ML18010A287
| ML18010A287 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 01/13/2014 |
| From: | Swanson M, Vania I TestAmerica Labs - St. Louis, Westinghouse |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| ML18010A247 | List:
|
| References | |
| HEM-17-72 160-4704-2 | |
| Download: ML18010A287 (15) | |
Text
{{#Wiki_filter:ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-4704-2 Client Project/Site: RFP-CBA-022 (21 DAY TAT) For: Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by: 1/13/2014 4:30:35 PM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. 1 2 3 4 5 6 7 8 9 10 11
Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) TestAmerica Job ID: 160-4704-2 Page 2 of 15 Cover Page.............................................. 1 Table of Contents......................................... 2 Case Narrative........................................... 3 Chain of Custody.......................................... 4 Receipt Checklists......................................... 5 Definitions/Glossary....................................... 6 Method Summary......................................... 7 Sample Summary......................................... 8 Client Sample Results...................................... 9 QC Sample Results........................................ 14 QC Association Summary................................... 15 1 2 3 4 5 6 7 8 9 10 11
Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-4704-2 Project/Site: RFP-CBA-022 (21 DAY TAT) Job ID: 160-4704-2 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (21 DAY TAT) Report Number: 160-4704-2 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required. TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below. The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory. Calculations are performed before rounding to avoid round-off errors in calculated results. All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below. All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a % solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client. This laboratory report is confidential and is intended for the sole use of TestAmerica and its client. RECEIPT The samples were received on 11/27/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 2.2 C. RADIUM-226 BY GAMMA SPEC (21 DAY INGROWTH) Samples L100601BES00 (160-4704-1), L100602BES00 (160-4704-2), L100603BES00 (160-4704-3), L100604BES00 (160-4704-4), L100605BRQ00 (160-4704-5), L100605BRS00 (160-4704-6), L100606BES00 (160-4704-7), L100607BES00 (160-4704-8), L100608BES00 (160-4704-9) and L100609BES00 (160-4704-10) were analyzed for Radium-226 by gamma spec (21 day ingrowth) in accordance with EPA GA_01_R. The samples were leached on 12/18/2013, prepared on 12/20/2013 and analyzed on 01/10/2014. No other difficulties were encountered during the Radium 226 analysis. All other quality control parameters were within the acceptance limits. TestAmerica St. Louis Page 3 of 15 1 2 3 4 5 6 7 8 9 10 11
Page 4 of 15 1 2 3 4 5 6 7 8 9 10 11 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision: 3 I Page I ofl Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAJN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP. Chain of Cutodv ID No. F-112713-01 Pa!!e 1/1 ...,,,;.]}{eaueSfed An~lysis Laboratorv Name: Project Name: '~\\*,',;i ,-._ I'
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TA-MO \\0 Westinghouse Electric ComplJily js, N ?'.' N
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Laboratory Address: rt;~ Gerald Rood '8 1*,.... l?~i 13715 Rider Trail North ~ ~
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t1i ~ ~ = Phone Number: 1,, **,, -~ Phone No. 314-810-3382 t~Ii",~; .5 I 8 314-298-8566 Sampler Name 1G' I> ~~ 2 Laboratory Contact Person: "O Scott Jenkins 8 § ~ Joe Walker N g ~- Phone No. ~ 0 . ~I (1) 708-870-8453 ~ 0., tt~ 0 r/J. Turn Around Time Q...... II Q el Ci I~< )
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E fJ~I'i Rush (7 days) s'., .8 § ~ ~:!, Sample ID Date Time Matrix i\\ 1 ti 0 i~t Remarks 0 ~ CJ u LI 0060IBESOO 11/26/2013 11:20 s C X X 1 L., A-( o -c>C.0 5v:s. Sa...""1./JJ.1.<. LI 00602BESOO 11/26/2013 11:05 s C 1, X
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) ~ I c::, LI 00603BESOO 11/26/2013 10:45 s C 3 X X 1 L100604BESOO 11/26/2013 10:55 s C [.',~,.+/-~. X X 1 L100605BRQOO 11/26/2013 9:50 s C b'!~fu X X 1 L100605BRSOO 11/26/2013 9:50 s C t,,} ' X X 1 L100606BESOO 11/26/2013 9:55 s C ')}~
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L 100607BESOO 11/26/2013 10:20 s C.**.* '\\-9-' X X 1 L100608BES00 11/26/2013 10:00 s C X X ' 1 ~. L100609BESOO 11/26/2013 10:15 s C ti,,, ,,X X 1 LSf:::.i -10,0~ <vs. c;t:L~PI.A. <
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j:'[{1, I. Relinquished bye__: _::.- Date/Time Recei~c/';/!~fi 1 crl' Date/Time Total Cooler Temoerature: [(,~*JJ f'r-1,..,-, J 10 ArnhiPnt Company Name: LO b-l..- Company ~e: I,"',.... -, Cooler ID: Shiooer and Number: r I'.,.,- l 12fi-/'\\'J Received by: Date/Time Relintshed by: Date/Time Comments: Please provide Tc-99 results on a 7 day TAT. Please '\\ /t*""- ll"'\\.'7-{) analyze the samples for gamma spec. after a 21 day ingrowth ComoanY Name: Compaey Name: I~ fijl period. e,.. I'\\. l., Relinquished by: Date/Time Rer:!fd/JY~ Date/Time Ji *;;2.t* t3 Ve~By: Company Name: Com~4Sfl-- r-JSofJ -?* ~ C) --+
Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-4704-2 Login Number: 4704 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter. True The cooler's custody seal, if present, is intact. N/A Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or tampered with. False Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. Thermal preservation not required. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time. True Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is <6mm (1/4"). True Multiphasic samples are not present. True Samples do not require splitting or compositing. N/A Residual Chlorine Checked. TestAmerica St. Louis Page 5 of 15 1 2 3 4 5 6 7 8 9 10 11
Definitions/Glossary TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Qualifiers Rad Qualifier Description U Indicates the analyte was analyzed for but not detected. Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation %R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference) Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin) NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TestAmerica St. Louis Page 6 of 15 1 2 3 4 5 6 7 8 9 10 11
Method Summary TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Method Method Description Laboratory Protocol DOE GA-01-R Radium-226 & Other Gamma Emitters (GS) TAL SL Protocol
References:
DOE = U.S. Department of Energy Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 7 of 15 1 2 3 4 5 6 7 8 9 10 11
Sample Summary TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Lab Sample ID Client Sample ID Received Collected Matrix 160-4704-1 L100601BES00 Solid 11/26/13 11:20 11/27/13 15:00 160-4704-2 L100602BES00 Solid 11/26/13 11:05 11/27/13 15:00 160-4704-3 L100603BES00 Solid 11/26/13 10:45 11/27/13 15:00 160-4704-4 L100604BES00 Solid 11/26/13 10:55 11/27/13 15:00 160-4704-5 L100605BRQ00 Solid 11/26/13 09:50 11/27/13 15:00 160-4704-6 L100605BRS00 Solid 11/26/13 09:50 11/27/13 15:00 160-4704-7 L100606BES00 Solid 11/26/13 09:55 11/27/13 15:00 160-4704-8 L100607BES00 Solid 11/26/13 10:20 11/27/13 15:00 160-4704-9 L100608BES00 Solid 11/26/13 10:00 11/27/13 15:00 160-4704-10 L100609BES00 Solid 11/26/13 10:15 11/27/13 15:00 TestAmerica St. Louis Page 8 of 15 1 2 3 4 5 6 7 8 9 10 11
Client Sample Results TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Lab Sample ID: 160-4704-1 Client Sample ID: L100601BES00 Matrix: Solid Date Collected: 11/26/13 11:20 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.04 (2+/-) 0.189 (2+/-) 1 01/10/14 17:09 12/20/13 10:21 pCi/g 0.184 RL MDC 0.156 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.469 0.359 0.348 0.819 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.0864 0.188 0.135 1.26 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.0683 0.151 0.0783 1.00 Lead 212 pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.0726 0.180 0.101 1.44 Lead 214 pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.259 2.09 1.22 16.6 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 17:09 1 1.41 0.856 0.853 U -0.591 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.0864 1.00 0.188 0.135 1.26 Radium 226 pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.184 0.189 0.156 1.04 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 17:09 1 1.01 0.861 0.839 1.84 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.278 0.160 0.160 U 0.142 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 17:09 1 0.114 0.0672 0.0672 U 0.000206 Americium 241 pCi/g 12/20/13 10:21 01/10/14 17:09 1 6.62 3.69 3.69 U 0.0192 Protactinium 234m Lab Sample ID: 160-4704-2 Client Sample ID: L100602BES00 Matrix: Solid Date Collected: 11/26/13 11:05 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.06 (2+/-) 0.153 (2+/-) 1 01/10/14 17:10 12/20/13 10:21 pCi/g 0.113 RL MDC 0.108 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.335 0.369 0.351 1.09 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.0695 0.147 0.101 1.03 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.0546 0.163 0.0694 1.14 Lead 212 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.0684 0.156 0.0876 1.24 Lead 214 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.377 2.33 1.14 19.9 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 17:10 1 1.02 0.277 0.272 U 0.491 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.0695 1.00 0.147 0.101 1.03 Radium 226 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.113 0.153 0.108 1.06 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.813 0.342 0.323 1.06 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.171 0.130 0.129 U 0.165 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 17:10 1 0.0975 0.0579 0.0579 U 0.00379 Americium 241 pCi/g 12/20/13 10:21 01/10/14 17:10 1 4.40 2.46 2.46 U 0.594 Protactinium 234m Lab Sample ID: 160-4704-3 Client Sample ID: L100603BES00 Matrix: Solid Date Collected: 11/26/13 10:45 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.04 (2+/-) 0.236 (2+/-) 1 01/10/14 17:13 12/20/13 10:21 pCi/g 0.145 RL MDC 0.211 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:13 1 0.536 0.573 0.554 1.42 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 17:13 1 0.0880 0.187 0.138 1.22 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 17:13 1 0.0747 0.162 0.0838 1.07 Lead 212 TestAmerica St. Louis Page 9 of 15 1 2 3 4 5 6 7 8 9 10 11
Client Sample Results TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Lab Sample ID: 160-4704-3 Client Sample ID: L100603BES00 Matrix: Solid Date Collected: 11/26/13 10:45 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued) Analyte Lead 214 1.20 (2+/-) 0.177 (2+/-) 1 01/10/14 17:13 12/20/13 10:21 pCi/g 0.0931 RL MDC 0.125 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:13 1 0.299 2.36 1.36 18.9 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 17:13 1 1.43 0.340 0.333 U 0.608 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 17:13 1 0.0880 1.00 0.187 0.138 1.22 Radium 226 pCi/g 12/20/13 10:21 01/10/14 17:13 1 0.145 0.236 0.211 1.04 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 17:13 1 1.01 0.432 0.399 1.58 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 17:13 1 0.227 0.183 0.178 0.385 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 17:13 1 0.0999 0.0593 0.0593 U 0.0137 Americium 241 pCi/g 12/20/13 10:21 01/10/14 17:13 1 5.68 1.24 1.24 U 0.000 Protactinium 234m Lab Sample ID: 160-4704-4 Client Sample ID: L100604BES00 Matrix: Solid Date Collected: 11/26/13 10:55 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.09 (2+/-) 0.176 (2+/-) 1 01/10/14 17:46 12/20/13 10:21 pCi/g 0.134 RL MDC 0.136 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.461 0.501 0.484 1.25 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.0756 0.178 0.130 1.17 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.0680 0.165 0.0841 1.10 Lead 212 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.0795 0.155 0.110 1.05 Lead 214 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.316 1.96 1.24 14.9 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 17:46 1 1.30 0.372 0.367 U 0.572 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.0756 1.00 0.178 0.130 1.17 Radium 226 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.134 0.176 0.136 1.09 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.936 0.740 0.724 1.48 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.249 0.147 0.147 U 0.108 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 17:46 1 0.117 0.0690 0.0690 U -0.00108 Americium 241 pCi/g 12/20/13 10:21 01/10/14 17:46 1 6.50 3.76 3.76 U 1.51 Protactinium 234m Lab Sample ID: 160-4704-5 Client Sample ID: L100605BRQ00 Matrix: Solid Date Collected: 11/26/13 09:50 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.14 (2+/-) 0.190 (2+/-) 1 01/10/14 17:51 12/20/13 10:21 pCi/g 0.135 RL MDC 0.150 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.450 0.460 0.445 1.12 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.0609 0.164 0.112 1.15 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.0678 0.168 0.0805 1.14 Lead 212 pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.0730 0.162 0.0977 1.25 Lead 214 pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.352 2.24 1.25 18.2 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 17:51 1 1.14 0.290 0.284 U 0.552 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.0609 1.00 0.164 0.112 1.15 Radium 226 TestAmerica St. Louis Page 10 of 15 1 2 3 4 5 6 7 8 9 10 11
Client Sample Results TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Lab Sample ID: 160-4704-5 Client Sample ID: L100605BRQ00 Matrix: Solid Date Collected: 11/26/13 09:50 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued) Analyte Thorium 232 1.14 (2+/-) 0.190 (2+/-) 1 01/10/14 17:51 12/20/13 10:21 pCi/g 0.135 RL MDC 0.150 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.807 0.328 0.312 0.960 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.254 0.150 0.150 U 0.0297 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 17:51 1 0.114 0.769 0.769 U -0.00586 Americium 241 pCi/g 12/20/13 10:21 01/10/14 17:51 1 5.28 3.13 3.13 U 1.82 Protactinium 234m Lab Sample ID: 160-4704-6 Client Sample ID: L100605BRS00 Matrix: Solid Date Collected: 11/26/13 09:50 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.07 (2+/-) 0.186 (2+/-) 1 01/10/14 17:52 12/20/13 10:21 pCi/g 0.187 RL MDC 0.150 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.523 0.664 0.640 1.72 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0931 0.162 0.119 1.07 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0727 0.158 0.0836 1.03 Lead 212 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0919 0.191 0.132 1.33 Lead 214 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.430 2.27 1.37 17.7 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.984 4.44 4.44 U 0.0103 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0931 1.00 0.162 0.119 1.07 Radium 226 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.187 0.186 0.150 1.07 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 17:52 1 1.04 0.869 0.856 1.43 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.196 0.150 0.149 U 0.152 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.121 0.0731 0.0730 U 0.0456 Americium 241 pCi/g 12/20/13 10:21 01/10/14 17:52 1 6.36 3.85 3.84 U 2.89 Protactinium 234m Lab Sample ID: 160-4704-7 Client Sample ID: L100606BES00 Matrix: Solid Date Collected: 11/26/13 09:55 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.09 (2+/-) 0.154 (2+/-) 1 01/10/14 17:52 12/20/13 10:21 pCi/g 0.0822 RL MDC 0.106 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.421 0.513 0.492 1.38 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0652 0.156 0.104 1.12 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0569 0.159 0.0707 1.10 Lead 212 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0593 0.159 0.0923 1.24 Lead 214 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.204 2.07 1.04 17.4 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 17:52 1 1.03 0.242 0.238 U 0.420 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0652 1.00 0.156 0.104 1.12 Radium 226 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0822 0.154 0.106 1.09 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.874 0.680 0.668 1.22 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.186 0.116 0.116 U 0.0879 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 17:52 1 0.0959 0.0571 0.0571 U 0.0116 Americium 241 TestAmerica St. Louis Page 11 of 15 1 2 3 4 5 6 7 8 9 10 11
Client Sample Results TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Lab Sample ID: 160-4704-7 Client Sample ID: L100606BES00 Matrix: Solid Date Collected: 11/26/13 09:55 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued) Analyte Protactinium 234m -0.504 U (2+/-) 63.4 (2+/-) 1 01/10/14 17:52 12/20/13 10:21 pCi/g 5.01 RL MDC 63.4 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. Lab Sample ID: 160-4704-8 Client Sample ID: L100607BES00 Matrix: Solid Date Collected: 11/26/13 10:20 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.20 (2+/-) 0.193 (2+/-) 1 01/10/14 18:20 12/20/13 10:21 pCi/g 0.137 RL MDC 0.150 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.586 0.750 0.719 2.06 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.0915 0.184 0.138 1.17 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.0740 0.189 0.0944 1.27 Lead 212 pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.0918 0.194 0.135 1.34 Lead 214 pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.350 2.47 1.49 19.3 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 18:20 1 1.48 0.896 0.893 U -0.627 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.0915 1.00 0.184 0.138 1.17 Radium 226 pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.137 0.193 0.150 1.20 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 18:20 1 1.09 0.410 0.397 U 1.00 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.301 0.191 0.190 U 0.118 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 18:20 1 0.124 0.0753 0.0751 U 0.0502 Americium 241 pCi/g 12/20/13 10:21 01/10/14 18:20 1 7.29 3.73 3.73 U 1.05 Protactinium 234m Lab Sample ID: 160-4704-9 Client Sample ID: L100608BES00 Matrix: Solid Date Collected: 11/26/13 10:00 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.11 (2+/-) 0.187 (2+/-) 1 01/10/14 18:23 12/20/13 10:21 pCi/g 0.113 RL MDC 0.148 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.354 0.379 0.362 1.07 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.0644 0.151 0.101 1.08 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.0567 0.161 0.0715 1.11 Lead 212 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.0724 0.159 0.0962 1.21 Lead 214 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.316 2.24 1.11 19.0 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 18:23 1 1.15 0.287 0.282 U 0.494 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.0644 1.00 0.151 0.101 1.08 Radium 226 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.113 0.187 0.148 1.11 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.949 0.353 0.339 0.949 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.240 0.154 0.154 U 0.121 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 18:23 1 0.116 0.0692 0.0692 U -0.000466 Americium 241 pCi/g 12/20/13 10:21 01/10/14 18:23 1 5.38 2.99 2.99 U 0.347 Protactinium 234m TestAmerica St. Louis Page 12 of 15 1 2 3 4 5 6 7 8 9 10 11
Client Sample Results TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Lab Sample ID: 160-4704-10 Client Sample ID: L100609BES00 Matrix: Solid Date Collected: 11/26/13 10:15 Date Received: 11/27/13 15:00 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Analyte Actinium 228 1.07 (2+/-) 0.187 (2+/-) 1 01/10/14 18:24 12/20/13 10:21 pCi/g 0.116 RL MDC 0.151 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert. Uncert. pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.403 0.452 0.431 1.33 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.0851 0.164 0.117 1.11 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.0866 0.159 0.0820 1.05 Lead 212 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.0818 0.166 0.107 1.23 Lead 214 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.366 2.37 1.20 20.0 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 18:24 1 1.24 0.260 0.255 U 0.476 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.0851 1.00 0.164 0.117 1.11 Radium 226 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.116 0.187 0.151 1.07 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.985 0.395 0.382 U 0.981 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.257 0.157 0.156 U 0.139 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 18:24 1 0.119 0.0716 0.0715 U -0.0232 Americium 241 pCi/g 12/20/13 10:21 01/10/14 18:24 1 5.55 3.17 3.17 U 0.590 Protactinium 234m TestAmerica St. Louis Page 13 of 15 1 2 3 4 5 6 7 8 9 10 11
QC Sample Results TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) Client Sample ID: Method Blank Lab Sample ID: MB 160-93557/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 97316 Prep Batch: 93557 Actinium 228 Analyte U 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0537 MDC RL 0.0222 0.0222 (2+/-) (2+/-) MB 0.0000 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert. Count Uncert. Total 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.152 0.0829 0.0829 U 0.02844 Bismuth 212 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0360 0.0208 0.0208 U -0.002331 Bismuth 214 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0244 0.0322 0.0322 U -0.005957 Lead 212 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0323 0.119 0.119 U -0.01237 Lead 214 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.182 2.97 2.97 U -0.07423 Potassium 40 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.300 0.0847 0.0847 U 0.009655 Protactinium 231 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0360 1.00 0.0208 0.0208 U -0.002331 Radium 226 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0537 0.0222 0.0222 U 0.0000 Thorium 232 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.273 0.175 0.175 U -0.01643 Thorium 234 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0579 0.0372 0.0371 U 0.02249 Uranium 235 1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0291 0.0126 0.0126 U 0.0000 Americium 241 1 01/10/14 17:04 12/20/13 10:21 pCi/g 2.86 0.241 0.241 U 0.0000 Protactinium 234m Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-93557/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 97309 Prep Batch: 93557 Americium 241 Analyte 116 87 99 99.73 101 10.4 0.492 RL MDC (2+/-) LCS LCS pCi/g Unit Result Qual %Rec Added Spike Limits %Rec. Uncert. Total Cesium 137 35.9 35.17 3.69 0.202 pCi/g 98 87 - 120 Cobalt 60 42.5 41.32 4.17 0.117 pCi/g 97 87 - 115 Client Sample ID: L100601BES00 Lab Sample ID: 160-4704-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 97314 Prep Batch: 93557 Actinium 228 Analyte 1 0.01 1.033 1.04 0.167 0.0602 RL MDC (2+/-) DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert. Total RER RER Bismuth 212 0.819 1.068 0.381 0.361 pCi/g 0.34 1 Bismuth 214 1.26 1.402 0.182 0.0605 pCi/g 0.37 1 Lead 212 1.00 1.028 0.149 0.0509 pCi/g 0.09 1 Lead 214 1.44 1.485 0.187 0.0806 pCi/g 0.13 1 Potassium 40 16.6 17.24 2.05 0.312 pCi/g 0.16 1 Protactinium 231 -0.591 U -0.6256 U 0.716 1.17 pCi/g 0.02 1 Radium 226 1.26 1.402 0.182 1.00 0.0605 pCi/g 0.37 1 Thorium 232 1.04 1.033 0.167 0.0602 pCi/g 0.01 1 Thorium 234 1.84 1.457 0.707 0.871 pCi/g 0.24 1 Uranium 235 0.142 U 0.09667 U 0.141 0.242 pCi/g 0.15 1 Americium 241 0.000206 U -0.01055 U 0.0639 0.107 pCi/g 0.08 1 Protactinium 234m 0.0192 U 0.7795 U 2.86 5.05 pCi/g 0.12 1 TestAmerica St. Louis Page 14 of 15 1 2 3 4 5 6 7 8 9 10 11
QC Association Summary TestAmerica Job ID: 160-4704-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (21 DAY TAT) Rad Leach Batch: 92866 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-4704-1 L100601BES00 Total/NA Solid Dry and Grind 160-4704-1 DU L100601BES00 Total/NA Solid Dry and Grind 160-4704-2 L100602BES00 Total/NA Solid Dry and Grind 160-4704-3 L100603BES00 Total/NA Solid Dry and Grind 160-4704-4 L100604BES00 Total/NA Solid Dry and Grind 160-4704-5 L100605BRQ00 Total/NA Solid Dry and Grind 160-4704-6 L100605BRS00 Total/NA Solid Dry and Grind 160-4704-7 L100606BES00 Total/NA Solid Dry and Grind 160-4704-8 L100607BES00 Total/NA Solid Dry and Grind 160-4704-9 L100608BES00 Total/NA Solid Dry and Grind 160-4704-10 L100609BES00 Total/NA Prep Batch: 93557 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-21 92866 160-4704-1 L100601BES00 Total/NA Solid Fill_Geo-21 92866 160-4704-1 DU L100601BES00 Total/NA Solid Fill_Geo-21 92866 160-4704-2 L100602BES00 Total/NA Solid Fill_Geo-21 92866 160-4704-3 L100603BES00 Total/NA Solid Fill_Geo-21 92866 160-4704-4 L100604BES00 Total/NA Solid Fill_Geo-21 92866 160-4704-5 L100605BRQ00 Total/NA Solid Fill_Geo-21 92866 160-4704-6 L100605BRS00 Total/NA Solid Fill_Geo-21 92866 160-4704-7 L100606BES00 Total/NA Solid Fill_Geo-21 92866 160-4704-8 L100607BES00 Total/NA Solid Fill_Geo-21 92866 160-4704-9 L100608BES00 Total/NA Solid Fill_Geo-21 92866 160-4704-10 L100609BES00 Total/NA Solid Fill_Geo-21 LCS 160-93557/2-A Lab Control Sample Total/NA Solid Fill_Geo-21 MB 160-93557/1-A Method Blank Total/NA TestAmerica St. Louis Page 15 of 15 1 2 3 4 5 6 7 8 9 10 11}}