ML22251A119
| ML22251A119 | |
| Person / Time | |
|---|---|
| Site: | Sequoyah  |
| Issue date: | 09/08/2022 |
| From: | Markum T Tennessee Valley Authority |
| To: | Document Control Desk, Office of Nuclear Reactor Regulation |
| References | |
| Download: ML22251A119 (13) | |
Text
Tennessee Valley Authority, Sequoyah Nuclear Plant, P.O. Box 2000, Soddy Daisy, TN 37384 September 8, 2022 ATTN: Document Control Desk U.S. Nuclear Regulatory Commission Washington, D.C. 20555-0001
Subject:
Sequoyah Nuclear Plant, Discharge Monitoring Report (DMR) Quality Assurance Study 42 Final Report 2022 Attached is the Discharge Monitoring Report Quality Assurance Study 42 Final Report 2022 for Sequoyah Nuclear Plant.
Respectfully, Travis R. Markum Environmental Scientist 1\\14 TENNESSEE VALLEY AUTHORITY
1 Markum, Travis R From:
Markum, Travis R Sent:
Thursday, September 08, 2022 8:24 AM To:
Barbara Loudermilk
Subject:
TN0026450 - DMR-QA Study 42 Test Results Attachments:
SQN TN0026540 DMR-QA 42 Final Report 2022.pdf; TN00999 Final Report.pdf; NC00030 Final Report.pdf; NC00014 Final Report.pdf; NC01230 Final Report.pdf Ms.Loudermilk,
Pleasefindattachedtheprovidergradedtestresultsandchecklistsforthe2022DMRQAStudy42Laboratory PerformanceEvaluation.TheseresultswereobtainedbyTVASequoyahNuclearPlantandsupportinglaboratoriesas requiredbyNPDESPermitTN0026450.Letmeknowifyouhaveanyquestions.
Travis R. Markum Env. Scientist (Compliance)
Environmental Operations TVA Sequoyah Nuclear Plant PO Box 2000, OPS 5N Soddy Daisy, TN 37384
- 423-843-6714
- trmarkum@tva.gov NOTICE: This electronic message transmission contains information that may be TVA SENSITIVE, TVA RESTRICTED, or TVA CONFIDENTIAL. Any misuse or unauthorized disclosure can result in both civil and criminal penalties. If you are not the intended recipient, be aware that any disclosure, copying, distribution, or use of the content of this information is prohibited. If you have received this communication in error, please notify me immediately by email and delete the original message.
0MB Control No. 2080-0021. Approval expires 05/31/202.
OEPA United States Environmental Protection Agency Office of Enforcement and Compliance Assurance DMR-QA Study 42 (This data is collected under the authority of Section 308 of the Clean Water Act.)
NPDES Permittee Data Report Form
~22 Attention: Follow the instructions on the previous page to complete this form and submit data for evaluation.
Due September 9, 2022 Permittee Name TV A Sequoyah Nuclear Plant Current Permittee Mailing Address P.O. Box 2000 Mail top - OPS 4A-SQN City Soddy-Daisy Phone Number 423-843-6714 Fax Number Optional: If WP Study was used, list PT Provider name(s):
Optional : IF WP Study was used, list WP Study N umber(s):
NPDES Permit Number (State + 7-digit ID)
Permit Extension TN 0 0 2 6 4 State TN 5
0 Zip Code 37384-2000 E-Mail Address trmarkum tva.gov For DMR-QA Study 42, conducted in 2022, the Permittee ensured that their laboratory(ies) performing the required analyses:
Submitted Complete and Received a Graded Report by Received PT Samples Accurate Data by July 15, 2022 August 12, 2022 YES rll NO YES rll NO O
YES ill NO D
Certification by Permit Holder or Authorized Representative I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. Each reported value was produced from a single analytical run using the analytical system that routinely performs these analyses to produce compliance monitoring data required under our National Pollutant Discharge Elimination System (NPDES) permit. Neither I nor any of my subordinates compared our results with results from independent analyses conducted by us or any other laboratory before we reported our results to the U.S. EPA. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.
Name of Certifying Official Matthew R. Lovitt Signature Title Vice President (Acting)
Date =>/
~f ZO~z Address, phone number and e-mail of certifying official are required if different from above.
Address City State Zip Code EPA Form 6400-01 (Rev. 0-22). Previous editions are obsolete.
Page 13 Phone Number 423-843-6504 E-Mail Address mrlovitt@tva.gov
0MB Control No. 2080-0021. Approval expires 05/31/202 OEPA United States Environmental Protection Agency Office of Enforcement and Compliance Assurance DMR-QA Study 42 (This data is collected under the authority of Section 308 of the Clean Water Act.)
~22 Permittee Name NPDES Permit Number (State + 7-digit ID)
Permit Extension TV A Sequoyah Nuclear Plant TN 0026450 Identification of all CHEM, MICRO and WET laboratories who performed analyses for this permit U.S. EPA Lab Lab Analysis Lab State-Laboratory Name Laboratory Address Check box(esl that apply certified Code Chem Micro WET Type*
Lab**
T
-Sequoyah P.O. Box 2000 uclear Mailstop: OPS-5 Plant Soddy-Daisy, T 373 4 T
0 0 9 9 9
~ F Pace Ana lytical -
2225 River ide Ori e A he ille A heville, N 28804 C O O O 3 0
~ C Pace Analytical -
9800 Kincey A venue Hunter vi lle Suite 100 Huntersville N 28078 N C O O 0 1 4
~ C Environmental Testing 351 Depot Street S lution A heville, NC 2880 I C O 1 2 3 0
~ C
- Lab Types: C = Commercial; F = Federal; G = Local Government; I = Industrial; 0 = Other; S = State
- See Footnote on page 5 (Frequently Asked Questions) for the current list of states with lab accreditation programs If you need additional space, please make a copy of this page for additional laboratories.
EPA Form 6400-01 (Rev. 0-22). Previous editions are obsolete.
Page 14
Permittee Name TV A Sequoyah uclear Plant NPDES Permit No. T '
0 0 2 6 4 5 0 EPA Lab Code T N O O 9 9
9
&EPA Chemistry/Microbiology Analyte Checklist
~22 DMR-QA Study 42 Laboratorv's Graded Result Analyte Analyte Test Test Method Number Used Not Acceptable determined by Required (Optional)
Acceptable (Corrective Action state-certified Reauired) lab*
Microbiology E. coli, MF or MPN Fecal Coliform, MF or MPN Total Coliform, MF or MPN Trace Metals Aluminum Antimony Arsenic Barium Beryllium Cadmium Chromium, total Chrom ium, hexavalent Cobalt Copper Iron Lead Manganese Mercury Mercury (Low Level)
Molybdenum Nickel Selenium Silver Thallium Vanadium Zinc Demands 5-day BOD 5-day Carbonaceous BOD COD TOC Minerals Alkalinity, total (CaC03)
Chloride Fluoride Hardness, total (CaCOJ)
Specific conductance (25°C)
Sulfate Total Dissolved Solids (180°C)
Nutrients Ammonia as N Nitrate as N Nitrite as N Orthophosphate as P Total Kjeldahl-Nitrogen as N Total Phosphorus as P Misc. Analrles Non-Filterable Residue (TSS)
Oil and Grease pH X
uses l-15X6-XS (198S)
X Total Cyanide Total Phenolics (4-AAP)
Total Residual Chlorine X
IIAOl 8 167 Slh ~ I) ?008 X
Total Residual Chlorine (Low-Level)
Settleable Solids I
Turbidity n
r I,1,l l Z-112?...
I Name Matthew R. Lovitt Signature
/ /77
~
Date r;
- See Footnote on page 5 Page 15 Complete a separate checklist for EACH lab.
tJage :> OJ 11
~ERA DMR-QA 42 Final Report A Waters Company TNI Analyte Analyte Code
>MRQA pH (cat# 577, lot# Q042-977) 1900 pH NPDES Permit #: TN0026450 Permit Holder:
Travis Markum Units S.U.
SQN Environmental Scientist TVA - Sequoyah Nuclear Plant P.O. Box 2000 Mailstop: OPS-4A-SQN Soddy-Daisy, TN 37384-2000 423-843-6714 Performance Reported Assigned Acceptance Evaluation Value Value Limits Acceptable 7.86 7.83 7.63 - 8.03
>MRQA Total Residual Chlorine (cat# 587, lot# Q042-501) 1945 Free Residual Chlorine mg/L Not Reported 1.62 1.20- 1.91 1940 Total Residual Chlorine mg/L Acceptable 1.56 1.72 1.27 - 2.02 ERA Customer Number:
Report Issued:
Study Dates:
Method Description USGS 1-1586-85 1985 HACH 8167 5th ED 2008 Study Mean 7.88 1.55 1.61 16341 Table Mountain Pkwy* Golden, CO 80403
- 800.372.0122
- 303.431.8454
- fax 303.421.0159
- www.eraqc.com T203302 08/12/2022 04/15/2022 - 07/15/2022 Study USEPA Lab Standard Study Deviation Code 0.0752 TN00999 DMRQA42 0.161 TN00999 DMRQA42 0.114 TN00999 DMRQA42 Study# : DMR-QA 42 ~
Permittee Name TV A Sequoyah Nuclear Plant NPDES Permit No. TN O o 2 6 4 5 o EPA Lab Code r C O O O 3 O
oEPA Chemistry/Microbiology Analyte Checklist
~22 DMR-QA Study 42 Laboratorv's Graded Result Analyte Analyte Test Test Method Number Used Not Acceptable determined by Required (Optional)
Acceptable (Corrective Action state-certified Required) lab*
Microbiolol!Y E. coli, MF or MPN Fecal Coliform, MF or MPN Total Coliform, MF or MPN Trace Metals Aluminum Antimony Arsenic Barium Beryllium Cadmium Chromium, total Chromium, hexavalent Cobalt Copper Iron Lead Manganese Mercury Mercury (Low Levell Molybdenum Nickel Selenium Silver Thallium Vanadium Zinc Demands 5-day BOD 5-day Carbonaceous BOD COD TOC Minerals Alkalinity, total (CaCO3)
Chloride Fluoride Hardness, total (CaCO3)
Specific conductance (25°C)
Sulfate Total Dissolved Solids (180°C)
Nutrients Ammonia as N Nitrate as N Nitrite as N Orthophosphate as P Total Kjeldahl-Nitrogen as N Total Phosphorus as P Misc. Ana/ytes Non-Filterable Residue (TSS)
X SM 2540 D-20 11 X
Oil and Grease pH Total Cyanide Total Phenolics (4-AAP)
Total Residual Chlorine Total Residual Chlorine (Low-Levell Settleable Solids Turbidity Name Matthew R. Lovitt Signature
~
_,1 Date I q Ir&~,
- See Footnote on a e 5 Com letea se arate checklist for EACH lab.
p g Page 15 p
p
phenovo Certified Reference Ma er als DMRQA42 Graded Results Report Study: WP0122 for DMRQA42 p
Corrpany Opening Date: January 10, 2022 - Closing Date: February 24, 2022 EPA Lab ID:
NC00030 Laboratory:
Pace Analytical - Asheville 2225 Riverside Drive Asheville, NC 28804 UNITED STATES Mr. Jacob Cottrell, Quality Manager 8184 176052 Specific Conductance (PT-COND-WP)
NELAC Analyte Method Code Code 1610 Specific Conductance (25°C) 10006403 1610 Specific Conductance (25°C) 10006403 1610 Specific Conductance (25°C) 10006403 Solids (PT-SOL-WP)
NELAC Analyte Method Code Code 1955 Total Dissolved Solids at 180° (TFR) 2005041 3 1955 Total Dissolved Solids at 180° (TFR) 20050435 1960 Non-Filterable Residue (TSS) 20051212 1960 Non-Filterable Residue (TSS) 20051223 NPDES Permit ID: TN0026450 Permittee Name: TVA-SEQUOYAH NUCLEAR Method Description Units EPA 120.1
µmhos/cm EPA 120.1, Rev. 1982
µmhos/cm EPA 120.1 (1982)
µmhos/cm Method Description Units SM 2540 C-2011 mg/L SM 2540 C-2015 mg/L SM 2540 D-2011 mg/L SM 2540 D-2015 mg/L Assigned Result Value 509 521 509 521 509 521 Assigned Result Value 493 496 493 496 33.2 32 33.2 32 6390 Joyce Drive
- 100 Golden, CO 80403 Lot #: 8229-72 Acceptance Evaluation Limits 458 - 560 Acceptable 458 - 560 Acceptable 458 - 560 Acceptable Lot #: 8229-09 Acceptance Evaluation Limits 444 - 542 Acceptable 444 - 542 Acceptable 23.9 - 39.3 Acceptable 23.9 - 39.3 Acceptable
~
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iCtency f eshng ProvJCler Certificate # 2427.01 Phone 303-940-0033 Fax 866-283-0269 www.phenova.com
uclear Plant N PDES Permit No. T N O O 2 6 4 5 O EPA Lab Code
' C O I 2 3 0 oEPA Chemistry/Microbiology Analyte Checklist
~22 DMR-QA Study 42 Laboratorv's Graded Result Analyte Analyte Test Test Method Number Used Not Acceptable determined by Required (Optional)
Acceptable (Corrective Action state-certified Reauiredl lab*
MicrobloloPY E. coli, MF or MPN Fecal Coliform, MF or MPN Total Coliform, MF or MPN Trace Metals Aluminum Antimony Arsenic Barium Beryllium Cadmium Chromium, total Chromium, hexavalent Cobalt Copper Iron Lead Manganese Mercury Mercury (Low Level)
Molybdenum Nickel Selenium Silver Thallium Vanadium Zinc Demands 5-day BOD 5-day Carbonaceous BOD COD TOG Minerals Alkalinity, total (CaCO3)
Chloride Fluoride Hardness, total (CaCO3)
Specific conductance (25°CJ Sulfate Total Dissolved Solids (180°CJ Nutrients Ammonia as N Nitrate as N Nitrite as N Orthophosphate as P Total Kjeldahl-Nitrogen as N Total Phosphorus as P Misc. Analytes Non-Filterable Residue (TSS)
Oil and Grease X
E:PA 1664 IJ (11 1;:M) ?Olli X
pH Total Cyanide Total Phenolics (4-AAP)
Total Residual Chlorine Total Residual Chlorine (Low-Levell Settleable Solids Turbidity Matthew R. Lovitt
.,,.,-2,-""--
I 9.{efwiL I Name Signature
///7
_,.1 Date
- See Footnote on page 5 Page 15 Complete a separate checklist for EACH lab.
phenovo Certified Reference Materials DMRQA42 Graded Results Report Study: WP0122 for DMRQA42 Opening Date: January 10, 2022 - Closing Date: February 24, 2022 EPA Lab ID:
NC00014 Laboratory:
Pace Analytical - Huntersville 9800 Kincey Avenue Suite 100 Huntersville, NC 28078 UNITED STATES Mrs. Melissa Honbarger, Quality Analyst 704-977-0944 Oil & Grease - 1 L (PT-OGR1 L-WP)
NELAC Analyte Code 1803 n-Hexane Extractable Material (O&G) (Gravimetric)
NPDES Permit ID: TN0026450 Permittee Name: TVA-SEQUOYAH NUCLEAR Method Method Description Units Code 10261617 EPA 1664 B (HEM) 2010 mg/L Assigned Result Value 31.5 27.4 6390 Joyce Drive
- 100 Golden, CO 80403 Lot #: 8229-1038 Acceptance Evaluation Limits 17.8-40.6 Acceptable
~
~
EDl!]E ncy Tes1w,g e1 Certificate # 2427 01 Phone 303-940-0033 Fax 866-283-0269 www.phenova.com
NPDES Permit No. T O O 2 6 4 5 o EPA Lab Code
' C O I 2 3 0
&EPA Whole Effluent Toxicity (WET) Analyte Checklist
~22 DMR-QA Study 42 Laboratorv's Graded Result Analyte Analyte Organism I Conditions Endpoint Test Not Acceptable determined by Number Required Acceptable (Corrective Action state-certified Required) lab*
Test Code 13 (refer to EPA Method 2000.0) 754 Fathead minnow (Pimephales promelas) - MHSF 25°C LC50 Test Code 14 (refer to EPA Method 2000.0) 755 Fathead minnow (Pimephales promelas) - 20% DMW LC50 Test Code 15 (refer to EPA Method 1000.0) 756 Fathead minnow (Pimephales promelas) - MHSF NOEC SURVIVAL 181 181 808 Fathead minnow (Pimephales promelas) - MHSF IC25** (ON) GROWTH 181 181 810 Fathead minnow (Pimephales promelas) - MHSF NOEC (ON) GROWTH 181 181 Test Code 16 (refer to EPA Method 1000.0) 759 Fathead minnow (Pimephales promelas) - 20% DMW NOEC SURVIVAL 812 Fathead minnow (Pimephales promelas) - 20% DMW IC25** (ON) GROWTH 814 Fathead minnow (Pimephales promelas) - 20% DMW NOEC (ON) GROWTH Test Code 19 (refer to EPA Method 2002.0) 764 Ceriodaphnia dubia - MHSF 25°C LC50 Test Code 20 (refer to EPA Method 2002.0) 765 Ceriodaphnia dubia - 20% DMW 25°C LC50 Test Code 21 (refer to EPA Method 1002.0) 766 Ceriodaphnia dubia - MHSF NOEC SURVIVAL 181 181 767 Ceriodaphnia dubia - MHSF IC25** REPRODUCTION 181 181 768 Ceriodaphnia dubia - MHSF NOEC REPRODUCTION 181 181 Test Code 22 (refer to EPA Method 1002.0J 769 Ceriodaphnia dubia - 20% DMW NOEC SURVIVAL 770 Ceriodaphnia dubia - 20% DMW IC25** REPRODUCTION 771 Ceriodaphnia dubia - 20% DMW NOEC REPRODUCTION Test Code 32 (refer to EPA Method 2021.0) 788 Daphnia magna - MHSF 25°C LC50 Test Code 38 (refer to EPA Method 2021.0) 794 Daphnia pulex - MHSF 25°C LC50 Test Code 42 (refer to EPA Method 2007.Ol 798 Mysid (Americamysis bahia, Mysidopsis bahia) 25°C LC50 Test Code 43 (refer to EPA Method 1007.0) 799 Mysid (Americamysis bahia, Mysidopsis bahia)
NOEC SURVIVAL 816 Mysid (Americamysis bahia, Mysidopsis bahia)
IC25** (ON) GROWTH 818 Mysid (Americamysis bahia, Mysidopsis bahia)
NOEC(ON)GROWTH Test Code 44 (refer to EPA Method 2006.0) 803 Inland silverside (Menidia beryllina) 25°C LC50 Test Code 45 (refer to EPA Method 1006.0) 824 Inland silverside (Menidia beryllina)
NOEC SU RVIVAL 825 Inland silverside (Menidia beryllina)
IC25** (ON) GROWTH 826 Inland silverside (Menidia beryllina)
NOEC CON) GROWTH Test Code 46 (refer to EPA Method 2004.0) 804 Sheepshead minnow (Cyprinodon variegatus) 25°C LC50 Test Code 47 (refer to EPA Method 1004.0l 805 Sheepshead minnow (Cyprinodon variegatus)
NOEC SURVIVAL 820 Sheepshead minnow (Cyprinodon variegatus)
IC25** (ON) GROWTH 822 Sheepshead minnow (Cyprinodon variegatus)
NOEC (ON) GROWTH
__,,_,,,,., 7
- 4/fV
?/7/74,z Name Matthew R. Lovitt Signature Yo~
Date r
- See Footnote on page 5
- Preferred endpoint for OM R-QA performance test reporting Complete a separate checklist for EACH lab.
Page 16
phenovofl~
Cer11f1ed Reference Materials DMRQA42 Graded Results Report Study: DMRQA42-WET A
r 1,
n x Company Opening Date: April 15, 2022 - Closing Date: July 15, 2022 EPA Lab ID:
NC01 230 Laboratory:
Environmental Testing Solutions, Inc.
351 Depot Street Asheville, NC 28801 USA Ms. Kelley Keenan, President 828-350-9364 Fathead Minnow Method 13 (PT-13-WET)
NELAC Analyte Code 3410 Fathead Minnow Acute MHSF 25' - LCSO Fathead Minnow Method 15 (PT-15-WET)
NELAC Analyte Code 3410 Fathead Minnow Chronic MHSF - Survival NOEC 3410 Fathead Minnow Chronic MHSF - Growth IC25 (ON) 3410 Fathead Minnow Chronic MHSF - Growth NOEC (ON)
Ceriodaphnia Method 19 (PT-19-WET)
NELAC Analyte Code 3315 Ceriodaphnia Acute MHSF 25' - LC50 NPDES Permit ID: TN0026450 Permittee Name: TVA/ Sequoyah Nuclear Plant Method Code Method Description Units 10213602 EPA 2000. 0 - Fathead s.u.
minnow, 48-hr Acute, nonrenewal, MHSF, Method Code Method Description Units 10214207 EPA 1000.0 - Fathead S.U.
minnow, 7-day Chronic, daily renewal, MHSF, 25' C (2002) 10214207 EPA 1000.0 - Fathead S.U.
minnow, 7-day Chronic.
daily renewal. MHSF, 25"C (2002) 10214207 EPA 1000.0 - Fathead S.U.
minnow, 7-day Chronic, daily renewal, MHSF, 25' C (2002)
Method Code Method Description Units 10213646 EPA 2002.0 -
S.U.
Ceriodaphnia dubia, 48-hr Acute, nonrenewal, MHSF, 2s*c (2002)
Assigned Result Value 33.6 30.8 Assigned Result Value 50 50 54.1 53.9 50 25 Assigned Result Value 52.1 36.6 6390 Joyce Drive
- 100 Golden, CO 80403
~
Gg]eo1T]iil ncy Testing Provider Certificate# 2427.01 Phone 303-940-0033 Fax 866-283-0269 www.phenova.com Lot #: 8553-13 Acceptance Evaluation Limits 15.1 - 52.0 Acceptable Lot#: 8553-15 Acceptance Evaluation Limits 25 - 100 Acceptable 38.0 - 70.2 Acceptable 12.5 - 100 Acceptable Lot#: 8553-19 Acceptance Evaluation Limits 18.7 - 85.5 Acceptable
I phenovo*
Certlf ed Re erence atenals DMRQA42 Graded Results Report Study: DMRQA42-WET A Pie n
( rimpcmy Opening Date: April 15, 2022 - Closing Date: July 15, 2022 EPA Lab ID NC01230 Laboratory:
Environmental Testing Solutions, Inc.
351 Depot Street Asheville, NC 28801 USA Ms. Kelley Keenan, President 828-350-9364 Ceriodaphnia Method 21 (PT-21-WET)
NELAC Analyte Code 3315 Ceriodaphnia Chronic MHSF - Survival NOEC 3315 Ceriodaphnia Chronic MHSF - Reproduction IC25 3315 Ceriodaphnia Chronic MHSF - Reproduction NOEC NPDES Permit ID: TN0026450 Permittee Name: TVA/ Sequoyah Nuclear Plant Method Code Method Description Units 10253040 EPA 1002.0-S.U.
Cenodaphnia dubia, 3-Brood Chronic, daily renewal, MHSF, 25' C (2002) 10253040 EPA 1002.0 -
S.U.
Ceriodaphnia dubia, 3-Brood Chronic, daily renewal, MHSF, 25' C (2002) 10253040 EPA 1002.0-S.U.
Ceriodaphnia dubia, 3-Brood Chronic, daily renewal, MHSF, 25' C (2002)
Assigned Result Value 50 25 29.8 31.2 25 25 6390 Joyce Drive
- 100 Golden, CO 80403
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Certificate # 2427 01 Phone 303-940-0033 Fax 866-283-0269 www.phenova.com Lot#: 8553-21 Acceptance Evaluation Limits25-100 Acceptable 19.2 - 40.3 Acceptable 12.5-50 Acceptable