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Initiation
- Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request, Request
- Acceptance...
- Supplement, Supplement
Administration
- Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting, Meeting
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MONTHYEARML0506900352005-03-0303 March 2005
Response to NRC Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design Basis Accidents at Pressurized-Water Reactors
Project stage: Request
ML0515100172005-05-31031 May 2005
Draft RAI on Response to Generic Letter 2004-02
Project stage: Draft RAI
ML0515303042005-06-0303 June 2005
6/3/05, Calvert Cliffs - RAI Potential Impact of Debris Blockage on Emergency Sump Recirculation at Pressurized-Water Reactors
Project stage: RAI
ML0520200572005-07-15015 July 2005
Response to NRC Request for Additional Information Re NRC Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design Basis Accidents at Pressurized-Water Reactors
Project stage: Response to RAI
ML0603803582006-02-0909 February 2006
RAI, Response to Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design-Basis Accidents at Pressurized-Water Reactors
Project stage: RAI
ML0609500512006-04-12012 April 2006
Approval of Extension Request for Completion of Corrective Actions in Response to Generic Letter 2004-02
Project stage: Other
ML0618702222006-06-30030 June 2006
Update of Response to Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Basis Accidents at Pressurized Water Reactors
Project stage: Other
ML0626405472006-09-20020 September 2006
Update of Response to Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design Basis Accidents at Pressurized-Water Reactors
Project stage: Other
ML0633407022006-12-18018 December 2006
Unit No.1 - Approval of Extension Request for Completion of Corrective Action in Response to Generic Letter 2004-02
Project stage: Other
ML0712703722007-05-0202 May 2007
Revision to Generic Letter 2004-02 Response
Project stage: Other
ML0734504992007-12-10010 December 2007
Attachment (1) Request for Extension of the Completion Date for Corrective Actions Related to Generic Letter 2004-02
Project stage: Request
ML0734504982007-12-10010 December 2007
Request for Extension for Completion of Activities Related to Generic Letter 2004-02
Project stage: Request
ML0811307392008-04-22022 April 2008
Revision to Generic Letter 2004-02 Response
Project stage: Other
ML0817101052008-06-18018 June 2008
Attachment 1, Request for Extension of the Completion Date for Corrective Actions Related to Generic Letter 2004-02
Project stage: Request
ML0827404892008-09-30030 September 2008
Supplemental Response to Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design Basis Accidents at Pressurized Water Reactors
Project stage: Supplement
ML0827404972008-09-30030 September 2008
Attachment 2, ECCS and CS System Figures
Project stage: Other
ML0833003202008-12-0404 December 2008
Request for Additional Information Supplemental Response to Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design Basis Accidents at Pressurized Water Reactors-Calvert Cliffs Unit 1 & 2
Project stage: RAI
ML0906807672009-03-0404 March 2009
Request for Additional Information: Supplemental Response to Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design Basis Accidents at Pressurized Water Reactors
Project stage: Supplement
ML1009500782010-04-12012 April 2010
Request for Additional Information Generic Letter 2004-02 Calvert Cliffs Nuclear Power Plant, Unit Nos. 1 and 2-
Project stage: RAI
ML1011903842010-05-0606 May 2010
Notice of Forthcoming Conference Call with Calvert Cliffs to Discuss Supplemental Responses to Generic Ltr. 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design Basis Accidents at Pressurized Water Reactors
Project stage: Request
ML1014708982010-06-0707 June 2010
Summary of Meeting with Calvert Cliffs Nuclear Power Plant, LLC, to Discuss Supplement to Responses to Generic Letter 2004-02
Project stage: Meeting
ML1028701002010-09-30030 September 2010
Draft Responses to NRC Request for Additional Information Related to Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Design Basis Accidents on Pressurized-Water..
Project stage: Draft Response to RAI
ML1029306502010-10-20020 October 2010
Notice of Forthcoming Conference Call with Duke Energy Carolinas, LLC Regarding McGuire Nuclear Station, Units 1 and 2 and Catawba Nuclear Station, Units 1 and 2,
Project stage: Other
ML1030810242010-11-10010 November 2010
Summary of November 1, 2010, Meeting with Duke to Discuss Responses to Generic Letter (GL) 2004-02 (Tac Nos. MC4673, MC4674, MC4692, and MC4693)
Project stage: Meeting
ML1031903612010-11-10010 November 2010
Response to Request for Additional Information Regarding Generic Letter 2004-02
Project stage: Response to RAI
ML12356A0852012-12-27027 December 2012
January 8, 2013 - Notice of Teleconference with Calvert Cliffs Nuclear Power Plant, LLC
Project stage: Meeting
ML13038A5432013-01-24024 January 2013
Chemical Effects Head Loss Experiment (Chle) Test Protocol for Calvert Cliffs Nuclear Power Plant (CCNPP-CHLE-002, Revision 0d)
Project stage: Request
ML13038A6042013-01-24024 January 2013
PIRT Item Summary
Project stage: Request
ML13038A4872013-01-24024 January 2013
CCNPP-CHLE-001, Revision 0c, Chemical Effects Head Loss Experiment (Chle) Test Plan for Calvert Cliffs Nuclear Power Plant
Project stage: Request
ML13038A5782013-01-24024 January 2013
Chemical Effects Pirt Considerations for Calvert Cliffs Nuclear Power Plant (CCNPP-CHLE-003, Revision 0b)
Project stage: Request
ML13086A5512013-01-24024 January 2013
MC4672 & MC4673 - CCNPP-CHLE-003, Rev 0c Chemical Effects PIRT Considerations Excerpts with Respect to GL2004-02, GSI-191
Project stage: Other
ML13030A3482013-02-0707 February 2013
Summary of Teleconference with Calvert Cliffs Nuclear Power Plant, Units 1 and 2 to Discuss Proposed Risk-Informed Approach to the Resolution of Generic LTR 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During Des
Project stage: Meeting
ML13045A1822013-02-19019 February 2013
March 20, 2013, Notice of Forthcoming Teleconference with Calvert Cliffs and Nrc/Nrr Staff to Have Additional Discussions of Licenseess Proposed Path for Resolution of Generic Letter 2004-02
Project stage: Meeting
ML13050A5112013-02-19019 February 2013
MC4672-3 Corrected Notice -Public Meeting on March 20, 2013 Re-GL2004-02
Project stage: Request
ML13086A5502013-03-0101 March 2013
MC4672 & MC4673, CCNPP-CHLE-002, Rev 0e Chemical Effects Experimental Protocol with Respect to GL2004-02, GSI-191
Project stage: Request
ML13088A2202013-03-18018 March 2013
MC4672 & MC4673 - CCNPP-CHLE-005, Rev 1 Chemical Effects Autoclave Experimental Plan with Respect to GL2004-02, GSI-1 91
Project stage: Request
ML13086A5492013-03-20020 March 2013
MC4672 & MC4673 - Licensee Presentation-Category 1, Public Meeting on March 20, 2013 with Respect to GL2004-02, GSI-191
Project stage: Meeting
ML13091A0552013-04-10010 April 2013
Summary of Meeting on March 20, 2013, with Calvert Cliffs Nuclear Power Plant, LLC, to Discuss the Proposed Risk-Informed Approach to the Resolution of Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation D
Project stage: Meeting
ML13149A3942013-05-20020 May 2013
Chemical Effects Head Loss Experiment (Chle) Test Protocol for Calvert Cliffs Nuclear Power Plant, CCNPP-CHLE-002, Revision 0 May 20, 2013
Project stage: Request
ML13149A3992013-05-20020 May 2013
Chemical Effects Autoclave Experiment Test Plan for Calvert Cliffs Nuclear Power Plant CCNPP-CHLE-005, Revision 2, May 20, 2013
Project stage: Request
ML13149A4052013-05-23023 May 2013
Metals BENCH-TOP Autoclave Experiment Test Plan for Calvert Cliffs Nuclear Power Plant, CCNPP-CHLE-006, Revision 0, May 23, 2013
Project stage: Request
ML13148A3962013-05-29029 May 2013
Forthcoming Meeting with Calvert Cliffs Nuclear Power Plant, LLC to Discuss Licensees Proposed Plan for Resolution of GL 2004-02
Project stage: Meeting
ML13179A3132013-07-11011 July 2013
June 12, 2013 Summary of Meeting with Constellation Energy Group, Inc., to Continue Discussions on the Proposed Risk-Informed Approach to the Resolution of Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculati
Project stage: Meeting
ML13224A0942013-08-0606 August 2013
Chemical Effects PIRT Considerations for Calvert Cliffs Nuclear Power Plant, CCNPP-CHLE-003, Revision 0c
Project stage: Request
ML13224A1032013-08-0808 August 2013
CCNPP-CHLE-007, Revision 0c, Coatings Bench-Top Autoclave Experiment Test Plan for Calvert Cliffs Nuclear Power Plant
Project stage: Request
ML13226A0902013-08-14014 August 2013
Notice of Forthcoming Meeting with Constellation Energy Nuclear Group, LLC
Project stage: Meeting
ML13304B4032013-11-0101 November 2013
Notice of Forthcoming Meeting with Constellation Energy Nuclear Group, LLC,
Project stage: Meeting
ML13319A9392013-11-13013 November 2013
Ri GSI-191 November 2013 Meeting with NRC Rev 0
Project stage: Request
ML13310B9292013-12-0606 December 2013
Summary of Meeting with Constellation Energy Group, Inc., to Continue Discussions on the Proposed Risk-Informed Approach to the Resolution of Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During .
Project stage: Meeting
ML14014A0392014-01-29029 January 2014
Summary of Meeting with Constellation Energy Group, Inc., to Continue Discussions on the Proposed Risk-Informed Approach to the Resolution of Generic Letter 2004-02, Potential Impact of Debris Blockage on Emergency Recirculation During
Project stage: Meeting
2010-06-07
[Table View] |
Text
CHEMICAL EFFECTS AUTOCLAVE EXPERIMENT TEST PLAN for Calvert Cliffs Nuclear Power Plant CCNPP-CHLE-005, Revision 1 March 18, 2013 Prepared by:
Craig D. Sellers Reviewed by:
Andy Henni and Steve Kinsey
Chemical Effects Autoclave Experiment Test Plan for Calvert Cliffs Nuclear Power Plant CCNPP-CHLE-005 Revision 1, March 18 2013 REVISION HISTORY Log Revision Description 0
Issue for initial experiment Reduce aluminum concentration to 2x best estimate and revise boron & lithium concentrations to actual maximum concentrations.
I i
Chemical Effects Autoclave Experiment Test Plan for Calvert Cliffs Nuclear Power Plant CCNPP-CHLE-005 Revision 1, March 18 2013 Contents 1.0 Introduction.................................................................................................................................................................
1 2.0 Pu rpose.........................................................................................................................................................................
1 3.0 O verall experim ental Plan.....................................................................................................................................
1 4.0 Experim ental Param eters......................................................................................................................................
2 4.1 D ebris Q uantities..................................................................................................................................................
2 4.2 R eactive M aterial..................................................................................................................................................
2 4.3 Chem istry Conditions.........................................................................................................................................
2 4.4 B uffer.........................................................................................................................................................................
2 4.5 T em perature Conditions...................................................................................................................................
2 4.6 A gitation...................................................................................................................................................................
2 5.0 Chem istry A nalysis...................................................................................................................................................
3 List of Tables T able 1: Insulation Sam ple Q uantities.............................................................................................................................
2 T able 2: R eactive M aterial Q uantities.............................................................................................................................
2 T able 3: Chem istry Conditions...........................................................................................................................................
2 ii
Chemical Effects Autoclave Experiment Test Plan for Calvert Cliffs Nuclear Power Plant CCNPP-CHLE-005 Revision 1, March 18 2013
1.0 INTRODUCTION
Calvert Cliffs Nuclear Power Plant (CCNPP) is implementing a risk-informed approach to resolving GSI-191 that includes the performance of a number of chemical effects experiments. These experiments are intended to simulate temperature, pressure, fluid, and debris conditions in containment after a loss of coolant accident (LOCA).
Temperature conditions inside containment during the initial portion of a large break LOCA peak at approximately 280'F. Simulating these temperature conditions in a chemical effects test requires the use of a pressurized test facility. The objective of this autoclave test is to investigate whether the time the containment temperature is over 190°F has a significant effect on the corrosion of materials in the fluid, the production of precipitants, and the potential for precipitation. The results of this test will influence the decision on whether the CCNPP Chemical Effects Head Loss Experiment (CHLE) facility needs to be pressurized (which supports test temperature greater than 190'F) or whether it can be an atmospheric pressure facility (which allows test temperature less than or equal to 190'F).
2.0 PURPOSE The purpose of this document is to describe the autoclave experiment planned for the CCNPP CHLE program. This plan presents the sequence for performing the experiment and the conditions for each experiment.
3.0 OVERALL EXPERIMENTAL PLAN The overall concept for the experiment is four 12-hour corrosion experiments, one maintained at 280'F and the other maintained at 190'F, with fluid simulating the post-LOCA fluid solution in containment and corrodible materials expected in containment in the fluid. The identification and concentration of corrosion products and characterization of any precipitates will be compared to determine if there is a significant difference in corrosion in 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br /> at the two temperatures.
Materials used in the test will be representative of the materials submerged in the containment pool or exposed to containment spray and expected to dissolve and contribute to chemical effects in the initial 12 hours1.388889e-4 days <br />0.00333 hours <br />1.984127e-5 weeks <br />4.566e-6 months <br /> of the LOCA. These include destroyed insulation, concrete, latent debris and other miscellaneous materials in containment. The material quantities will be scaled to approximate the ratio of the test fluid volume to the volume of debris materials immersed in the pool fluid or the surface area of solid materials exposed to pool at CCNPP.
Page 1 of 3
Chemical Effects Autoclave Experiment Test Plan for Calvert Cliffs Nuclear Power Plant CCNPP-CHLE-005 Revision 1, March 18 2013 The fluid chemistry will be similar to the initial post-LOCA pool chemistry expected at CCNPP. A scaled quantity of NaTB buffer will be allowed to dissolve in the test chamber to simulate the dissolution of buffer in the plant.
4.0 EXPERIMENTAL PARAMETERS 4.1 Debris Quantities Table 1: Insulation Sample Quantities Insulations Debris Test Quantity Transco Thermal Wrap or NUKON (LDFG) 0.91 gram/Liter (g/L)
Mineral Wool 0.34 g/L Calcium Silicate 0.001 g/L 4.2 Reactive Material Table 2: Reactive Material Quantities Material Description Test Quantity Metallic Aluminum 0.02 in2/L Galvanized Steel 7.5 in2/L Copper 0.1 in2/L Exposed Concrete 0.1 in2/L 4.3 Chemistry Conditions Table 3: Chemistry Conditions Purified Water with Boron Concentration (H3B0 3) 2600 ppm Lithium Hydroxide 0.80 ppm Initial pH
-4.5 4.4 Buffer Include 3.5 grams per liter sodium tetraborate decahydrate (NaTB) buffer.
4.5 Temperature Conditions One experiment will be maintained at 280°F +/-5°F and the other maintained at 190OF +/-50 F.
4.6 Agitation The autoclave shall be agitated continuously throughout the experiment to facilitate fluid flow across the contained materials.
Page 2 of 3
Chemical Effects Autoclave Experiment Test Plan for Calvert Cliffs Nuclear Power Plant CCNPP-CHLE-005 Revision 1, March 18 2013 5.0 REPEATABILITY The experiment will be repeated to investigate repeatability of results.
6.0 CHEMISTRY ANALYSIS Mass spectrometry of the fluid used in the experiment shall be performed:
- 1.
On the purified water prior to addition of the boric acid and lithium hydroxide, and
- 2.
On the fluid solution after each 12-hour experiment.
The relative concentrations between the 280'F and the 190'F experiment of the following elemental species shall be reported:
- 1. Alumina
- 2. Boron
- 3. Calcium
- 4. Iron S. Magnesia
- 6. Phosphorus
- 7. Silica
- 8. Sulfur
- 9. Zinc Page 3 of 3
