ML18010A288

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Final Status Survey Final Report Volume 3, Chapter 6, Survey Area Release Record for Land Survey Area 10, Analytical Report: 160-4764-1
ML18010A288
Person / Time
Site: 07000036
Issue date: 12/12/2013
From: Swanson M, Vania I
TestAmerica Labs - St. Louis, Westinghouse
To:
Office of Nuclear Material Safety and Safeguards
Shared Package
ML18010A247 List: ... further results
References
HEM-17-72 160-4764-1
Download: ML18010A288 (18)
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ANALYTICAL REPORT TestAmerica Laboratories, Inc.

TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-4764-1 Client Project/Site: RFP-CBA-022 (7 DAY TAT)

For:

Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:

12/12/2013 3:07:54 PM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

TestAmerica Job ID: 160-4764-1 Page 2 of 18 Cover Page..............................................

1 Table of Contents.........................................

2 Case Narrative...........................................

3 Chain of Custody..........................................

5 Receipt Checklists.........................................

7 Definitions/Glossary.......................................

8 Method Summary.........................................

9 Sample Summary.........................................

10 Client Sample Results......................................

11 QC Sample Results........................................

14 QC Association Summary...................................

16 Tracer Carrier Summary....................................

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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-4764-1 Project/Site: RFP-CBA-022 (7 DAY TAT)

Job ID: 160-4764-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)

Report Number: 160-4764-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %

solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.

RECEIPT The samples were received on 12/04/2013 and 12/04/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.2 C.

TECHNETIUM-99 (ICPMS)

Samples L100701BUI01 (160-4764-1), L100701BUI02 (160-4764-2), L100701BUI03 (160-4764-3), L100701BUI04 (160-4764-4),

L100715BUB00 (160-4764-5), L100716BUB00 (160-4764-6), L100610BUB00 (160-4764-7), L100611BUB00 (160-4764-8) and L100612BUB00 (160-4764-9) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 12/09/2013 and analyzed on 12/10/2013.

No difficulties were encountered during the Tc-99 analysis. All quality control parameters were within the acceptance limits.

PERCENT SOLIDS Samples L100701BUI01 (160-4764-1), L100701BUI02 (160-4764-2), L100701BUI03 (160-4764-3), L100701BUI04 (160-4764-4),

L100715BUB00 (160-4764-5), L100716BUB00 (160-4764-6), L100610BUB00 (160-4764-7), L100611BUB00 (160-4764-8) and L100612BUB00 (160-4764-9) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 12/05/2013.

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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-4764-1 Project/Site: RFP-CBA-022 (7 DAY TAT)

Job ID: 160-4764-1 (Continued)

Laboratory: TestAmerica St. Louis (Continued)

No difficulties were encountered during the % solids analysis. All quality control parameters were within the acceptance limits.

TestAmerica St. Louis Page 4 of 18 1

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10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision: 3 I

Page 1 ofl Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.

Chain ofCutodv ID No.

F-120413-02 Pa2e 1/1 Reauested.Aiiaivsis Labonitorv Name:

f'-==...c=~"--""~='--------------1 Project Na.me:

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TA-MO Westinghouse Electric Company

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Contact Person:

("*i !~

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1-L-a_b_o_r-at_o_ry_A_d_d_r_es_s_:------------1 Gerald Rood

'ij '8,

13715 Rider Trail North

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fi' Phone Number:

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[;:~

Phone No.

314-810-3382

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.5 314-298-8566 Sampler Name f'_-'

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708-870-8453

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Sample ID Date Time Matrix 8

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t~ '.d Remarks L100701BU101 12/3/2013 14:50 S

C

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X X _ _

1 LSA-10-07 Investigation L100701BU102 12/3/2013 14:55 S

C ~"' <

  • X X

3 1 LSA-10-07 Investigation L100701BUI03 12/3/2013 15:05 S

C s.< :,,

X: X 1 LSA-10-07 Investigation L100701BU104 12/3/2013 15:10 S

C ~}~. *

  • X X

1 LSA-10-07 Investigation L100715BUBOO 12/3/2013 14:40 S

C *:;~

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1 LSA-10-07 Bias Samples Ll00716BUBOO 12/3/2013 15:30 S

C.. :'-"'-, '

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  • X 1 LSA-10-07 Bias Samples

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Relinquished by~

Date/rime

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Date/rime Total Cooler Temperature:

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6 Amhient Company Nam~

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poa.02 Received by:

Date/rime

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Date/rime Comments: Please analyze samples for Tc-99 on a 7 day TAT.

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_-Li4 Please analyze samples for gamma spec after a 21 day ingrowth Company Name:

!.(omEI:?-~~~"'

\\ v 13"V period.

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Relinquished by:

Dateffime Re~ived~:

Da_ te!yime F, ~

z_/ i/ / 13 Verified By

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ComuanvName:

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!Procedure HPP-PR-QA-006, Chain of Custody Hematite Decommissioning Project !Revision: 3 Page I ofl l Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY fustructions: Each time the container is transferred to another organization, a person from each organization should sign the Coe The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.

Chain ofCutodv ID No. I F-120413-01 Page 1/1 Project Name:

Westinghouse Electric Company Contact Person:

Gerald Rood Phone Number:

314-810-3382 Sampler Name Scott Jenkins 1~-, --:5:!j~};J 6' '.'\\7', E

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!;fl lsample ID loate

!Time

!Matrix I ~ ~,£~:'j ~

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L100610BUBOO Ll00611BUBOO IL100612BUBOO Relinquished by~ --.!:.

,Company Name: (.,( ){::. ~

Received by:

Company Name:

Relinquished by:

Company Name:

12/3/2013 16:051 S

c

  • I 1x1x1 12/3/2013 15:501 S

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Laboratory Name:

TA-MO Laboratory Address:

13715 Rider Trail North

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8 314-298-8566 i I Laboratory Contact Person:

f-< Joe Walker Phone No.

708~ 70-8453 Turn Around Time Rush (7 days)

Remarks 1 ILSA-10-06 Bias Samples 1 ILSA-10-06 Bias Samples 1 ILSA-10-06 Bias Samples Total

!Cooler Temperature:

3 Ambien1 Cooler ID: I Shipper and Number:

1204-02 Comments: Please analyze samples for Tc-99 on a 7 day TAT.

Please analyze samples for gamma spec after a 21 day ingrowth period.

Verified By:

('_

---~------------------ ---- ---:---:-;---;-1: *1--------

Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-4764-1 Login Number: 4764 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.

True The cooler's custody seal, if present, is intact.

N/A Sample custody seals, if present, are intact.

True The cooler or samples do not appear to have been compromised or tampered with.

False Samples were received on ice.

True Cooler Temperature is acceptable.

True Cooler Temperature is recorded.

Thermal preservation not required.

True COC is present.

True COC is filled out in ink and legible.

True COC is filled out with all pertinent information.

True Is the Field Sampler's name present on COC?

True There are no discrepancies between the containers received and the COC.

True Samples are received within Holding Time.

True Sample containers have legible labels.

True Containers are not broken or leaking.

True Sample collection date/times are provided.

True Appropriate sample containers are used.

True Sample bottles are completely filled.

True Sample Preservation Verified.

True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is

<6mm (1/4").

True Multiphasic samples are not present.

True Samples do not require splitting or compositing.

N/A Residual Chlorine Checked.

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Definitions/Glossary TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Qualifiers Rad Qualifier Description U

Indicates the analyte was analyzed for but not detected.

Qualifier Glossary These commonly used abbreviations may or may not be present in this report.

Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation

%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)

NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

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Method Summary TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL Protocol

References:

EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory

References:

TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 9 of 18 1

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Sample Summary TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID Client Sample ID Received Collected Matrix 160-4764-1 L100701BUI01 Solid 12/03/13 14:50 12/04/13 18:30 160-4764-2 L100701BUI02 Solid 12/03/13 14:55 12/04/13 18:30 160-4764-3 L100701BUI03 Solid 12/03/13 15:05 12/04/13 18:30 160-4764-4 L100701BUI04 Solid 12/03/13 15:10 12/04/13 18:30 160-4764-5 L100715BUB00 Solid 12/03/13 14:40 12/04/13 18:30 160-4764-6 L100716BUB00 Solid 12/03/13 15:30 12/04/13 18:30 160-4764-7 L100610BUB00 Solid 12/03/13 16:05 12/04/13 18:45 160-4764-8 L100611BUB00 Solid 12/03/13 15:50 12/04/13 18:45 160-4764-9 L100612BUB00 Solid 12/03/13 15:40 12/04/13 18:45 TestAmerica St. Louis Page 10 of 18 1

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Client Sample Results TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4764-1 Client Sample ID: L100701BUI01 Matrix: Solid Date Collected: 12/03/13 14:50 Percent Solids: 82.4 Date Received: 12/04/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg

12/09/13 09:43 12/10/13 17:55 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.000 U

(2+/-)

0.000 (2+/-)

1 12/10/13 17:55 12/09/13 09:43 pCi/g 0.226 1.32 RL MDC 0.000 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 17:55 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 91 Lab Sample ID: 160-4764-2 Client Sample ID: L100701BUI02 Matrix: Solid Date Collected: 12/03/13 14:55 Percent Solids: 82.0 Date Received: 12/04/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg

12/09/13 09:43 12/10/13 17:59 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0184 U

(2+/-)

0.0628 (2+/-)

1 12/10/13 17:59 12/09/13 09:43 pCi/g 0.230 1.34 RL MDC 0.0573 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 17:59 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 91 Lab Sample ID: 160-4764-3 Client Sample ID: L100701BUI03 Matrix: Solid Date Collected: 12/03/13 15:05 Percent Solids: 82.1 Date Received: 12/04/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000068 0.000020 mg/Kg

12/09/13 09:43 12/10/13 18:02 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0317 U

(2+/-)

0.0561 (2+/-)

1 12/10/13 18:02 12/09/13 09:43 pCi/g 0.231 1.35 RL MDC 0.0509 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 18:02 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 91 TestAmerica St. Louis Page 11 of 18 1

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Client Sample Results TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4764-4 Client Sample ID: L100701BUI04 Matrix: Solid Date Collected: 12/03/13 15:10 Percent Solids: 84.1 Date Received: 12/04/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg

12/09/13 09:43 12/10/13 18:06 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.00881 U

(2+/-)

0.0219 (2+/-)

1 12/10/13 18:06 12/09/13 09:43 pCi/g 0.226 1.32 RL MDC 0.0198 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 18:06 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 91 Lab Sample ID: 160-4764-5 Client Sample ID: L100715BUB00 Matrix: Solid Date Collected: 12/03/13 14:40 Percent Solids: 81.4 Date Received: 12/04/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000019 mg/Kg

12/09/13 09:43 12/10/13 18:10 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.00178 U

(2+/-)

0.0130 (2+/-)

1 12/10/13 18:10 12/09/13 09:43 pCi/g 0.223 1.30 RL MDC 0.0123 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 18:10 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 94 Lab Sample ID: 160-4764-6 Client Sample ID: L100716BUB00 Matrix: Solid Date Collected: 12/03/13 15:30 Percent Solids: 81.2 Date Received: 12/04/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg

12/09/13 09:43 12/10/13 18:14 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0130 U

(2+/-)

0.0272 (2+/-)

1 12/10/13 18:14 12/09/13 09:43 pCi/g 0.228 1.33 RL MDC 0.0253 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 18:14 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 93 Lab Sample ID: 160-4764-7 Client Sample ID: L100610BUB00 Matrix: Solid Date Collected: 12/03/13 16:05 Percent Solids: 81.8 Date Received: 12/04/13 18:45 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg

12/09/13 09:43 12/10/13 18:18 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier TestAmerica St. Louis Page 12 of 18 1

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Client Sample Results TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4764-7 Client Sample ID: L100610BUB00 Matrix: Solid Date Collected: 12/03/13 16:05 Percent Solids: 81.8 Date Received: 12/04/13 18:45 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.00458 U

(2+/-)

0.0574 (2+/-)

1 12/10/13 18:18 12/09/13 09:43 pCi/g 0.229 1.34 RL MDC

-0.0526 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 18:18 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 92 Lab Sample ID: 160-4764-8 Client Sample ID: L100611BUB00 Matrix: Solid Date Collected: 12/03/13 15:50 Percent Solids: 84.4 Date Received: 12/04/13 18:45 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000019 mg/Kg

12/09/13 09:43 12/10/13 18:22 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0130 U

(2+/-)

0.0180 (2+/-)

1 12/10/13 18:22 12/09/13 09:43 pCi/g 0.221 1.29 RL MDC 0.0165 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 18:22 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 92 Lab Sample ID: 160-4764-9 Client Sample ID: L100612BUB00 Matrix: Solid Date Collected: 12/03/13 15:40 Percent Solids: 81.8 Date Received: 12/04/13 18:45 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg

12/09/13 09:43 12/10/13 18:33 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.00853 U

(2+/-)

0.0622 (2+/-)

1 12/10/13 18:33 12/09/13 09:43 pCi/g 0.224 1.31 RL MDC 0.0584 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 09:43 12/10/13 18:33 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 94 TestAmerica St. Louis Page 13 of 18 1

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QC Sample Results TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-90397/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 91083 Prep Batch: 90397 RL MDL Technetium 99 ND 0.000051 0.000015 mg/Kg 12/09/13 09:43 12/10/13 17:16 1

MB MB Analyte Dil Fac Analyzed Prepared D

Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-90397/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 91083 Prep Batch: 90397 Technetium 99 0.00236 0.00232 mg/Kg 98 80 - 120 Analyte LCS LCS D

Unit Result Qualifier

%Rec Spike Added

%Rec.

Limits Client Sample ID: Matrix Spike Lab Sample ID: 160-4801-A-21-B MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 91083 Prep Batch: 90397 Technetium 99 0.000071 J

0.00293 0.00293 mg/Kg 97 75 - 125

Analyte MS MS D

Unit Result Qualifier

%Rec Spike Added Sample Result Sample Qualifier

%Rec.

Limits Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-4801-A-21-C MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 91083 Prep Batch: 90397 Technetium 99 0.000071 J

0.00296 0.00302 mg/Kg 100 75 - 125 3

30

Analyte MSD MSD D

Unit Result Qualifier

%Rec Spike Added Sample Result Sample Qualifier

%Rec.

Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-90397/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 91084 Prep Batch: 90397 Technetium 99 Analyte U

1 12/10/13 17:16 12/09/13 09:43 pCi/g 0.173 MDC 1.01 RL 0.0186

-0.0184 (2+/-)

(2+/-)

MB

-0.01700 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.

Count Uncert.

Total Carrier Re 30 - 110 12/09/13 09:43 12/10/13 17:16 1

Dil Fac Prepared Analyzed Qualifier Limits

%Yield 99 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-90397/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 91084 Prep Batch: 90397 Technetium 99 Analyte 120 80 98 39.68 40.3 3.88 1.03 0.176 RL MDC (2+/-)

LCS LCS pCi/g Unit Result Qual

%Rec Added Spike Limits

%Rec.

Uncert.

Total Re Carrier 30 - 110 LCS Qualifier Limits

%Yield 98 LCS TestAmerica St. Louis Page 14 of 18 1

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QC Sample Results TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)

Client Sample ID: Matrix Spike Lab Sample ID: 160-4801-A-21-B MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 91084 Prep Batch: 90397 Technetium 99 Analyte 125 75 97 50.11 50.2 1.22 5.88 1.37 0.235 RL MDC (2+/-)

MS MS pCi/g Unit Result Qual

%Rec Added Spike Result Sample Sample Qual Limits

%Rec.

Uncert.

Total Re Carrier 30 - 110 MS Qualifier Limits

%Yield 91 MS Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-4801-A-21-C MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 91084 Prep Batch: 90397 Technetium 99 Analyte 1

0.15 125 75 100 51.72 50.7 1.22 5.21 1.38 0.237 RL MDC (2+/-)

MSD MSD pCi/g Unit Result Qual

%Rec Limit Added Spike Result Sample Sample Qual Limits

%Rec.

Uncert.

Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits

%Yield 92 MSD TestAmerica St. Louis Page 15 of 18 1

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QC Association Summary TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Metals Prep Batch: 90397 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-4764-1 L100701BUI01 Total/NA Solid None 160-4764-2 L100701BUI02 Total/NA Solid None 160-4764-3 L100701BUI03 Total/NA Solid None 160-4764-4 L100701BUI04 Total/NA Solid None 160-4764-5 L100715BUB00 Total/NA Solid None 160-4764-6 L100716BUB00 Total/NA Solid None 160-4764-7 L100610BUB00 Total/NA Solid None 160-4764-8 L100611BUB00 Total/NA Solid None 160-4764-9 L100612BUB00 Total/NA Solid None 160-4801-A-21-B MS Matrix Spike Total/NA Solid None 160-4801-A-21-C MSD Matrix Spike Duplicate Total/NA Solid None LCS 160-90397/2-A Lab Control Sample Total/NA Solid None MB 160-90397/1-A Method Blank Total/NA Analysis Batch: 91083 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 90397 160-4764-1 L100701BUI01 Total/NA Solid 6020A 90397 160-4764-2 L100701BUI02 Total/NA Solid 6020A 90397 160-4764-3 L100701BUI03 Total/NA Solid 6020A 90397 160-4764-4 L100701BUI04 Total/NA Solid 6020A 90397 160-4764-5 L100715BUB00 Total/NA Solid 6020A 90397 160-4764-6 L100716BUB00 Total/NA Solid 6020A 90397 160-4764-7 L100610BUB00 Total/NA Solid 6020A 90397 160-4764-8 L100611BUB00 Total/NA Solid 6020A 90397 160-4764-9 L100612BUB00 Total/NA Solid 6020A 90397 160-4801-A-21-B MS Matrix Spike Total/NA Solid 6020A 90397 160-4801-A-21-C MSD Matrix Spike Duplicate Total/NA Solid 6020A 90397 LCS 160-90397/2-A Lab Control Sample Total/NA Solid 6020A 90397 MB 160-90397/1-A Method Blank Total/NA General Chemistry Analysis Batch: 89896 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-4763-D-13 MS Matrix Spike Total/NA Solid Moisture 160-4763-D-13 MSD Matrix Spike Duplicate Total/NA Solid Moisture 160-4764-1 L100701BUI01 Total/NA Solid Moisture 160-4764-2 L100701BUI02 Total/NA Solid Moisture 160-4764-3 L100701BUI03 Total/NA Solid Moisture 160-4764-4 L100701BUI04 Total/NA Solid Moisture 160-4764-5 L100715BUB00 Total/NA Solid Moisture 160-4764-6 L100716BUB00 Total/NA Solid Moisture 160-4764-7 L100610BUB00 Total/NA Solid Moisture 160-4764-8 L100611BUB00 Total/NA Solid Moisture 160-4764-9 L100612BUB00 Total/NA Solid Moisture 160-4764-9 DU L100612BUB00 Total/NA TestAmerica St. Louis Page 16 of 18 1

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QC Association Summary TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Rad Prep Batch: 90397 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-4764-1 L100701BUI01 Total/NA Solid None 160-4764-2 L100701BUI02 Total/NA Solid None 160-4764-3 L100701BUI03 Total/NA Solid None 160-4764-4 L100701BUI04 Total/NA Solid None 160-4764-5 L100715BUB00 Total/NA Solid None 160-4764-6 L100716BUB00 Total/NA Solid None 160-4764-7 L100610BUB00 Total/NA Solid None 160-4764-8 L100611BUB00 Total/NA Solid None 160-4764-9 L100612BUB00 Total/NA Solid None 160-4801-A-21-B MS Matrix Spike Total/NA Solid None 160-4801-A-21-C MSD Matrix Spike Duplicate Total/NA Solid None LCS 160-90397/2-A Lab Control Sample Total/NA Solid None MB 160-90397/1-A Method Blank Total/NA TestAmerica St. Louis Page 17 of 18 1

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Tracer/Carrier Summary TestAmerica Job ID: 160-4764-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)

Re 91 160-4764-1 Percent Yield (Acceptance Limits)

L100701BUI01 91 160-4764-2 L100701BUI02 91 160-4764-3 L100701BUI03 91 160-4764-4 L100701BUI04 94 160-4764-5 L100715BUB00 93 160-4764-6 L100716BUB00 92 160-4764-7 L100610BUB00 92 160-4764-8 L100611BUB00 94 160-4764-9 L100612BUB00 91 160-4801-A-21-B MS Matrix Spike 92 160-4801-A-21-C MSD Matrix Spike Duplicate 98 LCS 160-90397/2-A Lab Control Sample 99 MB 160-90397/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 18 of 18 1

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