ML12230A222

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NPDES Permit No. TN0026450 - 2012 Discharge Monitoring Report Quality Assurance (DMR-QA) Study 32 Provider-Graded Test Results Final Report
ML12230A222
Person / Time
Site: Sequoyah  Tennessee Valley Authority icon.png
Issue date: 08/14/2012
From: John Carlin
Tennessee Valley Authority
To: Waits D
Office of Nuclear Reactor Regulation, State of TN, Dept of Environment & Conservation, Div of Water Pollution Control
References
TN0026450
Download: ML12230A222 (11)


Text

Tennessee Valley Authority, Post Office Box 2000, Soddy Daisy, Tennessee 37384-2000 August 14, 2012 Ms. Dana Waits State of Tennessee Department of Environment and Conservation Division of Water Pollution Control 6 th Floor, L&C Annex 6' -3 401 Church Street Nashville, Tennessee 37243-1534

Dear Ms. Waits:

TENNESSEE VALLEY AUTHORITY (TVA) - SEQUOYAH NUCLEAR PLANT (SQN) -

NPDES PERMIT NO. TN0026450 - 2012 DISCHARGE MONITORING REPORT QUALITY ASSURANCE (DMR-QA) STUDY 32 PROVIDER-GRADED TEST RESULTS FINAL REPORT Please find enclosed the provider-graded test results of the 2012 DMR-QA Study 32 Laboratory Performance Evaluation obtained by TVA Sequoyah Nuclear Plant (SQN) and supporting Laboratories as required by NPDES Permit TN0026450.

If you have any questions or need additional information, please contact Brad Love at

  • (423) 843-6714 or by e-mail at bmlove@tva.gov Sequoyah's Environmental staff.

Site-VipPresident Sequoyah Nuclear Plant Enclosure cc (Enclosure):

Chattanooga Environmental Field Office U.S. Nuclear Regulatory Commission Division of Water Pollution Control ATTN: Document Control Desk State Office Building, Suite 550 Washington, D.C. 20555 540 McCallie Avenue Chattanooga, Tennessee 37402-2013 e~Th~

U SEPA NPDES PERMITTEE M DMR-QA 32 DATA REPORT FORM A Waters Company USEPA NPDES TN0026450 Permit #: Permit Ext:

Permittee Name: TVA - Sequoyah Nuclear Plant Facility Address: P.O. Box 2000 Mailstop: OPS-4A-SQN City: Soddy-Daisy State: TN Postal Code: 37384-2000 Phone Number: 423-843-7001 Fax Number:

E-mail address: jtcarlin@tva.gov For DMR-QA Study 32, conducted in 2012, the Permittee ensured that their laboratory(s) performing the required analyses:

Received PT Samples Submitted Complete and Accurate Data Received a Graded Report by July by July 6, 2012 27, 2012 Yes No 13 Yes No 0 Yes ['] No Certification by Permit Holder or Authorized Representative (as per 40 C.F.R. Section 122.22) 1certify under penalty of law that this document and all attachments were prepared under my direction orsupervision in accordance with a system designed to assure that qualifiedpersonnelproperty gatherand evaluate the information submitted. Based on my inquiryof the person or persons who manage the system, or those persons directly responsiblefor gatheringthe information, the information submitted is, to the best of my knowledge and belief, true, accurate and complete. Each reported value was produced from a single analyticalrun using the analytical system that rountinelyperforms these analyses to produce compliance monitoring data requiredunder our National PollutantDischarge EliminationSystem (NPDES)Permit. NeitherI nor any of my subordinatescomparedour resultsfrom independent analyses conducted by us or any other laboratorybefore we reported ourresults to the USEPA. lam aware that there are significant penaltiesfor submitting false information,including the possibility of fine and imprisonmentfor knowing violations.

Name of Certifying Official: John T. Carlin

Title:

Sequoyah Site Vice President Signature: " Date Signed: / /2012 Mailing Address: P.O. O (enter only ifdifferent from address above)

Mailstop: OPS-4A-SQN City: Soddy-Daisy State: TN Postal Code: 37384-2000 Phone Number: 423-843-7001 E-mail address: jtcarlin@tva.gov Please make corrections in boxes above

United States ENVIRONMENTAL PROTECTION AGENCY A Waters Eompnw Laboratory Performance Evaluation Laboratory DMR-QA Evaluation Study 32 USEPA NPDES Permit #: TN0026450 Permit Ext:

Identification of all CHEM, MICRO and TOX laboratories who did analyses for this permit Lab Analysis Name of Laboratory Address of Laboratory U.S. EPA Lab Check box(es) that apply Lab Type Code CHEM MICRO TOX Environmental Science Corp 12065 Lebanon Rd.

Mt Juliet,TN 37122 TN00003 D1 El C Environmental Testing PO Box 7565 NC,1230 Solutions, Inc. Asheville,NC 28802-7565 E2D D X A - Sequoyah Nuclear P.O. Box 2000 Plant Mailstop: OPS-5N-SQN Soddy-Daisy,TN 37384-2000 TN00999 L I Lab Types: C = Commerical F = Federal G = Local Government I = Industrial 0 = Other S = State

fjERA A Waters Company Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: NC01230 Nuclear Plant WET Organisms/Test Conditions/End Points Checklist MIlAD('nA .,,,, I). __

Laboratory's Graded Result Not Acceptable Analyte Organisms / Conditions End Points Test (Corrective Number Required Acceptable Action Required)

Fathead minnow (Test Code 13) 0754 48Hr., Acute, Non-Renewal, 250 C, MHSF LC50 Fathead minnow (Test Code 14) 0755 48Hr., Acute, Non-Renewal, 250 C, 20% DMW LC50 Fathead minnow (Test Code 15) 0808 7-day Short term Chronic, Daily Renewal, MHSF IC25 (ON) Growth EPA 1000 0810 7-day Short term Chronic, Daily Renewal, MHSF NOEC (ON) Growth 0756 7-day Short term Chronic, Daily Renewal, MHSF NOEC Survival Fathead minnow (Test Code 16) 0812 7-day Short term Chronic, Daily Renewal, 20% DMW IC25 (ON) Growth 0814 7-day Short term Chronic, Daily Renewal, 20% DMW NOEC (ON) Growth 0759 7-day Short term Chronic, Daily Renewal, 20% DMW NOEC Survival Ceriodaphnia dubia (Test Code 19) 0764 . 48Hr., Acute Renewal, 25' C, MHSF LC50 Ceriodaphnia dubia (Test Code 20) 0765 48Hr., Acute Renewal, 250 C, 20% DMW LC50 Ceriodaphnia dubia (Test Code 21) 0767 7-day Short term Chronic, Daily Renewal, MHSF IC25 Reproduction EPA 1002 0768 7-day Short term Chronic, Daily Renewal, MHSF NOEC Reproduction 0766 7-day Short term Chronic, Daily Renewal, MHSF NOEC Survival Ceriodaphnia dubia (Test Code 22) 0770 7-day Short term Chronic, Daily Renewal, 20% DMW IC25 Reproduction 0771 7-day Short term Chronic, Daily Renewal, 20% DMW NOEC Reproduction 0769 7-day Short term Chronic, Daily Renewal, 20% DMW NOEC Survival Daphnia magna (Test Code 32) 0788 48Hr., Acute, Non-Renewal, 25' C, MHSF LC50 Daphnia pulex (Test Code 38) 0794 48Hr., Acute, Non-Renewal, 250 C, MHSF LC50 Mysid (Test Code 42) 0798 48Hr., Acute, Non-Renewal, 250 C, 40 FSW LC50 Mysid (Test Code 43) 0816 7-day Short term Chronic, Daily Renewal, 40 FSW IC25 (ON) Growth 0818 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC (ON) Growth 0799 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC Survival Inland silverside (Test Code 44) 0803 48Hr., Acute, Non-Renewal, 250 C, 40 FSW LC50 Inland Silverside (Test Code 45) 0825 7-day Short term Chronic, Daily Renewal, 40 FSW IC25 (ON) Growth 0826 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC (ON) Growth 0824 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC Survival Sheepshead minnow (Test Code 46) 0804 48Hr., Acute, Non-Renewal, 250 C, 40 FSW LC50

0WERA A Waters Company Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: NC01230 Nuclear Plant WET Organisms/Test Conditions/End Points Checklist Laboratory's Graded Result Not Acceptable Analyte Organisms / Conditions End Points Test Acceptable (Corrective Number Required Action Required)

Sheepshead minnow (Test Code 47) 0820 7-day Short term Chronic, Daily Renewal, 40 FSW IC25 (ON) Growth 0822 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC (ON) Growth 0805 7-day Short term Chronic, Daily Renewal, 40 FSW NOEC Survival JOQi; C0 k~ ý~A 8/,'1 /Zo Z-Pr G\Ac eintQ\ Date Use a separate checklist for EACH lab used Signatureif6@

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AERA A Waters Company Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: TNO0003 Nuclear Plant Chemistry/Microbiology Analyte Checklist WP Study 204 Laboratory's Graded Result dTest Required Acceptable Not Acceptable Analyte Test / Method Ts(Corrective Action Required)

Mhinerals Conductivity at 25°C Alkalinity as CaCO3 Chloride Sodium Fluoride Sulfate Total Solids at 105°C Potassium Total Dissolved Solids at 180 0C Hardness Non-Filterable Residue (TSS)

SM2540D Q Calcium Magnesium Calcium Hardness as CaCO3 Total Hardness as CaCO3 pH Settleable Solids Settleable Solids SM2540F .

Solids Concentrate Non-Filterable Residue (TSS)

Total Dissolved Solids at 180°C Total Solids at 105°C Solids Non-Filterable Residue (TSS)

Total Dissolved Solids at 180°C Total Solids at 105°C Simple Nutrients Nitrate + Nitrite as N Nitrate as N ortho-Phosphate as P Ammonia as N Comolex Nutrients Total phosphorus as P Total Kjeldahl Nitrogen Nitrite as N

AERA A Waters Companyj Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: TNO0003 Nuclear Plant Chemistry/Microbiology Analyte Checklist WP Study 204 Laboratory's Graded Result Analyte Test I Method Test Required Acceptable Not Acceptable (Corrective Action Required)

De~mand BOD COD CBOD TOC Oil & Grease Concentrate n-Hexane Extractable Material(O&G)

(Gray)

EPA 1664A/SPE lxi o n-Hexane Extractable Material(O&G) n-Hexane Extractable Material(O&G)

(Gray)

Barium Iron EPA 200.7 Thallium Antimony Cadmium Molybdenum Aluminum Beryllium Silver Vanadium Selenium Boron Manganese Strontium Chromium Cobalt Zinc Arsenic Copper Lead Nickel Mercury Mercury Low-Level Mercury Low Level Mercury Hexsvalent Chromium Hexavalent Chromium

_ERA A Waters Company Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: TNO0003 Nuclear.Plant Chemistry/Microbiology Analyte Checklist WP Study 204 Laboratory's Graded Result Analyte Test / Method Test Required Acceptable Not Acceptable (Corrective Action Required)

Turbiity Turbidity Total Cyanide Cyanide, total Total Phenolics (4-AAP)

Phenolics, total Total Residual Chlorine Total Residual Chlorine Low-Level Total Residual Chlorine Low Level Total Residual Chlorine WasteWatRTM Coliform MicrobE TM Total Coliforms (MF)

Fecal Coliforms (MF)

E.coli (MF)

Total Coliforms (MPN)

Fecal Coliforms (MPN)

E.coli (MPN)

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&)ERA A Waters Company Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: TN00999 Nuclear Plant Chemistry/Microbiology Analyte Checklist DMRQA Study 32 Laboratory's Graded Result Analyte Test) Method Test Required Acceptable Not Acceptable Analyte____Test______Method _ Test__Required__ A t(Corrective Action Required)

Alkalinity as CaCO3 Conductivity at 25°C Fluoride Sulfate Total Dissolved Solids at 180°C Sodium Chloride Potassium Total Solids at 105°C Hardness Non-Filterable Residue CTSS)

Calcium Magnesium Calcium Hardness as CaCO3 Total Hardness as CaCO3 pH pH USGS 1-1586-85 o Settleable Solids Settleable Solids Solids Concentrate Non-Filterable Residue (TSS)

Total Dissolved Solids at 180°C Total Solids at 105°C Non-Filterable Residue (TSS)

Total Dissolved Solids at 180°C Total Solids at 105°C SimRle Nutrients Nitrate + Nitrite as N Ammonia as N Nitrate as N ortho-Phosphate as P Complex Nutrients Total phosphorus as P Total Kjeldahl Nitrogen Nitrite as N

0WERA AWaters Comipany Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: TN00999 Nuclear Plant Chemistry/Microbiology Analyte Checklist DMRQA Study 32 Laboratory's Graded Result eAcceptable Not Acceptable Analyte Test!/ Method Test Required (Corrective Action Required)

Demand COD BOD CBOD TOC Oil & Grease Concentrate n-Hexane Extractable Material(O&G)

(Grav)

Oil & Grease n-Hexane Extractable Material(O&G)

(Gray) n-Hexane Extractable Material(O&G)

(IR)

Trace Metals Aluminum Barium Cadmium Iron Vanadium Antimony Boron Lead Thallium Arsenic Cobalt Copper Nickel Zinc Beryllium Manganese Molybdenum Selenium Chromium Silver Strontium Mercury Mercury Low-Level Mercury Low Level Mercury Hexavalent Chromium Hexavalent Chromium Turbidity Turbidity

0)ERA A Waters Company Permittee Name: TVA - Sequoyah Permit Number: TN0026450 EPA Lab Code: TN00999 Nuclear Plant Chemistry/Microbiology Analyte Checklist DMRQA Study 32 Laboratory's Graded Result Analyte Test / Method Test Required Acceptable Not Acceptable (Corrective Action Required)

Total Cyanide Cyanide, total Total Phenolics (4-AAP)

Phenolics, total Total Residual Chlorine Total Residual Chlorine SM4500CI G o Low-Level Total Residual Chlorine Low Level Total Residual Chlorine WasteWatRTm Coliform MicrobETM Total Coliforms (MF)

Fecal Coliforms (MF)

E.coli (MF)

Total Coliforms (MPN)

Fecal Coliforms (MPN)

E.coli (MPN)

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