ML20246E558

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Effluent & Waste Disposal Semiannual Rept,Jan-June 1989
ML20246E558
Person / Time
Site: Zion  File:ZionSolutions icon.png
Issue date: 06/30/1989
From: Joyce T
COMMONWEALTH EDISON CO.
To:
NRC OFFICE OF INFORMATION RESOURCES MANAGEMENT (IRM), Office of Nuclear Reactor Regulation
References
NUDOCS 8908290193
Download: ML20246E558 (31)
v • d • e


Text

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*1  : Commonw:: lth E'::on Zion G;nzting Stetlon

,, 101 Shiloh Blvd.

l4 Zion, Illinois 60099 Telephone 312/746-2084 August 21,1989 Director of Nuclear Reactor Regulation U. S. Nuclear Regulatory Commission

. Document Control Desk Mail Station P1-137 l Washington, DC 20555 1

Subject:

Zion Station Operating Report NRC Dockets 50-295 and 50-304 To Whom It May Concern:

1 Enclosed is the Radioactive Effluent Report for January through June,1989 for Zion Nuclear Station.

' A copy of this report will t>e furnished to the NRC Resident Inspector.

Sincerel j, . -

T. P. Joyce Station Manager Zion Station

-TPJ/BT/rmd ,

Enclosure cc: Distribution List N

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8908290193 890630 l DR ADOCK0500g5 RD/7

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"Mr. Bert Daviss f;L " , LActing Regional Administrator, B l <'A Directorate of. Inspection. and Enforcement.'

Region I11: 4

U.S. Nuclear Regulatory Commission.

t799 Roosevelt Road-1 Glen Ellyn.:IL ;60137 4 .IllinoisDehartmentofNuclearSafety Office' of. Nuclear Facility Safety-1035 Outer Park Drive Springfield, IL 62704 ANI

'The' Exchange, Suite 245 y 270 Farmington. Avenue F, farmington, CT 06032-

.B.P.I.

109 North Dearborn St.

Suite 1001 Chicago, IL '60602 i

American Electric Power Service Corp.

L Nuclear Operations Division t1 Riverside Plaza Columbus .OH 43216 o

thS. Environmental Protection Agency 230 S.:Dearborn Street-

. Chicago IL 60606

Illinois Environmental Protection Agency Region III_-'DHPC/F05

.5415_ North University p Peoria IL 61614 Illinois Environmental Protection Agency Division of Hater. Pollution Control Field Operation Manager 2200 Churchill: Road Springfield,'IL- 62706

' Illinois Power Company Clinton Power Station Plant Radiation Protection R.R. #3, Box 228 Clinton,.IL 61727 14270 g:-

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4l/ Murray &.Trettel,.Inc.

9:? l Environmental Meteorologist' '

1414 Hest Frontage Road L. " > ' Northfield,JIL 60093 p , n.

Teledyne'. Isotopes Midwest Laboratory '

' General' Manager p- .700 Landwehr= Road

'Northbrook IL' 60062 n.

City. of North Chicago, Hater Department e Argonne Drive & Lewis Avenue F . North Chicago,.IL 60064-

. City Hall . .

Department of Hater-

- Kenoshai HI 53140 i City of Haukegan-Hater: Department, Director 106. North Utica

'Haukegan, IL '60085 i

Radiochemistry. Services Group-Supervisor of Chemistry and L

LRadwaste Services

-Room 306 Tech. Center Emergency Planning Supervisor of Emergency Planning z Room 1248 Edison Bldg.

NRC Resident Inspector Zion Station

.P.H.R.: Operations Zion Station Project Engineer 35 FNH' Chemistry Department Zion Station-

-14270-

l ZION STATION

~'

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS '-- SUMMATION OF ALL RELEASES

' A. Gaseous Effluents Released - Sumnary Sheet First Uni ts January February March Quarter

1. Gross Radioactivity Releases
a. Total Release Ci 9.0 E+1 5.9 E+2 1.2 E+1 6.9 E+2
b. Max. Release Rate pCi/Hr. 9.7 E+5 2.2 E+7 2.8 E+5 2.2 E+7
c.  % of Quarterly Limit  % 0.42 (5mRy/10mR B)2 .-- -- --

1.45

2. Iodine Releases
a. Total I-131, I-133 Ci 7.4 E-5 6.2 E-4 3.5 E-4 1.0 E-3
3. Particulate Releases
a. Gross Radioactivity Ci 6.0 E-4 1.7 E-4 2.0 E-4 9.7 E-4
b. Gross Alpha Radioactivity Ci -- -- --

<LLD

c. Gross Particulate with Ci 6.0 E-4 1.2 E-4 5.6 E-5 7.8 E-4 Half Lives > B Days
4. Sum of I-131 I-133 & Particulate Hith Half Lives Greater lhan_8 Days
a. Total Ci 6.7 E-4 7.4 E-4 4.1 E-4 1.8 E-3
b.  % of Quarterly Limit  % -- -- --

3.96 (7.5 mR Organ)

5. Tritium Releases
a. Total Release Ci 2.5 E0 2.1 E+1 1.2 E+1 3.6 E+1 1- Noble Gas Gamma / Beta 2- Data will be presented in an errata to the Semi-Annual Report (LLD - No detectable activity above background 0711R 2

. . ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989

. GASEOUS EFFLUENTS - ELEVATED RELEASE A. Gaseous Effluents Released - Isotopes Iso op 8 Units January February March e 0 ar er

1. Gross Radioactivity Releases Ar-41 _Ci 7.0 E-3 5.8 E-3 1.5 E-2 2.8 E-2 Kr-85 3.1 E-1 (LLD 6.2 E-1 9.3 E-1 Kr-85M 4.0 E-3 (LLD (LLD 4.0 E-3 Kr-87 Ci <LLD <LLD <LLD <LLD Kr-88 (LLD <LLD (LLD (LLD Xe-131 Ci (LLD < t LD ___1LLD (LLD

__le-13]M 8.8 E-3 <LLD 3 . 5_I_2__ 4.4 E-Z__

Xe-133 8.7 E+1 5.8 E+2 9.2 EO 6.8 E+2 Xe-133M 1.0 E-1 1.7 E0 2.2_E-4 .t.8 EO Xe-135 Ci .2.8 EO 5.9 E0 2.1 E0 1.1 E+1

__Ke-135M <LLD <LLD <LLD <LLD

__Xg-138 <LLD (LLD <LLD <lLD Ci _

Ci (LLD - No detectable activity above background 0711R 3

U :.i ./ ZION STATION- ,

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989

. GASEOUSLEFFLUENTS - ELEVATED RELEASE D. Gaseous Effluents Released - Isotopes (continued) j

]; Units January February March -

ter l

'2. Iodine Releases Na-24 Ci 1.9 E-8 1.8 E-7 1.2 E-7 3.2 E-7 l

l

-1 Mn-54 (LLD <tLD <LLD <lLD Co-58 Ci- <LLD 1.9 E-7 9.6_E-8 2.9 E-7  !

Co 2.1 E-9 (LLD 3.7 E-9 5.8 E-9 i Co-57 <LLD <LLD (LLD (LLD _

I Ci j 1

'N.' Br-82 1.3 E-6 4.9 E-7 1.5 E-6 3.3 E-6 j I

Rb-88~ (LLD (LLD <LLD (LLD C.i -  !

Ru-105 (LLD <LLD <LLD (LLD -)

Aa-110M <LLD <LLD - ( ,' LD (LLD j l

I-D1 Ci 3.7 E-5 5.0 E-4 1.9 E-4 7.3 E-4 I-132 3.0 E-6 9.6 E-6 1.4 E-6 1.4 E-5 I-133 3.7 E-5 1.2 E-4 1.6 E-4 3.2 E-4 l

_I-134 2.5 E-5 7.8 E-6 1.2 E-5 4.5 E-5  ;

Cs-134 2.7 E-8 5.5 E-7 7.3 E-9 5.8 E-7 I-135 _.

Ci 7.4 E-6 1.9 E-6 1.9 E-4 2.0 E-4 Cs-136 <LLD <LLD <LLD <LLD Cs-137 1.0 E-7 1.9 E-8 1.1 E-8 1.3 E-7 Cs-138 <LLD <LLD <LLD (LLD

<LLD - No detectable activity above background  ;

l 0711R 4

- _ _ _ _ _ _ _ _ - _ _ _ _ i

.- . ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989

, GASEOUS EFFLUENTS - ELEVATED RELEASE B. Gaseous Effluents Released - Isotopes (continued)

Units January February March f3f09es, 0a er

3. Particulate Releases Na-24 Ci 4.9 E-7 1.4 E-5 2.4 E-6 1.7 E-5 Mq-54 <LLD 4.4 E-9 7.0 E-9 1.1 E-8 Mn-56 <LLD <LLD <LLD (LLD Co-58 Ci 4.5 E-8 7.7 f-7 1.Z_E-7 9.9 E-7 Co-60 8.0 E-8 1.2 E-7 3.4 E-8 9.5 E-7 Ci Br-B2 <LLD <LLD <LLD <LLD Rb-88 Ci 5.7 E-4 1.1 E-4 5.0 E-5 7.3 E-4 Sr-89 -- -- -- (LLD

__SI-90 -- -- --

(LLD Sr-91 Ci <lLD <LLD <LLD (LLD Sr-92 <LLD (LLD <LLD <LLD Nb-95 <lLD <LLD 6.3 E-9 6.3 E-9

__Zr-95 Ci (LLD (LLD 4.0 E-9 4.0 E-9 Mo-93 2.2 E-8 1mB E-8 1.8 E-9 4.2 E-8

__Tc-99M <LLD <LLD (LLD <LLD (LLD - No detectable actirrty above background 1 - Data will be presented in an errata to the Semi-Annual Report 0711R 5

. -. ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989-

. GASEOUS EFFLUENTS - ELEVATED RELEASE B. Gaseous Effluents Released - Isotopes (continued)

'l g Units January February March ar er

3. Particulate Releases (continued)

Ru-103 Ci <LLD <LLD <LLD (LLD ... . _

~Ag-110M . . .. . . < L LD (LLD 6.1 E-8 6.1 E-8

_Sh .J 22 Ci <tLD <LLD <LLD (LLD

_1-131 5.2 E-7 5.1 E-6 4.3 E-8 5.7 E-6

_l-132 9.1 E-7 3.6 E-7 4.8 E-8 1.3 E-6 Te-132 <LLD <LLD <LLD <LLD I-133 Ci 8.4 E-7 8.7 E-6 1.4 E-7 9.7 E-6

_._Cs-134 2.8 E-7 9.9 E-7 2.1 E-7 1.5 E-6_._

W 34 _.L2 E-7 3 61-8 <LLD _ _2_,2._E- 7 I-135.. 1.0 E-6 3.4 E-5 11 1 E-7 3.5 E-5

_Ci-136 C1 1.8 E-8 2,.5_E-8 2.1_E-9 4.5 E-8

_C5-137 3.9 E-7 l d..E-6 2.5 E-7 _2,3_E 5_

Cs-138 2.8 E-5 4.4 E-6 5.2 E-6 3.8 E-5

_Ba-139 <LLD 1.4 E-7 <LLD ~ l 1.4 E-7

_BA-140 Ci _(LLD 1.0 E-8 <lLD 1. 0l-B_

La-140 <LLD 2.9 L-9 <lLD 2.9 E-9_

H-1B[ Ci <LLD 1.7 E-7 (LLD 1.7 E-7

__Bi-214 <LLD < LLD__ _ (LLD (LLD Pb-214 <LLD (LLD. < LLD <LLD

<LLD - No detectable activity above background 0711R 6

7_

t.

i s . ZION STATION

~

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989

. LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 1 C; Liquid Effluents Released - Summary Sheet l First-Units January February March Quarter

1. Gross Radioactivity:
a. Total Release C1 2.9 E-1 1.1 E-1 3.6 E-1 7.6 E-1
b. Av centration Ci/ml 3.5 E-9 2.1 E-9 4.4 E-9 3.3 E-9
c. Ma centration Ci/ml 3.0 E-8 1.8 E-8 3.4 E-8 3.4 E-8 e
d.  % of Tech. Spec. Qtr.  % -- -- -- 0.06 Limit (1.5mR/5mR):

0.02 0.03

e.  % of Tech. Spec. Yearly  %

Limit (3mR/10mR)2 -- -- --

0.01

2. Tritium
a. Total Release Ci 7.2 E+1 4.6 E+1 2.1 E+1 1.4 E+2
b. Avg. Concentration Ci/ml 8.8 E-7 8.6 E-7 2.6 E-7 6.7 E-7 Released I
3. Dissolved Noble Gases
a. Total Release Ci 6.2 E-2 2.0 E-1 4.0 E-2 3.0 E-1
b. Avg. Concentration Ci/ml 7.6 E-10 3.7 E-9 4.9 E-10 1.7 E-9 Released
4. Gross Alpha Radioactivity
a. Total Release Ci 1.8 E-4 1.6 E-5 2.7 E-5 2.2 E-4
b. Avg. Concentration Ci/ml 2.2 E-12 3.0 E-13 3.3 E-13 9.4 E-13 Released
5. Volume of Liquid Haste Liters 1.7 E+7 3.7 E+6 1.8 E+7 3.9 E+7 to Discharge
6. Volume of Dilution Hater Liters 1.3 E+11 8.1 E+10 1.2 E+11 3.3 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole body / organ

<LLD - No detectable activity above background 0711R 7

_-_______-_-__________a

L e .' . ZION STATION 'l '

.c . ' EFFLUENT:AND HASTE. DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS r

n.,

-UNIT 1 DL Liquid Effluents Released - Isotopes .

\

p 5UfP(( Units- January- February March 0 rt r

'Na-24 Ci 2.8 E-4' 7.8 E 1.7 E-3 2.0 E-3 i

l-

__Cr-51 Ci -5.5 E-3 1. 5 E-Z___ 1.4 E-2 3.5 E-R__

L Mn-54 1.3 E-3 9.9 E-4 1.9 E-4 22 5 E-3

, Co-57 4.2 E-3 9.1 E-5 2.9 E-5 4.3 E-3 Co-58 1.-1 E-1 4.2 E-2 6.D E-2 2m1_E-1 Fe-59 7.7 E-4 2.5 E-3 4.3 E-4 3.7 E-3 Co-60 Ci 7.8 E-2 1.9 E-2 3.3 E-2 1.3 E-1 Kr-85 Ci <LLD <LLD (LLD (LLD Kr-88 <LLD <LLD <LLD <LLD Rb-88 <LLD <LLD <tLD <LLD

__St-89' -- -- -- --

Sr-90 2 -- -- -- --

Sr-92 <LLD (LLD (LLD <LLD Nb-95 Ci 1.6 E-3 3.9 E-3 1.7 E-4 5.7 E-3 Zr-95 1.0 E-3 2.8 E-3 1.6 E-3 5.4 E-3

__MQ-99 <LLD _

<lLD 5.0 E-6 5.0 E-6 Tc-99M <LLD <LLD '

2.5 E-5 2.5 E-5

<LLD No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 0711R 8

'Y2 E ..

- ZION STATION .

N. EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT ~1989 .l 0- , LIQUID EFFLUENTS {

.. UNIT-:11 i

.D.. Liquid Effluents Released -. Isotopes (continued)-

_h j-Units January-

~

-February March r er

'Ci _,

Ru:105- (LLD <lLD <LLD <LLD Sn-113 1.6 E-B 6.2 E-5 <LLD 6.2 E-5 Ac-1LQM 7.7 E-3 1.2_E-2 1.2 E-2 3,2 E-2

! Sb-122 Ci- <LLD (LLD <LLD <LLD L Sb-124- 2.5 E-3 1.7 E-4 6.4 E-2 6.7 E-2 L Sb-125 1.8 E-2 2.6 E-3 1.5 E-1 1.7 E-1

_,JtL.126 <LLD (LLD 6.6 E-4 6.6 E-4 I-13.1 Ci 1.7'E-4 1.4 E-3 1.5 E-2 '1.7 E-2 I-132 1.0 E-3 ' LLD

< 2.6 E-3 3.6 E-3 I-133 <LLD 3.0 E-5 1.7 E-3 1.7 E-3 Xe-133 6.2 E-2 2.0 E-1 3.9 E-2 3.0 E Xe-133M Ci <LLD 1.3 E-4 2.2 E-4 3.5 E-4 Cs-134 2.7 E-2 8.0 E_4 6.8 E-4 2.8 E-2__

I-134 <LLD (LLD <LLD <LLD Xe-135 2.9 E-4 6.7 E-5 3.3 E-4 6.9 E-4 i

Cs-136 Ci <LLD (LLD _

<LLD <LLD Cs-137 2.6 E-2 1.1 E-3 1.1 E-3 2.8 E-2 Cs-138 <LLD <LLD (LLD (LLD La-140 Ci 6.0 E-5 8.6 E-4 <LLD 9.2 E-4

.... H-18 7 <LLD (LLD (LLD <tLD (LLD - No detectable activity above background 1

0711R 9

[, H : ' ZION STATION 1

,x< >

'i, :EFTLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 J

i . LIQUID. EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 2 g C; Liquid' Ef'luents-. Released .- Summary . Sheet

.y 4 First.

Units January February March Quarter

1. Gross Radioactivity-i -- 1
a. Total Release C1 2.1 E-2 1.3 E-1 4.4 E-1 .5.9 E-1
b. Av C centration Ci/ml 1.9 E-9 2.1'E-9 5.0 E-9 3.0 E-9.

c.- C centration pCi/ml 6.7 E-9 2.1 E-8 3.1 E-8 3.1 E-8

~d.  % of Tech.. Spec. Qtr.

.f, __ __ __ 0.05 j /

Limit (1.5mR/5mR)2 / 0.02

e. 1 of Tech. Spec. Yearly  % __ __ __

0.03 Limit (3mR/10mR)2 0.01

2. Tritium
a. ' Total Release Ci 3.7 EO 6.1 E+1 3.1 E+1 9.6 E+1
b. Av entration Ci/mi 3.4 E-7 9.9 E-7 3.5 E-7 5.6 E-7
3. Dissolved Noble Gases
a. Total' Release C1 1.8 E-3 1.4 E-1 3.7 E-2 1.8 E-1
b. Av C centration Ci/ml 1.7 E-10 2.3 E-9 '

4.2 E-10 9.6 E-10

4. Gross Alpha Radioactivity
a. ' Total Release Ci 7.5 E-7 2.4 E-5 5.7 E-6 3.0 E-5
b. Av C centration Ci/ml 6.9 E-14 3.9 E-13 6.4 E-14 1.7 E-13

.5 . ' Volume of Liquid Haste Liters 4.6 ESS 1.7 E+7 3.0 E+6 2.0 E+7 to Discharge

6. Volume of Dilution Water Liters 1.1 E+11 1.0 E+11 1.1 E+11 3.2 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole Body / Organ

<LLD - No detectable activity above background 0711R 10

. i. ZION STATION-

. EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS i

.- UNIT 2 i D. Liquid Effluents Released - Isotopes

$t p soopej Units January February March 0 ari, __

Na-24 Ci (LLD 1.6 E-4 1.6 E-3 1.B_E-3

~

Ar-41 <LLD (LLD <LLD <LLD

_CJ-51 Ci <LLD__ _ 1.0 E-2 1.6 E-2 l d_E-Z__

__Mn:54 1 1,7 ,f. 5.4 E-4 2.6 E-4 9.8 E-4

_Co-5] 5.t k ,5. _ 7. L 1=5_ __. _.L 1 E-4 _lA E-4

__Co:58 8.4 E-3 4.8 E-2 9.3 1-2 '

1.5 E-1 Fe-59 <LLD 1.6 E-3 7.4 E-5 1.7 E-3

__Cp 60 Ci 6.6 E-3 2.2 E-2 5.7 E-2 82 6 E-2 Kr-85 Ci <LLD <LLD <LLD <LLD Kr-88 (LLD (LLQ <LLD <LLD l Sr-89' -- -- -- --

Sr-90* Ci -- -- -- --

Sr-92 <LLD <LLD <LLD <LLD Nb-95 Ci <LLD 1.2_E-3 12 0_f-3. 2.2 E-3_

Zr-95 (LLD 1.1 E-3 7.9 E-4 1.9 E-3

~~

__Mp 99 <LLD 1.8 E-5 6.4 E-4 6.6 E-4

__lt:99M <LLD (LLD 3.3 E-5 31 3 E-5 (LLD - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 0711R 11

p ..J r J ZION STATION

'. EFFLUENT ~AND HASTE DISPOSAL SEMIANNUAL REPORT 1989

,, LIQUID EFFLUENTS.

1 . . . UNIT-2

, D.LLiquidEffluentsReleasea-Isotopes'(continued) rst hPQ January February Unitsf March r 9, J u-103 Ci (LLD <LLD <LLD <LLD'

" ___RU-105 'LLD

< <LLD' _ <LLD (LLQ___

Sn-111- < t LD - ._L3_E-4 __J.J E ._6.,3_E-4 Sn-117M (1LD (LLD <LLD (LLD Ag-110M 1.7 E-3 9.6 E-3 1.5 E-2 2.6 E-2_

L

_Sb-122 Ci (LLD <LLD . . .

<LLD (LLD

,_S.b-124 2.7 E-4 7.3 E-3 6.6 E-2 7.4 E-2

_Sb-125 1.8 E-3 9.8 E-3 1.5 E-1 14. E-1

._Sh-126- ___1LLD 5.6 E-3 5.5 E-4 6.2 E-3 Xe-13.1M <LLD <LLD <LLD <LLD 1-131 Ci (LLD 4.2 E-3 2.0 E-2 2.4 E-2

_J-j]2 - _

<LLD 1.Z_E-4 1.7 E-4 2.9 E;4_._

__l-133' <LLD 6.7 E-5 4.9 E-3 5.0 E.3__.

Xe-133 L,LE 3 1.4 E-1 3.6 E-2 1.8 E-1

-Xe-133M- Ci <LLD 2.1 E-4 (LLD 2.1 E-4_

__Chil4 1.2 E-3 1.9 E-3 3.6 E-3 6.7 E-3 I-134 <LLD <LLD (LLD <QD

_ I- 135 <LLD (LLD (LLD (LLD

__Xe-J35 6.6 E-5 2.8 E-5 7.5 E-4 . fL4 E-4

__..C1-13fi ci <tLD (LLD_ <LLD <LLD

_Ci-137 _ LLE-3 __ _La_E.-3 4.7 E-3 7.7 E-3_

_.Cs-138 (LLD <LLD <LLD (LLD La-140 Ci 1.1 E-5 9.0 E-4 <LLD 9.1 E-4 Pr-L44 < L.LD (LLD <LLD. <LLO H-1117 <LLD <lLD l (LLD <tLD

<LLD - No detectable activity above background 0711R- 12

l 1 . '-

ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPOR1 1989

!. GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES A._ Gaseous Effluents Released - Summary-Sheet i

Second Units April May June Quarter

1. Gross Radioactivity Releases
a. Total Release Ci 7.1 E41 1.6 E+2 4.2 E+1 2.7 E+2
b. Max. Release Rate pCi/Hr. 2.3 E+5 3.0 E+5 3.3 E+4 3.0 E+5
c.  % of Quarterly Limit  % 0.31 (EmRy/10mR 0)1 -- -- --

0.79

2. Iodine Releases
a. Total I-131, I-133 Ci 6.3 E-5 2.4 E-4 9.0 E-5 3.9 E-4
3. Particulate Releases
a. Grcss Radioactivity Ci 2.1 E-4 1.0 E-3 7.8 E-3 9.0 E-3
b. Gross Alphar Ci -- -- -- --
c. Gross Particulate with Ci 4.5 E-5 2.7 E-4 7.8 E-3 8.1 E-3 Half Lives > 8 Days
4. Sum of I-131, I-133 & Particulate With Half Lives Greater Thar, 8 Days
a. Total Ci 1.1 E-4 5.1 E-4 7.9 E-3 8.5 E-3
b.  % of Quarterly Limit  % -- -- --

3.52 (7.5 mR Organ)

5. Tritium Releases
a. Total Release Ci 9.2 E-1 3.5 EO 8.6 E-1 5.3 E0 1- Noble Gas Gamma / Beta 2- Data will be presented in an errata to the Semi-Annual Report

<LLD - No detectable activity above background 13 0685R

'- . ZION STATION i

EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989

.. GASE0US EFFLUENTS - ELEVATED RELEASE I

B. G.iseous Effluents Released - Isotopes Isotopes April Sec nd Units May June Ouarter ]

_ Released 1

1. Gross Radioactivity Releases Ar-41 Ci 5.1 E-2 4.1 EO 3.7 E-3 4.2 E0 Kr-85 <LLD <LLD <ll D <LLD Kr-85M <LLD 3.1 E-1 < lid 3.1 E-1 Kr-E7 Ci <LLD_ 3.6 E-1 <LLD 3.6 E-1 Kr-88 <LLD 6.9 E-1 <LLD 6.9 E-1 Xe-131 Ci <LLD <LLD <LLD (LLD

___Ke-131M <LLQ <LLD <LLD_ <LLD Xe-133. ,

4.2 E+1 J .5 E+2 3.9 E+1 2.3 E+2 Xe-133M (LLD 6.0 E-2 <LLD 6.0 E-2 Xe-1.'i5 Ci 2.9 E+1 4.4 EO 3.3 EO 3.7 E+1 i Xe-135M <LLD 2.0 E0 <LLD 2.0 EO

_. Xe-138 <LLD 1.2 E0 <LLD 1.2 EO Ci Ci 1

<LLD - No detectable activity above background 14 s

0685R

tv

, i .; C .- ZION STATION l....

L'

' 'i EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT: 1989-

~ GASEOUS EFFLUENTS -ELEVATED RELEASE

, B-.4 Gaseous Effluents Released - Isotopes (continuedF Isotopes April' Second Released Units May' June Ouarter

2. Iodine. Releases Na-14~ Ci 3.2 E-8 4.9 E-B 1.8-E-8 9.9 E-8 I

i r

'l

.l Co-58 Ci <LLD 9.8 E-10 (LLD 9.8 E-10 Co-60 <LLD <LLD 2.8 E-9 2.8 E-9 j 1

l Ci 7 Br-82 1.7 E-6 2.2 E-6 3.0 E-6 6.9 E-6 _

Rb-88 (LLD (LLD <LLD (LLD I I

l

'i

'Ci ,

~

i 1

1-131 Ci 2.5 E-5 1.1 E-4 4.0 E-5 1.8 E-4 I-132 2.4 E-6 6.3 E-6 4.0 E-6 1.3 E-5 I-133 3.8 E-5 1.3 E-4 5.0 E-5 2.2 E-4 )

I-134 1.6 E-7 9.9 E-6 3.3 E-5 <4.3 E-5 j Cs-134 1.0-E-8 1.4 E-8 (LLD -2.4 E-8 j i

l 1-135 Ci 7.8 E-6 2.8 E-5 1.4 E-5 5.0 E-5 Cs-136 <LLD _(LLQ <LLD <lLQ Cs-137 9.0 E-9 2.7 E-8 5.3 E-9 4.1 E-8 )

Cs-138 1.6 E-4 1.8 E-7 <LLD 1.6 E-4 j

<LLD - No detectable activity above background 15 ,

I i

i

0685R

_ __ -___.-__.--_-________--.-_.__-._______A

lfoi n ZION STATION

" ' EFFLUENT.AND HASTE DISPOSAL SEMIANNUAL REPORT 1989-

+-

, ., GASEOUS ~ EFFLUENTS 4 ELEVATED RELEASE w? ,

Gaseous; Effluents Released , Isotopes .(continued)

L Isotopes U

April Second-l

Released l -Units May ' June.

Ouarter

-3. Particulate Releases l* Na-24: ' Ci - 5.8 E-7 ~1.0 E-6 7.9 E-7 2.4 E-6 h

__.Ma-54 <LLD <LLD (LLD -(LLD J Mn-56 <LLD <LLD 2.4 E 2.4 E 'Co-58 Ci- 1.2 E-8' 1.9 E-4 8.7 E-9 '1.9 E-4 Co-60 7.0 E-11_ 2.5 E-9 2.6 E -2.9 E Ci i Br-82 <LLD -(LLD (LLD (LLD i

Rh-88 Ci 3.8 E-5 7.3 E-5 7.8 E-3 7.9 E-3 Sr-891 -- -- -- --

Sr-901' -- -- -- --

__S -91 Ci <LLD <LLD <LLD <LLD Sr-92 <LLD <LLD <LLD <LLD Nb-95 <LLD 3.5 E-9 <LLD 3.5 E-9 Ci Mo-99 1.2 E-8 1.5 E-8 3.2 E-8 5.9 E-B Tc-99M <LLD <LLD <LLD <LLD

<LLD - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 16 0685R

_=_1________=___=-_________ _ _ _ _ _ _ _ _ _ _ _ _ _ - - _ _ _ - - _ - - _ _ _ _ _ - - _ _ _ _ - - - - - _ - _ _ _ _ _ _ _ . _ _ _ _ _ _ _ _ _

'- .- ZION STATION EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 GASEOUS EFFLUENTS - ELEVATED RELEASE B. Gaseous Effluents Released - Isotopes (continued)

Isotopes April Sec nd Released Units May June Ouarter

3. Particulate Releases (centinued)

Ru-103 Ci <LLD

. <LLD <LLD <LLD l

Ag-110M (LLD <LLQ <LLD <LLD Sb-122 Ci <LLD <LLD (LLD <LLD I-131 4.1 C-8 9.9 E-8 1.5_L-7 2.9 E-7 1-132 4 19._E-7 3.6 E-7 3.4 E-7 1.2 E-6 Te-132 _-(LLD <tLD <LLD <LLD I-133 Ci 1.8 E-7 3.2 E-7 4.6 E-7 9.6 E-7 Cs-134 4.4 E-7 1.7 E-7 1.4 E-7 7.5 E-7

__J-134 <LLD <llD 9.0 E-8 9.0 E-8 I-135 1.9 E-7 3.9 E-7 5.4 E-7 1.1 E-6

__CE:136 Ci <LLD (LLD <LLD (LLQ Cs-137 3.0 E-7 2.4 E-7 6.2 E-7 1.2 f-6

__Li-138 6.4 E-6 81 1 E-6 1.4 E-5 2.9 E-5

__Ba:139 <LLD <LLD (LLD (LLD Ba-140 Ci (LLD <LLD <LLD <lLD

_La-L40 <LLD . . <LLD 1.2 E-9_ __L 2 E-9 H-187 Ci <LLD 3.1 E-8 7.5 E-9 3.9 E-8 Bi-214 (LLD ____fLLD (LLD <LLD

__Eb-214 <LLD <LLD 3LLD (LLD (LLD - No detectable activity above background 17 0685R

~e

,.. e _ g3 ZION STATION:

EFFLUENT. AND HASTE DISPOSAL SEMIANNUAL- REPORT 1989 '

. LIQUID EFFLUENTS --SUMMATION OF ALL RELEASES

, UNIT 1 C. Liquid- Effluents Released - Summary Sheet-Second Units April 'May - June Quarter 1 '. Gross Radioactivity 1

a. Total Release Ci 3.6 E-2 <LLD <LLD '3.6 E-2 b; Avg. Concentration pC1/ml 1.2 E-9 <LLD <LLD 4.0 E-10 Released
c. Max. Concentration pCi/ml 6.7 E-9 (LLD <LLD' 6.7 E-9 Released
d.  % of Tech. Spec. Otr*  % 0.01 Limit. (1.5mR/5mR)2 __ __ __

'0.00

.03

e.  % of Tech. Spec. Yearly  %

Limit (3mR/10mR): __ __ __

0.01

2. ' Tritium
a. Total Release Ci 2.2 E+1 3.2 E 1.3 E-2 2.2'E+1
b. _ Avg. Concentration pCi/ml 7.1 E-7 -2.3 E-10 6.4 E-10 2.4 E-7 Released
3. Dissolved Noble Gases
a. Tctal Release C1 2.9 E-2 (LLD <LLD 2.9 E-2
b. Avg. Concentration pCi/ml 9.4 E-10 <LLD <LLD-l3.1E-10 Released l
4. Gross Alpha Radioactivity
a. Total Release Ci 8.9 E-7 (LLD (LLD 8.9 E-7
b. Avg. Concentration pCi/mi 2.9 E-14 <LLD <LLD 9.7 E-15 Released
5. Volume of Liquid Haste Liters 1.9 E+6 1.3 E+6 2.1 E+6 5.3 E+6 to Discharge
5. Volume of Dilution Hater Liters 1.2 E+11 1.1 E+11 1.1 E+11 3.4 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Hhole body / organ

<LLD - No detectable activity above background 18 0685R l' _ - _ ._. - . _ - _ - _ _ _ _ _ - _ _ _ - - - _ _ _ _ _ _ _ _ - - _ _ - - _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ - _ _ _ _

. - . ZION STATION

. C FLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS

. UNIT 1

-Liquid Effluents Released - Isotopes-Isotopes Second Units April May June 0 garter Released Na-24 Ci <LLD <LLD (LLD <LLD s

Ar-41 <LLD <LLD <LLD <LLD Cr-51 Ci <LLD <LLD <LLD <LLD Mn-54 <LLD (LLD (LLD <LLD Co-57 <LLD s LD <LLD (LLD Co-58 4.4 E-3 <LLD <LLD 4.4 E-3 Fe-59 <LLD <LLD <LLD <LLD

__CO:10 Ci 2.6 E-3 <LLD <LLD 2.6 E-3 l

Kr-85 Ci <LLD <LLD <LLD <LLD

_lr-88 <LLD <LLD (LLD <tLD Rb-88 <LLD <LLD <LLD <LLD Sr-891 -- -- -- --

l l

l Sr-901 Ci -- -- -- --

Sr-92 ...<LLD <LLD (LLD <LLD 1

l Nb-95 Ci <LLD <LLD <LLD <LLD Zr-95 < LLD <LLD <LLD (LLD Mo-99 2.4 E-a <LLD <LLD 2.4 E-4

<LLD - No detectable activity above background 1 - Data will be presented in errata to Semi-Annual Report 19 0685R l

.; .; ZION-STATION-R. . . EFFLUENT AND HASTE DISPOSAt SEMIANNUAL REPORT 1989 Li' LIQUID EFFLUENTS

-* UNIT 1 l <

D. ' Liquid Effluents' Released - Isotopes (continued)

L Isotopes- Second Released Units April May- June Ouarter Ru-103 Ci <lLD (L1D <LLD <tLD Ru-105 <LLD (LLD <LLD <LLD L

Sn-113 <LLD <LLD (LLD (LLD _

Sn-117M (LLD (LLD <LLD <LLD Ag-110M- 6.5 E-4 <LLD (LLD 6.5 E-4 Sb-122 Ci (LLD (LLD

<LLD <tLD Sb-124 1.8 E-3 <LLD <LLD 1.8 E-3 Sb-125 7.3 E-3 <LLD <LLD 7.3 E-3~

I-131 Ci 7.3 E-3 (LLD (LLD 7.3 E-3 1-132 <LLD <LLD <LLD <LLD

.I-133 4.5 E-3 <LLD (LLD 4.5 E-3 I-135 Xe-133 2.8 E-2 <LLD <LLD 2.8 E-2__

Xe-133M Ci 2.1 E-4 <LLD <LLD 2.1 E-4 Cs-134 3.0 E-3 <LLD <LLD 3.0 E-3 I-134 <LLD <LLD <tLD <LLD I-135 3.0 E-4 <LLD <LLD 3.0 E-4 Xe-135 6.8 E-4 <LLD <LLD 6.8 E-4 Cs-136 Ci <LLD <LLD <LLD <LLD Cs-137 3.9 E-3 <LLD <LLD 3.9 E-3 Cs-138 <LLD <LLD <LLD <LLD La-140 Ci 3.0 E-5 <LLD <tLD 3.0 E-5 H-187 <LLD <LLD <LLD <LLD

<LLD - No detectable activity above background 20 0685R

m * : r. ' ZION STATION.

  • l L. '

, ' EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT'1989- y

  • l

. . . , LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES

'l UNIT 2 C.' Liquid Effluents Released - Summary Sheet Second Units April May June Quarter

1. Gross Radioactivity 1 o .a. Total Release C1 1.4 E-1 2.5 E-1 1.7 E-1 5.6 E-1
b. Av centration Ci/ml 1.9 E-9 2.8 E-9 1.6 E-9 2.1 E-9
c. C centration pCi/ml 1.4 E-8 1.6 E-8 1.1 E-8 1.6 E-8
d.  % of Tech. Spec. Qtr.  % -- --- --

0.09 Limit (1.5mR/5mR):

0.03 0.07.

e.  % of Tech. Spec. Yearly  % -- -- --

Limit (3mR/10nR)2 0.03

2. Tritium
a. Total Release Ci 1.0 E42 1.1 E+2 2.1 E+2 4.2 E+2
b. Avg. Concentration pCi/mi 1.4 E-7 1.2 E-6 2.0 E-6' 1.1 E-6 Released l

l 3. Dissolved Noble Gases

a. Total Release Ci 8.6 E-2 7.2 E-2 3.2 E-1 4.8 E-1
b. Avg. Concentration pCi/ml 1.2 E-9 8.1 E-10 3.1 E-9 1.7 E-9 Released
4. Gross Alphi Radioactivity
a. Total Release Ci 6.5 E-5 1.3 E-4 4.0 E-5 2.4 E-4
b. Avg. Concentration pCi/ml 8.8 E-13 1.5 E-12 3.8 E-13 9.2 E-13 Released
5. - L id Haste Liters 1.4 E+7 1.5 E+7 1.5 E+7 4.4 E+7 charge 1.
6. Volume of Dilution Hater Liters 1.3 E+11 1.3 E+11 1.3 E+11 3.9 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases
l. 2 - Whole Body / Organ I <LLD - No detectable activity above background l

21

.0685R

. + ZION STATION

.- EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS

. UNIT 2 D. Liquid Effluents Released - Isotopes Isotopes April Second Released Units May June Ouarter

__Ha-24 Ci 7.6 E-5 <LLD 6.8 E-5 1.4 E-4 l

l

! Cr-51 Ci 1.3 E 4 2.15 E-2 1.9 E-3 2.8 E-2 l Mn-54 3.5 E-4 2.0 E-3 9.4 E-4 3.3 E-3 Co-57 2.1 E-5 3.5 E-4 2.1 E-4 5.8 E-4 Co-58 2.1 E-2 1.2 E-1 _f.7 E-2 2.1 E-1 Fe-59 <LLD 1.13 E-3 <tLD 1.3 E 3__

Co-60 Ci 3.1 E-2 3.9 E-2 2.2 E-2 9.2 E-2_

l l

Kr-85 Ci l <LLD <LLD (LLD <LLD Kr-88 (LLD <LLD (LLD <LLD Sr-891 -- -- -- --

Sr-9Di ci --

Sr-92 <LLD <LLD <LLD <LLD Nb-95 Ci (LLD 1.1 E-2 1.6 E-3 1.3 E-2 Zr-95 <LLD 8.1 E-3 1.7 E-3 9.8 E-3 He-gp 7.5 E-4 5.4 E-4 7.8 E-4 2.1 E-3

, Tc-99M 2.3 E-5 (LLD < LLDL__ 2.3 E-5 l

l <LLD - No detectable activity above background 1 - Data will be presented in an errata to Semi-Annual Report 22 0685R

3-

^ '

.- *:= ZION STATION

~ EFFLUENT AND HASTE DISPOSAL SEMIANNUAL REPORT 1989 LIQUID EFFLUENTS

.: UNIT 2 D. Liquid Effluents Released - Isotopes-Isotopes- ' April June b'C0"d Released ' Units May Ouarter

_By .103 Ci (LLD 4.4 E-5 <LLD 4.4 E-5 Ru-105 <LLD (LLD <LLD <LLD Sn-113 (LLD 9.6 E-4 <LLD 9.6 E-4 Sn-117M (LLD <LLD <LLD (LLD Aa-110M 1.7 E-2 7.4 E-3 1.6 E-2 4.0 E-2 Sb-122 Ci (LLD <LLD <LLD <LLD Sb-124 3.8 E-3 2.3 E-3 1.0 E-3 7.1 E.3 Sb-125 1.5 E-2 9.7 E-3 7.9 E-3 3.3 E-2 1-131 Ci 1.3 E-2 1.5 E-3 8.7 E-3 2.3 E-2 I-132 <LLD <LLD <LLD <tLD I-133 8.1 E-3 6.6 E-3 4.5 E-3 1.9 E-2 Xe-133 8.i_E-2 7.0 E-2 3.1 E-1 4.7 E-1 Xe-133M Ci (LLD 2.0 E-4 4.3 E-3 4.5 E-3

__CS-134 1.4 E-2 7.8 E-3 1.4 E-2 3.6 E-2 1-134 (LLD <LtD (LLD <LLD I-135 2.5 E-4 1.9 E-4 <tLD 4.4 E-4 Xe-135 1.9 E-4 1.3 E-3 8.0 E-3 9.5 E-3 i

Cs-136 Ci < LED <LLD (LLD <LLD Cs-137 1.8 E-2 9.9 E-3 1.9 E-2 4.7 E-2 Cs-138 <LLD <LLD <LLD <LLD Ba-140 (LLD <LLD <LLD <LLD La-140 Ci 3.7 E-4 5.5 E-4 4.8 E-4 1.4 E-3 l

l-H-187 <LLD <LLD <LLD <LLD

<LLD - No detectable activity above background 23 0685R

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