ML18010A305
| ML18010A305 | |
| Person / Time | |
|---|---|
| Site: | 07000036 |
| Issue date: | 10/02/2013 |
| From: | Testamerica Labs, Westinghouse |
| To: | Office of Nuclear Material Safety and Safeguards |
| Shared Package | |
| ML18010A247 | List:
|
| References | |
| HEM-17-72 160-3891-1 | |
| Download: ML18010A305 (24) | |
Text
ANALYTICAL REPORT TestAmerica Laboratories, Inc.
TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-3891-1 Client Project/Site: RFP-CBA-022 (7 DAY TAT)
For:
Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:
10/2/2013 5:18:55 PM Ivan Vania, Project Manager I (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
TestAmerica Job ID: 160-3891-1 Page 2 of 24 Cover Page..............................................
1 Table of Contents.........................................
2 Case Narrative...........................................
3 Chain of Custody..........................................
5 Receipt Checklists.........................................
6 Definitions/Glossary.......................................
7 Method Summary.........................................
8 Sample Summary.........................................
9 Client Sample Results......................................
10 QC Sample Results........................................
19 QC Association Summary...................................
22 Tracer Carrier Summary....................................
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3891-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3891-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)
Report Number: 160-3891-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT The samples were received on 09/25/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.0 C.
TECHNETIUM-99 (ICPMS)
Samples L100901BES00 (160-3891-1), L100902BES00 (160-3891-2), L100903BES00 (160-3891-3), L100904BEQ00 (160-3891-4),
L100904BES00 (160-3891-5), L100905BES00 (160-3891-6), L100906BES00 (160-3891-7), L100907BES00 (160-3891-8),
L100908BUB00 (160-3891-9), L100909BUB00 (160-3891-10) and L100910BUB00 (160-3891-11) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 09/26/2013 and analyzed on 09/27/2013.
Preparation Batches 75052 & 75059, Analytical Batch 75298:
The internal standard was outside QC limits in the CCB. All analytes and tracer recoveries were within acceptable limits, showing that there was no bias. Original results will be reported. (CCB 160-75298/81)
Preparation Batch 75052 & 75059, Analytical Batch 75299:
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Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-3891-1 Project/Site: RFP-CBA-022 (7 DAY TAT)
Job ID: 160-3891-1 (Continued)
Laboratory: TestAmerica St. Louis (Continued)
The internal standard was outside QC limits in the CCB. All analytes and tracer recoveries were within acceptable limits, showing that there was no bias. Original results will be reported. (CCB 160-75299/81)
No difficulties were encountered during the Tc-99 analysis. All quality control parameters were within the acceptance limits.
PERCENT SOLIDS Samples L100901BES00 (160-3891-1), L100902BES00 (160-3891-2), L100903BES00 (160-3891-3), L100904BEQ00 (160-3891-4),
L100904BES00 (160-3891-5), L100905BES00 (160-3891-6), L100906BES00 (160-3891-7), L100907BES00 (160-3891-8),
L100908BUB00 (160-3891-9), L100909BUB00 (160-3891-10) and L100910BUB00 (160-3891-11) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 09/26/2013.
No difficulties were encountered during the % solids analysis. All quality control parameters were within the acceptance limits.
CESIUM-137 & OTHER GAMMA EMITTERS (GS)
Samples L100901BES00 (160-3891-1), L100902BES00 (160-3891-2), L100903BES00 (160-3891-3), L100904BEQ00 (160-3891-4),
L100904BES00 (160-3891-5), L100905BES00 (160-3891-6), L100906BES00 (160-3891-7), L100907BES00 (160-3891-8),
L100908BUB00 (160-3891-9), L100909BUB00 (160-3891-10) and L100910BUB00 (160-3891-11) were analyzed for Cesium-137 & Other Gamma Emitters (GS) in accordance with DOE GA-01-R. The samples were leached on 09/26/2013, prepared on 09/30/2013 and analyzed on 09/30/2013 and 10/01/2013.
Preparation Batch 75266:
The blank results for bismuth-214/radium-226 and lead-214 were above the MDC. The blank matrix is clean sodium sulfate that contains low levels of naturally occurring isotopes. The lab does not consider this a reflection of contamination. The results are reported with this narrative. (160-3891-11 DU), (LCS 160-75266/2-A), (MB 160-75266/1-A), L100901BES00 (160-3891-1), L100902BES00 (160-3891-2),
L100903BES00 (160-3891-3), L100904BEQ00 (160-3891-4), L100904BES00 (160-3891-5), L100905BES00 (160-3891-6),
L100906BES00 (160-3891-7), L100907BES00 (160-3891-8), L100908BUB00 (160-3891-9), L100909BUB00 (160-3891-10),
L100910BUB00 (160-3891-11)
The reporting limit for thorium-234 analyzed by gamma spectroscopy was not met due to the reduced sample size. There was not enough sample to fill the client requested marn soil geometry. The tuna can geometry was used instead. The data is reported with the MDC achieved. L100902BES00 (160-3891-2)
Radium 226 was detected in method blank MB 160-75266/1-A at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate (see note above).
No other difficulties were encountered during the Gamma spec analysis. All other quality control parameters were within the acceptance limits.
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10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision: 3 I
Page I ofl Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAlN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.
Chain of Cutody ID No.
F-092513-01 Pa2e 1/1 Requested Analysis Laboratorv Name:
Project Name:
I*
G' TA-MO N
Westinghouse Electric Company N
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Contact Person:
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Laboratory Address:
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Gerald Rood
'8 13715 Rider Trail North
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314-810-3382 gi
" 314-298-8566 8
Sampler Name
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Andrew Schooley G
a Joe Walker
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LI 0090 IBESOO 9/19/2013 13:20 s
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1 LI 00904BESOO 9/19/2013 14:20 s C
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L100905BESOO 9/19/2013 14:30 s C
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Relinquished bye.__:
Date/Time l~e~_by=AP
...... l Date/Time Total Cooler Temperature:
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Cooler ID: Shiooer and Number:
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Dg!Time Comments: Please re-analyze samples after 21-day ingrowth
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Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-3891-1 Login Number: 3891 Question Answer Comment Creator: Daniels, Brian J List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.
True The cooler's custody seal, if present, is intact.
N/A Sample custody seals, if present, are intact.
True The cooler or samples do not appear to have been compromised or tampered with.
False Samples were received on ice.
True Cooler Temperature is acceptable.
True Cooler Temperature is recorded.
True COC is present.
True COC is filled out in ink and legible.
True COC is filled out with all pertinent information.
True Is the Field Sampler's name present on COC?
True There are no discrepancies between the containers received and the COC.
True Samples are received within Holding Time.
True Sample containers have legible labels.
True Containers are not broken or leaking.
True Sample collection date/times are provided.
True Appropriate sample containers are used.
True Sample bottles are completely filled.
True Sample Preservation Verified.
True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
True Multiphasic samples are not present.
True Samples do not require splitting or compositing.
N/A Residual Chlorine Checked.
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Definitions/Glossary TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Qualifiers Rad Qualifier Description U
Indicates the analyte was analyzed for but not detected.
Qualifier Glossary These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation
%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)
NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
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Method Summary TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL DOE GA-01-R Cesium-137 & Other Gamma Emitters (GS)
TAL SL Protocol
References:
DOE = U.S. Department of Energy EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory
References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 8 of 24 1
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Sample Summary TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID Client Sample ID Received Collected Matrix 160-3891-1 L100901BES00 Solid 09/19/13 13:20 09/25/13 18:30 160-3891-2 L100902BES00 Solid 09/19/13 13:25 09/25/13 18:30 160-3891-3 L100903BES00 Solid 09/19/13 13:30 09/25/13 18:30 160-3891-4 L100904BEQ00 Solid 09/19/13 14:25 09/25/13 18:30 160-3891-5 L100904BES00 Solid 09/19/13 14:20 09/25/13 18:30 160-3891-6 L100905BES00 Solid 09/19/13 14:30 09/25/13 18:30 160-3891-7 L100906BES00 Solid 09/19/13 15:00 09/25/13 18:30 160-3891-8 L100907BES00 Solid 09/19/13 15:05 09/25/13 18:30 160-3891-9 L100908BUB00 Solid 09/19/13 15:55 09/25/13 18:30 160-3891-10 L100909BUB00 Solid 09/19/13 16:00 09/25/13 18:30 160-3891-11 L100910BUB00 Solid 09/23/13 15:40 09/25/13 18:30 TestAmerica St. Louis Page 9 of 24 1
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-1 Client Sample ID: L100901BES00 Matrix: Solid Date Collected: 09/19/13 13:20 Percent Solids: 86.6 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000061 0.000018 mg/Kg
09/26/13 14:54 09/27/13 20:04 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0739 U
(2+/-)
0.0500 (2+/-)
1 09/27/13 20:04 09/26/13 14:54 pCi/g 0.210 1.23 RL MDC 0.0467 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:04 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.24 (2+/-)
0.207 (2+/-)
1 09/30/13 22:07 09/30/13 10:22 pCi/g 0.101 RL MDC 0.163 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.0983 0.0580 0.0580 U
0.00520 Americium 241 pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.435 0.464 0.446 1.23 Bismuth 212 pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.0745 0.137 0.110 0.799 Bismuth 214 pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.0738 0.167 0.0845 1.12 Lead 212 pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.0785 0.135 0.0926 0.946 Lead 214 pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.179 2.36 1.35 18.8 Potassium 40 pCi/g 09/30/13 10:22 09/30/13 22:07 1
1.38 0.247 0.243 U
0.412 Protactinium 231 pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.0745 1.00 0.137 0.110 0.799 Radium 226 pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.878 1.00 0.706 0.678 1.89 Thorium 234 pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.215 0.149 0.148 U
0.191 Uranium 235 pCi/g 09/30/13 10:22 09/30/13 22:07 1
6.89 4.27 4.25 U
3.94 Protactinium 234m pCi/g 09/30/13 10:22 09/30/13 22:07 1
0.101 0.207 0.163 1.24 Thorium 232 Tl-208 0.386 0.0595 0.0717 0.0439 pCi/g 09/30/13 10:22 09/30/13 22:07 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3891-2 Client Sample ID: L100902BES00 Matrix: Solid Date Collected: 09/19/13 13:25 Percent Solids: 83.2 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
09/26/13 14:54 09/27/13 20:23 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0250 U
(2+/-)
0.0600 (2+/-)
1 09/27/13 20:23 09/26/13 14:54 pCi/g 0.221 1.29 RL MDC 0.0558 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:23 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 93 TestAmerica St. Louis Page 10 of 24 1
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-2 Client Sample ID: L100902BES00 Matrix: Solid Date Collected: 09/19/13 13:25 Date Received: 09/25/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 0.835 (2+/-)
0.309 (2+/-)
1 09/30/13 22:06 09/30/13 10:22 pCi/g 0.388 RL MDC 0.297 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 09/30/13 22:06 1
0.314 50.7 50.7 U
-0.0417 Americium 241 pCi/g 09/30/13 10:22 09/30/13 22:06 1
1.55 0.888 0.887 U
0.409 Bismuth 212 pCi/g 09/30/13 10:22 09/30/13 22:06 1
0.230 0.285 0.266 0.986 Bismuth 214 pCi/g 09/30/13 10:22 09/30/13 22:06 1
0.128 0.239 0.175 1.26 Lead 212 pCi/g 09/30/13 10:22 09/30/13 22:06 1
0.225 0.229 0.205 0.992 Lead 214 pCi/g 09/30/13 10:22 09/30/13 22:06 1
1.12 3.38 2.75 19.1 Potassium 40 pCi/g 09/30/13 10:22 09/30/13 22:06 1
3.88 0.412 0.410 U
0.429 Protactinium 231 pCi/g 09/30/13 10:22 09/30/13 22:06 1
0.230 1.00 0.285 0.266 0.986 Radium 226 pCi/g 09/30/13 10:22 09/30/13 22:06 1
2.31 1.00 0.789 0.780 U
1.12 Thorium 234 pCi/g 09/30/13 10:22 09/30/13 22:06 1
0.660 0.116 0.116 U
0.0795 Uranium 235 pCi/g 09/30/13 10:22 09/30/13 22:06 1
14.7 7.08 7.07 U
4.00 Protactinium 234m pCi/g 09/30/13 10:22 09/30/13 22:06 1
0.388 0.309 0.297 0.835 Thorium 232 Tl-208 0.435 0.110 0.119 0.0784 pCi/g 09/30/13 10:22 09/30/13 22:06 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3891-3 Client Sample ID: L100903BES00 Matrix: Solid Date Collected: 09/19/13 13:30 Percent Solids: 80.7 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
09/26/13 14:54 09/27/13 20:27 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0207 U
(2+/-)
0.0173 (2+/-)
1 09/27/13 20:27 09/26/13 14:54 pCi/g 0.220 1.29 RL MDC 0.0166 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:27 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 96 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.18 (2+/-)
0.194 (2+/-)
1 09/30/13 22:11 09/30/13 10:22 pCi/g 0.121 RL MDC 0.152 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.0909 0.0538 0.0537 U
0.0137 Americium 241 pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.410 0.446 0.427 1.25 Bismuth 212 pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.0653 0.138 0.104 0.875 Bismuth 214 pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.0560 0.162 0.0762 1.10 Lead 212 pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.0918 0.131 0.0900 0.919 Lead 214 pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.262 2.29 1.25 18.8 Potassium 40 pCi/g 09/30/13 10:22 09/30/13 22:11 1
1.28 0.789 0.785 U
-0.722 Protactinium 231 pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.0653 1.00 0.138 0.104 0.875 Radium 226 TestAmerica St. Louis Page 11 of 24 1
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-3 Client Sample ID: L100903BES00 Matrix: Solid Date Collected: 09/19/13 13:30 Date Received: 09/25/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 234 1.12 (2+/-)
0.343 (2+/-)
1 09/30/13 22:11 09/30/13 10:22 pCi/g 0.827 1.00 RL MDC 0.322 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.231 0.131 0.131 U
0.0941 Uranium 235 pCi/g 09/30/13 10:22 09/30/13 22:11 1
6.03 3.40 3.40 U
0.448 Protactinium 234m pCi/g 09/30/13 10:22 09/30/13 22:11 1
0.121 0.194 0.152 1.18 Thorium 232 Tl-208 0.334 0.0497 0.0606 0.0356 pCi/g 09/30/13 10:22 09/30/13 22:11 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3891-4 Client Sample ID: L100904BEQ00 Matrix: Solid Date Collected: 09/19/13 14:25 Percent Solids: 82.2 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg
09/26/13 14:54 09/27/13 20:31 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0159 U
(2+/-)
0.00909 (2+/-)
1 09/27/13 20:31 09/26/13 14:54 pCi/g 0.220 1.29 RL MDC 0.00846 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:31 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.18 (2+/-)
0.182 (2+/-)
1 09/30/13 22:12 09/30/13 10:22 pCi/g 0.0909 RL MDC 0.136 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.125 0.0739 0.0739 U
0.00294 Americium 241 pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.427 0.495 0.473 1.43 Bismuth 212 pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.0730 0.133 0.103 0.805 Bismuth 214 pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.0703 0.156 0.0807 1.03 Lead 212 pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.0854 0.142 0.102 0.953 Lead 214 pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.280 2.29 1.31 18.4 Potassium 40 pCi/g 09/30/13 10:22 09/30/13 22:12 1
1.24 0.295 0.285 U
0.682 Protactinium 231 pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.0730 1.00 0.133 0.103 0.805 Radium 226 pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.977 1.00 0.784 0.770 1.41 Thorium 234 pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.278 0.167 0.167 U
0.0989 Uranium 235 pCi/g 09/30/13 10:22 09/30/13 22:12 1
5.75 3.23 3.23 U
1.96 Protactinium 234m pCi/g 09/30/13 10:22 09/30/13 22:12 1
0.0909 0.182 0.136 1.18 Thorium 232 Tl-208 0.366 0.0522 0.0645 0.0380 pCi/g 09/30/13 10:22 09/30/13 22:12 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-5 Client Sample ID: L100904BES00 Matrix: Solid Date Collected: 09/19/13 14:20 Percent Solids: 82.8 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg
09/26/13 14:54 09/27/13 20:34 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.00796 U
(2+/-)
0.0350 (2+/-)
1 09/27/13 20:34 09/26/13 14:54 pCi/g 0.227 1.33 RL MDC
-0.0320 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:34 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 91 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.08 (2+/-)
0.162 (2+/-)
1 09/30/13 22:13 09/30/13 10:22 pCi/g 0.0916 RL MDC 0.118 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.108 0.0648 0.0647 U
-0.0162 Americium 241 pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.445 0.547 0.520 1.63 Bismuth 212 pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.0696 0.143 0.104 0.935 Bismuth 214 pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.0528 0.174 0.0751 1.22 Lead 212 pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.0748 0.147 0.0955 1.07 Lead 214 pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.465 2.30 1.22 19.1 Potassium 40 pCi/g 09/30/13 10:22 09/30/13 22:13 1
1.19 0.726 0.723 U
-0.621 Protactinium 231 pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.0696 1.00 0.143 0.104 0.935 Radium 226 pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.888 1.00 0.701 0.685 1.42 Thorium 234 pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.228 0.143 0.142 U
0.112 Uranium 235 pCi/g 09/30/13 10:22 09/30/13 22:13 1
5.30 14.7 14.7 U
-0.368 Protactinium 234m pCi/g 09/30/13 10:22 09/30/13 22:13 1
0.0916 0.162 0.118 1.08 Thorium 232 Tl-208 0.332 0.0509 0.0614 0.0412 pCi/g 09/30/13 10:22 09/30/13 22:13 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3891-6 Client Sample ID: L100905BES00 Matrix: Solid Date Collected: 09/19/13 14:30 Percent Solids: 81.4 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000020 mg/Kg
09/26/13 14:54 09/27/13 20:38 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0206 U
(2+/-)
0.0373 (2+/-)
1 09/27/13 20:38 09/26/13 14:54 pCi/g 0.224 1.31 RL MDC
-0.0351 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:38 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 94 TestAmerica St. Louis Page 13 of 24 1
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-6 Client Sample ID: L100905BES00 Matrix: Solid Date Collected: 09/19/13 14:30 Date Received: 09/25/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.03 (2+/-)
0.177 (2+/-)
1 09/30/13 22:14 09/30/13 10:22 pCi/g 0.128 RL MDC 0.143 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.102 0.0610 0.0610 U
-0.0118 Americium 241 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.358 0.494 0.457 1.79 Bismuth 212 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.0531 0.148 0.0957 1.08 Bismuth 214 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.0788 0.145 0.0737 0.964 Lead 212 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.0832 0.152 0.0913 1.18 Lead 214 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.442 2.29 1.15 19.4 Potassium 40 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.982 0.329 0.327 U
0.336 Protactinium 231 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.0531 1.00 0.148 0.0957 1.08 Radium 226 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.814 1.00 0.320 0.310 U
0.739 Thorium 234 pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.228 0.140 0.140 U
0.00768 Uranium 235 pCi/g 09/30/13 10:22 09/30/13 22:14 1
4.36 2.51 2.47 4.53 Protactinium 234m pCi/g 09/30/13 10:22 09/30/13 22:14 1
0.128 0.177 0.143 1.03 Thorium 232 Tl-208 0.344 0.0489 0.0606 0.0374 pCi/g 09/30/13 10:22 09/30/13 22:14 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3891-7 Client Sample ID: L100906BES00 Matrix: Solid Date Collected: 09/19/13 15:00 Percent Solids: 80.0 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000020 mg/Kg
09/26/13 14:54 09/27/13 20:42 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.144 U
(2+/-)
0.0337 (2+/-)
1 09/27/13 20:42 09/26/13 14:54 pCi/g 0.223 1.30 RL MDC 0.0297 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:42 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 96 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.04 (2+/-)
0.215 (2+/-)
1 10/01/13 01:33 09/30/13 10:22 pCi/g 0.119 RL MDC 0.187 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.113 0.0677 0.0677 U
-0.0215 Americium 241 pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.341 0.510 0.477 1.73 Bismuth 212 pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.0828 0.154 0.125 0.878 Bismuth 214 pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.0705 0.162 0.0842 1.07 Lead 212 pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.0945 0.141 0.102 0.925 Lead 214 pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.191 2.24 1.35 17.5 Potassium 40 pCi/g 09/30/13 10:22 10/01/13 01:33 1
1.37 0.275 0.270 U
0.499 Protactinium 231 pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.0828 1.00 0.154 0.125 0.878 Radium 226 TestAmerica St. Louis Page 14 of 24 1
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-7 Client Sample ID: L100906BES00 Matrix: Solid Date Collected: 09/19/13 15:00 Date Received: 09/25/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 234 0.676 U
(2+/-)
0.373 (2+/-)
1 10/01/13 01:33 09/30/13 10:22 pCi/g 1.13 1.00 RL MDC 0.367 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.278 0.164 0.164 U
0.104 Uranium 235 pCi/g 09/30/13 10:22 10/01/13 01:33 1
5.90 3.46 3.45 U
1.82 Protactinium 234m pCi/g 09/30/13 10:22 10/01/13 01:33 1
0.119 0.215 0.187 1.04 Thorium 232 Tl-208 0.383 0.0625 0.0741 0.0468 pCi/g 09/30/13 10:22 10/01/13 01:33 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3891-8 Client Sample ID: L100907BES00 Matrix: Solid Date Collected: 09/19/13 15:05 Percent Solids: 83.3 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000019 mg/Kg
09/26/13 14:54 09/27/13 20:46 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.106 U
(2+/-)
0.0417 (2+/-)
1 09/27/13 20:46 09/26/13 14:54 pCi/g 0.221 1.29 RL MDC 0.0377 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:46 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 93 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.06 (2+/-)
0.163 (2+/-)
1 10/01/13 01:34 09/30/13 10:22 pCi/g 0.121 RL MDC 0.122 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.110 0.276 0.276 U
-0.00690 Americium 241 pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.405 0.482 0.460 1.39 Bismuth 212 pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.0664 0.125 0.0942 0.793 Bismuth 214 pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.0637 0.162 0.0780 1.10 Lead 212 pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.0756 0.122 0.0785 0.893 Lead 214 pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.363 2.36 1.29 19.3 Potassium 40 pCi/g 09/30/13 10:22 10/01/13 01:34 1
1.23 0.242 0.235 U
0.533 Protactinium 231 pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.0664 1.00 0.125 0.0942 0.793 Radium 226 pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.769 1.00 0.323 0.308 0.920 Thorium 234 pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.231 0.141 0.140 U
0.132 Uranium 235 pCi/g 09/30/13 10:22 10/01/13 01:34 1
6.08 3.40 3.40 U
-0.199 Protactinium 234m pCi/g 09/30/13 10:22 10/01/13 01:34 1
0.121 0.163 0.122 1.06 Thorium 232 Tl-208 0.310 0.0474 0.0573 0.0386 pCi/g 09/30/13 10:22 10/01/13 01:34 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
TestAmerica St. Louis Page 15 of 24 1
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-9 Client Sample ID: L100908BUB00 Matrix: Solid Date Collected: 09/19/13 15:55 Percent Solids: 83.5 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000020 mg/Kg
09/26/13 14:54 09/27/13 20:50 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0179 U
(2+/-)
0.0191 (2+/-)
1 09/27/13 20:50 09/26/13 14:54 pCi/g 0.224 1.31 RL MDC
-0.0174 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:50 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 92 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.05 (2+/-)
0.175 (2+/-)
1 10/01/13 01:35 09/30/13 10:22 pCi/g 0.109 RL MDC 0.139 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.119 0.0702 0.0702 U
0.00114 Americium 241 pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.556 0.438 0.422 1.13 Bismuth 212 pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.0852 0.147 0.118 0.851 Bismuth 214 pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.0728 0.157 0.0834 1.02 Lead 212 pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.0954 0.141 0.104 0.926 Lead 214 pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.303 2.27 1.34 17.9 Potassium 40 pCi/g 09/30/13 10:22 10/01/13 01:35 1
1.30 0.222 0.217 U
0.438 Protactinium 231 pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.0852 1.00 0.147 0.118 0.851 Radium 226 pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.969 1.00 0.797 0.782 1.47 Thorium 234 pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.222 0.178 0.177 U
0.163 Uranium 235 pCi/g 09/30/13 10:22 10/01/13 01:35 1
6.49 3.58 3.58 U
-0.0649 Protactinium 234m pCi/g 09/30/13 10:22 10/01/13 01:35 1
0.109 0.175 0.139 1.05 Thorium 232 Tl-208 0.359 0.0616 0.0720 0.0485 pCi/g 09/30/13 10:22 10/01/13 01:35 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3891-10 Client Sample ID: L100909BUB00 Matrix: Solid Date Collected: 09/19/13 16:00 Percent Solids: 81.0 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg
09/26/13 14:54 09/27/13 20:54 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99
-0.0236 U
(2+/-)
0.00822 (2+/-)
1 09/27/13 20:54 09/26/13 14:54 pCi/g 0.229 1.34 RL MDC
-0.00733 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 20:54 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 93 TestAmerica St. Louis Page 16 of 24 1
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-10 Client Sample ID: L100909BUB00 Matrix: Solid Date Collected: 09/19/13 16:00 Date Received: 09/25/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.20 (2+/-)
0.203 (2+/-)
1 10/01/13 02:13 09/30/13 10:22 pCi/g 0.111 RL MDC 0.162 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.123 0.0733 0.0733 U
-0.0101 Americium 241 pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.466 0.505 0.492 1.13 Bismuth 212 pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.0854 0.172 0.133 1.04 Bismuth 214 pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.0738 0.182 0.0910 1.22 Lead 212 pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.115 0.156 0.118 0.979 Lead 214 pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.499 2.54 1.54 19.8 Potassium 40 pCi/g 09/30/13 10:22 10/01/13 02:13 1
1.53 0.932 0.928 U
-0.759 Protactinium 231 pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.0854 1.00 0.172 0.133 1.04 Radium 226 pCi/g 09/30/13 10:22 10/01/13 02:13 1
1.00 1.00 0.806 0.790 1.56 Thorium 234 pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.269 0.155 0.155 U
0.139 Uranium 235 pCi/g 09/30/13 10:22 10/01/13 02:13 1
8.19 2.34 2.32 U
2.88 Protactinium 234m pCi/g 09/30/13 10:22 10/01/13 02:13 1
0.111 0.203 0.162 1.20 Thorium 232 Tl-208 0.351 0.0516 0.0632 0.0353 pCi/g 09/30/13 10:22 10/01/13 02:13 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
Lab Sample ID: 160-3891-11 Client Sample ID: L100910BUB00 Matrix: Solid Date Collected: 09/23/13 15:40 Percent Solids: 81.8 Date Received: 09/25/13 18:30 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000070 0.000021 mg/Kg
09/26/13 14:54 09/27/13 21:05 1
Analyte Dil Fac Analyzed Prepared Unit D
Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0259 U
(2+/-)
0.0942 (2+/-)
1 09/27/13 21:05 09/26/13 14:54 pCi/g 0.240 1.40 RL MDC 0.0825 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
Re 30 - 110 Carrier 09/26/13 14:54 09/27/13 21:05 1
Dil Fac Analyzed Prepared Qualifier Limits
%Yield 88 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Analyte Actinium 228 1.06 (2+/-)
0.164 (2+/-)
1 10/01/13 02:15 09/30/13 10:22 pCi/g 0.0704 RL MDC 0.123 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.104 0.0633 0.0631 U
0.0440 Americium 241 pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.434 0.352 0.336 1.03 Bismuth 212 pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.0692 0.127 0.0935 0.823 Bismuth 214 pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.0525 0.165 0.0734 1.14 Lead 212 pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.0691 0.127 0.0776 0.964 Lead 214 pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.379 2.22 1.16 18.5 Potassium 40 pCi/g 09/30/13 10:22 10/01/13 02:15 1
1.23 0.200 0.197 U
0.339 Protactinium 231 pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.0692 1.00 0.127 0.0935 0.823 Radium 226 TestAmerica St. Louis Page 17 of 24 1
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Client Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Lab Sample ID: 160-3891-11 Client Sample ID: L100910BUB00 Matrix: Solid Date Collected: 09/23/13 15:40 Date Received: 09/25/13 18:30 Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Analyte Thorium 234 1.15 (2+/-)
0.341 (2+/-)
1 10/01/13 02:15 09/30/13 10:22 pCi/g 0.797 1.00 RL MDC 0.319 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.
Uncert.
pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.170 0.139 0.138 0.173 Uranium 235 pCi/g 09/30/13 10:22 10/01/13 02:15 1
4.39 2.38 2.38 U
0.405 Protactinium 234m pCi/g 09/30/13 10:22 10/01/13 02:15 1
0.0704 0.164 0.123 1.06 Thorium 232 Tl-208 0.367 0.0490 0.0621 0.0360 pCi/g 09/30/13 10:22 10/01/13 02:15 1
(2+/-)
(2+/-)
MDC RL Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Other Detected Radionuclides Uncert.
Uncert.
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QC Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-75052/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 75298 Prep Batch: 75052 RL MDL Technetium 99 ND 0.000049 0.000015 mg/Kg 09/26/13 14:54 09/27/13 19:44 1
MB MB Analyte Dil Fac Analyzed Prepared D
Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-75052/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 75298 Prep Batch: 75052 Technetium 99 0.00238 0.00247 mg/Kg 104 80 - 120 Analyte LCS LCS D
Unit Result Qualifier
%Rec Spike Added
%Rec.
Limits Client Sample ID: L100901BES00 Lab Sample ID: 160-3891-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 75298 Prep Batch: 75052 Technetium 99 ND 0.00290 0.00284 mg/Kg 98 75 - 125
Analyte MS MS D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Client Sample ID: L100901BES00 Lab Sample ID: 160-3891-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 75298 Prep Batch: 75052 Technetium 99 ND 0.00291 0.00284 mg/Kg 98 75 - 125 0
30
Analyte MSD MSD D
Unit Result Qualifier
%Rec Spike Added Sample Result Sample Qualifier
%Rec.
Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-75052/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 75299 Prep Batch: 75052 Technetium 99 Analyte U
1 09/27/13 19:44 09/26/13 14:54 pCi/g 0.169 MDC 0.989 RL 0.0426
-0.0430 (2+/-)
(2+/-)
MB
-0.005416 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Carrier Re 30 - 110 09/26/13 14:54 09/27/13 19:44 1
Dil Fac Prepared Analyzed Qualifier Limits
%Yield 101 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-75052/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 75299 Prep Batch: 75052 Technetium 99 Analyte 120 80 104 42.23 40.7 3.98 1.02 0.174 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 LCS Qualifier Limits
%Yield 98 LCS TestAmerica St. Louis Page 19 of 24 1
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QC Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)
Client Sample ID: L100901BES00 Lab Sample ID: 160-3891-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 75299 Prep Batch: 75052 Technetium 99 Analyte 125 75 98 48.67 49.6 0.0739 U
4.87 1.24 0.212 RL MDC (2+/-)
MS MS pCi/g Unit Result Qual
%Rec Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total Re Carrier 30 - 110 MS Qualifier Limits
%Yield 93 MS Client Sample ID: L100901BES00 Lab Sample ID: 160-3891-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 75299 Prep Batch: 75052 Technetium 99 Analyte 1
0 125 75 98 48.65 49.8 0.0739 U
5.22 1.24 0.213 RL MDC (2+/-)
MSD MSD pCi/g Unit Result Qual
%Rec Limit Added Spike Result Sample Sample Qual Limits
%Rec.
Uncert.
Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits
%Yield 93 MSD Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS)
Client Sample ID: Method Blank Lab Sample ID: MB 160-75266/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 75324 Prep Batch: 75266 Actinium 228 Analyte U
1 09/30/13 21:11 09/30/13 10:22 pCi/g 0.0952 MDC RL 0.0290 0.0289 (2+/-)
(2+/-)
MB 0.02214 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.0253 0.0141 0.0141 U
0.003101 Americium 241 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.130 0.0632 0.0630 U
0.04757 Bismuth 212 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.0392 0.0396 0.0389 0.06888 Bismuth 214 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.0434 0.332 0.332 U
-0.008303 Lead 212 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.0265 0.0242 0.0235 0.05394 Lead 214 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.512 0.0473 0.0473 U
0.0000 Potassium 40 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.391 0.219 0.219 U
0.08496 Protactinium 231 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.0392 1.00 0.0396 0.0389 0.06888 Radium 226 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.321 1.00 0.177 0.177 U
-0.01325 Thorium 234 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.0670 0.0373 0.0372 U
0.03041 Uranium 235 1
09/30/13 21:11 09/30/13 10:22 pCi/g 3.73 0.424 0.424 U
0.0000 Protactinium 234m 1
09/30/13 21:11 09/30/13 10:22 pCi/g 0.0952 0.0290 0.0289 U
0.02214 Thorium 232 Other Detected Radionuclide None MB (2+/-)
(2+/-)
MDC RL pCi/g 09/30/13 10:22 09/30/13 21:11 1
MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.
Count Uncert.
Total Radionuclides Other Detected TestAmerica St. Louis Page 20 of 24 1
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QC Sample Results TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: GA-01-R - Cesium-137 & Other Gamma Emitters (GS) (Continued)
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-75266/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 75333 Prep Batch: 75266 Americium 241 Analyte 116 87 97 94.95 97.7 9.88 0.489 RL MDC (2+/-)
LCS LCS pCi/g Unit Result Qual
%Rec Added Spike Limits
%Rec.
Uncert.
Total Cesium 137 31.6 31.42 3.29 0.200 0.128 pCi/g 99 87 - 120 Cobalt 60 24.5 23.71 2.39 0.0737 pCi/g 97 87 - 115 Client Sample ID: L100910BUB00 Lab Sample ID: 160-3891-11 DU Matrix: Solid Prep Type: Total/NA Analysis Batch: 75491 Prep Batch: 75266 Actinium 228 Analyte 1
0.18 1.122 1.06 0.194 0.143 RL MDC (2+/-)
DU DU pCi/g Unit Result Qual Limit Result Sample Sample Qual Uncert.
Total RER RER Americium 241 0.0440 U
0.04306 U
0.0690 0.114 pCi/g 0.01 1
Bismuth 212 1.03 1.655 0.590 0.477 pCi/g 0.67 1
Bismuth 214 0.823 0.9676 0.161 0.0678 pCi/g 0.50 1
Lead 212 1.14 1.098 0.169 0.0848 pCi/g 0.13 1
Lead 214 0.964 0.9808 0.146 0.100 pCi/g 0.06 1
Potassium 40 18.5 19.64 2.53 0.389 pCi/g 0.24 1
Protactinium 231 0.339 U
0.5126 U
0.261 1.38 pCi/g 0.38 1
Radium 226 0.823 0.9676 0.161 1.00 0.0678 pCi/g 0.50 1
Thorium 234 1.15 1.529 0.853 1.00 1.07 pCi/g 0.32 1
Uranium 235 0.173 0.1349 U
0.156 0.275 pCi/g 0.13 1
Protactinium 234m 0.405 U
0.8615 U
4.06 6.58 pCi/g 0.07 1
Thorium 232 1.06 1.122 0.194 0.143 pCi/g 0.18 1
TestAmerica St. Louis Page 21 of 24 1
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QC Association Summary TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Metals Prep Batch: 75052 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3891-1 L100901BES00 Total/NA Solid None 160-3891-1 MS L100901BES00 Total/NA Solid None 160-3891-1 MSD L100901BES00 Total/NA Solid None 160-3891-2 L100902BES00 Total/NA Solid None 160-3891-3 L100903BES00 Total/NA Solid None 160-3891-4 L100904BEQ00 Total/NA Solid None 160-3891-5 L100904BES00 Total/NA Solid None 160-3891-6 L100905BES00 Total/NA Solid None 160-3891-7 L100906BES00 Total/NA Solid None 160-3891-8 L100907BES00 Total/NA Solid None 160-3891-9 L100908BUB00 Total/NA Solid None 160-3891-10 L100909BUB00 Total/NA Solid None 160-3891-11 L100910BUB00 Total/NA Solid None LCS 160-75052/2-A Lab Control Sample Total/NA Solid None MB 160-75052/1-A Method Blank Total/NA Analysis Batch: 75298 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 75052 160-3891-1 L100901BES00 Total/NA Solid 6020A 75052 160-3891-1 MS L100901BES00 Total/NA Solid 6020A 75052 160-3891-1 MSD L100901BES00 Total/NA Solid 6020A 75052 160-3891-2 L100902BES00 Total/NA Solid 6020A 75052 160-3891-3 L100903BES00 Total/NA Solid 6020A 75052 160-3891-4 L100904BEQ00 Total/NA Solid 6020A 75052 160-3891-5 L100904BES00 Total/NA Solid 6020A 75052 160-3891-6 L100905BES00 Total/NA Solid 6020A 75052 160-3891-7 L100906BES00 Total/NA Solid 6020A 75052 160-3891-8 L100907BES00 Total/NA Solid 6020A 75052 160-3891-9 L100908BUB00 Total/NA Solid 6020A 75052 160-3891-10 L100909BUB00 Total/NA Solid 6020A 75052 160-3891-11 L100910BUB00 Total/NA Solid 6020A 75052 LCS 160-75052/2-A Lab Control Sample Total/NA Solid 6020A 75052 MB 160-75052/1-A Method Blank Total/NA General Chemistry Analysis Batch: 74867 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-3889-A-13 DU Duplicate Total/NA Solid Moisture 160-3891-1 L100901BES00 Total/NA Solid Moisture 160-3891-2 L100902BES00 Total/NA Solid Moisture 160-3891-3 L100903BES00 Total/NA Solid Moisture 160-3891-4 L100904BEQ00 Total/NA Solid Moisture 160-3891-5 L100904BES00 Total/NA Solid Moisture 160-3891-6 L100905BES00 Total/NA Solid Moisture 160-3891-7 L100906BES00 Total/NA Solid Moisture 160-3891-8 L100907BES00 Total/NA Solid Moisture 160-3891-9 L100908BUB00 Total/NA Solid Moisture 160-3891-10 L100909BUB00 Total/NA Solid Moisture 160-3891-11 L100910BUB00 Total/NA TestAmerica St. Louis Page 22 of 24 1
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QC Association Summary TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Rad Leach Batch: 74888 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Dry and Grind 160-3891-1 L100901BES00 Total/NA Solid Dry and Grind 160-3891-2 L100902BES00 Total/NA Solid Dry and Grind 160-3891-3 L100903BES00 Total/NA Solid Dry and Grind 160-3891-4 L100904BEQ00 Total/NA Solid Dry and Grind 160-3891-5 L100904BES00 Total/NA Solid Dry and Grind 160-3891-6 L100905BES00 Total/NA Solid Dry and Grind 160-3891-7 L100906BES00 Total/NA Solid Dry and Grind 160-3891-8 L100907BES00 Total/NA Solid Dry and Grind 160-3891-9 L100908BUB00 Total/NA Solid Dry and Grind 160-3891-10 L100909BUB00 Total/NA Solid Dry and Grind 160-3891-11 L100910BUB00 Total/NA Solid Dry and Grind 160-3891-11 DU L100910BUB00 Total/NA Prep Batch: 75052 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-3891-1 L100901BES00 Total/NA Solid None 160-3891-1 MS L100901BES00 Total/NA Solid None 160-3891-1 MSD L100901BES00 Total/NA Solid None 160-3891-2 L100902BES00 Total/NA Solid None 160-3891-3 L100903BES00 Total/NA Solid None 160-3891-4 L100904BEQ00 Total/NA Solid None 160-3891-5 L100904BES00 Total/NA Solid None 160-3891-6 L100905BES00 Total/NA Solid None 160-3891-7 L100906BES00 Total/NA Solid None 160-3891-8 L100907BES00 Total/NA Solid None 160-3891-9 L100908BUB00 Total/NA Solid None 160-3891-10 L100909BUB00 Total/NA Solid None 160-3891-11 L100910BUB00 Total/NA Solid None LCS 160-75052/2-A Lab Control Sample Total/NA Solid None MB 160-75052/1-A Method Blank Total/NA Prep Batch: 75266 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Fill_Geo-0 74888 160-3891-1 L100901BES00 Total/NA Solid Fill_Geo-0 74888 160-3891-2 L100902BES00 Total/NA Solid Fill_Geo-0 74888 160-3891-3 L100903BES00 Total/NA Solid Fill_Geo-0 74888 160-3891-4 L100904BEQ00 Total/NA Solid Fill_Geo-0 74888 160-3891-5 L100904BES00 Total/NA Solid Fill_Geo-0 74888 160-3891-6 L100905BES00 Total/NA Solid Fill_Geo-0 74888 160-3891-7 L100906BES00 Total/NA Solid Fill_Geo-0 74888 160-3891-8 L100907BES00 Total/NA Solid Fill_Geo-0 74888 160-3891-9 L100908BUB00 Total/NA Solid Fill_Geo-0 74888 160-3891-10 L100909BUB00 Total/NA Solid Fill_Geo-0 74888 160-3891-11 L100910BUB00 Total/NA Solid Fill_Geo-0 74888 160-3891-11 DU L100910BUB00 Total/NA Solid Fill_Geo-0 LCS 160-75266/2-A Lab Control Sample Total/NA Solid Fill_Geo-0 MB 160-75266/1-A Method Blank Total/NA TestAmerica St. Louis Page 23 of 24 1
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Tracer/Carrier Summary TestAmerica Job ID: 160-3891-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)
Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)
Re 94 160-3891-1 Percent Yield (Acceptance Limits)
L100901BES00 93 160-3891-1 MS L100901BES00 93 160-3891-1 MSD L100901BES00 93 160-3891-2 L100902BES00 96 160-3891-3 L100903BES00 94 160-3891-4 L100904BEQ00 91 160-3891-5 L100904BES00 94 160-3891-6 L100905BES00 96 160-3891-7 L100906BES00 93 160-3891-8 L100907BES00 92 160-3891-9 L100908BUB00 93 160-3891-10 L100909BUB00 88 160-3891-11 L100910BUB00 98 LCS 160-75052/2-A Lab Control Sample 101 MB 160-75052/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 24 of 24 1
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