ML18010A292

From kanterella
Jump to navigation Jump to search
Final Status Survey Final Report Volume 3, Chapter 6, Survey Area Release Record for Land Survey Area 10, Analytical Report: 160-4744-1
ML18010A292
Person / Time
Site: 07000036
Issue date: 12/12/2013
From: Swanson M, Vania I
TestAmerica Labs - St. Louis, Westinghouse
To:
Office of Nuclear Material Safety and Safeguards
Shared Package
ML18010A247 List: ... further results
References
HEM-17-72 160-4744-1
Download: ML18010A292 (20)
v • d • e


Text

ANALYTICAL REPORT TestAmerica Laboratories, Inc.

TestAmerica St. Louis 13715 Rider Trail North Earth City, MO 63045 Tel: (314)298-8566 TestAmerica Job ID: 160-4744-1 Client Project/Site: RFP-CBA-022 (7 DAY TAT)

For:

Westinghouse Electric Company LLC 3300 State Road P Festus, Missouri 63028 Attn: Martin Swanson Authorized for release by:

12/12/2013 3:00:06 PM Ivan Vania, Project Manager II (314)298-8566 ivan.vania@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

1 2

3 4

5 6

7 8

9 10 11 12

Table of Contents Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

TestAmerica Job ID: 160-4744-1 Page 2 of 20 Cover Page..............................................

1 Table of Contents.........................................

2 Case Narrative...........................................

3 Chain of Custody..........................................

5 Receipt Checklists.........................................

7 Definitions/Glossary.......................................

8 Method Summary.........................................

9 Sample Summary.........................................

10 Client Sample Results......................................

11 QC Sample Results........................................

16 QC Association Summary...................................

18 Tracer Carrier Summary....................................

20 1

2 3

4 5

6 7

8 9

10 11 12

Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-4744-1 Project/Site: RFP-CBA-022 (7 DAY TAT)

Job ID: 160-4744-1 Laboratory: TestAmerica St. Louis Narrative CASE NARRATIVE Client: Westinghouse Electric Company LLC Project: RFP-CBA-022 (7 DAY TAT)

Report Number: 160-4744-1 With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmericas operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %

solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the client.

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.

RECEIPT The samples were received on 12/03/2013; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 20.0 C.

TECHNETIUM-99 (ICPMS)

Samples L100701BUB00 (160-4744-1), L100702BES00 (160-4744-2), L100703BSS00 (160-4744-3), L100704BRQ00 (160-4744-4),

L100704BRS00 (160-4744-5), L100705BES00 (160-4744-6), L100706BRS00 (160-4744-7), L100707BES00 (160-4744-8),

L100708BES00 (160-4744-9), L100709BRS00 (160-4744-10), L100710BES00 (160-4744-11), L100711BRS00 (160-4744-12),

L100712BES00 (160-4744-13), L100713BRS00 (160-4744-14) and L100714BES00 (160-4744-15) were analyzed for Technetium-99 (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 12/09/2013 and analyzed on 12/11/2013.

No difficulties were encountered during the Tc-99 analysis. All quality control parameters were within the acceptance limits.

PERCENT SOLIDS Samples L100701BUB00 (160-4744-1), L100702BES00 (160-4744-2), L100703BSS00 (160-4744-3), L100704BRQ00 (160-4744-4),

TestAmerica St. Louis Page 3 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Case Narrative Client: Westinghouse Electric Company LLC TestAmerica Job ID: 160-4744-1 Project/Site: RFP-CBA-022 (7 DAY TAT)

Job ID: 160-4744-1 (Continued)

Laboratory: TestAmerica St. Louis (Continued)

L100704BRS00 (160-4744-5), L100705BES00 (160-4744-6), L100706BRS00 (160-4744-7), L100707BES00 (160-4744-8),

L100708BES00 (160-4744-9), L100709BRS00 (160-4744-10), L100710BES00 (160-4744-11), L100711BRS00 (160-4744-12),

L100712BES00 (160-4744-13), L100713BRS00 (160-4744-14) and L100714BES00 (160-4744-15) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 12/04/2013.

No difficulties were encountered during the % solids analysis. All quality control parameters were within the acceptance limits.

TestAmerica St. Louis Page 4 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Page 5 of 20 1

2 3

4 5

6 7

8 9

10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project !Revision: 3 Page 1 ofll Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.

Chain of Cutody ID No. I F-120213-01 Page 1/2 Project Name:

Westinghouse Electric Company Contact Person:

Gerald Rood Phone Number:

314-810-3_382 Sampler Name Scott Jenkins Sample ID Ll00701BUBOO Ll 00702BESOO Ll00703BSSOO Ll00704BRQOO Ll00704BRSOO Ll00705BESOO Ll 00706BRSOO Ll 00707BESOO Ll 00708BESOO L 100709BRSOO LI 0071 OBESOO Date 11/20/2013 11/26/2013 11/27/2013 11/27/2013 11/27/2013 11/26/2013 11/27/2013 11/27/2013 11/27/2013 11/26/2013 11/26/2013 Time Matrix 9:45 s

16:00 s

14:30 s

14:50 s

14:50 s

15:50 s

14:10 s 14:15 s 10:00 s

15:30 s 15:35 s

8

.D e 0....

0 s

0.

s 0

C)

C C

C C

C C

C C

C C

C X

X X

X X

X X X X

X X X X

X X

X

,x X X

X

[!;

-~

0 C) 0 f-<

Laboratory Name:

TA-MO Laboratory Address:

13715 Rider Trail North Phone No.

314-298-8566 Laboratory Contact Person:

Joe Walker Phone No.

708-870-8453

°'¥ Tum Around Time

~

Rush (7 days)

~

Remarks L<.A 10,02 E;_d...~

I I L.S_A -11) -o 7.S,,s..

1 1 J_.< A 10-()7 Svs 1 11 sA 10.,01 Ql-I I L~A

  • eJ-07 J~..$

I I A--

11

~ -

Ll00711BRSOO 11/27/2013 10:20 S

IC I' I

IXI X 1 1 L_J A

!(J_... o7 Sv.s Relinquished byt_;- ~

ComPanv Nam'k, £,(_

Received bv:

Date/Time l.2..,.1., 1..3 t CPO?'

Date/Time Date/Time Cooler Temperature:

  • \\?..," '3, D~ I Cooler ID: I Shipper and Number:

\\lo 1202-02 Total 15 AnihlPnt Date/Time Comments: Please analyze samples for Tc-99 on a 7 TAT.

('I,,4)

~Q Please analyze samples for Gamma Spec after a 21 day ingrowth Company Name.

\\ 'v -$J '\\

period.

Relinquished by:

Date/Time Date/Time

(:J-o).-0

,r:10 Company Name:

Verified By:

~~~~~~~~~~~~~~~~~~~~~~-----i;

'i

Page 6 of 20 1

2 3

4 5

6 7

8 9

10 11 12 Procedure HDP-PR-QA-006, Chain of Custody Hematite Decommissioning Project Revision: 3 I

Page 1 ofl Westinghouse Non-Proprietary Class 3 FORM HDP-PR-QA-006-1 CHAIN OF CUSTODY Instructions: Each time the container is transferred to another organization, a person from each organization should sign the CoC. The Laboratory/End User must verify that the sample is correctly identified before the sample is released for use or analysis and send the completed CoC to HDP.

Chain ofCutodv ID No.

F-120213-01 Pa!!e 2/2

' R-eouesfed.Afiaiysis O

Laboratory Name:

r-------------------t Project Name:

'i';'""'.2~

t,e' ~ <

~~

  • ** [ *{

TA-MO Westinghouse Electric Company

' 1*t 1

!i~.. '

Contact Person:

I'!

?I ':

\\tl fr:~

Laboratory Address:

Gerald Rood

.;x, '8 t*

13715 Rider Trail North

~

,µ
. liff

~

Phone Number:

~ f

~ ;'._

  • ! 1-P-h_o_n_e_N_o-.---------------1 314-810-3382

.E

.~

8 314-298-8566 Sampler Name

  • '~,t~

.g -

"* A.

  • ,\\\\ "'1 E "'L'""a-=-b-=oa.;ar-=at'-o:;;.:ry=..:C'-o-n-t-a-ct-P-e-r-s-on-:--------i Scott Jenkins S

g ' >i N C 'C\\

~ i.::J..,.o=.e...:.W.:...;a::lk.,.e"'r---------------1

'e O

  • a

~

c_;:s:-

\\.c.

Phone No.

~ $. ***

~

  • t*s t-

,,i 108-870-8453 o

  • rn.
J czi

~-

l-'-"-"'"""-~--="--------------1 G',.*. io-..

.::l ~** ro f,

1-------T_u=rn~A-ro~un=* =d_T=im=e~------1

-;;:. -~ ' g.

. S

'.-i 1..::,

_.dft Rush (7 days)

Sample ID Date Time Matrix 8 ~.~

  • '< ]

~ fo,L I'.',

Ii

-?

Remarks L100712BESOO 11/27/2013 10:25 S

C };;{

X X

1 LS A

/ l"l - t> 7 S vs L100713BRSOO 11/27/2013 10:50 S

C

'f;f;,.,.

X X

1 J

( b,.

}t\\.,07

~'1~

. L100714BESOO 11/27/2013 11:00 S

C

' 01~,i X

X 1

/

( ~ J f); (') /

_s vs

  • ~

"'-*C,

/ '1 j

Relinquished bv;..

Date/fime R~ceivecl by: /'t /J Date/fime Total Cooler Temperature:

r

~

,.; I~

cm-,*Z'.);;:.,, _f J,J.)..,,,., r, 1"i Amhie,nt 1-C-om-pan--v-N_am_!. e!...: -=-.,._..::,:::::::::

~=::t- /.l. }.,.,' ';;:V (fompany Namei

\\2' '?\\'.6 ~ Cooler ID: Shipper and Number:

U) 'l'.A' ~

h..u v-5, C:_ ('1";SSY""~d C::.

120?-/YJ Received bv:

Date/Time Relinquished b~ /l Date/Time Comments: Please analyze samples for Tc-99 on a 7 TAT.

~'~-Y1f~u~

~

~,f'.

Please analyze samples for Gamma Spec after a 21 day mgrowth

~c_o_m_p_an_v_N_arn_e_*: ------1--------1'~:..:o:S:m!::p~an~-5Y~~~~~~e=i\\~

<S-,,,e---W\\~?,'....."_~~\\V-*_* -!period.

Relinquished bv:

Date/Time Receive~/A Date/rime

'r-" '

( ~. <I J-r; verified By:

CompanvNarne:

CompanyNarne:

rf-.'tv

/

~

RJ~,.A

- -~--- -~----- ------- ------ -,1

, 111--*

( J.

Login Sample Receipt Checklist Client: Westinghouse Electric Company LLC Job Number: 160-4744-1 Login Number: 4744 Question Answer Comment Creator: Daniels, Brian J List Source: TestAmerica St. Louis List Number: 1 True Radioactivity wasn't checked or is </= background as measured by a survey meter.

True The cooler's custody seal, if present, is intact.

N/A Sample custody seals, if present, are intact.

True The cooler or samples do not appear to have been compromised or tampered with.

True Samples were received on ice.

True Cooler Temperature is acceptable.

True Cooler Temperature is recorded.

True COC is present.

True COC is filled out in ink and legible.

True COC is filled out with all pertinent information.

True Is the Field Sampler's name present on COC?

True There are no discrepancies between the containers received and the COC.

True Samples are received within Holding Time.

True Sample containers have legible labels.

True Containers are not broken or leaking.

True Sample collection date/times are provided.

True Appropriate sample containers are used.

True Sample bottles are completely filled.

True Sample Preservation Verified.

True There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs N/A Containers requiring zero headspace have no headspace or bubble is

<6mm (1/4").

True Multiphasic samples are not present.

True Samples do not require splitting or compositing.

N/A Residual Chlorine Checked.

TestAmerica St. Louis Page 7 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Definitions/Glossary TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Qualifiers Rad Qualifier Description U

Indicates the analyte was analyzed for but not detected.

Qualifier Glossary These commonly used abbreviations may or may not be present in this report.

Listed under the "D" column to designate that the result is reported on a dry weight basis Abbreviation

%R Percent Recovery CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit ML Minimum Level (Dioxin)

NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica St. Louis Page 8 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Method Summary TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method Method Description Laboratory Protocol SW846 6020A Metals (ICP/MS), Tc-99 TAL SL EPA Moisture Percent Moisture TAL SL SW846 6020A Metals (ICP/MS), Tc-99 in Activity TAL SL Protocol

References:

EPA = US Environmental Protection Agency SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory

References:

TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566 TestAmerica St. Louis Page 9 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Sample Summary TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID Client Sample ID Received Collected Matrix 160-4744-1 L100701BUB00 Solid 11/20/13 09:45 12/03/13 18:10 160-4744-2 L100702BES00 Solid 11/26/13 16:00 12/03/13 18:10 160-4744-3 L100703BSS00 Solid 11/27/13 14:30 12/03/13 18:10 160-4744-4 L100704BRQ00 Solid 11/27/13 14:50 12/03/13 18:10 160-4744-5 L100704BRS00 Solid 11/27/13 14:50 12/03/13 18:10 160-4744-6 L100705BES00 Solid 11/26/13 15:50 12/03/13 18:10 160-4744-7 L100706BRS00 Solid 11/27/13 14:10 12/03/13 18:10 160-4744-8 L100707BES00 Solid 11/27/13 14:15 12/03/13 18:10 160-4744-9 L100708BES00 Solid 11/27/13 10:00 12/03/13 18:10 160-4744-10 L100709BRS00 Solid 11/26/13 15:30 12/03/13 18:10 160-4744-11 L100710BES00 Solid 11/26/13 15:35 12/03/13 18:10 160-4744-12 L100711BRS00 Solid 11/27/13 10:20 12/03/13 18:10 160-4744-13 L100712BES00 Solid 11/27/13 10:25 12/03/13 18:10 160-4744-14 L100713BRS00 Solid 11/27/13 10:50 12/03/13 18:10 160-4744-15 L100714BES00 Solid 11/27/13 11:00 12/03/13 18:10 TestAmerica St. Louis Page 10 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Client Sample Results TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4744-1 Client Sample ID: L100701BUB00 Matrix: Solid Date Collected: 11/20/13 09:45 Percent Solids: 83.2 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg

12/09/13 10:55 12/11/13 11:55 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.0280 U

(2+/-)

0.0361 (2+/-)

1 12/11/13 11:55 12/09/13 10:55 pCi/g 0.221 1.29 RL MDC

-0.0338 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 11:55 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 94 Lab Sample ID: 160-4744-2 Client Sample ID: L100702BES00 Matrix: Solid Date Collected: 11/26/13 16:00 Percent Solids: 81.9 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg

12/09/13 10:55 12/11/13 12:07 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.0215 U

(2+/-)

0.0670 (2+/-)

1 12/11/13 12:07 12/09/13 10:55 pCi/g 0.224 1.31 RL MDC

-0.0625 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:07 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 93 Lab Sample ID: 160-4744-3 Client Sample ID: L100703BSS00 Matrix: Solid Date Collected: 11/27/13 14:30 Percent Solids: 81.4 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000068 0.000020 mg/Kg

12/09/13 10:55 12/11/13 12:11 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.193 U

(2+/-)

0.112 (2+/-)

1 12/11/13 12:11 12/09/13 10:55 pCi/g 0.232 1.36 RL MDC 0.100 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:11 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 91 TestAmerica St. Louis Page 11 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Client Sample Results TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4744-4 Client Sample ID: L100704BRQ00 Matrix: Solid Date Collected: 11/27/13 14:50 Percent Solids: 85.6 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000062 0.000019 mg/Kg

12/09/13 10:55 12/11/13 12:15 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.00597 U

(2+/-)

0.0388 (2+/-)

1 12/11/13 12:15 12/09/13 10:55 pCi/g 0.213 1.25 RL MDC

-0.0363 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:15 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 94 Lab Sample ID: 160-4744-5 Client Sample ID: L100704BRS00 Matrix: Solid Date Collected: 11/27/13 14:50 Percent Solids: 85.0 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000063 0.000019 mg/Kg

12/09/13 10:55 12/11/13 12:18 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.00664 U

(2+/-)

0.0104 (2+/-)

1 12/11/13 12:18 12/09/13 10:55 pCi/g 0.214 1.25 RL MDC

-0.00984 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:18 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 95 Lab Sample ID: 160-4744-6 Client Sample ID: L100705BES00 Matrix: Solid Date Collected: 11/26/13 15:50 Percent Solids: 80.8 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000071 0.000021 mg/Kg

12/09/13 10:55 12/11/13 12:22 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.0315 U

(2+/-)

0.0207 (2+/-)

1 12/11/13 12:22 12/09/13 10:55 pCi/g 0.245 1.43 RL MDC

-0.0179 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:22 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 87 Lab Sample ID: 160-4744-7 Client Sample ID: L100706BRS00 Matrix: Solid Date Collected: 11/27/13 14:10 Percent Solids: 83.7 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000064 0.000019 mg/Kg

12/09/13 10:55 12/11/13 12:34 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier TestAmerica St. Louis Page 12 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Client Sample Results TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4744-7 Client Sample ID: L100706BRS00 Matrix: Solid Date Collected: 11/27/13 14:10 Percent Solids: 83.7 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0983 U

(2+/-)

0.0622 (2+/-)

1 12/11/13 12:34 12/09/13 10:55 pCi/g 0.218 1.27 RL MDC 0.0581 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:34 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 95 Lab Sample ID: 160-4744-8 Client Sample ID: L100707BES00 Matrix: Solid Date Collected: 11/27/13 14:15 Percent Solids: 83.4 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000019 mg/Kg

12/09/13 10:55 12/11/13 12:38 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0398 U

(2+/-)

0.0293 (2+/-)

1 12/11/13 12:38 12/09/13 10:55 pCi/g 0.222 1.30 RL MDC 0.0267 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:38 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 92 Lab Sample ID: 160-4744-9 Client Sample ID: L100708BES00 Matrix: Solid Date Collected: 11/27/13 10:00 Percent Solids: 81.5 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000068 0.000020 mg/Kg

12/09/13 10:55 12/11/13 12:42 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.0348 U

(2+/-)

0.0582 (2+/-)

1 12/11/13 12:42 12/09/13 10:55 pCi/g 0.232 1.35 RL MDC

-0.0530 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:42 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 91 Lab Sample ID: 160-4744-10 Client Sample ID: L100709BRS00 Matrix: Solid Date Collected: 11/26/13 15:30 Percent Solids: 81.4 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg

12/09/13 10:55 12/11/13 12:46 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier TestAmerica St. Louis Page 13 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Client Sample Results TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4744-10 Client Sample ID: L100709BRS00 Matrix: Solid Date Collected: 11/26/13 15:30 Percent Solids: 81.4 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.0166 U

(2+/-)

0.0691 (2+/-)

1 12/11/13 12:46 12/09/13 10:55 pCi/g 0.224 1.31 RL MDC

-0.0650 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:46 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 94 Lab Sample ID: 160-4744-11 Client Sample ID: L100710BES00 Matrix: Solid Date Collected: 11/26/13 15:35 Percent Solids: 80.7 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg

12/09/13 10:55 12/11/13 12:49 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.0149 U

(2+/-)

0.0748 (2+/-)

1 12/11/13 12:49 12/09/13 10:55 pCi/g 0.230 1.34 RL MDC

-0.0690 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:49 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 92 Lab Sample ID: 160-4744-12 Client Sample ID: L100711BRS00 Matrix: Solid Date Collected: 11/27/13 10:20 Percent Solids: 82.3 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000065 0.000019 mg/Kg

12/09/13 10:55 12/11/13 12:53 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.0293 U

(2+/-)

0.0503 (2+/-)

1 12/11/13 12:53 12/09/13 10:55 pCi/g 0.222 1.30 RL MDC

-0.0469 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:53 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 93 Lab Sample ID: 160-4744-13 Client Sample ID: L100712BES00 Matrix: Solid Date Collected: 11/27/13 10:25 Percent Solids: 81.3 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000066 0.000020 mg/Kg

12/09/13 10:55 12/11/13 12:57 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier TestAmerica St. Louis Page 14 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Client Sample Results TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Lab Sample ID: 160-4744-13 Client Sample ID: L100712BES00 Matrix: Solid Date Collected: 11/27/13 10:25 Percent Solids: 81.3 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.0202 U

(2+/-)

0.117 (2+/-)

1 12/11/13 12:57 12/09/13 10:55 pCi/g 0.224 1.31 RL MDC

-0.110 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 12:57 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 94 Lab Sample ID: 160-4744-14 Client Sample ID: L100713BRS00 Matrix: Solid Date Collected: 11/27/13 10:50 Percent Solids: 81.0 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg

12/09/13 10:55 12/11/13 13:01 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99

-0.00737 U

(2+/-)

0.0755 (2+/-)

1 12/11/13 13:01 12/09/13 10:55 pCi/g 0.230 1.35 RL MDC

-0.0698 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 13:01 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 93 Lab Sample ID: 160-4744-15 Client Sample ID: L100714BES00 Matrix: Solid Date Collected: 11/27/13 11:00 Percent Solids: 79.9 Date Received: 12/03/13 18:10 Method: 6020A - Metals (ICP/MS), Tc-99 RL MDL Technetium 99 ND 0.000067 0.000020 mg/Kg

12/09/13 10:55 12/11/13 13:05 1

Analyte Dil Fac Analyzed Prepared Unit D

Result Qualifier Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Analyte Technetium 99 0.0213 U

(2+/-)

0.0163 (2+/-)

1 12/11/13 13:05 12/09/13 10:55 pCi/g 0.230 1.34 RL MDC 0.0151 Dil Fac Analyzed Prepared Unit Result Qualifier Count Total Uncert.

Uncert.

Re 30 - 110 Carrier 12/09/13 10:55 12/11/13 13:05 1

Dil Fac Analyzed Prepared Qualifier Limits

%Yield 93 TestAmerica St. Louis Page 15 of 20 1

2 3

4 5

6 7

8 9

10 11 12

QC Sample Results TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method: 6020A - Metals (ICP/MS), Tc-99 Client Sample ID: Method Blank Lab Sample ID: MB 160-90407/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 91401 Prep Batch: 90407 RL MDL Technetium 99 ND 0.000051 0.000015 mg/Kg 12/09/13 10:55 12/11/13 11:48 1

MB MB Analyte Dil Fac Analyzed Prepared D

Unit Result Qualifier Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-90407/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 91401 Prep Batch: 90407 Technetium 99 0.00234 0.00232 mg/Kg 99 80 - 120 Analyte LCS LCS D

Unit Result Qualifier

%Rec Spike Added

%Rec.

Limits Client Sample ID: L100701BUB00 Lab Sample ID: 160-4744-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 91401 Prep Batch: 90407 Technetium 99 ND 0.00282 0.00273 mg/Kg 97 75 - 125

Analyte MS MS D

Unit Result Qualifier

%Rec Spike Added Sample Result Sample Qualifier

%Rec.

Limits Client Sample ID: L100701BUB00 Lab Sample ID: 160-4744-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 91401 Prep Batch: 90407 Technetium 99 ND 0.00282 0.00266 mg/Kg 94 75 - 125 2

30

Analyte MSD MSD D

Unit Result Qualifier

%Rec Spike Added Sample Result Sample Qualifier

%Rec.

Limits Limit RPD RPD Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Client Sample ID: Method Blank Lab Sample ID: MB 160-90407/1-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 91402 Prep Batch: 90407 Technetium 99 Analyte U

1 12/11/13 11:48 12/09/13 10:55 pCi/g 0.176 MDC 1.03 RL 0.0504

-0.0489 (2+/-)

(2+/-)

MB

-0.02478 MB Dil Fac Prepared Analyzed Unit Result Qualifier Uncert.

Count Uncert.

Total Carrier Re 30 - 110 12/09/13 10:55 12/11/13 11:48 1

Dil Fac Prepared Analyzed Qualifier Limits

%Yield 97 MB MB Client Sample ID: Lab Control Sample Lab Sample ID: LCS 160-90407/2-A Matrix: Solid Prep Type: Total/NA Analysis Batch: 91402 Prep Batch: 90407 Technetium 99 Analyte 120 80 99 39.65 40.1 3.89 1.02 0.175 RL MDC (2+/-)

LCS LCS pCi/g Unit Result Qual

%Rec Added Spike Limits

%Rec.

Uncert.

Total Re Carrier 30 - 110 LCS Qualifier Limits

%Yield 98 LCS TestAmerica St. Louis Page 16 of 20 1

2 3

4 5

6 7

8 9

10 11 12

QC Sample Results TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method: 6020A - Metals (ICP/MS), Tc-99 in Activity (Continued)

Client Sample ID: L100701BUB00 Lab Sample ID: 160-4744-1 MS Matrix: Solid Prep Type: Total/NA Analysis Batch: 91402 Prep Batch: 90407 Technetium 99 Analyte 125 75 97 46.74 48.3

-0.0280 U

5.55 1.32 0.226 RL MDC (2+/-)

MS MS pCi/g Unit Result Qual

%Rec Added Spike Result Sample Sample Qual Limits

%Rec.

Uncert.

Total Re Carrier 30 - 110 MS Qualifier Limits

%Yield 92 MS Client Sample ID: L100701BUB00 Lab Sample ID: 160-4744-1 MSD Matrix: Solid Prep Type: Total/NA Analysis Batch: 91402 Prep Batch: 90407 Technetium 99 Analyte 1

0.12 125 75 94 45.59 48.3

-0.0280 U

4.45 1.27 0.218 RL MDC (2+/-)

MSD MSD pCi/g Unit Result Qual

%Rec Limit Added Spike Result Sample Sample Qual Limits

%Rec.

Uncert.

Total RER RER Re Carrier 30 - 110 MSD Qualifier Limits

%Yield 95 MSD TestAmerica St. Louis Page 17 of 20 1

2 3

4 5

6 7

8 9

10 11 12

QC Association Summary TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Metals Prep Batch: 90407 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-4744-1 L100701BUB00 Total/NA Solid None 160-4744-1 MS L100701BUB00 Total/NA Solid None 160-4744-1 MSD L100701BUB00 Total/NA Solid None 160-4744-2 L100702BES00 Total/NA Solid None 160-4744-3 L100703BSS00 Total/NA Solid None 160-4744-4 L100704BRQ00 Total/NA Solid None 160-4744-5 L100704BRS00 Total/NA Solid None 160-4744-6 L100705BES00 Total/NA Solid None 160-4744-7 L100706BRS00 Total/NA Solid None 160-4744-8 L100707BES00 Total/NA Solid None 160-4744-9 L100708BES00 Total/NA Solid None 160-4744-10 L100709BRS00 Total/NA Solid None 160-4744-11 L100710BES00 Total/NA Solid None 160-4744-12 L100711BRS00 Total/NA Solid None 160-4744-13 L100712BES00 Total/NA Solid None 160-4744-14 L100713BRS00 Total/NA Solid None 160-4744-15 L100714BES00 Total/NA Solid None LCS 160-90407/2-A Lab Control Sample Total/NA Solid None MB 160-90407/1-A Method Blank Total/NA Analysis Batch: 91401 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid 6020A 90407 160-4744-1 L100701BUB00 Total/NA Solid 6020A 90407 160-4744-1 MS L100701BUB00 Total/NA Solid 6020A 90407 160-4744-1 MSD L100701BUB00 Total/NA Solid 6020A 90407 160-4744-2 L100702BES00 Total/NA Solid 6020A 90407 160-4744-3 L100703BSS00 Total/NA Solid 6020A 90407 160-4744-4 L100704BRQ00 Total/NA Solid 6020A 90407 160-4744-5 L100704BRS00 Total/NA Solid 6020A 90407 160-4744-6 L100705BES00 Total/NA Solid 6020A 90407 160-4744-7 L100706BRS00 Total/NA Solid 6020A 90407 160-4744-8 L100707BES00 Total/NA Solid 6020A 90407 160-4744-9 L100708BES00 Total/NA Solid 6020A 90407 160-4744-10 L100709BRS00 Total/NA Solid 6020A 90407 160-4744-11 L100710BES00 Total/NA Solid 6020A 90407 160-4744-12 L100711BRS00 Total/NA Solid 6020A 90407 160-4744-13 L100712BES00 Total/NA Solid 6020A 90407 160-4744-14 L100713BRS00 Total/NA Solid 6020A 90407 160-4744-15 L100714BES00 Total/NA Solid 6020A 90407 LCS 160-90407/2-A Lab Control Sample Total/NA Solid 6020A 90407 MB 160-90407/1-A Method Blank Total/NA General Chemistry Analysis Batch: 89681 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-4744-1 L100701BUB00 Total/NA Solid Moisture 160-4744-1 DU L100701BUB00 Total/NA Solid Moisture 160-4744-2 L100702BES00 Total/NA Solid Moisture 160-4744-3 L100703BSS00 Total/NA TestAmerica St. Louis Page 18 of 20 1

2 3

4 5

6 7

8 9

10 11 12

QC Association Summary TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

General Chemistry (Continued)

Analysis Batch: 89681 (Continued)

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid Moisture 160-4744-4 L100704BRQ00 Total/NA Solid Moisture 160-4744-5 L100704BRS00 Total/NA Solid Moisture 160-4744-6 L100705BES00 Total/NA Solid Moisture 160-4744-7 L100706BRS00 Total/NA Solid Moisture 160-4744-8 L100707BES00 Total/NA Solid Moisture 160-4744-9 L100708BES00 Total/NA Solid Moisture 160-4744-10 L100709BRS00 Total/NA Solid Moisture 160-4744-11 L100710BES00 Total/NA Solid Moisture 160-4744-12 L100711BRS00 Total/NA Solid Moisture 160-4744-13 L100712BES00 Total/NA Solid Moisture 160-4744-14 L100713BRS00 Total/NA Solid Moisture 160-4744-15 L100714BES00 Total/NA Rad Prep Batch: 90407 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch Solid None 160-4744-1 L100701BUB00 Total/NA Solid None 160-4744-1 MS L100701BUB00 Total/NA Solid None 160-4744-1 MSD L100701BUB00 Total/NA Solid None 160-4744-2 L100702BES00 Total/NA Solid None 160-4744-3 L100703BSS00 Total/NA Solid None 160-4744-4 L100704BRQ00 Total/NA Solid None 160-4744-5 L100704BRS00 Total/NA Solid None 160-4744-6 L100705BES00 Total/NA Solid None 160-4744-7 L100706BRS00 Total/NA Solid None 160-4744-8 L100707BES00 Total/NA Solid None 160-4744-9 L100708BES00 Total/NA Solid None 160-4744-10 L100709BRS00 Total/NA Solid None 160-4744-11 L100710BES00 Total/NA Solid None 160-4744-12 L100711BRS00 Total/NA Solid None 160-4744-13 L100712BES00 Total/NA Solid None 160-4744-14 L100713BRS00 Total/NA Solid None 160-4744-15 L100714BES00 Total/NA Solid None LCS 160-90407/2-A Lab Control Sample Total/NA Solid None MB 160-90407/1-A Method Blank Total/NA TestAmerica St. Louis Page 19 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Tracer/Carrier Summary TestAmerica Job ID: 160-4744-1 Client: Westinghouse Electric Company LLC Project/Site: RFP-CBA-022 (7 DAY TAT)

Method: 6020A - Metals (ICP/MS), Tc-99 in Activity Prep Type: Total/NA Matrix: Solid Lab Sample ID Client Sample ID (30-110)

Re 94 160-4744-1 Percent Yield (Acceptance Limits)

L100701BUB00 92 160-4744-1 MS L100701BUB00 95 160-4744-1 MSD L100701BUB00 93 160-4744-2 L100702BES00 91 160-4744-3 L100703BSS00 94 160-4744-4 L100704BRQ00 95 160-4744-5 L100704BRS00 87 160-4744-6 L100705BES00 95 160-4744-7 L100706BRS00 92 160-4744-8 L100707BES00 91 160-4744-9 L100708BES00 94 160-4744-10 L100709BRS00 92 160-4744-11 L100710BES00 93 160-4744-12 L100711BRS00 94 160-4744-13 L100712BES00 93 160-4744-14 L100713BRS00 93 160-4744-15 L100714BES00 98 LCS 160-90407/2-A Lab Control Sample 97 MB 160-90407/1-A Method Blank Tracer/Carrier Legend Re = Re TestAmerica St. Louis Page 20 of 20 1

2 3

4 5

6 7

8 9

10 11 12

Retrieved from "https://kanterella.com/w/index.php?title=ML18010A292&oldid=5046653"