ML18096B006

Test Rept A28173 for Project, Fuel Oil Spills,Crane & Filter.

ML18096B006
Person / Time
Site:	Salem
Issue date:	09/03/1992
From:	Fioriglio C ANALYTIKEM, INC. (FORMERLY S-R ANALYTICAL, INC.)
To:
Shared Package
ML18096B004	List: ML18096B003 ML18096B005 ML18096B006 ML18096B008
References
A28173, A28173-01, A28173-1, NUDOCS 9210020139
Download: ML18096B006 (21)

Text

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AnalytiKEM An American NuKEM Company AnalytiKEM Inc.

28 Springdale Road Cherry Hill, NJ El8003 6091751-1122 1-800-TRY-LAB1 Fax: 6091751-0824 TEST REPORT NO. A28173 September 3, 1992 Prepared for:

PSE&G P.O. Boz 236 Hail Code N34 Hancocks Bridge, NJ 08038 Attention: James Sterner Project: Fuel Oil Spills, Crane & Filter llevieved &

Approved b / ~

~ * ~

Name: Ca= .~glfo

Title:

QA/QC Manager

TABLE OF CONTENTS 4na/ytihE"r1 Page I. List of Certifications 1 II. Definition of Terms 2 III. Sample Designations 3 IV. Methodology 4

v. Laboratory Chronicle 5 VI. Extraction Log 6 VII. Outlier Summary 7 VIII. Analytical Results 8 - 11 IX. Quality Control Data 12 - 18

~ I i Test Report N~ A28173 Page 1 I. Certification 4.na/ytil'\E\.1 AnalytiKEM, Inc.

Current Certifications/Regulatory Approvals Tabulated below are the current laboratory certifications that are held by each AnalytiKEM Laboratory. Analyses performed at multiple AnalytiKEM locations will be noted in the test report.

Cherry Hill, NJ Rock Hill, SC !Houston Analytical, TX State Cert # State Cert # State Cert #

!Arkansas

• s. Carolina 46067 N. Dakota R-006 tonnecticut PH-0715 IN. Carolina 316  !Oklahoma 8403 Florida 880985G INew Jersey 79795  !Texas Water Commission Massachusetts NJ117  !Louisiana 92-07

!New Jersey 04012 s. Carolina 82011 INew York 10815 IN. Carolina 367 IN. Carolina 258  !Wisconsin 998010530 IN. Dakota R-038  !New Jersey 82869 Pennsylvania 68366

s. Carolina 94004 IT'ennessee 02908

~ermont Oklahoma 9107

• No certification numbers are issued for these states.

Test Report ~o. A2 8173

) Page 2 ~

.I

' II. Definition of Terms

-- 4nalytikEH Definition DI Deionized Water J Compound was detected at levels below the practical quantitation limit. The level reported is approximate.

MS/MSD Matrix Spike/Matrix Spike Duplicate NA Analysis not applicable to the sample matrix.

ND Not Detected NR Not Requested RPO Relative Percent Difference RSD Relative Standard Deviation u Compound was analyzed for but not detected. The preceding number is the practical quantitation limit for the compound.

mg/L Milligrams of constituent per liter of TCLP Leachate; equivalent to parts-per-million (ppm).

CCC Calibration Check Compound; used to verify the precision of a GC/MS calibration curve.

SPCC System Performance Check Compound; used to verify the correct operation of a GC/MS instrument.

PQL Practical Quantitation Limit; the minimum level at which compounds can be dependably quantitated.

TCLP Toxic Characteristic Leachate Procedure ZHE Zero Headspace Extraction TC Toxic Characteristic ug Micrograms

Test Report No. A28l?J Page 3 ~

• III. Sample Designations AnalytiKEM 4nalytik.E'H Client Date Designation Designation Matrix Sampled A28173-l HZS-92-08-01 Nonaqueous 8/11/9~

A28173-2 HZS-92-08-02 Nonaqueous 8/11/92 Note: Samples will be held for 30 days beyond the test report date unless otherwise requested.

Test Report ~o. A2 3173 Page 4 -

... IV. Methodology 4.na/yt:il(EH All analysis are performed in accordance with methodologies found in the following publications:

Federal Register, Vol. 55, No. 126, June 29, 1990.

40 CFR, Part 216, Appendix 2, Method 1311.

Test Methods for Evaluating Solid Waste, USEPA, SW-846, Second Edition, 1982.

Test Methods for Evaluating Solid Waste, USEPA, SW-846, Third Edition, 1982.

Methods for Chemical Analysis of Water and Wastes, EPA-600/4-79-020, USEPA, March 1983.

e Test Report ~o. A2BLiJ Page S V. Laboratory Chronicle J\na/ytil\El1 I II Date Sampled 8/11/92 Receipt/Refrigeration 8/12/92 TCLP Extractions Zero Headspace Extraction 8/13/92 TC Extraction 8/13/92 Sample Preparations Semi volatiles 8/21/92 Pesticides 8/21/92 Metals:

General 8/18/92 Mercury 8/21/92 Analyses Volatiles 8/19 & 8/20/92 Semivolatiles 8/28/92 Pesticides 8/23/92 Metals General 8/20/92 Mercury 8/21/92 Laboratory Manager (Signature)

Review & Approval (Printed Name)

(Date)

NOTE: If fractions are reextracted and reanalyzed because the initial endeavors failed to meet the required quality control criteria, the dates of reextraction and/or reanalysis will be entered in column II additionally.

Test Report

• A28173 Page 6 VI. Extraction Log Sample J\na/ytil(E'H Zero Headspace TGLP Extraction Fluid Designation Extraction, (g) Extraction, (g) ~ Volume (ml)

A28173-l 25 A28173- l 1 500 100 1 2,000 A28173-2 25 A28173-2 1 500 100 1 2,000

• Test Report No. A2Sl?J Page 7 -

Ana/y£ik. E 'H VII. OUtlier SYmmary: Toxicity Characteristic Leachate Procedure CTCLP)

No Compounds were reported above the Regulatory Limits for the following samples:

A28173-l HZS-92-08-01 A28173-2 HZS-92-08-02

Test Report No. A28173

• VIII.

Page 8 Analytical Results e

4.nd/yr-ik. E'H TCLP Organic Analyses AnalytiKEH Desig~ation: A28173-l Client Designation: HZS-92-08-01 EPA Method Sample Regulatory Number Parameter Blank Result Level Volatile Organics 0043 Vinyl Chloride 0.011 u 0.063 u 0.2 0029 1,1-0ichloroethylene 0.010 u 0.051 u 0.7 0022 Chloroform 0.010 u 0.051 u 6.0 0028 1,2-0ichloroethane 0.010 u '0.053 u 0.5 0035 2-Butanone (MEI<) 0.022 u 0.046 u 200 0019 Carbon Tetrachloride 0.010 u 0.052 u 0.5 0040 Trichloroethylene 0.010 u 0.051 u 0.5 0018 Benzene 0.010 u 0.052 u 0.5 0039 Tetrachloroethylene 0.010 u 0.051 u 0.7 0021 Chlorobenzene 0.011 u 0.051 u 100 Semivolatile Organics 0038 Pyridine 0.071 u 0.071 u 5.0 0027 1,4-0ichlorobenzene 0.016 u 0.016 u 7.5 0023 o-Cresol 0.019 u 0.019 u 200 0024,0025 m,p-Cresol 0.019 u 0.019 u 200 0034 Hexachloroethane 0.023 u 0.023 u 3.0 0036 Nitrobenzene 0.013 u 0.013 u 2.0 0033 Hexachlorobutadiene 0.013 u 0.013 u 0.5 0042 2,4,6-Trichlorophenol 0.018 u 0.018 u 2.0 0041 2,4,5-Trichlorophenol 0.081 u 0.081 u 400 0030 2,4-Dinitrotoluene 0.030 u 0.030 u 0.13 0032 Hexachlorobenzene 0.025 u 0.025 u 0.13 D037 Pentachlorophenol 0.056 u 0.056 u 100 Pesticides 0020 Chlordane 0.0088 u 0.0088 u 0.03 0012 Endrin 0.0022 u 0.0022 u 0.02 0031 Heptachlor 0.0019 u 0.0019 u 0.008 0031 Heptachlor Epoxide 0.0010 u 0.0010 u 0.008 0013 Lindane 0.12 u 0.12 u 0.4 0014 Methoxychlor 0.14 u 0.14 u 10 0015 Toxaphene 0.44 u 0.44 u 0.5 Units (mg/l) (mg/l) (mg/l)

Note: All results are corrected for spike recoveries.

Note: The TCLP Herbicides analyses were subcontracted to Laboratory Resources, Inc. Please see the attached copy of their report .

Page 9 e Test Report No. A2Bl?J

• -* VIII. Analytical Results (Cont'd)

TCLP Metals Analytik.E 'H AnalytiKEM Designation: A28173-l Client Designation: HZS-92-08-01 EPA Method Sample , Regulatory Number Parameter Blank Result Level 0004 Arsenic 0.54 u 0. 54 u 5.0 0005 Barium 2.2 u 0.077 J 100 0006 Cadmium 0.11 u 0.11 u 1. 0 0007 Chromium 0.52 u 0.52 u 5.0 0008 Lead 0.56 u 0.56 u 5.0 0009 Mercury 0.017 u 0.017 u 0.2 0010 Seleni~ 0.50 u 0.50 u 1.0 DOll Silver 0.44 u 0.44 u 5.0 Units (mg/1) (mg/1) (mg/l)

Note: All results are corrected for spike recoveries.

Test Report Page 10 e~o. A 23 ~

73

'VIII. Analytical Results (Cont'd)

,4flalyt:ik.E H TCLP Organic Analyses Analyt!KEM Designation: A28173-2 Client Designation: HZS-92-08-02 EPA Method Sample Regulatory Number Parameter Blank Result Level Volatile Organics 0043 Vinyl Chloride 0. 011 u 0.063 u 0.2 0029 1,1-0ichloroethylene 0.010 u 0.051 u 0. 7 0022 Chloroform 0.010 u 0.051 u 6.0 0028' 1,2-0ichloroethane 0.010 u 0.053 u 0.5 0035 2-Butanone (MEI<) 0.022 u 0.046 u 200 0019 Carbon Tetrachloride 0.010 u 0.052 u 0.5 0040 Trichloroethylene 0.010 u 0.051 u 0.5 0018 Benzene 0.010 u 0.052 u 0.5 0039 Tetrachloroethylene 0.010 u 0.051 u 0.7 0021 Chlorobenzene 0.011 u 0.051 u 100 Semivolatile Organics 0038 Pyridine 0 .071 u 0.071 u 5.0 0027 1,4-0ichlorobenzene 0.016 u 0.016 u 7.5 0023 o-Cresol 0.019 u 0.019 u 200 0024,0025 m,p-Cresol 0.019 u 0.019 u 200 0034 Hexachloroethane 0.023 u 0.023 u 3.0 0036 Nitrobenzene 0.013 u 0.013 u 2.0 0033 Hexachlorobutadiene 0.013 u 0. 013 u 0.5 0042 2,4,6-Trichlorophenol 0.018 u 0.018 u 2.0 0041 2,4,5-Trichlorophenol 0.081 u 0.081 u 400 0030 2,4-0initrotoluene 0.030 u 0.030 u 0.13 0032 Hexachlorobenzene 0.025 u 0.025 u 0.13 0037 Pentachlorophenol 0.056 u 0.056 u 100 Pesticides 0020 Chlordane 0.0088 u 0.0088 u 0.03 0012 Endrin 0.0022 u 0.0022 u 0.02 0031 Heptachlor 0.0019 u 0.0019 u 0.008 0031 Heptachlor Epoxide 0.0010 u 0.0010 u 0.008 0013 Lindane 0.12 u 0.12 u 0.4 0014 Methoxychlor 0.14 u 0.14 u 10 0015 Toxaphene 0.44 u 0.44 u 0.5 Units (mg/l) (mg/l) (mg/l)

Note: All results are corrected for spike recoveries.

Note: The TCLP Herbicides analyses were subcontracted to Laboratory Resources, Inc. Please see the attached copy of their report.

-r e

Test Report ~o. A28L73 Page 11 "lIII. Analytical Results (Cont'd) 4na/ytikE H TGLP Metals AnalytiKEH Designation: A28173-2 Client Designation: HZS-92-08-02 EPA Method Sample Regulatory Number Parameter Blank Result Level 0004 Arsenic 0.54 u 0.54 u 5.0 0005 Barium 2.2 u 0.97 J 100 0006 Cadmium 0.11 u 0.11 u 1. 0 0007 Chromium 0.52 u 0.52 u 5.0 0008 Lead 0.56 u 0.56 u 5.0 0009 Mercury 0.017 u 0.017 u 0.2 0010 Selenium 0. 50 u 0.50 u 1.0 0011 Silver 0.44 u 0.44 u 5.0 Units (mg/l) (mg/l) (mg/l)

Note: All results are corrected for spike recoveries.

T Test Report ~ A23L7J

.- Page 12 W IX. Quality Control Data 4.na/ytik.E l1 TCLP Procedure Volatile Organics Aqueous Matrix Spike Recovery Data Sample Spiked A27863-6 Alnount Recovery Parameter of Spike MS Vinyl Chloride 0.25 92 1,1-Dichloroethene 0.25 98 Chloroform 0.25 97 1,2-Dichloroethane 0.25 97 2-Butanone (MEI<) 0.25 46 Carbon Tetrachloride 0.25 98 Trichloroethene 0.25 98 Benzene 0.25 100 Tetrachloroethene 0.25 100 Chlorobenzene 0.25 94 Units (ug) (%)

l.

Test Report Page 13 e

~o. A281 ~3

~I IX. Quality Control Data (Cont'd) 4.na/ytik.I: H TCLP Procedure Volatile Organics Aqueous Surrogate Recovery Data Surrogate Recovery Sample l,2-Dichloroethane-d 4 Toluene-d 8 4-Bromofluorobenzene Designation (0.25 ug Added) (0.25 ug Added) (0.25 ug Added)

Method Blank 1 104 96 102 Method Blank 2 112 99 98 A27863-6 Spike 95 95 100 A28173-1 102 96 104 A28173-2 99 103 105 Units (%) (%) (%)

Test Report Page 14 e

~o. A2317 J IX. Quality Control Data (Cont'd)

TCLP Procedure Semivolatile Organics Aqueous Matrix Spike Recovery Data Sample Spiked A28073-l Alnount Recovery Parameter of Spike MS Pyridine 100 14 1,4-Dichlorobenzene 100 61 o-Cresol 200 53 m,p-Cresol 400 54 Hexachloroethane 100 43 Nitrobenzene 100 77 Hexachlorobutadiene 100 77 2,4,6-Trichlorophenol 200 56 2,4,5-Trichlorophenol 200 62 2,4-Dinitrotoluene 100 33 Hexachlorobenzene 100 40 Pentachlorophenol 200 90 Units (ug) (%)

Test Report ~o. A2817 3 Page 15

~ .,

, IX. Quality Control Data (Cont'd)

TCLP Procedure Semivolatile Organics Aqueous Surrogate Recovery Data Surrogate Recovery Sample *2-Fluorophenol Phenol-d 5 2,4,6-Tribromophenol Designation (200 ug Added) (200 ug Added) (200 ug Added)

Method Blank 76 68 106 A28073-l Spike 37 34 122 A28173-l 91 108 122 A28173-2 94 85 109 Units (%) (%) (%)

Surrogate Recovery Sample Nitrobenzene-d 5 2-Fluorobiphenyl Terphenyl-d 14 Designation (100 ug Added) ClOO ug Added) (100 ug Added)

Method Blank 86 49 127 A28073-l Spike 39 60 75 A28173-l 108 98 76 A28173-2 102 93 81 Units (%) (%) (%)

Test Report Page 16 e~o A28t7J IX. Quality Control Data (Cont'd)

TCLP Procedure Pesticides Aqueous Matrix Spike Recovery Data Sample Spiked A28173-l Amount Recovery Parameter of Spike ..l1L gamma-BHC (Lindane) 0.2 34 Heptachlor 0.2 43 Heptachlor Epoxide 0.2 79 Endrin 0.5 93 Methoxychlor 2.0 70 alpha-Chlordane 0.2 78 gamma-Chlordane 0.2 90 Toxaphene ; 4.0 113 Units (ug) (%)

Spike performed on sample A28173-2.

e Test Report Page 17

~0 A 23 ~

73 IX. Quality Control Data (Cont'd)

TCLP Procedure Pesticides Aqueous Surrogate Recovery Data Surrogate Recovery Sample Dibutylchlorendate Designation (1. 0 ug Added)

Method Blank 98 A28173-l Spike (Pest.) 66 A28173-2 Spike (Tox.) 39 A28173-l 62 A28173-2 84 Units (%)

,._.-', Page 18 e Test Report ~o A2817J IX. Quality Control Data (Cont'd)

TCLP Procedure Metals Aqueous Matrix Spike Recovery Data Sample Spiked A28174-1 Amount Recovery Parameter of Spike ~

Arsenic 100 92 Barium 300 90 Cadmium 300 90 Chromium 300 96 Lead 300 89 Mercury ~ 20 117 Selenium 100 101 Silver 300 90 Units (ug) (%)

~ Spike performed on sample A28173-1.

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28 Springdale Road 454 South Anderson Ro;:id OTC 59}-

Cherry Hill, New Jersey 08003 Chain-of-Custody Rock Hill, South Carolina 2!:1730 (609)751-1122 * (215)923-2068 (803) 329-9690 rax: (609~ 751-0824 Fax: (803) 329-9689 Client /15..l. l l, Projed:f"ucL o.*L 'ip1l L~j ~a.nr: ff~* /I.t'~AnalytiKEM Contact f-k'Df'u.

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1. Field Measurements: II.

• Field Conditions/Comments: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __

Data Sheets: Y N Filtered: Y Not Required Ill. Special Instructions: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __

(Detection Limits, Data Package, etc.)

Relinquished By: Time/Date: Time/Date: