Text

Effluent & Waste Disposal Semiannual Rept 1987
	ML20150B362
Person / Time
Site:	Zion File:ZionSolutions icon.png
Issue date:	12/31/1987
From:	Pliml G; COMMONWEALTH EDISON CO.
To:	Davis A; NRC OFFICE OF INSPECTION & ENFORCEMENT (IE REGION III)
References
	NUDOCS 8803160345
	Download: ML20150B362 (29)
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PRIORITY P0J'TI M Q Zion Generating Station Eint_

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101 Shiloh Blvd.

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Zion, Illinois 60099

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N Telephone 3121746 2084

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?CZ February 9, 1988 g

Mr. Bert Davis Acting Regional Administrator Directorate of Inspection and Enforcement, Region III U.

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Nuclear Regulatory Commission 799 Roosevelt Road Glen Ellyn, IL 60137 i

Subject:

Zion Nuclear Power Station Operating Report, NRC Dockets 50-295 and 50-304 Enclosed is the radioactive effluent report for July through December, 1987 for Zion Nuclear Power Station.

one copy of this report is provided for your use.

Two copies will be forwarded to Document Control and the NRC Resident Inspector will receive a report as outlined in the November '86 Federal Register.

Sincerely yours,

/

ft i

G.J.

Pliml i

Station manager Zion Station i

GJP/jlc i

Enclosure s

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ADOCK 05000295 PDR DCD R

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ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPOR1 1987 GASEOUS EFFLUENTS - SUMMATION OF ALL RELEASES Gaseous Effluents Released - Summary Sheet Thi rd Units July August September Quarter 1.

Gross Radioactivity Releases a.

Total Release Ci 2.5 EO 9.6 E-2 5.7 EO 8.3 E0 b.

Max. Release Rate pCi/Hr.

1.5 E+5 1.2 E+4 9.4 E+3 1.5 E+5 c.

% of Quarterly Limit 0.00 (SmRy/10mR 6)1 0.02 2.

lodine Releases a.

Tota l I-131,1-133 Ci 4.9 E-7 2.1 E-5 2.6 E-5 4.7 E-5 3.

Particulate Releases a.

Gross Radioactivity Ci 9.6 E-4 6.3 E-4 9.4 E-4 2.5 E-3 b.

Gross Alpha Radioactivity Ci 5.5 E-4 2.3 E-4 3.0 E-4 1.1 E-3 c.

Gross Particulate with Ci 1.4 E-4 5.6 E-5 1.7 E-4 3.7 E-4 Half Lives > 8 Days 4.

Sum of I-131,1-133 & Particulate With Half Lives Greater Than 8 Days a.

Total Ci 1.4 E-4 1.7 E-5 2.0 E-4 4.2 E-4 b.

% of Quarterly Limit 0.37 (7.5 mR Organ) 5.

Tritium Releases a.

Total Release Ci 6.2 E0 2.0 E+1 3.9 EO 3.0 E+1 1-Noble Gas Gamma / Beta

<LLO - No detectable activity above background i

s

/

0651R 2

/

11 1

ZION STATION

,3 EFFLUENT AND WASTE DISPOSAL. SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE Gaseous Effluents Released - Isotopes plff ['d 5

fer Units July August September 1.

Gross Radioactivity Releases A r-41 Ci 8.9 E-2 4.4 E-3 4.4 E-2 1.4 E-1 Kr-85 7.1 E-1

<LLO 1.7 E-2 7.3 E-1 Kr-85M 2.7 E-3

<LLO

<LLO 2.7 E-3

__Ky-87 Ci 7.2 E-4

<LLO

<LLO 7.2 E-4 ar-88 3.4 E-3

<LLO

<LLO 3.4 E-3 Xe-131 Ci

<LLO

. LLO Xe-131 M 6.1 E-3

<LLO

<LLO 6.1 E-3 Xe-133 1.6 EO 8.8 E-2 4.7 EO 6:4 EO Xe-133M 1.8 E-2

<LLO

<LLO 1.8 E-2 i

Xe-135 Ci 7.6 E-2 3.2 E-3 9.7 E-1 1.0 EO Xe-13 5M 5.5 E-3

<LLO

<LLO 5.5 E-3 Xe-138

<LLO

<LLO 4

Ci Ci

<LLO - No detectable activity above background 3

i 1

i 0651R 3

ZION ST TION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE Gaseous Effluents Released - Isotopes (continued)

T pff((l Units July August September 0

er 2.

Iodine Releases Na-24 Ci

<lLO

<LLO

<lLO Mn-54

<LLO

<LL1

<LLO

<LLO Co-58 Ci

<LLO

<LLD

<LLD Co-60 2.6 E-8 4.5 E-9 8.4 E-7 6.7 E-7 Co-57

<LLO

< L L D __

Se-75 Ci 4.9 E-9 8.5 E-8

<LLO 9.0 E-8 Br-82 1.5 E-6 2.2 E-6 1.8 E-6 5.5 E-6 Rb-88

<LLO

<LLO Ci Ru-105

<LLO

<LLD Aq-110M

<LLO

<LLO Sn -113 5.9 E-10

<tLD

<LLO 5.9 E-10 1-131 Ci 3.9 E-7 1.2 E-5 9.0 E-6 2.1 E-5 I-132 2.8 E-8 7.3 E-8 2.1 E-8 1.2 E-7 I-133 9.7 E-8 9.0 E-6 1.7 E-5 2.6 E-5 l-134

<LLD

<LLO

<LLO C s -134 3.6 E-10

<LLO

<LLD 3.6 E-10 I-135 Ci 3.1 E-7 4.7 E 'i 3.1 E-7 1.1 E-6 Ce-144

<LLO

<LLO Cs-136

<LLD

<LLO

<LLO C s -137 2.5 E-8

<LLO 2.5 E-7 2.8 E-7 C s -138

<LLO

<LLO 4.9 E-5 4.9 E-5

<LLO - No detectable activity above background 0651 R 4

1

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REP 3RT 1987 GASEOUS F.FFLUENTS - ELEVATED RELEASE Gaseous Ef fluents Released - Isotopes (continued) pfffaPl Units July August September Ou tr 3.

Particulate Releases Na-24 Ci

<LLO 2.7 E-7 2.4 E-7 5.1 E-7 Mn-54

<lLO

<LLO

<LLD

<lLD Mn-56

<LLO

<([h_

<LLO Co-58 Ci 7.4 E-9 1.5 E-9

<LLO 8.9 E-9 Co-60 9.0 E-5 4.2 E-8 2.2 E-7 9.0 E-5 Ci Br-82

<LLO

<LLD

<lLO Rb-88 Ci 4.5 E-5 5.5 E-5 4.7 E-5 1.5 E-4 Sr-89' Sr-90' Sr-91 Ci

<LLO

<LLO Sr-92

<LLO

<LLO Nb-95

<LLO

<LLO Ci i

Mo-99

<LLO

<LLO Tc-99M

<LLO

<LLD - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 0651R 5

ZION S1ATION EFFLUENT AND WASTE DISPOSAL SEW [ ANNUAL REPORT 1981 GASE0US EFFLUINTS - ELEVATED RELEASE Gaseous Effluents Released - Isotopes (continued) f*0fUP'8 r

Units July August September

,d er 3.

Particulate Releases (continued)

Ru-103 Ci

<LLO

<LLD

<LLO AQ-110M

<tLO

<LLO (LLO

<LLO 5b-122 Ci

<LLO 2.8 E-8

<LLO 2.8 E-8 5b-124 2.1 E-9

<LLO

<LLO 2.1 E-9 l-131

<LLO

<LLD

<LLO

<LLO l-132

<tLD

<LLO

<LLO Te-132

<LLO

<lLD

<LLO I-133 Ci 4.3 E-9 3.7 E-9

<LLO 8.0 E-9 Cs-134 6.4 E-8 2.2 E-8 1.1 E-8 9.7 E-8 I-134

<LLO

<LLO I-135

<LLD

<tLD

<LLO

<LLO C s -136 Ci

<LLO

<LLO Cs-137 6.5 E-8 6.0 E-8 3.3 E-8 1.6 E-7 l

Cs-138 3.6 E-7 1.3 E-6 1.2 E-4 1.2 E-4 l

Ba-139

<LLO

<LLO i

8a-140 Ci

<LLO

<tLD

<LLO l

La-140

<LLO

<LLO W-187 Ci

<tLD

<LLD (LLO

<LLO Bi-214 (LLO

<LLO

<LLO Pb-214 (LLO

<LLD

<LLO

<LLO - No detectable activity above background 0651R 6

l

ZION STAT 10N EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 1 Liquid Ef fluents Released - Summary Sheet Third Units July August September Quarter 1.

Gross Radioactivity 1 a.

Total Release C1 1.1 E-1 3.0 E-2 5.1 E -3 1.5 E-1 b.

Avg. Concentration pCi/mi Released 1.6 E-9 8.8 E-9

7. 5 E-10 3.7 E-9 c.

Max. Concentration pCi/ml Released 5.0 E-8 2.6 E-8 5.4 E-9 5.0 E-8 d.

% of Tech. Spec. Qtr.

Limit (1.5mR/5mR)2 0.03 e.

% of Tech. Spec. Yearly Limit (3mR/10mR)2 0.03 2.

Tritium a.

Total Release Ci 3.0 E +1 9.4 E-1 7.4 EO 3.8 E+1 b.

Avg. Concentration uti/mi Released 4.4 E-7 2.8 E-7 1.1 E-6 6.1 E-7 3.

Dissolved Noble Cases a.

Total Release Ci 1.6 E-2 4.4 E-4 6.4 E-4 1.7 E-2 b.

Avg. Concentration pCi/mi Released

, 2. 3 E-10 1.3 E-10 9.4 E-11

1. 5 E-10 i

4.

Gross Alpha Radioactivity l

a.

Total Release Ci 2.7 E-5 1.4 E-6 1.3 E-6 3.0 E-5 b.

Avg. Concentration pCi/ml Released 4.0 E-13 4.1 E-13 1.9 E-13 3.3 E-13 l

S.

Volume of Liquid Waste l

Liters to Discharge 1.4 E+7 7.5 E+5 1.5 E+5 1.5 E+7 i

l 6.

Volume of Dilution Water Liters

1. 2 E +11 1.0 E +11 1.1 E+11 3.3 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole body / organ

<LLD - No detectable activity above background 0651R 7

IION STAfl0N EFFLUEN) AND WA$TE UISPOSAL 5EM1ANNUnL REPORT 1987 LIQUID EFFLUENTS UNIT I s

Liquid Effluents Released - Isotopes SOf0P']

Units July August September p

3, Qua ter Na-24 Ci

<LLO

<lLO w

C r-51 Ci 1.3 E-4

<LLO

<LLO 1.3 E-4 Mn-54 3.9 E-4 5.8 E-5 2.3 E-5 4.7 E-4 Co-57

<LLO

<LLO Co-58 1.0 E-2 1.2 E-3 1.8 E-4 1.1 E-2 Fe-59 4.1 E-5

<LLO

<LLD 4.1 E-5 Co-60 Ci 1.6 E-2 1.2 E-3 2.3 E-3 2.0 E-2 Kr-85 Ci (LLO

<LLO

<LLO Kr-88 (LLO

<LLO (LLD

<lLD Rb-88 (LLO (LLO

<LLO (LLO

$r-89' i

Sr-90*

Sr-92 (LLO

<LLO

<LLO l

l l

Nb-95 Ci 3.1 E-4 1.7 E-4

<LLO 4.8 E-4 Zr-95 2.4 E-4 7.2 E-5 (LLD 3.1 E-4 Tc -99M

<LLO

<LLD (LLO

<LLO - No detectable activity above background 1 - Data will be presented in an errata to the Semi-Annual Report 1

0651R 8

Z[0N 51AI!ON EFFLUENT AND WA$TE DISPO5AL 5EMIANNUaL R PORT 1987 LIQUID EFFLUENTS UNIT I Liquid Effluents Released - Isotopes (continued) fS0f0[e'd 5

Units July August September

,p Ci Ru-105

<LLO

<LLO Sn-113

<tLO

<LLD

<LLO

<LLO AQ-110M 6.8 E-3 2.1 E-4 5.2 E-4 7.5 E-3 Sb-122 Ci

<LLO

<tLO Sb-124 9.7 E-4 8.0 E-5

<LLO 1.1 E-3 Sb-125 8.6 E-3 8.0 E-4 5.8 E-4 1.0 E-2 I-131 Ci (LLO

<LLO

<LLO I-133

<tLD

<LLD (LLO

<LLO Xe-133 1.6 E-2 4.4 E-4 6.4 E-4 1.7 E-2 Xe-133M Ci

<LLD

<LLO

<tLO Cs-134 9.8 E-3 1.2 E-2 6.0 E-4 2.2 E-2 I-134

<LLO

<tLO X e -13 5 1.5 E-4

<tLD

<LLD 1.5 E-4 C s -136 Ci I

(LLO (LLO

<LLD

<LLO Cs-137 5.5 E-2 1.4 E-2 9.4 E-4 7.0 E-2 C s -138

<LLO

<LLD La-140 Ci 7.3 E-5

<LLO

<LLO 7.3 E-S W-187 (LLO

<LLO (LLO

<LLO

<LLO - No detectable activity above background 0651R 9

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 2

. Liquid Ef fluents Released - Sumary Sheet Third Units July August September Quarter

1. Gross Radioactivity 1 a.

Total Release Ci 2.9 E-2 1.4 E-1 4.7 E-2 2.2 E-1 b.

ncentration Ci/mi 4.5 E-9 1.5 E-9 5.5 E-10 2.2 E-9 c.

ncentration Ci/ml 3.2 E-8 4.5 E-8 6.5 E-9 4.5 E-8 0.13 d.

% of Tech. Spec. Otr.

g Limit (1.5mR/5mR)2

/ 0.05 e.

% of Tech. Spec Yearly 0.08 Limit (3mR/10mR)*

0.03

2. Tritium a.

Total Release Ci 1.0 E+1 4.5 E+1 1.0 E+2 1.6 E+2 b.

ncentration Ci/mi 1.6 E-6 4.8 E-7 1.2 E-6 1.1 E-6

3. Dissolved Noble Gases a.

Total Release Ci 7.0 E-3 2.1 E-2 5.4 E-2 8.2 E-2 b.

ncentration pCi/mi 1.1 E-9 2.2 E-10 6.4 E-10 6.5 E-10

4. Gross Alpha Radioactivity a.

Total Release Ci 2.8 E-6 1.9 E-5 5.7 E-5 7.9 E-5 b.

ncentration j

pCi/ml 4.4 E-13 2.0 E-13 6.7 E-13 4.4 E-13 5.

Volume of Liquid Waste Liters 3.8 E+5 1.5 E+7 1.5 E+7 J.0 E+7 to Discharge 6.

Volume of Oilution Water Liters 1.8 E+10 1.2 E+11 1.3 E+11 2.7 E+11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole Body / Organ

<LLO - No detectable activity above background 0651R 10

ZION STATION EFFLUENT AND WA5TE DISPOSAL SEMIANNUAL REPORT 1987 LIQU10 EFFLUENTS UNIT 2 Liquid Effluents Released - Isotopes f*fae'5 P

Units July August September

,7 Na-24 Ci

<LLO 7.9 E-5

<LLO 7.9 E-5 Ar-41

<LLD

<LLO

<LLO l

Cr-51 Ci

<lLO

<LLO

<LLO Mn-54 1.7 E-4 1.8 E-4 4.8 E-5 4.0 E-4 Co-57

<LLO 1.3 E-5

<LLO 1.3 E-5 Co-58 3.8 E-3 7.4 E-3 3.7 E-3 1.5 E-2 Fe-59

<LLO

~

, Co-60 Ci 4.8 E-3 1.6 E-2 1.9 E-2 4.0 E-2 Kr-85 Ci

<LLD

<LLO

<LLO Kr-88

<LLO

<lLD Sr-891 Sr-901 C1 Sr-92

<LLO

<LLO Nb-95 C1 3.7 E-4 5.3 E-4 1.3 E-4 1.0 E-3 Zr-95 5.7 E-5 6.9 E-5

<LLO 1.3 E-4 Mo-99

<LLO

<LLD 3.2 E-5 3.2 E-5 Tc-99M

<LLD 3.2 E-5 1.0 E-5 4.2 E-5

<LLO - No detectable activity above backgt-ound 1 - Data will be presented in an errata to the Semi-Annual Report 0651R 11

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPOR1 1987 LIQU10 EFFLUENTS l

UNIT 2 Liquid Effluents Released - Isotopes (continued) 50), Pes Units July August September p

Ci Ru-105

<LLO

<LLD

<LLD Sn-113

<LLO

<LLO Aa-110M 1.3 E-3 4.3 E-3 4.0 E-3 9.6 E-1

.I Sb-122 Ci

<LLO

<LL9 Sb-124 1.4 E-4 7. 2 E -4 1.8 E-4 1.0 E-3 Sb-125 1.5 E-3 1.1 E-2 5.8 E-3 1.8 E-2 _

Xe-131 M

<tLD

<lLD

<LLO

<LLO I-131 Ci

<LLO 4.8 E-5

<LLO 4.8 E-5 I-133

<LLO 3.1 E-4 1.6 E-5 3.3 E-4 Xe-133 6.8 E-3 2.1 E-2 4.8 E-2 7.6 E-2 Xe-133M Ci

<LLO

<LLO 2.8 E-4 2.8 E-4 Cs-134 7.1 E-3 4.6 E-2 5.8 E-3 5.9 E-2 I-134

<LLO

<LLO I-135

<LLO 7.3 E-5

<LLO 7.3 E-5 Xe-135 2.0 E-4 2.1 E-4 6.0 E-3 6.4 E-3 Cs-136 Ci

<LLO

<tLD 3.5 E-4 3.5 E-4 C s -137 9.2 E-3 5.8 E-2 8.2 E-3 7.5 E-2

__C s -13 8

<lLO

<LLO

<LLD

<lLD La -140 C1

1. 0 E-4 9.1 E-6 3.0 E-5 1.4 E-4 i

W-187

<LLD

<LLO

<LLO - No detectable activity above background J

i j

Do31R 12

ZION SIATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - SUMMATION OF ALL RELEASES A. Gaseous Ef fluents Released - Summary Sheet Fourth Units October November December Quarter 1.

Gross Radioactivity Releases a.

Total Release Ci 3.4 E0 2.5 E0 2.4 E+1 3.0 E+1 b.

Max. Release Rate pCi/Hr.

2.0 E+4

2. 7 E +4 3.0 E+5 3.0 E+5 c.

% of Quarterly Limit 0.02 (SmRy/10mR 8)1 0.07 2.

todine Releases a.

Tota l 1-131,1-133 Ci 4.2 E-5 4.6 E-6 1.2 E-5 5.9 E-5 3.

Particulate Releases a.

Gross Radioactivity C1 4.9 E-4 7.1 E-4 7.3 E-4 1.9 E-4 b.

Gross Alpha Radioactivity Ci 2.4 E-4 2.3 E-4 3.0 E-5 5.0 E-4 c.

Gross Farticulate with Ci 2.7 E-d 7.1 E-4 7.3 E-4 1.7 E-3 Half Lives > 8 Days 4.

Sum of I-131,1-133 & Particulate With Half Lives Greater Than 8 Days a.

Total Ci 3.1 E-4 7.1 E-4 7.4 E-4 1.8 E-3 b.

% of Quarterly Limit"~

~

0*13 (7.5 mR Organ) 5.

Tritium Releases a.

Total Release Ci 6.8 E0 1.0 E+1 2.5 E+1 4.2 E+1 1-Noble Gas Gamma / Beta

<LLO - No detectable activity above background 13 0660R 0798A

~

^

ZION STATION EFFLUENT AND WASTE 0!SPGSAL SEMIANNUAL FEPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE B.

Gaseous Ef fluents Released - Isotopes fsotops hUurt Units October November December ur p 1.

Gross Radioactivity Releases A r-41 Ci 5.0 E-2 4.3 E-3 1.2 E-2 6.6 E-2 K r -85 9.2 E-3 1.8 E-2 1.4 E-1 1.7 E-1 Kr-85M

<LLO

<LLD

<LLO

<LLO Kr-87 Ci

<lLD

<LLD

<LLO

<LLO Kr-88

<LLO

<LLO Xe-131 Ci

<LLD

<lLD

<LLO

<LLO Xe-131 M

<LLO

<LLO 1.4 E-2 1.4 E-2 Xe -133 2.5 E0 2.2 E0 2.4 E+1 2.9 E+1 Xe-133M

<LLO

<LLO 4.6 E-3 4.6 E-3 Xe-135 Ci 8.4 E-1 2.4 E-1 4.7 E-3 1.1 EO

__Xe-135M

<LLO

<LLO Xe-138

<LLO

<LLO Ci 1

Ci

<LLO - No detectable activity above background 14 0660R 0798A l

ZION STATION l

EFFLUENT AND WASTE O!SPOSAL SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE

8. Gaseous Effluents Released Isotopes (continued) fsoop'8 ou th Units October November December e

, 9 2.

lodine Releases Na-24 Ci

<lLD 8.8 E-9

<lLO 8.8 E-9 Co-58 Ci 6.8 E-9

<LLO

<LLD 6.8 E-9 Co-60 4.8 E-9 9.5 E-9

<lLO 1.4 E-8 Ci Br-82 2.0 E-6 2.3 E-6 2.6 E-6 6.9 E-6 Rb-88

<LLO

<LLD

<LLO Ci I

I-131 Ci 9.3 E-6 2.2 E-6 8.6 E-6 2.0 E-5 I-132 8.5 E-7

<LLO

<LLO 8.5 E-7 I-133 3.3 E-5 2.4 E-6 3.5 E-6 3.9 E-5 I-134

<LLO

<LLO 1.4 E-6 1.4 E-6 Cs-134 2.2 E-7

<LLO 1.5 E-10 2.2 E-7 I-135 Ci 3.4 E-6 6.7 E-7 9.0 E-7 5.0 E-6 C s -136

<LLD

<LLO

<LLO C s -13 7 2.8 E-6

<LLO 6.0 E-9 2.8 E-6 Cs-138

<LLO 2.9 E-5

<LLO - No detectable activity above background 15 0660R 0798A

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE Gaseous Ef fluents Released - Isotopes (continued) fsotopes ou t Units October November December e,

3.

Particulate Releases Na-24 C1 1.2 E-6 3.9 E-7 2.8 E-7 1.9 E-6 _

Cr-51 5.5 E-8

<LLD

<LLD 5.5 E-8 Mn-54 2.1 E-8

<LLO

<LLD 2.1 E-8 Co-58 Ci 2.9 E-7

<LLD

<LLO 2.9 E-7 Co-60 2.8 E-7 4.3 E-9 3.9 E-9 2.9 E-7 Ci Br-82 7.5 E-9

<LLO

<lLO 7.5 E-9 Rb-88 Ci 4.1 E-5 2.6 E-4 6.1 E-4 9.1 E-4 Rb-89

<LLO

<LLO Sr-89)

Sr-90' ll Sr-91 Ci

<lLO

<LLD

<LLO

<LLO Sr-92

<lLD

<LLO

<LLO Nb-95

<LLO

<LLD Zr-95 C1 1.3 E-8

<LLD

<tLO 1.3 E-8 i

Mo-99

<lLO

7. 3 E-10

<LLO 7.3 E-10 Tc-99M

<LLD

<LLO - No detectable activity above background l

1 - Data will be presented in an errata to the Semi-Annual Report l

16 0660R j

0798A

ZIONSTAT[0N EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 GASE0US EFFLUENTS - ELEVATED RELEASE B. Gaseous Ef fluents Released - !sotopes (continued) fsotopes F

t Units October November December 0

3.

Particulate Releases (continued)

Ru-103 Ci

<LLO

<LLO An-110M

<LLD

<LLO

<LLO Sb-122 Ci

<LLO

<LLO I-131 6.8 E-9 1.4 E-8 1.4 E-8 3.5 E-8 I-132 6.1 E-7

<LLO

<LLO 6.1 E-7 Te-132

<LLO

<tLD

<LLO I-133 Ci 4.4 E-8 1.2 E-8 3.2 E-8 8.8 E-8 C s -134 1.3 E-7 1.3 E-8 2.3 E-10 1.4 E-7 I-134 1.5 E-7

<LLO

<LLO 1.5 E-7 I-135

<LLO

<LLD

<LLD Cs-136 Ci

<LLD

<LLO

<LLO C s -137 1.6 E-6 2.5 E-9 1.4 E-8 1.6 E-6 Cs-138 2.3 E-4 4.5 E-4 1.2 E-4 8.0 E-4 Ba-139

<LLO

<LLO Ba -140 Ci

<LLO

<LLO La-140

<LLO

<LLD

<LLO

<LLO W-187 Ci 1.5 E-7

<LLO

<LLD 1.5 E-7 81-214

<LLO

<lLD

<LLO

<LLO Pb-214

<LLO

<LLO - No detectable activity above background 17 0660R 0798A

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 LIQUIO EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 1 C. Liquid Effluents Released - Summary Sheet Fourth Units October November December Quarter 1.

Gross Radioactivity 1 a.

Total Release Ci 1.5 E-2 8.0 E-3

<LLO 2.3 E-2 b.

C centration Ci/ml 6.3 E-10 1.7 E-10 0

2.7 E-10 c.

Max. Concentration Released pCi/ml 1.2 E-8 4.5 E-9

<LLO 1.2 E d.

% of Tech. Spec. Otr.

0.01 Limit (1.5mR/5mR)2 0.00 e.

% of Tech. Spec. Yearly Limit (3mR/10mR)2 0.03l 2.

Tritium a.

Total Release Ci 2.2 E+1 2.9 E+1 3.9 E-2 5.1 E+1 b.

Avg. Concentration pCi/ml 9.2 E-7 6.1 E-7 5.7 E-9 5.1 E-7 Released 3.

Dissolved Noble Gases a.

Total Release Ci 1.0 E-2 8.9 E-2

<LLO 9.9 E-2 b.

Avg. Concentration UCi/ml 4.2 E-10 1.9 E-9 0

7.7 E-10 Released 4.

Gross Alpha Radioactivity a.

Total Release Ci 3.1 E-5 6.3 E-6

<LLO 3.7 E-5 b.

Avg. Concentration uti/ml 1.3 E-2

.3 E-13 0

4.8 E-13 Released 5.

Volume of Liquid Waste Liters 5.6 E+5 1.5 E+6 5.8 E+5 2.6 E+6 to Discharge 3

' l 1.1 E+11 6.

Volume of Dilution Water Liters 9.5 e 1.1 E+11 3.2 E+11 1 - Exc ludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole body / organ l

<LLO - No detectable activity above background 18 0660R 0798A

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS UNIT 1 Liquid Ef fluents Released - Isotopes f80f,0P'8 ou Units October November December Na-24 Ci

<lLD

<LLO

<LLO A r-41

<LLO

<LLO Cr-51 Ci

<LLO

<LLO Mn-54 1.4 E-4 6.1 E-6

<LLD 1,5 E-4 Co-57 1.8 E-5

<LLO

<LLO 1.8 E-5 Co-58 1.0 E-3 3.5 E-4

<LLO 1.4 E-3 Fe-59

<LLO

<LLO Co-60 Ci 8.0 E-3 2.6 E-3

<LLO 1.1 E-2 Kr-85 Ci

<LLO

<LLO Kr-88

<LLO

<LLD

<LLO Rb-88,

<LLO

<lLD

<LLD Sr-89' Sr-90 C1 Sr-92

<LLO

<lLO Nb-95 Ci 1.3 E-4

<LLO

<tLD

1. 3 E-4 Zr-95 1.1 E-4,

<LLO

<LLO 1.1 E-4 Mo-99

<LLD

<LLO

<LLO 1

i

<LLO - No detectable activity Jbove background 1 - Data will be presented in e ata to Semi-Annual Report 1

0660R 0798A y---+

++9 b--

--rw e

'fB"r "M-

)

ZION STATION EFFLUENT AND WASTE DISPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS UNIT 1 0.

Liquid Effluents Released - Isotopes (continued) fsotopej hou Units October November December e,,

p Ru-103 Ci

<LLO

<LLD Ru-105

<lLD

<LLO

<LLO Sn-113

<LLO

<LLD

<LLO

<LLO Sn-117M

<lLD

<LLO

<LLO Aa-110M 3.0 E-3 3.8 E-4

<LLD 3.4 E-3 Sb-122 Ci

<LLO

<LLO Sb-124

<lLO 1.1 E-5

<LLO 1.1 E-5 Sb-125 4.2 E-4 1.8 E-3

<LLO 2.2 E-3 I-131 Ci

<LLO

<LLO I-132 fLLO

<LLO

<lLD

<tLD I-133

<LLD

<tLD

<LLO

<LLO Xe-133 8.1 E-3 3.6 E-2

<LLO 4.4 E-2 Xe-133M Ci

<LLO 4.9 E-4

<LLO 4.9 E-4 Cs-134 7.7 E-4 1.0 E-3

<LLO 1.8 E-3 I-134

<LLO

<LLO Xe-13 5 2.3 E-3 2.7 E-3

<LLO 5.0 E-3 Cs-136 Ci

<LLO

<LLO C s -137 9.9 E-4 1.9 E-3

<LLO 2.9 E-3 Cs-138

<LLO

<LLO La-140 Ci 7.4 E-6

<LLO

<LLO 7.4 E-6 W-187

<LLO

<LLO - No detectable activity above background 20 0660R 0798A

2 ON STATION EFFLUENT AND WASTE O!SPOSAL SEMIANNUAL REPORT 1987 LIQU10 EFFLUENTS - SUMMATION OF ALL RELEASES UNIT 2 C. Liquid Ef fluents Released - Summary Sheet Fourth Units October November December Quarter

1. Gross Radioactivity 2 i

a.

Total Release Ci 4.9 E-2 3.0 E-2 4.5 E-2 1.2 E-1 b.

Av Co centration pCi/ml 5.7 E-10 7.2 E-10 4.9 E-10 5.9 E-10 c.

Max. Concentration Released pCi/mi 7.9 E-9 1.4 E-8 1.2 E-8 1.4 E-8 d.

% of Tech. Spec. Qtr.

0.03 g

Limit (1.5mR/5mR)2 0.01 0.10 e.

% of Tech. Spec. Yearly Limit (3mR/10mR)2 0.04

2. Tritium a.

Total Release Ci 7.7 E+1 1.9 E +1 8.6 E+1 1.8 E+2 b.

Avg. Concentration Released uCi/mi 9.1 E-7 4.6 E-7 9.4 E-7 7.7 E-7

3. Dissolved Noble Gases a.

Total Release C1 3.7 E-2 1.7 E-2 1.2 E-1 1.7 E-1 b.

Avg. Concentration uti/mi 4.4 E-10 4.1 E-10 1.3 E-9 7.2 E-10 Released

4. Gross Alpha Radioactivity a.

Total Release Ci 3.3 E-4 2.9 E-5 9.0 E-5

4. 5 E -4 b.

Avg. Concentration Released pCi/mi 3.9 E-12 7.0 E-13 9.8 E-13

1. 9 E -12 5.

Volume of Liquid Waste liters 1.1 E +7 1.0 E+7 1.9 E+7 4.0 E+7 l

to Discharge i

l 6.

Volume of Dilution Water Liters 1.3 E+11 1.1 E&1l 1.1 E+11 3.5 E +11 1 - Excludes Tritium, Alpha, and Dissolved Noble Gases 2 - Whole Body / Organ

<LLO - No detectable activity above background 21 0660R 0798A

ZION STATION EFFLUENT AND WASTE 0!SPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS UNIT 2 0.

Liquid Effluents Released - Isotepes fSOf0[l5 h,ur Units October November December r r Na-24 Ci

<LLD

<LLO

<LLD

<LLD C r-51 Ci 4.1 E-4

<LLO

<LLO 4.1 E-4 Mn-54 2.2 E-4 2.8 E-5

<LLD 2.5 E-4 Co-57

<LLO

<LLD

<lLD

<LLO Co-58 2.9 E-3 1.4 E-3 1.9 E-3 6.2 E-3 Fe-59

<LLO

<LLO Co-60 Ci 2.6 E-2 1.2 E-2 1.7 E-2 5.5 E-2 Kr-85 Ci

<LLO

<LLO Kr-88

<LLO

<LLO Sr-892 Sr-902 Ci i

Sr-92

<lLO

<LLD

<LLO i

l l

l Nb-95 Ci 7.2 E-4

<LLO

<LLO 7.2 E-4 Zr-95 1.9 E-4

<LLD 2.5 E-5 2.2 E-4__

i

<LLO - No detectable activity above background i

2 - Waiting for analysis results - Data will be presented in an errata to the Semi-Annual Report 22 0660R 0798A 1

ZION STATION EFFLUENT AND WASTE OlSPOSAL SEMIANNUAL REPORT 1987 LIQUID EFFLUENTS UNIT 2 O.

Liquid Effluents Released - Isotopes f30f0P's hour Units October November December

,p p

i Ci Ru-105

<LLO

<LLO Aa-110M 8.9 E-3 6.2 E-4 1.2 E-3 1.1 E-2 l

$b-122 Ci

<LLO

<LLD Sb-124 1.6 E-5 1.1 E-4 5.9 E-5 1.9 E-4 l

Sb-125 2.5 E-3 6.9 E-3 7.1 E-3 1.7 E-2 1-131 Ci 1.4 E-5 1.5 E-5 6.3 E-4 6.6 E-4 f

I-133

<LLO

<LLO Xe-133 3.5 E-2 1.6 E-2 1.2 E-1 1.7 E-1 X e -133M Ci

<LLD 1.3 E-4 7.1 E-4 8.4 E-4 Cs-134 2.4 E-3 2.9 E-3 5.3 E-3 1.1 E-2 I-134

<LLO

~~

Xe -13 5 1.7 E-3 4.7 E-4 1.7 E-3 3.9 E-3 Cs-136 Ci 5.5 E-5

<lLD

<LLO 5.5 E-5 Cs -137 3.8 E-3 6.3 E-3 1.2 E-2 2.2 E-2 Cs-138

<LLO

<tLD Ba-140

< L L O__ _

(LLO

<LLO

<LLO 1

I La -140 Ci 3.5 E-5 8.9 E-6 1.3 E-5 5.7 E-5

.a W-187

<LLO

<tLD

<LLO

<LLO 4

<LLO - No detectable activity above background 4

23 l

0660R 0798A

ZION GENERAllNL A110N UNIl 1/2 Month July Year 1987 1

SOLID RADIDACTIVE WAS1E (lech Spec 6.6.1.D.3)

Destination Waste Principal Container Solidification Volume Activity

Date LSA/

I of Material Ma. 2ria l Radionuclides

NON LSA Type Agent (ft*)

(millicuries)

}

(If Applicablel 06

~

LSA 2x 14-195 Cement / Lime /

350 1.984 (c)

Beatty, NV Waste Oil JUL Co-60(M)

Liners Emulsifier 1

87 Cs-134(M) Ni-63(E) 09

~ II

~

(

Barnwell, SC Spent Resins LSA H-06 NA 194.1 690.46 (c)

JUL

-60(M) Fe-55(E)

(Dewatered)

Liner 87 Cs-134(M) Ni-63(E) 16

~ I

~

I" Barnwell, SC Spent Resins LSA H-09 NA 194.1 4155.93 (c)

JUL

~

("I

~ I}

(Dewatered)

Liner 87 Cs-134(M) Ni-63(E)

A 688.1 487.50(c)

JUL N

3 s17M 55 a 67 1

87 Co-60(M) Co-58(M) 83aal. x 16 4

MON 1H 10lAL 1426.3 5335.87_(c),

Specify whether measured (M), estimated (L), or a combination (C).

0611R

ZION GENERAlltG.A110N UNii 1/2 o

Month August Year 1987 SOLID RAD 10AC11VE WASIL (tech Spec 6.6.1.D.3)

Destination Waste Principal Container SoI M cadon Volume Ac t Wy

Date t3gf of Material Material Radionuclides

NON LSA Type Agent (ft')

(millicuries)

(If Applicable) 27 Richland, WA uper-Co-58(M) Cs4 37(M)

Drums g3g NA 555.7 551.099 (c)

AUG compacted Co-60(M) Fe-55(E) 55 gal. x 71 87 DAW Cs-134(M) Ni-63(E) 839al. x 2 27 Super-Co-58(M) Cs-137(M)

Drums Richland, WA g3g NA 574.1 598.787 (c)

AUG compacted Co-60(M) fe-55(E) 5',ga l. x 75 87 DAW Cs-134(M) Ni-63(E) 83qal. x 1 arwell, K Spent Resins AUG g

GA NA m.1 36M E (c)

( ewa ered) gjy_

87 Cs-134(M) Ni-63(El MONIH 101AL 1323.9 4841.04_(c) 5pecif y whether measured (M), estimated (E), or a corr.bination (C).

06/1R

= __.

\\

ZION GENERAllNt eA110N UNii I/2 Month September Year 1987 _

~

S01.10 RAD 10ACIIVE WASTE i

{

(l':h Spec 6.6.1.D.3)

]

~

5 *

"C Ed' C ntainer Solidification Volume Activity

Date LSA/

j of Material Material Radionuclides

NON LSA Iype Agent (ft*)

(millicuries)

_02 U'

}

(If Applicable) 8arnwell, SC Spent Resins LSA NA 194.1 3777.72 (c)

SEP O-OM N-3

'01

-H C (DewatereO

)

87 Cs-134(M) Fe-55(El

{

10 "E'#~

~

I"}

I}

Richland, WA LSA NA

$81.6 947.350 (c)

SEP compacted Co-60(M) f e-55(E) 55 gal. x 76 j

87 DAW Cs-134(M) Ni-631Q.

839al. x 1 10 "E

( }

("}

4 Richland, WA LSA NA 600.0 647.507 (c)

SEP compacted Co-60(M) Fe-55(E) 55 gal. x 80 87 DAW Cs-134(M) Ni-63Q)

Super-Co-s8(M) Cs-ia7(M)

""5 Richland, WA tSA NA 600.0 747.834 (c)

SEP compacted Co-60(M) Fe-55(E) 55 gal. x 80 1

87 DAW Cs -134(M) Ni-63(E) 17 "E"

~

4 Richland, WA LSA NA 547.5 537.978 (c)

SEP compacted Co-60(M) Fe-55(E) 55 gal. x 73 87 DAW Cs-134(M) Ni-61(E) 24 Super-Co-58(M) Cs-137(M)

D mms Richland, WA L33 NA 516.3 371.612 (c)

SEP compacted DAW Co-60(M) Fe-55(E) 55 gal. x 41 87 e WWIF Sludge Cs-134(M) Ni-63(E) 83 gal. x 18 24 upe -

Co-58(M) Cs-137(M)

Dmms Richland, WA L3g NA 595.5 472.265 (c)

SEP compacted DAW Co-60(M) Fe-55(E) 55 gal. x 33 87

+ WWIF Sludge Cs-134(M) Ni-63(E) 83qal. x 3_0, 30 E*"

- ( }

"I

h Barnwell, SC LSA NA 125.2 280,909.12(c)

SEP Storage lank Co-60(M) Cs-131(E)

Steel Liner 87 Mixed 8ed Ni-63(E)

MONIH 101AL 3760.2 288.204.12(c)

Spec if y whether measured (M), estimated (L), or a combination (C).

06/lR

-. =.

ZION GENERAllCt. sA110N UNil 1/2 Month October Year 1987 SOLID RAD 10AC11VE WASIL (lech Spec 6.6.1.0.3)

Destination Waste Principal Container Solidification Volume Activity

Date t3gj of Material Material Radionuclides

NON LSA Type Agent (ft')

(millicuries)

(If Applicable) 06 Dewat ued Co48(M) Fe-W)

Barnwell, SC NON NA 73.4 112,460.5 (c) 0C1 Filters &

Co-60(M) Ni-63(E)

HIC L33 87 DAW Cs-137(M)

I3 fier Beatty, NV Waste Oil LSA Cement 206.1 0.596 (c) 0CT 6

-6 87 Cs-137(M) 001

}

tr 87 Cs-13)(M)

E'"

"S "5 A

64.17 (c) 0C1 6 M Ni-63(E) ie 87 (Dewatered)

Cs-134(M) Fe-55(E) i MONIH TOTAL 667.7 _116,7bl.83 (c)

Specify whether measured (M), estimated (L), or a combination (C).

{

Ob11R l

s ZION GLDERAllNL.AllDN UNIl 1/2 l

r s

Month November Year 1987 h

{

SOLID RAD 10AC11VL WASIL (tech Spec 6.6.1.D.3) j Destination Waste l

Principal Containen-Solidification Volume Activity

Date L3gf j

of Material Material Radionuclides

NON LSA Iype Agent (ft*)

(mil 11 curies)

(If Applicable) l 04

~

LSA NA 613.3 325.046 (c)

Richland, WA NOV DAW Co-60(M) Fe-55(E) 55 gal. x 23 i

87 Cs-134(M) Ni-63(E) 83qal. x 38 I3 Spent Resins Co-60(M) Fe-55(E)

H-21 8arnwell, SC t33 NA 194.1 2387.59 (c)

NOV (Dewatered)

Cs-134(M) Ni-63(C)

Liner 87 Cs-137(M) 18 Vert. Pipe Co-60(M) C-14(E)

S-14 Barnwell, SC (33 Cement 125.2 2112.55 (c)

NOV Chase Co-137(M) f e-55(E)

Liner 4

j 87 Sludge NS-63(E1..

4 23 DAW Co-58(M) Cs-137(M)

Drums:

CNSI E33 NA 1036.35 1230.63 (c)

NOV (to be Co-60(M) Fe-55(E) 52 gal x147 U"'

j 87

_supercomp'd) Cs-134(M) Ni-63(E) j i

i MONIH 10TAL 1968.95 6055.82 (c]_

Specif y whether measured (M), estimated (E), or a combination (C).

1 Ob f l R

ZION GENERAllK.A110N UNil 1/2 Month December Year 1987 t

SOLID RA010AC11VE WAS1T (lech Spec 6.6.1.D.3) e nad n as e ncipal Container Solidification Volume Activity

Date t3Af of Material Material Radionuclides

NON LSA Type Agent (ft')

(millicuries)

(If Applicable) 01 DE Co-58(M) Cs-137(M)

Drums g,3g L3g NA 810.75 754 51 (c)

DEC (to be.

Co-60(M) Fe-55(E) 52 gal x 115 Channahon II.

87 supu m 'd)

Cs-134(M) Ni-63(E)

'SA NA 194.1 1688.64 (c)

DEC C

)

i

)

er at 87 Cs-137(M) l l

MONTH 101AL 1004.85 2443.15 fcl_

Specify whether measured (M), estimated (E), or a combination (C).

I i

ObilR

-.

ML20150B362

Text

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