ML18096A908

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Test Rept A27611, Well House 5 Spill.
ML18096A908
Person / Time
Site: Salem  PSEG icon.png
Issue date: 06/12/1992
From: Fioriglio C
ANALYTIKEM, INC. (FORMERLY S-R ANALYTICAL, INC.)
To:
Shared Package
ML18096A907 List:
References
A27611, NUDOCS 9208240233
Download: ML18096A908 (28)
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,* AnalytiK.EM An American NuKEM Company TEST REPORT NO. A27611 June 12, 1992 Prepared for: PSE&G P.O. Box 236 Mail Code N34 Hancocks Bridge, NJ 08038 Attention:

Jame-s Sterner Project: #5 Well House Spill Reviewed & Approved by: Name: AnalytiKEM Inc. 28 Springdale Road Cherry Hill, NJ 08003 6091751-1122 1-800-TRY-LAB1 Fax:609/751-0824 Title: QA/QC Manager --92-0824023-3 920814 ' '\ PDR ADOCK 05000272 S PDR l

' ' I. II* III. IV. v. VI. Certification Definition of Terms Sample Designations Methodology Analytical Results Quality Control Data TABLE OF CONTENTS AnalgtiKEM F..ag_e_ 1 2 3 4 s 6 -7

'. ' . I ! I i Test R 1 eport ** A27611 Page I. Certification AnalytiKEM AnalytiKEM, Inc. Current Certifications/Regulatory Approvals Tabulated below are the current laboratory certifications that are held by each AnalytiKEM Laboratory.

Analyses performed at multiple AnalytiKEM locations will be noted in the test report. !Cherry Hill, NJ Hill, SC Analytical, Tx State Cert # State Cert # State Cert I !Arkansas

!Massachusetts NJ117 Louisiana

  • No certification numbers are issued for these states. -..*: '

r---

II. Test Report Page 2 *

  • pefinition of Terms AnalytiKEM D DI J MS/MSD NA ND NR. NTU RPD RSD u ppb ppm ug/l ug/kg ug/kg dw CCC SPCC PQL B Definition Detected; result must be greater than zero. Deionized Water Compound was detected at levels below the practical quantitation limit. The level reported is approximate.

Matrix Spike/Matrix Spike Duplicate.

Analysis not applicable to the sample matrix. Not Detected Not Requested Nephelometric Turbidity Units Relative Percent Difference Relative Standard Deviation Compound was analyzed for but not detected.

The preceding number is the practical quantitation limit for the compound.

Parts-per-billion; may be converted to ppm by dividing by 1,000. Parts-per-million; may be converted to ppb by multiplying by 1,000. Micrograms of constituent per liter of sample; equivalent to parts-per-billion.

Micrograms of constituent per kilogram of sample; equivalent to parts-per-billion.

Micrograms of constituent per kilogram of sample reported on a dry weight basis. Calibration Check Compound; used to verify the precision of a GC/MS calibration curve. System Performance Check Compound; used to verify the correct operation of a GC/MS instrument.

Practical Quantitation Limit; the minimum level at which compounds can be dependably quantitated.

Analyte detected in associated blank as well as the sample. It indicates possible/probable blank contamination.

Test Report No. A27611 Page 3 III. Sample Designations AnalytiKEM Designation A27611-l Client Designation HZS-92-05-02 Matrix Nonaqueous AnalytiKEM Date Sampled 5/26/92 Note: Samples will be held for 30 days beyond the test report date unless otherwise requested.

' '

-.r IV. Test R 4 eport Page ,_, Methodology AnalytiKEM Polychlorinated Biphenyls Method 3550, Sonication Extraction, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

Method 8080, Organochlorine Pesticides and PCBs, Test Methods for Evaluating Solid Waste Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986, with all promulgated revisions.

General Chemistry Method 1010, Flashpoint (Pensky-Martens Closed-Cup Method for Determining Ignitability).

Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986 with all promulgated revisions.

Method 9045, Soil pH. Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, 1986 with all promulgated revisions.

Section 7.3.3.2, Test Method to Determine Hydrogen Cyanide Released from Wastes (Interim Guidance for Reactive Cyanide).

Test Methods for Evaluating Solid Waste, Physical/Chemical SW846, Third Edition, USEPA, Revison 1 November 1990. Section 7.3.4.2, Test Method to Determine Hydrogen Sulfide Released from Wastes (Interim Guidance for Reactive Sulfide).

Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW846, Third Edition, USEPA, Revison 1 November 1990. '

v. Test Report No. A27611 Page 5 Analytical Results Polychlorinated Biphenyls Parameter Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 Units Method Blank 650 u 650 u. 650 u 650 u 650 u 650 u 650 u (ug/kg) Sample Designation A27611-l HZS-92-05-02 650 u 650 u 650 u 650 u 650 u 650 u 650 u (ug/kg) AnalytiKEM Note: All compounds reported at levels exceeding the PQL have been confirmed by alternate column GC. General Chemistry Parameter Reactivity-Sulfide Reactivity-Cyanide Units Parameter Flashpoint, closed cup, "F pH, units Sample Designation Method Blank 50,000 u 50,000 u (ug/kg) A27611-l HZS-92-05-02 50,000 u 50,000 u (ug/kg) Sample Designation A27611-l HZS-92-05-02

> 200 8.4 ' '

      • Test Report No. A27611 Page 6 e VI. Quality Control Data Polychlorinated*Biphenyls Nonaqueous Matrix Spike/Matrix Spike Duplicate Recovery Data PCB Sample Spiked A27600-l AnalytiKEM C12ntr12l Amount Recovery Max. Parameter Qf Spike MS. HSU Rf.ll Recovery Aroclor 1248 20 96 108 12 64-100 20 Aroclor 1248 f/J 20 64 64-100 20 Units (ug) (%) (%) (%) (%) (%) Recovery:

out of __l_ outside control limits RPO:

out of outside control limits Test Report No. A27611 Page 7 e VI. Quality Control Data (Cont'd) Polychlorinated Biphenyls Nonaqueous Surrogate Recovery Data and Retention Time Shift Sample Designation Method Blank A27600-l Spike A27600-l Spike Dup. DI Water Spike A27611-l Units Control Limits Dibutylchlorendate (2.0 ug Added) Recovery 70 58 110 84 74 (%)40-156 Retention Time Shift 0.4 1.3 1.3 0.7 0.7 (%) 0-2 AnalytiKEM 0 out of ---2.__ surrogate recoveries are outside control limits. '

l I ! I AnalytiKEM An American NuKEM Company TEST REPORT NO. A27611 June 12, 1992 Prepared for: PSE&G P.O. Box 236 Mail Code N34 Hancocks Bridge, NJ 08038 Attention:

James Sterner Project: #5 Well House Spill Reviewed & AnalytiKEM Inc. -28 Springdale Road Cherry Hill, NJ 08003 609/751-1122 1-800-TRY-LA81 Fax:609/751-0824 Approved by:

Name: Carmine Title: QA/QC Manager AnalytiKEM TABLE OF CONTENTS ' I. List of Certifications 1 II* Definition of Terms 2 III. Sample Designations 3 IV. Methodology 4 v. Laboratory Chronicle 5 VI. Extraction Log 6 VII. Outlier Summary 7 VIII. Analytical Results 8 -9 IX. Quality Control Data 10 -16 Test Report e. A27611 Page 1 I. Certification AnalytiKEM, Inc. Current Certifications/Regulatory Approvals AnalytiKEM Tabulated below are the current laboratory certifications that are held by each AnalytiKEM Laboratory.

Analyses performed at multiple AnalytiKEM locitions will be noted in the test report. Cherry Hill, NJ !Rock Hill, SC Houston Analytical, Tx State Cert I State Cert # State Cert # Arkansas

-:,': New Jersey 04012 New York 10815 IN. Carolina 258 IN. Dakota R-038 Pennsylvania 68366 s. Carolina 94004 Tennessee 02908 [Vermont *

  • No certification numbers are for these states. '

Test Repbrt No. A27611 Page 2 e II. Definition of Terms AnalytiKEM DI J MS/MSD NA ND NR RPO RSD u mg/L CCC SPCC PQL TCLP ZHE TC ug Definition Deionized Water Compound was detected at levels below the practical quantitation limit. The level reported is approximate.

Matrix Spike/Matrix Duplicate Analysis not applicable to the sample matrix. Not Detected Not Requested Relative Percent Difference Relative Standard Deviation Compound was analyzed for but not detected.

The preceding number is the practical quantitation limit for the compound.

Milligrams of constituent per liter of TCLP Leachate; equivalent to parts-per-million (ppm). Calibration Check Compound; used to verify the precision of a GC/MS calibration curve. System Performance Check Compound; used to verify the correct operation of a GC/MS instrument.

Practical Quantitation Limit; the m1n1mum level at which compounds can be dependably quantitated.

Toxic Characteristic Leachate Procedure Zero Headspace Extraction Toxic Micrograms

'

' . ' III. Test Report No. A27611 Page 3 e Sample Designations AnalytiKEM Designation A27611-l Client Designation HZS-92-05-02 Matrix Nonaqueous AnalytiKEM Date Sampled 5/26/92 Note 1: Samples will be held for 30 days beyond the test report date unless otherwise requested.

Note 2: The TCLP Herbicides analysis was subcontracted to Laboratory Resources, Incorporated.

A copy of their report is attached.

' L ' L ,/

  • l IV
  • fest Report No. A27611 ----Page 4 e e AnalytiKEM All analysis are performed in accordance with methodologies found in the following publications: Federal Register, Vol. SS, No. 126, June 29, 1990. 40 CFR, Part 216, Appendix 2, Method 1311. Test Methods for Evaluating Solid Waste, USEPA, SW-846, Second Edition, 1982. Test Methods for Evaluating Solid Waste, USEPA, SW-846, Third Edition, 1982. Methods for Chemical Analysis of Water and Wastes, EPA-600/4-79-020, USEPA, March 1983.

Test Report No. A27611 Page S e V. Laboratory Chronicle Date Sampled Receipt/Refrigeration TCLP Extractions Zero Headspace Extraction TC Extraction Sample Preparations Semi volatiles Pesticides Metals: General Mercury Analyses Volatiles Semivolatiles Pesticides Metals General Mercury Laboratory Manager Review & Approval (Signature) (Printed Name) (Date) AnalytiKEM I II 5/26/92 5/27192 6/1/92 6/1/92 6/3/92 6/3192 6/5/92 6/5/92 6/3/92 6/7/92 6/8/92 6/7/92 6/6/92 NOTE: If fractions are reextracted and reanalyzed because the initial endeavors failed to meet the required quality control criteria, the dates of reextraction and/or reanalysis will be entered in column II additionally.

VI. -Test Report No.* A27611 Page 6 Extraction Lo' Sample pesignation A27611-l A27611-l Zero Headspace Extraction. (g) 25 AnalytiKEM TCLP Extraction Fluid Extraction, (g) Volume (ml) 100 1 1 2,000 500 VII. Test Report No. A27611 Page 7 e AnalytiKEM Outlier Summary; Toxicity Characteristic Leachate Procedure (TCLP) No Compounds were reported above the Regulatory Limits for the following samples: A27611-l HZS-92-05-02 ,,J ,,

est Keport No. A27611 Page 8 . ' . VIII

  • Analytical Analyt.iKEM ICLP Organic Analyses AnalytiKEM Designation:

A27611-l Client Designation:

HZS-92-05-02 EPA Method Sample Regulatory Number Parameter Blank Resul*t Level volatile Organics 0043 Vinyl Chloride 0.011 u 0.055 u 0.2 0029 1,1-0ichloroethylene 0.010 u 0.052 u 0.7 0022 Chloroform 0.010 u 0.051 u 6.0 0028 1,2-0ichloroethane 0.010 u 0.051 u 0.5 0035 2-Butanone (MEK) 0.015 u 0.075 u 200 D019 Carbon Tetrachloride 0.0086 u 0.043 u 0.5 D040 Trichloroethylene 0.0088 u 0.044 u 0.5 0018 Benzene 0.0094 u 0.047 u 0.5 0039 Tetrachloroethylene 0.010 u 0.050 u 0.7 0021 Chlorobenzene 0.010 u 0.051 u 100 0038 Pyridine 0.029 u 0.029 u 5.0 {I 0027 1,4-0ichlorobenzene 0.013 u 0.013 u 7.5 t 0023 o-Cresol 0.010 u 0.010 u 200 I 0024,0025 m,p-Cresol 0.011 u 0.011 u 200 *} 0034 Hexachloroethane 0.012 u 0.012 u 3.0 0036 Nitrobenzene 0.010 u 0.010 u 2.0 0033 Hexachlorobutadiene O.OOB8 u 0.0088 u 0.5 0042 2,4,6-Trichlorophenol 0.0095 u 0.0095 u 2.0 0041 2,4,5-Trichlorophenol 0.043 u 0.043 u 400 0030 2,4-0initrotoluene 0.012 u 0.012 u 0.13 0032 Hexachlorobenzene 0.028 u 0.028 u 0.13 0037 Pentachlorophenol 0.078 u 0.078 u 100 Pesticides 0020 Chlordane 0.0055 u 0.0055 u 0.03 0012 Endrin 0.0031 u 0. 0031 . u 0.02 0031 Heptachlor

o. 0011 u 0. 0011 u 0.008 0031 Heptachlor Epoxide 0. 0011 u 0. 0011 u 0.008 0013 Lindane 0.042 u 0.042 u 0.4 0014 Methoxychlor 0.22 u 0.22 u 10 0015 Toxaphene 0.20 u 0.20 u 0.5 Units (mg/l) (mg/l) (mg/l) tf Note: All results are corrected for spike recoveries. . ' '

.. VIII. est eport No. A27611 Page 9 Analytical (Cont'd) TCLP Metals AnalytiKEM Designation:

A27611-l Client Designation:

HZS-92-05-02 EPA Number Parameter 0004 Arsenic 0005 Barium 0006 Cadmium 0007 Chromium 0008 Lead 0009 Mercury 0010 Selenium DOU Silver Units Method Blank 0.48 u 2.1 u 0.097 u 0.46 u 0.50 u 0.018 u 0.47 u 0.40 u (mg/l) Note: Ali results are corrected for spike recoveries.

AnalytiKEM Sample Regulatory Result Level 0.48 u 5.0 0.44 J 100 0.097 u 1.0 0.46 u 5.0 0.50 u 5.0 0.0061 J 0.2 0.47 u 1.0 0.40 u 5.0 (mg/ 1) (mg/l)

... ' . IX. Test Report No. A27611 Page 10 Quality Control Data TCLP Procedure Volatile Organics Matrix Spike Recovery Data Parameter Vinyl Chloride 1,1-Dichloroethene Chloroform 1,2-Dichloroethane 2-Butanone (MEK) Carbon Tetrachloride Trichloroethene Benzene Tetrachloroethene Chlorobeazene Units Sample Amount of Spike 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 (ug) Spiked A27590-l Recovery MS. 91 96 99 98 67 116 113 106 100 99 (%) AnalytiKEM .1 IX. Test Report No. Page 11 Quality Conti. TCLP Procedure A27611 Volatile Organics Surrogate Recovery Data Sample Designation Method Blank A27590-l Spike A27611-l Units l,2-Dichloroethane-d 4 (0.25 ug Added) 102 100 99 (%) Analyt.iHEM Surrogate Recovery Toluene-d 8 (0.25 ug Added) 97 98 99 (%) 4-Bromofluorobenzene (0.25 ug Added) 102 99 100 (%)

Test Report No. A27611 Page 12 IX. Quality Control Data (Cont'd) ICLP Procedure

-Semivolatile Organics Matrix Spike Recovery Data Parameter Pyridine 1,4-Dichlorobenzene o-Cresol m,p-Cresol Hexachloroethane Nitrobenzene Hexachlorobutadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol . 2,4-Dinitrotoluene Hexachlorobenzene Pentachlorophenol Units Sample Spiked A27600-l Amount of Spike 100 100 200 400 100 100 100 200 200 100 100 200 (ug) Recovery HS. 34 76 98 88 82 97 113 105 115 81 36 64 (%) AnalytiKEM r* .I IX. Test Report No. A27611 Page 13 Quality Control Data (Cont'd) TCLP Procedure Semivolatile Organics Surrogate Recovery Data Sample Designation Method Blank A27600-l Spike A27611-l Units Sample Designation Method Blank A27600-l Spike A27611-l Units 2-Fluorophenol (200 ug Added) 44 82 40 (%) Nitrobenzene-d 5 ClOO ug Added) 70 85 58 (%)

  • Surrogate Recovery Phenol-d 5 (200 ug Added) 21 72 21 (%) Surrogate Recovery 2-Fluorobiphenyl ClOO ug Added) 68 76 48 (%) AnalytiKEM 2,4,6-Tribromophenol (200 ug Added) 92 116 88 (%) Terphenyl-d 14 (lQQ ug Added) 115 117 96 (%) I -.I i1

IX. Test Report No. A27611 Page 14 Quality Control Data (Cont'd) TCLP Procedure Pesticides Agueous Matrix Spike Recovery Data Sample Spiked A27301-l Parameter gamma-BHC (Lindane)

Heptachlor Heptachlor Epoxide Endrin Methoxychlor alpha-Chlordane alpha-Chlordane

-gamma-Chlordane Toxaphene Toxaphene*

-Units Amount of Spike 0.2 0.2 0.2 0.5 2.0 0.2 0.2 0.2 4.0 4.0 (ug) Recovery __ML9673706545 41 77 68 25 99 (%) AnalytiKEM

-Spike performed on DI Water. This recovery was used to spike correct results. I i1

. (. Test Report No. A27611 Page 15 IX. Quality Control Data (Cont'd) TCLP Procedure Pesticides Aqueous Surrogate Recovery Data Sample Designation Method Blank A27301-l Spike (Pest.) DI Water Spike (Pest.) A27301-l Spike (Tox.) DI Water Spike (Tox.) A27611-l Units Surrogate Recovery Dibutylchlorendate ( 1. 0 ug Added) 80 79 158 95 85 137 (%) AnalgtiKEM I 1. '

.. ' ll Test Report No. A27611 Page 16 AnalytiKEM IX. Quality Control Data (Cont'd) TCLP Procedure Metals Matrix Spike Recovery Pata Sample Spiked A27622-5 Ainount Recovery Parameter of Spike _M.S__ Arsenic 100 112 Arsenic 100 104 Barium -300 97 Cadmium 300 103 Chromium 300 122 300 108 Lead 300 101 Mercury 20 109 Selenium 300 106 Silver 300 99 Units (ug) (%) Spike performed on DI water. This recovery was used to spike correct results.

28 Springdale Road Cherry Hill. New Jersey 08003 (609) 751-1.122

  • (215) 923-2068 Fax: (609) 751-0824 Client PSE{b SAMPLE DESIGNATION DATE J.-0 2-1,-/-q:J 1. Field Measurements:

Data Sheets: Y N Filtered:

Y Not Required Relinquished By: Chain-of-Custody

-1,-i-i.-7,--!

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MATRIX $:§G I! /i ;J ;J Ii &el

-.;, .DitZ: '-,. *.i 454 South Anderson Road BTC 532 Rock Hill, South Carolina 29730 (803) 329-9690 Fax: (803) 329-9689 Analytit<EM Contact J..n. '1 C;c ef?<J I I PARAMETERS TC.L P, 1 f:JB, .P\,

t?-.1. s... * ,,,,. .,. c .. ,.._ ... '° . . \J Ill. Special Instructions:

_______________________________

_ (Detection Limits, Data Package, etc.) Time/Date:

Time/Date:

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