ML20206M129
| ML20206M129 | |
| Person / Time | |
|---|---|
| Site: | South Texas  |
| Issue date: | 06/12/1985 |
| From: | Bausch H, Danesh P, Pazargadi S WYLE LABORATORIES |
| To: | |
| Shared Package | |
| ML20206M077 | List:
|
| References | |
| 57694, 57694-RA, NUDOCS 8704200031 | |
| Download: ML20206M129 (166) | |
Text
{{#Wiki_filter:.. . WYLE tasonarones sceawc saavces a sesttus ow ENGINEERING Wyle Repo,, No. 37694
,m Wi$ttRN OPERAflCNS. NORCO PACILITY
\ te4 Hittsroe AvtNut NORCO. CALIFORNIA 91760 Wyle Job No. NES 57694 (h ARIA CODE 714 7374471 TWX 910 332-1204 ftLECOPY (714) 7374071 Customer P.O. No.14926-EQ01EQ Task 12 l Total Pages this Report 12 Date: February 25, 1985 1 Revision A - June 12, 1985 r- ,
AGING ANALYSIS OF NON-METALLIC MATERIAL OF PACKLESS METAL DIAPHRAGM VALVES L. J i
. O PREPARED BYr aden,IV
. Pizzargad
/
VERIFIED BY, Oe #- ' F. Danesh APPROVED BY, / H. PIBausch QUALITY ASSURANCE: ~ N 8704200031 870415 L. HousCeau PDR ADOCK 05000498 A PDR M
WYLE LA80RATORIES SCIENTIFIC SERVICES & SYSTEMS GROUP
/
("o, REVISIONS Rev.No. Date Pages Affected Preparer Reviewer QA PE Description of Changes l A 6/12/85 2, 11 Sf, 4..p 3' Incorporated Customer Comments O W.92
M-semimac nemens a smew-REPORT NO. 2 N OPERAfloNS, NOACO FACluTY noe no V Revision A TABLE OF CONTENTS Page No. 3 1.0 SCOPE............................................................... 1.1 O b j e c t iv e s . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1.2 Applicable Qualification Standards . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 and Documents 4 1.3 Non-Me tallic M ate rials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6 2.0 DEFINITION OF SERVICE CONDITION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 3.0 EVALU ATION CRITERI A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.1 Evaluation of Susceptibility . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 { to Radiation Degradation 3.2 Evaluation of Susceptibility . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 to Time / Temperature 10 4.0 E V ALU ATIO N . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 4.1 R a d ia ti on . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.2 Tim e/Te mperatu re Aging . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 11 4.2.1 Temperature / Pressure Ef fects . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 i 4.3 H u mi d it y . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11 5.0 CO NC LU SIO N . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 j 6.0 R EFER ENC ES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l l l
REPORT NO 57694 tasonatomas sosam,ic sanwicas 6 systems enoue , WESTERN oPERArioN$.NoRCo FACluTY ,,,, ,,o 3 ]
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V 1.0 SCOPE This document was prepared by Wyle Laboratories for Bechtel Energy - Corporation (BEC) for equipment to be used in the South Texas Project Electric Generating Station. 1.1 Objectives The purpose of this report is to perform an aging analysis of non-metallic materials used in the packing rings of the Kerotest Packless Metal Diaphragm valves listed in Section 1.3. The aging analysis of non-metallic materials was based on the criteria of susceptibility to time / temperature and radiation mechanisms. 1.2 Applicable Qualification Standards and Documents o IEEE 323-1974 "Standied for Qualifying Class lE Equipment for Nuclear Power Generating Station". l ' o IEEE 627-1980 " Standard for Design Qualification of Safety' Systems p Equipment Used in Nuclear Power Generating Stations". o Bechtel Specification 4A479ES1018, Rev. 2, " Specification for the l Environmental Qualification of Safety-Related Electrical and l Mechanical Equipment for the Houston Lighting and Power Company South Texas Project Electric Generating Station". o bechtel Specification IL529TS0104, Rev. O, " Specification for ASME Section III Bellow Seal or Packless Metal Diaphragm Valves 2 inches and smaller for the Houston Lighting and Power Company, South Texas i i Project Electric Generating Station," with Addendum 1, January 17, 1983. o Wyle Laboratories Western Test and Engineering, Quality Assurance Manual,380 Rev. D dated 15 April 1984. f I lO
M694 M REPORT NO westeenopenatom wonco paauty ,, 4 O ! 1.3 Non-Metallic Materials The subject of this analysis is non-metallic materials used in the Kerotest Packless Metal Diaphragm Valves listed in Table 1. TABLE 1
- LIST OF NON-METALLIC M ATERIALS PACKING IDENTIFICATION NUMBER MATERIAL VSS NO. LOCATION 1/2DH 2655 3A-C 2CR3 48 Outside RCB 1/2DH 2655 3B-C 2CR3 49 Inside RCB 1/2DH 4655 3A-C 2CR3 50 Outside RCB 1/2DH 46SS 2A-3 2CR3 1 Outside RCB 1/2DH 46S5 28-3 1871 2 Inside RCB 1/2DH 46S5 2C-3 1871 3 Outside RCB 1/2DH 4655 3A-3 187I 4 Outside RCB 1/2DH 4655 3C-3 1871 5 Inside RCB 1/2DH 46T3 2B-C Grafoil 89 Inside RCB l
i 1/2DH 4655 2b3 2CR3 73 Outside RCB ! 1/2DH 2655 2A-C 1871 51 Inside RCB l 1/2DH 2655 28-C 1871 52 Outside RCB 1/2DH 2655 3A-C 2CR3 83 Inside RCB i 3/4DH 2655 3bC 1871 6 Inside RCB
-3/4DH 4655 IB-3 1871 7 Inside RCB 3/4DH 4655 IBB3 1871 53 Outside RCB 3/4DH 4655 2A-3 1871 8 Inside RCB
. 3/4DH 4655 2B-3 187I 10 Inside RCB 3/4DH 4655 2BB3 1871 11 Outside RCB 3/4DH 4655 2C-E 1871 54 Outside RCB
- 3/4DH 46S5 2C-3 1871 12 Outside RCB 3/4DH 4655 3A-3 1871 14 Outside RCB 3/4DH 4655 3B-3 1871 15 Inside RCB 16 Outside RCB ,
3/4DH 4655 3C-3 187I 3/4NH 4255 3CB3 1871 74 Outside RCB 1 DH 2655 IB-C 1871 91 Inside RCB
'I DH 2655 2A-A 1871 82 Outside RCB 1 DH 2655 2A-C 1871 55 Outside RCB 1 DH 2655 2B-C 1871 87 I.V.C.
! 1 DH 2655 3A-C 187I 18 Outside RCB ! 1 DH 2655 3B-B 1871 86 Inside RCB 1 DH 2655 3B-C 1871 56 Inside RCB 1 DH 46SS IB-C 1871 90 Inside RCB lO i
M - -.- - . . neroni NO 57694 m OPNAfl0NL N00C0 FAcuTY , , J 4 O l 1.3 Non-Metallic Materials, (Continued) i - PACKING IDENTIFICATION NUMBER MATERIAL VSS NO. LOCATION l i-1 DH 4655 IB-3 1871 19 Inside RCB 1 DH 46S5 2A-C 1871 79 Outside RCB t 1 DH 4655 2A-3 1871 57 Outside RCB 1 DH 4655 2AB3 1871 58 Outside RCB 1 DH 4655 2B-C . 1871 88 Inside RCB 1 DH 46S5 2B-3 1871 20 Inside RCB i 1 DH 4655 2BB3 1871 59 Inside RCB 3 1 DH 4655 2C-E 1871 80 Outside RCB 1 DH 4655 2C-3 1871 60 Inside RCB 1 DH 4655 3A-C 1871 61 Outside RCB 1 DH 4655 3A-3 1871 21 Outside RCB 1 DH 4655 3BB3 1871 63 Inside RCB 1 DH 4655 3B-B 1871 84 Inside RCB i 1 DH 4655 3B-3 1871 62 Inside RCB i 1 DH 4655 3C-3 1871 64 Outside RCB i 1 NH 46S5 2BB3 1871 75 Inside RCB
'1-1/2DH 2655 2B-C 1871 81 Inside RCB 1-1/2DH 2655 3A-C 1871 65 Outside RCB i 2 DH 2655 3A-C 1871 66 Outside RCB 2 DH 2655 3B-B 1871 85 Inside RCB 2 DH 46BP IBB3 1871 78 Inside RCB
+ 2 DH 46SS IB-3 1871 22 Inside RCB
~2 DH 4655 IBB3 1871 67 Inside RCB 2 DH 46S5 2A-3 1871 23 Outside RCB 2 DH 4655 2AB3 1871 24 Outside RCB
. 2 DH 4655 2B-3 1871 25 Outside RCB s 2 DH 4655 2C-3 1871 26 Outside RCB -
2 DH 4655 3A-3 1871 27 Outside RCB 2 DH 4655 3AB3 1871 68 Outside RCB 2 DH 46S5 3B-3 1871 69 Inside RCB 2 DH 4655 3BB3 1871 70 Inside RCB 2 DH 4655 3C-3 1871 28 Outside RCB 2 DM 46SS 2B-3 SXH 1871 31 Inside RCB i.' 2 KR 46SS 2A-3 1871 38 Outside RCB 2 KR 4655 2C-3 1871 40 Outside RCB 2 KR 4655 2CB3 1871 41 Outside RCB . 2 NH 4255 3CB3 1871 76 Outside RCB 2 NH 4655 2BB3 1871 77 Inside RCB 1 t . ?
M umanarones seemc sences a smew aaove REPORT NO 57694 WETGANopetATioNS NotCoFAcIUTY PAog no 8 1.3 Non-Metallic Materials,(Continued) PACKING IDENTIFICATION NUMBER MATERIAL VSS NO. LOCATION 2ACTDM 46BP IB-3 FXX 1871 92 Inside RCB 2ACTDM 4655 2A-3 FXX 1871 33 Outside RCB (Other than IVC) 2CTRDM 46S5-2B-3 FXX 1871 71 Inside RCB 2ACTDM 46SS 2C-3 FXX 1871 72 Outside RCB (Other than IVC) 2ACTDM 46SS 3A-3 FXX 1871 34 Outside RCB (Other than IVC) NOTES: 2CR3 = John Crane 2CR3 (Braided Asbestos with Resilient Plastic Core) 1871 = John Crane 187I (Braided Asbestos with Inconel Wire) . Grafoil = Garlock Grafoil (graphite) with zinc spacers 2.0 DEFINITION OF SERVICE CONDITION C's BEC has specified the following environmental service conditions (Ref.1). 2.1 Valves for Inside Containment Service Valves designed for inside containment service will be subjected to the following harsh environmental conditions: Normal Conditions Accident Pressure +0.3 psig (Max) 48.4 psig (Max)
-0.1 psig (Min) -3.1 psig (Min)
Temperature 650F (Min), 3230F 1200F (Max) Radiation 2.0 x 107 rads 1.4 x 108 rads (40 years) (180 days) Relative Humidity 0-80 percent 100 percent l Radiation Type gamma gamma and beta 0
RgpoRT NO. $ m msaavcesasysismcam* wastaan opseAnon nosco raciuty , , , , , 7 l l I 2.0 DEFINITION OF SERVICE CONDITION, (Continued) 2.2 Valves for Outside Containment Service (Excluding IVC RMS 054,244 A Thru Il Valves designed for outside containment service will be required to operate under the following worst-case harsh environmental conditions: Normal Conditior s Accident Pressure Atm 2.1 psig Temperature 1350 (Max) 2400F 500F (Min) Radiation 107 rads 8 x 106 rads
~
(40 years) (180 days) Relative Humidity 0 to 80 percent 100 percent Radiation Type gamma gamma 2.3 Valves for Isolation Valve Cubicle (IVC) Service Valves (excluding operators) designed for IVC will be subjected to the following worst-case harsh environmental conditions: Normal Conditions Accident Pressure Atm 5.8 psig Temperature 1040F (max) 3350F 290F (min) Radiation 100 rads 3.5 x 105 rads (40 years) (180 days) Relative Humidity 0 to 80 percent 100 percent Radiation Type gamma gamma i 1 v i
r l M _ - - _ . . , ~ REPORT NO 57694 womanopenAm menco rAouw , ,, . 3 3.0 EVALUATION CRITERIA 3.1 Evaluation of Susceptibility to Radiation Degradation The approach for evaluating radiation sensitive materials of the valves is a two-step process:
- 1. Research Wyle Laboratories Aging Library for information on threshold levels, severe damage levels, degradation characteristics, and failure criteria.
- 2. Provide evaluation based on potential material degradation and ability to perform its design function after exposure to the specified radiation dosage.
3.2 Evaluation of Susceptibility to Time / Temperature Related Mechanisms - For many organic materials,it is known that the degradation process can be defined by a single temperature-dependent reaction that follows the Arrhenius equation (Ref. I and 3): k = A exp (-(Ea/kgT)) where, k = reaction rate l i A = frequency factor ! exp = exponent to base e Ea = activation energy kB = Boltzmann's Constant (8.617 x 10-SeV/K) < I T = absolute temperature i O
/0
r M usonavenes ses==c sewees a ennus enoup nepoaf NO. 57694 6 oPMAM NoACo FACluTY , 9 4 3.2 Evaluation of Susceptibility to Time / Temperature Related Mechanisms (Con't.) It is further noted that, for many reactions, the activation energy can be considered to be constant over the applicable temperature range. Life is assumed to be inversely proportional to the chemical reaction rate (Ref. 2 and 4). In terms of life, and after converting to Napierlan base logarithms, equation (1) becomes: In Ulfe) = (Ea/kg)(1/T) + Constant (2) Equation (2) has the algebraic form: y = mx + b, where y = InUlfe) O- x = 1/T m = Ea/kB, constant for single dominant reactions b = constant The constants, m and b, can be estimated by fitting the experimental data in the form of Inulfe) versus 1/T to the above simple linear relationship. For example, Dow Corning #732 RTV Silicone Rubber with a failure criterion of 50% elongation: In(life) = 8956.8356(1/T) - 11.4998 for a baseline temperature of 313K (IC40F) life = 3.09 x 103years O n
nepoaf NO. 57694
- M,emme usena scowsesamucasasvsmseonow womanopenanons,noncoraciury moe no 10 4
i 4.0 EVALUATION Three types of packing rings are used in the Kerotest Packless Metal Diaphragm Valves. These three types of rings are: John Crane type 1871, John Crane type 2CR3 and Garlock Grafoil. 1871 packing rings are made of braided pure asbestos yarn with an Incone!
- wire inserted around a resilient asbestos core and impregnated with Graphite.
l The 2CR3 type packing ring is made of asbestos with a Neoprene binder and . graphite lubricant. Grafoil packing rings are an all graphite packing containing no resin binders or inorganic fillers. Asbestos and graphite are high temperature and radiation resistant materials. The following paragraphs discuss the effect of radiation and temperature on the packing rings made of these materials. i 4.1 Radiation l The radiation damage threshold for packing ring type 1871 is 107rads gamma (Ref. 5, 6). ' i The radiation damage threshold level for type 2CR3 packing is 8.0E5 (Ref. 7). This radiation damage threshold is based on the damage threshold of the binder material (Neoprene). 1 i The radiation damage threshold level for the Grafoil packing ring is 1.5x10 9
! -rads (Ref. 6).
j Grafoll packing 18 Insensitive to the radiation levels specified in Paragraph t
- 2.0. John Crane packing ring types 1871 and 2CR3 are insensitive to the radiation level of the IVC area. These two types of packing rings are sensitive to the total integrated radiation dose of areas other than the IVC. '
- 4.2 Time / Temperature Azing i The packing rings are made of non-organic materlats, except for the
,1 Neoprene used as a binder in the 2CR3 type. Types 1871,2CR3 and Grafoil have temperature ratings of 12000F,7000F and 10000F respectively (Ref. 6).
I The non-organic materials, asbestos, graphite and metal, are not sensitive to i' the effects of the time / temperature aging. Neoprene is the weak link material of the 2CR3 type ring. The Arrhenius parameters for Neoprene when used as a gasket are: Slope = 12190.06379 (Ref. 8) l Intercept = -24.09326 (Ref. 8)
; I%
1 - - - - _ _ _ . - . . -- - - . - - , - - -
M -- scarme ssancu n evememou, REPORT NO Il westeencessatom wonco mciun p ,, Revision A 4.2 Time / Temperature Aging,(Continued) The worst case normal service temperature specified in paragraph 2.0 is 1350F. The expected life of the Neoprene materlat when used as a gasket, in the worst case service temperature,is greater than 40 years. The effects of time / temperature aging on the 2CR3 ring is judged insignificant in 40 years, because the Neoprene expected life exceeds 40 years and its application is as a binder. Since time / temperature effects are insignificant for these packing rings in 40 years, shelf life is not a concern, if the packing rings are stored per Manufacturer recommendation.
~
4.2.1 Temperature / Pressure Effects Reference 9 is a report of temperature and pressure testing of the braided asbestos-graphite impregnated and grafoil packing rings in a borated water system . The test objective was to determine the leakage rate when valves I containing these types of packing rings were subjected to a number of high temperature, pressure cycles. Tests were conducted at 2000 psi at 1300F, and 2250 ps! at 550-6500F. This test program showed that braided asbestos-graphite impregnated
- packings are not recommended for critical nuclear services where high
- pressure borated water is encountered and periodic gland adjustments cannot
- be performed.
This test program also showed that packing rings made of grafoil are superior i to braided asbestos-graphite. 4.3 Humidity The pacliing materials in all of the valves are sealed against the outside i humidity and therefore the humidity has no significant effect on aging of the non-metallic materials used in the valves. ,
5.0 CONCLUSION
John Crane 1871 and 2CR3 packing rings are not significantly affected by time / temperature aging and humidity in 40 years of normal service. However, these packing rings have rad!ation damage thresholds that are lower than the required TID except for the IVC location of the plant.
- Therefore, this analysts cannot support the qualification of John Crane 1871 and 2CR3 packing rings (see Table I for those valves with these types of packing ring materials). Moreover, these packing rings are not recommended for high pressure borated water service and where periodic gland adjustments cannot be performed. Grafoil packing rings, however, are not affected by the required radiation and time / temperature and humidity effects in 40 years and ,
i are therefore quallfled for this period of time. , l l
M
- -- _ - noewsc senwes a enn= onow REPORT NO- 57694 womBN OPERAMONI.NotCo FACluTY ,g, no ]2
6.0 REFERENCES
- 1. Bechtel Task Description, Task No. EQOqEQ-4032EQl, Rev. 0
- 2. "IEEE Guide for the Statistical Analysis of Thermal Life Test Data, "IEEE 101-1972, Library Code 265-80
- 3. "A Review of Equipment Aging Theory and Technology," 5.P. Carfagno and R.3. Gibson, Frank!!n Research Center, Electric Power Research Report No. EPRI-NP-1558, Library Code 600-82
- 4. Handbook of Engineering Fundamentals, 3rd Edition, O.W. Eshback and M. Sanders, pp.1284, John Wiley & Sons,1975, Library Code 247-80
- 5. Severe Service Graphite Filament Yarn Packing, John Crane Bulletin No. P-3006 2
- 6. Wyle Contact Report with Kerotest, dated January 23.1985, Report by Shayan Pazargadi
'7. "The Use of Plastics and Elastomers in Nuclear Radiation," W.W.
D Parkinson and O. Sisman, Library Code 438-81
- 8. " Wires and Cords for Original Equipment Manufacturers," General Electric Company, No. WCC-2, Library Code 185-79A
.9. Rockwell-Edward Univalve Borated Water Stem Packing Tests, by Roger D. Norden, Supervisor Product Engineering Valve Engineering and Research, Rockwell Manufacturing Company .
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f-WESTINGHOUSE LETTER ST-WN-YB-2875 l I I l Y i 1 '
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@.SI-WNY8-2 fitt he E Westinghouse Electric Corporation Power Sgggg)k g 5 g 5 "jUll,7 s I s t X
y WG" "{j5 '{ !$[NesPennsisess1523003tn PAOC (amc Wr ICs Cryit Pt<0hriG WGi fG5Coh'1sts
$eptember 16. 1986 PE.syst(Us !
EGS ILIC ' Nr.A*M311UI n ,m ,3, m ,cs.ig x 5.0. No: 1GK 219 pg .h uCit C X (Gs WICM a Project Engineering Managerant.ocicost tos+vetua Ref.: ST-Y8-WN-1599 Bechtel Energy Corporatton ountiiW:a c resethi os s
$400 Westheimer Court asss cocao x tGs rsso Action Item No.: 1058 P.O. Box 2166 aus m X EGUQc Houston. Texas 77252-2166
$0UTH 1EXA$ PROJEC1 UN11$ NUM8tR$ 1 & 2 CON 1RACT NUMBER $ 35-1197-4Q00 AND 35-1197-8000 -
JOHN CRANE VALVE PACKING RADIATION RFS1 STANCE
Dear Mr. Mattuk:
On the reference letter BEC noted that NS$$ supplied valves 8901 A/8/C qualified under WCAP 11024 have John Crane 1871 packing rings. SEC also noted per WCAP 11024 packing rings are qualified to 1.0x10 10 rads gama and John j O. Crane bulletin shows and John Crane letter attached to the reference confires a radiation resistance dose of 1.0x107 rads gama. BEC requested, in the i l reference, that Westinghouse provide clarification and justification for the 1.0x1010 rads gamma radiation resistance for valves with John Crane 1871 packing rings. The radiation threshold limit of John Crane 187-1 Packing is 1 x 107 rad as reported in the referenced letter. This threshold limit is based on the luna 5 binder that makes up at most 105 of the packing material. The other 905 of the packing material is comprised of asbestos and graphite which are very radiation resistant materials and have a minimum radiation threshold of 1 x 1010 rads. Westinghouse assigned a radiation limit of 1 x 10 10 rads in WCAP 11024 based upon the functions of the individual components of John Crane 187-1. The asbestos and graphite fibers are the primary components of the 187-1 packing rings. The Suna $ binder is used to help keep these fibers in place during handling and installation. Once the packing rings are placed in the Stutfing box and compressed, the packing rings assume the shape of the stuffing box. Thus, once installed, the packing rings will maintain their shape and perform their function even if the luna $ binder becomes brittle when subjected to radiation levels greater than 1 x 10 7 rads because the asbestos and graphite perform the primary packing function.
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-_---- .- - - - _ - - - =-_.- .
51-WN-YB-2815 Page 2 4
; therefore, Westinghouse concludes that lohn Crane 181-1 Packing is acceptable l for radiation levels up to 1 x 10 10 rads because the asbsestos and graphite l fibers perform their primary packing function and maintain their shape even if the Buna 5 binder becomes brittle due to radiation levels greater than ; 1 x 101 rads.
Very truly yours. WI{511NG J5E ELECTRIC CORPORA 110N N \L F. Twogoo . Manager Sout i Texas roject d CVernon/ajs/1148F:1 cc: A. Matiuk (BEC) IL N. C. Horning (BLC) IL RMS (SEC) IL E. W. Dotson (HL&P) 2L B. W. Heery (W Houston Of fice) IL G. Glasbergen (W So. lexas Site IL O. A. L. Hogarth (W So.lexas Site) 2L IL R. Shomo (W So.lexas Site) C. W. Rowland (W So.lexas Site) IL l l l . O .
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OVERSIZE DOCUMENT , PAGE PULLED SEE APERTURE CARDS NUMBER OF OVERSIZE PAGES FILMED ON APERTURE CARDS 5 I l APERTURE CAPD/HARD COPY AVAILABLE FROM RECORD SERVICES BRANCH,TIDC FT5 492 = 8989
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- - MECHANICAL EQUIPMENT QUALIFICATION
?. APPROACH AND FLOW DIAGRAM (Excerpts from MEQ-1 Report, Section 5,pages 5-14 5-2) i e e E 9 9' . J
.14926-MEQ-1 Revision 0 5.0 MECHANICAL EQUIPMENT QUALIFICATION APPROACH The non-metallic parts of the safety-related mechanical equipment are identified in Appendix A. Also in this Appendix the Mechanical Equipment Qualification Summary status for each part is provided. A determination is l nade during qualification analysis in Appendices A and D as to whether the j - non-metallic part is required for the equipment to perform its safety function. If a.part is not required, no further an.alysis is performed and the l rationale is provided. If the part is required, it must be constructed of '
materials with the capabilities to withstand the environment and process condition imposed on it. The non-setallic part's degradation must not prevent the equipment from performing its safety functions during its exposure to these environmental , conditions. j Material capabilities are compared against the environmental and process of facts of radiation, temperature, and aging, to determine part i susceptibility. The Arrhenius equation is used where applicable to calculate the life of materials. The af facts of pressure and innsidity were not analysed l since these are enveloped by the process conditions given in the design ' l specification. The effect of external beta radiation is considered to be insignificant as the non-metallic parts are shielded. The non-metallic material qualification in Appendix D shows the results of the material-capability analysis, and the qualified life of each non-metallic j asterial.; The life , calculation is based on the radiation and temperature only and must be used in conjunction with the specified maintenance / surveillance l i program identified in equipment manual provided by respective vendor / manufacturer. A flow diagram of the overall approach for mechanical equipment qualification l
- is shown on F. S.2. ,
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3V101tDA113 T044400 DAMPER 132t106 4 VE M326 091 11 AMERICAN WARM. NBD-70 H A A 4 WIG 1VGA115 !G44ADG-GAMPEA-252Altt --
"320 000 iMEAICA4-WARM. " 0P 71 -
. P .A A I 3 191VDA119 TORMADD DAMPER'264X144 'M HM 'M324 060 AMERICAN WARM.' NBD-71 u' .'M A A 3 1E1VDA120 TCRNADD DAMPER 158X191 M HM- M324 060 AMERICAN WARM. NBD-711- -M ,A A - 1] 's M v1 1VD&173 T644400-BA888E4-77f 27 - "- " 3 2+-9 9 7 A PsERIC A8eWa#Ms-490-7 0 " * '
$*,U101V34222 BACEDRAFT D4"PER 14X16 M HM M3274 060 AMERICAN WARM. NBD-53 H A AM 30101 COA 223 BACKDRAFT DAMPER 14:16 M HM M3274 060 AMERICAN WARM. NBD-53 H A A 7"C111VGA&75 !4AkADO-GAMPEA--72X40 , , _ - - - M2-M591-660 . APERICAN-bARM. :.00-71. . - - a , ,_ 43:111;DA076 - TD4NADO DAMPER 54X72 ~ - . .M HE' M5029-086 AMERICAN WAR 9.' NSD-78 '* H +A A ~' fi 7 l3J111VDA077 TORNADD DAMPER 48I48 M HE M5028 096 AMERICAN WARM. NBD ' H A'- B c'- 1
'L3V111V9447?
~
T044400-04858E4-4884 0 "
"C "%24-69', e Mr#IC A4-v49n ~.-4e0-71 "
0 3V111 COA 206 PARALLEL BLADE DAMPER 72330 9 HE M1049 020 06 AMERICAN WARM. NVC-41 H A A 3v11100A207 PARALLEL BLADE DAMPER 72X30 M HE M2068 053 AMERICAN WARM. NVC-41 H A A
@ *a11VGA2GS P AA ALLE k-BL AGE-GAMPE A-72 A & O - ME "414 --476-GhAMEA I CAN-d A A M.-4 WC41 - "
A- A [33111VDA209 CPPOSED BLADE DAMPER 72X72 M HE M1048 020 06 AMERICAN WARM. NVC-41 ' H A 'A "- _M
'37111YDA210 . CPPOSED BLADE DAMPER 72X72. -
M HE M2069 046 06-AMERICAN WARM. NVC-411 H A A ,d 4 Gil1VOAPl* 0 40SE0k-BLADE-04aaPE4-72w72 = "E - - *+ 19-471-06-A *E# f C A M-W A P M.-N VC-41 " e A *l 3U111TDA212 PARALLEL BLADE DAMPER 72E30 M HE M104B 020 06 AMERICAN WARM. NVC-41 H A A 3V11100A213 PARALLEL BLADE DAMPER 72x30 M HE M2069 046 06 AMERICAN WARM. NVC-41 H A A '735111VOA21" P AA ALLEL-6LAGE-GAMPEA-72 EE -
" ME- - M t 16-471-4hAMEAiGA4-W ARM.--4VG _ "
i e ._ m [32111VDA215 BACKDRAFT DAMPER 18X18 M HE - M104B 020 06 AMERICAM WARM. NBD-53 H A A ,% 32111;DA216 BACKDRAFT DAMPER 18X18 M HE 'M2068 045 06 AMERICAN WARM. 480-53 H A A *i '
--3';111V04217 SACKDAAFT-04##E4-14NIS ~ "
ME "' 14-471-65-AME# f C&4-W A R M.-NBO-53 " ^ 3V111vDA218 BACKDRAFT DAMPER 50I50 M HE M1048 020 06 AmERICAN WARM. NBD-53 H A A 371110:4219 BACKDRAFT DAMPER 50X50 m HE M2068 045 11 AMERICAN WARM. NBD-53 H A A I W 1110DA222 SACKDAAFT-DA4PE b 5GA50 M "i - M 414-67 3-G o- A ME R I C A n-d A R M .--4BO-53 " a S , l 3J111VDA224 BACKDRAFT DAMPER 88X36 M HE M104B 025 09 AMERICAN WARM. NBD-53 H A A 7 -' 1
'3:111 CA225 BACKDRAFT' DAMPER'88X36' 'M HE' M2063 050 e3 AMERICAN VARM. NBD-53, -H A A yl
-0011140 A22i "ACKCAAFT-GAmAER-84EJE "
"E 85414--47 5 A ME A I C A 4- W A R M .-4 BD-53 "
A-S 3V111CDA230 OPPOSED BLADE DAMPER 12I12 M HB M508 089 AMERICAN WAR". NVC-42 H A 4 3:111:02231 OPPOSED BLADE DAMPER 12X12 M HB M507 090 07 AMERICAN WARM. NVC-42 H A 4
-30111VGA232 CDPOSEE-BL AGE-DAMPEb12 X12 "3 M 54 9-487-oh4 ME A I C A k-W A R 4.---N V C-4 2 A
- p .
30111VZA249 CPPOSED BLADE DAMPER 30X32 M HB M013 016 05 AMERICAN WARM. NVC-41 M A A - 30111VDA250 CPPOSED BLADE DAMPER 30X32 M HB M206 041 AMERICAN WARM. NYC-41 M A A
-30111VDA251 OPPOSED-9L ADe-Da=PE4-34x32 = kB-*10 7-46 E AMERICA 4-MADN,- WVC-41 " A 3 37111VDA252 BACKDRAFT D4"PER 40I24 9 HB M013 012 08 AMERICAN WARM. hBD-53 H A A 3V111tDA253 BACKDRAFT D4"PER 40I24 M HB M206 037 08 AMERICAN WARM. NBD-53 H A A S ACKDR AFT-C AMPER-4G A2 ^ "
-33111tDA254 M "S - M347-46b--AME AIC A M-M ARM.-4BD-53 A-A 33111CCA258 PARALLEL BLADE DAMPER 20I20 M HB M013 017 10 AMERICAN MARM. NVC-42 M A A 30111TCA259 PARALLEL BLADE DAMPER'20X20 M HB M206 042 AMERICAN WARM. NVC-42 M A A
- 30111VDA268 P A A AL L EL-BL ADE-LANTER-20EP S M un "347 - 467 iMEAICA4-WASM.--4WC-42 M A-3 33111VDA261 BACRDRAFT DAMPER 30M32 M HB M013 015 03 AMERIC AN WARa. NBD-53 H A A 33111VDA262 BACMDRAFT DA4PER 30I32 M H8 M206 040 03 AMERICAN WARM. NBD-53 H A A
-30111VDA263 8 ACKDR AF T-D AM PE R-30 232 4-Ha M307-065 AMERIC AL W AR M.-480-53 H---A - A 3V111VDA264 CPPOSED BLADE DAMPER 24X24 M HB M013 016 07 AMERICAN WARM. NVC-42 H A A 3V111CCA265 OPPOSED BLADE DAMPER 24r24 9 HB M206 041 07 AMERICAN WARM. NVC-42 H A A
- 30111VD A266-- - - -- OPPOSED -BL ADE-D AMPER- 24r24 M HR M307-066 07 AMERICAN WARM.. NVC-42----- H- A A--
3:111WDA269 BACKDRAFT DA"PER 12I12 M h9 *206 050 04 AMERICAN WARM. NBD-53 H A A _ _ _ _ _ _ . _ _ _ _ _ - - - _ - _. _ _ . _ _ . - _ - _ _ - - . - - . _ _ _ _ _ _ -- _ _-__ - . _ _ Jl 1 l l J
7 s-O ( SECTION 3 -Purchase Order No. & Equipment Description SOURCE: MEQ-1 O e t t O
14926-MIQ-1
. Revicito 0
(- l l PURCHASE ORDERl EQUIPMENT DESCRIPTION l SPECIFICATION NO. 4C56 l Essential cooling Water l 3R289NS0036-0 lSelf Cleaning l 1 I 4062 l58 Fool Gate System l 3F269550034-1 4076 lECW hap Lube Straine'rs 1 3R289NS0037-E 4092 l Essential CIA Water l 3R289NS0035-E l Traveling Screens l , 4099 l Air Manning Units 1 3V259VS0005-1 4102 lRefriseration 1 3V249?S0004-0 G13 - lMstallic Empnasion Joints l SL359PS0505-3 f l Safety Class Fans 3Y229VS0002-3 4119 4120 Safety Liams Fans 3V229VS0002-3 4122 l Miscellaneous haps & l 3Q089NS0001-0 l Motors l 4129 l Safety Class Part Filteral 3Y239VS0003-2 la Control Immels l N 4168 Safety class Dampers , 3V289VS0008-3 4308 i Nisation Dampeners for 1 2R179MS1012-1 lhaps l l l O MFARD1/SDM7CTI
-3.3-
i ik i 1 i SECTION 4- Environmental Conditions I t I l SOURCE: MEQ-1 , I l I l [ l l l l I l& f' i i i
l 4.0 EuY1mosesswrAL CDNDITIONS (continued) 14926-80B9-1
. Re v. 1 r% ~
(V l I l Ambient Environmental Conditione i *- erature ( F) r-Radiation ( Red) l Reference l l l l 70 S^ r Ilormal Accident Normal Accident I l t 14076/8076 34-104 104: ; 1 0E02 1 0E02 l 3R289 tis 0037-01 l 0-304ays I l , I l4092/3092 34-104 104: 1 0E02 1 0802 14E019WQ1009-6l l .0-30 days note 1 moto 1 I 50-135 155: 1 0807 7.2E06 ,3V259150005-1l l4099/8099 luote 9 l l 10.2-99eee I i l l l l 150: l l l l . I i 199.1-400seel l I I l 1 1 i 13s: 1 ' I l I J l 640s-30 days! l l 14102/8102 50-120 125:0-10mial1 0E03 ,1 3502 i3V249V50004-1l 45019WQ1009-61 l 115:14 min i l4113/8113' l
' l l l 1
14119/s119 I 50-104 120 , 1 0803 , 1 3804 i i i l i I I luote 9 1 I 1 ! !
; I 14120/8120 , 50-120 335 1 3.5504 2.3807 l l l l (man) l l(Ref.is0) l mote 9 l 1
l l l See Fig.4.2 l 1 14122/8122 .; 50-104 125: l 2.0803 1.0E32 l I I ,12.7-600eec I l l Note 9 i
-s
- 1. 104: - l l l l . l
. 4010see 14129/8129.: 50-104 . 120s 1 0803 1.3504 3V239430003-31 i l
l l 0-304ays I ! , l4168/816e 45-120 323 , 3 5504 l 2.3507 l3v289950000-31 l(1aside the i I (Itam) l Note 5 l Mote 5 Iw/dasper detal l RCB) i ISee Fig.4.11 l Ref.180 leheets" I I note 9 I . l416e/s16e 29-120 120 1 0803 1.7504 3V289950000-3l i l(Outside i 10-30 days l l lw/ damper detal ' l l the RCB) l l l l Isheets l Note 9 }[ l I l 50-135 ISS: 1 0E07 1 0502 ,2R179ms1012-2l i 14308/8300 j i l l0.2-99eec l - l l480191891009-61 l l l 150: 1 I I I i i 199.1-600. eel l I I i - I I i 135: l l l l i L l 640s-30 days l
.4310/0310 50-120 125:0-10 min 1 0503 1 3802 '
3V249951007-31 4501900Q1009-61 I 115:14 min l
- No safety related organic /non-metallic components (Ref.164) i
{ 14926 Mag /stP2 4,4 - 4 l 1
4.0 ENV m aneWTAL CDNDITIONS (ContiIued) 14926-NEQ-1 Rev. 2 NOFES:
- 1) The Essential C1f. Water Travelling Screens are located in the essential cooling water intake structure. The environmental conditions therefore are obtained from 4E019NQ1009-Rav. 7. . .
- 2) Osloted.
- 3) hre are two (2) areas outside the containment as specified by
' dB019WQ1009-7 which are exposed to more than 1 0807 rade (gamma only) for normal range 40 years total integrated dose (TID). h oe - *
! rooms in building MAa are Roon a) Eigh Activity Spent Rosin Storage Tank 0054 244A-T b) mized med Domineraliser Cubicles Sinoe no tag No. was identified in Rooms 0054 a 2444-T (Refer to EQ master file listing dated 6/26/86). m worst case normal l radiation of 2.0507 Reds (for inside RC3 except reactor savity rooms) is used as a conservative normal radiation level for the qualification of inside and outside RCB. f 4) (Del ted) I 5) h environmental conditions for the safety-related dampers with no actuators in F.C. 4168/8168 are listed. The environmental conditions for the safety-related dampers with Miller pneumatic actuators, Model 65A Series ares Temperature Radiation , i Wormals 29-120*F 1000 Reds l i l Accidents 120*F 4300 Reds j , c h environmental conditions for the safety-related dampers with Borg-Warner modulating hydraulic actuators, Models RMM-PC { and ROM-PC are , I Temperature Radiation i l Normal: 50-104*F 1000 Rada Accident: 120"F 13,000 Rads l 1492 ens 9/srF2 1 I e s--,- - - . - . , - - - - - . , , , , , , - - . , , - - , , ~n__,n.-_.-, y r a m_ - , , , . . , , , , - _ , , ,-,-._--n~n'
4.0 ENVIROISSNTAL GNIDITIONS (contiIued) 14926-NEQ-1
- new. 2 IIOTES :
1
- 6) (Deleted)
- 7) For the outside containment radiation of 10E07 Rads is the worst case for all locations except rooms 0054 and 2444-T.
- 8) The turbine-driven ymp and its associated equipment shall be qualifi'ed for the environmental condit' ions existing when cubicle -
ventilation has been lost. For this state of operation, this equipment must be qualified for the tagerature rising from a steady temp. of 104*F to 140'F in a 30-minute period and continuing to increase at the rate of 15'F/ Day for a period of 2 days once every 5 years, and encursions of 130*F for a duration of 24 hours once a year (Ref. 38149080043, Rev.3) . .
- 9) The environmental conditions were determined per EQ Master File Listing and Design Criteria (450191101009, Rev. 7 ) for the specific room where the equipment is located.
- 10) Norst ease harsh environmental conditions enveloping all areas in Ivc subicles (emoluding accident condition), EAB, DS, MAS rooms 18, 184, 33, 39 and 62, Puol Mandling Building and Control Room (Inaccessible Areas).
- 11) In Euel Esneling Building, radiation exposure of 40 year normal operation and ISO-day post accident are 2.0E03 Rads and 8.0E06 Rads respectively.
i O B C 14926MEQ/STF2
- 4.9 -
. . - - . . . - . . _ . . . . - - - . . . . . . - - ~ _ . . - - .... - - - - . - . . . ~ . ~ . . - - - - .
fi c - ( n, .> Q-
. z .,. >
h, r, -t . y f: F i 1 , i. r . ! I l
- i i' !
i. 4 ). u 4 i I t i i i
; -- APPENDIX A i f, . .
l ' i G ( Definition of symbols & determination of i l Qualf fled Life. Taken From MEQ-1 pages l
- 1. A-1&A-2) !,
j 2 > 1
- I
- j. !
f n I , t 1 ! {' ! 1 l 1 t I
.l f
t'i a
- i 1
\
O 4, f t f
14926-MEQ-1
~! Revision 2 i
APPENDIX A The following are the definitions of some of the headings, abbreviations, and symbols used in this appendix: CWVENTION l FORM APPEARED IN l l APPENDIX "A" l DEFINITION 4
- l l l l ACCEPTABLE r
- l ace opt; ACCEPT l. - -
STATIC + l ISta, S, s l l The part containing the degradable material
. A l l operates on static mechanical clearance l l(non-soving surf aces).
! l l l , DYNAMIC + lDyn, D, d l The part containing the degradable material 3 l l operates on dynamic mechanical clearance l l (moving surfaces). a i I .
--- lUNDER REVIEW; U.R. l The information is still under review and will l l be resolved on the next revision.
;' ._l l 3 :Ifen , l Function
/ ;I
($/
) -- -
. lNMQ #
-l l
l Non-metallic Qualification Data Sheet (shown l in Appendix D).
- l l .
. lQ .L . l Qualified Life x i l I
! l l . A Item No. l Item i l Fictitious number assigned when material l requisition Iten No. not available. l l
- I lSEE ALT l The manuf acturer recommendation asterial is l l not qualified use recommended alternative l l material.
i l l lRef. Document l Ref. document numbers shown in this Appendix A i l(e.g. 01003AFC) l are :for Unit 1 equipment unless otherwise noted.h i l I f x See page A-2
+ Table Heading i
l EQR/MFARD1 A-1 /M\ I i l l
-- - ~ _ _ _ - , _ _ . - _ _ _ , _ _ _ .
14926-MEQ-1 Revicicn 2 y APPENDIX A The qualified life is either a calculated life based on the radiation and temperature capabilities shown on the material data sheet (MDS) or the life extracted frou the reports listed below. -If both are available, the more conservative life is used. The qualified life must be used in conjunction with the specified maintenance / surveillance program identified in equipment manual provided by respective vendor / manufacturer.
~
4026EQ1-00001-DUL 40275Q2-00008-SUP 4028-00073-AHM
~
4029E9-00004-AHA 40305Q1-00001-BUL 40'30EQ-00007-BXD 4031EQ-00001-BAG 4032EQ1-00001-3% 40375Q-00001-AML 4039EQ-00002-3W 4409-00257-CW 4409-00245-AW 4409-00244-BW 4409-00243-AW 4409-00207-CW
- 4409-00206-BW 4409-00204-CW % 4409-00203-C W y 4409-00201-CW 4409-00200-BW 4409-00199-BW
- 4409-00193-CW 4409-00192-AW 6360-00022-3r7
,-m ; .
6380-00019-AED 6381-00024-CJL 6)78-00090-3)A N 6512-00024-CDE 6413-00044-BFR 6452-00002-AOI h
- 6455-00025-BQY 6373-00068-ANY 0387EQ(1)-00001-GUL 0011(1)-00158-CPD 401s-00003-BSC 4022EQ1-00001-B W 4040EQ1-00001-BHY 4053-00016-BRT 40556EQl-00002-BUL 40706EQ1-00001-BUL 4092EQ1-00001-CUL 4099 -00105-BAN 4122RQl-00001-BHX 4129-00116-ANN 4168-00267-3VA 4310-00182-AYD 4315-00110-3I9 _
4318-00035-DJJ 4370-00057-CYN
\
- d. -
EQa/aranD1 A-7.
i y i
,k APPENDIX A (Specific page in Appendix A for Tag Number 3V101VDA222)
SOURCE: MEQ-1
; y kl(4.
s-e I i
_- ~ -- _. -- - _ - + - . . - l SNEET 1 0F f MACNASE INDER 4168/8168 REVISION 1 APPE W IX A . EWIPIENT DAIIPERS ORIGINATOR IWir DATE SIRITN TEMAS P90 JECT MECNANICAL EOUIPMENT G14LIFICATION CNECKED aM DATE se
- 4 i
Re-CGNOIENT DATA MAT'L e mL DATA i *
- Fcn Melntensnce Recommended .
! Tag me. Component Descrfp. Degradalete Port Ste/ Ref. Reptscenent IIstl Guel Guel. Attornettve f Ites No. Ref. Dec. Status Meteriel Romerte l Part & Cat.IIe. IIeterial Dyne Document Respalremente
= -
3V101vDA052 SAFETY EPOM-1 AULB ETNYLENE DYN E 6.L. 15 YRS 1500 #196 E NOTE 1 AIS FOR CUTSIDE l ! 3V10140A113 CLASS SEAL BLADE EDS PROPYLENE ' CNTIself CNLY ! 3V101vDA118 DAMPERS SEAL MCLF7395 DICONJ.MDIsa -~~~~ ~~-~- *~~~~~ ~ ~ - ~ - ~ ~ -
~ ~ ~ ~ ~ ~ - - - ~ ~ ~ ~ ~~ ~ ~ ~ ~ ~ " ~ ~
3V101vDA119 (NYC-42 GUTSIDE IIRITAI NeD-53 VITON 0-RIIIG Flewm STA 4.L. 8 YEARS Islef135 ACCEPT _ 3V101vDA120 ISIENT APPLICAT l 3v101vDA173 Neo 70 & 2116-v00675, (VITON) ~ Iou CNLY
--> 3v101vDA222 Neo 71) 2214 =,2218 "
~ ~ ~ ~ ~ - ~ ~~~~~~ ~~ ~ ~ ~ ~ ~ ~ - ~ ~ ~~-~~ ~-~~- --- ~~ ~~~~~---
l 3v101vpA223 4.L. 5 YEARS Islef106 ACCEPT GlTSIDE CENTAI l 3V102VDA052 EPT 4 LEDGE ETIILYII/PROPY DYN leENT APPLICAT l 3V102VDA113 SEAL W/DRYSCK' LYN /TERPLYIIR IGN ONLY l 3V102WDA118 ADNSV/MCLf7400 CLSD CL SPNG --- - ---~~ ~~~ - --- ~~~ ,
- ~ ~ ~ ~ ~ ~ ~ ~ - -- ~ ~ ~ ~ ~ ~ ~
- 3V102VDA119 GUTSIDE CDJTAI EPON3 BLS W/3M ETIILYII/PROPY DYli 0.L. 5 YEARS 15I00106 ACCEPT '
! 3V102VDA120 *' 180ENT APPLICAT 3V102VDA173 SCTCNGRP 1300 LYN /DI CONJU IGN ONLY 3v102VDA222 ADNSV IICLf7404 GATO IIONOMER
~~~~~~" - ~ ~ ~ ~ -a ~~~~~~~~~ - - - --~~- ~~~~~~ --.---~~
3V102WDA223 '. 3V111vDA075 EPT RECTNGLR ETIILYll/PROPY STA 0.L. 20 YEARS 1s108106 ACCEPT DIIPR TGet USED 3V121/122VDA,
! 3V111vDA076 SPIIG FLIIG GSKT LYN /TRP9LYMR 163,164,165 .
3V111vDA077 RUBATEM R4957 - - - - - ~~-~~~- -e=~~~-
- - - ~ ~ ~ ~- ~~~~~~~~~ - - - -
3v111vDA078 ~ ~ ~ - - - -
- GE RTV 106 SILICON STA
- 4.L. 10 YEARS WIOf132 ACCEPT 3v111vDA215 .
3V111vDA216 SILICONE SEAL 3V111vDA217 COMPCUW - ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ -
---~~~~ - - ~ ~ ~ ~ ~~ ~~~ar~~"~ ~ ~ ~ ~ - ~ra 3V111vDA218 CUTSIDE CONTA-WOOL FELT & DYN NOTE 2 NOTE 2 N01E- 2 3V111vDA219 BALL SEARIIIG IINENT APPLIC-3V111vDA220 ASSEISLY FLIIGR POLYAMIDE ATION' CIILY 3V1119DA224 SilVLoll C04TilIG (NYLOII) - ~ ~ - ~~~~~~ ~ ~ ~ ~ ~ ~
~ - ~ ~ ~ ~ ~ ~ - - ~~ ~~~~~"~~~ ~ ~ ~ -
3v111vDA225 ,
- 3V111vDA226 .
3V111vDA252 3V111vDA253 3V111vDA254 I 3V111vDA261 3V111vDA262 4 3V111vDA263 i . 3V111vDA264
!' 3V111vDA265 l 3V111vDA266
, 3V11190A269 3V11190A275 l 3V111vDA276
! 3v111vDA277 .
3V111vDA286 3V111vDA287 3V111vD4288 3v1119DA289 a l
O . o O i i SHEET 8 0F 8 ] PURCHASE ORDER 4168/8168 REVISIm t EQUIPMENT DAMPERS ORIGINATDR 12M DATE so/ss/pd APPENDIX A DATE is/s/rg S0tfrH TEXAS PROJECT CHECKED M ' l NECHANICAL EQUIPN.NT QUALIFICATIN 1 4 I NOTE:
- 1. Unit 2 tag nos, have not been checked against the latest Unit 2 EQ Hasterfile Listing.
; 2. Sealmaster Relubricable Ball Bearing with Wool' Felt Seal Nylon coated steel ball retainer 90' grease
{ These materials are qualified to outside containment fitting and Shell A1vania No. -2 grease. j application. ' Refer to 4168-00267-BVA P.8 and P.55.
- 3. The EPT-4 janb (wedge) seal was to be replaced by a metallic seal which was unaffected by. the environmental parameters.
Modified dampers are. Model NBD-53, damper tag nos. 3V141VDA-165 through -168 i
'and 3V142VDA-165 through 168 (Refer to 4168-0026.7-BVA, page 370/Section 9.0) i 4
i
- 4. The EPDH-3 would maintain its functionality if mechanically fastened as ;well as adhesively bounded for use inside containment. (Refer to 4168-00267-BVA, page 370/Section 9.0).
i ' STPAPPXA/stpappxa
~
Page 43
\
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\ .
6
. s
't:
5 l O ; APPENDIX A1 LUBRICATION FOR SAFETY RELATED DAMPERS SOURCE : MEQ -1 O e
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0 B I ee .IS ee9 i e' bw E 1 i e n I e e t a e 4 3.a==se == es e 3 en Its GG Ib 6hw Ibb I M h* i ga il as as e as e as 4 ee as == O u I las U es saa 3 .a i ma E BB .e4 eB E E IE
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O O~ PURCHASE ORDER 4168/8168 SHEET 3 0F 3 EQUIPMENT DAMPERS , REVISION : j APPENDIX Al ORIGINATOR , g .s
~
DATE re/A ff4; i S0tHH TEXAS PR(kiECT CHECKED uc DATE u /Up MECHANICAL EQUIP)ENT QUALIFICATI(M
* * ~"
( "
i 1
- - - NOTE
- 1. Reference 828 provides Culf 011 Co.'s recommendations of alternative Gulf lubricant replacements, if
- any. The original equipment manufacturer has yet to approve or disapprove the Gulf alternatives, i
l i i i 1 i l : i l i t l 1 i i l APPENDA1/ Disk C l
7 E L v
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![ APPENDIX C e '%
(Specific pages in the Non-Metallic Qualification for material identified in the equipment) SOURCE: MEQ-1
l l STP NMQ # 22 SHEET 1 of 1 REVISION t ( ORIG . M DATE fc/3 t /3 e CHKD. ga DATE n /if p,6 APPENDIX C "- SOUTH TEXAS PROJECT MECHANICAL EQUIPMENT QUALIFICATION PROGRAM NON-METALLIC MATERIAL QUALIFICATION MATERIAL: MOLYKOTE M-#41 GREASE FROM DOW CORNING , MATERIAL DATA SHEET: MDS - 22 ASSOCIATED P.O.: 4034/8034;4168/8168 SYSTEM MEDIA: Air , QUALIFICATION: LUBRICANT OF BALL BEARINGS OF BACKDRAFT DAMPERS ACTUATORS INSIDE THE CONTAINMENT. THE QUALIFICATION PARAMETERS ARE SUMMARIZED BELOW. l ENVELOPING l MATERIAL l PARAMETERS l ENVIRONMENTAL l CAPABILITIES / l REMARKS l' CONDITION l QUALIFICATIONS l TEMPERATURE (F) l NORMAL: 29 - 120 l -31 TO 550F l , l ACCIDENT PROFILE: l l l 170,1.0 sec l l l 323,10 - 200 see l l l 280, 500 - 5000 secl l l 170,1 day l l l 140,1 - 11 days l l l 120,11 - 30 days l l l l l l PROCESS: l l l AMBIENT ENVIRONMENT l l ' OPERABILITY TIME l 30 days l l l l l 2.0E07 l 5.0E08 RADIATION (RADS) l NORMAL: l l l l 4 l ACCIIENT: 2.3E07 l l l l l l INTERNAL: l lSAME AS THE AMBIENT l l l ENVIRONMENT __l______- _l____________ l _______ MAINTENANCE REPLACEMENT RECOMMENDATIONS: FOLLOW THE ORIGINAL EQUIPMENT MANUFACTURER'S REPLACEMENT RECOMMENDATIONS AS STATED IN APPENDIX A1. CONCLUSIONS: The radiation damage threshold far exceeds the requirements, and is not considered radiation sensitive for the specified enviroment. Since the thermal capability also far exceeds the requirement, the lubricant is not considered temperature sensitive for the specified O environment. For P.O. 4034/8034, lubricant is used in reassembly only, and does not perform any safety function. Therefore, this lubricant is qualified for this plant specific application. DOC /appndxC1/32
. . -- - . - .. - _- - =. - .
STP NMQ f 47 SHEET 1 of 2 REVISION [ N ORIC . M t DATE es/Afff, CHKD. we DATE n f , f, 4
-- gs av APPENDIX C SOUTH TEXAS PROJECT MECHANICAL EQUIPMENT QUALIFICATION PROGRAM NON-METALLIC MATERIAL QUALIFICATIN ,
l
; MATERIAL: CULFCROWN GREASE FROM CULF OIL CO.
1 MATERIAL DATA SHEET: MD S - 47 ASSOCIATED , P.O.: 4000/8000;4027/8027;4029/8029;4038i8038;4041/8041;4092/8092;4122/8122; , 4 4168/8168;4315/8315;4409/8409 SYSTEM MEDIA: Air QUALIFICATIm: LUBRICANT USED ON BEARINGS. THE QUALIFICATION PARAMETERS ARE SUMMARIZED BELOW. I ENVELOPING l MATERIAL l PARAMETERS l ENVIRONMENTAL l CAPABILITIES / l REMARKS
! l CONDITION l QUALIFICATIONS l r -
__ _l__ , _l___ _l __ TEMPERATURE (F) l NORMAL: 29 - 135 l 10 TO 250F l l ACCIENT PROFILE: l l i 2irG, 0 'i sec l l l 335, 20-400 sec l 379 DROPPING PT.lSEE REFERENCE 246, 4 l 324, 400 sec-0.5hrl l ACCEPTABLE l 203, I hr-7 days l l 2 l 104, 7-30 days l l 4 l l l l PROCESS: 200F l l(SEE NOTE) l l l
- OPERABILITY TIME l 30 days l l l l l RADIATI M (RADS) l NORMAL
- 2.0E07 l 2.0E08 RADS l l l l' l ACCIDENT: '2.3E07 l l l l l l INTERNAL: l lNOT IN CONTACT WITH l l lTHE PROCESS FLUID l l l(REF. 198)
_l . _l______ _l____ ___ _ _ MAINTENANCE REPLACEMENT j RECOMMENDATIONS: FOLLOW THE ORIGINAL EQUIPMENT MANUFACTURER'S REPLACEMENT RECOMMENDATIONS AS STATED IN APPENDIX A1. I i CONCLUSIONS: The radiation damage threshold far exceeds the requirements, and < is not considered radiation sensitive for the specified environment. Since the thermal capability also far exceeds the requireme nt , the lubricant is not considered temperature sensitive for the specified environment. The re fore, this lubricant is qualified for this plant specific application. 2/appC1/5
STP NMQ # 47 SHEET 2 of 2 NUIES: Based on the above P.O.'s, the process temperature that the lubricant for the Limitorque Valve operator will be exposed to are: 200*F per 4041/8041,120*F per the "RA" system of 4029/8029,135*F per 4032/8032 (See telecon E003034, Ref.165) & 130*F per 4038/8038. There fore, the maximum process temperature the lubricant will experience is 200*F. 4 (O 2/appC1/6
STP NHQ # 53 4- SHEET 1 of 1 ( REVISION ORIC. i G CHKD. M Mr DATE ,s/A/f;, DATE tl,h /Mr APPENDIX C SOLTTH TEXAS PROJECT MECHANICAL EQUIPENT QUALIFICATION PROGRAM NON- E TALLIC MATERIAL QUALIFICATI N MATERIAL: CULFEARMONT #68 FROM CULF OIL CO. I MATERIAL 1%TA SHEET: MDS - 53
- ASSOCIATED P.O. : 0011(1) & .
i .. C011( 2 ); 4000 /8000; 4014 /8014 ; 4040 /8040 ; 4041/8041 ; 4053 /8053 ; 4168 /8168 SYSTEM MEDIA: Air QUALIFICATIW: LUBRICANT USED ON THE DAMPER BEARINGS & LINKAGE PIVOTS, AC CENERATOR BEARINGS AND THE MOTOR BEARINGS OF THE ECW PUMPS. Tite QUALIFICATIW PARAMETERS ARE SUMMARIZED BELOW. l ENVELOPING l MATERIAL l PARAETERS l ENVIRONMENTAL l CAPABILITIES / l REMARKS i l . CONDITION l QUALIFICATIONS l ____l___ l-
- l TEMPERATURE (F) l NORMAL: 29 - 135 l 40 TO 130F l l ACCIIENT PROFILE: l l 4 l 290, 0.5 sec l l l 335, 20-400 sec l l l 324, 400'see-0.5hr l l ACCEPTABLE FOR TRANSI-l 203, I hr-7 days l lENT TEMPERATURE NOT TO l 104, 7-30 days l 450F FLASH PT. l EXCEED 85% OF FLASH i' '
l l lPT. (REF. 246) l PROCESS: 200F l l l l l OPERABILITY TIME l 30 days l l l 1 l RADIATION (RADS) l NORMAL: 2.0E07 l 1.0E08 RADS l l l l l ACCIDENT: 2.3E07 l l
, I l l l INTERNAL: l lSAME AS THE AMBIENT i l l l ENVIRONMENT.
___l_____ _l____ l____ ____ _ i NAINTENANCE i REPLACEMENT RECOMMENDATIONS: FOLLOW THE ORIGINAL EQUIPMENT MANUFACTURER'S REPLACEMENT RECOMMENDATIONS AS STATED IN APPENDIX A1. CONCLUSIONS: The radiation damage threshold far exceeds the requirements, I and is not considered radiation sensitive for the specified I environment . Since the thermal capability also far exceeds the I requirement, the lubricant is not considered temperature : sensitive for the specified environment. Therefore, this l lubricant is qualified for this plant specific application. 1 2 /aneC1/13
. _ ... _ _ _ . _ _ _ . . _ . _ . ~ . _ . . . _ . . _ _ _ _ . - . _ _ _ _ . _ _ _ _ _ _ _ _ _ _
- __-._ -.. . .. -- -. - _..- - - _ - _ _ _ _ . ~ _
STP NMQ # ~53E SHEET 1 of 1 h,. REVISION I ORIG . m- DATE f. /5f /G.- CHKD. g.t c DATE ft /2 /A c
* ~
APPENDIX C SOUTH TEXAS PROJET MECHANICAL EQUIPENT QUALIFICATION PROGRAM NON-METALLIC MATERIAL QUALIFICATION l 1 MATERIAL: GULF HIGH TEMPERATURE GREASE FROM GULF OIL CO. , MATERIAL DATA SHEET: MDS-53E ASSOCIATED P.O.: 0011(1) & (2);4000/8000;4027/8027;4034/8034;4041/8041;4168/8168 SYSTEM MEDIA: Air . QUALIFICATIW: LUBRICANT IS USED AS TE ALTERNATIVE LUBRICANT FOR THE BOTTOM BLOCK SHEAVE BEARINGS AND UPPER SHEAVE BEARINGS OF THE EQUALIZER FOR THE EQUIPMENT HATCH. ALSO USED AS THE i ALTERNATIVE LUBRICANT IN THE INTERNAL PARTS OF THE MECHANICAL
& INTERLOCK SYSTEM OF THE AUKILIARY AIR LOCK. THE QUALIFICAT7.ON PARAMETERS ARE SUMMARIZED BELOW..
4 l ENVELOPING l MATERIAL l l PARAMETERS l ENVIRONENTAL l CAPA3ILITIES/ I REMARKS l l . CW DITIM l QUALIFICATIONS l l
-l -l l-TEMPERATURE (F) l NORMAL: 29 - 135 1 0 TO 325F l l l ACCIDENT PROFILE: l l l 290, 0.5 see l I i l 335, 20-400 see l l l 324, 400sec-0.5hr l l l 203, I hr-7 days l l . l 104, 7-30 days 1568F DROPPING lSEE REFERENCE 246, I
l l POINT l ACCEPTABLE I PROCESS: AMBIENT l l l; l ENVIRONMENT l l OPERABILIIY TIME l 30 days I l l l 1 RADIATION (PADS) l NORMAL: 2.OE07 l 1.0E08 RADS l 1 I l i l ACCIDENT: 2.3E07 l l l l 1
- l INTERNAL
- l lNOT IN CONTACT WITH ITHE PROCESS FLUID 7
l l l l l(REF. 198) _l _l___ _l__ _____ MAINTENANCE REPLACEENT RECOMMENDATIONS: FOLLOW THE ORIGINAL EQUIPENT MANUFA0TURER'S REPLACEMENT ! RECOMENDATIONS AS STATED IN APPENDIX A1. f CONCLUSIONS: The radiation damage threshold far exceeds the requirements, and is not considered radiation sensitive for the specified l l environment. Since the thermal capability also far exceeds the l requirement, the lubricant is not considered temperature nment. th s sensitive lubricant for is the specified qualified for gvirgant t sp specgraforgcat{on. c app 2/appC1/18
APPENDIX C STP NMJ l 72 1 OF 1 l SHEET PEVISION l
/
ORIG. W DATE re /3, /f5 CHKD. MF DATE e r h /g
'"g S0lTIH TEXAS PR(MECT MECHANICAL DJUIPMENT QUALIFICATION PROGRAM NON-METALLIC MATERIE QUALIFICATION MATERIE: EVANIA 92 GREASE FROM MTL MATERIE DATA SHEEI: MDS - 72 i
ASSOCIATED P.O. 4014/8014:4119/8119:4168/8168 SYSIEM EDIA: Air QUALIFICATION: ISBRICANI USED IN THE DAMPER BEARINGS fi MOIOR BEARINGS. THE QUALIFICATION PARAMElTERS ARE SUMMARIZED BEIDW. MATERIE I l l ENVEIDPING l PARAMETIERS l ENVIRONMENTAL l CAPABILITIES / l REMARKS l CONDITION I QUALIFICATIONS l 1 1 I TEMPERATURE (F) l NORMAL: 65 - 120 l-30 TO 275F l f' l ACCIDENI PROFILE: l l l 323, 10 - 100 sec I l l 280, 500 - 5000 sect I i 185, 1 day I i 1 75, 11 days l lSEE REFERENCE 246, i 120, 30 days l365F DROPPING POINrlACCEPTABLE I I 1 l PROCESS: 165F l l OPERABILITY TIE l 30 Days l l 1 1 I RADIATION (RADS) i NORMAL: 3.5E04 l 2.0E08 Rads [ l l I I ACCIDENT: 2.3E07 l l 1 1 I l INTERNAL: l lSAME AS THE AMBIENE I I IENVIRONMENT I I l MAINTENANCE REPLACEMENI RECOMENDATIONS: FOLIDW THE OtIGINAL EQUIPMENT MANUFACIURER'S REPLACEMENT RECOMMENDATIONS AS STATED IN a@PENDIX A1. CONCLUSIONS: The radiation danage threshold far exceeds the requirements, and is not considered radiation sensitive for the specified environment. Since the thermal capability also far exceeds the c requirement, the lubricant is not cocsidered tenperature sensitive for the specified environment. Therefora, this lubricant is qualified for this plant specific application. The item has been deleted from P.O. 4119/8119 since the centrifugal fans do not exist at SIP. 1380r/Page 18
, . , , _ _ , . , _ . . - _ , _ _ _ , - - - - - -, , , , , _ _ , , - - ,,,,-n_ . , - _, - , , , , . ,
i APPENDIX C ; STP NMQ 0106 SHEET 4 OF 13 ! REVISION
-{ O. ORIG. w7 DATE t o -):-M CHKD.
2 MP DATE (t-t- M l SOUTH TEXAS PROJECT l MECHANICAL EQUIPMENT gJALIFICATION PROGRAM i NON-METALLIC MATERIAL QUALIFICATION MATERIAL. EPT/EPDM , MATERIAL DATA SHEET: MDS #106 ASSOCIATED P.O.. 4168 (Outside RCB) . QUALIFICATION: EPDM is used as blade seal material (Mechanically fastened). l ENVEIOPING l MATERIAL l l ENVIRONMENTAL l CAPABILITIES / l CONDITION l QUALIFICATIONS l REMARKS PARAMETERS l _ l TEMPERATURE (F) l HORMAL: 120 (Max), Aging Test l l 584 Ers at 203 F l l ACCIDENT: 120 Max l (95'C) l !O ( l~ l PROCESS: N/A i l l l l l l l 30 Days l lHVAC Damper Data 1 OPERABILITY TIME 2 l l l Sheet (Dwg. No. l NORMAL: 1 0E03 l 3.54E06 l3V289V24010) s Wyle RADIATION (RADS) 3 l l l Test Report No. l ACCIDENT.1 7506 l l$47531-1) l l 1 l INTERNAL 3.96E04 l l QUALIFIED LIFE 5 years at 120*F fer wedge seal (EPT) with dryback adhesive. 20 years at 120-F for flange gasket (EPT) used on damper tag Nos. 3V121/122VDA163 164, & 165 only. (Ref. 4168-00267BVA). % 5 years at 120*F for bulb seal (EPDM) with 3M scotchgrip 1300 { adhesive. 15 years at 120*F for bulb seal (blade edge seal). l CONCLUSIONS Acceptable. l 1 l NtQMF2/APPC2/18 l Oi l l l
APPENDIX C STP NMQ # 132 SHEET 2 0F 5 O REVISION ORIC. Np CHKD. g DATE n-i.pg 1 DATE /o- 11-Es 1 SOUTH TEXAS PROJECT MECHANICAL EQUIPMENT QUALIFICATION PROGRAM l NON-METALLIC MATERIAL QUALIFICATION l MATERIAL: CE RTV-106 SILICONE SEALANT MATERIAL DATA SHEET: M)S #132 ASSOCIATED P .O. : 4168 QUALIFICATION: SILICONE IS USED AS SEALING COMPOUND FOR BOTH INSIDE AND OUTSIDE CONTAINMENT APPLICATION. l ENVELOPING l MATERIAL l l ENVIRONMENTAL l CAPABILITIES / l PARAMETERS l CONDITION l QUALIFICATIONS l REMARKS
- I l I TEMPERATURE (F)' l NORMAL
- 120 (Max) l AGING TEST l l l 584 HRS 9 203*F l l ACCIIENT: 323(Max)l (95'C) l
!- l l l l PROCESS: N/A l l O, OPERABILITY TIME l l 30 DAYS l l l l l l -l RADIATION (RADS) l NORMAL: 3.5E04 l lREF. WLE TEST REPORT l l lNO. 47531-1. l ACCIDENT: 2.3E07 l 1.54E08 l(4168-00267-BVA, l l lP.90) l INTERNAL: 3.96E04 l l I l l QUALIFIED LIFE: 10 YEARS (REF. 4168-00267-BVA) wiF--- CONCLUSIONS: ACCEPTABLE l 4 NQ121140/NQ121t140 lO _.______j
. . . . _ ___ ___.. ,.. . .. m.. . - _ . . _ . _ _ - __ _ _ _ _ _ _ _ . _ . . . _ _ . _ _ _ _ _ , ___ . _. -
4 APPENDIX C STP NMQ f 135 4 SHEET 2 OF 7 O REVISION ORI G. N# CHKD. wr 7 DATE /o-3/-pf DATE ,, - d f_n SOUTH TEXAS PROJECT MECHANICAL EQUIPMENT QUALIFICATION PROGRAM NON-METALLIC MATERIAL QUALIFICATION MATERIAL: VITON MATERIAL DATA SHEET: MDS #135 ASSOCIATED P.O.: 4168 QUALIFICATIW: VITON IS USED AS 0-RING MATERIAL FOR OUTSIDE CONTAINMENT APPLICATION.
. l ENVELOPING l MATERIAL l
. l ENVIRONMENTAL l CAPABILITIES / l PARAMETERS l CONDITION I QUALIFICATIONS l REMARKS s i I I TEMPERATURE (F) l NORMAL: 29-120 l 400 l l l l l ACCIDENT: 120 l l l l l
, l PROCESS: N/A l l j ' ' ' OPERABILITY TIME 30 DAYS (O.' l l l I I I
- RADIATION (RADS) INORMAL: 1.0E03 l 8.75E06 l
! l l(Max. for dynamic l l ACCIDENT: 1.7E06 l application) l I I I IINTERNAL: 3.96E04 l l
- l l I j QUALIFIED LIFE: 8 YEARS AT 120*F (REF.14926-4168-00267-BVA). --
l, CONCLUSIONS: ACCEPTABLE i I I lO r
=,w ayw -ww,w,-r,,-m,+m--, rip-eyw-w-- ww,- - . , _ ,- - + - w-w y,--g,m .w,yyg,ywy,,9-*p ,y,--ww. , w-w w-m-e+---N.ewww m9mp.-
y -. i:. fv 0-1- -:.
^
I i i f + i
- t i !
i ! I i r i I i-h :'
- APPENDIX B i f, i 4- !
t ! (Specific pages in Appendix B that address the threshold level of the ! { material under investigation in the component ) i' i - je Y. i
! 6 1
i + j SOURCE: - MEQ-1 ; i .i a 1 1
)
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)
l i L..-._---.
APPENDIX B HATERIAL DATA SHEET b' MDS f 22 Page 1 of 2 U MATERIAL. MOLYKOTE fM-41 GREASE Revision 1 GRADE, CLASS: VISCOSITY 4 MANUFACTURER (S). DOW CORNING SHELF LIFE: 18 MONTHS
REFERENCE:
58 e TEMPERATURE RESISTANCE. MEDIUM: OPERATING RANCE. -31 TO 550'F (USEFUL REFERENCE. 58 P.32 - RANGE) TRANSIENTa REFERENCE. TEMPERATURE LEVEL FOR NO DETERIORATION. (a) i THRESHOLD FOR NOTED DETERIORATION. (b) (c) J (d) REFERENCES. (a) (b) 58 P.32 (c) (d) ARRHENIUS CONSTANTe BASIS.
- REFERENCE; RADIATION RESISTANCE:
RADIATION LEVEL FOR SLIGHT DETERIORATION CAMMA. (a) (b) THRESHOLD FOR NOTED DETERIORATION (c) 500 MRADS (d) MDS21t40/ Memo 32 Page 3 ) T
--, . , . - - . - , _ ,_e,_, _ . _ - , . _ - - . , , p , , , - - _ , , . ,,-___...._,,%.., . , - . , _ - - . - . _ , , _ _ . - - _ _ , - ..-...e
APPENDIX B MATERIAL DATA SHEET (cont'd) MDS # 22 {s - Page 2 of 2 (e) Revision 1 (f) , (g) ., (h) (d) *
REFERENCE:
(a) (b) (c) 58 P.32 (e) (f) (g) (h) l DOSE RATE EFFECTS:
REFERENCE:
f SYNERGISTIC EFFECTS. REFERENCE. MEDIA LIMITATIONS:
REFERENCE:
NOTES. MOLYKOTEM-f4kGREASEISACARBONBLACK-GELLEDMETHYLPHENYLSILICONEAS INDICATED IN 1115. ITS RADIATION DOSAGE FOR SLIGHT DETERIORATION IS ESTIMATED To BE 5E07 RADS AND A MAXIMUM RECOMMENDED DOSAGE OF 2E08 RADS (REFERENCE 240). I lC i i MDS21t40/ Memo 32 Page 4
- - _ _ _ _ _ _ _ _ _ . - . . , _ , - . _ , _ _ . _ _ _ _ _ - - _ _ _ _ _ _ _ . _ _ . _ _ _ _ _ _ _ _ _ _ _ . . _ _ _ _ _ _ - . _ _ - _ _ ~_. __ _
APPFFDIX R MATERIAL DATA SHEET MDS # 47 Page hadidon 1 MATERIAL: Gn.FCROWN GREASE . CPADE, CLASS: N1.CI #2 VISCOSITY: MANUFACTURER (S): GULF OIL CO SHELF LIFE: RE}TREfrE: TEMPERATURE PESISTANCE: MEDIUM: OPERATING RAtEE: 10 TO 250F
REFERENCE:
82
- TRANSIEhT: 379 DROPPING POINT
REFERENCE:
82 e TEMPERATURE LEVEL FOR NO DETERIORATION (a) THRESHOLD FOR NOTED DETLRIO8tATION: ( b) (c) (d)
REFERENCES:
(a) ( b) (c) (d) ARRHENIUS CONSTAhT: 1 BASIS: REFEPEECE: RADIATION RESISTATCE: . PADI ATION LEVF.L FOR SLIGHT DETERIORATION CAMMA (a) RESISTANT UP TO 100 MRADS. (b) UP TO 500 MRADS. THE 'GPTASE FH01.T.D LITTLE OR NO CHANGE IN OIL SEPAPATION.
'INRESHOLD FOR NOTED DETERIOPATION (c)- AT 100 MRADS THE GPEASE CHAhT:ED FROM LIGHT AMBEE TO RED AND B\RK AMPER, AND A PRONOUNCED BURNING ODOR WAS PRESEhT.
(' (d) A DRAR\ TIC DECPEASE IN DROPPING POINT TOTFF.\TUFE WAS NOTED AT 250 MRADS. f BIS 41t o60/MEM033 Panc 13
----s . _ _ , _ _ _
. (')
MATERIAL DATA SHEET (cont'd) APPENDIX B MDS # 47 Page 2Refifion 1 o (e) THE WORKED PENETRATION OF THE GREASE WAS SERIOUSLY DECFADED AT 200 HRADS. (MAXIlfUM RECOMMENDED - SEE NOTE) ( f) THE GREASE BECAME MORE ACID AS RADIATION INCPIAFED WITH SEVERE ACIDITY OCCURRING AT ABOUT 200 MRADS. (g) (h) RETIRENCE: (a) 101 p. 30 (b) 101 p. 31 (c) 101 p. 30 (d) 101 p. 31 (e) 101 p. 31 ( f) 101 p. 31 (g) (h) DOSE RATE EFFECTS:
REFERENCE:
( RYNERGISTIC EFFECTS: REFEPINCE: MEDI A LIMITATIONS: REFEPENCE: NOTES: THE FOLLOWING IWTA ARE FROM REFERENCE 101: DOSE DROPPINC POINT WORKED PEhTTRATION SE07 U nehanged +107 IE08 -27 -8? 2E08 -2% -23' MDS41t o60/MEM033 l Par.c 14 J
.~. - - . . . , , - . , - . _ - . , , . . _ - - , - , . -- - _ _ . . _ . . , , , . .. - - - . . _ _ . , . . _ , - - . , , _ , - . . _ - - , . , . . . _ . . - - , -
APPENDIX B MATERIAL DATA SHEET MDS # 53 Page IRefition 1 MATEPIAL: CtLFNARMONY #68 - GRADE , CLASS: AGm #2 VISCOSITY: 323 SSUGIOOF MNUFACTURER(S): CULF OIL C0 SHELF LIFE:
REFERENCE:
TEMPERATURE RESISTANCE: MEDIUM: OPEPATI!C RANCE: 40 TO 130F REFEPINCE: 82
- i TRANSIENT: 450F FLASH POINT
REFERENCE:
82 % TEMPERATURE LEVEL FOR NO DETERIORATION (a) THRESHOLD FOR NOTED DETERIORATION: ( b) o .
REFERENCES:
(a) ( b) (c) (d) ! ARPHENIUS CONSTAhT: BASIS:
- REFTPINCE:
RADIATION RES2.CANCE: . RADI ATICN LEVEL FOP SLICHT DETERIOPATION GAMMA (a) RESISTANT UP TO 10 MRADS (SEE NOTE). (b) THRESIOLD FOR NCrrED DETERIORATION (c) AT THE 10 MRAD LEVEL SOPE DETERIORATION OF RCST PROTECTION IS SEEN AS A 307 REDUCTION IN OXIDATION STABILITY. O (d) AT THE 50 MRAD LFV!L, FURTHER DETERIOPATION OF RUST AND OXIDATION PROPERTIES CONTINUES. NO OTi!ER ADVERSE RESILTS ARE NOTED. MDS41t o60/W.M033 Page 25
APPENDIX B (pg MATERIAL DATA SHEET (cont'd) MDS f 53
\j Page 2 of 2 Revision 1 (e) AT THE 100 MRAD LEVEL,NO RUST PROIECTION RESINS AND THE REMAINING OX1DAT10N INHIBITOR HAS REEN REDUCED TO 52%. (MAXIMUM RECOMMENDED - SEE NOTE)
(f) AT THE 200 MRAD LEVEL, OX1DATION STABILITY IS ESSENTIALLY THAT OF AN UNINHIBITED OIL. ANALYSIS SHOWED ONLY 15% OF THE OX1DAT10N INHIBITOR REMAINS. (g) (h) ,
REFERENCE:
(a) 101 p.5 (b) (c) 101 F.5 (d) 101 P.5 (e) 101 p 5 (f) 101 p.5 (g) (h) DOSE RATE EFFECTS.
REFERENCE:
SYNERGISTIC EFFECTS. REFERENCE. MEDIA LIMITATIONS.
REFERENCE:
NOTES. THE RADIATION RESULTS ARE BASED ON GULFHARMONY f 68 BEING SIMILAR TO GULFHARMONY #78EP AS A HARMONY CLASS OIL PER REFERENCE 82. GULFHARMONY #68 IS EXPECTED TO REACT AND HAVE THE SAME RADIATION TENDENCIES AS GULFHARMONY (REF. 82 TELECON). DATA PERTINENT TO HARMONY #68 BUT FOR GULF HARMONY 78EP ARE FROM REFERENCE 101. DOSE VISCOSITY W 100*F 3E07 +2% SEU7 +7% IE08 +15% 2E08 +32% t O MDS41to60/ MEMO 33 Fage 26 1
I APPE!:DIF. B MATERI AL DATA SHEET l I~3 PDS
- 53F Page I of 2 Revision 1 MATERI AL: CULT HIGH TEMPERATURE CREASE GRADE, CLASS: NLCI #I VISCOSITY: 600 SLtV 6 100F MANUFACTURER (S): CULF OIL CO SHELF LIFE:
REFERENCE:
TEMPEPATURE RESISTANCE: MEDIUM: OPER$ TING FANGE: O TO 325F
REFERENCE:
82A (TEL) * ** TRANSIEhT: 568 DROPPING POINT
REFERENCE:
82A TEMPERATURE LEVEL FOR NO DETERIOPATION (a) THRESHOLD FOR NOTED DETERIORATION: (b) (c) ilV(f(7 (d)
REFERENCES:
(a) (b) (c) (d) ARRHENIUS CONSTANT: BASIS: PEFERENCE: RADIATION RESISTANCE: RADIATICK LEVEL FOR SLIGHT DETERIORATION CAMMA (a) (b) THRESHOLD FOR NOTED DETFRIOPATION (c) 50 MRADS I4% INCREASE IN DROPPING PolhT 15% INCPEASE IN PENETRATION 6 4 9 Pane 35
- - - --- -ww, , , - , , . - , . . , - - ,n,-.c,,,,- ,-,. - - - - - , . _ , . _ , - - , - - , , - - - - - - - - - , , , , , - - . . , - . , ,
APPENDIX B MATERIAL DATA SHEET (cont'd) MDS # 53E ReBaston of 2 (d) 100 MRADS 11% INCREASE IN DROPPING POINT 18% INCREASE IN PENETRATION (MAXIMUM RECOMMENDED) (e) ; (f) ( g) (h)
REFERENCE:
(a) (b) (c) 101 p.32 (d) 101 p.32 (e) (f) (g) (h) DOSE RATE EFFECIS:
REFERENCE:
SYNERGISTIC EFFECTS:
REFERENCE:
MEDIA LIMITATIONS:
REFERENCE:
NOTES: CULF HICH TEMPERATURE IS A CALCIUM COMPLEX SOAP THICKEhTD CREASE IN MINERAL OIL (REF 82A). THE FOLLOWING DATA APE FROM REFERENCE 101: DOSE DROPPING POINT WORKED PENETRATI(N
~
5E07 +14% +15% IE08 +11% +157.
-32 +4 27, 2E08 C
HnS41t60/MENO33
, @ Page 36
i APPENDIX B
/ MATERIAL DATA SHEET MDS # 72 i[' Page 1 of 2 ALVANIA #2 GREASE !
MATERIAL Revision 1 l GRADE, CLASS: NLG1 #2 VISCOSITY: 515 SUS 9100F
- l MANUFACTURER (S). SHELL ,
i SHELF LIFE: 18 MONTHS
REFERENCE:
90 ' i TEMPERATURE RESISTANCE. MEDIUM: OPERATING RANGE. -30 to 275F (SEE NOTE 2) REFERENCE; 90 h TRANSIENT: 365F DROPPING POINT
REFERENCE:
90 2 TEMPERATURE LEVEL FOR NO DETERIORATION: (a) THRESHOLD FOR NOTED DETERIORATION: (b) (c)
*(d)
REFERENCES:
(a) (b) (c) (d) ARRHENIUS CONSTANT: BASIS.
REFERENCE:
4 RADIATION RESISTANCE. ~ RADIATION LEVEL FOR SLIGHT DETERIORATION GAMMA. (a) 1E07 RADS (SEE NOTE 3) (b) THRESHOLD FOR NOTED DETERIORATION (c) 2E08 RADS (MAXIMUM RECOMMENDED - BASED ON DATA FROM A SIMILAR GREASE, GULFCROWN). i (d) SHELL TESTED ALVANIA #2 GREASES SHOWING A 20% SOFTEN 1t.G AFTER RADIATION EXPOSURE AT 4.75E08 ROENTCENS (4.1EUB RADS) IN STATIC IESTS. MnS61tsu/M31 Page 25 l
APPENDIX B MATERIAL DATA SHEET (cont'd) MDS # 72 Page 2 of 2 (*) Revision 1 (f) (g) (h)
REFERENCE:
(a) 101 (b) (c) 101 (d) 90 4 (e) (f) (g) (h) DOSE RATE EFFECTS:
REFERENCE:
SYNERGISTIC EFFECTS.
REFERENCE:
MEDIA LIMITATIONS:
REFERENCE:
NOTES: 1.) REFERENCE 90 INDICATES THAT ALVANIA GREASES ARE MINERAL OIL THICKENED WITH A LITHIUM 12 HYDROXYSTEARATE SOAP. THESE GREASES ARE INHIBITED WITH ADDITIVES FOR LONG SERVICE CONDITIONS. SHELL PERFOR.E D TESTS ON ALVANIA #2 TO 4.8E08 ROENTGENS.
- 2) THE OPERATING TEMPERATURE IS STATED AS A FUNCTION SF THE BEARING SPEED FACTOR (REFERENCE 90).
- 3) DATA PERTINE!E TO ALVANIA GREASES, BOT FOR GULFCROWN CREASE ARE FROM REFERENCE 101.
DOSE DROPPING POINT WORKED PENETRATION 5E07 Unchanged +10% IE08 -2% -8% 2E08 Unchanged -23% l I 4E08 -21% -5% l l O MDS61tBU/H31 Page 26
~
a
- APPENDIX B MATERIAL DATA SHEET MDS # 106,Rev. I
)~ Page 1 of 2 MATERIAL: EDIYLENE PROPYLENE ELASTOMERS GRADE, CLASS: EPR(EPM *), EPT(EPDM*) VISCOSITY:
- ASTM Designation MANUFACTURER (S):
SHELF LIFE:
REFERENCE:
TEMPERATURE RESISTANCE: MEDIUM:
/ OPERATING RANGE: 90*C (194*F)
REFERENCE:
.176/ Table 4-87/ 4
? P.4-200 TRANSIENT: 350*F
REFERENCE:
177/P.272 e
- t
- TEMPERATURE LEVEL FOR NO DETERIORATION (a)
THRESHOLD FOR NOTED DETERIORATION: (b) (e) (d)"
REFERENCES:
(a) (b) (c) (d) ARRHENIUS CONSTANT: In (Life) = 15524.1267(1/T)-29.8774 (EPR)' In (Life) = 17024.15987(1/T)-36.76409 (EPDM) t BASIS:
REFERENCE:
172/P.7.i' and P.27 N RADIATION RESISTANCE: , RADIATION LEVEL FOR NO DETERIORATION , GAMMA (a) 1.0E06 Rads (Compression set) (b) THRESHOLD FOR NOTED DETERIORATION
.(c) 1.0E07 Rads: No dynamic seals be used af ter radiation doses greater than 1.0E07 Ands.
(d) 2.0E07 Rads: EPDM 50% compression set (e) 4.6587E07 Rads: EPDM 70% compression set ( f) 5.0E07 Rads: EPRo -59% elongation
, EPDM: -52% elongation i (g) 8.0E07 Rads: EPR: mild to, moderate damage, utility is often satisfactory.
(h) 1.0E08 Rads: EPR.k-10% tensile strength EPDM: -21% tensile strength Other than dynamic sea 2, EPA & EPDM are considered qualified for 4.6587E07 O Rads. STPtDSNL/ >O SNOLUB Page 11
-i
,fg APPENDIX B MATERIAL DATA SHEET (cont'd)
O MDS # 106,Rev.t Page 2 of 2 REFERENCE (a)172/P.21 & P.27 (b) (c) 10/P.3-24 (d)0387EQ(1)- h 10/P .3-24 00001-GUL/P.43 (e)0387EQ(1)-00001-GUL/P.43 ( f)10/P.3-24 (g) 172/P.11 e (h)10/P 3-24 DOSE RATE EFFECTS:
REFERENCE:
SYNERGISTIC EFFECTS:
REFERENCE:
MEDIA LIMITATIONS:
REFERENCE:
NOTES: O I O STPHDSNL/HDSNOLUB Page 12
APPENDIX B MATERIAL DATA SHEET C) MDS f 132, Rev. I Page 1 of 2 MATERIAL: SILICONE RUBBER GRADE, CLASS: VISCOSITY: MANUFACTURER (S): SHELF LIFE:
REFERENCE:
TEMPERATURE RESISTANCE: MEDIUM OPERATING RANGE: 500*F
REFERENCE:
208/P.436
~
TRANSIENT: 600*F
REFERENCE:
208/P.436 TEMPERATURE LEVEL FOR NO DETERIORATION (a) THRESHOLD POR NOTED DETERIORATION: (b) (c) (d) (b) (c) (d) (
REFERENCES:
(a) ARRHENIUS CONSTANT: In(life) = 11541 (1/T)-21.9 BASIS:
REFERENCE:
4390-00067-CYv/ Appendix B RADIATION RESISTANCE: RADIATION LEVEL FOR NO DETERIORATION CAMMA (a) 7.0E06 Rads (Tensile strength) (b) THRESHOLD FOR NOTED DETERIORATION
,( c) 7.0E07 rads (-50% tensile strength)
(d) 1.0E07 rads (-31.4% compression set) , (e) No visible degradation was noted af ter 1.54E08 rads ex po su r2. l (f) Demonstrated that silicone rubber 0-ring seal performed its function af ter 1.0E09 rads exposure l I M121to140 Page 23 1 -___. . _ - - - -..
APPENDIX B HATERIAL MTA SHEET O MDS # 132, Rev. I l Page 2 of 2 l (3) l (h) ILEFERENCE:(a)178/P.B-173 (b) (c)178/P.B-173 (d)178/P.B-178 (e)4168-00267-BVA/ (f)4390-00067-CYV(g) (h) DOSE RATE EFFECTS:
REFERENCE:
SYNDtGISTIC EFFECTS:
REFERENCE:
MEDIA LIMITATIONS:
REFERENCE:
NOTES: 1 L O HDS2/MDS8F2/8
APPENDIX B g MATERIAL DATA SHEET MDS f 135,itev. i i Q Page 1 of 2 MATERIAL: VITON GRADE, CLASS: Fluoroelast omer VISCOSITY: MANUFACTURER (S): DUPONT SHELF LIFE:
REFERENCE:
TEMPERATURE PESISTANCE: MEDIUM OPERATING RANGE: 400*F
REFERENCE:
15 TRANSIENT: 600*F for 48 Hours
REFERENCE:
15 e TEMPERATURE LEVEL FOR NO DETERIORATION (a) THRESHOLD FOR NOTED DETERIORATION: (b) (c) i (
REFERENCES:
(a) (b) (c) (d) ARRHENIUS CONSTANT: 1.09eV BASIS: In (life) = 12639.561 (1/T)-19.5298
REFERENCE:
4022EQ1-00001-EHT/P.9 e -- RADIATION RESISTANCE: RADIATION LEVEL FOR NO DETERIORATION CAMMA (a) 1.0E05 Rads to 1.0E06 Rads (Little or no ef fect) ( b) THRESHOLD FOR NOTED DETERIORATION (c) 8.75E06 Rads (1X107 Roentgens) Max for dynamic applications (d) 1.0E06 to IE07 Rads Moderate ef fects . (50% loss of elongation at break 50% increase in modulus) (e) 1.0E08 Rads Produces a sever ef fect (Final elongation at break < 50%) ( f) (g) M121t140 Page 29
APPENDIX B MATERIAL DA1A SHEET O MDS # 135,Wev. I Page 2 of 2 (a) 171 (b) (c) 15/P.9
REFERENCE:
(d) 171 .r _ ~ (e) 171 (f) DOSE RATE EFFECTS:
REFERENCE:
SYNERGISTIC. EFFECTS:
REFERENCE:
MEDIA LIMITATIONS:
REFERENCE:
NOTES: O L l l l . I l O MDS2/HDSMF2/16
h- - a e.
._A_. A- +- +
I REFERENCES 2 l e 1 i k
.----c., ,----nn,,,..no-,----,.rn.,,, ,_, ,-e.,,.,,-. -,_,,,.,,,__,,,_.,.,---._.--_.,,__-_-_...-n__,__n.
1 14926-MEQ-1 Revision 2 APPENDIX D SOUTH TEXAS PROJECT MECHANICAL EQUIPMEtfr QUALIFICATION , REFERENCE LIST This Appendix contains a list of selected references from the Equipment Qualification Library; and others which are used in this report. Raf. No. Reference Title
- 6. Dow Corning - Information about Dimethyl Silicone Compounds, Dow Corning 7, 4, 111 Silicone Compounds.
*8. Dow Corning - Information about Silicone Elastomers. Silastic 732 MTV Adhesive / Sealant.
- 10. EPRI MP 2129, dated November 1981. " Radiation Effects on Organic -
Materials in Nuclear Plants."
- 11. 3M Engineering Manual, Eel-F 81 Plastic.
- 13. Polymer Handbook, Brandrup and Immergut, Wiley Interscience, N.Y.
2nd Ed., 1975. 7 *15. The Engineering Properties of Viton, Fluoroelastomer.
- 20. EPRI 1558, dated September 1980. "A Review of Equipment Aging Theory and Technology."
, 28. DuPont Tefsel Design Mandbook.
- 40. Chevron Teknifax - Chevron SRI Grease.
I
- 50. Standard Handbook for Mechanical Engineers, Baumeister and Marks (Seventh Edition).
. 56. Nuclear Engineering Handbook, Etherington, First Edition.
- 57. Engineering Compendium on Radiation Shielding, Volume II Sponsored by International Atomic Energy Agency. Vienna.
- 58. Dow Corning Materials for High Technology Applications. Form No.
10-008A-83. i 60. " Effects of Radiation on Materials and Components" by Kircher and Bowman. Reinhold Publishing Corporation.
*68. John Crane Packing Recommendations: Technical Data Bulletin, '
PP 400-1. ,
*69 Union Carbide Technical Information Bulletin No. 524-205.
*73. Dubois Chemicals, A Division of Chemed Corporation.
i I I Letter, Dubois Chemicals to Bechtel, dated September 19, 1985,
' Material Safety Data Sheet, dated 5/14/85.
Technical Data / Material Safety Data Sheet, Dubois 910 dated 10/24/84.
* = Document Included D-1 MFARDl/RIMDS1
< 14926-MEQ-1 Revision 2
--Ref. No. Reference Title
*74. Crane Co..
Crane, Accessories and Pazts, pg. 75: Telecon Bechtel and Patrick Maney (Crane Co. ), dated 9/23/85. Telecon, Bechtel to Larry Miller (Crane Co. , Deming Puays Division), dated 1/28/86.
*75. Acheson Colloids Company.
Product Data Sheet. DAG 156 (13-108-R282),
*76. Amoco Oil Co.
Types of Greasess Product Information Sheet, Aeolith Grease #8516 ' Product Information Sheet, Aeolith Greases. Product Information Sheet, Rykon Premium Greases.
*77. Bel-Ray Co. Inc. :
Technical Bulletin, Molylube No. 80 Grease, Page 1960; Technical Bulletin, Ternalene 80 Grease, Page 1980s Technical Bulletin, Molylube 80-16 Grease, Page 1965.
*77A Bel-Ray Co. Inc.: )
Telecon, Bechtel to P. h==and (Bel-Ray Co. ), dated 5/21/86.
*78. Biddle Instruments:
Letter, Biddle Instruments to Bechtel, dated December 5,1985, i O ~ Composition of Apiezon Products; Oil, Greases and Waxes for High Vacuum Work - Apiezon, Technical Bulletin 43c.
- 79. Exxon Company, USA:
Data Sheet DG-3C, dated 4/26/85, Nebula EP; Material Safety Data Sheet, Nebula EPO4 Material Safety Data Sheet, Nebula EP1
, *80. Lubriplate Division /Fiske Brothers Refining Co.:
Lubriplate Data Sheet Lubriplate - Lul;;ication Data Book for all Industries. Telecons, Bechtel to J. Girard and D. H. Clem ( Fiske Bros. ) , ; dated 10/4/85 and 1/7/865.
- *81. GE Co , Silicone Products Department: J Versilube lubricating greases. l 7*82. Gulf Oil Corporation:
i Gulf Product Data Sheets Gulferown Grease SP15145, Gulf Product Data Sheets Gulfgen Grease SP15405-981 Gulf Product Data Sheet Gulf Harmony SP15590-882;
- Gulf Product Data Sheets Gulf Harmony SP15589-882,
- Gulf Product Data Sheets Gulf EP Lubricants, HD-series SP15363
- Gulf Product Data Sheet Gulf Harmony AW SP15583-882
- , Gulf Product Data Sheets Gulfcrown EP Grease SP.65155 Gulf 011 Products Co. letter to Bechtel Power, dated Dec.11,
# 1985; Telecons, D. Wright (Gulf / Chevron) to Bechtel dated 1/9/86 and 1/14/86
', * = Document Included D-2 unen, rot une,
l 14926-MEQ-1 Revision 2 Ref. No. Reference Title
*82A Chevron / Gulf letter to Bechtel Power, dated Jan. 23, 1986 and Feb. 24, 1986. and April 7,1986; i Gulf Product Data Sheet: Gulf Premium Lubcote E.P., SP 15749484.
Gulf Product Data Sheet Gulf Super Duty Plus, SP 15310-381 Telecon, D. Wright (Gulf / Chevron) to Bechtel, dated 3/24/86, J
't 3/25/86 & 3/31/86.
*823 Gulf Lubrication Charts, with recommendations for alternative
, lubricant replacements, dated 12/23/85. 3/25/86.
- 8 3. Balocarbon Products Corp.: ;
Product Data Sheets, Halocarbon Greases.' i *84. Jet-Iatbe, Inc.: I Bulletin No. C-15, Jet-Lube SS-30s - Material Safety Data Sheet, dated June 20, 1983; Jet-Iatbe Anti-Seize Compounds; Sagle - Certificate of Compliance for Batch 28092, dated May 2, 1984. Telecons, Bechtel to V. Wilcox (Jet-Lube), dated 1/9/86 and 9/18/85.
*85. Loctite Corporation:
Test Data for Loctite, Grades AA, A, D, B, C, E, Hs Product Data Sheet, Formula 592, 569, 571 & 277
- Product Data Sheet, Formula 49 thru 92 with Letter Grades &
"JILS", July 1980.
- *85A Telecon, Bechtel to R. Valitsky (Loctite Corp.), dated 3/24/86.
*86 Mobil Oil Co.:
Mobil Product Data Sheet, Mobilux 1, 2 Mobil Product Data Sheet, Mobilux EPOl,2; Mobil Product Data Sheet, Mobilith AW-1, 2 and 3; Mobil Product Data Sheet Mobilgrease 28,
- Mobil Product Information, Mobilplex 40 Series Greases; i.
Mobil Industrial Products; } NYVAC FR 200 Fluid; Telecons, 1/9/86, 9/18/85, 9/17/85, Bechtel to J. Powell (Mobil 011).
*86A Mobil Product Data Sheet, Mobil DTE Oils; Telecon 1/21/86 Bechtel to J. Powell (Mobil 011).
l
" Lubrication Fundamentals," J. George Wills (Mobil Oil Corporation). Copyright 1980.
i . , *868 Mobil Technical Bulletin, "Iaabrication of Nuclear Power r Plants", Ma 1974
*87. Parker Seal Group, 0-Ring Division:
Data Sheet, Parker Super 0-Lube, OP-SMS-77; Material Safety Data Sheet, Parker Super 0-Lubes ( Material Safety Data Sheet. Parker Super 0-Lube, Data Sheet, ORD5890, Parker 0-Iatbe s Descriptive Features of Parker's 0-Lube,
* = Document Included D-3 MFARDl/RIJtDS1
14926-MEQ-1 Revision 2 Ref. No. Reference Title
\ Material Safety Data Sheet, Parker 0-Inbe; Telecon Bechtel to D. Haddock, (Parker Seal Group) dated 9/27/85: I Telecon, Bechtel to J. D. Thompson (Parker Seal Group), dated 1/10/86.
*88. Phillips Petroleum Company Lube Lines WO-7726 12-79, Philube L.
Telecon, Bechtel to M. Mathink (Phillips Petroleum), dated 9/18/85; Telecon, Bechtel to J. Huffman (Phillips Petrolues), dated 1/10/86.
*89. Rohm & Haas Company:
Product Data Sheets p. 4, Triton X-Detergent.
; '90. Shell Oil Company:
Zetter, Shell to Bechtel, dated October 10, 1985; Technical Bulletin, SOC:88-82 Technical Bulletin, SOC:265-83 Technical Bulletin, SOC 158-85; Technical Bulletin, SOC:54-84 Telecon, Bechtel to H. Doran (Shell), dated 1/13/86. Telecon, Bechtel to E. Mironchick (Shell), dated 1/16/86
*90A Shell Oil Company:
Letter, Shell to Bechtel, dated 1/21/86; Telecon. Bechtel to J. Martin (Shell), dated 2/25/86. Technical Bulletin, Shell Hydraulic Oils. Technical Bulletin, Shell APL Grease. 1
*91. Sun Refining and Marketing Co.:
Product Information Sheet, Group. Gear Lubricants. Producti SUNEP 1000 Product Information Sheet, Group: Greases, Product: SUNAPLEX l 990 EP Greasess . Telecon, Bechtel to S. Bunnell (Sun Refining and Marketing) dated 10/10/85.
- 92. Texaco, Inc.:
Product Information Sheet, Code No. 938/951/987, (Issued 3-82) .
*92A Product Information Sheet, Code No. 1982, General Purpose Greases (Issued 10/1/68):
Telecons, Bechtel to J. Shields (Texaco USA), dated 1/23/86 and 5/7/86
' 9 3. Valvoline Oil Company, Division of Ashland Oil, Inc. : l Product Information Sheet, Tectyl rust preventivest Material Safety Data Sheet, Tectyl 9846.
( >
* = Document Included D-4 MFARDl/RIMDS1
._ . - . .. ~ .... . .,, , . .. 14926-MEQ-1 Revision 2 Ref. No. Reference Title V *166. Intter from Bisco to Bechtel, dated 2/21/86 (E003041).
*167. Letter from Dow Corning to Bechtel Energy Corporation, dated 3/21/86 (E003042).
*168. Memo from B.D. Shah to B. Dilodare, dated 4/14/86 (ION 842140).
*169. Telecon, Bechtel (SFO-EQG) to Bechtel (Houston) dated 03/31/86.
*170. Tresco Mfg. Co. Product Data for Tresco 440 Tape & Pre-shimmed Tresco 440 Tape A *171. Radiation resistance of Viton.
p 172. 14926-4026EQl-00001-CUL. Nyle report No. 57688-1 " Evaluation of Environmental Qualification and Aging Analysis of Control Valves for use in STP."
*173. Memorandum from B.P. Shah to B. Dilodare, dated 4/21/86 (IOM 42264).
174. "The Effect of Nuclear Radiation on Elastomeric and Plastic Components and Material." R.V. Eing et al. Bettelle Memorial Instituter distributed by NTIS.
*175. " Engineering Guide to the DuPont Elastomers" ( Adiprene, Hypalon, Hytrel, Neoprene, Nordel, Viton) .
176. " Standard Handbook for Electrical Engineering." Fink & Beaty, lith Edition. 177. " Material Handbook." George S. Brady & Henry R. Clauser, lith Edition. 178. EPRI NP-4172SP, Final Report, 8/85 " Radiation Data for Design & Qualification of Nuclear Plant Equipment,"
*179. John Crane Bulletin No. P-3010, "Grafoil Endless Packing Rings."
*180. Memo from B D. Shah to B. Dilodare, dated 4/29/86 (IOM #42382) .
*181. Memo from E. A. Goldenberg to B.D. Shah (E003077), dated 4/25/86.
182. " Handbook of Chemistry & Physics, Chemical Rubber Publishing Company," 1982-1983, 63rd Edition.
*183. Memo from B.D. Shah /Dr. Shah to B. Dilodare (IOM 942411), dated 4/30/86.
*184. "Polyr.yte Detailed Information", Parker Technical Bulletin 08B, t
dated 3/8/81.
* = Document Included D-10 MFARDl/RIJtDSI
14926-MEQ-1 Revision 2
- f. Ref. No. Reference Title
; (
"A Product Survey for the Power Generation Industry", Garlock
*185.
MP-904. 4
*186. Chesterton Product Info. for Style 5200 & 5300 Graphite Tape Packing.
*187. Telecon, Bechtel-Houston to Bechtel-SF0, dated 5/16/86.
*188. Memo 9E003087, dated 5/9/86: B. Dilodare (Bechtel-SFO) to B.D.
Shah (Bechte1-Houston) . .; *189. Memo #E003088, dated 5/8/86: B. Dilodare (Bechtel-SFO) to B.D. l Shah (Bechtel-Houston) .
*190. Memo GE003089, dated 5/8/86; B. Dilodare (Bechtel-8FO) to B.D.
~
Shah (Bechtel-Houston).
*191. Memo 9E003097, dated 5/8/86: B. Dilodare (Bechtel-SFO) to B.D.
Shah (Bechtel-Bouston).
*192. Telecon: Bechtel-Bouston to Bechtel-SF0, 5/20/86.
*193. Memo 642578, dated 5/9/86: B.D. Shah (Bechtel-Houston) to B.
Dilodare (Bechtel-SFO).
*194. Letter from Dow Corning USA to Bechtel Power Corporation dated May 15, 1986, E003110.
4
*195. Memo 9E003109, dated 5/21/86: B. Dilodare (Bechtel-SFO) to B. D. Shah (Bechtel-Houston) .
l *196. Goodyear Aerospace Corporation " Rubberized Fabric Specification for D-901A."
*197. Telephone calls from Mehdi Fard of Bechtel to Bill Kysh of Techno Corp. E003112.
>*198. Memo from P. Trudel to B. D. Shah (IOM-041666), dated 3/17/86.
1
*199 Memo #E003085, dated 5/5/86: B. Dilodare (Bechtel-SFO) to B. D.
f Shah (Bechtel-Houston) . l
*200. Memo from Nas Islam to Mehdi Fard 4/21/86. i 1
i
*201. Telephone call from Baldwin Toy to D. Warsing of Limitorque l Corporation dated 5/12/86. '
*202. Garlock FCP-3/85-30M
! 127-AFP Asbestos-Free Valve Stem Packing
*203. Telecon Bechtel t.o I. Villaiva (Control Components, Inc.) dated i
y 5/27/86.
*204. 14tter, Anchor / Darling Valve Company to Bechtel, GE003116, dated 5/23/86.
* = Document Included D-ll
14926-MEQ-1 Revision 3 3\ Ref. No. Reference Title ( * *246. Letter, R. O. Bolt to E. A. Goldenberg, dated October 16, 1986,
#E003313. l
*247. Garlock Service Condition Reference Table.
*248. Letter, R. O. Bolt to E. A. Goldenberg, dated September 9, 1986, #E003260.
*249. IOM #44583, R. H. Pence to B. D. Shah, dated September 18, 1986.
*250. Letter, R. O. Bolt to E. A. Goldenberg, dated September 8, 1986, #E003261.
*251. Letter, R. O. Bolt to E. A. Goldenberg, dated September 10, 1986, #E003263.
*252. Letter, R. O. Bolt to E. A. Goldenberg, dated October 20, 1986,
#E003314.
253. IEEE Transaction Paper No. 68TP651-PWR, " Insulations and Jackets for Control and Power Cables in Thermal Reactor Nuclear Generating Stations".
*254. Letter, R. O. Bolt to E. A. Goldenberg, dated October 15, 1986,
#E003309.
G(o ./ *255. IOM #45870, R. Witthaver/N. Islam to B. Dilodare, dated November 20, 1986.
*256. IOM #46022 R. Witthaver/N. Islam to M. Fard, dated 12/2/1986.
*257. Telecon (12/2/86): Bechtel (SF0) to Tak Takahashi (Dow Corning).
258. Dow Corning " Thermal Aging Program For One Component Silicone /A Sealants" by S. B. Smith and T. C. Hanpton, dated February 1 D\ 1971.
*259. Telecon (12/11/86): Bechtel (SF0) to Tom Green (Johns Manville).
260. Plastic Engineering Handbook of the Society of the Plastics Industry Inc., Fourth Edition, Van Nostrand Reinhold Company (n
.v
* = Document Included D-15 MFARDl/RLMDS1
i.
?
I. I-
~
l 3.. r t t t. A i' ,
- t. ..
l I, REFERENCE # 15
?
2
?
f SOURCE : MEQ- 1 i+ , e f l l l
r 3 Y' E K 6 H C 6 l5 MECHANICAL EQUIPMENT QUALIFICATION REFERENCE #15 g PAst / of 21 , .,,
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i VITON' fluorcelastomer, a fluorine. Its original prominence with a ' containing hydrocarbon polymer, growing number of uses detailed in i is a high performance synthetic a later section of this booklet. rubber with exceptional resistance to VITON is marketed as a raw matenal oils and chemicais at efevated to the rubber manufactunng industrv , temperatures. Since its by the Elastomer Chemicals commercialization in 1958. Du Pont Department of Du Pont No finished has developed a variety of products are made from VITON bv , types of VITON possessing specific ' property improvements. notably in the Elastomer Chemicals Oeoartmeet.
' ' "8 Our customers offer a variety of l nd en pro t esis ance Solid and cellular products solvent l
- compression set. solutions and ccated fabrics. all Among the earliest uses of VITON based on VITON. The compounded were O rings for severe service product can be molded. estruded.
or calendered using standard rubb.er conditions. This continues to be an important application, while shanng processing equipment.
' }
Ma ;.e___ _m.s
- 7g.i. gygg' 7.r " dbr ,
=
t" j, X 8 K lp_'f M 8'y f T i
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. p ', #
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i $ i... L g. . 3 e,
- Se : ~
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~ ! properties $.
4,g4 pw' a y ' VITON' fluoroelastomer is an '. .' M' ,,,, , s'
- exceptional rubber. It possesses the I; - I'4 l
traditional rapid recovery from 5',
. .a P '
W i- 1 d: formation, or resilience. of a true i=% v - 'J
....- ~+-
' ' ~Q elastomer. It also exhibits mechanical 6+ , i. ff
,-% y Ai ; - ,
proparties of the same order of -
%:j[p
'* -m ,
9.'.;',',. ;4 t D, ' t)f,(l' -
. mi magnitude as those of conventional synthetic rubbers. However, the
'.j L :
A. d.
. 1i;
.f g ' ',i
% i Q
resistance properties of VITON are, c. . I
~'
in many respects, far beyond the
*^
I.,, R.7
- k
' y.
~
rangs of those of ordinary rubbers. - Vschanical and resistance properties p[.1
#'M,g -
0-I i-' of Du Pont VITON will be discussed 1 in that order. 9 . il k. .
.y
.'# g{'
} .
i
% ' ~ '.
a ' ,~ 4%j, , [ JECHANICAL WTOPERTIES 6.estal purpose formulations of F g wrc jre g w y r
' , m m fg4 lm. W N wW vlTON were used for the ... f g a, measurements reported herein.
Q*] W . -* . j(. W cxcept as specifically noted. The values cited should be taken as
,' y3 % *" f.9 8%.g(
f U L
}*' O;.
du. c9 r:presentative of what you might I* - f,J1 et - - - - - - - - - r expect of a product supplied by a g.
>: A" N_h*.' C .'y-i rcputabfe rubber manufacturer.
Exact duplication of every figure.
$,4 g-g 'a 'h ',
SM@i12)v "# '
- :;I
, however. should not be expected. 4 r I,. m.g ,
7 { r d _ .,N As is the case with all elastomers.
,-5,
, g' 'g_ ,0p g -
, J VITON may be Compounded to enhance certain properties while ~"
Ca l } h * - - ,O p s s compromising, to some degree. ,, i ' [ ,. 1 certain other properties. But, unless
~
g E:3 ( .. cr:.Vi ,i-. f M.;.7 <' . . . ~,3 3
^*E:
4*- 4E I the compounding is drastically f'o j, t - - l modified. mechanical properties of one product made of VITON will A A ( Tensile strecgth and elongation The mechanical properties of VIToN are clos 3fy parallel those of another, measurements from -63 to aco*t. evaluated in a variety of equipment. t-54 to 204*o may be made on v ton including this dynamic fles tester. PHYSICAL CONSTANTS in the thermally controlled enclosure of Specific gravities of the raw polvmers this machine. of VITON range from 1.80 to 1.86. < l Miasurements on typical compounds J will closely approximate the ' l following figures? ' 5pecific heat-0.395 Cosfficient of linear expansion-
# = 10**/*F. (16 a 10-'/*C.)
mal Conductivitv- 1.58 BTU /ini F.thr. at 100*F.1196 kg. call icm.8/ *C./hr. at 38'C.) 1 l ..........e l i i
; nu eau
= x :-
g.. so.se
, % E i
i e= I -. E . li i i .. e A i MECHANICAL PROPERTIES a u h HARDNESS typical compounds of VITON range The durometer A hardness of from 75 to 150 percent. general ' purpose compounds of COMPRESSION SET VITON* fluoroelastomer is approxi. mately 70. Harder and softer Fi 1 ilbrms m wie formulations (50 to 95) can be good compression set shown bv a furnished and produc;s with great typical compound of VITON after apparent softness may be obtained test compressions for vanous pe'iods by the use of cellular VITON. of time at 300'F. and 392'F. 8149 and
' 200*C). These values become more Depending upon polymer and meaningful when it is realized that
'A .f formulation, hardness may change most rubbers have a service temoera-
, , very little or may decrease 5 to 15 ture ceiling less than 250'F. f121*C:
,-. points at temperatures between 250
,+
- U, - O' and 500'F. (121 and 260*C) Such FABRIC COATING
. variations must be taken into Coatings of VITON are commoniv A ' consideration in specifying hardness employed on fabrics to confer
; of products used at elevated necessary heat or fluid resistance to
. hy i temperatures. the end product. Adhesion to the
- ;i. O \* ], F *
,..... fabrics is generally good and.
j " " , ' '. !I Q TENSILE STRENGTH depending upon the heat resistance
- Compounds of VITON have good of the fabric u, sed, temperatures up
' } t $50'F. (258 C) cause no problems.
i
.1 - tensile strengths, adequate for most
'V applications A typical value, when Heat stabilities of three representative tested at 75'F. (24'C), is 2.000 psi fluorcelastomer coatings on glass (140.6 kg/cm.'). And, measured at fabric are shown in Figure 2. As can 300'F. (149'C), the tensile strength be seen, all three compounds exhibit of VITON remains in the vicinity of excellent heat aging properties and 600 psi (42.2 kgicm.8). are useful for more than 100 hours at 550*F. (288'Cl ELONGATION AT BREAK Above 500*F. t260*C) singfe olies of Percent elongation at break is a coated fabrics are more stable than common yardstick for evaluating a multiple plies. This is because at rubber's durability in service. The the,e high temperatures the decom-performance of VITON at 75'F. position products of VITON cannot (24*C) normally ranges from 150 to escape as readily from multi piv 300 percent elongation at break. construction. Their entrapment At 300*F. (149'C) the elongations of causes faster deterioration.
it '~L .';;; _. m,
.a kDq
_. I
~
e."- )
- _ g -m-
'$W , , 2.5 Asbestos fabric coated with VITON is _ _
l used on iet aircraft for firewall sleeves g ' and seals. , 4
- ees. U.S. Pat. & Tm. off.
. : . * . .. :. . . . :. . a.+. ,,,+ x.> - r--nt::.ch: .:,.. & GE S o F 1 !
~-
3 ^~sd4w .etofVf!DLW
*'p.?. _ . Ecag-Tena-Compression T *;,s:
# K. . . . +n
. .r V. & . S -r
( - 4.r~.m.? aa :
,:.= : :-nw .trw..
.<?FQ :-! ,.
3.*-7 : _..:e socir.* :m
. a.* .. At- ~
AS 1 '
~
At- ~ ' ~d ' Time, hr.. RJ. -300*F. (f 49'C) 392*F. (200*C) 1,000 - 12 50 2.000 - lir 6 21 22 7,5 4.000 8.000 21 32 98
*AfD4 Oste. Meehod L W
RESILIENCE Th3 dynamic properties of VITON* tluorcelastomer make it suitable for Heat Stability of Glass Fabric coated with VITON use as a vibration isolator at high t;mperatures and as a vibration Compound Compound Compound damper tenergy absorbert at room A 8 C temperature. In the latter case. 1 p h 2 ply 1 p h 2 ply 1 p h 2 ply however,it would normally be Original grab employed onlyin very corrosive tensile strength, cnvironments. Ib/linest in. 91 194 80 190 109 185 (ks/cm.) 062)(34.6) 043) 03.9) 093)(33.0) ADHE510N TO METALS VITON can be adhered to a variety After 50 hr. oven 93 123 57 121 94 128 cf metals, using special adhesive aging at 550*F. G88'C) 0 6.6) (22.0) (10.21 G1.6) (16.8) (22.9) f:rmulations also based on VITON. After 100 hr. oven 78 98 54 102 74 107 Assemblies do not fail at the bond.
- aging at 550*F. (288'C) (13.9) (17.51 (9.6) (18.2) 63.2)(19.1)
Brnd strength exceeds the tear p" strength of cured VITON, both at % Weight Lose . 5'F. (24*C) and at temperatures After 50 hr. oven s high as 400*F. (204*C). The aging at 550*F. G88*C) 6.7 7.4 8.0 8.7 7.8 8.4 ihesive bonds also endure 500*F. After 100 hr. oven a@g at H04. (288'C) m 152 133 19.8 13.8 m re nta ve a es on alues b: tween VITON and some common m:tals.
$ PONCE PROPERTIES Cdfular VITON,in densities from W3 10 to 95 lb1ft.', (0.16 to 1.52 gicm.'), Adhesion of VITON to Metals
- crfers the advantages of extreme
. softness and compressibility while Original Aged 64 hr. at 500*F. (260*C) rstaining to a high degree the Measured Measured Measured cxceptional heat and fluid resistance Metal at 75*F. (24*C) at 75*F. (24*C) at 400*F. (204*C) of solid fluorcelastomer products. Aluminum 160 (28.6) 20 (3.6) 6 (10.7) i Both open and closed cell materials Brass 160 (28.6) 20 (3.6) 6 (10.7) l can be produced. Steel 160 (28.6) 20 (3.6) 6 (10.7) l
*1e58 peel adhemen a lbstmeer en th6/asiJ. AH is.leres weve by sasch seenne.
l
~
. K
' Reg. U.S. Pat. & Tm. Off. 3 l
- - - - - _ _ , . _ ~._._... ,. -. , . - _ . - . . _ _ - , _ _ _ - - _ _ - _ - - - - - - _ . - - - -
I l PAse & of 21 ) l M RESISTANCE PROPERTlES ' i mechanical propert=s better than sections, of course, exhibiting less Again we point out the influence oT stiffness than thicker ones at every l compounding upon specific any other elastomer. Oil and chemical sosistance also em relatively temperature. The bnttle point of . properties; like acid resistance, I unaffected by elevated temperatures. VITON. at a thickness of 0.075 in. electrical charactenstics, water (1.9 mm.I,is in the neighborhood of I absorption, etc. General-purpose Compounds of VITDN wmain usefuily elastic indefmitely when -50*F. (-45'C). Depending upon formulations of VITON' fluoroelas- exposed to laboratory air oven aging thickness and hardness, this value tomer will be referred to throughout may range from ~25 to -7$'F. up to 400*F. (204'C). Contmuous unless otherwise indicated. service limits are generally (-32 to -59'CL Under certain It is important to note that if you conditions. some of these fluoro-considered to be: require a high degree of resistance elastomer products perform to a specific exposure you should >3.000 hours at450,*F. (232.C) satisfactonly in dynamic applications stress this fact to your rubbet 1,000 hours at 500 F. (260*C) at temperatures approaching their supplier. He can fumish you with a 240 hours at $30*F. (288'C) bnttle points. i I product specially compounded to 48 hours at 600*F. 015'C) Although VITON has limitations at suit your purpose. For instance, very low temperatures when dynamic volume swell of VITON in hot water service is required, static applications ; can be reduced by two-thirds LOW TEMPERATURE are readily handled. As a matter of without significant sacrifice m overall Especially in aircraft and space fact general purpose O-rings made performance. Similar improvement ecuspment. both low and high of VITON have proven satisfactory as of other resistance properties temperature conditicins must be . static seals under cryogenic condi-can be achieved through special satisfied. VITON is generally service- tions approaching absolute Zero. compounding. able m dynamic applications down to -10*F. (-23'C). HIGH TEMPERATURE Thickfiess of the sample has a VITON withstands high temperature marked effect upon sects of flexibility and simultaneously retains its good at low temperature: the thinner cross l l l Creaseless stopcock for high-wacuum em (In10-*mm. Hg) service up to a50*F. 8F - 1232*CJ is closed by a resilient diaphragm a f
- -d@g ,_,,
,. i of outgassing and radiation-eesistant VTTON.
m t-- i _ _ _ _/ 3 j
.! r.
m . 4 0tiMhgh' _hD _ p ;
-O gQT ..a .aew
.w.- u p=
l 6 .. . . ..
A,d o c 7 w 2I O o ,
.g 1) vEm"'Ir iN]
s
- CA5KET OF VITON N
- VULCANIZED TO
(
. i s
-g'? i BARREL CIVE5
'jf 3 ' .s, e
, PO5tTivt SEAL WITH : r d' VALVE STEM 5 TAT. 1 f
.. f ~
^
' 1 g8 id 0
,' ,[ f kljY
.:8 .
- q. .? .
3 i
~
ff'
/
1p g I
. s,;.6 , < c k(u
' -h*- [.P 1 E::d .
.. =
.g i . ym '
i
* (I CUP CASKET OF VITON FOR SEAllNC
( AIR. FLOW PA55 ACE. L'
.;[
, 3 Valve inside let aircraft wiwels uses s 4O gaskets of VITON* fluoroelassemer.
. f Specification calls for operation from
. , g T. -65 to 500*F. (= 54 to 260*C.) plus
- . . i*, ,
pressures over 300 psi (21.1 kg/cm.r). W. I G
- f}.: i j .e.7]
v [ g The flange seal of VITON on this vacuum
' drier cover was in place for 12 years.
(' ,' . 11
'!j 'kl Estimated temperatures within the I*
;*j -
. lacketed stainless steel vessel ran 4Wa0*F. (234 249'C.) and the contents
, ". ? E C .i .. -
were acidic organics. Seal replacement L #;*'p 3 was made only when the drier had to be
'8 '
r i p- . *,
-. e mechanically overhauled. At no tiene had
[ *',' A
- the seal,shown any evidence of leaking.
.e :. > .
p. 3 P j, .
.b.w_l~ E l gf,
, ... . lG.%. .:k ...
[ih y.n, . 'q{Y,p.
.<.v . '
r
' .Y . # 8 ,
=
~
).
O n s.u.s.Pt.ar on. , _ - _ _ _ . - . - . _,,..___._r.___._.--..
- ~~ - - -, . __ _
~~
= .:.
. . . PAGE 7 QN 2 l O(
\
RESISTANCE PROPERTIES l On the other hand.VITON is not CAS PERMEABILITY FLUlO RESISTANCE VITON is relatively impermeable to recommended for service in low VITON* fluorcelastomer has the best molecular weight esters and ethers- air and gases, ranking about midwav proven fluid resistance characteristics ketones, certam amines, hot between the best and the poorest of any commercial rubber available anhydrous hydrofluoric or chloro
- elastomers in this respect. These to date. It has excellent resistance to sulfonic acids, and a few proprietary comparative measurements were oils, fuels, lubricants, most mineral fluids such as Skydrol $00A.The made using standard sized specimens acids, and resists many aliphatic and solubility of VITON in low molecular (1 sq. cm. by 1 cm. thick) of typical aromatic hydrocarbons (carbon compounds, each exposed to a weight ketones is, of course, useful tetrachionde, benzene. toluene, in producing solution coatings of pressure differential of one atmos.
xylene) that act as solvents for other phere at 176*F. (80*C) VITON. rubbers. The permeability of VITON can be Tabulated on pages 1819 are modified considerably by the way it evaluations of VITON versus a is compounded. But,in all cases. representative list of nearly 200 fluids. permeability increases rapidly with increasing temperature. Additional O .
.10 -
data on the permeability of VITON are tabulated in Figure 4 e i. , Figure 4
, 8. '
'M .
- Permeability
- of Compounded VITON l '
86*F. 250*F. 400*F.
' 75*F. *
(24*Cl 00*C) (121*C) (204*C) l M_ 1 Air 0.0099 x 10-' - - -
' #M ,
Carbon - dioxide - 0.59 x 10-' - p' Y ' 0.892 x 10-' - 17.4 x 10-' 67.0 x 10-' O ' e 2, Helium
' - Nitrogen 0.0054 x 10-'
t , - Oxygen - 0.11 x 10*' - L L
)%
i < *s.s/an a/cm/sesJasa. A High temperature Guld resistance tests in the laboratory condem that products of VITON, such as those shown at right, will successfully perform in the Reid where other rubbers fail completely. o
- Oo oO Ona
.:. ss
- 4M .
47 PAGE 9c L
~
t y 4 pcaQ;. y p' l
.- 7
. Vacuum chamber a e - t.r.on. o.f giant proton
. mmeoo sr w a_ w _ t
~.
circumference was gastieted with I=% C
- g radiation-eesistant, non volatillaing h[ - c VITON to improve the vacuum so 3 tg 1 to-'in.Hg. .
4 , p, ( 2 o ...
! .v.?j ,.',.
g {', g "
,. I C & .. u
\ '
..$h FIAMMA81LITY RADIATION RESISTANCE ENVIRONMENTAL RESISTANCE VITON* fluoroelastomer. like Exposure of VITON to gamma Neoprene and HYPALON* synthetic VITON has excellent resistance to radiation from a Cobalt 60 isotope atmospheric oxidation, sun and rubber, ss a halogen-containing poly- source brings about an increase in weather. Samples weathered in direct mer and thus is more resistant to hardness and stiffness. This seems to bummg than are exclusively sunlight showed little or no change be as a result of an increased state in properties or appearance after hydrocarbon rubbers. of cure induced by the radiation. 13 years' exposure in Flonda. The In laboratory tests, products made For dynamic applications. VITON same is true for samples exposed to of normally compounded VITON will should not be exposed to radiation various tropical conditions in Panama bum if directly exposed to flame but exceeding 1 x 10' roentgens. For for ten years.
will go out when the flame is static applications, higher dosage tsmoved. Natural rubber and many are permissable. VITON gives n Articles produced with VITON are synthetics will, under the same evidence of radiation-induced stress unaffected by ozone concentrations conditions, contmus to bum, cracking. as high as 100 ppm. No cracking
- However, despite its advantage occurred in a bent loop test after over other matenals in such VITON ranks about midway among one year's exposure to 100 ppm of Iaboratory tests. VITON will bum if commonly available elastomers with ozone in air at 100*F.138'C).
respect to radiation resistance alone. " nvolved m an actual fire situation. However, since high temperature is The biological resistance of VITON - Special compounding can enhance frequently involved simultaneously also is excellent. A typical com. the flame resistance of VITON. One with exposure to radiation, the d $ d sp cation formulation, specifically developed practical effectiveness of VITON (,""E 52 rb ,again I, f:r the Space Program, will not ignite correspondingly increases. In many growth after 30 days. This spec under condstions of the NASA test, cases, the temperatures will rule out covers our common groups of fungL which specify 100 percent orygen at most other elastomers and plastics. 6.2 psi fabsolute). Under extreme vacuu'm conditions VITON exhibits a weight loss of only ELECTRICAL PROPERTIES 2-3 percent, indicatmg that it is FOOD AND DRUG CONTACT The electrical properties of VITON , virtually completely immune to The U.S. Food and Drug Adminis, suggest its use as a wire insulation outgassing. Products of VITON are tration has amended its regulations for low voltage, low frequency commonly baked at 400-500*F to provide for the use of vulcanizares applications requiring unusual heat (204-260*C) for 16 24 hr. m order of VITON in the formulation of and fluid resistance. It normally has a to post cure them. This procedure rubber articles intended for repeated D C resistivity on the order of removes virtually all volatiles before food contact use. 2 x 10'8 ohm cm., a dielectric con. the item goes into service. More details are available in the stant around 10, dissipation factor Federal Register, Vol. 33, No. 5, of about 0.05 and a dielectne Tuesday, January 9,1968. Part 121- strength of 500 volts per mil Food Additives. Subpart F-Food 12.000 vohs per mm1 Additives Resultmg From Contact With Containers or Equipment and Food Additives Otherwise Affecting Food-Rubber Articles intended for Repeated Use. Figure 5 ABRASION RESISTANCE End products made from VITON are Electrical Properties of VITON at Various Temperatures tcugh and long weanng. In the (Testedin air)
**ber abrasion test a loss per 75*F. 300*F. 390*F.
volution of 0.10 2 milligrams. 24*C 149'C 199*C ( 4th a H.22 wheel and 1.000-gram Dissipatron Factor, ioad was measured on a typical 0.034 0.273* 0.39 to 1.19* l (1,o00 H,,j compound of VITON. Dielectric Constant, 10.5 7.1 9.1 (1,000 Hr.)
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AUTOMCHNE !E Since 1962, VITON has bee' the between overhauls as a result. Many opportunities exist for the Hydraulic fittings in automotive E incorporation of VITON* fluoro- standard seal matenal on diesel service are reliably sealed against 5 elastomer in parts for the engine and engine brake solenoids.These vibration induced leakage bv sleeves i dnve train of modem passenger devices have been installed in more $ than 50.000 vehicles ranging from of VITON which absorb angular vehicles and trucks. Cost is a major displacement and withstand hot oils. ! factor in this industry and any use of city buses to logging trucks. The 0 ring seals of VITON were pur. And automatic transmission front a high-priced elastomer like VITON pump seals of VITON have proven is an exceptional testimonial to its chased against MIL-R-25897 speci-fication and hold against hot tube their worth after years of successful premium performance. However, service. oil at up to 60-70 psig (4.2-4.9 the long-term value provided by VITON is being increasingly recog- kgicm 8.) in the truck engine. Other automotive uses for VITON mzed as justifying its use in place of Off.the-road equipment also uses include an axle pinion shaft seal, cheaper materials as performance VITON. A major manufacturer has diesel cylinder liner seals solenoid' msurance for certain automotive standardized on VITON for rear plunger tips, seals for automatic parts. This is true not only for crankshaft lip seals in its heavy duty transmissions in buses, vacuum ' I extreme exposure conditions but. in diesel engines used on certain of tubing and diaphragm for a spark some cases, also where only . its earthmoving machines. Some of advance mechanism. moderate conditions are normally these engines have run 8.000 hr. I encountered. . . , ,; g , , in carburetors needle valves tipped n % - y, _ '.igs- J with VITON provide a resilient, Q i
=e L fuel-resistant, abrasion resistant ,
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seating material that is the key to a q q'~ y -
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non flooding carburetion system. A ~ e component of VITON on truck
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carburetors is the acceleratot pump ' " c I cup which must remain dimension-
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have been used for a number of R. j #
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i' truck engines designed for 100.000 , I Jf A' ,,g, ig ; n C $ ~
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- t miles (160.930 km.1 of maintenance-Ih g ;
free operation. And many have run
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heat and oil resistance.
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't' j'$ p- maintenance costa per rn.ne.
Eg I-d , VITON on tip of carburetor needle valve , MI.i #, 4' Q. Pmvents flooding, does not swellla l P f.. ., .i 8 g43 aromatic fuels. 4 j- v gg a;y s,
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_ ._. _=d T k h" " s} i sw _ . . g, 4 i i C niercial letliners use vtTON in neany critical appikations where enceptional j' 4 'd , g )q[ heat and oil resistance are necessary .-
, 4 i a requironients. Ig i ,
n Connecto, seals on let engine wiring ) 4
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a e !h harnesses are VITON for heat. oil, weather and v&eation resistance. .
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l PMa* /3 of : / i v . Aircraft designers havs reported aircraft manufacturer, involved I Aeliability of materials under extreme dynamic tests at elevated exposure conditions is a prime O-rings of VITON have a usable thermal range of -65 to +600fF. temperatures. O-rings of VITON, requisite in this field. The high and properly designed and installed low temperature properties of (-54 to + 31S*C.): and at 680 to 730*F.1360 to 388'C.) tests have according to their recommendations. VITON' fluoroelastomer have been proved capable of successfully well demonstrated in a number of been successful but service life is reduced to about 30-40 hours. They completing 50.000-cycle compression aircraft and missile cornponents: further report that VITON has tests at 500*F. (260*C.) manifold gaskets, coated fabrics, firewall seals, heat-shrinkable tubing excellent abrasion resistance and resistance to thermal cycling, a Among other applications of VITON and fittings for wire and cable, l common condition encountered in in aviation are its uses as an abrasion-mastic adhesive sealants, protective resistant solution coating over braid- 1 coatms: and numerous 0-ring seals. rapid ascent to, and descent from. the ' stratosphere or higher. In several sheathed ignition cable: heat-An additional characteristic of resistant connector seals on jet VITCN pertinent to space tests. VITON sealed just as well at room temperature, and also at engine wiring hamesses; flexible, com wnents is its ability to seal reduced temperatures,after 40 impregnated fiber glass sheathmg for agahst "hard" vacuum, down to a electric wire: coated fabric covers tant,e of 10-'mm. Hg by actual test. thermal cycles as it did when new, Other elastomers, after two or three for jet engine exhausts between thermal cycles, would no longer flights; and syphon hose for hot
' maintain their seals at room engine lubricants.
temperature. One study on the service life of O-rings, run by an I N .
-.. k f *n _-- s e, let engine enhaust covers see made of a;,,,, . glass
,oo.r fab.ric co.ated
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_ _ _ -ei h __ h{ ~ ~ A VITON is entensively used aboard the
> ?, supersonic CONCOeDE in structural sealants and gasketing, fire-resistant
- ,. coated fabric, cable lacketing, protective
-v e r- coatings and various seals.
, O "* ,
e - N7g.' . o ' Molded-in-place, reusable seals of VITON are designed for *hard vacuum
- space ll g,"h. t A I N .**y applications,below1 10*rmm. Hg, I
f
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I AA Ga* /4/ df .2 { h " universal" seal Fas simpised the O1 pumpins station handling more than 80 different solvents oils and chem:cals. Seals of VITON used in production and markediv *ecuced the number of customer service calls
; the piping's swivel joints and on the instrument.
e, ; , telescoping joints were inspecte after two years ser' rice and found But VITON serves the chemical industry in more ways than as seals
' ' ' ' a d as t e ay they were fn", gdg alone. Fluoroetastomer lined valves eliminate heat and corrosion wornes Another example is a door gasket for in many a plant. Transfer hose for a wood impregnation autee rave, solvents and reactive petroci e mcals Temperatures to 245'F. (118'C.), is in daily use for both processine .
steam pressures of 150 psig 1103 kg) and distnbution facilities. Included l cm.8), and exposure to cresol oils are installations on ocean tankers as CH and other phecolics are involved, well as highway trailers. Proportionine VITON overcame the permanent set rwmps handling highly reactise i DU deficiency of the original woven asbestos gasketing and gave much chemicals are equipped with diaphragms of VITON. Processine A " universal" material of longer service than previously tned rolls for hot or corrosive service are construction is the ideal sought by synthetic rvbber seals. covered with VITON. And aerosol. harried production and maintenance propelled solvent solutions of VITON engineers in this rough-on. A third example is the rotameter are spraved on as multi. purpose i equipment industry. The high costs manufactured by a leading supplier maintenance coatings throughout l involved in dismantling and replacing of measurement and control the chemical industry.
! failed components, to say nothing equipment. All of its rotameters of the production losses, far intended for metering chemicals are outweigh any materials cost factor, fumished with O. ring seats of ,
Standardization on VITON. VITON. This adoption of a fluoroelastomer is becoming more common as its economic justification . in longer production runs between *
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maintenance shutdowns is being c, more widely demonstrated. In two documented instances, chemical
- l piping and equipment seals have (k/;.Sia '
i remained in uninterrupted service g ,Tj[g ,,y - for over 10 years. L n,; f -- l VITON is very close to being a . l universal seal for chemical prcetss " " " "
' j l
equipment. One example is a -
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4 ~W V Packing of pipeline swivelioint is heavily encrusted with deposits after years of _.y i E Ng Q handling a variety of solvents, yet it remains as leak. free as when Erst 6 .,
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7 ' $# (p installed because it's made of VITON. WP .. = . at - _- = e'h 14 .. . . . . . .
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Door of wood impregnation autoclave is W ') g as o N?d(Mtf {a The lenproved steam / vacuum sealing T.a = system replaced woven asbestos gaskets. r [ g."q , A b .3 S - 1 ' .4 I
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MISCELLANEOUS INDUSTPJAL USE5 - Cutting across all industry lines are steel mill signal cabfe, deffector rolls customanly replaced oniv dunng a wealth of additional applications on high speed tinplatir.g lines, periodic maintenance overhauls.
- where the good mechanical precision-molded balls for check bposure is to a variety of hydraulic properties of VITON* fluoroelastomer valves in oil or chemical service, and fluids at temperatures up to 325'F.
have permitted it to replace conven- an assortment of O-ring seafs for test (163*C.) and pressures. in some - tional elastomers. To cite a few: equipment in an automotive cases rapidly attemating up to 2.000 stable-dimensioned O-ring seals in manufacturer's experimentallab. psi (140.6 kg./cm.8). the meters of automatic gasoline blending pumps, high-vacuum seals The lattermost example well According to the lab's mechanical for a proton accelerator, a heat and illustrates the general principle that design engineer, their previous seals corrosion resistant expansion joint for we have been stressing in this ** baked so hard they snapped like a utility company's stack gas exhaust booklet. Previously, various test ma- pretzelf'when removed after a ducts, tubing and seals for a variety of chines had to be dismantfed every short time because of leakage. The premium-grade indus trial instruments, few days to repair leaks. Use of switch to VITON eliminated a real conveyor tires for hot plate glass. VITON permits the units to run maintenance headache and, he feels. psching rings for hydraulic activators continuously for three months without has come very close to providing on steel mill ladfes. lacketing for attention to the seals. Seals now are the long-sought universal seal." 9 4 Molded packing rings, made of YtTON
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sI, r reinforced with asbestos cloth, seal P+- p, i f-- - e n.; 41 J. hydraulic actuators of steel millladies. ll Reactive.nonRammable hydraulle Avids I"
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m'*' ad'. - at 550*F. G88*C.) and 1.500 pois (105.4 kgdem.8) destroyed previous packings. j
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==ur; a outlasted the previous roll by more 'hS
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, & PAGE / 7 di 2 l opp #AMS-7280 MIL-R-83248 AMS-7278D 5pec VITON Spec VITON Spec VITON original crisinal Tensile Strength, psi 1.600 1.?35 oneinal Tensile Strength, psi 1,200 1.735 Tensile Strength, psi 1.600 1.735 . kgJcm.8 112.5 122.0
, k3Jcm.' 64.4 122.0
. k g/cm.' 112.5 122.0 125 190 Elongation, % 125 190 Etongation. %
Elongation. % 125 190 100% Modulus, psi 350 880 Haroness. Durometer Hardness. Durometer , kg/cm.8 24.6 61.9 A comes 75 25 79 4 points 75 25 79 +5 -4 Hardness. Durometer T
- F.. max.
7,er mas. +5 -4 - 15 - 20
- 20 A pomes 7525 79 T.*C max.
T.*C max. - 15 +5 -4 T. *F., max. Compression Set--ASTM -15 - 20 D395 Method 3 T.'C max. Aged 70 hr. at 75'F. (24*C in Reference fuel s 70 hr. at 75'F. Tensile $rrength.% change - 15 -15 (24*C, % 15 12 Aged 70 hr. at 75'F. 04*Q in Efongation.% change - 15 - 10 Reference Fuel 5 Tensile Strength, % change ~15 -15 Hardness. pomts change -5 to + 5 -2 Aged 70 hr. at 75'F. 04*C in ~15 -10 Volume,% change o to +10 +16 Elongation % change Reference fuel e Hardness. points charige -5 to +5 -2 Tensile 5crength. % change - 20 - 15
-10 Volume.% change O to +10 +1.6 Aged 70 hr. at 392*F. (200*C in Elongation. % change = 20 5 tau #er glend 7700 Hardness. pomts change 25 -2 0 to +10 +1.6 Aged 70 hr. at 392*F. (200*C in Tensile Strength. % change - 40 - 26 Volume, % change
- Andeeol l 774 Elongation.% change - 20 -16 Tensele Strength.% change ~ 40 -13 Hardness. pomes change -15 to + 5 -9 Elongation. % change - 20 +11 Volume. % change o to +25 + 19.5 taeWer tiend 7700 -7 O' need 70 hr. at 347'F. (175*Q in nsile Strength.% charige ansation. % change
- 25
- 20
- 22
-5 Hardness. pomts change ~15 to +5 Volume. % change 0 to +20 +11.3 Aged 70 hr. at 442*F. (250*C in Alt Tensile Strength.% change - 20 -2 Hydness, points change O to -15 -7 O to +20 + 16.4 Aged 70 hr. at 482*F. (250'Q in Air Elongation. % change - 20 -10 Vziume, % change +t ccmpression 5et-A57M D395. Method 8 Tensile Strength.% change ~ 30 -2 Hardness. pomes change o to + 10 0 Elongation % change - 40 -10 Weight. % change -5 - 0.94 Standard Measurement % 10 Measurement After18-hr. Hardness. pomts change O to +15 +1 Cooling. % 15 7 weight. % change -8.0 - 0.94 Compression 5et-ASTM D395. Method s 70 hr. at 392'F. (200*Q. % 30 13 Aged 70 hr. at 528'F. (275'Q in Air C-- ; :::'n SeWM D395. Method 5 336 hr. at 392*F. f200'Q. % 55 32 Tensile Strength, % change - 35 - 20 70 hr. at 392*F. (200'Q.% 50 13 El$ngation.% change - 15 + 42
+ Hardness.pomts change -5 to +10 +1 weight. % chanse -10 - 5.06 Compressaon Set-ASTM D395. Method t-22 hr. at 392*F. (200*C. % 15 3 Compresesen Set-ASTM D395. Method 3 ' Aged 166 hr. at 347'F. (175'O Standard Measurement. % 20 15 .: g g Measurement After18.hr. r Cooling. % 35 24 4 g[. V %. . a 3). ' t Casoline pump metering shaft seal-- ) R % YtTOY Suoroetastomer since 1954. 17
' Reg. U.S. Pat. & Tm. Off.
PASC /7s; 2/
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- Chemkal eat l
;.? Acetaldehyde (
-.?* Acetic acid. 20?. (
.J Acetic acid. 30?. ( l Acetic acid. glacial (
- Acetic anhydnde (
, Acetone i Acerviene Aluminum chlonde solutions Aluminum sulfate solutions Ammonia. anhydrous i Ammonium chlonde solutions Ammonium hydroxide solutions Ammonium sulfate solutions Amyl acetate a Amyl alcohol Ai:1 i Aniline A l Analine 8:15 Aniline C:30 ASTM oil at A(3C
. ASTM oil #3 A(35 ASTM reference fuel A
. . ASTM reference fuel 8
/7 . ASTM reference fuel C Products made from VITON* with*a particular fluid also depends Asphalt WC fluoroelastomer are successfully on such variables as temperature, Banum hydroside solutions used in contact with a great variety time, velocity of flow, aeration, Beer of fluids,in many instances at stability of the fluid, degree of con. Benraidehyde tact. nature of suspended solids, etc. Benzene 8:15 temperatures far higher than are practical with other elastomers. The it is always advisable to test the o as solutio choice of premium-priced VITON is Bonc acid solutions justfied W b trouMm semice conditions before speofication. If 8'om'ne. anhydrous licuid At:1 which saves far more expensive gutane this is impractical, then tests should maintenance and downtime costs.
be devised which simulate actual 8" M ** To assist design engineers concemed service conditions as closely as possible. Obviously, your rubber k'[n*[d[d with specifying rubber components Calcium bisulfite solutions exposed to severe chemical supplier should be provided with Calcium chlonde solutions environments, the accompanying complete details os the conditions Calcium hvdroxide solutions tabulation has been prepared. It involved. since correct compounding Calcium hvoochlonte. 5*'. includes evaluations of the fluid and processing are important to the Calcium hypochtonte. 20*. 841 ! resistance of VITON versus a success of any resilient part where Carbon bisulfide chemical resistance is one of the d selection of materials whose service requirements. os de mfluences, at various temperatures Carbon tetrachionde Ai1! and for certam exposure times, range Castor oil from virtually no effect on, t Rating Key A--Uttle or no eMect Chionne gas. drv AC-complete solution of, products made Chionne gas. wet from properly compounded VITON. B-Minor to moderate effect Chloroacetic acid re e#m rangmg to We emphasize that it should be used complete destruction ,","' as a guide only. The tabulation is T-No data-likely to be chlorosulfonic acid based on laboratory tests and records compatible Chromic acid.10-50*'. of actual service performance. But X-No data-not likely to be Citnc acid solutions an elastomer's degree of compatibility compatible Copper chlonde solutions (
- Reg. U.S. Pat. & Tm. CHf.
*e
I i I o g44k d-
.ps di4Q% B+s Chemical Acetaldehyde Acetic acid. 20*.
o Rating C C - a l Acetic acid. 30% C Acetic acid, gfacial C
, Acetic anhydnde C ,
Acetone C
- l AcetWene A i Aluminum chlonde solutions A Aluminum sulfate solutions A Ammonia, anhydrous C Ammonium chlonde solutions A Ammonium hydronide solutions A Ammonium sulfate solutions A Amyl acetate C Amyl aICDhol Ai212* F ) i Aniline A.B l Aniline 8(158'F 1 I Aniline Cf300*F3 l ASTM oil 21 A(300*F3 ASTM oil #3 Af 350*F 1 ASTM reference fuel A A ASTM reference fuel B A ASTM reference fuel C A Products made from VITON* with a particular fluid also depends Asphalt Atano*F i O fluoroelastomer are successfully used in contact with a great variety of fluids,in many instances at on such variables as temperature, time, velocity of flow, aeration, stability of the fluid. degree of con.
84num hydroxide solutions 8eer tenaaldehyde Benaene C temperatures far higher than are tact. nature of suspended solids.etc. Br158'F3 practical with other elastomers. Thy It is always advisable to test the o as I tio choice of premium-priced VITON is product under actual service 8onc acid solutions A sustified by its trouble-free service conditions before specification. If 8'0*'ne. anhydrous figuid Ar2i2*F which saves far more expensive Butane A this is impractical, then tests should maintenance and downtime costs. suryl acetate C be devised which simulate actual To assist design engmeers concemed service conditions as closely as gy, jd')d
,c with specifying rubber components possible. Obviously, your rubber calcium bisulfite solutions A exposed to severe chemical supplier should be provided with Calcium chlonde solutions A environments, the accompanying complete details on the conditions Calcium hvdronide solutions A ,
tabulation has been prepared. It involved, since correct compounding Calcium hvoochionte. 5*. A ' includes evaluations of the fluid and processing are important to the Calcium hvoochionte. 20*'. 8:138'F' resistance of VITON versus a success of any resilient part where carbon besulfide A - selection of materials whose chemical resistance is one of the Carbon dioxide A
- influences, at various temperatures service requirements. Carbon monoside T 6 and for certain exposure times, range from virtually no effect on, t f,j,",',f" fg," ,
8 l g,,;,,A-g{ttle
- or no effect Chlonne gas. drv Al212*F ? '
- complete solution of, products made Chionne gas. wer A
- from properly compounded VITON. B-M nor to moderate effect ,
C-Severe effect. rangmg to oroacm acid C e We emphasize that it should be used " # as a guide only. The tabulation is complete destruction T-No data-likely to be 4 [ Chlorosulfonic acid C t-based on laboratory tests and records compatible Chromic acid.10 50*. A t of actual service performance. But X-No data-not likely to be Citnc acid solutions A !. an elastomer's degree of compatibility compatible Cooper chlonde solutions A 4 tf 1
@ d l O
- seg. u.5. Pat. & Tm. Off.
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e 1 AACE.Le dp 2 Omnical Radas Chemical Basing Chemical Rating Copper sulfate solutions A JP 3 Af400*FJ Silicone Brease A Cottonseed oil A000*F.) JP 6 Af100*FJ SKYDROL 500 C Creosoes oil Af212*F.) IP 4 Bf550*F.) 5KYLU8f 450 Cf392*F.) Cvelohenane A Kerosene Af158'FJ Soao solutions A Dibutyl phthalate 8 Kerosene 8 f400*F.) Sodium chionde solutions A Diethyl sebacate 3 Lacquer solvents C Sodium dichromate. 20% A Dioctvl phthalate g Lactic acid A Sodium hydroxide. 20% A DOWTHERM A Af212*FJ Linseed od A Sodium hydroxide. 46% % A DOWTHERM A O f400*F.) Lubncating oals AM38'FJ Sodium hydroxide. 46% % fpschforchydnn Cn00*FJ Cn22*F.) M38"eS'um chlonde solutions A Sodium hydroxide,50% f thyl acetate M88"e5'um hydroode solutions A C C Sodium hydroxide. 73% C fthyl alcohol A Mercune chloride soluticns A th ry Sodium hypochionte,5% A de Sodium hypochionte. 20%
, ,g , 8058*FJ fthylene dichlonde Methyl ethyl ketone C xide solutions A A-802&F.)
Methylene chlonde Soy rn an p7i o Af25&FJ (thylene gfvcol Af250*FJ Bf100*FJ f thylene ourde Mineral od A $ tannic chloride A Cf158*F.) Mobd XRM 206A Stannous chlonde,15% A Exxon 2380 turbo oelIlubncano A092*FJ Ferne chlonde solutions A faircraft eng. lube) Af350*F.) Steam (see water) Of300*FJ Fluosilicic acid T Naphtha An58*F.) Steanc sod T Formeidehyde. 40% A Naphthalene A(176*FJ 5tyrene A Formicsod Cf158*F.) NitnC acid.10% A Sulfur, molten Af250*F.) FREONt 11 g Nitric aed. 30% A Sulfur dioude, liquid A l l F REON-11 Tf130*F.) Nitnc sod. 60% A Sulfur dionde, gas A FRf0N-12 A8 Nitnc aod. 70% A Sulfur trionde A RION 12 8(130*FJ NitnC aod. 70% 8000*FJ Sulfunc acid, up to 5% .A
. REON 22 C Nitnc aod, red fuming 8 Sulfuric acid. 510% A FRION-22 Xn30*F.) Nitnc aod. red fuming Cf158'F.) Sulfuric acid.10 50% A FRf0N-113 A Nitrobenzene g Sulfuric acid. 50 80% A FRf0N-113 Tf130*F.) Oleic acid 8 Sulfuric acid. 60%
FRf0N-114 Af250*F ) A Ofeum.20 25% A Sulfunc aed,90%
- FREON-114 Palmitic acid A An58'FJ Tf130*F.) Sulfunc acid. 95% A Furfural Cn 58*F.) Perchloroethyfene Af212*FJ Fyrovel 220 thydraulic fluid) Phenol Sulfunc acid. 95% Af158*FJ Af212*F.) Af212*FJ Sulfunc aed, fuming (20% ofeum) A Casoline A Phenol 8000*FJ Clue A Phosphoneacid 20% A Sulf **"' **'d A Civeenn Af250*F.) Phosphone aed. 60% Af212*F.) Sunoco X5-820 fEP lubricant) Af300*F.)
n-Henane Phosphoric acid 70% annse aod,10% A A A Hydrazine C Phosphoric aed. 85% A Tartanc aod A Hydrochloric acid. 20% A Pickling solution Tetrahydrofuran C Hydrochtonc aed. 20% Af230*F.) (20% nienc aed.4% HF) A Toluene 8f100*FJ Hydrochloric acid,37% Af158'F.) Pickling solution Tnbutyi phosphate Cf212*FJ Hydrochloric aod,37% Bf230*FJ n7% nitric sod.4% HF) A inchlorethylene A i Hydrocyanic acid A Pickling solution Tnchloroethyfene On58'F) HydrofluonC acid. 48% A f212*F.) n7% nitricaod,4% HF) Cf225'FJ Tncresvi phosphate A000*F.) t Hvdrofluonc aed. 75% 8f158*F.) Picnc acid A Tnerhanolamine C l Hydrofluonc acid. anhydrous A Ntassium dichromate solutions A insodium phosphate solutions A Hydrogen A Ntassium hydroside solutions A Tung oil l A i Hydrogen peroside. 90% A .Pydraul 312C A Turpentine l Pyndine An58*F.t Hydrogen peroxide. 90% Cf270*FJ C Water Hydrogen sulfide An58'FJ gf270*F.) QFI 2023 (s4!icone brake fluid) A092*FJ Water A(212*F.) Isooctane A SAE #10 oil A Xylene isopropyl alcohol Sea water A A A Xylene fsooropyi ether Shell turbine oil 307 8f158*FJ C 8092*F.) Zinc chloride solutions A IP-4 Af400*F.)
,a, ,, ,,ememt ersea ,e et t a v pone a waew, a ce tsac s CONVit$10N5 FOR EXPOSURE TEMPERATURE 5 INDICATED IN TABLE 1
[j\ ( 100 120 122
.g 38 49 50 158 176
.c 70 80 7,
230 250
.g 110 121 350 392 7, .c 176 200 212 100 270 132 400 204 130 54 225 107 300 149 550 288
A4 CE 2 / cf *' / FOR FURTHER INFORMATION .[s ( Du Pont supplies raw VITON* fluoroelastomer to leading rubber manuf acturers throughout the world. They. in turn, fabncate stock items as well as custom pans of VITON and sell throw gn local - rubber goods suposiers or direct to end users. To obtaan more information on VITON. Contact your normal source of supply for rubber products or wnte to Du Pont for a list of manuf acturers who produce these items. iPlease be sure to indicate the paracular products in which you are interesteda If you wish to evaluate VITON for a custom rubber product or for a new application, contact the Elastomers Divis+on Distnct Office nearest you. A sales service engineer win weicome the opportunity to discuss your application and can ref er you to a rubber manuf acturer with the facilines and espenence required to follow your project to complecon.
- nes. u.s. P's, and Tm. off.
United States Sales Offkn United Kingdom I Detroit, Mi Du Pont (U.K.) Umsted 29201 Telegraph Road Elastomers Division P.O. Box 985 Maylands Avenue Southfield, MI 48037 (313) 559-6000 Hemel Hempstead Hertfordshire England 61251 5717 E. Ferguson Dnve (213) 685-6851 Australia Stow OH 44224 Du Pont (Australia) Umited 4330 Allen Road (216) 929-2 % 1 Northside Cardens 168 Walker Street Wilmingron. DE 19898 P.O. Box 930 Kirk Mill 8tdg. North Sydney, N.S.W. 2060 Barley Mill Plaza (302) 999-4850 Australia (022) 929 4455 Canada Europe Africa and Near East Du Pont Canada. Inc. Du Pont de Nemours
, Toronto international S.A.
P.O. Box 2300 Elastomers Division Streetsville Postal Station 50 52 route des Acacias Mississauga. Ontano CH 1211 Ceneva 24. Switzerfand LSM 214 (416) 821 3300 (022) 27 81-11 Montreal P.O. Box 660 , Montreal 3. Quebec Latin America and Far East H3C 2V1 (514) 861 3861 E.1. du Pont de Nemours & Co. (Inc.) Elastomers Division Export Sales Wilmington. Delaware 19898. U.S.A. E. I. DU PONT DE NEMOURS & CO. (INC.) POLYMER PRODUCTS DEPARTMENT ELASTOMERS DIVISION WILMINGTON, DE 19898 1 I g e ts have e L s (
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age 346 - e - - =, O, @nB @M rpnx0mm Cc2np2my MOUSTON M ARKETING OISTRICT December 11, 1985 Bechtel Power c/o Mr. Baldwin Toy (Mail Stop 221/5/A44) P. O. Box 3965 San Francisco, California 94119
Dear Mr. Toy:
Our November 27th telephone conversation identified three needs as follows:
- 1. Product brochure for Gulf Precision Grease.
- 2. A definition of complex as used in defining thickeners in grea'e.
s
- 3. Gulf Harmgny 150D - our brochure SP15589-882 fndicates an operating temperature of 40 - 130 F where your requirement is 38 - 150 F.
Gulf Precision Grease - Gulf ceased manufacture of this sodium soap type grease in 1979, however, the properties of this product are described in the attached product bulletin. As a general rule, we recommend a Gulferown Grease (!!thium soap type) of the same p consistency to replace Gulf Precision. Sodium soap greases, in general, do not exhibit good compatibility with other greases. Therefore, we recommend that any sodium soap (b] grease be removed before introducing any other type of grease. Short of totally dismant!!ng a piece of equipment, purging can be accomplished by pulling plugs and applying new grease untl! fresh new grease appears. Grease Thickeners - Numerous chemical compounds have been used in lubricant formulation as thickeners to produce a solid or semi-fluid product which we call a grease. , A petroleum based grease, then, is the product of a finely dispersed so!Id (the thickener) in a lubricating oil. The chemistry discussion below focuses on soap thickened and soap complex thickened greases in layman's terms; it is not a recipe for making grease nor does it address the properties imparted by the various thickeners. The thickener in a soap-type grease is produced by a chemical reaction between a fat or fatty acid and an alkall such as sodium, lithium hydroxide. The reaction is called saponification and the soap takes its name from the kind of hydroxide used. Chemically these soaps are call hydroxysterates. Soap complex thickeners were the result of efforts to improve the heat resistance of soap-type greases. They are produced by further reaction (s) of the soap thickener with , other chemicals. Numerous complexes are possible and I have not attempted to list their l chemical names. l Harmony 1500 - Our brochure indicates that Gulf Harmony Oils fully meet a requirement for hydraulic application in whic!g"responsg should be consistently good over the range of plant temperatures (normally 40 F to 130 F)." Your question as I recall is what is the operating temperature range for Harmony 150D. O ' W
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Among other attributes, a suitable hydraulic oil must possess good oxidation stability at operating conditions and be between the upper and lower viscosity limits established by hydraulic pump manufacturers (65 to 4,000 SSU at operating temperature are generally accepted to be the outer !!mits). . In recommending a particular viscosity grade, we try to choose an oil that will satisfy the (t equipment manufacturer's requirements over the entire range of operating temperatures encountered. Harmony 150D contains a mild detergent and a special high temperature oxidation inhibitor permitting its use at temperatures as high as 175 F. The usual ,
, application of Harmony 150D is for paper machine bearings where it's excellent oil / water i separation charactegistics are required. Using the viscosity parameter above, this oil may be suitable from 65 F to 225 F. At the higher operating temperatures, oxidation stability ,
becomes the controlling consideration for Harmony 150D. Therefore, our preferred I operating temperature !!mits for Harmony 1500 as a hydraulic oil is 65 F to 175 F. Should we need to explore this subject further, I will need more detail as to the application, such as the equipment manufacturer's name, make and model and any oil specification the manufacturer has provided. I appreciate receiving your questions and the opportunit'y to provide a timely response. Very truly yours, 0 . I
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D. B. Wright i Technical Representative - Marketing DBW:ke
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and agitation while resisting foaming. They are General Qualities and Characteristics especially well fortified with rust inhibitors and Refined from the finest crudes, blended with quality are outstanding in their ability to quickly and com-additives Gulf Harmony os is for gear reducers are pletely separate any moisture occurring from leaks formulated especially to meet the requirements of a or condensation. quality gear lubricant. Rey offer high film strength. high tubricity. superior chemical stability, and Recommendations good separation from water. Work-tested additives in Gulf Harmony oils enhance their ability to resist Gulf Harmony 46,68.100.150D,220 and 320 are foaming and combat corrosion. recommended for gear reducer applications in line with the general ree'mmendations of AGMA. Application Requirements American Gear Disastrous results occur when gears are permitted Mfg. Assoc. Gulf Harmony to operate without adequate lubrication. Operating Lubricant No. Grade gear reducers for long periods without using a i 46 properly selected lubricant will be equally destruc- 2 68 tive, if less dramatic. Metal-to-metal contact of the 3 100 teeth results in rapid wear and eventual failure. A 4 150D & 150 quality lubricant must have the proper fluidity to 5 220 g( ^ assure fast distribution of an oil film over the gear 6 320 teeth that will resist rupture as the teeth slide over While these grades meet most requirements. each other. He lubricant must be able to operate additional Gulf Marmony grades (32.115. 460 and effectively under varying loads, temperature and 680) are available for use in gear reducers. speed. and resist invasion of contaminants that Harmony 78 E.P. oilis a special grade made for threaten chemical stability and long life. use as a marine. geared turbine lubricant. This oil Gulf Harmony oils have all of the physical has E.P. properties to meet Military Specification and chemical properties to make them effective MIL-L-17331G(Ships) and has been approved by , the Navy against this specification. His military and eff cient in meeting the rigid requirements of gear lubrication. specification is often referred to as Navy Symbol ; ne wide viscosity range of Harmony oils that is Oil 2190-TEP. J available provides the correct fluidity and oil body Selectio'n of a grade for a particular application for each gear speed, pressure and temperature. De involves consideration of a combination of factors tenacity of Gulf Harmony and its high film strength including operating speed. loading, temperatures. greatly reduces friction and assures a sufficient oil gearing design, and equipment manufacturers' rec-cushion for shock loads. He high chemical stability ommendations. Consult with your Gulf representa-of Harmony oils amply protects against oxidation tive regarding which Harmony grades are correct and assures durability under continuous circulation for your particular applications. e , tO l
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Typical Properties
' WN N:p . ,] Geof Hannee7 32 46 68 500 115 150D 220 320 464 680 78 EP
([h Former Dmgaarum ISO %scosdy Grace 44 32 47 46 53 68 90 100 69 75 150 88/97 220 121 320 151 460
.D 680 e9EP Gravey:' API 31.4 30.5 29.9 29 28.7 28.1 27.3 26.6 25.8 25.3 29 i
%scosmy,kanemaec cst 40'C (104'F) 29.06 42.35 62.5 92.0 116.5 138.9 205 301 465 709 80 1 100*C (212*F) 5.09 6.46 8.34 10.78 12.41 14.04 18 22 23.42 31.12 41.13 9 70
%scosny. SSU 100*F 150.3 218 323 478 610 728 1064 1598 2492 3826 416 210"F 43.3 47.9 54.3 63.1 69.3 75.8 93.4 116.6 152.5 200 59.1 wacosayindex.
ASTM D 2270 102 101 102 100 97 97 97 97 97 97 98 Flash.OC:'F 410 425 450 480 500 505 515 540 560 590 475 Fre.OC 'F 465 490 515 535 560 575 585 600 630 660 545 Pour:*F +5 +5 +10 -10 +10 +5 -5 -5 -5 -5 - 10 color. ASTM D 1500 LO.5 LO.5 L1.0 Lt.5 2.0 L3.0 L4.0 L5.0 L6.0 L7.0 Lt.5 Careon Rosasue. Ramsbottom:% 0.07 0.07 0.08 0.10 0.11 0.42 0.51 0.62 0.73 0.80 0.03 Neutrakzanon Value ASTM D 974 Total Acus No. 0.10 0.10 0.10 0.10 0.10 0.15 0.15 0.15 0.15 0.15 0.16
- i O Gulf Oil Corporation h Ask the pro from Gulf G uIt- e.o. 8ex is63 Houston, Texas 77251 SP 15590-882 l
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is further enhanced because of Harmony's high General Qualities and Characteristics viscosity index. They maintain their viscosity over Gulf Harmony soils possess the properties neces- a wide temperature range, not thinning significantly sary to act as a force. transmitting fluid in modern with heat nor thickening with cold. hydraulically actuated machinery. nese include: Harmony oils are triple inhibited with highly excellent air-release characteristics. high viscosity effective additives. making them exceptionally index. stability in long. term service and ability to stable in service. Rey resist change in character-protect metal parts against rust and corrosion. such as sludging, darkening and acid formation-with time and service. Rey offer a high degree of Applicatinn Re ;uirements rust and corrosion protection, passing Procedures A and B of the ASTM D 665 method for determin-Basically, all oils have the ability to transmit force, ing rust preventing characteristics of oil. but modern hydraulic equipment imposes environ-mental operating conditions which require special
, , Recommendations' attention. Not every oil will do. De oils most suited for hydraulic applications meet these Gulf Harmony 22,32. 46,68,100 and 150 represent requirements: a range of viscosities to meet the requirements of
- 1. Response should be consistently good over the the vast majority of hydraulic systems. In selecting range of plant temperatures (normally 40*F to the correct viscosity grade to use, the manufac-130*F). Hydraulic oil should not thicken exces- turer's recommendations and specifications should
('- sively at the low range of temperatures, nor thin significantly at the high end of the scale.
- 2. Oil should resist deterioration over long service be reviewed. This is most important because toler.
ance in hydraulic systems is more critical than in most mechanical industrial equipment. Every sys-l l periods. tem requires a particular viscosity because of its l I
- 3. It should protect system elements against rust design and the specific conditions under which and corrosion. it operates. I
- 4. It should resist foaming and air entrainment. Your Gulf representative will be happy to help l Gulf Harmony oils fully meet these require- you interpret manufacturers' specifications in terms ;
ments. With Harmony in a hydraulic system, of the right Harmony grade for your hydraulic l response is dependable. A selected foam sup- synems. pressant additive gives Harmony oils excellent . Note: For heavy dutv hydraulic service and for alternate ree-air-release characteristics. This ehminates the pos- ommendations for sistems in normal senice. Gulf Harmony sibility of spongy, mushy control which results Aw oils are recommended. These oils have an added effective with air entrainment. Consistently positive control ann
- ear agent. See separate data sheet.
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Typical Properties g - m. mm ;;:y Gulf Harmony 22 32 46 68 100 150 Former Designation 4t 44 47 $3 90 77 m ISO Viscosity Grade 22 32 46 68 100 15 0 Gravity:' API 32.3 31.4 30.5 29.9 29 28.3 Viscosity, kinematic: cst 40*C (104*F) 21.36 29.08 42.35 62.5 92.0 145 l 100*C (212*F) 4.19 5.09 6.46 8.34 10.78 14.25 I Viscosity, SSU ; 100*F 112 150.3 218 323 478 762 1 210*F 40.4 43.3 47.9 54.3 63.1 76.7 l Viscosity Index, l 95 ASTM D 2270 96 102 101 102 100 Flash, OC:'F 400 410 425 450 480 505 Fire, OC:'F 445 465 490 515 535 565 Pour:'F +10 +5 +5 +10 +10 +5 Color, ASTM D 1500 LO.5 LO.5 LO.5 L1.0 L1.5 L3.0 Carbon Residue, . Ramsbottom: % 0.06 0.07 0.07 0.08 0.10 0.10 Neutralization Value. ASTM D 974, , Total Acid No. 0.10 0.10 0.10 0.10 0.10 0.10 ! Aniline Point:'F 214 220 223 231 240 246 l 1 Gulf Oil Corporation Ask the pro from Gulf GuH e.o. 80x is63 Houston, Texas 77251 l SP 15589-682
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y ,C n (I .:.2 .c 7@. . -;R-tac g.DM- d elit. . 6. .. m 2 5: .ja:E - . . g ..; y __ r - m u m ..:9 t_m ( _ __ for water spray-off, water leaching and j General Qualities and Characteristics water washout. i Gulfgem Grease is a versatile, multi- Gulfgem has also proved to contribute purpose grease for elevated temperatures, to low noise levels in bearings. high speeds and extended lubrication In applications where clay-thickened, intervals. aluminum complex, calcium complex. Performance testing demonstrates it is and sodium soap grease have previously an outstanding lubricant for anti-friction been used, care should be taken to avoid bearings, under extended periods at 350* F contamination of Gulfgem Grease as these and remains functional at temperatures as products have been found incompatible low as minus 20 E Gulfgem Grease main- with aryl diurea thickened greases. tains its consistency under shear even at intermittent temperatures of 400* E, Recommendations however lubrication intervals should be Gulfgem Grease is recommended for all shortened to approximately one-tenth of types of grease-lubricated plain and anti-those at 350 E friction bearings, especially pre packed and s sealed-for-life bearings operating at ele-Application Requirements vated temperatures and/or high speeds and The Gulf patented aryl diurea thickener in where contact with water is likely. Gulfgem Gulfgem provides unique advantages over is suitable in applications involving moder-conventional soap-based greases. It is an ate to high speeds and moderate loads. ' outstanding lubricant for ball and roller The properties of Gulfgem Grease bearings at relatively high temperatures and make it particularly suitable for dryer roll speeds, and has outperformed lithium com- bearings, oven conveyor bearings, rotary plex greases and calcium complex greases steam joints, induced draft fan bearings, in difficult applications. In bearing life electric motor bearings, commercial roof-performance tests run at 10,000 rpm and top air conditioning units and equipment 350* F under light load, Gulfgem Grease adjacent to high radiant heat sources. lubricated for over 1300 hours before bear- Its operating extremes make it possi- , ing failure, which was five times longer ble to consolidate inventories which include than competitive polyurea greases tested. more than one grade of grease. Gulfgem has performed wellin tests O
.% - fag e. Io e$ 19 -
h,Vi Typ.ical Propert.ies 4 ._ m .c - . . . . s.. . m;- ,=s glp Dropping Point: C(F) 288 (550) Penetration. D-217 Unworked 270 Worked 60 Strokes 285 Worked 10.000 Strekes 308 Color. Visual Cream Texture Smooth-Buttery Rust Prevention. D-1743 Pass (No. I Rating) Wear Test. 4-Ball. D-2266 Ave. Scar diameter: mm 0.32 EP Test. 4-Ball. D-25% L. W. I. 49.6 Weld Point: kg 400 Water Washout. D-1264 Loss at 37.8C (100F): % 0.5 Loss at 74.4C (175F): % l.0 Leakage Tendencies. D-1263 (Mod.) 24 hrs. 121.lC (250F) Total Leakage: g 0.5 Oxidation Stability. D-942 Pressure drop: kPa (psi) 100 hours 0 (0) b 200 hours 6.9 (1) / 300 hours 6.9 (l) 400 hours 6.9 (I) 500 hours 13.8 (2) Copper Strip. FTMS 791-5308 24 hrs. 100C (212F) No Corrosion Fafnir Fretting Corrosion Test GM Method 9096-P Weight Loss: mg 2.5
, Ball joint Wear Test. D-3428 Housing weight loss: mg 7.9 Brine Sensitivity Pass (no Squawk) l l
l l Gulf Oil Corporation O ASk the pro from Gulf LE . 'ife g P.O. Box 1563 b/ Houston, Texas 77001 SP 15405-981
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m' - - - 7 e _' T 2 -:-- * ,_] 2 -s 7 1;r -,m ---as r -- r n a - n-- - - - - g- ,_ i 500 hours at 99 C (210 F) and under 110 psi l General Qualities and of oxygen, indicates longer life in bearings l Characteristics with much less deterioration than greases of ! Gulferown Grease is an amber colored, but- l lesser quality. tery smooth lithium grease suitable for a wide he excellent mechanical shear stability range of uses. Gulferown has very good of Gulferown allows use where lesser greases mechanical stability and excellent oxidation . might mn out of poorly sealed bearings. stability, insuring long life. It is specially inhibited against mst and corrosion and has superior resistance to the washing-out action Recommendations Gulferown Grease, as a true multipurpose of water. Gulferown maintains good pump-grease, is suitable for applications found ability, even in cold weather. and is ideal for throughout industry, such as electric motor centralized grease systems. bearings, fan bearings, pump bearings and other plain and antifriction applications. Application Requirements Gulfemwn Grease is suitable for bearing It's recommended for use where water I contamination is encountered, and is suitable temperatures up to 121.1 C (250 F) and down for bearings operating at temperatures as high to - 12.2 C (10 F). He water washout test as 121.1 C (250 F) or higher if replenished on the No.1,2 and 3 grades shows them to be frequently. Its pumpability makes it especially applicable where water contammation is en-suitable in centralized grease systems, even countered. He excellent oxidation resistance, as indicated by the low drop in pressure after at low temperatures. 0 O
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General Qualities and or where. under high pressure conditions, the Characteristics action of the machine elements are oscillating. Gulferown Grease E.P. is a multipurpose E.P. grease with a light amber color and smooth Gulf Recommendations buttery texture, available in NLG1 consisten- Gulferown Grease E.P. is recommended as cies No. O.1. 2 and 3. It's a lithium soap a multipurpose grease in many applications. thickened grease possessing extreme pressure. Specit'ically in such uses as electric motor excellent load-canying and antiwear prop- bearings fan bearings. and pump bearings. erties in both steel-on-steel and steel-on- and for those applications where water con-bronze applications. In addition. it effectively tamination is encountered. Pumpability is inhibits against oxidation and rust. excellent and Gulferown Grease E.P. is rec-ommended for service in centralized crease Application Requirements systems. Gulferown E.P. No. O is rec'om-p Gulferown Gmase E.P. has good high tem- mended for low temperature / low torque applications. Gulferown E.P. No.1 is rec-J perature characteristics and may be used at temperatures as high as 121.l*C (250 F) or ommended for centralized pumping systems higher if the grease is replenished frequently. at temperatures as low as - 12 C (10*F). Gulferown Grease E.P. is suitable for most Gulferown E.P. No. 2 can also be used in grease applications where the loads are high, automotive applications when an extreme and where shock loads may be encountered, pressure No. 2 grease is required. l l OG
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g.. _ _ _ _ m __ _ __ q7 inventory Controi General Qualities and Characteristics One product performing two functions, a premium Gulf E.R Lubricants. HD-Series are high quality industrial gear oil and a premium mist oil. (sulfur-phosphorus) type gear oils, specifically des.igned for severe duty conditions. They are produced from high qual-icy base stocks which provide excellent oxidation stability. PPliCations and Recommendations Gulf E.R Lubricants. HD-Series meet all the requirements of high viscosity indexes. high flash and low pour points. Dese lubricants pass all the AGMA requirements for E.R AGMA Standard Specification 250.04 (September,1981). type gear oils. All grades except Gulf E.R Lubncant for E.R type gear oils, also those of Cincinnati Milacron. HD680 contain a highly effective stray mist suppressant Wheeling Pittsburgh Steel Corporation, and U.S. Steel and are premium quality oil mist tubricants. Corporation for sulfur-phosphorus gear oils. Gulf E.R Lubricants. HD-Senes are recommended for the lubrication of bearings and gear drives in extra heavy Features and Benefits service. ney are recommended for steet mill gear enves
+ Wear Protection which are subjected to large quantities of water, dirt, scale The modem sulfur-phosphorus additive package pro- and boundary lubrication.
tects against scuffing, spalling or welding of mating Dough primanly gear lubricants, these oils arc suit-gear teeth and bearing surfaces under high ambient able for use in many types of plain or antifriction beanngs temperatures or loading conditions. which are subjected to heavy shock loading, overloading or
+ Good Demulsibility high localized pressures. ney may also be used success-Superior water separating characteristics. fully in worm gear lubrication. These HD-Series gear
. Wide Temperature Range Performance lubricants are especially recommended where extended The high quality, paraffinie base stocks provide excel- drain intervals are required.
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(j tent oxidation stability, high viscosity indexes, high flash and low pour points, Gulf E.R Lubricants. HD-Series are outstanding for mist applications, where shock loading and overloading
- Formulated for Misting Systems - are encountered. Rolling bearings plain bearings, slides Excellent oxidation and thermal stability coupled with and ways and chain dnves may all be mist lubricated with ,
I a special mist control additive make these lubricants these products. ney minimize reservoir sludging and l suitable for the most severe misting applications. mist head plugging. Gulf E.P. Lubricants, HD-Series l NDice HDise HD224 HD320 HD464 HD680 Golf E.R Lebu HD32 ND68 AEP SEP 6EP 7EP SEP AGMA No - 2EP 3EP 29 1 28 4 27 6 26 9 26 2 23 6 IS I Graverv APl 30 7
%scosary. css 438 633 1 30.00 64 8 93 0 138 9 203 293 40T tIO4"F) 23 42 30 OS 38 43 i
100*C t 212*F) $ 39 8 64 11 13 14 el 18 48
%scoserv.stiv s 1556 1302 3405 IS4 $ 483 727 1070 37 8'Cil00"F) 335 Sa 5 i16 6 147 4 187 3 98 9"C(210*F)
- 44 3 55.3 64 4 77 3 502 800 99 98 90 Mscosary lases lia 10$ 10$
2271440n t 229:44Si 232r450s 238s 460i/ 24)e 470) 249:480s 15 2:48S1 Flash. OC. "C i*F) 199:390) 260 3001 26ee S10 274a S 2$i 283d S4Si 088a 3501 Pive. OC: "C s"F) 227(440t 2491440) 23h49$1
- lBion - 1840) - 18401 - 1840s -1840s - 12r e lon Pour *C t"F) - 18801 - 1880s L 3.3 L35 L40 t45 4S $0 LSS SS Conor. DIS 00 0 36 0 40 0 as 0 49 0 65 Carton Resusine. Rams :% 0 26 0 26 u.31 Neutraliaanon No.. D664 0 86 0 86 0 86 Total Acid No. 0 Se 0 86 0 84 0 86 0 86 Tamaca ress 29 Sc6Si 31 88 'Oi 29 5<65: 29 Sc65) 29 $<636 29 SieSi 29 S<65:
tever Load kg albi 29 S(65) Ress.Prevennve Tess. D665. 24 Hr. passes passes passes pasm l Procedure A passes passes passes passes passes passes J passes passes passes passes passes passes Precedure 8 l J M Gulf Oil Corporation l Ask the pro from Gulf GuI l e.o. sox 1563 sP ms>m W Houston, Texas 7725f
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g 44g _ ,r gg .=-w_m_.-- m _ =- .- . _ :::p < General Qualities and Characteristics General Recommendations } Gulf Harmony AW oils were deseloped to proside max- Pump Ts pe-Harmons AW imum pump life and trouble-free service in industrial and Vane. Gear and Axial Piston Pumps 32. 46 or 68 AW mobile hydraulic systems. They fulfill the demand of hydraulic pump and hydraulic machinery manufacturers Oilgear Pumps requiring Heavy Oil 100 AW j l for a prerruum hydraulic oil. They possess proven protee- Piston Pumps iRadiah b 150 AW. j tion against w ear. outstandme oxidation and thermal Pumps reqmne cura Heavy Oil stability and are able to satisfy low ambient temperature , applications in appropnate viscosity grades. These in the selection of an oil from this chart. progress to l properties make them suitable for vane gear or piston heavier viscosity as operating pressures increase or g [(. J type hydraulic pumps. and motors. range of temperature increases. Whenever possible. i refer to original equipment manufacturer's recom- ; Features and Benefits mendation for viscosity grades. [-
- EXCELLENT WEAR PROTECTION - Provides l' -
highest wear protection. especially with operating pres. Package Size p. : sures in the range of 3000 to 6000 pounds per square Available in bulk and 55 gallon retumable steel drums. , inch. Harmony 32 AW. 46AW. and 68 AW are available in ! R< 5 gallon pails'
- LONGER R.UID LIFE -The proper combination of c, high quality base oils and selected additive components
[, provides outstanding oxidation and thermal stability and R [ v lower sludge forming tendencies. n I
- RESIST FOAN11NG AND ENTRAINED AIR-Re- C duces equipment noise, spongy or erratic operation and [ ~
rapid oxidation of the fluid that may result from exces. ' sive aeration. ,.
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- GOOD DESIULSIBILITY-Harmony AW Oils r' possess excellent water separation properties, thereby 'J minimizine emulsions which can cause lubrication !
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- StEETS EQUIP 5 TENT NiANUFACTURERS' I.
REQUIREhtE.NTS - Approsed by major manufactur- f. ers specifying a premium hydraulic oil providing wear l protection, oxidation resistance. corrosion and anti-sludge forming tendencies (see inside for more details). ((j{
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> + INVENTORY CONTROL- One hydraulic oil may be $ used in many varied applications. therefore reducing fJ cost and chances for misapplication. n 9.i l l . l
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m._,. m p i (hidation and Thermal Stabilit,s tection and these oils can be recommended for use in l Oxidation of hydraulic fluid can occur at the oil-air inter. Sperry Vickers equipment. These oil, also show excellent face and withir5 the oil from reaction uith dissolved and wear protection in the Rexnord " Cyclic" Test utilinng a - entramed air. The products of this reaction include weak Racine model"S" pump. acids and soaps. Acids can pit metal surfaces; soaps tend to hold moisture which lead > to plugged pressure sendng Present3 Foam and Entrained Air onfices and flow paths. In addition, moisture containing Not only do they resist foaming. they also readily release soaps tend to reduce the effectis eness of many filtration entrained air. Foaming appears as atr bubble > abos e the systems. Another location where high temperature oil surface of the fluid. and entrained air 23 bubble > below oxidation occurs is at the outlet i I the pump. w here it the surface of the fluid. Both situations. if not corrected. forms a resinous material that c: n deposit on hot surfaces may result in spongy, erratic operations. rapid oil oxi-t pump rotor. relief valves and spoolsi causing them to dation and noise. stick. Resinous material forms sludges w hich combine , with dirt and moisture w hich float around the system Rust Protection ;i plugging small openings in valves and tilters and interfere The component surfaces in a hydraulic sy stem are pro-with heat tran3fer from the reservoir. Gulf Harmony AW tected against rusting with Gulf Harmony AW Oils. They Oils provide excellent resistance to the degradation effects provide superior rust protection as rneasured by both pro-of high temperature oxidation. cedures A (distilled water > and B tsalt water > of ASTN1 I Wear Protection Operation pressures in the range of 3000 and 6000 . Viscosit,s Rance . giounds per square inch are now commonly encountered Five grades of Gulf Harmony AW Oils are available to in industrial applications. With these pressures. mechan- satisfy the vast majonty of hydraulie system require-ical tolerances are closer and the need for w ear protection ments. Gulf Harmony 32AW. 46AW and 68AW oils are charactenstics is greater. Gulf Harmony AW provides the recommended for the majority of vane. gear and nial lughest wear protection for hydraulie systems operating piston pumps and motors encountered in industry. The under the most severe conditions. choice of a particular viscosity grade depends on sy stem Gulf Harmony 32AW.4bAW.68AW.100AW and operating conditions. Stost pump manufacturers recom-150AW are approved by the Denison Division of Abes mend that certain minimum and maximum siscosity Corporation against their HF-0 and HF-2 specifications. ranges at start-up and dunng running be maintained. The The HF-0 approval required that Gulf Hannony AW be proper grade for a gis en sy stem should be chosen so that pump tested by Denison in a complex hydraulie system over the entire temperature range encountered - the using both a large vane and a large axial piston pump. start-up viscosity and the operating viscosity range - the The vane pump w as operated at 2.500 psi and the piston pump manufacturer's requirements are met. pump at 5.000 psi with the oil inlet temperature held Gulf Harmony 100AW satisfies the requirements of at 160*E for the first seventy hours and then increased to certain Oilgear pumps whichN;ecify the use of a "heas>" 210*E to the conclusion of the test at one hundred hours. hydraulic oil. Both pumps were in excellent condition and showed insig- ' Gulf Harmony 150AW is offered to satisfy the higher nificant wear after one hundred hours of test time. viscosity requirements of certain radial piston and special Gulf Harmony 32AW. 46AW and 68AW are also gear type pumps w here the manufacturer specifies an oil approved against Cincinnati Stilaeron Antiwear Hydrau- in the 129.5-194 2 eSt range at 37.8'C.1600-900 SSl? lic Oil specificanons P-68. P-70 and P-69. respectively. range at 100'E i. They are recommended for all Cincinnati Stilacron equip-ment requinng either R&O turbine quality or anu wear I.ubrication Applieutions rype hydraulie oil. Gulf Harmony AW Oils are recommended to handle the Gulf Harmony AW Oils hase pared the Sperr) Vick- more severe hydraulie applications, and will satisfy many
' ers 35VQ25 high prenure vane pump test w here the oil is lubrication applicanons. such as machine tools. gear cases subjected to 3000 pu and 200 E The results of this test and miscellaneous beanng sy stem 3. so a3 to permit a l showed Gulf Harmony AW prosided escellent wear pro- nunimum number of lubncants to be in entoned in a plant.
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'I)piuti Propertie 32AW 46AW 68AW 100AW L(OAW ISO Viscosity Grade 32 46 68 100 150 ASTN1 Viscosity Grade No. tSaybolti 150 215 315 465 700 !
Gravity: API 31.2 30.4 29.7 29.0 28.3 ; I Viscosity. Kinematic: cst (; l 40 *C i 104*Fi 30.04 42.70 62.9 % 138.2 [ 1 100 'C t 212'Fi 5.26 6.57 8.43 11.03 14.10 }D Viscosity. SSU t.' 100'F 155 220 325 500 724 lj 210*F 43.9 48.2 54.6 64 76 b Viscosirv index. ASTN1 D 2270 106 105 104 99 99 E l Interfacial Tension. D 971 0 ' 77'F :dytt em 31 31 31 32 32 Flash. P-51:'F 400 405 450 465 475 (0 Flash. OC:'F 425 430 470 490 500 l Fire. OC:'F 455 470 500 545 565 O Pour:'F - 25 - 25 - 20 +5 +5 9 (, Color. ASTN1 D 1500 Carbon Residue. Ramsbottom:G L 1.5 0.27 L 1.5 0.27 L 1.5 0.28 L2.0 0.29 L3.0 0.33 i' 1 Rust Preventive Test. ASTN1 D 665 E Procedure A. 24 hr Passes Passes Passes Passes Passes Procedure B. 24 hr Passes Passes Passes Passes Passes _ Neutralization No. ASTN1 D 974 Total Acid No. 0.50 0.50 0.50 0.50 0.50 Oxidation Test. ASTN1 D 943 Time Oxidized , Hr. to 2.0 Acid No. 2500 + 2500+ 2500 - 2000 - 2000 - F Emulsion. D l-101.130*F !.' l
- Test Run at 180*F Distilled Water. Niinutes 40-40-0 (Si 40-40-0 t Si 40-40-0 t 5 i 40 40-0 t 10e 40-40-0 t IOP Aniline Pomt. ASTNI D 6tt:'F 221 225 232 241 245 k
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/, A ') (X' Chewan Chevron U.S.A. Inc. P.O. Box 4256. Houston. IX 77210 . Phone 17131827 4800 l February 24, I?86 ( h MECHANICAL i EQUIPMENT QUALIFICATION Mr. Baldwin Toy REFERENCE f RA Bechtel Power ( P. O. Box 3?6S (Moll Stop 221/S/A44) y A;t b 1 *r . Son Francisco, CA 941I?
Dear Mr. Toy:
In our February I? telephone conversation, you requested our thoughts, from o radiation
- tolerance standpoint, on the suitability of Gulf Seneco 68 in a mild radiation environment possibly as high as 2,000 rods.
I have discussed this application with Mr. G. J.'Schreuders at Chevron Research and we do not foresee any difficulty with Seneco 68 in the 2000 rods range. Sincerely,, 9
. 4 D. B. Wright Technical Representative Dew:pbm O
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GULF SENECA y g g d[ For General Purpose A .g g ' . l Industrial Applications [H l dU i l t Tv=3cin n rirDTTPL'mm:?T"'a~ e.
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3 ..__ General Qualities and ditions. Since they're non-inhibited mineral Characteristics oils, they may be used with any type filter, Gulf Seneca is a non-inhibited mineral oil including fuller's earth, manufactured from selected naphthenic Gulf Seneca 45 and Gulf Seneca 49 type crudes. Its low pour point and good meet the requirements of Military Speci-oxidation stability are developed by sol- fication MIL L-15016B Amendment 1, . vent processing and refining. Low carbon for Military symbol 2110 and 2135 oils, residue, freedom from gumming tenden- respectively. cies, and light color are other important properties of this oil. Carbon formed from Gulf Recommendations the combustion of these oils is soft and All grades of Gulf Seneca are suitable for flaky and therefore easily removed. hydraulic systems, circulating systems, and general purpose applications requiring a Application Requirements low pour point and good oxidation sta-The nine viscosity grades of Gulf Seneca bility. In particular: provi.de an across-the-board capability in Gulf Seneca 42,45 and 49 are recom-(-(~'
} general purpose industrial lubrication.
They are used effectively for oil lubricated mended for refrigeration compressor lubri-cation where naphthenic type non-inhibited ball and roller bearings; hydraulic and cir- mineral oils are required. Gulf Seneca 49 l culating systems; enclosed light. duty, high- is being used in both rotary and recipro-speed gears; reciprocating steam engines; cating ammonia refrigeration compressors machine tools, and general machinery having evaporator temperatures as low as where lubrication is accomplished by ring- -50 F. oilers, chain-oilers, sight feed cups, bottle Gulf Seneca 49. 54, and 57 are recom-l l oilers, drip cups or hand application; and mended as compressor lubricants for both for certain process applications. Since low starting temperatures and. high op-these products contain no additives, they crating temperatures where carbon deposits will not react with or displace the fluid in are a critical problem. liquid filled lubricator sight glasses. Gulf Seneca 39 and 42 have good burn-l Application requirements which most off characteristics and have proven to be frequently dictate the use of a Gulf Seneca outstanding roll oils for use in Sendzimir I grade, however, are low carbon build-up, mills when rolling both ferrous and non-soft, flaky characteristics of any carbon ferrous metals. that might form, and low temperature Gulf Seneca oils are eminently suited , operating capability. for use as rubber compounding oils and in The low pour points of all Gulf Seneca other process applications wherever good grades make them highly desirable in ap- compatibility. light color, and color sta-plications involving low starting or oper- bility are required. ating temperature or where machinery The low odor, adhesiveness and vis-or equipment is subjected to low ambient cosity of Gulf Seneca 66 make it suitable , {C temperatures. for use as an air filter oil on reusable air In applications requiring efficient filtra- conditioning filters to capture dirt and dust tion, Gulf Seneca oils mect all normal con- from the air. l
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Typical Properties of Gulf Seneca "* Oils " G 7 '* I( '8 y :p u.v; ; 2e:4"" Y
.,64 AIT A6 ' ,Tti 84 39' .42 A5' 49 ASTM Viscosity Grade (Saybolt) 105 150 215 315 - 465 700 1000 -
27.9 27.0 26.1 26.0 26.1 25.5 25.2 25.0 Gravity:
- API 28.5 ,
Viscosity, SUV: Sec. 407 509 766 978 1245 100 F 110.0 146.6 204.0 305 75.4 84.6 39.2 41.6 44.8 49.4 53.6 57.8 67.4 210 F 53 63 61 60 60 59 61 62 Viscosity Index 53 Flash, OC: F 345 355 370 400 400 430 '435 455 500 390 410 450 445 465 485 515 575 Fire, OC: F 380 Pour: F below* 40 35 15 10 - 10 L0.5 L 1.0 L 1.0 L 1.0 1.0 0.5 L1.5 L 1.5 ' L 1.5 , w Cotor, ASTM D 1500 0.06 0.06 0.06 0.07 0.08 0.08 0.09 0.09 0.10 Carbon Residue, Ramstiottorn % Copper Strip Test 1 1 1 1 1 1 1 1 1 212 F,3 Hr. Neutralization Value ASTM D 974 0.03 0.03 0.03 0.04 0.04 . Total Acid No. 0.03 0.03 0.03 0.03
~
199 203 205 213 216 221 226 229 Anillne Point: F 189
* "below" appiles only to Gulf Seneca 39 \W sp.tostamin Gulf Oil Company-U.S.
I gN I Gulf Building Houston, Texas 77002
1 [ Chevron U.SA Inc. C 8554 Katy Freeway. Houston. Texas 77024 . Phone 1713182M800 mo s. mo.un rx mio 3muary 23,1986 d;ych 2.h YAGtE -"~ Bechtel Power p ,,..- 1? c/o Mr. Baldwin Toy - P. O. Box 3965 (Mall Stop 221/5/A44) ' San Francisco, Californla 94119
Dear Mr. Toy:
This letter is intended to document our several telephone conversations dating back to early December,1985, to respond to two questions that you posed over this period.
- 1. Can we predict the effect of radiation on other Gulf products based on previous laboratory work? 'The products are: Seneca Oils (particularly Seneca 68), Super Duty Plus Motor 011, Automotive Transmission Fluid - Dexron II, EP Lubricant HD 220, all Gulferown and Gulferown EP greases, all Harmony Olis, Lubcote and
. Premium Lubcotes.
- 2. Can we provide product degradation curves by product or family of prcducts to be used to establish a basis for lubricant change-out intervals? Probably need two
' curves; 6ne to consider radiation exposure / rust inhibitor loss and a second as a 'q ,
function of operating temperature / oxidation.
'- First, let's consider predicting radiation effects based on previous laboratory work. On 3anuary 13,1986, I spoke with Mr. Gerard Schreuders at Chevron Research to address this question.
Mr. Schreuders, you may recall, is the author of the report which I sent to you in October titled " Irradiation of Gulf Lubricants - 2nd Edition". In essence, his comments were that laboratory results could be extended to other products of suffIciently similar composition. Speelfically, for the products of concern to you, our position is as follows. EP Lubricant HD 220 should exhibit tendencies under radiation much as EP Lubricant HD 150 which we have evaluated. Other Gulferown greases should behave similarly to Gulferown Grease No. 2 since the major difference is the quantity of soap; likewise other Gulferown EP Grease should behave similar to Gulferown EP Grease No. 2. Other Harmony c11s (excluding the Harmony AW series) should react sImilarly to Harmony 46 and 115.
- Harmony AW oils should react to radiation in much the same way as the Harmony 32 AW test results reported.
We beve net t~ted en ;- .itet :hikr 13 ox Cu.r.a Olh, ATF-
Dear. II,
Sopen l>uty Plus, Lubcote or Premlum Lubcote products, therefore, we do not have a basis for predicting the effect of radiation on these products. However, our concerns extend l beyond radiation for some of these products and their application in the power plant. The l j application of automotive type products such as Dexron 11 and Super Duty Plus (assuming i they are not for automotive type equipment) In an Industrial plant, causes some concern to me. Our radiation research work did not include motor oils, etc., because we did not p anticipate such a need in a nuclear environment. It may be that the app!! cation of these automotive products is based on a strict Interpretation of the equipment vendor's
- ~ - , ~ . - - - - -, , , , , , - - - - - , . - , -
Page Two Mr. Baldwin Tcy - - NkC1E 5 of74 - ~
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January 23,1986 7 .. ~7 lubricant recommendation when an industrial lubricant may perform as well, or better, in the specific piece of equipment. In a 1/20/86 conversation you told me that the Super Duty Plus is to be used in a diesel generator in a mild radiation environment, possibly as high as 1,000 rads. We foresee no difficulty with Super Duty Plus tolerating 1,000 rads - (not megarads)la this application. The second question concerns degradation curves. While it may be possible to generate the type of degradation curves which you have requested, we prefer a more generalized approach to lubricant change-out Intervals (particularly when due to radiation exposure). In a nuclear plant, it is our understanding, lubricants are not exposed to large quantitles of
- radiation on a day-to-day basis. Instead, exposure occurs primarily because of some kind i of accident such that the exposure is very large for a relatively short duration; obviously these accidents are going to be unpredictable in all aspects - random events. At this point, the other unknown just prior to an accident is the condition of the lubricant in each piece of equipment.
Numerous factors can degrade a lubricant. They include, in no particular order, cumulative radiation exposure, higher operating temperatures, dirt, wear metals, water, contamination from mis-lubrication and others. The best techniques that we have seen employed throughout industry include: 1) a comprehensive preventive maintenance O program that includes periodic laboratory testing of tubricants used in key items of equipment and 2) a firm commitment to preventive maintenance throughout the plant management. Our Irradiation testing of Gulf lubricants led to two conclusions. First, all oils should provide sufficient lubricating properties (for their intended application) to permit continued equipment operation for some period of time sufficient, at least, to allow for a safe and orderly plant shutdown, even though some losses have or are occurring in rust protection and oxidation stability. Second, there is no evidence that the lubricants would Interfere in any way with shutdown procedures. Therefore, our general recommendation to the nuclear power Industry using Gulf lubricating oils and greases is to replace the lubricant as soon as practicable after exposure to 50 megarads and preferably after exposure has reached 10 megarads. One final comment. On occasion I have mentioned that Chevron has a family of products
- NRR Lubricants - which are nuclear radiation resistant. Enclosed is Chevron Technical Bulletin No.10 for your future reference.
1 Mncerely,
. L)
D. B. Wright Technical Representative O DBW:ke l l
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*
- Published by Chewee U.SA trn:. to report important product technicat information. -
FAC1 E 6 of2k - {lthevron ' r- m Technical Bulletin @ Revised No.10 12-20-83 CHEVRON NRR LUBRICANTS ~ ~ Chevron markets a line of Nuclear Radiation-Resistant Lubricants -- currently two olis and four greases -- for use in environments subjected to high radiation dosages. These specialty products have successfully served the nuclear industry since the 1950's. To the best of our knowledge, they are the most radiation resistant of any products of this sort and are the most readily available, certainly in the U.S. if not throughout the non-Communist world. Because of their expense and limited application, Chevron NRR lubricants are available for sale only through the Central Order Desk, Richmond, CA. Sales are F.O.B. Richmond freight collect -- products will not be shipped until a Purchase Order or Telex is in hand. For Information regarding price and availability call (415) 620-2084 or write to: Chevron U.S.A. Inc. Central Order Group , fO ' P. O. Box 1272 M-l
. Richmond, CA 94802 1 .
The purpose of this Bulletin is to assist in the handling of technical and sales
. Inquiries. Technical questions not covered here should be directed to Chevron Research Company, Marketing Services, 576 Standard Avenue, Richmond, CA 94802 (Telephone (415) 620-3000, Ext. 4079).
Nuclear radiation affects organic lubricants. Any resulting change Is' generally undesirable because lubricant properties are highly optimized for a given application. Thus, it is important to use radiation-resistant oils and greases in all applications subjected to high doses of destructive nuclear radiation (radiolysis). Certain general effects are common in the radiolysis of both oils and greases. Chemically, hydrogen and other gases evolve; and unsaturation and cross-linking are produced in the organic molecules. Both -low and high molecular weight l materials are formed -- the larger molecules predominate. This is reflected Greases initially l physically in an increase in viscosity and ultimate gelation. l become softer due to attack on the gelling agent. Eventually, they harden as the l base oil cross-links. Encl. - Tables I-VIII Limited Distribution Technical Representatives Figures 1 and 2 l Sales Representatives ( - Others Upon Request D
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1 l There are many specific radiolysis effects depending upon the composition of a given lubricant. For example, diester synthetic base oils, phosphate esters l (antiwear additives), and halogenated materials (EP agents) each produce acids when exposed to low radiation doses. Common polymers such as polybutenes and l polymethacrylates cleave readily and thus lose their V.I.-improving function. ! Silicone antifoam agents are also easily destroyed. The approximate order of ' radiation stability of organic fluids used in lubricants is shown in Figure 1. High aromatic content promotes radiation resistance.' . Other factors also affect stability. An oxidizing atmosphere is bad and increasing ; temperature low'ers the useful life of lubricants. Fluids below polyphenyl ethers in
- l stability in Figure 1 can have radiation resistance improved by including selected additives.
Chevron's nuclear radiation-resistant lubricants are made from alkyl-aromatic-type base oils and contain special additives. They retain their physical properties I and lubricating ability over a much wider range of radiation doses than conventional materials. l Conventional soap-gelled, mineral oil-based greases will generally withstand about
- ( 107(10 million) rads.1 Special conventional greases will withstand doses of at least 108(100 million) rads. Much higher doses can be tolerated by the NRR products.
( Conventional compounded oils will generally endure more radiation than similar greases, but the oils exhibit wide variations in the doses they will withstand. These variations depend on the base material, the additives used, the exposure conditions, and the performance property being measured. Our radiation-resistant lubricants are described in Table f.2 Information on operating limits and recommended uses is included. 1 I Tables II-VIII give pertinent test data.2 , l l l 1A rad is a unit of radiation energy absorption: 1 rad = 100 ergs taken up by each gram of absorber = 4.3 x 10-6 Btu /lb. i 2This information is based on a wealth of data developed previously on similar materials (see Bolt, Carroll; " Radiation Effects on Organic Materials," Academic Press,1963; Chapter 9, " Lubricants"). Although chemical integrity has been i maintained, the actual lubricants offered for sale now are not identical with those ' originally developed. The present lubricants have not been exposed to tests with radiation. This has not been necessary due to the background cited. I I e O e , r- -~,,,r---- -
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. CHEVRON NRR LUBRICANTS Radiation Operatin Dose Limit - Recommended **se Product Renne.*C(gF)8 100 Million flads Fieduct Description ,
Nuclear Radiation- . Resistant Greases Premium synthetic aromatic oil. Antifriction bearings up to 10.000 Chevron NRR -23 to 163
- 30 aodium terophthalamate es11 ant, and rps, motors, pumps, accessories.
Grease 159 (-10 to 325) selenide oxidation inhibitor. 6 Synthette aromatie oils, silica Low speed, high load s11 ding sur- t Chevron NRR -18 to 93 50 faces; screw mechanisms; provides Orease 235 (0 to 200) gellant, and selenide oxidation residual lubrication in remote j 2nhibitor. Also contains graphite and molybdenum disulfide as machinery, e.g., remote valves. a
" residual lubricants."
l l synthette aromatie olls, sodium Antifriction bearings up to 10,000 Chevron NRR -18 to 121 50 Terephthalamate sellant, and rpm; valve activating and screw Grease 335 (0 to 250) mechanisme. sel..enide oxidation inhibitor. 1 A soft version of NRRG-335 con- special product developed for ' Chevron NRR -18 to 93 50 taining molybdenum disulfide, enclosed gear trains. , Grease 509 (o to 200) f Nuclear Radiation- l p Resistant 011s l 25 est at 40*C synthetic aromatic Hydraulic pumps and accessory equip- M t,nevron NRR 7 to 107 (+20 to 225) 50 oil plus polymers monts gear trains; control mecha- Im j 011 358 - selected to resist nisms. e viscosity changes during irradiation; .; g. Chevron NRR 7 to 107 50 280 cst at 40*C also contains sele- i (+20 to 225) nido osidstion ,; 011 360 inhibitor. 1 i iln airs een'b. .it.nded in in.rt atmosonere. 4
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.tesults ASTM -
NRi Grease Test Method 159 235 335 509 J Worked Penetration, Pso D 217 260 290 290 370 Drspping Point, *C D 2265 260+ 260+ 260+ 260+ Oil Separation, 25'C, 24 Hr, 5 D 1742 1 0 1.3 2.8 8.7 il Separation, 100*C, 30 Hr. 5 791-321 1.2 17 2.6 28 ur-Ball Weld,)cg D 2596 - 175 - 190 rd Wear Index, kg D 2596 - 38 - 31
' cur-Ball Wear, 20 kg, 54*C, D 2266 -
0.77 - 0.71 O
. . 1800 rpm, 1 Er, aun Extracted Oil Viscosity: 40*C, cst .D 445- 64 al 35 32 100*C, cst 90 7.2' 6.0 5.4 '
Viscosity Index D 22702 118 140 115 100 Thin Film Oven Life: 121*C , Days - 16 39 33 149'C, Days 30 6 12 5 l 177'C, Days 9 - - - 2 Faderal Test Method aJ. L. Dreher, " Predicting High Temperature Performance of Lubricating Greases," NLGI spokesman 2_l,, (2) 13 (1957) I CNEVRON RESEARCN ! COMPANY RICIINGAS. CALIF 0051A , 7-16-80 ROB l ,
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TABLE III PROPERTIES OF UNIRRADIATED CHEVRON NRR OILS ASTM Test Typical Results on Chevron Test Procedure NRRO-355 NRRO-360 Viscosity, 40*C, cst D 445 25.2 282.8 Viscosity, 100*C, cst D 445 4.6 18.4 Viscosity Index D 2270 91 64 Pour Point, "C D 97 -7 -12 Flash Point, COC, *C D 92 138 210 Color . D 1500 6.0 7.0 Copper Corrosion at 100*C D 130 2C 8 2C5 sulfur, Mass 5 D 2622 0.006 0.005 -
- Evaporation, 5, 22 Hr at 100*C 28.4 1.5 Sulfated Ash D 874 <0.002 <0.002 1
I CHEVRON RESEARCH ! COMPANY I l nienisono, catirceura l ROB 7-17-80 , 1
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TABLE IV TEST DATA ON CHEVRON NRR 159-TYPE GREASE Radiation Dose, 100 Million Rads 0 7 ASTM Penetration Worked 60 Strokes 261 330 Worked 100,000 Strokes 325 307 ASTM Drop Point, 'C 260+ 260+ Oxygen Bomb Copper Corrosion, 100 Hr at 100*C Slight Stain Slight Stain oxidation, 100 Hr at 121*C, psi Drop 9 24 Water Resistance, 5 Grease Loss 0 0 5 Evaporation,49'C 22 Hr at 1 1.7 3.1 22 Hr at 204*C 21 18.5 k arent Viscosity, Poises (%- ~
'C at 12 Sec-1* -
7000 '2600 /~h O'C at 20 See 5000 2000 Low Temperature Torque Temperature, 'C
-54 -18 4 -54 -18 4 Starting Torque, g-cm - 2767 554 - 1106 554 Running Torque, g-cm -
553 185 10.325 369 344 Navy Gear Wear Test, Wt Loss of Brass Gear 5 Lb Load, mg/1000 Cycles 2.0 1.8 10 Lb Load, mg/1000 Cycles 57 50 Bearing Performance 10,000 rpm, Hr at 149*C (Repeat runs) 1577(634) 306(265) 10,000 rpm, Hr at 177'C (Repeat runs) 400(279;188) 196(196) I CHEVRON RES URCH COMPANY RICNMONO. CALIFORNIA 7-17-80 ROB ,
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to 6 pounds; helium atmosphere. 11000 hours represent incident electromagnetic radiation of 1 35 billion rada plus 3 2 x 10 18
- thermal neutrons /sq. cm, plus 0.64 x 101 "
fast neutrons /sq. cm; this roughly corresponds i to 1.4 billion rads, ignoring thermal neutronu. i
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TABLE VI . TEST DATA ON CHEVRON NRR 235-TYPE GREASE NRRG-235 Dose, 100 Million Rads 0 41 to 45' 4 i ASTM Penetration 379: 388; l Worked 60 Strokes 290 397 ASTM Drop Point, ac 260+ 260+ 1 Bearing Performance in Size 204K Ball Bearing, Hr to Failure 10,000 rpm, 121*C 248 4,0.00 rpm, 93*c 3000 Navy Gear Wear Test, Wt Loss in ag/1000 Cycles
/~'N 6000 cycles at 5 Lb 0.27, 0.22 2
\s / 3000 cycles at 10 Lb 0 90, 1.03 2
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Four-Ball Wear Test - 30 Minutes at'800 rpm Scar Diameter, mm Steel / Bronze, 2 Lb 0.23
- Jaw Load i Steel / Bronze, 5 Lb 0 76 Jaw Load Steel / Steel, 20 Lb 0.47 Jaw Load 1Three separate irradiations; two in air, one in helium. - .
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' 2 MIL-0-3278 specification calls for maxima of 2.5 -
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J - ' PAC, E 14 oh th - q . . . . . . . . l l I TABLE VII TEST DATA ON CHEVRON NRR 3351 TYPE GREASE NRRG-335' Dose, 100 Million Rads 0 4 9 26 30 ,, ASTM Penetration Unworked 276 257 238 246 221 worked 60 strokes 289 289 308 400 359 ASTM Drop Point, *C 260+ 260+ 260+ 260+ 260+ Bearing Performance in Size 204K Ba11 Bearings, Hr to Failure 10,000 rpm, 121*C 7631 10,000 rpc, 149'C . 154 155 - 39 INRRG-509 is a soft grade of NRRG-335 NNRG-509 contains molybdenum disulfide and has an ASTM penetration in the range 360 to 380; the radiation stability of NRRG-509 should be similar although its performance characteristics are different from NRRG-335 CNEVRON RESEARCH
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i , l TABLE 21I - i . I ~ TEST DATA ON CHEVRON NRR 358- AND 360-TYPE OILS , .c Chevron NRR 355-Type Oil Chevron NRR 360-Type Oil i Gamma Dose, 100 :41111on Rada 0 4 9 50 0 7 12 52 -
' Appearance of 011 - - S1t. - - Clear Cloudy -
Haze ) Color, ASTM 4- - 4- 4-1/2 4- 3-1/2 5 8 Appearance of Exposure Can - - OK - - OK Black Black Viscosity eSt at 100*C 4.4 35 38 7.1 17 11 11 31 cst at 40*C 26 20 22 72 365 200 200 1155 Viscosity Index 85 22 41 43 24 -13 -1 11 Copper Corrosion, 3 Hr at Ib 2c 2c 2c lb 2a 2a lb 100*C, Strip Color . Neutralization Number, mg Nil 0.10 0.06 0.02 0.01 0.09 0.06 0.01 j KOH/g Micro ;i
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I Pour-Ball Wear Test Scar Diameter in am; 0.51 - 0.50 - - - - - 10 kg Load; 30 Min. at 0 51 - 0 57 - - - - - 9 l 1200 rpm; Steel / Steel (q Pour Point. *C -9 -29 -54 -40 -7 -29 -21 -18 i Evaporation, 5, 22 Hr at 31 - 30 - - - - - l () l , 100*C . J h
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{. FIGURE-1 RADI ATION RESISTANCE OF B ASE OILS Approximate Gelation Point u 100,0d0
- Polyphenyls Polyphenyl Ethers _ .
Alkylaromatics 1,000 _ Polyglycols
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- Olefins Silicones l .
1 Dose, Millions of Rads
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< FIGURE 2 GAMMA IRRADI ATED OILS .
Dose, Millions of Rads 0 900 4400 - l 1
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{ym 'T . b..L _ . . .. . I U omron Chevron U.SA inc. {fwg'qg P 0. Son 4256. Hounca TX 17210 . Phone (1131821 da00 April 7,1986 Mr. Baldwin Toy c/o Bechtel Power P. O. Box 3965 (Moll Stop 221/5/A44) , Son Francisco, CA 94119 Deor Baldwin: As you requested, this letter will document our recent telephone conversations. In providing you with.ollowable operating temperature ranges for specific products and applications, I endeavored to sofisfy your requirements without extending our products to their outer limits. So, the upper temperatures I provided are somewhat conservative. The ranges are: ,
- . A.. EP Lubricant HD 68, os o gear oi1, operating temperature range is +100F to 120+0F.
You con relate this product to EP Lubricant I-D 150 for predicting radiation y tolerance. s B. Seneco 68, os a refrigeration oil, operating temperature range from -200F to 120+0F. C. Premium Lubcote, as lubricant for cables and chains on air-lock doors, operating . temperature range from OoF to 7 5500F. Since the dropping point of the product exceeds 5500F, we con imply that its flash point otso exceeds 5500F. Per your conversation with Paul Vortonion, Chevron Research j it has been ogreed that the rodlotion tolerance of Premium Lubcote No. I is 5x10 rods or higher. D. Hormony 220, on AGMA #5 product for use in gear reducers, operating temperature is from 150F to 1850F. I have enclosed five pages of lubricant recommendations which have been completed. This should bring me up to date in providing responses and documentation which you have requested. Please let me'know when additional lubrication questions crise regarding the South Texas Nuclear Project. Very truly y rs, D. B. WRIG TECHNICAL REPRESENTATIVE l DBW:pbm Attachments. .
- - - . _ , w a PAGE -EE y_ , 1 9 o h 6 __-.-. ._ _ __3 .
y -- General Qualities and Characteristics Typical Properties Gulf High Temperature Grease is a calcium-complex lubricant which was developed to meet a Gulf Hlah Temperature Grease growing need for a superior high-temperature petro- Type Caldum Complex , leum base grease. It is also an outstandmg multi- 568 ' Drop Point F purpose grease, and has proven itself in a wide Penetration, ASTM D 217 rangeofapplications. In addition to its high-temperature perfor- Worked,60 strokes 325 100,000 strokes 348 . mance, Gulf High Temperature Grease exhibits excellent inherent extreme pressure and anti-wear Color Beige characteristics. These properties are not achieved by Texture smooth. Buttery additive chemicals that must be heat activated but C nosi n.COPPerStriP by the nature of a portion of the complex. These No Corrosion 24 Hrs @ 212 F ht E. R Mm hfm M RustTest, ASTM D 1743 1 t more effective and useful than conventional E. R systems, since they do not require high heat to be Oxidation Stabthty, ASTM D 942 ( effective. Gulf High Temperanne Grease has high Pressure Drop, psi affinity for metallic surfaces and excellent water- 100 Hr I wash resistance. It has very good mechanical stabil- 500 Hr . 3 ity and is effectively inhibited against rust, corm- Water Washout, ASTM D 1264 sion, and oxidation, crea,, w 100 F 4.0 Recommendations 175 F 7.0
'Ihis product has found uses in the steel, paper, rubber refractories, chemical, cement and glass Load Carrying Capacity. FIMS 791-6503 industries. As a further example ofits multi-purpose Lead wearIndex 53.2 3 E E E. P. Test,4 Ball.1735 RPM used in such varied applications as electric rnotor 10 Sec 70-80*F bearmgs, laundry and dry cleaning eq4 ment, chip Weld Point Kgs 357 and sawdust cookers, screw conveyors for hot mate-rial, molding presses, hot gas fans and blowers, and WearTest,4 Ball,1800 RPM other applications where high temperature or other 20 Kg., I Hr.130 F Avg Scar Diameten mm 0.325 adverse conditions require a superior lubricant.
Avr Coefficient of Friction 0.0741 Gulf Hight +4ure Greaseis an NLGI No. I consistency. Since it performs satisfactorily Timba OK Load, Lbs 50 over wide temperature and operanng extremes, Mmeraloil there is little reason for other grades of this parti:u- SUV @ 100 F 600 lar product - a contribution to simplified viscosiry Index 96 lubrication. Gulf OilCorporation O Ask the pro from Gulf GuH' no sox 1563 Houston, Texas 77001 sP 154441181 I
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E General Qualities and Characteristics they retained from 82-86% of the grease Gulf Premium Lubcote E.R greases are applied, at speeds up to 300 RPM. f high dropping point products utilizing a They will maintain a " grease-like" con- k polyurea thickened base grease, and are . sistency at 0 F, which means that they can i designed for applicauons where asphaltic- be applied at low temperature by grease E type lubn, cants are not recommended or gun, brush or paddle without heating. . I have proved to be less than satisfactory They have good pumpability and can be f ' because of high gear speed, high or low applied using air operated grease pumps 5. operau,ng temperatures and the inconve- having a minimuin pump ratio of 40:1. :. nience of heating for application. Special components are included in the In addition, they can also be sprayed using the same equipment and acceptable fi products to impart adhesion characteris- spray nozzles. E tics necessary in open gear lubricants. i Selected additives help them maintain a
" grease-like" consistency over a wide Recommendations Gulf Premium Lubcote E.R greases are
[ d temperature range. recommended for application where y equipment is subjected to shock and over- t
. loading, high or low operating tempera- Ij
. Application Requirements
, tures and when superior adhesiveness is h Gulf Premium Lubcote E.R greascis fea: needed. Some typical applications are $
ture excellent water wash-out resistance m couplings, fifth wheels, open gears on i addition to good antiwear and E.R prop- power shovels, draglines, ball-mills, $ erties. In addition, they are effectively rotary kilns, and overhead cranes. They mhibited agamst rust. { are also recommended for use in cam and g Their adhesion properties are excellent. In slide walking mechardsms such as those 3 a special bench-scale gear adhesion test, found on certainlarge draglines. IM 0 l q 3 E i i ! _.-___-._-...,__.__--,.____-._,,,___--.,..---_,--.....w,__,,.--.- -
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I Q m 7ACa6 2. I cf7Mf -n::: 7 .. _.. . - - . 1 - 7~ General Qualities and Recommendations Characteristics' Gulf Super Duty Plus Motor Oil is recommended Gulf Super Duty Plus Motor Oil, available in for use in automotive diesel and gasoline engines SAE grade 15W/40, provides protection to diesel CPented in heavy duty service. It is particularly and gasoline engines operating under the most recommended for supercharged diesel engine:,, ' severe conditions. and in off-road constmetion equipment. Since it - It is formulated to meet or exceed the most meets Caterpillar recommendations for a 10 TBN l severe requirements for motor oil, both on-and. oil. it is suitable for use when the sulfur content off highway. It provides protection over extended of the diesel fuel is unknown. drain intervals, and can function extremely well Using Gulf Super Duty Plus will satisfy the as a single oil in fleets of mixed engine types. warmnty requirements of nearly all engine manu-Gulf Super Duty Plus 15W/40 gives effec. facturers, and allow operators with several types tive all-weather protection and easier cold. of engines, and more than one make of equip-weather starting. It also contains a friction reduc. rnent, to stock only one engine oil. ing additive that can yield up to 3% increased . . fuel efficiency. Typical Properties super outy Prus Application Requirements SAE Grade 15W/40 Super Duty Plus is an API CD/SF product that Gravity, API 28.3 meets engine manufacturers' toughest require-ments, and has a Total Base Number (TBN) of '#**I'Y' t$' C .6 10 as determined by ASTM D 2896. 'Ihis meets SUV,1007 512 Caterpillar recommendations for an oil to be SUV,2107 73.7 used when the sulfur content of the diesel l'uel is Viscosity Index 136 unknown. Super Duty Plus meets Mack EO-K Flash, COC, *C 210 and EO-J specifications; MIL-L-2104 C, MIL-L- T 410 46152B; Caterpillar (Former Series 3); Foni Pour, *C - 28 M2C-153-B, M2C-157-A; General Motors GM- T - 20 6049M,GM 6048M;and Cummins. It has a maxi. Zinc,% 0.134 Sulfated Ash. % 0.93 mum sulfated ash of 1% by weight to meet the requirements of Detroit Diesel and meets the war-Total Base No. D-2896 10 ranty requirements of all U.S. car manufacturers. k Gulf Oil Corporation Ask the pro from Gulf i y P.O. Box 1563 ( c.*? m : Houston, Texas 77001
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O gg Technical Bulletin Ndf Shell Oil Company r.w a 4 is -
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i l Alvania* Greases Premium quality, multipurpose greases - i
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Productline applications, including heavy or shock loading sit-untions, where bearing temperatures do not exceed t Sheirs Aivania Greases 1,2 and 3 are smooth- 275'F. I textured, amber coloredgreasesmanufacturedwith A!vania Grease D is a long-life grease for railroad a lithium 12-hydroxystearate soap thickener. They antifriction joumal bearings designed for field relu-are inhibited with additives to assure long sennce brication as well as those bearings requiring shop or life, and provide good lubrication anc corrosion pro- factory relubrication. It is approved against AAR
- tectien of grease-lubricated parts in both heavy and Specification M-942.
I light industry. Alvania Greases are excellent as ( general plant and electric motor lubricants. NLGI Applications . Grades 1 and 2 are readily pumpable in pressure lf Proper grease selection depends upon many fac-
\ grease dispensing systems.
A!vania EP Greases ROO, RO,1 and 2 are dark tors. including bearing size, speed, temperature, brown in color and are fortified with extreme pres- load and method of application (hand gun, central-sure additives to give increased load canying prop- ized systems). The bearing lubrication guide in this erties. They have excellent antirust properties, bulletin will assist in this selection.
- Aivania EP Greases are an excellent selection for all f
f' AGE 4 oF 18 - E An80Ticton teseringlutwicsuon g Op-ans assamawaded As.enis G ,e Temperenese seertnes o e
'F Faceae Grade 0 to 75.000 1 30 to 100 75.000 to 150.000 1 150.000 to 300.000 2 0 to 150 0 to 75.000 2 75.000 to 150.000 2 150.000 to 300.000 3 100 to 275 0 to 75.000 2 75.000 to 150.000 3 150.000 to 300.000 3
'The bearing speed lector is the beenng bore meneured in rahmotors enultiplied try the beartng shaft speed measured in rowducone per mswto. For the purpose of convertmg to mdlwnesers from inches, one ince equale 25.4 mdlimseers.
W pn4per9es 3 EP A00 EP R$ EP1 WP 2 O ASTM f,. . . Alumnio Gresas 1 2 j 7183B 71830 71031 7103E 710b4 teosted Shed code member 71911 71012 71913 2 3 et 8 1 2 - 88.08yees 1 ASTM worsed penetreuen 423 378 330 285 306 D 217 at 77'F 80 strokes 325 287 238 Dropptig poted,*F 300 386 / 370 / 335 350 v 300 370/ 383 D 588 40 3s 50 50 5 D 250s namen EP test,me. pese 5 5 5 12 12 12 12 3 0 942 Gemt eeldeten,100 hrs. 3 4 5
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st 21rF, poi orop ,, tenerales veneessy 725 720 1100 1100 842 D 445 SUS at 100*F 314 515 405 06 66 80 80 76 D 445 SUS et 210*F 51 50 SS shes oE Cesapeny t.utricante sales Ofness warveney 100 Executhe Drhe All products purchased froen Shell are subject to terms Emet Coast andcondsbonssetoutinthecontract orderacknowledge-(201) 325 6407 West Orange, New Jersey 07052 ment and/or bill of lading. Shell warrants only that its Chicago 1415 West 22nd Street Oak Brook, Illinois 80521 product will meet those specifications designated as such (312) 887 5500 herem or in ots".or publicebons. All other information sup-Cleveland 7123 Peart Road Middleburg Heights, Ohio 44130 plied by Shellis considered accurate but is fumashed upon (216) 842 4000 the express condebon that the customer shall make its own Houston 24 Greerway Plaza. Suite 711 assessment to determine the product's suitability for a (713) 438 1000 Houston, Texas 77046 particular purpose. No warranty is emproceed or impaled I West Coast 511 N. Brookhurst Street Anaheim.Califomia 92803 regarding such other information,9w data upon which the (714) 981 9000 same is bened, or the results to be obtained from the use H Ofnoe sales thereof; that any product shaN be merchentatne or flt for shoe 08 C1w.i ead any perucular purpose: or that the use of such other Houston One Shell Plaza (713) 241-4201 P.O. Box 2463 informanon or product wel not infringe any potent. Houston, Texas 77001 February 1964
$oc='s O Technical Bulletin 1 Shell Oil Company
- % s 5 A Is -
u -w l Shell VPI 260 l Volatile corrosion inhibitor l j l Description corrosion. With suitable safeguards industrial l Shell VPI 260 is a volatile or " vapor-phase" floc guns may be used. An alternative or supple- [ l inhibitor developed by Shell specifically for the mentary means of application is to suspend the ! protection of iron and steel surfaces against crystals in small porous bags near the surfaces to
/ rusting.Itisastablenitriteof anorganicamine. A be protected. l
- fine white powder it possesses appreciable vapor l pressure at ambient temperatures. VPl 260 acts Application in solution by volatilizing, reaching metal surfaces in the The application of Shell VP/ 260 in solution in a volatile solvent such as methy or ethyl alcohol will :
vapor phase, and being adsorbed on the metal to form a normally invisible film which acts to aid in distributing the material throughout arti-cles with complex shapes. This method also [(e b prevent corrosion by passivating the metal. VP1260 normally is introduced as a solid, but helps to provide rapid protection, since the inhib-occasionally as a solution, into an enclosed air itor can directly reach the area where it is re-space containing the surfaces to be protected. A quired. The solvent should be completely evapo-third method of introduction is by coating or rated before the package is sealed. impregnating packaging material. Such VPI-treated material is usually wrapping paper and is Application as a packaging material commercially available from several paper con- Frequently the most convenient method of apply-verters, ing VPI crystals is to use it on packaging mate-l rials. Coating or impregnation of paper or board is l Methods of application done under license by several paper converters. In principle, the method of using Shell VP1260 is Shell Oil Company does not sell coated paper simply to enclose the metal surf aces or articles in directly. However, Shell sales offices can provide a package in which ventilation is absent or manufacturers' names so that availability and f application details may be obtained. severely restricted, and to include in the package sufficient VP/ 260 to maintain a saturated or near-saturated concentration of the vapor for the Quantity required period of protection required. For maximum The quantity of Shell VP1260 required to maintain effectiveness the VP1 crystals should be ade- a sufficient concentration of vapor will depend on j quately dispersed within the package and should the efficiency of sealing in a given application. An be within at least one fo.ot of the surface to be adequate quantity may be very small where vapor protected. No special preparation is necessary loss is completely prevented. Genera!Iy speak-except to be sure that the surfaces to be protected ing, however, a suitable quantity is two grams are reasonable dry. (0.07 ounce) per cubic foot of enclosed space or one gram per square foot of metal surface. Application as a powder whichever is the g reater. The recommended quan-
\O Shell VF1260 may simply be dusted on when the shape of the article to be protected permits adequate distribution and allows the powder to tity of inhibitor should be introduced into the confined space regardless of the method used to apply it.
remain on or near the surfaces vulnerable to
I Suggestions to help assure .
- 10. Sh:ll laboratories hava investigated th2 ef-sati; factory perf:rm:nca feet cf the v:pors cn m:ny n:n-met:llic
- 1. VP/ 260 should be used ont/ to protect items materials and surface coatings. In most cases there is no effect at all. However, since the 3
/ that will be packaged or otherwise enclosed. y ! 2. While no special preparation is required, the possibilities for use are so varied. it may be ,o surfaces to be protected should be reason- advisable to carry out a prelimmary trial M Q ably dry. under specific conditions.
- 3. Air-tight packaging is not essential and for g some purposes very simple arrangements Safety precautions will suf fice, provided that no gaping openings Shell YPl 260 has toxicological properties similar are left.
- 4. Adequate weather proofing should be pro-to those of sodium nitrite. Excessive exposure can result in headache and a lowering of blood QF vided particularly to insure that water does pressure. VPI 260 is rated as moderately toxic, not penetrate and wash away the inhibitor. and contact with foods for human consumption *
- 5. Excessively high temperatures should be or with animal feeds must be avoided. O avoided. The loss of VPl 260 from non-air- Handling VPI 260 under normal conditions tight packages will increase sharply above does not cause any trouble. However, it is a 125' F. matter of ordinary prudence to minimize contact
- 6. Shell VP/ 260 is virtually insoluble in oll and with crystals and solutions, just as with many E greases. If it is mixed with such products, other chemicals. Workers exposed for prolonged 4 1 ,
the rate of vaporization and therefore the periods of time to air containing VPI260 should effectiveness is greatly reduced. However,if wear dust masks. It can be introduced into the vapor space sur- VPl 260 is combustible. If welding is to be rounding a coated or oiled object additional performed on vessels or pipes that have been protection may be obtained. protected intemally with VPI 260, precautions
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- 7. Acidic materials tend to decompose VPl must be taken to remove the residual crystals 260. Strong alkalai will do the same. There- prior to welding. This can be accomplished by l fore acidic packaging material such as par- means of a water wash.
tially seasoned timber and some types of paper should not contact the metal being (Ay protected from corrosion.
- 8. The rough surface of cast-iron is generally more susceptible to electro-chemical attack Physical properties g
g than smooth surfaces. It is recommended Vapor Pressure at 70*F, mm Hg 0.0001 that rough cast-iron components of articles to be protected by VPl 260 should first be caiutwesey et 77'F. Grams per 100 grams of solution in water a coated with a good quality mineral oil.
- 9. Shell VP/ 260 is not specifically designed for in Methanol 23 in Ethanos 9 preventing corrosion of non-ferrous metals.
in isopropanol 2 Its use with lead and cadmium is not recom-
. mended because of potential corrosion. secutweier in weter et various semp.catures, Some staining has been observed upon direct Grams per 100 grams of solution contact with brass and copper. With other at 32* F 3 nonferrous metals, exposure was either with- at 115'F 5 out effect or in some cases, gave a slight at 150* F 7 degree of protection. One notable exception asseung Point,'F 3e0 was aluminium, where excellent protection Flash Point, COC.* F 240 was recorded.
Shell 05 Company Lutwicents Sales Ofilces Warranty East Coast 100 Executrve Drive All products purchased from Shell are subject to terms (201) 325-5450 West Orange New Jersey 07062 and conditions set out in the contract, order acknowledge- , Chicago 1415 West 22nd Street ment and/or bill of lading. Shell warrants only that its (312) 887-5708 Oak Brook, Illinois 60521 product will meet those specifications designated as such (800) 323-3405 herein or in other publications. All other information sup-l Cleve4and 7123 Peart Road plied by Shell is considered accurate but is femished upon , (218) 842-4000 Middlebug Heights. Ohio 44130 the express condition that the customer shall make its own i Houston 24 Greenway Plaza. Suite 711 assessment to determine the product's suitability for a g p13) 439-1000 Houston, Texas 77046 particular purpose. No warranty is expressed or Irripiled O WestCoast 9 14) 991-9200 511 N. Brookhurst Street Anaheim, Califomia 92803 regarding such other information, the data upon which the same is based, or the results to be obtained from the use thereof; that any product shall be merchantable or fit for Shen 05 Company Head Office Sales any particular purpose; or that the use et such other Houston One Shell Plaza information or product will not Infringe any patent. F13) 241-4201 P.O. Box 2463 Houston Texas 77001 Apnl 1985 l
1 I l 7 d IO
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- PAGE eM Shell Development Company p\v'4 e 3...s O= r $w 3* Cree **
west'ioao. Aesearen Ceme- i A O Bo= 1380 , Houston Temas 770C' October 10, 1985 Mr. Baldwin Toy Bechtel Power P.O. Box 3965 Mail Stop 221-5/A44 San Francisco, CA 94119
Dear Mr. Toy:
During our recent conversation you requested information as to the radiation resistance and anticipated shelf-life of certain Shell lubricants. With reference to the VSI* Circulating 011 32, no irradiation tests have ' been conducted by Shell. However, with reference to a chapter authored by E. R. Booser of General Electric which appears in the Standard Handbook of Lubrication Engineering, he states that a radiation dose ( which_results in a 25% increase in the viscosity at 100*F can,be,,taken as a tolerance limit. With this gi,de, the tolerance limit for a ifght turbine oil is shown to be 1.5x10 rads. Since our VSI 011 32 would meet that definition, we would anticipate its tolerance to be in the same range. The maximum operating temperature reconnended for VSI Oil is 150*F. Operation above this temperature rapidly depletes the volatile inhibitors and accelerates oxidation of the oil. , Relative to gresses we are supplying details of our radiation testing of
, Shell DOLIUM* R Crease. This product was irradiated to a level of 2.2x10 8 rads, af ter which tests were conducted to detect the effects.
Certification of the radiation testing showing the dose rate and duration is attached. The radiation source was Cobalt 60. Af ter being irradiated, DOLIUM R on visual inspection indicated it had maintained its normal grease texture and consistency, with only a slight darkening in color. Penetration tests confirmed the grease consistency to be relatively unchanged. The ASIM D 1743 Rust Test showed rust protection properties were maintained. To evaluate the ability of the grease to lubricate effectively, a test bearing was packed with the irradiated grease and run for a period of 168 hours in a Pope Bearing Rig at 300*F, and performance was found to be satisfactory. The test results are also attached. Duplicate tests were run on an " improved" DOLIUM formulation designed "DR-31" as we anticipate this new version to be adopted after user qualification testing and review. Earlier test ( i results with ALVANIA* Crease radiation exposure at 4.75x10 8 2 showed only a 20% softening after roentgens in static tests. Thickener systems of the type employed in DARINA greases, a hectoritic clay,
l
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1 l W A 4 E. 8 d l& - l Emms ! 2. reflect good radiation resistance and would be expected to reflect minor : changes, if any, at a dose level of lx10 6 rads. The shelf life of most lubricants can be quite extensive given good storage conditions. As a general rule, a term of 2 years could be utilized for oils and a term of 18 months for gresses. The products may be completely satisfactory for use after that period, but should be visually examined for contamination or changes before use. Good inventory control should elimina~te the problem of old or contaminated stock. , We trust this information will be useful, Mr. Toy. Thank you for your use of Shell products at the So. Texas Nuclear Project. Very.tfuly yoprs,
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E. Mironch'ik Sr. Staff Research Engineer Fuels and Lubricants Dept. {1,j\ EM/awb Attachments cc: Shell Oil Company West Coast Lubricants Sales District Manager - J. M. Coghlan . Houston Lubricants Sales District Manager - W. R. Davenport, Jr l l l l l O i
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S"ET C ([ 22301 Mt. Ephraim Road, P.O. Box 68 Dickerson, Maryland 20842 USA 301/349 3001 TWX: 710 828-0542 October 14, 1983 Mr. Edward Mironchick - Shall Development Corp. P. C. Box 1380 *
- Bauston, Texas 77001 D3cr Mr. Mironchick:
Enclosed please find the radiation test reports for your grease samples. Shsuld you require additional information, or clarification of data presented' haroin, please do not hesitate te call me at 301-349-5001. Sincerely, , NEUTRON PRODUCTS, INC.
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v Elizabethd. Baker . Enclosure - l I ELB/kmw l 1 - t . w
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- G IRunutzn cRuSr.S ' i TEST RESULTS . .
8
- Original _ 2.2 I 10 Rads _* l DOLIUM* R 192' 226 1/4 Pen, Unvorked 252 271 Worked Pen, 60 Strokes .
1,1 1.1 ASTM D - 1743 Rust Test Normal Pope Rig, J0O*F Operation _ 168 Hrs. I "DR-31" 294 275 1/4 Pen. Unworked 301 301 Worked Pen, 60 Strokes : 1,l' , 1.1 ASTF. D-1743 Rust Test -
. Normal I Pope Rig, 350*F Operation }
- 168 Ers. .
l e O
SOC:265-83 , gh Technical Bulle":in je SHP Shell Oil Company l
-%e. II e5 IS -
ununummuummunumummmmmer Shell Darina* Greases Superior quality multipurpose greases ! for lubrication of bearings operating at elevated temperatures. . Product Description well suited to ball, roller, and sleeve bearings as well Shell Darina Greases are superior quality, multi- as to sliding surfaces and grease-lubricated gears. purpose, non-soap grosses They give excellent They perform well where water is present because lubrication in wet or dry applications, over a wide they can adhere to wet parts, resist dissolving it, temperature range and forlong penods of time.This water, and resist its washing action. The extreme performance makes them more versatile than many pressure version, Darina EP Grease, is recom-soap-based industrial grosses . mended for heavily loadod machines and is some-h The Darina Greases are based on Microgete, a what better in its water resistance. Shell-developed inorganic thickening agent. Micro- One of the major industries having a requirement gol does not have the limitations of soap-type for a grease with these characteristics and therefore thickeners. It does not melt, dissolve, or lose its one of the largest consumers cf Darina Greases is thickening power from sheardown, as soap fibers the steel industry. Steel mills have heavy machinery sometimes do. Because of MicrogeI's superior and difficult service conditions and therefore use characteristics, Darina Greases can be used in a Darina EP Grease more often than Darina, Steel much wider variety of applications than most soap- mills frequently have centralized grease dispensing base greases systems. These systems have distribution lines that Darina Greases are available with and without are exposed to temperature extremes from winter's extreme pressure agents. Both versions are made in cold to radiation from hot steel. The ability to be three National Lubricating Grease Institute (NLGI) pumped through piping and tubing under a wide consistencies, Grades 0,1, and 2. range of conditions is important in the steel industry Environmental concerns can be minimized by and is known as grease " mobility." Darina EP using either Darina or Darina EP Greases, because Grease 1 has good mobility and is especially suited they do not contain lead compounds. Because the to these conditions. non-EP version does not contain any components The Darina Greases are also excellent candidates which the U.S. Department of Ag riculture considers for applications in chemical plants and paper mills particularly toxic, it is approved for use in,most and where grease is exposed to very wet conditions: poultry processing plants where there is no possibil- mining and process plants where crushers, screens. ity of contact with the food. and kilns are operated at high temperatures; and general industry where a multi-purpose grease can Applications simplify plant lubrication by meeting virtually every Darina Greases are intended for industrial grease- grease lubrication need.
, lubricated machinery particularly where the grease is exposed to tem peratures as hig h as 250' F or, with frecuent relubrication. 350*F. Danna Greases are l
l - - . - - . . . _ _ -
-m e. la 4 18 -
Performance Test Results for Darins em is usuany neeoed to prevent grease from being W Greases washed away by rain or cooling spray. In the Water ( Oxidation Resistance Spray-off Test. water at 100* F and 40 psi is sprayed
, Denna Greases owe their oxidative excellence to the onto a thin layer of grease. The more the grease fact that they are manufactured using high quality stays in place, the better its adhesion in wet service.
baae oils which are further enhanced with an oxida- With Darina EP, half of the grease remained.where-tion inhibitor. Oxidation stability is measured in the as only 10-15 percent was left after the. test on Eomb Oxidation Test ASTM D942. In this test, a another inorganic EP grease. grease sample is placed in a bomb heated to 210* F and filled with oxygen to 110 psi. The Bomb Oxida- Water Washout tion Test indicates the tendency for a grease to take in addition to the spray-off test, which measures the up oxygen by measuring the pressure drop of the adhesive properties of grease, Darina Greases were oxygen, usually after 100 hours. The less the pres- subjected to the Water Washout Characteristics Test sure drop during the test, the less prone to oxidation ASTM D1264. This test evaluates a lubricating will be the grease. Some less stable grosses give grosse's resistance to washout from a beanng by pressure drops as high as 28 psi. water. The test is carried out at 100 or 175* F and at Darina Grease 600 rpm. The percent of the grease sample washed Gave a pressure drop of 10 psi, after 100 hours. sway by water is reported. Shell Darina EP Grease Darina EP Groese showed " nil" loss in the test. Gave a pressure drop of 1 psi after the 100 hour test and only 4 psi after 500 hours. Grease Leakage These results mean that you may be able to re- The tendency for a grease to leak from bearings in duce the grease quantity that you feed to the bear- service can be measured in the Wheel Bearing ings and that Darina EP, will retain its original t.eakage Test ASTM D1263. In this test, the grease characteristics in service for a long time. sample is rotated in a modified automobile front wheel hub at a speed of 660 rpm and at a spindle Mechanical Stability temperature of 220* F. The Roll Stability Test, ASTM D1831, simulates Darina Grease grease being worked in a roller bearing. In this test Darina Grease 2 showed no loss by leakage. some greases tend to change their consistency - Darina EP Grease some even become liquid after being chumed by the A scant 2 gmms of Darina EP 2 and 5 grams of ro!Ier. If this occurs in a bearing, it can result in- Darina EP 1 leaked from the 90 gram sample at leakage. The change of consistency is measured as 220*F. This was two-thirds less than leakage a percentage of the original consistency after being with another EP inorganic-thickened grease. tested at room temperature and at 212* F. The less These results show that you can expect long
- the percentage of change in this test, the greater will service from Darina Greases at elevated tempera-be the grease's stability in service. tures without losing the grease.
Darina Grease
- The NLGI 2 grade changed 15% after being Load Carrying Ability tested for four hours at room temperature. Extreme pressure characteristics are necessary for Darina EP Grease heavily loaded machines to prevent metal to metal Darina EP Greases changed less than 1% after contact that can destroy gears and bearings. Only being tested for two hours at room temperature. the Darina EP Grease is tested for this property.
At 212*F, Darina EP 1 changed by 6% and Several extreme pressure tests are recognized, and Darina EP 2 changed by only 12%. the results for Darina EP 2 Grease in these tests are These results mean Darina Greases can be ex- given below: pected to stay on the job, giving lower grease con-sumption and less frequent relubncation. ASTM Test Test Method Result Adhesion Adhesion as a lubrication problem relates most T",ayEP
,, est.vhold oed Kg 3 significantly to extreme pressure greases because 4-Ban EP Test. Load wear incex D2596 40 they are used in heavily loaded applications often in 4. san weer scar. mm.,
the presence of cooling water. Although adhesion 40 Kg.1800 rpm.1 Hr. 02266 '173 O can sometimes be important in dry applications (to stay on gears or wire ropes, for example) tackiness 2
i l
' PAC1E. 13 ef 18 -
E Protection Against Corrosion
- The ability of a grease to protect expensive ma- Hig h temperature performance was measured in the Federal Test Method 331.2, the Navy Rig Test. This (i chinery against corrosion is an important consid-eration especia!!y where the machinery is exposed test consists of stressing the grease both thermally to high humidity. This property is measured by the and oxidatively in a beanng running at 10.000 rpm ASTM Corrosion Preventive Properties Test, ASTM and 300' F with a three-pound radial load. The test is 01743. In this test, a cleaned and greased bearing is run until the bearing fails or binds.Darina EP Grease stored for 48 hours at 125' F and 100 percent relative 2 lasted 1.135 hours in this test, compared with a humidity. Darina Greases passed this test, which lithium hydroxysteerste soap grease at 280 hours.
means there are no black stains, pitting, etching, or This performance means that less frequent re-rusting. No corrosion means lower maintenance and plenishment of the grease will be required, which ( longer machine service life. can save both grease and maintenance costs. It also means fewer bearings to be cleaned or replaced. I 1 i
)
l Table 1/ Typical Properties of Shell Darinse Groeeee ASTM Darine Denne Denne Denne EP Denne EP Denne EP Method Grosse 0 Groese 1 Grosso 2 Groese O Grocee 1 Grosse 2 i NGLI Gredo Number 0 1 2 0 1 2 71500 71501 71502 71520 71521 71522 ! Code Number Thickener Merogel* Merogel* Meroge* Merogee M.croge* Merogee Ameer Arnber Ameer Arnber Arnber Arnber Conor Appearance Smooth Smooth Smooth Smooth Smooth Smooth weseed Poneseson at 77*F, D217 364 330 280 375 337 288 80 Strokee. omm Worked Penetreelon at 77'F.
- - - - 352 332 <
100.000 Strokee. omm
- Dropping Point. 'F D2265 500 , 500+ 500* 500* $00* 500*.
Some Ostdemon at 210*F Pressure Drop at 0942 9 9 1 1 - 1 100 Hours. pai - ASTM corrooton Test D1743 No Rust No Rust No Rust No Rust No Rust No Rust 14 Days Wheel Beertne Test D1263 - - Nil - 5 2 r et 220* F. gm Weeer sproy-Off l 54 38 40 pas at 38*C. % - - - 65 I Weser WesM)ut D1264 - - 2 7 Nil Nil at 100* F. % Loss Thnhen Test, Pounde D2509 - - - 50 50 50 Pese Lead weer indes, Kg D2596 - - - - 48 50 Mob 8My,0* F. g/mm. - - - 2.7 1.4 06 Uncoln Venemster Test - 30* F, pas - - - 190 350 0* F. ps. - - - 475 850 Proportes of Minored 08: vocoerry. cst D445 99 99 99 109 109 109 at 40*C 11.2 11.2 11.2 11.6 11.6 11 6 at 100* C t 3
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l shes os Company Comme,ew se on.e w = ney l 1 i East Coast 100 Executrve Drive All products purchased from Shell are subject to terms 9 01) 3 5 6200 West Orange, New Jersey 07052 and conditions set outin the contract, order acknowledge- ; 1415 West 22nd Street ment and/or bill of lading. Shell warrants only that its l { 1 912) -8000 Oak Brook. Illinois 60621 product will meet those specifications designated as such ' Cleveland 7123 Peart Road herein or in other publications. All otherinformation sup- , 916) N Middleburg Heights, Ohio 44130 plied by Shellis considered accurate but is fumished upon Houston 24 Greenway Ptara. Suite 711 the express ccadition that the customer shatt make its own l F13) 4361000 Houston, Texas 77046 assessment to determine the product's suitability for a PeclRc Southwest 511 N. Brookhurst Street ', particular purpose. No warranty is exproceed or implied 914) 981 9200 Anaheim, Califomia 92801 regarding such other information,tw data upon which the PactSc Northwest 400106th Avenue N.E. same is beeed, or the results to be obtained from the use 908) N Bettevue, Washington 90004 thereof, that any product shall be merchentab6e or fit for any particular purpose; or that the use of such other information or product will not infringe any patent. Apnt1983 4
SOC:88-82 (Superseces soc 88-74 t Techn.ical Bullet,in 2 Shell Oil Company w ,s am - - VSl* Circulating Oil Hydraulic and lubricating oil for rust protection in vapor spaces I with a unique additive combination to provide good ! f*^ Product line rust protection to intemal surfaces of a circulating I Moisture in the enclosed air spaces over a circulat- system whether or not they are completely covered ing oil is very likely to cause rusting when it con- by oil. It is available in 55-gallon drums. I denses on the cool walls of the case or reservoir. Further, this condensed moisture is constantly re- Application recommendations plenished as the system " breathes" through vents VSI Circulating Oil is recommended for enclosed and other openings. Shell has developed VSI (Vapor lubricating oil systetis where rusting is likely to Space inhibiting) Circulating Oil with polar antirust occur. Typical applications include oil-lubric'ated compounds which are oil-soluble and volatile.These antifriction bearings and gears, reservoirs. system corrosion inhibitors fill the vapor space above the oil housings piping and similar system components. l level to form a rust preventive barrier on the exposed VSI oil is especially recommended for use in machine metal surface and combat vapor space rusting. The tools that may be idle for a weekend or longer. oils also contain the more customary types of rust Machinery that is, idle or in intermittent use is partic-inhibiting additives which function below the oil ularly susceptible to rusting as oil drains from inte- ! level. rior surfaces. Shell's VSI Circulating Oil can protect l In addition to its ability to combat vapor space such surfaces against rusting. rusting. VSI Circulating Oil also has the following The properties of VSl Circulating Oil permit run-important features: in of new equipment and rust protection with the , same oil by leaving all or a portion of the oil in the l 1. Good demulsibility - separates f rom water readily. machine during shipment, providing that the ma-t 2. Good oxidation stability - over 2000 hour life in the chine can be sealed. It is not recommended as a ASTM D 943 Turbine Oil Stability Test. protective for surfaces exposed to weather or where
- 3. Good resistance to foaming -in the ASTM D 892 the internal surf aces are so welt ventilated that inhib-Foam Stability Test no reportable foam volume itor vapors are prevented from accumulating to an was obtained. effective concentration. -
^
Shell's VS1 Circulating Oil is available in the three it is an easy matter to drain the VSI oil from the g viscosities most common to hydraulic and lubricat- system and to install the operating lubricant after
\ ing applications. All grades are blended from high shipping. In many cases VS1 Circulating Oil itself quality, high viscosity index, turbine oil base stocks may be left in as the operating lutricant.
l
I64(8
-%i . E g33333333333g HMMMEMMM W The principle of vapor space rusting 6.For maximum effectiveness, the longest distance hCl VSI Circulating inhibition.
Oil protects the surfaces of a lubri-from the oil to the surfaces requiring protection should be kept reasonably short. Exponence inai-l cating system from rusting by releasing into the air cates that with 80* F oil the distance should be no l space over the oil a volatile corrosion inhibitor more than about six teet.Where temperatures are l which is then adsorbed on to the surfaces to be lower, the maximum distance should be less. and ) protected.The rate of release of the inhibitor and the at temperatures over 80*F it may be somewhat length of time that an effective concentration is greater. maintained depend on the bulk oil temperature and 7.Because of the significant effect that temperature the degree of ventilation of the system.The balance and ventilation have on depleting the rust inhibit-between temperature and ventilation will determine ing additive and because of differences in make-tr,e rate at which the inhibitor becomes depleted. up rates, it is difficult to predict oil service life. and therefore the effective antirust life or the oil However, experience has indicated that while the change period. oil change interval is shorter.than that for pre-mium quality turbine oils, it is sufficiently long Recommended practices for using VSI enough to fit in with plant preven'ive maintenance Circulating Oli schedules. 1.High temperature will accelerate inhibitor release while low temperature will retard it. An initial Examples of field experiences temperature of 80* to 100*F will assist in early Some examples of applications that have benefitted distribution of the VSI agents. In an operating from the use of VSI Circulating Oils: system recommended bulk oil temperatures are 1.VSI oil used to run-in gear drives and to protect 80' to 150' F. Temperatures over 150* F should be finished units during shipping. Units as heavy as kept to a minimum and temperatures over 200*F 40 tons and as high as 25 feet have been success-should be avoided because of excessive rust fully protected. inhibitor loss. 2.VSI oil used to protect gas and steam turbines.
- 2. A tightly closed system is best. and no attempt Units are tested with the VSI oil and drained. A f\ should be made to protect a completely open system. Most oil circulating systems and reser-residual amount is left in the sump (about 1 inch deep) to replenish inhibitor as needed.
voirs afford a relatively closed system to keep the 3.VSI oil used to run-in or operate centrifugal air oil free of contamination. Any reduction in system conditioning compressors. Residual oil protects ventilation will help improve the corrosion inhibit- the unit during shipping. ing action. 4.VSI oil used to protect gears and bearings of 3.The equipment should be clean before installing gearhead motors during storage prior to service.
- VSI Circulating Oil. Contamination may promote Units can range from fractional to as high as 150 rusting. horsepower. VSi oil has been left in the unit for up l
- 4. Freshly cleaned surfaces should be immediately to two years. Before use in service, the unit is coated with VS1 oil. if possible.to afford protection flushed and filled with the operating charge. VSI until rust inhibiting vapors can form. oil could be used for the operating charge if used 5.VSI Circulating Oil is designed primarily for pro- in the appropriate viscosity.
tection of ferrous metals. It is non-corrosive to most non-ferrous metals including brass, copper, bronze, zinc. babbitt aluminum and magnesium. However, contact with lead and lead alloys should be avoided unless the alloys have been tested for suitability under actual operating conditions.
) 4 \
-%E 17 d 16 -
a mummmmmmmume Typical properties for VSI Circulating Olis Shoe grade number 32 88 100 ASTM Code number 65249 65251 65254 metnoc Gravity.
- API 31 30 29 D 1298 Meeh. COC. 'F 395 430 450 D 92 Flash. PMCC. 'F 360 360 360 0 92 Pour point. 'F 10 10 10 0 97 Neutreitsamon no TAN-C 0.6 06 0.6 0974 Vlecosity, cst at 40'C 31.1 63 94 0 445 et 100* C 5.2 81 106 0 445 VIncoetty indes 97 94 95 O 2270 Huet test. synthetic sea water No rust No rust No rust O665 Copper corvoeion, at 212* F 1A 1A 1A D130 Demuleiblitty, minutes 10 10 10 0 1401 Foera test. stat >hty, me 0/0/0 04/0 0/04 0892 TurtHne ou etabatty test hrs 2000* 2000+ 2000- D 943 Rotating bomt osidation test. min 200* 200+ 200- D :'272 t
m
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4 l O . e l l Shell Oil Company Commercial District Sales Offices Warranty East Coast 100 Executive Drive All products purchased from Shell are subject to terms l (201) 325-5200 West Orange. New Jersey 07052 and conditions set out in the contract. order acknowledge-t Chicago 1415 West 22nd Street ment and/or bill of lading. Shell warrants only that its j (312) 887-5500 Oak Brook. tilinois 60521 product will meet those specifications designated as such 1 Cleveland 7123 Peart Road herein or in other pubhcations. All other information sup-l (216) 842-4000 Middleburg Heights. Ohio 44130 plied by Shell is considered accurate but is fumished upon l Houston 2001 Kirby Drive the express condition that the customer shall mak e its own l (713) S28 4431 Houston. Texas 77019 assessment to determine the product's sJitability for a t Southem Califomia 511 N. Brookhurst Street particular purpose. No wortanty is empressed or impiled (714) 981 9200 Anaheim Califomia 92803 reganSng su2 otherinf6 the data upon which me i Norttwoot 400108th Avenue N.E. same le based, or the results to be obtained from the use ( (208) 453-3000 Bellevue, Washington 98004 thereof; that any product shall be merchantable or fit for i St. Louis Suite 1000. 500 Northwest Plaza any particular purpose; or that the use of such other (314) 291-5700 St. Ann. Missouri 63074 Information or product will not infringe anf potent. Company Head Office Sales One Shell Plaza (713) 241 4201 P.O. Box 2105 Houston. Texas 77001 August 1982
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4 REFERENCE f 171 4 A SOURCE : NEQ -1 A er 4- -t i e- n-, en-ee,www--,,.--e,r-,e--,
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)'N .{u QUALIFIC EION C 1 --
e mrs- m le_' l t' e ~' " 2 i shakuh M > VT.51:
. RADIATION RESISTANCE OF 'VITON'
- Yurcanizates of VITow Auoroetastamer,irrespectiv's of type or filler, can withstand 105-10" rads [108 10' J/kg] with litde or no elTect on
, . physical properties and 108-10' rads [I04-105 J/kg] with moderate t ,
effect (50% loss of elongation at break. 50% incrsase in modulus): 108 ,
. rads [10'J/kgi produces a severs etrcet (final elongation at break <50%).
HANDLING PRECAUTIONS Using recommended handling procedures.Yttnw Auo- cautions there shou!J be no problem in staying within i - O rocia temer eoirmers and products h >cd on ihem. in themac!ves present no health hazards of which the iheii-iisseihrosiii. nefore h ndiini or processini VIToN, be sure to read and be guided by suggestions in Du Pont Company is aware. liowever. imrtain hazards Bulletin YT-100.1, "Handlin5 Precautions for VITow and Related Chemicals". may the rawariac polymers during the cximpounding into Anished products. For example. and processing of
- Compounding ingredients that a r tonic vapors, which may include hydro 5en 8voride.8 . to prepare Anished products may present hazards in
. . . may be liberated from producss based on Vrmw dur- handling and use. Before proceeding with any com.
ing cure. puna cure or service at temperatures above pounding or processing work, consult and fo!!ow label j 200'C [393'Fl. Adequate ventilation should be pro. directions and handlins Precautions from suppliers of
. vided in work areas where compbunds or parts of all ialredients
) VtTow are being processed or are likely to he expused
- 8Hy6 eye aver
- is reptaud as as air oneiamiaans is dw Unsmi to temperatures in this range. Avoid breathing vapors 54ase under the Oerupatamal Sarety and Heahn Ans trefer to i or dusts from such operations. If vapors or dusts are cf.a.no mmim e m-W a r.
inhaled, remove to fresh air. By following them pre- sy is any s.k=r et is.n er a chunt wars a as 3 ppva.
* , SPECIAl. NOTE-Escept as otherwise provided by law outside the USA, the fol-
, lowing information should he noted: ,
The information set forth herein is furnished free of charge and is hated on technical data that Du Pont believes to be reliable. It is intended for use by persons havins-
, ' technical skill, at their own discretion and risk.The handling precaution information-
. contained herein is given with the understanding that.those using it will satisfy themselves that their particular conditions of use present no health or safety hazards.
Since conditions of product use are outside our cuntrol. we make no warranties.
- f. espress or implied, and assume no liability in connection with any use of this information. Nothing herein is to be taken as a lisanne to operate under or a resx>mmendation to infriale any patents.
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e RADIATION RESISTANCE OF 'VITON'
'the radiation reistance of Yunw fluoroclastomer is by the maicrial may produce a variety of cerects se
((- summariasd in the fiillowin5 sables. Heliere docuping the results, tile liillowing gusJsimo and definition, will sui;h as sroutinLing and degradation. Excessive , be useful: snergy abwrption usually resulta m iailure of the ! nuhstance. cither by embrutlemerit due to over. I.' Radiatiswa can be defined as the transmiaion of cruulinkmg or by reverniim Idelradationi dus to high sacrgy wavam or particles through spass or chain cicavage. through a material medium. Energy alwirptiivi Table I Comparative Radie ion
- Resistance of VITON Fluoroetastomers IA 10 IC ce#Pouse virOe A . ............ ... 100 -
VIION I . . . ......, . . . . . . - 100 -
' Vil0ft A HV . . . . ... ......... - -
, 100 Ili cartee Blast. .
. . . . . . . . . 20
. 20 20 asACL11( f . . . .... .... ... 15
- 15 15 l 0 tan les. l . . . . . . . . . . . . . . . . . . . I -
1 I m eAm w PiOPurics - c.c Pren.3s sesas lat*c(200*rl -
, Osen-Weg siis 24 hows of 204*C[4fl0*rj I,
e smsuaisaadanessual!4*c[7s*r] Onced 10es aseemius. MPs (seil . . . . . . . . . 2.513751 16(1751 3.214151 feensie 3ireeste. MPaipesl . . . . .. . . IL212 2001 11212200) . 16BII425l liessates a Ineat. % . . . . . . . . . . 320 ' 300 250 Isomens suemeter A . . . . . . . . . . 58 80 85 Alter S:IP taas($ Ir1/tg " 100% m IBPa(sel.....!Badeems
. . . 4.41550! 4.4 [ Ele) 4.81700l Temule$steegtt.NPs(sel........ 114[2225l IL2(22001
, , finagues at areat % . : . . . . . . . . 230 ILO!!175) 230 220 Iseraess. seremote 4 . . . . . . . . . . 71 71 -
11 aner1r ends [trMalBasedes 100% Heavius NPs (pel . . . . . . . . . 10(1751 LS(150l 18(B50) Teassie Strengt4, IIPs [pm) . . . . . . . 13.8 [! NOj 13.2 (1 125) [longstesetAreat,% .. . . . .. . .. 170 160 13 2 [I 925) 170 Ilumess. eeroness a . . . . . . . . . . 70 12 !! Ameris:It'asas[2.5:ISSMg Redeems 100% assemies, asPa feel . . . . . . .]. . IE4 Il11.011000l . 5001 Teande Serenget. #Pa lem) . . . . . . . , llJ (1700l 96Il400l 12.6(1825) 11.2 [L 625l
, Elseemme as Ireat. S . . . . . . . . . . 110 120 Noeness, aweneser A . . . . . . . .. 110 73 78 34 Aber la ir Bees [1:IF 1/t 1Badelsen 4
leanse $4renett. MPa lemj . . . . . . 18 [I 2$01 9.2[1325) . 12[I 3251
, finesales al Grea6. S . . . . . .... 50 11 Ilareces,dweester A . ........ 50 .
It il Il *
- after Ir Bees (IP1/te]toestas **
Ieeste 53eenet6. #Pa tem l . . . . . . . 7.8 ll 1001 lisagesee as best, % . 7.8(l1251 i.411075l
........ le 10
- 10
{ Mmmens. enemeter A . . . . 87 82 R$
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2 9
. . _ . , .-_..._____._--,.___,,_...-,,,,..m_ ,, - - .
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- 2. Canuera railiation may be nmsidered typical of with regard to radiation caposures.1hus, ten ex.
T* the type to which clastomers would be subjected
/* pmurcs of 80' rads (102 Jikgl are equivalent to and is u>ed in many laboratory nadiation studies.
r
- one esposure of 10* rada [10' J/kgl.
linwever. Juu to equipment availability, test re.
, (. 3 suits reported in this bulletin are from caposure
- 3. Conscrning clastomst scrsiwability, a gumm,, ra.
diation Jose icw than 5 a 10 rads [5 e 10' J, kgj is
- kt bria radiation. Based on these and other tests. considered low. Up to ID" rada [Ity* J/Lglis con.
evidense indicates that equivalent damage is I incurred by equivalent dosages of beta and sidered intermediate and 10" to 10' rada (10".10' r J/kg!is high.
.grunme radiation under identic31 environmental umditions. ' Data in Table f indicate that the type of Virnw poly.
l 3. Radiation dme is expreized as rads. One tad is mer has listic or no c! Test on radiation resistance. I , the dow which produces an energy absorption of Vrrow A.HV and Vnow 8 areidentical to Vitum A at
- equal exposures. Table il demonstrates that the use of 100 ergs per gram in one subic centimeter of air V: TON E.60C, with a variety ofIlliers, does not improve
- at standard temperature and pressure.10" rads resistance. *
= I m*5arad. Also, one rad m .01 J/Jr5 In summary, exposure of vulcanizates of Veron to
- 4. In general radiation dom are additive. A mare. !
more than 10"-10' rada (10*-105 J/kg] pri. duces mod. rial can be asumed to have a " perfect memory" erste to severe effects on physical properties. t .
~.
i - Table 11 Test Compounds of VIT0N E.60C for Radiation" Esperiments
)
l M N E 5 COMP 0050 N k - VIToll E40C. . . . . . . . . . . . . . . ' . 100 100 100 , ==m e . . . . . . . . . . . . . . . . . 3100 . 2 3 3 100
, . Cainme Nyeemde . . . . . . . . . . . . . . . 5 6
. 5 4 8 fee Grenad Cainem Carlenate . . . . . . . . - ,-
30 - 9tase lme . . . . . . . . . . . . . . . . . . . *
- - ~- 70 MI 8 tack . . . . . . . . . . . . . . . . . . . . - . 30 20 - -
en camirsrg pg0PUTits h Csa: Press-15 masses at 177*C (350'F] * [ o e-24 news a 232*Cl450*r] g e mensmaisamenadassimat Cps'r) eng I .
! 100% Meemise. NPs losil . . . . . . . . . 2.8 (3001 E2(900) O(7001 1811501 Tammie trengen mPa Isail . . . . . . . 7.4 [I 075) L41925) i
!)engeles at treat. 4. . . . . . . . . . . 13.0Il300) I!Jil7001 15.s[2 250) !!Jil6251 200 Mareness, dweneter A. . . . . . . . . . .
180 100 ISO . 100 13 72 68 68 73 g
- after5:IrEnds(1 IP1/tt Eadsume
. Tommie Strengte. MPa (sm) . . . .]. . . 14 (775) SJ[I 3541 -
Dengasem at erest,5 . . . . . . . . . . RJ!!350] IJ[l350] - El 45 - 48 45 Marenssa,esenseerA .......... 71 85 5 35 - 3. After IPtads(Irl/ts] Andstes
; Tesmie ShangtL MPa lgej . . . . . . . 12(900) 1 6[I 4001 7.8(I1001 18(12751 - -
. Dangeses as Areat.S . . . . . . . . . . 45 as g- 25 29 -
Hereness, duumster A . . . . . . . .*. . 90 It IB 5 . - ARet LS: tr Rads (2.5 s IF1/t
- fasade D,essta MPs [pmj .. .1&8(15751 . . . 1 Radstine - -
- Dengaene at Areak 5 . . . . . . . . . . 15 -
LS(1000) * . 11.1 11 725]
<20 :. <22
!!=2.a::. iir. mats : . . . . . . . . . . 64 77 70 75 -
76 Amer S: Er Reds (5 :IF1/talanestse *..
. feede Shemett. MPs lpm) .'. . . . . . . - - - - -
Doetales at Brest. % . ........ - - - . - Maremess, esenster 0 . . . . . . . . . . 30 81 80 85 30
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