ML18010A284
| ML18010A284 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 12/13/2017 |
| From: | Swanson M, Vania I TestAmerica Labs - St. Louis, Westinghouse |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| ML18010A247 | List:
|
| References | |
| 160-6589-2, HEM-17-72 | |
| Download: ML18010A284 (16) | |
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-6589-2 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Mr. Martin Swanson Authorized for release by:
6/6/2014 2:14:40 PM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-6589-2 Page 2 of 16 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
14 QC Association Summary...................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-6589-2 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-6589-2 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-6589-2 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 05/08/2014; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.3 C.
RADIUM-226 BY GAMMA SPEC (21 DAY INGROWTH)
Samples L100529BSB00 (160-6589-1), L100530BSB00 (160-6589-2), L100531BSB00 (160-6589-3), L100532BSB00 (160-6589-4),
L100533BSB00 (160-6589-5), L100534BSB00 (160-6589-6), L100535BSB00 (160-6589-7) and L100536BSB00 (160-6589-8) were analyzed for Radium-226 by gamma spec (21 day ingrowth) in accordance with EPA GA_01_R. The samples were leached on 05/12/2014, prepared on 05/14/2014 and analyzed on 06/05/2014.
Preparation Batch 122007:
The RER was outside of the acceptance limits of 1 for protactinium-231. Both the sample and duplicate activity were less than the MDC.
Lead-214 analyzed by gamma spectroscopy was detected above the MDC in the method blank. Variations in Compton backgrounds and statistical analyses allow for small area counts in the ROIs of this nuclide. Other Uranium decay chain products are not present in the TestAmerica St. Louis Page 3 of 16 1
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-6589-2 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-6589-2 (Continued)
Laboratory: TestAmerica St. Louis (Continued) blank to support Lead-214 identification. The data is reported. (160-6589-1 DU), (LCS 160-122007/2-A), (MB 160-122007/1-A),
L100529BSB00 (160-6589-1), L100530BSB00 (160-6589-2), L100531BSB00 (160-6589-3), L100532BSB00 (160-6589-4),
L100533BSB00 (160-6589-5), L100534BSB00 (160-6589-6), L100535BSB00 (160-6589-7), L100536BSB00 (160-6589-8)
No other difficulties were encountered during the Radium 226 analysis. All other quality control parameters were within the acceptance limits.
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(0 Procedure HDP-PR-QA-006, Chain of Custody Page 1 of 1 Hematite Decommissioning Project !Revision: 3 I
I Westinghouse Non-Proprietary Class 3 rvKM nDr-rK-QA-VV0-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and. send the completed CoC to HDP.
Chain ofCutody ID No. I F-050614-01 Pa2:e Project Name:
Westinghouse Electric Company Contact Person:
Clark Evers Phone Number:
314-810-3336 Sampler Name Scott Jenkins U1 G'
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Laboratory Name:
TA-MO Laboratory Address:
13715 Rider Trail North "t---------------------t
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"' 8 314-298-8566 s Laboratory Contact Person:
~ Joe Walker 1
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Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-6589-2 Login Number: 6589 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
False Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
Thermal preservation not required.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Rad Qualifier Description U
Result is less than the sample detection limit.
Qualifier F
Duplicate RPD exceeds the control limit Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CFL Contains Free Liquid CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol DOE GA-01-R Radium-226 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 16 1
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Sample Summary TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-6589-1 L100529BSB00 Solid 05/06/14 10:30 05/08/14 11:30 160-6589-2 L100530BSB00 Solid 05/06/14 10:35 05/08/14 11:30 160-6589-3 L100531BSB00 Solid 05/06/14 10:40 05/08/14 11:30 160-6589-4 L100532BSB00 Solid 05/06/14 10:45 05/08/14 11:30 160-6589-5 L100533BSB00 Solid 05/06/14 10:50 05/08/14 11:30 160-6589-6 L100534BSB00 Solid 05/06/14 10:55 05/08/14 11:30 160-6589-7 L100535BSB00 Solid 05/06/14 11:00 05/08/14 11:30 160-6589-8 L100536BSB00 Solid 05/06/14 11:05 05/08/14 11:30 TestAmerica St. Louis Page 9 of 16 1
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Client Sample Results TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-1 Client Sample ID: L100529BSB00 Matrix: Solid Date Collected: 05/06/14 10:30 Date Received: 05/08/14 11:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.18 (2+/-)
0.190 (2+/-)
1 06/05/14 01:37 05/14/14 12:24 pCi/g 0.128 RL MDC 0.151 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.388 0.531 0.500 1.85 Bismuth 212 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.0877 0.151 0.117 0.975 Bismuth 214 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.0648 0.211 0.0871 1.27 Lead 212 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.0931 0.179 0.116 1.25 Lead 214 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.457 2.39 1.35 20.5 Potassium 40 pCi/g 05/14/14 12:24 06/05/14 01:37 1
1.11 0.332 0.319 U
0.782 Protactinium 231 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.0877 1.00 0.151 0.117 0.975 Radium 226 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.128 0.190 0.151 1.18 Thorium 232 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.894 0.576 0.563 1.21 Thorium 234 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.294 0.169 0.169 U
0.100 Uranium 235 pCi/g 05/14/14 12:24 06/05/14 01:37 1
0.108 0.0643 0.0643 U
0.0192 Americium 241 pCi/g 05/14/14 12:24 06/05/14 01:37 1
6.20 3.70 3.70 U
2.36 Protactinium 234m Tl-208 0.381 0.0506 0.0627 0.0372 pCi/g 05/14/14 12:24 06/05/14 01:37 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-2 Client Sample ID: L100530BSB00 Matrix: Solid Date Collected: 05/06/14 10:35 Date Received: 05/08/14 11:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.19 (2+/-)
0.193 (2+/-)
1 06/05/14 01:39 05/14/14 12:24 pCi/g 0.142 RL MDC 0.155 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.244 0.382 0.356 1.42 Bismuth 212 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.0824 0.139 0.113 0.829 Bismuth 214 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.0776 0.154 0.0868 1.18 Lead 212 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.0901 0.140 0.107 0.936 Lead 214 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.252 2.14 1.28 17.8 Potassium 40 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.882 0.416 0.409 U
0.779 Protactinium 231 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.0824 1.00 0.139 0.113 0.829 Radium 226 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.142 0.193 0.155 1.19 Thorium 232 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.883 0.349 0.341 U
0.730 Thorium 234 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.296 0.184 0.183 U
0.0782 Uranium 235 pCi/g 05/14/14 12:24 06/05/14 01:39 1
0.124 0.0749 0.0748 U
-0.0371 Americium 241 pCi/g 05/14/14 12:24 06/05/14 01:39 1
6.56 3.76 3.76 U
1.09 Protactinium 234m Tl-208 0.445 0.0657 0.0787 0.0492 pCi/g 05/14/14 12:24 06/05/14 01:39 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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Client Sample Results TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-3 Client Sample ID: L100531BSB00 Matrix: Solid Date Collected: 05/06/14 10:40 Date Received: 05/08/14 11:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.40 (2+/-)
0.211 (2+/-)
1 06/05/14 01:40 05/14/14 12:24 pCi/g 0.0813 RL MDC 0.163 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.491 0.418 0.397 1.35 Bismuth 212 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.0681 0.149 0.110 1.03 Bismuth 214 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.0588 0.162 0.0836 1.29 Lead 212 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.0768 0.150 0.0975 1.18 Lead 214 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.420 2.47 1.35 21.5 Potassium 40 pCi/g 05/14/14 12:24 06/05/14 01:40 1
1.26 0.224 0.221 U
0.365 Protactinium 231 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.0681 1.00 0.149 0.110 1.03 Radium 226 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.0813 0.211 0.163 1.40 Thorium 232 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.839 0.325 0.311 0.980 Thorium 234 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.205 0.153 0.152 U
0.182 Uranium 235 pCi/g 05/14/14 12:24 06/05/14 01:40 1
0.0990 0.0585 0.0585 U
0.00404 Americium 241 pCi/g 05/14/14 12:24 06/05/14 01:40 1
5.46 3.31 3.30 U
2.48 Protactinium 234m Tl-208 0.350 0.0498 0.0603 0.0378 pCi/g 05/14/14 12:24 06/05/14 01:40 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-4 Client Sample ID: L100532BSB00 Matrix: Solid Date Collected: 05/06/14 10:45 Date Received: 05/08/14 11:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.13 (2+/-)
0.186 (2+/-)
1 06/05/14 13:16 05/14/14 12:24 pCi/g 0.111 RL MDC 0.146 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.344 0.402 0.375 1.39 Bismuth 212 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.0702 0.155 0.111 1.05 Bismuth 214 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.0648 0.163 0.0777 1.11 Lead 212 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.0810 0.156 0.100 1.15 Lead 214 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.257 2.41 1.27 20.0 Potassium 40 pCi/g 05/14/14 12:24 06/05/14 13:16 1
1.24 0.251 0.247 U
0.390 Protactinium 231 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.0702 1.00 0.155 0.111 1.05 Radium 226 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.111 0.186 0.146 1.13 Thorium 232 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.810 0.547 0.525 1.45 Thorium 234 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.193 0.129 0.126 0.283 Uranium 235 pCi/g 05/14/14 12:24 06/05/14 13:16 1
0.106 0.0633 0.0633 U
-0.0151 Americium 241 pCi/g 05/14/14 12:24 06/05/14 13:16 1
5.64 3.23 3.23 U
0.923 Protactinium 234m Tl-208 0.379 0.0470 0.0613 0.0292 pCi/g 05/14/14 12:24 06/05/14 13:16 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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Client Sample Results TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-5 Client Sample ID: L100533BSB00 Matrix: Solid Date Collected: 05/06/14 10:50 Date Received: 05/08/14 11:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.05 (2+/-)
0.177 (2+/-)
1 06/05/14 13:58 05/14/14 12:24 pCi/g 0.117 RL MDC 0.140 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.485 0.522 0.504 1.29 Bismuth 212 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.0709 0.146 0.109 0.944 Bismuth 214 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.0622 0.157 0.0761 1.06 Lead 212 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.0749 0.142 0.0947 1.02 Lead 214 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.262 2.39 1.27 19.8 Potassium 40 pCi/g 05/14/14 12:24 06/05/14 13:58 1
1.15 0.311 0.306 U
0.535 Protactinium 231 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.0709 1.00 0.146 0.109 0.944 Radium 226 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.117 0.177 0.140 1.05 Thorium 232 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.854 0.557 0.542 1.22 Thorium 234 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.230 0.139 0.139 U
0.154 Uranium 235 pCi/g 05/14/14 12:24 06/05/14 13:58 1
0.105 0.0619 0.0619 U
0.00149 Americium 241 pCi/g 05/14/14 12:24 06/05/14 13:58 1
5.80 3.29 3.29 U
0.639 Protactinium 234m Tl-208 0.364 0.0528 0.0649 0.0382 pCi/g 05/14/14 12:24 06/05/14 13:58 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-6 Client Sample ID: L100534BSB00 Matrix: Solid Date Collected: 05/06/14 10:55 Date Received: 05/08/14 11:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.18 (2+/-)
0.193 (2+/-)
1 06/05/14 13:59 05/14/14 12:24 pCi/g 0.0886 RL MDC 0.150 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.397 0.317 0.303 0.887 Bismuth 212 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.0617 0.143 0.0999 0.982 Bismuth 214 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.0566 0.161 0.0714 1.12 Lead 212 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.0608 0.134 0.0879 0.968 Lead 214 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.308 2.30 1.14 19.6 Potassium 40 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.533 0.377 0.367 0.775 Protactinium 231 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.0617 1.00 0.143 0.0999 0.982 Radium 226 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.0886 0.193 0.150 1.18 Thorium 232 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.789 0.321 0.298 1.14 Thorium 234 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.224 0.134 0.132 U
0.175 Uranium 235 pCi/g 05/14/14 12:24 06/05/14 13:59 1
0.106 0.0632 0.0632 U
0.00212 Americium 241 pCi/g 05/14/14 12:24 06/05/14 13:59 1
5.39 3.09 3.08 U
2.55 Protactinium 234m Tl-208 0.348 0.0484 0.0604 0.0381 pCi/g 05/14/14 12:24 06/05/14 13:59 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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Client Sample Results TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-7 Client Sample ID: L100535BSB00 Matrix: Solid Date Collected: 05/06/14 11:00 Date Received: 05/08/14 11:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.30 (2+/-)
0.215 (2+/-)
1 06/05/14 14:38 05/14/14 12:24 pCi/g 0.140 RL MDC 0.169 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.519 0.633 0.609 1.66 Bismuth 212 pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.0647 0.177 0.129 1.17 Bismuth 214 pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.0702 0.178 0.0890 1.20 Lead 212 pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.0928 0.171 0.123 1.14 Lead 214 pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.460 2.31 1.43 17.7 Potassium 40 pCi/g 05/14/14 12:24 06/05/14 14:38 1
1.58 0.956 0.954 U
-0.669 Protactinium 231 pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.0647 1.00 0.177 0.129 1.17 Radium 226 pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.140 0.215 0.169 1.30 Thorium 232 pCi/g 05/14/14 12:24 06/05/14 14:38 1
1.01 0.655 0.638 1.41 Thorium 234 pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.254 0.210 0.209 U
0.232 Uranium 235 pCi/g 05/14/14 12:24 06/05/14 14:38 1
0.112 0.0668 0.0667 U
0.0269 Americium 241 pCi/g 05/14/14 12:24 06/05/14 14:38 1
6.69 3.83 3.83 U
1.68 Protactinium 234m Tl-208 0.394 0.0573 0.0703 0.0394 pCi/g 05/14/14 12:24 06/05/14 14:38 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-8 Client Sample ID: L100536BSB00 Matrix: Solid Date Collected: 05/06/14 11:05 Date Received: 05/08/14 11:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.30 (2+/-)
0.191 (2+/-)
1 06/05/14 14:33 05/14/14 12:24 pCi/g 0.104 RL MDC 0.143 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.369 0.511 0.479 1.83 Bismuth 212 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.0837 0.166 0.124 1.13 Bismuth 214 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.0650 0.219 0.0877 1.32 Lead 212 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.0819 0.169 0.111 1.16 Lead 214 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.377 1.89 1.15 15.6 Potassium 40 pCi/g 05/14/14 12:24 06/05/14 14:33 1
1.31 0.297 0.293 U
0.422 Protactinium 231 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.0837 1.00 0.166 0.124 1.13 Radium 226 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.104 0.191 0.143 1.30 Thorium 232 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.837 0.302 0.292 U
0.812 Thorium 234 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.180 0.116 0.115 U
0.179 Uranium 235 pCi/g 05/14/14 12:24 06/05/14 14:33 1
0.105 0.0621 0.0621 U
0.00671 Americium 241 pCi/g 05/14/14 12:24 06/05/14 14:33 1
4.99 3.09 3.08 U
2.77 Protactinium 234m Tl-208 0.405 0.0575 0.0697 0.0422 pCi/g 05/14/14 12:24 06/05/14 14:33 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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QC Sample Results TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-122007/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 125288 Prep Batch: 122007 Actinium 228 Analyte U
1 06/04/14 23:01 05/14/14 12:24 pCi/g 0.0527 MDC RL 0.0282 0.0282 (2+/-)
(2+/-)
MB 0.007468 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.161 0.0538 0.0538 U
0.0000 Bismuth 212 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.0353 0.000384 0.000383 U
0.0001964 Bismuth 214 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.0231 0.0120 0.0119 U
0.004458 Lead 212 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.0202 0.0159 0.0156 0.02820 Lead 214 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.283 1.44 1.44 U
-0.07779 Potassium 40 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.338 0.106 0.106 U
0.02002 Protactinium 231 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.0353 1.00 0.000384 0.000383 U
0.0001964 Radium 226 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.0527 0.0282 0.0282 U
0.007468 Thorium 232 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.267 0.142 0.141 U
0.1034 Thorium 234 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.0711 0.0383 0.0383 U
0.01135 Uranium 235 1
06/04/14 23:01 05/14/14 12:24 pCi/g 0.0204 0.0111 0.0111 U
0.0004633 Americium 241 1
06/04/14 23:01 05/14/14 12:24 pCi/g 1.58 0.945 0.943 U
0.6374 Protactinium 234m Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 05/14/14 12:24 06/04/14 23:01 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-122007/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 125670 Prep Batch: 122007 Americium 241 Analyte 116 87 103 104.2 101 10.8 0.629 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 35.5 36.00 3.78 0.234 pCi/g 101 87 - 120 Cobalt 60 40.3 40.32 4.07 0.129 pCi/g 100 87 - 115 Client Sample ID: L100529BSB00 Lab Sample ID: 160-6589-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 125665 Prep Batch: 122007 Actinium 228 Analyte 1
0.05 1.156 1.18 0.176 0.137 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Bismuth 212 1.85 1.521 0.480 0.414 pCi/g 0.32 1
Bismuth 214 0.975 1.203 0.179 0.0903 pCi/g 0.69 1
Lead 212 1.27 1.169 0.152 0.0696 pCi/g 0.27 1
Lead 214 1.25 1.230 0.157 0.0812 pCi/g 0.06 1
Potassium 40 20.5 20.70 2.40 0.311 pCi/g 0.04 1
Protactinium 231 0.782 U
-0.5922 U F 0.774 1.27 pCi/g 1.24 1
Radium 226 0.975 1.203 0.179 1.00 0.0903 pCi/g 0.69 1
Thorium 232 1.18 1.156 0.176 0.137 pCi/g 0.05 1
Thorium 234 1.21 0.9648 0.631 0.869 pCi/g 0.20 1
Uranium 235 0.100 U
0.08579 U
0.153 0.262 pCi/g 0.04 1
Americium 241 0.0192 U
0.001242 U
0.0632 0.107 pCi/g 0.14 1
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QC Sample Results TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: L100529BSB00 Lab Sample ID: 160-6589-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 125665 Prep Batch: 122007 Protactinium 234m Analyte 1
0.25 U
0.7311 2.36 U
2.87 5.08 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER TestAmerica St. Louis Page 15 of 16 1
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QC Association Summary TestAmerica Job ID: 160-6589-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Rad Leach Batch: 121572 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-6589-1 L100529BSB00 Total/NA Solid Dry and Grind 160-6589-1 DU L100529BSB00 Total/NA Solid Dry and Grind 160-6589-2 L100530BSB00 Total/NA Solid Dry and Grind 160-6589-3 L100531BSB00 Total/NA Solid Dry and Grind 160-6589-4 L100532BSB00 Total/NA Solid Dry and Grind 160-6589-5 L100533BSB00 Total/NA Solid Dry and Grind 160-6589-6 L100534BSB00 Total/NA Solid Dry and Grind 160-6589-7 L100535BSB00 Total/NA Solid Dry and Grind 160-6589-8 L100536BSB00 Total/NA Prep Batch: 122007 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-21 121572 160-6589-1 L100529BSB00 Total/NA Solid Fill_Geo-21 121572 160-6589-1 DU L100529BSB00 Total/NA Solid Fill_Geo-21 121572 160-6589-2 L100530BSB00 Total/NA Solid Fill_Geo-21 121572 160-6589-3 L100531BSB00 Total/NA Solid Fill_Geo-21 121572 160-6589-4 L100532BSB00 Total/NA Solid Fill_Geo-21 121572 160-6589-5 L100533BSB00 Total/NA Solid Fill_Geo-21 121572 160-6589-6 L100534BSB00 Total/NA Solid Fill_Geo-21 121572 160-6589-7 L100535BSB00 Total/NA Solid Fill_Geo-21 121572 160-6589-8 L100536BSB00 Total/NA Solid Fill_Geo-21 LCS 160-122007/2-A Lab Control Sample Total/NA Solid Fill_Geo-21 MB 160-122007/1-A Method Blank Total/NA TestAmerica St. Louis Page 16 of 16 1
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