ML090130382

Millstone Power Station - Revision 002 to CP 3804L Procedure Action Request, Pass Containment Air Sample, Dated 12/26/2008

ML090130382
Person / Time
Site:	Millstone
Issue date:	12/26/2008
From:	Dominion Nuclear Connecticut, Northern States Power Co
To:	Document Control Desk, Office of Nuclear Security and Incident Response
References
000108216 CP 3804L, Rev 002-02
Download: ML090130382 (41)

Text

TPCIW2 To Facility Address DOCUMENT CONTROL DESK MP Department

806 NUC REGULATORY COMMISSION (0140)DOCUMENT CONTROL DESK WASHINGTON, DC 20555 PASSPORT DOCUMENT TRANSMITTAL Page: I NH Nl I WI II II II I From : NDS Date/Time 12/26/08 08: Trans No. : 000108216 Total Items: 00001 CONT DOCUMENTS Transmittal Group Id: 805307 Item Facility Type Sub Document Number Title Sheet Revision Doc Date Copy # Media Copies* 0001 MP PROC CH CP 3804L 002 02 P 01 PASS CONTAINMENT AIR SAMPLE Please check the appropriate response and return form to NDS Bldg 475/3 Millstone Power Station or Fax to 860-440-2057.

All documents received.Documents noted above not received (identify those not received).

I no longer require distribution of these documents.

Date: Signature:

02/26/08 Approval Date 02/27/08 Effective Date r_Procedure Action Request L__Document No.: CP 3804L Writer:.Initiator Provencher Lebruto Rev. No. Minor Rev.o02 02 Title: PASS Containment Air Sample For New Documents:

Document is QA LI DH Title: (Include distribution information on page 2)El Revision Z Minor Revision El Cleanup Revision E] Biennial Review El Void (Cancel) El Suspend (Do Not Use) El Expire 0l Superceded By: Comments:

El Administrative Correction FLS: Associated ARs Reviews Print Sign Date Department Emergency Planning jj -LI m 4 4 .4. 4 .4.I p I LI WC 9 Att 3 Req. 0 Yes Z No Dave Provencher I-12/16/08 NPO Licensing Basis / RCD lI Dave Provencher 12/16/08 NPO (50.59/72.48 Screen Req. El Yes 0 No) n D Tech Independent

[ Bob McDonald j ala'/?' Validation None El Field -Use Simulated Performa El Table Top and FI Comparison MP-05-DC-SAP01-004 Use MP-05-DC-SAP 1-004 Walk-through (minimum of two) Print Sign Date Dept Coordinator I Member Training: 0 None El Nuclear Training .L Briefing El Familiarization Z] SQR Review and Approval Approval ] Disapproval El F] FSRC Review and Approval NIA (1) Department Head. Sign/Date (2) FSRC Meeting Number (3) FSRC ADDroval Sion F] Department Head Review and Aporoval I I -- --F .............................

FI ........NIA (1) Department Head Approval Sign Sign/Date (2) DepartmeUF$Hdd Approval Sign 4 WC 9 database Approval Date: /2.22.'2 Effective Date: /2-3o.'E" ElUpdated IfReq.MP-05-DC-FAPO1.1-005 Rev. 002-03 Page 1 of__-j N MILLSTONE POWER STATION CHEMISTRY PROCEDURE) ~ ~ritainment Air[4,.Ref. 6.28]Sample CP 3804L Rev. 002-02 is NOTE A review by the Emergency Planning Department is required whenever this procedure is revised or whenever changes are made to this procedure which impact the ability to collect and analyze a PASS sample.Approval Date: Effective Date: 12/22/08 12/30/08 I]Level of Use Continuous Millstone Unit 3 Chemistry Procedure PASS Containment Air Sample TABLE OF CONTENTS 1. PU R PO SE .....................................................

2 2. PREREQU ISITES ..........................

....................

2 3. PRECAU TIONS ................................................

7 4. INSTRU CTIONS ...........................

• ...................

8 4.1 Preparation for PASS Sample Acquisition

......................

8 4.2 Sam ple Acquisition

........................................

15 4.3 System Flush Prior To Sample Retrieval

......................

17 4.4 Retrieval of Containment Air Samples .......................

18 4.5 Sample Analysis ..........................................

21 4.6 Gas Isotopic Analysis ......................................

22 4.7 Gas Composition Analysis .................................

24 4.8 Restoration from PASS Sample Acquisition

..................

25 5. REVIEW AND SIGNOFF ....................................

31 6. REFEREN CES ................................................

31 7.

SUMMARY

OF CHANGES ..................................

32 ATTACHMENTS AND FORMS Attachment 1, "Initial System Alignment Check" ...................

35 Attachment 2, "Gas Activity Worksheet" ..........................

36 Attachment 3, "3SSP-SAS2 Septum Replacement" ..................

37 Attachment 4, "Containment Air PASS Simplified Drawing"............

38 CP 3804L-001,"PASS Containment Air Sample Data" CP 3804L-002,"PASS Containment Air Sample Restoration Lineup" Level of Use CP 3804L .Contin sSTOP THINK CT EVIEW Rev. 002-02 Continuous 1of38

1. PURPOSE 1.1 Objective Provide instructions for operation of the Unit 3 containment air post accident sample system for containment air sample acquisition when high radioactivity levels, may preclude the normal (conventional) sampling method.This procedure satisfies regulatory commitment B18443-01 to maintain contingency plans for obtaining and analyzing highly radioactive samples of the containment atmosphere.

This procedure was developed using the reactor technical manual for the containment air PASS (Ref.6.2) and other documents identified herein.1.2 Discussion If conditions arise that will not allow Sections 4.1 through 4.4 to be completed, the procedure user will be directed to Section 4.8,"Restoration from PASS Sample Acquisition," to return the system to normal.Attachment 4 contains a simplified drawing of the containment air post accident sample system.1.3 Applicability This procedure is applicable when in-plant radioactivity levels are too high to permit containment air sampling via the normal (conventional)

(method.1.4 Frequency As required during periods of elevated in-plant levels. I )2. PREREQUISITES

2.1 General

2.1.1 Heat tracing panel 3HTS-PNLA3 (OP 3352) has been energized for. at least 1/2 hour.2.1.2 To prevent condensation and iodine plate-out in the sample lines, verify containment temperature is less than or equal to 170 F Level of Use CP 3804L STOP THINK ACT V HREViE Rev. 002-02 Continuous 2 2of 38 E 2.1.3 Key has been obtained to unlock the following:

Train A 3SSP*V51 3SSP*V59 3HCS*V2 3HCS*V3 3HCS*V6 Train B 3SSP*V52 3SSP*V60 3HCS*V9 3HCS*V10 3HCS*V13 2.1.4 Health Physics has been notified that a containment air PASS sample will be taken.2.1.5 Health Physics has evaluated need for RWP 2.1.6 Lab ventilation is operating.

2.1.7 Lead brick shielding has been placed in lab ventilation hood.2.1.8 Computer radioisotopic analysis system in operation and calibrated.

2.1.9 Gas chromatograph has been set up and calibrated, or calibration has been initiated for PASS containment air sample analysis if desired.2.1.10 Proper operation of sample syringes in PASS suitcase has been.verified.2.1.11 13 cc gas vial has been stoppered and evacuated.

2.1.12 One train of SLCRS in operation.

I]1(D E Level of Use Continuous STOP THINK<TH It'd K CP 3804L ACT REVIEW' Rev. 002-02-+ ... of 38 I 2.1.13 Manager of Radiological Dose Assessment (MRDA) or the Assistant Manager of Radiological Dose Assessment (AMRDA)has requested a containment air sample to include the following:

Check Requested Analysis Sample Equipment Needed Gas isotopic n] Gas composition"GAS ISOTOPIC" syringe, stoppered and evacuated 13 cc gas vial I0"GAS COMP" syringe Check Sample Point Ij Hydrogen Recombiner Train A 1] Hydrogen Recombiner Train B 2.1.14 Containment Air PASS Team has completed pre-job brief as follows:* Manager of Operational Support Center (MOSC) -designates, assembles, and briefs the Containment Air PASS Team for implementation of this procedure* Operational Support Center Assistant Radiological Protection Supervisor (OSC ARPS) with the concurrence of the Manager of Radiological Consequence Assessment (MRCA) -specifies the radiological controls required for implementation of this procedure 2.2 Documents El 2.2.1 CP 2803/3803P, "Operation and Calibration for Perkin-Elmer Autosystem XL Gas Chromatograph" 2.2.2 C CP 803.6, "Gamma Spectroscopy Counting System Maintenance and Operation" 2.2.3 CP 3804K Attachment, "PASS Sample Equipment Inventory" 2.2.4 PI-AA-200, "Corrective Action" 2.2.5 RP16, "Trouble Reporting" 2.2.6 RWP for PASS sample collection.

2.2.7 Gas sample isotopic printout©I Level of Use Continuous STFOP R EV IEWýýCP 3804L Rev. 002-02 4 of 38 I I 2.3 Personnel 2.3.1 Assistant Director, Technical Support (ADTS)2.3.2 Manager of Radiological Dose Assessment (MRDA) or Assistant Manager of Radiological Dose Assessment (AMRDA)2.3.3 Manager of Operational Support Center (MOSC)2.3.4 Operational Support Center Assistant Radiological Protection Supervisor (OSC ARPS)2.3.5 Manager of Control Room Operations (MCRO)2.3.6 Manager of Radiological Consequence Assessment (MRCA)2.3.7 Containment Air PASS Team consisting of the following personnel:

• At least two Chemistry Technicians

• At least one Health Physics Technician 1-Level of Use Continuous STOP CP 3804L THNK ACT HVEVI'W Rev. 002-02 5< of 38 4 2.4 Tools 2.4.1 and Consumables Located in Unit 3 Chemistry Lab 0 13 cc gas vial* 13 cc gas vial stopper* 24 Lead bricks* PASS transport cart* Syringe transfer container* 250 [d syringe labeled "GAS ISOTOPIC"* 2.0 ml syringe labeled "GAS COMP"* Key to 3SSP -PNL2 (Issued to U3 Chemistry personnel)

• Key to the following valves: Train A Train B 3SSP*V51 3SSP*V52 3SSP*V59 3SSP*V60©I 3HCS*V2 3HCS*V3 3HCS*V6 Watch 3HCS*V9 3HCS*V10 3HCS*V13 2.4.2 Located in PASS Cabinet in H 2 Recombiner Building* Spare syringe needles* 3SSP-SAS2 septums* 1/2" socket wrench 0 Phone headset* Scribe* Tweezers* Septum insertion tool* Calculator o Damper operating tool* Flat-tipped screwdriver

• Valvewrench I I 2.5 Responsibilities 2.5.1 The ADTS shall make the decision to obtain a sample using PASS.2.5.2 The Manager of Operational Support Center designates, assembles and briefs the PASS team.1A Level of Use Continuous STOP THINK ACT CP 3804L REVIEW Rev. 002-02 S 6 of 38 I I 2.5.3 The Manager of Radiological Consequence Assessment specifies PASS team radiological controls.2.5.4 The Operational Support Center Assistant Radiological Protection Supervisor assigns HP technicians and briefs the PASS team on radiological conditions.

2.5.5 The Manager of Radiological Dose Assessment or the Assistant Manager of Radiological Dose Assessment specify PASS team sampling and analysis requirements.

2.6 Definitions

2.6.1 SLCRS

-supplementary leak collection and release system 2.6.2 CR -Condition Report 3. PRECAUTIONS 3.1 The inside of 3SSP-SAS2, containment air sample module, is potentially contaminated.

Proper Health Physics practices and RWP requirements must be followed to prevent the spread of contamination.

3.2 Nitrogen

pressures

>100 psig can damage the tubing in 3SSP-PNL2.

I Level of Use Continuous S- JO F'............................

ACT-CP 3804L REVIEW Rev. 002-02 7 of 38 I 4. INSTRUCTIONS

4.1 Preparation

for PASS Sample Acquisition

4.1.1 PERFORM

the following and INITIAL CP 3804L-001:

• VERIFY "General Prerequisites" have been completed* REVIEW Section 3, "Precautions" 4.1.2 IF during performance of Sections 4.1 through 4.8 any operational problems are encountered, RECORD noted problems on CP 3804L-001.

4.1.3 IF during performance of Sections 4.1 through 4.4, operational problems are encountered that will not allow sampling to be completed, Go To Section 4.8, "Restoration from PASS Sample Acquisition." 4.1.4 PROCEED to containment air sample module with the following:

• Stoppered and evacuated 14.4 cc gas vial* Key to 3SSP-PNL2 (Issued to U3 Chemistry personnel) 0 Key to the following valves: Train A Train B 3SSP*V51 3SSP*V52 1-1 3SSP*V59 3HCS*V2 3HCS*V3 3HCS*V6 3SSP*V60 3HCS*V9 3HCS*V10 3HCS*V13* Watch" CP 3804L-001 and CP 3804L-002* Syringe transfer container 4.1.5 UNLOCK 3SSP-PNL2, containment air sample remote panel.4.1.6 Refer To Attachment 1 and CHECK system alignment.

4.1.7 NOTIFY

MCRO of the following:

a. 3HVR*DMP60 will be opened Level of Use Continuous STO-1P ITHII.K KAcT f REVIEW CP 3804L Rev. 002-02 8 of 38 I b. IF in operating Modes 1-4, Enter LCO 3.6.6.2 for 3HVR*DMP60

[Ref. 6.1]c. PERFORM one of the following:

1) IF hydrogen recombiner train A was selected in step 2.1.13, NOTIFY MCRO that the following valves will be opened if not already open:* 3HCS*V2, recombiner 1A supply outer isolation 0 3HCS*V3, recombiner 1A supply inner isolation-3HCS*V6, recombiner RBNR-1A return isolation 2) IF hydrogen recombiner train B was selected in step 2.1.13, NOTIFY MCRO that the following valves will be opened if not already open: " 3HCS*V9, recombiner 1B supply outer isolation* 3HCS*V10, recombiner 1B supply inner isolation* 3HCS*V13, recombiner RBNR-lB return isolation d.. IF in operating Modes 1-4, Track Tech Spec surveillance requirements of 4.6.1.1.a for thevalves opened in step 4.1.7 c.II NOTE Constant communications with the control room are required when 3HCS*V2, 3HCS*V3, 3HCS*V6, 3HCS*V9, 3HCS*V1O, or 3HCS*V13 are opened in Modes 1-4;4.1.8 IF in operating Modes 1-4, DON phone headset and ESTABLISH communications with Control Room.4.1.9 PERFORM the following:

a. Using damper operating tool, OPEN 3HVR*DMP60, 3SSP-SAS1/SAS2 exhaust isolation damper [Ref. 6.1]b. OPEN 3HVR-DMP1301, 3SSP-SAS2 exhaust damper[Ref. 6.1].Ll Level of Use Continuous STOP~THINK A~T RVIEW CP 3804L-AU I REVIVV'Rev.

002-02 9 of 38 4 I 4.1.10 PERFORM the following at 3SSP-PNL2, containment air sample remote panel: a. ZERO timer.b. PUSH and HOLD "POWER ON" button for 1 to 2 seconds to energize remote operating module and RECORD time: NOTE A lit fuse indicator light indicates the fuse is blown.c. VERIFY line fuses and blower fuse indicator lights are not lit.d. OPEN 3SSP-V53, nitrogen supply to containment air sample PNL2.NOTE 3SSP-PCV82 may require periodic adjustment to maintain 45-50 psig outlet pressure.N n r 0 CAUTION i Nitrogen pressures

> 100 psig can damage the tubing in 3SSP -PNL2.El e. ADJUST 3SSP-PCV82, nitrogen pressure regulator, to 45- 50 psig.I1 Level of Use Continuous STOP THINK AC FVEVYI4 CP 3804L Rev. 002-02 10 of 38 0 6 ALARA The inside of 3SSP-SAS2, containment air sample module, is potentially contaminated.

Proper Health Physics practices and RWP requirements must be followed to prevent the spread of contamination.

4.1.11 At 3SSP-SAS2, containment air sample module, CHECK exhaust fan is running.4.1.12 IF exhaust fan is not running, PERFORM the following at 3SSP-PNL2, containment air sample remote panel: a. PUSH "POWER ON" button to de-energize panel.b. PUSH and HOLD "POWER ON" button for 1 to 2 seconds to energize remote operating module and RECORD time: c. At 3SSP-SAS2, containment air sample module, CHECK exhaust fan is running.d. IF. exhaust fan is not running, NOTIFY MOSC..I 4 I I I Level of Use Continuous STOPV THINK ACT CP 3804L REVIEW Rev. 002-02* S11 of 38 I]NOTE If hydrogen recombiner train A is running, the following valves will already be open: 3HCS*V2, recombiner 1A supply outer isolation* 3HCS*V3, recombiner 1A supply inner isolation* 3HCS*V6, recombiner RBNR-1A return isolation CAUTION`ý7 4 It is imperative not to push in on the hand wheel when operating the following valves unless SM/US permission is obtained.

This engages the clutch override and could result in damage to the valve.Train A Train B 3HCS*V2 3HCS*V6 3SSP*V59 3HCS*V9 3HCS*V13 3SSP*V60 3HCS*V3 3SSP*V51 3HCS*V10 3SSP*V52 4.1.13 IF hydrogen recombiner train A was selected in step 2.1.13, UNLOCK and OPEN the following valves:* 3HCS*V2, recombiner IA supply outer isolation* 3HCS*V3, recombiner 1A supply inner isolation* 3HCS*V6, recombiner RBNR-1A return isolation* 3SSP*V51, containment air sample return cross-connect

• 3SSP*V59, containment air sample supply cross-connect Level of Use A'Jo .WAK Continuous sTOP AJi~CP 3804L REVI:w Rev. 002-02* <' 12 of 38 F1 CAUTION V/It is imperative not to push in on the hand wheel when operating the following valves unless SM/US permission is obtained.

This engages the clutch override and could result in damage to the valve.Train A Train B 3HCS*V2 3HCS*V6 3SSP*V59 3HCS*V9 3HCS*V13 3SSP*V60 3HCS*V3 3SSP*V51 3HCS*V10 3SSP*V52 NOTE If hydrogen recombiner train B is running, the following valves will already be open:* 3HCS*V9, recombiner 1B supply outer isolation* 3HCS*V10, recombiner 1B supply inner isolation* 3HCS*V13, recombiner RBNR-1B return isolation I I 4.1.14 IF hydrogen recombiner train B was selected in step 2.1.13, UNLOCK and OPEN the following valves:* 3HCS*V9, recombiner 1B supply outer isolation* 3HCS*V10, recombiner 1B supply inner isolation* 3HCS*V13, recombiner RBNR-1B return isolation* 3SSP*V52, containment air sample return cross-connect , 3SSP*V60, containment air sample supply cross-connect 4.1.15 At 3SSP-PNL2, containment air sample remote panel, POSITION the following valves as indicated:

a. 3SSP-V2037 to "OPEN." b. 3SSP-V2035 to "SAMPLE." c. 3SSP-V112 to "OFE" d. 3SSP-V2034 to "OFF" 0 Level of Use Continuous

'-'101' H I ]K~ACT~ RKVIEW:i CP 3804L Rev. 002-02 13 of 38 0 ALARA.3SSP-PNL2, containment air sample remote panel, requires a 15 minute warm-up period. The time that the instrument was energized is recorded on Chem Form 3804L-1. The PASS Team Health Physics Technician will determine the best location to wait for the completion of the warm-up.4.1.16 REQUEST Health Physics Technician determine most appropriate location to wait for completion of 15 minute warm-up of 3SSP-PNL2, containment air sample remote panel.-End of Section 4.1 -E 0 Level of Use Continuous S O, p .11111 ACT REVIEW CP 3804L Rev. 002-02 14 of 38

4.2 Sample

Acquisition

4.2.1 Refer

To step 4.1.10 b. or step 4.1.12 b. and VERIFY 15 minute warm-up of 3SSP-PNL2, containment air sample remote panel, is complete.4.2.2 Refer To CP 3804L-001 and MARK box corresponding to hydrogen recombiner train being sampled.4.2.3 At 3SSP-PNL2, containment air sample remote panel, POSITION 3SSP-V112 to "SAMPLE INFLUENT" 4.2.4 At 3SSP*PNL3, post accident sample panel, PERFORM the following:

a. ROTATE 'AIR SAMPLE PUMP P4 SPEED CONTROL'knob fully clockwise.

b. PUSH 'AIR SAMPLE PUMP P4" start button to start 3SSP-P4 4.2.5 RECORD time purge started: 4.2.6 At 3SSP-PNL2, containment air sample remote panel, RECORD flow rate: 1pm 4.2.7 PERFORM the following calculation to determine purge time in minutes.Purge time = 220 / purge flow rate in lpm Purge time = 220 / 1pm = _ minutes 4.2.8 WHEN purge time has passed, ISOLATE sample as follows: a. At 3SSP*PNL3, post accident sample panel, ADJUST 3SSP'-P4 speed control to achieve a sample flow rate of 10 to 12 1pm indicated on 3SSP-PNL2, containment air sample remote panel.b. At 3SSP-PNL2, containment air sample remote panel, RECORD flow rate: 1pm c. POSITION 3SSP-V2037 to "CLOSE." CP 3804L Level of Use " ; P384 Lel use I [J K AT> REVIEW .Rev. 002-02 Continuous 15 of 38 E I d. CHECK that flow rate is less than value recorded in step 4.2.8 b.e. WAIT 1 minute.f. POSITION 3SSP-V2035 to "BYPASS AND FLUSH." g. Refer To CP 3804L-001 and RECORD sample date and time.h. POSITION 3SSP-V112 to "OFF" 4.2.9 At 3SSP*PNL3, post accident sample panel, PUSH 'AIR SAMPLE PUMP P4" stop button to stop 3SSP-P4.-End of Section 4.2 i Level of Use Continuous STOP THINK ACT- I REVIEW CP 3804L Rev. 002-02 16 of 38

4.3 System

Flush Prior To Sample Retrieval 4.3.1 At 3SSP-PNL2, containment air sample remote panel, INITIATE nitrogen purge as follows: a. POSITION the following valves as indicated:

1) 3SSP-V112 to "NITROGEN FLUSH." 2) 3SSP-V2037 to "OPEN." 3) 3SSP-V2034 to "ON." b. RECORD flow rate: 1pm c. WAIT 3 minutes.d. POSITION 3SSP-V2037 to "CLOSE." e. CHECK that flow rate is less than value recorded in step 4.3.1 b.f. WAIT 3 minutes.g. POSITION the following valves as indicated:

1) 3SSP-V2034 to."OFE" 2) 3SSP-V112 to "OFE" 3) 3SSP-V2037 to "OPEN." Health 4.3.2 Based on radiation reading in sample module room, DIRECT Physics Chemistry Technicians to perform one-of the following:

Technician

• Go To step 4.3.1 and REPEAT flush 0 Go To Section 4.4 and retrieve samples-End of Section 4.3 -Level of Use f, CP 3804L Continuous STOP .THINK .ACT Rev. 002-02 17 of 38 1-4.4 Retrieval of Containment Air Samples 4.4.1. At 3SSP-SAS2, containment air sample module, OPEN cabinet door.4.4.2 IF gas isotopic sample was requested in step 2.1.13, PERFORM the following:

a. VERIFY needle is screwed fully into 250 [d syringe labeled"GAS ISOTOPIC." NOTE 3SSP-V2036 is open when handle is inline with needle guide.b. OPEN 3SSP-V2036, containment air sample module internal bypass valve.c. INSERT syringe into needle guide until syringe nut is engaged.E& ALARA 1. Do not unscrew syringe body more than 2 turns counterclockwise.

Excessive turns will disengage needle from syringe.2. Steps 4.4.2 d. through g. should be performed rapidly to minimize exposure.d. Rapidly DRAW 250 [l gas sample into syringe and TURN syringe body 2 turns counterclockwise to lock sample in syringe.e. REMOVE syringe from needle guide and INSERT needle into stoppered 13 cc gas vial.f. HOLD syringe tip and TURN syringe body 2 turns clockwise to unlock syringe and INJECT contents of syringe into stoppered 13 cc gas vial.g. PLACE syringe and gas vial into syringe transfer container and PLACE lid on syringe transfer container.

I0 I0 Level of Use Continuous STOP THfINK~~Q REVIEW CP 3804L Rev. 002-02 18 of 38 I I h. CLOSE 3SSP-V2036, containment air sample module internal bypass valve.4.4.3 IF gas composition sample was requested in step 2.1.13, PERFORM the following:

a. VERIFY needle is screwed fully into 2.0 ml syringe labeled"GAS COME" b. OPEN 3SSP-V2036, containment air sample module internal bypass valve.c. INSERT syringe into needle guide until syringe nut is engaged.A ALARA 1. Do not unscrew syringe body more than 2 turns counterclockwise.

Excessive turns will disengage needle from syringe.2. Steps 4.4.3 d. and e. should be performed rapidly to minimize exposure.0 d. Rapidly DRAW 1 cc gas sample into syringe and TURN syringe body 2 turns counterclockwise to lock sample in syringe.e. REMOVE syringe from needle guide and PLACE syringe into syringe transfer container and PLACE lid on syringe transfer container.

f. CLOSE 3SSP-V2036, containment air sample module internal bypass valve.4.4.4 CLOSE cabinet door.Is I Level of Use Continuous THINK CP 3804L ACT REVIEW Rev. 002-02 19 of 38 EI II I NOTE If sufficient personnel are available, Sections 4.5 and 4.8 may be performed simultaneously.

4.4.5 WHEN all samples requested in step 2.1.13 have been retrieved, PERFORM the following:

TRANSPORT samples to laboratory and Go To Section 4.5,"Sample Analysis"* Go To Section 4.8, "Restoration from PASS Sample Acquisition"-End of Section 4.4 -I1 Level of Use Continuous-STOP THINK< "ACT REVIEW CP 3804L Rev. 002-02 20 of 38 4 I 4.5 Sample Analysis Health Physics Technician

4.5.1 DETERMINE

handling requirements as follows: Chemistry Technician N a. OPEN transport container cover and MEASURE dose rate.b. IF dose rate is greater than or equal to 1 rem/hr, NOTIFY OSC ARPS and REQUEST instructions for handling.c. IF dose rate is less than 1 rem/hr, DIRECT Chemistry Technicians to handle samples as normal radioactive samples-and to minimize radiation exposure when performing required analyses.4.5.2 PERFORM PASS sample analysis as follows: Refer To the following Sections as applicable and PERFORM analysis:* Section 4.6, "Gas Isotopic Analysis"* Section 4.7, "Gas Composition Analysis" 4.5.3 WHEN analyses are complete, REPORT results to MRDA or AMRDA.4.5.4 Refer To CP 3804L-001 and SIGN and DATE "Performed By" section.4.5.5 IF copies of results are requested, FAX or SEND copies of the following to requesting individuals:

• Attachment 2* CP 3804L-001 4.5.6 IF Section 4.8, "Restoration from PASS Sample Acquisition," has not been completed, Go To Section 4.8 and COMPLETE PASS system restoration.

-End of Section 4.5 -4 Level of Use Continuous STOP>T A>l,]~ACT CP 3804L Rev. 002-02 S 21 of 38 4.6 Gas Isotopic Analysis 4.6.1 PLACE 2.5 cm shelf in detector to be used for gas isotopic analysis.4.6.2 DETERMINE gas isotopic activity as follows: a. Using the following information, Refer To C CP 803.6,"Gamma Spectroscopy Counting System Maintenance and (Operation," and ANALYZE sample: 0 Open cave 0 Applicable geometry for shelf being used a Five minute count time 0 General library 0 Sample volume of 0.250 cc* Sample date and time as recorded on CP 3804L-001 b. IF dead time is greater than or equal to 20%, PERFORM the following:

1) ABORT count.2) REPLACE shelf with next higher shelf.3) Go To step 4.6.2.c. STORE gas vial in shielded location.Level of Use CP 3804L nSTOP THINK ACT REVIEW Rev. 002-02 Continuous.

N d. DETERMINE background as follows: 1) Using the following information, Refer To C CP 803.6,"Gamma Spectroscopy Counting System Maintenance and Operation," and PERFORM background count on detector that was used for gas isotopic analysis.I 4 0* Open cave* Applicable geometry for shelf that was used* Five minute count time* General library" Sample volume of 0.250 cc 2) RECORD all identified isotopes and their associated background activity levels in [tCi/cc on Attachment 2.e. Refer To Attachment 2 and CALCULATE gas activity as follows: 1) Refer To gas isotopic printout and RECORD all identified isotopes and their associated activity levels in[tCi/cc.2) For each isotope listed, SUBTRACT background activity from printout activity and RECORD as isotope activity in[Ci/cc.3) ADD isotope activities and RECORD as gas activity in[tCi/cc.4) Refer To CP 3804L-001 and RECORD gas activity in[tCi/cc in "Sample Data" table: 4.6.3 PLACE empty "GAS ISOTOPIC" syringe in shielded location.-End of Section 4.6 -0 Level of Use Continuous

• INK .ACT CP 3804L STOP 'THINK AC REW Rev. 002-02-- -I23 of 38 1-4.7 Gas Composition Analysis NOTE The "GAS COMP" results are for information only and are not used in any sample calculations.

4.7.1 Refer

To CP 2803/3803P, "Operation and Calibration for Perkin-Elmer Autosystem XL Gas Chromatograph," and ANALYZE 2.0 ml syringe labeled "GAS COMP" for the following:

• % hydrogen* % oxygen* % nitrogen 4.7.2 PLACE empty "GAS COMP" syringe in shielded location.4.7.3 WHEN analysis is complete, Refer To CP 3804L-001 and RECORD gas composition results in % in "Sample Data" table.-End of Section 4.7 -4 I I I Level of Use Continuous STOPI THINK \cC]TI REVIEW CP 3804L " Rev. 002-02 24 of 38 EI EI 4.8 Restoration from PASS Sample Acquisition NOTE Entry into Section 4.8 may occur at any timeduring performance of Sections 4.1 through 4.4. Some steps in Section 4.8 may already be completed depending on the entry point.4.8.1 IF sample flow was achieved at any time during PASS sample, FLUSH PASS system as follows: a. IF Section 4.3, "System Flush," has not been performed, PERFORM Section 4.3.b. At 3SSP-PNL2, containment air sample remote panel, POSITION 3SSP-V2035 to "SAMPLE." c. INITIATE nitrogen purge as follows: 1) POSITION 3SSP-V112 to "NITROGEN FLUSH." 2) POSITION 3SSP-V2037.to "OPEN." I 3) POSITION 3SSP-V2034 to "ON." d. RECORD flow rate: lpm e. WAIT 3 minutes.f. POSITION 3SSP-V2037 to "CLOSE." g. CHECK that flow rate is less than value recorded in step 4.8.1 d.h. WAIT 3 minutes.4.8.2 POSITION the following valves as indicated:

a. 3SSP-V2034 to "OFE" b. 3SSP-V112 to"OFE" c. 3SSP-V2037 to "OPEN." I Level of Use Continuous ST, o(PF I THINK ACT CP 3804L RI EIEW Rev. 002-02 i 25 of 38-I I I 4.8.3 Refer To CP 3804L-002 and VERIFY or INITIAL valve lineup for valves at 3SSP-PNL2.

4.8.4 CLOSE

3SSP-V53, nitrogen supply to containment air sample PNL2.4.8.5 PUSH "POWER ON" button to de-energize panel.4.8.6 CLOSE and LOCK panel door.4.8.7 PERFORM the following:

a. CLOSE 3HVR-DMP1301, 3SSP-SAS2 exhaust damper[Ref. 6.1].b. Using damper operating tool, CLOSE 3HVR*DMP60, 3SSP-SAS1/SAS2 exhaust isolation damper [Ref. 6.1]Level of Use Continuous STOP~THN ACTCP 3804L THIN AGT REVIEW- Rev. 002-02 26 of38 I`N7 CAUTION It is imperative not to push in on the hand wheel when operating the following valves unless SM/US permission is obtained.

This engages the clutch override and could result in damage to the valve.Train A Train B 3HCS*V2 3HCS*V6 3SSP*V59 3HCS*V9 3HCS*V13 3SSP*V60 3HCS*V3 3SSP*V51 3HCS*V10 3SSP*V52 c. IF hydrogen recombiner train A was selected in step 2.1.13, PERFORM the following:

1) CLOSE and LOCK the following valves* 3SSP*V51, containment air sample return cross -connect" 3SSP*V59, containment air sample supply cross -connect 2) IF train A hydrogen recombiner is not running, CLOSE and LOCK the following valves:* 3HCS*V2, recombiner 1A supply outer isolation* 3HCS*V3, recombiner 1A supply inner isolation* 3HCS*V6, recombiner RBNR-1A return isolation F]I I Level of Use Continuous 4 ST1-RP TH INK ACT CP 3804L'REVIEW Rev. 002-02 S 27 of 38 17 CAUTION 1ý7 It is imperative not to push in on the hand wheel when operating the following valves unless SM/US permission is obtained.

This engages the clutch override and could result in damage to the valve.Train A Train B 3HCS*V2 3HCS*V6 3SSP*V59 3HCS*V9 3HCS*V13 3SSP*V60 3HCS*V3 3SSP*V51 3HCS*V10 3SSP*V52 d. IF hydrogen recombiner train B was selected in step 2.1.13, PERFORM the following:

1) CLOSE and LOCK the following valves* 3SSP*V52, containment air sample return cross -connect* 3SSP*V60, containment air sample supply cross-connect

2) IF train B hydrogen recombiner is not running, CLOSE and LOCK the following valves: O I* 3HCS*V9, recombiner 1B supply outer isolation* 3HCS*V10, recombiner 1B supply inner isolation* 3HCS*V13, recombiner RBNR-1B return isolation 4.8.8 Refer To CP 3804L-002 and VERIFY remainder of valve lineup.4.8.9 Refer To CP 3804L-002 and PERFORM independent verification of system lineup.NOTE When this step is completed, constant communications with the control room in Modes 1-4 is no longer required.1 Level of Use Continuous STOP' THINK ~AG'I IREVIEW4 CP 3804L Rev. 002-02 28 of 38

___4.8.10 NOTIFY MCRO of the following:

0 IF closed in step 4.8.7 c.2), the following valves are closed and locked:* 3HCS*V2, recombiner IA supply outer isolation, 0 3HCS*V3, recombiner 1A supply inner isolation* 3HCS*V6, recombiner RBNR- IA return isolation* IF closed in step 4.8.7 d.2), the following valves are closed and locked:* 3HCS*V9, recombiner 1B supply outer isolation* 3HCS*V10, recombiner 1B supply inner isolation 0 3HCS*V13, recombiner RBNR-1B return isolation 0 IF in operating Modes 1-4, NOTIFY MCRO that tracking requirements of Tech Spec surveillance 4.6.1.1.a are no longer required for valves that were reported closed and locked* 3HVR*DMP60 is closed* IF in operating Modes 1-4, REQUEST MCRO exit LCO 3.6.6.2 for 3HVR*DMP60

[Ref. 6.1].* PASS system is secured.* IF in operating Modes 1-4, REQUEST permission to secure constant communications with control room 4.8.11 RETURN valve key.4.8.12 SUBMIT completed CP 3804L-002 to Chemistry Supervision for review.Level of Use

• CP 3804L Continuous STOP THI.NK ACT REVIEW Rev. 002-02 29 of 38 II II I 4.8.13 IF operational difficulties were encountered, PERFORM one or both of the following: " Refer To RP16, "Trouble Reporting," and INITIATE trouble report for applicable equipment and RECORD TR number on CP 3804L-001" Refer To PI-AA-200, "Corrective Action," and INITIATE CR and RECORD CR number on CP 3804L-001 4.8.14 RECORD number of needle punctures for the containment air septum in PASS log.&4 ALARA &4 Step 4.8.15 may not be performed due to the radiation levels in the hydrogen recombiner building.4.8.15 OBTAIN permission from MOSC and PERFORM the following:

• IF containment air septum has been punctured 10 times or more since its last replacement, Refer To Attachment 3 and REPLACE septum 0 Refer To CP 3804K Attachment, "PASS Sample Equipment Inventory," and INVENTORY PASS sampling equipment and LOCK PASS cabinet door handle 4.8.16 SIGN and DATE "Performed By" block on CP 3804L-001.

4.8.17 SUBMIT the following completed documents to Chemistry Supervision.

• CP 3804L-001©* CP 3804K Attachment, "PASS Sample Equipment Inventory" 4.8.18 SUBMIT copy of reviewed CP 3804L-001 and applicable CR's to system engineer.Chemstry7 Superviionj

-. End of Section 4.8 -Level of Use Continuous STOP 'TH~INK ACT REVIEW CP 3804L Rev. 002-02 30 of 38

5. REVIEW AND SIGNOFF 5.1 The review and signoff for this procedure is located in the following attachments and forms:* Attachment 2 a Attachment 3* CP.3804L-001

• CP 3804L-002 6. REFERENCES 6.1 PIR 3-93-021, "SLCRS Boundary Breach" 6.2 Technical Manual for Containment Air Post Accident Sample System," General Dynamics Corporation, Electric Boat Division, Reactor Plant Services 6.3 Installation,Operating, and Maintenance Instructions Model MB-151 Post Accident Air Sample Compressor

6.4 Regulatory

Guide 1.97 6.5 Post Accident Sample System Component Instruction Literature 6.6 INPO Good Practice CT-707, "Post-Accident Sampling Preparedness" 6.7 NUREG 0737 6.8 Millstone DWG. No 12179-EM-155A

6.9 Millstone

DWG. No 12179-EM-115A 6.10 Millstone DWG. No 12179-CP-402001 6.11 Millstone DWG. No 12179-CP-402002 6.12 Millstone DWG. No 12179-CP-402003 6.13 Millstone DWG. No 12179-CP-402004 6.14 Millstone DWG. No 12179-CP-402006 Level of Use ..CP 3804L u Op .. THINK 'ACT REVIEW Rev. 002-02 Continuous 31 of 38 I 6.15 Millstone DWG. No 12179-CP-402009 6.16 Millstone DWG. No 12179-CP-4020014 6.17 Millstone DWG. No 12179-CP-4020015 6.18 Millstone DWG. No 12179-CP-4020053 6.19 Millstone DWG. No 12179-CP-4020054 6.20 Millstone DWG. No 12179-CP-4020056 6.21 Millstone DWG. No 12179-CP-402700 6.22 Correspondence B11121, "Millstone Nuclear Power Station, Unit No. 3, Response to Chemical Engineering Branch DSER Open Item," dated April 9, 1984, from Northeast Utilities to the NRC 6.23 Correspondence B11177, "Millstone Nuclear Power Station, Unit No. 3, Response to Chemical Engineering Branch DSER Open Item," dated May 10, 1984, from Northeast Utilities to the NRC 6.24 NUREG-1031, "Safety Evaluation report related to the operation of Millstone Nuclear Power Station, Unit No. 3," dated August 2, 1984.6.25 DCR M3-98034, "Setpoint Change to 3GSN-PCV106, 3SSP-PCV80, and 3SSP-PCV82" 6.26 DCN DM3-00-0638-98, "Setpoint Change to 3GSN-PCV106, 3SSP-PCV80, and 3SSP-PCV82" I 6.27 Engineering Calculation 3SSP-01632-1-3 6.28 NRC, B18443 Dated July 31, 2001.7.

SUMMARY

OF CHANGES I ISummary of Changes Rev. 002-02 7.1 Added prerequisite for the verification of containment temperature being at or below 170°E 7.2 Removed Note statement on cover page that required document to be reviewed by Nuclear Fuels Safety Analysis.Level of Use Continuous STOP THINK ACT CP 3804L.REVIEW, Rev. 002-02 32 of 38

'7.3 Removed references to Technical Specifications and E-Plan in Objective Section and added regulatory commitment B18443-01.

7.4 Removed

references to SERO and SERO activation throughout the document.7.5 Changed volume of gas vial from 14.4 cc to 13 cc.7.6 Updated Documents Section and references to superseded and cancelled documents throughout.

Summary of Changes Rev. 002-01 7.7 Editorial Correction; Added Reference 6.28 NRC commitment letter.B18443. AR #01005693-01.

Summary of Changes Rev. 002-00 7.8 Added simplified drawing of containment air PASS system.7.9 Added flat-tipped screwdriver and valve wrench to tools and consumables.

7.10 Deleted "(Obtained from MCRO)" from valve key description.

7.11 Changed basis for 45-50 psig on 3SSP-PCV82 to Engineering Calculation 3SSP-01632-I-3.

7.12 Added caution associated with remotely operated valves that have clutches.7.13 Added numerous signoffs to substeps.7.14 Added initial system alignment check and deleted associated steps in body of procedure.

7.15 Deleted step to remove counting shelf when counting background.

7.16 Changed steps to allow hydrogen recombiner isolations to remain open if hydrogen recombiner is running.7.17 Added steps to generate TR and/or CR when operational difficulties are encountered.

7.18 Added bullet to request permission from SM/US prior to securing constant communications.

Level of Use CP 3804L Continuous STOP THINK ACT Rev. 002-02 33 of 38 4 I 7.19 Added requirement to obtain permission from MOSC to changeout septum and inventory PASS equipment.

Added alara above step.7.20 Changed septum changeout frequency to every 10 punctures.

7.21 Added containment air equipment to CP 3804K (Att), "PASS Sample Equipment Inventory," and deleted inventory list from this procedure.

Added requirement to lock PASS cabinet door handle when inventory is completed.

7.22 Added step to submit PASS inventory to Chemistry Supervision.

7.23 Added step to submit copy of reviewed chemistry form CP 3804L-001 and applicable CR's to system engineer.7.24 A note was added to the cover page of this procedure to ensure a review is performed by the Radiological Engineering Services whenever modifications to this procedure are made that may impact dose limit time and motion study calculations.

This is in response to AR 99005798-06.

F1 I I Level of Use Continuous STOP TH.IN. K AG F REWEW--CP 3804L Rev. 002-02 34 of 38 Attachment 1 Initial System Alignment Check (Sheet 1 of 1)El Performed Component ID Description Position Initial Date 3SSP-PNL2 3SSP-V2027 Containment air remote module N2 supply OP isolation valve 3SSP-V2029 Containment air remote module N2 stor- CL age tank isolation valve 3SSP-V2030 Containment air remote module N2 stor- CL age tank vent valve 3SSP-PCV82 Nitrogen pressure regulator Backed Off Outside "A" Recombiner Cubicle Observe caution sign at 3SSP-V46 3SSP-V46 Air sample pump P4 inlet isolation valve OP Post Accident Sample Module Room 3SSP-V2036 Containment air sample module internal CL bypass valve 3SSP-V188 3-way divert valve to iodine filter FLT1 BYP 3SSP-V189 Iodine filter FLT1 outlet isolation valve CL 3SSP-V191 Iodine filter FLT1 inlet isolation valve, CL I 0 Level of Use Continuous STOP HIINK ACT R~EVIEW CP 3804L Rev. 002-02 35 of 38 Attachment 2 Containment Air Gas Activity Worksheet (Sheet 1 of 1)I Printout Activity Background

= Isotope Activity Isotope Printout Activity Background Isotope Activity (2-place accuracy)

(2- place accuracy)NOTE: Gas Activity = summation of all isotope activities.

Gas Activity (2-place accuracy)

([tCi/cc)Prepared by: Date: SUBMIT completed attachment to Chemistry Supervision.

Level of Use Continuous STOiP THINK CP 3804L ACT Rev. 002-02' 36 of 38 Attachment 3 3SSP-SAS2 Septum Replacement (Sheet 1 of 1)I]NOTE The required tools and consumables can be found in the PASS cabinet located in the H 2 recombiner building.________1.

2.3.4.5.6.DON protective clothing as directed by Health Physics.Using 1/2" socket, UNSCREW and REMOVE needle guide.IF old septum did not come out with septum holder, REMOVE old septum using scribe or tweezers.Using tweezers and septum insertion tool, INSTALL new septum.Using 1/2" socket wrench, INSTALL needle guide.RECORD septum replacement in PASS log.1 Replaced by: Date: SUBMIT completed attachment to Chemistry Supervision.

1 Level of Use Continuous I T P'p THINK CP 3804L A\CT RI EIEW Rev. 002-02 37 of 38

).i W Attach lt 4 Containment Air PASS Simplified Drawing (Sheet 1 of 1)W Suction Line of: Train A Hydrogen Recombiner Sample From Containment Suction Line of: Train B Hydrogen Recombiner Return Lines of: Train A Hydrogen Recombiner Return To Containment Return Lines of: -: 'Train B Hydrogen Recombiner Nitrogen Flush Level of Use Continuous

'STOP THINK AC T R E~VI EW CP 3804L Rev. 002-02 38 of 38