ML18010A306
| ML18010A306 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 10/22/2013 |
| From: | Westinghouse |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| ML18010A247 | List:
|
| References | |
| HEM-17-72 160-3891-2 | |
| Download: ML18010A306 (16) | |
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-3891-2 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:
10/22/2013 3:08:16 PM Ivan Vania, Project Manager I (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-3891-2 Page 2 of 16 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
15 QC Association Summary...................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3891-2 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3891-2 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-3891-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 09/25/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.0 C.
TECHNETIUM-99 (ICPMS)
Samples L100901BES00 (160-3891-1), L100902BES00 (160-3891-2), L100903BES00 (160-3891-3), L100904BEQ00 (160-3891-4),
L100904BES00 (160-3891-5), L100905BES00 (160-3891-6), L100906BES00 (160-3891-7), L100907BES00 (160-3891-8),
L100908BUB00 (160-3891-9), L100909BUB00 (160-3891-10) and L100910BUB00 (160-3891-11) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 09/26/2013 and analyzed on 09/27/2013.
No difficulties were encountered during the Tc-99 analysis. All quality control parameters were within the acceptance limits.
PERCENT SOLIDS Samples L100901BES00 (160-3891-1), L100902BES00 (160-3891-2), L100903BES00 (160-3891-3), L100904BEQ00 (160-3891-4),
L100904BES00 (160-3891-5), L100905BES00 (160-3891-6), L100906BES00 (160-3891-7), L100907BES00 (160-3891-8),
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3891-2 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3891-2 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
L100908BUB00 (160-3891-9), L100909BUB00 (160-3891-10) and L100910BUB00 (160-3891-11) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 09/26/2013.
No difficulties were encountered during the % solids analysis. All quality control parameters were within the acceptance limits.
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Samples L100901BES00 (160-3891-1), L100902BES00 (160-3891-2), L100903BES00 (160-3891-3), L100904BEQ00 (160-3891-4),
L100904BES00 (160-3891-5), L100905BES00 (160-3891-6), L100906BES00 (160-3891-7), L100907BES00 (160-3891-8),
L100908BUB00 (160-3891-9), L100909BUB00 (160-3891-10) and L100910BUB00 (160-3891-11) were analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R. The samples were leached on 09/26/2013, prepared on 09/30/2013 and analyzed on 09/30/2013 and 10/01/2013.
Radium 226 was detected in method blank MB 160-75266/1-A at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. Refer to the QC report for details.
No other difficulties were encountered during the Gamma spec analysis. All other quality control parameters were within the acceptance limits.
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10 11 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision: 3 I
Page I ofl Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAlN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.
Chain of Cutody ID No.
F-092513-01 Pa2e 1/1 Requested Analysis Laboratorv Name:
Project Name:
I*
G' TA-MO N
Westinghouse Electric Company N
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Contact Person:
1*,
Laboratory Address:
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Gerald Rood
'8 13715 Rider Trail North
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0 Phone Number:
"ii Phone No.
314-810-3382 gi
" 314-298-8566 8
Sampler Name
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ol Laboratory Contact Person:
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Andrew Schooley G
a Joe Walker
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Remarks 0
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LI 0090 IBESOO 9/19/2013 13:20 s
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X X
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L100902BESOO 9/19/2013 13:25 s C
X X
X 1
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LI 00903BESOO 9/19/2013 13:30 s
C X
X X
1 L100904BEQOO 9/19/2013 14:25 s
C X
X X
1 LI 00904BESOO 9/19/2013 14:20 s C
X X
X 1
L100905BESOO 9/19/2013 14:30 s C
X X
X 1
LI 00906BESOO 9/19/2013 15:00 s
C X
X X
1
,1 L100907BESOO 9/19/2013 15:05 s
C X
X X 1
F.SS 10-(R SY~
Ll00908BUBOO 9/19/2013 15:55 s
C X
X X
1 F.55
/0-0<i cs~..s LI 00909BUBOO 9/19/2013 16:00 s
C X
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~J L100910BUBOO 9/23/2013 15:40 s
C X
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1 F.55 lD-Dq 6 td.. c.,
Relinquished bye.__:
Date/Time l~e~_by=AP
...... l Date/Time Total Cooler Temperature:
q~J.~l-3 X?
0 11 Ambient Company Name: (.,t_) t,.l.-
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Cooler ID: Shiooer and Number:
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-ras:,;'t"°oa 1)024-0T Received by:
Date/Time
~linq~ed ~P.
Dg!Time Comments: Please re-analyze samples after 21-day ingrowth
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Company Name:
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Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-3891-2 Login Number: 3891 Question Answer Comment Creator: Daniels, Brian J List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
False Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Rad Qualifier Description U
Indicates the analyte was analyzed for but not detected.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol DOE GA-01-R Radium-226 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 16 1
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Sample Summary TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-3891-1 L100901BES00 Solid 09/19/13 13:20 09/25/13 18:30 160-3891-2 L100902BES00 Solid 09/19/13 13:25 09/25/13 18:30 160-3891-3 L100903BES00 Solid 09/19/13 13:30 09/25/13 18:30 160-3891-4 L100904BEQ00 Solid 09/19/13 14:25 09/25/13 18:30 160-3891-5 L100904BES00 Solid 09/19/13 14:20 09/25/13 18:30 160-3891-6 L100905BES00 Solid 09/19/13 14:30 09/25/13 18:30 160-3891-7 L100906BES00 Solid 09/19/13 15:00 09/25/13 18:30 160-3891-8 L100907BES00 Solid 09/19/13 15:05 09/25/13 18:30 160-3891-9 L100908BUB00 Solid 09/19/13 15:55 09/25/13 18:30 160-3891-10 L100909BUB00 Solid 09/19/13 16:00 09/25/13 18:30 160-3891-11 L100910BUB00 Solid 09/23/13 15:40 09/25/13 18:30 TestAmerica St. Louis Page 9 of 16 1
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Client Sample Results TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-1 Client Sample ID: L100901BES00 Matrix: Solid Date Collected: 09/19/13 13:20 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.09 (2+/-)
0.166 (2+/-)
1 10/21/13 02:10 09/30/13 11:27 pCi/g 0.101 RL MDC 0.124 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.427 0.491 0.472 1.31 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0594 0.168 0.113 1.20 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0583 0.167 0.0753 1.15 Lead 212 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0713 0.169 0.105 1.27 Lead 214 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.309 2.42 1.25 20.2 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 02:10 1
1.16 0.198 0.195 U
0.319 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0594 1.00 0.168 0.113 1.20 Radium 226 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.101 0.166 0.124 1.09 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.836 0.632 0.617 1.33 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.253 0.150 0.149 U
0.179 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0875 0.0523 0.0522 U
0.0239 Americium 241 pCi/g 09/30/13 11:27 10/21/13 02:10 1
5.48 3.18 3.16 U
3.95 Protactinium 234m Lab Sample ID: 160-3891-2 Client Sample ID: L100902BES00 Matrix: Solid Date Collected: 09/19/13 13:25 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.24 (2+/-)
0.279 (2+/-)
1 10/21/13 20:12 09/30/13 11:27 pCi/g 0.122 RL MDC 0.247 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 20:12 1
1.41 0.937 0.927 U
1.28 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 20:12 1
0.196 0.287 0.249 1.37 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 20:12 1
0.180 0.311 0.172 1.20 Lead 212 pCi/g 09/30/13 11:27 10/21/13 20:12 1
0.244 0.338 0.264 1.60 Lead 214 pCi/g 09/30/13 11:27 10/21/13 20:12 1
1.38 3.10 2.39 19.2 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 20:12 1
2.61 0.936 0.925 U
0.887 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 20:12 1
0.196 1.00 0.287 0.249 1.37 Radium 226 pCi/g 09/30/13 11:27 10/21/13 20:12 1
0.122 0.279 0.247 1.24 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 20:12 1
2.53 0.902 0.896 U
0.989 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 20:12 1
0.624 0.249 0.249 U
0.158 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 20:12 1
0.349 0.234 0.234 U
-0.0147 Americium 241 pCi/g 09/30/13 11:27 10/21/13 20:12 1
17.8 1.74 1.74 U
0.000 Protactinium 234m Lab Sample ID: 160-3891-3 Client Sample ID: L100903BES00 Matrix: Solid Date Collected: 09/19/13 13:30 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.14 (2+/-)
0.213 (2+/-)
1 10/21/13 02:10 09/30/13 11:27 pCi/g 0.0961 RL MDC 0.179 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.456 0.544 0.523 1.44 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0796 0.169 0.125 1.09 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0806 0.165 0.0869 1.08 Lead 212 TestAmerica St. Louis Page 10 of 16 1
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Client Sample Results TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-3 Client Sample ID: L100903BES00 Matrix: Solid Date Collected: 09/19/13 13:30 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)
Analyte Lead 214 1.27 (2+/-)
0.176 (2+/-)
1 10/21/13 02:10 09/30/13 11:27 pCi/g 0.0913 RL MDC 0.117 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.451 2.25 1.37 17.5 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 02:10 1
1.25 0.285 0.280 U
0.479 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0796 1.00 0.169 0.125 1.09 Radium 226 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.0961 0.213 0.179 1.14 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 02:10 1
1.19 0.445 0.434 U
0.952 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.281 0.160 0.160 U
0.123 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 02:10 1
0.117 0.0705 0.0704 U
0.0298 Americium 241 pCi/g 09/30/13 11:27 10/21/13 02:10 1
9.20 1.39 1.39 U
0.000 Protactinium 234m Lab Sample ID: 160-3891-4 Client Sample ID: L100904BEQ00 Matrix: Solid Date Collected: 09/19/13 14:25 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.19 (2+/-)
0.190 (2+/-)
1 10/21/13 03:00 09/30/13 11:27 pCi/g 0.118 RL MDC 0.145 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.410 0.350 0.328 1.17 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.0637 0.163 0.103 1.21 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.0573 0.167 0.0719 1.16 Lead 212 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.0776 0.176 0.0917 1.45 Lead 214 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.251 2.18 1.07 18.6 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 03:00 1
1.09 0.212 0.208 U
0.396 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.0637 1.00 0.163 0.103 1.21 Radium 226 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.118 0.190 0.145 1.19 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.819 0.640 0.622 1.44 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.236 0.154 0.153 U
0.169 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.104 0.0621 0.0621 U
0.0147 Americium 241 pCi/g 09/30/13 11:27 10/21/13 03:00 1
5.07 2.79 2.70 6.72 Protactinium 234m Lab Sample ID: 160-3891-5 Client Sample ID: L100904BES00 Matrix: Solid Date Collected: 09/19/13 14:20 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.24 (2+/-)
0.207 (2+/-)
1 10/21/13 03:01 09/30/13 11:27 pCi/g 0.0928 RL MDC 0.164 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.369 0.483 0.452 1.63 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.0781 0.162 0.111 1.13 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.0827 0.163 0.0800 1.10 Lead 212 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.0763 0.180 0.0994 1.45 Lead 214 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.351 2.36 1.16 20.1 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 03:01 1
1.19 0.367 0.359 U
0.697 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.0781 1.00 0.162 0.111 1.13 Radium 226 TestAmerica St. Louis Page 11 of 16 1
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Client Sample Results TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-5 Client Sample ID: L100904BES00 Matrix: Solid Date Collected: 09/19/13 14:20 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 232 1.24 (2+/-)
0.207 (2+/-)
1 10/21/13 03:01 09/30/13 11:27 pCi/g 0.0928 RL MDC 0.164 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.896 0.737 0.716 1.68 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.265 0.153 0.153 U
0.0456 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.116 0.0695 0.0694 U
-0.0131 Americium 241 pCi/g 09/30/13 11:27 10/21/13 03:01 1
5.03 3.06 3.05 U
2.43 Protactinium 234m Lab Sample ID: 160-3891-6 Client Sample ID: L100905BES00 Matrix: Solid Date Collected: 09/19/13 14:30 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.06 (2+/-)
0.176 (2+/-)
1 10/21/13 03:00 09/30/13 11:27 pCi/g 0.130 RL MDC 0.138 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.349 0.385 0.366 1.15 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.0694 0.210 0.132 1.57 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.0652 0.159 0.0774 1.08 Lead 212 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.0737 0.202 0.114 1.60 Lead 214 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.361 2.31 1.27 18.9 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 03:00 1
1.25 0.179 0.177 U
0.214 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.0694 1.00 0.210 0.132 1.57 Radium 226 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.130 0.176 0.138 1.06 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.763 0.546 0.533 1.15 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.256 0.154 0.153 U
0.102 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 03:00 1
0.108 0.0953 0.0953 U
-0.0329 Americium 241 pCi/g 09/30/13 11:27 10/21/13 03:00 1
6.06 2.98 2.92 6.06 Protactinium 234m Lab Sample ID: 160-3891-7 Client Sample ID: L100906BES00 Matrix: Solid Date Collected: 09/19/13 15:00 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.08 (2+/-)
0.189 (2+/-)
1 10/21/13 03:01 09/30/13 11:27 pCi/g 0.144 RL MDC 0.154 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.528 0.611 0.592 1.45 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.0733 0.175 0.123 1.20 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.0671 0.160 0.0811 1.07 Lead 212 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.0850 0.170 0.112 1.24 Lead 214 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.406 2.35 1.36 18.7 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 03:01 1
1.47 0.886 0.884 U
-0.594 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.0733 1.00 0.175 0.123 1.20 Radium 226 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.144 0.189 0.154 1.08 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.969 0.770 0.759 1.25 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.180 0.147 0.146 U
0.172 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 03:01 1
0.120 0.0710 0.0710 U
0.00267 Americium 241 TestAmerica St. Louis Page 12 of 16 1
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Client Sample Results TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-7 Client Sample ID: L100906BES00 Matrix: Solid Date Collected: 09/19/13 15:00 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)
Analyte Protactinium 234m 6.02 U
(2+/-)
2.90 (2+/-)
1 10/21/13 03:01 09/30/13 11:27 pCi/g 9.44 RL MDC 2.83 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Lab Sample ID: 160-3891-8 Client Sample ID: L100907BES00 Matrix: Solid Date Collected: 09/19/13 15:05 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.12 (2+/-)
0.163 (2+/-)
1 10/21/13 03:35 09/30/13 11:27 pCi/g 0.125 RL MDC 0.116 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.364 0.476 0.443 1.67 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.0754 0.165 0.113 1.15 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.0495 0.162 0.0703 1.13 Lead 212 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.0665 0.161 0.0987 1.22 Lead 214 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.324 2.13 1.09 17.9 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 03:35 1
1.22 0.259 0.251 U
0.576 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.0754 1.00 0.165 0.113 1.15 Radium 226 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.125 0.163 0.116 1.12 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.929 0.786 0.769 1.54 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.250 0.145 0.145 U
0.0888 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.108 0.0646 0.0646 U
-0.0125 Americium 241 pCi/g 09/30/13 11:27 10/21/13 03:35 1
5.03 2.86 2.86 U
0.426 Protactinium 234m Lab Sample ID: 160-3891-9 Client Sample ID: L100908BUB00 Matrix: Solid Date Collected: 09/19/13 15:55 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.13 (2+/-)
0.171 (2+/-)
1 10/21/13 03:36 09/30/13 11:27 pCi/g 0.110 RL MDC 0.126 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.343 0.370 0.353 1.06 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0600 0.155 0.102 1.13 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0797 0.141 0.0742 0.926 Lead 212 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0804 0.162 0.0895 1.29 Lead 214 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.364 2.30 1.15 19.5 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 03:36 1
1.08 0.208 0.204 U
0.374 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0600 1.00 0.155 0.102 1.13 Radium 226 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.110 0.171 0.126 1.13 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.834 0.662 0.647 1.36 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.242 0.128 0.128 U
0.0996 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0870 0.0514 0.0514 U
0.00339 Americium 241 pCi/g 09/30/13 11:27 10/21/13 03:36 1
5.51 1.92 1.91 U
2.45 Protactinium 234m TestAmerica St. Louis Page 13 of 16 1
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Client Sample Results TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-10 Client Sample ID: L100909BUB00 Matrix: Solid Date Collected: 09/19/13 16:00 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.10 (2+/-)
0.172 (2+/-)
1 10/21/13 03:35 09/30/13 11:27 pCi/g 0.107 RL MDC 0.131 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.470 0.366 0.353 0.913 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.0716 0.170 0.119 1.16 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.0632 0.169 0.0800 1.15 Lead 212 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.0755 0.175 0.105 1.35 Lead 214 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.366 2.44 1.32 20.0 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 03:35 1
1.26 0.224 0.221 U
0.371 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.0716 1.00 0.170 0.119 1.16 Radium 226 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.107 0.172 0.131 1.10 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.912 0.345 0.328 1.02 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.243 0.151 0.150 U
0.122 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 03:35 1
0.112 0.0980 0.0980 U
-0.0347 Americium 241 pCi/g 09/30/13 11:27 10/21/13 03:35 1
6.38 3.16 3.10 U
5.76 Protactinium 234m Lab Sample ID: 160-3891-11 Client Sample ID: L100910BUB00 Matrix: Solid Date Collected: 09/23/13 15:40 Date Received: 09/25/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.25 (2+/-)
0.224 (2+/-)
1 10/21/13 03:36 09/30/13 11:27 pCi/g 0.0814 RL MDC 0.184 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.532 0.451 0.430 1.29 Bismuth 212 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0964 0.197 0.147 1.26 Bismuth 214 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0740 0.167 0.0871 1.10 Lead 212 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0840 0.179 0.114 1.33 Lead 214 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.457 2.39 1.44 18.7 Potassium 40 pCi/g 09/30/13 11:27 10/21/13 03:36 1
1.28 0.451 0.443 U
0.761 Protactinium 231 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0964 1.00 0.197 0.147 1.26 Radium 226 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.0814 0.224 0.184 1.25 Thorium 232 pCi/g 09/30/13 11:27 10/21/13 03:36 1
1.20 0.417 0.408 U
0.822 Thorium 234 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.242 0.150 0.149 U
0.167 Uranium 235 pCi/g 09/30/13 11:27 10/21/13 03:36 1
0.126 0.0749 0.0749 U
-0.00979 Americium 241 pCi/g 09/30/13 11:27 10/21/13 03:36 1
6.86 3.97 3.97 U
1.55 Protactinium 234m TestAmerica St. Louis Page 14 of 16 1
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QC Sample Results TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-75280/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 80126 Prep Batch: 75280 Actinium 228 Analyte U
1 10/21/13 02:09 09/30/13 11:27 pCi/g 0.0298 MDC RL 0.0221 0.0220 (2+/-)
(2+/-)
MB 0.01828 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.187 0.0955 0.0955 U
-0.0005792 Bismuth 212 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.0421 0.0206 0.0206 U
-0.0003736 Bismuth 214 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.0254 0.0136 0.0135 U
0.009142 Lead 212 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.0358 0.0175 0.0175 U
0.008476 Lead 214 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.233 4.95 4.95 U
-0.1238 Potassium 40 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.324 0.176 0.176 U
0.02238 Protactinium 231 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.0421 1.00 0.0206 0.0206 U
-0.0003736 Radium 226 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.0298 0.0221 0.0220 U
0.01828 Thorium 232 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.265 0.0448 0.0448 U
0.01166 Thorium 234 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.0663 0.0298 0.0298 U
0.002143 Uranium 235 1
10/21/13 02:09 09/30/13 11:27 pCi/g 0.0224 0.0130 0.0130 U
0.005807 Americium 241 1
10/21/13 02:09 09/30/13 11:27 pCi/g 2.12 0.0494 0.0494 U
0.01092 Protactinium 234m Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-75280/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 80124 Prep Batch: 75280 Americium 241 Analyte 116 87 96 94.20 97.7 9.80 0.479 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 31.5 31.06 3.25 0.130 pCi/g 98 87 - 120 Cobalt 60 24.3 23.62 2.38 0.0871 pCi/g 97 87 - 115 Client Sample ID: L100910BUB00 Lab Sample ID: 160-3891-11 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 80127 Prep Batch: 75280 Actinium 228 Analyte 1
0.34 1.111 1.25 0.182 0.156 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Bismuth 212 1.29 1.510 0.477 0.384 pCi/g 0.24 1
Bismuth 214 1.26 1.258 0.183 0.0771 pCi/g 0
1 Lead 212 1.10 1.167 0.172 0.0676 pCi/g 0.19 1
Lead 214 1.33 1.459 0.183 0.0933 pCi/g 0.36 1
Potassium 40 18.7 19.45 2.38 0.278 pCi/g 0.16 1
Protactinium 231 0.761 U
0.5601 U
0.420 1.23 pCi/g 0.23 1
Radium 226 1.26 1.258 0.183 1.00 0.0771 pCi/g 0
1 Thorium 232 1.25 1.111 0.182 0.156 pCi/g 0.34 1
Thorium 234 0.822 U
1.330 0.686 0.892 pCi/g 0.46 1
Uranium 235 0.167 U
0.1606 U
0.136 0.256 pCi/g 0.02 1
-0.00979 U
0.001473 U
0.0629 0.107 pCi/g 0.08 1
Protactinium 234m 1.55 U
5.846 U
2.63 6.32 pCi/g 0.65 1
TestAmerica St. Louis Page 15 of 16 1
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QC Association Summary TestAmerica Job ID: 160-3891-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Rad Leach Batch: 74888 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-3891-1 L100901BES00 Total/NA Solid Dry and Grind 160-3891-2 L100902BES00 Total/NA Solid Dry and Grind 160-3891-3 L100903BES00 Total/NA Solid Dry and Grind 160-3891-4 L100904BEQ00 Total/NA Solid Dry and Grind 160-3891-5 L100904BES00 Total/NA Solid Dry and Grind 160-3891-6 L100905BES00 Total/NA Solid Dry and Grind 160-3891-7 L100906BES00 Total/NA Solid Dry and Grind 160-3891-8 L100907BES00 Total/NA Solid Dry and Grind 160-3891-9 L100908BUB00 Total/NA Solid Dry and Grind 160-3891-10 L100909BUB00 Total/NA Solid Dry and Grind 160-3891-11 L100910BUB00 Total/NA Solid Dry and Grind 160-3891-11 DU L100910BUB00 Total/NA Prep Batch: 75280 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-21 74888 160-3891-1 L100901BES00 Total/NA Solid Fill_Geo-21 74888 160-3891-2 L100902BES00 Total/NA Solid Fill_Geo-21 74888 160-3891-3 L100903BES00 Total/NA Solid Fill_Geo-21 74888 160-3891-4 L100904BEQ00 Total/NA Solid Fill_Geo-21 74888 160-3891-5 L100904BES00 Total/NA Solid Fill_Geo-21 74888 160-3891-6 L100905BES00 Total/NA Solid Fill_Geo-21 74888 160-3891-7 L100906BES00 Total/NA Solid Fill_Geo-21 74888 160-3891-8 L100907BES00 Total/NA Solid Fill_Geo-21 74888 160-3891-9 L100908BUB00 Total/NA Solid Fill_Geo-21 74888 160-3891-10 L100909BUB00 Total/NA Solid Fill_Geo-21 74888 160-3891-11 L100910BUB00 Total/NA Solid Fill_Geo-21 74888 160-3891-11 DU L100910BUB00 Total/NA Solid Fill_Geo-21 LCS 160-75280/2-A Lab Control Sample Total/NA Solid Fill_Geo-21 MB 160-75280/1-A Method Blank Total/NA TestAmerica St. Louis Page 16 of 16 1
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