ML071730464

Final Status Survey (FSS) Final Report - Phase VII - Chapter 17 of 19 - Appendix A16, Survey Unit Release Record 9801-0000, Subsurface Soils in the Radiologically Controlled Area

ML071730464
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Site:	Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png
Issue date:	05/02/2007
From:	Massengill B Connecticut Yankee Atomic Power Co
To:	NRC/FSME
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Book 1 of 1 Final Status Survey Final Report Phase VII Appendix Al 6 Survey Unit Release Record 9801 -0000, Subsurface Soils in the Radiologically Controlled Area May 2007

CYAPCO FINAL STATUS SURVEY RELEASE RECORD SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 Prepared By:  ?."15ej/ Date: 5-/-2~

FSS Enginleer Reviewedd IW OIL Date: SJ-c7 Approved By: Date: ____-7 Technical Support Manager Revision 0

SUBSURFACE SOILS IN RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD TABLE OF CONTENTS

1. SURVEY UNIT DESCRIPTION ........................................... 3

2. CLASSIFICATION BASIS................................................. 4

3. DATA QUALITY OBJECTIVES (DQO) ................................ 15

4. SURVEY DESIGN.......................................................... 18

5. SURVEY IMPLEMENTATION .......................................... 23

6. SURVEY RESULTS........................................................ 24

7. QUALITY CONTROL ..................................................... 30

8. INVESTIGATIONS AND RESULTS .................................... 30

9. REMEDIATION AND RESULTS........................................ 30

10. CHANGES FROM THE FINAL STATUS SURVEY PLAN .......... 30

11. DATA QUALITY ASSESSMENT (DQA)............................... 31

12. ANOMALIES................................................................ 32

13. CONCLUSION.............................................................. 32

14. ATTACHMENTS ........................................................... 34 14.1 Attachment 1 - Figures (7 pages including cover) 14.2 Attachment 2 - Laboratory Data (209 pages including cover) 14.3 Attachment 3 - DQA Results (19 pages including covers)

TOTAL 269 Revision 0

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD SURVEY UNIT DESCRIPTION Based on the Connecticut State Plane System, North American Datum (NAD) 1927, this subsurface Survey Unit (980 1-0000) is located approximately one thousand two hundred and seventy-one (1,271) feet (ft) to the southeast of the site benchmark (Northing: 237370.20, Easting: 667394.51). The survey area has a total surface area of approximately fifteen thousand seven hundred and eighty-eight (15,788) square meters (in 2 ).

LTP Section 2.3.3.1.5 defines a subsurface Class A area as a subsurface soil area that has had known contaminating events and has a high potential to be at or exceed the DCGL. Consequently, following evaluation of historical events and an assessment of radiological surveys performed in support of characterization and remediation, subsurface Survey Area 9801, which contains subsurface Survey Unit 9801-0000, received a final classification as subsurface Class A.

Figure 1 - Conceptual layout of Survey Area 9801-0000.

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9802 The subsurface Survey Unit 9801-0000 corresponds to the surface Survey Units 9312-0001 through 9312-0010. Survey Units 9312-0009 & 9312-0010 include the rock wall on the east side of the former RCA. All of the aforementioned surface survey units are classified as Class 1.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801 -0000 RELEASE RECORD The reference coordinates associated with this survey unit are E008 through E016 by S065 through S072 (refer to "HNP License Termination Plan" (LTP) Section 5.4.4). The reference coordinates provide the maximum dimensions of a rectangle containing this survey unit. Some areas contained in this rectangle may not be part of this survey unit. The boundary of the survey unit was defined using a Global Positioning System (GPS) based on the Connecticut State Plane System North American Datum (NAD) 1927.

2. CLASSIFICATION BASIS The survey unit was classified in accordance with Procedure RPM 5.1-10, "Survey Unit Classifiation."

The "Classifcation Basis Summary" conducted for Survey Unit 980 1-0000 consisted of:

a) A review of the 10CFR5O.75 (g) (1) database, b) A review of the "Initial Characterization Report" and the "Historic Site Assessment Supplement,"

c) Historic and current survey records review.

The radiological characterization of subsurface soil was conducted in this area to support decommissioning activities that commenced in 2002 and continued through 2006. Sampling activities were concentrated in several areas but the main area was designated as the "Big Dig" or Excavation #1, which was a large excavation that was immediately adjacent to the Reactor Building and constituted the surface Survey Units 93 12-0005 & 93 12-0006. Samples were acquired from the floor and walls of the excavation as part of the process to determine the effectiveness of the remediation effort in the subsurface.

Although the samples were collected from the surface of the excavations, they are considered suitable for subsurface soil characterization purposes because when the excavation was backfilled, the excavation floor and sidewall samples were indicative of the "as left" soil activity levels present in the subsurface.

Additional samples were collected in a similar fashion from the following areas within Survey Unit 9801-0000; the Decay Tank Excavation, the Spent Fuel Building (SFB) footprint, the Fuel Transfer Tube (FTT) excavation, the Spent Fuel Building East, Excavation #f5, the Containment Southeast, the Spent Fuel Building, Excavation #3, the Containment West, Excavation #6 and the RCA East trench. All soil samples were analyzed by an approved off-site laboratory for the gamma emitting radionuclides. Selected samples were analyzed for Hard-To-Detect (HTD) radionuclides. Cs- 137 was the predominant radionuclide detected in the sample population. Co-60 was also detected in the sample population. Additionally, Sr-90 was positively identified (i.e. a result greater than two (2) standard deviations uncertainty) in twenty-two (22) of forty-four (44) samples analyzed within this survey unit.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD During plant operation, Survey Unit 9312-0001 was the location of significant, radiologically contaminated structures and systems, namely the reactor, the reactor systems and the Containment structure. All contaminated systems and components, including the reactor vessel, were removed, appropriately packaged and shipped to an approved off-site disposal facility. The interior walls and floors within the Containment structure were demolished and removed. The Containment liner was removed with the exception of the Incore Sump. The dose from residual radioactivity on the remaining steel and concrete in the sump was accounted for in the "Basement Fill Dose Model". The Incore Sump was then filled with concrete "flow-able fill" to the basement floor elevation. The remaining interior surfaces inside the Containment shell were then decontaminated. Following decontamination, the Containment basement was backfilled to grade. The above grade portion of the Containment structure was then demolished and removed. Fill was then placed over the survey unit, raising the grade of the area by approximately four (4) feet.

Prior to remediation, significant soil contamination was present in and around this survey unit. Cs-137 was detected in soil samples at concentrations greater than two hundred (200) times its Operational Derived Concentration Guideline Level (DCGL); Co-60 was positively detected at a concentration twice its Operational DCGL and Sr-90 was positively identified at a concentration of 42%

of its DCGL. Outside of the containment shell, soil remediation began beneath and around each ancillary structure as each structure was demolished and removed and/or until bedrock was exposed. As with the Containment basement shell, all excavations were backfilled with soil material. Due to the fact that the current subsurface soils located in Survey Unit 9801-0000 is composed of essentially fill, the results of surface soil samples taken post-remediation and prior to backfill on the sidewalls of the remediated excavations were used to provide data with regard to types and quantities of radioactive material for the design of this survey.

In Survey Unit 9312-0001, post-remediation soil samples were taken under several Survey and Sampling Work Plans, including SSWP-05-06-00l, SSWP-05-08-002, SSWP-05-09-007 and SSWP-06-09-002. Thirty-eight (38) surface soil samples were collected from the sidewalls of various excavations in and around Survey Unit 93 12-0001 prior to backfill. All samples were collected and analyzed by gamma spectroscopy by an approved off-site laboratory. Eleven (11) of the thirty-eight (38) total samples collected were analyzed for "Hard-to-Detect" (HTD) radionuclides.

A review of this sample data shows Cs-137, Co-60 and Sr-90 to be the primary radionuclides of concern. Cs-137 was the predominant radionuclide over Co-60 and Sr-90 by a factor of 7 to 1. In one (1) sample, Cs-137 and Co-60 was detected in a concentration equivalent to 115% of the Operational DCGL incorporating the "sum of fractions". Additional remediation was performed at Revision 05 5

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD this location prior to backfill. A summary of the sample results are provided in Table 1.

Tbe1-Sample Analysis Results from Post-Remediation Soil Sample Table 1 Population for Survey Unit 93 12-0001I Parameter (Csilg) (Co-60 (prilg Minimum Value: -5.90E-03 -2.22E-02 7.67 E-03 Maximum Value: 5.46E+00 2.16E-0lI 9.68E-02 Mean: 6.14E-0lI 4.17E-02 4.02E-02 Median: 3.20E-01 1.46E-02 2.74E-02 Standard Deviation: 9.85E-01 6.20E-02 3.1lIE-02 Sr-90 was positively identified (i.e., a result greater than two (2) standard deviations uncertainty) in six (6) of the eleven (11) soil samples analyzed for HTD radionuclides. The sample results were evaluated to assess the distribution of the detected radionuclides. The radionuclide distribution percentage for each sample in the population was calculated by dividing the concentration of each detected radionuclide by the total activity concentration in the sample, expressing the abundance of the specific nuclide in the sample compared against the total activity.

During plant operation, Survey Unit 9312-0002 was the location of significant, radiologically contaminated structures and systems, including the Spent Fuel Pool (SFP), the Spent Fuel Building (SFB), the "Bus 10" area and the northeastern quadrant of the 11I5kV Switchyard.

The Spent Fuel Building (SFB) was a concrete structure designed for the storage of new and spent fuel. It contained radiologically contaminated items and process equipment necessary for safe handling and storage of spent nuclear fuel. The Spent Fuel Pool (SFP) itself was located in the northern half of the SEB. The Bus 10 Pad was originally an outdoor staging area designed to function as a decontamination facility. The 115 kV Switchyard was situated outside the RCA just south of the Containment building. This area included two Station Service Transformers and the 115 kV Tie Breaker. Also, Bus 12 was located at the SW comner of the yard. In addition to these, there were several other transformers with associated power lines that extended beyond the switchyard area.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD Major demolition and remediation activities began in 2002. All radioactive systems and components located inside the SFB were removed and building structural surfaces were decontaminated to ensure contamination levels were acceptable for controlled demolition. Confirmatory radiological surveys were performed throughout the demolition process. The SFP liner was removed and the exposed concrete was decontaminated. The structural concrete of the SFP and the SFB was then demolished to grade. The dose from residual radioactivity on the remaining below grade concrete footings and foundations from the SFP and SFB was accounted for in the "Basement Fill Dose Model".

Outside of the structures, remediation was performed on the soils surrounding the SFP and SFB. The analysis of samples taken of the soils located along the northwest corner of the SFB between the SFB and Containment structure indicated the presence of Cs-137 and Co-60 at concentrations up to 988 pCi/g and 1.20 pCi/g respectively. The presence of Sr-90 was also positively identified. Contamination was also identified in the soils to the south of the SFP as a result of SFB sump and cask wash-down pad leakage. In this area, a significant volume of contaminated soil that exhibited direct exposure rates was removed prior to commencing soil sampling for isotopic analysis. Remediation support samples taken of the remaining soils in this area exhibited radionuclide concentrations of up to 992 pCi/g Cs-137 and 86.4 pCi/g Co-60. The presence of Sr-90, Eu-154 and Am-241 in the soil were also positively identified. The soils in both of these areas were remediated to bedrock and the excavations were backfilled with clean soil following the performance of radiological assessments.

Soil remediation also occurred at the "Bus 10" area. Previous investigations had identified elevated levels of Cs-137 and Co-60 in the soils in this area.

Remediation was successful in this area prior to excavating to the beginning of the saturated zone or bedrock. The area was backfilled following the performance of a radiological assessment.

In Survey Unit 9312-0002, post-remediation soil samples were taken under several Survey and Sampling Work Plans, including SSWP-05-08-002, SSWP-05-09-007 and SSWP-06-09-004. Thirty-nine (39) surface soil samples were collected from the sidewalls of various excavations in and around Survey Unit 9312-0002 to support remediation and soil excavation prior to backfill. All samples were collected and analyzed by gamma spectroscopy by an approved off-site laboratory. Eight (8) of the thirty-nine (39) total samples collected were analyzed for "Hard-to-Detect" (HTD) radionuclides.

A review of this sample data shows that Cs-137 and Co-60 are the primary radionuclides of concern. These radionuclides were detected in twenty-six (26) of the thirty-nine (39) soil samples. In addition, Am-241 and Eu-154 were positively identified (i.e., a result greater than two (2) standard deviations uncertainty) in two (2) of the samples in concentrations greater than 5% of their Revision 07 7

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD respective Operational DCGLs. A summary of the sample results are provided in Table 2.

Table 2 - Sample Analysis Results from Post-Remediation Soil Sample I Population in Survey Unit 9312-0002 PrmtrCs-137 Co-60 Am-241 Eu-154 Parameter ... (pCilg) 00/0g (Kci/g)

Minimum Value : -6.34E-03 -2.22E-02 2.17E+00 2.13E-01 Maximum Value: 5.46E+00 2.45E+00 5.06E+/-00 6.01E-01 Mean: 4.32E-01 1.70E-01 3.62E+00 4.07E-0 I Median: 1.1OE-01I 1.09E-02 3.62E+/-00 4.07E-01 Standard Deviation: 9.72E-01 4.65E-0I 2.05E+00 2.74E-01 Cs-137 was the predominant radionuclide over Co-60 and Sr-90 by a factor of approximately 3 to 1. In two (2) of the remediation support samples, Cs-137 and Co-60 was detected in concentrations greater than 100% of the Operational DCGL while incorporating the "sum of fractions". Additional remediation was performed at these sample locations prior to backfill. No HTD radionuclides were positively identified.

During plant operation, Survey Unit 9312-0003 was the location of significant reactor support structures and systems, including the southwestern corner of the Primary Auxillary Building (PAB), the Feed Water/Steam Penetration Building (FW/STM), the Shutdown Auxiliary Feed Pump House, the Demin Water Storage Tank (DWST), the Condensate Storage Tank (CST) and the northwestern quadrant of the 115kV Switchyard.

The PAB was a concrete structure designed to house systems containing radioactive materials. The building was designed to contain and control leakage occurring during routine operations as well as unusual conditions. With the exception of the service water, gas and air systems, the majority of the systems within the PAB were radiologically contaminated. The PAB also contained highly contaminated pipe trenches and pump pit areas. The lower level of the PAB under the boron recovery equipment was contaminated due to past spills involving evaporator bottoms. Contamination levels in several of these systems Revision 08 8

SUBSURFACE SOILS TN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD were high enough to create high radiation areas in their vicinity. Most of the cubicles that contained maj or systems were posted as "Contaminated Areas" identifying the presence of loose radioactive contamination in these areas.

Radiological surveys performed during facility operations indicated beta/gamma contamination levels in the PAB at levels up to hundreds of thousands of dpm/ 100 cm 2. Alpha contamination was also present at levels up to several thousand-dpm/100 cm2 Radiation levels in the PAB ranged from less than five (5) mR/hr to up to several thousand mR/hr.

Historically, leaks were found at the junction between the steam generator blow down line and the service water discharge line beneath the floor of the PAB drumming room. On at least one occasion, a leak resulted in contamination of the soil beneath the drumming room floor.

The FW/STM Penetration Building or "Terry Turbine Building" was located directly to the west of the Containment Building location. The building had three (3) basic levels. The lower level room contained auxiliary Feedwater pumps and piping, the middle level room contained the main steam dump valves and the upper level rooms housed the main steam stop valves. An outside catwalk that connected this building to the Service Building was located directly above Main Steam and Feedwater piping. The upper level also served as the alternate access HP control point to the Containment Building during decommissioning. The FW/STM Penetration Building was maintained free of loose radioactive contamination during facility operation. Periodic radiological surveys were routinely performed to substantiate this radiological condition.

The Electric Shutdown Auxiliary Feed Pump House contained the Electric Shutdown Auxiliary Feed Pump and all above grade DWST piping. The building was an independent structure with outer aluminum siding, inner sheetrock walls, slightly tapered sheet metal roof, asphalt floor, a building exhaust ventilation and a concrete support base beneath the pump. No significant radiological events were identified regarding this building.

The Demin Water Storage Tank (DWST), Condensate Storage Tank (CST), as defined includes the "Demin Water Storage Tank TK-25-1A" and the "Condensate Storage Tank TK-25-IB."

The 115 kV Switchyard (#11 11)was situated outside the RCA just south of the Containment building. This area included two (2) Station Service Transformers (#

204 & #205) and the 115 kV Tie Breaker (#218). Also, Bus 12 (ff120) was located at the SW corner of the yard. In addition to these, there were several other transformers with associated power lines that extended beyond the switchyard area.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD The DWST and the CST were located to the southwest of the Contaimnment Building in the northwest corner of the 115 kV Switchyard. Even though these tanks were designed to normally contain only non-radioactive water, there is a documented history of radiologically contaminated water occasionally being introduced into these systems. Events that have contributed to the introduction of contaminated water into these tanks were steam generator tube failures and misalignment of valves. Historical surveys in the vicinity of these tanks do not indicate radioactive contamination was >1000 dpmll 00cm 2 f3/y. During April 1999, a shallow monitoring well and a deep monitoring well on the west side of the DWST produced samples that showed positive results for tritium.

Major demolition and remediation activities in this area began in 2002. All radioactive systems and components located inside the PAB were removed and building structural surfaces were decontaminated to ensure contamination levels were acceptable for controlled demolition. Confirmatory radiological surveys were performed throughout the demolition process. The structural concrete of the PAB and FW/STM Penetration Building were then demolished to grade. The Electric Shutdown Auxiliary Feed Pump House, the DWST, the CST and the concrete base pads for all three (3) structures were completely demolished and removed. The dose from any residual radioactivity on the remaining below grade concrete footings and foundations were accounted for in the "Basement Fill Model".

Outside of the structures, remediation was performed on the soils surrounding the PAB. The excavation around the PAB footing was designated as Excavation #2; the excavation around the FW/STM Penetration Building was designated as Excavation #6 and the excavation adjacent to the Containment Building in the Southeast section of the survey unit was designated as Excavation #3. A significant volume of contaminated soil that exhibited direct exposure rates was removed prior to commencing soil sampling for isotopic analysis. Remediation support samples taken of the remaining soils in this area exhibited radionuclide concentrations of up to 5.46 pCi/g Cs-137 and 0.20 pCi/g Co-60. See the note provided in Table 5. The soils in all of these areas were remediated to bedrock and the excavations were backfilled following the performance of radiological assessments.

During plant operation, Survey Unit 9312-0005 was the location of several significant reactor support structures and systems, primarily consisting of a grouping of liquid and gas storage tanks referred to as the "Tank Farm" and the Spent Resin Facility. The Tank Farm was an asphalt covered area located to the northeast of the former location of the Containment structure where the Refueling Water Storage Tank (RWST), the Waste Test Tanks A & B, the Aerated Drains Holdup Tank (ADHUT), the Borated Waste Storage Tank (BWST) and the Recycle Test Tanks (RTT's) were located. In addition, the area also contained sub-grade covered and shielded pipe trenches that housed subsurface piping and Revision 0 10

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD conduit associated with the tanks and other adjacent support systems. The Resin Slurry and Ion Exchange Area included the "Ion Exchange Structure", the "Spent Resin Facility" and "Spent Resin Storage Facility". These facilities were located in the yard on the east side of the Tank Farm. All storage tanks, radioactive systems and components located in this area were removed and building structural surfaces were decontaminated to ensure contamination levels were acceptable for controlled demolition. Confirmatory radiological surveys were performed throughout the demolition process. The concrete pads for the tanks and structures were demolished and removed.

Extensive remediation was performed on the soils under and surrounding the Tank Farm. This excavation was designated as Excavation #1. A significant volume of contaminated soil that exhibited direct exposure rates was removed prior to commencing soil sampling for isotopic analysis. Soil samples taken in this area to support remediation continued to exhibit detectable concentrations of Cs-137, Co-60 and Sr-90. The soils in all of these areas were remediated to bedrock and the excavations were backfilled with clean soil following the performance of radiological assessments.

Post-remediation soil samples were taken under several Survey and Sampling Work Plans, including SSWP 05-06-006. Seven (7) surface soil samples were collected from the sidewalls of various excavations in and around Survey Unit 9312-0005 to support remediation and soil excavation prior to backfill. All samples were collected and analyzed by gamma spectroscopy by an approved off-site laboratory. All of the samples collected were analyzed for "Hard-to-Detect" (HTD) radionuclides.

A review of this sample data shows that Cs-137 and Co-60 are the primary radionuclides of concern. These radionuclides were detected in five (5) of the seven (7) soil samples. Cs-137 was the predominant radionuclide over Co-60 by a factor of sixteen (16) to one (1). Sr-90 was positively detected (i.e., a result greater than two (2) standard deviations uncertainty) in one (1) sample, but at a concentration of less than 5% of the Operational DCGL. A summary of the sample results for Cs-137 and Co-60 are provided in Table 3.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD Table 3 - Sample Analysis Results from Post-Remediation Soil Parameter Cs-137 Co-60 Minimum Value: 9.43E-03 -1.04E-02 Maximum Value: 1.85E+00 1.44E-01 Mean: 3.54E-01 5.16E-02 Median: 5.33E-02 3.3 5E-02 Standard Deviation: 6.75E-01 6.16E-02 During plant operation, Survey Unit 9312-0006 was the location of significant reactor support structures and systems, primarily the Primary Auxiliary Building (PAB).

Outside of the structure, remediation was performed on the soils surrounding the PAB. The excavation around the PAB footing was designated as the "Big Dig".

A significant volume of contaminated soil that exhibited direct exposure rates was removed prior to commencing soil sampling for isotopic analysis. Soil samples taken in this area to support remediation continued to exhibit significant concentrations of Cs-137, Co-60 and Sr-90. The soils in all of these areas were remediated to bedrock and the excavations were backfilled with clean soil following the performance of radiological assessments.

Post-remediation soil samples were taken under several Survey and Sampling Work Plans, including SSWPs 05-06-00 1 and 05-06-006. Thirty-seven (37) surface soil samples were collected from the sidewalls of various excavations in and around Survey Unit 9312-0006 to support remediation and soil excavation prior to backfill. All samples were collected and analyzed by gamma spectroscopy by an approved off-site laboratory. Eighteen (18) of the thirty-seven (37) total samples collected were analyzed for "Hard-to-Detect" (HTD) radionuclides.

A review of this sample data shows that Cs- 137, Co-60 and Sr-90 are the primary radionuclides of concern. These radionuclides were detected in twenty (20) of the thirty-seven (37) soil samples. Cs-137 was the predominant radionuclide over Co-60 by a factor of ten (10) to one (1). Sr-90 was positively detected (i.e.,

a result greater than two (2) standard deviations uncertainty) in seven (7) samples at concentrations up to 20% of the Operational DCGL. In addition, other "Hard-Revision 0 12

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD to-Detect" (HTD) radionuclides were also positively identified, but in concentrations less than 5% as a single isotope and 10% as an aggregate of their respective Operational DCGLs. A summary of the sample results are provided in Table 4.

Table 4 - Sample Analysis Results from Post-Remediation Soil Sample Population in Survey Unit 9312-0006 Parameter pCsi137 (Co-60 (prilg Minimum Value: -1.23E-02 -1.99E-02 1.26E-02 Maximum Value: 1.85E+00 5.04E-01 1.90E-01 Mean: 1.32E-01 3.07E-02 7.05E-02 Median: 2.38E-02 8.69E-03 3.56E-02 Standard Deviation: 3.82E-01 8.68E-02 7.28E-02 To aid in the determination of the radionuclides of concern for Survey Unit 980 1-0000, a total of thirty-nine (39) characterization and post remediation samples from within the survey unit that were analyzed for Hard-To-Detect (HTD) radionuclides, identified in Table 6, were assembled and the results are provided in Table 5.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD Table 5 - IITD Characterization Sample Results for Survey Unit 980 1-0000 Nuclide Operational Minimum Maximum Mean Median Standard # of >2a #

DCGL Deviation Samples > Samples OP.

DCGL"1 )

H-3 2.48E+/-02 -1.85E+00 3.62E+/-02 1.65E+01 1.18E+00 5.9213+01 1 14 39 C-14 3.39E+/-00 -5.92E-01 6.85E+00 3.50E-01 -1.55E-01 1.57E+00 3 9 39 Fe-55 1.64E+/-04 -1.21E+/-01 3.32E+/-02 8.54E+00 -8.32E-03 5.34E+01 0 5 39 Ni-63 4.3413+02 -1.09E+/-01 3.89E+03 1.03E+02 7.52E-01 6.23E+02 1 11 39 Sr-90 9.28E-01 -1.38E-02 1.72E+02 4.57E+/-00 2.57E-02 2.75E+01 3 24 39 Tc-99 7.56E+00 -9.39E-01 1.71E+/-00 2.83E-01 2.38E-01 4.2513-01 0 13 38 Pu-238 1.78E+01 -3.55E-02 3.65E+01 1.04E+00 -6.43E-04 5.83E+00 1 5 39 Pu- 1.60E+01 -2.89E-02 1.25E+/-01 3.61 E-0 I 3.60E-03 2.OOE+00 0 6 39 239/240 Pu-241 5.2213+02 -2.15E+01 3.18E+/-01 -3.47E-01 3.OOE-02 6.94E+00 0 2 38 Cm- 1.74E+01 -1I.62E-02 2.I101+Ol1 5.81 E-0 1 2.4313-04 3.36E+00 1 4 39 243/244 (1)TThis column identifies the number of Characterization samples that may have exceeded the Operational DCGL. Where the Operational DCGL was exceeded, additional remediation was conducted to reduce the contamination levels to below the Operational DCGL.

Based on the characterization and post-remediation sample results from each area within this survey unit, the radionuclides of concern are Cs-137, Co-60, Sr-90, Am-241, Eu-154 and H-3.

However, in the interest of conservatism, 100% of the subsurface soil samples taken in this survey unit were analyzed by an approved off-site laboratory for All radionuclides specified in Table 6. All radionuclides listed in Table 6 that are verified to be present in FSS samples were included in the assessment of data and incorporated into the decision process, as necessary.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD

3. DATA QUALITY OBJECTIVES (DQO)

FSS design and planning used the Data Quality Objective (DQO) process as described by the LTP, Procedure RPM 5. 1-11, "Preparation of Final Status Survey Plan," and the "Multi-Agency Radiation Survey and Site Investigation Manual" (MARSSIM). A summary of the main features of the DQO process are provided herein.

The DQO process incorporated hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis. Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition. The baseline condition is technically known as the null hypothesis. Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection. In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria. Rejection of the null hypothesis would indicate that residual activity within the survey unit does not exceed the release criteria. Therefore, the survey unit does satisfy the primary objective of the FSS plan.

The primary objective of the FSS plan was to demonstrate that the level of residual radioactivity in Survey Unit 980 1-0000 did not exceed the release criteria specified in the LTP and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).

A fundamental precursor to survey design is to establish a relationship between the release criteria and some measurable quantity. This is done through the development of DCGLs. The DCGLs represent average levels of radioactivity above background levels and are presented in terms of surface or mass activity concentrations. Chapter 6 of the LTP describes in detail the modeling used to develop the DCGLs for soil (called Base Case Soil DCGL), existing groundwater radioactivity and fuiture groundwater radioactivity that will be contributed by building basements and footings.

The DCGLs presented in Chapter 6 of the LTP were developed for exposures from three (3) components, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity. Equation 1 shows the mathematical relationship between the three (3) components and the total dose.

Equation 1 H Total=11Soil+HExistingGw + JFutureGW Revision 0 15

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD The total dose under the LIP criteria is twenty-five (25) mrem/yr Total Effective Dose Equivalent (TEDE) from all three (3) components. The allowable total dose under the Connecticut Department of Environmental Protection (CTDEP) radiological remediation standard for CY is nineteen (19) mremlyr TEDE. To satisfy both the LTP and CY CTDEP criteria, the dose from soil must be reduced when using the existing and future groundwater dose values discussed above.

This survey area is affected by existing groundwater (reference CY memo ISC 06-024). Therefore, the dose contribution from existing groundwater is bounded by two (2) mrem/yr TEDE.

This survey unit is considered impacted by future groundwater radioactive contamination, as there are underground foundations containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo LSC 06-024). The dose contribution from future groundwater, the third dose component, is bounded by two (2) mremlyr TEDE.

Equation 2 19 mrem/yrT0 ,aj = 15 mrem/yrsoil + 2 mremlyrrxisting GW+ 2 mrem1/yrFut~reGW The allowable dose for soil in this survey unit is fifteen (15) mrem/yr TEDE as shown by Equation 2 above. The concentration of residual radioactivity resulting in fifteen (15) mrem/yr TEDE is designated as the Operational DCGL, and has been established for the radionuclides of concern as provided in Table 6.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD Table 6 - Radionuclide Specific Base Case Soil DCGLs, Operational DCGLs and]

Required Minimum Detectable Concentrations (MDCs)

Radionuclide () Base Case Soil Operational DCGL Required MDC DCGL (pC/g) ()(pC/g) (3) (PC/g) (4)

H-3 4.12E+02 2.47E+02 1.65E+/-01 C-14 5.66E+00 3.40E+/-00 2.26E-01I Mn-54 1.74E+01 1.04E+01 6.96E-0 I Fe-55 2.74E+04 1.64E+04 1.1OE+03 Co-60 3.81E+00 2.29E+00 1.52E-01 Ni-63 7.23E+02 4.34E+02 2.89E+01 Sr-90 1.55E+00 9.30E-01 6.20E-02 Nb-94 7.12E+i00 4.27E+00 2.85E-01 Tc-99 1.26E+01 7.56E+00 5.04E-0 I Ag- 108m 7. 14E+00 4.28E+00 2.86E-0 1 Cs-134 4.67E+00 2.80E+00 1.87E-01 Cs-137 7.9 1E+00 4.75E+00 3.16E-01 Eu-i 52 1.01lE+0 1 6.06E+00 4.04E-0 1 Eu-154 9.29E+00 5.57E+00 3.72E-01 Eu-155 3.92E+02 2.35E+02 1.57E+01 Pu-238 2.96E+01 1.78E+0 1 1.18E+00 Pu-239/240 2.67E+0 1 1.60E+0 1 1.07E+00 Am-241 (5) 2.5 8E+01I 1.55E+01 1.03E+00 Pu-241 8.70E+02 5.22E+02 3.48E+01I Cm-243/244 2.90E+0 1 1.74E+0 1 1.16E+00 (1) Bold indicates those radionucidies considered Hard to Detect (HTD)

(2) The Base Case Soil DCGL(s) are specified by the LTP in Chapter 6 and are equivalent to twenty-five (25) mremlyr TEDE (3) The Operational DCCL is equivalent to achieving fifteen (15) miremlyr TEDE (4) The required MDC is equivalent to achieving one (1) mremlyr TEDE (5) Americium-241 can be analyzed by gamma and alpha spectroscopy and is considered to be Easy to Detect (ETD). The preferred result is the alpha spectroscopy's when both analyses are performed Revision 0 17

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD Another important facet of the DQO process is to identify' the radionuclides of concern and determine the concentration variability. Based on the characterization and post remediation of the subsurface soils within this survey unit, Cs-137 and Co-60 were identified as the principle gamma emitting radionuclides which were present in sufficient concentrations that could potentially exceed the screening criteria. In addition, Sr-90, H-3, Am-241 and Eu- 154 were positively identified (i.e. a result greater than two (2) standard deviations uncertainty) in several samples.

As stated previously, 100% of the subsurface soil samples taken in this survey unit were analyzed by an approved off-site laboratory for All of the radionuclides specified in Table 1. All radionuclides listed in Table 1 that are verified to be present in FSS samples were included in the assessment of data and incorporated into the decision process, as necessary.

As part of the DQOs applied to laboratory processes, analysis results were reported as actual calculated results. Results reported as less than Minimum Detectable Concentration (MDC) were not accepted for FSS. Sample report summaries included unique sample identification, analytical method, radionuclide, result, and uncertainty to two (2) standard deviations, laboratory data qualifiers, units, and the required and observed MDC.

4. SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. Guidance for preparing FSS plans is provided in Procedure RPM 5. 1-11, "Preparationof Final Status Survey Plans".

The FSS plan uses a sample design that includes either random or biased media sampling.

The DQO process determined that Cs-137, Co-60, Sr-90, H-3, Am-241 and Eu-154 were the primary radionuclides of concern in Survey Unit 9801-0000.

However, all radionuclides positively identified at concentrations greater than the screening criteria during the performance of this FSS would also be evaluated to ensure adequate survey design. Radionuclide screening or de-selection is a process where an individual radionuclide or aggregates may be considered insignificant and eliminated from the FSS. The criteria for de-selection are concentrations less than 5% for individual radionuclides and less than 10% for aggregates.

As the survey unit is classified as a Class A subsurface soils area, and discrete, elevated areas of contamination were possible, the application of the Elevated Measurement Comparison (EMC) remained an option.

The Sign Test was selected as the non-parametric statistical test. The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation. This approach was conservative since it included background Cs-137 as part of the sample set.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD LTP Section 5.7.3.2.2 states that for a Subsurface Class A area there shall be a minimum of thirty-one (3 1) measurement locations, 2based on a sample population of approximately one (1) per five hundred (500) mn in a Class A subsurface soil area. However, thirty-one (3 1) measurement locations over the surface area identified in this survey unit as approximately fifteen thousand seven hundred and eighty-eight (15,788) m2 would equate to one (1) sample every five hundred and nine (509) in . Since this ratio is larger than the ratio for a Class A subsurface area identified in the LTP, the minimum number of samples to be collected, within this survey unit, was increased to thirty-two (32) measurement locations. The sample density for Survey Unit 9801-0000 with a sample population of thirty-two (32) measurements over approximately fifteen thousand seven hundred and eighty-eight (15,788) m2ý is one (1) measurement every four hundred and ninety-three 2

(493) Mn . In addition, biased measurements or samples will be obtained at the locations of localized remediation efforts where subsurface leaks are suspected to have created soil contamination.

Additionally, LTP Section 5.7.3.2.2 states that the range of the number of measurements in Class A areas corresponds to the range of values for N (for Sign test), considering a = 0 .05, P1= 0.05, and a relative shift of < 3.0.

The grid pattern and locations of the soil samples were determined using Visual Sample Plan (VSP) in accordance with Procedure RPM 5.1-14, "Identifying, and Marking Surface Sample Locationsfor Final Status Survey." Visual Sample Plan was created by Pacific Northwest National Laboratory (PNINL) for the United States Department of Energy. A systematic triangular grid pattern with a random starting point was selected for sample design, which is appropriate for a Class A subsurface survey area.

Sample locations were identified using AutoCAD-LT, a commercially available plotting software package with coordinates consistent with the Connecticut State Plane System. These coordinates were integrated with a GPS to locate sample locations in the field. Sample Measurement Locations for the design are listed with the GPS coordinates in Table 7.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD Table 7 - Sample Measurement Locations with Associated GPS Coordinates for Non-parametric Sample Population Designation~') Northing Easting 980 1-0000-003F 236790.69 668689.11 9801-0000-005F 236723.29 668572.38 9801-0000-006F 236723.29 668650.20 9801-0000-007F 236723.29 668728.02 9801-0000-008F 236723.29 668805.85 9801-0000-009F 236655.90 668455.64 9801-0000-OlOF 236655.90 668533.46 9801-0000-01 IF 236655.90 668611.29 9801-0000-012F 236655.90 668689.11 9801-0000-013F 236655.90 668766.93 9801-0000-014F 236655.90 668844.76 9801-0000-015F 236655.90 668922.58 9801-0000-016F 236655.90 669000.40 9801-0000-017F 236588.50 668572.38 9801-0000-018F 236588.50 668650.20 9801-0000-019F 236588.50 668728.02 9801-0000-020F 236588.50 668805.85 9801-0000-021F 236588.50 668883.67 9801-0000-022F 236588.50 668961.49 9801-0000-023F 236588.50 669039.31 9801-0000-024F 236521.10 668689.11 9801-0000-025F 236521.10 668766.93 9801-0000-026F 236521.10 668844.76 9801-0000-027F 236521.10 668922.58 9801-0000-028F 236521.10 669000.40 9801-0000-029F 236453.71 668728.02 9801-0000-030F 236453.71 668805.85 9801-0000-031F 236453.71 668883.67 9801-0000-032F 1236386.31 1668844.761

()Non-parametric statistical testing sample numbers 9801-0000-OO1F, 9801-0000-002F and 9801 -0000-004F were inaccessible due to GeoProbeA refusal prior to the required volume being collected. Therefore, addendum #1 to the FSSP was written and sample numbers 980 1-0000-040F, 9801-0000-041IF and 9801 -0000-042F were identified as replacement samples.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD During the performance of the survey, it was discovered that three (3) of the thirty-two (32) sample locations identified for non-parametric testing were deemed to be inaccessible due to refusal of the direct push probe sampling technology (GeoProbeg) prior to retrieving the required amount of sample. The three (3) inaccessible locations identified were 9801-0000-OO1F, 9801-0000-002F and 9801-0000-004F. Subsequently, three (3) additional sample measurement locations were designated to replace the locations that were deemed to be inaccessible. The location of the samples were determined using Visual Sample Plan (VSP) in accordance with RPM 5.1-14, "Identifying and Marking Surface Sample Locationsfor FSS in Open Land Areas" using a random selection which is appropriate for relocating a small number of sample locations in a Class A area.

Sample Measurement Locations for the additional samples are listed with the GPS coordinates in Table 10.

In accordance with LTP Section 5.7.3.2.2, judgmental samples were identified as a part of the sample design.

The FSSP identified that a minimum of six (6) judgmental samples would be collected in this survey area. Three (3) judgmental samples were to be collected from the location referred to as the "Big Dig". An additional judgmental sample was to be collected from each one (1) of the following locations: North of Spent Fuel Building (SFB), south of SFB (Bus 10) and north of the Make-up Water Storage Tank (MWST) area. The general locations of the judgmental samples are illustrated on the Sample Location Map & Work Sheet and coordinates are provided in Table 8. Additional judgmental samples may be collected, at the discretion of the FSS Engineer.

Table 8 - Sample Measurement Locations with Associated GPS Coordinates for Judgmental Sample Locations Designation~1 ) Northing Easting 9801-0000-033B 236681.07 668555.32 9801-0000-034B 236685.06 668696.45 980 1-0000-035B 236675.11 668724.27 9801-0000-036B 236671.04 668798.85 9801-0000-037B 236570.96 668910.03

()Judgmental sample # 9801-0000-038B was inaccessible because the random location selected was sixteen (16) feet up the mountain side. Therefore, addendum #1 to the FSSP was written and sample # 980 1-0000-039B was identified as a replacement sample location.

Addendum #1 to the FSSP was developed to identify both the three (3) replacement non-parametric statistical samples and the one (1) judgmental sample that were inaccessible. Table 9 identifies the replacement sample locations.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD Table 9 - Sample Measurement Locations with Associated GPS Coordinates for Replacement Sample Locations Designation"l) Northing Easting 9801-0000-040F 236632.77 668781.15 9801-0000-041F 236465.06 668926.89 980 1-0000-042F 236542.21 668994.01 980 1-0000-039B 236664.60 668895.83

()"F" denotes non-parametric statistical testing Final Status Survey sample and "B" denotes Judgmental or Biased sample.

Procedure RPM 5.1-11 specifies that 5% of the samples are required to be selected for HTD analysis. However, in the interest of conservatism all thirty-eight (38) samples were sent off-site for a full suite analysis of the HTD radionuclides specified in the LTP, Table 2-12, "Radionuclides Potentially Presentat Haddam Neck Plant" and as provided in Table 6.

The implementation of quality control measures as referenced by Procedure RPM 5.1-24, "Split Sample Assessment for FinalStatus Survey," included the collection of two (2) soil sample for "split sample" analysis by the off-site laboratory. This location was selected randomly using the Microsoft Excel "RANDBETWEEN" function.

Survey Unit 980 1-0000 is a subsurface survey unit. Subsequently, no scanning was required.

For this Class A survey unit, the "Investigation Level" for soil sample measurement results are those levels specified in LTP, Table 5-8. Table 10 provides a synopsis of the survey design.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD Table 10 - Synopsis of the Survey Design Feature Design Criteria Basis Subsurface Survey Unit 15,788 m2 Based on AutoCAD-LT Land Area 38 lAW LTP Section Numbr o Meaureent(32Sysematc gid) 5.7.3.2.2 for a Class A Numbr o Meaureent (32Sysematc gid) Subsurface Soil Survey (6 Judgmental) Unit Grid Spacing 23.87 mn Based on triangular grid 4.75 pCi/g Cs-137, 2.29 pCi/g Co-60, 0.93 Administratively set to Operational DCGL pCilg Sr-90, 247 pCi/g H- achieve 15 mrem/yr TEDE 3, 15.5 pCi/g Am-241 and()

5.57 pCi/g Eu-154.

4.75 pCi/g Cs-137, The Operational DCGL(s) 2.29 pCi/g Co-60, 0.93 are more conservative that Soil Investigation Level pCi/g Sr-90, 247 pCi/g H- the LTP criteria for a Class 3, 15.5 pCi/g Am-241 and A survey unit 5.5 7 pCi/g Fu-154.

(1) The allowable dose for soil in this survey unit is fifteen (15) mrem/yr TEDE as the bounding dose from existing and future groundwater has been established based on field data (reference CY memo ISC 06-024).

5. SURVEY IMPLEMENTATION Final status survey field activities were conducted in accordance with the FSSP and Addendum #1 to the FSSP for Survey Unit 9801-0000. Subsurface soil sampling was conducted in accordance with Site Excavation Permit # 2006-0007.

The FSS plan included a job safety analysis, a job planning checklist, a site excavation permit and related procedures for reference. Daily briefings were conducted to discuss the expectations for job performance and the safety aspects of the survey. The "Daily Survey Journal" was used to document field activities and other information pertaining to the FSS.

Measurement locations were identified in North American Datum (NAD) 1927 coordinates using GPS coordinates; sample locations were identified and marked with a surveyor's flag or paint for identification.

Thirty-eight (38) subsurface soil samples were collected and packaged in accordance with Haddam Neck Plant (HNP) Procedure RPM 5.1-3, "Collection of Sample Media for Final Status Survey" and FSS design. Samples were collected using GeoProbe.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD All samples were obtained to a depth of three (3) meters or refusal. Table I11 and Table 12 identified the depth of each sample in addition to the Cs-137, Co-60 and Sr-90 activity.

Samples were controlled, transported, stored, and transferred to the off-site laboratory using Chain-of-Custody (COC) protocol in accordance with Procedure RPM 5.1-5, "Chain of Custody for Final Status Survey Samples." The off-site laboratory employed for the radiological analyses of samples was General Engineering Laboratories, LLC.

All thirty-eight (38), thirty-two (32) for non-parametric statistical testing and six (6) judgmental, samples were selected for gamma spectroscopic and HTD radionuclide analysis for the twenty site specific radionuclides of interest, identified in Table 6.

The implementation of survey specific quality control measures included the collection of two (2) samples (9801-0000-015F and 9801-0000-022F) for "split sample" analysis.

6. SURVEY RESULTS All field survey activities were conducted between March 28, 2007 and April 3, 2007.

The off-site laboratory employed for the radiological analyses of samples was General Engineering Laboratories, LLC. The laboratory analyzed the thirty-two (32) samples collected for non-parametric statistical testing, the associated field splits and the six (6) judgmental samples using gamma spectroscopy.

As stated in Section 4, the off-site laboratory processed all thirty-two (32) samples identified for non-parametric statistically testing for gamma spectroscopy and HTD analyses. Additionally, the six (6) judgmental samples were also analyzed by gamma spectroscopy and HTD for the radionuclides of interest. The requested analyses included alpha spectroscopy, gas proportional counting, and liquid scintillation depending on the radionuclide and the measurement method.

The criteria for de-selection of a radionuclide is a concentration that is less than 5% of the Operational DCGL for individual radionuclides and less than 10% of the Operational DCGLs for aggregates.

All analyses met the required MD)Cs.

Cs-137 was identified in seventeen (17) and Co-60 was identified in four (4) of the thirty-two (32) samples collected for non-parametric statistical testing.

Additionally, Cs-137 was identified in four (4) and Co-60 was not identified in any of the six (6) judgmental samples collected. The mean of the gamma spectroscopic analysis results for the sample population indicated that Cs-137 was present at levels approaching the concentrations of Cs- 137 found in soil at off-site Revision 0 24

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD locations within the vicinity of the HNP as presented in the Health Physics TSD BCY-HP-0063.

Sr-90 was positively identified (i.e., a result greater than two (2) standard deviations uncertainty) in three (3) of the thirty-two (32) non-parametric statistical and one (1) of the judgmental samples analyzed for HTD radionuclides.

A summary of the thirty-two (32) samples collected for non-parametric statistical testing results is provided in Table 11.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD Table 11- Summary of Sample Results for Subsurface Soil Samples Comprising the Statistical Sample Population SmlNu br Depth"'~ Cs-137 Co-60 Sr-90 SapeNu br (feet) pCilg pcilg pCilg 9801-0000-003F 3.5 9.6713-02 4.41 E-04 -1.14E-02 9801-0000-005F 6.0 8.62E-02 -1.17E-02 -2.41 E-02 9801-0000-006F 6.0 5.93E-02 1.19E-02 -1.72E-02 9801-0000-007F 8.5 0.00E+/-00 1.06E-02 -1.11 E-02 9801-0000-008F 5.0 7.03E-02 0.00E+00 -1.95E-03 9801-0000-009F 9.0 5.98E-02 2.16E-02 -2.49E-03 9801-0000-0010F 7.5 6.4713-03 6.82E-02 -5.78E-03 980 1-0000-0011IF 9.0 4.60E-02 -1.79E-03 4.03E-02 9801-0000-0012F 8.5 6.81 E-02 1.27E-03 -1.29E-03 9801-0000-0013F 6.5 4.3613-03 8.20E-03 -5.16E-04 9801-0000-0014F 8.0 2.20E-01 6.24E-01 -2.0013-02 9801-0000-0015F 5.5 6.61 E-01I 1.64E-01 5.8513-03 9801-0000-0016F 9.0 5.4613-04 4.09E-03 1.51E-03 9801-0000-0017F 5.0 1.94E-02 1.38E-02 -1.02E-02 9801-0000-0018F 8.0 1.24E-01 4.7413-02 3.7913-02 9801-0000-0019F 8.0 1.57E-02 2.02E-02 3.48E-02 9801-0000-0020F 8.0 9,94E-03 -8.79E-03 1.99E-02 9801-0000-0021 F 8.0 1.51 E-02 -1 .26E-02 -7.32E-03 9801-0000-0022F 9.5 1.46E-01 5.27E-02 -7.13E-03 9801-0000-0023F 9.0 1.09E-01 -2.63E-02 -7.86E-03 9801-0000-0024F 8.0 2.9413-02 -6.49E-03 1.11 IE-02 9801 -0000-0025F 8.0 -5.53E-03 -3.72E-02 1.8513-03 9801-0000-0026F 8.0 2.78E-02 3.03E-02 -1.5513-03 9801-0000-0027F 8.0 6.1413-02 1.15E-02 -9.41E-03 9801l-0000-0028F 9.0 6.14E-02 7.7013-03 8.77E-04 9801-0000-0029F 8.0 1.1913-02 2.44E-03 4.84E-03 9801-0000-0030F 7.5 5.61 E-02 2.0013-02 -3.42E-03 9801-0000-003 1F 8.5 2.20E-02 1.16E-03 -2.67E-02 9801-0000-0032F 8.0 1.48E-02 -2.84E-02 1.04E-02 9801-0000-0040F 8.0 2.53E-02 6.42E-03 1.3 1E-02 9801-0000-0041F 10.5 2.14E-02 2.9 1E-02 1.1OE-02 9801-0000-0042F 10.5 4.92E-02 1.34E-02 -1.45E-03 Depth in feet is approximate. One (1) push of GeoProbeg equals approximately four (4) feet of vertical depth.

(2)

Samples that were of depth of less than nine (9) feet were generally the result of refusal by the coring devise.

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD A summary of the six (6) judgmental sample results is provided in Table 12.

Table 12- Summary of Sample Results for Subsurface Soil Samples Comprising the Judgmental Sample Population Sample Number Depth(') Cs-137Co6 r9 (feet) pcilg pcilg pcilg 9801-0000-033B 7.5 1.57E-02 2.17E-02 2.4313-03 9801-0000-034B 6.0 7.75E-02 -6.18E-04 9.13E-03 9801-0000-035B 8.0 4.87E-02 1.80E-02 5.42E-03 9801-0000-036B 6.0 4.84E-02 1.05E-02 3.28E-02 9801-0000-037B 8.0 1.74E-02 -5.79E-03 1.12E-02 9801-0000-039B 4.5 5.49E-02 1.04E-02 5.5 1E-03 (3) Depth in feet is approximate. One (1) push of GeoProbeg equals approximately four (4) feet of vertical depth.

Of the remaining radionuclides of concern, identified in Section 4, H-3, Eu-154 and Am-241 were positively detected (i.e., a result greater than two (2) standard deviations uncertainty) in one (1), none and five (5) of the thirty-eight (38) samples analyzed, respectively. Additionally, based on the sample results, all three radionuclides mentioned above met the criteria for de-selection of a radionuclide of concern. Therefore, H-3, Eu-154 and Am-241 were de-selected based on the criteria discussed in Section 4.

Of the remaining site specific radionuclides of interest, identified in Table 6, only Manganese-54 (Mn-54), Iron-55 (Fe-S 5), Niobium-94 (Nb-94), Silver-108 meta-stable (Ag-108m), Cesium-134 (Cs-134) and Plutonium-238 (Pu-238) were positively detected (i.e., a result greater than two (2) standard deviations uncertainty) in two (2), one (1), one (1), two (2), nine (9) and one (1) of the thirty-eight (38) samples analyzed, respectively. Based on the sample results, the de-selection of these radionuclides based on the criteria discussed in Section 4, was appropriate. A summary of the results of the remaining radionuclides of interest, from Table 6, is provided in Attachment 3.

The "sum-of-fractions" or "unity rule" is the mathematical test used to evaluate compliance with radiological criteria for license termination when more than one radionuclide has been determined to be potentially present. The unity rule is:

Equation 3 C, C2 Cn <

DCGL, DCGL 2 DCGLn Where: Cn = concentration of radionuclide n and Revision 0 27

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD DCGL,, DCGL of radionuclide n.

The results of the unity rule calculation for the radionuclides of concern in the statistical sample population for Survey Unit 980 1-0000 are provided in Table 13 below.

Table 13- Results of Unity Calculation for Subsurface Soil Samples Comprising the Statistical Sample Population SmlNubrFraction of the Operational DCGL~l)(2) r3 nt(4)

Cs-137 Co-60 Sr-90 Other 3 Unt 9801-0000-003F 0.020 0.000 -- 0.020 9801-0000-005F 0.018 - -- 0.018 9801-0000-006F 0.012 0.005 -0.025 0.042 9801-0000-007F - 0.005 -- 0.005 9801-0000-008F 0.015 0.000 -0.024 0.039 9801-0000-009F 0.013 0.009 -0.029 0.051 9801-0000-OOIOF 0.001 0.030 - - 0.031 9 80 1-0000-001IIF 0.010 - 0.043 0.004 0.057 9801-0000-0012F 0.014 0.001 - 0.004 0.019 9801-0000-0013F 0.001 0.004 -- 0.005 9801-0000-0014F 0.046 0.274 - - 0.320 9801-0000-0015F 0.139 0.072 0.006 0.017 0.234 9801-0000-0016F 0.000 0.002 0.002 - 0.004 9801-0000-0017F 0.004 0.006 - - 0.010 9801-0000-0018F 0.026 0.021 0.041 0.005 0.093 9801-0000-0019F 0.003 0.009 0.037 - 0.049 9801-0000-0020F 0.002 - 0.021 0.002 0.025 9801-0000-0021F 0.003 - - - 0.003 9801-0000-0022F 0.031 0.023 -0.012 0.066 9801-0000-0023F 0.023 - - - 0.023 9801-0000-0024F 0.006 -0.012 0.014 0.032 980 1-0000-0025F - - 0.002 - 0.002 9801-0000-0026F 0.006 0.013 - -0.019 9801-0000-0027F 0.013 0.005 - - 0.018 9801-0000-0028F 0.013 0.003 0.001 0.002 0.019 9801-0000-0029F 0.003 0.001 0.005 0.009 0.018 9801-0000-0030F 0.012 0.009 - - 0.021 9801-0000-0031F 0.005 0.001 - -0.006 9801-0000-0032F 0.003 - 0.011 -0.014 9801-0000-0040F 0.005 0.003 0.014 -0.022 Revision 0 28

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801 -0000 RELEASE RECORD 9801-0000-0041F 0.005 0.013 0.012 0.013 0.043 9801-0000-0042F 0.010 0.006 - 0.019 0.035 Table 13- Continued SThe Operational DCGLs are 4.75 pCilg for Cs-137, 2.29 pCi/g for Co-60 and 0.93 pCi/g for Sr-90, from Table 6, and are used in conjunction with the unity rule. Fraction of Operational DCGL is determined by dividing the concentration of a radionuclide by the corresponding Operational DCGL, provided in Table 6, to determine the fraction of Unity that is present in the sample. For this Survey Unit, the Operational DCGL corresponds to fifteen (15) mremlyr, TEDE.

(2) "-"in cells indicates that the radionuclide was not positively detected in the sample.

(3) Determined by using the Operational DCGLs, from Table 6, for the remaining radionuclides and dividing the sample activity by the corresponding Operational DCGL to determine the fraction present. For this Survey Unit, the Operational DCGL corresponds to fifteen (15) mremlyr, TEDE.

(4) Determined by using Equation #3.

The results of the unity rule calculation for the radionuclides of concern in the judgmental sample population for Survey Unit 9801-0000 are provided in Table 14 below.

Table 14- Results of Unity Calculation for Subsurface Soil Samples Comprising the Judgmental Sample Population SmlNu brFraction of the Operational DCGL~l)(2 ) 3 nt (4)

Cs-137 Co-60 Sr-90 Other~3 nt 9801-0000-033B 0.003 0.010 0.003 - 0.016 9801-0000-034B 0.016 - 0.010 0.026 0.052 980 1-0000-035B 0.0 10 0.008 0.006 0.008 0.032 9801-0000-036B 0.010 0.005 0.035 0.019 0.069 9801-0000-037B 0.004 - 0.012 0.016 0.032 9801-0000-039B 0,012 1 0.005 1 0.006 - 0I 2 (1)~ The Operational DCGLs are 4.75 pCi/g for Cs-137, 2.29 pCi/g for Co-60 and 0.93 pCilg for Sr-90, from Table 6, and are used in conjunction with the unity rule. Fraction of Operational DCGL is determined by dividing the concentration of a radionuclide by the corresponding Operational DCGL, provided in Table 6, to determine the fraction of Unity that is present in the sample. For this Survey Unit, the Operational DCGL corresponds to fifteen (15) mremlyr, TEDE.

(2) "-"in cells indicates that the radionuclide was not positively detected in the sample.

(3) Determined by using the Operational DCGLs, from Table 6, for the remaining radionuclides and dividing the sample activity by the corresponding Operational DCGL to determine the fraction present. For this Survey Unit, the Operational DCGL corresponds to fifteen (15) mremlyr, TEDE.

(4) Determined by using Equation #3.

Revision 0 29

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD

7. QUALITY CONTROL The off-site laboratory processed the split samples and performed gamma spectroscopic and HTD analyses. Two (2) of the thirty-two (32) non-parametric statistical samples, or 6.3%, of the samples were selected for analysis, which exceeds the 5% minimum required by the LTP. The data were evaluated using USNRC acceptance criteria specified in Inspection Procedure 84750 as detailed in HNP Procedure RPM 5.1-24, "Split Sample Assessment for FinalStatus Survey ".

Co-60 was not detected in sufficient quantities in the field split results at locations 9801-0000-013 or 9801-0000-022 to evaluate in accordance with procedure. Cs-137 was not detected in sufficient quantities in the field split results at location 9801-0000-013. Evaluation using the reported results for naturally occurring K-40 resulted in acceptable agreement between the field-split results at these locations.

The sample analysis vendor, GEL, maintains quality control and quality assurance plans as part of normal operation. Refer to Attachment 3 for data and data quality analysis results.

8. INVESTIGATIONS AND RESULTS No investigations were conducted within this survey unit.

9. REMEDIATION AND RESULTS Significant remediation activities occurred in this survey unit prior to FSS. All above grade and many below grade commodities and facility systems were removed and properly dispositioned. Contaminated soils were identified, excavated and removed as part of the numerous remediation projects which occurred in this survey area. All excavations were characterized and backfilled prior to performing FSS. As a byproduct of remediation activities, the ground area is comprised of barren dirt with no vegetation, and the soils have been graded relatively flat to the corresponding elevation of the survey units to the north and west. Health Physics TSD BCY-HP-0078, "ALARA Evaluation of Soil Remediation in Support of Final Status Survey, " determined that remediation beyond that required to meet the release criteria is unnecessary and that the remaining residual radioactivity in soil was ALARA.

10. CHANGES FROM THE FINAL STATUS SURVEY PLAN During the performance of the survey, it was discovered that three (3) of the thirty-two (32) sample locations identified for non-parametric testing and one (1) of the judgmental sample locations were deemed to be inaccessible. The four (4) locations identified were 9801-0000-OO1F, 9801-0000-002F, 9801-0000-004F and 9801-0000-038B. Subsequently, Addendum #1 to the FSSP was written and Revision 0 30

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD four (4) additional sample measurement locations (9801-0000-040F, 9801-0000-041F, 9801-0000-042F and 9801-0000-039B) were designated to replace the locations that were deemed to be inaccessible.

11. DATA QUALITY ASSESSMENT (DQA)

The DQO sample design and data were reviewed in accordance with Procedure RPM 5.1-23, "Data Quality Assessment, " for completeness and consistency.

The Sign Test was performed on the data and compared to the original assumptions of the DQOs. The evaluation of the Sign Test results demonstrates that the survey unit passes the unrestricted release criteria, thus, the null hypothesis is rejected.

Documentation was complete and legible. Surveys and sample collection were consistent with the DQOs and were sufficient to ensure that the survey unit was properly designated as Class A.

The preliminary data review consisted of calculating basic statistical quantities (e.g., mean, median, standard deviation). The mean and median values are well below the Operational DCCL.

Therefore, the survey unit meets the unrestricted release criteria with adequate power as required by the DQOs. The basic statistical quantities for the statistical sample population are provided below in Table 15.

Table 15 - Basic Statistical Quantities for Cs-137 and Co-60 from the Final Status Survey Cs-137 Co-60 Sr-90 Parameter pCi/g pCilg pCilg DCGL,0 p: 4.75E+00 2.29E+00 9.30E-0 1 Minimum Value: -5.53E-03 -3.72E-02 -2.41E-02 Maximum Value: 6.61E-01 6.24E-01 4.03E-02 Mean: 7.63E-02 4.2 1E-02 -1.36E-03 Median: 5.61E-02 8.20E-03 -2.49E-03 Standard Deviation: 1.65E-01 1.23E-01 1.84E-02 Revision 0 31

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD For Cs-137, the range of the data, about four (4) standard deviations, was not a particularly large variation considering that the levels were essentially at existing environmental levels where such variation is to be expected. The difference between the mean and median was about 12% of the standard deviation which indicates some skewness in the data. The data was represented graphically through posting plots, a frequency plot, and a quantile plot. The frequency plot indicates positive skewness as confirmed by the calculated skew of 3.96.

For Co-60, the range of the data, about five (5) standard deviations, was not a particularly large variation considering that the levels were essentially at existing environmental levels where such variation is to be expected. The difference between the mean and median was about 28% of the standard deviation which indicates some skewness in the data. The data was represented graphically through posting plots, a frequency plot, and a quantile plot. The frequency plot indicates positive skewness as confirmed by the calculated skew of 4.39.

For Sr-90, the range of the data, about four (4) standard deviations, was not a particularly large variation considering that the levels were essentially at existing enviromnmental levels where such variation is to be expected. The difference between the mean and median was about 61% of the standard deviation which indicates some skewness in the data. The data was represented graphically through posting plots, a frequency plot, and a quantile plot. The frequency plot indicates positive skewness as confirmed by the calculated skew of 1.43.

The other radionuclides of concern, H1-3, Eu-154 and Am-241, although included in the FSS plan for compliance purposes, were positively identified (i.e., a result greater than two (2) standard deviations uncertainty) in one (1), none and five (5) of the thirty-two (32) samples collected for non-parametric statistical testing, respectively. H-3, Eu-154 and Am-241 were de-selected based on the criteria discussed in Section 4. Data assessment and graphical representation of these radionuclides was not considered useful given the limited number of data points to represent the distribution.

All data, assessments, and graphical representations are provided in Attachment 3.

12. ANOMALIES No anomalies were noted.

13. CONCLUSION Subsurface soil Survey Unit 980 1-0000 has met the final DQOs of the FSS plan.

The ALARA criteria for soils as specified in Chapter 4 of the LTP were achieved.

Elevated Measurement Comparison was not required.

For this survey unit, Cs-137, Co-60 and Sr-90 were used for statistical testing to determine the adequacy of the FSS.

Revision 0 332

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD The sample data passed the Sign Test. The null hypothesis was rejected. The survey unit is properly designated as Class A.

Compass was not used to determine the adequacy of the survey unit because Survey Unit 9801-0000 is a subsurface Class A survey unit and that does not conform to the Compass model parameters. However, the survey unit meets the requirements established in LTP Section 5.7.3.2.2 which states that there will be a minimum of thirty-one (3 1) measurement locations, based on a sample population of approximately one (1) per five hundred (500) M2 in a Class A subsurface soil area. However, thirty-one (31) measurement locations over the surface area identified in this survey unit as approximately fifteen thousand seven hundred and eighty-eight (15,788) M2 would equate to one (1) sample every five hundred and nine (509) in . Since this ratio is larger than the ratio for a Class A subsurface area identified in the LTP, the minimum number of samples to be collected, within this survey unit, was increased to thirty-two (32) measurement locations.

The sample density for Survey Unit 9801-0000 with a sample population of thirty-two (32) measurements over approximately fifteen thousand seven hundred and eighty-eight (15,788) Mn2 is one (1) measurement every four hundred and ninety-three (493) in2 .

The dose contribution from soil is 0.52 inremlyr TEDE based on the average radionuclide concentrations in the samples used for non-parametric statistical sampling.

This survey area is affected by existing groundwater (reference CY memo ISC 06-024); therefore the dose contribution from existing groundwater is bounded at two (2) inreinlyr TEDE.

This survey unit is considered impacted by future groundwater radioactive contamination, as there are underground foundations containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo ISC 06-024). The dose contribution from future groundwater, the third dose component, is bounded by two (2) mrem/yr TEDE.

The average total dose from residual radioactivity in this survey unit, including exposures from the three (3) components as described in Section 3, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity, will not exceed 4.52 inremlyr TEDE. Therefore, Survey Unit 980 1-0000 is acceptable for unrestricted release.

Revision 0 33

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD

14. ATTACHMENTS 14.1 Attachment 1 - Survey Unit Location Map 14.3 Attachment 2 - Laboratory Results 14.4 Attachment 3 - DQA Results Revision 0 34

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD ATTACHMENT 1 (FIGURES)

Revision 0

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Figure 1 Survey Unit 9801 -0000 April2007

& ~Site Map With Reference To

952 7-0005 9312-0010 L Subaurff, S--eymUt 9522-000 7 surf 9312-0005 9312-000 7 9312-0006 --

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Figurr 3Connecticut Yankee Atomic Power Company APRIL 2007CraebyR.Msngl I Subsurface Sample Locations for Survey Unit 9801 -0000 Revsion: 0

I 0.001 0.1619 0.070 0.661 0.055 O.04f Yý- 0.097 0.000 0.048 0.220 0.146 0.017 0.061 O .--

0.049 0.004 0.015 0.025 0.061 0.059 0.078 0.086 0.010 0.068 0.021 0 S08 30f 0.028 0.046 0.016 0.022 0.016

-0.006 0.006 0.124 NAD27C~o~0..a 0.056 0.029 0.015 0.060 0.019 0.012 0.060 9801-0000 I-M Atoic owerComanyAPRIL Connctiut Ynke 2007 Figure4 CnetctYneAtmcPwropayCreated by: R. Massegill I Cesium-J137PostingPlot for Stuvey Unit 9801 -0000 Revision: 0 1

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-0.006 0.014 ,0.002 -0.028 0.022 9801-0000 I-Jý Connecticut Yankee A tomic Power Company APRIL 2007 Figure5 Createdby:- R. Massengill ICobalt-60 PostingPlot for Survey Unit 9801-0000 Revision: 0 d

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD ATTACHMENT 2 (LABORATORY DATA)

Revision 0

U

- The GEL Group 0'712 Jýby Chatles1on, SC 29417T

,ýfk4,:mlge RaM a, Chaistrlf,30 SC 2940?

P 843.556.8171 F843.766.1178 Connecticut Yankee Atomic Power Co.

Soils PO# 002332 Work Order: 183607 SDG: MSR#07-00137 Laboratory ID Client ID 183607001 9801 -0000-003 F 183607002 9801 -0000-005 F 183607003 9801 -0000-006F 183607004 9801 -0000-007 F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 980) -0000-0 1O 183607008 9801 -0000-01 IF 183607009 980 1-0000-0 12F 183607010 9801-0000-01 3F 183607011 980 1-0000-01I3FS 183607012 980 1-0000-0 14F 183607013 980 1-0000-0 15F 1836070M4 9801-0000-01 6F 183607015 9801-0000-01 7F 183607016 980 1I-0000-0189F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 980 1-0000-02 1IF 183607020 9801 -0000-022 F 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 980 1-0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028 F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-03 1 F 183607031 9801-0000-032 F 183607032 9801-0000-033B problem solvedl

183607033 980!1-0000-034B 183607034 980!1-0000-035B 183607035 9801-0000-036B 183607036 980!1-0000-037B 183607037 9801-0000-039B 183607038 980!1-0000-040F 183607039 980!1-0000-041 F 183607040 980!1-0000-042F GEL Laboratories I.LC GEL PO Laoratores Bux 30712LLC Chaftlesn. SC 2WI 17 204OSAvageftac Crnlaosior, SC294ý27 P843.556.8171 F843.766.1178 wwgexr

TABLE OF CONTENTS General Narrative ............................................ 1 Chain of Custody and Supporting Documentation ........ 5 Data Review Qualifier Definitions........................... 16 Radiological Analysis ........................................ 18 Sample Data Summary................................... 66 Quality Control Data ...................................... 188

General Narrative Page I of 205

General Narrative for Connecticut Yankee Atomic Power Co.

Work Order: 183607 SDG: MSR#07-00137 April 09, 2007 Laboratory Identification:

GEL Laboratories LLC 2040 Savage Road Charleston, South Carolina 29407 (843) 556-8171 Summary Sample receipt The samples arrived at GEL Laboratories LLC, Charleston, South Carolina on April 05, 2007 for analysis.

Shipping container temperatures were checked, documented, and within specifications. The samples were delivered with proper chain of custody documentation and signatures. All sample containers arrived without any visible signs of tampering or breakage.

Sample Identification The laboratory received the following samples:

Laboratory Sample Identification Description 183607001 9801 -0000-003F 183607002 9801 -0000-005F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801 -0000-01 OF 183607008 9801 -0000-01 IF 183607009 9801-0000-01 2F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801-0000-014F 183607013 9801-0000-015F 183607014 9801-0000-01 6F 183607015 9801-0000-01 7F 183607016 9801-0000-01 8F 183607017 9801-0000-019F 183607018 9801-0000-020F 183607019 9801-0000-021IF 183607020 9801 -0000-022F 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 9801 -0000-026F GEL Laboratories Pfige 2PNffSa~l 2 Charleon. SC 2,9417 2040 Savage Road Chaeresn, SC 29407 P843.555.171 F8437551178 www.gal.com wgecm

183607026 980 1-0000-027F 183607027 9801-0000-028F 183607028 9801-0000-029F 183607029 9801-0000-030F 183607030 9801-0000-031iF 183607031 9801-0000-032F 183607032 9801-0000-033B 183607033 9801-0000-034B 183607034 9801 -0000-035SB 183607035 9801-0000-036B 183607036 9801 -0000-037B 183607037 9801-0000-039B 183607038 9801 -0000-040F 183607039 9801-0000-041F 183607040 9801 -0000-042F Items of Note The incorrect date was listed on the COC for seven samples. Please see attached email for correction.

Case Narrative Sample analyses were conducted using methodology as outlined in GEL Laboratories, LLC (GEL) Standard Operating Procedures. Any technical or administrative problems during analysis, data review, and reduction are contained in the analytical case narratives in the enclosed data package.

Analytical Reguest Forty soil samples were analyzed for FSSALL.

Data Package The enclosed data package contains the following sections: General Narrative, Chain of Custody and Supporting Documentation, Data Review Qualifier Definitions, and data from the following fractions: Radiochemistry.

Icertify that this data package isincompliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.

Cheryl Jones Project Manager GEL Laboratories fi~ge 3P&P2W~12 Chaileftn, SC 29417 2040 Savage Road CharleSton, SC 29407 P843.r5558171 F 843.755.1178 www.goI.com

List of current GEL Certifications as of 09 April 2007 State Certification Alaska UST-062 Arizona AZ0668 Arkansas 88-0651 CLIA 42DO904046 California 0115]ICA Colorado GenEngLabs Connecticut PH-01 69 Dept. of Navy NFESC 413 EPA WG-15J Florida/NELAP E87 156 Georgia E87 156 (FLINELAP)

Hawaii N/A Idaho N/A Illinois 200029 Indiana C-SC-01 Kansas E-10332 Kentucky 90129 Louisiana 03046 Maryland 270 Massachusetts M-SCOI 2 Michigan 9903 Nevada SCI2 New Jersey SCO02 New Mexico Fl, NELAP E87 156 New York 11501 North Carolina 233 North Carolina Drinking W 45709 North Dakota R-158 Oklahoma 9904 Pennsylvania 68-00485 South Carolina 10120001/10585001/10120002 Tennessee 02934 Texas NELAP T104704235-06-TX U.S. Dept. of Agriculture S-52597 US Army Corps of Engineer N/A Utah 8037697376 GEL Vermont VT87 156 Virginia 00151 Washington jC1641 Page 4 of 205

Chain of Custody and Supporting Documentation Page 5 of 205

Connecticut Yankee Atomic Power Company Chain of Custody FormNo207015 362 Injun Hollow Road, East Hampton, CT 06424 N.20-00 860-267-2556 ______________________________ __________________ _____

Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

JcMcaty860-267-3924 Media Sample Container Jak c~rtyCode Type Size-Analytical Lab (Name, City, State): Code &Type General Engineering Laboratories Code 2040 Savage Road Charleston, SC 29407 ATT: Cheryl Jones ( 843-556-8171)

Priority:E] 30 D. 0i 14 D. Z 7 D. le Other:

Sample Designation Date Time Comment, Preservation Lab Sample ID 9~0 OiFN/A 000 N/A __T=&BP _______

99 i9 0000 001 N/A N/A =T=9 _ ____ 4P x_ __

9801-0000-003F 3/29/07 1000 TS C BP X __

9801 0000 QG44,F N/A N/A __T_9 G___ 4P x ___________

980 1-0000-005F 3/28/07 1135 TS C BP X __ __ ____ _________

9801-0000-006F 3/29/07 0835 TS C BP X __ ____________________

9801l-0000-007F 3/29/07 1105 TS C BP X________________

9801-0000-008F 3/29/07 1430 TS C BP X __ _________

980 1-0000-009F 3/30/07 0745 TS C BP X __ __ _________

9801-0000-OlOF 3/28/07 1408 TS C BP X __ __

9801-0000-OIIF 3/29/07 0815 1TS C BP ]X ___ ______ _________

NOTES: P0 #: 002332 MSR #: 07-00 13 7 Z LTP QA Ii] Radwaste QA EL Non QA Samples Shipped Via: Internal Container Z Fed Ex Temp.: ___ Deg. C El] UPS

________________________________ _________________________________ MF Hand Custody Sealed?

1) Re] ate/Time P*qi~y 2) Recei d By Date/Time Custody Seal intact?

y/y ~ ~ E Other

3) Relinquished By Date/Time 4) Recgled By bAe/Tim'e __________ YO] NO I Bill of Lading #

5) Relinquished By Date/Time 16) Received By Date/Time

Connecticut Yankee Atomic Power Company Chain of Custody Form N.20-00 362 Injun Hollow Road, East Hampton, CT 06424 N.20-00 860-267-2556 ___________________________

Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

Jack McCarthy 860-267-3924 Media Sample Container

_________________________________ Code Type Size-Analytical Lab (Name, City, State). Code &Type General Engineering Laboratories Code 2040 Savage Road Charleston, SC 29407 ATT: Cheryl Jones ( 843-556-8171)

Priority:E]i 30 D. Ei] 14 D. E 7 D.

Other:____ __

Sample Designation Date Time Comment. Preservation Lab Sample ID 98010000012 3/2/07 330 TS C BP 9801-0000-013F 3/29/07 1330 TS C BP X 9801-0000-013FS 3/29/07 1530 TS C B3P X 9801-0000-014FS 3/29/07 1053 TS C BP X 9801-0000-015F 3/30/07 1035 TS C BP X ___

9801-0000-016F 4/2/07 1125 TS C BP X 9801l-0000-017F 4/28/07 11445 TS C BP X __

9801-0000-018F 3/28/07 1450 TS C BP X 9801-0000-019F 3/29/07 07250 T C BP- X _____________

9801-0000-029F 3/30/07 10725 TS C B3P X __ __ _________

9801-0000-021F 3/30/07 1000 TS C BP X __ _________

NOTES: P0 #: 0023 32 MSR #: 07-0013 7 LIP QA D1 Radwaste QA DNon QA Samples Shipped Via: Internal Container M Fed Ex Temp.: ___ Deg. C Elup Custody Sealed?

1) Relin~ ~ ,> 1 ate/Tinie 2) heived B Date/Time LIHand Custody Seal Intact?

3) Relinquished By Date/Time 4) ýceived By bate/Time Bill__ofLading __# YfIJ N 0

5) Relinquished By Date/Time 6)Received By Date/Time

Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2007-00107 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 ______________________

Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments:

Jack McCarthy 860-267-3924 Media Sample Container

_________________________________ Code Type Size-Analytical Lab (Name, City, State): Code &Tvpe General Engineering Laboratories Code 2040 Savage Road Charleston, SC 29407 ATT: Cheryl Jones ( 843-556-8171)

Priority: 0i 30 D.LI 14 D. E7D.

Other:_____ __

Sample Designation Date Time CnComment, Preservation Lab Sample ID 980 1-0000-022F 4/2/07 1100 TS C BP X___

980 1-0000-022FS 4/2/07 1100 TS C BP X _____ _____________

9801-0000-023F 4/2/07 1255 TS C BP X_________

9801-0000-024F 4/2/07 1515 TS C BP X___________

9801-0000-025F 3/30/07 0940 TS C BP X __

9801-0000-026F 3/30/07 1255 TS C BP X_________

980 1-0000-027F 4/2/07 1355 TS C BP X ________

9801-0000-028F 4/2/07 1342 TS C BP X ________

9801-0000-029F 3/30/07 0825 TS C B3P X 9901-0000-030F 4/2/07 1456 TS C BP X _____ __ _________

9801-0000-031F 4/2/07 1412 TS C BP X ____________________

NOTES: PO #: 002332 MSR #: 07-00 137 Z LTP QA 0i Radwaste QA EII Non QA Samples Shipped Via: Internal Container H Fed Ex Temp.: ___ Deg. C L] ups

____ ____ ____ ____ ___ ____ ____ ____ ___ ___ ustoy aSeled 1)Re Date/Time 2) Recei d By Date/Time LIHand Custody Seal Intact?

3) Relinquished By Date/Time 4) Rec led By 1ate/Time Bill___ofLading _ YLE NE

5) Relinquished By Date/Time 6) Received By Date/Time

Connecticut Yankee Atomic Power Company Chain of Custody Form N.20-00 362 Injun Hollow Road, East Hampton, CT 06424 N.20-00 860-267-2556 ____ ____

Project Name: Haddam Neck Decommissioning ___ Analyses Requested Lab Use Only Contact Name & Phone: Comments:

JcMcaty860-267-3924 Media Sample Container Jak c~rtyCode Type Size-Analytical Lab (Name, City, State): Code &Type General Engineering Laboratories Code 2040 Savage Road Charleston, SC 29407 ATT: Cheryl Jones ( 843-556-8171)

Priority:F130D. D 14 D. Z 7 D.

Other:

Sample Designation Date Time Comment, Preservation Lab Sample ID 9801-0000-032F 4/2/07 1442 TS C BP X ________

9801-0000-033B 4/28/07 1328 TS C BP X __ _____________

980 1-0000-034B 4/29/07 1125 TS C BP X ___________

9801-0000-035B 4/29/07 1400 TS C BP X ________ ____________

9801-0000-036B 4/29/07 1445 TS C BP X ____________

9801-0000-037B 4/30/07 1240 TS C BP X __

980i go00) 034B __101_ gig4 T__& 1___ 4P_ 9x_________

9801-0000-039B 4/3/07 0740 TS C B3P X __ __

980 1-0000-040F 4/3/07 0752 TS C BP X __

9801-0000-041F 4/3/07 0952 TS C BP X __________________

980 1-0000-042F 4/3/07 0825 TS C_ BP X _____________________

NOTES: P0 #I: 002332 MSR #:07-00137 LTP QA [I Radwaste QA F] Non QA Samples Shipped Via: Internal Container Z Fed Ex Temp.: ___ Deg. C EnUP Custody Sealed?

1) R in hed By Qatj/Time 2) ~ceivel Bqyri/ Date/Time El Hand Custody Seal Intact?

p~~~~~~~l~E

_ _ _ _ __ _ _ _ _ _ _ _ Other

3) Relinqui~hed. By Dalte/Time 40)ceived By t bat'e/Time Bill__ofLading __ YOI NO

5) Relinquished By Date/Time 6) Received By Date/Time

Connecticut Yankee Statement of Work for Analytical Lab Services .Cy-Isc-Sow-ool Figure 1. -Sample Check-in List.

DateiTime Received: 1/116?.

• SDG#: c)O13-+

Work Order Number: _ ~ ~~Y Shipping CicAtaincr ID: .eei colk '5aL'ee ChainOf CUStody # e CUOA4-' 4~ee J-

1. Custody Seals od shipping container intact?.. -Yes, LNo [

2. Custody Seals dated and. signed? Yes*(.)i No [

3. Chain-of-Custody record present? Yes [A No I I

4. Cooler temperature L e nE.,e.I 5.. Vermiculitelpacking materials -is: Wet []Dry hi 6:' Number of samples in shipping container, 'IC

7. Sample holding times ex~ceeded?Ye[1N

ý8. Samples have.

-ý1tape hazard labels

..k-custody seals -, appropriate sample lbl are; Samples-L ngood condition leaking 19.

broken-have air bubbles

10. Were any anomalies identified in sample receipt? Yes [JNo PV*

I I... Description of anomalies. (include sample numbers):

Sample Csoiwaoaoy. Dato~

Telephoned to:____________ By Page 10 of205- 1,5 0~

SAMPLE RECEIPT & REVIEW FORM PM use only Client: ~ .A$ .SDG/ARCOC/Work Order: 3LO Date Received: ~ 3PM(A) Review (ensure non-confo igtes are resoilved prior to signing):

Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforming Items)

Circle Applicable: seals broken damaged container leaking container other (describe)

Iý Shipping containers received tWact and sealed?

Sa es requiring cold Circle Coolant # ice bags blue ice dry ice none other describe) 2 pre--serv on within (4 +/- 2 C)?

-Record pre ation method.___________________________

3Chain of custo' documents lincluded with sh~i t?___________________________

Crcle Applicable: seals broken damaged container leaking container other (describe) 4 iSample containers intc ýnd sealed?

5Samples requiring chemical N. Sample JD's. containers affected and observed pH:

preservation at proper pH? ____________________________

6 VOA vials free of headspace Sample ID's and containers affected:

-(defined as < 6mm bubble)?___________________________

Are Encore containers present?

7 (If yes, immediately deliver to 1VOA laboratory 8Samples received within holding Id's and tafetd affected:

9Sample ID's on COC match ID's Sample ID's and contai on bottles?

10Date & time on COC match date Sample ID's affected:

10& time on bottles?

Number of containers received Sample ID's affected:

match number indicated on COC?

12 COC form is properly signed in

__ relinquished/received sections?

14 Air Bill ,Tracking #'s, &

Additional Comments o'u ~RSO RAD Receipt # _____________

Suspcte haard nfomatcc *If > x2 area background is observed on samples identified as "non-u Z regulated/non-radioactive", contact the Radiation Safety group for further Sinvestigation.

A Radiological Classification? Maximum Counts Observed*` '2ýO C-PI T PCB Regulated?

Shipped as D07 Hazardous--

C Material? If yes, contact Waste A'Hazard UN#:

Class Shipped:

IManager or ESH Manager.

Ek Regulated as a Foreign Soil?

PM (or Pft 4NljWfMfJazar classification:

b Initials Date:

11

SAMPLE RECEIPT & REVIEW FORM

-.1 w

CONTINUATION FORM 0

"I-i 1 ~ 5f o~-

rit:\1A ItJ (A Date Received: Page -L of -

7`4144j3-)'1065- ~~

CoC L 4-Z? o-7.- 0010-Page 12 of 205

Subject:

RE: Sub surface area 9801-0000 From: "Rick E. Gault" <Gault@CYAPCO.com>

Date: Wed, 4 Apr 2007 15:22:35 -0400 To: "Cheryl Jones" <cj ~ge1.com>

Thanks for the catch Cheryl. This should be March dates for those samples you identified.

Please use this email as authorization to make a pen and ink change to COC 07-00108 sent with the shipment for samples 9801-0000-33B,34B,35B,36B & 37B.

Thanks for identifying this mistake; Rick

--- Original Message ---

From: Cheryl Jones [mailto:cj@gel.coml Sent: Wednesday, April 04, 2007 3:00 PM To: Rick E. Gault

Subject:

Re: Sub surface area 9801-0000

Rick, On the attached COG 2007-00108, the collect date listed for samples 9801-0000-033B through -037B appear to be incorrect (late April) . Can you confirm that these should be March dates or send a corrected COC?

Thanks, Cheryl Rick E. Gault wrote:

Cheryl; We're sending 40 samples under MSR 07-0137 to GEL today. All of the samples have a 7 day TAT request. It is acceptable for GEL to use the traced/untraced Tc-99 process for these quick TAT requests. See attached COC for requested analyses.

Also if you could send up a few coolers for future shipments it would be appreciated, about 4 would be enough for now.

Thanks Rick Gault CYAPCO 860-267-3903 Cheryl A. Jones Project Manager/PM Team Leader GEL Laboratories, LLC 2040 Savage Road Charleston, SC (USA) 29407 Direct: 843.769.7388 Main: 843.556.8171 x 4243 Fax: 843.766.1178 E-mail: cj@gel.com Web: www.gel.com The information contained in this message is confidential and is Page 13 of 205

intended only for the use of the individual or firm of record. If you are not the intended recipient and have received this message in error, you are asked not to copy or distribute any of the pages that follow. Please notify the sender immediately by telephone or email if you have received this communication in error and destroy the contents that do not pertain to your business with The GEL Group, INC.

Content-Description: COC 2007-00108_9801.doc COC 2007-00108_9801 .doc'l Content-Type: application/msword Content-Encoding: base64 Page 14 of 205

Subject:

Sub surface area 9801-0000 From: "Rick E. Gault" <Gault@CYAPCO.com>

Date: Wed, 4 Apr 2007 11:06:26 -0400 To: "Cheryl Jones" <cj~ge1.com>

Cheryl; We're sending 40 samples under MVSR 07-0137 to GEL today. All of the samples have a 7 day TAT request. It is acceptable for GEL to use the traced/untraced Tc-99 process for these quick TAT requests. See attached COC for requested analyses.

Also if you could send up a few coolers for future shipments it would be appreciated, about 4 would be enough for now.

Thanks Rick Gault CYAPCO 860-267-3903 COC Content-Description: 0_00_00_00_00.d COC~0 07_00105_00106_0107 00108.pdf Content-Type: applicationloctet-streamn Content-Encoding: base64 Page 15 of 205

Data Review Qu'alifier Definitions Page 16 of 205

Data Review Qualifier Definitions Qualifier Explanation

• A quality control analyte recovery is outside of specified acceptance criteria

• • Analyte is a surrogate compound c Result is less then value reported

> Result is greeter than value reported ARPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank B Metals-Either presence of analyte detected in the associated blank, or MDL/IDL < sample value c PQL BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by CC/MS analysis D Results are reported from a diluted aliquot of the sample d S-day DOD-The 2:1 depletion requirement was not met for this sample E Organics-Concentration of the target analyte exceeds the instrument calibration range E Metals-%difference of sample and SD is >10%. Sample concentration must meet flagging criteria H Analytical holding time was exceeded h Preparation or preservation holding time was exceeded J Value is estimated N Metals-The Matrix spike sample recovery is not within specified control limits N Organics-Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC) . Quantitation is based on nearest internal standard response factor N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the reporting limit DI Gamma Spectroscopy-Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound Z Paint Filter Test-Particulates passed through the filter, however no free liquids were observed.

GEL Laboratories R1 ge 1'JO&9prI 2 Charleston, Sc 29417 2040 Savage Road Charlesto, SC 29407 P843.555.8171 F843.785.1178 www.gel.com

RADIOLOGICAL ANALYSIS Page 18 of 205

Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)

Work Order 183607 Method/Analysis Information Product: Aiphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623058 Prep Batch Number: 623036 Dry Soil Prep GL-RAD-A-021 Batch Number: 623034 Sample ID Client ID 183607001 9801 -0000-003F 183607002 9801 -0000-005F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801 -0000-01IOF 183607008 9801 -0000-01 IF 183607009 9801-0000-01 2F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801-0000-01 4F 183607013 9801-0000-015SF 183607014 9801-0000-01 6F 183607015 9801-0000-01 7F 183607016 9801-0000-018F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 9801 -0000-021iF 183607020 9801-0000-022F 1201309427 Method Blank (MB) 1201309428 183607001(9801 -0000-003F) Sample Duplicate (DUP) 1201309429 183607001(9801 -0000-003F) Matrix Spike (MS) 1201309430 Laboratory Control Sample (LCS)

Page 19 of 205

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0 11 REV# 15.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607001 (9801-0000-003F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 183607002 (9801-0000-005F), 183607009 (9801-0000-.012F), 183607011 (9801-OOO0-013FS) and 183607018 (9801-0000-020F) were recounted due to a suspected false positive.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Page 20 of 205

Additional Comments Additional comments were not required for this sample set.

Oualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Aiphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 624198 Prep Batch Number: 623039 Dry Soil Prep GL-RAD-A-021 Batch Number: 623038 Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025 F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-031 F 183607031 9801 -0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801 -0000-035B 183607035 9801 -0000-036B 183607036 9801 -0000-037B 183607037 9801 -0000-039B 183607038 9801 -0000-040F 183607039 9801-0000-041F 183607040 9801 -0000-042F 1201312041 Method Blank (MB) 1201312042 183607021(9801 -0000-022FS) Sample Duplicate (DUP) 1201312043 183607021(9801 -0000-022FS) Matrix Spike (MS) 1201312044 Laboratory Control Sample (LCS)

Page 21 of 205

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-O1 1 REV# 15.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Ouality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607021 (9801-O0O0-022FS).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 183607035 (9801-0000-03613) was recounted due to a suspected false positive. Samples were reprepped due to low/high carrier/tracer yield.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Page 22 of 205

Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Aiphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- I I-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623060 Prep Batch Number: 623036 Dry Soil Prep GL-RAD-A-021 Batch Number: 623034 Sample ID Client ID 183607001 9801 -0000-003F 183607002 9801 -0000-005F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801-0000-008F 183607006 9801 -0000-009F 183607007 9801-0000-01 OF 183607008 9801-0000-01 IF 183607009 9801-0000-01 2F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801 -0000-014F 183607013 9801-0000-015F 183607014 9801-0000-01 6F 183607015 9801-0000-01 7F 183607016 9801-0000-01 8F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 9801-0000-021 F 183607020 9801 -0000-022F 1201309431 Method Blank (MB) 1201309432 183607001(9801 -0000-003F) Sample Duplicate (DUP) 1201309433 183607001(9801 -0000-003F) Matrix Spike (MS) 1201309434 Laboratory Control Sample (LCS)

Page 23 of 205

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-O1 1 REV# 15.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607001 (9801-0000-003F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Page 24 of 205

Oualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- II-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623061 Prep Batch Number: 623036 Dry Soil Prep GL-RAD-A-021 Batch Number: 623034 Sample ID Client ID 183607001 9801 -0000-003F 183607002 9801 -0000-005F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801-0000-OlOF 183607008 9801-0000-01 IF 183607009 9801-0000-012F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801-0000-014F 183607013 980 1-0000-015F 183607014 9801-0000-016F 183607015 9801-0000-017F 183607016 9801-0000-01 8F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 9801-0000-021F 183607020 9801 -0000-022F 1201309435 Method Blank (MB) 1201309436 183607001(9801 -0000-003F) Sample Duplicate (DUP) 1201309437 183607001(9801 -0000-003F) Matrix Spike (MS) 1201309438 Laboratory Control Sample (LCS)

SOP Reference Page 25 of 205

Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 9.

Calibratio~n Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume isrepresentative of the sample volume inthis batch.

Designated QC The following sample was used for QC: 183607001 (9801-0000-003F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 1201309436 (9801-0000-003F), 1201309437 (9801-0000-003F), 1201309438 (LCS),

183607001 (9801 -0000-003F), 183607002 (9801 -0000-005F), 183607003 (9801 -0000-006F),

183607004 (9801 -0000-007F), 183607005 (9801 -0000-008F), 183607006 (9801 -0000-009F),

183607007 (9801-0000-01lOF), 183607008 (9801-0000-011IF), 183607009 (9801-0000-012F),

183607010 (9801-0000-013F), 183607011 (9801-0000-013FS), 183607012 (9801-0000-014F),

183607013 (9801-0000-015F), 183607018 (9801-0000-020F), 183607019 (9801-0000-021F) and 183607020 (9801-0000-022F) were recounted due to the quench number being outside the calibration range.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Page 26 of 205

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Aiphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- II-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623063 Prep Batch Number: 623039 Dry Soil Prep GL-RAD-A-021 Batch Number: 623038 Page 27 of 205

Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801-0000-025F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-031 F 183607031 9801 -0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801 -0000-035B 183607035 9801 -0000-036B 183607036 9801 -0000-037B 183607037 9801 -0000-039B 183607038 9801 -0000-040F 183607039 9801 -0000-041iF 183607040 9801 -0000-042F 1201309443 Method Blank (MB) 1201309444 183607023(9801 -0000-024F) Sample Duplicate (DUP) 1201309445 183607023(9801 -0000-024F) Matrix Spike (MS) 1201309446 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0l1 IREV# 15.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607023 (980 1-0000-024F).

Page 28 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- II-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623064 Prep Batch Number: 623039 Dry Soil Prep GL-RAD-A-021 Batch Number: 623038 Page 29 of 205

Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 9801-0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-031F 183607031 9801 -0000-032F 183607032 9801 -0000-033B 183607033 9801-0000-034B 183607034 9801 -0000-035B 183607035 9801 -0000-036B 183607036 9801-0000-037 B 183607037 9801 -0000-039B 183607038 9801 -0000-040F 183607039 9801-0000-041F 183607040 9801 -0000-042F 1201309447 Method Blank (MB) 1201309448 183607023(9801-0000-024F) Sample Duplicate (DUP) 1201309449 183607023(9801-0000-024F) Matrix Spike (MS) 1201309450 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 9.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607023 (9801-0000-024F).

Page 30 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 183607032 (9801-0000-033B) was recounted due to missing count. Sample 183607034 (980 1-0000-035B) was recounted due to high MDA.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Manual Integration No manual integrations were performed on data in this batch.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Analytical Method: EML HASL 300, 4.5.2.3 Prep Method: Dry Soil Prep Analytical Batch Number: 623177 Prep Batch Number: 623034 Page 31 of 205

Sample ID Client ID 183607001 9801 -0000-003F 183607002 9801 -0000-005F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801 -0000-01 OF 183607008 9801-0000-01 IF 183607009 9801 -0000-012F 183607010 9801-0000-013F 183607011 9801-0000-013FS 183607012 9801 -0000-014F 183607013 9801-0000-015SF 183607014 9801-0000-01 6F 183607015 9801-0000-01 7F 183607016 9801-0000-018F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 9801-0000-021F 183607020 9801 -0000-022F 1201309684 Method Blank (MB) 1201309685 183607003(9801 -0000-006F) Sample Duplicate (DUP) 1201309686 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 3 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607003 (980 1-0000-006F).

Page 32 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Page 33 of 205

Qualifier Reason Analyte Sample U' Data rejected due to interference. Europiumn- 155 183607016 U' Data rejected due to low abundance. Bismuth-2 12 183607005 183607008 183607009 183607010 183607012 183607013 183607016 183607018 Bismuth-2 14 183607017 183607018 Cesium- 134 183607004 183607007 183607008 183607009 183607011 183607012 183607014 183607019 Cobalt-60 183607005 Potassium-40 183607018 U' Data rejected due to no valid peak. Cesium- 137 183607004 Method/Analysis Information Page 34 of 205

Product: Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Analytical Method: EML HASL 300, 4.5.2.3 Prep Method: Dry Soil Prep Analytical Batch Number: 623178 Prep Batch Number: 623038 Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801-0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 980 1-0000-031iF 183607031 9801 -0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801 -0000-035B 183607035 9801 -0000-036B 183607036 9801 -0000-037 B 183607037 9801 -0000-039B 183607038 9801 -0000-040F 183607039 9801 -0000-041F 183607040 9801 -0000-042F 1201309687 Method Blank (MB) 1201309688 183607023(9801-0000-024F) Sample Duplicate (DUP) 1201309689 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-0 13 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Page 35 of 205

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Ouality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607023 (9801-0000-024F).

QC Information All of the QC samples met the required acceptance limits.

Technrical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 183607022 (9801 -0000-023F) and 183607029 (9801-0000-030F) were recounted due to a peak shift.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments The sample and the duplicate, 1201309688 (9801-0000-024F) and 183607023 (9801-0000-024F), did not meet the relative percent difference requirement for Ac-228, however they do meet the relative error ratio requirement with value of 1.65.

Qualifier information Page 36 of 205

Qualifier Reason Analyte Sample U' Data rejected due to interference. Europium- 155 183607031 Manganese-54 183607025 U' Data rejected due to low abundance. Americium-241 1201309688 Bismuth-2 12 183607021 183607022 183607024 183607026 183607032 183607038 Cesium- 134 183607023 183607026 183607027 183607028 183607030 183607034 183607040 Niobium-94 1201309688 Method/Analysis Information Product: GFPC, Sr9O, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623055 Prep Batch Number: 623036 Dry Soil Prep GL-RAD-A-021 Batch Number: 623034 Page 37 of 205

Sample ID Client ID 183607001 9801 -0000-003F 183607002 9801 -0000-005F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801 -0000-01 OF 183607008 9801-0000-01 IF 183607009 9801-0000-01 2F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801-0000-01 4F 183607013 9801-0000-015F 183607014 9801-0000-01 6F 183607015 9801-0000-01 7F 183607016 9801 -0000-018F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 9801-0000-021F 183607020 9801 -0000-022F 1201309415 Method Blank (MB) 1201309416 183607002(9801 -0000-005F) Sample Duplicate (DUP) 1201309417 183607002(9801-0000-005F) Matrix Spike (MS) 1201309418 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 11.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607002 (9801-0000-005F).

Page 38 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 183607005 (9801 -0000-008F) was recounted due to a negative result greater than three times the error.

Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: GFPC, Sr9O, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623056 Prep Batch Number: 623039 Dry Soil Prep GL-RAD-A-021 Batch Number: 623038 Page 39 of 205

Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-031F 183607031 9801 -0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801 -0000-035B 183607035 9801 -0000-036B 183607036 9801 -0000-037B 183607037 9801 -0000-039B 183607038 9801 -0000-040F 183607039 9801-0000-041F 183607040 9801-0000-042F 1201309419 Method Blank (MB) 1201309420 183607022(9801-0000-023F) Sample Duplicate (DUP) 1201309421 183607022(9801-0000-023F) Matrix Spike (MS) 1201309422 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 11.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607022 (9801-0000-023F).

Page 40 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 183607026 (9801-0000-027F) and 183607030 (9801-0000-031IF) were recounted due to a negative result greater than three times the error.

Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 623185 Page 41 of 205

Sample ID Client ID 183607001 9801 -0000-003F 183607002 9801 -0000-005F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801-0000-OlOF 183607008 9801-0000-0 1iF 183607009 9801 -0000-012F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801-0000-014F 183607013 9801-0000-015F 183607014 9801-0000-01 6F 183607015 9801-0000-017F 183607016 9801-0000-01 8F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 9801-0000-021F 183607020 9801 -0000-022F 1201309714 Method Blank (MB) 1201309715 183607001(9801-0000-003F) Sample Duplicate (DUP) 1201309716 183607001(9801 -0000-003F) Matrix Spike (MS) 1201309717 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607001 (9801-0000-003F).

Page 42 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellanjeous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 623187 Page 43 of 205

Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801-0000-024F 183607024 9801 -0000-025F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-031 F 183607031 9801-0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801 -0000-035B 183607035 9801 -0000-036B 183607036 9801-0000-037 B 183607037 9801 -0000-039B 183607038 9801 -0000-040F 183607039 9801-0000-041F 183607040 9801 -0000-042F 1201309718 Method Blank (MB) 1201309719 183607022(9801 -0000-023F) Sample Duplicate (DUP) 1201309720 183607022(9801-0000-023F) Matrix Spike (MS) 1201309721 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607022 (9801-0000-023F).

Page 44 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 1201309721 (LCS) was recounted due to a missing count.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Oualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-I, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623181 Prep Batch Number: 623036 Dry Soil Prep GL-RAD-A-021 Batch Number: 623034 Page 45 of 205

Sample ID Client ID 183607001 9801-0000-003F 183607002 9801 -0000-005F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801-0000-OlOF 183607008 9801-0000-01 IF 183607009 9801l-0000-012F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801-0000-014F 183607013 9801-0000-015F 183607014 9801-0000-01 6F 183607015 9801-0000-01 7F 183607016 9801-0000-018F 183607017 9801-0000-019F 183607018 9801 -0000-020F 183607019 9801-0000-021F 183607020 9801 -0000-022F 1201309698 Method Blank (MB) 1201309699 183607001(9801 -0000-003F) Sample Duplicate (DUP) 1201309700 183607001(9801 -0000-003F) Matrix Spike (MS) 1201309701 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 4.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualfty Control (OC) Information:

Blank Information The blank volume is representative of the sample volumes in this batch.

Designated QC The following sample was used for QC: 183607001 (980 1-0000-003F).

Page 46 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 1201309698 (MB), 183607002 (9801-0000-005F), 183607005 (9801-0000-008F),

183607009 (9801-0000-012F), 183607010 (9801-0000-013F) and 183607013 (9801-0000-015F) were recounted due to the quench number being outside the calibration range.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Oualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-i1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623182 Prep Batch Number: 623039 Dry Soil Prep GL-RAD-A-021 Batch Number: 623038 Page 47 of 205

Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-031 F 183607031 9801-0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801-0000-035 B 183607035 9801 -0000-036B 183607036 9801 -0000-037B 183607038 9801-0000-040F 183607039 9801-0000-041F 183607040 9801 -0000-042F 1201309702 Method Blank (MB) 1201309703 183607022(9801 -0000-023F) Sample Duplicate (DUP) 1201309704 183607022(9801-0000-023F) Matrix Spike (MS) 1201309705 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 4.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607022 (9801-0000-023F).

Page 48 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 1201309703 (9801-0000-023F) and 183607022 (9801-0000-023F) were recounted due to high relative percent difference/relative error ratio. Samples 1201309702 (MB), 1201309704 (9801 -0000-023F), 183607021 (9801 -0000-022FS), 183607024 (9801 -0000-025F), 183607026 (9801-0000-027F) and 183607035 (9801-0000-036B) were recounted due to the quench number being outside the calibration range.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-i, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 625732 Prep Batch Number: 623039 Dry Soil Prep GL-RAD-A-021 Batch Number: 623038 Page 49 of 205

Sample ID Client ID 183607037 9801-0000-039B 1201315808 Method Blank (MB) 1201315809 183607037(9801 -0000-039B) Sample Duplicate (DUP) 1201315810 183607037(9801-0000-039B) Matrix Spike (MS) 1201315811 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 4.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Guality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607037 (9801-0000-039B).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 183607037 (9801 -0000-039B) was reprepped due to the quench number being outside the calibration range.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from Page 50 of 205

referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-I, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623183 Prep Batch Number: 623036 Dry Soil Prep GL-RAD-A-021 Batch Number: 623034 Page 51 of 205

Sample ID Client ID 183607001 9801 -0000-003F 183607002 9801 -0000-005 F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801 -0000-OlOF 183607008 9801-0000-01iIF 183607009 9801-0000-01 2F 183607010 9801-0000-013F 183607011 9801-0000-013FS 183607012 9801-0000-0 14F 183607013 9801-0000-015F 183607014 9801-0000-016F 183607015 9801-0000-01 7F 183607016 9801-0000-01 8F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 9801-0000-021 F 183607020 9801 -0000-022F 1201309706 Method Blank (MB) 1201309707 183607003(9801-0000-006F) Sample Duplicate (DUP) 1201309708 183607003(9801 -0000-006F) Matrix Spike (MS) 1201309709 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607003 (9801-0000-006F).

Page 52 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-I, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 623184 Prep Batch Number: 623039 Dry Soil Prep GL-RAD-A-021 Batch Number: 623038 Page 53 of 205

Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-031IF 183607031 9801 -0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801 -0000-035B 183607035 9801 -0000-036B 183607036 9801 -0000-037B 183607037 9801 -0000-039B 183607038 9801 -0000-040F 183607039 9801-0000-041IF 183607040 9801 -0000-042F 1201309710 Method Blank (MB) 1201309711 183607023(9801 -0000-024F) Sample Duplicate (DUP) 1201309712 183607023(9801-0000-024F) Matrix Spike (MS) 1201309713 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (0C) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607023 (980 1-0000-024F).

Page 54 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments The blank result for 12013097 10 (MB) is greater than the MDA but less than the detection limit.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: LSC, Tritium Dist, Solid - 3 pCilg Analytical Method: EPA 906.0 Modified Analytical Batch Number: 623189 Page 55 of 205

Sample ID Client ID 183607001 9801 -0000-003 F 183607002 9801 -0000-005 F 183607003 9801 -0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801 -0000-OIOF 183607008 9801-0000-01 IF 183607009 9801-0000-01 2F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801 -0000-014F 183607013 9801-0000-015F 183607014 9801-0000-016F 183607015 9801-0000-01 7F 183607016 9801-0000-01 8F 183607017 9801-0000-01 9F 183607018 9801 -0000-020F 183607019 9801 -0000-021iF 183607020 9801-0000-022F 1201309722 Method Blank (MB) 1201309723 183607004(9801 -0000-007F) Sample Duplicate (DUP) 1201309724 183607004(9801 -0000-007F) Matrix Spike (MS) 1201309725 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Ouality Control (00 Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607004 (980 1-0000-007F).

Page 56 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 1201309725 (LCS) was recounted due to the quench number being outside the calibration range.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: LSC, Tritium Dist, Solid - 3 pCilg Analytical Method: EPA 906.0 Modified Analytical Batch Number: 623190 Page 57 of 205

Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607028 9801 -0000-029F 183607029 9801 -0000-030F 183607030 9801-0000-031IF 183607031 9801 -0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801 -0000-035B 183607035 9801 -0000-036B 183607036 9801 -0000-037B 183607037 9801 -0000-039B 183607038 9801 -0000-040F 183607039 9801-0000-041 F 183607040 9801 -0000-042F 1201309729 Method Blank (MB) 1201309730 183607024(9801-0000-025F) Sample Duplicate (DUP) 1201309731 183607024(9801 -0000-025F) Matrix Spike (MS) 1201309732 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 14.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607024 (9801-0000-025F).

Page 58 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint C14, Solid All,FSS Analytical Method: EPA EERF C-0OI Modified Analytical Batch Number: 623192 Page 59 of 205

Sample ID Client ID 183607001 9801-0000-003F 183607002 9801 -0000-005F 183607003 9801-0000-006F 183607004 9801 -0000-007F 183607005 9801 -0000-008F 183607006 9801 -0000-009F 183607007 9801 -0000-OlOF 183607008 9801 -0000-01 IF 183607009 9801 -0000-012F 183607010 9801-0000-01 3F 183607011 9801-0000-01 3FS 183607012 9801-0000-014F 183607013 9801-0000-015SF 183607014 9801-0000-016F 183607015 9801 -0000-017F 183607016 9801 -0000-018F 183607017 9801-0000-01 9F 183607018 9801-0000-020F 183607019 9801-0000-021 F 183607020 9801 -0000-022F 1201309733 Method Blank (MB) 1201309734 183607004(9801-0000-007F) Sample Duplicate (DUP) 1201309735 183607004(9801-0000-007F) Matrix Spike (MS) 1201309736 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 9.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Quality Control (OC) Information:

Blank Information The blank volume is representative of the sample volumes inthis batch.

Designated QC The following sample was used for QC: 183607004 (980 1-0000-007F).

Page 60 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Samples 1201309733 (MB), 183607013 (9801-0000-015F), 183607014 (9801-0000-016F),

183607015 (9801-0000-017F), 183607017 (9801-0000-019F), 183607018 (9801-0000-020F),

183607019 (9801-0000-021F) and 183607020 (9801-0000-022F) were recounted due to a negative result greater than three times the error.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint C14, Solid AlI,FSS Analytical Method: EPA EERF C-01 Modified Analytical Batch Number: 623194 Page 61 of 205

Sample ID Client ID 183607021 9801 -0000-022FS 183607022 9801 -0000-023F 183607023 9801 -0000-024F 183607024 9801 -0000-025F 183607025 9801 -0000-026F 183607026 9801 -0000-027F 183607027 9801 -0000-028F 183607029 9801 -0000-030F 183607030 9801-0000-031 F 183607031 9801-0000-032F 183607032 9801 -0000-033B 183607033 9801 -0000-034B 183607034 9801-0000-035B 183607035 9801 -0000-036B 183607036 9801 -0000-037B 183607037 9801 -0000-039B 183607038 9801-0000-040F 183607039 9801 -0000-041iF 183607040 9801 -0000-042F 1201309738 Method Blank (MB) 1201309739 183607024(9801 -0000-025F) Sample Duplicate (DUP) 1201309740 183607024(9801-0000-025F) Matrix Spike (MS) 1201309741 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 9.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Oualitv Control (OC) Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607024 (9801-0000-025F).

Page 62 of 205

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis Sample 183607028 (9801 -0000-029F) was recounted due to the quench number being outside the calibration range.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier information Manual qualifiers were not required.

Method/Analysis Information Product: Liquid Scint C14, Solid All,FSS Analytical Method: EPA EERF C-01 Modified Analytical Batch Number: 625942 Sample ID Client ID 183607028 9801 -0000-029F 1201316378 Method Blank (MB) 1201316379 183607028(9801 -0000-029F) Sample Duplicate (DUP) 1201316380 183607028(9801 -0000-029F) Matrix Spike (MS) 1201316381 Laboratory Control Sample (LCS)

SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in Page 63 of 205

accordance with GL-RAD-A-003 REV# 9.

Calibration Information:

Calibration Information All initial and continuing calibration requirements have been met.

Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).

Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.

Ouality Control (OC Information:

Blank Information The blank volume is representative of the sample volume in this batch.

Designated QC The following sample was used for QC: 183607028 (9801 -0000-029F).

QC Information All of the QC samples met the required acceptance limits.

Technical Information:

Holding Time All sample procedures for this sample set were performed within the required holding time.

Preparation Information All preparation criteria have been met for these analyses.

Sample Re-prep/Re-analysis None of the samples in this sample set required reprep, or reanalysis.

Miscellaneous Information:

NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents. A nonconformance report (NCR) was not generated for this SDG.

Additional Comments Additional comments were not required for this sample set.

Qualifier inlformation Manual qualifiers were not required.

Certification Statement Page 64 of 205

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.

Review Validation:

GEL requires all analytical data to be verified by a qualified data validator. In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.

The following data validator verified the information presented in this case narrative:

Reviewer/Date: j P4C - +

Page 65 of 205

SAMPLE DATA

SUMMARY

Page 66 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report for YANKOO I Connecticut Yankee Atomnic Power Co.

Client SDG: MSR#07-00 137 GEL Work Order: 183607 The Qualifiers in this report are defined as follows:

• A quality control analyte recovery is outside of specified acceptance criteria

• • Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification ND The analyte concentration is not detected above the detection limit.

The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.

This data report has been prepared and reviewed in accordance with GEL Laboratories LLC standard operating procedures. Please direct any questions to your Project Manager, Cheryl Jones.

Reviewed by Page 67 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston 30 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-003F Project: YANKO 1204 Sample ID: 183607001 Client ID: YANKOOlI Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 4.6%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U -0.0468 +/-0.0725 0.0445 +/-0.0726 0.184 pCi/g MXA 04/09/07 1504 623058 Curium-242 U 0.0368 +/-0.0721 0.00 +/-0.0723 0.0998 pCi/g Curium-243/244 U 0.0533 +/-0.0999 0.0445 +/-0.100 0.184 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0406 +/-0.126 0.0888 +/-0.126 0.259 pCi/g MXA 04/09/07 1503 623060 Plutonium-239/240 U -0.0143 +/-0.0198 0.0379 +/-0.0199 0.157 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -3.91 +/-6.73 5.84 +/-6.73 12.3 pCi/g MXA 04/11/07 1633 623061 Rad Gamma Spec Analysis Gamma,Solid~-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.873 +/-0.283 0.0989 +/-0.283 0.198 pCi/g MIHI 04/06/07 1206 623177 Americium-241 U 0.058 +/-0.0471 0.0405 +/-0.0471I 0.0809 pCi/g Bismuth-212 0.472 +/-0.323 0.207 +/-0.323 0.413 pCi/g Bismuth-214 0.679 +/-0.155 0.0508 +/-0.155 0.102 pCi/g Cesium-134 U 0.0682 +/-0.0626 0.0354 +/-0.0626 0.0707 pCi/g Cesium-137 0.0967 +/-0.039 0.0239 +/-0.039 0.0477 pCi/g Cobalt-60 U 0.000441 +/-0.0378 0.0271 +/-0.0378 0.0542 pCi/g Europium-152 U 0.0356 +/-0.0896 0.07 16 +/-0.0896 0.143 pCi/g Europium-154 U -0.0788 +/-0.0996 0.0744 +/-0.0996 0.149 pCi/g Europium-155 U 0.0592 +/-0.0749 0.0693 +/-0.0749 0.139 pCi/g Lead-212 0.631 +/-0.114 0.0394 +/-0.114 0.0788 pCi/g Lead-214 0.812 +/-0.136 0.0488 +/-0.136 0.0976 pCi/g Manganese-54 U 0.0157 +/-0.0316 0.0236 +/-0.03 16 0.0472 pCi/g Niobium-94 U 0.00268 +/-0.0301 0.0256 +/-0.0301 0.05 12 pCi/g Potassium-40 12.9 +/-1.50 0.233 +/-1 .50 0.466 pCi/g Radium-226 0.679 +/-0.155 0.0508 +1-0.155 0.102 pCi/g Silver-108m U 0.0248 +/-0.0273 0.0243 +/-0.0273 0. 0486 pCi/g Thallium-208 0.253 +/-0.0573 0.0264 +/-0.0573 0.0528 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U -0.0114 +/-0.019 0.0179 +/-0.019 0.0422 pCi/g NXL3 04/09/07 1750 623055 Page 68 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr.. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-003F Project: YANK01 204 Sample ID: 183607001 Client ID: YANKOO 1 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U 1.31 +/-1.46 1.18 +1-1.46 2.45 pCi/g AXD2 04/06/07 2331 623189 Liquid Scint C14, Solid All, FSS Carbon- 14 U -0.0896 +/-0.116 0.0992 +/-0.116 0.202 pCi/g AXD2 04/07/07 0821 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 20.4 +/-33.0 22.6 +/-33.1 47.7 pCilg MXPl 04/11/07 0416 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -1.97 +/-6.84 5.80 +/-6.84 12.0 pCi/g MXP1 04/10/07 2329 623183 Liquid Scint Tc99, Solid-ALL ESS Technetium-99 U -0.00876 +/-0.188 0.158 +/-0.188 0.321 pCi/g MXP1 04/11/07 1515 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- II-RC Modified 3 DOE EML HASL-300, Pu- II-RC Modified 4 EML HASL 300,4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-I, Modified 9 DOE RESL Ni-l, Modified 10 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 78 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 87 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 93 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 79 (25%-125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 66 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 75 (25%-125%)

Page 69 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-003F Project: YANK01204 Sample ID: 183607001 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 73 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 70 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certifie2te of AnaIv~i~

Certificate ofAnalvsis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-005F Project: YANKO01204 Sample ID: 183607002 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 28-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 5.23%

Parameter Qualifier Result Uncertainty LC TPU MIDA units DF Analyst Date Time Batch A%

Rad Alpha Spec Analysis Alpl'aspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0646 +/-0.111 0.0473 +/-0.112 0.196 pCi/g MXA 04/10/07 1232 623058 Curium-242 U 0.0205 +/-0.0817 0.0501 +/-0.0818 0.207 pCi/g Curium-243/244 U 0.152 +/-0.186 0.0947 +/-0.187 0.290 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0672 +/-0.103 0.0458 +/-0.103 0.172 pCi/g MXA 04/09/07 1503 623060 Plutonium-239/240 U 0.0153 +/-0.061 0.0374 +1-0.061 0.155 pCi/g Liquid Scint Pu24J1, Solid-ALL FSS Plutonium-241 U -1.49 +/-6.85 5.82 +/-6.85 12.3 pCi/g MXA 04/11/07 1649 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL ESS 226 Ingrowth Waived Actinium-228 0.833 +/-0.255 0.118 +/-0.255 0.235 pCi/g MJH1 04/06/07 1207 623177 Americium-241 U -0.016 +/-0.0684 0.05 13 +/-0.0684 0.103 pCi/g Bismuth-2 12 0.774 +/-0.396 0.273 +/-0.396 0.546 pCi/g Bismuth-214 0.734 +/-0.176 0.0644 +/-0.176 0.129 pCi/g Cesium-I 34 U 0.072 +/-0.080 0.0456 +/-0.080 0.09 1 pCi/g Cesium-i 37 0.0862 +/-0.0566 0.0322 +/-0.0566 0.0644 pCi/g Cobalt-60 U -0.0117 +/-0.0416 0.0337 +/-0.0416 0.0673 pCi/g Europium-152 U -0.101 +/-0.125 0.077 +/-0.125 0.154 pCi/g Europium-154 U 0.0213 +/-0.128 0.104 +/-0.128 0.209 pCi/g Europium-ISS U 0.0642 +/-0.0878 0.0809 +/-0.0878 0.162 pCi/g Lead-212 0.905 +/-0.119 0.0477 +/-0.119 0.0954 pCi/g Lead-214 0.812 +/-0. 159 0.0595 +/-0.159 0.119 pCi/g Manganese-54 U 0.0187 +/-0.0427 0.0382 +/-0.0427 0.0763 pCi/g Niobium-94 U 0.00513 +/-0.0362 0.0308 +/-0.0362 0.0616 pCi/g Potassium-40 12.6 +/-1.56 0.3 11 +/-1.56 0.621 pCi/g Radium-226 0.734 +/-0.176 0.0644 +/-0.176 0.129 pCi/g Silver-108m U 0.01 63 +/-0.0426 0.0276 +/-0.0426 0.0552 pCi/g Thallium-208 0.304 +/-0.0721 0.030 +/-0.0721 0.0601 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL ESS Strontium-90 U -0.0241 +/-0.0185 0.0188 +/-0.0185 0.0426 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 71 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-005F Project: YANK01204 Sample ID: 183607002 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.0565 +/-1.35 1.13 +1-1.35 2.36 pCi/g AXD2 04/07/07 0034 623189 Liquid Scint 014, Solid A~lFSS Carbon-14 U -0.129 +/-0.107 0.0917 +/-0.107 0.187 pCi/g AXD2 04/07/07 0925 623192 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U -19.2 +/-33.4 24.1 +/-33.4 50.6 pCi/g MXPI 04/11/07 1333 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -6.55 +/-6.40 5.57 +/-6.40 11.5 pCi/g MXP1 04/11/07 0001 623183 Liquid Scint Tc99, Solid-ALL ESS Technetium-99 U -0.209 +/-0.279 0.236 +/-0.279 0.479 pCi/g MXPI 04/11/07 1638 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-I l-RC Modified 4 DOE EML HASL-300, Pu- Il-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-i, Modified 10 DOE RESL Fe-i, Modified I1I DOE RESL Ni-l, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 78 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 83 (15%-I125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 94 (25%-125%)

(25%-I125%)

Page 72 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-005F Project: YANK01204 Sample ID: 183607002 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Strontium Carrier GFPC, Sr90, solid-ALL FSS 84 Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 76 (15%-I 25%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 75 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 48 (15%-I125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 73 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Cprtifiert o An21v~i~

Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 980 1-0000-006F Project: YANKI1204 Sample ID: 183607003 Client ID: YANKOOI Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 7.47%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U 0.0847 +/-0.114 0.0413 +/-0.115 0.171 pCi/g MXA 04/09/07 1504 623058 Curium-242 U 0.026 +/-0.069 0.0307 +/-0.0691 0.154 pCi/g Curium-243/244 U -0.00782 +/-0.0657 0.0293 +/-0.0658 0.147 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0103 +/-0.0983 0.0768 +/-0.0983 0.241 pCi/g MXA 04/09/07 1503 623060 Plutonium-239/240 U 0.00905 +/-0.0686 0.0503 +/-0.0686 0.188 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -2.91 +/-7.06 6.07 +/-7.06 12.8 pCi/g MXA 04/11/07 1706 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.15 +/-0.303 0.114 +/-0.303 0.228 pCi/g MJHI 04/06/07 1208 623177 Americium-241 U 0.046 +/-0.052 0.0432 +/-0.052 0.0863 pCi/g Bismuth-212 0.674 +/-0.407 0.235 +/-0.407 0.469 pCi/g Bismuth-214 0.947 +/-0.164 0.05 15 +/-0.164 0.103 pCi/g Cesium-134 U 0.0698 +/-0.057 0.0415 +/-0.057 0.083 pCi/g Cesium-137 U 0.0593 +/-0.0412 0.0398 +/-0.0412 0.0795 pCilg Cobalt-60 U 0.0119 +/-0.043 6 0.0378 +/-0.0436 0.0756 pCi/g Europium- 152 U -0.0263 +/-0.0981 0.0729 +/-0.0981 0.146 pCi/g Europium-154 U 0.0706 +/-0.127 0.114 +/-0.127 0.227 pCi/g Europium-iSS U 0.0544 +/-0.109 0.0676 +/-0.109 0.135 pCi/g Lead-212 0.869 +/-0.113 0.037 +/-0.113 0.074 pCi/g Lead-214 0.923 +/-0.159 0.0548 +/-0.159 0.110 pCi/g Manganese-54 U 0.00548 +1-0.0367 0.0323 +/-0.0367 0.0645 pCi/g Niobium-94 U -0.0 107 +/-0.0308 0.0261 +/-0.0308 0.0522 pCilg Potassium-40 13.1 +/-1.40 0.242 +/-1.40 0.484 pCi/g Radium-226 0.947 +/-0.164 0.05 15 +/-0.164 0.103 pCi/g Silver-108m U -0.023 3 +/-0.0309 0.0252 +/-0.0309 0.0504 pCi/g Thallium-208 0.336 +/-0.0864 0.0301 +/-0.0864 0.0602 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U -0.0172 +/-0.0178 0.017 +/-0.0178 0.0382 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 74 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr, Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 980 1-0000-006F Project: YANK01 204 Sample ID: 183607003 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Rad Liquid Scintillation Analysis ISC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.359 +/-1.42 1.20 +/-1.42 2.50 pCi/g AXD2 04/07/07 0136 623189 Liquid Scint C14, Solid All, FSS Carbon-14 U -0.0437 +/-0.112 0.0943 +/-0.112 0.192 pCi/g AXD2 04/07/07 1029 623192 Liquid Scint FeSS, Solid-ALL ESS Iron-55 U 25.0 +/-28.0 19.0 +/-28.0 40.2 pCi/g MXPI 04/11/07 0449 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 3.24 +/-7.22 5.96 +/-7.22 12.3 pCi/g MXP1 04/11/07 0032 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.046 +/-0.197 0.166 +/-0.197 0.337 pCi/g MXPI 04/11/07 1801 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- II-RC Modified 3 DOE EML HASL-300, Pu- II-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-I, Modified 9 DOE RESL Ni-I, Modified 10 DOE EML HASL-300, Tc-02-RC Modified Surrogate/T racer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 80 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 90 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 90 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 92 (25%-1 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 64 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 76 (25%-I125%)

Page 75 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-006F Project: YANKO 1204 Sample ID: 183607003 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MIDA Units DF Analyst Date Time Batch N%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 70 (15%-1 25%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 76 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-007F Project: YANK01204 Sample ID: 183607004 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 9.58%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Alphaspec Am24 1, Cm, Solid ALL FSS Americium-241 U -0.0384 +/-0.0719 0.032 +/-0.072 0.161 pCilg MXA 04/09/07 1504 623058 Curium-242 U 0.0374 +/-0.0734 0.00 +/-0.0736 0.10 1 pCi/g Curium-243/244 U -0.017 1 +/-0.0738 0.0453 +/-0.0739 0.187 pCilg Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0221 +/-0.0754 0.0771 +/-0.0754 0.242 pCilg MXA 04/09/07 1503 623060 Plutonium-239/240 U 0.01 69 +/-0.0672 0.0412 +/-0.0672 0. 170 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -4.54 +/-7.43 6.47 +/-7.43 13.7 pCi/g MXA 04/11/07 1722 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 1.13 +/-0.3 12 0.0963 +/-0.3 12 0.192 pCi/g MIHI 04/09/07 0943 623177 Americium-241 U 0.0229 +/-0.0522 0.0433 +/-0.05 22 0.0866 pCi/g Bismuth-21 2 0.886 +/-0.405 0.220 +/-0.405 0.440 pCi/g Bismuth-214 0.942 +/-0.170 0.0575 +/-0.170 0.115 pCi/g Cesium-134 UI 0.00 +/-0.0446 0.038 +/-0.0446 0.076 pCi/g Cesium-137 UI 0.00 +/-0.042 1 0.0271 +/-0.0421 0.0542 pCi/g Cobalt-60 U 0.01 06 +/-0.0316 0.0277 +/-0.0316 0.0554 pCi/g Europium-152 U 0.0442 +/-0.098 0.078 +/-0.098 0.156 pCi/g Europium-154 U 0.100 +/-0.113 0.104 +/-0.113 0.208 pCi/g Europium-iSS U 0.0418 +/-0.0792 0.0725 +/-0.0792 0.145 pCi/g Lead-212 1.03 +/-0.142 0.0412 +/-0.142 0.0824 pCi/g Lead-214 1.08 +/-0.170 0.05 15 +/-0.170 0.103 pCi/g Manganese-54 U-0 .000325 +/-0.0331 0.0288 +/-0.03 31 0.0575 pCi/g Niobium-94 U -0.0205 +/-0.0312 0.0246 +/-0.03 12 0.0492 pCi/g Potassium-40 13.3 +/-1.44 0.227 +/-1.44 0.454 pCi/g Radium-226 0.942 +/-0.170 0.0575 +/-0.170 0.115 pCi/g Silver-108rn U 0.01 23 +/-0.027 0.0243 +/-0.027 0.0486 pCi/g Thallium-208 0.341 +/-0.0692 0.0323 +/-0.0692 0.0645 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U -0.0111 +/-0.0216 0.0196 +/-0.0216 0.0451 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 77 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 980 1-0000-007F Proiect: YANK01 204 Sample ID: 183607004 Client ID: YANKOO 1 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A' Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U 0.0374 +1-1.35 1.13 +1-1.35 2.35 pCi/g AXD2 04/07/07 0238 623189 Liquid Scint 014, Solid AIIFSS Carbon-14 U -0.00688 +/-0.111 0.0936 +/-0.111 0.191 pCi/g AXD2 04/07/07 1133 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -1.74 +/-27-1 19.0 +/-27-1 40.1 pCi/g MXP1 04/11/07 0506 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -5.56 +/-6.43 5.57 +/-6.43 11.5 pCi/g MXP1 04/11/07 0104 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.154 +/-0.189 0.157 +/-0.189 0.318 pCi/g MXP1 04/11/07 1924 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- II-RC Modified 3 DOE EML HASL-300, Pu-i 1-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-i, Modified 9 DOE RESL Ni-I, Modified 10 DOE EML HASL-300, Tc-02-RC Modified Surrogate/T racer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 73 (15%-125%)

Plutonium-242 Tracer Aiphaspec Put, Solid-ALL FSS 84 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 85 (25%-125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 76 (25%-125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 76 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 79 (25%-1 25%)

Page 78 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-007F Project: YANKO 1204 Sample ID: 183607004 Client ID: YANKO0 I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 74 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +I-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 79 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.comn Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-008F Proiect: YANK01204 Sample ID: 183607005 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 2.35%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Alphaspec Am24 1, Cm, Solid ALL FSS Americium-241 U 0.223 +1-0.25 1 0.0603 +/-0.253 0.303 pCi/g MXA 04/09/07 1504 623058 Curium-242 U -0.017 +/-0.142 0.0634 +/-0.143 0.318 pCi/g Curium-243/244 U

-0.0484 +/-0.143 0.105 +/-0.143 0.391 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0059 +/-0.160 0.132 +/-0.160 0.365 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U 0.028 +/-0.0743 0.033 1 +/-0.0744 0.166 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 1.09 +/-6.91 5.75 +/-6.91 12.1 pCi/g MXA 04/11/07 1738 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.520 +/-0.118 0.0431 +/-0.118 0.0862 pCi/g MJH 1 04/09/07 0945 623177 Americium-241 U 0.0794 +/-0.0813 0.0549 +/-0.08 13 0.110 pCi/g Bismuth-212 UI 0.00 +/-0.191 0.128 +/-0.191 0.256 pCi/g Bismuth-214 0.816 +/-0.105 0.0257 +1-0. 105 0.0513 pCi/g Cesium-i 34 U 0.024 +/-0.0223 0.01 56 +/-0.0223 0.0311 pCi/g Cesium-I 37 0.0703 +/-0.0244 0.0128 +/-0.0244 0.0255 pCi/g Cobalt-60 UI 0.00 +/-0.0181 0.0152 +/-0.0181 0.0304 pCi/g Europium-I 52 U 0.0589 +/-0.0636 0.0367 +/-0.0636 0.0734 pCi/g Europium-154 U 0.015 +/-0.0491 0.0432 +/-0.0491 0.0863 pCi/g Europium-iSS U -0.0336 +/-0.0476 0.0432 +/-0.0476 0.0863 pCi/g Lead-21 2 0.404 +/-0.052 1 0.0225 +/-0.0521 0.045 pCi/g Lead-214 1.01 +/-0.112 0.025 1 +/-0.112 0.0501 pCi/g Manganese-54 U 0.00607 +/-0.0178 0.0137 +/-0.01 78 0.0274 pCi/g Niobium-94 U 0.000981 +/-0.0142 0.0123 +/-0.0142 0.0245 pCi/g Potassium-40 6.28 +/-0.637 0.119 +/-0.637 0.238 pCi/g Radium-226 0.816 +/-0.105 0.0257 +/-0. 105 0.0513 pCi/g Silver-108m U -0.00347 +/-0.01 37 0.0116 +/-0.0137 0.0232 pCi/g Thallium-208 0.113 +/-0.0308 0.013 +/-0.0308 0.0259 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL ESS Strontium-90 U -0.00195 +/-0.016 0.0138 +/-0.016 0.0324 pCi/g NXL3 04/10/07 2039 623055 Rad Liquid Scintillation Analysis Page 80 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.comn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 980 1-0000-008F Project: YANK01204 Sample ID: 183607005 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.685 +/-1.37 1.18 +/-1.37 2.46 pCi/g AXD2 04/07/07 0341 623189 Liquid Scint C14, Solid AllFSS Carbon- 14 U -0.0563 +/-0.1 12 0.0946 +/-0.112 0.193 pCi/g AXD2 04/07/07 1237 623192 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U -0.454 +/-44.1 30.7 +/-44.1 64.4 pCi/g MXPI 04/11/07 1350 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -3.56 +/-6.30 5.40 +/-6.30 11.2 pCi/g MXP1 04/11/07 0135 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0594 +/-0.177 0.148 +/-0.177 0.300 pCi/g MXP1 04/11/07 2047 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- II-RC Modified 3 DOE EML HASL-300, Pu- I I -RC Modified 4 EML HASL 300,4.5.2.3 5 EPA 905.0 Modified 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Fe-I, Modified I1I DOE RESL Ni-I, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 38 (15%-1 25%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL F55 72 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL F5 95 (25%-1 25%)

(25%-125%)

Page 81 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-008F Project: YANK01204 Sample ID: 183607005 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Strontium Carrier GFPC, Sr90, solid-ALL FSS 83 Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 77 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 83 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 78 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 82 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomvic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-009F Project: YANK01 204 Sample ID: 183607006 Client ID: YANKOO 1 Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 8.72%

Parameter Qualifier Result Uncertainty LC TPU MDA units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.0457 +/-0.0718 0.044 +/-0.0718 0.182 pCi/g MXA 04/09/07 1504 623058 Curium-242 U 0.0363 +/-0.0711 0.00 +/-0.0713 0.0983 pCi/g Curium-243/244 U 0.0264 +/-0.0699 0.0311 +/-0.070 pCi/g 0.156 Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00824 +/-0.0161 0.0308 +/-0.0162 0.155 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U -0.00412 +/-0.130 0.111 +/-0.130 0.3 15 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 1.29 +/-6.96 5.78 +/-6.97 12.2 pCi/g MXA 04/11/07 1754 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.933 +/-0.269 0.114 +/-0.269 0.227 pCi/g MIHi 04/09/07 1132 623177 Americium-241 U 0.036 +/-0.0651 0.0537 +/-0.0651 0.107 pCi/g Bismuth-21 2 0.905 +/-0.515 0.237 +/-0.515 0.474 pCi/g Bismuth-2 14 0.760 +/-0.142 0.0594 +/-0.142 0.119 pCi/g Cesium-i 34 U 0.0804 +/-0.0689 0.0422 +/-0.0689 0.0843 pCi/g Cesium-I 37 U 0.0598 +/-0.057 0.036 +/-0.057 0.072 pCi/g Cobalt-60 U 0.0216 +/-0.040 0.0355 +/-0.040 0.0709 pCi/g Europium-152 U 0.0214 +/-0.116 0.0852 +/-0.116 0.170 pCi/g Europium-I 54 U -0.135 +/-0.148 0.0902 +/-0.148 0.180 pCi/g Europium-iSS U 0.0238 +/-0.0919 0.0828 +/-0.0919 0.166 pCi/g Lead-212 0.887 +/-0.118 0.045 +/-0.118 0.0899 pCi/g Lead-214 0.836 +/-0.158 0.0614 +/-0.158 0.123 pCi/g Manganese-54 U 0p.00909 +/-0.044 0.0337 +/-0.044 0.0673 pCi/g Niobium-94 Uc0 ~.00468 +/-0.0392 0.0332 +/-0.0392 0.0664 pCi/g Potassium-40 10.0 +/-1.34 0.300 +/-1.34 0.600 pCi/g Radium-226 0.760 +/-0.142 0.0594 +/-0.142 0.119 pCi/g Silver-108m U -0.014 +/-0.0339 0.0287 +/-0.0339 0.0573 pCi/g Thallium-208 0.342 +/-0.0923 0.0303 +/-0.0923 0.0605 pCi/g Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U - 0.00249 +/-0.0185 0.0159 +/-0.0185 0.0377 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 83 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-009F Proiect: YANK01204 Sample ID: 183607006 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis ISC, Tritium Dist, Solid - 3 pCilg Tritium U -0.287 +/-1.36 1.15 +/-1.36 2.40 pCi/g AXD2 04/07/07 0705 623189 Liquid Scint 014, Solid All, FSS Carbon- 14 U -0.0629 +/-0.119 0.101 +/-0.119 0.205 pCi/g AXD2 04/07/07 1341 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 25.5 +/-31.6 21.6 +/-31.7 45.6 pCi/g MXPI 04/11/07 0540 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -0.917 +/-8.00 6.74 +/-8.00 13.9 pCilg MXPI 04/11/07 0206 623183 Liquid Scint Tc99, Solid-ALL ['55 Technetium-99 U 0.181 +/-0.247 0.205 +/-0.247 0.415 pCi/g MXPI 04/11/07 2210 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- I I1-RC Modified 3 DOE EML HASL-300, Pu- I -RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-I, Modified 9 DOE RESL Ni-I, Modified 10 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 77 (15 %-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 76 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL Fý 94 (25%-i125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 87 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 63 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 65 (25%-125%)

Page 84 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-009F Project: YANK0 1204 Sample ID: 183607006 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 54 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 85 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-01 OF Proiect: YANK0 1204 Sample ID: 183607007 Client ID: YANKOO 1 Matrix: TS Vol. Recv.:

Collect Date: 28-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 6.8 1%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.00383 +/-0.0289 0.0307 +/-0.0289 0.154 pCi/g MXA 04/09/07 1504 623058 Curium-242 U 0.0361 +/-0.0707 0.00 +/-0.0709 0.0978 pCi/g Curium-243/244 U 0.00 +/-0.0671 0.00 +/-0.0671 0.0928 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0329 +/-0.111 0.0774 +/-0.111 0.237 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U 0.0159 +/-0.0631 0.0387 +/-0.0631 0.160 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 1.12 +/-8.95 7.46 +/-8.95 15.7 pCi/g MXA 04/11/07 1810 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 1.20 +/-0.257 0.0493 +/-0.257 0.0985 pCi/g MJHI 04/09/07 1133 623177 Americium-241 U 0.0352 +/-0.0595 0.0475 +/-0.0595 0.0949 pCi/g Bismuth-212 U 0.436 +/-0.508 0.361 +/-0.508 0.721 pCi/g Bismuth-214 0.973 +/-0.200 0.0559 +/-0.200 0.112 pCi/g Cesium-I134 UI 0.00 +/-0.0506 0.0429 +/-0.0506 0.0858 pCi/g Cesium- 137 U 0.00647 +/-0.0401 0.0354 +/-0.0401 0.0708 pCi/g Cobalt-60 U 0.0682 +/-0.0425 0.0393 +/-0.0425 0.0785 pCi/g Europium-152 U 0.0815 +/-0.124 0.0802 +/-0.124 0.160 pCi/g Europium-154 U -0.0833 +/-0.147 0.113 +/-0.147 0.226 pCi/g Europium-ISS U 0.114 +/-0.0976 0.0734 +/-0.0976 0.147 pCi/g Lead-212 1.12 +/-0.141 0.0439 +/-0.141 0.0878 pCi/g Lead-214 1.13 +/-0.176 0.0522 +/-0.176 0.104 pCi/g Manganese-54 U 0.0165 +/-0.0456 0.0355 +/-0.0456 0.071 pCi/g Niobium-94 U 0.0227 +/-0.0689 0.0322 +/-0.0689 0.0644 pCi/g Potassium-40 14.1 +/-1.50 0.296 +1-1.50 0.592 pCi/g Radium-226 0.973 +/-0.200 0.0559 +/-0.200 0.112 pCi/g Silver-108m U-0.000684 +/-0.032 0.0273 +/-0.032 0.0546 pCi/g Thaflium-208 0.379 +/-0.0823 0.0264 +/-0.0823 0.0528 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00578 +/-0.0217 0.019 +/-0.0217 0.0439 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 86 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-OlOF Project: YANK01204 Sample ID: 183607007 Client ID: YANKOG 1 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units 1W Analyst Date Time Batch A~

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.222 +/1-.44 1.21 +/-1.44 2.53 pCi/g AXD2 04/07/07 0807 623189 Liquid Scint C14, Solid AlIFSS Carbon- 14 U -0.0553 4/-0.110 0.093 +/-0.110 0.189 pCi/g AXD2 04/07/07 1445 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 0.200 +/-28.4 20.1 +/-28.4 42.4 pCi/g MXPI 04/11/07 0556 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -0.274 +/-6.86 5.76 +/-6.86 11.9 pCi/g MXP1 04/11/07 0238 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.00536 +/-0.231 0.194 +/-0.231 0.393 pCi/g MXP1 04/11/07 2333 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I ~DOE EMIL HASL-300, Am-05-RC Modified 2 DOE EMIL HASL-300, Pu- I I1-RC Modified 3 DOE EMIL HASL-300, Pu- I I -RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-i, Modified 9 DOE RESL Ni-i, Modified 10 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Aiphaspec Am241, Cm, Solid ALL 77 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 89 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL Fý 72 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 80 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 68 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 77 (25%-I 25%)

Page 87 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-OIOF Project: YANK01204 Sample ID: 183607007 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Unce rtainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 60 (15%-I125%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCJMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 88 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address :362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-01iIF Project: YANK01 204 Sample ID: 183607008 Client ID: YANKOO 1 Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 7.91%

Parameter luallifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Alplmspec Am241, Cm, Solid ALL FSS Americium-241 U 0.026 +/-0.116 0.0659 +/-0.116 0.331 pCi/g MXA 04/09/07 1504 623058 Curium-242 U 0.00 +1-0.151 0.00 +1-0.151 0.209 pCi/g Curium-243/244 U -0.0176 +1-0.0345 0.0659 +/-0.0347 0.331 pCilg Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.021 +1-0.135 0.122 +1-0.135 0.338 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 * -0.0658 +/-0.0892 0.109 +/-0.0896 0.3 13 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -4.03 +/-7.38 6.40 +/-7.38 13.5 pCi/g MXA 04/11/07 1826 623061 1

Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL ['55 226 In growth Waived Actinium-228 0.9 13 +/-0.322 0.101 +/-0.322 0.201 pCi/g MJIi 04/09/07 1145 623177 Americium-241 U 0.049 +/-0.0511 0.0429 +1-0.0511 0.0857 pCi/g Bismuth-212 UI 0.00 +/-0.417 0.3 16 +/-0.417 0.632 pCi/g Bismuth-2 14 0.875 +/-0.161 0.058 +/-0.161 0.116 pCi/g Cesium- 134 UI 0.00 +/-0.0434 0.0386 +/-0.0434 0.0771 pCi/g Cesium-137 U 0.046 +/-0.0605 0.0354 +/-0.0605 0.0707 pCi/g Cobalt-60 U - -0.00179 +/-0.0336 0.0278 +/-0.0336 0.0556 pCi/g Europium-152 U 0.0533 +/-0.0958 0.0766 +/-0.0958 0.153 pCi/g Europium-I 54 U 0.08 18 +/-0. 164 0.103 +/-0.164 0.205 pCi/g Europium-ISS U 0.105 +/-0.107 0.0701 +/-0.107 0.140 pCi/g Lead-212 1.10 +/-0.151 0.0417 +/-0.151 0.0834 pCi/g Lead-214 0.844 +/-0.175 0.0509 +/-0.175 0.102 pCi/g Manganese-54 U -0.0445 +/-0.0347 0.0262 +/-0.0347 0.0523 pCi/g Niobium-94 U -0.0153 +/-0.0311 0.0248 +/-0.0311 0.0495 pCi/g Potassium-40 12.7 +/-1.56 0.288 +/-1.56 0.575 pCi/g Radium-226 0.875 +/-0. 161 0.058 +/-0.161 0.116 pCi/g Silver-108m U - -0.00402 +/-0.0288 0.0248 +/-0.0288 0.0495 pCi/g Thallium-208 0.371 +/-0.0741 0.0315 +/-0.0741 0.063 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL ['55 Strontium-90 U 0.0403 +/-0.0293 0.0212 +/-0.0293 0.0466 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 89 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-011IF Project: YANK01 204 Sample ID: 183607008 Client ID: YANKOO 1 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/'g Tritium U 1.33 +/-1.44 1.16 +/-1.44 2.42 pCi/g AXD2 04/07/07 0909 623189 Liquid Scint C14, Solid AIIFSS Carbon-14 U -0.133 +/-0.111 0.0956 +/-0.111 0.195 pCi/g AXD2 04/07/07 1550 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 66.3 +/-37.4 24.1 +/-37.7 50.8 pCi/g MXPI 04/11/07 0613 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -2.86 +/-6.15 5.25 +/-6.15 10.9 pCi/g MXPI 04/11/07 0309 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0154 +/-0.189 0.159 +/-0.189 0.323 pCi/g MXP1 04/12/07 0056 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- I I-RC Modified 3 DOE EML HASL-300, Pu- II -RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-I, Modified 9 DOE RESL Ni-I, Modified 10 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 36 (15%-I125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 86 (15%-I125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 85 (25%-i125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 76 (25%-1 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 69 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 86 (25%-i125%)

Page 90 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-01iIF Project: YANK01204 Sample ID: 183607008 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 73 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 91 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-012F Project: YANK01 204 Sample ID: 183607009 Client ID: YANKOOI Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 9.38%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U 0.0684 +/-0.127 0.0697 +/-0.127 0.233 pCi/g MXA 04/10/07 1232 623058 Curium-242 U 0.00146 +1-0.0796 0.0657 +/-0.0796 0.23 1 pCi/g Curium-243/244 U -0.0306 +/-0.112 0.108 +/-0.112 0.310 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00698 +/-0.0776 0.070 +/-0.0776 0.235 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U -0.00697 +/-0.0776 0.070 +/-0.0776 0.234 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 1.91 +/-7.69 6.36 +/-7.69 13.4 pCi/g MXA 04/11/07 1842 623061 Rad Gammna Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.869 +/-0.258 0.0837 +/-0.258 0.167 pCi/g MIHI 04/09/07 1418 623177 Americium-241 U 0.0635 +/-0.048 0.0412 +/-0.048 0.0823 pCi/g Bismuth-212 UI 0.00 +/-0.386 0.300 +/-0.386 0.599 pCi/g Bismuth-2 14 0.681 +/-0.137 0.0483 +/-0.137 0.0965 pCi/g Cesium-134 UI 0.00 +/-0.0659 0.037 +/-0.0659 0.0739 pCi/g Cesium-I 37 0.0681 +/-0.0341 0.0298 +/-0.0341 0.0595 pCi/g Cobalt-60 U 0.00127 +/-0.0325 0.0273 +/-0.0325 0.0545 pCi/g Europium-152 U -0.0165 +/-0.0969 0.073 1 +/-0.0969 0.146 pCi/g Europium-154 U -0.111 +/-0.111 0.0807 +/-0.111 0.161 pCi/g Europium-ISS U 0.00431 +/-0.0755 0.0678 +/-0.0755 0.135 pCi/g Lead-212 0.954 +/-0.138 0.0373 +/-0.138 0.0745 pCi/g Lead-214 0.747 +/-0.138 0.0557 +/-0.138 0.111 pCi/g Manganese-54 U -0.0115 +/-0.0314 0.0262 +/-0.0314 0.0524 pCi/g Niobium-94 U 0.0131 +/-0.0329 0.0286 +/-0.0329 0.057 1 pCi/g Potassium-40 12.5 +/-1.35 0.199 +/-1.35 0.397 pCi/g Radium-226 0.681 +/-0.137 0.0483 +/-0.137 0.0965 pCi/g Silver-108m U- -0.00552 +/-0.0265 0.0227 +/-0.0265 0.0454 pCi/g Thallium-208 0.296 +/-0.077 0.0266 +/-0.077 0.0533 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U - -0.00129 +/-0.025 7 0.0218 +/-0.0257 0.0492 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 92 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-012F Proiect: YANK01204 Sample ID: 183607009 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3pCi/g Tritium U -0.258 +/-1.41 1.20 +1-1.41 2.49 pCi/g AXD2 04/07/07 1012 623189 Liquid Scint 014, Solid AllFSS Carbon- 14 U -0.0146 +/-0.112 0.0944 +/-0.112 0.192 pCi/g AXD2 04/07/07 1654 623192 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U -31.9 +/-44.4 32.0 +/-44.4 67.0 pCi/g MXP1 04/11/07 1406 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -1.48 +/-6.45 5.46 +/-6.45 11.3 pCi/g MXPI 04/11/07 0340 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.123 +/-0.192 0.160 +/-0.192 0.324 pCi/g MXP1 04/12/07 0219 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I1-RC Modified 4 DOE EML HASL-300, Pu- I I1-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Fe-l, Modified 11I DOE RESL Ni-l, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 88 (15 %-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 84 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 85 (25%-I125%)

(25%-I125%)

Page 93 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Cp~rtifinttp (if An21v~i~

Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-012F Proiect: YANK0 1204 Sample ID: 183607009 Client ID: YANKOO I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Strontium Carrier GFPC, Sr90, solid-ALL FSS 84 Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 76 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 80 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 71 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 94 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-01 3F Project: YANK01204 Sample ID: 183607010 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 7.45%

Parameter Qualifier Result Uncertainty LC TPU MDA units DF Analyst Date Time Batch Ai Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.00285 +/-0.0186 0.00 +/-0.0186 0.0858 pCi/g MXA 04/09/07 1504 623058 Curium-242 U 0.00 +/-0.0652 0.00 +/-0.0652 0.0901 pCi/g Curium-243/244 U 0.00 +/-0.0621 0.00 +/-0.0621 0.0859 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0447 +/-0.0392 0.0748 +/-0.0396 0.251 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U 0.0104 +/-0.0791 0.0579 +/-0.0791 0.217 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 1.74 +/-8.03 6.65 +/-8.03 14.0 pCi/g MXA 04/11/07 1859 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.431 +/-0.207 0.0837 +/-0.207 0.167 pCi/g MJH1 04/09/07 1620 623177 Americium-241 U 0.00305 4-0.0414 0.0341 +/-0.0414 0.0681 pCi/g Bismuth-212 UI 0.00 +/-0.316 0.252 +/-0.316 0.505 pCi/g Bismuth-214 0.453 +/-0.130 0.0423 +/-0.130 0.0846 pCi/g Cesium-134 U 0.0106 H /-0.0342 0.0308 +/-0.0342 0.0615 pCi/g Cesium-137 U 0.00436 HV-0.0286 0.0247 +/-0.0286 0.0493 pCi/g Cobalt-60 U 0.0082 H4-0.0288 0.0252 +/-0.0288 0.0504 pCi/g Europium-152 U 0.0136 +/-0.071 0.0558 +/-0.071 0.112 pCi/g Europium-154 U -0.00238 /-0.0962 0.0806 +/-0.0962 0.161 pCi/g Europium-ISS U -0.0283 H /-0.0698 0.062 +/-0.0698 0.124 pCi/g Lead-212 0.622 H/-0.0968 0.0335 +/-0.0968 0.067 pCi/g Lead-214 0.452 H4/-0.0996 0.0407 +/-0.0996 0.0814 pCi/g Manganese-54 U 0.00999 4-0.0304 0.0273 +/-0.0304 0.0545 pCi/g Niobium-94 U-0.000756 H /-0.0275 0.0232 +/-0.0275 0.0463 pCi/g Potassium-40 9.83 +/-1.17 0.180 +/-1.17 0.360 pCi/g Radium-226 0.453 +/-0.130 0.0423 +/-0.130 0.0846 pCi/g Silver-108m U -0.0078 H4-0.0246 0.021 +/-0.0246 0.0419 pCi/g Thallium-208 0.174 4-0.0663 0.0234 +/-0.0663 0.0468 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U-0.000516 -F/-0.0183 0.0155 +/-0.0183 0.0369 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 95 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-013F Project: YANK0 1204 Sample ID: 183607010 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U 0.949 +/-1.43 1.17 +/-1.43 2.43 pCi/g AXD2 04/07/07 1114 623189 Liquid Scint C14, Solid AIIFSS Carbon-14 U -0.122 +/-0.110 0.0947 +/-0.110 0.193 pCi/g AXD2 04/07/07 1758 623192 Liquid Scint Fe55, Solid-ALL FSS lron-55 U -16.4 ÷1-40.8 28.9 ÷/-40.8 60.7 pCi/g MXPI 04/11/07 1423 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -5.93 +/-7.21 6.23 +/-7.21 12.9 pCi/g MXP1 04/11/07 0412 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0353 +/-0.179 0.150 +/-0.179 0.305 pCi/g MXPI 04/12/07 0342 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- II-RC Modified 3 DOE EML HASL-300, Pu- I I1-RC Modified 4 EML HASL 300,4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-l, Modified 9 DOE RESL Fe-l, Modified 10 DOE RESL Ni-I, Modified I1I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 88 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 81 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 83 (25%-I 25%)

Strontium Carrier GFPC, SrOO, solid-ALL FSS 83 (25%-I125%)

Iron-59 Tracer Liquid Scint FeSS, Solid-ALL FS 78 (15%-125%)

Page 96 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-013F Project: YANK01204 Sample ID: 183607010 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 71 (25%-i125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 78 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit

• Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 97 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-013FS Proiect: YANK01204 Sample ID: 183607011 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 7.45%

Parameter Qualifier Result Uncertainty LC TPU MDA units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am24I1, Cm, Solid ALL FSS Americium-241 U 0.0611 +/-0.116 0.0649 +/-0.117 0.217 pCi/g MXA 04/10/07 1232 623058 Curium-242 U 0.0177 +/-0.0706 0.0433 +/-0.0706 0.179 pCi/g Curium-243/244 U -0.0608

+/-0.0825 0.101 +/-0.0828 0.289 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0395 +/-0.111 0.0682 +/-0.111 0.239 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U 0.0198 +/-0.0787 0.0482 +/-0.0787 0.199 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -0.194 +/-6.92 5.82 +/-6.92 12.3 pCi/g MXA 04/11/07 1915 623061 1

Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.564 +/-0.100 0.0292 +/-0.100 0.0583 pCi/g MIHI 04/09/07 1905 623177 Americium-241 U 0.00421 +/-0.0391 0.03 11 +/-0.0391 0.0622 pCi/g Bismuth-212 0.472 +/-0.111 0.059 +/-0.111 0.118 pCi/g Bismuth-214 0.439 +/-0.0568 0.0162 +/-0.0568 0.0324 pCi/g Cesium-134 UI 0.00 +/-0.0172 0.00986 +/-0.0172 0.01 97 pCi/g Cesium-]137 U 0.0115 */-0.01 35 0.0086 +/-0.0135 0.0172 pCi/g Cobalt-60 U -0.00251 +1-0.0103 0.00867 +/-0.0103 0.0173 pCi/g Europium-152 U -0.0365 +1-0.0472 0.0224 +/-0.0472 0.0448 pCi/g Europium-154 U -0.00171 +/-0.0363 0.0264 +/-0.0363 0.0528 pCi/g Europium-155 U 0.0343 +/-0.0369 0.026 +/-0.0369 0.052 pCi/g Lead-212 0.533 +/-0.0487 0.013 +/-0.0487 0.0259 pCi/g Lead-214 0.508 +/-0.0607 0.0155 +/-0.0607 0.0309 pCi/g Manganese-54 U 0.00621 +/-0.0101 0.00899 +/-0.0101 0.018 pCi/g Niobium-94 U 0.00305 +. /-0.00897 0.00775 +/-0.00897 0.01 55 pCi/g Potassium-40 10.6 +/-0.768 0.0668 +/-0.768 0.134 pCi/g Radium-226 0.439 +/-0.0568 0.01 62 +1-0.0568 0.0324 pCi/g Silver-108m U 0.00206 + 1-0.00844 0.0146 pCi/g Thallium-208 0.186 +/-0.0253 0.00771 +/-0.0253 0.01 54 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U -0.0108 +/-0.0128 0.0129 +/-0.0128 0.031 pCi/g NXL3 04/09/07 1750 623055 Page 98 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-013FS Project: YANK01204 Sample ID: 183607011 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch IN Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCIg Tritium U -0.362 +/-1.43 1.21 +/-1.43 2.52 pCi/g AXD2 04/07/07 1216 623189 Liquid Scint 014, Solid All, FSS Carbon- 14 U -0.0945 +/-0.115 0.0982 +1-0.115 0,200 pCi/g AXD2 04/07/07 1902 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 10.5 +/-28.1 19.5 +/-28.1 41.1 pCi/g MXPI 04/11/07 0703 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -4.67 +/-6.48 5.58 +/-6.48 11.5 pCi/g MXP1 04/11/07 0443 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0525 +/-0.167 0.141 +/-0.167 0.285 pCi/g MXPI 04/12/07 0505 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 DOE EML HASL-300, Pu- I I -RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-i, Modified 10 DOE RESL Ni-I, Modified I1I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 93 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 81 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL F5 94 (25%-I 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 92 (25%-I 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 70 (15%-I125%)

Page 99 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-013FS Project: YANK01204 Sample ID: 183607011 Client ID: YANKOOlI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 82 (25%-I125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 83 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCJMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 100 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-014F Project: YANK01 204 Sample ID: 183607012 Client ID: YANKOO 1 Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 1.94%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0377 +/-0.0851 0.0344 +/-0.0853 0.173 pCi/g MXA 04/09/07 1504 623058 Curium-242 U 0.0305 +/-0.0809 0.036 +/-0.081 0.18 1 pCi/g Curium-243/244 U 0.0384 +/-0.0753 0.00 +/-0.0754 0.104 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.031 +/-0.106 0.108 +/-0.106 0.340 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U -0.0547 +/-0.0479 0.0914 +/-0.0483 0.306 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -3.4 +/-7.07 6.10 +/-7.07 12.9 pCi/g MXA 04/11/07 1931 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.772 +/-0.148 0.0516 +/-0.148 0.103 pCi/g MJH1 04/10/07 0942 623177 Americium-241 U 0.0492 +/-0.0694 0.0582 +/-0.0694 0.116 pCi/g Bismuth-212 UI 0.00 +/-0.232 0.145 +/-0.232 0.291 pCi/g Bismuth-21 4 0.619 +/-0.0949 0.0265 +/-0.0949 0.053 pCi/g Cesium-i 34 UI 0.00 +/-0.0275 0.01 87 +/-0.0275 0.0373 pCi/g Cesium-i 37 0.220 +/-0.0382 0.0142 +/-0.0382 0.0284 pCi/g Cobalt-60 0.624 +/-0.0596 0.017 +/-0.0596 0.0339 pCi/g Europium-152 U -0.0146 +/-0.0576 0.0381 +/-0.0576 0.0761 pCi/g Europium-154 U 0.0441 +/-0.0537 0.0487 +/-0.0537 0.0973 pCi/g Europium-I 55 U 0.0284 +/-0.0477 0. 0457 +/-0.0477 0.0913 pCi/g Lead-212 0.721 +/-0.0708 0.0229 +/-0.0708 0.0458 pCi/g Lead-214 0.589 +/-0.0871 0.0267 +/-0.0871 0.0534 pCi/g Manganese-54 U 0.00521 +/-0.0165 0.0148 +/-0.0165 0.0295 pCi/g Niobium-94 U 0.00817 +/-0.0158 0.014 +/-0.0158 0.0279 pCi/g Potassium-40 12.4 +/-0.977 0.108 +/-0.977 0.217 pCi/g Radium-226 0.619 +/-0.0949 0.0265 +/-0.0949 0.053 pCi/g Silver-108m U- 0.00271 +/-0.0154 0.0133 +/-0.0154 0.0266 pCi/g Thallium-208 0.195 +/-0.0326 0.0142 +/-0.0326 0.0284 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.02 +/-0.0207 0.0206 +/-0.0207 0.0482 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 101 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-0 14F Project: YANKO 1204 Sample ID: 183607012 Client ID: YANKOO 1 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Liquid Scintillation Analysis LSC, Tritium Djst, Solid - 3 pCi/g Tritium U 0.430 +1-1.42 1.18 +/-1.42 2.45 pCi/g AXD2 04/07/07 1318 623189 Liquid Scint 014, Solid AIIFSS Carbon-14 U -0.0183 +/-0.118 0.0996 +/-0.118 0.203 pCi/g AXD2 04/07/07 2006 623192 Liquid Scint Fe5S, Solid-ALL FSS Iron-55 U 0.581 +/-29.1 20.7 ÷/-29.1 43.7 pCilg MXPI 04/11/07 0720 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -3.14 +/-7.04 6.01 +/-7.04 12.4 pCi/g MXPI 04/11/07 0514 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.204 +/-0.222 0.182 +/-0.222 0.373 pCi/g MXP1 04/12/07 0737 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- II-RC Modified 3 DOE EML HASL-300, Pu-i 1-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-I, Modified 9 DOE RESL Ni-I, Modified 10 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 72 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 67 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL F,5 90 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 75 (25%-1 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 64 (15%-1 25%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 73 (25%-125%)

Page 102 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-014F Project: YANK01204 Sample ID: 183607012 Client ID: YANKOOlI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1'%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 77 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 103 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-015F Project: YANK01 204 Sample ID: 183607013 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 5.64%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.063 +/-0.0557 0.0911 +/-0.0563 0.280 pCi/g MXA 04/09/07 1503 623058 I

Curium-242 U -0.0445 +/-0.039 0.0744 +/-0.0395 0.249 pCi/g Curium-243/244 U 0.00862 +/-0.191 0.158 +/-0.191 0.413 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0521 +/-0.0916 0.106 +/-0.0918 0.3 12 pCi/g MXA 04/09/07 1504 623060 I

Plutonium-239/240 U -0.00894 +/-0.0751 0.0334 +/-0.0751 0.168 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -3.33 +/-6.92 5.98 +/-6.92 12.6 pCi/g MXA 04/11/07 1947 623061 1

Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.800 +/-0.194 0.0675 +/-0.194 0.135 pCi/g MJH1 04/10/07 1042 623177 Americium-241 U 0.0273 +/-0.120 0.0954 +/-0.120 0.191 pCi/g Bismuth-212 UI 0.00 +/-0.262 0.200 +/-0.262 0.40 1 pCi/g Bismuth-214 0.756 +/-0.137 0.0398 +/-0.137 0.0795 pCi/g Cesium-I 34 U 0.0468 FI-0.0303 0.0242 +/-0.0303 0.0483 pCi/g Cesium-137 0.661 t-I-0.0835 0.0223 +/-0.0835 0.0446 pCi/g Cobalt-60 0.164 +I-0.0472 0.0173 +/-0.0472 0.0347 pCi/g Europium-152 U 0.00396 +I-0.0868 0.0572 +/-0.0868 0.114 pCi/g Europium-154 U -0.00534 +I-0.0665 0.057 +/-0.0665 0.114 pCi/g Europium-155 U 0.0332 +/-0.0693 0.065 1 +/-0.0693 0.130 pCi/g Lead-21 2 0.749 +/-0.0963 0.0345 +/-0.0963 0.0691 pCi/g Lead-214 0.801 +/-0.122 0.0384 +/-0.122 0.0768 pCi/g Manganese-54 U -0.024 FI-0.0244 0.0192 +/-0.0244 0.0384 pCi/g Niobium-94 U5.9 I0E-05 t-I-0.0222 0.01 94 +/-0.0222 0.0387 pCi/g Potassium-40 10.4 +/-1.03 0.124 +/-1.03 0.248 pCi/g Radium-226 0.756 +/-0.137 0.0398 +/-0.137 0.0795 pCi/g Silver-108m U 0.00163 +I-0.0228 0.0197 +/-0.0228 0.0393 pCi/g Thallium-208 0.268 +I-0.0478 0.0187 +/-0.0478 0.0374 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.00585 i-/-0.0171 0.0133 +/-0.0171 0.0322 pCi/g NXL3 04/09/07 1750 623055 Rad Liquid Scintillation Analysis Page 104 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-015SF Proiect: YANK01204 Sample ID: 183607013 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U 1.10 +/-1.48 1.20 +/-1.48 2.50 pCi/g AXD2 04/07/07 1421 623189 Liquid Scint C14, Solid All, FSS Carbon- 14 U -0.0759 +/-0.118 0.101 +/-0.118 0.205 pCilg AXD2 04/10/07 1256 623192 Liquid Scint FeSS, Solid-ALL ['55 Iron-55 U 7.49 +/-63.3 43.9 +/-63.3 92.0 pCi/g MXPI 04/11/07 1440 623181 Liquid Scint Ni63, Solid-ALL ['55 Nickel-63 U -4.52 +/-5.93 5.12 +/-5.93 10.6 pCi/g MXP1 04/11/07 0546 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0263 +/-0.271 0.227 +/-0.271 0.468 pCi/g MXP1 04/12/07 0901 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- Il-RC Modified 3 DOE EML HASL-300, Pu-I 11-RC Modified 4 EML HASL 300,4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Fe-I, Modified I1I DOE RESL Ni-l, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24I, Cm, Solid ALL 77 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL F55 88 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 92 (25%-1 25%)

(25%-i125%)

Page 105 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Anallsis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801-0000-015F Project: YANK01204 Sample ID: 183607013 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Strontium Carrier GFPC, Sr90, solid-ALL FSS 83 Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 73 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 85 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 79 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 106 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.comn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-016F Project: YANK0 1204 Sample ID: 183607014 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 10.5%

Parameter Qualifier Result Uncertainty LC TPU MIDA Units DF Analyst Date Time Batch A%

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.147 +/-0.196 0.109 +/-0.197 0.321 pCi/g MXA 04/09/07 1503 623058 1

Curium-242 U -0.0459 +1-0.095 6 0.107 +/-0.095 8 0.320 pCi/g Curium-243/244 U 0.150 +1-0.225 0.142 +/-0.226 pCi/g 0.388 Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0232 +/-0.115 0.108 +1-0.115 0.3 13 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U 0.0101 +/-0.0768 0.0562 +/-0.0768 0.210 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 3.91 +/-7.57 6.16 +/-7.58 13.0 pCi/g MXA 04/11/07 1209 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.688 +/-0.271 0.075 +/-0.271 0.150 pCi/g MJH1 04/10/07 1135 623177 Americium-241 U 0.0321 +1-0.115 0.0966 +/-0.115 0.193 pCi/g Bismuth-212 U 0.393 +/-0.283 0.200 +/-0.283 0.399 pCi/g Bismuth-214 0.891 +/-0.129 0.045 1 +/-/-0.129 0.0901 pCi/g Cesium-134 U1 0.00 +/-0.0346 0.0277 +/-/-0.0346 0.0554 pCi/g Cesium-137 U 0.000546 +/-0.026 0.0221 +/-0.026 0.0442 pCi/g Cobalt-60 U 0.00409 +/-0.0232 0.020 +/-0.0232 0.040 pCi/g Europium-152 U 0.0424 +/-0.0984 0.0601 +/-0.0984 0.120 pCi/g Europium-154 U 0.0394 +/-0.0795 0.0704 +/-0.0795 0.141 pCi/g Europium-155 U 0.00548 +/-0.0709 0.0642 +/-0.0709 0.128 pCi/g Lead-212 0.733 +/-0.0857 0.0334 +1-0.0857 0.0667 pCi/g Lead-214 1.09 +/-0.145 0.0405 +/-0.145 0.0809 pCi/g Manganese-54 U -0.00712 +/-0.0255 0.02 15 +/-0.0255 0.043 pCi/g Niobium-94 U 0.00468 +/-0.0229 0.0203 +/-0.0229 0.0405 pCi/g Potassium-40 11.3 +/-1.12 0.196 +/-1.12 0.392 pCi/g Radium-226 0.89 1 +/-0.129 0.0451 +/-0.129 0.0901 pCi/g Silver-108m U -0.0125 +/-0.0212 0.0181 +/-0.0212 0.0362 pCi/g Thallium-208 0.251 +/-0.0456 0.0206 +/-0.0456 0.0412 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.00151 +-/-0.01 97 0.0163 +/-0.0197 0.0385 pCi/g NXL3 04/09/07 1751 623055 Rad Liquid Scintillation Analysis Page 107 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-01 6F Project: YANK01204 Sample ID: 183607014 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.0197 +/-1.42 1.19 +/-1.42 2.48 pCi/g AXD2 04/07/07 1523 623189 Liquid Scint 014, Solid AIIFSS Carbon-14 U -0.0854 +/-0.121 0.103 +/-0.121 0.210 pCi/g AXD2 04/10/07 1400 623192 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U 1.37 +/-27.8 19.6 +/-27.8 41.3 pCilg MXP1 04/11/07 0753 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -5.57 +/-6.18 5.36 +/-6.18 11.1 pCilg MXPI 04/11/07 0617 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0368 +/-0.250 0.211 +/-0.250 0.436 pCi/g MXP1 04/12/07 0923 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-02 1 JMB 1 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-iI1-RC Modified 3 DOE EML HASL-300, Pu-i I-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-i, Modified II DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 82 (15%-125%)

Plutonium-242 Tracer Aiphaspec Pu, Solid-ALL FSS 92 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 81 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 80 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 70 (15%-125%)

Page 108 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-016F Project: YANKOI1204 Sample ID: 183607014 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 84 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 86 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 109 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-017F Project: YANK0 1204 Sample ID: 183607015 Client ID: YANKOOI Matrix: TS Vol. Recv.:

Collect Date: 28-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 6.14%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.0264 +/-0.118 0.114 +/-0.118 0.349 pCi/g MXA 04/09/07 1503 623058 1

Curium-242 -0.0454 +/-0.0445 0.085 +/-0.045 0.298 pCi/g Curium-243/244 0.0952 +/70.210 0.140 +/-0.210 pCi/g 0.401 Aiphaspec Pu, Solid-ALL FSS Plutonium-238 -0.0661 +/-0.0896 0.109 +/-0.0899 0.3 14 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U 0.00141 +/-0.0764 0.0631 +/-0.0764 0.221 pCi/g Liquid Scint Pu24J, Solid-ALL F Plutonium-241 U -1.45 +/-6.63 5.64 +/-6.63 11.9 pCi/g MXA 04/11/07 1225 623061 I

Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 1.19 +/-0.294 0.127 +/-0.294 0.254 pCi/g MIHI 04/10/07 1135 623177 Americium-241 U 0.0457 +1-0.050 0.0423 +/-0.050 0.0845 pCi/g Bismuth-212 0.520 +/-0.409 0.214 +/-0.409 0.427 pCi/g Bismuth-214 0.852 +/-0.162 0.0505 +/-0.162 0.101 pCi/g Cesium-134 U 0.0382 +/-0.0575 0.0388 +/-0.0575 0.0775 pCi/g Cesium-I 37 U 0.0194 +/-0.0214 0.0301 +/-0.0214 0.0601 pCi/g Cobalt-60 U 0.0138 +/-0.039 0.034 +/-0.039 0.0679 pCi/g Europium-152 U 0.0308 +/-0.116 0.0735 +/-0.116 0.147 pCi/g Europium-i 54 U 0.085 +/-0.118 0.0889 +/-0.118 0.178 pCi/g Europium-I 55 U 0.0524 +/-0.0785 0.0722 +/-0.0785 0.144 pCi/g Lead-212 1.08 +/-0.148 0.0412 +/-0.148 0.0823 pCi/g Lead-214 1.00 +/-0.146 0.0495 +/-0.146 0.0989 pCi/g Manganese-54 U 0.0101 +/-0.0397 0.0307 +/-0.0397 0.0613 pCi/g Niobium-94 U -0.0194 +/-0.0342 0.0273 +/-0.0342 0.0546 pCi/g Potassium-40 14.2 +/-1.61 0.283 +/-1.61 0.565 pCi/g Radium-226 0.852 +/-0.162 0.0505 +/-0.162 0.10 1 pCi/g Silver-108m U 0.0166 +/-0.0281 0.0255 +/-0.0281 0.051 pCi/g Thallium-208 0.308 +/-0.0843 0.0288 +/-0.0843 0.0575 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.0102 +/-0.0243 0.0216 +/-0.0243 0.0486 pCi/g NXL3 04/09/07 1751 623055 Rad Liquid Scintillation Analysis Page 110 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-017F Project: YANK01204 Sample ID: 183607015 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1'%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.645 +1-1.30 1.11 +/-1.30 2.32 pCi/g AXD2 04/07/07 1625 623189 Liquid Scint C14, Solid All, FSS Carbon- 14 U -0.214 +/-0.117 0.102 +/-0.117 0.207 pCi/g AXD2 04/10/07 1504 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 2.45 +/-32.1 22.4 +/-32.1 47.1 pCi/g MXP1 04/11/07 0810 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -7.68 +/-5.92 5.21 +/-5.92 10.8 pCi/g MXP1 04/11/07 0648 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0411 +/-0.269 0.225 +/-0.269 0.464 pCi/g MXPI 04/12/07 0944 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 04/05/07 1039 623034 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- II-RC Modified 3 DOE EML HASL-300, Pu- II-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-i, Modified 11I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Aiphaspec Am241, Cm, Solid ALL 65 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL P55 89 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL Fý 88 (25%-i125%)

Strontium Carrier GFPC, Sr90, solid-ALL F55 76 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 73 (15%-125%)

Page 111 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-017F Project: YANK01204 Sample ID: 183607015 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 86 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 78 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCJMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Anallyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 112 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-018F Project: YANK01204 Sample ID: 183607016 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 5.27%

Parameter Qualifier Result Uncertainty LC TPU MIDA Units DF Analyst Date Time Batch 1A Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.111 +/-0.252 0.177 +1-0.253 0.475 pCilg MXA 04/09/07 1503 623058 Curium-242 U 0.0353 +/-0.0936 0.0417 +/-0.0937 0.209 pCi/g Curium-243/244 U 0.0389 +/-0.189 0.143 +/-0.189 0.406 pCilg Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.00941 +/-0.0713 0.0522 +/-0.0713 0.196 pCilg MXA 04/09/07 1504 623060 Plutonium-239/240

• 0.0685 +/-0.ý118 0.0603 +/-0.119 0.212 pCilg Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -4.5 +/-6.01 5.28 +/-6.01 11.1 pCi/g MXA 04/11/07 1241 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.893 +/-0.332 0.120 +/-0.332 0.241 pCi/g MIHI 04/10/07 1141 623177 Americium-241 U 0.0845 +/-0.0658 0.0558 +/-0.0658 0.112 pCi/g Bismuth-212 UI 0.00 +/-0.410 0.328 +/-0.410 0.656 pCi/g Bismuth-214 0.857 +/-0.186 0.0652 +/-0.186 0.130 pCi/g Cesium-134 U 0.0483 +/-0.0621 0.0398 +/-0.0621 0.0795 pCi/g Cesiumn-i37 0.124 +/-0.0674 0.034 +/-0.0674 0.0679 pCi/g Cobalt-60 U 0.0474 +/-0.0631 0.040 +/-0.0631 0.080 pCi/g Europium-I 52 U -0.0334 +/-0.120 0.0846 +/-0.120 0.169 pCi/g Europium-154 U 0.0732 +/-0.120 0.107 +/-0.120 0.214 pCi/g Europium-iSS Ut 0.00 +/-0.133 0.0815 +/-0. 133 0.163 pCi/g Lead-212 0.942 +/-0.138 0.0545 +/-0.138 0.109 pCi/g Lead-214 0.817 +1-0.151 0.063 +/-0.151 0.126 pCi/g Manganese-54 U 0.0104 +/-0.0482 0.0369 +/-0.0482 0.0737 pCi/g Niobium-94 U 0.00281 +/-0.0385 0.0325 +/-0.0385 0.0649 pCi/g Potassium-40 14.6 +/-1.61 0.299 +/-1.61 0.598 pCi/g Radium-226 0.857 +/-0.186 0.0652 +/-0.186 0.130 pCi/g Silver-108m U 0.0228 +/-0.0356 0.032 +/-0.0356 0.0641 pCi/g Thallium-208 0.268 +/-0.0827 0.033 +/-0.0827 0.066 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.0379 +/-0.0263 0.0168 +/-0.0263 0.0396 pCi/g NXL3 04/09/07 2049 623055 Rad Liquid Scintillation Analysis Page 113 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801-0000-01 8F Project: YANK01 204 Sample ID: 183607016 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.294 +1-1.40 1.18 +/-1.40 2.46 pCi/g AXD2 04/07/07 1728 623189 Liquid Scint C14, Solid All, FSS Carbon-14 U -0.172 +/-0.115 0.0998 +/-0.115 0.203 pCi/g AXD2 04/08/07 0025 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -7.18 +1-25.5 18.2 +1-25.5 38.4 pCi/g MXPI 04/11/07 0826 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -1.65 +/-7.17 6.07 +/-7.17 12.5 pCi/g MXPl 04/11/07 0720 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0909 +1-0.256 0.212 +/-0.256 0.438 pCi/g MXP1 04/12/07 1006 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-i 1-RC Modified 3 DOE EML HASL-300, Pu- I I1-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 DOE RESL Fe-I, Modified 9 DOE RESL Ni-I, Modified 10 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24I, Cm, Solid ALL 75 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 89 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL Fý 96 (25%-125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 71 (25%-125%)

Iron-S 9 Tracer Liquid Scint Fe55, Solid-ALL FS 74 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 75 (25%-125%)

Page 114 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-018F Project: YANK01204 Sample ID: 183607016 Client ID: YANKOO I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 85 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 115 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-019F Project: YANK01204 Sample ID: 183607017 Client ID: YANKOO 1 Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 7.71%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U -0.129 +/-0.118 0.153 +/-0.119 0.413 pCi/g MXA 04/09/07 1503 623058 Curium-242 U 0.0115 +/-0.087 0.0637 +/-0.087 0.239 pCi/g Curium-243/244 U 0.125 +/-0.233 0.157 +/-0.233 0.421 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0944 +/-0.137 0.0676 +/-0.137 0.227 pCi/g MXA 04/09/07 1504 623060 1

Plutonium-239/240 U 0.035 1 +/-0.0987 0.0605 +/-0.0987 0.2 12 pCi/g Liquid Scint Pu24J1, Solid-ALL FSS Plutonium-241 U -2.91 +/-6.52 5.62 +/-6.52 11.9 pCi/g MXA 04/11/07 1257 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.748 +/-0.265 0.0933 +/-0.265 0.187 pCi/g MIHi 04/10/07 1142 623177 Americium-241 U 0.0106 F/-0.0462 0.037 1 +/-0.0462 0.0742 pCi/g Bismuth-212 U 0.449 +/-0.453 0.284 +/-0.453 0.567 pCi/g Bismuth-214 UIl 0.00 +/-0.154 0.113 +/-0.154 0.226 pCi/g Cesium-134 U 0.0109 F/-0.0407 0.0363 +/-0.0407 0.0725 pCi/g Cesium-137 U 0.0157 F/-0.0349 0.0319 +/-0.0349 0.0637 pCi/g Cobalt-60 U 0.0202 F/-0.0306 0.0284 +/-0.0306 0.0567 pCi/g Europium-152 U -0.0533 +/-0.142 0.0664 +/-0.142 0.133 pCi/g Europium-154 U -0.0614 +/-0.116 0.0895 +/-0.116 0.179 pCi/g Europium-155 U 0.0252 +/-0.0666 0.0598 +/-0.0666 0.120 pCi/g Lead-212 0.711 +/-0.0987 0.0353 +/-0.0987 0.0705 pCi/g Lead-214 0.642 +/-0.133 0.0467 +/-0.133 0.0933 pCi/g Manganese-54 U -0.0235 +/-0.0346 0.0276 +/-0.0346 0.055 1 pCi/g Niobium-94 U 0.01 28 +/-0.0308 0.028 +/-6.0308 0.056 pCi/g Potassium-40 10.7 +/-1.24 0.354 +/-1.24 0.707 pCi/g Radium-226 0.58 1 +/-0.154 0.0483 +/-0.154 0.0965 pCi/g Silver-108m U 0.0301 +/-0.0289 0.0244 +/-0.0289 0.0488 pCi/g Thallium-208 0.155 +/-0.0692 0.0271 +/-0.0692 0.0541 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.0348 +/-0.0258 0.0168 +/-0.0258 0.0395 pCi/g NXL3 04/09/07 2049 623055 Rad Liquid Scintillation Analysis Page 116 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.comn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April1 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-01 9F Project: YANK01 204 Sample ID: 183607017 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis ISC, Tritium Dist, Solid - 3 pCIg Tritium U 0.192 +/-1.39 1.16 +/-1.39 2.41 pCi/g AXD2 04/07/07 1830 623189 Liquid Scint C14, Solid All, FSS Carbon- 14 U -0.206 +/-0.111 0.0964 +/-0.111 0.196 pCi/g AXD2 04/10/07 1607 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -11.9 +/-31.1 22.2 +/-31.1 46.9 pCi/g MXP1 04/11/07 0843 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -2.66 +/-6.28 5.36 +/-6.28 11.1 pCi/g MXPI 04/11/07 1543 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.109 +/-0.240 0.205 +/-0.240 0.424 pCi/g MXP1 04/12/07 1027 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- I I-RC Modified 3 DOE EML HASL-300, Pu- I I -RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA FERF C-01 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-i, Modified I1I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 76 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 85 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu24l, Solid-ALL FS 89 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 83 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL ES 70 (15%-125%)

Page 117 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-01 9F Project: YANK01 204 Sample ID: 183607017 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 81 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 86 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 118 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801 -0000-020F Proiect: YANK0 1204 Sample ID: 183607018 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 8.35%

Parameter Qualifier Result Uncertainty LC TPU NMA Units DF Analyst Date Time Batch A Rad Alpha Spec Analysis Alp/rnspec Am24J1, Cm, Solid ALL FSS Americium-241 U 0.0652 +/-0.122 0.0674 +/-0.122 0.226 pCi/g MXA 04/10/07 1232 623058 Curium-242 U -0.00846 +/-0.0711 0.03 16 +/-0.0711 0.159 pCi/g Curium-243/244 U -0.0309 +/-0.0796 0.0853 +/-0.0797 0.262 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00667 +/-0.0742 0.0669 +/-0.0742 0.224 pCi/g MXA 04/09/07 1504 623060 1

Plutonium-239/240 U 0.012 +/-0.125 0.0992 +/-0.125 0.289 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -2.95 +/-7.16 6.16 +/-7.16 13.0 pCi/g MXA 04/11/07 2003 623061 1

Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.592 +/-0.140 0.0502 +/-0.140 0.100 pCi/g MJH1 04/10/07 1246 623177 Americium-241 U- 0.00425 +/-0.0671 0.0538 +/-0.0671 0.108 pCi/g Bismuth-212 UI 0.00 +/-0.198 0.126 +/-0.198 0.252 pCi/g Bismuth-214 UI 0.00 +/-0.0793 0.0536 +/-0.0793 0.107 pCi/g Cesium-I 34 U 0.01 96 +/-0.0241 0.0159 +/-0.0241 0.0318 pCi/g Cesium-137 U 0.00994 +/-0.0164 0.0146 +/-0.0164 0.0293 pCi/g Cobalt-60 U- 0.00879 +/-0.0157 0.0128 +/-0.01 57 0.0256 pCi/g Europium-152 U -0.0252 +/-0.0545 0.035 +/-0.0545 0.0699 pCi/g Europium-154 U -0.0151 +/-0.0503 0.0399 +/-0.0503 0.0798 pCi/g Europium-I155 U 0.0174 +/-0.0451 0.0425 +/-0.0451 0.0849 pCi/g Lead-21 2 0.589 +/-0.0624 0.0206 +/-0.0624 0.0412 pCi/g Lead-21 4 0.557 +/-0.0795 0.025 +/-0.0795 0.0499 pCi/g Manganese-54 U 0.022 +/-0.01 69 0.014 +/-0.0169 0.028 pCi/g Niobium-94 U - 0.00563 +/-0.01 39 0.0117 +/-0.0139 0.0233 pCi/g Potassium-40 U1 0.00 +/-0.809 0.643 +/-0.809 1.28 pCi/g Radium-226 0.428 +/-0.0793 0.0285 +/-0.0793 0.0569 pCi/g Silver-108m U - 0.00245 +/-0.0141 0.0121 +/-0.0141 0.0241 pCi/g Thallium-208 0.168 +/-0.0322 0.01 28 +/-0.0322 0.0256 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.0199 +/-0.0274 0.0204 +/-0.0274 0.047 1 pCi/g NXL3 04/09/07 2049 623055 Rad Liquid Scintillation Analysis Page 119 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-020F Project: YANK01204 Sample ID: 183607018 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U 0.0812 +/-1.46 1.22 +/-1.46 2.55 pCi/g AXD2 04/07/07 1932 623189 Liquid Scint C14, Solid All, FSS Carbon- 14 U -0.127 +/-0.119 0.102 +/-0.119 0.208 pCi/g AXD2 04/10/07 1711 623192 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -35.9 +/-65.2 46.5 +/-65.2 97.4 pCi/g MXPI 04/11/07 0900 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -5.04 +/-6.61 5.70 +/-6.61 11.8 pCi/g MXP1 04/11/07 1614 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0551 +/-0.247 0.209 +/-0.247 0.432 pCi/g MXP1 04/12/07 1049 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 04/05/07 1039 623034 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- II-RC Modified 4 DOE EML HASL-300, Pu-l I-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-i, Modified 11I DOE RESL Ni-i, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 88 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 92 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 89 (25%-I125%)

(25%-1 25%)

Page 120 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801-0000-020F Project: YANK01204 Sample ID: 183607018 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Strontium Carrier GFPC, Sr90, solid-ALL FSS 82 Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 70 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 75 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 86 (15%-1 25%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 121 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-021 F Project: YANK0 1204 Sample ID: 183607019 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 5.42%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Alpha Spec Analysis Aiphaspec Am24J1, Cm, Solid ALL FSS Americium-241 U -0.0445 +/-0.0479 0.076 +/-0.0483 0.246 pCi/g MXA 04/09/07 1503 623058 1

Curium-242 U 0.0188 +/-0.0749 0.0459 +/-0.0749 0.190 pCi/g Curium-243/244 U -0.00415 +/-0.131 0.112 +/-0.131 pCi/g 0.318 Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0427 +/-0.0963 0.0518 +/-0.0964 0.194 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U 0.00267 +/-0.102 0.0846 +/-0.103 0.260 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -0.205 +/-7.28 6.12 +/-7.28 12.9 pCi/g MXA 04/11/07 2020 623061 1

Rad Gamma Spec Analysis Gamma,So/id-FSS GAM & ALL ['55 226 In growth Waived Actinium-228 0.57 1 +/-0.219 0.0889 +/-0.2 19 0.178 pCi/g MJHI 04/10/07 1412 623177 Americium-241 U 0.01 08 +/-0.0388 0.0328 +/-0.0388 0.0656 pCi/g Bismuth-2 12 0.565 +/-0.264 0.184 +/-0.264 0.369 pCi/g Bismuth-214 0.511 +/-0.123 0.0458 +/-0.123 0.09 15 pCi/g Cesium-134 UI 0.00 +/-0.035 0.0275 +/-0.035 0.055 pCi/g Cesium-137 U 0.0151 +/-0.04 15 0.0259 +/-0.0415 0.0517 pCi/g Cobalt-60 U -0.0126 +/-0.0342 0.0225 +/-0.0342 0.045 pCi/g Europium-152 U -0.0691 +/-0.0859 0.0577 +/-0.0859 0.115 pCi/g Europium-154 U 0.129 +/-0.210 0.0813 +/-0.210 0.162 pCi/g Europium-ISS U 0.0254 +/-0.0618 0.0577 +/-0.0618 0.115 pCi/g Lead-21 2 0.646 +/-0.101 0.0333 +/-0.101 0.0666 pCi/g Lead-214 0.542 +/-0.110 0.0411 4/-0.110 0.0822 pCi/g Manganese-54 U -0.0149 +/-0.0276 0.0229 +/-0.0276 0.0457 pCi/g Niobium-94 U 0.0198 +/-0.0264 0.0239 +/-0.0264 0.0478 pCi/g Potassium-40 10.1 +/-1.13 0.226 +/-1.13 0.453 pCi/g Radium-226 0.511 +/-0.123 0.0458 +/-0.123 0.0915 pCi/g Silver-108m U 0.00677 +/-0.0215 0.01 95 +/-0.0215 0.0389 pCi/g Thallium-208 0.197 +/-0.0642 0.0223 +/-0.0642 0.0445 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL ['55 Strontium-90 U - 0.00732 +/-0.0223 0.0197 +/-0.0223 0.0452 pCi/g NXL3 04/09/07 2049 623055 Rad Liquid Scintillation Analysis Page 122 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-021F Proiect: YANK0 1204 Sample ID: 183607019 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rnd Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.593 +/-1.39 1.19 +/-1.39 2.48 pCi/g AXD2 04/07/07 2035 623189 Liquid Scint 014, Solid All, FSS Carbon-14 U -0.149 +/-0.110 0.0951 +/-0.110 0.194 pCi/g AXD2 04/10/07 1815 623192 Liquid Scint FeSS, Solid-ALL ESS Iron-55 U 8.18 +/-36.2 25.0 +/-36.2 52.7 pCilg MXPI 04/11/07 0916 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -4.79 +/-6.44 5.55 +/-6.44 11.5 pCilg MXP1 04/11/07 1646 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.307 +/-0.234 0.206 +/-0.234 0.425 pCi/g MXPI 04/12/07 1110 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-lI1-RC Modified 3 DOE EML HASL-300, Pu- II-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-l, Modified 10 DOE RESL Ni-I, Modified 11I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 84 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 90 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL Fý 90 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL F55 83 (25%-I 25%)

Iron-S 9 Tracer Liquid Scint Fe55, Solid-ALL FS 72 (15%-I125%)

Page 123 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-021F Project: YANK01204 Sample ID: 183607019 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU NMA Units DF Analyst Date Time Batch A~

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 79 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 86 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 124 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-022F Project: YANKO] 204 Sample ID: 183607020 Client ID: YANKOO I Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 10.3%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Alphaspec Am24J, Cm, Solid ALL FSS Americium-241 U -0.0767 +/-0.167 0.163 +/-0.168 0.414 pCi/g MXA 04/09/07 1503 623058 Curium-242 U -0.0565 +/-0.0419 0.0799 +/-0.0425 0.251 pCi/g Curium-243/244 U -0.167 +1-0.159 0.180 +/-0.160 0.449 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0415 +/-0.117 0.0716 +/-0.117 0.251 pCi/g MXA 04/09/07 1504 623060 Plutonium-239/240 U -0.0287 +/-0.0325 0.062 +/-0.0326 0.232 pCi/g Liquid Scint Pu24J, Solid-ALL ['55 Plutonium-241 U -2.12 +/-6.75 5.77 +/-6.75 12.2 pCi/g MXA 04/11/07 2036 623061 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL F'55226 In growth Waived Actinium-228 0.710 +/-0.249 0.122 +/-0.249 0.244 pCi/g MIHI 04/10/07 1413 623177 Americium-241 U 0.0657 +/-0.059 0.0504 +/-0.059 0.101 pCi/g Bismuth-212 U 0.593 +/-0.538 0.309 +/-0.538 0.618 pCi/g Bismuth-214 0.698 +/-0.152 0.0566 +/-0.152 0.113 pCi/g Cesium-l 34 U 0.0438 ý1-0.0446 0.0415 +1-0.0446 0.0829 pCi/g Cesium-137 0.146 F/-0.0552 0.0329 +/-0.0552 0.0659 pCi/g Cobalt-60 U 0.0527 +/-0.0408 0.0373 +/-0.0408 0.0745 pCi/g Europium-152 U -0.0361 +/-0.102 0.0802 +/-0.102 0.160 pCi/g Europium-154 U -0.0473 +1-0.119 0.0955 +/-0.119 0.191 pCi/g Europium-ISS U 0.0274 +/-0.0864 0.0787 +/-0.0864 0.157 pCi/g Lead-212 0.784 +/-0.106 0.0429 +/-0.106 0.0858 pCi/g Lead-214 0.717 +/-0.142 0.0602 +/-0.142 0.120 pCi/g Manganese-54 U -0.0102 +/-0.036 1 0.0307 +/-0.0361 0.0614 pCi/g Niobium-94 U 0.033 +/-0.035 1 0.0316 +/-0.0351 0.0632 pCi/g Potassium-40 10.6 +/-1.23 0.220 +/-1.23 0.441 pCi/g Radium-226 0.698 +/-0. 152 0.0566 +/-0.152 0.113 pCi/g Silver-lO8rm U 0.0329 +/-0.0326 0.0302 +/-0.0326 0.0603 pCi/g Thallium-208 0.290 +/-0.0829 0.0305 +/-0.0829 0.0609 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U -0.00713 +/-0.019 0.0171 +/-0.019 0.0396 pCi/g NXL3 04/09/07 2049 623055 Rad Liquid Scintillation Analysis Page 125 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-022F Project: YANK0 1204 Sample ID: 183607020 Client ID: YANKOO I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U 0.141 +/-1.45 1.21 +/-1.45 2.53 pCi/g AXD2 04/07/07 2137 623189 Liquid Scint 014, Solid All, FSS Carbon- 14 U -0.173 +/-0.114 0.0986 +/-0.114 0.201 pCi/g AXD2 04/10/07 1918 623192 Liquid Scint FeSS, Solid-ALL FSS Iron-55 87.6 +/-41.4 26.3 +/-41.9 55.3 pCi/g MXPI 04/11/07 0933 623181 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -6.01 +/-5.87 5.11 +/-5.87 10.6 pCilg MXPI 04/11/07 1717 623183 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0301 +/-0.276 0.232 +/-0.276 0.480 pCi/g MXPI 04/12/07 1132 623185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623034 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu- I I -RC Modified 3 DOE EML HASL-300, Pu- I1-RC Modified 4 EML HASL 300,4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified 11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24I, Cm, Solid ALL 87 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL F55 77 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 95 (25%-125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 90 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 68 (15%-I 25%)

Page 126 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 C lient Sample ID: 9801l-O000-022F Project: YANK0 1204 Sample ID: 183607020 Client ID: YANKOOlI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 75 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 127 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-022FS Project: YANK01204 Sample ID: 183607021 Client ID: YANKOOlI Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 10.5%

Parameter Qualifier Result Uncertainty LC TPU NMA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am24 1, Cm, Solid ALL FSS Americium-241 U 0.( +/-0.123 0.071 +/-0.124 0.223 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U -0.( +/-0.0328 0.0626 +/-0.0332 0.210 pCi/g Curium-243/244 U -0.( +/-0.0776 0.0969 +/-0.078 0.275 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.( )268 +/-0.069 0.0739 +/-0.069 0.227 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U -0 .014 +/-0.0194 0.037 +/-0.0194 0.153 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U 1.79 +/-6.70 5.56 +/-6.71 11.6 pCi/g PXH2 04/10/07 1409 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.707 +/-0.170 0.0725 +/-0.170 0.145 pCi/g MJH1 04/10/07 1544 623178 Americium-241 U 0.0448 +/-0.0929 0.0808 +/-0.0929 0.162 pCi/g Bismuth-212 UI 0.00 +/-0.273 0.182 +/-0.273 0.363 pCi/g Bisniuth-214 0.657 +/-0.0975 0.0361 +/-0.0975 0.0722 pCi/g Cesium-134 U -0.00526 +/-0.030 0.022 +/-0.030 0.0439 pCi/g Cesium-137 0.0728 +/-0.0316 0.0191 +/-0.0316 0.0382 pCi/g Cobalt-60 U 0.0217 +/-0.0227 0.02 12 +/-0.0227 0.0423 pCi/g Europium-152 U 0.0601 +/-0.0716 0.0512 +/-0.0716 0.102 pCi/g Europium-154 U -0.0391 +/-0.0703 0.0569 +/-0.0703 0.114 pCi/g Europium-ISS U 0.0416 +/-0.0752 0.057 +/-0.0752 0.114 pCi/g Lead-21 2 0.645 +/-0.0765 0.0289 +/-0.0765 0.0579 pCi/g Lead-21 4 0.807 +/-0.110 0.0354 +/-0.110 0.0708 pCi/g Manganese-54 U 0.00298 +/-0.0251 0.0195 +/-0.0251 0.039 pCi/g Niobium-94 U 0.00122 +/-0.0196 0.0174 +/-0.0196 0.0348 pCi/g Potassium-40 11.2 +/-1.03 0.181 +/-1.03 0.361 pCi/g Radium-226 0.657 +/-0.0975 0.0361 +/-0.0975 0.0722 pCi/g Silver-108m U -0.00199 +/-0.0197 0.0177 +/-0.0197 0.0353 pCi/g Thallium-208 0.246 +/-0.0523 0.0179 +/-0.0523 0.0358 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.000885 +/-0.0246 0.0206 +/-0.0246 0.0457 pCi/g KSDI 04/09/07 2055 623056 Rad Liquid Scintillation Analysis LSG, Tritium Dist, Solid - 3 pCilg Tritium U -0.431 +/-1.20 1.03 +/-1.20 2.17 pCi/g AXD2 04/09/07 1613 623190 Page 128 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 980 1-0000-022FS Project: YANK0 1204 Sample ID: 183607021 Client ID: YANKOO I Vol. Recv ParameterQ lualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint 014, Solid All, FSS Carbon- 14 U -0.119 +/-0.115 0.0999 +1-0.115 0.206 pCi/g AXD2 04/10/07 1627 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -1.39 +/-29.5 20.9 +/-29.5 44.0 pCi/g MXPI 04/12/07 1157 623182 Liquid Scint Ni6-3, Solid-ALL FSS Nickel-63 U -0.65 +/-11.0 9.24 +/-11.0 19.1 pCi/g MXPI 04/10/07 1815 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.115 +/-0.248 0.212 +/-0.248 0.440 pCi/g MXPI 04/11/07 1642 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 1MBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I Il-RC Modified 4 DOE EML HASL-300, Pur-I I-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified II DOE EML HASL-300, Tc-02-RC Modified Surrogate/T racer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 91 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 98 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu24I, Solid-ALL FS 103 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL F55 72 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 67 (15%-I125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 85 (25%-I 25%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 69 (15%-125%)

Page 129 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-022FS Project: YANK01204 Sample ID: 183607021 Client ID: YANKOOlI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU NMA Units DF Analyst Date Time Batch 1%

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy---Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 130 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-023F Project: YANK01 204 Sample ID: 183607022 Client ID: YANKOO 1 Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 12.4%

Parameter Qualifier Result Uncertainty LC TPU MIDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Alpha spec Am24J, Cm, Solid ALL FSS Americium-241 U 0.0275 +/-0.160 0.125 +/-0.160 0.339 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.104 +/-0.138 0.0614 +/-0.139 0.216 pCi/g Curium-243/244 U --0.0171 +/-0.162 0.141 +/-0.162 0.371 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0204 +1-0.126 0.0966 +1-0.126 0.285 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.0517 +/-0.097 0.0432 +1-0.0971 0.179 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U 3.14 +/-7.09 5.84 +/-7.10 12.1 pCi/g PXH2 04/11/07 0824 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 1.03 +1-0.285 0.107 +1-0.285 0.214 pCi/g MJHI 04/12/07 0906 623178 Americium-241 U 0.0136 +/-0.058 0.0492 +/-0.058 0.0984 pCi/g Bismuth-212 UI 0.00 +/-0.445 0.316 +/-0.445 0.632 pCi/g Bismuth-214 1.14 +/-0.173 0.058 +/-0.173 0.116 pCi/g Cesium-134 U 0.0641 +/-0.0579 0.0375 +1-0.0579 0.0749 pCi/g Cesium-137 0.109 +/-0.0634 0.0334 +/-0.0634 0.0667 pCi/g Cobalt-60 U -0.0263 +/-0.0359 0.0276 +/-0.0359 0.0552 pCi/g Europium-152 U 0.0493 +/-0.106 0.0814 +/-0.106 0.163 pCi/g Europium-154 U 0.00427 +/-0.109 0.0926 +/-0.109 0.185 pCi/g Europium- 155 U -0.0148 +/-0.0831 0.0764 +/-0.0831 0.153 pCi/g Lead-212 0.933 +/-0.119 0.0427 +/-0.119 0.0853 pCi/g Lead-214 0.968 +/-0.150 0.0547 +1-0.150 0.109 pCi/g Manganese-54 U -0.0274 +/-0.0349 0.0289 +/-0.0349 0.0578 pCi/g Niobium-94 U 0.0163 +/-0.0347 0.0306 +/-0.0347 0.0611 pCi/g Potassium-40 11.4 +/-1.21 0.233 +/-1.21 0.466 pCi/g Radium-226 1.14 +/-0.173 0.058 +/-0.173 0.116 pCi/g Silver-108m U 0.000244 +/-0.0308 0.0274 +/-0.0308 0.0547 pCi/g TIhallium-208 0.263 +/-0.079 0.0283 +/-0.079 0.0566 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U -0.00786 +/-0.0199 0.0179 +/-0.0199 0.0417 pCi/g KSDI 04/09/07 2055 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.655 +/-1.27 1.10 +/-1.27 2.31 pCi/g AXD2 04/09/07 1659 623190 Page 131 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-023F Proiect: YANK01204 Sample ID: 183607022 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch i%

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All, FSS Carbon-14 U -0.037 +/-0.120 0.102 +/-0.120 0.211 pCilg AXD2 04/10/07 1659 623194 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U -2.64 ÷/-35.6 24.9 +/-35.6 52.3 pCi/g MXPI 04/12/07 1213 623182 Liquid Scint Ni63, Solid-ALL ESS Nickel-63 U 3.62 +/-11.6 9.62 +/-11.6 19.9 pCilg MXP1 04/10/07 1832 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.152 +/-0.263 0.226 +/-0.263 0.470 pCilg MXP1 04/11/07 1708 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL.-300, Pu- I I-RC Modified 4 DOE EML HASL-300, Pu- I I-RC Modified 5 EML HASL 300,4.5.2.3 6 EML HASL 300, 4.5.2.3 7 EPA 905.0 Modified 8 EPA 906.0 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-i, Modified 11 DOE RESL Ni-I, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 85 (15%-I125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 99 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 99 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 78 (25%-1 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 74 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 76 (25%-I125%)

Page 132 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-023F Project: YANK01204 Sample ID: 183607022 Client ID: YANKOOlI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU NMA Units DF Analyst Date Time Batch A Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 65 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by CC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 133 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-024F Project: YANK01204 Sample ID: 183607023 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 5.15%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U 0.0895 +/-0.119 0.0424 +/-0.119 0.175 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U- -0.0167 +/-0.0722 0.0442 +/-0.0722 0.183 pCi/g Curium-243/244 U -0.0134 +1-0. 105 0.0949 +1-0.105 0.280 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.096 +/-0.153 0.0824 +/-0.154 0.267 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.153 +/-0.187 0.0952 +/-0.188 0.292 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -1.52 +/-7.40 6.27 +/-7.40 13.0 pCi/g PXH2 04/11/07 0916 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.32 +/-0.327 0.119 +/-0.327 0.239 pCi/g MIHI 04/10/07 1618 623178 Americium-241 U 0.0409 4-0.0667 0.05 13 +/-0.0667 0.103 pCi/g Bismuth-212 0.680 +/-0.393 0.249 +/-0.393 0.497 pCi/g Bismuth-214 1.31 +/-0.242 0.061 1 +/-0.242 0.122 pCi/g Cesium-I 34 UI 0.00 +/-0.055 0.0424 +/-0.055 0.0847 pCi/g Cesium-137 U 0.0294 /-0.0325 0.0372 +/-0.0325 0.0743 pCi/g Cobalt-60 U -0.00649 +1-0.053 0.037 +/-0.053 0.074 pCi/g Europium-152 U -0.106 +/-0.119 0.0787 +/-0,A19 0.157 pCi/g Europium-154 U -0.00187 +/-0.121 0.101 +/-0.121 0.202 pCi/g Europium-155 U 0.0357 +/-0.118 0.0806 +/-0.118 0.161 pCi/g Lead-212 1.38 +/-0.184 0.0452 +/-0.184 0.0903 pCi/g Lead-214 1.61 +/-0.231 0.0583 +/-0.231 0.116 pCi/g Manganese-54 U 0.0489 d-0.0375 0.0355 +/-0.0375 0.071 pCi/g Niobium-94 U 0.038 +/-0.037 0.0333 +/-0.037 0.0666 pCi/g Potassium-40 20.3 +/-2.00 0.291 +/-2.00 0.582 pCi/g Radium-226 1.31 +/-0.242 0.0611 +/-0.242 0.122 pCi/g Silver-108m U -0.0268 F/-0.03 18 0.026 +/-0.0318 0.0519 pCi/g Thallium-208 0.431 4-0.0873 0.03 19 +/-0.0873 0.0637 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.0111 d-0.0269 0.0212 +/-0.0269 0.0483 pCi/g KSDI 04/09/07 2055 623056 Rad Liquid Scintillation Analysis LSC, Tritiumn Dist, Solid - 3 pCilg Tritium U 0.275 +/-1.28 1.06 +/-1.28 2.24 pCi/g AXD2 04/09/07 1745 623190 Page 134 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 980 1-0000-024F Project: YANK0 1204 Sample ID: 183607023 Client ID: YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All, FSS Carbon- 14 U 0.00808 +/-0.117 0.0978 +/-0.117 0.202 pCi/g AXD2 04/10/07 1731 623194 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U 17.2 +/-28.9 19.9 +/-28.9 41.9 pCi/g MXP1 04/11/07 2043 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -6.44 +/-12.8 11.0 +/-12.8 22.7 pCi/g MXPI 04/10/07 1848 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0689 +/-0.240 0.204 +/-0.240 0.424 pCi/g MXPI 04/11/07 1735 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I Il-RC Modified 4 DOE EML HASL-300, Pu- II-RC Modified s EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified a EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-l, Modified 11I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 85 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 99 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 91 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 82 (25%-125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 68 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 74 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 71 (15%-125%)

Page 135 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-024F Project: YANKOI1204 Sample ID: 183607023 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +I-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 136 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-025F Project: YANK01204 Sample ID: 183607024 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 6.85%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Aiphaspec Am24J1, Cm, Solid ALL FSS Americium-241 U 0.0308 +/-0.0987 0.0646 +/-0.0988 0.216 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.00 +/-0.0667 0.00 +/-0.0667 0.0922 pCi/g Curium-243/244 U 0.00773 +/-0.172 0.142 +/-0.172 0.371 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0984 +/-0.160 0.0933 +/-0.160 0.280 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U -0.0194 +/-0.153 0.136 +/-0.153 0.365 pCi/g Liquid Scint Pu24J1, Solid-ALL FSS Plutonium-241 U 1.36 +/-8.69 7.24 +/-8.69 15.1 pCi/g PXH2 04/11/07 1007 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.06 +/-0.314 0.127 +/-0.3 14 0.254 pCi/g MJHI 04/10/07 1752 623178 Americium-241 U 0.0244 F/-0.0464 0.0549 +/-0.0464 0.110 pCi/g Bismuth-212 UI 0.00 +/-0.483 0.375 +/-0.483 0.749 pCi/g Bismuth-214 1.08 +/-0.218 0.0626 +/-0.218 0.125 pCi/g Cesium-134 U 0.0439 F/-0.0457 0.0423 +/-0.0457 0.0845 pCi/g Cesium-137 U -0.00553 F/-0.0454 0.038 +/-0.0454 0.0759 pCi/g Cobalt-60 U -0.0372 F/-0.0439 0.0329 +/-0.0439 0.0658 pCi/g Europium-152 U -0.127 +/-0.129 0.0772 +/-0.129 0.154 pCi/g Europium-154 U -0.0574 +/-0.120 0.0946 +/-0.120 0.189 pCi/g Europium-1 55 U 0.0802 F/-0.096 1 0.0881 +/-0.0961 0.176 pCi/g Lead-212 0.943 +/-0. 126 0.0506 +/-0.126 0.101 pCi/g Lead-214 1.07 +/-0.184 0.0635 +/-0.184 0.127 pCi/g Manganese-54 U -0.03 F/1-0.0501 0.035 +/-0.0501 0.070 pCi/g Niobium-94 U -5.630E- F/-0.0369 0.031 +/-0.0369 0.0619 pCi/g 05 Potassium-40 15.5 +/-1.66 0.287 +/-1.66 0.575 pCi/g Radium-226 1.08 +/-0.218 0.0626 +/-0.218 0.125 pCi/g Silver-I 08m U 0.00582 +/0.0343 0.0302 +/-0.0343 0.0603 pCi/g Thallium-208 0.378 ý/-0.0825 0.0342 +/-0.0825 0.0684 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.00185 +/-0.0224 0.0185 +/-0.0224 0.0438 pCi/g KSD1 04/09/07 2055 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, So/id - 3 pCi/g Page 137 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analy:sis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801l-0000-025F Project: YANK0 1204 Sample ID: 183607024 Client ID: YANK0OI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCI/g Tritium U -0.323 +/-1.23 1.05 +/-1.23 2.22 pCi/g AXD2 04/09/07 1832 623190 Liquid Scint C14, Solid All, FSS Carbon- 14 U -0.0879 +/-0.117 0.101 +/-0.117 0.208 pCi/g AXD2 04/10/07 1803 623194 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U -12 +/-32.6 23.0 +/-32.6 48.4 pCi/g MXP1 04/12/07 1229 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 1.19 +/-12.3 10.3 +/-12.3 21.2 pCi/g MXP1 04/10/07 1904 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.189 +/-0.223 0.194 +/-0.223 0.402 pCi/g MXPI 04/11/07 1802 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB1 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I I-RC Modified 4 DOE EML HASL-300, Pu- I1-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-i, Modified 10 DOE RESL Ni-I, Modified I1I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 88 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 99 (15%-I 25%)

Plutonium-242 Tracer Liquid Scint Pu 241, Solid-ALL F5 79 (25%-125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 75 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 75 (15%-125%)

Page 138 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Anallsis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-O000-025F Project: YANKOl1204 Sample ID: 183607024 Client ID: YANKOOlI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 79 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 71 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit

• Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 139 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-026F Project: YANK01 204 Sample ID: 183607025 Client ID: YANK00l Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 7.02%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U 0.0221 +/-0.101 0.072 +/-0.101 0.233 pCilg PXH2 04/11/07 2315 624198 Curium-242 U 0.0263 +/-0.0698 0.03 11 +/-0.0698 0.156 pCilg Curium-243/244 U - -0.0131 +/-0.103 0.093 +/-0.103 0.275 pCilg Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.124 +/-0.187 0.110 +/-0.187 0.320 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.0207 +/-0.111 0.0813 +/-0.111 0.263 pCilg Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -8.12 +/-6.84 6.04 +/-6.84 12.6 pCilg PXH2 04/11/07 1058 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.626 +/-0.222 0.0737 +/-0.222 0.147 pCilg MJH1 04/10/07 1752 623178 Americium-241 U 0.032 +/-0.0394 0.0361 +/-0.0394 0.0721 pCilg Bismuth-212 U 0.127 +/-0.370 0.227 +/-0.370 0.453 pCilg Bismuth-214 0.593 +/-0.116 0.0497 +/-0.116 0.0993 pCi/g Cesium-134 U 0.023 +/-0.0311 0.0294 +/-0.0311 0.0587 pCilg Cesium-137 U 0.0278 +/-0.0369 0.0239 +/-0.0369 0.0478 pCilg Cobalt-60 U 0.0303 +/-0.0332 0.0255 +/-0.0332 0.051 pCilg Europium-152 U 0.00997 +/-0.0714 0.0581 +/-0.0714 0.116 pCilg Europium-154 U -0.0752 +/-0.0918 0.067 1 +/-0.0918 0.134 pCilg Europium-iSS U 0.0211 +/-0.0584 0.0557 +/-0.0584 0.111 pCilg Lead-212 0.605 +/-0.0831 0.0298 +/-0.0831 0.0596 pCilg Lead-214 0.557 +/-0.0991 0.0365 +/-0.0991 0.073 pCilg Manganese-54 UI 0.00 +/-0.0383 0.0232 +/-0.0383 0.0464 pCi/g Niobium-94 U -0.0096 1 +/-0.0256 0.0207 +/-0.0256 0.0414 pCi/g Potassium-40 9.95 +/-1.11 0.226 +/-1.11 0.451 pCilg Radium-226 0.593 +/-0.116 0.0497 +/-0.116 0.0993 pCilg Silver-108m U -0.0155 +/-0.0228 0.0191 +/-0.0228 0.0382 pCilg Thallium-208 0.246 +/-0.0561 0.0219 +/-0.0561 0.0437 pCilg Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U -0.00155 +/-0.0273 0.023 +/-0.0273 0.049 pCi/g KSD1 04/09/07 2055 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.467 +/-1.20 1.03 +/-1.20 2.18 pCilg AXD2 04/09/07 1918 623190 Page 140 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-026F Project: YANKO 1204 Sample ID: 183607025 Client ID: YANKOO I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All,FSS Carbon- 14 U -0.0573 +/-0.117 0.100 +/-0.117 0.207 pCi/g AXD2 04/10/07 1835 623194 Liquid Scint FeSS, Solid-ALL ESS Iron-55 U 26.1 +/-26.4 17.8 +/-26.5 37.5 pCi/g MXPI 04/11/07 2116 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -3.39 +/-11.4 9.64 +/-11.4 20.0 pCi/g MXPI 04/10/07 1920 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.146 +/-0.293 0.241 +/-0.293 0.500 pCi/g MXPI 04/11/07 1828 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-i 1-RC Modified 4 DOE EML HASL-300, Pu- I I1-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-0lI Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified I1I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 93 (15 %-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 96 (15%-I125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 92 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 83 (25%-I 25%)

Iron-S 9 Tracer Liquid Scint Fe55, Solid-ALL FS 72 (15%-I 25%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 83 (25%-I125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 62 (15%-I125%)

Page 141 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Anal[3sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-026F Project: YANK01204 Sample ID: 183607025 Client ID: "YANKO0l Vol. Recv.:

Parameter Qualifier Result Uacertainty LC TPU NMA Units DF Analyst Date Time Batch 1%

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 142 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gelicom Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-027F Project: YANK01204 Sample ID: 183607026 Client ID: YANKOG 1 Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 8.27%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch IN Rad Alpha Spec Analysis Aiphaspec Am24J1, Cm, Solid ALL FSS Americium-241 U -0.047 ý/-0.0429 0.07 16 +/-0.0432 0.225 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.0164 1/-0.0651 0.0399 +/-0.0652 0.165 pCi/g Curium-243/244 U 0.035 +/-0.144 0.108 +/-0.144 0.299 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0314 -F/-0.061 6 0.00 +/-0.0617 0.0851 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U -0.0377 +/-0.033 0.063 +/-0.0333 0.211 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -6.35 +/-6.93 6.06 +/-6.93 12.6 pCi/g PXH2 04/11/07 1150 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.625 +/-0.116 0.0325 +/-0.116 0.0649 pCi/g MJHI 04/10/07 1953 623178 Americium-24 I U 0.0652 - F-/-0.0759 0.0627 +/-0.0759 0.125 pCi/g Bismuth-212 UI 0.00 +/-0.209 0.112 +/-0.209 0.223 pCi/g Bismuth-214 0.574 -F/-0.0743 0.020 +/-0.0743 0.0399 pCi/g Cesium-134 UI 0.00 - 1/-0.0203 0.01 32 +/-0.0203 0.0263 pCi/g Cesium-137 0.0614 -ý4-0.01 73 0.0116 +/-0.0173 0.0233 pCi/g Cobalt-60 U 0.0115 -F/-0.01 78 0.0 112 +/-0.0178 0.0225 pCi/g Europium-152 U -0.0259 -+/-0.0368 0.0293 +/-0.0368 0.0586 pCi/g Europium-l 54 U -0.0207 -+/-0.0401 0.0326 +/-0.0401 0.0652 pCi/g Europium-155 U 0.0535 -F/-0.0517 0.0344 +/-0.0517 0.0687 pCi/g Lead-212 0.682 -+/-0.0634 0.01 65 +/-0.0634 0.0329 pCi/g Lead-214 0.637 -+/-0.0708 0.0205 +/-0.0708 0.0409 pCi/g Manganese-54 U 0.00113 -ý/-0.0143 0.0109 +1-0.0143 0.02 17 pCi/g Niobium-94 U -0.00205 -+/-0.0l 19 0.010 +/-0.0119 0.0201 pCi/g Potassium-40 10.1 +/-0.825 0.0814 +/-0.825 0.163 pCi/g Radium-226 0.574 -+/-0.0743 0.020 +/-0.0743 0.0399 pCi/g Silver-l O8m U 0.0101 -+/-0.01 07 0.0098 +/-0.0107 0.01 96 pCi/g Thallium-208 0.186 +/-0.0282 0.01 06 +i/-0.0282 0.0213 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00941 +/-0.019 0.0173 +/-0.019 0.0398 pCi/g KSD1 04/10/07 2038 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U -0.796 +/-1.20 1.05 +/-1.20 2.21 pCi/g AXD2 04/09/07 2004 623190 Page 143 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801-0000-027F Project: YANK01 204 Sample ID: 183607026 Client ID: YANK0OI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint 014, Solid All, FSS Carbon-14 U 0.070 +/-0.119 0.0975 +/-0.119 0.201 pCi/g AXD2 04/10/07 1906 623194 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U 4.34 +/-34.9 24.1 +/-34.9 50.7 pCi/g MXP1 04/12/07 1246 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -6.49 +/-10.8 9.23 +/-10.8 19.1 pCi/g MXP1 04/10/07 1937 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0571 +/-0.229 0.191 +/-0.229 0.396 pCi/g MXPI 04/11/07 1855 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- II-RC Modified 4 DOE EML HASL-300, Pu-lI -RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 905.0 Modified 8 EPA 906.0 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-i, Modified I1I DOE RESL Ni-I, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Lim-its Americium-243 Tracer Alphaspec: Am241, Cm, Solid ALL 90 (15%-i125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 90 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu24t, Solid-ALL F5 94 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 77 (25 %-1 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 77 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 81 (25%-125%)

Page 144 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-027F Project: YANK01204 Sample ID: 183607026 Client ID: YANKOQI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 73 (15%-I125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 145 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel~com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-028F Project: YANK01 204 Sample ID: 183607027 Client ID: YANKOO I Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 11.2%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U 0.0725 +/-0.151 0.0955 +/-0.151 0.287 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U - -0.0266 +/-0.0301 0.0575 +/-0.0303 0.215 pCi/g Curium-243/244 U 0.0483 +/-0.242 0.191 +/-0.242 0.478 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -( 0.00734 +/-0.0616 0.0274 +/-0.0617 0.138 pCi/g PXH2 04/09/07 0935 623063 Plutonium-2391240 U- -0.0 147 +/-0.0633 0.0388 +/-0.0633 0.160 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U 0.628 +/-6.98 5.84 +/-6.98 12.1 pCi/g PXH2 04/11/07 1241 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.918 +/-0.173 0.0477 +/-0.173 0.0954 pCi/g MJHI 04/10/07 1953 623178 Americium-241 U 0.0305 +/-0.0252 0.0206 +/-0.0252 0.04 11 pCi/g Bismuth-2 12 0.581 +/-0.221 0.105 +/-0.221 0.209 pCi/g Bismuth-2 14 0.762 +/-0.112 0.0252 +/-0.112 0.0505 pCi/g Cesium-134 U1 0.00 +/-0.0248 0.01 82 +/-0.0248 0.0364 pCi/g Cesium-I 37 0.0614 +/-0.0243 0.0144 +/-0.0243 0.0288 pCi/g Cobalt-60 U 0.0077 +/-0.0193 0.0144 +/-0.0193 0.0287 pCi/g Europium-152 U- 0.00569 +/-0.0499 0.0358 +/-0.0499 0.0715 pCi/g Europium-I 54 U -0.031 +/-0.0529 0.0424 +/-0.0529 0.0848 pCi/g Europium-I 55 U 0.0414 +/-0.047 0.0335 +/-0.047 0.0669 pCi/g Lead-21 2 0.837 +1-0. 103 0.0193 +/-0. 103 0.0386 pCi/g Lead-21 4 0.793 +/-0.0984 0.0258 +/-0.0984 0.05 15 pCi/g Manganese-54 U 0.00446 +/-0.0 184 0.01 39 +/-0.0184 0,0278 pCilg Niobium-94 U 0.00743 +/-0.016 0.0136 +/-0.016 0.0272 pCi/g Potassium-40 11.5 +/-0.9 16 0.112 +/-0.916 0.224 pCi/g Radium-226 0.762 +/-0.112 0.0252 +/-0.112 0.0505 pCi/g Silver-108m U 0.00415 +/-0.0139 0.01 19 +/-0.0139 0.0237 pCi/g Thallium-208 0.246 +/-0.0421 0.014 +/-0.0421 0.028 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0 .000877 +/-0.0208 0.0173 +/-0.0208 0.0408 pCi/g KSDI 04/09/07 2158 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U -0.968 +/-1.13 0.999 +/-1.13 2.11 pCi/g AXD2 04/09/07 2050 623190 Page 146 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-028F Project: YANK01204 Sample ID: 183607027 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All, FSS Carbon-14 U -0.0796 +1-0.119 0.102 +/-0.119 0.210 pCilg AXD2 04/10/07 1939 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 12.5 +/-25.1 17.3 +/-25.1 36.5 pCi/g MXP1 04/11/07 2148 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -2.39 +/-12.0 10.1 +/-12.0 21.0 pCi/g MXPI 04/10/07 1953 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.229 +/-0.263 0.229 +/-0.263 0.475 pCilg MXPI 04/11/07 1922 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-l l-RC Modified 4 DOE EML HASL-300, Pu-l l-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-0lI Modified 9 DOE RESL Fe-i, Modified 10 DOE RESL Ni-l, Modified 11I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24l, Cm, Solid ALL 87 (15%-125%)

Plutonium-242 Tracer Alphaspec Put, Solid-ALL FSS 88 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 97 (25%-125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 75 (25%-I 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 73 (15%-I 25%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 78 (25%-I125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 63 (15%-125%)

Page 147 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801l-0000-028F Project: YANK0 1204 Sample ID: 183607027 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch I%

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result~is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis ID Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy---Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 148 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-029F Project: YANK01204 Sample ID: 183607028 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 9.26%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-24 I * -0.0427 +/-0.0883 0.0972 +/-0.0885 0.287 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.00145 +/-0.0787 0.0649 +/-0.0787 0.228 pCi/g Curium-243/244 U -0.0288 +/-0.133 0.123 +/-0.133 0.339 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0219 +/-0.0581 0.0258 +/-0.0581 0.130 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0,015 +/-0.0596 0.0365 +/-0.0596 0.151 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 0.344 +/-9.95 8.33 +/-9-95 18.0 pCi/g PXH2 04/11/07 1522 623064 Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.809 +/-0.119 0.0293 +/-0.119 0.0586 pCi/g MJHI 04/10/07 1954 623178 Americium-241 U 0. 0321 +/-0.063 8 0.0539 +/-/-0.0638 0.108 pCi/g Bismuth-212 0.667 +/-0.131 0.0628 +/-0.131 0.126 pCi/g Bismuth-214 0.669 +/-/-0.0783 0.0174 +/-0.0783 0.0348 pCi/g Cesium-i 34 UI 0.00 +/-0.019 0.0117 +/-0.019 0.0233 pCi/g Cesium-137 U 0. 0119 +/-/-0.0125 0,00895 +/-0.0125 0.0179 pCi/g Cobalt-60 U 0.0'0244 +/-0.0108 0.00937 +/-0.0108 0.0187 pCi/g Europium-152 U -0. 0172 +/-0.0321 0.0236 +/-0.0321 0.0472 pCi/g Europium-154 U 0.00569 +/-0.0357 0.0267 +/-0.0357 0.0533 pCi/g Europium-I 55 U 0. 0339 +/-0.040 0.030 +/-0.040 0.060 pCi/g Lead-21 2 0.837 +/-0.0736 0.014 +/-0.0736 0.0279 pCi/g Lead-214 0.779 +1-0.0815 0.0167 +/-0.0815 0.0333 pCi/g Manganese-54 U 0. 0127 +/-0.0134 0.00909 +/-0.0134 0.01 82 pCi/g Niobium-94 U 0.0 0543 +/-0.00995 0.0086 +/-0.00995 0.0172 pCi/g Potassium-40 11.0 +/-/-0.758 0.0781 +/-0.758 0.156 pCi/g Radium-226 0.669 +/-0.0783 0.0174 +/-0.0783 0.0348 pCi/g Silver-108m U -0.0 0102 +/-0.0101 0.00783 +/-0.0101 0.0157 pCi/g Thallium-208 0.268 +/-0.0346 0.00854 +/-0.0346 0.0171 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.0 0484 +/-0.0227 0.0184 +/-/-0.0227 0.0424 pCi/g KSDI 04/09/07 2158 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U 2.17 +/-1.39 1.07 +/-/-1.39 2.25 pCi/g AXD2 04/09/07 2137 623190 Page 149 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomidc Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801l-0000-029F Project: YANK01204 Sample ID: 183607028 Client ID: YANKOO I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DIF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All,FSS Carbon-14 U -0.156 +/-0.114 0.0987 +/-0.114 0.201 pCi/g AXD2 04/18/07 1005 625942 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U 6.54 +/-27.5 19.2 +/-27.5 40.5 pCi/g MXPI 04/11/07 2205 623182 Liquid Scint Ni63, Solid-ALL ESS Nickel-63 U -0.234 +/-11.3 9.51 +/-11.3 19.7 pCi/g MXP1 04/10/07 2009 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0966 +/-0.208 0.178 +/-0.208 0.370 pCi/g MXP1 04/11/07 1948 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-1 I-RC Modified 4 DOE EML HASL-300, Pu-IlI -RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 EPA EERF C-01 Modified 10 EPA EERF C-01 Modified 11I DOE RESL Fe-l, Modified 12 DOE RESL Ni-I, Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 95 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 91 (15%-1 25%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL F5 III (25%-125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 76 (25%-I125%)

(1 5%-1 25%)

Page 150 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801l-0000-029F Project: YANK01204 Sample ID: 183607028 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MIDA units DF Analyst Date Time Batch 1'%

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 74 Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 79 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 79 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 151 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston 30 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company :Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-030F Project: YANK01 204 Sample ID: 183607029 Client ID: YANK00l Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 6.73%

Parameter Qualifier Result Uncertainty LC TPU NMA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Alphaspec Am24J, Cm, Solid ALL FSS Americium-241 U 0.112 +/-0.134 0.05 11 +/-0. 134 0.191 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.0261 +/-0.0691 0.0308 +/-0.0692 0.155 pCi/g Curium-243/244 U 0.01 97 +/-0.122 0.0934 +/-0.122 0.276 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0275 +/-0.0538 0.00 +/-0.0539 0.0744 pCi/g PXH2 04/09/07 0935 623063 Plutonium-2391240 U 0.0209 +1-0.0554 0.0246 +/-0.0554 0.124 pCilg Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -2.77 +/-11.2 9.59 +/-11.2 20.8 pCi/g PXH2 04/11/07 1538 623064 Rad Gamma Spec Analysis Gamma,Solid-FSSGAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.861 +/-0.247 0.0829 +/-0.247 0.166 pCi/g MJHl 04/12/07 0906 623178 Americium-241 U 0.0376 +/-0.0203 0.0297 +/-0.0203 0.0594 pCi/g Bismuth-212 U 0.421 +/-0.400 0.216 +/-0.400 0.432 pCi/g Bismuth-214 0.534 +/-0.117 0.0418 +/-0.117 0.0835 pCilg Cesium-I 34 U 0.0296 +/-0.033 0.0263 +/-0.033 0.0525 pCilg Cesium-137 0.0561 +/-0.0311I 0.0203 +/-0.0311 0.0406 pCi/g Cobalt-60 U 0.020 +/-0.032 0.0259 +/-0.032 0.05 17 pCi/g Europium-152 U 0.00375 4-1-0.0738 0.0544 +/-0.0738 0.109 pCi/g Europium-154 U 0.0799 +/-0.0808 0.0741 +/-0.0808 0.148 pCi/g Europium-iSS U 0.0544 +/-0.0684 0.0486 +/-0.0684 0.0972 pCi/g Lead-212 0.654 +/-0.0909 0.0307 +/-0.0909 0.0613 pCi/g Lead-214 0.688 +/-0.118 0.0386 +/-0.118 0.0771 pCi/g Manganese-54 U 0.00702 +/-0.0262 0.0234 +/-0.0262 0.0468 pCi/g Niobium-94 U -0.00601 +/-0.0269 0.01899 +1-0.0268 0.0378 pCi/g Potassium-40 9.98 +/-1.17 0.192 +/-1.17 0.383 pCi/g Radium-226 0.534 +/-0.117 0.0418 +/-0.117 0.0835 pCilg Silver-108m U -0.00183 +1-0.0221 0.0193 +/-0.0221 0.0386 pCi/g Thalliurn-208 0.157 +/-0.0457 0.02 19 +/-0.0457 0.0438 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U -0.00342 +/-0.0245 0.021 +/-0.0245 0.0482 pCi/g KSDI 04/09/07 2158 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U -0.514 +/-1.24 1.06 +/-1.24 2.24 pCi/g AXD2 04/09/07 2223 623190 Page 152 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-030F Project: YANK01204 Sample ID: 183607029 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA units DF Analyst Date Time Batch A Rad Liquid Scintillation Analysis Liquid Scint 014, Solid All, ['55 Carbon-14 U -0.141 +/-0.113 0.0994 +/-0.113 0.205 pCi/g AXD2 04/10/07 2043 623194 Liquid Scint FeSS, Solid-ALL ['55 Iron-55 U -5.54 +/-24.4 17.4 +/-24.4 36.8 pCi/g MXP1 04/11/07 2221 623182 Liquid Scint Ni63, Solid-ALL ['55 Nickel-63 U 4.67 +1-11.5 9.47 +1-11.5 19.6 pCi/g MXP1 04/10/07 2026 623184 Liquid Scint Tc99, Solid-ALL ['55 Technetium-99 U -0.168 +/-0.229 0.198 +/-0.229 0.411 pCi/g MXPI 04/11/07 2015 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-lI1-RC Modified 4 DOE EML HASL-300, Pu-lI 1-RC Modified 5 EML HASL 300, 4.5.2.3 6 EML HASL 300, 4.52.3 7 EPA 905.0 Modified 8 EPA 906.0 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified I1I DOE RESL Ni-I, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 88 (15%-i125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 97 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 97 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL F55 72 (25%-i125%)

lron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 72 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 85 (25%-I 25%)

Page 153 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 980 1-0000-030F Project: YANK01204 Sample ID: 183607029 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 74 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +I-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 154 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-031iF Proiect: YANK01204 Sample ID: 183607030 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 7.84%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.096 +/-0.0812 0.110 +/-0.082 0.299 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.05 32 +1-0.085 0.0271 +1-0.0852 0.136 pCi/g Curium-243/244 U -0.0 104 +/-0.111 0.0973 +/-0.111 0.273 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.00 +/-0.0625 0.00 +/-0.0625 0.0864 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.00 +/-0.0625 0.00 +/-0.0625 0.0864 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -5.59 +/-1.2 9.80 +/-11.2 21.2 pCi/g PXH2 04/11/07 1554 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.715 +/-0.140 0.05 19 +/-0.140 0.104 pCi/g MJH1 04/10/07 1959 623178 Americium-241 U 0.0148 +1-0.0297 0.0246 +/-0.0297 0.0492 pCi/g Bismuth-212 0.521 +/-0.217 0.116 +/-0.217 0.232 pCi/g Bismuth-214 0.763 +/-0.105 0.0277 +/-0.105 0.0554 pCi/g Cesium-134 UI 0.00 +/-0.033 0.0188 +/-0.033 0.0376 pCi/g Cesium-137 U 0.022 +1-0.0319 0.0165 +/-0.03 19 0.033 1 pCi/g Cobalt-60 U 0.00 116 +/-0.018 0.0151 +/-0.018 0.0302 pCi/g Europium-152 U 0.0169 +/-0.0527 0.0391 +/-0.0527 0.078 1 pCi/g Europium-154 U -0.0711 +/-0.0561 0.0436 +/-0.0561 0.0872 pCi/g Europium-155 U 0.0406 +/-0.0569 0.0377 +/-0.0569 0.0754 pCi/g Lead-212 0.807 +/-0.0845 0.0205 +/-0.0845 0.041 pCi/g Lead-214 0.791 +/-0.0975 0.0276 +/-0.0975 0.0552 pCi/g Manganese-54 U 0.0278 +/-0.0152 0.0151 +/-0.0152 0.0302 pCi/g Niobium-94 U 0.0113 +/-0.0172 0.0149 +/-0.0172 0.0298 pCi/g Potassium-40 9.86 +/-0.772 0.128 +/-0.772 0.256 pCi/g Radium-226 0.763 +1-0.105 0.0277 +1-0.105 0.0554 pCi/g Silver-108m U 0.0001 */-0.0175 0.01 33 +/-0.0 175 0.0265 pCi/g Thallium-208 0.240 +/-0.0435 0.0147 +/-0.0435 0.0294 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.0267 +/-0.0192 0.0201 +/-0.0192 0.046 pCi/g KSD1 04/10/07 2038 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.322 +/-1.23 1.05 +/-1.23 2.21 pCi/g AXD2 04/09/07 2309 623190 Page 155 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-031iF Project: YANK01204 Sample ID: 183607030 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1'%

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid AIIFSS Carboni-14 U 0.0407 +/-0.128 0.107 +/-0.128 0.220 pCi/g AXD2 04/10/07 2115 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 16.2 +/-29.2 20.0 +/-29.2 42.1 pCi/g MXP1 04/11/07 2237 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -9.24 +/-10.1 8.75 +/-10.1 18.1 pCi/g MXP1 04/10/07 2042 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.235 +1-0.244 0.213 +1-0.244 0.443 pCi/g MXPI 04/11/07 2041 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- II-RC Modified 4 DOE EML HASL-300, Pu- II-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 905.0 Modified 8 EPA 906.0 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified I1I DOE RESL Ni-i, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 97 (15%-I125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 90 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 95 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 67 (25%-1 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 76 (15%-I125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 81 (25%-i125%)

Page 156 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-031IF Project: YANK01204 Sample ID: 183607030 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1A Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 67 (15%-I125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Anallyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 157 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801l-0000-032F Project: YANKO 1204 Sample ID: 183607031 Client ID: YANKOOI Matrix: TS Vol. Recv.:

Collect Date: 02-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 4.23%

Parameter Qualifier Result Uncertainty LC TPU MDA units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0485 +/-0.100 0.0521 +/-0.101 0.195 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U -0.00839 +/-0.0704 0.0314 +/-0.0705 0.157 pCi/g Curium-243/244 U -0.0684 +/-0.135 0.138 +/-0.135 0.366 pCi/g Aiphaspec Pu, Solid-ALL ESS Plutonium-238 U 0.117 +/-0.123 0.0279 +/-0.123 0.140 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.0236 +/-0.0626 0.0279 +/-0.0626 0.140 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -0.743 +/-11.8 9.99 +/-11.8 21.6 pCi/g PXH2 04/11/07 1610 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.745 +/-0.252 0.0847 +/-0.252 0.169 pCi/g MJHI 04/11/07 0940 623178 Americium-241 U 0.0549 +/-0.0424 0.0372 +/-0.0424 0.0743 pCi/g Bismuth-212 0.469 +/-0.262 0.209 +/-0.262 0.418 pCi/g Bismuth-214 0.692 +/-0.143 0.0394 +/-0. 143 0.0788 pCi/g Cesium-134 U 0.0339 +/-0.0392 0.0309 +/-0.0392 0.06 17 pCi/g Cesium-l 37 U 0.0148 +/-0.0296 0.0264 +/-0.0296 0.0528 pCi/g Cobalt-60 U -0.0284 +/-0.0293 0.0206 +/-0.0293 0.04 12 pCi/g Europium-152 U -0.0746 +/-0.0859 0.0611 +/-0.0859 0.122 pCi/g Europium-154 U -0.0682 +/-0.0919 0.0694 +/-0.0919 0.139 pCi/g Europium-ISS UI 0.00 +/-0.101 0.0597 +/-0.101 0.119 pCi/g Lead-212 0.706 +/-0.104 0.0343 +/-0. 104 0.0685 pCi/g Lead-214 0.650 +/-0.127 0.0472 +/-0.127 0.0942 pCi/g Manganese-54 U 0.036 +/-0.0388 0.0244 +/-0.0388 0.0488 pCi/g Niobium-94 U 0.0217 +/-0.0261 0.0239 +/-0.0261 0.0477 pCi/g Potassium-40 9.80 +/-1.26 0.225 +/-1.26 0.450 pCi/g Radium-226 0.692 +/-0.143 0.0394 +/-0. 143 0.0788 pCi/g Silver-108m U -0.0119 +/-0.0236 0.020 +/-0.0236 0.0399 pCi/g T'hallium-208 0.249 +/-0.059 0.0263 +/-0.059 0.0525 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.0104 +/-0.0225 0.0172 +/-0.0225 0.0407 pCi/g KSDI 04/09/07 2158 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U -1.12 +/-1.21 1.07 +/-1.21 2.26 pCi/g AXD2 04/09/07 2355 623190 Page 158 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.comn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-032F Proiect: YANK01204 Sample ID: 183607031 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All, FSS Carbon-14 U -0.0225 +/-0.121 0.102 +/-0.121 0.210 pCilg AXD2 04/11/07 0349 623194 Liquid Scint Fe5S, Solid-ALL FSS Iron-55 U -20.8 +/-36.4 26.2 +/-36.4 55.1 pCi/g MXP1 04/11/07 2254 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -2.57 +1-10.8 9.13 +/-10.8 18.9 pCi/g MXPI 04/10/07 2058 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.109 +/-0.250 0.206 +1-0.250 0.427 pCi/g MXP1 04/11/07 2108 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 04/05/07 1039 623038 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-I I1-RC Modified 4 DOE EML HASL-300, Pu- I I-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA FERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified 11I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 80 (15%-I125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 86 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 90 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 80 (25%-I 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 72 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 89 (25%-I 25%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL ES 72 (15%-125%)

Page 159 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-032F Project: YANK01204 Sample ID: 183607031 Client ID: YANKOQ I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A' Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCJMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 160 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis CertifirAl"tAn Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-033B Proiect: YANK0 1204 Sample ID: 183607032 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 28-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 7.15%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Alphaspec Am24J, Cm, Solid ALL FSS Americium-241 U -0.0407 +/-0.0346 0.0634 +/-0.0349 0.205 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U -0.0147 +/-0.0636 0.039 +1-0.0636 0.161 pCi/g Curium-243/244 U -0.0254 +/-0.0928 0.0897 +/-0.0928 0.258 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00697 +/-0.0586 0.0261 +/-0.0586 0.131 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.00813 +/-0.0617 0.0451 +/-0.0617 0.169 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -1.13 +/-15.2 12.9 +/-15.2 27.3 pCi/g PXH2 04/12/07 1138 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.14 +/-0.311 0.116 +/-0.3 11 0.231 pCi/g MJHI 04/11/07 0940 623178 Americium-241 U 0.0368 +/-0.067 0.0557 +/-0.067 0.111 pCi/g Bismuth-212 UI 0.00 +/-0.43 1 0.343 +/-0.431 0.685 pCi/g Bismuth-214 0.911 +/-0. 171 0.0644 +/-0. 171 0.129 pCi/g Cesium-134 U 0.0393 +/-0.07 12 0.0441 +/-0.0712 0.0882 pCi/g Cesium-137 U 0.0157 +/-0.0442 0.0383 +/-0.0442 0.0765 pCi/g Cobalt-60 U 0.0217 +/-0.0437 0.0384 +/-0.0437 0.0767 pCi/g Europium-152 U 0.0159 +/-0.l111 0.0903 +/-0.111 0.181 pCi/g Europium-154 U 0.228 +/-0. 140 0.125 +/-0.140 0.249 pCi/g Europium-iSS U 0.0233 +/-0.0984 0.0828 +/-0.0984 0.166 pCi/g Lead-212 0.949 +/-0.123 0.0479 +/-0.123 0.0957 pCi/g Lead-214 0.833 +/-0.160 0.0642 +/-0.160 0.128 pCi/g Manganese-54 U -0.0254 +/-0.0389 0.0321 +/-0.0389 0.0642 pCi/g Niobium-94 U 0.00407 +/-0.0364 0.0309 +/-0.0364 0.0617 pCi/g Potassium-40 14.9 +/-1.59 0.289 +/-1.59 0.578 pCi/g Radium-226 0.911 +/-0. 171 0.0644 +/-0.171 0.129 pCi/g Silver-108m U -0.00655 +/-0.0315 0.0272 +/-0.0315 0.0543 pCi/g Thallium-208 0.319 +/-0.0796 0.0341 +/-0.0796 0.0682 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.00243 +/-0.0223 0.0183 +/-0.0223 0.0435 pCi/g KSDl 04/09/07 2159 623056 Rad Liquid Scintillation Analysis ISC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.268 +1-1.15 0.976 +/-1.15 2.06 pCi/g AXD2 04/10/07 0814 623190 Page 161 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 980 1-0000-033B Project: YANK0 1204 Sample ID: 183607032 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All, FSS Carbon-14 U 0.00 +1-0.122 0.103 +/-0.122 0.212 pCi/g AXD2 04/10/07 2147 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 18.7 +/-31.6 21.6 +/-31.7 45.5 pCi/g MXP1 04/11/07 2310 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -2.89 +/-10.4 8.83 +/-10.4 18.3 pCi/g MXPI 04/10/07 2115 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0418 +/-0.235 0.199 +/-0.235 0.412 pCi/g MXP1 04/11/07 2135 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-l 1-RC Modified 4 DOE EML HASL-300, Pu- II-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified 11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Aiphaspec Am24I, Cm, Solid ALL 95 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 95 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 91 (25%-I125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 67 (25%-i125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 74 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 89 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 72 (15%-125%)

Page 162 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address :362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-033B Project: YANK01 204 Sample ID: 183607032 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 163 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801-0000--034B Proiect: YANKO 1204 Sample ID: 183607033 Client ID: YANKOO I Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 8.66%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U 0.0242 +1-0.150 0.118 +1-0.150 0.3 19 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.0171 +/-0.0679 0.0417 +/-0.068 0.172 pCi/g Curium-243/244 U 0.00495 +/-0.135 0.111 +/-0.135 0.306 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.139 +/-0.136 0.039 +/-0.137 0.161 pCilg PXH2 04/09/07 0935 623063 Plutonium-2391240 U 0.108 +/-0.122 0.039 +/-0.123 0.161 pCilg Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U -1.79 +/-11.6 9.85 +/-11.6 21.3 pCi/g PXH2 04/11/07 1627 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.924 +/-0.2 10 0.0737 +/-0.210 0.147 pCi/g MJHI 04/11/07 0941 623178 Americium-241 U 0.00321 +/-0.0443 0.0361 +/-0.0443 0.0721 pCi/g Bismuth-212 0.526 +/-0.393 0.167 +/-0.393 0.334 pCi/g lBismuth-214 0.769 +/-0.132 0.0417 +/-0.132 0.0834 pCi/g Cesium-134 U 0.0508 +/-0.048 0.0325 +/-0.048 0.0649 pCi/g Cesium-137 0.0775 +1-0.0448 0.0263 +/-0.0448 0.0526 pCi/g Cobalt-60 U-0.00061 8 +/-0.03 11 0.0259 +/-0.0311 0.0519 pCi/g Europium-152 U -0.097 +/-0.0845 0.0537 +/-0.0845 0.107 pCi/g Europium-154 U 0.0885 +/-0.0901 0.0719 +/-0.090 1 0.144 pCi/g Europium-ISS U 0.0658 +/-0.0621 0.0579 +/-0.0621 0.116 pCi/g Lead-212 0.877 +1-0.115 0.033 1 +1-0.115 0.0661 pCi/g Lead-214 0.871 +/-0.133 0.0421 +/-0.133 0.0842 pCi/g Manganese-54 U 0.003 +/-0.0258 0.0227 +/-0.0258 0.0453 pCi/g Niobium-94 U -0.00399 +/-0.026 0.0215 +/-0.026 0.0431 pCi/g Potassium-40 11.3 +/-1.26 0.206 +/-1.26 0.412 pCi/g Radium-226 0.769 +/-0.132 0.0417 +/-0.132 0.0834 pCi/g Silver-108m U -0.00345 +/-0.0249 0.0216 +/-0.0249 0.0431 pCi/g Thallium-208 0.272 +/-0.0638 0.0217 +/-0.0638 0.0433 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.00913 +/-0.0246 0.0192 +/-0.0246 0.0454 pCi/g KSDI 04/09/07 2159 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U -0.845 +/-1.22 1.07 +/-1.22 2.25 pCi/g AXD2 04/10/07 0901 623190 Page 164 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 9801 -0000-034B Project: YANK01204 CletSample ID: Client ID: YANKOO 1 183607033 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A%

Rad Liquid Scintillation Analysis Liquid Scint 014, Solid AlIFSS Carbon-14 U -0.0718 +/-0.114 0.0977 +/-0.114 0.201 pCi/g AXD2 04/11/07 0426 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 11.4 +/-26.3 18.2 +/-26.3 38.3 pCi/g MXPI 04/11/07 2326 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -1.68 +/-10.6 8.99 +/-10.6 18.6 pCi/g MXP1 04/10/07 2131 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0662 +/-0.231 0.196 +/-0.231 0.407 pCi/g MXP1 04/11/07 2201 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-lII-RC Modified 4 DOE EML HASL-300, Pu-I I-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-0lI Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified 11I DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 87 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL ESS 83 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 92 (25%-1 25%)

Strontium Carrer GFPC, Sr90, solid-ALL ESS 69 (25%-i125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL ES 72 (15%-i125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL ES 87 (25%-125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL ES 75 (15%-125%)

Page 165 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801-0000-034B Project: YANK01204 Sample ID: 183607033 Client ID: YANKOOlI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCJMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 166 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-035B Project: YANK0 1204 Sample ID: 183607034 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 8.48%

Parameter Qualifier Result Uncertainty LC TPU AMDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0348 +/-0.0798 0.0432 +/-0.0799 0.162 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U -I 0.00708 +/-0.0139 0.0265 +/-0.0139 0.133 pCi/g Curium-243/244 U 0.00445 +/-0. 121 0.0999 +/-0.121 0.275 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0699 +/-0.0868 0.0227 +/-0.0871 0.114 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.0506 +/-0.0702 0.00 +/-0.0704 0.0686 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U 3.31 +/-17.2 14.4 +/-17.2 29.5 pCi/g PXH2 04/16/07 1524 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 1.15 +/-0.297 0.0907 +/-0.297 0.181 pCi/g MJH1 04/11/07 1144 623178 Americium-241 U 0.0222 +/-0.0491 0.0407 +/-0.0491 0.08 14 pCi/g Bismuth-212 U 0.415 +/-0.429 0.273 +/-0.429 0.547 pCi/g Bismuth-214 0.785 +/-0.154 0.0524 +/-0.154 0.105 pCi/g Cesium-134 UI 0.00 +/-0.0601 0.0378 +/-0.0601 0.0755 pCi/g Cesium-137 U 0.0487 +/-0.0335 0.0293 +/-0.0335 0.0586 pCi/g Cobalt-60 U 0.018 +/-0.0372 0.033 +/-0.0372 0.0659 pCi/g Europium-152 U -0.019 +/-0.107 0.0707 +/-0.107 0.141 pCi/g Europium-154 U -0.106 +/-0.105 0.076 +1-0.105 0.152 pCi/g Europium-iSS U 0.0359 +/-0.0767 0.0679 +/-0.0767 0.136 pCi/g Lead-212 0.960 +/-0.135 0.0384 +/-0.135 0.0768 pCi/g Lead-214 0.773 +1-0. 166 0.0519 +/-0.166 0.104 pCi/g Manganese-54 U 0.0316 +/-0.0335 0.0313 +/-0.0335 0.0625 pCi/g Niobium-94 U 0.0108 +/-0.0316 0.0274 +/-0.0316 0.0547 pCi/g Potassium-40 12.7 +1-1.36 0.214 +/-1.36 0.427 pCi/g Radium-226 0.785 +/-0.154 0.0524 +/-0.154 0.105 pCi/g Silver-108m U 0.0343 +/-0.0282 0.0266 +/-0.0282 0.0532 pCi/g Thallium-208 0.332 +/-0.0663 0.0269 +/-0.0663 0.0537 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.00542 +/-0.0226 0.0182 +/-0.0226 0.0424 pCi/g KSD1 04/09/07 2159 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.323 +/-1.24 1.05 +/-1.24 2.22 pCi/g AXD2 04/10/07 0947 623190 Page 167 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801 -0000-035B Project: YANK01204 Sample ID: 183607034 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All, FSS Carbon- 14 U -0.106 +/-0.118 0.102 +/-0.118 0.211 pCilg AXD2 04/10/07 2219 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -3.05 +/-26.4 18.7 +/-26.4 39.4 pCi/g MXPI 04/11/07 2343 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -6.52 +/-10.1 8.70 +/-10.1 18.0 pCilg MXP1 04/10107 2147 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0754 +/-0.242 0.200 +/-0.242 0.416 pCi/g MXPl 04/11/07 2228 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I Il-RC Modified 4 DOE EML HASL-300, Pu- I Il-RC Modified 5 DOE EMIL HASL-300, Pu- I -RC Modified 6 EML HASL 300,4.5.2.3 7 EPA 905.0 Modified 8 EPA 906.0 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified I1I DOE RESL Ni- 1, Modified 12 DOE EMIL HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 97 (15%-I 25%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL ESS 101 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL Fý 27 (25%-125%)

Strontium Carrier GFPC, SOO0, solid-ALL FSS 76 (25%-I 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 76 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 88 (25%-1 25%)

Page 168 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-035B Project: YANK01204 Sample ID: 183607034 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 74 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Saimple concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 169 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-036B Project: YANK01 204 Sample ID: 183607035 Client ID: YANKOO 1 Matrix: TS Vol. Recv.:

Collect Date: 29-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 9.11%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Alphaspec Ani24l, Cm, Solid ALL FSS Americium-241 U --0.0416 +/-0.0623 0.0382 +/-0.0623 0.158 pCi/g PXH2 04/12/07 1052 624198 Curium-242 U -0.023 +/-0.0679 0.0497 +/-0.0679 0.186 pCi/g Curium-243/244 U -0.012 +/-0.0948 0,0855 +/-0.0948 0.253 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0508 +/-0.0811 0.0259 +/-0.0813 0.130 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.023 1 +/-0.0855 0.0579 +/-0.0855 0.194 pCi/g Liquid Scint Pu24J, Solid-ALL FSS Plutonium-241 U 0.912 +/-12.0 10.0 +/-12.0 21.7 pCi/g PXH2 04/11/07 1643 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.780 +/-0.283 0.0949 +/-0.283 0.190 pCi/g MJH1 04/11/07 1144 623178 Americium-241 U 0.0438 +1-0.0544 0.047 +/-0.0544 0.094 pCi/g Bismuth-21 2 U 0.540 +/-0.442 0.293 +/-0.442 0.585 pCi/g Bismuth-214 0.679 +/-0.138 0.0573 +/0138 0.115 pCi/g Cesium-134 U 0.0521 +/-0.0395 0.0378 +/-0.0395 0.0755 pCi/g Cesium- 137 U 0.0484 +1-0.045 8 0.0309 +/-0.0458 0.06 18 pCi/g Cobalt-60 U 0.0105 +/-0.0389 0.0336 +/-0.0389 0.0672 pCi/g Europium-152 U 0.125 +/-0.0808 0.0775 +/-0.0808 0.155 pCi/g Europium-154 U -0.0366 +/-0.104 0.0845 +/-0.104 0.169 pCi/g Europium-I 55 U -0.00338 +/-0.080 0.0735 +/-0.080 0.147 pCi/g Lead-21 2 0.651 +/-0.0957 0.0421 +/-0.0957 0.0842 pCi/g Lead-214 0.568 +/-0.121 0.0548 +/0121 0.110 pCi/g Manganese-54 U -0.00754 +/-0.0358 0.0309 +/-0.0358 0.0618 pCi/g Niobium-94 U 0.00219 +/-0.03 11 0.0266 +/-0.0311 0.0532 pCi/g Potassium-40 9.98 +/-1.27 0.264 +/-1 .27 0.528 pCi/g Radium-226 0.679 +/-0.138 0.0573 +/-0.138 0.115 pCi/g Silver-108m U -0.00504 +/-0.0283 0.0247 +/-0.0283 0.0495 pCi/g Thallium-208 0.207 +/-0.058 1 0.0267 +/-0.0581 0.0533 pCi/g Rad Gas Flow Proportional Counting GFPC, SOO0, solid-ALL FSS Strontium-90 U 0.0328 +/-0.0262 0.0172 +/-0.0262 0.0408 pCi/g KSDI 04/09/07 2159 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCi/g Tritium U -0.3 14 +/-1.20 1.02 +/-1.20 2.15 pCi/g AXD2 04/10/07 1033 623190 Page 170 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-036B Project: YANKO 1204 Sample ID: 183607035 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty [C TPU MIDA Units DF Analyst Date Time Batch A Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All, FSS Carbon- 14 U -0.0974 +/-0.118 0.102 +/-0.118 0.211 pCi/g AXD2 04/10/07 2251 623194 Liquid Scint Fe55, Solid-ALL ['55 Iron-55 U 6.43 +/-33.8 23.4 +/-33.8 49.2 pCi/g MXPI 04/12/07 1302 623182 Liquid Scint Ni63, Solid-ALL ['55 Nickel-63 U -7.64 +/-10.5 9.05 +/-10.5 18.7 pCi/g MXPI 04/10/07 2203 623184 Liquid Scint Tc99, Solid-ALL ['55 Technetium-99 U -0.0118 +/-0.244 0.205 +/-0.244 0.426 pCi/g MXPI 04/111/07 2255 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Am-05-RC Modified 4 DOE EML HASL-300, Pu- I I-RC Modified 5 DOE EML HASL-300, Pu- II-RC Modified 6 EML HASL 300,4.5.2.3 7 EPA 905.0 Modified 8 EPA 906.0 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified I1I DOE RESL Ni-i, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24i, Cm, Solid ALL 81 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 87 (15%-I125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL Fý 94 (25%-i125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 78 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 73 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 88 (25%-i125%)

Page 171 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-036B Project: YANK01204 Sample ID: 183607035 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 69 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 172 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-037B Project: YANK01204 Sample ID: 183607036 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 30-MAR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 8.24%

Parameter Qualifier Result Uncertainty [C TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Alphaspec Am24 1, Cm, Solid ALL FSS Americium-241 U -0.0506 +/-0.0933 0.105 +/-0.0935 0.304 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.0475 +/-0.107 0.0577 +/-0.107 0.216 pCi/g Curium-243/244 U 0.135 +/-0.176 0.0947 +/-0.177 0.285 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0151 +/-0.060 0.0368 +/-0.060 0.152 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U -0.0139 +/-0.060 0.0368 +/-0.060 0.152 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -11.3 +/-10.4 9.65 +/-10.4 20.9 pCi/g PXH2 04/11/07 1659 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.767 +/-0.188 0.0623 +/-0.188 0.125 pCi/g MJHI 04/11/07 1145 623178 Americium-241 U 0.0263 +/-0.0355 0.031 +/-0.0355 0.062 pCi/g Bismuth-212 0.446 +/-0.272 0.166 +/-0.272 0.331 pCi/g Bismuth-214 0.602 +/-0.107 0.0383 +/-0.107 0.0765 pCi/g Cesium-134 U 0.0445 +/-0.0259 0.026 +/-0.0259 0.052 pCi/g Cesium-137 U 0.0174 +/-0.0275 0.0229 +/-0.0275 0.0457 pCi/g Cobalt-60 U -0.00579 +/-0.0224 0.0181 +/-0.0224 0.0362 pCi/g Europium-152 U 0.0253 +/-0.0642 0.0546 +/-0.0642 0.109 pCi/g Europium-154 U 0.0453 +/-0.0746 0.0679 +/-0.0746 0.136 pCi/g Europium-155 U 0.0881 +/-0.065 0.0465 +/-0.065 0.0929 pCi/g Lead-212 0.649 +/-0.0902 0.029 +/-0.0902 0.0579 pCi/g Lead-214 0.652 +/-0.106 0.0366 +/-0.106 0.0731 pCi/g Manganese-54 U -0.00592 +/-0.0242 0.0208 +/-0.0242 0.04 16 pCi/g Niobium-94 U 0.0036 +/-0.0238 0.0207 +/-0.0238 0.0413 pCi/g Potassium-40 9.09 +/-1.02 0.117 +/-1.02 0.234 pCi/g Radium-226 0.602 +/-0.107 0.0383 +/-0.107 0.0765 pCi/g Silver-108m U -0.00372 +/-0.0201 0.01 76 +/-0.0201 0.0352 pCi/g Thallium-208 0.227 +/-0.0511 0.020 +/-0.0511 0.0399 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.0112 +/-0.0268 0.0212 +/-0.0268 0.0479 pCi/g KSD1 04/09/07 2159 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U 0.270 +/-1.26 1.05 +/-1.26 2.21 pCi/g AXD2 04/10/07 1119 623190 Page 173 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com of An~,Iv5~i~

Certificateof Analvsis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801-0000-037B Project: YANKO 1204 Sample ID: 183607036 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Liquid Scintillation Analysis Liquid Scint 014, Solid All, FSS Carbon-14 U -0.104 +/-0.111 0.0962 +/-0.111 0.199 pCi/g AXD2 04/10/07 2322 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 4.28 +/-28.8 20.3 +/-28.8 42.8 pCi/g MXPI 04/12/07 0015 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -9.43 +/-10.8 9.34 +/-10.8 19.3 pCi/g MXP1 04/10/07 2220 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0205 +/-0.225 0.189 +/-0.225 0.393 pCi/g MXPI 04/11/07 2321 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I I-RC Modified 4 DOE EML HASL-300, Pu- I I1-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01I Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified II DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 91 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 93 (15%-I 25%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL Fý 94 (25%-I 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 59 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 67 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 86 (25%-I125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 76 (15%-125%)

Page 174 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-037B Project: YANK01204 Sample ID: 183607036 Client ID: YANKOOlI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MIDA Units DF Analyst Date Time Batch A Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCJMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 175 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of AnaIvsi5~

Cerfiricate ofA alvsis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-039B Proiect: YANK01204 Sample ID: 183607037 Client ID: YANKOO 1 Matrix: TS Vol. Recv.:

Collect Date: 03-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 2.02%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Rad Alpha Spec Analysis Aiphaspec Am24J1, Cm, Solid ALL FSS Americium-241 U 0.102 +/-0.153 0.080 +/-0.153 0.258 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U -0.0181 +/-0.0251 0.0479 +/-0.0252 0.198 pCi/g Curium-243/244 U -0.0495 +/-0.119 0.122 +/-0.120 0.343 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.021 +/-0.0557 0.0248 +/-0.0558 0.125 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.0486 +/-0.0777 0.0248 +/-0.0779 0.124 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -0.738 +/-11.8 9.93 +/-11.8 21.5 pCi/g PXH2 04/11/07 1715 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.242 +/-0.181 0.0903 +/-0.181 0.181 pCi/g MJH1 04/11/07 1147 623178 Americium-241 U 0.0124 +/-0.0391 0.0329 +/-0.0391 0.0657 pCi/g Bismuth-212 U 0.262 +/-0.263 0.187 +/-0.263 0.374 pCi/g Bismuth-214 0.639 +/-0.139 0.0475 +/-0.139 0.0948 pCi/g Cesium-134 U -0.00539 +/-0.0329 0.0285 +/-0.0329 0.0569 pCi/g Cesium-137 0.0549 +/-0.0335 0.0258 +/-0.0335 0.05 16 pCi/g Cobalt-60 U 0.01 04 +/-0.0308 0.0274 +/-0.0308 0.0548 pCi/g Europium-152 U -0.0294 +/-0.0778 0.0582 +/-0.0778 0.116 pCi/g Europium-154 U -0.00647 +/-0.0963 0.0806 +/-0.0963 0.161 pCi/g Europium-ISS U 0.0336 +/-0.0564 0.0528 +/-0.0564 0.106 pCi/g Lead-212 0.274 +/-0.0656 0.0323 +/-0.0656 0.0645 pCi/g Lead-214 0.727 +/-0.119 0.0451 +/-0.119 0.0902 pCi/g Manganese-54 U 0.011 +/-0.0259 0.0238 +/-0.0259 0.0476 pCi/g Niobium-94 U -0.006 +/-0.027 0.0235 +/-0.027 0.047 pCi/g Potassium-40 8.54 +/-1.06 0.152 +/-1.06 0.303 pCi/g Radium-226 0.639 +/-0.139 0.0475 +/-0.139 0.0948 pCi/g Silver-108m U 0.00681 +/-0.0227 0.0206 +/-0.0227 0.041 1 pCi/g Thallium-208 0.152 +/-0.0471 0.0226 +/-0.0471 0.0451 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.00551 +/-0.0266 0.0217 +/-0.0266 0.0493 pCi/g KSD1 04/09/07 2159 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U 0.0693 +/-1.28 1.07 +/-1.28 2.26 pCi/g AXD2 04/10/07 1205 623190 Page 176 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Certificate ofAnalvsis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-039B Proiect: YANK01204 Sample ID: 183607037 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A Rad Liquid Scintillation Analysis Liquid Scint C14, Solid AIIFSS Carbon-14 U -0.0329 +/-0.110 0.0929 +/-0.110 0.191 pCi/g AXD2 04/11/07 0503 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -83.3 +/-249 178 +/-249 376 pCi/g MXPI 04/17/07 2242 625732 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -8.73 +/-11.0 9.55 +1-11.0 19.8 pCi/g MXP1 04/10/07 2236 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0778 +/-0.235 0.200 +/-0.235 0.416 pCi/g MXP1 04/11/07 2348 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMB 1 04/05/07 1039 623038 The following Analytical Methods were performed Method Description 1 DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I I-RC Modified 4 DOE EML HASL-300, Pu-I I-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Fe-l, Modified 11I DOE RESL Ni-I, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 95 (15%-125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 95 (15%-1 25%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL F5 97 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 82 (25%-I 25%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 82 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 83 (25%-1 25%)

Page 177 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-039B Project: YANKO 1204 Sample ID: 183607037 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 74 (15%-125%)

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD1 Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +f-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 178 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address :362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-040F Project: YANK01204 Sample ID: 183607038 Client ID: YANK001 Matrix: TS Vol. Recv.:

Collect Date: 03-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 6.25%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am241, Cm, Solid ALL FSS Americium-241 U - ).00034 +/-0.107 0.0899 +/-0.107 0.270 pCilg PXH2 04/11/07 2315 624198 Curium-242 U - ).00833 +/-0.0163 0.03 11 +/-0.0164 0.156 pCilg Curium-243/244 U 0.0628 +/-0.157 0.108 +1-0.157 0.307 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U- -0.0078 +/-0.0655 0.0292 +/-0.0656 0.146 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239I240 U 0.0494 +/-0.0926 0.0412 +/-0.0928 0.171 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -9.86 +/-10.7 9.78 +/-10.7 21.2 pCi/g PXH2 04/11/07 1731 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 In growth Waived Actinium-228 0.691 +/-0.222 0.0661 +/-0.222 0.132 pCi/g MJIi 04/11/07 1317 623178 Americium-241 U 0.0595 +1-0.0966 0.0826 +/-0.0966 0.165 pCi/g Bismuth-212 UI 0.00 +/-0. 234 0.193 +/-0.234 0.386 pCi/g Bismuth-214 0.562 +1-0.0934 0.0383 +/-0.0934 0.0766 pCi/g Cesium-I 34 U 0.0258 +1-0.0275 0.0247 +/-0.0275 0.0493 pCi/g Cesium- 137 U 0.0253 +1-0.0249 0.0226 +/-0.0249 0.0451 pCi/g Cobalt-60 U 0.00642 +/-0.025 0.02 17 +/-0.025 0.0434 pCi/g Europium-152 U -0.0313 4/-0.110 0.0519 +/-0.110 0.104 pCi/g Europium-154 U -0.048 +/-0.0915 0.0636 +/-0.0915 0.127 pCi/g Europium-ISS U 0.0952 +/-0.0638 0.0605 +/-0.0638 0.121 pCi/g Lead-212 0.592 +/-0.0731 0.028 +/-0.0731 0.056 pCi/g Lead-214 0.605 +/-0.111 0.0383 +/-0.111 0.0765 pCi/g Manganese-54 U -0.0163 +1-0.0233 0.019 +/-0.0233 0.0379 pCi/g Niobium-94 U 0.00995 i./-0.0213 0.0192 +/-0.0213 0.0384 pCi/g Potassium-40 11.0 +/-1.09 0.153 +/-1.09 0.306 pCi/g Radium-226 0.562 +1-0.0934 0.0383 +/-0.0934 0.0766 pCi/g Silver-108m U -0.00766 +1-0.0209 0.0173 +/-0.0209 0.0345 pCi/g Thallium-208 0.178 +1-0.0474 0.0195 +/-0.0474 0.0389 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.0131 +/-0.0204 0.015 +/-0.0204 0.0358 pCi/g KSD1 04/09/07 2159 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U -0.936 +/-1.22 1.07 +/-1.22 2.26 pCi/g AXD2 04/10/07 1252 623190 Page 179 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - wvww.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-040F Project: YANK01204 Sample ID: 183607038 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch IN Rad Liquid Scintillation Analysis Liquid Scint C14, Solid A/lFSS Carbon- 14 U -0.103 +1-0.1 19 0.103 +/-0.119 0.212 pCilg AXD2 04/10/07 2354 623194 Liquid Scint FeSS, Solid-ALL FSS Iron-55 U 13.8 +/-41.8 28.8 +/-41.8 60.5 pCi/g MXPI 04/12/07 0048 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -3.55 +/-11.9 10.1 +/-11.9 20.9 pCi/g MXP1 04/10/07 2252 623184 Liquid Scint Tc99, Solid-ALL ['55 Technetium-99 U 0.235 +/-0.261 0.211 +/-0.261 0.438 pCi/g MXPI 04/12/07 0014 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBIl 04/05/07 1039 623038 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I1-RC Modified 4 DOE EML HASL-300, Pu-i 1-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-i, Modified I11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Aiphaspec Am24I, Cm, Solid ALL 99 (15%-125%)

Plutonium-242 Tracer Aiphaspec Pu, Solid-ALL FSS 80 (15%-1 25%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 94 (25%-1 25%)

Strontium Carrier GFPC, Sr90, solid-ALL F55 74 (25%-i125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 74 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 81 (25 %-1 25%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 71 (15%-125%)

Page 180 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801l-0000-040F Project: YANK0 1204 Sample ID: 183607038 Client ID: YANKO0l Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Notes:

The Qualifiers in this report are defined as follows:

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

13D Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification

• Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD, of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 181 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 980 1-0000-041F Project: YANK01 204 Sample ID: 183607039 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 03-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 8.08%

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am24J, Cm, Solid ALL FSS Americium-241 U -0.0839 +/-0.0708 0.112 +/-0.0716 0.330 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.00 +/-0.0801 0.00 +/-0.0801 0.111 pCi/g Curium-243/244 U -0.0268 +/-0.0914 0.0934 +/-0.0914 0.294 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0331 +/-0.0648 0.00 +/-0.0649 0.0896 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.0172 +/-0.0685 0.042 +/-0.0685 0.174 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -0.161 +1-11.6 9.74 +/-11.6 21.1 pCi/g PXH2 04/11/07 1747 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.753 +/-0.170 0.0599 +/-0.170 0.120 pCi/g MJHI 04/11/07 1318 623178 Americium-241 U 0.0621 +/-0.0704 0.0592 +/-0.0704 0.118 pCi/g Bismuth-212 0.413 +/-0.238 0.123 +/-0.238 0.245 pCi/g Bismuth-214 0.614 +/-0.0989 0.0312 +/-0.0989 0.0624 pCi/g Cesium-134 U 0.0362 +/-0.0327 0.0189 +/-0.0327 0.0377 pCi/g Cesium-137 U 0.0214 +/-0.0213 0.0174 +/-0.0213 0.0348 pCilg Cobalt-60 U 0.0291 +/-0.0324 0.016 +/-0.0324 0.032 pCi/g Europium-152 U 0.0435 +/-0.0621 0.0449 +/-0.0621 0.0898 pCi/g Europium-154 U -0.0287 +/-0.0611 0.0475 +/-0.0611 0.0949 pCi/g Europium-155 U 0.0723 +/-0.0821 0.0466 +/-0.0821 0.0932 pCi/g Lead-212 0.688 +/-0.0764 0.0265 +/-0.0764 0.053 pCi/g Lead-214 0.654 +/-0.0919 0.0298 +/-0.0919 0.0595 pCi/g Manganese-54 U 0.0139 +/-0.0213 0.0173 +/-0.0213 0.0345 pCi/g Niobium-94 U 0.011 +/-0.0187 0.0165 +/-0.0187 0.033 pCi/g Potassium-40 10.0 +/-0.927 0.142 +/-0.927 0.285 pCi/g Radium-226 0.614 +/-0.0989 0.0312 +/-0.0989 0.0624 pCi/g Silver-108m U 0.00194 +/-0.0158 0.014 +/-0.0158 0.028 pCi/g Thallium-208 0.201 +/-0.0445 0.01 56 +/-0.0445 0.0313 pCi/g Rad Gas Flow Proportional Counting GFPC, 5r90, solid-ALL FSS Strontium-90 U 0.011 +/-0.0231 0.0175 +/-0.0231 0.0421 pCi/g KSD1 04/09/07 2159 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U -0.229 +1-1.19 1.01 +/-1.19 2.14 pCi/g AXD2 04/10/07 1338 623190 Page 182 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-041 F Project: YANK01204 Sample ID: 183607039 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint 0]4, Solid All, FSS Carbon- 14 U 0.0139 +/-0.119 0.0994 +/-0.119 0.204 pCilg AXD2 04/11/07 0540 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 19.2 +/-27.6 18.9 +/-27.7 39.9 pCi/g MXP1 04/12/07 0104 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 1.20 +/-12.4 10.4 +/-12.4 21.5 pCi/g MXPl 04/10/07 2308 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.191 +/-0.227 0.184 +/-0.227 0.382 pCi/g MXP1 04/12/07 0041 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 JMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 DOE EML HASL-300, Pu- I I-RC Modified 5 EML HASL 300,4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-l, Modified I11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am24I, Cm, Solid ALL 89 (15%-I125%)

Plutonium-242 Tracer Alphaspec Pu, Solid-ALL FSS 79 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 92 (25%-I125%)

Strontium Carrier GFPC, SrOO, solid-ALL FSS 68 (25%-125%)

Iron-59 Tracer Liquid Scint FeSS, Solid-ALL FS 70 (1 5%-1 25%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 78 (25%-I125%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 77 (15%-125%)

Page 183 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analy:sis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils P04* 002332 Client Sample ID: 9801-0000-041F Project: YANK01204 Sample ID: 183607039 Client ID: YANKO0 I Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DIF Analyst Date Time Batch 1%

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected

• Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UL Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 184 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certifleate of Analysis Certificateof A alvsis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-042F Project: YANK01204 Sample ID: 183607040 Client ID: YANKO0l Matrix: TS Vol. Recv.:

Collect Date: 03-APR-07 Receive Date: 05-APR-07 Collector: Client Moisture: 13.2%

Parameter Qualifier Result Uncertainty LC TPU MIDA Units DF Analyst Date Time Batch 1%

Rad Alpha Spec Analysis Aiphaspec Am24J1, Cm, Solid ALL FSS Americium-241 U - -0.0342 +1-0.0651 0.029 +/-0.0651 0.145 pCi/g PXH2 04/11/07 2315 624198 Curium-242 U 0.0335 +/-0.0657 0.00 +/-0.0659 0.0908 pCi/g Curium-243/244 U 0.0646 +/-0.0895 0.00 +/-0.0899 0.0875 pCi/g Aiphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.00 +/-0.0585 0.00 +/-0.0585 0.0809 pCi/g PXH2 04/09/07 0935 623063 Plutonium-239/240 U 0.0382 +/-0.0862 0.0464 +/-0.0863 0.174 pCi/g Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -2.81 +/-11.3 9.73 +/-11.3 21.1 pCi/g PXH2 04/11/07 1803 623064 Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.14 +/-0.248 0.0873 +/-0.248 0.175 pCi/g MJH1 04/11/07 1410 623178 Americium-241 U 0.0506 +/-0.0464 0.040 +/-0.0464 0.0799 pCi/g Bismuth-212 0.793 +/-0.394 0.181 +/-0.394 0.361 pCi/g Bismuth-214 0.782 +/-0.154 0.0521 +/-0.154 0.104 pCi/g Cesium-134 UI 0.00 +/-0.0443 0.0354 +/-0.0443 0.0707 pCi/g Cesium-137 U 0.0492 +/-0.0419 0.0268 +/-0.0419 0.0535 pCi/g Cobalt-60 U 0.0134 +/-0.038 0.0292 +/-0.038 0.0583 pCi/g Europium-152 U -0.0312 +/-0.0938 0.0663 +/-0.0938 0.132 pCi/g Europium-154 U -0.0911 +/-0.0959 0.0697 +/-0.0959 0.139 pCi/g Europium-155 U 0.0244 +/-0.0805 0.0686 +/-0.0805 0.137 pCi/g Lead-212 0.907 +/-0.129 0.0375 +/-0. 129 0.075 pCi/g Lead-214 0.878 +/-0.150 0.0458 +/-0.150 0.09 16 pCi/g Manganese-54 U 0.00722 +/-0.027 0.0242 +/-0.027 0.0483 pCi/g Niobium-94 U -0.0231 +/-0.0284 0.022 +/-0.0284 0.044 pCi/g Potassium-40 10.9 +/-1.23 0.169 +/-1.23 0.338 pCi/g Radium-226 0.782 +/-0.154 0.0521 +/-0.154 0.104 pCi/g Silver-108m U -0.00532 +/-0.0271 0.0235 +/-0.0271 0.0469 pCi/g Thallium-208 0.3 17 +/-0.0742 0.0257 +/-0.0742 0.05 14 pCi/g Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00145 +/-0.0207 0.0176 +/-0.0207 0.0411 pCi/g KSD1 04/09/07 2159 623056 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid - 3 pCilg Tritium U -0.668 +/-1.19 1.03 +/-1.19 2.18 pCi/g AXD2 04/10/07 1424 623190 Page 185 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certific2te of Ana1vsi~

alvsis Certificate ofA Company :Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801 -0000-042F Project: YANK01204 Sample ID: 183607040 Client ID: YANK001 Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch 1%

Rad Liquid Scintillation Analysis Liquid Scint C14, Solid All, FSS Carbon-14 U -0.06 +/-0.123 0.105 +/-0.123 0.216 pCi/g AXD2 04/11/07 0027 623194 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -3.16 +/-23.8 16.9 +/-23.8 35.7 pCi/g MXP1 04/12/07 0121 623182 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 10.7 +/-11. 1 8.99 +/-11. 1 18.6 pCi/g MXPI 04/10/07 2325 623184 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.207 +/-0.221 0.192 +/-0.221 0.400 pCi/g MXP1 04/12/07 0108 623187 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 IMBI 04/05/07 1039 623038 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu- I I-RC Modified 4 DOE EML HASL-300, Pu- I I-RC Modified 5 EML HASL 300, 4.5.2.3 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-0lI Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified 11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery% Acceptable Limits Americium-243 Tracer Alphaspec Am241, Cm, Solid ALL 83 (15%-125%)

Plutonium-242 Tracer Aiphaspec Pu, Solid-ALL FSS 96 (15%-125%)

Plutonium-242 Tracer Liquid Scint Pu241, Solid-ALL FS 92 (25%-125%)

Strontium Carrier GFPC, Sr90, solid-ALL FSS 82 (25%-I125%)

Iron-59 Tracer Liquid Scint Fe55, Solid-ALL FS 73 (15%-125%)

Nickel Carrier Liquid Scint Ni63, Solid-ALL FS 89 (25%-1 25%)

Technetium-99m Tracer Liquid Scint Tc99, Solid-ALL FS 77 (15%-125%)

Page 186 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: April 19, 2007

Contact:

Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9801-0000-042F Project: YANK01204 Sample ID: 183607040 Client ID: YANKOOI Vol. Recv.:

Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch A~

Notes:

The Qualifiers in this report are defined as follows

• • Analyte is a surrogate compound

• Result is less than value reported

• Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier

• QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.

Page 187 of 205

I QUALITY CONTROL DATA Page 188 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Report Date: April 19, 2007 Client : Connecticut Yankee Atomic Power Page 1 of 17 362 Injun Hollow Rd East Hampton, Connecticut

Contact:

Mr. Jack McCarthy Workorder: 183607 Parnmame NOM Sample Qual OC Units RPD% REC % Raniz Anlst Date Time Rad Alpha Spec Batch 623058 QC1201309428 183607001 DUP Americium-241 u -0.0468 U -0.0424 pCi/g 10 (0% - 100%) V1XA1 04/09/07 15:03 Uncert: +/-0.0725 +/-0.161 TPU: +/-0.0726 +/-0.161 Curium-242 U 0.0368 U -0.0299 pCi/g 1930 (0% - 100%)

Uncert: +/-0.072 1 +/-0.0339 TPU: +/-0.0723 +/-0.0341 Curium-243/244 U 0.0533 U 0.019 pCi/g 95 (0% -100%)

Uncert: +/-0.0999 +/-0.2 10 TPU: +/-0.100 +/-0.2 10 QC1201309430 LCS 13.2 12.8 pCi/g 97 (75%-125%) 04/09/07 15:03 Americium-24 I Uncert: +/-1.21 TPU: +/-2.07 Curium-242 U -0.00723 pCi/g Uncert: +/-0.0142 TPU: +/-0.0142 Curium-243/244 15.8 15.5 pCi/g 98 (75%-125%)

Uncert: +/-1.33 TPU: +/-2.43 QC 1201309427 MB Americium-241 U 0.04 14 pCi/g 04/09/07 15:03 Uncert: +/-0.104 TPU: +/-0.104 Curium-242 U 0.0377 pCi/g Uncert: +/-0.127 TPU: +/-0.128 Curium-243/244 U -0.0454 pCi/g Uncert: +/-0.135 TPU: +/-0. 136 QCI 201309429 183607001 MIS Americium-241 13.7 U -0.0468 11.9 pCi/g 87 (75%-125%)

Uncert: +/-0.0725 +/-1.22 TPU: +/-0.0726 +/-1.99 Curium-242 U 0.0368 U 0.00945 pCi/g Uncert: +/-0.0721 +/-0.07 16 TPU: +/-0.0723 +/-0.0716 Curium-243/244 16.4 U 0.0533 13.7 pCi/g 84 (75%-125%)

Uncert: +/-0.0999 +/-1.31 TPU: +/-0.100 +/-2.23 Batch 623060 QC1201309432 183607001 DUP Plutonium-238 U 0.0406 U 0.0145 pCi/g 95 (0% - 100%) AlXAI 04/09/07 15:04 Page 189 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 2 of 17 Parmname NOM Sample Ouai OC Units RPD% REC% Ranize AnIst Date Time Rad Alpha Spec Batch 623060 Uncert: +/-0.126 +/-0.159 TPU: +/-0.126 +/-0. 159 Plutonium-239/240 U -0.0143 U 0.00132 pCilg 241 (0% -100%)

Uncert: +/-0.0198 +/-0.0716 TPU: +/-0.0199 +/-0.07 16 QC 1201309434 LCS Plutonium-238 U 0.119 pCi/g (75%-I125%)

Uncert: +1-0. 15 1 TPU: +/-0.152 Plutonium-239/240 13.1 13.4 pCi/g 102 (75%-125%)

Uncert: +/-1.31 TPU: +/-1.92 QC1201309431 MB Plutonium-238 U -0.0221 pCi/g Uncert: +/-0.0653 TPU: +/-0.0653 Plutonium-239/240 U -0.0148 pCi/g Uncert: +/-0.0636 TPU: +/-0.0637 QC1201309433 183607001 MIS Plutonium-238 U 0.0406 U 0.0733 pCi/g (75%-I125%)

Uncert: +/-0.126 +/-0.101 TPU: +/-0.126 +/-0. 101 Plutonium-239/240 13.7 U -0.0143 11.5 pCi/g 84 (75%-125%)

Uncert: +/-0.0 198 +/-1.13 TPU: +/-0.0199 +/-1.60 Batch 623061 QC1201309436 183607001 DUP Plutonium-241 U -3.91 U -3.18 pCi/g 0 (0% - 100%) VAXAI 04/11/07 20:52 Uncert: +/-6.73 +/-8.3 1 TPU: +/-6.73 +/-8.31 QC1201309438 L.CS Plutonium-24 I 139 127 pCi/g 91 (75%-125%) 04/11/07 21:24 Uncert: +/- 14.2 TPU: +/-19.2 QC1201309435 MB Plutonium-24 1 U -2.02 pCi/g 04/11/07 14:02 Uncert: +/-6.41 TPU: +/-6.4 1 QC1201309437 183607001 MIS Plutonium-24 1 141 U -3.91 138 pCi/g 98 (75%-125%) 04/11/07 21:08 Uncert: +/-6.73 +/-13.9 TPU: +/-6.73 +/-19.7 Batch 623063 QC1201309444 183607023 DUP Plutonium-238 u 0.096 U -0.00772 pCi/g 235 (0% - 100%) PXH2 04/09/07 09:35 Uncert: +/-0.153 +/-0.0649 TPU: +/-0.154 +/-0.0649 Plutonium-239/240 U 0.153 U 0.00129 pCi/g 197 (0% -100%)

Page 190 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 3 of 17 Parmname NOM Samnie Ouai OC Units RPD% REC% Ranee Anist Date Time Rad Alpha Spec Batch 623063 Uncert: +/-0.187 +/-0.070 TPU: +/-0.188 +/-0.070 QC 1201309446 LCS Plutonium-238 U 0,0266 pCi/g (75%-125%) 04/09/07 09:35 Uncert: +/-0.0522 TPU: +/-0.0523 Plutonium-239/240 12.7 12.6 PCi/g 99 (75%-125%)

Uncert: +/-1.14 TPU: +/-1.82 QC1201309443 MB Plutonium-238 U 0.0283 pCi/g 04/09/07 09:35 Uncert: +/-0.0555 TPU: +/-0.0556 Plutonium-239/240 U -0.0204 pCi/g Uncert: +/-0.0231 TPU: +/-0.0232 QC1201309445 183607023 MS Plutonium-238 u 0.096 0.188 pCi/g (75%- 125%) 04/09/07 09:35 Uncert: +/-0.153 +/-0.145 TPU: +/-0.154 +/-0. 147 Plutonium-239/240 13.4 U 0.153 14.7 pCi/g 110 (75%-125%)

Uncert: +/-0.187 +/-1.26 TPU: +/-0.188 +/-2.08 Batch 623064 QC1201309448 183607023 DUP Plutonium-24 1 U -1.52 U -4.52 pCi/g 0 (0% - 100%) PXH2 04/11/07 18:35 Uncert: +/-7.40 TPU: +/-7.40 QC1201309450 LCS Plutonium-24 I 342 276 pCi/g 81 (75%-125%) 04/11/07 19:08 Uncert: +/-26.2 TPU: +/-36.9 QC1201309447 MB Plutonium-24 1 U -1.86 pCi/g 04/11/07 18:19 Uncert: +/- 12.0 TPU: +/-12.0 QC1201309449 183607023 MS Plutonium-24 I 343 U -1.52 309 pCi/g 90 (75%-125%) 04/11/07 18:51 Uncert: +/-7.40 +/-39.2 TPU: +/-7.40 /-3.7 Batch 624198 QC1201312042 183607021 DUP Americium-241 u 0.0697 U -0.00769 pCi/g 250 (0% - 100%) PXH2 04/11/07 23:15 Uncert: +/-0.123 +/-0.0546 TPU: +/-0.124 +/-0.0546 Curium-242 U -0.0375 U 0.00 pCi/g 200 (0% -100%)

Uncert: +/-0.0328 +/-0.0553 TPU: +/-0.0332 +/-0.0553 Curium-243/244 u -0.0635 U 0.00758 pCi/g 254 (0% -100%)

Page 191 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 4 of 17 Parnmame NOM Sample Oual OC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 624198 Uncert: +/-0.0776 +/-0.0575 TPU: +/-0.078 +/-0.0575 QC 1201312044 LCS Americium-241 12.1 12.1 pCilg 100 (75%-125%)

Uncert: +1-1.17 TPU: +/-2.02 Curium-242 U -0.0144 pCilg Uncert: +1-0.0619 TPU: +/-0.062 Curium-243/244 14.5 14.5 pCilg 100 (75%-125%)

Uncert: +/-1.28 TPU: +/-2.34 QC 1201312041 MB Americium-241 U -0.0327 pCi/g Uncert: +1-0.0519 TPU: +/-0.052 Curium-242 U 0.00 pCilg Uncert: +/-0.0509 TPU: +/-0.0509 Curium-243/244 U -0.0185 pCilg Uncert: +/-0.021 TPU: +/-0.0211 QC12013 12043 183607021 NIS Arnercium-241 13.5 u 0.0697 13.8 pCi/g 102 (75%-125%)

Uncert: +/-0.123 +/-1.36 TPU: +/-0.124 +/-2.33 Curium-242 u -0.0375 u 0.00 pCilg Uncert: +/-0.0328 +/-0.071 TPU: +/-0.0332 +/-0.071 Curium-243/244 16.1 u -0.0635 16.9 pCilg 105 (75%-125%)

Uncert: +1-0.0776 +1-1.50 TPU: +/-0.078 +/-2.77 Rad Gamma Spec Batch 623177 Actinium-228 1.15 0.763 pCilg 40 (0% - 100%) MJH 1 04/10/07 14:13 Uncert: +/-0.303 +/-0.211 TPU: +/-0.303 +/-0.211 Americium-241 U 0.046 U 0.00633 pCi/g 152 (0%-100%)

Uncert: +/-0.052 +/-0.0453 TPU: +1-0.052 +/-0.0453 Bismuth-212 0.674 U 0.478 pCilg 34 (0%-100%)

Uncert: +/-0.407 +/-0.473 TPU: +/-0.407 +1-0.473 Bismuth-214 0.947 0.8 19 pCi/g 15 (0%-100%)

Uncert: +/-0.164 +/-0.136 TPU: +/-0.164 +/-0.136 Cesium- 134 U 0.0698 U 0.00676 pCilg 165 (0%-100%)

Page 192 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com OC Summary Workorder: 183607 Page 5 of 17 Parmname NOM Sample Quall QC Units RPD% REC % Range AnIst Date Time Rad Gamma Spec Batch 623177 Uncert: +/-0.057 +/-0.0352 TPU: +/-0.057 +/-0.0352 Cesium- 137 U 0.0593 U 0.0505 pCi/g 16 (0% -100%)

Uncert: +/-0.04 12 +/-0.055 TPU: +1-0.0412 +1-0.055 Cobalt-60 U 0.0119 U 0.00183 pCi/g 146 (0% -100%)

Uncert: +/-0.0436 +/-0.0374 TPU: +/-0.0436 +/-0.0374 Europium- 152 U -0.0263 U 0.0169 pCi/g 918 (0% - 100%)

Uncert: +/-0.0981 +/-0.07 17 TPU: +/-0.098 1 +/-0.0717 Europium- 154 U 0.0706 U 0.0837 pCi/g 17 (0% -100%)

Uncert: +/-0.127 +/-0.095 TPU: +/-0.127 +/-0.095 Europium- 155 U 0.0544 U 0.0535 pCi/g 2 (0% -100%)

Uncert: +/-0.109 +/-0.0668 TPU: +/-0.109 +/-0.0668 Lead-212 0.869 0.903 pCi/g 4 (0% -20%)

Uncert: +/-0.113 +/-0.115 TPU: +/-0.113 +/-0.115 Lead-214 0.923 0.876 pCi/g 5 (0% -20%)

Uncert: +/-0.159 +/-0.145 TPU: +/-0.159 +/-0.145 Manganese-54 U 0.00548 U -0.0078 pCi/g 1140 (0% -100%)

Uncert: +/-0.0367 +/-0.0354 TPU: +/-0.0367 +/-0.0354 Niobium-94 U -0.0107 U -0.00365 pCi/g 99 (0% -100%)

Uncert: +/-0.0308 +/-0.0311I TPU: +/-0.0308 +/-0.0311 Potassium-40 13.1 12.4 pCi/g 6 (0% -20%)

Uncert: +/-1.40 +/-1.37 TPU: +/-1.40 +/-1.37 Radium-226 0.947 0.8 19 pCi/g 15 (0% -100%)

Uncert: +/-0.164 +/-0.136 TPU: +/-0.164 +/-0.136 Silver- 108m U -0.0233 U 0.00469 pCi/g 301 (0% - 100%)

Uncert: +/-0.0309 +/-0.0261 TPU: +/-0.0309 +/-0.0261 Thallium-208 0.336 0.252 pCi/g 28* (0% -100%)

Uncert: +/-0.0864 +/-0.0618 TPU: +/-0.0864 +/-0.0618 QC1 201309686 LCS 1.28 pci/g 04/09/07 12:46 Actinium-228 Uncert: +/-0.584 TPU: +/-0.584 Americium-24 1 16.0 13.9 pci/g 87 (75%-125%)

Uncert: +/-1.31 TPU: +/-1.3 1 Page 193 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 6 of 17 Parimname NOM Sample Q)ual QC Units RPD % REC% Range Anist Date Time Rad Gamma Spec Batch 623177 Bismuth-2 12 1.12 pCi/g Uncert: +/-0.6 14 TPU: +/-0.6 14 Bismuth-214 0.542 pCi/g Uncert: +/-0.221 TPU: +/-0.221 Cesium-134 U 0.00382 pCi/g Uncert: +/-0.0785 TPU: +/-0.0785 Cesium- 137 6.20 5.87 pCi/g 95 (75%-125%)

Uncert: +/-0.553 TPU: +/-0.553 Cobalt-60 9.30 9.02 pCi/g 97 (75%-125%)

Uncert: +/-0.606 TPU: +/-0.606 Europium-152 U 0.0986 pCi/g Uncert: +/-0.249 TPU: +/-0.249 Europium- 154 U -0.041 pCi/g Uncert: +/-0.172 TPU: +/-0.172 Europium-155 U 0.0112 pCi/g Uncert: +/-0.211 TPU: +/-0.2 11 Lead-212 1.01 pCi/g Uncert: +/-0. 170 TPU: +/0170 Lead-214 0.633 pCi/g Uncert: +/-0.235 TPU: +/-0.235 Manganese-54 U -0.047 pCi/g Uncert: +/-0.08 14 TPU: +/-0.0814 Niobium-94 U 0.0623 pCi/g Uncert: +/-0.0722 TPU: +/-0.0722 Potassium-40 U 0.485 pCi/g Uncert: +/-1.07 TPU: +/-1.07 Radium-226 0.542 pCi/g (75%-125%)

Uncert: +/-0.22 1 TPU: +/-0.22 1 Silver- 108m U -0.0585 pCi/g Uncert: +/-0.0643 TPU: +/-0.0643 Thallium-208 0.350 pCi/g Uncert: +/-0.115 TPU: +/-0.115 Page 194 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com

.QC Summary Workorder: 183607 Page 7 of 17 Parmname NOM Sample Qua] OC Units RPD% REC% Rain2e AnIst Date Time Rad Gamma Spec Batch 623177 MB Actinium-228 U -0.0125 pCi/g 04/09/07 12:44 Uncert: +/-0.0552 TPU: +/-0.0552 Americium-24 1 U -0.183 pCi/g Uncert: +/-0.0828 TPU: +/-0.0828 Bismuth-212 U -0.0888 pCi/g Uncert: +/-0.118 TPU: +/-0.118 Bismuth-214 U -0.0136 pCi/g Uncert: +/-0.0356 TPU: +/-0.0356 Cesium- 134 U 0.00835 pCi/g Uncert: +/-0.0144 TPU: +/-0.0144 Cesium- 137 U 0.0107 pCi/g Uncert: +/-0.013 TPU: +/-0.013 Cobalt-60 U 0.00525 pCi/g Uncert: +1-0.0149 TPU: +/-0.0149 Europium- 152 U 0.0445 pCi/g Uncert: +/-0.0453 TPU: +/-0.0453 Europium-I 54 U -0.0176 pCi/g Uncert: +/-0.0384 TPU: +/-0.0384 Europium- 155 U 0.0146 pCi/g Uncert: +/-0.041 TPU: +/-0.041 Lead-212 U -0.00725 pCi/g Uncert: +/-0.0262 TPU: +/-0.0262 Lead-214 U -0.00264 pCi/g Uncert: +/-0.0312 TPU: +/-0.0312 Manganese-54 U 0.0033 pCi/g Uncert: +/-0.0127 TPU: +/-0.0127 Niobium-94 U -0.00183 pCi/g Uncert: +/-0.0137 TPU: +/-0.0137 Potassium-40 U 0.0431 pCi/g Uncert: +/-0.184 TPU: +/-0.184 Radium-226 U -0.0136 pCi/g Uncert: +/-0.0356 TPU: +/-0.0356 Page 195 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 8 of 17 Parmname NOM Sample Qual OC Units RPD% REC% Ranize Anist Date Time Rad Gamma Spec Batch 623177 Silver- 108m U 0.0115 pCi/g Uncert: +/-0.012 TPU: +/-0.012 Thallium-208 U 0.00513 pCi/g Uncert: +/-0.0 17 TPU: +/-0.017 Batch 623178 QC1201309688 183607023 DUP Actinium-228 1.32 1.74 pCi/g 28 (0% - 100%) MJHI 04/11/07 14:12 Uncert: +/-0.327 +/-0.377 TPU: +/-0.327 +/-0.377 Americium-241 u 0.0409 UT 0.00 pCi/g 92 (0% - 100%)

Uncert: +/-0.0667 +/-0.0662 TPU: +/-0.0667 +/-0.0662 Bismuth-2 12 0.680 0.915 pCi/g 30 (0% -100%)

Uncert: +/-0.393 +/-0.427 TPU: +/-0.393 +/-0.427 Bismuth-2 14 1.31 1.46 pCi/g 11 (0% -20%)

Uncert: +/-0.242 +/-0.253 TPU: +/-0.242 +/-0.253 Cesium- 134 UT 0.00 U 0.0809 pCi/g 29 (0% -100%)

Uncert: +/-0.055 +/-0.0596 TPU: +/-0.055 +/-0.0596 Cesium- 137 u 0.0294 U -0.0123 pCi/g 489 (0% -100%)

Uncert: +/-0.0325 +/-0.0412 TPU: +/-0.0325 +/-0.0412 Cobalt-60 u -0.00649 U 0.00352 pCi/g 674 (0% -100%)

Uncert: +/-0.053 +/-0.0491 TPU: +/-0.053 +/-0.0491 Europium- 152 U -0.106 U -0.00847 pCi/g 170 (0% - 100%)

Uncert: +/-0.119 +/-0. 155 TPU: +/-0.119 +/-0.155 Europium-154 U -0.00187 U 0.0241 pCi/g 234 (0% -100%)

Uncert: +/-0.121 +/-0.153 TPU: +/-0.121 +/-0.153 Europium- 155 u 0.0357 U 0.0622 pCi/g 54 (0% -100%)

Uncert: +/-0.118 +/-0.114 TPU: +/-0.118 +/-0.114 Lead-212 1.38 1.48 pCi/g 7 (0%-20%)

Uncert: +/-0.184 +/-0.167 TPU: +/-0.184 +/-0.167 Lead-214 1.61 1.64 pCi/g 2 (0% -20%)

Uncert: +/-0.231 +/-0.234 TPU: +/-0.231 +/-0.234 Manganese-54 u 0.0489 U 0.0149 pCi/g 106 (0% -100%)

Uncert: +/-0.0375 +/-0.0465 TPU: +1-0.0375 +/-0.0465 Niobium-94 u 0.038 UT 0.00 pCi/g 100 (0% -100%)

Page 196 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 9 of 17 Parmname NOM Sample Qual QC Units RPD % REC% Range Anist Date Time Rad Gamma Spec Batch 623178 Uncert: +/-0.037 +/-0.134 TPU: +/-0.037 +/-0.134 Potassium-40 20.3 21.1 pCi/g 4 (0% -20%)

Uncert: +/-2.00 +/-1.83 TPU: +/-2.00 +/-1.83 Radium-226 1.31 1.46 pCi/g I11 (0% -100%)

Uncert: +/-0.242 +/-0.253 TPU: +/-0.242 +/-0.253 Silver-I 08m U -0.0268 U -0.0196 pCi/g 31 (0% - 100%)

Uncert: +/-0.03 18 +/-0.03 81 TPU: +/-0.0318 +/-0.03 81 Thallium-208 0.43 1 0.488 pCi/g 12 (0% -20%)

Uncert: +/-0.0873 +/-0.0993 TPU: +/-0.0873 +/-0.0993 QC1201309689 LCS Actinium-228 0.960 pCi/g 04/11/07 14:15 Uncert: +/-0.454 TPU: +/-0.454 Americium-24 1 16.0 13.6 pCi/g 85 (75%-125%)

Uncert: +/-1.66 TPU: +/-1.66 Bismuth-212 U 0.185 pCi/g Uncert: +/-0.566 TPU: +/-0.5 66 Bismuth-2 14 0.703 pCi/g Uncert: +/-0.209 TPU: +/-0.209 Cesium- 134 U 0.0613 pCi/g Uneert: +/-0.0763 TPU: +/-0.0763 Cesium-i 37 6.20 6.01 pCi/g 97 (75%-125%)

Uncert: +/-0.575 TPU: +/-0.575 Cobalt-60 9.30 9.53 pCi/g 103 (75%-125%)

Uncert: +/-0.605 TPU: +/-0.605 Europium- 152 U 0.085 pCi/g Uncert: +/-0. 192 TPU: +/-0. 192 Europium- 154 U 0.100 pCi/g Uncert: +/-0.304 TPU: +/-0.304 Europium- 155 U -0.0215 pCi/g Uncert: +/-0.227 TPU: +/-0.227 Lead-212 0.829 pCi/g Uncert: +/-0. 191 TPU: +/-0.191 Page 197 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 10 of 17 Parnmame NOM Sample Qul 0 Units RPD % REC% Range AnIst Date Time Rad Gamma Spec Batch 623178 Lead-214 0.823 pCi/g Uncert: +/-0.2 14 TPU: +/-0.2 14 Manganese-54 U -0.0231 pCi/g Uncert: +/-0.0731 TPU: +/-0.0731 Niobium-94 U -0.0405 pCi/g Uncert: +/-0.0647 TPU: +/-0.0647 Potassium-40 U 0.626 pCi/g Uncert: +/-0.677 TPU: +/-0.677 Radium-226 0.703 pCi/g (75%-I125%)

Uncert: +/-0.209 TPU: +/-0.209 Silver- 108m U 0.00368 pCi/g Uncert: +/-0.0605 TPU: +/-0.0605 Thallium-208 0.294 pCi/g Uncert: +/-0. 116 TPU: +/-0.116 QC1201309687 MB Actinium-228 U -0.0426 pCilg 04/11/07 14:11 Uncert: +/-0.103 TPU: +/-0.103 Americium-24 1 U 0.0126 pCi/g Uncert: +/-0.0344 TPU: +/-0.0344 Bismuth-212 U -0.00392 pCi/g Uncert: +/-0.202 TPU: +/-0.202 Bismuth-2 14 U 0.0546 pCi/g Uncert: +/-0.0558 TPU: +/-0.0558 Cesium- 134 U -0.0151 pCi/g Uncert: +/-0.0279 TPU: +/-0.0279 Cesium- 137 U 0.00063 pCi/g Uncert: +/-0.0266 TPU: +/-0.0266 Cobalt-60 U -0.00454 pCi/g Uncert: +/-0.0313 TPU: +/-0.0313 Europium- 152 U 0.0126 pCi/g Uncert: +/-0.0636 TPU: +/-0.0636 Europium- 154 U -0.0126 pCi/g Uncert: +/-0.0788 Page 198 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gei.com QC Summary Workorder: 183607 Page 11 of 17 Parmnamne NOM Sample Qual OC Units RPD % REC% Ranae AnIst Date Time Rad Gamma Spec Batch 623178 TPU: +/-0.0788 Europium- 155 U -0.0475 pCi/g Uncert: +/-0.0523 TPU: +/-0.0523 Lead-21 2 U 0.00218 pCi/g Uncert: +/-0.041 TPU: +/-0.041 Lead-214 U 0.0112 pCi/g Uncert: +/-0.0739 TPU: +/-0.0739 Manganese-54 U -0.00906 pCi/g Uncert: +/-0.0247 TPU: +/-0.0247 Niobium-94 U -0.00268 pCi/g Uncert: +/-0.0236 TPU: +/-0.0236 Potassium-40 U 0.0137 pCi/g Uncert: +/-0.290 TPU: +/-0.290 Radium-226 U 0.0546 pCi/g Uncert: +/-0.0558 TPU: +/-0.0558 Silver- 108m U -0.00694 pCi/g Uncert: +/-0.0255 TPU: +/-0.0255 Thallium-208 U 0.00846 pCi/g Uncert: +/-0.0318 TPU: +/-0.0318 Rad Gas Flow Batch 623055 QC1201309416 183607002 DUP Strontium-90 U -0.0241 U 0.00838 pCi/g 0 (0% - 100%) NXL3 04/09/07 20:49 Uncert: +/-0.0185 +/-0.02 14 TPU: +/-0.0185 +/-0.0214 QC1201309418 LCS Strontium-90 1.44 1.58 pCi/g 110 (75%-125%) 04/09/07 20:49 Uncert: +/-0.102 TPU: +/-0.109 QC1201309415 MB Strontium-90 U -0.00496 pCi/g 04/09/07 20:49 Uncert: +/-0.0155 TPU: +1-0.0155 QC1201309417 183607002 MS Strontium-90 4.27 U -0.024 1 4.24 pCi/g 99 (75%-125%)

Uncert: +/-0.0 185 +/-0.293 TPU: +/-0.0185 +/-0.312 Batch 623056 QC1201309420 183607022 DUP Page 199 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 12 of 17 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gas Flow Batch 623056 Strontium-90 u -0.00786 U -0.00378 pCi/g 0 (0% - 100%) KSD1 04/09/07 22:02 Uncert: +/-0.0199 +/-0.0208 TPU: +/-0.0199 +/-0.0208 QC1201309422 LCS Strontium-90 1.41 1.49 pCi/g 106 (75%-125%) 04/09/07 22:02 Uncert: +/-0.0976 TPU: +/-0.107 QC1201309419 MB Strontium-90 U 0.0244 pCi/g 04/09/07 21:58 Uncert: +/-0.0 176 TPU: +/-0.0 177 QC1201309421 183607022 MS Strontium-90 5.25 U -0.00786 5.76 pCi/g 110 (75%-125%) 04/09/07 22:02 Uncert: +/-0.0199 +/-0. 395 TPU: +/-0.0199 +/-0.418 Rad Liquid Scintillation Batch 623181 QC1201309699 183607001 DUP Iron-55 U 20.4 U -5.61 pCi/g 0 (0% - 100%) VIXPI 04/11/07 10:07 Uncert: +/-3 3.0 +/-29.5 TPU: +/-33.1 +/-29.5 QC1201309701 LCS Iron-55 1170 1150 pCi/g 98 (75%-125%) 04/11/07 10:40 Uncert: +/-88.0 TPU: +/- 120 QC1201309698 MB Iron-55 U 46.2 pCi/g 04/11/07 14:56 Uncert: +/-46.3 TPU: +/-46.4 QC1201309700 183607001 MS Iron-55 1210 U 20.4 1120 pCi/g 93 (75%-125%) 04/11/07 10:23 Uncert: +/-33.0 +/-67.9 TPU: +/-33.1 +/-105 Batch 623182 QC1201 309703 183607022 DUP Iron-55 U -2.64 U 7.26 pCi/g 0 (0% - 100%) \4XP1 04/12/07 13:35 Uncert: +/-35.6 +/-37.1 TPU: +/-35.6 +/-37.1 QC1201309705 LCS Iron-55 1100 979 pCi/g 89 (75%-125%) 04/12/07 02:26 Uncert: +/-57.2 TPU: +/-89.2 QC1201309702 MB Iron-55 U 10.0 pCi/g 04/12/07 13:18 Uncert: +/-37.4 TPU: +/-37.4 QC1201309704 183607022 MS Iron-55 1220 U -2.64 1050 pCi/g 87 (75%-125%) 04/12/07 13:51 Uncert: +/-35.6 +/-70.0 Page 200 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 13 of 17 Parmname NOM Sample Quall QC Units RPD % REC% Range Anlst Date Time Rad Liquid Scintillation Batch 623182 TPU: +/-35.6 +/-104 Batch 623183 QC1201309707 183607003 DUP Nickel-63 U 3.24 U -2.99 pCi/g 0 (0%- 100%) \4XPI 04/11/07 18:20 Uncert: +/-7.22 +/-6.69 TPU: +/-7.22 +/-6.69 QC1201309709 LCS Nickel-63 536 478 pCi/g 89 (75%-125%) 04/11/07 19:22 Uncert: +/-15.5 TPU: +/-22.9 QC1201309706 MB Nickel-63 U -2.25 pCi/g 04/11/07 17:48 Uncert: +/-6.18 TPU: +/-6.18 QC1201309708 183607003 MS Nickel-63 582 U 3.24 470 pCi/g 81 (75%-125%) 04/11/07 18:51 Uncert: +/-7.22 +/-15.7 TPU: +/-ý/-7 22 +/-23.3 Batch 623184 QC1201309711 183607023 DUP Nickel-63 U -6.44 U -0.657 pCi/g 0 (0%- 100%) \4XP1I 04/10/07 23:57 Uncert: +/-12.8 +/-I LI TPU: +/-12.8 +/-11. 1 QC 1201309713 LCS Nickel-63 519 447 pCi/g 86 (75%-125%) 04/11/07 00:30 Uncert: +/-21.4 TPU: +/-26.4 QC1201309710 MB Nickel-63 20.2 pCi/g 04/10/07 23:41 Uncert: +/-10.4 TPU: +/-10.4 QC1201309712 183607023 MS Nickel-63 589 U -6.44 537 pCi/g 91 (75%-125%) 04/11/07 00:13 Uncert: +/-12.8 +/-25.8 TPU: +/-12.8 +/-32.5 Batch 623185 QC1201309715 183607001 DUP Technetium-99 U -0.00876 U -0.095 pCi/g 0 (0% - 100%) VIXPi 04/12/07 12:15 Uncert: +/-0.188 +/-0.240 TPU: +/-0.188 +/-0.240 QC 1201309717 LCS Technetium-99 19.1 18.1 pCi/g 95 (75%-125%) 04/12/07 12:58 Uncert: +/-0.691 TPU: +/-0.831 QC 1201309714 MB Technetium-99 U -0.0543 pCi/g 04/12/07 11:53 Uncert: +/-0.224 TPU: +/-0.224 QC1201309716 183607001 MS Page 201 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 14 of 17 Parmname NOM Samplee Quall QC Units RPD% REC % Range AnIst Date Time Rad Liquid Scintillation Batch 623185 Technetium-99 20.1 U -0.00876 19.2 pCilg 95 (75%-125%)

Uncert: +/-0.188 +/-0.636 TPU: +/-0.188 +/-0.802 Batch 623187 QC1201309719 183607022 DUP Technetium-99 U -0.152 U -0.0589 pCilg 0 (0% - 100%) "AXP1 04/12/07 02:01 Uncert: +/-0.263 +/-0.222 TPU: +/-0.263 +/-0.222 QC1201309721 LCS Technetium-99 18.7 18.5 pCilg 99 (75%-125%) 04/12/07 13:15 Uncert: +/-0.764 TPU: +/-0.897 QC 1201309718 MB Technetium-99 U -0.0489 pCilg 04/12/07 01:34 Uncert: +/-0.201 TPU: +/-0.201 QC1201309720 183607022 MS Technetium-99 19.9 U -0.152 18.8 pCi/g 95 (75%-125%) 04/12/07 02:27 Uncert: +/-0.263 +/-0.633 TPU: +/-0.263 +/-0.794 Batch 623189 QC1201309723 183607004 DUP Tritium U 0.0374 U 0.708 pCilg 0 (0%- 100%) ekXD2 04/07/07 23:41 Uncert: +/-1.35 TPU: +/-1.35 QC1201309725 LCS Tritium 11.0 9.59 pCilg 87 (75%-125%) 04/10/07 10:54 Uncert: +/-3.76 TPU: +/-3-77 QC1201309722 MB Tritium U 1.09 pCilg 04/07/07 22:39 Uncert: +/-1.38 TPU: +/-1.38 QC1201309724 183607004 MS Tritium 11.2 U 0.0374 11.1 pCilg 99 (75%-125%) 04/08/07 00:44 Uncert: +/-1.35 +/-1.79 TPU: +/-1.35 +/- 1.80 Batch 623190 QC1201309730 183607024 DUP Tritium U -0.323 U -0.697 pCilg 0 (0% - 100%) '\XD2 04/10/07 15:56 Uncert: +/-1.23 +/-1.18 TPU: +1-1.23 +1-1.18 QC1201309732 LCS Tritium 11.2 13.6 pCilg 122 (75%-125%) 04/10/07 17:29 Uncert: +/-1.84 TPU: +/-1.86 QC1201309729 MB Tritium U -0.97 pCi/g 04/10/07 15:10 Page 202 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com OC Summary Workorder: 183607 Page 15 of 17 Parnmame NOM Sam le OuaIl OC Units RPD% REC% Ranee AnIst Date Time Rad Liquid Scintillation Batch 623190 Uncert: +/-1.12 TPU: +/-1.12 QC1201309731 183607024 MS Tritium 11.3 U -0.323 11.0 pCi/g 98 (75%-125%) 04/10/07 16:43 Uncert: +/-1.23 +/-1.75 TPU: +/-1.23 +/-1.76 Batch 623192 QC1201309734 183607004 DUP Carbon- 14 u -0.00688 U -0.156 pCilg 0 (0%- 100%) 'AXD2 04/08/07 06:53 Uncert: +/-0.111 +/-0.107 TPU: +/-0.111 +/-0.107 QC1201309736 LCS Carbon- 14 6.65 6.36 pCi/g 96 (75%-125%) 04/08/07 09:0 1 Uncert: +/-0.197 TPU: +/-0.221 QC1201309733 MB Carbon-14 U -0.0677 pCi/g 04/10/07 20:22 Uncert: +/-0.105 TPU: +1-0.105 QC1201309735 183607004 MS Carbon- 14 6.85 U -0,00688 6.47 pCi/g 95 (75%-125%) 04/08/07 07:57 Uncert: +/-0.111 +/-0.203 TPU: +/-0.111 +/-0.226 Batch 623194 QC1201309739 183607024 DUP Carbon-14 U -0.0879 U -0.0295 pCi/g 0 (0% - 100%) NXD2 04/11/07 06:17 Uncert: +/-0.117 +/-0.119 TPU: +/-0.117 +/-0.119 QC 1201309741 LCS Carbon- 14 6.63 5.99 pCi/g 90 (75%-125%) 04/11/07 02:03 Uncert: +/-0.246 TPU: +/-0.263 QC1201309738 MB Carbon- 14 U -0.0568 pCi/g 04/11/07 00:59 Uncert: +/-0.112 TPU: +/-0.112 QC1201309740 183607024 MS Carbon- 14 7.24 U -0.0879 6.56 pCi/g 91 (75%-125%) 04/11/07 01:31 Uncert: +/-0.117 +/-0.270 TPU: +/-0.117 +/-0.288 Batch 625732 QC1201315809 1836070,37 DUP Iron-55 U -83.3 U 118 pCi/g 0 (0% - 100%) MAXP1 04/17/07 23:15 Uncert: +/-249 +/-257 TPU: +/-249 +/-257 QC1201315811 LCS Iron-55 11900 11000 pCi/g 92 (75%-125%) 04/17/07 23:48 Uncert: +/-578 TPU: +/-944 Page 203 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 16 of 17 Parmname NOM Sample Cluall QC Units RPD% REC%/ Range Anist Date Time Rad Liquid Scintillation Batch 625732 QC1201315808 MB Iron-55 U 32.5 pCi/g 04/17/07 22:59 Uncert: +/-258 TPU: +/-258 QC1201315810 183607037 MS Iron-55 12200 U -83.3 10800 pCilg 88 (75%-125%) 04/17/07 23:31 Uncert: +/-249 +/-571 TPU: +/-249 +/-920 Batch 625942 QC1201316379 183607028 DUP Carbon- 14 U -0.156 U -0.123 pCi/g 0 (0% - 100%) '\XD2 04/18/07 12:13 Uncert: +/-0.114 +/-0.113 TPU: +/-0.114 +/-0.113 QC1201316381 LCS Carbon-14 7.05 6.71 pCilg 95 (75%-125%) 04/18/07 14:20 Uncert: +/-0.251 TPU: +/-0.272 QC1201316378 MB Carbon-I14 U -0.114 pCilg 04/18/07 11:09 Uncert: +/-0.113 TPU: +/-0.113 QC1201316380 183607028 MS Carbon-14 7.24 U -0.156 7.05 pCi/g 97 (75%-125%) 04/18/07 13:17 Uncert: +1-0.114 +/-0.216 TPU: +/-0.114 +/-0.243 Notes:

The Qualifiers in this report are defined as follows:

Analyte is a surrogate compound Result is less than value reported Result is greater than value reported A The TIC is a suspected aldol-condensation product B For General Chemistry and Organic analysis the target analyte was detected in the associated blank.

BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more ND Analyte concentration is not detected above the detection limit R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.

UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier QC Samples were not spiked with this compound Page 204 of 205

GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com QC Summary Workorder: 183607 Page 17 of 17 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Y

A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.

• • Indicates analyte is a surrogate compound.

A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.

For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.

Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.

Page 205 of 205

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD ATTACHMENT 3 (DQA RESULTS)

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SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD ATTACHMENT 3A (PRELIMINARY DATA REVIEW)

Revision 0

Ilealth PhN sics Procedure 6PP-G(iGR-R5 12 1-001 Attacluncilt It. Re%. CY-00 I kIAJOR Preliminary Data Review Form - Samples for the Sign Test Suir~e\ I init- 9801 000(0 Su~c I ýnit Namne: SUBSURFACE RCA A

SurvxL\ Media: soil I PC of Sunc\: Final Status Survey I \ pe of Measurement: Gross Measurement Numbevr of M'easurenients: 32 Operational DCOI.:

BIASIC S'I A HS FICAI. QI ANI IFIFS Cs-I137 Co-60 Sr-90 Minimum Value: -5.53E-03 -3.72E-02 -2.41E-02 M~axinrnu Value: 6.6113-01 6.24E-01 4.03E-02 Mean: 7.6313-02 3.76"-2 -1.36E-03 Median: 5.61E-02 8.2016,03 -2.49E-03 Standard D)e'iation: 1.65E-01 1.23E-01 1.94"-2 Skev.: 3.6+O 4.52E4-00 1.43E+00 RAI)IONI ICI .1l)F (ONCIN IRA I ION (p*i/g)

NUMBER Cs- 137 Co-60 Sr-90 C's Identified? Co Identified? Sr Ided 9801-0000-003F _ 9.87E-02 4.41E-04 -1.14E-02 YES NO NO 99014)000-005F _ 8.62E-02 -1,17E.02 41E-02 YES NO NO 9801-0000-006F _5-93E-02 1.19E-02 -1.72E-02 YES NO NO 9801-0000-007F O.00E+00 1.O6E-02 -.1.1E-02 NO NO NO M81-0000-009F _ 7.03E-02 O.OOE.00 -1.95E-03 YES NO, NO 981-OO-009F __F 5.96E-02 2.1OSE.02 -2.49E-03 YES NO NO 9901-0000-OIOF 6.47E-03 6.82E-02 -5.78E-03 NO YES NO 9901-0000-011iF __4.80E-02 -1.79E-03 4.03E-02 NO NO YES 9601-0000-012F _ 6.81E-02 1.27E-03 -1.29E-03 YES NO NO 9801-0000-013F 4.36&W0 S.20E.03 -5.16E-04 NO NO NO 99014)000-014F _ 2.20E-01 6.24E-01 -2.OOE-02 YES YES NO 9901-0000-015F __6.61E-01 1.64E-01 5.95E-03 YES YES NO MI0-0000-016F _ 5AOE-04 4.09E-03 1.51E-03 NO NO NO 9801-0000-017F _ 1.94E..02 1.38t0 -1.02E-02 NO NO NO 9301 -0000-01 9F _ 1.24E-01 4.74E-02 3.79E-02 YES NO YES M9-0-000-019F _ 1.57E-02 2.02E-02 3.48E-02 NO NO YES 98014)00-020F 9.94E-03 -8,79E-03 1.9W6-02 NO NO NO 9801-0000-021F 1.t51E-02 -1,266-02 -7132E-03 NO NO NO 9801-0000-022F 1t48E-01 &.27E-02 -7,13E-03 YES YES -NO 9901-0000-023F 11.0960O1 -2.63E-02 -7.866-03 YES NO NO 9S01-0000024M 2.94E-02 -649E-03 1.l11E-02 NO NO NO "801-0000-025F _-5.536-03 -372E-02 1.85E-03 NO NO NO 9801-0000-026F 2.78E-02 3.03E-02 -1.65E-03 NO NO NO 9801-0000-027F _ 6.W4-02 1.156-02 -9,41E-03 YES NO NO 9801-0000-028F &614E-02 7.70E-03 8.77E-04 YES NO NO 9801-0000-029F _ 1.19E-02 2.44E-03 4.84E-03 NO NO NO 910 1-0000-03OF __ 56116.02 2.006-02 -3.42E-03 YES NO NO 9901-0000-03 1F 2.20E-02 11-A6E-03 -2.676-02 NO NO NO 9801-0000-032F __1.48E-02 *2,84E-02 1.04E602 NO NO NO 9901-0000-04OF _ 2.5311-02 6.42E-03 1.31E6-02 YES NO NO 9901-ODDO-041F __2.146-02 2.91E-02 1.106-02 YES NO NO 9801-0000-042F 4.9X6-02 1.346-02 AAWE-3~ YES NO NO Perfonned liv: ~ /-ca/

Ifate

• 2 Independent Re,, iex, ) c

lilalth I'livsics ProcIdurf 24265-000-GPP-GGGR-R5123-00(

Ilfaith Physics Procfdurf 24265-OOO-(iPP-GGGR-R5 I 23-OO(

Preliminary Data Review Form - Judgemental Samples Survey Unit: 9801-0000 1 Survey Unit Name:

SUBSURFACE RCA Classification:

Survey Media:

Type oc Survey: Final Status Survey ____ _ _ _ _ _ _ _ _ _ _ _ _

Type oe Measurement: Gross Measureumet ______ ______ ____________

Number of Measurements: 6zzzu _ _ _

Operational DCGCL:

BASIC STATISTICALQUANTITIES_____

Cs- 137 Co-60 Sr-90 Minimum Value: 1.57E-02 -3.79E-03 2.43E-03 Maximum Value: 7.75M-0 2.17E-02 3.2$E-02 Mean: 4.76E-02 9.03E-03 1.24E-02 Median: 4.96E-02 1.43E-02 7.32E-03 Standard D~eviation: 2.36E-02 1.06E-02 1.11 E-02 RADIONUCLIDE CONCENTRATION (pCi~g)

NUMBER Cs- 137 Cs I D'ed? Co-60 Co ID'ed Sr-90 Sr ID'ed 9801-0000-033B 1.57E-02 NO 2.17FE-02 NO 2.43E-03 NO 9801-0000-034B 7.75E-02 YES -618E-04 NO 9.13E-03 NO 980140000-035B 4.87E-02 YES 1.80E-02 NO 5.4212-03 NO 9801-0000-036B 4.84E-02 YES 1.O5E-02 NO 3.28E-02 YES 9801-0000-0378 i.74rz02 NO -6.79E-03 NO 1.12E-02 NO 9801-0000-039B -5.49E-02 YES 1.0415-02 NO 6.61 E-03 NO Performed 14) Date: Y~- / -c>7 Independent Rev'i AV' AA Date:

Dae 51 S12/0-) /c

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD ATTACHMENT 3B (GRAPHICAL REPRESENTATION OF DATA)

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Ilealth 11h\sics Procedure I kaih l~h~icsI'rocdurc(jGG(R-R5 I23-Rc\ .('Y-00 Attachmentn (

Quantile Plot For Cesium - 137 surxe' I lut 9801-0000 Sur~e\ I Init Name SUBSURFACF RCA

%lean 763F-02 pCi g

&95E-01 5.95E-01 4-95E-01 C.)

La 3.95E-01 0

2,95E-01 0

1.95E-01 9.50E-02

-5 OOE-W3 0 20 40 60 80 100 Percentage CS-137 Rank Percentage

-5,53E-03 2%

O.OOEOO0 2 5%

5.46E-04 3 8%

4.36E-03 4 11%

6.47E-03 5 14 %

9.94E-03 6 17 %

I 119E-02 7 20 %

1.48E-02 8 23 %

1.61E-02 9 27 %

I ZM7-02 10 30 %

1.94E-02 11 33  %

2.14E-02 12 36  %

2.20E-02 13 39  %

2.63E-02 14 42  %

2.78E-02 15 45 %

2.94E-02 16 48 %

4.60E-02 17 52 %

4.92E-02 18 55 %

5.61E-02 19 58 %

5,93E-02 20 61 %

5.98E.02 21 64 %

6.14E-02 22 67  %

6.14E-02 23 70  %

6.81 E-02 24 73  %

7.03E-02 25 77  %

8,62E-02 26 80  %

9.67E-02 27 83 %

1,09E-01 28 86 %

1 .24E-01 29 89 %

1 .46E-01 30 92 %

2.20E-01 31 95 %

6.BIE-01 32 98 %

Date Date S

Ikealth Phy sics P~rocedure (j(6(R-R5 I 23,-Rex .CY-0() Attaichment(

Quantike Plot For Cobalt - 60 Sur-%eN I nit: 9801-0000 Surxey I !nit Name: StIBlSI RlACl' RCA Wean: 4 211F402 p(-I'g 6.1 OE-01 5,60E-01 5.10E-01 4.60E-01 0 4.10E-01 3.60E-01 3,10E-01

0. 2.60E-01 C) 2.10E-01 1,60E-01 1 lGE-01 6,OOE-02 1.OOE-02

-400OE-02 '

100 0 20 40 6080 Percentage CoO-6 Rank Percentage

-3.72E-02 1 2%

-2.84E-02 2 5%

-2.63E-02 3 8%

-1.26E-02 4 11 %

-1.17E-02 5 14%

-8.79E-03 6 17 %

-6.49E-03 7 20%

-1.79E-03 8 23 %

O.OOE.OO 9 27 %

4.41 E-04 10 30 %

1.16E-03 11 33 %

1.27E-03 12 36 %

2.44E-03 13 39 %

4.09E-03 14 42 %

6.42E-03 15

• 45 %

7.70E-03 16 48%

8.20E-03 17 52 %

1.06E-02 18 55 %

1.15E-02 19 58 %

1.19E-02 20 61 %

1.34E-02 21 64%

1.38E-02 22 67 %

2.OOE-02 23 70 %

2.02E-02 24 73 %

2.16E-02 25 77 %

2.9 1E-02 26 80%

3.03E-02 27 83 %

4.74E-02 28 86%

5.27E-02 29 89%

6.82E-02 30 92%

1.64E-01 31 95%

6.24E-01 32 98%

Prepared Date: / C Date:III3III

I leaith PhN sics I'roccdure G(iG(R-R51I23-Rcx .(,y_0I tt( hcn (

Quantile Plot For Strontium-90 Surxc\ I. nit 980 1-0m00

'Surxc, I 'nit Namec St IVSIRIý-AC[ RCA

.Mean -1 36L-0; p~l.

5 OOL-02 4 OOE-02 3 OOE-02 2 OOE-02 C

.2 1 OOE-02 o 00E+GO C -1OOE-02 ,W0 ý **40Q 60 80 100 0

u

-2. 00E-02

-3 OOE-02

-4 OOE-02 Percentage Sr-90 Rank Percentage

-2.67E-02 1 2%

-ZO4E-02 2 5%

-2.OOE-02 3 8%

-1.72E-02 4 11 %

-1.14E-02 5 14 %

-1.11E-02 6 17 %

-1,02E-02 7 20  %

-9.41 E-03 8 23  %

-7.86E-03 9 27  %

-7.32E-03 10 30  %

-7.13-03 11 33 %

-5178E-03 12 36 %

-3.42E-03 13 39 %

-2.49E-03 14 42 %

-1.95E-03 15 45 %

-1.55E-03 16 48 %

-1.45E-03 17 52 %

-1.29E-03 18 55 %

-5.16E-04 19 58 %

8.77E-04 20 61 %

1.51E-03 21 64 %

1.85E-03 22 67 %

4.84E-03 23 70 %

5.85E-03 24 73 %

1.04E-02 25 77 %

1.1OE-02 26 80 %

1.11E-02 27 83 %

131E-02 28 86 %

1.99E-02 29 89 %

3.48E-02 30 92 %

3.79E-02 31 95 %

4.03E-02 32 98 %

Prepared B. - / L~Dale Reviewed Byý Date I1~~Z

I lealth Physics Procedure Icith hysis Pocedre 12-3-Rev.C'Y-(00I Attachment C IGGG~R-R5 Frequency Plot For Cesium-137 Survey Unit: 980 1-0000 Survey Unit Namne: SUBSURFACE RCA Mean: 0.076 pCi/g 10 8

Ur 6 0

4 S-UL1 2 0 -AL--

I0 000 0*I0 0 Icb 0*09,0 00*

0* 0* 0*@0 (,Z00 Upper End Value (pC i/g)

Upper End Observation Observation %

Value Frequency Frequency 0.000 2 6%

0.020 9 28%

0.040 5 16%

0.060 5 16%

0.080 4 13%

0.100 2 6%

01250 4 13%

0.500 0 0%

0.700 1 3%

Total 32 Prepared By: Date:

Reviewed By: Dt:si)-

Date: -5 1 1 1C)ý

Health Physics Procedure .C'Y-001I Attachment C I Icaih Physcs Proedure(;~~R-R51I23-Rex Frequency Plot For Cobalt-60 Survey Uit:fj~ 9)801I-0000)

Survey t init Name: SUBSU1 RFACE: RCA Mean: 0,042 pCi/g 10 8

CD) 6 4

L.

UL 2 0

0z 0 41N N0 Upper End Value (pCilg)

Upper End Observation Observation %

Value Frequency Frequency o.ooo 9 28%

o.006 5 16%

0.011 4 13%

0 022 7 22%

0.044 2 6%

0.088 3 9%

0,175 1 3%

0.350 0 0%

0.700 1 3%

Total 32 100%

// f P~repared B~y: D~ate: s.-

j Reviewed I 5 j, Re ixedIDate: C7

I lealth Physics Procedure Iait I~vsis 1rocdur I23-Rev.C'Y-00( I Attachment C I(GGGR-R5 Frequency P'lot For Sr - 90 Survey Unit: 980 1-0000 Survey Unit Name: SUI3BSJRIFACIi RCA Mean: -0.00 1 pCi/g 10 8

C 6

LL.

4 2

0 -- 4 0 CO II 0lz E =

0) 0~D0 i

000 0 0* 0 0 Q1 0* 0* 0' 0*

Upper End Value (pCilg)

Upper End Observation Observation %

Value Frequency Frequency

-0030 0 0%

-0.020 3 9%

-0.010 4 13%

0.000 12 38%

0.010 5 16%

0ý020 5 16%

0.030 0 0%

0.040 2 6%

0.050 1 3%

Total 32 100%

Prepared By: 7 Date: 57 - / - (ý-ý 'ý-

ReviewedB'_____Iat:5 Date: -5 o

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980t1-0000 RELEASE RECORD ATTACHMENT 3C (SIGN TEST)

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Ilealth Physics Procedure 6 P P-( i(i(iR-R5121-000 Attachment A, Roý CY-001 MAJOR I icaith Physics 1~roeedure (iPP-( ,( j(,R-R5 121-000 Attachment A. Rex (Y-0() I MAJOR Sign Test Calculation Sheet For Multiple Radionuclisdes SurecI nit Numbt-er: 9801 -0000 SurseN Unit Name: SU!1151R1-ACI RCA WP&IR#: NA Classification :A I Y PEII ((x error):0.05 I Y PE I W~error(:0.05 Radion icIides: Cs-137 Co-60 Sr-90 Operational DCGI, (pCi/g): 4.75 2.28 0.93 Results Cs- 137 Results Co-60 Results Sr-90 Weighted Sumn (W,) IX'(i-Result Sign 9.67E-02 4.41 E-04 - 1.14E-02 8.29E-03 9.92E-01 I 8.62E-02 -1.17E,02 -2.41E-02 -1.29E-02 11.01E+0O 5.93E.-02 1.19E-02 -1.72E-02 -7.91E-04 1.OOE+00 O.OOE+OO 1.06E-02 -I. IE-02 -7.29E-03 I.O1E+00 7.03E-02 O.OOE+00 -1.95E-03 1.27E-02 9.87E-01 I SA9E402 2.16E-02 49E-03 4.30E-02 9.57E-01 I 6.47E-03 6.92E-02 -5.78E-03 4.57E-02 9.34E-01 I 4.60E-02 -I.79Eo-03 4.03E-02 3.61E-02 9.64E-01 I 6.81E-02 1.27E-03 -1.29E-03 1.35E-02 9.96E-01 4.36E-03 8.20"-3 -5.16E-04 3.96E-03 9.96E-0I 2.20E-01 6.24E-01 -2.00E-02 2.98E-I 7.02E-01 I 6.61E-01 1.64E-01 5.85E-03 2.17E-01 7.S33E-01 1 5.46E-04 4,09E-03 I.51E-03 3.53E-03 9,96E-01 I 1.94E-02 1.39E-02 -1.02E-02 31E-04 1.OOE+00O 1.24E-01 4.74E-02 3.79E-02 8.7613-02 9. 12E-01 I 1.57E-02 2.02E.-02 3.48E-02 4.96E-02 9.50E-01 I 9.94E-03 -8.79E-03 t99E-02 1.96E-02 9.80E-01 I 1.51E-02 -1.26E-02 -7.32F-03 -i.02E-O2 I.O11E+00 I 1.46'E-01 5.27E-02 -7.1SE.03 4.62E-02 9.54E-01 I 1.09E-01 -2.63E-02 -7.g6E-03 2.96E-03 9.97E-01 I 2.94E-02 -6.49E-03 1.11 E-02 1.533E-02 9.85E-01 I

-5.53E-03 -3.72E-02 1.85E-03 -1.55E-02 I.02E+00 I 2.78E-02 3.03E-02 -1.55E-03 1.7513-02 9.83E-01 I 6.14E-02 1.15E-02 -9.41E-03 7.85E-03 9.92E-01 I 6.14E-02 7.7013-03 8.77E-04 1.72E-02 9.g3E-01 I 1.19E-02 2.44E-03 4.94E-03 8.78E-03 9.91E-01 I 5.61E-02 2.OOE-02 -3.42E-03 1.69E-02 9.93E-01I 2.20E-02 1.16E-03 -2.67E-02 -2.36E-02 1.02E+00 I 1.4&E-02 -2.94E-02 1.04E-02 1.94E-03 9,998E-O 1 2.53E-02 6.42E-03 1.31E3-02 2.22E3-02 9.781E-01 I 2.14E3-02 2.91E-02 11.10E3-02 2.91"3-2 9.71E-01 I 4.92E3-02 1.34E-02 -1.45E-03 1,47E3.02 9.85E3-01 I Number of Positive Differences (S+ ): 32 Critical Value: I3 Surse% ('nit: Meets Acceptance Criterion ly-Performed D;2 51 /: . Date: 5- 1' Independent RexievNL Date:

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 9801-0000 RELEASE RECORD ATTACHMENT 3D (QC SPLIT RESULTS)

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(Connecticut Yankee lDeconimissionling Pro~ject IIcalth 24265-000-6iPR-( A 1(1R-R5 12.4-000~t Attachment A IPhxsics Procedure Split Sample Assessment Form Survey 9801 Survey 000Survey Uni SUBSURFACE RCA Area#: IUnit #: Name:

Sample Plan or WPIR4: NA SME it: 0 Sample D)escription: Comparison of split samples collected from sample measurement location 4 13 and analyzed using gamma spectroscopy by an off-site vendor laboratory. The standard sample was 9801-0000-01 31-. the comparison sample was 9801-0000-013FS.

STAN DARD ICOMPARISON

_______ Value Error ______ Range Value E'rror Ratio Cs-137 4.36E-03 1.43E-02 0 NONE - 1.1 E-02 6.75E-03 2.64 NA Co-60 8.20E-03 1.44E-02 I NONE - -2.5S1E-03 5.15E-03 -0.31 NA K-40 9.83E+00 5.85E-01 17 0.75 - 1.33 1.06E+01 3.94E-01 1.08 Y

.4. 4 4 4 .4. 4 4

+ 9 4 4 4 9 4 4 I 4 4 8 4 Comments/Corrective Actions: For both Cs-137 and Co-60. the Table is provided to show acceptance criteria used to resolution rations are less than 4. The guidance for agreement assess split samples.

ranges. obtained from LJSNRC Inspection Procedure 84750, does not address resolution ratios less than 4. therefore, a Resolution Agreement Range determination of acceptability for such rations cannot be made. 4 7 0.50 2.00 K-40 was found to be present at an acceptable level of 8 15 0.60 1.66 agreement. T~herefore. no further action is warranted. 16 50 0.75 1.33 51 200 0.80 1.25

>200 0.85 1.18 WPIR - Work Plan' and Inspection Record SNIL .- Sample Measurement Location designation P'age I Of I

Connecticut Yankee Decommnissioning Project I Icalth 242651fl)O-( IPR-( I( ( JR-l<51I24-000( Attachment A Phy sics procedure Split Sample Assessment Form Survey 981 Survey 000Survey Unit SBUFC C Areag': 981 Unit 0001Name.: SBUFC C Sample Plan or WPlRt#: NA SML 4: 0 Sample

Description:

Comparison of split samples collected from sample measurement location _22and analyzed using gamma spectroscopy by an otT-site vendor laborator~y. The standard sample was 9801 -0000-022F. the comparison sample was 980 l-0000-022[S.

STAN DARD COMPARISON Radionuclide Activity Standard Resolution Agreement Actix, its Standard Comparison Acceptahle (YIfN)

________ Value Firror ______ Range Value E~rror Ratio Cs-137 1.46E-01 2.766-02 5 0.5- 2 7.28E-02 1.58E-02 0.50 Y Co-60 5.27E-02 2.04E-02 3 NONE - 2.17F,02 1.14E-02 0.41 NA K-40 1.06E+01 6.15E-01 17 0.75- 1.33 1.12E+01 5.15E-01 1.06 Y Comments/Corrective Actions~:For Co-60. the resolution ratio TFable is provided to show acceptance criteria used to was less than 4. The guidance for agreement ranges. obtained assess split samples.

from USNRC Inspection Procedure 84750. does not address resolution ratios less than 4. therefore, a determnination of Resolution Agreement Range acceptability for such rations cannot be made. 1-16wever. for 470.50 2.00 both Cs- 13 7 and K-40 were found to be present at an acceptable 8 15 0.60 1.66 levels of agreement. Therefore, no further action is warranted. 16 50 0.75 1.33 5I 200 0.80 1.25 1200 0.85 1.18 Performed By: )Date: Rev iewed [By: Date WPIR - Work Plan and Inspection Record SMIL - Sample Measurement Location designation Page I ot, I

SUBSURFACE SOILS IN THE RADIOLOGICALLY CONTROLLED AREA SURVEY UNIT 980 1-0000 RELEASE RECORD ATTACHMENT 3E (HTD ANALYSIS)

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Sample ID 15 Pu-241 C-14 Ni-63 TC-99 H-3 Cs-1134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam TOTAL DCGL DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801 -0000-00SF 0.0698 FRACTION 0.000 0.000 0.000 0.000 0.000 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.025 Fract.of Unity Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-1 34 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-0000-008F 0.024 FRACTION 0.000 0.000 0.00 0.000 0.000 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Fract~of Unity Sample ID 15 Pu-241 C-14 N 1.3 TC-99 H-3 Cs-I 34 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-0000-009F 0.0804 FRACTION 0.000 0.000 0.000 0.000 0.000 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Fractaof Unity Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-1 34 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loa8m DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-0000-011F 66.3 FRACTION 0.000 0.000 0.000 0.000 0.000 0.000 0.004 0.000 0.000 0.000 0.000 0.000 0.004 Fract~of Unity Sample ID 15 Pu-241 C-14 Ni-63 TC-99 H-3 Cs-1 34 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-000-012F 0.0635 FRACTION 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 0.000 0.000 0.000 0.000 0.004 Fract~of Unity Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-I 34 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-I O8m DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-0000-1IF 0.0468 FRACTION 0.000 0.000 0.000 0.000 0.000 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Fract.of Unity Sample ID 15 Pu-2411 C-14 NI-63 TC-99 H-3 Cs-I 34 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-0000-1SF 0.0845 FRACTION 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 0.000 0.000 0.000 0.000 0.005 Fract.of Unity Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-0000-2OF 0.022 FRACTION 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.000 0.000 0.000 0.002 Fract.of Unity Sample ID 15 Pu-241 C-14 Ni-63 TC-99 H-3 Cs-134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-40000-22F 0.0657 0.0329 FRACTION 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 0.000 0.000 0.000 0.008 0.012 Fract.of Unity Sample ID 15 Pu-241 C-14 Ni-63 TC-99 H-3 Cs-1 34 Fe-55 Amn-241 Mn-54 Nb-94 Pu-238 Ag-l0am DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-40000-24F 0.0489 0.038 FRACTION 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 0.009 0.000 0.000 0.014 IFract.of Unity

Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801400W042SF 0.0305 FRACTION 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 0.000 0.000 0.000 0.000 0.002 Fract-of Unity Sample ID 15 Pu-241 C-14 NI-63 TC-99 HW3 Cs-134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 980140004-2SF 2.17 0.000 0.000 0.000 0.000 0.000 0.000 0.00 0.009 Fract~of Unity FRACTION 0.000 0.000 0.000 0.000 0.009 Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 980140004-345 0.0508 0.139 0.026 Fract~of Unity FRACTION 0.000 0.000 0.000 0.000 0.000 0.018 0.000 0.000 0.000 0.000 0.008 0.000 Sample ID 15 Pu-241 C-14 Ni-63 TC-99 H-3 Cs-1 34 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 980140004-355 0.0343 0.008 0.008 Fract.of Unity FRACTION 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-1 34 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DOOL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 98014-000368 0.0521 0.000 0.000 0.019 Fract.of Unity FRACTION 0.000 0.000 0.000 0.000 0.000 0.019 0.000 0.000 0.000 0.000 Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 980140004-375 0.0445 0.000 0.000 0.000 0.016 Fract.of Unity FRACTION 0.000 0.000 0.000 0.000 0.000 0.016 0.000 0.000 0.000 Sample ID 15 Pu-241 C-14 Ni-63 TC-99 H-3 Cs-134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-108m DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-0000-41F 0.0362 0.000 0.000 0.000 0.000 0.013 Fract~of Unity FRACTION 0.000 0.000 0.000 0.000 0.000 0.013 0.000 0.000 Sample ID 15 Pu-241 C-14 NI-63 TC-99 H-3 Cs-134 Fe-55 Am-241 Mn-54 Nb-94 Pu-238 Ag-loam DCGL is DCGL 522 3.396 433.8 7.56 247.2 2.81 16500 15.5 10.4 4.28 17.7 4.29 9801-40000-42F 0.0445 0.0506 0.016 0.000 0.003 0.000 0.000 0.000 0.000 0.019 Fract.of Unity FRACTION 0.000 0.000 0.000 0.000 0.000