ML18010A289

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Final Status Survey Final Report Volume 3, Chapter 6, Survey Area Release Record for Land Survey Area 10, Analytical Report: 160-4764-2
ML18010A289
Person / Time
Site: 07000036
Issue date: 01/14/2014
From: Swanson M, Vania I
TestAmerica Labs - St. Louis, Westinghouse
To:
Office of Nuclear Material Safety and Safeguards
Shared Package
ML18010A247 List: ... further results
References
HEM-17-72 160-4764-2
Download: ML18010A289 (15)
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ANALYTICAL REPORT TestAmerica Laboratories, Inc.

TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-4764-2 Client Project/Site: RFP-CBA-022 (7 DAY TAT)

For:

Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:

1/14/2014 9:23:03 AM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

TestAmerica Job ID: 160-4764-2 Page 2 of 15 Cover Page..............................................

1 Table of Contents.........................................

2 Case Narrative...........................................

3 Chain of Custody..........................................

4 Receipt Checklists.........................................

6 Definitions/Glossary.......................................

7 Method Summary.........................................

8 Sample Summary.........................................

9 Client Sample Results......................................

10 QC Sample Results........................................

14 QC Association Summary...................................

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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-4764-2 Project/Site: RFP-CBA-022 (7 DAY TAT)

Job ID: 160-4764-2 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)

Report Number: 160-4764-2 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %

solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.

RECEIPT The samples were received on 12/04/2013 and 12/04/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.2 C.

RADIUM-226 BY GAMMA SPEC (21 DAY INGROWTH)

Samples L100701BUI01 (160-4764-1), L100701BUI02 (160-4764-2), L100701BUI03 (160-4764-3), L100701BUI04 (160-4764-4),

L100715BUB00 (160-4764-5), L100716BUB00 (160-4764-6), L100610BUB00 (160-4764-7), L100611BUB00 (160-4764-8) and L100612BUB00 (160-4764-9) were analyzed for Radium-226 by gamma spec (21 day ingrowth) in accordance with EPA GA_01_R. The samples were leached on 12/18/2013, prepared on 12/20/2013 and analyzed on 01/10/2014 and 01/11/2014.

No other difficulties were encountered during the Radium 226 analysis. All other quality control parameters were within the acceptance limits.

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10 11 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision: 3 I

Page 1 ofl Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.

Chain ofCutodv ID No.

F-120413-02 Pa2e 1/1 Reauested.Aiiaivsis Labonitorv Name:

f'-==...c=~"--""~='--------------1 Project Na.me:

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TA-MO Westinghouse Electric Company

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Contact Person:

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1-L-a_b_o_r-at_o_ry_A_d_d_r_es_s_:------------1 Gerald Rood

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13715 Rider Trail North

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fi' Phone Number:

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Phone No.

314-810-3382

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.5 314-298-8566 Sampler Name f'_-'

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708-870-8453

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Sample ID Date Time Matrix 8

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t~ '.d Remarks L100701BU101 12/3/2013 14:50 S

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1 LSA-10-07 Investigation L100701BU102 12/3/2013 14:55 S

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  • X X

3 1 LSA-10-07 Investigation L100701BUI03 12/3/2013 15:05 S

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X: X 1 LSA-10-07 Investigation L100701BU104 12/3/2013 15:10 S

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  • X X

1 LSA-10-07 Investigation L100715BUBOO 12/3/2013 14:40 S

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1 LSA-10-07 Bias Samples Ll00716BUBOO 12/3/2013 15:30 S

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  • X 1 LSA-10-07 Bias Samples

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Date/rime

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Date/rime Total Cooler Temperature:

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poa.02 Received by:

Date/rime

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Date/rime Comments: Please analyze samples for Tc-99 on a 7 day TAT.

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_-Li4 Please analyze samples for gamma spec after a 21 day ingrowth Company Name:

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ComuanvName:

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!Procedure HPP-PR-QA-006, Chain of Custody Hematite Decommissioning Project !Revision: 3 Page I ofl l Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY fustructions: Each time the container is transferred to another organization, a person from each organization should sign the Coe The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.

Chain ofCutodv ID No. I F-120413-01 Page 1/1 Project Name:

Westinghouse Electric Company Contact Person:

Gerald Rood Phone Number:

314-810-3382 Sampler Name Scott Jenkins 1~-, --:5:!j~};J 6' '.'\\7', E

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!;fl lsample ID loate

!Time

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L100610BUBOO Ll00611BUBOO IL100612BUBOO Relinquished by~ --.!:.

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Received by:

Company Name:

Relinquished by:

Company Name:

12/3/2013 16:051 S

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  • I 1x1x1 12/3/2013 15:501 S

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Laboratory Name:

TA-MO Laboratory Address:

13715 Rider Trail North

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8 314-298-8566 i I Laboratory Contact Person:

f-< Joe Walker Phone No.

708~ 70-8453 Turn Around Time Rush (7 days)

Remarks 1 ILSA-10-06 Bias Samples 1 ILSA-10-06 Bias Samples 1 ILSA-10-06 Bias Samples Total

!Cooler Temperature:

3 Ambien1 Cooler ID: I Shipper and Number:

1204-02 Comments: Please analyze samples for Tc-99 on a 7 day TAT.

Please analyze samples for gamma spec after a 21 day ingrowth period.

Verified By:

('_

---~------------- ----- ---- ---:---:-;---;-1: *1--------

Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-4764-2 Login Number: 4764 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.

True The cooler's custody seal, if present, is intact.

N/A Sample custody seals, if present, are intact.

True The cooler or samples do not appear to have been compromised or tampered with.

False Samples were received on ice.

True Cooler Temperature is acceptable.

True Cooler Temperature is recorded.

Thermal preservation not required.

True COC is present.

True COC is filled out in ink and legible.

True COC is filled out with all pertinent information.

True Is the Field Sampler's name present on COC?

True There are no discrepancies between the containers received and the COC.

True Samples are received within Holding Time.

True Sample containers have legible labels.

True Containers are not broken or leaking.

True Sample collection date/times are provided.

True Appropriate sample containers are used.

True Sample bottles are completely filled.

True Sample Preservation Verified.

True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is

<6mm (1/4").

True Multiphasic samples are not present.

True Samples do not require splitting or compositing.

N/A Residual Chlorine Checked.

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Definitions/Glossary TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Qualifiers Rad Qualifier Description U

Indicates the analyte was analyzed for but not detected.

Qualifier Glossary These commonly used abbreviations may or may not be present in this report.

Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation

%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)

NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

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Method Summary TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method Method Description Laboratory Protocol DOE GA-01-R Radium-226 & Other Gamma Emitters (GS)

TAL SL Protocol

References:

DOE = U.S. Department of Energy Laboratory

References:

TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 15 1

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Sample Summary TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID Client Sample ID Received Collected Matrix 160-4764-1 L100701BUI01 Solid 12/03/13 14:50 12/04/13 18:30 160-4764-2 L100701BUI02 Solid 12/03/13 14:55 12/04/13 18:30 160-4764-3 L100701BUI03 Solid 12/03/13 15:05 12/04/13 18:30 160-4764-4 L100701BUI04 Solid 12/03/13 15:10 12/04/13 18:30 160-4764-5 L100715BUB00 Solid 12/03/13 14:40 12/04/13 18:30 160-4764-6 L100716BUB00 Solid 12/03/13 15:30 12/04/13 18:30 160-4764-7 L100610BUB00 Solid 12/03/13 16:05 12/04/13 18:45 160-4764-8 L100611BUB00 Solid 12/03/13 15:50 12/04/13 18:45 160-4764-9 L100612BUB00 Solid 12/03/13 15:40 12/04/13 18:45 TestAmerica St. Louis Page 9 of 15 1

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Client Sample Results TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4764-1 Client Sample ID: L100701BUI01 Matrix: Solid Date Collected: 12/03/13 14:50 Date Received: 12/04/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.18 (2+/-)

0.187 (2+/-)

1 01/10/14 18:25 12/20/13 10:21 pCi/g 0.0566 RL MDC 0.144 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.364 0.439 0.415 1.38 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.0690 0.176 0.117 1.26 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.0634 0.163 0.0769 1.11 Lead 212 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.0794 0.169 0.107 1.25 Lead 214 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.341 2.37 1.26 19.6 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.930 0.341 0.335 U

0.582 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.0690 1.00 0.176 0.117 1.26 Radium 226 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.0566 0.187 0.144 1.18 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.865 0.360 0.340 1.13 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.213 0.158 0.157 0.214 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 18:25 1

0.0992 0.0585 0.0585 U

0.00448 Americium 241 pCi/g 12/20/13 10:21 01/10/14 18:25 1

6.54 3.70 3.70 U

-0.220 Protactinium 234m Lab Sample ID: 160-4764-2 Client Sample ID: L100701BUI02 Matrix: Solid Date Collected: 12/03/13 14:55 Date Received: 12/04/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.00 (2+/-)

0.167 (2+/-)

1 01/10/14 18:26 12/20/13 10:21 pCi/g 0.169 RL MDC 0.132 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.370 0.480 0.454 1.50 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.0757 0.161 0.117 1.06 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.0720 0.144 0.0769 0.937 Lead 212 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.0739 0.165 0.106 1.21 Lead 214 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.392 2.25 1.30 17.9 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 18:26 1

1.28 0.256 0.251 U

0.420 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.0757 1.00 0.161 0.117 1.06 Radium 226 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.169 0.167 0.132 1.00 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.941 0.783 0.764 1.62 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.213 0.129 0.129 U

0.132 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 18:26 1

0.113 0.0674 0.0674 U

0.00847 Americium 241 pCi/g 12/20/13 10:21 01/10/14 18:26 1

7.66 2.37 2.33 U

4.60 Protactinium 234m Lab Sample ID: 160-4764-3 Client Sample ID: L100701BUI03 Matrix: Solid Date Collected: 12/03/13 15:05 Date Received: 12/04/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.12 (2+/-)

0.170 (2+/-)

1 01/10/14 18:27 12/20/13 10:21 pCi/g 0.105 RL MDC 0.126 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.460 0.361 0.343 1.08 Bismuth 212 pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.0649 0.154 0.0994 1.13 Bismuth 214 pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.0567 0.153 0.0686 1.05 Lead 212 TestAmerica St. Louis Page 10 of 15 1

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Client Sample Results TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4764-3 Client Sample ID: L100701BUI03 Matrix: Solid Date Collected: 12/03/13 15:05 Date Received: 12/04/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)

Analyte Lead 214 1.22 (2+/-)

0.155 (2+/-)

1 01/10/14 18:27 12/20/13 10:21 pCi/g 0.0660 RL MDC 0.0888 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.260 2.30 1.10 19.7 Potassium 40 pCi/g 12/20/13 10:21 01/10/14 18:27 1

1.01 0.202 0.197 U

0.415 Protactinium 231 pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.0649 1.00 0.154 0.0994 1.13 Radium 226 pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.105 0.170 0.126 1.12 Thorium 232 pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.821 0.634 0.617 1.36 Thorium 234 pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.229 0.146 0.146 U

0.0755 Uranium 235 pCi/g 12/20/13 10:21 01/10/14 18:27 1

0.104 0.0615 0.0615 U

0.000553 Americium 241 pCi/g 12/20/13 10:21 01/10/14 18:27 1

4.64 2.73 2.73 U

1.82 Protactinium 234m Lab Sample ID: 160-4764-4 Client Sample ID: L100701BUI04 Matrix: Solid Date Collected: 12/03/13 15:10 Date Received: 12/04/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.17 (2+/-)

0.202 (2+/-)

1 01/11/14 02:01 12/20/13 10:21 pCi/g 0.121 RL MDC 0.163 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.441 0.517 0.494 1.47 Bismuth 212 pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.0764 0.181 0.130 1.21 Bismuth 214 pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.0791 0.177 0.0901 1.17 Lead 212 pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.0965 0.177 0.117 1.27 Lead 214 pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.463 2.57 1.50 20.4 Potassium 40 pCi/g 12/20/13 10:21 01/11/14 02:01 1

1.50 0.275 0.270 U

0.465 Protactinium 231 pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.0764 1.00 0.181 0.130 1.21 Radium 226 pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.121 0.202 0.163 1.17 Thorium 232 pCi/g 12/20/13 10:21 01/11/14 02:01 1

1.00 0.804 0.781 1.82 Thorium 234 pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.269 0.174 0.174 U

0.0575 Uranium 235 pCi/g 12/20/13 10:21 01/11/14 02:01 1

0.0934 0.0680 0.0676 U

0.0703 Americium 241 pCi/g 12/20/13 10:21 01/11/14 02:01 1

6.61 3.83 3.82 U

1.53 Protactinium 234m Lab Sample ID: 160-4764-5 Client Sample ID: L100715BUB00 Matrix: Solid Date Collected: 12/03/13 14:40 Date Received: 12/04/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.15 (2+/-)

0.189 (2+/-)

1 01/11/14 01:56 12/20/13 10:21 pCi/g 0.0908 RL MDC 0.148 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.459 0.351 0.337 0.973 Bismuth 212 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.0744 0.167 0.111 1.21 Bismuth 214 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.0540 0.163 0.0704 1.13 Lead 212 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.0810 0.161 0.0983 1.22 Lead 214 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.384 2.15 1.10 18.1 Potassium 40 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.708 0.425 0.422 U

0.465 Protactinium 231 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.0744 1.00 0.167 0.111 1.21 Radium 226 TestAmerica St. Louis Page 11 of 15 1

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Client Sample Results TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4764-5 Client Sample ID: L100715BUB00 Matrix: Solid Date Collected: 12/03/13 14:40 Date Received: 12/04/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)

Analyte Thorium 232 1.15 (2+/-)

0.189 (2+/-)

1 01/11/14 01:56 12/20/13 10:21 pCi/g 0.0908 RL MDC 0.148 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.985 0.414 0.401 U

0.971 Thorium 234 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.232 0.297 0.228 1.87 Uranium 235 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.117 0.0702 0.0702 U

0.0181 Americium 241 pCi/g 12/20/13 10:21 01/11/14 01:56 1

5.05 2.83 2.83 U

0.623 Protactinium 234m Lab Sample ID: 160-4764-6 Client Sample ID: L100716BUB00 Matrix: Solid Date Collected: 12/03/13 15:30 Date Received: 12/04/13 18:30 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.14 (2+/-)

0.170 (2+/-)

1 01/11/14 01:57 12/20/13 10:21 pCi/g 0.132 RL MDC 0.124 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.444 0.332 0.321 0.832 Bismuth 212 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0509 0.156 0.0985 1.16 Bismuth 214 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0829 0.162 0.0802 1.09 Lead 212 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0806 0.164 0.0906 1.31 Lead 214 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.298 2.48 1.19 21.3 Potassium 40 pCi/g 12/20/13 10:21 01/11/14 01:57 1

1.29 0.790 0.786 U

-0.698 Protactinium 231 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0509 1.00 0.156 0.0985 1.16 Radium 226 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.132 0.170 0.124 1.14 Thorium 232 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.883 0.663 0.655 0.949 Thorium 234 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.201 0.139 0.138 U

0.164 Uranium 235 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.113 0.0676 0.0676 U

0.0136 Americium 241 pCi/g 12/20/13 10:21 01/11/14 01:57 1

3.92 1.47 1.47 U

0.156 Protactinium 234m Lab Sample ID: 160-4764-7 Client Sample ID: L100610BUB00 Matrix: Solid Date Collected: 12/03/13 16:05 Date Received: 12/04/13 18:45 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.26 (2+/-)

0.188 (2+/-)

1 01/11/14 01:55 12/20/13 10:21 pCi/g 0.139 RL MDC 0.137 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.367 0.438 0.410 1.48 Bismuth 212 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.0675 0.155 0.111 1.05 Bismuth 214 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.0669 0.167 0.0794 1.13 Lead 212 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.0773 0.156 0.0968 1.18 Lead 214 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.362 2.51 1.33 20.9 Potassium 40 pCi/g 12/20/13 10:21 01/11/14 01:55 1

1.36 0.833 0.829 U

-0.756 Protactinium 231 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.0675 1.00 0.155 0.111 1.05 Radium 226 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.139 0.188 0.137 1.26 Thorium 232 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.807 0.326 0.311 0.924 Thorium 234 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.244 0.161 0.161 U

0.123 Uranium 235 pCi/g 12/20/13 10:21 01/11/14 01:55 1

0.0923 0.0546 0.0545 U

0.0122 Americium 241 TestAmerica St. Louis Page 12 of 15 1

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Client Sample Results TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4764-7 Client Sample ID: L100610BUB00 Matrix: Solid Date Collected: 12/03/13 16:05 Date Received: 12/04/13 18:45 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS) (Continued)

Analyte Protactinium 234m 1.09 U

(2+/-)

3.05 (2+/-)

1 01/11/14 01:55 12/20/13 10:21 pCi/g 5.29 RL MDC 3.05 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Lab Sample ID: 160-4764-8 Client Sample ID: L100611BUB00 Matrix: Solid Date Collected: 12/03/13 15:50 Date Received: 12/04/13 18:45 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.03 (2+/-)

0.205 (2+/-)

1 01/11/14 01:56 12/20/13 10:21 pCi/g 0.137 RL MDC 0.176 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.507 0.606 0.585 1.53 Bismuth 212 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.0651 0.165 0.116 1.13 Bismuth 214 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.0728 0.166 0.0844 1.10 Lead 212 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.0946 0.167 0.106 1.24 Lead 214 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.275 2.30 1.33 18.3 Potassium 40 pCi/g 12/20/13 10:21 01/11/14 01:56 1

1.34 0.245 0.242 U

0.330 Protactinium 231 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.0651 1.00 0.165 0.116 1.13 Radium 226 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.137 0.205 0.176 1.03 Thorium 232 pCi/g 12/20/13 10:21 01/11/14 01:56 1

1.06 0.940 0.886 3.01 Thorium 234 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.265 0.271 0.256 0.889 Uranium 235 pCi/g 12/20/13 10:21 01/11/14 01:56 1

0.134 0.0799 0.0799 U

-0.00860 Americium 241 pCi/g 12/20/13 10:21 01/11/14 01:56 1

6.51 3.85 3.85 U

2.15 Protactinium 234m Lab Sample ID: 160-4764-9 Client Sample ID: L100612BUB00 Matrix: Solid Date Collected: 12/03/13 15:40 Date Received: 12/04/13 18:45 Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Analyte Actinium 228 1.08 (2+/-)

0.174 (2+/-)

1 01/11/14 01:57 12/20/13 10:21 pCi/g 0.119 RL MDC 0.134 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.408 0.470 0.448 1.35 Bismuth 212 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0662 0.143 0.0980 0.997 Bismuth 214 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0558 0.160 0.0715 1.10 Lead 212 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0594 0.149 0.0903 1.14 Lead 214 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.287 2.16 1.10 18.1 Potassium 40 pCi/g 12/20/13 10:21 01/11/14 01:57 1

1.00 0.400 0.398 U

0.357 Protactinium 231 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0662 1.00 0.143 0.0980 0.997 Radium 226 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.119 0.174 0.134 1.08 Thorium 232 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.886 0.709 0.695 1.34 Thorium 234 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.221 0.136 0.135 U

0.143 Uranium 235 pCi/g 12/20/13 10:21 01/11/14 01:57 1

0.0922 0.0551 0.0551 U

-0.0190 Americium 241 pCi/g 12/20/13 10:21 01/11/14 01:57 1

5.33 2.94 2.94 U

0.0867 Protactinium 234m TestAmerica St. Louis Page 13 of 15 1

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QC Sample Results TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method: GA-01-R - Radium-226 & Other Gamma Emitters (GS)

Client Sample ID: Method Blank Lab Sample ID: MB 160-93557/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 97316 Prep Batch: 93557 Actinium 228 Analyte U

1 01/10/14 17:04 12/20/13 10:21 pCi/g 0.0537 MDC RL 0.0222 0.0222 (2+/-)

(2+/-)

MB 0.0000 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.

Count Uncert.

Total 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.152 0.0829 0.0829 U

0.02844 Bismuth 212 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.0360 0.0208 0.0208 U

-0.002331 Bismuth 214 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.0244 0.0322 0.0322 U

-0.005957 Lead 212 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.0323 0.119 0.119 U

-0.01237 Lead 214 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.182 2.97 2.97 U

-0.07423 Potassium 40 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.300 0.0847 0.0847 U

0.009655 Protactinium 231 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.0360 1.00 0.0208 0.0208 U

-0.002331 Radium 226 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.0537 0.0222 0.0222 U

0.0000 Thorium 232 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.273 0.175 0.175 U

-0.01643 Thorium 234 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.0579 0.0372 0.0371 U

0.02249 Uranium 235 1

01/10/14 17:04 12/20/13 10:21 pCi/g 0.0291 0.0126 0.0126 U

0.0000 Americium 241 1

01/10/14 17:04 12/20/13 10:21 pCi/g 2.86 0.241 0.241 U

0.0000 Protactinium 234m Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-93557/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 97309 Prep Batch: 93557 Americium 241 Analyte 116 87 99 99.73 101 10.4 0.492 RL MDC (2+/-)

LCS LCS pCi/g Unit Result Qual

%Rec Added Spike Limits

%Rec.

Uncert.

Total Cesium 137 35.9 35.17 3.69 0.202 pCi/g 98 87 - 120 Cobalt 60 42.5 41.32 4.17 0.117 pCi/g 97 87 - 115 Client Sample ID: Duplicate Lab Sample ID: 160-4704-A-1-I DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 97314 Prep Batch: 93557 Actinium 228 Analyte 1

0.01 1.033 1.04 0.167 0.0602 RL MDC (2+/-)

DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.

Total RER RER Bismuth 212 0.819 1.068 0.381 0.361 pCi/g 0.34 1

Bismuth 214 1.26 1.402 0.182 0.0605 pCi/g 0.37 1

Lead 212 1.00 1.028 0.149 0.0509 pCi/g 0.09 1

Lead 214 1.44 1.485 0.187 0.0806 pCi/g 0.13 1

Potassium 40 16.6 17.24 2.05 0.312 pCi/g 0.16 1

Protactinium 231

-0.591 U

-0.6256 U

0.716 1.17 pCi/g 0.02 1

Radium 226 1.26 1.402 0.182 1.00 0.0605 pCi/g 0.37 1

Thorium 232 1.04 1.033 0.167 0.0602 pCi/g 0.01 1

Thorium 234 1.84 1.457 0.707 0.871 pCi/g 0.24 1

Uranium 235 0.142 U

0.09667 U

0.141 0.242 pCi/g 0.15 1

Americium 241 0.000206 U

-0.01055 U

0.0639 0.107 pCi/g 0.08 1

Protactinium 234m 0.0192 U

0.7795 U

2.86 5.05 pCi/g 0.12 1

TestAmerica St. Louis Page 14 of 15 1

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QC Association Summary TestAmerica Job ID: 160-4764-2 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Rad Leach Batch: 92866 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-4704-A-1-I DU Duplicate Total/NA Leach Batch: 92876 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-4764-1 L100701BUI01 Total/NA Solid Dry and Grind 160-4764-2 L100701BUI02 Total/NA Solid Dry and Grind 160-4764-3 L100701BUI03 Total/NA Solid Dry and Grind 160-4764-4 L100701BUI04 Total/NA Solid Dry and Grind 160-4764-5 L100715BUB00 Total/NA Solid Dry and Grind 160-4764-6 L100716BUB00 Total/NA Solid Dry and Grind 160-4764-7 L100610BUB00 Total/NA Solid Dry and Grind 160-4764-8 L100611BUB00 Total/NA Solid Dry and Grind 160-4764-9 L100612BUB00 Total/NA Prep Batch: 93557 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-21 92866 160-4704-A-1-I DU Duplicate Total/NA Solid Fill_Geo-21 92876 160-4764-1 L100701BUI01 Total/NA Solid Fill_Geo-21 92876 160-4764-2 L100701BUI02 Total/NA Solid Fill_Geo-21 92876 160-4764-3 L100701BUI03 Total/NA Solid Fill_Geo-21 92876 160-4764-4 L100701BUI04 Total/NA Solid Fill_Geo-21 92876 160-4764-5 L100715BUB00 Total/NA Solid Fill_Geo-21 92876 160-4764-6 L100716BUB00 Total/NA Solid Fill_Geo-21 92876 160-4764-7 L100610BUB00 Total/NA Solid Fill_Geo-21 92876 160-4764-8 L100611BUB00 Total/NA Solid Fill_Geo-21 92876 160-4764-9 L100612BUB00 Total/NA Solid Fill_Geo-21 LCS 160-93557/2-A Lab Control Sample Total/NA Solid Fill_Geo-21 MB 160-93557/1-A Method Blank Total/NA TestAmerica St. Louis Page 15 of 15 1

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