ML20150B362

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Effluent & Waste Disposal Semiannual Rept 1987
ML20150B362
Person / Time
Site: Zion  File:ZionSolutions icon.png
Issue date: 12/31/1987
From: Pliml G
COMMONWEALTH EDISON CO.
To: Davis A
NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION III)
References
NUDOCS 8803160345
Download: ML20150B362 (29)
v • d • e


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QCcmmonwealth Zion Generating Station Edison 101 Shiloh Blvd.

PRIORITY P0J'TI M Eint_ im.n1 C 1

\;V ' Zion, Illinois 60099  ? -

N Telephone 3121746 2084 U[

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% ,m :t IUR ?CZ February 9, 1988 g Mr. Bert Davis Acting Regional Administrator Directorate of Inspection and Enforcement, Region III U. S. Nuclear Regulatory Commission 799 Roosevelt Road i Glen Ellyn, IL 60137

Subject:

Zion Nuclear Power Station Operating Report, NRC Dockets 50-295 and 50-304 Enclosed is the radioactive effluent report for July through December, 1987 for Zion Nuclear Power Station. ,

one copy of this report is provided for your use. Two copies will be forwarded to Document Control and the NRC Resident Inspector will receive a report as outlined in the November '86 Federal Register. ,

Sincerely yours,

/  ;

i ft '

G.J. Pliml i Station manager Zion Station i

GJP/jlc i

s Enclosure r

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i 8803160345 871231 l'

PDR ADOCK 05000295 '

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gE 't'8 y;s t o WA ,i l

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPOR1 1987 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES Gaseous Effluents Released - Summary Sheet Thi rd Units July August September Quarter

1. Gross Radioactivity Releases
a. Total Release Ci 2.5 EO 9.6 E-2 5.7 EO 8.3 E0
b. Max. Release Rate pCi/Hr. 1.5 E+5 1.2 E+4 9.4 E+3 1.5 E+5
c.  % of Quarterly Limit '

% 0.00 (SmRy/10mR 6)1 -- -- --

0.02

2. lodine Releases
a. Tota l I-131,1-133 Ci 4.9 E-7 2.1 E-5 2.6 E-5 4.7 E-5
3. Particulate Releases
a. Gross Radioactivity Ci 9.6 E-4 6.3 E-4 9.4 E-4 2.5 E-3
b. Gross Alpha Radioactivity Ci 5.5 E-4 2.3 E-4 3.0 E-4 1.1 E-3
c. Gross Particulate with 1.4 E-4 Half Lives > 8 Days Ci 5.6 E-5 1.7 E-4 3.7 E-4
4. Sum of I-131,1-133 & Particulate With Half Lives Greater Than 8 Days
a. Total Ci 1.4 E-4 1.7 E-5 2.0 E-4 4.2 E-4
b.  % of Quarterly Limit (7.5 mR Organ)  % -- -- --

0.37

5. Tritium Releases
a. Total Release Ci 6.2 E0 2.0 E+1 3.9 EO 3.0 E+1 1- Noble Gas Gamma / Beta

<LLO - No detectable activity above background i

s

/

0651R 2

/

11 1

, ,3 ZION STATION

, . . , EFFLUENT AND WASTE DISPOSAL. SEMIANNUAL REPORT 1987

, GASE0US EFFLUENTS - ELEVATED RELEASE Gaseous Effluents Released - Isotopes plff ['d5 Units July August September fer

1. Gross Radioactivity Releases A r-41 Ci 8.9 E-2 4.4 E-3 4.4 E-2 1.4 E-1

, Kr-85 7.1 E-1 <LLO 1.7 E-2 7.3 E-1 Kr-85M 2.7 E-3 <LLO <LLO 2.7 E-3

__Ky-87 Ci 7.2 E-4 <LLO <LLO 7.2 E-4 ar-88 3.4 E-3 <LLO <LLO 3.4 E-3 Xe-131 Ci <LLO <LLO <LLO . <LLO Xe-131 M 6.1 E-3 <LLO <LLO 6.1 E-3 Xe-133 1.6 EO 8.8 E-2 4.7 EO 6:4 EO Xe-133M 1.8 E-2 <LLO <LLO 1.8 E-2 i Xe-135 Ci 7.6 E-2 3.2 E-3 9.7 E-1 1.0 EO Xe-13 5M 5.5 E-3 <LLO <LLO 5.5 E-3 Xe-138 <LLO <LLO <LLO <LLO 4

Ci Ci 3

<LLO - No detectable activity above background i

1 i

0651R 3

ZION ST TION

. EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987

, GASE0US EFFLUENTS - ELEVATED RELEASE Gaseous Effluents Released - Isotopes (continued) pff((l Units July August September T 0 er

2. Iodine Releases Na-24 Ci <lLO <LLO <LLO <lLO Mn-54 <LLO <LL1 <LLO <LLO Co-58 Ci <LLO <LLO <LLD <LLD Co-60 2.6 E-8 4.5 E-9 8.4 E-7 6.7 E-7 Co-57 <LLO <LLO <LLO < L L D __

Se-75 Ci 4.9 E-9 8.5 E-8 <LLO 9.0 E-8 Br-82 1.5 E-6 2.2 E-6 1.8 E-6 5.5 E-6 Rb-88 <LLO <LLO <LLO <LLO Ci Ru-105 <LLO <LLO <LLO <LLD Aq-110M <LLO <LLO <LLO <LLO Sn -113 5.9 E-10 <tLD <LLO 5.9 E-10 1-131 Ci 3.9 E-7 1.2 E-5 9.0 E-6 2.1 E-5 I-132 2.8 E-8 7.3 E-8 2.1 E-8 1.2 E-7 I-133 9.7 E-8 9.0 E-6 1.7 E-5 2.6 E-5 l-134 <LLD <LLO <LLO <LLO

, C s -134 3.6 E-10 <LLO <LLD 3.6 E-10 I-135 Ci 3.1 E-7 4.7 E 'i 3.1 E-7 1.1 E-6 Ce-144 <LLO <LLO <LLO <LLO Cs-136 <LLD <LLO <LLO <LLO C s -137 2.5 E-8 <LLO 2.5 E-7 2.8 E-7 C s -138 <LLO <LLO 4.9 E-5 4.9 E-5

<LLO - No detectable activity above background 0651 R 4 1

, ,, ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REP 3RT 1987 GASEOUS F.FFLUENTS - ELEVATED RELEASE Gaseous Ef fluents Released - Isotopes (continued) pfffaPl Units July August September Ou tr

3. Particulate Releases Na-24 Ci <LLO 2.7 E-7 2.4 E-7 5.1 E-7 Mn-54 <lLO <LLO <LLD <lLD Mn-56 <LLO <LLO <([h_ <LLO Co-58 Ci 7.4 E-9 1.5 E-9 <LLO 8.9 E-9 Co-60 __

9.0 E-5 4.2 E-8 2.2 E-7 9.0 E-5 Ci Br-82 <LLO <LLO <LLD <lLO Rb-88 Ci 4.5 E-5 5.5 E-5 4.7 E-5 1.5 E-4 Sr-89' -- -- -- --

Sr-90' -- -- -- --

Sr-91 Ci <LLO <LLO <LLO <LLO Sr-92 <LLO <LLO <LLO <LLO Nb-95 <LLO <LLO <LLO <LLO Ci i

Mo-99 <LLO <LLO <LLO <LLO Tc-99M <LLO <LLO <LLO <LLO

<LLD - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 0651R 5

ZION S1ATION

. EFFLUENT AND WASTE DISPOSAL SEW [ ANNUAL REPORT 1981 GASE0US EFFLUINTS - ELEVATED RELEASE Gaseous Effluents Released - Isotopes (continued)

Units July August September r f*0fUP'8,d er

3. Particulate Releases (continued)

Ru-103 Ci <LLO <LLO <LLD <LLO AQ-110M <tLO <LLO (LLO <LLO 5b-122 Ci <LLO 2.8 E-8 <LLO 2.8 E-8 5b-124 2.1 E-9 <LLO <LLO 2.1 E-9 l-131 <LLO <LLD <LLO <LLO l-132 <tLD <LLO <LLO <LLO Te-132 <LLO <LLO <lLD <LLO I-133 Ci 4.3 E-9 3.7 E-9 <LLO 8.0 E-9 Cs-134 6.4 E-8 2.2 E-8 1.1 E-8 9.7 E-8 I-134 <LLO <LLO <LLO <LLO I-135 <LLD <tLD <LLO <LLO C s -136 Ci <LLO <LLO <LLO <LLO

Cs-137 6.5 E-8 6.0 E-8 3.3 E-8 1.6 E-7 l Cs-138 3.6 E-7 1.3 E-6 1.2 E-4 1.2 E-4 l

Ba-139 <LLO <LLO <LLO <LLO i

8a-140 Ci <LLO <LLO <tLD <LLO l La-140 <LLO <LLO <LLO <LLO W-187 Ci <tLD <LLD (LLO <LLO Bi-214 (LLO <LLO <LLO <LLO -

Pb-214 (LLO <LLD <LLD <LLO

<LLO - No detectable activity above background 0651R 6 l

, ,, ZION STAT 10N EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 1 Liquid Ef fluents Released - Summary Sheet Third Units July August September Quarter

1. Gross Radioactivity 1
a. Total Release C1 1.1 E-1 3.0 E-2 5.1 E -3 1.5 E-1
b. Avg. Concentration pCi/mi Released 1.6 E-9 8.8 E-9 7. 5 E-10 3.7 E-9
c. Max. Concentration pCi/ml -

Released 5.0 E- 8 2.6 E-8 5.4 E-9 5.0 E-8

d.  % of Tech. Spec. Qtr.

Limit (1.5mR/5mR)2 0.03

e.  % of Tech. Spec. Yearly  %

Limit (3mR/10mR)2 -- --

0.03

2. Tritium
a. Total Release Ci 3.0 E +1 9.4 E-1 7.4 EO 3.8 E+1
b. Avg. Concentration Released uti/mi 4.4 E-7 2.8 E-7 1.1 E-6 6.1 E-7
3. Dissolved Noble Cases
a. Total Release Ci 4.4 E-4 6.4 E-4 1.6 E-2 1.7 E-2
b. Avg. Concentration pCi/mi Released , 2. 3 E-10 1.3 E-10 9.4 E-11 1. 5 E-10 i 4. Gross Alpha Radioactivity l
a. Total Release Ci 2.7 E-5 1.4 E-6 1.3 E-6 3.0 E-5
b. Avg. Concentration pCi/ml Released 4.0 E-13 4.1 E-13 1.9 E-13 3.3 E-13 l

S. Volume of Liquid Waste l

to Discharge Liters 1.4 E+7 7.5 E+5 1.5 E+5 1.5 E+7 i

l

6. Volume of Dilution Water Liters 1. 2 E +11 1.0 E +11 1.1 E+11 3.3 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole body / organ

<LLD - No detectable activity above background 0651R 7

,. ,, IION STAfl0N EFFLUEN) AND WA$TE UISPOSAL 5EM1ANNUnL REPORT 1987

, LIQUID EFFLUENTS s . UNIT I Liquid Effluents Released - Isotopes Units July August September p SOf0P']

3, Qua ter Na-24 Ci <LLO <LLO <LLO <lLO w

C r-51 Ci 1.3 E-4 <LLO <LLO 1.3 E-4 Mn-54 3.9 E-4 5.8 E-5 2.3 E-5 4.7 E-4 Co-57 <LLO <LLO <LLO <LLO Co-58 1.0 E-2 1.2 E-3 1.8 E-4 1.1 E-2 Fe-59 4.1 E-5 <LLO <LLD 4.1 E-5 Co-60 Ci 1.6 E-2 1.2 E-3 2.3 E-3 2.0 E-2 Kr-85 Ci (LLO <LLO <LLO <LLO Kr-88 (LLO <LLO (LLD <lLD Rb-88 (LLO (LLO <LLO (LLO

$r-89' -- -- -- --

i Sr-90* -- -- -- --

Sr-92 (LLO <LLO <LLO <LLO l

l l

Nb-95 Ci 3.1 E-4 1.7 E-4 <LLO 4.8 E-4 Zr-95 2.4 E-4 7.2 E-5 (LLD 3.1 E-4 Tc -99M <LLO <LLO <LLD (LLO

<LLO - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 1

0651R 8

Z[0N 51AI!ON EFFLUENT AND WA$TE DISPO5AL 5EMIANNUaL R PORT 1987 LIQUID EFFLUENTS UNIT I Liquid Effluents Released - Isotopes (continued) 5 fS0f0[e'd Units July August September

,p Ci Ru-105 <LLO <LLO <LLO <LLO Sn-113 <tLO <LLD <LLO <LLO AQ-110M 6.8 E-3 2.1 E-4 5.2 E-4 7.5 E-3 Sb-122 Ci <LLO <LLO <LLO <tLO Sb-124 9.7 E-4 8.0 E-5 <LLO 1.1 E-3 Sb-125 8.6 E-3 8.0 E-4 5.8 E-4 1.0 E-2 I-131 Ci (LLO <LLO <LLO <LLO I-133 <tLD <LLD (LLO <LLO Xe-133 1.6 E-2 4.4 E-4 6.4 E-4 1.7 E-2 Xe-133M Ci <LLD <LLO <LLO <tLO Cs-134 9.8 E-3 1.2 E-2 6.0 E-4 2.2 E-2 I-134 <LLO <LLO <LLO <tLO X e -13 5 1.5 E-4 <tLD <LLD 1.5 E-4 C s -136 Ci I (LLO (LLO <LLD <LLO Cs-137 5.5 E-2 1.4 E-2 9.4 E-4 7.0 E-2 C s -138 <LLO <LLO <LLO <LLD La-140 Ci 7.3 E-5 <LLO <LLO 7.3 E-S W-187 (LLO <LLO (LLO <LLO

<LLO - No detectable activity above background 0651R 9

ZION STATION

, . EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987

. LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 2

. Liquid Ef fluents Released - Sumary Sheet Third Units July August September Quarter

1. Gross Radioactivity 1
a. Total Release Ci 2.9 E-2 1.4 E-1 4.7 E-2 2.2 E-1
b. ncentration
Ci/mi 4.5 E-9 1.5 E-9 5.5 E-10 2.2 E-9
c. ncentration Ci/ml 3.2 E-8 4.5 E-8 6.5 E-9 4.5 E-8
d.  % of Tech. Spec. Otr. g __ __ __

0.13 Limit (1.5mR/5mR)2 / 0.05

e.  % of Tech. Spec Yearly  % __ __ __

0.08 Limit (3mR/10mR)* 0.03

2. Tritium
a. Total Release Ci 1.0 E+1 4.5 E+1 1.0 E+2 1.6 E+2
b. ncentration Ci/mi 1.6 E-6 4.8 E-7 1.2 E-6 1.1 E-6
3. Dissolved Noble Gases
a. Total Release Ci 7.0 E-3 2.1 E-2 5.4 E-2 8.2 E-2
b. ncentration pCi/mi 1.1 E-9 2.2 E-10 6.4 E-10 6.5 E-10
4. Gross Alpha Radioactivity
a. Total Release Ci 2.8 E-6 1.9 E-5 5.7 E-5 7.9 E-5
b. ncentration j pCi/ml 4.4 E-13 2.0 E-13 6.7 E-13 4.4 E-13
5. Volume of Liquid Waste Liters 3.8 E+5 1.5 E+7 1.5 E+7 J.0 E+7 to Discharge
6. Volume of Oilution Water Liters 1.8 E+10 1.2 E+11 1.3 E+11 2.7 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole Body / Organ

<LLO - No detectable activity above background 0651R 10

., ,, ZION STATION EFFLUENT AND WA5TE DISPOSAL SEMIANNUAL REPORT 1987

, LIQU10 EFFLUENTS

. UNIT 2 Liquid Effluents Released - Isotopes P

f*fae'5 Units July August September

,7 Na-24 Ci <LLO 7.9 E-5 <LLO 7.9 E-5 Ar-41 <LLD <LLO <LLO <LLO l

Cr-51 Ci <lLO <LLO <LLO <LLO Mn-54 1.7 E-4 1.8 E-4 4.8 E-5 4.0 E-4 Co-57 <LLO 1.3 E-5 <LLO 1.3 E-5 Co-58 3.8 E-3 7.4 E-3 3.7 E-3 1.5 E-2 ~

Fe-59 <LLO <LLO <LLO <LLO

, Co-60 Ci 4.8 E-3 1.6 E-2 1.9 E-2 4.0 E-2 Kr-85 Ci <LLD <LLO <LLO <LLO Kr-88 <LLO <LLO <LLO <lLD Sr-891 -- -- -- --

Sr-901 C1 -- -- -- --

Sr-92 <LLO <LLO <LLO <LLO Nb-95 C1 3.7 E-4 5.3 E-4 1.3 E-4 1.0 E-3 Zr-95 5.7 E-5 6.9 E-5 <LLO 1.3 E-4 Mo-99 <LLO <LLD 3.2 E-5 3.2 E-5 Tc-99M <LLD 3.2 E-5 1.0 E-5 4.2 E-5

<LLO - No detectable activity above backgt-ound 1 - Data will be presented in an errata to the Semi-Annual Report 0651R 11

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPOR1 1987 l .- LIQU10 EFFLUENTS UNIT 2 Liquid Effluents Released - Isotopes (continued) p 50), Pes Units July August September Ci Ru-105 <LLO <LLO <LLD <LLD Sn-113 <LLO <LLO <LLO <LLO Aa-110M 1.3 E-3 4.3 E-3 4.0 E-3 9.6 E-1

.I Sb-122 Ci <LLO <LLO <LLO <LL9 '

Sb-124 1.4 E-4 7 . 2 E -4 1.8 E-4 1.0 E-3 Sb-125 1.5 E-3 1.1 E-2 5.8 E-3 1.8 E-2 _

Xe-131 M <tLD <lLD <LLO <LLO I-131 Ci <LLO 4.8 E-5 <LLO 4.8 E-5 I-133 <LLO 3.1 E-4 1.6 E-5 3.3 E-4 Xe-133 6.8 E-3 2.1 E-2 4.8 E-2 7.6 E-2 Xe-133M Ci <LLO <LLO 2.8 E-4 2.8 E-4 Cs-134 7.1 E-3 4.6 E-2 5.8 E-3 5.9 E-2 I-134 <LLO <LLO <LLO <LLO I-135 <LLO 7.3 E-5 <LLO 7.3 E-5 Xe-135 2.0 E-4 2.1 E-4 6.0 E-3 6.4 E-3 Cs-136 Ci <LLO <tLD 3.5 E-4 3.5 E-4 C s -137 9.2 E-3 5.8 E-2 8.2 E-3 7.5 E-2

__C s -13 8 <lLO <LLO <LLD <lLD La -140 C1 1. 0 E-4 9.1 E-6 3.0 E-5 1.4 E-4 i W-187 <LLD <LLO <LLO <LLO

<LLO - No detectable activity above background J

i j

Do31R 12

ZION SIATION

  • EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - SUMMATION OF ALL RELEASES A. Gaseous Ef fluents Released - Summary Sheet Fourth Units October November December Quarter
1. Gross Radioactivity Releases
a. Total Release Ci 3.4 E0 2.5 E0 2.4 E+1 3.0 E+1
b. Max. Release Rate pCi/Hr. 2.0 E+4 2. 7 E +4 3.0 E+5 3.0 E+5
c.  % of Quarterly Limit (SmRy/10mR 8)1 0.02 0.07
2. todine Releases
a. Tota l 1-131,1-133 Ci 4.2 E-5 4.6 E-6 1.2 E-5 5.9 E-5
3. Particulate Releases
a. Gross Radioactivity C1 4.9 E-4 7.1 E-4 7.3 E-4 1.9 E-4
b. Gross Alpha Radioactivity Ci 2.4 E-4 2.3 E-4 3.0 E-5 5.0 E-4
c. Gross Farticulate with Half Lives > 8 Days Ci 2.7 E-d 7.1 E-4 7.3 E-4 1.7 E-3
4. Sum of I-131,1-133 & Particulate With Half Lives Greater Than 8 Days
a. Total Ci 3.1 E-4 7.1 E-4 7.4 E-4 1.8 E-3

~

b.  % of Quarterly Limit"~

(7.5 mR Organ)  % -- -- --

0*13

5. Tritium Releases
a. Total Release Ci 6.8 E0 1.0 E+1 2.5 E+1 4.2 E+1 1- Noble Gas Gamma / Beta

<LLO - No detectable activity above background -

13 0660R 0798A

-- - ~ - - ^

, , ZION STATION

  • EFFLUENT AND WASTE 0!SPGSAL SEMIANNUAL FEPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE B. Gaseous Ef fluents Released - Isotopes fsotops Units October November December hUurt ur p
1. Gross Radioactivity Releases A r-41 Ci 5.0 E-2 4.3 E-3 1.2 E-2 6.6 E-2 K r -85 9.2 E-3 1.8 E-2 1.4 E-1 1.7 E-1 Kr-85M <LLO <LLD <LLO <LLO Kr-87 Ci <lLD <LLD  ! <LLO <LLO Kr-88 <LLO <LLO <LLO <LLO Xe-131 Ci <LLD <lLD <LLO <LLO Xe-131 M <LLO <LLO 1.4 E-2 1.4 E-2 Xe -133 2.5 E0 2.2 E0 2.4 E+1 2.9 E+1 Xe-133M <LLO <LLO 4.6 E-3 4.6 E-3 Xe-135 Ci 8.4 E-1 2.4 E-1 4.7 E-3 1.1 EO

__Xe-135M <LLO <LLO <LLO <LLO Xe-138 <LLO <LLO <LLO <LLO Ci 1

Ci

<LLO - No detectable activity above background 14 0660R 0798A l

ZION STATION l -

EFFLUENT AND WASTE O!SPOSAL SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE

8. Gaseous Effluents Released Isotopes (continued)

, fsoop'8 Units October November December ou th e , 9

2. lodine Releases Na-24 Ci <lLD 8.8 E-9 <lLO 8.8 E-9 Co-58 Ci 6.8 E-9 <LLO <LLD 6.8 E-9 Co-60 4.8 E-9 9.5 E-9 <lLO 1.4 E-8 Ci Br-82 2.0 E-6 2.3 E-6 2.6 E-6 6.9 E-6 Rb-88 <LLO <LLO <LLD <LLO Ci I

I-131 Ci 9.3 E-6 2.2 E-6 8.6 E-6 2.0 E-5 I-132 8.5 E-7 <LLO <LLO 8.5 E-7 I-133 3.3 E-5 2.4 E-6 3.5 E-6 3.9 E-5 I-134 <LLO <LLO 1.4 E-6 1.4 E-6 Cs-134 2.2 E-7 <LLO 1.5 E-10 2.2 E-7 I-135 Ci 3.4 E-6 6.7 E-7 9.0 E-7 5.0 E-6 C s -136 <LLD <LLO <LLO <LLO _

C s -13 7 2.8 E-6 <LLO 6.0 E-9 2.8 E-6 Cs-138 <LLO 2.9 E-5 <LLO 2.9 E-5

<LLO - No detectable activity above background 15 0660R 0798A

, , ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE Gaseous Ef fluents Released - Isotopes (continued) fsotopes Units October November ou t e, December , ,

3. Particulate Releases Na-24 C1 1.2 E-6 3.9 E-7 2.8 E-7 1.9 E-6 _

Cr-51 5.5 E-8 <LLD <LLD 5.5 E-8 Mn-54 2.1 E-8 <LLO <LLD 2.1 E-8 Co-58 Ci 2.9 E-7 <LLD <LLO 2.9 E-7 Co-60 2.8 E-7 4.3 E-9 3.9 E-9 2.9 E-7 Ci Br-82 7.5 E-9 <LLO <lLO 7.5 E-9 Rb-88 Ci 4.1 E-5 2.6 E-4 6.1 E-4 9.1 E-4 Rb-89 <LLO <LLO <LLO <LLO Sr-89) -- -- -- --

Sr-90' -- -- -- --

ll Sr-91 Ci <lLO <LLD <LLO <LLO Sr-92 <lLD <LLO <LLO <LLO Nb-95 <LLO <LLO <LLO <LLD Zr-95 C1 1.3 E-8 <LLD <tLO 1.3 E-8 i

Mo-99 <lLO 7. 3 E-10 <LLO 7.3 E-10

, Tc-99M <LLD <LLD <LLD <LLD

<LLO - No detectable activity above background l 1 - Data will be presented in an errata to the Semi-Annual Report l

16 0660R j 0798A

ZIONSTAT[0N EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987

, GASE0US EFFLUENTS - ELEVATED RELEASE B. Gaseous Ef fluents Released - !sotopes (continued)

F fsotopes Units October November December t 0

3. Particulate Releases (continued)

Ru-103 Ci <LLO <LLO <LLO <LLO An-110M <LLD <LLO <LLO <LLO Sb-122 Ci <LLO <LLO <LLO <LLO I-131 6.8 E-9 1.4 E-8 1.4 E-8 3.5 E-8 I-132 6.1 E-7 <LLO <LLO 6.1 E-7 Te-132 <LLO <LLO <tLD <LLO I-133 Ci 4.4 E-8 1.2 E-8 3.2 E-8 8.8 E-8 C s -134 1.3 E-7 1.3 E-8 2.3 E-10 1.4 E-7 I-134 1.5 E-7 <LLO <LLO 1.5 E-7 I-135 <LLO <LLO <LLD <LLD Cs-136 Ci <LLD <LLO <LLO  !

<LLO C s -137 1.6 E-6 2.5 E-9 1.4 E-8 1.6 E-6 Cs-138 2.3 E-4 4.5 E-4 1.2 E-4 8.0 E-4 Ba-139 <LLO <LLO <LLO <LLO Ba -140 Ci <LLO <LLO <LLO <LLO La-140 <LLO <LLD <LLO <LLO W-187 Ci 1.5 E-7 <LLO <LLD 1.5 E-7 81-214 <LLO <lLD <LLO <LLO Pb-214 <LLO <LLO <LLO <LLO

<LLO - No detectable activity above background 17 0660R 0798A

., , ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987

, LIQUIO EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 1 C. Liquid Effluents Released - Summary Sheet Fourth Units October November December Quarter

1. Gross Radioactivity 1
a. Total Release Ci 1.5 E-2 8.0 E-3 <LLO 2.3 E-2
b. C centration Ci/ml 6.3 E-10 1.7 E-10 0 2.7 E-10
c. Max. Concentration Released pCi/ml 1.2 E-8 4.5 E-9 <LLO 1.2 E d.  % of Tech. Spec. Otr.

% 0.01 Limit (1.5mR/5mR)2 -- -- --

0.00

e.  % of Tech. Spec. Yearly  %
  • Limit (3mR/10mR)2 -- -- --

0.03l

2. Tritium
a. Total Release Ci 2.2 E+1 2.9 E+1 3.9 E-2 5.1 E+1
b. Avg. Concentration pCi/ml 9.2 E-7 6.1 E-7 5.7 E-9 5.1 E-7 Released
3. Dissolved Noble Gases
a. Total Release Ci 1.0 E-2 8.9 E-2 <LLO 9.9 E-2
b. Avg. Concentration Released UCi/ml 4.2 E-10 1.9 E-9 0 7.7 E-10
4. Gross Alpha Radioactivity
a. Total Release Ci 3.1 E-5 6.3 E-6 <LLO 3.7 E-5
b. Avg. Concentration Released uti/ml 1.3 E-2 .3 E-13 0 4.8 E-13
5. Volume of Liquid Waste 3 to Discharge Liters 5.6 E+5 1.5 E+6 5.8 E+5 2.6 E+6
6. Volume of Dilution Water Liters 9.5 e 'l 1.1 E+11 1.1 E+11 3.2 E+11 1 - Exc ludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole body / organ l <LLO - No detectable activity above background 18 0660R 0798A

, , ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS

. UNIT 1 Liquid Ef fluents Released - Isotopes Units October ou f80f,0P'8

, November December Na-24 Ci <lLD <LLO <LLO <LLO A r-41 <LLO <LLO <LLO <LLO Cr-51 Ci <LLO <LLO <LLO <LLO Mn-54 1.4 E-4 6.1 E-6 <LLD 1,5 E-4 Co-57 1.8 E-5 <LLO <LLO 1.8 E-5 Co-58 1.0 E-3 3.5 E-4 <LLO 1.4 E-3 Fe-59 <LLO <LLO <LLO <LLO Co-60 Ci 8.0 E-3 2.6 E-3 <LLO 1.1 E-2 Kr-85 Ci <LLO <LLO <LLO <LLO Kr-88 <LLO <LLO <LLD <LLO Rb-88, <LLO <LLO <lLD <LLD Sr-89' -- -- -- --

Sr-90 C1 -- -- -- --

Sr-92 <LLO <LLO <LLO <lLO Nb-95 Ci 1.3 E-4 <LLO <tLD 1. 3 E-4 Zr-95 1.1 E-4, <LLO <LLO 1.1 E-4 Mo-99 <LLD <LLO <LLO <LLO 1

i <LLO - No detectable activity Jbove background 1 - Data will be presented in e ata to Semi-Annual Report 1

0660R 0798A y---+ -----++9 b--

--rw e 'fB"r "M-

)

,, ZION STATION

- *' EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS UNIT 1

0. Liquid Effluents Released - Isotopes (continued) fsotopej e, , Units October November December hou, p Ru-103 Ci <LLO <LLO <LLO <LLD Ru-105 <lLD <LLO <LLO <LLO Sn-113 <LLO <LLD <LLO <LLO Sn-117M <lLD <LLO <LLO <LLO Aa-110M 3.0 E-3 3.8 E-4 <LLD 3.4 E-3 Sb-122 Ci <LLO <LLO <LLO <LLO Sb-124 <lLO 1.1 E-5 <LLO 1.1 E-5 Sb-125 4.2 E-4 1.8 E-3 <LLO 2.2 E-3 I-131 Ci <LLO <LLO <LLO <LLO I-132 fLLO <LLO <lLD <tLD I-133 <LLD <tLD <LLO <LLO Xe-133 8.1 E-3 3.6 E-2 <LLO 4.4 E-2 Xe-133M Ci <LLO 4.9 E-4 <LLO 4.9 E-4 Cs-134 7.7 E-4 1.0 E-3 <LLO 1.8 E-3 I-134 <LLO <LLO <LLO <LLO Xe-13 5 2.3 E-3 2.7 E-3 <LLO 5.0 E-3 Cs-136 Ci <LLO <LLO <LLO <LLO C s -137 9.9 E-4 1.9 E-3 <LLO 2.9 E-3 Cs-138 <LLO <LLO <LLO <LLO La-140 Ci 7.4 E-6 <LLO <LLO 7.4 E-6 W-187 <LLO <LLO <LLO <LLO

<LLO - No detectable activity above background 20 0660R 0798A

2 ON STATION

' ' EFFLUENT AND WASTE O!SPOSAL SEMIANNUAL REPORT 1987 LIQU10 EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 2 C. Liquid Ef fluents Released - Summary Sheet Fourth Units October November December Quarter

1. Gross Radioactivity 2 i
a. Total Release Ci 4.9 E-2 3.0 E-2 4.5 E-2 1.2 E-1
b. Av Co centration pCi/ml 5.7 E-10 7.2 E-10 4.9 E-10 5.9 E-10
c. Max. Concentration Released pCi/mi 7.9 E-9 1.4 E-8 1.2 E-8 1.4 E-8
d.  % of Tech. Spec. Qtr. g _, __ , , _

0.03 Limit (1.5mR/5mR)2 0.01

e.  % of Tech. Spec. Yearly  % -- -- --

0.10 Limit (3mR/10mR)2 0.04

2. Tritium
a. Total Release Ci 7.7 E+1 1.9 E +1 8.6 E+1 1.8 E+2
b. Avg. Concentration Released uCi/mi 9.1 E-7 4.6 E-7 9.4 E-7 7.7 E-7
3. Dissolved Noble Gases
a. Total Release C1 3.7 E-2 1.7 E-2 1.2 E-1 1.7 E-1
b. Avg. Concentration Released uti/mi 4.4 E-10 4.1 E-10 1.3 E-9 7.2 E-10
4. Gross Alpha Radioactivity
a. Total Release Ci 3.3 E-4 2.9 E-5 9.0 E-5 4. 5 E -4
b. Avg. Concentration pCi/mi 3.9 E-12 7.0 E-13 9.8 E-13 1. 9 E -12 Released
5. Volume of Liquid Waste l to Discharge liters 1.1 E +7 1.0 E+7 1.9 E+7 4.0 E+7 i

l 6. Volume of Dilution Water Liters 1.3 E+11 1.1 E&1l 1.1 E+11 3.5 E +11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole Body / Organ

<LLO - No detectable activity above background 21 0660R 0798A

ZION STATION EFFLUENT AND WASTE 0!SPOSAL SEMIANNUAL REPORT 1987

- . LIQUID EFFLUENTS

, UNIT 2

0. Liquid Effluents Released - Isotepes fSOf0[l5 Units October November December h,urr r Na-24 Ci <LLD <LLO <LLD <LLD C r-51 Ci 4.1 E-4 <LLO <LLO 4.1 E-4 Mn-54 2.2 E-4 2.8 E-5 <LLD 2.5 E-4 Co-57 <LLO <LLD <lLD <LLO Co-58 2.9 E-3 1.4 E-3 1.9 E-3 6.2 E-3 Fe-59 <LLO <LLO <LLO <LLO Co-60 Ci 2.6 E-2 1.2 E-2 1.7 E-2 5.5 E-2 Kr-85 Ci <LLO <LLO <LLO <LLO Kr-88 <LLO <LLO <LLO <LLO Sr-892 - - - --

Sr-902 Ci -- -- -- --

i Sr-92 <lLO <lLO <LLD <LLO i

l l

l Nb-95 Ci 7.2 E-4 <LLO <LLO 7.2 E-4 Zr-95 1.9 E-4 <LLD 2.5 E-5 2.2 E-4__

i

<LLO - No detectable activity above background i

2 - Waiting for analysis results - Data will be presented in an errata to the Semi-Annual Report 22 0660R 0798A 1

  • ZION STATION EFFLUENT AND WASTE OlSPOSAL SEMIANNUAL REPORT 1987 ,

LIQUID EFFLUENTS UNIT 2

. O. Liquid Effluents Released - Isotopes f30f0P's Units October November December hour

,p p i

Ci Ru-105 <LLO <LLO <LLO <LLO Aa-110M 8.9 E-3 6.2 E-4 1.2 E-3 1.1 E-2 l

$b-122 Ci <LLO <LLO <LLO <LLD Sb-124 1.6 E-5 1.1 E-4 5.9 E-5 1.9 E-4 l Sb-125 2.5 E-3 6.9 E-3 7.1 E-3 1.7 E-2 1-131 Ci 1.4 E-5 1.5 E-5 6.3 E-4 6.6 E-4 f I-133 <LLO <LLO <LLO <LLO Xe-133 3.5 E-2 1.6 E-2 1.2 E-1 1.7 E-1 X e -133M Ci <LLD 1.3 E-4 7.1 E-4 8.4 E-4 Cs-134 2.4 E-3 2.9 E-3 5.3 E-3 1.1 E-2 I-134 <LLO <LLO <LLO <LLO '

~~

Xe -13 5 1.7 E-3 4.7 E-4 1.7 E-3 3.9 E-3

' Cs-136 Ci 5.5 E-5 <lLD <LLO 5.5 E-5 Cs -137 3.8 E-3 6.3 E-3 1.2 E-2 2.2 E-2 Cs-138 <LLO <LLO <LLO <tLD Ba-140 < L L O__ _ (LLO <LLO <LLO 1

I La -140 Ci 3.5 E-5 8.9 E-6 1.3 E-5 5.7 E-5

.a W-187 <LLO <tLD <LLO <LLO 4

<LLO - No detectable activity above background 4

23 l

0660R

.! 0798A

ZION GENERAllNL A110N UNIl 1/2

, Month July Year 1987 .' -

1 SOLID RADIDACTIVE WAS1E (lech Spec 6.6.1.D.3)

Date Destination Waste Principal Container Solidification Volume Activity

  • LSA/

I of Material Ma. 2ria l Radionuclides

  • NON LSA Type Agent (ft*) (millicuries)

} (If Applicablel

06 ~

" ~

JUL Beatty, NV Waste Oil LSA 2x 14-195 Cement / Lime / 350 1.984 (c)

Co-60(M) 1 87 Cs-134(M) Ni-63(E) Liners Emulsifier 09 ~ II ~

(

Barnwell, SC Spent Resins LSA H-06 NA 194.1 JUL -60(M) Fe-55(E) 690.46 (c) 87 (Dewatered) Cs-134(M) Ni-63(E) Liner 16 ~ I ~

I" Barnwell, SC Spent Resins LSA H-09 NA 194.1 JUL ~

("I *~ I} 4155.93 (c) .

87 (Dewatered) Cs-134(M) Ni-63(E) Liner

  1. " 688.1 JUL
  • N 3 s17M 55 a 67 A 487.50(c) 1 87 Co-60(M) Co-58(M) 83aal. x 16 4

MON 1H 10lAL 1426.3 5335.87_(c),

Specify whether measured (M), estimated (L), or a combination (C).

0611R

ZION GENERAlltG .A110N UNii 1/2 o Month August Year 1987 *

Date Destination Waste Principal Container SoI M cadon Volume Ac t Wy

  • t3gf of Material Material Radionuclides
  • NON LSA Type Agent (ft') (millicuries)

(If Applicable) 27 uper- Co-58(M) Cs4 37(M) Drums Richland, WA g3g NA 555.7 AUG compacted Co-60(M) Fe-55(E) 55 gal. x 71 551.099 (c) 87 DAW Cs-134(M) Ni-63(E) 839al. x 2 27 Super- Co-58(M) Cs-137(M) Drums Richland, WA g3g NA 574.1 AUG compacted Co-60(M) fe-55(E) 5',ga l . x 75 598.787 (c) 87 DAW Cs-134(M) Ni-63(E) 83qal. x 1 arwell, K #

AUG Spent Resins _

g ,

GA gjy_ NA m .1 36M E (c) 87 ( ewa ered)

Cs-134(M) Ni-63(El MONIH 101AL 1323.9 4841.04_(c) 5pecif y whether measured (M), estimated (E), or a corr.bination (C).

06/1R

__ _ _ _ ._. _ = __ . __ _ _

ZION GENERAllNt eA110N UNii I/2 -

Month September Year 1987 _

~

S01.10 RAD 10ACIIVE WASTE i .

{ (l':h Spec 6.6.1.D.3)

] ~

Date

    • "# " #5 * "C Ed' LSA/

C ntainer Solidification Volume Activity

  • j of Material Material Radionuclides
  • Agent NON LSA Iype (ft*) (millicuries)
(If Applicable)

_02 U' } ' "

8arnwell, SC Spent Resins LSA NA 194.1 SEP O- OM N-3 '01 -H C 3777.72 (c)

) 87 (DewatereO Cs-134(M) Fe-55(El 10

{ Richland, WA "E'#~ ~

I"} I} ""

SEP compacted LSA NA $81.6 947.350 (c)

Co-60(M) f e-55(E) 55 gal. x 76 j 87 DAW Cs-134(M) Ni-631Q. 839al. x 1 4

10 "E ("}

  • Richland, WA ( }

LSA NA 600.0 SEP compacted Co-60(M) Fe-55(E) 55 gal. x 80 647.507 (c) 87 DAW Cs-134(M) Ni-63Q)

" Richland, WA Super- Co-s8(M) Cs-ia7(M) ""5 SEP compacted tSA NA 600.0 747.834 (c)

Co-60(M) Fe-55(E) 55 gal. x 80 1 87 DAW Cs -134(M) Ni-63(E) 4 17 "E" - ~

Richland, WA LSA NA 547.5 SEP compacted Co-60(M) Fe-55(E) 55 gal. x 73 537.978 (c) 87 DAW Cs-134(M) Ni-61(E) 24 Super- Co-58(M) Cs-137(M) D mms Richland, WA L33 NA 516.3 SEP compacted DAW Co-60(M) Fe-55(E) 55 gal. x 41 371.612 (c) 87 e WWIF Sludge Cs-134(M) Ni-63(E) 83 gal. x 18 24 upe - Co-58(M) Cs-137(M) Dmms Richland, WA L3g SEP compacted DAW Co-60(M) Fe-55(E) 55 gal. x 33 NA 595.5 472.265 (c) 87 + WWIF Sludge Cs-134(M) Ni-63(E) 83qal. x 3_0, ,

30 ' "

SEP Barnwell, SC E*" - ( }

Storage lank Co-60(M) Cs-131(E)

"I LSA h Steel Liner NA 125.2 280,909.12(c) 87 Mixed 8ed Ni-63(E) _

MONIH 101AL 3760.2 288.204.12(c)

Spec if y whether measured (M), estimated (L), or a combination (C).

06/lR

-. -- . . . .--- - - . . . _ - . - - . . . - . = . __ __

ZION GENERAllCt. sA110N UNil 1/2 ,

Month October Year 1987 -

SOLID RAD 10AC11VE WASIL (lech Spec 6.6.1.0.3)

Date Destination Waste Principal Container Solidification Volume t3gj Activity

  • of Material Material Radionuclides
  • Type Agent NON LSA (ft') (millicuries)

(If Applicable) 06 Dewat ued Barnwell, SC Co48(M) Fe-W) NON 0C1 Filters & Co-60(M) Ni-63(E) HIC NA 73.4 112,460.5 (c) 87 DAW L33 Cs-137(M)

I3 Beatty, NV Waste Oil 0CT 87 6

Cs-137(M)

-6 LSA fier Cement 206.1 0.596 (c) 001 -

tr

} "*

87 Cs-13)(M) 0C1 ' ""

  • E'" "S "5 6 M Ni-63(E) ie A 64.17 (c) 87 (Dewatered)

Cs-134(M) Fe-55(E) i MONIH TOTAL 667.7 _116,7bl.83 (c)

Specify whether measured (M), estimated (L), or a combination (C).

Ob11R '

. . _ l

s ZION GLDERAllNL .AllDN UNIl 1/2 l r s Month November Year 1987 . h

{ SOLID RAD 10AC11VL WASIL (tech Spec 6.6.1.D.3) j Date Destination Waste l Principal L3gf Containen- Solidification Volume Activity

  • j of Material Material Radionuclides
  • NON LSA Iype Agent (ft*) (mil 11 curies)

(If Applicable) l 04 ~ ~

Richland, WA LSA NA 613.3 NOV DAW Co-60(M) Fe-55(E) 55 gal. x 23 325.046 (c) i 87 Cs-134(M) Ni-63(E) 83qal. x 38 _ , _ _

I3 Spent Resins Co-60(M) Fe-55(E) # H-21 8arnwell, SC t33 NA 194.1 NOV (Dewatered) Cs-134(M) Ni-63(C) Liner 2387.59 (c) 87 Cs-137(M)

, 18 Vert. Pipe Co-60(M) C-14(E) # S-14 Barnwell, SC (33 Cement 125.2 4 NOV Chase Co-137(M) f e-55(E) Liner 2112.55 (c) j 87 Sludge NS-63(E1..

4 23 DAW Co-58(M) Cs-137(M) Drums:

CNSI E33 NA 1036.35

! NOV

""# U"' (to be Co-60(M) Fe-55(E) 52 gal x147 1230.63 (c) j 87 _supercomp'd) Cs-134(M) Ni-63(E) j i

i MONIH 10TAL 1968.95 6055.82 (c]_

1 Specif y whether measured (M), estimated (E), or a combination (C).

Ob f l R

ZION GENERAllK .A110N UNil 1/2 ,

Month December Year 1987 .' t SOLID RA010AC11VE WAS1T (lech Spec 6.6.1.D.3)

Date e nad n as e ncipal Container Solidification Volume Activity

  • t3Af of Material Material Radionuclides
  • NON LSA Type Agent (ft') (millicuries)

(If Applicable) 01 g,3g DE Co-58(M) Cs-137(M) Drums L3g NA 810.75 DEC Channahon II. (to be. Co-60(M) Fe-55(E) 52 gal x 115 754 51 (c) 87 supu m 'd) Cs-134(M) Ni-63(E)

  • ""' '" 'SA NA 194.1 DEC C ) i ) er 1688.64 (c) 87 at Cs-137(M) l l MONTH 101AL 1004.85 2443.15 fcl_

Specify whether measured (M), estimated (E), or a combination (C).

I i

ObilR ,

- - _. _-. _-. ____

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