ML18010A283
| ML18010A283 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 12/13/2017 |
| From: | Swanson M, Vania I TestAmerica Labs - St. Louis, Westinghouse |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| ML18010A247 | List:
|
| References | |
| 160-6589-1, HEM-17-72 | |
| Download: ML18010A283 (22) | |
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-6589-1 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:
5/16/2014 12:01:44 PM Rhonda Ridenhower, Manager of Project Management rhonda.ridenhower@testamericainc.com Designee for Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-6589-1 Page 2 of 22 TestAmerica St. Louis 5/16/2014 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
17 QC Association Summary...................................
20 Tracer Carrier Summary....................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-6589-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-6589-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-6589-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 05/08/2014; the samples arrived in good condition and properly preserved. The temperature of the coolers at receipt was 20.3 C.
TECHNETIUM-99 (ICPMS)
Samples L100529BSB00 (160-6589-1), L100530BSB00 (160-6589-2), L100531BSB00 (160-6589-3), L100532BSB00 (160-6589-4),
L100533BSB00 (160-6589-5), L100534BSB00 (160-6589-6), L100535BSB00 (160-6589-7) and L100536BSB00 (160-6589-8) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 05/12/2014 and analyzed on 05/14/2014.
No difficulties were encountered during the Tc-99 analysis.
All quality control parameters were within the acceptance limits.
PERCENT SOLIDS Samples L100529BSB00 (160-6589-1), L100530BSB00 (160-6589-2), L100531BSB00 (160-6589-3), L100532BSB00 (160-6589-4),
L100533BSB00 (160-6589-5), L100534BSB00 (160-6589-6), L100535BSB00 (160-6589-7) and L100536BSB00 (160-6589-8) were TestAmerica St. Louis Page 3 of 22 5/16/2014 1
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-6589-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-6589-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued) analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 05/09/2014.
No difficulties were encountered during the % solids analysis.
All quality control parameters were within the acceptance limits.
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Samples L100529BSB00 (160-6589-1), L100530BSB00 (160-6589-2), L100531BSB00 (160-6589-3), L100532BSB00 (160-6589-4),
L100533BSB00 (160-6589-5), L100534BSB00 (160-6589-6), L100535BSB00 (160-6589-7) and L100536BSB00 (160-6589-8) were analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R. The samples were dried on 05/09/2014, prepared on 05/13/2014 and analyzed on 05/13/2014 and 05/14/2014.
Radium-226 is reported in these samples at the clients request. Radium-226 is reported from the 609.31 keV line of Bismuth-214.
Because the samples have not had a 21-day ingrowth, the activity for Radium-226 is an estimated value and may be biased low. This bias is caused by the disruption of secular equilibrium between Radium-226 and Bismuth-214 by the loss of Radon-222 during sample preparation (160-6589-1 DU), (LCS 160-121740/2-A), (MB 160-121740/1-A), L100529BSB00 (160-6589-1), L100530BSB00 (160-6589-2), L100531BSB00 (160-6589-3), L100532BSB00 (160-6589-4), L100533BSB00 (160-6589-5), L100534BSB00 (160-6589-6),
L100535BSB00 (160-6589-7), L100536BSB00 (160-6589-8)
No other difficulties were encountered during the Gamma spec analysis.
All other quality control parameters were within the acceptance limits.
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Procedure HDP-PR-QA-006, Chain of Custody Page 1 of 1 Hematite Decommissioning Project !Revision: 3 I
I Westinghouse Non-Proprietary Class 3 rvKNI nDr-rK-QA-000-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and. send the completed CoC to HDP.
Chain ofCutody ID No. I F-050614-01 Pae:e Project Name:
Westinghouse Electric Company Contact Person:
Clark Evers Phone Number:
314-810-3336 Sampler Name Scott Jenkins U1 Requested Antlljrsis I
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1-------------~--------,e-_-.--~---i i 9H ~, r L100529BSBOO 5/6/2014 10:30 s G j"~{ j I,~
Ll 00530BSBOO 5/6/2014 10:35 s G 1:,'~@ '**"'
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Ll00531BSBOO 5/6/2014 10:40 s GI' :&'.']
)C L100532BSBOO 5/6/2014 10:45 s G L~
i, :x Ll00533BSBOO 5/6/2014 10:50 s G F*:x:4 X
L l 00534BSBOO 5/6/2014 10:55 s G L_]{:'f;
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Ll00535BSBOO 5/6/2014 11:00 s G [:,X /
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Laboratory Name:
Laboratory Address:
13715 Rider Trail North
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C *.s Phone No.
C 314-298-8566 0 u
'Ii Laboratory Contact Person:
~ Joe Walker Phone No.
708-870-8453 Turn Around Time Rush (7 days)
Remarks l
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Ll 00536BSBOO 5/6/2014 11:05 s 1 T<A,".-.~
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Company Name:
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Received by:
Company Name:
Relinquished by:
Company Name:
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Date/rime~
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e otal CoolerTemperature:
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7 Cooler ID: Shipper and Number:
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Verified By: C.. v-r-4*5 L<): \\ d.J...r c::
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Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-6589-1 Login Number: 6589 Question Answer Comment Creator: Clarke, Jill C List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
False Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
Thermal preservation not required.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Metals Qualifier Description J
Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier Rad Qualifier Description U
Result is less than the sample detection limit.
Qualifier F
Duplicate RPD exceeds the control limit Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL DOE GA-01-R Cesium-137 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 22 5/16/2014 1
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Sample Summary TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-6589-1 L100529BSB00 Solid 05/06/14 10:30 05/08/14 11:30 160-6589-2 L100530BSB00 Solid 05/06/14 10:35 05/08/14 11:30 160-6589-3 L100531BSB00 Solid 05/06/14 10:40 05/08/14 11:30 160-6589-4 L100532BSB00 Solid 05/06/14 10:45 05/08/14 11:30 160-6589-5 L100533BSB00 Solid 05/06/14 10:50 05/08/14 11:30 160-6589-6 L100534BSB00 Solid 05/06/14 10:55 05/08/14 11:30 160-6589-7 L100535BSB00 Solid 05/06/14 11:00 05/08/14 11:30 160-6589-8 L100536BSB00 Solid 05/06/14 11:05 05/08/14 11:30 TestAmerica St. Louis Page 9 of 22 5/16/2014 1
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Client Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-1 Client Sample ID: L100529BSB00 Matrix: Solid Date Collected: 05/06/14 10:30 Percent Solids: 79.8 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000069 0.000021 mg/Kg
05/12/14 13:53 05/14/14 18:48 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0799 U
(2+/-)
0.0706 (2+/-)
1 05/14/14 18:48 05/12/14 13:53 pCi/g 0.236 1.38 RL MDC 0.0639 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 05/12/14 13:53 05/14/14 18:48 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 91 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.25 (2+/-)
0.213 (2+/-)
1 05/14/14 12:15 05/13/14 09:49 pCi/g 0.118 RL MDC 0.171 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.102 0.0603 0.0603 U
-0.00763 Americium 241 pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.432 0.487 0.460 1.56 Bismuth 212 pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.0825 0.139 0.107 0.859 Bismuth 214 pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.0801 0.171 0.0857 1.15 Lead 212 pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.0853 0.144 0.0993 1.01 Lead 214 pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.363 2.64 1.34 22.2 Potassium 40 pCi/g 05/13/14 09:49 05/14/14 12:15 1
1.37 0.839 0.835 U
-0.702 Protactinium 231 pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.0825 1.00 0.139 0.107 0.859 Radium 226 pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.850 1.00 0.350 0.331 1.08 Thorium 234 pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.265 0.161 0.160 U
0.113 Uranium 235 pCi/g 05/13/14 09:49 05/14/14 12:15 1
5.94 3.44 3.44 U
1.63 Protactinium 234m pCi/g 05/13/14 09:49 05/14/14 12:15 1
0.118 0.213 0.171 1.25 Thorium 232 Other Detected Radionuclide None pCi/g 05/13/14 09:49 05/14/14 12:15 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-2 Client Sample ID: L100530BSB00 Matrix: Solid Date Collected: 05/06/14 10:35 Percent Solids: 82.8 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000020 mg/Kg
05/12/14 13:53 05/14/14 18:52 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0741 U
(2+/-)
0.0873 (2+/-)
1 05/14/14 18:52 05/12/14 13:53 pCi/g 0.223 1.30 RL MDC 0.0811 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 05/12/14 13:53 05/14/14 18:52 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 93 TestAmerica St. Louis Page 10 of 22 5/16/2014 1
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Client Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-2 Client Sample ID: L100530BSB00 Matrix: Solid Date Collected: 05/06/14 10:35 Date Received: 05/08/14 11:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.21 (2+/-)
0.172 (2+/-)
1 05/13/14 21:24 05/13/14 09:49 pCi/g 0.0940 RL MDC 0.119 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.102 0.0612 0.0612 U
-0.0192 Americium 241 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.256 0.359 0.325 1.49 Bismuth 212 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0660 0.120 0.0915 0.753 Bismuth 214 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0465 0.175 0.0694 1.24 Lead 212 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0621 0.112 0.0766 0.787 Lead 214 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.260 2.01 0.993 17.1 Potassium 40 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.928 0.244 0.240 U
0.396 Protactinium 231 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0660 1.00 0.120 0.0915 0.753 Radium 226 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.805 1.00 0.526 0.510 1.25 Thorium 234 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.222 0.133 0.132 U
0.0880 Uranium 235 pCi/g 05/13/14 09:49 05/13/14 21:24 1
4.88 2.79 2.79 U
0.415 Protactinium 234m pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0940 0.172 0.119 1.21 Thorium 232 Other Detected Radionuclide None pCi/g 05/13/14 09:49 05/13/14 21:24 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-3 Client Sample ID: L100531BSB00 Matrix: Solid Date Collected: 05/06/14 10:40 Percent Solids: 82.7 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000063 0.000019 mg/Kg
05/12/14 13:53 05/14/14 18:56 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.114 U
(2+/-)
0.0144 (2+/-)
1 05/14/14 18:56 05/12/14 13:53 pCi/g 0.216 1.26 RL MDC 0.00882 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 05/12/14 13:53 05/14/14 18:56 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 96 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.14 (2+/-)
0.180 (2+/-)
1 05/13/14 21:25 05/13/14 09:49 pCi/g 0.134 RL MDC 0.137 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.112 0.0669 0.0669 U
-0.0199 Americium 241 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.479 0.587 0.567 1.46 Bismuth 212 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.0743 0.129 0.100 0.776 Bismuth 214 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.0828 0.157 0.0820 1.04 Lead 212 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.0699 0.123 0.0889 0.813 Lead 214 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.403 2.58 1.31 21.7 Potassium 40 pCi/g 05/13/14 09:49 05/13/14 21:25 1
1.30 0.267 0.260 U
0.570 Protactinium 231 TestAmerica St. Louis Page 11 of 22 5/16/2014 1
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Client Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-3 Client Sample ID: L100531BSB00 Matrix: Solid Date Collected: 05/06/14 10:40 Date Received: 05/08/14 11:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Radium 226 0.776 (2+/-)
0.129 (2+/-)
1 05/13/14 21:25 05/13/14 09:49 pCi/g 0.0743 1.00 RL MDC 0.100 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.905 1.00 0.335 0.317 1.04 Thorium 234 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.257 0.166 0.165 U
0.211 Uranium 235 pCi/g 05/13/14 09:49 05/13/14 21:25 1
5.98 5.36 5.36 U
-1.99 Protactinium 234m pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.134 0.180 0.137 1.14 Thorium 232 Other Detected Radionuclide None pCi/g 05/13/14 09:49 05/13/14 21:25 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-4 Client Sample ID: L100532BSB00 Matrix: Solid Date Collected: 05/06/14 10:45 Percent Solids: 80.0 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg
05/12/14 13:53 05/14/14 19:00 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.133 U
(2+/-)
0.0753 (2+/-)
1 05/14/14 19:00 05/12/14 13:53 pCi/g 0.225 1.32 RL MDC 0.0702 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 05/12/14 13:53 05/14/14 19:00 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 95 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.09 (2+/-)
0.185 (2+/-)
1 05/13/14 21:23 05/13/14 09:49 pCi/g 0.123 RL MDC 0.148 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.104 0.0624 0.0624 U
-0.0216 Americium 241 pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.342 0.445 0.415 1.56 Bismuth 212 pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.0669 0.122 0.0947 0.740 Bismuth 214 pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.0607 0.166 0.0773 1.13 Lead 212 pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.0705 0.131 0.0940 0.874 Lead 214 pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.352 2.40 1.28 19.9 Potassium 40 pCi/g 05/13/14 09:49 05/13/14 21:23 1
1.21 0.272 0.267 U
0.479 Protactinium 231 pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.0669 1.00 0.122 0.0947 0.740 Radium 226 pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.774 1.00 0.519 0.501 1.32 Thorium 234 pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.244 0.145 0.143 U
0.202 Uranium 235 pCi/g 05/13/14 09:49 05/13/14 21:23 1
5.63 3.36 3.35 U
2.08 Protactinium 234m pCi/g 05/13/14 09:49 05/13/14 21:23 1
0.123 0.185 0.148 1.09 Thorium 232 TestAmerica St. Louis Page 12 of 22 5/16/2014 1
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Client Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-4 Client Sample ID: L100532BSB00 Matrix: Solid Date Collected: 05/06/14 10:45 Date Received: 05/08/14 11:30 Other Detected Radionuclide None pCi/g 05/13/14 09:49 05/13/14 21:23 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-5 Client Sample ID: L100533BSB00 Matrix: Solid Date Collected: 05/06/14 10:50 Percent Solids: 80.6 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg
05/12/14 13:53 05/14/14 19:04 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0326 U
(2+/-)
0.0991 (2+/-)
1 05/14/14 19:04 05/12/14 13:53 pCi/g 0.225 1.31 RL MDC 0.0933 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 05/12/14 13:53 05/14/14 19:04 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.18 (2+/-)
0.237 (2+/-)
1 05/13/14 21:24 05/13/14 09:49 pCi/g 0.133 RL MDC 0.205 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.126 0.0623 0.0623 U
0.000 Americium 241 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.485 0.580 0.556 1.60 Bismuth 212 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0723 0.136 0.108 0.794 Bismuth 214 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0732 0.159 0.0830 1.05 Lead 212 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0865 0.129 0.0943 0.845 Lead 214 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.263 2.35 1.35 18.8 Potassium 40 pCi/g 05/13/14 09:49 05/13/14 21:24 1
1.30 0.160 0.159 U
0.211 Protactinium 231 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.0723 1.00 0.136 0.108 0.794 Radium 226 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.895 1.00 0.314 0.299 0.904 Thorium 234 pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.261 0.155 0.155 U
0.0481 Uranium 235 pCi/g 05/13/14 09:49 05/13/14 21:24 1
6.30 2.79 2.78 U
2.47 Protactinium 234m pCi/g 05/13/14 09:49 05/13/14 21:24 1
0.133 0.237 0.205 1.18 Thorium 232 Other Detected Radionuclide None pCi/g 05/13/14 09:49 05/13/14 21:24 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-6 Client Sample ID: L100534BSB00 Matrix: Solid Date Collected: 05/06/14 10:55 Percent Solids: 87.5 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 0.000033 J
0.000061 0.000018 mg/Kg
05/12/14 13:53 05/14/14 19:08 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier TestAmerica St. Louis Page 13 of 22 5/16/2014 1
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Client Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-6 Client Sample ID: L100534BSB00 Matrix: Solid Date Collected: 05/06/14 10:55 Percent Solids: 87.5 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.566 (2+/-)
0.178 (2+/-)
1 05/14/14 19:08 05/12/14 13:53 pCi/g 0.208 1.21 RL MDC 0.159 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 05/12/14 13:53 05/14/14 19:08 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.15 (2+/-)
0.172 (2+/-)
1 05/13/14 21:25 05/13/14 09:49 pCi/g 0.129 RL MDC 0.125 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.0959 0.0570 0.0570 U
-0.00840 Americium 241 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.401 0.464 0.447 1.21 Bismuth 212 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.0656 0.132 0.0963 0.875 Bismuth 214 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.0487 0.159 0.0691 1.11 Lead 212 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.0708 0.123 0.0858 0.844 Lead 214 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.305 2.32 1.14 19.8 Potassium 40 pCi/g 05/13/14 09:49 05/13/14 21:25 1
1.08 0.660 0.657 U
-0.585 Protactinium 231 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.0656 1.00 0.132 0.0963 0.875 Radium 226 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.803 1.00 0.302 0.280 1.07 Thorium 234 pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.199 0.143 0.139 0.336 Uranium 235 pCi/g 05/13/14 09:49 05/13/14 21:25 1
6.25 2.57 2.57 U
0.000 Protactinium 234m pCi/g 05/13/14 09:49 05/13/14 21:25 1
0.129 0.172 0.125 1.15 Thorium 232 Other Detected Radionuclide None pCi/g 05/13/14 09:49 05/13/14 21:25 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-7 Client Sample ID: L100535BSB00 Matrix: Solid Date Collected: 05/06/14 11:00 Percent Solids: 84.7 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
05/12/14 13:53 05/14/14 19:12 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.240 (2+/-)
0.0534 (2+/-)
1 05/14/14 19:12 05/12/14 13:53 pCi/g 0.219 1.28 RL MDC 0.0442 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 05/12/14 13:53 05/14/14 19:12 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 92 TestAmerica St. Louis Page 14 of 22 5/16/2014 1
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Client Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-7 Client Sample ID: L100535BSB00 Matrix: Solid Date Collected: 05/06/14 11:00 Date Received: 05/08/14 11:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.20 (2+/-)
0.169 (2+/-)
1 05/13/14 22:12 05/13/14 09:49 pCi/g 0.105 RL MDC 0.117 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.107 0.0639 0.0639 U
-0.0216 Americium 241 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.373 0.443 0.417 1.44 Bismuth 212 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.0693 0.127 0.0964 0.795 Bismuth 214 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.0744 0.162 0.0761 1.11 Lead 212 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.0666 0.127 0.0861 0.896 Lead 214 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.439 2.24 1.14 18.9 Potassium 40 pCi/g 05/13/14 09:49 05/13/14 22:12 1
1.10 0.214 0.209 U
0.440 Protactinium 231 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.0693 1.00 0.127 0.0964 0.795 Radium 226 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.836 1.00 0.549 0.531 1.32 Thorium 234 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.244 0.160 0.159 U
0.157 Uranium 235 pCi/g 05/13/14 09:49 05/13/14 22:12 1
4.40 2.60 2.59 U
1.71 Protactinium 234m pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.105 0.169 0.117 1.20 Thorium 232 Other Detected Radionuclide None pCi/g 05/13/14 09:49 05/13/14 22:12 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-6589-8 Client Sample ID: L100536BSB00 Matrix: Solid Date Collected: 05/06/14 11:05 Percent Solids: 71.7 Date Received: 05/08/14 11:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000077 0.000023 mg/Kg
05/12/14 13:53 05/14/14 19:15 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0760 U
(2+/-)
0.140 (2+/-)
1 05/14/14 19:15 05/12/14 13:53 pCi/g 0.264 1.54 RL MDC 0.127 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 05/12/14 13:53 05/14/14 19:15 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 91 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.39 (2+/-)
0.220 (2+/-)
1 05/13/14 22:12 05/13/14 09:49 pCi/g 0.0721 RL MDC 0.167 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.113 0.0665 0.0665 U
0.00524 Americium 241 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.524 0.581 0.560 1.49 Bismuth 212 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.0703 0.129 0.105 0.728 Bismuth 214 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.0696 0.206 0.0960 1.41 Lead 212 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.0850 0.127 0.0991 0.770 Lead 214 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.333 2.10 1.30 16.1 Potassium 40 pCi/g 05/13/14 09:49 05/13/14 22:12 1
1.25 0.347 0.340 U
0.632 Protactinium 231 TestAmerica St. Louis Page 15 of 22 5/16/2014 1
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Client Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-6589-8 Client Sample ID: L100536BSB00 Matrix: Solid Date Collected: 05/06/14 11:05 Date Received: 05/08/14 11:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Radium 226 0.728 (2+/-)
0.129 (2+/-)
1 05/13/14 22:12 05/13/14 09:49 pCi/g 0.0703 1.00 RL MDC 0.105 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.817 1.00 0.541 0.526 1.21 Thorium 234 pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.234 0.0717 0.0715 U
0.0575 Uranium 235 pCi/g 05/13/14 09:49 05/13/14 22:12 1
6.52 3.99 3.99 U
1.50 Protactinium 234m pCi/g 05/13/14 09:49 05/13/14 22:12 1
0.0721 0.220 0.167 1.39 Thorium 232 Other Detected Radionuclide None pCi/g 05/13/14 09:49 05/13/14 22:12 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
TestAmerica St. Louis Page 16 of 22 5/16/2014 1
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QC Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-121549/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 122192 Prep Batch: 121549 RL MDL Technetium 99 ND 0.000050 0.000015 mg/Kg 05/12/14 13:53 05/14/14 18:13 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-121549/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 122192 Prep Batch: 121549 Technetium 99 0.00240 0.00243 mg/Kg 101 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: Matrix Spike Lab Sample ID: 160-6590-A-21-D MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 122192 Prep Batch: 121549 Technetium 99 0.000049 J
0.00309 0.00325 mg/Kg 103 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-6590-A-21-E MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 122192 Prep Batch: 121549 Technetium 99 0.000049 J
0.00308 0.00319 mg/Kg 102 75 - 125 2
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-121549/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 122193 Prep Batch: 121549 Technetium 99 Analyte U
1 05/14/14 18:13 05/12/14 13:53 pCi/g 0.170 MDC 0.991 RL 0.0208 0.0211 (2+/-)
(2+/-)
MB 0.01035 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 05/12/14 13:53 05/14/14 18:13 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 101 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-121549/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 122193 Prep Batch: 121549 Technetium 99 Analyte 120 80 101 41.59 41.2 4.24 1.02 0.175 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 98 LCS TestAmerica St. Louis Page 17 of 22 5/16/2014 1
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QC Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: Matrix Spike Lab Sample ID: 160-6590-A-21-D MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 122193 Prep Batch: 121549 Technetium 99 Analyte 125 75 103 55.60 53.0 0.831 5.92 1.39 0.238 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 93 MS Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 160-6590-A-21-E MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 122193 Prep Batch: 121549 Technetium 99 Analyte 1
0.08 125 75 102 54.69 52.8 0.831 5.38 1.35 0.232 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 95 MSD Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-121740/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 121759 Prep Batch: 121740 Actinium 228 Analyte U
1 05/13/14 20:35 05/13/14 09:49 pCi/g 0.0379 MDC RL 0.0103 0.0103 (2+/-)
(2+/-)
MB 0.0000 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.0281 0.0157 0.0157 U
-0.002635 Americium 241 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.259 0.131 0.131 U
0.001064 Bismuth 212 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.0546 0.0218 0.0218 U
0.004223 Bismuth 214 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.0275 0.0137 0.0137 U
0.003291 Lead 212 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.0313 0.00460 0.00460 U
0.001644 Lead 214 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.236 2.69 2.69 U
-0.06725 Potassium 40 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.503 0.170 0.170 U
0.0000 Protactinium 231 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.0546 1.00 0.0218 0.0218 U
0.004223 Radium 226 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.283 1.00 0.105 0.103 U
0.1547 Thorium 234 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.0834 0.0290 0.0289 U
0.01928 Uranium 235 1
05/13/14 20:35 05/13/14 09:49 pCi/g 1.43 0.549 0.549 U
0.0000 Protactinium 234m 1
05/13/14 20:35 05/13/14 09:49 pCi/g 0.0379 0.0103 0.0103 U
0.0000 Thorium 232 Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 05/13/14 09:49 05/13/14 20:35 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected TestAmerica St. Louis Page 18 of 22 5/16/2014 1
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QC Sample Results TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-121740/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 121760 Prep Batch: 121740 Americium 241 Analyte 116 87 100 100.9 101 10.5 0.487 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 35.6 34.40 3.60 0.200 0.158 pCi/g 97 87 - 120 Cobalt 60 40.6 38.55 3.89 0.129 pCi/g 95 87 - 115 Client Sample ID: L100529BSB00 Lab Sample ID: 160-6589-1 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 121826 Prep Batch: 121740 Actinium 228 Analyte 1
0.02 1.260 1.25 0.201 0.135 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Americium 241
-0.00763 U
-0.02103 U
0.0773 0.129 pCi/g 0.1 1
Bismuth 212 1.56 1.494 0.494 0.410 pCi/g 0.07 1
Bismuth 214 0.859 0.8404 0.138 0.0791 pCi/g 0.07 1
Lead 212 1.15 1.239 0.181 0.0620 pCi/g 0.26 1
Lead 214 1.01 0.9047 0.136 0.0757 pCi/g 0.36 1
Potassium 40 22.2 19.68 2.39 0.376 pCi/g 0.50 1
Protactinium 231
-0.702 U
0.4810 U F 0.270 1.33 pCi/g 1.07 1
Radium 226 0.859 0.8404 0.138 1.00 0.0791 pCi/g 0.07 1
Thorium 234 1.08 1.500 0.757 1.00 0.960 pCi/g 0.38 1
Uranium 235 0.113 U
0.2768 0.169 0.220 pCi/g 0.50 1
Protactinium 234m 1.63 U
1.920 U
3.41 5.76 pCi/g 0.04 1
Thorium 232 1.25 1.260 0.201 0.135 pCi/g 0.02 1
TestAmerica St. Louis Page 19 of 22 5/16/2014 1
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QC Association Summary TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Metals Prep Batch: 121549 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-6589-1 L100529BSB00 Total/NA Solid None 160-6589-2 L100530BSB00 Total/NA Solid None 160-6589-3 L100531BSB00 Total/NA Solid None 160-6589-4 L100532BSB00 Total/NA Solid None 160-6589-5 L100533BSB00 Total/NA Solid None 160-6589-6 L100534BSB00 Total/NA Solid None 160-6589-7 L100535BSB00 Total/NA Solid None 160-6589-8 L100536BSB00 Total/NA Solid None 160-6590-A-21-D MS Matrix Spike Total/NA Solid None 160-6590-A-21-E MSD Matrix Spike Duplicate Total/NA Solid None LCS 160-121549/2-A Lab Control Sample Total/NA Solid None MB 160-121549/1-A Method Blank Total/NA Analysis Batch: 122192 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 121549 160-6589-1 L100529BSB00 Total/NA Solid 6020A 121549 160-6589-2 L100530BSB00 Total/NA Solid 6020A 121549 160-6589-3 L100531BSB00 Total/NA Solid 6020A 121549 160-6589-4 L100532BSB00 Total/NA Solid 6020A 121549 160-6589-5 L100533BSB00 Total/NA Solid 6020A 121549 160-6589-6 L100534BSB00 Total/NA Solid 6020A 121549 160-6589-7 L100535BSB00 Total/NA Solid 6020A 121549 160-6589-8 L100536BSB00 Total/NA Solid 6020A 121549 160-6590-A-21-D MS Matrix Spike Total/NA Solid 6020A 121549 160-6590-A-21-E MSD Matrix Spike Duplicate Total/NA Solid 6020A 121549 LCS 160-121549/2-A Lab Control Sample Total/NA Solid 6020A 121549 MB 160-121549/1-A Method Blank Total/NA General Chemistry Analysis Batch: 121151 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-6589-1 L100529BSB00 Total/NA Solid Moisture 160-6589-1 DU L100529BSB00 Total/NA Solid Moisture 160-6589-2 L100530BSB00 Total/NA Solid Moisture 160-6589-3 L100531BSB00 Total/NA Solid Moisture 160-6589-4 L100532BSB00 Total/NA Solid Moisture 160-6589-5 L100533BSB00 Total/NA Solid Moisture 160-6589-6 L100534BSB00 Total/NA Solid Moisture 160-6589-7 L100535BSB00 Total/NA Solid Moisture 160-6589-8 L100536BSB00 Total/NA Rad Leach Batch: 121301 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-6589-1 L100529BSB00 Total/NA Solid Dry and Grind 160-6589-1 DU L100529BSB00 Total/NA Solid Dry and Grind 160-6589-2 L100530BSB00 Total/NA Solid Dry and Grind 160-6589-3 L100531BSB00 Total/NA TestAmerica St. Louis Page 20 of 22 5/16/2014 1
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QC Association Summary TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Rad (Continued)
Leach Batch: 121301 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-6589-4 L100532BSB00 Total/NA Solid Dry and Grind 160-6589-5 L100533BSB00 Total/NA Solid Dry and Grind 160-6589-6 L100534BSB00 Total/NA Solid Dry and Grind 160-6589-7 L100535BSB00 Total/NA Solid Dry and Grind 160-6589-8 L100536BSB00 Total/NA Prep Batch: 121549 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-6589-1 L100529BSB00 Total/NA Solid None 160-6589-2 L100530BSB00 Total/NA Solid None 160-6589-3 L100531BSB00 Total/NA Solid None 160-6589-4 L100532BSB00 Total/NA Solid None 160-6589-5 L100533BSB00 Total/NA Solid None 160-6589-6 L100534BSB00 Total/NA Solid None 160-6589-7 L100535BSB00 Total/NA Solid None 160-6589-8 L100536BSB00 Total/NA Solid None 160-6590-A-21-D MS Matrix Spike Total/NA Solid None 160-6590-A-21-E MSD Matrix Spike Duplicate Total/NA Solid None LCS 160-121549/2-A Lab Control Sample Total/NA Solid None MB 160-121549/1-A Method Blank Total/NA Prep Batch: 121740 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 121301 160-6589-1 L100529BSB00 Total/NA Solid Fill_Geo-0 121301 160-6589-1 DU L100529BSB00 Total/NA Solid Fill_Geo-0 121301 160-6589-2 L100530BSB00 Total/NA Solid Fill_Geo-0 121301 160-6589-3 L100531BSB00 Total/NA Solid Fill_Geo-0 121301 160-6589-4 L100532BSB00 Total/NA Solid Fill_Geo-0 121301 160-6589-5 L100533BSB00 Total/NA Solid Fill_Geo-0 121301 160-6589-6 L100534BSB00 Total/NA Solid Fill_Geo-0 121301 160-6589-7 L100535BSB00 Total/NA Solid Fill_Geo-0 121301 160-6589-8 L100536BSB00 Total/NA Solid Fill_Geo-0 LCS 160-121740/2-A Lab Control Sample Total/NA Solid Fill_Geo-0 MB 160-121740/1-A Method Blank Total/NA TestAmerica St. Louis Page 21 of 22 5/16/2014 1
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Tracer/Carrier Summary TestAmerica Job ID: 160-6589-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 91 160-6589-1 Percent Yield (Acceptance Limits)
L100529BSB00 93 160-6589-2 L100530BSB00 96 160-6589-3 L100531BSB00 95 160-6589-4 L100532BSB00 94 160-6589-5 L100533BSB00 94 160-6589-6 L100534BSB00 92 160-6589-7 L100535BSB00 91 160-6589-8 L100536BSB00 93 160-6590-A-21-D MS Matrix Spike 95 160-6590-A-21-E MSD Matrix Spike Duplicate 98 LCS 160-121549/2-A Lab Control Sample 101 MB 160-121549/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 22 of 22 5/16/2014 1
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