ML070780367: Difference between revisions

From kanterella
Jump to navigation Jump to search
(Created page by program invented by StriderTol)
 
(Created page by program invented by StriderTol)
Line 60: Line 60:
== Description:==
== Description:==
SCREEN IAW NOP92A1 Response:
SCREEN IAW NOP92A1 Response:
Subresponse  
Subresponse
: CONVERTED DATA Initial Due Date:
: CONVERTED DATA Initial Due Date:
10/01/1996 Closure Comments: PAC APPROVED NOP92A1 EXHIBIT 3   
10/01/1996 Closure Comments: PAC APPROVED NOP92A1 EXHIBIT 3   
~~ I I CA Number: 2 -I -- - I 1" - Name - _--I Group Assigned By: Tech Chemistry Staff Assigned To: Tech Chemistry Staff LOOMIS, L. Loomis,Larry Subassigned To  
~~ I I CA Number: 2 -I -- - I 1" - Name - _--I Group Assigned By: Tech Chemistry Staff Assigned To: Tech Chemistry Staff LOOMIS, L. Loomis,Larry Subassigned To
: Originated By: LOOMIS, L. Performed By: LOOMIS, L. Subperformed By: Approved By: Closed By: LOOMIS, L. 9/24/1996 0O:OO:OO 7/ 14/1997 0O:OO:OO 7/14/1997 0O:OO:OO Current Due Date:
: Originated By: LOOMIS, L. Performed By: LOOMIS, L. Subperformed By: Approved By: Closed By: LOOMIS, L. 9/24/1996 0O:OO:OO 7/ 14/1997 0O:OO:OO 7/14/1997 0O:OO:OO Current Due Date:
08/30/1997 Initial Due Date: 08/30/1997 CA Type: GENERAL Plant Constraint:
08/30/1997 Initial Due Date: 08/30/1997 CA Type: GENERAL Plant Constraint:
Line 71: Line 71:


CONDUCT AN EVALUATION TO DETERMINE THE CAUSE OF THE HIGH NITRATE LEVELS IN THE TBCCW SYSTEM. DETERMINE CORRECTIVE ACTIONS AND ACTIONS TO PRECLUDE RECURRENCE.
CONDUCT AN EVALUATION TO DETERMINE THE CAUSE OF THE HIGH NITRATE LEVELS IN THE TBCCW SYSTEM. DETERMINE CORRECTIVE ACTIONS AND ACTIONS TO PRECLUDE RECURRENCE.
Response: COMPLETE EVALUATION PER NOP92A1, SECTION  
Response: COMPLETE EVALUATION PER NOP92A1, SECTION 6.4. PROBLEM DESCRIPTION: HIGH NITRATE LEVELS EXIST IN THE TBCCW SYSTEM WHICH HAVE BEEN ASSOCIATED WITH SCC IN CARBON STEEL PIPING. DIRECT CAUSE: ONE LIKELY CAUSE COULD HAVE BEEN A SYSTEM LEAK WHICH INTRODUCES AIR WHICH CONVERTS NITRITE (THE CHEMICAL ADDITIVE)
 
===6.4. PROBLEM===
DESCRIPTION: HIGH NITRATE LEVELS EXIST IN THE TBCCW SYSTEM WHICH HAVE BEEN ASSOCIATED WITH SCC IN CARBON STEEL PIPING. DIRECT CAUSE: ONE LIKELY CAUSE COULD HAVE BEEN A SYSTEM LEAK WHICH INTRODUCES AIR WHICH CONVERTS NITRITE (THE CHEMICAL ADDITIVE)
TO NITRATEL.
TO NITRATEL.
HOWEVER, THE TBCCW SYSTEM IS KNOWN TO BE A TIGHT SYSTEM WITH LITTLE LEAKAGE. ANOTHER POSSIBLE CAUSE SEEN IN THE INDUSTRY IS THE CONVERSION OF NITRITE TO NITRATE DUE BACTERIA. THIS IS LIKELY CONSIDERING SYSTEM CONDITIONS SUCH AS TEMPERATURE AND FLOW. REPEAT OCCURRENCE:
HOWEVER, THE TBCCW SYSTEM IS KNOWN TO BE A TIGHT SYSTEM WITH LITTLE LEAKAGE. ANOTHER POSSIBLE CAUSE SEEN IN THE INDUSTRY IS THE CONVERSION OF NITRITE TO NITRATE DUE BACTERIA. THIS IS LIKELY CONSIDERING SYSTEM CONDITIONS SUCH AS TEMPERATURE AND FLOW. REPEAT OCCURRENCE:
NO MAINTENANCE RULE: UNKNOWN Subresponse  
NO MAINTENANCE RULE: UNKNOWN Subresponse
: Closure Comments: COMPLETE EVALUATION PER NOP92A1, SECTION  
: Closure Comments: COMPLETE EVALUATION PER NOP92A1, SECTION 6.4. PROBLEM DESCRIPTION:
 
===6.4. PROBLEM===
DESCRIPTION:
HIGH NITRATE LEVELS EXIST IN THE TBCCW SYSTEM WHICH HAVE BEEN ASSOCIATED WITH SCC IN CARBON STEEL PIPING. DIRECT CAUSE: ONE LIKELY CAUSE COULD HAVE BEEN A SYSTEM LEAK WHICH INTRODUCES AIR WHICH CONVERTS NITRITE (THE CHEMICAL ADDITIVE)
HIGH NITRATE LEVELS EXIST IN THE TBCCW SYSTEM WHICH HAVE BEEN ASSOCIATED WITH SCC IN CARBON STEEL PIPING. DIRECT CAUSE: ONE LIKELY CAUSE COULD HAVE BEEN A SYSTEM LEAK WHICH INTRODUCES AIR WHICH CONVERTS NITRITE (THE CHEMICAL ADDITIVE)
TO NITRATEL.
TO NITRATEL.
Line 104: Line 98:
MEMO DETAILING THE RESULTS THE EVALUATION AND THE REQUIRED CORRECTIVE ACTIONS. CONCURRENCE MUST BE OBTAINED FROM ACTION ITEM OWNERS. NOTE: CHEMISTRY HAS ALSO BEEN ASSIGNED AN ACTION TO DETERMINE THE CAUSE OF THE EXCESS NITRATE AND SHOULD BE ABLE TO PROVIDE ADDITIONAL INFORMATION TO ASSIST IN YOUR EVALUATION.
MEMO DETAILING THE RESULTS THE EVALUATION AND THE REQUIRED CORRECTIVE ACTIONS. CONCURRENCE MUST BE OBTAINED FROM ACTION ITEM OWNERS. NOTE: CHEMISTRY HAS ALSO BEEN ASSIGNED AN ACTION TO DETERMINE THE CAUSE OF THE EXCESS NITRATE AND SHOULD BE ABLE TO PROVIDE ADDITIONAL INFORMATION TO ASSIST IN YOUR EVALUATION.
PROBLEM REPORT PROBLEM REPORT No.
PROBLEM REPORT PROBLEM REPORT No.
96.0396.02  
96.0396.02
: 1. Problem
: 1. Problem


Line 110: Line 104:


High Nitrate levels exist in the TBCCW System. High Nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping. 2. Apparent/Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates.
High Nitrate levels exist in the TBCCW System. High Nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping. 2. Apparent/Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates.
An action item should be given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.  
An action item should be given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.
: 3. Repeat Occurrence: u YES NO 4. Maintenance Rule Functional Failure: - YES -u- NO - Unknown 5. Corrective Actions Completed (include Dates if possible) A literature search (See Attached Letter for details and date completed) was performed to determine the most probable cause of the Nitrate build-up and its affect on carbon steel piping. Based on this research for the Nitrate concentration, system operating conditions and the duration of the present problem, the probability of developing stress corrosion cracking is low. However due to the lack of conclusive data at the appropriate operating conditions there is sufficient probability of stress corrosion cracking that an action item should be given to the MSTP Group to develop a program of sufficient duration to inspect TBCCW piping welds. Civ/ Struct./
: 3. Repeat Occurrence: u YES NO 4. Maintenance Rule Functional Failure: - YES -u- NO - Unknown 5. Corrective Actions Completed (include Dates if possible) A literature search (See Attached Letter for details and date completed) was performed to determine the most probable cause of the Nitrate build-up and its affect on carbon steel piping. Based on this research for the Nitrate concentration, system operating conditions and the duration of the present problem, the probability of developing stress corrosion cracking is low. However due to the lack of conclusive data at the appropriate operating conditions there is sufficient probability of stress corrosion cracking that an action item should be given to the MSTP Group to develop a program of sufficient duration to inspect TBCCW piping welds. Civ/ Struct./
Mech will assist the MSTP Group in the selection of inspection locations, as necessary.  
Mech will assist the MSTP Group in the selection of inspection locations, as necessary.
: 6. Corrective Actions Required 13 U (check "NR" if not required) - NIR a) Action Required chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria. OClosure Requirement If Nitrobacter bacteria are found a biocide should be introduced as a part of a chemical treatment program to eliminate the bacteria and reduce the Nitrate concentration. Responsible Manager Dave Fountain Due Date 04/01/97 E 0 ODead Date 05/30/97 b) Action Required MSTP Group develop a weld inspection program. EClosure Requirement MSTP Group develop a weld inspection program of sufficient duration for TBCCW piping welds. Responsible Manager Kevin Burke   
: 6. Corrective Actions Required 13 U (check "NR" if not required) - NIR a) Action Required chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria. OClosure Requirement If Nitrobacter bacteria are found a biocide should be introduced as a part of a chemical treatment program to eliminate the bacteria and reduce the Nitrate concentration. Responsible Manager Dave Fountain Due Date 04/01/97 E 0 ODead Date 05/30/97 b) Action Required MSTP Group develop a weld inspection program. EClosure Requirement MSTP Group develop a weld inspection program of sufficient duration for TBCCW piping welds. Responsible Manager Kevin Burke   
---- ~ ~ CORRECTIVE ACTION Entwgy 7. Corrective Actions Required to Preclude Recurrence (check "NR" if not required)
---- ~ ~ CORRECTIVE ACTION Entwgy 7. Corrective Actions Required to Preclude Recurrence (check "NR" if not required)
__ N/R CR-PNP- 1996-00396 a) Action Required Mechanical select inspection points. Closure Requirement Mechanical/Civil/Structural selection of 5 to 10 inspection points based on the attached letter with proposed Altran criteria. Responsible Manager Thomas White, Jr. Due Date 04/01/97 ODead Date 05/31/97 b) Action Required Closure Requirement Responsible Manager Due Date / / 0 0 ODead Date -/-/- 8. Trend Data for Apparent Cause@ 0 (check "N/R" for Direct Cause Analysis) u N/R NOTE If more than 2 Inappropriate Actions are defined, use Exhibit  
__ N/R CR-PNP- 1996-00396 a) Action Required Mechanical select inspection points. Closure Requirement Mechanical/Civil/Structural selection of 5 to 10 inspection points based on the attached letter with proposed Altran criteria. Responsible Manager Thomas White, Jr. Due Date 04/01/97 ODead Date 05/31/97 b) Action Required Closure Requirement Responsible Manager Due Date / / 0 0 ODead Date -/-/- 8. Trend Data for Apparent Cause@ 0 (check "N/R" for Direct Cause Analysis) u N/R NOTE If more than 2 Inappropriate Actions are defined, use Exhibit
: 14. a) Inappropriate Action (IA)
: 14. a) Inappropriate Action (IA)


== Description:==
== Description:==


IA Job Title IA Group IA Department IA Job Title IA Group IA Department BECO OContractor Work Process Key Activity Work Process Key Activity O&P Failure Mechanism Human Error Type (Circle 1): Skill BasedU HEIA Failure Mechanism Subresponse  
IA Job Title IA Group IA Department IA Job Title IA Group IA Department BECO OContractor Work Process Key Activity Work Process Key Activity O&P Failure Mechanism Human Error Type (Circle 1): Skill BasedU HEIA Failure Mechanism Subresponse
:
:
EntHgy Closure Comments: MEMO DETAILING THE RESULTS THE EVALUATION AND THE REQUIRED CORRECTIVE ACTIONS. CONCURRENCE MUST BE OBTAINED FROM ACTION ITEM OWNERS. CORRECTIVE ACTION CR-PNP-1996-00396 NOTE: CHEMISTRY HAS ALSO BEEN ASSIGNED AN ACTION TO DETERMINE THE CAUSE OF THE EXCESS NITRATE AND SHOULD BE ABLE TO PROVIDE ADDITIONAL INFORMATION TO ASSIST IN YOUR EVALUATION.
EntHgy Closure Comments: MEMO DETAILING THE RESULTS THE EVALUATION AND THE REQUIRED CORRECTIVE ACTIONS. CONCURRENCE MUST BE OBTAINED FROM ACTION ITEM OWNERS. CORRECTIVE ACTION CR-PNP-1996-00396 NOTE: CHEMISTRY HAS ALSO BEEN ASSIGNED AN ACTION TO DETERMINE THE CAUSE OF THE EXCESS NITRATE AND SHOULD BE ABLE TO PROVIDE ADDITIONAL INFORMATION TO ASSIST IN YOUR EVALUATION.
PROBLEM REPORT PROBLEM REPORT No. 96.0396.02  
PROBLEM REPORT PROBLEM REPORT No. 96.0396.02
: 1. Problem
: 1. Problem


== Description:==
== Description:==


High Nitrate levels exist in the TBCCW System. High Nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping.  
High Nitrate levels exist in the TBCCW System. High Nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping.
: 2. Apparent/Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates.
: 2. Apparent/Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates.
An action item should be given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.  
An action item should be given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.
: 3. Repeat Occurrence: u YES NO 4. Maintenance Rule Functional Failure: - YES -u- NO - Unknown 5. Corrective Actions Completed (include Dates if possible) A literature search (See Attached Letter for details and date completed) was performed to determine the most probable cause of the Nitrate build-up and its affect on carbon steel piping. Based on this research for the Nitrate concentration, system operating conditions and the duration of the present problem, the probability of developing stress corrosion cracking is low. However due to the lack of conclusive data at the appropriate operating conditions there is sufficient probability of stress corrosion cracking that an action item should be given to the MSTP Group to develop a program of sufficient duration to inspect TBCCW piping welds. Civ/ Struct./ Mech will assist the MSTP Group in the selection of inspection locations, as necessary.  
: 3. Repeat Occurrence: u YES NO 4. Maintenance Rule Functional Failure: - YES -u- NO - Unknown 5. Corrective Actions Completed (include Dates if possible) A literature search (See Attached Letter for details and date completed) was performed to determine the most probable cause of the Nitrate build-up and its affect on carbon steel piping. Based on this research for the Nitrate concentration, system operating conditions and the duration of the present problem, the probability of developing stress corrosion cracking is low. However due to the lack of conclusive data at the appropriate operating conditions there is sufficient probability of stress corrosion cracking that an action item should be given to the MSTP Group to develop a program of sufficient duration to inspect TBCCW piping welds. Civ/ Struct./ Mech will assist the MSTP Group in the selection of inspection locations, as necessary.
: 6. Corrective Actions Required 0 0 (check "NIR" if not required) - NIR a) Action Required Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.
: 6. Corrective Actions Required 0 0 (check "NIR" if not required) - NIR a) Action Required Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.
CClosure Requirement If Nitrobacter bacteria are found a biocide should be introduced as a part of a chemical treatment program to eliminate the bacteria and reduce the Nitrate concentration. Responsible Manager Dave Fountain Due Date 04/01/970 0 ODead Date 05/30/97 b) Action Required MSTP Group develop a weld inspection program. OClosure Requirement MSTP Group develop a weld inspection program of sufficient duration for TBCCW piping welds. Responsible Manager Kevin Burke Ent43g-y 7. Corrective Actions Required to Preclude Recurrence a) Action Required Mechanical select inspection points. (check "NR" if not required)
CClosure Requirement If Nitrobacter bacteria are found a biocide should be introduced as a part of a chemical treatment program to eliminate the bacteria and reduce the Nitrate concentration. Responsible Manager Dave Fountain Due Date 04/01/970 0 ODead Date 05/30/97 b) Action Required MSTP Group develop a weld inspection program. OClosure Requirement MSTP Group develop a weld inspection program of sufficient duration for TBCCW piping welds. Responsible Manager Kevin Burke Ent43g-y 7. Corrective Actions Required to Preclude Recurrence a) Action Required Mechanical select inspection points. (check "NR" if not required)
Line 165: Line 159:
IF NITROBACTER BACTERIA ARE FOUND A BIOCIDE SHOULD BE INTRODUCED AS A PART OF A CHEMICAL TREATMENT PROGRAM TO ELIMINATE THE BACTERIA AND REDUCE THE NITRATE CONCENTRATION.
IF NITROBACTER BACTERIA ARE FOUND A BIOCIDE SHOULD BE INTRODUCED AS A PART OF A CHEMICAL TREATMENT PROGRAM TO ELIMINATE THE BACTERIA AND REDUCE THE NITRATE CONCENTRATION.
PROVIDE MEMO DOCUMENTING DETAILS OF TASK COMPLETION.
PROVIDE MEMO DOCUMENTING DETAILS OF TASK COMPLETION.
CR-PNP-1996-00396  
CR-PNP-1996-00396
[4/2/98;FOUNTAIN, D.] TESTING WAS PERFORMED IN HOUSE DUE TO THE INABILITY TO LOCATE A QUALIFIED LABORATORY CAPABLE OF PERFORMING TESTING JN THIS AREA. (SAMPLES MUST BE AT THE VENDORS LABORATORY LESS THAN 24 HOURS AFTER SAMPLING.)
[4/2/98;FOUNTAIN, D.] TESTING WAS PERFORMED IN HOUSE DUE TO THE INABILITY TO LOCATE A QUALIFIED LABORATORY CAPABLE OF PERFORMING TESTING JN THIS AREA. (SAMPLES MUST BE AT THE VENDORS LABORATORY LESS THAN 24 HOURS AFTER SAMPLING.)
THE HACH COMPANY PROVIDES TEST KITS FOR PERFORMING NITROBACTERIA TESTING ON SITE. THESE TEST KITS WERE PURCHASED AND SAMPLES WERE ANALYZED IN HOUSE FOR THE RBCCW, TBCCW AND MAKEUP WATER SYSTEMS. NO DETECTABLE NITROBACTERIA WAS IDENTIFIED. MULTIPLE SAMPLES WERE ANALYZED ON THE TBCCW SYSTEM FROM VARIOUS LOCATIONS WHERE THE HIGHEST POTENTIAL FOR BACTERIA EXISTED. SAMPLES FROM THE SLIPSTREAM FILTER WERE INCUBATED TO INCREASE THE NUMBER OF COLONIES PRESENT IF ANY NITROBACTERIA EXISTED. THESE SAMPLES ALSO SHOWED NO SIGNS OF DETECTABLE NITROBACTERIA WHEN TESTED WITH THE HACH TEST KITS.
THE HACH COMPANY PROVIDES TEST KITS FOR PERFORMING NITROBACTERIA TESTING ON SITE. THESE TEST KITS WERE PURCHASED AND SAMPLES WERE ANALYZED IN HOUSE FOR THE RBCCW, TBCCW AND MAKEUP WATER SYSTEMS. NO DETECTABLE NITROBACTERIA WAS IDENTIFIED. MULTIPLE SAMPLES WERE ANALYZED ON THE TBCCW SYSTEM FROM VARIOUS LOCATIONS WHERE THE HIGHEST POTENTIAL FOR BACTERIA EXISTED. SAMPLES FROM THE SLIPSTREAM FILTER WERE INCUBATED TO INCREASE THE NUMBER OF COLONIES PRESENT IF ANY NITROBACTERIA EXISTED. THESE SAMPLES ALSO SHOWED NO SIGNS OF DETECTABLE NITROBACTERIA WHEN TESTED WITH THE HACH TEST KITS.
Line 180: Line 174:
== Description:==
== Description:==
CONVERTED DATA Approved:
CONVERTED DATA Approved:
Previous Duedate: 0313 111998 03/25/1998 03/25/1998 Ent43g-y CA Number: 5 CORRECTIVE ACTION CR-PI"-1996-00396 I __-I__ _I_-____ --- ----- - ---1-1 1--1-11111~1 I i Group Name Assigned By: CA&A Staff Assigned To: Operations Support Staff WOLLMAN, S. Burke,Kevin R Subassigned To  
Previous Duedate: 0313 111998 03/25/1998 03/25/1998 Ent43g-y CA Number: 5 CORRECTIVE ACTION CR-PI"-1996-00396 I __-I__ _I_-____ --- ----- - ---1-1 1--1-11111~1 I i Group Name Assigned By: CA&A Staff Assigned To: Operations Support Staff WOLLMAN, S. Burke,Kevin R Subassigned To
: Originated By: WOLLMAN, S. Performed By: BURKE, K. Subperformed By: Approved By: Closed By:
: Originated By: WOLLMAN, S. Performed By: BURKE, K. Subperformed By: Approved By: Closed By:
WOLLMAN, S. 2/6/1997 0O:OO:OO 5/22/1997 0O:OO:OO 5/22/ 1 997 00: 00: 00 Current Due Date: 05/30/1997 Initial Due Date:
WOLLMAN, S. 2/6/1997 0O:OO:OO 5/22/1997 0O:OO:OO 5/22/ 1 997 00: 00: 00 Current Due Date: 05/30/1997 Initial Due Date:
Line 189: Line 183:


MSTP GROUP DEVELOP A WELD INSPECTION PROGRAM.
MSTP GROUP DEVELOP A WELD INSPECTION PROGRAM.
Entergy Response: PROBLEM REPORT PROBLEM REPORT No. PR96.0396.05  
Entergy Response: PROBLEM REPORT PROBLEM REPORT No. PR96.0396.05
: 1. UProblem
: 1. UProblem


Line 195: Line 189:


CORRECTIVE ACTION CR-PNP-1996-00396 High nitrate levels exist in the TBCCW system.
CORRECTIVE ACTION CR-PNP-1996-00396 High nitrate levels exist in the TBCCW system.
High nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping.  
High nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping.
: 2. O Apparent/ Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates. 3.ORepeat Occurrence: - -YES -X NO 4.OMaintenance Rule Functional Failure: - YES X- NO Unknown 5. OCorrective Actions Completed (include Dates if possible)
: 2. O Apparent/ Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates. 3.ORepeat Occurrence: - -YES -X NO 4.OMaintenance Rule Functional Failure: - YES X- NO Unknown 5. OCorrective Actions Completed (include Dates if possible)
A past action item (PR.0396.02) was given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria. Mechanical/ Civil/ Structural selection of 5 to 10 inspection points based on the Altran Letter with proposed criteria.  
A past action item (PR.0396.02) was given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria. Mechanical/ Civil/ Structural selection of 5 to 10 inspection points based on the Altran Letter with proposed criteria.
: 6. @Corrective Actions Required 0 0 0 (check "NtR" if not required) - - NtR a) Action Required Visual inspection program developed for selected points. See Attached.
: 6. @Corrective Actions Required 0 0 0 (check "NtR" if not required) - - NtR a) Action Required Visual inspection program developed for selected points. See Attached.
Closure Requirement Visual inspection program implemented.
Closure Requirement Visual inspection program implemented.
Line 204: Line 198:
06 / 30t 97 0 0 ODead Date:
06 / 30t 97 0 0 ODead Date:
08 t 3 1 / 97 7. CCorrective Actions Required to Preclude Recurrence (check "N/R" if not required) 4 N/R 08.ClTrend Data for Apparent CauseOU (check "NW for Direct Cause Analysis) -X-N/R 9. OThe Significance should: Be Upgraded 4 Remain the Same If applicable, the reason for the upgraded:NtA Completed By: R. PACE Date: 4 t 8 1 00 EvaluatortMentor Approved By: T. WHITE Date: 4 I 8 t 0 Manager PROBLEM STATEMENT As discussed in PR 96.0396.02 [3]
08 t 3 1 / 97 7. CCorrective Actions Required to Preclude Recurrence (check "N/R" if not required) 4 N/R 08.ClTrend Data for Apparent CauseOU (check "NW for Direct Cause Analysis) -X-N/R 9. OThe Significance should: Be Upgraded 4 Remain the Same If applicable, the reason for the upgraded:NtA Completed By: R. PACE Date: 4 t 8 1 00 EvaluatortMentor Approved By: T. WHITE Date: 4 I 8 t 0 Manager PROBLEM STATEMENT As discussed in PR 96.0396.02 [3]
it has been determined that elevated nitrate concentrations can result in intergranular stress corrosion cracking (IGSCC) of carbon steel (CS) piping. Because Pilgrim Nuclear Power Station (PNPS) has had a short duration of marginally unacceptable nitrate concentrations, PR 96.0396.05 requests that NESG, Mechanical/ Civil/ Structural select 5 to 10 inspection locations on the affected Turbine Building Closed Cooling Water (TBCCW) system  
it has been determined that elevated nitrate concentrations can result in intergranular stress corrosion cracking (IGSCC) of carbon steel (CS) piping. Because Pilgrim Nuclear Power Station (PNPS) has had a short duration of marginally unacceptable nitrate concentrations, PR 96.0396.05 requests that NESG, Mechanical/ Civil/ Structural select 5 to 10 inspection locations on the affected Turbine Building Closed Cooling Water (TBCCW) system
[4].  
[4].  


Line 214: Line 208:
Structural).
Structural).
All locations should be visually inspected at a minimum of two inspection intervals over the program duration. If problems are discovered during later inspections the scope would be expanded by the addition of several new locations for inspection and the use of volumetric inspection techniques.
All locations should be visually inspected at a minimum of two inspection intervals over the program duration. If problems are discovered during later inspections the scope would be expanded by the addition of several new locations for inspection and the use of volumetric inspection techniques.
In this case, criteria for scope expansion will be developed based on the inspection results and water chemistry history. Therefore nitrate concentration history is an important input to the program. Chemistry was given an action item  
In this case, criteria for scope expansion will be developed based on the inspection results and water chemistry history. Therefore nitrate concentration history is an important input to the program. Chemistry was given an action item
[3] to develop a program and document this information to NESG. If no IGSCC is found over the recommended program duration and low nitrate levels (400 PPM) are maintained the inspection program can be discontinued. A closed cooling water/ plant heating corrosion monitoring system will be installed in the near future. If a corrosion sample for the TBCCW system containing a carbon steel weld (Pl) can be incorporated into the program the piping inspections may be eliminated. The monitoring of the corrosion sample is a more accurate predictor of the system condition.
[3] to develop a program and document this information to NESG. If no IGSCC is found over the recommended program duration and low nitrate levels (400 PPM) are maintained the inspection program can be discontinued. A closed cooling water/ plant heating corrosion monitoring system will be installed in the near future. If a corrosion sample for the TBCCW system containing a carbon steel weld (Pl) can be incorporated into the program the piping inspections may be eliminated. The monitoring of the corrosion sample is a more accurate predictor of the system condition.
ASSUMPTIONS As stated in the Altran Corporation letter attached to the problem report, IGSCC is not co Subresponse  
ASSUMPTIONS As stated in the Altran Corporation letter attached to the problem report, IGSCC is not co Subresponse
: Closure Comments: MSTP GROUP DEVELOP A WLD INSPECTION PROGRAM OF SUFFICIENT DURATION FOR TBCCW PIPING WELDS. PROVIDE MEMO DOCUMENTING DETAILS OF TASK COMPLETION.
: Closure Comments: MSTP GROUP DEVELOP A WLD INSPECTION PROGRAM OF SUFFICIENT DURATION FOR TBCCW PIPING WELDS. PROVIDE MEMO DOCUMENTING DETAILS OF TASK COMPLETION.
CLOSURE: MSTP NODE SO01262 CREATED TO TRACK WELD SELECTION AND EXAMINATION.
CLOSURE: MSTP NODE SO01262 CREATED TO TRACK WELD SELECTION AND EXAMINATION.
Line 229: Line 223:
MECHANICAL SEAL INSPECTION POINTS.
MECHANICAL SEAL INSPECTION POINTS.
Response:
Response:
Subresponse  
Subresponse
: CONVERTED DATA CORRECTIVE ACTION I CR-PNP-1996-00396 Closure Comments:
: CONVERTED DATA CORRECTIVE ACTION I CR-PNP-1996-00396 Closure Comments:
MECHANICAL/CIVIL/STRUCTURAL SELECTION OF 5 TO 10 INSPECTION POINTS BASED ON THE ATTACHED LETTER WITH PROPOSED ALTRAN CRITERIA PROBLEM REPORT PROBLEM REPORT No. PR96.0396.05  
MECHANICAL/CIVIL/STRUCTURAL SELECTION OF 5 TO 10 INSPECTION POINTS BASED ON THE ATTACHED LETTER WITH PROPOSED ALTRAN CRITERIA PROBLEM REPORT PROBLEM REPORT No. PR96.0396.05
: 1. @Problem
: 1. @Problem


Line 243: Line 237:
See Attached. Responsible Manager C. Garrow Due Date: 06 I 30/ 97 0 0 ODead Date: 08 / 3 1 / 97 7.OCorrective Actions Required to Preclude Recurrence (check "N/R" if not required) 4 N/R 0 8. OTrend Data for Apparent Cause0 0 (check "N/R" for Direct Cause Analysis)
See Attached. Responsible Manager C. Garrow Due Date: 06 I 30/ 97 0 0 ODead Date: 08 / 3 1 / 97 7.OCorrective Actions Required to Preclude Recurrence (check "N/R" if not required) 4 N/R 0 8. OTrend Data for Apparent Cause0 0 (check "N/R" for Direct Cause Analysis)
X N/R 9. OThe Significance should:
X N/R 9. OThe Significance should:
Be Upgraded 4 Remain the Same If applicable, the reason for the upgraded:N/A Completed By: R. PACE Date: 4 I 8 1 on EvaluatorIMentor Approved By: T. WHITE Date: 4 I 8 1 0 0 Manager PROBLEM STATEMENT As discussed in PR 96.0396.02  
Be Upgraded 4 Remain the Same If applicable, the reason for the upgraded:N/A Completed By: R. PACE Date: 4 I 8 1 on EvaluatorIMentor Approved By: T. WHITE Date: 4 I 8 1 0 0 Manager PROBLEM STATEMENT As discussed in PR 96.0396.02
[3] it has been determined that elevated nitrate concentrations can result in intergranular stress corrosion cracking (IGSCC) of carbon steel (CS) piping. Because Pilgrim Nuclear Power Station (PNPS) has had a short duration of marginally unacceptable ritrate concentrations, PR 96.0396.05 requests that NESG, Mechanical/
[3] it has been determined that elevated nitrate concentrations can result in intergranular stress corrosion cracking (IGSCC) of carbon steel (CS) piping. Because Pilgrim Nuclear Power Station (PNPS) has had a short duration of marginally unacceptable ritrate concentrations, PR 96.0396.05 requests that NESG, Mechanical/
CiviY Structural select 5 to 10 inspection locations on the affected Turbine Building Closed Cooling Water (TBCCW) system  
CiviY Structural select 5 to 10 inspection locations on the affected Turbine Building Closed Cooling Water (TBCCW) system
[4].
[4].
CORRECTIVE ACTION I Entergy I CR-PNP- 1996-00396 If problems are discovered during later inspections the scope would be expanded by the addition of several new locations for inspection and the use of volumetric inspection techniques.
CORRECTIVE ACTION I Entergy I CR-PNP- 1996-00396 If problems are discovered during later inspections the scope would be expanded by the addition of several new locations for inspection and the use of volumetric inspection techniques.
Line 256: Line 250:


VISUAL INSPECTION PROGRAM DEVELOPED FOR SELECTED POINTS. Response:
VISUAL INSPECTION PROGRAM DEVELOPED FOR SELECTED POINTS. Response:
Subresponse  
Subresponse
: CONVERTED DATA CORRECTIVE ACTION I CR-PNP-1996-00396 CA Number: 7 - l_l-_ - .-. _lll_ .___-___I._  
: CONVERTED DATA CORRECTIVE ACTION I CR-PNP-1996-00396 CA Number: 7 - l_l-_ - .-. _lll_ .___-___I._  
-- -I 1~-1 -I-l-x-_.-l  
-- -I 1~-1 -I-l-x-_.-l  

Revision as of 03:29, 13 July 2019

CR-PNP-1996-00396, High Mitrate Levels Exists in the Tbccw System
ML070780367
Person / Time
Site: Pilgrim
Issue date: 09/24/1996
From:
Entergy Corp
To:
Office of Nuclear Reactor Regulation, NRC/OGC, NRC Region 1
References
CR-PNP-1996-00396
Download: ML070780367 (22)
v • d • e


Text

EnteLqgy CONDITION REPORT CR-PNP-1996-00396 Originator:

CONVERTED DATA Originator Group: CONVERTED DATA Supervisor Name: CONVERTED DATA Discovered Date:

09/24/1996 0O:OO Originator Phone: 0 Operability Required:

N Reportability Required:

N Initiated Date:

09/24/1996 0O:OO Condition

Description:

HIGH MITRATE LEVELS EXIST IN THE TBCCW SYSTEM. HIGH NITRATE CONCENTRATIONS HAVE BEEN ASSOCIATED WITH STRESS CORROSION CRACKING OF CARBON STEEL PIPING. Immediate Action

Description:

Suggested Action

Description:

EQUIPMENT: Tag Name REFERENCE ITEMS: Type Code CONVERTED PR Tag Suffix Name Component Code Process Svstem Code 30B DescriDtion PR.96.0396 Enfefgy ADMIN Initiated Date:

9/24/1996 0:OO Current Contact:

MCDONALD, G. Current Significance:

D - ADMIN CLOSE Owner Group :CA&A Staff Closed by: MCDONALD, G.

10/1/1996 0:OO CR-PNP-1996-00396 Summary

Description:

HIGH MITRATE LEVELS EXIST IN THE TBCCW SYSTEM. HIGH NITRATE CONCENTRATIONS HAVE BEEN ASSOCIATED WITH STRESS CORROSION CRACKING OF CARBON STEEL PIPING.

Remarks

Description:

HIGH NITRATE TBCCW CHEMISTRY TRENDING DECREASING NITRITE INCREASING CONDUCTIVITY RBCCW STRESS CORROSION CRACKING BACTERIA CORROSION INHIBITOR SODIUM NITRITE EXCESS OXYGEN CARBON STEEL PIPING Closure

Description:

PAC REVIEW AFTER EVALUATION EVALUATION AND CORRECTIVE ACTION COMPLETE Entergy Version: 1 Significance Code: D - ADMIN CLOSE Classification Code: NON-SIGNIFICANT Owner Group: CA&A Staff Performed By: Shatas,Albert A Assignment

==

Description:==

SCREEN IAW NOP92A1 ASSIGNMENTS CR-PNP-1996-00396 09/24/1996 0O:OO I CORRECTIVE ACTION 1 CR-PNP-1996-00396 CA Number: 1 - - I r- - - Name f . .. . Grout, Assigned By: CA&A Staff SHATAS, A. Assigned To: CA&A Staff Subassigned To : Shatas,Albert A Originated By: SHATAS, A. Performed By: SHATAS, A. Subperformed By: Approved By: Closed By:

SHATAS, A. 9/24/1996 0O:OO:OO 9/24/1996 0O:OO:OO 9/24/1996 0O:OO:OO Current Due Date:

10/01/1996 CAType: GENERAL Plant Constraint:

NONE CA

Description:

SCREEN IAW NOP92A1 Response:

Subresponse

CONVERTED DATA Initial Due Date:

10/01/1996 Closure Comments: PAC APPROVED NOP92A1 EXHIBIT 3

~~ I I CA Number: 2 -I -- - I 1" - Name - _--I Group Assigned By: Tech Chemistry Staff Assigned To: Tech Chemistry Staff LOOMIS, L. Loomis,Larry Subassigned To

Originated By: LOOMIS, L. Performed By: LOOMIS, L. Subperformed By: Approved By: Closed By: LOOMIS, L. 9/24/1996 0O:OO:OO 7/ 14/1997 0O:OO:OO 7/14/1997 0O:OO:OO Current Due Date:

08/30/1997 Initial Due Date: 08/30/1997 CA Type: GENERAL Plant Constraint:

NONE CA

Description:

CONDUCT AN EVALUATION TO DETERMINE THE CAUSE OF THE HIGH NITRATE LEVELS IN THE TBCCW SYSTEM. DETERMINE CORRECTIVE ACTIONS AND ACTIONS TO PRECLUDE RECURRENCE.

Response: COMPLETE EVALUATION PER NOP92A1, SECTION 6.4. PROBLEM DESCRIPTION: HIGH NITRATE LEVELS EXIST IN THE TBCCW SYSTEM WHICH HAVE BEEN ASSOCIATED WITH SCC IN CARBON STEEL PIPING. DIRECT CAUSE: ONE LIKELY CAUSE COULD HAVE BEEN A SYSTEM LEAK WHICH INTRODUCES AIR WHICH CONVERTS NITRITE (THE CHEMICAL ADDITIVE)

TO NITRATEL.

HOWEVER, THE TBCCW SYSTEM IS KNOWN TO BE A TIGHT SYSTEM WITH LITTLE LEAKAGE. ANOTHER POSSIBLE CAUSE SEEN IN THE INDUSTRY IS THE CONVERSION OF NITRITE TO NITRATE DUE BACTERIA. THIS IS LIKELY CONSIDERING SYSTEM CONDITIONS SUCH AS TEMPERATURE AND FLOW. REPEAT OCCURRENCE:

NO MAINTENANCE RULE: UNKNOWN Subresponse

Closure Comments: COMPLETE EVALUATION PER NOP92A1, SECTION 6.4. PROBLEM DESCRIPTION:

HIGH NITRATE LEVELS EXIST IN THE TBCCW SYSTEM WHICH HAVE BEEN ASSOCIATED WITH SCC IN CARBON STEEL PIPING. DIRECT CAUSE: ONE LIKELY CAUSE COULD HAVE BEEN A SYSTEM LEAK WHICH INTRODUCES AIR WHICH CONVERTS NITRITE (THE CHEMICAL ADDITIVE)

TO NITRATEL.

HOWEVER, THE TBCCW SYSTEM IS KNOWN TO BE A TIGHT SYSTEM WITH LITTLE LEAKAGE. ANOTHER POSSIBLE CAUSE SEEN IN THE INDUSTRY IS THE CONVERSION OF NITRITE TO NITRATE DUE BACTERIA. THIS IS LIKELY CONSIDERING SYSTEM CONDITIONS SUCH AS TEMPERATURE AND FLOW. REPEAT OCCURRENCE:

NO MAINTENANCE RULE: UNKNOWN Entm I CA DUE DATE EXTENSION I CR-PNP-1996-00396 Corrective Action :-CR-PNP-1996-00396 CA-00002 Version: 3 Requested Duedate:

08/30/1997 Requested By: CONVERTED DATA Approved By: CONVERTED DATA Request

Description:

CONVERTED DATA Approved

Description:

CONVERTED DATA Approved: Previous Duedate:

08/29/1997 08/23/1997 08/23/1991 Enfq __ - Name 1-- CA Number: 3 _. I - -_ Group 11 Assigned By: Eng DE Mech Civil Struct Staff WHITE, T.F. CORRECTIVE ACTION CR-PNP-1996-00396 Assigned To: Eng DE Mech Civil Struct Staff Pace,Raymond M Subassigned To : Originated By: WHITE, T.F. Performed By: PACE, R. 9/24/1996 0O:OO:OO 2/4/1997 0O:OO:OO jubperformed By: Approved By:

Closed By: WHITE, T.F. 2/4/1997 0O:OO:OO Current Due Date:

01/15/1997 CA Type: GENERAL Initial Due Date: 01/15/1997 Plant Constraint:

NONE CA

Description:

DETERMINE THE EFFECTS OF THE ELEVATED NITRATE LEVELS ON THE CARBON STEEL PIPJNG OF THE TBCCW SYSTEM.

Response:

MEMO DETAILING THE RESULTS THE EVALUATION AND THE REQUIRED CORRECTIVE ACTIONS. CONCURRENCE MUST BE OBTAINED FROM ACTION ITEM OWNERS. NOTE: CHEMISTRY HAS ALSO BEEN ASSIGNED AN ACTION TO DETERMINE THE CAUSE OF THE EXCESS NITRATE AND SHOULD BE ABLE TO PROVIDE ADDITIONAL INFORMATION TO ASSIST IN YOUR EVALUATION.

PROBLEM REPORT PROBLEM REPORT No.

96.0396.02

1. Problem

Description:

High Nitrate levels exist in the TBCCW System. High Nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping. 2. Apparent/Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates.

An action item should be given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.

3. Repeat Occurrence: u YES NO 4. Maintenance Rule Functional Failure: - YES -u- NO - Unknown 5. Corrective Actions Completed (include Dates if possible) A literature search (See Attached Letter for details and date completed) was performed to determine the most probable cause of the Nitrate build-up and its affect on carbon steel piping. Based on this research for the Nitrate concentration, system operating conditions and the duration of the present problem, the probability of developing stress corrosion cracking is low. However due to the lack of conclusive data at the appropriate operating conditions there is sufficient probability of stress corrosion cracking that an action item should be given to the MSTP Group to develop a program of sufficient duration to inspect TBCCW piping welds. Civ/ Struct./

Mech will assist the MSTP Group in the selection of inspection locations, as necessary.

6. Corrective Actions Required 13 U (check "NR" if not required) - NIR a) Action Required chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria. OClosure Requirement If Nitrobacter bacteria are found a biocide should be introduced as a part of a chemical treatment program to eliminate the bacteria and reduce the Nitrate concentration. Responsible Manager Dave Fountain Due Date 04/01/97 E 0 ODead Date 05/30/97 b) Action Required MSTP Group develop a weld inspection program. EClosure Requirement MSTP Group develop a weld inspection program of sufficient duration for TBCCW piping welds. Responsible Manager Kevin Burke

~ ~ CORRECTIVE ACTION Entwgy 7. Corrective Actions Required to Preclude Recurrence (check "NR" if not required)

__ N/R CR-PNP- 1996-00396 a) Action Required Mechanical select inspection points. Closure Requirement Mechanical/Civil/Structural selection of 5 to 10 inspection points based on the attached letter with proposed Altran criteria. Responsible Manager Thomas White, Jr. Due Date 04/01/97 ODead Date 05/31/97 b) Action Required Closure Requirement Responsible Manager Due Date / / 0 0 ODead Date -/-/- 8. Trend Data for Apparent Cause@ 0 (check "N/R" for Direct Cause Analysis) u N/R NOTE If more than 2 Inappropriate Actions are defined, use Exhibit

14. a) Inappropriate Action (IA)

Description:

IA Job Title IA Group IA Department IA Job Title IA Group IA Department BECO OContractor Work Process Key Activity Work Process Key Activity O&P Failure Mechanism Human Error Type (Circle 1): Skill BasedU HEIA Failure Mechanism Subresponse

EntHgy Closure Comments: MEMO DETAILING THE RESULTS THE EVALUATION AND THE REQUIRED CORRECTIVE ACTIONS. CONCURRENCE MUST BE OBTAINED FROM ACTION ITEM OWNERS. CORRECTIVE ACTION CR-PNP-1996-00396 NOTE: CHEMISTRY HAS ALSO BEEN ASSIGNED AN ACTION TO DETERMINE THE CAUSE OF THE EXCESS NITRATE AND SHOULD BE ABLE TO PROVIDE ADDITIONAL INFORMATION TO ASSIST IN YOUR EVALUATION.

PROBLEM REPORT PROBLEM REPORT No. 96.0396.02

1. Problem

Description:

High Nitrate levels exist in the TBCCW System. High Nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping.

2. Apparent/Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates.

An action item should be given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.

3. Repeat Occurrence: u YES NO 4. Maintenance Rule Functional Failure: - YES -u- NO - Unknown 5. Corrective Actions Completed (include Dates if possible) A literature search (See Attached Letter for details and date completed) was performed to determine the most probable cause of the Nitrate build-up and its affect on carbon steel piping. Based on this research for the Nitrate concentration, system operating conditions and the duration of the present problem, the probability of developing stress corrosion cracking is low. However due to the lack of conclusive data at the appropriate operating conditions there is sufficient probability of stress corrosion cracking that an action item should be given to the MSTP Group to develop a program of sufficient duration to inspect TBCCW piping welds. Civ/ Struct./ Mech will assist the MSTP Group in the selection of inspection locations, as necessary.
6. Corrective Actions Required 0 0 (check "NIR" if not required) - NIR a) Action Required Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.

CClosure Requirement If Nitrobacter bacteria are found a biocide should be introduced as a part of a chemical treatment program to eliminate the bacteria and reduce the Nitrate concentration. Responsible Manager Dave Fountain Due Date 04/01/970 0 ODead Date 05/30/97 b) Action Required MSTP Group develop a weld inspection program. OClosure Requirement MSTP Group develop a weld inspection program of sufficient duration for TBCCW piping welds. Responsible Manager Kevin Burke Ent43g-y 7. Corrective Actions Required to Preclude Recurrence a) Action Required Mechanical select inspection points. (check "NR" if not required)

__ N/R CORRECTIVE ACTION CR-PNP-1996-00396 Closure Requirement Mechanical/CiviYStructural selection of 5 to 10 inspection points based on the attached letter with proposed Altran criteria. Responsible Manager Thomas White, Jr. Due Date 04/01/97 0 ODead Date 05/31/97 b) Action Required Closure Requirement Responsible Manager DueDate / / UDODeadDate / / 8. Trend Data for Apparent Cause0 0 (check "NR" for Direct Cause Analysis) u N/R NOTE If more than 2 Inappropriate Actions are defined, use Exhibit 14. a) Inappropriate Action (IA)

Description:

IA Job Title IA Group IA Department IA Job Title IA Group IA Department BECO UContractor Work Process Key Activity Work Process Key Activity O&P Failure Mechanism Human Error Type (Circle 1): Skill BasedU HEIA Failure Mechanism 4 I I CA DUE DATE EXTENSION EmfeGzY I CR-PNP- 1996-00396 Version: 1 Requested Duedate:

0 1/15/1997 Requested By: CONVERTED DATA Approved By: CONVERTED DATA Request

Description:

CONVERTED DATA Approved

Description:

CONVERTED DATA Approved: Previous Duedate:

01/14/1997 01/08/ 1997 01/08/1997 Entergy CA Number: 4 ____ --- - 1111 I I Name SMALLEY, P. Fountain,David W I Assigned By: Tech Chemistry Staff Assigned To: Training Technical Staff CORRECTIVE ACTION CR-PNP-1996-00396 Subassigned To : Originated By: SMALLEY, P. Performed By: FOUNTAIN, D. Subperformed By: Approved By: Closed By: SMALLEY, P. 2/6/1997 0O:OO:OO 4/3/1998 0O:OO:OO 4/3/1998 0O:OO:OO Current Due Date:

04/01/1998 Initial Due Date: 04/01/1998 CA Type: GENERAL Plant Constraint:

NONE CA

Description:

CHEMISTRY TO SAMPLE AND ANALYZE THE RBCCW AND TBCCW, INCUDING THE MAKE-UP WATER SOURCE, FOR THE PRESENCE OF NITROBACTER BACTERIA.

Response:

IF NITROBACTER BACTERIA ARE FOUND A BIOCIDE SHOULD BE INTRODUCED AS A PART OF A CHEMICAL TREATMENT PROGRAM TO ELIMINATE THE BACTERIA AND REDUCE THE NITRATE CONCENTRATION. PROVIDE MEMO DOCUMENTING DETAILS OF TASK COMPLETION. [4/2/98;FOUNTAIN, D.] TESTING WAS PERFORMED IN HOUSE DUE TO THE INABILITY TO LOCATE A QUALIFIED LABORATORY CAPABLE OF PERFORMING TESTING IN THIS AREA. (SAMPLES MUST BE AT THE VENDORS LABORATORY LESS THAN 24 HOURS AFTER SAMPLING.)

THE HACH COMPANY PROVIDES TEST KITS FOR PERFORMING NITROBACTERIA TESTING ON SITE. THESE TEST KITS WERE PURCHASED AND SAMPLES WERE ANALYZED IN HOUSE FOR THE RBCCW, TBCCW AND MAKEUP WATER SYSTEMS. NO DETECTABLE NITROBACTERIA WAS IDENTIFIED. MULTIPLE SAMPLES WERE ANALYZED ON THE TBCCW SYSTEM FROM VARIOUS LOCATIONS WHERE THE HIGHEST POTENTIAL FOR BACTERIA EXISTED. SAMPLES FROM THE SLIPSTREAM FTLTER WERE INCUBATED TO INCREASE THE NUMBER OF COLONIES PRESENT IF ANY NITROBACTERIA EXISTED. THESE SAMPLES ALSO SHOWED NO SIGNS OF DETECTABLE NITROBACTERIA WHEN TESTED WITH THE HACH TEST KITS. ADDITIONALLY, SAMPLES WERE TAKEN FOR TOTAL BACTERIA ON THESE SYSTEMS AND ZERO COLONIES WERE DETECTED. MONTHLY SAMPLING FOR TOTAL BACTERIA IS NOW ROUTINELY PERFORMED ON ALL CLOSED COOLING WATER SYSTEMS. SAMPLING FOR NITRATE LEVELS IN THE TBCCW SYSTEM (AND RBCCW) ARE ALSO PERFORMED MONTHLY. NO SIGNIFICANT TRENDS IN NITRATE HAVE BEEN IDENTIFIED.

THE RATIO OF THE

'SYSTEM CONDUCTIVITY' TO 'NITRITE IS ALSO CALCULATED DURING WEEKLY ANALYSIS.

THIS IS ANOTHER METHOD TO DETERMINE IF ANY ADVERSE TRENDS ARE OCCURING WITHIN A CLOSED COOLING SYSTEM. AGAIN NO SIGNIFICANT TRENDS HAVE BEEN IDENTIFIED.

DUE TO THE LACK OF TOTAL BACTERIA AND NITROBACTERIA AS DETERMINED BY GRAB SAMPLING THIS ITEM IS CLOSED. NO ADDITIONAL ACTIONS ARE REQUIRED UNLESS FUTURE ROUTINE TESTING WERE TO REVEAL ADVERSE TRENDS. A NEW PROBLEM REPORT WOULD BE GENERATED AT THAT TIME.

Entergy CORRECTIVE ACTION Closure Comments:

IF NITROBACTER BACTERIA ARE FOUND A BIOCIDE SHOULD BE INTRODUCED AS A PART OF A CHEMICAL TREATMENT PROGRAM TO ELIMINATE THE BACTERIA AND REDUCE THE NITRATE CONCENTRATION.

PROVIDE MEMO DOCUMENTING DETAILS OF TASK COMPLETION.

CR-PNP-1996-00396

[4/2/98;FOUNTAIN, D.] TESTING WAS PERFORMED IN HOUSE DUE TO THE INABILITY TO LOCATE A QUALIFIED LABORATORY CAPABLE OF PERFORMING TESTING JN THIS AREA. (SAMPLES MUST BE AT THE VENDORS LABORATORY LESS THAN 24 HOURS AFTER SAMPLING.)

THE HACH COMPANY PROVIDES TEST KITS FOR PERFORMING NITROBACTERIA TESTING ON SITE. THESE TEST KITS WERE PURCHASED AND SAMPLES WERE ANALYZED IN HOUSE FOR THE RBCCW, TBCCW AND MAKEUP WATER SYSTEMS. NO DETECTABLE NITROBACTERIA WAS IDENTIFIED. MULTIPLE SAMPLES WERE ANALYZED ON THE TBCCW SYSTEM FROM VARIOUS LOCATIONS WHERE THE HIGHEST POTENTIAL FOR BACTERIA EXISTED. SAMPLES FROM THE SLIPSTREAM FILTER WERE INCUBATED TO INCREASE THE NUMBER OF COLONIES PRESENT IF ANY NITROBACTERIA EXISTED. THESE SAMPLES ALSO SHOWED NO SIGNS OF DETECTABLE NITROBACTERIA WHEN TESTED WITH THE HACH TEST KITS.

ADDITIONALLY, SAMPLES WERE TAKEN FOR TOTAL BACTERIA ON THESE SYSTEMS AND ZERO COLONIES WERE DETECTED.

MONTHLY SAMPLING FOR TOTAL BACTERIA IS NOW ROUTINELY PERFORMED ON ALL CLOSED COOLING WATER SYSTEMS. SAMPLING FOR NITRATE LEVELS IN THE TBCCW SYSTEM (AND RBCCW) ARE ALSO PERFORMED MONTHLY. NO SIGNIFICANT TRENDS IN NITRATE HAVE BEEN IDENTIFIED. THE RATIO OF THE 'SYSTEM CONDUCTIVITY' TO 'NITRITE' IS ALSO CALCULATED DURING WEEKLY ANALYSIS.

THIS IS ANOTHER METHOD TO DETERMINE IF ANY ADVERSE TRENDS ARE OCCURING WITHIN A CLOSED COOLING SYSTEM. AGAIN NO SIGNIFICANT TRENDS HAVE BEEN IDENTIFIED.

DUE TO THE LACK OF TOTAL BACTERIA AND NITROBACTERIA AS DETERMINED BY GRAB SAMPLING THIS ITEM IS CLOSED.

NO ADDITIONAL ACTIONS ARE REQUIRED UNLESS FUTURE ROUTINE TESTING WERE TO REVEAL ADVERSE TRENDS. A NEW PROBLEM REPORT WOULD BE GENERATED AT THAT TIME.

Entei?gy I CA DUE DATE EXTENSION Version: 3 Requested Duedate: 04/01/1998 CR-PNP-1996-00396 Requested By: CONVERTED DATA Approved By: CONVERTED DATA Request

Description:

CONVERTED DATA Approved

Description:

CONVERTED DATA Approved:

Previous Duedate: 0313 111998 03/25/1998 03/25/1998 Ent43g-y CA Number: 5 CORRECTIVE ACTION CR-PI"-1996-00396 I __-I__ _I_-____ --- ----- - ---1-1 1--1-11111~1 I i Group Name Assigned By: CA&A Staff Assigned To: Operations Support Staff WOLLMAN, S. Burke,Kevin R Subassigned To

Originated By: WOLLMAN, S. Performed By: BURKE, K. Subperformed By: Approved By: Closed By:

WOLLMAN, S. 2/6/1997 0O:OO:OO 5/22/1997 0O:OO:OO 5/22/ 1 997 00: 00: 00 Current Due Date: 05/30/1997 Initial Due Date:

05/30/1997 CA Type: GENERAL Plant Constraint:

NONE CA

Description:

MSTP GROUP DEVELOP A WELD INSPECTION PROGRAM.

Entergy Response: PROBLEM REPORT PROBLEM REPORT No. PR96.0396.05

1. UProblem

Description:

CORRECTIVE ACTION CR-PNP-1996-00396 High nitrate levels exist in the TBCCW system.

High nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping.

2. O Apparent/ Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates. 3.ORepeat Occurrence: - -YES -X NO 4.OMaintenance Rule Functional Failure: - YES X- NO Unknown 5. OCorrective Actions Completed (include Dates if possible)

A past action item (PR.0396.02) was given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria. Mechanical/ Civil/ Structural selection of 5 to 10 inspection points based on the Altran Letter with proposed criteria.

6. @Corrective Actions Required 0 0 0 (check "NtR" if not required) - - NtR a) Action Required Visual inspection program developed for selected points. See Attached.

Closure Requirement Visual inspection program implemented.

See Attached.

Responsible Manager C. Garrow Due Date:

06 / 30t 97 0 0 ODead Date:

08 t 3 1 / 97 7. CCorrective Actions Required to Preclude Recurrence (check "N/R" if not required) 4 N/R 08.ClTrend Data for Apparent CauseOU (check "NW for Direct Cause Analysis) -X-N/R 9. OThe Significance should: Be Upgraded 4 Remain the Same If applicable, the reason for the upgraded:NtA Completed By: R. PACE Date: 4 t 8 1 00 EvaluatortMentor Approved By: T. WHITE Date: 4 I 8 t 0 Manager PROBLEM STATEMENT As discussed in PR 96.0396.02 [3]

it has been determined that elevated nitrate concentrations can result in intergranular stress corrosion cracking (IGSCC) of carbon steel (CS) piping. Because Pilgrim Nuclear Power Station (PNPS) has had a short duration of marginally unacceptable nitrate concentrations, PR 96.0396.05 requests that NESG, Mechanical/ Civil/ Structural select 5 to 10 inspection locations on the affected Turbine Building Closed Cooling Water (TBCCW) system

[4].

SUMMARY

Eleven inspection locations have been selected for the inservice inspection (ISI) of the TBCCW piping for IGSCC. It is recommended that an inspection program be implemented that is 10 years in duration with 2 year inspection intervals.

The n Entqgy CORRECTIVE

-2??5~i ON CR-PNP- 1 996-00396 Iocations should be selected

  • or each inspection interval and results reported to NESG (Mechanical/ Civil/

Structural).

All locations should be visually inspected at a minimum of two inspection intervals over the program duration. If problems are discovered during later inspections the scope would be expanded by the addition of several new locations for inspection and the use of volumetric inspection techniques.

In this case, criteria for scope expansion will be developed based on the inspection results and water chemistry history. Therefore nitrate concentration history is an important input to the program. Chemistry was given an action item

[3] to develop a program and document this information to NESG. If no IGSCC is found over the recommended program duration and low nitrate levels (400 PPM) are maintained the inspection program can be discontinued. A closed cooling water/ plant heating corrosion monitoring system will be installed in the near future. If a corrosion sample for the TBCCW system containing a carbon steel weld (Pl) can be incorporated into the program the piping inspections may be eliminated. The monitoring of the corrosion sample is a more accurate predictor of the system condition.

ASSUMPTIONS As stated in the Altran Corporation letter attached to the problem report, IGSCC is not co Subresponse

Closure Comments: MSTP GROUP DEVELOP A WLD INSPECTION PROGRAM OF SUFFICIENT DURATION FOR TBCCW PIPING WELDS. PROVIDE MEMO DOCUMENTING DETAILS OF TASK COMPLETION.

CLOSURE: MSTP NODE SO01262 CREATED TO TRACK WELD SELECTION AND EXAMINATION.

Entegy CA Number: 6 - __ I_ _I- - - - - __ __ I Name Group t r- "__ . Assigned By: Eng DE Mech Civil Struct Staff Assigned To: Eng DE Mech Civil Struct Staff WHITE, T.F. Pace,Raymond M CORRECTIVE ACTION CR-PNP-1996-00396 Subassigned To : Originated By:

WHITE, T.F. 2/6/1997 0O:OO:OO Performed By: PACE, R. 5/7/1997 0O:OO:OO subperformed By: Approved By:

Closed By: WHITE, T.F. 5/7/1997 0O:OO:OO Current Due Date:

05/31/1997 Initial Due Date: 05/31/1997 CA Type: GENERAL Plant Constraint:

NONE CA

Description:

MECHANICAL SEAL INSPECTION POINTS.

Response:

Subresponse

CONVERTED DATA CORRECTIVE ACTION I CR-PNP-1996-00396 Closure Comments:

MECHANICAL/CIVIL/STRUCTURAL SELECTION OF 5 TO 10 INSPECTION POINTS BASED ON THE ATTACHED LETTER WITH PROPOSED ALTRAN CRITERIA PROBLEM REPORT PROBLEM REPORT No. PR96.0396.05

1. @Problem

Description:

High nitrate levels exist in the TBCCW system. High nitrate concentrations have been associated with stress corrosion cracking of carbon steel piping. 2.0 Apparent/ Direct Cause: Based on a study of literature on this subject, the likely direct cause is Nitrobacter bacteria conversion of Nitrites to Nitrates.

3.0Repeat Occurrence: - -YES X NO 4.OMaintenance Rule Functional Failure: - YES -X- NO Unknown 5.OCorrective Actions Completed (include Dates if possible)

A past action item (PR.0396.02) was given Chemistry to sample and analyze the RBCCW and TBCCW, including the make-up water source, for the presence of Nitrobacter bacteria.

Mechanical1 Civil/ Structural selection of 5 to 10 inspection points based on the Altran Letter with proposed criteria. 6.CiCorrective Actions Required 0 0 0 (check "NR" if not required) - - N/R a) Action Required Visual inspection program developed for selected points.

See Attached. Closure Requirement Visual inspection program implemented.

See Attached. Responsible Manager C. Garrow Due Date: 06 I 30/ 97 0 0 ODead Date: 08 / 3 1 / 97 7.OCorrective Actions Required to Preclude Recurrence (check "N/R" if not required) 4 N/R 0 8. OTrend Data for Apparent Cause0 0 (check "N/R" for Direct Cause Analysis)

X N/R 9. OThe Significance should:

Be Upgraded 4 Remain the Same If applicable, the reason for the upgraded:N/A Completed By: R. PACE Date: 4 I 8 1 on EvaluatorIMentor Approved By: T. WHITE Date: 4 I 8 1 0 0 Manager PROBLEM STATEMENT As discussed in PR 96.0396.02

[3] it has been determined that elevated nitrate concentrations can result in intergranular stress corrosion cracking (IGSCC) of carbon steel (CS) piping. Because Pilgrim Nuclear Power Station (PNPS) has had a short duration of marginally unacceptable ritrate concentrations, PR 96.0396.05 requests that NESG, Mechanical/

CiviY Structural select 5 to 10 inspection locations on the affected Turbine Building Closed Cooling Water (TBCCW) system

[4].

CORRECTIVE ACTION I Entergy I CR-PNP- 1996-00396 If problems are discovered during later inspections the scope would be expanded by the addition of several new locations for inspection and the use of volumetric inspection techniques.

In this case, criteria for scope expansion will be developed based on the inspection results and water chemistry history. Therefore nitrate concentration history is an important input to the program. Chemistry was given an action item [3] to develop a program and document this information to NESG. If no IGSCC is found over the recommended program duration and low nitrate levels (400 PPM) are maintained the inspection program can be discontinued. A closed cooling water/ plant heating corrosion monitoring system will be installed in the near future.

If a corrosion sample for the I I I ~ Current Due Date: 08/3 1/1997 CA Type: GENERAL Initial Due Date:

08/3 1/1997 Plant Constraint:

NONE CA

Description:

VISUAL INSPECTION PROGRAM DEVELOPED FOR SELECTED POINTS. Response:

Subresponse

CONVERTED DATA CORRECTIVE ACTION I CR-PNP-1996-00396 CA Number: 7 - l_l-_ - .-. _lll_ .___-___I._

-- -I 1~-1 -I-l-x-_.-l

~. Group I Name Assigned By: QA Staff SHERIDAN, R. Assigned To: QA Staff Garrow,Charles G Subassigned To : Originated By: SHERIDAN, R.

Performed By: GARROW, C. Subperformed By: Approved By:

Closed By: SHERIDAN, R. 5/14/1997 0O:OO:OO 5/19/1997 0O:OO:OO 5/19/1997 0O:OO:OO I Closure Comments:

VISUAL INSPECTION PROGRAM IMPLEMENTED.

CLOSURE: THE EXAMINATION REQUIREMENTS WILL BE TRACKED BY THE MSTP TRACKING PROGRAM (ATTACHED FORM)

WITH EXAMINATION PERFORMED TO EXISTING PROCEDURES. THE INSPECTIONS WILL BE IMPLEMENTED WITH AN MR AS WITH ALL OTHER IS1 EXAMINATIONS.

NODE #S001262.

Retrieved from "https://kanterella.com/w/index.php?title=ML070780367&oldid=1828858"