Text

National Pollutant Discharge Elimination System (NPDES) Permit Renewal Application
	ML13102A132
Person / Time
Site:	Palisades
Issue date:	04/10/2013
From:	Gustafson O; Entergy Nuclear Operations
To:	; Document Control Desk, Office of Nuclear Reactor Regulation
References
	PNP 2013-027
	Download: ML13102A132 (71)
	v • d • e

Entergy Entergy Nuclear Operations, Inc.

Palisades Nuclear Plant 27780 Blue Star Memorial Highway Covert, MI 49043 269.764.2000 Otto W. Gustafson Licensing Manager PNP 2013-027 April 10, 2013 U. S. Nuclear Regulatory Commission ATTN: Document Control Desk Washington, DC 20555-0001

SUBJECT:

National Pollutant Discharge Elimination System (NPDES) Permit Renewal Application Palisades Nuclear Plant Docket 50-255 License No. DPR-20

Dear Sir or Madam:

This letter transmits a copy of the National Pollutant Discharge Elimination System (NPDES) application for renewal of permit number M10001457, in accordance with Palisades Facility Operating License, DPR-20, Appendix B, Section 3.2. The application for renewal was submitted to the Michigan Department of Environmental Quality, Water Division, on April 3, 2013.

This letter contains no new commitments and no revisions to existing commitments.

Sincerely, OWG/bed Attachments: 1. NPDES Permit Renewal Application CC Administrator, Region Ill, USNRC Project Manager, Palisades, USNRC Resident Inspector, Palisades, USNRC

ATTACHMENT 1 PALISADES NUCLEAR PLANT NPDES Permit Renewal Application 69 Pages Follow

S Entergy Entergy Nuclear Operations Inc.

Palisades Nuclear Power Plant 27780 Blue Star Memorial Highway Covert, MI 49043 April 3, 2013 Michigan Department of Environmental Quality Cashiers Office WRD-NP 1 PO Box 30657 Lansing, Michigan 48909-8157 ENTERYG NUCLEAR PALISADES-LLC, PALISADES NUCLEAR PLANT NPDES PERMIT NO. M10001457 PERMIT APPLICATION RENEWAL The NPDES Permit for the Palisades Nuclear Plant expires October 1, 2013. The enclosed State of Michigan NPDES Permit Application Forms (Rev. 1/2013) is hereby submitted to support reissuance of NPDES Permit No. MI0001457.

Enclosed is a completed application that reflects waste water effluents and systems over the next five years. It includes a check in the amount of $750.00 as the application fee, a flow diagram representing operations for the next five years, and an update on requested water treatment additive approvals.

The Palisades Nuclear Plant is owned and operated by Entergy Services Inc. Enclosed application is signed by the site vice president of the Palisades Plant whom is employed by Entergy Services Inc. This person is responsible for the overall operations of the plant and, therefore, meets the signatory requirements in Rule 323.2214 and 40 CFR 122.22(a)(1)(ii).

The wastewater discharges from this facility have been well characterized through the duration of the current and previous NPDES permits. Outfall 001A (mixing basin discharge) consists principally of noncontact cooling water, cooling tower blowdown from internal Outfalls 001A-001 C, and combined miscellaneous low volume waste.

Internal Outfalls 001D and 001F consist principally of radwaste water and turbine sump water. Monitoring at internal Outfalls 001A-001C were previously eliminated from NPDES permit regulation since-flows are calculated prior to combining with mixing_- --

basin flows where they are monitored and measured at Outfall 00IA.

Waivers are requested for parameters-where there is no source association or-at - - -

undetectable loading levels to the-effluent as a result-of plant operations through previous NPDES permit application and monitoring characterization. We request waivers from

certain reporting requirements in the application according to 40 CFR 122.53 (d)(7)(i)(B), subpart D for:

1. Outfall 001 A, a waiver is requested from reporting parameters of (a) BOD 5, (b)

COD, (c) TOC, (d) Ammonia Nitrogen (as N), and (e) Total Suspended Solids.

2. Outfall 001 D, a waiver is requested from reporting parameters of (a) BOD 5, (b)

COD, (c) TOC, (d) Ammonia Nitrogen (as N), (e) pH, (f) Temperature summer, and (g) Temperature winter.

3. Outfall 001F, a waiver is requested from reporting parameters of (a) BOD 5, (b)

COD, (c) TOC, (d) Ammonia Nitrogen (as N), (e) Total Suspended Solids, (f) pH, (g) Temperature summer, (h) Temperature winter.

WATER TREATMENT ADDITIVES The enclosed Attachment 1 is a current list of water treatment additives currently approved for use at the plant. The additives listed were approved by the Department through previous NPDES renewals or by separate approval, The company request continued approval of the attached additives.

STORM WATER Compliance with all storm water monitoring requirements is maintained as specified in the current permit. Currently this facility has an implemented Storm Water Pollution Prevention Plan which is retained and available for review and/or inspection upon request.

Enclosed as Attachment 2 is a completed "No Exposure to Storm Water" Certification form requesting continued exclusion from coverage under the NPDES storm water discharges associated with industrial activities. We believe facility conditions exist for a no exposure exemption based on MDEQ's no exposure guidance document qualifications and criteria.

CURRENT PERMIT STATUS & SUGGESTED CHANGES The Plant is in compliance with the NPDES Permit MI0001457. Requested changes to the permit are:

1. Removal of the monitoring requirement for LL Hg. Data obtained show plant to be very low source of mercury. Sampling requirements have already been reduced to annually by approval letter from 5/25/2011. (Attachment 3)

2. Permit-langu'age to be consistent-with-new 316(b) rule from the EPA. Seek continued consideration that the Palisades Plant, with cooling towers, has reduced intake-flf commensurate with a closed-cycle recitCiilatihg system. Requdt application of new rules be consistent with this perspective. (Attachment 4)

'ADw /it ,4vd Environmental Coordinator Palisades Nuclear Plant, Entergy Office: 269-764-2568 Email: sandre3@(centergy.com S-Entergy THE POWER OF PEOPLE"TH

Michigan Department of Environmental Quality - Water Resources Division

-WASTEWATER-DISCHARGE-PERMIT APPLICATION SECTION I - General Information Section I shall be completed by all permit applicants. Instructions Water Resources Division Use Cashier Use Only: 6000-42203-9512-481000-00 for completing Section I, Pages 1 and 2, are on Page 2 of the Only Appendix. To submit additional information, see Page ii, Item 3.

Receipt #:

PLEASE TYPE OR PRINT I

NPDES PERMIT NUMBER MI UUU1457 II Permit ID#:

Applicant Name Entergy Services Inc, Palisades Nuclear Plant z Address Address 2 or P.O. Box 3* 308 E. Pearl Street 0.

0. City State ZIP Code Jackson MS 39201 Telephone (with area code) FAX (with area code) Applicant Web Site Address (601) 969-2434 (601) 969-2696 sandre3@entergy.com Facility Name 1 Entergy Nuclear Palisades, LLC Facility Name 2 Facility Name 3

-J

,, Street Address (Do not use a P.O. Box Number) c4 27780 Blue Star Memorial Highway City State ZIP Code Covert Ml 49043 Telephone (with area code) FAX (with area code) Facility Web Site Address (269) 764-2000 (269) 764-2078 sandre3@entergy.com First Name Last Name

" Application Contact Steven Andrews TitleBusiness Facility Contact Title Environmental Coordinator

[Discharge Monitoring Reports Address 1 Address 2 E] Storm Water Billing 27780 Blue Star Memorial Highway City State ZIP Code 49043 El Biosolids Billing Covert MI 0 NPDES Annual Billing Telephone (with area code) Fax Number e-mail address 269-764-2568 sandre3@entergy.com First Name Last Name El Application Contact Joseph Hager TitleBusiness El Facility Contact Title

{,

D M gChemistry Technical Supervisor Discharge Monitoring Reports Address 1 Address 2 z

o0 Storm Water Billing 27780 Blue Star Memorial Highway City State ZIP Code El Biosolids Billing Covert MI 49043 El NPDES Annual Billing Telephone (with area code) Fax Number e-mail address 269-764-2536 jhager@entergy.com First Name Last Name E] Application Contact TitleBusiness Title El Facility Contact CE Discharge Monitoring Reports Address 1 Address 2 El Storm Water Billing CiyState ZIP Code city El Biosolids Billing El NPDES Annual Billing Telephone (with area code) Fax Number e-mail address 1 EQP 4659-A (Rev. 1/2013) NP2

Michigan Department of Environmental Quality - Water Resources Division

. WASTE-WATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER Entergy Nuclear Palisades, LLC Ml 0001457

5. PERMIT ACTION REQUESTED (Check one box only). Instructions for this item are on Page 2 of the Appendix.

[I NEW USE. A proposed discharge.

El EXISTING DISCHARGE that is currently unpermitted.

Z REISSUANCE of current permit.

Cl MODIFICATION of current permit. Attach a description of the proposed modification.

Note: Applications for New Use discharges, Existing Discharges that are currently unpermitted, and for either Reissuance or Modification that include an increased loading of pollutants to the receiving water are required to submit a Rule 98 Demonstration with the Application. See Item 6.

6. RULE 98- ANTIDEGRADATION REQUIREMENTS. Instructions for this item are on Page 2 of the Appendix.

In accordance with Rule 323.1098 of the Michigan Water Quality Standards, the applicant is required to submit an Antidegradation Demonstration for any new or increased loading of pollutants to the surface waters of the state. An Antidegradation Demonstration must contain the information specified in Rule 1098, outlined on Pages 8-9 of the Appendix. For assistance in completing this item, contact the Permits Section.

Will this discharge be an increased loading of pollutants to the surface waters of the state? C] Yes, continue below. Z No.

El Antidegradation Demonstration provided. E] Increased loading of pollutants is exempt from Antidegradation Demonstration as indicated below:

E] A short-term (weeks to months) or temporary lowering of water quality El Bypasses that are not prohibited by regulations set forth in 40 CFR 122.41(m)

El Response actions undertaken to alleviate a release of pollutants into the environment that may pose an imminent and substantial danger to the public health or welfare El Discharges of pollutant quantities from the intake water at a facility if the intake and discharge are to the same body of water El Increases in flow at a POTW if the increase is within the design flow of the facility, there is no increased loading of BCCs that are not specifically limited in the current permit, and there is no significant change expected in the characteristics of the wastewater collected El Intermittent increased loading related to wet-weather conditions El New or increased loading due to DEQ-approved controls related to wet-weather conditions El Discharges authorized by Certificates of Coverage (COC) and Notices of Coverage El Increased loadings within the authorized levels of a limit in an existing control document, except those loadings that result from actions by the permittee that would otherwise require submittal of an increased use request El Increased loadings of a pollutant which do not involve Bloaccumulative Chemicals of Concern and which use less than 10 percent of the unused loading capacity that exists at the time of the request

7. ADDITIONAL FACILITY LOCATION INFORMATION. Instructions for this item are on Page 2 of the Appendix.

A Local Unit of Government (LUG) LUG e-mail address South Haven www.south-haven.com County Township B

Van Buren Covert Town Range Section 1/4 14, 14 Private (French) Land Claim C. 02S 17W 05 NW SE Latitude Longitude D42 19' 23" 86 18' 56"

8. CERTIFIED OPERATOR Does the facility have a DEQ-certified operator? El Yes El No Instructions for this item are on Page 2 of the Appendix.

First Name Last Name Steven Andrews Certification Number Certification Classification(s)

W 5589 A-lh, B-2c Address 1 Address 2 27780 Blue Star Memorial Highway City State Zip Code Covert Ml 49043 Telephone Number Fax Number e-mail address 269-746-2568 (269) 764-2078 sandre3@entergy.com 2 EQP 4659-A (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWA-TER DISCHARGE-PERMIT APPLICATION-W SECTION I - General Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER Entergy Nuclear Palisades, LLC MI 0001457

9. OTHER ENVIRONMENTAL PERMITS Provide the information requested below for any other federal, state, or local environmental permits in effect or applied for at the time of submittal of this Application, including, but not limited to, permits issued under any of the following programs: Air Pollution Control, Hazardous Waste Management, Wetlands Protection, Soil Erosion and Sedimentation Control, and other NPDES permits. To submit additional information, see Page ii, Item 3.

Issuing Agency Permit or COC Number Permit Tvye MDEQ, Air Quality MI-ROP-B2934-2008 Renewable Operating Permi Federal EPA RCRA MID098644685 ID# Not a permit 4

4- 4

10. WATER FLOW DIAGRAM AND NARRATIVE DESCRIPTION Provide a flow diagram (using 8%/2" x 11" paper if possible) and a narrative description that explains the diagram. The diagram should show the wastewater flow through the facility (from intake through discharge), including all processes, treatment units, including any lagoons or ponds (lagoon

/ pond construction and liner information should be included) used for wastewater treatment or storage (identify treatment units that operate intermittently), and bypass piping. Show all operations contributing wastewater and the locations of flow meters, chemical feeds, and monitoring and discharge points. The water balance shall show the daily average flow rates at the intake and discharge points, and approximate daily flow rates between treatment units, including influent and treatment rates. Use actual measurements whenever available, otherwise use the best estimate.

Show all significant losses of water to products, atmosphere, and discharge. In addition, provide a flow diagram for any storm water discharges from secondary structures that are required by state or federal law and for storm water runoff from any Site of Environmental Contamination, pursuant to Part 201 of the Michigan Act. Do not send blueprints. Provide black-and-white reproducible diagrams.

Municipal Facilities - Include a narrative that briefly describes the history of the wastewater treatment facility and collection system, including the initial construction, facility improvements, future plans for upgrade, location of all constructed emergency overflows, and other pertinent information.

- Industrial and Commercial Facilities - The diagram shall include all operations contributing wastewater, including process and production areas, sanitary flows, cooling water, and storm water runoff. Include a narrative that provides a brief description of the nature of the business and the manufacturing processes.

ATTACH THIS INFORMATION TO THIS APPLICATION. PLEASE DO NOT BIND THIS INFORMATION. Comments:

11. MAP OF FACILITY AND DISCHARGE LOCATION Provide a detailed black-and-white reproducible map on 8Y" x 11" paper showing the location of the existing or proposed facility, wastewater and biosolids treatment system(s), water intakes, wastewater monitoring, and wastewater discharge points into receiving waters (including bypasses).

Include the exact location of the water intakes, wastewater monitoring and discharge point(s) and, if applicable, all areas through which the discharge flows (e.g., wetlands, open drains, storm sewers) between the discharge point and the receiving water. If the discharge is to a storm sewer, label the storm sewer and show its flow path to the receiving water. Also include the location of any water supply intakes or wells and groundwater monitoring wells. This map shall be a United States Geological Survey quadrangle (7.5 minute series) or other map of comparable detail, scale, and quality (which shows surface water bodies, roads, bathing beaches, and other pertinent landmarks). It is preferred that the minimum area this map shall encompass be approximately one (1) mile beyond the property boundaries.

ATTACH THIS INFORMATION TO THIS APPLICATION. Comments:

3 EQP 4659-A (Rev. 1/2013)

Palisades Nuclear Power Plant NPDES Permit M10001457: 4/3/13 Application Section I - General Information Item 10:

Narrative

Description:

Outfall 001A (mixing basin discharge) consist of noncontact cooling water, cooling tower blowdown from internal outfalls 001A-001C, and combined treated miscellaneous low volume wastestreams. Internal Outfalls 001D and 001F consist principally of treated radwaste water and turbine sump water. These flows combine within the mixing basin where the effluent quality is monitored and measured at Outfall 001A prior to discharge to Lake Michigan.

EXIBIT 1-10 Schematic of Water Flow Entergy Services Inc Palisades Nuclear Plant Outfall 001A NPDES Permit MI0001457 123.84 to Lake Michigan 141.12 MGD Demineralized Water Storage ---

Tank T-939

J Continuous Flow

Revised 3/18108 Intermittant Flow -...... -- JMWoyehoski

ROUTES OF ACCESS TO Palisades Plant PALISADE, PANT ENTRAN(

(J ROAD NOTE-PROCEDE WEST FROM EXIT 13 APPROX. I/2 MILE NWATERVLIET TO BLUE STAR - -" US-33 HIGHWAY. TURN RIGHT AND DRIVE APPROX. I MILE TO PLANT ENTRANCE RC*D.

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Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION I - General Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER Entergy Nuclear Palisades, LLC MI 0001457

12. CONTRACT LABORATORIES THAT PROVIDE ANALYTICAL SUPPORT Provide the name and address of each contract laboratory or consulting firm that performed any analyses submitted as part of this Application. To submit additional information, see Page ii, Item 3.

Laboratory Name Laboratory Name Consumers Energy Company, Trail Street Laboratory Brighton Analytical LLC Street Address Street Address 135 W. Trail Street 2105 Pless Drive City State ZIP Code City State ZIP Code Jackson MI 49201 Brighton MI 48114 Telephone (with area code) Fax (with area code) Telephone (with area code) Fax (with area code) 517-788-5888 (810) 229-7575 (810) 229-8650 Analysis Performed Analysis Performed GC/MS Scans (volatile, base/neutral, acids), metals, LL Hg GC/MS Scans (volatile, base/neutral, acids), metals Laboratory Name Laboratory Name Street Address Street Address City State ZIP Code City State ZIP Code Telephone (with area code) Fax (with area code) Telephone (with area code) Fax (with area code)

Analysis Performed Analysis Performed

13. LIST ADJACENT PROPERTY OWNERS List the names and mailing addresses of all property owners for all properties adjacent to the facility, treatment systems, and discharge locations.

For vacant lots or empty buildings, supply the owner's mailing address - NOT the lot or building property address. To submit additional information, see Page ii, Item 3.

Name Address City State ZIP Code State of Michigan 23960 Ruggles Road South Haven MI 49090 Palisades Country Club 1324 Meadow Brook Lane Kalamazoo MI 49001 r 1-t 1 1-

-t I +/-

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4 EQP 4659-A (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division

--- WASTEWATER-DISCHARGE PERMIT APPLICATION .

SECTION I - General Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER Entergy Nuclear Palisades, LLC MI 0001457

14. APPLICATION CERTIFICATION Rule 323.2114(1-4), promulgated under the Michigan Act, requires that this Application must be signed as follows:

A. For an organization, company, corporation, or authority, by a principal executive office, vice president, or higher B. For a partnership, by a general partner C. For a sole proprietor, by the proprietor D. For a municipal, state, or other public facility, by a principal executive officer or ranking elected official (e.g., mayor, village president, city or village manager, or clerk)

Note: If the signatory is not listed above, but is authorized to sign the Application, please provide documentation of that authorization.

"1certify under penalty of law that this document and all attachments were preparedunder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for having knowledge of violations."

The last Application for this facility was submitted on: 3/28/2008 I understand that my signature constitutes a legal agreement to comply with the requirements of the NPDES Permit. I certify under penalty of law that I possess full authority on behalf of the legal owner/permittee to sign and submit this Application.

Anthony J. Vitale Site Vice President Print Name ____ Title Signature ,. Date This completesSection I. Publicly-Owned Treatment Works discharging sanitary and industrial wastewater to the surface waters, and privately-owned treatment works discharging sanitary wastewater to the surface waters should complete Section II.

Privately-owned treatment works include, but are not limited to, Mobile Home Parks, Campgrounds, Condominiums, Hotels and Motels, and Nursing Homes. All other applicants should complete Section III. If assistance is needed to complete this Application, contact the Permits Section.

Permit Application Submittal Checklist Please confirm the following before submitting the Application:

0 1.Section I has been completed, including all diagrams, maps, and the treatment process narrative.

0 2. The Application has been signed as required above in Section 1.14.A.-D. or a copy of the letter authorizing the signatory to sign the letter has been included, as appropriate.

0D 3.Section II or Section III has been completed, including any additional information or submissions.

0 4.Section IV has been completed by any facility that discharges storm water.

El 5.Section V has been completed by any facility that is a Concentrated Animal Feeding Operation.

0 6.Section VI has been completed by any facility that has Cooling Water Intake Structures.

0 7. A check or money order for the appropriate application fee has been made out to the "State of Michigan" and has been included with the Application submittal.

0 8. E-mail addresses have been provided.

5 EQP 4659-A (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION_

SECTION II - Sanitary Wastewater Section Il is to be completed by Publicly-Owned Treatment Works (POTWs) discharging treated or untreated sanitary and industrial wastewater to the surface waters.Section II is also to be completed by all privately-owned treatment works discharging treated sanitary wastewater to the surface waters. The privately-owned treatment works include, but are not limited to, Mobile Home Parks, Campgrounds, Condominiums, Hotels and Motels, and Nursing Homes.

A. Facility Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER NA NA

1. WATER SUPPPLY INFORMATION List the source(s) of the water supply in the area served by sewers. Identify groundwater wells and surface water intakes, as well as the name(s) of any surface water(s) from which intake water is drawn.

2. SERVICE AREA INFORMATION POTWs are required to provide the following Information: List the governmental jurisdictions (e.g., cities, townships, villages) that this facility serves (applicants should include themselves). What is the population in each jurisdiction? Is the jurisdiction's collection system separate, combined, or both? If the collection system is both separate and combined, what percentage is combined? To submit additional information, see Page ii, Item 3.

Municipality and E-Mail Address Type of Collection System Percent Combined Population Served El Separate E] Combined 0_ Separate 0] Combined 0_ Separate El Combined 0] Separate 0 Combined

[o Separate [3 Combined Total population served by -this facility:

Privately-Owned Treatment Works are required to provide the following information:

Describe the area served by this facility (e.g., mobile home park, condominium, nursing home).

Provide the number of residential units served by this facility:

3. BIOMONITORING FOR ACUTE AND CHRONIC TOXICITY POTWs meeting one or more of the following criteria are required to submit with this Application the results of four (4) Whole Effluent Toxicity (WET) tests for each of the facility's discharge points, excluding combined sewer overflows: 1) POTWs with a design flow rate greater than or equal to one (1) million gallons per day (MGD); 2) POTWs with an approved Federal Industrial Pretreatment Program (FIPP); and/or 3) POTWs required to develop a FIPP.

The results of the tests shall be reported using the Acute Toxicity Test Report, Ceriodaphniadubia Chronic Toxicity Test Report, and the Fathead Minnow Chronic Toxicity Test Report available in the Appendix. Please do not submit additional forms or paperwork pertaining to WET tests with this Application.

At a minimum, the applicant shall submit the results of quarterly WET testing for a 12-month period prior to this Application or the results of annual WET tests conducted during the five years prior to this Application. In addition, the applicant shall submit the results of any other WET tests from the past five years. If a WET test in the past 4Y2 years revealed toxicity, provide all the information on the cause of toxicity or the results of all toxicity reduction evaluations, if any were conducted. The applicant does not need to submit results for previously-submitted WET tests. For assistance, see "Whole Effluent Toxicity Test Guidance and Requirements" on Page 17 of the Appendix. Comments:

6 EQP 4659-B (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II - Sanitary Wastewater B. Outfall Information Complete a separate Section ll.B. Outfall Information (Pages 7 - 12) for each outfall at the facility. Make copies of Section lI.B. for each additional outfall that discharges treated wastewater.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER

1. OUTFALL INFORMATION. Instructions for this item are on Page 3 of the Appendix.

Receiving Water Hydrologic Unit Code (HUC)

A.

County Township B.

Town Range Section 14 14, / Private (French) Land Claim C.

Latitude Longitude D.

E. Facility Annual Average Design Flow:

Seasonal Discharge: MGY (Continue with Item F.) Continuous Discharge: __ MGD (Continue with Item G.)

F. Seasonal Discharge:

List the discharge periods (by month) in the spaces provided below.

From Through Actual Discharge Volume (MGD) Annual Total From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

G. Continuous Discharge:

How often is there a discharge from this outfall (on average)? Hours/Day _ Days/Year Provide the actual facility flows for the past three years. Three Years Ago Two Years Ago Last Year Annual Average Daily Flow (MGD)

Maximum Daily Flow in a Single Day (MGD)

Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization? El Yes I] No Batch Peak Flow Rate: __ Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons)

Batch Duration (minutes)

H. Inflow and Infiltration:

What is the current average daily volume of inflow and infiltration at this outfall? Gallons/Day What corrective actions are being taken to minimize this inflow and infiltration?

7 EQP 4659-B (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMMIT APPLICATION SECTION II - Sanitary Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER NA I NA

2. EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS Existing Treatment Works Treating Domestic Sewage (TWTDS) are required to report data from effluent sampled and analyzed by the permittee for the parameters listed below. (See the Definition Section on Page 8 in the Appendix for sampling definitions, including "maximum daily concentration" and "maximum monthly concentration.") Retention Treatment Basins are required to provide a summary of influent and effluent data for the last three years. For analytical test requirements, or if alternate test procedures for any parameter listed below have been approved, see Page ii, Item 5. If the data was previously submitted via DMRs, check the box and proceed to Item 3.

New TWTDS are required to provide estimated effluent concentrations for the parameters listed below.

0l Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichiacoil or Fecal Coliform Bacteria as the indicator that effluent has been disinfected.

The DEQ will use the indicator selected below in the permit issued based on this Application.

o Use Escherichiaco/i as an indicator of disinfection.

o Use Fecal Coliform Bacteria as an indicator of disinfection.

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al*,"es S..ample* Typ~e',.

mg/I 0l Grab El Biochemical Oxygen Demand - 5 day (BOD 5 )

El 24-Hr Comp O1 BOD5, Lowest % Removed % Calculation mg/I 0l Grab El Carbonaceous BOD5 (CBOD 5 ) [] 24-Hr Comp El Carbonaceous BOD5 , Lowest % Removed % Calculation mg/I 0l Grab 0l Ammonia Nitrogen (as N) []1 24-Hr Comp El Total Suspended Solids mg/I El Grab

_E 24-Hr Comp El Total Suspended Solids, Lowest % Removed ......... % Calculation mg/I E2 Grab El Total Dissolved Solids []24-Hr Comp mg/I El Grab El Total Phosphorus (as P) []24-Hr Comp Fecal Coliform Bacteria Maximum 7-day counts/100 ml Grab (report geometric means)

Escherichiacoli Maximum 7-day counts/100 ml Grab (report geometric means)

El pig/I El Total Residual Chlorine El mg/I Grab El Dissolved Oxygen Minimum Daily mg/I Grab El pH Minimum Maximum standard units Grab El Temperature El oF EO°C Grab El El Grab El 24-Hr Comp 8 EQP 4659-B (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICAT!ON SECTION II - Sanitary Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER NA NA

3. EFFLUENT CHARACTERISTICS - TOXIC POLLUTANTS Existing POTWs with (1) a design flow greater than or equal to 1.0 MGD; or (2) an approved Federal Industrial Pretreatment Program (FIPP); or (3) required to develop a FIPP or otherwise required by the permitting authority, shall provide the results of a minimum of three effluent analyses for each parameter listed below for each outfall through which effluent is discharged. Any effluent testing data for pollutants not specifically listed shall be submitted on separate pages. Do not include information on combined sewer overflows in this section.

All existing POTWs (unless already included above) are required to provide (1) the results of at least one effluent analysis (taken in the last three years) for any chemical that is known or believed to be present in facility effluent that is listed in Tables 2, 3, and 4 of the Appendix; (2) a measured or estimated effluent concentration for any chemical that is known or believed to be present that is listed in Table 5 of the Appendix; (3) a measured or estimated concentration for any toxic or otherwise injurious chemical known or believed to be present in facility effluent that is not previously identified in this Application; and (4) results of all other effluent analyses that have been performed within the past five years for any chemical listed in Tables 2, 3, 4, and 5 of the Appendix.

New POTWs are required to provide an estimated effluent concentration for any chemical expected to be present in facility effluent that is listed in Tables 2, 3, 4, and 5 of the Appendix, and an estimated effluent concentration for any toxic or otherwise injurious chemical known or believed to be present in facility effluent that has not been previously identified in this Application.

Note: If the effluent concentrations are estimated, place an E in the "Analytical Method" column. In accordance with Rule 323.1211(7), facilities whose supply water contains toxic pollutants that are withdrawn from and discharged to the same body of water may qualify for intake credits for those toxic pollutants. See Rule 1211(7) for qualification and demonstration requirements. Effluent data submitted in response to this part may be recorded on Pages 9 - 12, or by submission of sampling analytical reports. To submit additional information, see Page ii, Item 3. Report all sampling results in pg/l.

For analytical test requirements, or if alternate test procedures for any parameter listed below have been approved, see Page ii, Item 5 and Table 7 in the Appendix.

Submitted SAMPLE DATE _.._

I,-

via DM Rs , V W.

or e-DMRs PARAMEN *TER _ -pCg/IC_ e M d6 METALS (TOTAL RECOVERABLE), CYANIDE, PHENOLS, AND HARDNESS El Antimony 7440360 El Arsenic 7440382 El Barium 7440393 El Beryllium 7440417 El Boron 7440428 El Cadmium 7440439 0- Chromium 7440473 El Copper 7440508 El Lead 7439921 El Mercury (USEPA Method 1631) 7439976 El Nickel 7440020 El Selenium 7782492 El Silver 7440224 El Thallium 7440280 El Zinc 7440666 El Available Cyanide (Method OIA 1677) 57125 El Total Phenolic Compounds None El Hardness (as CACO 3 ) None 9 EQP 4659-B (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II - Sanitary Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER NA NA Submitted SAMPLE DATE 4 via DMRs . . CAS,.. c C÷ Conid:$ ; c~ni* snalytical or e-DMRs PARAMETERkq1 ' .... _ _

VOLATILE ORGANIC COMPOUNDS

'- Acrolein 107028 O Acrylonitrile 107131 El Benzene 71432 El Bromoform 75252 r- Carbon Tetrachloride 56235

[] Chlorobenzene 108907 El Chlorodibromomethane 124481 El Chloroethane 75003

[] 2-chloro-ethylvinyl ether 110758 El Chloroform 67663 El Dichlorobromomethane 75274 0l 1,1-dichloroethane 75343 0l 1,2-dichloroethane 107062 El Trans-1,2-dichloroethylene 156605 El 1,1-dichloroethylene 75354 0l 1,2-dichloropropane 78875

[] 1,3-dichloropropylene 542756 El Ethylbenzene 100414 El Methyl Bromide 74839 El Methyl Chloride 74873 El Methylene Chloride 75092 El 1,1,2,2-tetrachloroethane 79345 El Tetrachloroethylene 127184 El Toluene 108883 El 1,1,1-trichloroethane 71556 El 1,1,2-trichloroethane 79005 El Trichloroethylene 79016 El Vinyl Chloride 75014 10 EQP 4659-B (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II - Sanitary Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER NA NA Submitted SAMPLE DATE "

via DMRs .",-,, .. *n*

-C . : . C ....... .ip=,ac.

or e-DMRs PARAMETER., . - .. -. (irgci)! ;. MgICn' .-*: L!_M.thatl El P-chloro-m-cresol None

[] 2-chlorophenol 95578 0l 2,4-dichlorophenol 120832 0l 2,4-dimethylphenol 105679 0l 4,6-dinitro-o-cresol 534521 0l 2,4-dinitrophenol 51285 El 2-nitrophenol 88755 0l 4-nitrophenol 100027 0l Pentachlorophenol 87865 0l Phenol 108952 0l 2,4,6-trchlorophenol 88062 BASE-NEUTRAL COMPOUNDS 0l Acenaphthene 83329 0l Acenaphthylene 208968

[] Anthracene 120127 El Benzidine 92875 El Benzo(a)anthracene 56553 El Benzo(a)pyrene 50328 El 3,4 benzofluoranthene 205992 El Benzo(ghi) perylene 191242 El Benzo(k)fluoranthene 207089 El Bis (2-chloroethoxy) methane 111911 El Bis (2-chloroethyl) ether 111444 El Bis (2-chloroiso-propyl) ether 108601 El Bis (2-ethylhexyl) phthalate 117817 El 4-bromophenyl phenyl ether 101553 El Butyl benzyl phthalate 85687 El 2-chloronaphthalene 91587 El 4-chlorophenylphenyl ether 7005723 11 EQP 4659-B (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division

__WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II - Sanitary Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER NA NA Submitted SAMPLE DATE 4 via DMRs :"**' *:::'°."':::";;i;::':"::*** 'CSr-:* *,iCOnC*',i "ConcA* *Conc* *C'ond* *.Sample . 'riaiytical*

o] Chrysene 218019 o] Oi-n-butyl phthalate 84742 vl Di-n-octyl phthalate 117840 El Dibenzo(a,h) anthracene 53703 o] 1,2-dichlorobenzene 95501 o 1,3-dichlorobenzene 541731

1,4-dichlorobenzene 106467 El 3,3-dichlorobenzidine 91941 0- Diethyl Phthalate 84662 El Dimethyl Phthalate 131113 El 2,4-dinitrotoluene 121142 El 2,6-dinitrotoluene 606201 El 1,2-diphenylhydrazine 122667 El Fluoranthene 206440 0- Fluorene 86737 El Hexachlorobenzene 118741 El Hexachlorobutadiene 87683 El Hexachlorocyclopentadiene 77474 El Hexachloroethane 67721 El Indeno(1,2,3-cd) pyrene 193395 El Isophorone 78591 El Naphthalene 91203 El Nitrobenzene 98953 El N-nitrosodi-n-propylamine None El N-nitrosodimethylamine 62759 El N-nitrosodiphenylamine 86306 El Phenanthrene 85018 Pyrene Na 129000 C1 1,2,4-trichlorobenzene 120821 12 EQP 4659-B (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II- Sanitary Wastewater C. Collection System Information PLASELITYP ORARMN PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER NA NA COMBINED SEWER SYSTEM INFORMATION Complete this item if there are outfalls at the treatment facility or along the combined sewer collection system from which discharges of untreated or partially-treated wastewater occur. Update the information in items A, B, and C below if it has changed since the last Application submission.

A. Estimate the percentage of the collection system that is combined: %

B. System Map. Provide a map that shows all Combined Sewer Outfall discharge points.

C. System Diagram. Provide a diagram, in the above map or on a separate drawing, of the combined sewer collection system. Include the locations of major trunk line sewers, both combined and separate sanitary; the locations of points where separate sanitary sewers feed into the combined sewer system; the locations of in-line and off-line storage structures; locations of flow regulating devices, and the locations of pump stations.

2. COMBINED SEWER OUTFALL INFORMATION Identify the outfall(s) from your current permit by number (e.g., 001, 002). Provide the current status of the outfall (i.e. active, inactive, bulk headed, removed) and indicate if continued authorization is required. Attach specific outfall location and discharge information for all outfalls not previously identified.

Outfall Numbe o n us~o of~

El Yes E3 No 0 Yes E] No 0 Yes El No El Yes El No 0 Yes F1 No 0 Yes El No 0 Yes [I No E Yes 0 No EYes ENo EYes ENo EYes ENo 0 Yes [I No EYes ENo El Yes El No El Yes CE No 0 Yes El No El Yes El No EYes ENo rE Yes ENo E3 Yes El No 0] Yes [] No 13 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION II - Sanitary Wastewater D. Nondomestic Wastewater Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER NAI NA

1. SEPTAGE - Does this facility accept septage?

C3 Yes. On a separate sheet, describe the allocation of the Maximum Allowable Headworks Loading (MAHL) capacity to domestic wastewater, nondomestic wastewater, and septage. The MAHL should include the treatment plant's design and current loading and, at a minimum, the number of gallons and concentrations of the pollutants BOD, TSS, P0 4 , and NH 3 that are attributable to each wastewater.

C] No. Continue with Item 2.

2. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) WASTEWATER Does this facility receive, or has it in the last three (3) years received, RCRA hazardous waste by truck, rail, or dedicated pipe?

El Yes. Provide the following information on a separate sheet: The method by which the waste is received (e.g., truck, rail, or dedicated pipe), the waste's "EPA Hazardous Waste Number," and the amount of waste received in either mass or volume.

El No. Continue with Item 3.

3. REMEDIATION WASTEWATER Does this facility receive, or has it been notified that it will receive in the next five (5) years, wastes from remedial activities?

0 Yes. Provide a list on a separate sheet that contains the following information for each current and future remediation site:

1) Describe the site and type of facility at which the CERCLA/RCRA or other remedial waste originates or will originate.

2) List the hazardous constituents that are, or are expected to be, received at the POTW. Include data on volume and concentration, if known.

3) Describe in detail any treatment the waste receives before being discharged to the POTW.

4) Provide the schedule for when the remediation wastewater is discharged to the POTW.

El No. Continue with Item 4.

4. INDUSTRIAL AND COMMERCIAL SOURCES A. Does this facility receive any nondomestic wastewater from any industrial or commercial facilities? (Nondomestic wastewater refers to water that carries wastes other than human and household wastes.)

El Yes. Continue with Item B.

0l No. Go to Part E. Biosolids Information.

B. Provide the following information:

1) Estimate the average volume of nondomestic wastewater received by this facility: __ MGD

2) Describe the type of nondomestic wastewater(s) received by this facility in the space provided below.

Wastewater Type Volume (MGD) Wastewater Type Volume (MGD)

Cl Industrial Process Wastewater El Landfill Leachate El Contact Cooling Water C] Trucked Industrial Wastewater El Noncontact Cooling Water _E Other: __

C. Is an Industrial Pretreatment Program (IPP) currently required by the DEQ? Note: Applicants with an IPP are required to also complete Item 5 on Page 15.

El Yes. Provide the most recent approval date for the following elements of the program:

Sewer Use Ordinance Interjurisdictional Agreements Procedures Other Legal Authority - Enforcement Response Plan Local Limits ElNo.

14 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION lI -,Sanitary Wastewater D. Nondomestic Wastewater Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER NA NA

5. SIGNIFICANT INDUSTRIAL USER (SIU) INFORMATION Supply the following information for each SIU that discharges to the treatment plant. Make additional copies of this page when necessary.

A. SIU location information Company Facility Address City State ZIP Code B. Describe all of the industrial processes that affect or contribute to the SIU's discharge.

C. Describe all of the principal processes and raw materials that affect or contribute to the SIU's discharge.

D. Flow Rate. What are the average daily volume(s) of wastewater discharged to the collection system? Are the discharge(s) continuous or intermittent?

Type of Wastewater Volume of Discharge (GPD) Continuous or Intermittent Process Wastewater Non-Process Wastewater E. Pretreatment Standards. Indicate whether the SIU is subject to one or both of the following:

El Local Limits El Categorical Pretreatment Standards. Category _ Subcategory __

Category - Subcategory __

F. Describe any problems at the treatment plant or in the collection system (e.g., upsets, pass through, interference, blockages) attributed to waste or wastewater discharged by this SIU during the last three years.

15 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION-SECTION II- Sanitary Wastewater E. Biosolids Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER NA NA

1. BIOSOLIDS HANDLING - All facilities that generate or propose to generate biosolids must complete Items 1. and 2.

Provide total English dry tons per 365-day period of residuals handled under the following practices:

Amount generated at the facility: Amount sent to municipal solid waste landfill:

Amount received from off-site: Amount sold or given away in a bag or other container for application to the land:

Amount treated on-site (including blending):

Amount transported to another POTW:

Amount used or disposed of by another practice: __

Transport Company:

Amount applied to land in bulk form:

Receiving POTW: __

Amount fired in incinerator:

BIOSOLIDS STORAGE Enter the volume of residual storage capacity at this facility: El million gallons or 0] cubic feet

2. LAND APPLICATION - Facilities that land apply must complete Items A. - D., or have submitted a Biosolids Annual Report as required in the facility's current Residual Monitoring Program. Latest Biosolids Annual Report submitted on __

A. BIOSOLIDS CHARACTERISTICS - New Land Appliers Only Report one year of residuals monitoring data and in no case less than three (3) sampling events for the following parameters. Provide the actual analytical data sheets as an attachment. Analytical methods shall be in accordance with Rule 323.2406 (2) "Methods for Biosolids."

J" Parameter Moynthly ......... uat flctri-

'*~~~ ConentrtI~n

-. - M',

'~ - nal .i ILevel,*

El Grab Copoit Total Solids %

[] Composite El El Grab Composite Total Arsenic mg/kg Total Cadmium mg/kg El Grab

[] Composite Total Copper mg/kg El Grab

[ Composite Total Lead mg/kg El Grab E Composite T a Grab Total Mercury mg/kg E CompositeG Ell CompositeG Grab Total Molybdenum mg/kg Total Nickel mg/kg El Grab Composite

]l Grab Total Selenium mg/kg El Composite Total Zinc mg/kg Ell[Composite Grab El Grab Total Kjeldahl Nitrogen mg/kg El Composite Ell Grab Composite Ammonium Nitrogen mg/kg E] Grab Total Phosphorus mg/kg l CompositeG El Grab Total Potassium mg/kg l CompositeG 16 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division

.. WASTEWATER DISCHARGE PERMIT-APPLICATION-SECTION II- Sanitary Wastewater E. Biosolids Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER NA NA B. POLLUTANTS OF CONCERN Are there currently, or is there potential for, pollutants (other than the parameters listed on the previous page) to be present in the residuals at concentrations that would make them unsuitable for land application?

E] Yes. On a separate sheet, provide representative analytical data for those pollutants.

0l No. Continue with Item C.

C. ADDITIONAL BIOSOLIDS MONITORING DATA Report any biosolids monitoring data from the last permit cycle for parameters not specifically listed on the previous page. Include the actual analytical data sheets as an attachment. Upon submittal review, additional monitoring may be required if the Water Resources Division has reason(s) to suspect that the information provided (or not provided) does not adequately characterize the residuals proposed to be land applied.

For assistance with completing this item, contact the Permits Section. To submit additional information, see Page ii, Item 3.

Pa~r net 1 $, Maxim umVI- its tiArna 60_ni,

_Mth to.

El Grab

[] Composite El Grab El Composite El Grab El Composite El Grab El Composite El Grab El Composite El Grab El Composite El Grab El Composite D. LAND APPLICATION SITE LIST Provide the following information for every new or existing site that may be used in the next five years (biosolids permit cycle). Each listed site should have been submitted to the DEQ on a Site Identification Form (with attachments) since January 1, 1998, or the required information should be included with this form. Additional sites may be added to the Land Application Site List during the biosolids permit cycle by submitting a completed Site Identification Form with the appropriate attachments and waiting the required ten-day notification period. To submit additional information, see Page ii, Item 3.

El El El El El El El El This completesSection II. Return the completed Application (Sections I, II, IV, and any attachments) to one of the addresses on Page ii of this Application. If assistance is needed to complete this Application, contact the Permits Section.

17 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division

-- WASTEWATER-DISGHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater Section III is to be completed by all facilities classified as Industrial or Commercial facilities. Industrial and Commercial facilities include, but are not limited to, facilities that discharge or propose to discharge a wastewater generated by a production process, a service provided, or through a remediation project. Municipal and public facilities are not required to complete Section III (unless requesting authorization for discharges other than sanitary wastewater).

A. Facility Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER Entergy Nuclear Palisades, LLC; MI 0001457

1. BUSINESS INFORMATION A. Provide up to four Standard Industrial Classification (SIC) or North American Industry Classification System (NAICS) codes, in order of economic importance, which best describe the major products or services provided by this facility 1.4911 2. 3. 4.

B. Indicate if this facility is a primary industry (refer to Table 1 of the Appendix to determine if this facility is a primary industry).

Z Yes. This facility is a primary industry. Indicate the primary industry as identified in Table 1 of the Appendix: Steam Electric Power E5 No. This facility is not a primary industry.

2. WATER SUPPLY AND DISCHARGE TYPE A. Identify all water sources entering the facility and treatment systems, and provide average flows. The volume may be estimated from water supply meter readings, pump capacities, etc. Provide the name of the source where appropriate (i.e., Grand River, Lake Michigan, City of, Millpond). To submit additional information, see Page ii, Item 3.

Name and Location of Source Average Volume or Flow Rate Units Municipal Supply South Haven Municipal 0.018 MGD Surface Water Intake Lake Michigan 141.12 MGD Private Well Other:

B. Identify water discharged by the facility and treatment systems, and provide average flows. If water is first used for one purpose and then is subsequently used for another purpose, indicate the type and amount of the last use. For example, if water is initially used for noncontact cooling water and then for process water, indicate the amount of process water. The amount of water from sources should approximate the amount of water usage. If the amounts are different, provide an explanation.

Average Flow Rate Units Average Flow Rate Units Process Wastewater 0.062 MGD Sanitary Wastewater 0.018 MGD Contact Cooling Water NA Regulated Storm Water unspecified MGD Noncontact Cooling Water 116.77 MGD High Pressure Test Water NA Groundwater Cleanup NA Other: NA Note: For A. and B. above, indicate units as MGD (million gallons per day), MGY (million gallons per year), GPD (gallons per day), or other appropriate unit.

1 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION.

SECTION III - Industrial and Commercial Wastewater B. Outfall Information Complete a separate Section III.B. - Outfall Information (Pages 19 - 24) for each outfall at the facility. Make copies of this blank section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457I 000-intake

1. OUTFALL INFORMATION. Instructions for this item are on Page 3 of the Appendix.

Receiving Water Hydrologic Unit Code Lake Michigan 0405002 County Township Van Buren Covert Town Range 04 Section 1/4, 14 1/4 Private (French) Land Claim 02S17V0NWS Latitude Longitude 42 19' 31" 86 19'41" Type of Wastewater Discharged (check all that apply to this outfall):

El Contact Cooling E] Groundwater Cleanup C3 Hydrostatic Pressure Test El Noncontact Cooling Water C1 Process Wastewater E] Sanitary Wastewater [I Storm Water - not regulated E] Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

0 Others (see Table 8 - Other Common Types of Wastewater on Page 17 in the Appendix) Plant Intake The Maximum Design Flow Rate for this outfall is: NA-intake MGD What is the Maximum Authorized Daily Discharge Seasonal Dischargers NA MGY (Continue with Item H.)

Flow for this outfall for the next five years? Continuous Dischargers N.A MGD (Continue with Item I.)

Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

From Through Actual Discharge Volume (MGD) Annual Total NA NA NA From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

Continuous Discharge:

How often is there a discharge from this outfall (on average)? NA Hours/Day __ Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization? 0l Yes Cl No Batch Peak Flow Rate: __ Number of batches discharged per day:

Minimum Average Maximum Batch Volume (gallons) NA Batch Duration (minutes) 2 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division

---WASTEWATER- DISCHARGE- PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457 000-intake

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is on Page 11 in the 'Summary of Information to be reported by Industry Type' section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility.

Facilities with production-based limits must report an estimated annual production rate for the next five (5) years or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A. Name of the process contributing to the discharge: NA-intake B. SIC or NAICS code:

C. Describe the process and provide measures of production:

PROCESS INFORMATION A. Name of the process contributing to the discharge:

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

PROCESS INFORMATION A. Name of the process contributing to the discharge: __

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

PROCESS INFORMATION A. Name of the process contributing to the discharge: __

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

PROCESS INFORMATION A. Name of the process contributing to the discharge: __

B. SIC or NAICS code:

C. Describe the process and provide measures of production:

3 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater

I *A* -Ir'%J* i*.* *lKI=T" B. Outfall Information r-"Lr-POr- I rT V.i r-rI'l FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457 000-intake

3. EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS. Instructions for this item are on Page 4 of the Appendix.

Cl Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichiacoi or Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The DEQ will use the indicator selected below in the permit issued based on this Application. El Use Escherichiacoli as an indicator of disinfection. C3 Use Fecal Coliform Bacteria as an indicator of disinfection.

Submitted ;A, w th6 .- . ........ .~ 11 , ..~

" ,. ; .~ .........

~ * ,,,,

4, Maximum,, :=, *Maximum,1 .:--,*-** ,..= ,* ,,...:i:,.-...;. :.** me!,

i -- ...... .... .. .... . ,. . .., . o n u . . DM a il m i .... *

- I'-*'

+ *,*" "'*=."*:* * =*, "!*'#-*i* -4L *". , ': ,'"'*'""" I ""

X41-V - ~

El Grab '

NA-intake Biochemical Oxygen Demand - five day (BOD 5) mg/I El 2r C El 24-Hr Comp El Grab NA-intake Chemical Oxygen Demand (COD) mg/I El 2r C C1 24-Hr Comp mg/I El Grab El 24-Hr Comp NA-intake Total Organic Carbon (TOC)

El Grab

NA-intake Ammonia Nitrogen (as N) mg/I El 24-Hr Comp NA-intake Total Suspended Solids mg/I El 2r p El 24-Hr Comp Waiver Request Not Required Total Dissolved Solids mg/I l Grab I El 24-Hr a omp Waiver Request Not Required Total Phosphorus (as P) mg/I El Grab Wv24-Hr Comp Waiver Request Not Required Fecal Coliform Bacteria (report geometric means) Maximum 7-day counts/100ml Grab Waiver Request Not Required Escherichiaooli (report geometric means) Maximum 7-day counts/1 00 ml Grab I

Waiver Request Not Required Total Residual Chlorine El mg/I Grab El Pg/I _____

Waiver Request Not Required Dissolved Oxygen Minimum Daily mg/I Grab Minimum Maximum NA-intake pH (report maximum and minimum of individual samples) standard units Grab Temperature, Summer 70.4 78.1 Z OF El °C 276 Grab, I

Temperature, Winter 43.0 47.2 ] OF EO°C 360 Grab Wa~ivpr Rpnij.ut Not Rpntuired Oil A rr . mall Gra6

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457I 000-intake Note: For questions on this page, Tables 1 - 5 are found in the Appendix.

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary Industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New primary industries that propose to discharge process wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

5. DIOXIN AND FURAN CONGENER INFORMATION Existing industries that use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid, (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, are required to submit the results of at least one effluent analysis for the dioxin and furan congeners listed in Table 6. All effluent analyses for dioxin and furan congeners shall be conducted using USEPA Method 1613.

In addition, submit the results of all other effluent analyses performed within the last three years for any dioxin and furan congener listed in Table 6.

New industries that expect to use or manufacture 2,3,5-trichlorophenoxy acetic acid (2,4,5-T); 2-(2,3,5-trichlorophenoxy) propanoic acid (Silvex, 2,3,5-TP); 2-(2,4,5-trichlorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothionate (Ronnel);

2,4,5-trichlorophenol (TCP); or hexachlorophrene (HCP), or knows or has reason to believe that 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is present in the facility's effluent, shall provide estimated effluent concentrations for the dioxin and furan congeners listed in Table 6.

6. OTHER INDUSTRY PRIORITY POLLUTANT INFORMATION Existing secondary industries or existing primary industries that discharge nonprocess wastewater are required to submit the results of at least one effluent analysis for any chemical listed in Tables 2 and 3 known or believed to be present in the facility's effluent.

In addition, submit the results of all other effluent analyses performed within the last three years for any chemical listed in Tables 2 and 3.

New secondary industries or new primary industries that propose to discharge nonprocess wastewater are required to provide an estimated effluent concentration for any chemical listed in Tables 2 and 3 expected to be present in the facility's effluent.

7. ADDITIONAL TOXIC AND OTHER POLLUTANT INFORMATION All existing industries, regardless of discharge type, are required to provide the results of at least one analysis for any chemical listed in Table 4 known or believed to be present in the facility's effluent, and a measured or estimated effluent concentration for any chemical listed in Table 5 known or believed to be present in the facility's effluent. In addition, submit the results of any effluent analysis performed within the last three years for any chemical listed in Tables 4 and 5.

New industries, regardless of discharge type, are required to provide an estimated effluent concentration for any chemical listed in Tables 4 and 5 expected to be present in the facility's effluent.

8. INJURIOUS CHEMICALS NOT PREVIOUSLY REPORTED New or existing industries, regardless of discharge type, are required to provide a measured or estimated effluent concentration for any toxic or otherwise injurious chemicals known or believed to be present in the facility's effluent that have not been previously identified in this Application.

Quantitative effluent data for these chemicals that is less than five years old shall be reported.

NOTE: All effluent data submitted in response to questions 4, 5, 6, 7, and 8 above should be recorded on Page 23. To submit additional information, see Page ii, Item 3. If the effluent concentrations are estimated, place an "E" in the "Analytical Method" column. The following fields shall be completed for each data row: Parameter, CAS No., Concentration(s), Sample Type, and Analytical Method. For analytical test requirements, see Page ii, Item 5. Tables 1, 2, and 3 can be found in the Appendix.

If Alternate Test Procedures have been approved for any parameter listed above (Items 4. through 8.), see Page ii, Item 5. for additional instructions.

5 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division

. WASTEWATER-DISCHARGE-PERMIT APP-LICATION---

SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Palisades Nuclear Power Plant M10001457 000-Intake Submitted SAMPLE DATE 4 03/25/13 - ,

via *~.......

DM.. *,... ... CAS4.F R.. on Con C Analytical,.

or e-DMRs PARAMETER4' .. ..... 7PC Conl~- (lgI)

Ca- Tpleý a ~Mt

. . . - ,.___.__O ,_ ( g!) , ( ) iii !( I ' Method "

El Total Antimony 07440-36-0 nd grab EPA200.8 El Total Arsenic 07440-38-2 nd grab EPA200.8 o Total Beryllium 07440-41-7 nd grab EPA200.8 El Total Cadmium 07440-47-3 nd grab EPA200.8 o1 Total Chromium 07440-47-3 1 grab EPA200.8 o1 Total Copper 07550-50-8 1 grab EPA200.8 El Total Lead 07439-92-1 nd grab EPA200.8 El Total Mercury 07439-97-6 0.000517 grab EPA1631E o1 Total Nickel 07440-02-0 2 grab EPA200.8 El Total Selenium 07782-49-2 nd grab EPA200.8 El Total Silver 07440-22-4 nd grab EPA200.8 El Total Thallium 07440-28-0 nd grab EPA200.8 El Total Zinc 07440-66-6 nd grab EPA200.8 El Total Cyanide 00057-112-5 nd grab OIA1677

[] Total Phenols nd grab EPA420.1 El El El El El El El E]

El El El El 6 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERM.ITAPPLICATION.

SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Palisades Nuclear Power Plant MIOO01457 000-Intake Submitted SAMPLE DATE 4 03/25/13 ..

via DMRs ~cn ~ ~~~~c oncs bc7~ ap i -

nalyt ca or e-DMRs PARAMETER;Vriqý~~O~~)k,~(li~l~ ~ uh)K~ ui)K ~ Y~t #

01 2-Chlorophenol 00095-57-8 nd grab EPA 625 0l Phenol 00108-95-2 nd grab EPA 625

[] 2-nitrophenol 00088-75-5 nd grab EPA 625 o 2,4-dimethylphenol 000105-67-9 nd grab EPA 625 El 2,4-dichlorophenol 00120-83-2 nd grab EPA 625 El 2,4,6-trichlorophenol 00088-06-2 nd grab EPA 625 El 4-nitrophenol 00100-02-7 nd grab EPA 625 E] 2,4-dinitrophenol 00051-28-5 nd grab EPA 625 El Pentachlorophenol 00087-86-5 nd grab EPA 625 El 4,6-Dinitro-O-Cresol 00534-52-1 nd grab EPA 625 El p-Chloro-m-Cresol 00059-50-7 nd grab EPA 625

[] 3,4-Benzofluoranthene 00205-99-2 nd grab EPA 625 El Chlorodibromomethane 00124-48-1 nd grab EPA 624 El Methyl Bromide 00074-83-9 nd grab EPA 624 El Methyl Chloride 00074-87-3 nd grab EPA 624 El El El El El El El El El El El El 6 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT_-APPLICATIQN..

SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Palisades Nuclear Power Plant M10001457 000 Submitted SAMPLE DATE 4 03/25/13 . , . .

CS ~~ n ~ c~- Con. co ..i.brd: ,Sopleý.

,A*fi.a._yt.id.a:...

via DMRs or e-DMRs PARAMETER: , Co.. Conc4;, Conc-k iipI. AIyticlI

- Acenaphthene 00083-32-9 nd grab EPA 625 Cr Acenaphthylene 00208-96-8 nd grab EPA 625 C1 Anthracene 00120-12-7 nd grab EPA 625 C] Benzidine 00092-87-5 nd grab EPA 625 C1 Benzo(a)anthracene 00056-55-3 nd grab EPA 625 0 Benzo(a)pyrene 00050-32-8 nd grab EPA 625 C1 Benzo(ghi)perylene 00191-24-2 nd grab EPA 625 C1 Benzo(k)fluoranthene 00207-08-9 nd grab EPA 625 C] Bis(2-chloroethoxy)methane 00111-91-1 nd grab EPA 625 C1 Bis(2-chloroethyl)ether 00111-44-4 nd grab EPA 625 C1 Bis(2-ethylhexyl)phthalate 00117-81-7 nd grab EPA 625 C 4-Bromophyenyl phenyl ether 00101-55-3 nd grab EPA 625 C[ Butyl benzyl phthalate 00085-68-7 nd grab EPA 625 C 2-Chloronaphthalene u 00091-58-7 nd grab EPA 625 0 4-Chlorophenyl phenyl ether 07005-72-3 nd grab EPA 625 0 Chrysene 00218-01-9 nd grab EPA 625 C1 Dibenzo(a,h)anthracene 00053-70-3 nd grab EPA 625 C 3,3-Dichlorobenzidine 00091-94-4 nd grab EPA 625 Cl 1,4-Dichlorobenzene 00106-46-7 nd grab EPA 625 C Diethyl

, phthalate 00084-74-2 nd grab EPA 625 C Dimethyl phthalate 00113-11-3 nd grab EPA 625 C Di-n-butyl phthalate 00084-74-2 nd grab EPA 625 C 2,4-Dinitrotoluene 00121-14-2 nd grab EPA 625 C1 2,6-Dinitrotoluene 00606-20-2 nd grab EPA 625 C] Di-n-octyl phthalate 00117-84-0 nd grab EPA 625 C Bis(2-chloroisopropyl)ether 39638-32-9 nd grab EPA 625 C3 6 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division

.. WASTEWATER-DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Palisades Nuclear Power Plant M10001457 000-intake Submitted SAMPLE DATE 4 03/25/13 _..__________..-,___......__-.

viaeDMRs P RM T R . .. ........ ...... " . (.ig. .-. g/ . N0/gl aT e i M to El Azobenzene 00122-66-7 nd grab EPA 625 13 Fluoranthene 00206-44-0 nd grab EPA 625 El Fluorene 00086-73-7 nd grab EPA 625 0] Hexachlorobenzene 00118-71-1 nd grab EPA 625 C1 Hexachlorobutadiene 00087-68-3 nd grab EPA 625

[] Hexachlorocyclopentadiene 00077-47-4 nd grab EPA 625 El Hexachloroethane 00067-72-1 nd grab EPA 625 El Indeno(1,2,3-cd)pyrene 00193-39-5 nd grab EPA 625 El Isophorone 00078-59-1 nd grab EPA 625 C3 Nitrobenzene 00098-95-3 nd grab EPA 625 El N-nitrosodimethylamine 00062-75-9 nd grab EPA 625 13 N-nitrosodi-n-propylamine 00621-64-7 nd grab EPA 625 El N-nitrosodiphenylamine 00086-30-6 nd grab EPA 625 El Phenanthrene 00085-01-8 nd grab EPA 625 El Pyrene 00129-00-0 nd grab EPA 625 C3 Naphthalene 00091-20-3 nd grab EPA 625 El 1,2,4-Trichlorobenzene 00120-82-1 nd grab EPA 625 El 1,2-Dichlorobenzene 00095-50-1 nd grab EPA 625 El 1,3-Dichlorobenzene 00541-73-1 nd grab EPA 625 El El El El El 6 EQP 4659-C (Rev. 1/2013)

--- Michigan Department-of Environmental-Quality - Water Resources Division -------- -

WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457 000-intake

9. WATER TREATMENT ADDITIVES Water treatment additives include any material that is added to water used at the facility or to wastewater generated by the facility to condition or treat the water.

Approvals of water treatment additives are authorized by the DEQ under separate correspondence. The issuance of an NPDES permit does not constitute approval of the water treatment additives that are included in this Application.

A. Are there water treatment additives in the discharge from this facility?

0 Yes.

El No. Proceed to Item 10.

B. Have these water treatment additives been previously approved?

0 Yes. Submit a list of the previously-approved water treatment additives and the date on which they were approved. The information listed in Item C., Items 1. - 8. shall be updated if it has changed since the previous approval.

E] No. Continue with Item C.

C. Submit a list of water treatment additives that are or may be discharged from the facility. Applicants are required to submit the information listed below for each additive.

1. The water treatment additive Material Safety Data Sheet

2. The proposed water treatment additive discharge concentration

3. The discharge frequency (i.e., number of hours per day, week)

4. The outfall from which the water treatment additive is to be discharged

5. The type of removal treatment, if any, that the water treatment additive receives prior to discharge

6. The water treatment additive function (i.e., microbiocide, flocculant)

7. A 48-hour LC50 or EC50 for a North American freshwater planktonic crustacean (either Ceriodaphniasp., Daphniasp., or Simocephalus sp.)

8. The results of a toxicity test for one other North American freshwater aquatic species (other than a planktonic crustacean) that meets a minimum requirement of Rule 323.1057(2)(a) of the Water Quality Standards. Examples of tests that would meet this requirement include a 96-hour LC50 for rainbow trout, bluegill, or fathead minnow.

The required toxicity information (described in Items 7. and 8. above) is currently available in the Water Resource Division's files for the water treatment additives listed on the DEQ's Internet page. To access that information, go to http://www.michigan.gov/deq, click on Site Map, at the bottom of the right column under Water Quality Monitoring, click on Assessment of Michigan Waters. Under the Information heading, click on the Water Treatment Additive List. If you intend to use one of the water treatment additives on this list, only the information in Items 1. through 6. above needs to be submitted to the Water Resources Division. Note: The availability of toxicity information for a water treatment additive does not constitute approval to discharge the water treatment additive. Comments:

10. WHOLE EFFLUENT TOXICITY (WET) TESTS Have any acute or chronic WET tests been conducted on any discharges or receiving water(s) in relation to facility discharges within the last three (3) years?

If yes, identify the tests and summarize the results on a separate sheet, unless the test has been submitted to the DEQ in the last three (3) years. For assistance with WET testing, see "Whole Effluent Toxicity Test Guidance and Requirements" on Page 17 in the Appendix. Comments:

This completesSection III. Return the completed Application (Sections 1, Ill, IV, Vi [if applicable], and any attachments) to one of the addresses on Page ii of this Application. If assistance is needed to complete this Application, contact the Permits Section.

7 EQP 4659-C (Rev. 1/2(

Michigan Department of Environmental Quality - Water Resources Division

....- WASTEWATER-DISCHARGE- PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information Complete a separate Section III.B. - Outfall Information (Pages 19 - 24) for each outfall at the facility. Make copies of this blank section of the Application as necessary for additional outfalls.

PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457 001A

1. OUTFALL INFORMATION. Instructions for this item are on Page 3 of the Appendix.

Hydrologic Unit Code A. Receiving Water Lake Michigan 0405002 B. County Township Van Buren Covert Town Range Section 1/4 14, 1 Private (French) Land Claim 02S 17W 05 NW SE D. Latitude Longitude 42 19'31" 86 19'41" E. Type of Wastewater Discharged (check all that apply to this outfall):

0 Contact Cooling C] Groundwater Cleanup 0] Hydrostatic Pressure Test 0 Noncontact Cooling Water 0 Process Wastewater -] Sanitary Wastewater El Storm Water - not regulated 0 Storm Water - regulated El Storm water subject to effluent guidelines (indicate under which category):

El Others (see Table 8 - Other Common Types of Wastewater on Page 17 in the Appendix)

F. The Maximum Design Flow Rate for this outfall is: 135.2 MGD G What is the Maximum Authorized Daily Discharge Seasonal Dischargers N._AMGY (Continue with Item H.)

Flow for this outfall for the next five years? Continuous Dischargers 135.2 MGD (Continue with Item I.)

H. Seasonal Discharge:

List the discharge periods (by month) and the volume discharged in the space provided below.

From Through Actual Discharge Volume (MGD) Annual Total NA NA NA From Through Actual Discharge Volume (MGD)

From Through Actual Discharge Volume (MGD)

1. Continuous Discharge:

How often is there a discharge from this outfall (on average)? 24 Hours/Day 365 Days/Year Batch dischargers are required to provide the following additional information:

Is there effluent flow equalization? C3 Yes El No Batch Peak Flow Rate: __ Number of batches discharged per day: __

Minimum Average Maximum Batch Volume (gallons) NA Batch Duration (minutes) 2 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER- DISCHARGE PERMIT-APPLICATION ---

SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457 000 INTAKE Submitted SAMPLE DATE 4 03/25/13 via DMRs : .-"**Ion.- IMCt9*a*..,- Cicr&. Cbnc*. . S m 6rA:. Anala ore-DMRs PAA~T "S _' IplI ii)$ j~~).~T ehd&

El Acrolein 00107-02-8 nd grab EPA 624 El Acrylonitrile 00107-13-1 nd grab EPA 624 C1 Benzene 00107-43-2 nd grab EPA 624 El Bromoform 00075-25-2 nd grab EPA 624 El Carbon tetrachloride 00056-23-5 nd grab EPA 624 El Chlorobenzene 00108-90-7 nd grab EPA 624

[] Chloroethane 00075-00-3 nd grab EPA 624 El 2-chloro-ethylvinyl ether 00110-75-8 nd grab EPA 624 El Chloroform 00067-66-3 nd grab EPA 624 El Dichlorobromomethane 00075-27-4 nd grab EPA 624 El 1 1-dichloroethane 00075-34-3 nd grab EPA 624 El 1,2-dichloroethane 00107-06-2 nd grab EPA 624 El Trans-1,2-dichloroethene 00156-60-5 nd grab EPA 624 El 1,1-dichloroethene 00075-35-4 nd grab EPA 624 El 1,2-dichloropropane 00078-87-5 nd grab EPA 624 El 1,3-dichloropropene 00542-75-6 nd grab EPA 624 El Ethylbenzene 00100-41-4 nd grab EPA 624 El Methylene chloride 00075-09-2 nd grab EPA 624 El 1,1,2,2-tetrachloroethane 00079-34-5 nd grab EPA 624 El Tetrachloroethene 00127-18-4 nd grab EPA 624 El Toluene 00108-88-3 nd grab EPA 624 El 1,1,1-trichloroethane 00071-55-6 nd grab EPA 624 El 1,1,2-trichloroethane 00079-00-5 nd grab EPA 624 El Trichloroethene 00079-01-6 nd grab EPA 624 El Vinyl chloride 00075-01-4 nd grab EPA 624 El El 23 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457 001A

2. PROCESS STREAMS CONTRIBUTING TO OUTFALL DISCHARGE Federal regulations require that different industries report different information, depending on the type of facility. The information below is used to determine the applicable federal regulations for this facility. An abbreviated list is on Page 11 in the 'Summary of Information to be reported by Industry Type' section of the Appendix. Applicants are required to provide the name and the SIC or the NAICS code for each process at the facility.

Facilities with production-based limits must report an estimated annual production rate for the next five (5) years or the life of the permit. If the wastestream is not regulated under federal categorical standards, the applicant is required to report all pollutants which have the reasonable potential to be present in the discharge. To submit additional information, see Page ii, Item 3.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Cooling Tower Blowdown B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

The cooling towers typically provide cooled water to the condenser. A portion of the noncontact cooling water flow rate is discharged directly to the mixing basin where flow is recorded and reported during discharge.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Treated Misc Low Volume Wastewater B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Waste consist of steam generator blowdown, demineralizer backwash, reverse osmosis filter backwash,turbine sump drainage, floor drains, laboratory waste, and radwaste wastewater.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Radwaste Wastewater (Outfall 001D)

B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

This process removes suspended solids and radioactivity by collection and then processing through a demineralizer prior to discharge at outfall 001 D. See flow diagram.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Turbine Sump Drainage (Outfall 001 F B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

The turbine sump collects filtered floor drainage from the turbine building which is treated by a oil/water sererator prior to discharge to outfall 001F. See flow diagram.

PROCESS INFORMATION A. Name of the process contributing to the discharge: Floor Drainage B. SIC or NAICS code: 4911 C. Describe the process and provide measures of production:

Floor drainage from plant secondary systems is drained to the turbine sump. Auxiliary building floor drains are processed through the radwaste system eventually discharging to outfall 001D. See flow diagram.

3 EQP 4659-C (Rev. 1/2013)

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457 001A

3. EFFLUENT CHARACTERISTICS - CONVENTIONAL POLLUTANTS. Instructions for this item are on Page 4 of the Appendix.

E0 Check this box if additional information is included as an attachment. To submit additional information, see Page ii, Item 3.

Please Note: Rule 323.1062 allows the use of either Escherichiacollor Fecal Coliform Bacteria as an indicator that effluent has been disinfected. The DEQ will use the indicator selected below in the permit issued based on this Application. El Use Escherichiacoil as an indicator of disinfection. El Use Fecal Coliform Bacteria as an indicator of disinfection.

Submitted ' Z-. , , , . .! 4 -"'* MaximumMaximum. Number via DMRs Mon',".. Maximum.. :eg. .:

oe-DMRs, 2~~a#~, _A ~ ~ ~ .~cocnrto Coenrto units ~ .nalyse '-.$Mp q Type o Request Waiver, no source addition Biochemical Oxygen Demand - five day (BODs) mg/I El Grab

[o 24-Hr Comp Chemical Oxygen Demand (COD) mg/I 2rab G]

El Request Waiver, no source addition []24-Hr Comp El Grab o Request Waiver, no source addition Total Organic Carbon (TOC) mg/I El 24-Hr Comp Ammonia Nitrogen (as N) mg/I El Grab El Request Waiver, no source addition

[o 24-Hr Comp Request Waiver, applied internally at T-i1 Grab source as treatment technology [T 24-Hr Comp El Waiver Request Not Required Total Dissolved Solids mg/I El Grab C] 24-Hr Coomp El Waiver Request Not Required Total Phosphorus (as P) mg/I El[]24-Hr Grab i Comp El Waiver Request Not Required Fecal Coliform Bacteria (report geometric means) Maximum 7-day counts/100ml Grab El Waiver Request Not Required Escherichiacoil (report geometric means) Maximum 7-day counts/100 ml Grab 0 Waiver Request Not Required Total Residual Chlorine 177 177 El Vg/I Z] mg/I 119Ga 1199 Grab Minimum Daily El Waiver Request Not Required Dissolved Oxygen mg/I Grab Minimum Maximum 0 pH (report maximum and minimum of individual samples) 7.35 8.88 standard units Grab z Temperature, Summer 105.1 110.4 El °F El °C Grab 0 Temperature, Winter 86.2 91.9 El oF EO°C Grab

%A1-;,-sa 0 - -f KIMG 0 a -t .6^iAr r%:1 0 / ý- - -- A

Michigan Department of Environmental Quality - Water Resources Division WASTEWATER DISCHARGE PERMIT APPLICATION SECTION III - Industrial and Commercial Wastewater B. Outfall Information PLEASE TYPE OR PRINT FACILITY NAME I NPDES PERMIT NUMBER OUTFALL NUMBER Entergy Nuclear Palisades, LLC MI 0001457I 001A Note: For questions on this page, Tables I - 5 are found in the Appendix.

4. PRIMARY INDUSTRY PRIORITY POLLUTANT INFORMATION Existing primary industries that discharge process wastewater are required to submit the results of at least one permittee-collected effluent analysis for selected organic pollutants identified in Table 2 (as determined from Table 1, Testing Requirements for Organic Toxic Pollutants by Industrial Category), and all of the pollutants identified in Table 3. Existing primary industries are required to also provide the results of at least one permittee-collected effluent analysis for any other chemical listed in Table 2 known or believed to be present in the facility's effluent.