101026BES00 Total/NA Solid None 160-5313-9 L101027BSS00 Total/NA Solid None 160-5313-10 L101028BRQ00 Total/NA Solid None 160-5313-11 L101028BRS00 Total/NA Solid None 160-5313-12 L101029BSS00 Total/NA Solid None 160-5313-13 L101030BRS00 Total/NA Solid None 160-5313-14 L101031BES00 Total/NA Solid None 160-5313-15 L101032BUB00 Total/NA Solid None 160-5313-16 L101033BUB00 Total/NA Solid None LCS 160-102058/2-A Lab Control Sample Total/NA Solid None MB 160-102058/1-A Method Blank Total/NA TestAmerica St. Louis Page 20 of 21 1
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Tracer/Carrier Summary TestAmerica Job ID: 160-5313-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 95 160-5313-1 Percent Yield (Acceptance Limits)
L101017BRS00 95 160-5313-1 MS L101017BRS00 94 160-5313-1 MSD L101017BRS00 87 160-5313-2 L101018BES00 96 160-5313-3 L101019BSS00 94 160-5313-4 L101020BRS00 94 160-5313-5 L101021BRS00 95 160-5313-6 L101023BRS00 94 160-5313-7 L101025BRS00 94 160-5313-8 L101026BES00 93 160-5313-9 L101027BSS00 94 160-5313-10 L101028BRQ00 94 160-5313-11 L101028BRS00 93 160-5313-12 L101029BSS00 96 160-5313-13 L101030BRS00 94 160-5313-14 L101031BES00 97 160-5313-15 L101032BUB00 93 160-5313-16 L101033BUB00 100 LCS 160-102058/2-A Lab Control Sample 103 MB 160-102058/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 21 of 21 1
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