ML063400437
| ML063400437 | |
| Person / Time | |
|---|---|
| Site: | Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png |
| Issue date: | 11/14/2006 |
| From: | Connecticut Yankee Atomic Power Co |
| To: | NRC/FSME |
| References | |
| 9106-0004 | |
| Download: ML063400437 (332) | |
Text
Book of 1 Final Status Survey Final Report Phase IV Appendix A4 Survey Unit Release Record 9106-0004, Discharge Canal November 2006 I CYAPCO FINAL STATUS SURVEY RELEASE RECORD DISCHARGE CANAL SURVEY UNIT 9106-0004 Prepared By: Reviewed By: F S n i-eer Date: -Date: Date: FSS§)Kgineer Approved By7O Technicar Support Manager Revision 0 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD TABLE OF CONTENTS 1. SURVEY UNIT DESCRIPTION
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3 2. CLASSIFICATION BASIS .............................................................
3 3. DATA QUALITY OBJECTIVES (DQO) .........................................
5 4. SU RV EY D ESIGN ...........................................................................
8 5. SURVEY IMPLEMENTATION
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11 6. SU RV EY RESU LTS .......................................................................
12 7. QUALITY CONTROL ..................................................................
14 8. INVESTIGATIONS AND RESULTS ............................................
14 9. REMEDIATION AND RESULTS ..................................................
15 10. CHANGES FROM THE FINAL STATUS SURVEY PLAN ...... 15 11. DATA QUALITY ASSESSMENT (DQA) .....................................
15 12. A N O M A LIE S .................................................................................
16 13. C O N CLU SIO N ...............................................................................
16 14. A TTA CH M E N TS .............................................................................
167 14.1 Attachment 1 -Figures (6 pages including cover)14.2 Attachment 2 -Sample and Statistical Data (312 pages including covers)Revision 0 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD SURVEY UNIT DESCRIPTION Survey Unit 9106-0004 (Discharge Canal) is designated as Final Status Survey (FSS) Class 2 and consists of approximately 9,900 m 2 (2.45 acres) of water covered sediment in an area located approximately 0.28 miles from the reference coordinate system benchmark used at the Haddam Neck Plant (HNP)(see Attachment 1, Figure 1). The Discharge Canal is a man-made mile long waterway that runs parallel to, and ultimately communicates with the Connecticut River. The Discharge Canal is subdivided into fifteen (15) survey units including two (2) permanent wetland areas for FSS purposes.
The survey unit is bounded as follows: Discharge Canal Survey Unit 9106-0003 is to the north, (called north as orientated with the north to south flow of the Connecticut River),land surface area Survey Unit 9528-0005 is to the east, Discharge Canal Survey Unit 9106-0005 is to the south and land Surface Area 9520 is to the west. The survey unit comprises the canal sediments to the deeper of three feet or the original construction depth. It extends up the canal banks to the mean high water level.The reference coordinates associated with this survey unit are E007 through E022 by S090 through S100 (refer to License Termination Plan Section 5.4.4).The reference coordinates provide the maximum dimensions of a rectangle containing this survey unit. Some areas contained in this rectangle may not be part of this survey unit. The boundary of the survey unit was defined using a Global Positioning System (GPS) based on the Connecticut State Plane System North American Datum (NAD) 1927.2. CLASSIFICATION BASIS The survey unit was classified in accordance with Procedure RPM 5.1-10,"Survey Unit Classification. " The historical information, scoping analyses and characterization results provided sufficient data to designate Survey Unit 9106-0004 as Class 2 in May 2006.The "Classification Basis Summary" conducted for this survey unit consisted of: a) A review of the 1OCFR50.75 (g) (1) database, b) A review of the "Initial Characterization Report" and the "Historic Site Assessment (HSA) Supplement, " c) Historic and current survey records review, d) Visual inspections and a "walkdown." e) Formal or informal interviews with cognizant personnel.
A review of the 1OCFR50.75(g)(1) database report identified a number of events that may have impacted this survey unit. Several events indicated the potential for plant related contamination in the survey unit. These included a number of primary side system to secondary side system leakage events, Revision 0 3 Revision 0 3 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD contamination found to be present in secondary side systems and components, and unmonitored spills that drained to the discharge canal. In 1986, samples were taken from the legacy dredge spoils removed in 1979 dredged spoils area and from recently dredged canal sediment.
The sample analyses indicated that the concentrations of Cs-137, Co-60 and other radionuclides were a small fraction of the DCGLs for those nuclides that could be identified by gamma spectroscopy. (refer to NE-86-RA-1142 dated 11-13-86).
None the available historical information reviewed would support a conclusion that any residual activity in this survey unit is likely to be present at concentrations greater than the respective DCGLs.Additional information was provided by several historical documents, including the "Results of Scoping Survey", (completed 9/1/98), the "Historical Site Assessment", and the HSA Supplement (dated 6-30-00).
These documents presented the results of several sediment samples taken in 1997. These sample results indicated concentrations of 0.5 pCi/g for Co-60, 0.024 pCi/g for Cs-134 and 0.722 pCi/g for Cs-137.An initial characterization survey was implemented during April and May of 2004. Six (6) samples from three (3) coring locations were obtained by biased sampling throughout the area. The samples were analyzed off-site by gamma spectroscopy and with radiochemical analyses for Sr-90 and Tritium.Additional Hard-to-Detect (HTD) analyses were also conducted on one (1) of the six (6) samples.For FSS, canal sediment sample collection methodology was achieved by producing one (1) thoroughly homogenized sample from each three (3) foot column of sediment obtained at each sampling location.
However, the characterization sample collection process was performed in a slightly different manner that split the top six (6) inches of the column of sediment from the rest of the column of sediment and analyzed them separately.
Additionally, only the top sample was analyzed for HTD nuclides.
This process may have had the effect of high biasing the HTD sample results.Based on the characterization data, the primary radionuclides of concern were determined to be Cesium-137, Cobalt-60 and Sr-90. Three (3) HTD nuclides (C-14, Ni-63 and Tc-99) were detected at slightly above the screening criteria but were deselected as radionuclides of concern because it is believed that the characterization data was high biased for HTDs and if the entire three (3) foot column of sediment was analyzed, the concentrations would have been below the screening criteria.
Cobalt-60 accounted for the majority of the dose in these samples with a maximum concentration of 3.04 pCi/g.A final Characterization was performed by Site Closure personnel in April and May of 2006 to obtain the necessary data of sufficient data quality for final status survey (FSS) planning purposes.
A 3-foot core sediment sample was Revision 0 4 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD taken from each of the six (6) locations identified.
All of the samples were analyzed by gamma spectroscopy.
Since five (5) of the six (6) initial characterization results tested positive for Sr-90, it was included as a nuclide of concern. No additional HTD testing was performed for characterization purposes.
However, four (4) of the fifteen (15) FSS samples collected were tested for HTD nuclides.
The purpose of the increased level of HTD sample analysis was to ensure that all radionuclides of concern, for this survey unit, were properly identified.
The only plant-related, dose significant radionuclides identified in the samples were Cesium-137, Cobalt-60 and Sr-90 (refer to Table 1).Median: 1.20E-01 2.1 lE-01 6.77E-02 Standard Deviation:
[ 6.76E-02 I .88E-01 4.25E-02 NOTE: The Operational DCGLs are 5.38 pCi/g for Cs-137, 2.59 pCi/g for Co-60 and 1.05 for Sr-90; these are used in conjunction with the unity rule to achieve 19 mrem/yr TEDE.The FSS Engineer performed a visual inspection and walkdown during April 2006 to assess the physical condition of the survey unit, evaluate access points and travel paths and identify potentially hazardous conditions.
The final designation was Class 2 based on historical information and the characterization survey data which provided sufficient data to conclude that FSS sample results will be less than the seventeen (17) mrem/yr Operational DCGL (refer to Section 3).3. DATA QUALITY OBJECTIVES (DQO)FSS design and planning is based on the Data Quality Objective (DQO) process as described by the LTP, Procedure RPM 5.1-11, "Preparation of Final Status Survey Plan, " and the "Multi-Agency Radiation Survey and Site Investigation Manual" (MARSSIM).
A summary of the main features of the DQO process are provided herein.The DQO process incorporates hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis.
Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition.
The baseline condition is technically known as the null hypothesis.
Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection.
In designing the survey plan, the underlying assumption, or null hypothesis was that residual Revision 0 5 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD activity in the survey unit exceeded the release criteria.
Rejection of the null hypothesis would satisfy the release criteria objective of the FSS.The primary objective of the Final Status Survey Plan (FSSP) was to demonstrate that the level of residual radioactivity in Survey Unit 9106-0004 did not exceed the release criteria specified in the LTP and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).A fundamental precursor to survey design is to establish a relationship between the release criteria and some measurable quantity.
This is done through the development of Derived Concentration Guideline Levels (DCGLs). The DCGLs represent the concentration of radioactivity above background, equivalent to a dose-based release criterion and is presented in terms of surface or mass activity concentrations.
Chapter 6 of the LTP describes in detail the modeling used to develop the DCGLs for soil (called Base Case Soil DCGL), for existing groundwater radioactivity and for future groundwater radioactivity that will be contributed by building foundations and footings.As described in detail in the LTP, the dose model applied to the discharge canal presumes that the canal sediments are dredged to a depth of three (3) feet below the top of the sediment layer and spread for the planting of crops per the Resident Farmer Scenario.
Consequently, the soil DCGLs are directly applied to the canal sediment media The DCGLs presented in Chapter 6 of the LTP were developed for exposures from three (3) components, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity.
Equation 1 shows the mathematical relationship between the three (3) components and the total dose.Equation ]: HTotal=Hsoil (sediment)
+ HExisting GW + HFuture GW The total dose under the LTP criteria is twenty-five (25) mrem/yr TEDE from all three (3) components.
The allowable total dose under the Connecticut Department of Environmental Protection (CTDEP) radiological remediation standard for Connecticut Yankee (CY) is nineteen (19) mrem/yr TEDE. To satisfy both the LTP and CY CTDEP criteria, the dose from soil must be reduced when using the groundwater dose values discussed above.This survey unit is affected by existing groundwater (reference CY memo ISC 06-024). The dose contribution from existing groundwater was determined not exceed two (2) mrem/yr TEDE.Revision 0 6 Revision 0 6 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no concrete foundations or footings remaining within the groundwater saturated zone in the area (reference CY memo ISC 06-024). The dose contributions from future groundwater, the third component is, therefore, zero (0) mrem/yr TEDE.Equation 2: 19 mrem/yrTotal 17 mrem/yrso 1+2 mrem/yrExisting GW+O mrem/yrFuture GW The allowable dose for soil in this survey unit is seventeen (17) mrem/yr TEDE as shown by Equation 2 above. The concentration of residual radioactivity resulting in seventeen (17) mrem/yr TEDE is designated as the Operational DCGL, and has been established for the radionuclides of concern as provided in Table 2 Note: The survey design used a much smaller value for investigation than the Operational DCGL provided by Table 2 to conservatively account for the contribution to the total dose from existing and future groundwater which had not been established at the time of planning the FSS.Revision 0 7 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD C-14 5.66E+00 3.85E+00 2.26E-01 Mn-54 1.74E+01 I. 18E+OI 6.96E-01 Fe-55 2.74E+04 1.86E+04 1.1OE+03 Co-60 3.81E+00 2.59E+00 1.52E-01 Ni-63 7.23 E+02 4.92E+02 2.89E+O1 Sr-90 1.55E+00 1.05E+00 6.20E-02 Nb-94 7.12E+00 4.84E+00 2.85E-01 Tc-99 1.26E+01 8.57E+00 5.04E-01 Ag-108m 7.14E+00 4.86E+00 2.86E-0 I Cs-134 4.67E+00 3.18E+00 1.87E-01 Cs-137 7.91 E+00 5.38E+00 3.16E-0I Eu-152 1.01E+OI 6.87E+00 4.04E-0I Eu-154 9.29E+00 6.32E+00 3.72E-01 Eu-155 3.92E+02 2.67E+02 1.57E+01 Pu-238 2.96E+01 2.01E+O1 1.18E+00 Pu-239/240 2.67E+01 1.82E+01 1.07E+00 Pu-241 8.70E+02 5.92E+02 3.48E+OI Am-241 2.58 E+O1 1.75E+01 1.03E+00 Cm-243/244 2.90E+O1 1.97E+OI 1.16E+00 (1) Bold indicates those radionuclides considered to be Hard to Detect (HTD)(2) The Base Case Soil DCGLs for soil are specified by the LTP in Chapter 6 and are equivalent to twenty-five (25) mrem/yr TEDE (3) The Operational DCGL is equivalent to seventeen (17) mrem/yr TEDE (4) The required MDC is equivalent to one (1) mrem/yr TEDE (5) Americium-241 can be analyzed by gamma and alpha spectroscopy and is considered to be Easy to Detect (ETD). The preferred result is the alpha spectroscopy's when both analyses are performed.
Another important facet of the DQO process is to identify the radionuclides of concern and determine the concentration variability.
The Radiological data that was used to support the DQO process was provided by the characterization surveys performed in 2004 and 2006, as discussed in Section 2. Cs-137, Co-60 and Sr-90 were found to be the predominate radionuclides of concern. The basic statistical quantities (i.e., mean, standard deviation, median) for Cs-137, Co-60 and Sr-90 are provided in Table 1.As part of the DQOs applied to laboratory processes, analysis results were reported as actual calculated results. Results reported as less than Minimum Revision 0 8 Revision 0 8 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Detectable Concentration
(<MDC) were not accepted for FSS. Sample report summaries included unique sample identification, analytical method, radionuclide, result, and uncertainty to two (2) standard deviations, laboratory data qualifiers, units, and the required and observed MDC.4. SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. Guidance for preparing FSS plans is provided in Procedure RPM 5.1-11, "Preparation of Final Status Survey Plans ".This survey was initially designed to 10 mrem/yr TEDE. At the time when the survey was designed, the dose contribution for existing and future groundwater had not yet been determined.
Subsequently, a conservative value was chosen for the Operational DCGL. This approach is no longer required as the total dose from existing and future groundwater has been established.
The dose for soil used for this survey unit to demonstrate compliance with the LTP criteria is seventeen (17) mrem/yr TEDE, as discussed in Section 2 of this Release Record.The DQO process determined that Cs-137, Co-60 and Sr-90 were the radionuclides of concern (refer to Section 3). The sum of fractions, or unity rule, was used with the individual Operational DCGLs because multiple radionuclides (Cs-137, Co-60 and Sr-90) were considered in the survey design.A common practice is to surrogate Sr-90, a HTD nuclide, to Cs-137 or another ETD nuclide. However, Sr-90 concentrations in sediment and soil, of this survey unit, were ascertained by direct analysis.The Elevated Measurement Comparison (EMC) did not apply to this survey unit since the survey unit is a Class 2 and discrete, elevated areas of contamination were not expected.The Sign Test was selected as the non-parametric statistical test to demonstrate that the null hypothesis was rejected.
The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation.
In addition, this approach is conservative since it includes background Cs-137 as part of the sample set.The number of soil samples for FSS was determined in accordance with Procedure RPM 5.1-12, "Determination of the Number of Samples for Final Status Survey. " The Lower Bound of the Gray Region (LBGR) was set in accordance with Procedure RPM 5.1-11 to 0.714 to maintain the relative shift (A/o) in the range of 1 and 3. The resulting relative shift was 2.0. A Prospective Power Curve was generated using COMPASS, a software package developed under the sponsorship of the United States Nuclear Regulatory Commission (USNRC) for implementation of the MARSSIM in support of the decommissioning license termination rule (10 CFR 20, Subpart E). The result of the COMPASS computer run showed adequate power for the survey design.Revision 0 9 Revision 0 9 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD This indicates that the survey unit has a high probability of rejecting the null hypothesis, assuming that the characterization data are representative of the FSS results. Survey design specified fifteen (15) sediment core samples for non-parametric statistical testing.The grid pattern and locations of the soil samples were determined using Visual Sample Plan (VSP) in accordance with Procedure RPM 5.1-14, "Identifying, and Marking Surface Sample Locations for Final Status Survey. " Visual Sample Plan was created by Pacific Northwest National Laboratory (PNNL) for the United States Department of Energy. A systematic triangular grid pattern with a random starting point was selected for sample design, which is appropriate for a Class 2 area.Sample locations were identified using AutoCAD-LT, a commercially available plotting software package with coordinates consistent with the Connecticut State Plane System. These coordinates were integrated with a GPS to locate sample locations in the field. Sample Measurement Locations for the design are listed with the GPS coordinates in Table 3.Table 3 -Sml laurmn oain ýihAscae P Coordinates D Aesi nation Y.Northing Eastina~)9106-0004-001F 235796.96 670148.53 9106-0004-002F 235796.96 670237.74 9106-0004-003 F 235796.96 670326.96 9106-0004-004F 235796.96 670416.17 9106-0004-005F 235796.96 670505.39 9106-0004-006F 235796.96 670594.60 9106-0004-007F 235796.96 670683.81 9106-0004-008F 235719.70 670103.92 9106-0004-009F 235719.70 670193.14 9106-0004-01 OF 235719.70 670549.99 9106-0004-01 IF 235719.70 670639.21 9106-0004-012F 235719.70 670728.42 9106-0004-013F 235719.70 670817.63 9106-0004-014F 235642.44 670773.03 9106-0004-015 F 235642.44 670862.24 Five (5) sediment samples were analyzed for the full suite of radionuclides specified in Table 1, exceeding the requirement to analyze 5% of the sample population for HTD analysis specified in procedure RPM 5.1-11.The implementation of quality control measures as referenced by Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey, " included the collection of two (2) soil samples for "split sample" analysis by the off-site laboratory.
These locations were selected randomly using the Microsoft Excel Revision 0 10 Revision 0 10 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD"RAND" function.
The number of quality control samples exceeded the 5%requirement.
The LTP specifies that scanning is not required for the FSS of the Discharge Canal. Table 4 provides a synopsis of the survey design.Survey Unit Land Area 9,900 m 2 Based on AutoCAD-LT and Visual Sample Plan calculations Type I and Type 2 errors were 0.05, Number of 15 sigma was 0.143 the LBGR was set to Measurements 0.714 to maintain Relative Shift in the range of 1 and 3, Relative Shift was 2.0 Grid Spacing 27.61 m Based on triangular grid 3.16 pCi/g Cs-137 Design DCGL 1.52 pCi/g Co-60 To achieve 10 mrem/yr TEDE 0.62 pCi/g Sr-90 Operational 5.38 pCi/g Cs-137 To achieve 17 mrem/yr DCGL 2.59 pCi/g Co-60 TEDE (2) to demonstrate compliance with 1.05 pCi/g Sr-90 Equation 2 of this Release Record Scan Coverage N/A The LTP exempts this area Sediment 5.38 pCi/g Cs-137 The Operational DCGL meets the LTP Investigation 2.59 pCi/g Co-60 criteria for a Class 2 survey unit Level 1.05 pCi/g Sr-90 (1) The survey design used a much smaller value for investigation than the Operational DCGL provided by Table 2 as the total dose from existing and future groundwater had not been established at the time of planning the FSS (2) The allowable dose for soil in this survey unit is 17 mrem/yr TEDE as the total dose from existing and future groundwater has been established (reference CY memo ISC 06-024)5. SURVEY IMPLEMENTATION Final Status Survey field activities were conducted under Work Plan and Inspection Record (WP&IR) 2006-0021.
The WP&IR package included a detailed FSSP, job safety analysis, job planning checklist and related procedures for reference.
Daily briefings were conducted to discuss the expectations for job performance and the safety aspects of the survey. The "Daily Survey Journal" was used to document field activities and other information pertaining to the FSS.Measurement locations were identified in North American Datum (NAD) 1927 coordinates that were supplied to the sampling vendor, Ocean Survey, Inc.(OSI) of Old Saybrook, Connecticut.
Discharge Canal sampling was accomplished using direct push technology to collect composite samples of Revision 0 I1I Revision 0 11 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD bottom and mean high water mark sediments.
Sediment cores from the Discharge Canal were obtained by OSI using a vibrating corer that is platform mounted on a sampling vessel. The core barrel was a three (3) inch diameter thin-walled aluminum tube, approximately ten (10) feet long, which also served as a core liner. A core catcher was available to prevent the sample from sliding out of the bottom of the tube. Vessel positioning and the determination of sample locations were accomplished using a GPS interfaced with a navigation and data logging system.After extraction, water was drained by drilling holes above the sediment column which would constitute the sample. The liner was cut, capped, sealed, labeled and turned over from the Ocean Surveys, Inc. to site personnel who processed and controlled each sample with a Chain-of-Custody (COC).Rinsing of the barrel and associated equipment was performed between sampling events. New aluminum tubes were used for each sample to prevent cross-contamination of subsequent samples.The fifteen (15) sediment samples were collected and packaged in accordance with Haddam Neck Plant (HNP) Procedure RPM 5.1-3, "Collection of Sample Media for Final Status Survey" and FSS design. Samples were controlled, transported, stored, and transferred to the off-site laboratory using COC protocols.
Five (5) samples (9106-0004-OOF, 9106-0004-005F, 9106-0004-013F, 9106-0004-014F and 9106-0004-015F) were selected for HTD radionuclide analysis by the off-site laboratory.
The implementation of survey specific quality control measures included the collection of two (2) split samples at locations 9106-0004-004F and 9106-0004-01 OF for "split sample" analysis by the off-site laboratory.
- 6. SURVEY RESULTS The off-site laboratory employed for the radiological analyses of samples was General Engineering Laboratories (GEL) -Charleston, South Carolina.
The laboratory analyzed the fifteen (15) samples taken for non-parametric statistical testing and the associated duplicates using gamma spectroscopy.
Sr-90 was analyzed by gas flow proportional counting.
All analyses were performed to the required MDC.Cesium-137 was identified in thirteen (13), Co-60 was identified in fourteen (14) and Sr-90 in two (2) of the fifteen (15) samples.Additionally, C-14 was positively identified (i.e., a result greater than two (2)standard deviations uncertainty) in all five (5) samples analyzed for HTD radionuclides and could not be de-selected or excluded using the 5% and 10%rule described in Section 5.4.7.2 of the LTP. Several other radionuclides which Revision 0 12 Revision 0 12 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD were positively identified (i.e., a result greater than two (2) standard deviations uncertainty) could' be de-selected or excluded using the 5% and 10% rule described in Section 5.4.7.2 of the LTP.None of the samples exceeded the Operational DCGL. A summary of the sample results is provided in Table 5.9106-0004-003 F 3.55E-01 9.45E-01 1.62E-02 0.431 0.507 9106-0004-004F 1.59E-01 2.63E-01 -7.59E-03 0.131 0.185 9106-0004-005F 3.99E-0I 1.74E+00 5.86E-03 0.746 0.842 9106-0004-006F 1.12E-01 2.23E-01 1.OIE-02 0.107 0.177 9106-0004-007F
-5.61E-03 1.16E-03 -6.09E-03
-0.001 0:055 9106-0004-008F 1.55E-01 2.56E-01 2.62E-02 0.128 0.214 9106-0004-009F 2.09E-02 0.OOE+00 2.16E-02 0.004 0.085, 9106-0004-01 OF 2.46E-03 7.39E-03 -1.75E-03 0.003 0.063 9106-0004-011F 2.12E-01 3.66E-01 9.13E-04 0.181 0.242 9106-0004-012F 1.59E-01 1.37E-01 -1.72E-03 0.082 0.142 9106-0004-013F 5.49E-01 1.81E+00 3.01E-03 0.801 0.873 9106-0004-014F
-7.91E-03 2.85E-02 8.27E-03 0.010 0.052 9106-0004-015F 3.77E-01 7.44E-01 -1.53E-03 0.357 0.396 (1) The Operational DCGLs from Table 2 are 5.38 pCi/g for Cs-137, 2.59 pCi/g for Co-60 and 1.05 for Sr-90; these are used in conjunction with the unity rule to achieve 17 mrem/yr TEDE (2) This column is the sum of the DCGL unity fraction from identified radionuclides of concern and HTD isotope (C-14) exceeding the 5%/10% rule for one or more FSS samples. For those samples not measured for HTD isotopes, an average calculated value of 6.1% of the DCGL was added to each sample.The off-site laboratory also processed five (5) samples for HTD analysis as required by the sample plan. The requested analyses included alpha spectroscopy, gas proportional counting, and liquid scintillation depending on the radionuclide and the measurement method. All analyses met the required MDC. Five (5) of the HTD radionuclides met the accepted criteria for detection (i.e., a result greater than two standard deviations uncertainty) in more than one (1) sample. Each of the positive results for HTD radionuclides could be de-selected based on the 5% and 10% rules, except for C-14. These results are presented in Table 6.Revision 0 13 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Table 6-Hard-t et'ec't Samp leI esults~Sample Numbher C-14 Fr~ 4iaction of the..........
....... O pg.. .. .........: ... ; I ! : ra tio n a l D C L ....9106-0004-001F 0.268 0.0696 9106-0004-005F 0.347 0.0902 9106-0004-013F 0.267 0.0694 9106-0004-014F 0.134 0.0348 9106-0004-015F 0.156 0.0405 (1) The Operational DCGL from Table 2 is 3.85 pCi/g for C-14.A biased sample location called for in the sample plan the (sample point 9106-0004-016F was found to be located on dry land. This point was replaced with a randomly generated sample point 9106-0004-17F.
For completeness this sample result is presented in the Table below.Table 7 -Additional Sam le Result SueNubr Cs-137 Co>> Sr9 raction ofthe 9106-0004-01 7F 3 .78E-01 2.94E-01 3.46E-02 0.184 (1) The Operational DCGLs from Table 2 are 5.38 pCi/g for Cs-137, 2.59 pCi/g for Co-60 and 1.05 pCi/g for Sr-90; these are used in conjunction with the unity rule to achieve 17 mrem/yr TEDE 7. QUALITY CONTROL The off-site laboratory processed the split samples and performed gamma spectroscopy analysis.
Two (2) of the samples were selected for analysis, which exceeds the 5% minimum required by the LTP. The data were evaluated using USNRC acceptance criteria specified in Inspection Procedure 84750 and as detailed in 1-NP Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey. " For one of the split-sample comparisons, Co-60 was found to not meet the comparison criterion; however this nuclide may be present in particulate form which is not necessarily an indicator of a non-homogenous mixing of the soil matrix. K-40, a natural radioisotope, was found to be present at an acceptable level of agreement, so the comparison was deemed acceptable.
There was acceptable agreement between the field split results for both of the"split sample" pairs tested.GEL, the sample analysis vendor, maintained quality control and quality assurance plans as part of normal operation.
Refer to Attachment 2 for data and data quality analysis results.8. INVESTIGATIONS AND RESULTS Two (2) sample results were found to exceed the Design DCGL of ten (10)mrem/yr, but were below the seventeen (17) mrem/yr Operational DCGL, as specified in Table 4. Confirmatory samples were collected to determine the extent of contamination.
The extent was bounded by taking four (4)Revision 0 14 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD confirmatory samples, one in each compass direction, two (2) meters distant from the elevated sample location.
The results are included in Table 8.005F 005C I 1.13E-01 [ 2.68E-01 I 8.20E-03 1 0.132'005D 5.03 E-01 1.72E+00-3.22E-03 0.754 013A -1.13E-03
-5.69E-03
-3.31E-03
-0.006 013F 013B 8.31E-02 1.96E-01 2.21E-03 0.093 013C 7.89E-02 7.40E-02 -1.57E-03 0.042 013D 1.70E-01 5.66E-01 7.38E-03 0.257 (1) The Operational DCGLs from Table 2 are 5.38 pCi/g for Cs-137, 2.59 pCi/g for Co-60 and 1.05 pCi/g for Sr-90; these are used in conjunction with the unity rule to achieve seventeen (17) mrem/yr TEDE.The confirmatory results demonstrate that no measurements exceed the 17 mrem/yr operational DCGL, indicating that no further actions are warranted.
- 9. REMEDIATION AND RESULTS Historically, no radiological remedial action as described by MARSSIM Section 5.4 was performed in this survey unit prior to or as a result of the FSS. Health Physics TSD BCY-HP-0078, "ALARA Evaluation of Soil Remediation in Support of Final Status Survey, " determined that remediation beyond that required to meet the release criteria to be unnecessary and that the remaining residual radioactivity in soil was ALARA.10. CHANGES FROM THE FINAL STATUS SURVEY PLAN The survey was designed to ten (10) mrem/yr TEDE which was conservative and necessary at the time of FSS planning.
It is no longer required as the total dose from existing and future groundwater has been established.
The dose for soil used to demonstrate compliance with the LTP criteria is seventeen (17)mrem/yr TEDE as discussed in Section 2 of this Release Record.Revision 0 15 Revision 0 15 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD 11. DATA QUALITY ASSESSMENT (DQA)The DQO sample design and data were reviewed in accordance with Procedure RPM 5.1-23, "Data Quality Assessment, " for completeness and consistency.
The sampling design had adequate power as indicated by the Retrospective Power Curve. The Sign Test was performed on the data and compared to the original assumptions of the DQOs. The Sign Test shows that the survey unit passes FSS.Documentation was complete and legible. Surveys and sample collection were consistent with the DQOs and were sufficient to ensure that the survey unit was properly designated as Class 2.The preliminary data review consisted of calculating basic statistical quantities (e.g., mean, median, standard deviation).
The sample standard deviation was slightly more than the value used for the survey design. This is represented by the shift in the retrospective power curve as shown in Attachment 2g. This would indicate a change to the original LBGR to maintain the number of samples at fifteen (15) to meet the Operational DCGL. However, the value of LBGR is less of a critical issue as the survey unit has passed the statistical test, and the mean and median values are well below the Operational DCGL when used in conjunction with the unity rule. Also, the retrospective power curve shows that a sufficient number of samples were collected to achieve the desired power. Therefore, the survey unit meets the release criteria with adequate power as required by the DQOs.The range of the data, about 3.02 standard deviations, was not unusually large.The difference between the mean and median was 42.5% of the standard deviation which indicates some skewness in the data. The data was represented graphically through posting plots, a frequency plot, and a quantile plot. The frequency plot shows some positive skewness as confirmed by the calculated skew of 1.23.All data, assessments, and graphical representations are provided in Attachment 2.12. ANOMALIES The finding of C-14 in excess of the screening criteria was the only anomaly associated with the FSS of this survey unit. For conservatism, the C-14 results were factored into all statistical evaluations of the survey data for this survey unit accounting for any possible dose contributions.
This action does not alter the conclusion that this survey unit meets the criteria for unconditional release.13. CONCLUSION Survey Unit 9106-0004 has met the final DQOs of the FSS. The ALARA criteria for soils as specified in Chapter 4 of the LTP were achieved.
Elevated Measurement Comparison and remediation was not required.Revision 0 16 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD The sample data passed the Sign Test. The null hypothesis was rejected.Graphical representation of data indicates some positive skewness that is probably due to localized differences in particulate deposition rates, hydraulic velocity and sedimentation rates. The Retrospective Power Curve generated using COMPASS shows adequate power was achieved.
The survey unit was properly designated as Class 2.The dose contribution from soil is 5.1 mrem/yr TEDE based on the average concentration of the samples used for non-parametric statistical sampling.This survey unit is affected by existing groundwater (reference CY memo ISC 06-024 and the Final Status Survey Final Report Phase IV). It has been determined that the dose contribution from groundwater sources will not exceed two (2) mrem/yr TEDE.This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no concrete foundations or footings containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo ISC 06-024). The dose contribution from future groundwater, the third dose component, is therefore zero (0) mrem/yr TEDE.The average total dose from residual radioactivity in this survey unit, including present ground water and sediment, will not exceed 7.1 mrem/yr Total Effective Dose Equivalent (TEDE).14. ATTACHMENTS 14.1 Attachment 1 -Figures 14.2 Attachment 2 -Sample and Statistical Data Revision 0 17 Revision 0 17 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Attachment 1 Figures (5 pages)
/V--I 'y!/J 44 Lllýt r7 Connecticut Yankee Atomic Power Company Site Map With Reference To Survey Unit 9106-0004 13D 12 Sample Lomton q~ Pond Connecticut Yankee Atomic Power Company 9106-0004 Final Status Survey Sample Locations
,f.1.0159'f Pond 0 30 60 IFeet NOTE.Cesium-137 zwudts am gim in pcil*Connecticut Yankee Atomic Power Company 9106-0004 Final Status Survey Cesium-13 7 Postinz Plot K Sample Loation V% Pond NOTE.Cobalt-60 7ewudty am given hpin k
$sample Locaton'V Pond 0 30 60 NOTE.stzvntm-90 resufs am given in pMi9 9106-0004 Fina Strontium-90 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Attachment 2 Sample and Statistical Data DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Attachment 2a Sample Data (292 Pages)
Table of Contents General Narrative
..................................................................
I Chain of Custody and Supporting Documentation
...........
4 Radiological Analysis .........................................................
12 Sample Data Summary ......................................................
31 Q uality C ontrol D ata ..........................................................
71 General Narrative 1 CASE NARRATIVE For CONNECTICUT YANKEE RE: Sediment PO# 002332 Work Order: 162832 SDG: MSR #06-0688 June 7, 2006 Laboratory Identification:
General Engineering Laboratories, LLC Mailing Address: P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shippin2 Address: 2040 Savage Road Charleston, South Carolina 29407 Telephone Number: (843) 556-8171 Summary: Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC, (GEL)in Charleston, South Carolina on May 12, 2006. All sample containers arrived without any visible signs of tampering or breakage.
The chain of custody contained the proper documentation and signatures except the sample container for sample 9106-0004-014F was received leaking. A Safety Technician contained the leak and salvaged the sample successfully.
No other samples were affected.
Analyses were conducted as normal.The laboratory received the following sample(s):
Sample ID Client Sample ID 162832001 9106-0004-008F 162832002 9106-0004-009F 162832003 9106-0004-OIOF 162832004 9106-0004-O1OFS 162832005 9106-0004-01 IF 162832006 9106-0004-012F 162832007 9106-0004-013F 162832008 9106-0004-014F GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.PO. Box 30712 .Charleston, SC 29417 -2040 Savage Road (29407)Phone (843) 556-8171
- Fqý (843) 766-1178
- www.gel.com Sample ID Client Sample ID 162832009 9106-0004-015F 162832010 9106-0004-OOIF 162832011 9106-0004-002F 162832012 9106-0004-003F 162832013 9106-0004-004F 162832014 9106-0004-004FS 162832015 9106-0004-005F 162832016 9106-0004-006F 162832017 9106-0004-007F 162832018 9106-0004-017F Items of Note: There were no items of note.Case Narrative:
Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures.
Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.
Analytical Request: Sixteen sediment samples were analyzed for FSSGAM and Sr-90.Two sediment samples were analyzed for FSSALL.Internal Chain of Custody: Custody was maintained for the sample(s).
Data Package: The enclosed data package contains the following sections:
Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.
I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.
Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.P.O. Box 30712
- Charleston, SC 29417 -2040 Savage Road (29407)Phone (843) 556-8171 -Fai (843) 766-1178 ° www.gel.com Chain of Custody and Supporting Documentation 4
H. -PtHealth Physips Prp~dure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connfctkut Yankee Atomic Power Company i362 Ijun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: HaddamNeck Decommissioning Contact Name & Phone: Jack McCarthy -860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D.[] 14D.EI7D.Ln Samples Shipped Via: 2 Fed Ex El uPs El Hand El Other Bill of Lading #
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06624 860-267-2556 Contact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D.E] 14 D. [] 7 D.Samples Shipped Via:[ Fed Ex El UPS[] Hand El Other Bill of Lading #
Connecticut Yankee Statement of Work for Analytical Lab Services , CY-ISC-SOW-00 Figure 1. Sample Check-in List.Date/Time Received:
A 'Aw 0 OQ, SDG#:0 Work Order Number: "-V3Y? -.Shipping Cditainer ID:., Chain of Custody# 33-4 -I. Custody Seals on'shipping container intact?.-
Yes [ No 2. Custody Seals dated and signed? Yes [ No 64, 3. Chain-of-Custody record present? Yes ? No [I 4. Cooler temperature I C ., 5. Vermiculite/packing materials is: -Wet F,/)Dry (, k 6,* Number of samples in shipping container
_7. Sample holding times exceeded?
Yes No.8. Samples have**tape -hazard labels_.. custody seals ----__.appropriate sample labels 9. Samples are'.n good conditin...dekn o n : , ..* .-broken -have air bubbles 10. Were any anomalies identified in sample receipt? Yes No*IL. Description
..... "ie:1. .Descrption of.anomalies (include sample numbers):,.
5Q ii \-J 3 ,_IL i O0 --Sample Custodian/Laboratory:C j ~ ~ D te ~Telephoned to:__ _ _ _ _ _ _ O-n By '.7 le 4S ,SAMPLE RECEIPT & REVIEW FORM" yPM use only Client: i~ eV DGIARCOC)
Work Order: /(L 32-D;ate Received:
C5- jai I JPM(A) Review rewocn(lm ame resolved prior to siging): Received By: (j i-e~v fi J ( A),GwLj Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforming Items)Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe)
Iand sealed?Samples requiring cold Circle Coolant # ice bags blue ice dry ice other describe)2 preservation within (4 +/- 2 C)?Record preservation method. I" Chain of custody documents CVO C0-b -S Ur included with shipment?
co-tai"e, Sample containers intact and irckCAppcablc;
=15 broe danaged conai leaking conainer (odtescie sealed? --C-M#I?- "lq- ) gq.c 'Samples requiring chemical Sample ID's. containers affected and observed pH: aFYIZ_preservation at proper pH? --..VOA vials free of headspace Sample ID's and cotnainers affected: (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory) 8 Samples received within holding lid's and tests affected: time?Sample ID's on COC match ID's Sample ID's and containers affected: on bottles? _, Date & time on COC match' date Sample ID's affected:& time on bottles?Number of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in no C0365 CU'L('. *.LYLU i s'Uks d relinquished/rcceived sections??EcA- 4%-- I Air Bill ,Tracking
- 's, & SUI Additiona1 Comments T RSO RAD Receipt _*If > x2 area background is observed on samples identified as "non-Suspected Hazard Information to =Do r -c regulated/non-radioactive", contact the Radiation Safety group for further I investigation.
A adiological Classification?
Maximum Counts Observed*:
B IPCB Regulated?
Comments: Shipped as DOIT Hazardous C jMaterial?
If yes, contact Waste i Hazard Class Shipped:[Manager or ESH Manager. I UN#: PM (or PMA) review of Hazard classitication:
Initials Date: 8 Y k9~SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM pIr- q(C4 p~o vf 5~lyf(-U~pI oYLW33) (--(2 6 1 0a30 , ( ") "iVl 4hi5, ce(!o'e had c,. " _"__"-L,,meLI
________________
U-fe ;LJ Uc", r _- I dI 9 SAMPLE RECEIPT & REVIEW FORM PM one oly IClient: (>< ya,,& , SDG/ARCOClWork Order: / ,, Date Received: , i- .PM(A) Review (ensure non-conforming items are resolved prior to signing): R eceived By: e- .- /A) l R e ( n n Sample Receipt Criteria >4 t , Comments/Qualifiers (Required for Non-Conforming Items)1 Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) and sealed? I Samples requiring cold Circle Coolant # ice bags blue ice dry ice none other describe)2 preservation within (4 +/- 2 C)?.Recordpreservation method.Chain of custody documents included with shipment?
____4 Sample containers intact and Circle Applicable:
seals broken damaged container le oaino other (describe) sealed? J '6,q) :" 0 (oe- 0oo0j-o 'a1 " 5 Samples requiring chemical Sample ID's, containers affected and observed pH:.preservation at proper pH?VOA vials free of headspace Sample ID's and containers affected: 6 (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory)
_8 Samples received within holding Id's and tests affected: time? __1 9 Sample ID's on COC match ID's Sample ID's and containers affected: on bottles? ___10 Date & time on COC match date Sample ID's affected:& time on bottles? __ll Number of containers received 1 Sample 's affected:.match number indicated on COC?12 COC form is properly signed in.relinquished/received sections?
X 1 4 .0 A_ A-. rd 14 Air Bill ,Tracking
- 's, & -..f ..-AJ ,A tyL .Additional Comments" ~~ ~P "U R§"- ' PORAD Receipt #..*'-Suspecte~d-.ad formation
- - -t *f f> x2 area background is observed on samples identified as ,on-S 2p f regulated/non-radioactive", contact the Radiation Safety group for further"____ "____"______
_ !investigation.
SRadiologia Classifation? -Maximum Counts Observed*: 7] PCB Regulated?
comments:! S-ipil as DO'Y.Hazardous C Material?
if yes, contact Waste Hazard Cla Shipped: Manager or ESH Manager. UN#: PM (or PMA) review of Hazard classification:
Initials 6141 Date: 10 U Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Chcck-in List DateF/imc Received: .Y- i/?. 0 (, SDG#: /14 tO0(,,- O0(,R e Work Order Number: 'Shipping Container ID: "lq S 315" 887Z 1. Custody Seals on shipping container intact?2. Custody Seals dated and signed?3. Chain-of-Custody record present?4. Cooler temperature
- 5. Vermiculite/packing materials is: 6. Number of samples in shipping container:
- 7. Sample holding times exceeded?114-,,220 I ID 0 6 0T3 1 Chain of Custody #A1/4 Yes j No []Yes No [Yes No []I Wet J Dry []Yes [] No I 8. Samples have: j( tape hazard labels_ custody seals appropriate sample labels 9. Samples are:____in good condition
_ leaking broken _ have air bubbles 10. Were any anomalies identified in sample receipt? Yes No [ ]11. Description of anomalies (include sample numbers): Sample Custodian/Laboratory: Telephoned to: Date: ,-1.' a. 6 'd's n :,.'7. -On B Page 45 of 56 11 RADIOLOGICAL ANALYSIS 12 Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)Work Order 162832 Method/Analysis Information Product: Alphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 533471 529742 529741 Sample ID 162832008 162832010 1201101117 1201101118 1201101119 1201101120 Client ID 9106-0004-014F 9106-0004-001F Method Blank (MB)162485017(9106-0005-005F)
Sample Duplicate (DUP)162485017(9106-0005-005F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
13 Ouality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162485017 (9106-0005-005F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information 14 Product: Alphaspec Pu, Solid-ALL FSS DOE EML HASL-300, Pu- 11-RC Modified Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 533472 529742 529741 Sample ID 162832008 162832010 1201101121 1201101122 1201101123 1201101124 Client ID 9106-0004-014F 9106-0004-001F Method Blank (MB)162485017(9106-0005-005F)
Sample Duplicate (DUP)162485017(9106-0005-005F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162485017 (9106-0005-005F).
QC Information All of the QC samples met the required acceptance limits.15 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS DOE EML HASL-300, Pu-1i -RC Modified Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 533473 529742 529741 16 Sample ID Client ID 162832008 9106-0004-014F 162832010 9106-0004-0OIF 1201101125 Method Blank (MB)1201101126 162485017(9106-0005-005F)
Sample Duplicate (DUP)1201101127 162485017(9106-0005-005F)
Matrix Spike (MS)1201101128 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162485017 (9106-0005-005F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis The tracer yield for sample 1201101127 (9106-0005-005F) was recounted due to poor resolution.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from 17 referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Analytical Method: Prep Method: Analytical Batch Number: Prep Batch Number: Sample ID 162832001 162832002 162832003 162832004 162832005 162832006 162832007 162832008 162832009 162832010 162832011 162832012 162832013 162832014 162832015 162832016 162832017 162832018 1201092338 1201092339 1201092340 Gamma,Solid-FSS GAM & ALL FSS EML HASL 300, 4.5.2.3 Dry Soil Prep 529778 529741 Client ID 9106-0004-008F 9106-0004-009F 9106-0004-OIOF 9106-0004-01OFS 9106-0004-01 IF 9106-0004-012F 9106-0004-013F 9106-0004-014F 9106-0004-015F 9106-0004-001F 9106-0004-002F 9106-0004-003F 9106-0004-004F 9106-0004-004FS 9106-0004-005F 9106-0004-006F 9106-0004-007F 9106-0004-017F Method Blank (MB)162832001(9106-0004-008F)
Sample Duplicate (DUP)Laboratory Control Sample (LCS)18 SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 11.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162832001 (9106-0004-008F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.19 Qualifier information Qualifier Reason Data rejected due to high Full-Width Half-Maximum.
UI Analyte Cobalt-60 Manganese-54 Americium-241 Lead-212 Manganese-54 Cesium- 134 UI UI UI Data rejected due to high counting uncertainty.
Data rejected due to interference.
Data rejected due to low abundance.
Sample 162832002 162832017 162832010 1201092338 162832001 162832002 162832003 162832004 162832006 162832007 162832012 162832013 162832015 162832016 162832017 162832018 1201092339 Method/Analysis Information 20 Product: GFPC, Sr90, solid-ALL FSS Analytical Method: EPA 905.0 Modified'Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 534448 529742 529741 Sample ID 162832001 162832002 162832003 162832004 162832005 162832006 162832007 162832008 162832009 162832010 162832011 162832012 162832013 162832014 162832015 162832016 162832017 162832018 1201103434 1201103435 1201103436 1201103437 Client ID 9106-0004-008F 9106-0004-009F 9106-0004-01OF 9106-0004-O1OFS 9106-0004-01 IF 9106-0004-012F 9106-0004-013F 9106-0004-014F 9106-0004-015F 9106-0004-001F 9106-0004-002F 9106-0004-003F 9106-0004-004F 9106-0004-004FS 9106-0004-005F 9106-0004-006F 9106-0004-007F 9106-0004-017F Method Blank (MB)162832001(9106-0004-008F)
Sample Duplicate (DUP)162832001(9106-0004-008F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.21 Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (Q) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162832001 (9106-0004-008F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Sample 162832008 (9106-0004-014F) was recounted due to high MDA.Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information 22 Product: Liquid Scint Tc99, Solid-ALL FSS DOE EML HASL-300, Tc-02-RC Modified Analytical Method: Analytical Batch Number: 531704 Sample ID 162832008 162832010 1201096867 1201096868 1201096869 1201096870 Client ID 9106-0004-014F 9106-0004-001F Method Blank (MB)162583001(NOL-02-02-005-F-S)
Sample Duplicate (DUP)162583001(NOL-02-02-005-F-S)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162583001 (NOL-02-02-005-F-S).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.23 Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-1, Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 531618 529742 529741 Sample ID 162832008 162832010 1201096631 1201096632 1201096633 1201096634 Client ID 9106-0004-014F 9106-0004-001F Method Blank (MB)163173001 (9304-0000-063RACR)
Sample Duplicate (DUP)163173001 (9304-0000-063RACR)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.24 Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before, the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (Q) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 163173001 (9304-0000-063RACR).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information 25 Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-1, Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 531622 529742 529741 Sample ID 162832008 162832010 1201096644 1201096645 1201096646 1201096647 Client ID 9106-0004-014F 9106-0004-001F Method Blank (MB)163173001 (9304-0000-063RACR)
Sample Duplicate (DUP)163173001 (9304-0000-063RACR)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (00 Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 163173001 (9304-0000-063RACR).
QC Information All of the QC samples met the required acceptance limits.26 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: LSC, Tritium Dist, Solid -1 to 2 pCi/g Analytical Method: EPA 906.0 Modified Analytical Batch Number: 531705 Sample ID 162832008 162832010 1201096877 1201096878 1201096879 1201096880 Client ID 9106-0004-014F 9106-0004-001F Method Blank (MB)162583001 (NOL-02-02-005-F-S)
Sample Duplicate (DUP)162583001 (NOL-02-02-005-F-S)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 11.27 Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162583001 (NOL-02-02-005-F-S).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Samples 1201096877 (MB) and 162832008 (9106-0004-014F) were recounted due to high MDAs.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information 28 Product: Liquid Scint C14, Solid AII,FSS EPA EERF C-01 Modified Analytical Method: Analytical Batch Number: 534984 Sample ID 162832008 162832010 1201104745 1201104746 1201104747 1201104748 Client ID 9106-0004-014F 9106-0004-001F Method Blank (MB)163173001 (9304-0000-063RACR)
Sample Duplicate (DUP)163173001 (9304-0000-063RACR)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (Q0 Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 163173001 (9304-0000-063RACR).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.29 Sample Re-prep/Re-analysis Samples were reprepped due to low/high recovery.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator.
In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.The following data validator verified the information presented in this case narrative:
Reviewer/Date:
30 SAMPLE DATA
SUMMARY
31 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Report for YANKOO 1 Connecticut Yankee Atomic Power Co.Client SDG: MSR#06-0688 GEL Work Order: 162832 The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification ND The analyte concentration is not detected above the reporting limit.The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures.
Please direct any questions to your Project Manager, Cheryl Jones.Reviewed by 32 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage .Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis C et if c t o .. .. T.. ....... i s--Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Report Date: June 9, 2006 Project: Soils PO# 002332 Client Sample ID: 9106-0004-008F Project: YANKO 1204 Sample ID: 162832001 Client ID: YANK001 Matrix: SE Vol. Recv.: Collect Date: 04-MAY-06 Receive Date: 12-MAY-06 Collector:
Client Moisture:
19.9%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U 0 Europium-155 U Lead-212 Lead-214 Manganese-54 UU1 Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.655 0.0325 0.551 0.447 0.0255 0.155 0.256 0.0135.000575 0.015 0.609 0.566 0.00 0.00427 10.8 0.447 0.00155 0.194+/-0.137+/-0.0823+/-0.165+/-0.0787+/-0.0237+/-0.0273+/-0.046+/-0.0376+/-0.048+/-0.0405+/-0.0665+/-0.0835+/-0.0194+/-0.0141+/-0.957+/-0.0787+/-0.0131+/-0.042 0.0451 0.0746 0.115 0.0262 0.017 0.0123 0.0129 0.0314 0.0407 0.039 0.0195 0.0228 0.0125 0.0123 0.125 0.0262 0.0119 0.013+/-0.137+/-0.0823+/-0.165+/-0.0787+/-0.0237+/-0.0273+/-0.046+/-0.0376+/-0.048+1-0.0405+/-0.0665+/-0.0835+/-0.0194+/-0.0141+/-0.957+/-0.0787+/-0.0131+/-0.042 0.0962 0.154 0.241 0.0549 0.0357 0.026 0.028 0.0656 0.0876 0.0803 0.0403 0.0476 0.0266 0.026 0.272 0.0549 0.0249 0.0274 0.0428 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/06 1727 529778 1 BXF1 06/02/06 1547 534448 2 0.0262 +/-0.0216 0.0193 +/-0.0217 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 33 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-008F Project: YANK01204 Sample ID: 162832001 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 33 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.34 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd Contact: Project: East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Qualifier Result 9106-0004-009F 162832002 SE 04-MAY-06 12-MAY-06 Client 10.5%Proiect:.Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium-137 U Cobalt-60 UUI Europium-152 U Europium-154 U Europium-t55 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U-(Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 1.02-0.0652 0.802 0.765 0.00 0.0209 0.00 0.0221 0.0603 0.0136 1.00 0.967 0.0255 0.00406 8.59 0.765 0.000766 0.355 Uncertainty
+/-0.127+/-0.121+/-0.219+/-0.0817+/-0.0222+/-0.0277+/-0.0245+/-0.0473+/-0.0585+/-0.0533+/-0.0543+/-0.0836+/-0.0272+/-0.0156+/-0.636+/-0.0817+1-0.0155+/-0.043 LC TPU MDA Units DF Analyst Date Time Batch Mtd 0.0487 0.073 0.116 0.0269 0.0212 0.0169 0.0151 0.0425 0.0478 0.0506 0.0256 0.0302 0.0152 0.014 0.105 0.0269 0.0134 0.0138+/-0.127+/-0.121+/-0.219+/-0.0817+/-0.0222+/-0.0277+/-0.0245+/-0.0473+/-0.0585+/-0.0533+/-0.0543+/-0.0836+/-0.0272+/-0.0156+/-0.636+/-0.0817+1-0.0155+/-0.043 0.104 0.149 0.244 0.0565 0.0443 0.0353 0.0326 0.0879 0.102 0.104 0.0527 0.0626 0.0321 0.0293 0.234 0.0565 0.0279 0.029 0.0333 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHl 06/06/06 1727 529778 1 BXF1 06/02/06 1547 534448 2 0.0216 +/-0.0169 0.0151 +/-0.0169 The following Prep Methods were performed Method Description Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B Dry Soil Prep Dry Soil Prep GL-RAD-A-021 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Analyst Date Time Prep Batch MXP2 LXM2 05/15/06 0846 529742 05/14/06 1230 529741 Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 35 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-009F Project: YANKO 1204 Sample ID: 162832002 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 42 (25%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.36 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-01OF 162832003 SE 03-MAY-06 12-MAY-06 Client 12.3%Proiect: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.983 Americium-241 U -0.00252 Bismuth-212 0.538 Bismuth-214 0.627 Cesium-134 UI 0.0529 Cesium-137 U 0.00246 Cobalt-60 U 0.00739 Europium-152 U -0.0137 Europium-154 U -0.0489 Europium-155 U 0.0513 Lead-212 0.904 Lead-214 0.679 Manganese-54 U 0.00548 Niobium-94 U 0.00502 Potassium-40 12.0 Radium-226 0.627 Silver-108m U 0.00214 Thallium-208 0.307 Rad Gas Flow Proportional Counting+/-0.148+/-0.0227+/-0.237+/-0.0778+/-0.0292+/-0.0235+/-0.0239+/-0.044+/-0.062+/-0.0527+/-0.0535+/-0.0766+/-0.0205+/-0.0179+/-0.847+/-0.0778+/-0.0148+/-0.0471 0.0597 0.020 0.122 0.0322 0.0232 0.0177 0.0204 0.0365 0.0476 0.032 0.0216 0.0285 0.0173 0.0154 0.127 0.0322 0.0132 0.0146+/-0.148+/-0.0227+/-0.237+/-0.0778+/-0.0292+/-0.0235+/-0.0239+/-0.044+/-0.062+/-0.0527+/-0.0535+/-0.0766+/-0.0205+/-0.0179+/-0.847+/-0.0778+/-0.0148+/-0.0471 0.127 0.0411 0.259 0.0675 0.0486 0.0373 0.0439 0.0765 0.104 0.066 0.0447 0.0596 0.0368 0.0325 0.285 0.0675 0.0278 0.031 0.0394 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/06/06 1727 529778 I GFPC, SO9O, solid-ALL FSS Strontium-90 U -0.00175 +/-0.0161 0.0179 +/-0.0161 BXF1 06/02/06 1548 534448 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 37 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-010F Project: YANKO 1204 Sample ID: 162832003 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits CarrierfTracer Recovery GFPC, Sr90, solid-ALL FSS 37 (25%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria* Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.38 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-01OFS 162832004 SE 03-MAY-06 12-MAY-06 Client 15.3%Proiect: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium-137 U Cobalt-60 U Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U -1.05 0.0328 0.664 0.695 0.00 0.0326 0.0254-0.0335-0.0475 0.044 1.08 0.807 0.0132 0.0108 13.2 0.695 0.00335 0.318+/-0.214+/-0.0355+/-0.345+/-0.115+/-0.0385+/-0.0317+/-0.0295+/-0.0559+/-0.0946+/-0.0779+/-0.0716+/-0.104+/-0.0275+/-0.0238+/-1.02+/-0.115+/-0.0237+/-0.0568 0.0808 0.0285 0.171 0.0398 0.0279 0.0224 0.0269 0.0482 0.0643 0.0477 0.0256 0.0381 0.0237 0.0207 0.198 0.0398 0.018 0.0211+/-0.214+/-0.0355+/-0.345+/-0.115+/-0.0385+/-0.0317+/-0.0295+/-0.0559+/-0.0946+/-0.0779+/-0.0716+/-0.104+/-0.0275+/-0.0238+/-1.02+/-0.115+/-0.0237+/-0.0568 0.172 0.0585 0.363 0.0839 0.0589 0.0474 0.0578 0.101 0.140 0.0983 0.0533 0.0794 0.0504 0.0436 0.438 0.0839 0.0379 0.0446 0.0452 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/06/06 1728 529778 1 BXFI 06/02/06 1548 534448 2 0.00925 +/-0.0179 0.0209 +/-0.0179 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 39 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-O1OFS Project: YANKO 1204 Sample ID: 162832004 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 39 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria* Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.40 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-011F 162832005 SE 03-MAY-06 12-MAY-06 Client 20.2%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 0 1.09-0.0786 0.602 0.890 0.0536 0.212 0.366-0.0415 0.0615 0.0805 1.13 0.910 0.0269 0.00641 15.0 0.890-0.0111 0.353+/-0.233+/-0.118+/-0.421+/-0.132+/-0.0558+/-0.0512+/-0.0849+/-0.0736+/-0.0839+/-0.0913+/-0.0826+/-0.0991+/-0.029+/-0.0253+/-1.15+/-0.132+/-0.0222+/-0.0647 0.088 0.0915 0.195 0.0453 0.0342 0.0247 0.0262 0.0582 0.0772 0.062 0.0317 0.0423 0.0262 0.0217 0.167 0.0453 0.0187 0.0236+/-0.233+/-0.118+/-0.421+/-0.132+/-0.0558+/-0.0512+/-0.0849+/-0.0736+/-0.0839+/-0.0913+/-0.0826+/-0.0991+/-0.029+/-0.0253+/-1.15+/-0.132+/-0.0222+/-0.0647 0.190 0.189 0.416 0.0961 0.0723 0.0527 0.0576 0.122 0.169 0.129 0.0663 0.089 0.056 0.0464 0.388 0.0961 0.0397 0.0503 0.0384 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/06 2000 529778 1 BXFI 06/02/06 1548 534448 2.000913 +/-0.0156 0.0173 +/-0.0156 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 41 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-01 IF Project: YANK0 1204 Sample ID: 162832005 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr9O, solid-ALL FSS 51 (25%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UJ Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.42 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-012F 162832006 SE 03-MAY-06 12-MAY-06 Client 16.5%Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM& ALL FSS Actinium-228 0.922 Americium-241 U -0.0134 Bismuth-212 0.782 Bismuth-214 0.677 Cesium-134 UJUI 0.00 Cesium-137 0.159 Cobalt-60 0.137 Europium-152 U 0.0336 Europium-154 U -0.0258 Europium-155 U 0.106 Lead-212 0.872 Lead-214 0.815 Manganese-54 U -0.0175 Niobium-94 U 0.0182 Potassium-40 10.6 Radium-226 0.677 Silver-108m U 0.00549 Thallium-208 0.308 Rad Gas Flow Proportional Counting+/-0.170+/-0.120+/-0.399+/-0.0964+/-0.0376+/-0.0393+/-0.0477+/-0.0517+/-0.0601+/-0.0614+/-0.0676+/-0.108+/-0.0212+/-0.0225+/-0.823+/-0.0964+/-0.0191+/-0.0518 0.0627 0.0779 0.137 0.035 0.0264 0.0175 0.0185 0.0475 0.0475 0.0583 0.0262 0.0311 0.0172 0.0199 0.163 0.035 0.0169 0.0159+/-0.170+/-0.120+/-0.399+/-0.0964+/-0.0376+/-0.0393+/-0.0477+/-0.0517+/-0.0601+/-0.0614+/-0.0676+/-0.108+/-0.0212+/-0.0225+/-0.823+/-0.0964+/-0.0191+/-0.0518 0.136 0.161 0.293 0.0742 0.0558 0.0374 0.0409 0.0998 0.106 0.120 0.0547 0.0655 0.0371 0.042 0.364 0.0742 0.0357 0.0341 0.0249 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH 1 06/06/06 2000 529778 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U -0.00172 +/-0.0113 0.0116 +/-0.0113 BXFI 06/02/06 1548 534448 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description 1 EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 43 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-012F Project: YANKO1204 Sample ID: 162832006 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 40 (25%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.44 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd Contact: Project: East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-013F 162832007 SE 03-MAY-06 12-MAY-06 Client 24.3%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U -Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 1.22 0.0867 0.964 0.878 0.00 0.549 1.81-0.0133 0.0295 0.0615 1.20 0.931 0.00585 0.00999 13.0 0.878 0.00427 0.432+/-0.297+/-0.102+/-0.391+/-0.134+/-0.106+/-0.100+/-0.147+/-0.101+/-0.141+/-0.0867+/-0.0985+/-0.148+/-0.0483+/-0.0382+/-1.30+/-0.134+/-0.0382+/-0.0807 0.146 0.064 0.277 0.0653 0.0448 0.0382 0.0323 0.0856 0.105 0.0765 0.0483 0.0581 0.0404 0.0331 0.241 0.0653 0.032 0.0333+/-0.297+/-0.102+/-0.391+/-0.134+/-0.106+/-0.100+/-0.147+/-0.101+/-0.141+/-0.0867+/-0.0985+/-0.148+/-0.0483+/-0.0382+/-1.30+/-0.134+/-0.0382+/-0.0807 0.305 0.130 0.581 0.136 0.0936 0.0798 0.0698 0.178 0.225 0.157 0.0996 0.121 0.0846 0.0693 0.534 0.136 0.0665 0.0698 0.0427 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/06 2001 529778 1 BXFI 06/02/06 1548 534448 2 0.00301 +/-0.0174 0.0188 +/-0.0174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 45 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013F Project: YANK01204 Sample ID: 162832007 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr9O, solid-ALL FSS 38 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.46 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-014F 162832008 SE 03-MAY-06 12-MAY-06 Client 21%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter.
Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.00364 Curium-242 U 0.0363 -Curium-243/244 U 0.0323 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0124 Plutonium-239/240 U 0.0515 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -2.38 Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.23 Americium-241 U -0.0143 Bismuth-212 0.868 Bismuth-214 0.813 Cesium-134 U 0.0502 -Cesium-137 U -0.00791 Cobalt-60 U 0.0285 Europium-152 U 0.0441 Europium-154 U -0.0149 Europium-155 U 0.0689 Lead-212 1.26 Lead-214 0.876 Manganese-54 U 0.0203 Niobium-94 U 0.00366 Potassium-40 19.0 Radium-226 0.813 Silver-108m U -0.0251 Thallium-208 0.382 Rad Gas Flow Proportional Counting GFPC, Sr90, solid -0. 025 pCi/g Strontium-90 U 0.00827 Rad Liquid Scintillation Analysis+/-0.0405+/-0.0711+/-0.0634+/-0.0534+/-0.0714 0.0368 0.00 0.00+/-0.0405+/-0.0712+/-0.0635 0.161 0.0983 0.0876 0.153 0.0698 pCi/g pCi/g pCi/g pCi/g pCi/g 0.0415 +/-0.0534 0.00 +/-0.0716+/-9.97 8.47 +/-9.98 17.7 pCi/g+/-0.279+/-0.0378+/-0.463+/-0.153 F/-0.0448+/-0.032+/-0.034+/-0.0707+/-0.103+/-0.0893+/-0.165+/-0.143+/-0.033 F/-0.0282+/-1.68+/-0.153+/-0.025+/-0.0739 0.0824 0.0331 0.199 0.0472 0.0345 0.026 0.0307 0.0634 0.0724 0.0541 0.0338 0.0419 0.0297 0.0235 0.220 0.0472 0.0199 0.0249+/-0.279+/-0.0378+/-0.463+/-0.153+/-0.0448+/-0.032+/-0.034+/-0.0707+/-0.103+/-0.0893+/-0.165+/-0.143+/-0.033+/-0.0282+/-1.68+/-0.153+/-0.025+/-0.0739 0.178 0.0681 0.425 0.0999 0.0729 0.0553 0.0667 0.133 0.159 0.112 0.0702 0.0881 0.063 0.050 0.493 0.0999 0.0421 0.0529 0.0226 0.905 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g LCW1 05/30/06 1156 533471 1 LCWI 05/30/06 2129 533472 2 LCW1 06/03/06 0613 533473 3 MJH 1 06/06/06 2029 529778 4 BXFI 06/08/06 1805 534448 5 NXPI 06/03/06 0030 531705 6+/-0.011 0.0105 +/-0.011 LSC, Tritium Dist, Solid -I to 2 pCi/g Tritium U -c 1.0191 +/-0.527 0.443 +/-0.527 47 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: 9106-0004-014F 162832008 Project: YANKO 1204 Client ID: YANKOOl Vol. Recv.: Parameter Qualifier Result Uncertainty Rad Liquid Scintillation Analysis Liquid Scint C14, SolidAllFSS Carbon-14 U 0.134 +/-0.103 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 2.49 +/-21.0 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -2.34 +/-3.32 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0698 +/-0.246 LC TPU MDA Units DF Analyst Date Time Batch Mtd 0.0826 +/-0.103 15.6 +/-21.0 2.83 +/-3.32 0.209 +/-0.246 0.171 32.9 pCi/g pCi/g ATH2 06/03/06 2137 534984 7 SLNI 05/29/06 1542 531618 9 SLNI 05/27/06 0019 531622 10 SXEI 05/30/062232 531704 11 5.77 pCi/g 0.431 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-l1-RC Modified 3 DOE EML HASL-300, Pu-1 -RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified 11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS GFPC, Sr90, solid -0.025 pCi/g Liquid Scint Fe55, Solid-ALL FS 93 85 72 46 79 (15%-125%)
(15%-125%)
(25% ,125%/)(25%-/125%)
(15%-125%)
48 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-014F Project: YANK01204 Sample ID: 162832008 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 77 (25%- 125%)Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (159/6-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.U1 Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.49 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Cet ifc t o ... .a-v- [Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-015F 162832009 SE 03-MAY-06 12-MAY-06 Client 34%Proiect: YANK01204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.832 Americium-241 U 0.0511 Bismuth-212 0.623 Bismuth-214 0.533 Cesium-134 U 0.0265 Cesium-137 0.377 Cobalt-60 0.744 Europium-152 U -0.0395 Europium-154 U 0.0498 Europium-155 U 0.0747 Lead-212 0.833 Lead-214 0.755 Manganese-54 U 0.0147 Niobium-94 U -0.00934 Potassium-40 12.3 Radium-226 0.533 Silver-108m U -0.0066 Thallium-208 0.276 Rad Gas Flow Proportional Counting+/-0.213+/-0.106+/-0.270+/-0.0981+/-0.0323+/-0.0611+/-0.0759+/-0.072+/-0.071+/-0.0598+/-0.0733+/-0.0997+/-0.0271+/-0.0224+1- 1.05+/-0.0981+/-0.023+/-0.0562 0.0785 0.088 0.160 0.044 0.0253 0.0221 0.0218 0.0526 0.0658 0.0586 0.033 0.038 0.0241 0.0188 0.178 0.044 0.019 0.0201+/-0.213+/-0.106+/-0.270+/-0.0981+/-0.0323+/-0.0611+/-0.0759+/-0.072+/-0.071+/-0.0598+/-0.0733+/-0.0997+/-0.0271+/-0.0224+1-1.05+/-0.0981+/-0.023+/-0.0562 0.168 0.182 0.342 0.0927 0.0538 0.047 0.0481 0.111 0.144 0.121 0.0685 0.0799 0.0513 0.0401 0.400 0.0927 0.040 0.0427 0.0408 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/06 2138 529778 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00153 +/-0.0159 0.0181 +/-0.0159 BXF1 06/02/06 1548 534448 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 50 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-015F Proiect: YANKO 1204 Sample ID: 162832009 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 45 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.51 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd Contact: Project: East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-OOIF 162832010 SE 03-MAY-06 12-MAY-06 Client 26.3%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.Curium-242 U (Curium-243/244 U -0.Alphaspec Pu,'Solid-ALL FSS Plutonium-238 U Plutonium-239/240 U -0.0 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 UUI Bismuth-212 (Bismuth-214 (Cesium-134 U 0.0'Cesium-137 Cobalt-60 (Europium-152 U -0.Europium-154 U -0.Europium-155 U 0.0'Lead-212 Lead-214 C Manganese-54 U -0.Niobium-94 U 0.'Potassium-40 Radium-226 C Silver-108m U 0.01 Thallium-208 C Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.0'Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C04, Solid AIlFSS+/-0.0855+/-0.0627+/-0.0605 0.0458 0.00 0.0563+/-0.0857+/-0.0628+/-0.0605 0.169 0.0866 0.190 0.0959 0.176 pCi/g pCi/g pCi/g pCi/g pCi/g 0.00 +/-0.0693 0.00 +/-0.0693 0849 +/-0.0713 0.0403 +/-0.0713-1.69 +/-9.07 7.68 +/-9.07 16.0 pCi/g+/-0.302+/-0.0601+/-0.528+/-0.161+/-0.0697+/-0.0758+/-0.129+/-0.0773+/-0.102+/-0.0644+/-0.0859+/-0.133+/-0.0371+/-0.0302+/-1.42+/-0.161+/-0.0259+/-0.0627 0.110 0.0312 0.246 0.0517 0.039 0.0333 0.0344 0.0623 0.0792 0.0542 0.0341 0.0476 0.0296 0.0274 0.237 0.0517 0.0233 0.029+/-0.302+/-0.0601+/-0.528+/-0.161+/-0.0697+/-0.0758+/-0.129+/-0.0773+/-0.102+/-0.0644+/-0.0859+/-0.133+/-0.0371+/-0.0302+/-1.42+/-0.161+/-0.0259+/-0.0627 0.237 0.0648 0.525 0.110 0.0828 0.0707 0.0754 0.132 0.176 0.113 0.0716 0.101 0.0638 0.0585 0.539 0.110 0.0495 0.0617 0.0398 11.7 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g LCWI 05/30/06 1156 533471 1 LCWI 05/30/06 2129 533472 2 LCWI 06/03/06 0629 533473 3 MJHI 06/06/06 2138 529778 4 BXF1 06/02/06 1548 534448 5 NXPI 05/28/06 0601 531705 6+/-0.017 0.0179 +/-0.017+/-7.01 5.61 +/-7.01 52 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: 9106-0004-OOIF 162832010 Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Liquid Scintillation Analysis Liquid Scint C14, SolidAIl, FSS Carbon- 14 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.268 +/-0.101 0.0769 +/-0.101 9.95 +1-15.5 11.3 +1-15.5-4.23 +/-3.97 3.41 +/-3.97 0.174 +/-0.269 0.220 +/-0.269 0.159 23.7 6.95 0.454 pCi/g pCi/g pCi/g pCi/g ATH2 06/03/06 2339 534984 7 SLN1 05/29/06 1559 531618 9 SLN1 05/27/06 0120 531622 10 SXEI 05/30/062248 531704 II The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 906.0 Modified 7 EPA EERF C-01 Modified 8 EPA EERF C-01 Modified 9 DOE RESL Fe-I, Modified 10 DOE RESL Ni-I, Modified 11 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýGFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS 92 65 84 46 74 (150/- 125%)(15%/,125
%)(2 5%l-I 2 5%)(2 59/- 12 5%)( 15'/- 12 5%)53 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-OOIF Project: YANK01204 Sample ID: 162832010 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 69 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 71 15%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.54 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Report Date: June 9, 2006 Project: Soils PO# 002332 Client Sample ID: 9106-0004-002F Project: YANKO 1204 Sample ID: 162832011 Client ID: YANKOO Matrix: SE Vol. Recv.: Collect Date: 03-MAY-06 Receive Date: 12-MAY-06 Collector:
Client Moisture:
16.8%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS Actinium-228 Americium-241 U 0 Bismuth-212 U Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U -'0.590.000531 0.439 0.436 0.00781 0.171 0.141-0.0415-0.0303 0.0113 0.628 0.506 0.00764-0.0101 9.74 0.436 0.0121 0.197 9.370E-05+/-0.227+/-0.0361+/-0.392+1-0.115+/-0.0309+/-0.0522+/-0.0653+/-0.0655+/-0.078+/-0.057+/-0.067+/-0.110+/-0.0308+/-0.0309+/-1.02+/-0.115+/-0.0208+/-0.0581 0.0948 0.0352 0.213 0.0442 0.0271 0.0221 0.0252 0.0577 0.0627 0.0542 0.0313 0.0414 0.0269 0.0222 0.171 0.0442 0.0197 0.0243+/-0.227+/-0.0361+/-0.392+/-0.115+/-0.0309+/-0.0522+/-0.0653+/-0.0655+/-0.078+/-0.057+/-0.067+/-0.110+/-0.0308+/-0.0309+/-1.02+/-0.115+/-0.0208+/-0.0581 0.207 0.073 0.460 0.0955 0.0592 0.0483 0.0568 0.123 0.143 0.113 0.0659 0.0881 0.0584 0.0481 0.407 0.0955 0.0424 0.0524 0.0417 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/06 2138 529778 1 BXF1 06/02/06 1548 534448 2+/-0.0166 0.0187 +/-0.0166 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 55 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-002F Project: YANKO 1204 Sample ID: 162832011 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr9O, solid-ALL FSS 48 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.56 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-003F 162832012 SE 03-MAY-06 12-MAY-06 Client 20.7%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U -Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium- 137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.837 0.00219 0.534 0.591 0.00 0.355 0.945 0.00575 0.0387 0.0875 0.819 0.690 0.0147 0.0131 12.6 0.591-0.0129 0.258+/-0.133+/-0.109+/-0.216+/-0.0832+/-0.0279+/-0.0442+/-0.0626+/-0.0435+/-0.0557+/-0.0767+/-0.0541+/-0.0799+/-0.0191+/-0.0167+/-0.691+/-0.0832+/-0.0149+/-0.0394 0.0558 0.090 0.119 0.0288 0.0197 0.0145 0.0137 0.0402 0.0492 0.0496 0.0239 0.0284 0.0176 0.0149 0.116 0.0288 0.0128 0.0134+/-0.133+/-0.109+/-0.216+/-0.0832+/-0.0279+/-0.0442+/-0.0626+/-0.0435+/-0.0557+/-0.0767+/-0.0541+/-0.0799+/-0.0191+/-0.0167+/-0.691+/-0.0832+/-0.0149+/-0.0394 0.117 0.186 0.249 0.0602 0.041 0.0306 0.0296 0.0836 0.104 0.102 0.0494 0.0592 0.0367 0.0311 0.253 0.0602 0.0268 0.0282 0.0402 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/06 2139 529778 1 BXFI 06/02/06 1549 534448 2 0.0162 +/-0.0189 0.018 +/-0.0189 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description 1 EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 57 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-003F Project: YANK01204 Sample ID: 162832012 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 45 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.58 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 lnjun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-004F 162832013 SE 03-MAY-06 12-MAY-06 Client 17.9%Project: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U -Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U -0.686 0.00826 0.505 0.495 0.00 0.159 0.263-0.0352 0.0517 0.0077 0.731 0.570 0.0131 0.0134 10.6 0.495 0.00381 0.215+/-0.125+/-0.0518+/-0.187+/-0.060+/-0.0279+/-0.0305+/-0.0399+/-0.0353+/-0.0426+/-0.0363+/-0.042+/-0.0626+/-0.0163+/-0.0199+/-0.623+/-0.060+/-0.0117+/-0.0302 0.0426 0.0509 0.0963 0.0217 0.0165 0.0126 0.0109 0.0291 0.0409 0.0348 0.0183 0.0228 0.0133 0.0113 0.0881 0.0217 0.0106 0.0124+/-0.125+/-0.0518+/-0.187+/-0.060+/-0.0279+/-0.0305+/-0.0399+/-0.0353+/-0.0426+/-0.0363+/-0.042+/-0.0626+/-0.0163+/-0.0199+/-0.623+/-0.060+/-0.0117+/-0.0302 0.0906 0.105 0.203 0.0457 0.0345 0.0265 0.0239 0.0606 0.0874 0.0714 0.0378 0.0473 0.028 0.0239 0.197 0.0457 0.0221 0.0259 0.0435 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/06 2350 529778 1 BXFI 06/02/06 1833 534448 2 0.00759 +/-0.0173 0.020 +/-0.0173 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 59 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.comr Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-004F Project: YANKO 1204 Sample ID: 162832013 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 37 (25%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.60 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd Contact: Project: East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-004FS 162832014 SE 03-MAY-06 12-MAY-06 Client 20.7%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U -Niobium-94 U Potassium-40 Radium-226 Silver-108m U-0 Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 0.947 0.0029 0.561 0.525 0.0375 0.216 0.300 0.00258 0.0578 0.0516 0.775 0.573 0.00468 0.0038 11.6 0.525.000154 0.265+/-0.184+/-0.0207+/-0.213+/-0.0921+/-0.0368+/-0.042+/-0,0499+/-0.0394+/-0.0507+/-0.0462+/-0.0975+/-0.081+/-0.0177+/-0.0149+/-0.941+/-0.0921+/-0.0141+/-0.044 0.0494 0.0199 0.120 0.0275 0.0188 0.0157 0.0141 0.0357 0.0468 0.0341 0.0201 0.0257 0.0154 0.0129 0.124 0.0275 0.0125 0.014+/-0.184+/-0.0207+/-0.213+/-0.0921+/-0.0368+/-0.042+/-0.0499+/-0.0394+/-0.0507+/-0.0462+/-0.0975+/-0.081+/-0.0177+/-0.0149+/-0.941+/-0.0921+/-0.0141+/-0.044 0.105 0.0407 0.251 0.0574 0.0392 0.0329 0.0305 0.0741 0.0997 0.0699 0.0415 0.0533 0.0324 0.027 0.271 0.0574 0.0261 0.0293 0.0394 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/06/06 2350 529778 1 BXF1 06/02/06 1549 534448 2 0.00386 +/-0.0163 0.0175 +/-0.0163 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 61 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006.Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-004FS Proiect: YANK0 1204 Sample ID: 162832014 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr9O, solid-ALL FSS 44 (25%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.62 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005F 162832015 SE 03-MAY-06 12-MAY-06 Client 13.3%Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 1.04 Americium-241 U 0.081 Bismuth-212 0.744 Bismuth-214 0.666 Cesium-134 UUI 0.00 Cesium-137 0.399 Cobalt-60 1.74 Europium-152 U 0.016 Europium-154 U 0.0483 Europium-155 U 0.028 Lead-212 0.976 Lead-214 0.756 Manganese-54 U -0.00383 Niobium-94 U 0.0245 Potassium-40 10.5 Radium-226 0.666 Silver-108m U 0.00682 Thallium-208 0.335 Rad Gas Flow Proportional Counting+/-0.213+/-0.0844+/-0.264+/-0.0896+/-0.0355+/-0.0533+/-0.0845+/-0.052+/-0.0602+/-0.0485+/-0.0593+/-0.0846+/-0.0252+/-0.0192+/-0.695+/-0.0896+/-0.0196+/-0.0501 0.0758 0.0717 0.147 0.0323 0.0245 0.0189 0.0184 0.0457 0.0551 0.0467 0.0274 0.033 0.0214 0.0178 0.136 0.0323 0.0169 0.0169+/-0.213+/-0.0844+/-0.264+/-0.0896+/-0.0355+/-0.0533+/-0.0845+/-0.052+/-0.0602+/-0.0485+/-0.0593+/-0.0846+/-0.0252+/-0.0192+/-0.695+/-0.0896+/-0.0196+/-0.0501 0.158 0.147 0.306 0.0672 0.0509 0.0393 0.0393 0.0944 0.117 0.0956 0.0562 0.0682 0.0445 0.0369 0.297 0.0672 0.035 0.0353 0.0432 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH-1 06/06/06 2350 529778 1 GFPC, SO9O, solid-ALL FSS Strontium-90 U 0.00586 +/-0.0183 0.0193 +/-0.0183 BXFI 06/02/06 1549 534448 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 63 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005F Project: YANK01204 Sample ID: 162832015 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 45 (25- 125%)Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.64 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-006F 162832016 SE 03-MAY-06 12-MAY-06 Client 15.2%Project: Client ID: Vol. Recv.: YANKO 1204 YANKOO1 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 0.984 Americium-241 U -0.0148 Bismuth-212 0.638 Bismuth-214 0.774 Cesium-134 UU1 0.00 Cesium-137 0.112 Cobalt-60 0.223 Europium-152 U -0.0103 Europium-154 U -0.0358 Europium-155 U 0.0827 Lead-212 0.983 Lead-214 0.823 Manganese-54 U 0.0093 Niobium-94 U 0.0043 Potassium-40 9.75 Radium-226 0.774 Silver-108m U -0.00725 Thallium-208 0.351 Rad Gas Flow Proportional Counting+/-0.130+/-0.087+/-0.246+/-0.0668+/-0.0296+/-0.0208+/-0.0348+1-0.035+/-0.0508+/-0.0422+/-0.0474+/-0.0628+/-0.0151+/-0.0138+/-0.555+/-0.0668+/-0.0123+/-0.0337 0.046 0.0606 0.101 0.0237 0.017 0.0134 0.0129 0.0319 0.0343 0.0419 0.0203 0.024 0.0139 0.0121 0.105 0.0237 0.0108 0.0127+/-0.130+/-0.087+/-0.246+/-0.0668+/-0.0296+/-0.0208+/-0.0348+/-0.035+/-0.0508+/-0.0422+/-0.0474+/-0.0628+/-0.0151+/-0.0138+/-0.555+/-0.0668+/-0.0123+/-0.0337 0.0966 0.124 0.211 0.0493 0.0354 0.028 0.0277 0.066 0.0734 0.0855 0.0416 0.0496 0.0291 0.0252 0.229 0.0493 0.0224 0.0264 0.0342 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/06 2351 529778 1 GFPC, S90, solid-ALL FSS Strontium-90 U 0.0101 +/-0.0157 0.0155 +/-0.0157 BXFI 06/02/06 1833 534448 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 65 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-006F Project: YANKO 1204 Sample ID: 162832016 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 42 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.66 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-007F 162832017 SE 04-MAY-06 12-MAY-06 Client 19.7%Project: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 1.74 Americium-241 U -0.0148 Bismuth-212 1.11 Bismuth-214 1.27 Cesium-134 UUI 0.00 Cesium-137 U -0.00561 Cobalt-60 U 0.00116 Europium-152 U -0.0221 Europium-154 U -0.0434 Europium-155 U 0.0586 Lead-212 1.67 Lead-214 1.32 Manganese-54 UUI 0.00 Niobium-94 U 0.0256 Potassium-40 11.4 Radium-226 1.27 Silver-108m U -0.0132 Thallium-208 0.539 Rad Gas Flow Proportional Counting+/-0.191+/-0.0357+/-0.288+/-0.0993+/-0.0481+/-0.0253+/-0.0253+/-0.0593+/-0.0719+/-0.0584+/-0.0714+/-0.0886+/-0.0532+/-0.0217+/-0.713+/-0.0993+/-0.0203+/-0.0503 0.0672 0.0336 0.163 0.0373 0.0291 0.0222 0.0217 0.0522 0.0597 0.0546 0.0298 0.0358 0.019 0.020 0.167 0.0373 0.0172 0.0204+/-0.191+/-0.0357+/-0.288+/-0.0993+/-0.0481+/-0.0253+/-0.0253+/-0.0593+/-0.0719+/-0.0584+/-0.0714+/-0.0886+/-0.0532+/-0.0217+/-0.713+/-0.0993+/-0.0203+/-0.0503 0.141 0.0683 0.337 0.0773 0.0601 0.0459 0.0458 0.107 0.126 0.111 0.061 0.0737 0.0398 0.0414 0.357 0.0773 0.0355 0.0422 0.0333 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/06/06 2351 529778 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U -0.00609 +/-0.0118 0.0147 +/-0.0118 BXF1 06/02/06 1549 534448 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 67 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 9, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-007F Project: YANK01204 Sample ID: 162832017 Client ID: YANKOOl Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits CarrierfIracer Recovery GFPC, Sr90, solid-ALL FSS 52 (25%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J. Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.68 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-017F 162832018 SE 04-MAY-06 12-MAY-06 Client 21%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid FSS GAM & ALL FSS Actinium-228 0.779 Americium-241 U-0.000356 Bismuth-212 0.610 Bismuth-214 0.505 Cesium-134 UU1 0.00 Cesium-137 0.378 Cobalt-60 0.294 Europium-152 U 0.0128 Europium-154 U -0.0423 Europium-155 U 0.027 Lead-212 0.741 Lead-214 0.614 Manganese-54 U 0.0061 Niobium-94 U 0.000512 Potassium-40 11.0 Radium-226 0.505 Silver-108m U -0.00685 Thallium-208 0.281 Rad Gas Flow Proportional Counting+/-0.129+/-0.0171+/-0.204+/-0.0714+/-0.0239+/-0.0359+/-0.0383+/-0.0344+/-0.0448+/-0.0385+/-0.0393+/-0.0628+/-0.0159+/-0.0139+/-0.600+/-0.0714+/-0.0111+/-0.0349 0.0463 0.0159 0.0972 0.0229 0.017 0.0129 0.0124 0.0305 0.0346 0.0238 0.017 0.0222 0.0137 0.012 0.0952 0.0229 0.00983 0.0126+/-0.129+/-0.0171+/-0.204+/-0.0714+/-0.0239+/-0.0359+/-0.0383+/-0.0344+/-0.0448+/-0.0385+/-0.0393+/-0.0628+/-0.0159+/-0.0139+/-0.600+/-0.0714+/-0.0111+/-0.0349 0.0977 0.0326 0.204 0.0479 0.0355 0.0271 0.0268 0.0633 0.0746 0.0489 0.0351 0.0461 0.0289 0.0252 0.210 0.0479 0.0206 0.0264 0.0474 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/06/06 2351 529778 1 GFPC, SO9O, solid-ALL FSS Strontium-90 U 0.0346 +/-0.0241 0.0215 +/-0.0242 BXFI 06/02/06 1549 534448 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B MXP2 05/15/06 0846 529742 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/14/06 1230 529741 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 69 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 9, 2006 Client Sample ID: Sample ID: 9106-0004-017F 162832018 Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 46 (25%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.70 QUALITY CONTROL DATA I 71 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Client : Connecticut Yankee Atomic Power 362 Injun Hollow Rd Report Date: June 9, 2006 Page 1 of 9 East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder:
162832 NJ"" Q I ý1 OC Units RPD%REC% Ranee Anist Date Time* dl Ilil*'.l II J lo.,amps e Rad Alpha Spec Batch 533471 QC1201101118 Americium-241 Curium-242 Curium-243/244 QC1201101120 Americium-241 162485017 DUP U -0.0415 Uncert: +/-0.0591 TPU: +/-0.0591 U -0.00755 Uncert: +/-0.0634 TPU: +/-0.0634 U 0.00112 Uncert: +/-0.0607 TPU: +/-0.0607 LCS Curium-242 Curium-243/244 QC1201101117 MB Americium-241 12.2 Uncert:.TPU: Uncert: TPU: 14.9 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: U -0.00249+/-0.0219+/-0.0219 U 0.0283+/-0.0555+/-0.0556 U 0.0131+/-0.0521+/-0.0521 10.8+/-0.975+/-1.73 U -0.0056+/-0.047+/-0.0471 12.4+/-1.04+/-I.95 U -0.00902+/-0.019+/-0.019 U 0.0399+/-0.0638+/-0.064 U 0.0392+/-0.0626+/-0.0628 pCi/g 177 pCi/g 346 pCi/g 168 Curium-242 Curium-243/244 QC1201101119 162485017 MS Americium-241 Curium-242 Curium-243/244 (0%- 100%) CWI 05/30/06 11:55 (0%- 100%)(0% -100%)pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 83 (75%-125%)
89 (75%-125%)
05/30/06 11:55 05/30/06 11:55 12.7 U -0.0415 Uncert: +/-0.0591 TPU: +/-0.0591 U -0.00755 Uncert: +/-0.0634 TPU: +/-0.0634 15.5 U 0.00112 Uncert: +/-0.0607 TPU: +/-0.0607 U 12.5+/-1 .06+/-1.96 0.00+/-0.0517+/-0.0517 12.6+/-1 .06+/-1.98 98 (75%-125%)
05/30/06 11:55 81 (75%-125%)
Batch 533472 QC1201101122 162485017 DUP Plutonium-238 U 0.0261 U 0.00 pCi/g (0%- 100%) CWI 05/30/06 21:29 72 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162832 Page 2 of 9 Parmname NOM Sample Qual QC Units RPD%REC% Range Anist Date Time Rad Alpha Spec Batch 533472 Plutonium-239/240 QC1201101124 LCS Plutonium-238 Uncert: +/-0.0511 TPU: +/-0.0512 U 0.0459 Uncert: +/-0.0733 TPU: +/-0.0734+/-0.0498+/-0.0498 U -0.00609+/-0.0511+/-0.0512 pCi/g 261 (0%- 100%)(75%-125%)
Plutonium-239/240 QCI201101121 MB Plutonium-238 Plutonium-239/240 QC1201101123 162485017 MS Plutonium-238 Plutonium-239/240 Uncert: TPU: 11.3 Uncert: TPU: Uncert: TPU: Uncert: TPU: 0.216+/-0.181+/-0.182 10.3+/-1.21+/-1.76 U -0.00623+/-0.0692+/-0.0693 U -0.0274+/-0.100+/-0.100 pCilg pCi/g pCi/g pCi/g pCi/g pCi/g 91 (75%-125%)
05/30/06 21:29 05/31/06 07:44 U 0.0261 Uncert: +/-0.0511 TPU: +/-0.0512 11.7 U 0.0459 Uncert: +/-0.0733 TPU: +/-0.0734 U -8.66 Uncert: +/-8.72 TPU: +/-8.77 U Batch 533473 QC1201101126 162485017 DUP Plutonium-241 0.0634+/-0.0787+/-0.079 10.7+/-0.971+/-1.52-6.36+/-6.79+/-6.82 106+/-12.3+/-16.4 (75%-125%)
05/30/06 21:29 92 (75%-125%)
U pCi/g 0 (0% -100%) LCW I QC1201101128 LCS Plutonium-241 QC1201101125 MB Plutonium-241 131 Uncert: TPU: Uncert: TPU: 135 U Uncert: TPU: U -1.18+/-9.02+/-9.02 pCi/g pCi/g pCi/g 81 (75%-125%)
06/03/06 07:35 06/03/06 08:07 06/03/06 07:18 06/03/06 07:51 QC1201101127 162485017 MS Plutonium-24 I Rad Gamma Spec Batch 529778 QC1201092339 162832001 DUP Actinium-228
-8.66+/-8.72+/-8.77 146+/-14.7+/-20.1 108 (75%-125%)
0.655+/-0.137 Uncert: 0.804+/-0.0979+/-0.0979 pCi/g 20 (0% -100%) MJHI 06/06/06 23:52 73 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162832 Page 3 of 9 Parmname NOM Sample Qual OC Units RPD%REC% Range Anist Date Time Rad Gamma Spec Batch 529778 Americium-241 Bismuth-212 Bismuth-214 Cesium- 134 Cesium- 137 Cobalt-60 Europium-152 Europium-154 Europium-155 TPU: +/-0.137 u 0.0325 U 0.0192 pCi/g 52 Uncert: +/-0.0823
+/-0.0754 TPU: +/-0.0823
+/-0.0754 0.551 0.361 pCi/g 42 Uncert: +/-0.165 +/-0.163 TPU: +/-0.165 +/-0.163 0.447 0.498 pCi/g 1I Uncert: +/-0.0787
+/-0.0532 TPU: +/-0.0787
+/-0.0532 U 0.0255 UUI 0.00 pCi/g 53 Uncert: +/-0.0237
+/-0.0216 TPU: +/-0.0237
+/-0.0216 0.155 0.252 pCi/g 48 Uncert: +/-0.0273
+/-0.0264 TPU: +/-0.0273
+/-0.0264 0.256 0.361 pCi/g 34 Uncert: +/-0.046 +/-0.0362 TPU: +/-0.046 +/-0.0362 U 0.0135 U -0.03 pCi/g 528 Uncert: +/-0.0376
+/-0.0305 TPU: +/-0.0376
+/-0.0305 U 0.000575 U 0.00301 pCi/g 136 Uncert: +/-0.048 +/-0.0385 TPU: +/-0.048 +/-0.0385 U 0.015 U 0.0377 pCi/g 86 Uncert: +/-0.0405
+/-0.0364 TPU: +/-0.0405
+/-0.0364 0.609 0.785 pCi/g 25 Uncert: +/-0.0665
+/-0.0398 TPU: +/-0.0665
+/-0.0398 0.566 0.640 pCi/g 12 Uncert: +/-0.0835
+/-0.053 TPU: +/-0.0835
+/-0.053 UU1 0.00 U -0.00338 pCi/g 239 Uncert: +/-0.0194
+/-0.014 TPU: +/-0.0194
+/-0.014 U 0.00427 U 0.00622 pCi/g 37 Uncert: +/-0.0141
+/-0.0108 TPU: +/-0.0141
+/-0.0108 10.8 12.9 pCi/g 18 Uncert: +/-0.957 +/-0.513 TPU: +/-0.957 +/-0.513 0.447 0.498 pCi/g 1I Uncert: +/-0.0787
+/-0.0532 TPU: +/-0.0787
+/-0.0532 U 0.00155 U 0.000741 pCi/g 71 Uncert: +/-0.0131
+/-0.0105 (0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 20%)(0%- 20%)(0%- 100%)(0%- 100%)(0%- 20%)(0%- 100%)(0%- 100%)Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver- 108m 74 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162832 Page 4 of 9 NJ '<.1Nin"l nuall OC Units RPD%REC% Range Anist Date Time Rad Gamma Spec Batch 529778 Thallium-208 TPU: +/-0.0131 0.194 Uncert: +/-0.042 TPU: +/-0.042+1-0.0105 0.230+/-0.0259+/-0.0259 pCi/g 17 (0%-100%)QC1201092340 Actinium-228 Americium-24 l Bismuth-212 LCS Bismuth-214 Cesium- 134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Uncert: TPU: 23.4 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: 9.64 Uncert: TPU: 15.1 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: U 0.589+/-0.539+/-0.539 21.4+/-3.52+/-3.52 U -0.211+/-1.02+/-1.02 U -0.102+/-0.244+/-0.244 U -0.0153+/-0.147+/-0.147 10.1+/-0.792+/-0.79215.3+/-1.14+/-1.14 U -0.0723+/-0.330+/-0.330 U -0.186+/-0.319+/-0.319 U -0.00538+/-0.364+/-0.364 U 0.193+/-0.187+/-0.187 U -0.117+/-0.232+/-0.232 U 0.0588+/-0.137+/-0.137 U 0.00234+/-0.126+/-0.126 U -0.473 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 105 (75%-125%)
102 (75%-125%)
91 (75%-125%)
06/06/06 20:05 Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 75 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162832 Page 5 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 529778 Radium-226 Silver-I 08m Thallium-208 QC1201092338 Actinium-228 Americium-241 MB Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU:+/-1.12+/-1.12 U -0.102+/-0.244+/-0.244 U -0.00368+/-0.117+/-0.117 U -0.0624+/-0.137+/-0.137 U 0.0718+/-0.0476+/-0.0476 U 0.00824+/-0.0133+/-0.0133 U 0.026+/-0.164+/-0.164 U 0.00907+/-0.0339+/-0.0339 U 0.00557+/-0.0132+/-0.0132 U -0.0114+/-0.0125+/-0.0125 U 0.000917+/-0.0131+/-0.0131 U 0.0155+/-0.0264+/-0.0264 U 0.00784+/-0.0345+/-0.0345 U 0.016+/-0.0209+/-0.0209 UUI 0.00+/-0.0304+/-0.0304 U 0.0403+/-0.0337+/-0.0337 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 06/06/06 23:51 (75%-125%)
Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 76 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162832 Page 6 of 9 NnN'A Qý I " ý1I ]nltc g R2nao Anlcf nr ll..*. Dpno/- Rvco/- Ran .A.1.* ný# Ir.Rad Gamma Spec Batch 529778 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver- 108m Thallium-208 Rad Gas Flow Batch Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: U 0.00515+/-0.0114+/-0.0114 U 0.00872+/-0.0117+/-0.0117 U 0.0972+/-0.106+/-0.106 U 0.00907+/-0.0339+/-0.0339 U 0.0115+/-0.00907
+/-0.00907 U 0.00346+/-0.0168+/-0.0168 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 534448 QC1201103435 162832001 DUP Strontiurn-90 QCI201103437 LCS Strontium-90 QC1201103434 MB Strontium-90 QC1201103436 162832001 MS Strontium-90 Rad Liquid Scintillation Batch 531618 QC1201096632 163173001 DUP Iron-55 U 0.0262 Uncert: +/-0.0216 TPU: +/-0.0217 U 0.00157+/-0.0157+/-0.0157 1.16+/-0.0871+/-0.0923 pCi/g 0 (0% -100%) BXFI 1.41 Uncert: TPU: Uncert: TPU: 1.51 U Uncert: TPU: U -0.000243+/-0.0111+/-0.0111 pCi/g pCi/g pCi/g 82 (75%-125%)
06/02/06 15:47 06/02/06 15:47 06/02/06 15:47 06/02/06 15:47 0.0262+/-0.0216+/-0.0217 1.16+/-0.0901+/-0.0968 77 (75%-125%)
U 10.3 Uncert: +/-20.1 TPU: +/-20.1 U 5.38+/-18.0+/-18.1 pCi/g 0 (0% -100%) SLNI QC1201096634 LCS Iron-55 QC1201096631 MB Iron-55 437 Uncert: TPU: 428+/-40.6+/-62.3 pCi/g 98 (75%-125%)
05/31/06 12:49 05/31/06 13:22 05/31/06 12:32 U 3.58 pCi/g 77 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162832 Page 7 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Liquid Scintillation Batch 531618 Uncert: TPU: QC0201096633 163173001 MS Iron-55 569 U Uncert: TPU: 10.3+/-20.1+/-20.1+/-24.7+/-24.7 544+/-39.3+/-69.3-5.49+/-4.33+/-4.33 pCi/g 96 (75%-125%)
05/31/06 13:05 Batch 531622 QC1201096645 163173001 DUP Nickel-63 QC1201096647 LCS Nickel-63 QC1201096644 MB Nickel-63 QC1201096646 163173001 MS Nickel-63 U -6.64 Uncert: +/-7.30 TPU: +/-7.31 362 Uncert: TPU: U pCi/g 0 (0% -100%) SLNI 301+/-7.49+/-11.1 U -1.66+/-3.41+/-3.41 pCi/g pCi/g pCi/g 83 (75%-125%)
05/28/06 01:38 05/28/06 03:40 05/28/06 00:37 05/28/06 02:39 Uncert: TPU: 460 U Uncert: TPU:-6.64+/-7.30+/-7.31 395+/-9.22+/-14.9 86 (75%-125%)
Batch 531704 QC1201096868 162583001 DUP Technetium-99 QC1201096870 LCS Technetium-99 U 0.161 Uncert: +/-0.254 TPU: +/-0.255 12.5 Uncert: TPU: QC1201096867 Technetium-99 MB Uncert: TPU: U 0.239+/-0.273+/-0.273 11.1+/-0.474+/-0.545 U 0.163+/-0.214+/-0.214 11.6+/-0.583+/-0.649 U 6.01+/-4.70+/-4.70 pCi/g pCi/g pCi/g pCi/g 0 (0% -100%) SXEI 89 (75%-125%)
05/31/06 00:27 05/31/06 01:00 05/31/06 00:11 05/31/06 00:44 QC1201096869 162583001 MS Technetium-99 13.1 U Uncert: TPU: 0.161+/-0.254+/-0.255 89 (75%-125%)
Batch 531705 QC1201096878 162583001 DUP Tritium U 1.17 Uncert: +/-4.09 TPU: +/-4.09 pCi/g 0 (0%- 100%) NXPI 05/28/06 09:10 QC1201096880 LCS Tritium 41.4 Uncert: TPU: 44.8+/-5.68+/-5.73 pCi/g 108 (75%-125%)
05/28/06 10:14 78 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162832 Page 8 of 9 REC% Range Anist Parmname NOM Samnie Oual OC Units RPD%Date Time Rad Liquid Scintillation Batch 531705 QC1201096877 MB Tritium Uncert: TPU: U 0.0641+/-0.533+/-0.533 pCi/g pCi/g 06/03/06 05:11 05/28/06 09:42 QC1201096879 162583001 MS Tritium 45.7 U Uncert: TPU: 1.17+/-4.09+/-4.09 Batch 534984 QC1201104746 163173001 DUP Carbon- 14 QC1201104748 LCS Carbon- 14 QC0201104745 MB Carbon-14 QC1201104747 163173001 MS Carbon- 14 U 0.00714 Uncert: +/-0.0996 TPU: +/-0.0996 U 52.3+/-6.44+/-6.50 0.00246+/-0.103+/-0.103 11.3+/-0.855+/-0.873 114 (75%-125%)
pCi/g 0 (0%- 100%) ATH2 06/05/06 03:00 12.1 Uncert: TPU: Uncert: TPU: 12.9 U Uncert: TPU: U -0.0368+/-0.101+/-0.101 pCi/g pCi/g pCi/g 94 (75%-125%)
06/05/06 05:20 06/05/06 00:57 06/05/06 05:02 0.00714+/-0.0996+/-0.0996 12.1+/-0.917+/-0.936 94 (75%-125%)
Notes: The Qualifiers in this report are defined as follows: A BD C D H J N/A R U U1 X Y A A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported The TIC is a suspected aldol-condensation product Results are either below the MDC or tracer recovery is low Analyte has been confirmed by GC/MS analysis Results are reported from a diluted aliquot of the sample Analytical holding time was exceeded Value is estimated Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more Sample results are rejected Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.Gamma Spectroscopy--Uncertain identification Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier QC Samples were not spiked with this compound RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL Preparation or preservation holding time was exceeded 79 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162832 Page 9 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time h N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.** Indicates analyte is a surrogate compound.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.80 Table of Contents General Narrative
...................................................................
1 Chain of Custody And Supporting Dpcumentation
...........
5 Radiological Analysis ...........................................................
12 Sample Data Summary ............................
18 Q uality C ontrol D ata ............................................................
60 General Narrative 1 CASE NARRATIVE For CONNECTICUT YANKEE RE: Soil PO# 002332 Work Order: 170256 SDG: MSR #06-1160 September 6, 2006 Laboratory Identification:
General Engineering Laboratories, LLC Mailing Address: P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address: 2040 Savage Road'Charleston, South Carolina 29407 Telephone Number: (843) 556-8171 Summary: Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC,' (GEL)in Charleston, South Carolina on August 25, 2006. All sample containers arrived without any visible signs of tampering or breakage.
The chain of custody contained the proper documentation and. signatures.
The laboratory received the following sample(s):
Sample 11) Client Sample ID 170256001 9106-0006-005A 170256002 9106-0006-005B
.170256003 9106-0006-005C 170256004 9106-0006-005D 170256005 9106-0005-0IOA 170256006 9106-0005-OIOB 170256007 9106-0005-OIOC 170256008 9106-0005-OIOD 170256009 9106-0014-033A GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.P.O. Box 30712 -Charlesion, SC 29417
- 2040 Savage Road (29407)Phone (843) 556-8171
- Fax 243) 766-1178 -www.gel.com 170256010 9106-0014-033B 170256011 9106-0014-033C 170256012 9106-0014-033D 170256013 9106-0004-013A 170256014 9106-0004-013B 170256015 9106-0004-013C 170256016 9106-0004-013D 170256017 9106-0004-005A 170256018 9106-0004-005B 170256019 9106-0004-005C 170256020 9106-0004-005D Items of Note: There are no items of note.Case Narrative:
Sample analyses were conducted using methodology as outlined in General Engiil eering Laboratories (GEL) Standard Operating Procedures.
Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.
Analytical Request: Twenty soil samples were analyzed for FSSGAM and Sr-90.Internal Chain of Custody: Custody was maintained for the sample(s).
Data Package: The enclosed data package contains the following sections:
Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.
I certify that this data package is in compliance with the SOW, both technically aid for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or.ja designee, as verified by the following signature.
Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP INC. !i P.O. Box 30712 -Charleston, SC 29417 -2040 Savage Road (29407)Phone (843) 556-8171
- 766-1178 -www.gel.com List of current GEL Certifications as of 06 September 2006 State Alaska Arizona Arkansas_. CLIA California
]Colorado-
_ __[ Conecticut I Dept. of Navy EPA Florida/NELAP Georgia Idaho Illinois Indiana Kansas Kentucky Maryland Massachusetts Michigan -_ __ Nevada New Jersey New York North Carolina North Carolina Drinking W North Dakota i Oklahoma Pennsylvania Certification UST-062 AZ0668 88-0651"
.0)1151iCA
... .(enEngLabs PH-0169 RFES I 4 13j ----WG-tI5J E7 156 E87156 (FL/NELAP)
N/A 200029 E-10332 90129 M-SCO12_____ 9903 SC12 SC002.-233.... ..457609_R-158 9904 68-485 South Carolina 10120001/10585001/1 0120002 Tennessee 02934 Texas TX213-2006A
-U.S. Dept.of Agriculture
§-52597 .US Army Corps of Engineer N/A Utah 8037697376 GEL Vermont N/A Virginia 00151 .Washington C223 I 4 Chain of Custody And Supporting Documentation 5
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00511 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8t71. Attn. Cheryl Jones U rA' V Priority:
[] 30 D. 2 14 D. [E 7 D. Container
'f______Sample Size- C -z Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample 1D 9106-0006-005A 8/8/06 14:35 SE C BP X X Transferred from COC # 2006-00488 9106-0006-005B 8/8/06 15:08 SE C BP X X Tranrsferred from COC # 2006-00488 9106-0006-005C 8/9/06 07:46 SE C BP X X Transferred from COC # 2006-00307 9106-0006-005D 8/9/06 08:18 SE C BP X X Transferred from COC # 2006-00307 NOTES: PO#: 002332 MSR#: 06-1160 SSWP#NA SLTP QA El Radwaste QA 1-El Non QA 1) Relinquished By Date/Time 2)" ,vedBy Date/Time JAI 6- ý-OV1/340 o ,, (I, -1 ogo0 Samples Shipped Via: E Fed Ex El ups ElHand El Other Bill of Lading #V00' 4~3 641f Internal Container Temp.: Deg. C Custody Sealed?YO -N E Custody Seal Intact?YC NO 3) Relinquished By Date/Time 4) ROceived By'f-1" Date/Time Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00512 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)General Engineering Laboratories o 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones C n Priority:
[1] 30 D. 0 14 D. El 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0005-OIOA 8/9/06 09:03 SE C BP x x Transferred from COC # 2006-00489 9106-0005-01OB 8/9/06 09:33 SE C BP X X Transferred from COC # 2006-00489 9106-0005-01OC 8/9/06 10:04 SE C BP X x Transferred from COC # 2006-00489 9106-0005-01OD 8/9/06 10:56 SE C BP X X Transferred from COC # 2006-00489 NOTES: PO #: 002332 MSR #: 06- 110 SSWP# NA Z LTP QA[] Radwaste QA El Non QA 1) Relinquished By Dat /Time 2) ceived By D te/Time 3) Relinquished By I6ate/rime 49fceived By L --1ate/Ttme Samples Shipped Via: Z Fed Ex El ups C1 Hand[ Other Bill of Lading #?qV0 4631 6419 Internal Container Temp.: __ Deg. C Custody Sealed?YQ NO Custody Seal Intact?YO NO GPP-GGGR-R5104-003-Attachment B-CY-00 1 Major 1, Health Physics Procedure Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00513 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones C Priority:
[ 30 D. Z 14 D. El 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0014-033A 8/11/06 07:58 SE C BP X X Transfenre
'from COC # 2006-00493 39106-0014-033B 8/11/06 08:24 SE C BP X X Transferred from C0C # 2006-00493 9106-0014-033C 8/11/06 08:45 SE C BP X X Transferred from COC # 2006-00493 9106-0014-033D 8/11/06 09:16 SE C BP X X Transferred from COC # 2006-00493 NOTES: PO #: 002332 MSR #: 06-1160 SSWP# NA Z LTP QA El Radwaste QA E] Non QA 1) Relinquished By Da e/Time 2) ived By Date/Time 01)1 RelnqusheTB Df2-/4 4o 71349 (Xh By "- V. & X4)0 3) Relinquished By Date/Time
- 4) R4ed By D7late/rime Samples Shipped Via: Z Fed Ex F1 UPS[] Hand El Other Bill of Lading #ý9oo 40q' 6'44q Internal Container Temp.: -Deg. C-Custody Sealed? -YE] NE]Custody Seal Intact?YE] NO Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00520 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)General Engineering Laboratories (c 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Q CA W Priority:
El 30 D. 10 14 D. E] 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0004-013A 8/9/06 12:53 SE C BP X X Transferred from COC 2006-00490 9106-0004-013B 8/9/06 13:27 SE C BP X X Transtfrred from COC 2006-00490 "9106-0004-013C 8/9/06 13:57 SE C BP X X Transferred from COC 2006-00490 9106-0004-013D 8/9/06 14:28 SE C BP X X Transferred from COC 2006-00490 9106-0004-OOSA 8/9/06 14:58 SE C BP x x Transferred from COC 2006-00490 9106-0004-005B 8/10/06 07:41 SE C BP X X Transferred from COC 2006-00491 9106-0004-OOSC 8/10/06 08:09 SE C BP X X Transferred from COC 2006-00491 9106-0004-005D 8/10/06 08:49 SE C B P X X Transferred from COC 2006-00491 NOTES: PO #: 002332 MSR#: 06-110e3 SSWP#NA Z LTP QA El Radwaste QA [] Non QA l) Relinquished By Date ime 2) Re ved By Date/Time 3) Relinquished By Date/Time 46ceived By Samples Shipped Via: Z Fed Ex[] ups[1 Hand[] Other Bill of Lading #79,9o 46ý3?14(Internal Container Temp.: _ Deg. C Custody Sealed?-- --Yr N Custody Seal Intact?YD N0 Connecticut Yankee Statement of Work for Analytical Lab Services_CylSCS0w_001 CY-lsc-sOw-o0l Figure 1. Sample Check-in List Date/Time Received: SDG#: / .-O.-- ..O Work Order Number.Shipping Cdntainer ID:A _ f3 .. Chain of Custody#1.. Custody Seals ori shipping container intact?.2. Custody Seals dated and signed?3. Chain-of-Custody record present?.4. Cooler temperature
_ ' "" 5. Vermiculite/packing materials is: 6. Number of samples in shipping container:
- 7. Sample holding times exceeded?I.-Yes I.j1~o ( 1 Yes HS"oc I Yes'ý- h " 605-1pa T.Wet HiTry (;,, wo 1,j Yes [,No [ i.8.8.Samples have:'_,etwitody seals i..-..hazard labels-appropriate sample labels 9. Samples are:'w0gog d condition leaking !-"broken ..Jiave air bubbles 10. Were any anomalies identified in sample receipt? .Yes [ No 11. .Description of anomalies (include sample numbers):/' .Telephoned i 10 I -Connecticut Yankee " Statement of Work for Analytical Lab Services -I -CY-SC-SOW-OO1 Figure 1. Sample Check-in List.Datefrime Received.
5 /4 SDG #:/ V -or -Work Order Nuntber: i tiD t2 0 Chain o utd# .4 T Shipping Cdhtatner of Custo.edy
- . 2 -" 1. Custody Seals od shipping container intact?_ Yes [4 o \ ]2. Custody Seals dated and signed? Yesk No f[J" 3. Chain-of-Custody record present? Yes E.hNo.4. Cooler temperature
.22 -5. Vermiculile/packing materials is: Wet W-'5ry, I 6 .' Number of sainples in shipping container:
- 7. Sample holding times exc'eeded?
Yes Lr,,"o [Le4l(, 11 RADIOLOGICAL ANALYSIS 12 Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)Work Order 170256 Method/Analysis Information Product: Analytical Method: Prep Method: Analytical Batch Number: Prep Batch Number: Sample ID 170256001 170256002 170256003 170256004 170256005 170256006 170256007 170256008 170256009 170256010 170256011 170256012 170256013 170256014 170256015 170256016 170256017 170256018 170256019 170256020 1201171525 1201171526 1201171527 Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived EML HASL 300, 4.5.2.3 Dry Soil Prep 563436 562444 Client ID 9106-0006-005A 9106-0006-005B 9106-0006-005C 9106-0006-005D 9106-0005-O1OA 9106-0005-OIOB 9106-0005-OIOC 9106-0005-OIOD 9106-0014-033A 9106-0014-033B 9106-0014-033C 9106-0014-033D 9106-0004-013A 9106-0004-013B 9106-0004-013C 9106-0004-013D 9106-0004-005A 9106-0004-005B 9106-0004-005C 9106-0004-005D Method Blank (MB)170256001(9106-0006-005A)
Sample Duplicate (DUP)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this 13 narrative has been analyzed in accordance with GL-RAD-A-013 REV# 12.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (Q0 Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 170256001 (9106-0006-005A).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Samples 170256007 (9106-0005-010C), 170256016 (9106-0004-013D) and 170256019 (9106-0004-005C) were recounted due to high MDAs.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information 14 Qualifier U'UI Reason Data rejected due to high counting uncertainty Data rejected due to interference.
Data rejected due to low abundance.
U'Analyte Bismuth-212 Europium-155 Bismuth-214 Cesium- 134 Europium-155 Sample 170256009 170256003 170256009 170256019 170256020 170256008 170256005 170256007 170256008 170256012 170256013 170256019 1201171526 170256018 Method/Analysis Information Product: Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: GFPC, Sr90, solid-ALL FSS EPA 905.0 Modified Ash Soil Prep Dry Soil Prep 562563 562478 562444 15 Sample ID 170256001 170256002 170256003 170256004 170256005 170256006 170256007 170256008 170256009 170256010 170256011 170256012 170256013 170256014 170256015 170256016 170256017 170256018 170256019 170256020 1201169421 1201169422 1201169423 1201169424 Client ID 9106-0006-005A 9106-0006-005B 9106-0006-005C 9106-0006-005D 9106-0005-OIOA 9106-0005-OIOB 9106-0005-OIOC 9106-0005-OIOD 9106-0014-033A 9106-0014-033B 9106-0014-033C 9106-0014-033D 9106-0004-013A 9106-0004-013B 9106-0004-013C 9106-0004-013D 9106-0004-005A 9106-0004-005B 9106-0004-005C 9106-0004-005D Method Blank (MB)170256002(9106-0006-005B)
Sample Duplicate (DUP)170256002(9106-0006-005B)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 170256002 (9106-0006-005B).
16 QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Samples were recounted due to low/high recovery.Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator.
In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.The following data validator verified the information presented in this case narrative:
Reviewer/Date:
K 1/ex-a 17 SAMPLE DATA
SUMMARY
18 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co.Client SDG: MSR#06-1160 GEL Work Order: 170256 The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification ND The analyte concentration is not detected above the detection limit.The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures.
Please direct any questions to your Project Manager, Cheryl Jones.Reviewed by 19 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Report Date: September 8, 2006 Project: Soils PO# 002332 Client Sample ID: 9106-0006-005A Project: YANK0 1204 Sample ID: 170256001 Client ID: YANKOO Matrix: SE Vol. Recv.: Collect Date: 08-AUG-06 Receive Date: 25-AUG-06 Collector:
Client Moisture:
15.8%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.966 +/-0.192 Americium-241 U 0.0375 +/-0.0387 Bismuth-212 0.366 +/-0.306 Bismuth-214 0.650 +/-0.135 Cesium-134 U 0.0366 +/-0.0355 Cesium-137 0.0666 +/-0.0355 Cobalt-60 0.104 +/-0.0726 Europium-152 U 0.00636 +/-0.0728 Europium-154 U -0.0788 +/-0.0938 Europium-155 U 0.0672 +/-0.0554 Lead-212 0.871 +/-0.0971 Lead-214 0.727 +/-0.105 Manganese-54 U -0.00916 +/-0.0319 Niobium-94 U 0.0101 +/-0.0244 Potassium-40 11.3 +/-0.986 Radium-226 0.650 +/-0.135 Silver-108m U -0.0067 +/-0.0208 Thallium-208 0.283 +/-0.0618 Rad Gas Flow Proportional Counting 0.0743 0.0329 0.175 0.042 0.0288 0.0236 0.0286 0.0538 0.0718 0.0518 0.0305 0.0379 0.0232 0.0223 0.201 0.042 0.018 0.0212+/-0.192+/-0.0387+/-0.306+/-0.135+/-0.0355+/-0.0355+/-0.0726+/-0.0728+/-0.0938+/-0.0554+/-0.0971+/-0.105+/-0.0319+/-0.0244+/-0.986+/-0.135+/-0.0208+/-0.0618 0.149 0.0658 0.350 0.0839 0.0576 0.0472 0.0573 0.108 0.143 0.104 0.061 0.0757 0.0465 0.0445 0.403 0.0839 0.036 0.0423 0.0298 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/01/06 1057 563436 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.0254 +/-0.0193 0.0126 +/-0.0193 KSDI 09/07/06 1742 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 20 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0006-005A Project: YANKO1204 Sample ID: 170256001 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 96 (251/6-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.21 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Certificateof Analvsis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005B 170256002 SE 08-AUG-06 25-AUG-06 Client 14.4%Proiect: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.606 +/-0.152 Americium-241 U 0.101 +/-0.114 Bismuth-212 0.685 +/-0.232 Bismuth-214 0.435 +/-0.0852 Cesium- 134 U 0.0313 +/-0.0286 Cesium-137 0.114 +/-0.0348 Cobalt-60 0.436 +/-0.0586 Europium-152 U -0.0448 +/-0.0525 Europium-154 U -0.0186 +/-0.0685 Europium-155 U 0.0423 +/-0.0579 Lead-212 0.643 +/-0.0623 Lead-214 0.462 +/-0.0885 Manganese-54 U -0.0167 +/-0.0261 Niobium-94 U 0.00909 +/-0.0195 Potassium-40 11.1 +/-0.983 Radium-226 0.435 +/-0.0852 Silver-108m U -0.00194 +/-0.0168 Thallium-208 0.243 +/-0.0457 Rad Gas Flow Proportional Counting 0.0599 0.0861 0.134 0.0332 0.0238 0.0206 0.0151 0.0416 0.0562 0.0552 0.0268 0.033 0.0174 0.0173 0.179 0.0332 0.0149 0.0176+/-0.152+/-0.114+/-0.232+/-0.0852+/-0.0286+/-0.0348+/-0.0586+/-0.0525+/-0.0685+/-0.0579+/-0.0623+/-0.0885+/-0.0261+/-0.0195+/-0.983+/-0.0852+/-0.0168+/-0.0457 0.131 0.179 0.290 0.0708 0.0507 0.0438 0.0345 0.0882 0.124 0.114 0.056 0.0696 0.0377 0.0369 0.399 0.0708 0.0317 0.0377 0.0278 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1220 563436 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.00501 +/-0.0149 0.0117 +/-0.0149 KSD1 09/07/06 1742 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 22 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0006-005B Proiect: YANKO 1204 Sample ID: 170256002 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrierf[racer Recovery GFPC, Sr90, solid-ALL FSS 101 (25%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery, limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.23 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005C 170256003 SE 09-AUG-06 25-AUG-06 Client 31.7%Project: YANKO1204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.07 +/-0.284 Americium-241 U 0.0251 +/-0.0367 Bismuth-212 0.684 +/-0.424 Bismuth-214 0.673 +/-0.121 Cesium-134 U 0.0516 +/-0.0548 Cesium-137 0.317 +/-0.0544 Cobalt-60 0.821 +/-0.0911 Europium-152 U -0.049 +/-0.0652 Europium-154 U 0.0883 +/-0.0913 Europium-155 UI 0.00 +/-0.0926 Lead-212 1.01 +/-0.0819 Lead-214 0.828 +/-0.117 Manganese-54 U -0.0228 +/-0.0296 Niobium-94 U -0.0353 +/-0.0279 Potassium-40 12.4 +/-1.15 Radium-226 0.673 +/-0.121 Silver-108m U 0.00475 +/-0.0263 Thallium-208 0.382 +/-0.0567 Rad Gas Flow Proportional Counting 0.101 0.0332 0.178 0.0445 0.0344 0.0247 0.0294 0.0539 0.0839 0.0506 0.0329 0.0423 0.0238 0.0205 0.189 0.0445 0.0227 0.0242+/-0.284+/-0.0367+/-0.424+/-0.121+/-0.0548+/-0.0544+/-0.0911+/-0.0652+/-0.0913+/-0.0926+/-0.0819+/-0.117+/-0.0296+/-0.0279+/-1.15+/-0.121+/-0.0263+/-0.0567 0.215 0.0683 0.383 0.0947 0.0729 0.0528 0.064 0.114 0.182 0.105 0.0685 0.089 0.0513 0.044 0.431 0.0947 0.0477 0.0515 0.0255 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1221 563436 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.00738 +/-0.0142 0.0107 +/-0.0142 KSD1 09/07/06 1745 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 24 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0006-005C Project: YANK01204 Sample ID: 170256003 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 104 (25%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.25 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis C et if c t o .. .. .... .. .... i Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005D 170256004 SE 09-AUG-06 25-AUG-06 Client 28.2%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.01 +/-0:197 Americium-241 U 0.0605 +/-0.132 Bismuth-212 0.534 +/-0.328 Bismuth-214 0.594 +/-0.105 Cesium-134 U 0.0478 +/-0.046 Cesium-137 0.103 +/-0.0401 Cobalt-60 0.148 +/-0.0644 Europium-152 U 0.00143 +/-0.0589 Europium-154 U 0.0154 +/-0.0766 Europium-155 U 0.0625 +/-0.0643 Lead-212 0.900 +/-0.0831 Lead-214 0.854 +/-0.106 Manganese-54 U -0.013 +/-0.0244 Niobium-94 U 0.0144 +/-0.022 Potassium-40 11.6 +/-0.886 Radium-226 0.594 +/-0.105 Silver-108m U 0.0118 +/-0.0187 Thallium-208 0.310 +/-0.0591 Rad Gas Flow Proportional Counting 0.0659 0.088 0.168 0.0384 0.0253 0.0181 0.0204 0.0517 0.0653 0.0586 0.0345 0.0372 0.0203 0.0192 0.177 0.0384 0.0169 0.0199+/-0.197+/-0.132+/-0.328+/-0.105+/-0.046+/-0.0401+/-0.0644+/-0.0589+/-0.0766+/-0.0643+/-0.0831+/-0.106+/-0.0244+/-0.022+/-0.886+1-0.105+/-0.0187+/-0.0591 0.143 0.182 0.358 0.0813 0.0537 0.0389 0.045 0.109 0.142 0.121 0.0714 0.078 0.0434 0.0408 0.396 0.0813 0.0357 0.0422 0.0376 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1221 563436 1 GFPC, S90, solid-ALL FSS Strontium-90 U 0.000446 +/-0.0198 0.0166 +/-0.0198 KSDI 09/07/06 1740 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 26 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: 9106-0006-005D 170256004 Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 50 (25%-.125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.27 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-OIOA 170256005 SE 09-AUG-06 25-AUG-06 Client 60.7%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.22 Americium-241 U 0.0503 Bismuth-212 0.628 Bismuth-214 0.834 Cesium-134 UI 0.00 Cesium-137 U 0.0463 Cobalt-60 U 0.077 Europium-152 U 0.00822 Europium-154 U-0.000512 Europium-155 U 0.0659 Lead-212 0.933 Lead-214 0.787 Manganese-54 U -0.0199 Niobium-94 U -0.0359 Potassium-40 20.0 Radium-226 0.834 Silver-108m U -0.00415 Thallium-208 0.347 Rad Gas Flow Proportional Counting+/-0.394+/-0.0522+/-0.547+/-0.160+/-0.0832+/-0.0542+/-0.0516+/-0.0958+/-0.129+1-0.115+/-0.111+/-0.146+/-0.0442+/-0.0364+1-1.50+/-0.160+/-0.0338+/-0.0918 0.120 0.0424 0.277 0.0633 0.0429 0.0333 0.0472 0.0766 0.0917 0.0674 0.0593 0.0602 0.0342 0.0275 0.288 0.0633 0.0282 0.0332+/-0.394+/-0.0522+/-0.547+/-0.160+/-0.0832+/-0.0542+/-0.0516+/-0.0958+/-0.129+1-0.115+/-0.111+/-0.146+/-0.0442+/-0.0364+/-1.50+/-0.160+/-0.0338+/-0.0918 0.255 0.0872 0.584 0.133 0.0903 0.0703 0.100 0.160 0.199 0.139 0.122 0.125 0.0725 0.0583 0.634 0.133 0.0591 0.0698 0.0274 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/01/06 1221 563436 1 GFPC, S90, solid-ALL FSS Strontium-90 U 0.00442 +/-0.0146 0.0116 +/-0.0146 KSD1 09/07/06 1745 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 28 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010A Project: YANK01204 Sample ID: 170256005 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 103 (25%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.29 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-010B 170256006 SE 09-AUG-06 25-AUG-06 Client 61.3%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.10 Americium-241 U -0.00576 Bismuth-212 0.760 Bismuth-214 0.576 Cesium-134 U 0.0332 Cesium-137 0.0908 Cobalt-60 0.115 Europium-152 U 0.00833 Europium-154 U -0.0828 Europium-155 U 0.0871 Lead-212 1.08 Lead-214 0.812 Manganese-54 U 0.0145 Niobium-94 U 0.00876 Potassium-40 19.3 Radium-226 0.576 Silver-108m U -0.00887 Thallium-208 0.282 Rad Gas Flow Proportional Counting GFPC, S90, solid-ALL FSS Strontium-90 U -0.00561+/-0.245+/-0.0366+/-0.351+/-0.139+/-0.0438+/-0.0468+/-0.0522+/-0.068+/-0.106+/-0.0591+/-0.0778+/-0.0928+/-0.0313+/-0.0271+/-1.35+/-0.139+/-0.0232+/-0.0641 0.0778 0.0263 0.189 0.0442 0.0314 0.0231 0.0225 0.0546 0.0808 0.0504 0.0306 0.0385 0.0262 0.0226 0.236 0.0442 0.0191 0.0224+/-0.245+/-0.0366+/-0.351+/-0.139+/-0.0438+/-0.0468+/-0.0522+/-0.068+/-0.106+/-0.0591+/-0.0778+/-0.0928+/-0.0313+/-0.0271+/-1.35+/-0.139+/-0.0232+/-0.0641 0.168 0.0543 0.402 0.0936 0.0665 0.0493 0.0499 0.115 0.175 0.104 0.0636 0.081 0.0557 0.0479 0.521 0.0936 0.0403 0.0475 0.0368 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1221 563436 1 KSD1 09/07/06 1746 562563 2+/-0.0185 0.0162 +/-0.0185 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 30 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010B Project: YANKO 1204 Sample ID: 170256006 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 89 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.31 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-01OC 170256007 SE 09-AUG-06 25-AUG-06 Client 49.2%Project: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UI Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 1.05 0.00111 0.539 0.626 0.00 0.192 0.522-0.0379-0.0318 0.0641 1.14 0.753 0.0134 0.0073 17.9 0.626 0.00496 0.354+/-0.196+/-0.108+/-0.392+/-0.101+/-0.0318+/-0.0408+/-0.0639+/-0.0596+/-0.0732+/-0.0925+/-0.0696+/-0.0911+/-0.0217+/-0.0216+/-1.02+/-0.101+/-0.0191+/-0.0504 0.0698 0.0862 0.142 0.0371 0.025 0.0197 0.0211 0.0464 0.0585 0.0488 0.0264 0.0337 0.0193 0.0181 0.190 0.0371 0.0165 0.0183+/-0.196+/-0.108+/-0.392+/-0.101+/-0.0318+/-0.0408+/-0.0639+/-0.0596+/-0.0732+/-0.0925+/-0.0696+/-0.0911+/-0.0217+/-0.0216+/-1.02+/-0.101+/-0.0191+/-0.0504 0.148 0.177 0.300 0.0775 0.0524 0.0414 0.0453 0.0966 0.126 0.100 0.0544 0.070 0.0408 0.038 0.412 0.0775 0.0344 0.0384 0.027 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/05/06 2124 563436 1 KSDI 09/07/06 1758 562563 2 0.00471 +/-0.0144 0.0114 +/-0.0145 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 32 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-OIOC Project: YANKO1204 Sample ID: 170256007 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 101 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.33 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-OIOD 170256008 SE 09-AUG-06 25-AUG-06 Client 58.1%Project: YANKO 1204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.920 Americium-241 U 0.159 Bismuth-212 0.975 Bismuth-214 UI 0.00 Cesium- 134 UI 0.00 Cesium-137 0.630 Cobalt-60 2.24 Europium-152 U 0.0801 Europium-154 U 0.159 Europium-155 U 0.0923 Lead-212 1.10 Lead-214 0.707 Manganese-54 U 0.0291 Niobium-94 U 0.0114 Potassium-40 16.4 Radium-226 0.761 Silver-108m U 0.00643 Thallium-208 0.396 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 0.0219+/-0.431+/-0.0868+/-0.615+/-0.170+/-0.0619+1-0.105+/-0.161+/-0.100+/-0.180+/-0.117+/-0.108+/-0.194+1-0.050+/-0.0446+/-1.57+/-0.170+/-0.0377+/-0.103 0.163 0.0423 0.310 0.126 0.0563 0.037 0.0361 0.0874 0.124 0.0649 0.0414 0.0578 0.0419 0.0367 0.341 0.0744 0.0316 0.0362+/-0.431+/-0.0868+/-0.615+/-0.170+/-0.0619+/-0.105+/-0.161+/-0.100+/-0.180+/-0.117+/-0.108+/-0.194+1-0.050+/-0.0446+/-1.57+/-0.170+/-0.0377+/-0.103 0.345 0.0871 0.654 0.259 0.118 0.0784 0.0793 0.182 0.267 0.134 0.086 0.121 0.0886 0.0774 0.753 0.156 0.0662 0.0763 0.0315 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1222 563436 1 KSDI 09/07/06 1805 562563 2+/-0.0196 0.0135 +/-0.0196 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 34 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-OIOD Proiect: YANKO1204 Sample ID: 170256008 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 97 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.35 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0014-033A 170256009 SE 11-AUG-06 25-AUG-06 Client 26.2%Proiect: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.28 +/-0.272 Americium-241 U 0.0199 +/-0.0632 Bismuth-212 UI 0.00 +/-0.484 Bismuth-214 0.920 +/-0.139 Cesium-134 U 0.0188 +/-0.0338 Cesium-137 0.709 +/-0.0983 Cobalt-60 0.697 +/-0.0935 Europium-152 U -0.0119 +/-0.0643 Europium-154 U 0.0763 +/-0.0741 Europium-155 Ut 0.00 +/-0.0951 Lead-212 1.13 +/-0.134 Lead-214 1.04 +/-0.151 Manganese-54 U -0.0049 +/-0.0275 Niobium-94 U 0.014 +/-0.0236 Potassium-40 14.3 +/-1.30 Radium-226 0.920 +/-0.139 Silver-108m U3.080E-05
+/-0.0263 Thallium-208 0.405 +/-0.066 Rad Gas Flow Proportional Counting 0.0796 0.0541 0.171 0.0421 0.0298 0.0246 0.0267 0.0538 0.0675 0.052 0.0457 0.0416 0.023 0.0211 0.185 0.0421 0.0202 0.0235+/-0.272+/-0.0632+/-0.484+/-0.139+/-0.0338+/-0.0983+/-0.0935+/-0.0643+/-0.0741+/-0.0951+/-0.134+/-0.151+/-0.0275+/-0.0236+/-1.30+/-0.139+/-0.0263+/-0.066 0.171 0.112 0.363 0.089 0.0628 0.0519 0.0577 0.113 0.147 0.108 0.0938 0.0871 0.049 0.0446 0.412 0.089 0.0424 0.0495 0.0291 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHl 09/01/06 1223 563436 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 0.0366 +/-0.0205 0.0124 +/-0.0205 KSD1 09/07/06 1807 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description 1 EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 36 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0014-033A Proiect: YANK01204 Sample ID: 170256009 Client ID: YANKOOl Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 99 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.U! Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.37 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd Contact: Project:* East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0014-033B 170256010 SE 11-AUG-06 25-AUG-06 Client 16.3%Proiect: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium- 137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 1.03 0.037 0.897 0.681 0.062 0.862 0.944 0.00733 0.00812 0.0592 0.896 0.773-0.0465 0.00334 11.6 0.681 0.00313 0.278+/-0.272+/-0.0519+/-0.563+/-0. 143+/-0.0748+/-0.117+/-0.113+/-0.118+/-0.115+/-0.0677+/-0.109+/-0.141+/-0.0487+/-0.0333+/-1.25+/-0.143+/-0.0324+/-0.0682 0.113 0.0353 0.237 0.057 0.0371 0.0301 0.0281 0.0695 0.0959 0.0595 0.0377 0.0491 0.032 0.029 0.247 0.057 0.0274 0.0296+/-0.272+/-0.0519+/-0.563+/-0.143+/-0.0748+/-0.117+/-0.113+/-0.118+/-0.115+/-0.0677+/-0.109+/-0.141+/-0.0487+/-0.0333+/-1.25+/-0.143+/-0.0324+/-0.0682 0.225 0.0705 0.473 0.114 0.0742 0.0601 0.0562 0.139 0.192 0.119 0.0754 0.0981 0.0639 0.0579 0.494 0.114 0.0548 0.0592 0.0268 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1559 563436 1 KSDI 09/07/06 1807 562563 2 0.00794 +/-0.015 0.0113 +/-0.015 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 38 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0014-033B Project: YANK0 1204 Sample ID: 170256010 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 103 (25%- 125%)Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.39 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East, Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: 9106-0014-033C Project: YANKO 1204 Sample ID: 170256011 Client ID: YANKOO Matrix: SE Vol. Recv.: Collect Date: 11-AUG-06 Receive Date: 25-AUG-06 Collector:
Client Moisture:
14.2%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.841 Americium-241 U 0.028 Bismuth-212 0.476 Bismuth-214 0.628 Cesium-134 U 0.0398 Cesium- 137 0.609 Cobalt-60 0.916 -Europium-152 U -0.0803 -Europium-154 U -0.0175 Europium-155 U 0.0335 -Lead-212 0.710 Lead-214 0.810 Manganese-54 U -0.0149 Niobium-94 U -0.00772 -Potassium-40 11.0 Radium-226 0.628 Silver-108m U 0.0295 Thallium-208 0.237 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U -0.0326+/-0.277+/-0.048+/-0.345+/-0.128+/-0.0385+/-0.0698 F/-0.0989+/-0.0732+/-0.0895 F/-0.0642+/-0.0819+/-0.110+/-0.0338+/-0.0304+/- 1.00+/-0.128+/-0.0254 F/-0.0761 0.100 0.0331 0.223 0.0439 0.0344 0.0277 0.0255 0.0581 0.0738 0.0553 0.0392 0.0428 0.0272 0.0254 0.220 0.0439 0.0239 0.0244+/-0.277+/-0.048+/-0.345+/-0.128+/-0.0385+/-0.0698+/-0.0989+/-0.0732+/-0.0895+/-0.0642+/-0.0819+/-0.110+/-0.0338+/-0.0304+/-1.00+/-0.128+/-0.0254+/-0.0761 0.212 0.068 0.468 0.0928 0.0721 0.0581 0.0552 0.121 0.159 0.114 0.0808 0.0895 0.0575 0.0533 0.484 0.0928 0.0499 0.0513 0.0359 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1829 563436 1 KSDI 09/07/06 1842 562563 2+/-0.013 0.0158 +/-0.013 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 40 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0014-033C Proiect: YANKO1204 Sample ID: 170256011 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 90 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.41 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0014-033D 170256012 SE 1 I-AUG-06 25-AUG-06 Client 11.9%Proiect: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.800 +/-0.169 Americium-241 U -0.00757 +/-0.0849 Bismuth-212 0.514 +/-0.239 Bismuth-214 0.496 +/-0.079 Cesium-134 UI 0.00 +/-0.0333 Cesium-137 0.240 +/-0.0466 Cobalt-60 0.329 +/-0.0616 Europium-152 U -0.0221 +/-0.047 Europium-154 U -0.0277 +/-0.0651 Europium-155 U 0.0409 +/-0.050 Lead-212 0.618 +/-0.0549 Lead-214 0.582 +/-0.0773 Manganese-54 U 0.0209 +/-0.0191 Niobium-94 U 0.0124 +/-0.0174 Potassium-40 10.8 +/-0.796 Radium-226 0.496 +/-0.079 Silver-108m U -0.00363 +/-0.0168 Thallium-208 0.222 +/-0.040 Rad Gas Flow Proportional Counting 0.0584 0.0733 0.125 0.0289 0.0215 0.0172 0.0159 0.0418 0.0444 0.0464 0.0246 0.0304 0.0165 0.0157 0.144 0.0289 0.0148 0.0156+/-0.169+/-0.0849+/-0.239+/-0.079+/-0.0333+/-0.0466+/-0.0616+/-0.047+/-0.0651+/-0.050+/-0.0549+/-0.0773+/-0.0191+/-0.0174+/-0.796+/-0.079+/-0.0168+/-0.040 0.125 0.151 0.265 0.0614 0.0454 0.0365 0.0349 0.0875 0.0974 0.0959 0.0511 0.0635 0.0352 0.0331 0.320 0.0614 0.0312 0.033 0.0276 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/05/06 0531 563436 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.020 +/-0.0174 0.0117 +/-0.0174 KSDI 09/07/06 1842 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 42 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0014-033D Project: YANK01204 Sample ID: 170256012 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 103 (25%6-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.43 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-013A 170256013 SE 09-AUG-06 25-AUG-06 Client 17.1%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 Bismuth-212 Bismuth-214 Cesium- 134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 Manganese-54 Niobium-94 1.15 U 0.0596 0.731 0.959 UI 0.00 U -0.00113 U -0.00569 U -0.0275 U -0.0292 U 0.0375 1.19 1.08 U 0.0199 U -6.020E-05 14.3 0.959 U -0.00566 0.423 nting+/-0.162+/-0.0865+/-0.295+/-0.0845+/-0.0287+/-0.0196+/-0.0174+/-0.0539+/-0.0495+/-0.0594+/-0.0671+/-0.090+/-0.0202+/-0.0164+/-0.771+/-0.0845+/-0.0152+/-0.0539 0.0511 0.0665 0.115 0.0284 0.0195 0.0162 0.0139 0.0402 0.0385 0.0534 0.0261 0.0305 0.0165 0.0143 0.130 0.0284 0.0128 0.0142+/-0.162+/-0.0865+/-0.295+/-0.0845+/-0.0287+/-0.0196+/-0.0174+/-0.0539+/-0.0495+/-0.0594+/-0.0671+/-0.090+/-0.0202+/-0.0164+/-0.771+/-0.0845+/-0.0152+/-0.0539 0.109 0.136 0.242 0.0597 0.041 0.034 0.0301 0.0837 0.0835 0.110 0.0537 0.0634 0.0347 0.030 0.283 0.0597 0.0268 0.030 0.0304 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1830 563436 1 Potassium-40 Radium-226 Silver-108m Thallium-208 Rad Gas Flow Proportional Coun GFPC, Sr9O, solid-ALL FSS Strontium-90 U -0.00331 +/-0.0151 0.0131 +/-0.0151 KSDI 09/07/06 1842 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 44 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013A Proiect: YANK01204 Sample ID: 170256013 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 101 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.U1 Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.45 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Cet ifc t o -- -- T Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-013B 170256014 SE 09-AUG-06 25-AUG-06 Client 19.6%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.23 Americium-241 U 0.0581 Bismuth-212 0.606 Bismuth-214 0.990 Cesium-134 U 0.0447 Cesium-137 0.0831 Cobalt-60 0.196 Europium-152 U 0.0248 Europium-154 U 0.0401 Europium-155 U 0.067 Lead-212 1.32 Lead-214 0.989 Manganese-54 U -0.00696 Niobium-94 U 0.00306 Potassium-40 9.89 Radium-226 0.990 Silver-108m U -0.017 Thallium-208 0.456 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 0.00221+/-0.302+/-0.0456+/-0.361+/-0.154 F/-0.0383+/-0.037 F/-0.0645+/-0.116+/-0.106 F/-0.0826+/-0.136+/-0.153 F/-0.0306 F/-0.0256+/-0.996+/-0.154+/-0.0253+/-0.084 0.0948 0.0383 0.199 0.046 0.033 0.0286 0.0258 0.061 0.0809 0.0584 0.0337 0.0431 0.0262 0.0228 0.207 0.046 0.0211 0.0253+/-0.302+/-0.0456+/-0.361+/-0.154+/-0.0383+/-0.037+/-0.0645+/-0.116+/-0.106+/-0.0826+/-0.136+/-0.153+/-0.0306+/-0.0256+/-0.996+/-0.154+/-0.0253+/-0.084 0.190 0.0765 0.399 0.0919 0.066 0.0571 0.0515 0.122 0.162 0.117 0.0674 0.0862 0.0523 0.0455 0.414 0.0919 0.0422 0.0505 0.0316 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/01/062110 563436 1 KSDI 09/07/06 1843 562563 2/-0.0172 0.0143 +/-0.0172 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 46 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013B Project: YANK01204 Sample ID: 170256014 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 103 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.47 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-013C 170256015 SE 09-AUG-06 25-AUG-06 Client 17.3%Proiect: Client ID: Vol. Recv.: YANK01204 YANKOO1 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 U -Bismuth-212 Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting 1.07-0.00337 0.808 0.614 0.0481 0.0789 0.074-0.0203-0.0129 0.0479 0.903 0.651-0.0163-0.022 12.9 0.614 0.00256 0.248+/-0.236+/-0.0367+/-0.311+/-0.118+/-0.0502+/-0.0569+/-0.0564+/-0.0622+/-0.0828+/-0.0527+/-0.0714+/-0.103+/-0.0298+/-0.0284+/-1.11+/-0.118+/-0.0199+/-0.0569 0.0703 0.034 0.157 0.0422 0.033 0.0226 0.0239 0.0547 0.0688 0.0529 0.0332 0.0431 0.0235 0.0226 0.250 0.0422 0.0177 0.0239+/-0.236+/-0.0367+/-0.311+/-0.118+/-0.0502+/-0.0569+/-0.0564+/-0.0622+/-0.0828+/-0.0527+/-0.0714.+/-0.103+/-0.0298+/-0.0284+/-1.11+/-0.118+/-0.0199+/-0.0569 0.154 0.0701 0.341 0.0899 0.0699 0.0484 0.0531 0.115 0.152 0.109 0.069 0.0904 0.0506 0.0481 0.553 0.0899 0.0378 0.0508 0.0289 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 2118 563436 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00157 +/-0.0143 0.0123 +/-0.0143 KSDI 09/07/06 1845 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 The following Analytical Methods were performed Method Description 1 EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified LXM2 08/27/06 1545 562444 Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 48 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013C Proiect: YANK01204 Sample ID: 170256015 Client ID: YANKOO 1 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 98 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier* QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.49 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-013D 170256016 SE 09-AUG-06 25-AUG-06 Client 25.9%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.03 Americium-241 U 0.0216 Bismuth-212 0.420 Bismuth-214 0.689 Cesium-134 U 0.0488 Cesium-137 0.170 Cobalt-60 0.566 Europium-152 U 0.0265 Europium-154 U 0.0628 Europium-155 U 0.0541 Lead-212 0.958 Lead-214 0.784 Manganese-54 U 0.00917 Niobium-94 U 0.0056 Potassium-40 12.6 Radium-226 0.689 Silver-108m U -0.00656 Thallium-208 0.314 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.00738+/-0.160+/-0.0981+/-0.350+/-0.0898+/-0.0307+/-0.0491+/-0.0694+/-0.0524+/-0.0639+/-0.0561+/-0.0653+/-0.0896+/-0.0221+/-0.019+/-0.931+/-0.0898+/-0.0175+/-0.0426 0.0664 0.0845 0.142 0.0339 0.0247 0.019 0.0198 0.0453 0.0591 0.0528 0.0265 0.0297 0.019 0.0164 0.166 0.0339 0.0151 0.0189+/-0.160+/-0.0981+/-0.350+/-0.0898+/-0.0307+/-0.0491+/-0.0694+/-0.0524+/-0.0639+/-0.0561+/-0.0653+/-0.0896+/-0.0221+/-0.019+/-0.931+/-0.0898+/-0.0175+/-0.0426 0.142 0.174 0.301 0.0715 0.0519 0.0402 0.0431 0.0946 0.127 0.109 0.055 0.0623 0.0403 0.0347 0.367 0.0715 0.0318 0.0398 0.0265 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/05/06 0521 563436 1 KSDI 09/07/06 1846 562563 2+/-0.0147 0.0112 +/-0.0147 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 50 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013D Project: YANK01204 Sample ID: 170256016 Client ID: YANKOOl Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/[racer Recovery GFPC, Sr90, solid-ALL FSS 106 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with .this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.51 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd Contact: Project: East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005A 170256017 SE 09-AUG-06 25-AUG-06 Client 17.9%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U -Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U -0.975 0.0504 0.804 0.647 0.0288 0.249 0.682 0.0893 0.0167 0.00619 0.912 0.747 0.0235 0.00608 10.5 0.647 0.00189 0.322+/-0.164+/-0.0306+/-0.393+/-0.112+/-0.0288+/-0.0491+/-0.0884+/-0.0683+/-0.0707+/-0.0524+/-0.0658+/-0.0939+/-0.0494+/-0.0244+/-0.910+/-0.112+/-0.0202+/-0.0462 0.0814 0.030 0.165 0.0371 0.0271 0.0255 0.0206 0.0526 0.0611 0.0476 0.0281 0.036 0.0228 0.0201 0.155 0.0371 0.0178 0.0209+/-0.164+/-0.0306+/-0.393+/-0.112+/-0.0288+/-0.0491+/-0.0884+/-0.0683+/-0.0707+/-0.0524+/-0.0658+/-0.0939+/-0.0494+/-0.0244+/-0.910+/-0.112+/-0.0202+/-0,0462 0.174 0.0616 0.351 0.0787 0.0574 0.0537 0.0453 0.110 0.134 0.0982 0.0584 0.0755 0.0486 0.0426 0.351 0.0787 0.0376 0.0442 0.0286 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 2119 563436 1 KSDI 09/07/06 1857 562563 2 0.00262 +/-0.0137 0.012 +/-0.0137 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 .08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 52 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005A Proiect: YANKO1204 Sample ID: 170256017 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 92 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.53 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com C~~r*ifpofa-f A nh-SLI~J~.LtLL
~J1 £~IiLtI V ~I3 Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005B 170256018 SE 10-AUG-06 25-AUG-06 Client 14%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.787 Americium-241 U 0.0759 Bismuth-212 0.403 Bismuth-214 0.636 Cesium-134 U 0.0378 Cesium-137 0.181 Cobalt-60 0.710 Europium-152 U 0.0183 Europium-154 U 0.0204 Europium-155 UI 0.00 Lead-212 0.722 Lead-214 0.832 Manganese-54 U 0.0204 Niobium-94 U 0.0129 Potassium-40 9.30 Radium-226 0.636 Silver-108m U 0.0081 Thallium-208 0.299 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.0109+/-0.187+/-0.0649+/-0.233+/-0.108+/-0.0274+/-0.0421+/-0.0716+/-0.0466+/-0.0516+/-0.0804+/-0.086+/-0.115+/-0.0232+/-0.0173+/-0.895+/-0.108+/-0.0194+1-0.0505 0.0725 0.0382 0.139 0.0306 0.0229 0.019 0.0155 0.0421 0.0449 0.0458 0.0317 0.0288 0.0192 0.0161 0.130 0.0306 0.0154 0.0157+/-0.187+/-0.0649+/-0.233+/-0.108+/-0.0274+/-0.0421+/-0.0716+/-0.0466+/-0.0516+/-0.0804+/-0.086+/-0.115+/-0.0232+/-0.0173+/-0.895+/-0.108+/-0.0194+/-0.0505 0.153 0.0789 0.294 0.0647 0.0482 0.040 0.034 0.0881 0.0982 0.0944 0.0651 0.0605 0.0406 0.0339 0.291 0.0647 0.0324 0.0332 0.0293 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/02/06 1713 563436 1 KSDI 09/07/06 1857 562563 2+/-0.0167 0.0123 +/-0.0167 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 54 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005B Project: YANKO 1204 Sample ID: 170256018 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 95 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.55 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005C 170256019 SE 10-AUG-06 25-AUG-06 Client 24.6%Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.810 Americium-241 U 0.0147 Bismuth-212 0.365 Bismuth-214 0.623 Cesium-134 UI 0.00 Cesium-137 0.113 Cobalt-60 0.268 Europium-152 U -0.00617 Europium-154 U -0.0248 Europium-155 UI 0.00 Lead-212 0.840 Lead-214 0.686 Manganese-54 U 0.00306 Niobium-94 U 0.0053 Potassium-40 10.2 Radium-226 0.623 Silver-108m U -0.0071 Thallium-208 0.288 Rad Gas Flow Proportional Counting+/-0.116+/-0.0176+/-0.171+/-0.0633+/-0.0297+/-0.0242+/-0.0379+/-0.0317+/-0.0417+/-0.0407+/-0.0404+/-0.0505+/-0.0143+/-0.013+/-0.535+/-0.0633+/-0.0113+/-0.031 0.0431 0.0169 0.099 0.0212 0.0166 0.0124 0.012 0.0284 0.0337 0.0265 0.0162 0.0197 0.0127 0.0112 0.0857 0.0212 0.00971 0.0115+/-0.116+/-0.0176+/-0.171+/-0.0633+/-0.0297+/-0.0242+/-0.0379+/-0.0317+/-0.0417+/-0.0407+/-0.0404+1-0.0505+/-0.0143+/-0.013+/-0.535+/-0.0633+/-0.0113+/-0.031 0.090 0.0345 0.206 0.044 0.0343 0.0257 0.0254 0.0585 0.0714 0.054 0.0332 0.0406 0.0265 0.0232 0.186 0.044 0.0201 0.0239 0.0284 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/05/06 2143 563436 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.0082 +/-0.0158 0.012 +/-0.0158 KSDI 09/07/06 1857 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 56 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis of Analvsis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: 9106-0004-005 C 170256019 Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 96 (25%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.57 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Cprtifienti-nf AnAlv~ii Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005D 170256020 SE 10-AUG-06 25-AUG-06 Client 19.1%Proiect: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.995 +/-0.411 Americium-241 U 0.0557 +/-0.0479 Bismuth-212 0.635 +/-0.589 Bismuth-214 0.760 +/-0.165 Cesium-134 U 0.0627 +/-0.0504 Cesium-137 0.503 +/-0.0894 Cobalt-60 1.72 +/-0.132 Europium-152 U 0.00265 +/-0.0988 Europium-154 U 0.0538 +/-0.114 Europium-155 UI 0.00 +/-0.119 Lead-212 1.09 +/-0.126 Lead-214 0.802 +/-0.135 Manganese-54 U 0.0185 +/-0.0434 Niobium-94 U -0.0168 +/-0.0366 Potassium-40 10.7 +/- 1. 11 Radium-226 0.760 +/-0.165 Silver-108m U -0.021 +/-0.0301 Thallium-208 0.343 +/-0.0887 Rad Gas Flow Proportional Counting 0.146 0.0365 0.261 0.0601 0.0463 0.0338 0.0307 0.0745 0.0996 0.0591 0.0386 0.0517 0.0383 0.0309 0.276 0.0601 0.0247 0.0298+/-0.411+/-0.0479+/-0.589+/-0.165+/-0.0504+/-0.0894+/-0.132+/-0.0988+/-0.114+/-0.119+/-0.126+/-0.135+/-0.0434+/-0.0366+/-1.11+/-0.165+/-0.0301+/-0.0887 0.291 0.0729 0.521 0.120 0.0926 0.0676 0.0614 0.149 0.199 0.118 0.0772 0.103 0.0766 0.0618 0.551 0.120 0.0494 0.0595 0.0299 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/02/06 1725 563436 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00322 +/-0.0146 0.0127 +/-0.0146 KSDI 09/07/06 1857 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 58 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PON 002332 Client Sample ID: 9106-0004-005D Project: YANKO 1204 Sample ID: 170256020 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 99 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.59 QUALITY CONTROL DATA 60 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn QC Summary Client : Connecticut Yankee Atomic Power 362 Injun Hollow Rd Report Date: September 8, 2006 Page 1 of 5 East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder:
170256 Parmname NOM Sample Qual -QC Units RPD% REC% Range AnIst Date Time Rad Gamma Spec Batch 563436 QC1201171526 170256001 DUP Actinium-228 Americium-24 I Bismuth-212 Bismuth-214 Cesium- 134 Cesium- 137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 Manganese-54 Niobium-94 0.966 1.01 Uncert: +/-0.192 +/-0.200 TPU: +/-0.192 +/-0.200 U 0.0375 U 0.0258 Uncert: +/-0.0387
+/-0.075 TPU: +/-0.0387
+/-0.075 0.366 0.592 Uncert: +/-0.306 +/-0.276 TPU: +/-0.306 +/-0.276 0.650 0.690 Uncert: +/-0.135 +/-0.0955 TPU: +/-0.135 +/-0.0955 U 0.0366 UI 0.00 Uncert: +/-0.0355
+/-0.035 TPU: +/-0.0355
+/-0.035 0.0666 0.0611 Uncert: +/-0.0355
+/-0.0415 TPU: +/-0.0355
+/-0.0415 0.104 0.159 Uncert: +/-0.0726
+/-0.0325 TPU: +/-0.0726
+/-0.0325 U 0.00636 U -0.00858 Uncert: +/-0.0728
+/-0.0624 TPU: +/-0.0728
+/-0.0624 U -0.0788 U 0.00919 Uncert: +/-0.0938
+/-0.0602 TPU: +/-0.0938
+/-0.0602 U 0.0672 U 0.0817 Uncert: +/-0.0554
+/-0.0557 TPU: +/-0.0554
+/-0.0557 0.871 0.847 Uncert: +/-0.0971
+/-0.0867 TPU: +/-0.0971
+/-0.0867 0.727 0.699 Uncert: +/-0.105 +/-0.102 TPU: +/-0.105 +/-0.102 U -0.00916 U -0.00665 Uncert: +/-0.0319
+/-0.0225 TPU: +/-0.0319
+/-0.0225 U 0.0101 U -0.00339 Uncert: +/-0.0244
+/-0.0176 TPU: +/-0.0244
+/-0.0176 pCi/g 4 pCi/g 37 pCi/g 47 pCi/g 6 pCi/g 56 pCi/g 9 pCi/g 41 pCi/g 1350 pCi/g 253 pCi/g 20 pCi/g 3 pCi/g 4 pCi/g 32 pCi/g 402 (0%- 100%) MJHI 09/02/06 17:26 (0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 20%)(0%- 20%)(0%- 100%)(0%- 100%)61 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Workorder:
170256 Parmname Rad Gamma Spec Batch 563436 Potassium-40 Radium-226 Silver- 108m Thallium-208 QC1201171527 LCS Actinium-228 Americium-241 Bismuth-212 Bismuth-214 Cesium- 134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 QC Summary Sample Qual QC Page 2 of 5 REC% Range Anist Date Time NOM Units RPD%Uncert: TPU: Uncert: TPU: U Uncert: TPU: Uncert: TPU: Uncert: TPU: 23.4 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: 9:58 Uncert: TPU: 14.5 Uncert: TPU: Uncert: TPU:.Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: 11.3+/-0.986+/-0.986 0.650+/-0.135+/-0.135-0.0067+/-0.0208+/-0.0208 0.283+/-0.0618+/-0.0618 11.7+/-1.03+/- 1.03 0.690+/-0.0955+/-0.0955 U 0.000104+/-0.018+/-0.018 0.283+/-0.048+/-0.048 U 0.254+/-0.565+/-0.565 24.1+/-1.28+/-1.28 U 0.575+/-0.944+/-0.944 U 0.0248+/-0.213+/-0.213 U 0.00032+/-0.147+/-0.147 9.84+/-0.487+/-0.487 14.7+/-0.660+/-0.660 U 0.125+/-0.292+/-0.292 U 0.0779+/-0.277+/-0.277 U -0.0876+/-0.277+/-0.277 U 0.0524+/-0.155+1-0.155 U -0.103+/-0.212 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 3 6 206 0 (0% -20%)(0%- 100%)(0%- 100%)(0% -100%)09/03/06 22:31 103 (75%-125%)
103 (75%-125%)
101 (75%-125%)
62 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
170256 Page 3 of 5 Parmname NOM Sample Oual OC Units RPD%REC% Range Anist Date Time Rad Gamma Spec Batch 563436 TPU: Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver- 108m Thallium-208 QC1201171525 Actinium-228 Americium-241 MB Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU:+/-0.212 U 0.0306+/-0.135+/-0.135 U -0.0513+/-0.115+1-0.115 U 0.769+/-1.10+/-1.10 U 0.0248+/-0.213+/-0.213 U 0.0782+1-0.105+1-0.105 U 0.180+/-0.177+/-0.177 U 0.0216+/-0.0479+/-0.0479 U -0.0654+/-0.0396+/-0.0396 U 0.110+/-0.0705+/-0.0705 U 0.00843+/-0.0317+/-0.0317 U -0.00203+/-0.012+/-0.012 U -0.00757+/-0.0117+/-0.0117 U -0.00589+/-0.0128+/-0.0128 U -0.0169+/-0.0308+/-0.0308 U 0.00802+/-0.0305+/-0.0305 U -0.00342 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g (75%-1 25%)09/02/06 17:16 Bismuth-212 Bismuth-214 Cesium- 134 Cesium- 137 Cobalt-60 Europium-152 Europium-154 Europium-155 63 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
170256 Page 4 of 5 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date. Time Rad Gamma Spec Batch 563436 Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m Thallium-208 Rad Gas Flow Batch Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU:+/-0.0294+/-0.0294 U 0.0151+/-0.028+/-0.028 U 0.00738+/-0.0252+/-0.0252 U 0.0127+/-0.0111+/-0.0111 U -0.00293+/-0.012+/-0.012 U 0.112+/-0.173+/-0.173 U 0.00843+/-0.0317 U 0.00354+/-0.0115+1-0.0115 U -0.011+/-0.0157+/-0.0157 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 562563 QC1201169422 170256002 DUP Strontium-90 QCI201169424 LCS Strontium-90 QC1201169421 MB Strontium-90 QC1201169423 170256002 MS Strontium-90 U 0.00501 Uncert: +/-0.0149 TPU: +/-0.0149 U 0.00534+/-0.0155+1-0.0155 1.57+/-0.140+/-0.147 pCi/g 0 (0% -100%) KSDI 1.74 Uncert: TPU: Uncert: TPU: 1.74 U Uncert: TPU: U 0.0172+/-0.0185+/-0.0185 pCi/g pCi/g pCilg 90 (75%-125%)
09/07/06 18:59 09/07/06 19:16 09/07/06 18:59 09/07/06 19:16 0.00501+/-0.0149+/-0.0149 1.32+/-0.124+/-0.130 76 (75%-125%)
Notes: The Qualifiers in this report are defined as follows: 64 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
170256 Page 5 of 5 Parmname NOM Sample Qual QC Units RPD%* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded REC% Range Anlst Date Time N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.** Indicates analyte is a surrogate compound.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.65 General Narrative Page 1 of 105 CASE NARRATIVE For CONNECTICUT YANKEE RE: Soil PO# 002332 Work Order: 168404 SDG: MSR #06-0652, 06-0675, 06-0687, 06-0688, 06-0707, 06-0743, 06-0755 August 15, 2006 Laboratory Identification:
General Engineering Laboratories, LLC Mailing Address: P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address: 2040 Savage Road Charleston, South Carolina 29407 Telephone Number: (843) 556-8171 Summary: Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC, (GEL)in Charleston, South Carolina on May 5, May 9, May 12, May 17, May 26, June 2, June 8, 2006. All sample containers arrived without any visible signs of tampering or breakage.
The chain of custody contained the proper documentation and signatures.
The laboratory received the following sample(s):
Sample ID Client Sample ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006.
9106-0004-015F 168404007 9106-0005-01 OF 168404008 9106-0005-014F 168404009 9106-0006-005F GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP INC.P.O. Box 30712
- Charleston, SC 29417
- 2040 Savage Road (29407)Page 2 of 105 Phone (843) 556-8171
- Fax (843) 766-1178
- www.gel.com 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-001F 168404015 9106-0010-012F Items of Note: At the request of Dale Randall on July 20, 2006, GEL analyzed the above samples according to the spreadsheet in the attached email.Case Narrative:
Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures.
Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.
Analytical Request: Seven soil samples were reanalyzed for FSSALL, except gamma and Sr-90.Four soil samples were reanalyzed for FSSALL, except gamma and Ni-63.Two soil samples were reanalyzed for FSSALL, except gamma.Two soil samples were reanalyzed for FSALL, except gamma, Sr-90 and Ni-63.Internal Chain of Custody: Custody was maintained for the sample(s).
Data Package: The enclosed data package contains the following sections:
Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.
I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.
Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.PO. Box 30712
- Charleston, SC 29417 ° 2040 Savage Road (29407)Phone (843) 556-8171
- Fax (843) 766-1178
- www.gel.com Page 3 of 105.I I :
Additional HTD analyses
Subject:
Additional HTD analyses From: "Dale Randall" <randall@cyapco.com>
Date: Thu, 20 Jul 2006 11:04:54 -0400 1(, 8, LI 0 (4, 1, To: "Cheryl Jones" <cj @gel.corn>
CC: "Clyde Newson" <Newson@CYAPCO.com>, "John McCarthy" <McCarthy@
CYAPCO.com>
Cheryl: Per our earlier discussion, attached is a list of samples that we would like to have analyzed to the FSSALL protocol.
I have included a list of test protocols performed on each sample to date. Once you have had an opportunity to determine our options for each sample please call or e-mail me at your convenience.
Thank You, Dale (860) 267-3133 Content-Description:
GEL FSSALL analyses request.xis GEL FSSALL analyses request.xls Content-Type:
application/vnd.ms-excel Content-Encoding:
base64 Page 4 of 105 ,I of I 8/2/2006 7:04 PM Done To be done Previous IGEL ID CY sample location IDs FSS Gain Sr-90 N,-63 Am Pu SrgO Pu241 Fe55 Ni63 Tc99 H3 C14 lq164220008 9106-0002-007F x x x x x x x x x x U,164220012 9106-0002-011 F x x x x x x x x x x p 162335004 9106-0003-004F x x x x x x x x x x.1162335014
.9106-0003-015F x x x x x- x x x x _x 9106-0004-005F x xx x x x x x x x 162832009 9106-0004-015F x x x x x x x x x X 162485008 9106-0005-01 5F x x x x x x x x x x 162485011 9106-0005-014F x x x x x x x x x x 162850014 9106-0006-005F x x x_ _ x x x x x x 163741005 9106-0008-006F x x x x x x x x x x 163741009 9106-0008-008F x x x x x x x x x x 164542008 9106-0009-002F x x x x x x x x x x 164542003 9106-0009-017F x x x x x x x x x x 163105009 9106-0010-001 F x x x x x x x x x x 163105016 9106-0010-012F x x x x x x x x x x Chain of Custody and Supporting Documentation Page 6 of 105 Health Physics Procedure 1462: o L(GPP-GGGR-R5104-003-Attachment B-CY-001 Major~Chain of Custody Form Connecticut Yankee Atomic Power Company No. 2006-00371 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones o SL Priority:
[ 30 D. [ 14 D. [ 7 D. container L 47J2q _Z Sample Size-.Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0002-OO1F 5/17/06 10:42 SE C BP X X Transferred from COC 2006-00357 9106-0002-002F 5/18/06 09:43 SE C BP X Trans*rred from COC 2006-00361 9106-0002-003F 5/18/06 10:14 SE C BP x x Transferred fromi COC 2o06-00361 91 06-0002-004F 5/18/06 10:39 SE C BP x x Transferred from COC 2006-00361 9106-0002-005F 5/18/06 12:49 SE C BP x x Transferred from COC 2006-00364 9106-0002-006F 5/18/06 13:14 SE C BP X X Transferred from COC 2006-00364 9106-0002-006FS 5/18/06 13:14 SE C BP X X Transferred from COC 2006-00364 9106-0002-007F 5/18/06 13:37 SE C BP X X Transferred from COC 2006-00364 9106-0002-008F 5/18/06 14:04 SE C BP X X Transferred from COC 2006-00364 NOTES: PO #: 002332 MSR #: 06- SSWP# NA Z LTP QA [] Radwaste QA [ Non QA Samples Shipped Via: Internal[15 Fed Ex Container UPS Temp.: Deg. C[ Hand Custody Sealed?I Re h q, Date/Time
- 2) 2, l~ived By Date/Time Custody Seal Cý1 O (Other Intact?
Date/Time
- 4) Received By Date/Time BillofLading
___YO No Bill of Lading #5-5) Relinquished By Date/Time
- 6) Received By Date/Time 7 ' '"65 /
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 1 Major CD 00 q Chain of Custody Form Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 No. 2006-00372 Project Name: Iaddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: " Comments:ly Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones C a Priority:
Z 30 D. ] 14 D. El 7 D. container Sample Size-SM leDsintinmedia Type &Type SampleDesignation Date Time CMde Code Code Comment, Preservation Lab Sample ID 9106-0002-009F 5/18/06 14:28 SE C BP x Transferred from COC 2006-00364 9106-0002-01OF 5/18/06 14:50 SE C BP x x Transferred frm COC 2006-00364 9106-0002-01IF 5/19/06 08:10 SE C BP x x Transferred from COC 2006-00365 9106-0002-012F 5/19/06 08:31 SE C BP x x Transferred from COC 2006-00365 9106-0002-013F 5/19/06 09:00 SE C BP X X Transferred from COC 2006-00365 9106-0002-014F 5/19/06 09:58 SE C BP X X Transferred from COC 2006-00365 9106-0002-014FS 5/19/06 09:58 SE C BP X X Transferred from COC 2006-00365 9106-0002-015F 5/19/06 10:29 SE C BP x x Transferred from COC 2006-00365 9106-0002-016F 5/19/06 13:19 SE C BP x x Transferred from COC 2006-00365 NOTES: PO #: 002332 MSR #: 06- SSWP# NA (9 LTP QA El Radwaste QA fl Non QA Samples Shipped Via: Internal 0'7 55 E Fed Ex Container 0 UPS Temp.: _Deg. C C Hand Custody Sealed?1 .Date/Time-
- 2) By' Dat§(Time Custody Seal M u~ -4r C Other Intact?3) 'lelinquished By Date/Time
- 4) Received By Date/Time Y _ _ N __Bill of Lading 5) Relinquished By Date/Time
- 6) Received By Date/Time 7W09 Y/ 176 Connecticut Yankee Statement of Work for Analytical Lab Services ("-.CY-ISC-SOW-O01 Figure 1. Sample Check-in List Date/Time 'SDG#: -(0 6 5 Work Order Number: (G LI'd ) Z .Shipping Container ID iOý_ , %/95591 Chain of Custody 40o oo- 9 1. Custody Seals oni shipping container intact?..
Yes No [ ]2. Custody Seals dated and signed? Yes No [.3. Chain-of-Custody record present? Yes N o ].4. Cooler temperature
" 5. Vermiculite/packing materials is:. Wet [] Dry 6:w -Number of samples in shipping container:
_7. Sample holding times exceeded?
Yes [ 3 No 8. Samples have:hazard labels_2.ustody seals sample labels 9. Samples are:--in good condition
.leaking-broken -have air bubbles 10.IL..Were any anomalies identified in sample receipt?Description of anomalies (include sample numbers): Yes[ ] NOX]Sample Custodiaa/Laboratory(:
i Dates -O(o Telephoned to:_ On ByPage 9 of 105 Connecticut Yankee Statement of Work for Analytical Lab Services-CY-ISC-SOW-OOI Figure 1. Sample Check-in List Date/Time Received?
' %SDG#: AAx-SfO(O O"-$j Work Order Number: i(0 ckzz (, Shipping Cdhtaiaer ID.- -59 02." Chain of 0 OV (t7 I. Custody Seals or shipping container intact? Yes No [)2. Custody Seals dated and signed? Yes No [ I 3. Chain-of-Custody record present? (Q Yes ] No.[]4. Cooler temperature
- 5. Vermiculite/pacling materials is: Wet [ ] Dry 6. Number of samples in shipping container.
-7. Sample holding times exceeded?
Yes []No.1 J~.8. sam.Sms have:._ tape h .hazard labels_custody seals .aporaesample labels 9. Samples are-.good condition leakig---broken -have air bubbles 10. Were any anomalies identified in sample receipt? Yes [I No 11. Description of anomalies (include sample numbers): Samn ie usdian/Laboratorv-C(Algj 2L'i Date.. ~Telephoned to: On 1:hJ Page 10 of 105 ESAMPLE SSAMPLE RECEIPT & REVIEW FORM-. 'S VIIO I" Mueol Client: ('ot~)flna?4-jr, c A nk%-1 es SDG/ARCOC/Work Order:- Y{~Date Received:
(, P10 PM(A) Review (ensure non-contorming items are resolved prior to signing);jReceived By: C_)" Sample Receipt Criteria i Comments/Qualifiers (Required for Non-Conforming Items)Shipping containers received intact Circle Applicable:
seals broken damaged conainelC container other (describe) and sealed? 7 Samples requiring cold Circle Coolain # ice bags blue ice dry ice none other describe)2 preservation within (4 +/- 2 C)?Record preservation inethod. 7 Chain of custody documents
-" included with shipment?Sample containers intact and imcic Applicab 5 e. s broken damaged container leaking container other (describe) sealed? 7" 5 Samples requiring chemical .536 iD's. continers affected and observed pH: preservation at proper pH? I'll..VOA vials free of headspace Sample ID's and containers affected: 6(defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory)
,__ _8 Samples received wi l holding Id's and tests affected: time? ___O_9 Sample ID's C match ID's Sample ID's and containers affected: on bottles?ýDate &xme on COC match date Sample ID's affected:& tiro6 on bottles?N4v er of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in relinquished/received sections? 00Q -003 -1 14Air Bill ,Tracking Fs, &Additional Comments'in "* I RSO RAD Receipt #Sset *Hfa> x2 area background is observed on samples identified as "non-Suspected Hazard Information ' ~ regulated/non-radioactive", contact the Radiation Safety group for fIurther A lRadioh-ical Classficin?
investigation.
lB PCB Regulated?
V " gShipped as D01' Hazardous C Material?
If yes, contact Waste.Manager or ESH Manager.1Mxmr ConsOsre* , 6 Cpe7e7 rnomlenls:-azard Class Shipped: JN#: Initials (.L- Date-LO/47,I.
I I PM (or PMA) review of Hazard classiticarion:
ti, Page 11 of 105 SAMPLE RECEIPT & REVIEW FORM PM use only Client: ?m vpl;tQ Y ric SID/ARCOC/Work Order: /C.9'ZW(Date Received:
-O~o PM(A) Review ( e ofor i e resolved prior to signing): "Received By: ,I!-Sample Receipt Criteria Comments/Qualifrers equired for Non-Conforming Items)J Shipping containers received intact I sirde APpliCable:
seals brkcoaner leaking container othe (describe).iarprI e Is uiring old 2LI ooant # Tags blue ice dry ice none other describe)2 jpreservation within (4 +/- 2 C)?1 Record preservation method. I I .3 'Chain °of custody documents included with shipment?Sample containers intact and 4 [sealed?fSamples requiring chemical Jpreservation at proper pH?6 IVOA vials free of headspace ic pplicable:
Seals broken damaged container lenking contaie h0er (describe)
Sample ID's. containers affected and observed PH: S Sample ID's, and containers aff.cte.d.
j I(defined as <z 6mm hiihhlel?--, fAre Encore containers present?7 [(If yes, immediately deliver to[.VOA laboratory) 8tSamples received within holdin Id's and tests time?9Sample ID's on COC matc D's Sam.ple ID's and containers affected: on bottles?10Dt ie nCC thdate .Ds fetd 10Date & time on COC thdt apeI' fetd& time on bottles?Number of contamine received Sample ID's affected: match number indic ted on COC?1 Cl form is pro ny signed in reiguse/rec~eved_.7 sections?
O-" -E,, O ,[l, 14 Air Bill ,Tracking
- 's, &Additional Comments Z RSO RAD Receipt #_____ ________Suspected Hazard Information
.-" n*If > x2 area background is observed on samples identified as -on.o~ r A .regulated/non-radioactive" contact the Radiation Safety group for fur-ther 4Z4 a investigation.
A M .adiologicalCous Observed*a OU "" Coments: C Material?
If yes, contact Waste Hazard Class Shipped: Manager or ESH Manager. UN#: PM (or PMA) review of Hazard classification:
Initials V Date: Page 12 of 105 Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-00 I Major Chain of Custody FormConnecticut Yankee Atomic Power Company-362 Injun Hollow Road, East Hampton, CT 06424 :Z .4 860-267-2556 Q 0 Project Name: Haddam Neck Decommissioning Analyses Requested
_Lab Use Only Contact Name & Phone: '2oments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories
< 0 2040 Savage Road. Charleston SC. 29407 0 9 843 556 8171. Attn. Cheryl Jones C Priority:
Z 30 D.E] 14 D. [3 7 D. Container Sample Size-Media Type &Type Lb" Sample Designation Date Time Code Code Code Comment, Preservation Lab Sampi:iple
.tO 9106-0003-OOIF 4/24/06 14:13 SE C BP x Transferred from COC2006-00221 P 9106-0003-002F 4/24/06 14:39 SE C BP X Transferred from COC2006-00221
! 9106-0003-003F 4/24/06 15:01 SE C BP X Transferred from COC2006-00221 9106-0003-004F 4/25/06 08:41 SE C BP X Transferred from COC2006-00223 9106-0003-004FS 4/25/06 08:41 SE C BP X Transferred from COC2006-00223 9'106-0003-05F 4/25/06 09:2 1 SE C BP X "Transferred from COC2006-00223 9106-0003-006F 4/25/06 09:46 SE C BP X Transferred from COC2006-00223 0 9106-0003-007F 4/25/06 10:28 SE C BP X Transferred from COC2006-00223 9106-0003-008F 4/25/06 11:15 SE C BP I X Transferred from COC2006-00223 NOTES: PO #: 002332 MSR #: 06-0" SSWP# NA ED LTP QA E Radwaste QA Non QA Samples Shipped Via: .nternalfl.iraer Combined samples 9106-0003-003F taken on 4/25/06 (@08:19 and 9106-0003-003FB taken on 4/25/06@ 08:19 in order to have sufficient sample for counting.
[ Fed Ex ,eýP;.J Deg. r El UPS .... ,:,:", ,.: U HandCstdSal?
- 1) Relinquished By Date/Time
- 2) .ec.ived By 1 Date Time CtustOdy Seal .Itact-'?{ '*'j (,Y ),oa, td IO L] Other 3) Relinquished By Date/Time
- 4) Received By Dab/TimeN Bill of Lading #5) Relinquished By Date/Time
- 6) Received By Date/Time
.2
- 2 V -'c/- 0 2 40 GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Health Physics Procedure Helh hscsPoedr GPGGRR 0403Atahmn -C-0I iao c L, Chain of Custody Form Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556
--- -ny R e , °/.Project Name: Haddam Neck Decommissioning Analyses Requestei
-Contact Name & Phone: will, Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 0 c 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D.E] 14 D.[] 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation
")i ple 112 A 9106-0003-009F 4/25/06 13:00 SE C BP X Transferred from CCC 2006-00236
.ii0 9106-0003-OIOF 4/25/06 13:23 SE C BP X Transferred from COC 2006-00236
\ 9106-0003-010FS 4/2 5/06 13 :23 SE C B P x Tr.nsferred from CO C-2006-00236 tk 9106-0003-012F 4/25/06 15:12 SE C BP X Transferred from COC 2006-00236 0t 9106-0003-013F 4/25/06 14:21 SE C BP X Transferred from COC 2006-00236 0Cj 9106-0003-013F 4/25/06 14:48 SE C BP x Transferred from COC 2006"0236 9106-0003-014F 4/25/06 14:48 SE C BP X Transferred from COC 2006-00236 i, 9106-0003-015F 4/26/06 08:16 SE C BP x Transferred from COC 2006-00237 1:..*, .-9106-0003-016F
/2/6 041 S C BP XTransferred from COC 2006-00237 :.:-. .2.;""
9106-0003-017F 4/26/06 09:18 SE C BP x Transferred from CCC 2006-00237
..9106-0003-018F 4/26/06 08:59 SE C BP x Transferred from COC 2006-00237 " of 4/6/06 08:5 0 0 C NOTES: PO #: 002332 MSR #: 0 6-0&2- SSWP#NA S LTP QA [I RadwasteQA E] Non QA 1) Relinquished By Date/ime 2) Received By Datfl'ime 3J)Re li4nzquich S-By Dte/5mO e 4 0 Reei By c_5° D/iOme1 3) Relinquished By Date/Time
- 4) Received By Date/Time Samples Shipped Via: Z Fed Ex UPS LI Hand LI Other Bill of Lading #TWy2O-gY/l'-
0261 Jre~p Sc'pW.eal'E Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-O01 Figure 1. Sample Cheek-in List Date/Time Received:
., t SDG#: o &&2-Work Order Number: -(Z -Shipping Cdotainer ID:. 1 7t(3 6 VU'-6 O I Chain of Custody# #)U? (, .,.. It OZ-IC) y .0 1.1. Custody Seals. od shipping container intact? * [ ] No '2. Custody Seals dated and signed? Yes [ jNo 3. Chain-of-Custody record present? Yes No [L 4. Cooler temperature , C_5. Vermiculite/packing materials is: Wet [] Dry.'] fl /_6.. Number of samples in shipping container:
nt .I -" 7- Sample holding times exceeded?
Yes [ No JKL.8. Sapls-tape __hazard labelsseals .appropriate sample labels 9. Samples are: good condition -broken -___have air bubbles 10. Were any anomalies identified in sample receipt? Yes [ ] No Q4 11. :Description of anomalies (include sample numbers): Sample Custodian/Laboratory: CC4"L Date.: .ý51 -) .Telephoned to: On By.Page 15 of 105 0 SAMPLE RECEIPT & REVIEW FORM i.PMuaneomly jV(a 2 33 Client: ,SDG/ARCOC/Work Order: Date Received:
ra ?)4 5 6 (e. PM(A) Review (ensure atncu tm are resolved prior to signing): Sample Receipt Criteria Z Comments/Qualifiers (Required for Non-Conforming Items)I Shipping containers received intact Circle Applicable:
seals broken danmaged container leaking container ohr (describe) and sealed? , _t= I'll Samples requiring cold Circle Coolant # ice bags blue ice dry ice none aib e 2 preservation within (4 +/- 2 C)?Record preservation method. Pen n.. _..Chain of custody documents included with shipment?4 Sample containers intact and Circle Applicable:
seals broken damaged comainer leaking container odier (describ)sealed?Samples requiring chemical Sample ID's, containers affected and observed pH: preservation at proper pH?VOA vials free of headspace Sample ID's and containers affected: (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory) 8 Samples received within holding Id's and w afeted time?9 Sample ID's on COC match ID's Sample ID's and containers affected: on bottles?Date & time on COC match date Sample In's affected:& time on bottles?Number of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in V relinquished/received sections?Air Bill ,Tracking
- 's, & C- d e 4--Additional Comments C.-- 0"a a RSO RAD Receipt#SsceH ad-o -*If > x2 area background is observed on samples identified as "non-Suspected Hazard Information 8.-U regulated/non-radioactive", contact the Radiation Safety group for further 1I investigation.
A lRadiological Classification?
Maximum Counts Observed*:
[B PCB Regulated?
.Comments: hippea' as COa HazardousS' C Material?
If yes, contact Waste Hazard Class Shipped:[Manager or ESH Manager. UN/: PM (or PMA) review of Hazard classification:
Initials Date: Page 16 of 105t I Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-00 1 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424ýProject Name: Haddam Neck Decommissic
ýDontact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
0 30 D.] 14 D. El 7D.Date Samples Shipped Via: 0 Fed Ex 0l uPs 0] Hand[I Other Bill of Lading #
"- Health Phys,, Pr~edure GPP-GGGR-R5104-003-Attachment B-CY-00 1 Major Yankee Atomic Power Company".. Hollow Road, East Hampton, CT 06424 860-267-2556 t Name: Haddam'Neck Decommissioning Contact Name & Phone: Jack McCarthy" 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
M 30 D. [] 14 D. M 7 D.Samples Shipped Via:[ Fed Ex O UPS[] Hand[] Other Bill of Lading N 477/c/7: 3xlrF9Z Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Check-in List Datc/Timc Rcccivcd:
X_ Z2. 0 G SDG#: /6tf ( O6, Work Order Number:- &-' 3 2 1 Shipping ContainerlD:
"1i 9Z,15" 8812-1. Custody Seals on shipping container intact?2. Custody Seals dated and signed?3. Chain-of-Custody record present?4. Cooler temperature
..5. Vermiculite/packing materials is: 6. Number of samples in shipping container:.
- 7. Sample holding times exceeded?69 , ,,2a Chain of Custody #.- ooo -60S3.7 Yes No [3 Yes No []Yes No []I Wet JA Dry [ ]Yes [ ] No 8. Samples have:_. tape hazard labels.custody seals appropriate sample labels 9. Samples are:_ in good condition
__.jeaking broken have air bubbles 10. Were any anomalies identified in sample receipt? Yes No [I II. Description of anomalies (include sample numbers): Sample Custodian/Laboratory:
J -. i, ' Date: 6. -,,.o Telephoned to: On By Page 45 of 56 Page 19 of 105
- Connecticut Yankee-Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Chcck-in List Date/ime Received.SDG#: Work Order Number:_ ___ ___ __hippin. Chain of Custody I. Custody Sea.ls oi shipping container intact?.. -Yes [ J No No 2. Custody Seals dated and signed? Yes[ ].No 3. Chain-of-Custody record present? Yes '4 No []4. Cooler temperature
- 5. VermiculJtedlpacng materials is: Wet E, Dry t\]6. 1 Number of samples in shipping container'
_ _ _ _"_"_; _ _7. Sample holding times exceeded? -N* Yes [],.No 10. Were, any anomlies identified nsamplereceipt?
Yes ' No [in Ii -~ .Decipton of anOnaliies(include sample nmes:~ I~a ~ -i~~$ampjeý~(Y Cusori-----------
Sample C~ t~dianLaborat zr C .~ (J~)*~~D ate :_ _ _ _ __ _ _ _Onch~e tyo-* " ...... ..--,=,7Y.Page 20 of 105 r" S SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM-Fed F. Y- Tvk-ni csI, o r (tK ,---- -- anln kc(\ -- OO3 0 C (. ") :5,u-'-iq(a 1055 Asx mai 0 (3 53 0 -: i Y _- _________--
o_ _5_, __,_-_________
1 00 ls_ __ _ _ V_ _hLL5Pcnje-5 CLr oLi.Page 21 of 105 ,!1I SAMPLE RECEIPT & REVIEW FORM PM use only Client: iSDGIARCOCWork Order: 1(e 2' 37-ate Received: , F M(A) Review (ensare non-conforming items are resolved prior 6o signing).eceived By: -_ _._ _ _ _ _,_, Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforming Items)Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) 1and sealed? x Samples requiring cold ircle Coolant # ice bags blue ice dry ice noe oher describ)2 preservation within (4 + /- 2 C)?Record preservation method.___________
_____________
Chain of custody documents included with shipment?..
SiSample containers intact and Circle Applicable:
seals broken damaged container l<E taw other (describe) sealed? A -( 'N: 91 -e- 0 01-5 Samples requiring chemical Smple affected and obsered pH1_ preservation at proper pH?..6 VOA vials free of headspace Sample ID's and containers affected: 6(defined as < 6mm bubble)?__________________________
Are Encore containers present?7 (If yes, immediately deliver to-VOA laboratory) 8 Samples received within holding Id's and tests affected: time?9 Sample ID's on COC match ID's Sa M's and continr aff 'on bottles? ,_i Date & time on COC match date 1 a le ID's affected: 10 & time on bottles? __ _Number of containers received Sample ID's affected: 11" match number indicated on COC?COC form is properly signed in 2relinuihed/recived sec*tions?1 A .o4 Air Bill ,Tracing Ps, &Additional Comments.. *HA. Kece"pti____________________
Suspected -Hazard Information 0 z JDRAD Receipt #.:.*If>x2 area b roun is oberved on sples idnifed as u-.non-regulated/non-radioactive", contact the Radiation Safety group forfurther investigaion.
u--I A I'Atdrologicad
.0asific~iin.
'sift.B CB Regulated?
1 , as .IJ Hazardous 1 C Material?
If yes, contact Waste Manager or Manager. y u1111 Counts Oberved*:
<Flazard'Clms Shipped; I.P~j~fj~yj~w of Hazard classific2rinn' J
-1,oeM V c of Haar clsifctinate.,5 UI SAMPLE RECEIPT & REVIEW FORM Phi use only client: Vri n Vo SDG/ARCOCIWork Order: /6 Z I' 2- A.Date Received:
I PM(A) Rfvr mloIm km. resolved prior to sigting): Received By: C c ...cC= I Sample Receipt Criteria i Comments/Quallfiers (Required for Non-Conforming Items)Shipping containers received intact 1icle Aplktable ses brken daMaged container leaking cormiw odwr (describe) and s-aled? __..-._-__
_ _ _ _ .Samples requiring cold Circle CoWlaN I ice bags blue ice dry ieC otr describe)2 preservation within (4 +/- 2 C)?Record preservation method.Chain of custody documents U) Us C I_> \ LV t-included with shipment?
Vcn0e Sample containers intact and ¶!m ' dar tiged cotainer ,lting com'r , (d-sealed? k %,7)/Samples requiring chemical S ID's. containers affected and observed pH: preservation at proper pH? 1 VOA vials free of headspace Sample ID's and containers affeced: 6 (defined as < 6mm bubble)? ,_ _ _... ...Are Encore containers present?7 (If yes, immedialely deliver to VOA laboratory)__
8 Samples received within holding Id's amd tesu affected time?9 Sample ID's on COC match ID's Sanp ID°Y and co..nie--
affecied: on bottles?Date & time on COC match date Satl-i_ Io's affected:& time on bottles?Number of containers received ID'S affecd: match number indicated on COC?COC form is properly signed in AC) " , y 1 ru i 7; t relinquished/received sections?
.. .. ....Air Bill ,Tracking
- 's, & E CACifp) 1Cd- Is _.-.-Additional Comments[O RAD Receipt _pcte *If > x2 areabackground is observed on samples identified as non-Suspected Hazard Information f @0gulaled/non-radioacive'.
contact the Radiation Safety group for further_investigation.
A Raiological Classification?
Maximum Counts Observed-:
!j 'C Regulated?
1VComments:
ripped as a o = Hazardous c Material?
If yes, contact Waste H r Class Shipped: NManager or ESH Manager. UN#: L PM (or FA) review of Hazard I Fage 23 of In,;
Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major HelhPyisPoeueGPGG-51403Atcmn B-C ii0 Mao Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424)ject Name: Haddam Neck Contact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D. [] 14 D. M 7 D.0] Other Bill of Lading #7'q9Z 1 '9S Connecticut Yankee Statement of Work for Analytical Lab Services Figure 1. Sample Check-in List Date/Time Receivei': oc.SDGj#: Work Order Number: -L- , Shipping CCntainer ID: , t%" 5-2 .Chain of Custody I. Custody Seals ori shipping container intact?2. Custody Seals dated and signed?3. Chain-of-Custody record present? ".4. Cooler temperature I g -. q °'5. Vermiculite/packing materials is: 6. Number ofsamples in shipping container:
7- Sample holding times exceeded?.CY-ISC-SOW-O01.Yes 4No[]Yes 4".No [.Yes IlNo NO I & e, 0 3L Wet t\Dry (Yes [NoL4 10. Were any anomalies identified in sample receipt? Yes [ No 11. .Description of anomalies. (include sample numbers):* : ' " ' " " ' " °.,.Page 25 of 105 SAMPLE RECEIPT & REVIEW FORM PM use only ClientSDG/ARCOCWork Order: (( Z 8 Date Received:
PM(A) Review (ensure non-coiiro g items are resolved prior to signing): Sample Receipt Criteria ; Comments/Qualifiers (Required for Non-Conforming Items)'," Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container oftr (describe)
I..Samp requiring cold Circle Coolant # ice bags blue ice dry ice none other describe)2 preservai'within (4 +/- 2 C)?*Record preserv' *n method.3Chain of custody d nts included with shipment?
_ ____ __4 Sample containers intact and Circle Applicable:
seals broken damaged container leaking comainer other (describe) sealed? I Samples requiring chemical Sample ID's. containers affecwd and observed pH: preservation at proper pH? 1_ _,_..6 VOA vials free of headspace IsnuSle ID's and containers affected: (defined as < 6mm bubble)?Are Encore containers present? /}, 7 (If yes, immediately deliver to VOA laboratory)"6LP 8 Samples received within holding Id's and t time?Sample ID's on COC match ID's Sample ID's and containers affected: on bottles? ,.. ...10 Date & time on COC match date Sample ID's affected:& time on bottles?Number of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in 12 relinquished/received sections?1 4 Air Bill ,Tracking
- 's, & 5 "q 1 4?5 /70 Additional Comments q2&o, -W RSORAD Receipt # __Sr *If > x2 area background is observed on samples identified as "non-S H a n regulated/non-radioactive", contact the Radiation Safety group for further F investigation.
A JRadiological Classification?
Maximum Counts Observed*:
PCB Regulated?
0, Comnmrlrts:
fShipped as IJUr Hazardous
.00 t ardCssSip:
C Materi? If yes, contact Waste Hazard Class Shipped: NManager or ESH Manager. I PM (or PMA) review of Hazard classification:
initials D 77 j /o U Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424.860-267-2556
"?roject Name: Haddam Neck Decommissioning
ý2ontact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D. [] 14 D. EI 7 D.Samples Shipped Via: 0 Fed Ex El ups 0J Hand[] Other Bill of Lading #-7 o- 9.00o- 4,411 Connecticut Yankee Statement of Work for Analytical Lab Services Cy-ISC-S0W-001 Figure 1. Sample Check-in List.DaterTime Received:
4 11 o , *(i" SD G #: A. A .7-( (0 .0 Work Order Number _ _4.7_ _ _ _ _ _Shipping .Coan er 113:ý 3M 0'_ShppngchtainrD
ýSE. (f ) v~??t Chain of Custody'#
~4' coysk'- (--I. Custody Seals olishipping container intact?. Ye. -Y No : 2. Custody Seals dated and. signed? Yes- No 3. Chain-of-Custody record present? Yes A).No [-4. Coolertmperature
.".5. Vermiculite/packing materials is: -Wet oDry \J]6: .' Numerofsan-ipes hppiSngcontai.
()x 'An- 3 ¥..7. Sample. holding tims exceeded?
Yes [ J No L)8. Samples havei-..__hazard labels S"
-.._-appropriate sample labels 9. Samples are; -..-i-ngood condition-leakin
- ' .........have air bubbl"s 10. Were any anormalies identifJed insamnpereceipt-Yes []No [)11.. .Descriptionofanomalies(include sample numbers): Sample CustodianALaboratory.
ae Telephoned to: ..Page 28 of 105 SAMLERECEIPT
& REVIEW FORM CA1 0T~f, 1V1.UZ- a, 7 PMo Vt Client: SDG/ARCOCIWork Order: 16 Z 93 /-Lat R cIivd 5-J PM(A) Review (srn.cuforsln~
itemi are resalved priom to sigaing): '___________________________
-" Sample Receipt Criteria Commentsl/Qualiriers (Required for Non-Conforming Items)I Shipping containers received intact Dirck Applicable; seals broken damaged container leaking container oaer (describe) and sealed? ____Samples requiring cold Circlk Codlmt ice bags blue ice dry c ( oier desri&)2 preservation within (4 + /- 2 C)?Record preservation method. ,_ ,. __,_.......
..Chain of custody documents C.OUs a 6 \/W ,Uk included with shipment? , ., Sample containers intact and inic abkcaIb ea darnaged coainer eaki cainer adi1ct (describc) sealed? Wo S c.ooll," a:rx=Samples requiring chemical sipk W3. conaine affecd and observed pH.-preservation at proper pH? r VOA vials free of headspace Sm ID' and conwtiners aftected: (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory) 8 Samples received within holding Id's and ts afece: ,ime?9 Sample ID's on COC match ID's Sample ID's and containers affected: on bottles?Date & time on COC match date Sample Ws affected:& time on bottles?Number of containers received match number indicated on COC?COC form is properly signed in no .c.a5.. v .iL i va d relinquished/received sections?Air Bill ,Tracking
- 's, & To .C (C )U .C,4- () -* Is Additional Comments-* RSO RAD Receipt I Suspected Hazard Information
_0 .*If > x2 area background is observed on samples identified as -non-Sd regulated/non-radioacive.
comact dhe Radiation Safety group for fiurther___ investigation.
A laadiological Classification?
Maximum =Counts Observed*:
IB lCB Regulated?
Comments: fSHipped as IXtI Hazardous C Material?
If yes, contact Waste I Hazard Class Shipped:_Manager or ESH Manager. UNI;PM (or PMA) review of Hazard classification:
initials Date: ti D1A Ci age 7> U 105 V SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM VAm 16,7 94Z.32 16 f 9a5--1' q 0l " 50 (0L-r C"0C ) a (.,.)r i kcIC, hc~d o0 .... "_" 5 st hiado JLfsf __Page 30 of 105*1 T1 in .
Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major 0 Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00367 362 Injun Hollow Road, East Hampton, CT 06424 860.267-2556 3-7_________________
___________________________
Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones C A .;14 Z Priority:
Z 30 D. [] 14 D. E] 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0008-001F 5/05/06 11:13 SE C BP X X X Transferred from COC # 2006-00324 9106-0008-003F 5/5/06 13:35 SE C BP X X X Transferred from COC # 2006-00325 9106-0008-004F 5/5/06 13:51 SE C BP x x x Transferred from COC # 2006-00325 9106-0008-005F 5/5/06 14:17 SE C BP x x x Transferred from COC # 2006-00325 9106-0008-006F 5/5/06 14:36 SE C BP x x x Transferred from COC # 2006-00325 9106-0008-006FS 5/5/06 14:36 SE C BP x x x Transferred from COC # 2006-00325 9106-0008-007F 5/5/06 15:03 SE C BP X Transferred from COC # 2006-00325 9106-0008-002F 5/5/06 13:10 SE C BP x X X Transferred from COC # 2006-00325 NOTES: PO #: 002332 MSR#: 06-7'"q,3 SSWP# NA Z LTP QA E] Radwaste QA E] Non QA 1) elinqu she Date/Time
- 2) e ived ate/Time 3)
By ,J Date/Time
- 4) RieeiveZ y ime Samples Shipped Via:[ Fed Ex El Hand El Other Bill of Lading #R V 564/ 11(P2_Internal Container Temp.: _ Deg. C Custody Sealed?YO NO Custody Seal Intact?YO NEI Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Health Physics Procedure GPP-GGGR-R5 104-003-Attachment B-CY-O0 1 Major Chain of Custody Form Connecticut Yankee Atomic Power Company UJ 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Ao__ LP V.Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only~Comments:
U Contact Name & %one: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road, Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones W Cn Z Priority:
Z 30 D. [ 14 D. 7 7 D. Container Sample Size-"DMedia Type &Tye Comment, Preservation Lab Sample ID Sample Designation Date Time Code Code Code CmetPrsvainabSplI (0 9106-0008-008F 5/08/06 08:01 SE C BP X X X Transferred from COC #2006-00327 0 9106-0008-009F 5/08/06 08:3 2 SE C BP X X X __" _ Transferred from COC # 2006-00327 0ol 9106-0008-010F 5/08/06 09:09 SE C BP X X X Transferred from COC # 2006-00327 ol 9106-0008-01OFS 5/08/06 09:09 SE C BP X X X Transferred from COC #2006-00327 011 9106-0008-01OF 5/08/06 09:30 SE C BP x X X Transferred from COC # 2006-00327)Iý. 9106-0008-012F 5/08/06 09:53 SE C BP X Transferred from COC #2006-00327
ýItt 9106-0008-013F 5/08/06 10:16 SE C BP X X x Transferred from COC # 2006-00327 N5 9106-0008-014F 5/08/06 10:47 SE C BP x x x Transferred from COC # 2006-00327 NOTES: PO #: 002332 MSR #: 06-Jq3 SSWP#NA SLTP QA Dl Radwaste QA E] Non QA Samples Shipped Via: 0 Fed Ex[] UPS E] Hand Dl Other Bill of Lading #Internal Container Temp.: "ZI Deg. C Custody Sealed?YO0 N)Custody Seal Intact?Y50 NO 1) Relinquished By Date/Time
- 2) Received By Date/Time 3) Relinquished By Date/Time
- 4) Received By Date/Time Connecticut Yankee Statement of Work for Analytical Lab Services 163274. w-CY-ISC-SOW-O0l F Date/Time Received: .A bmo SDG#: igure 1. Sample Check-in List.Work Order Number: Shipping Cdntainer ID:M. -Chain of Custody#"" 1. Custody Seals oii shipping container intact? -Yes I I 2. Custody Seals dated and signed? Yes' 7 No [, 3. Chain-of-Custody record present? " Yes [.-]"o I ].4. Cooler temperature I 5. Vermiculite/packing materials is: Wet M J Dry , J IVAJ.o 6: Number of samples in shipping container: " ;7. Sample holding times exceeded?
Yes [ ] No 10. Were any anomalies identified in sample receipt? Yes [] No 11. Description of anomalies (include sample numbers): Telephoned to:. n y on By. *.. ..Page 33 of 105 SAMPLE RECEIPT & REVIEW FORM#I PM UKe 00 I Bade: SD/A1RC1OCMMWorVkOrde:
f~at Reeirii.-C) (A)W~w(am"ur nou*tW~ftMU
~Ite are mol~ved Kprim ft" Recei-ved BY! , Sainple Recept Criteria gI ConuneutslQualilers (Required for Non-Conforming Items)and sealed? /)Samples requiring cold ,hee C"ho-- ice bar blae ice dry ice otbeeO&M 2 preservaation within (4 +/-2 C)/Record preservation method. -__ _ _ _.......3Chain of custody documents included with shi _ ?.......4 SampLe containers intact and Q ippli"cahWe sas broke dimapdwiconer leakin cnbwe adwc (descnifc)-scaled? ...._______________
Samples requiring chemical / ls .ID's. m'. affecoed and observed pH: preservation at proper pH? .......6 VOA vials free of headspace ID', as com.imes aracwd;(defined as < 6mm bubble)? /Are Encore containers present?7 (If yes. Imnndiately deliver to VOA laboratory) i 8 Samples received within holding /Id' and fs ftcW: time? --_ __----9 p D's on COC match ID's / s nies affeceed;-on bottles? _____________________
Dafte&lime on COC match date ID's affeemd:& time on bottles?Number of contafi-rs received :D'saffeeed:
match number indicated on COC?12 COC form is properly signed in relinquhedlreceived sections?4Air Bill ,Tracking
- 's, &Additional Comn~ts Suspected Hazard Information I V X cIpII________________
S0 R e c e ipx 2 a bckgr o is o b"ere d o n sM le s k f i e ed a s O n' .Ag .9htdflnon-radioctive", contact the Radiation Safety grou for furthe n .... ....... .* 'A 601UUIOOg5C8
%.asasflcation? (fut'I j 'A egulted? '4 t-N~lP~ asMT.Hazardous
--CMaterial?.
if ye, contact Waste "/Manager or ESH Manager.Counts Observed C40 h--1 3--ZJ HlaZwd Class Shipped: LINO: I'M (or PMA) review of Hazard classification:
'fltl~aJD
-, /J-z4'/&k Date: Page 34 of 105 0 SAMPLERECEIPT
& REVIEW FORM~PM use onl Client: yan~keu ~SDGIARCOC/Work Order: ()74//j Date Received:
jcoPM(A Review (ensure noo-confortning item wre resolved prior to signing):
J Received By: I Sample Receipt Criteria 4 Comments/Qualiflers (Required for Non-Conforming Itenis)Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) and sealed? __Samples requiring cold Circle Coolant 9 ice bags blue ice dry ice other describe)2 preservation within (4 +/- 2 C)?Record preservation method. .21/ 'Chain of custody documents included with shipment?4 Sample containers intact and Circle seals broken damaged leaking oter-(describe) sealed?Samples requiring chemical Sample ID's. containers affected and observed pH: preservation at proper pH?VOA vials free of headspace Sample ID's and containers affected: 6 (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory) 8 Samples received within holding Id's and sea affected: lime? ___9 Sample ID's on COC match ID's Sample 1.,s and containers affected: on bottles?10 Date & time on COC match date Sample ID's affected:& time on bottles?Number of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in [ c-.-- 1.t.l arnq.1Jkd relinquished/received sections?1 4 A ir B ill ,T r a c k in g # 's , & 'j V c -'I 1c _ -t -e L a c Additional Comments Iv Suspected Hazard Information V let.'Ian'IRSO RAD Receipt #I if > x2 area background is observed on samples identified as "non-regulated/non-radioactive', contact the Radiation Safety group for further investigation.
A lRadsological Classification'!
!2-4 FV I B PCB Regu Shipped as DOIi Hazardous C Material?
If yes, contact Waste L Manager or ESH Manager. ,, Maximum Counts Observed*:
Vf CA44 Comments: Hazard Class Shipped: UN#: Initials Z Date: I PM (or PMA) review of Hazard classification:
Page 35 of 105 Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Check-in List Date/Time Received:
57'! taI ( 003z.SDG#: Work Order Number: Shipping Cdntainer ID: -79c Z I 1 173 Chain of Custody'# "L_ a(S?3-1 " LaC., I. Custody Seals oni shipping container intact?- Yes k 0 [ ]2. Custody Seals dated and signed? .1Yes , o [ ]3. Chaia-of-Custody record present? Yes Ilo [ ]4. Cooler temperature
- 5. Vermiculite/packing materials is: Wet Dry i']6. Number of samples in shipping container:
Y ._A h tk 7. Sample holding times exceeded?
Yes-[ ] No 8. Samples have: tape ____hazard labels custody seals ____appropriate sample labels 9. Samples are:.i°"in good condition leaking__._broken have air bubbles 10. Were any anomalies
- identified in sample receipt? Yes [ ] No [-<* 11 Pescription of anomalies (include sample numbers):
"_IA Sample. Custodian/Laboratory:
Telephoned to: On By Page 36 of 105 GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Health Physics Procedure I"Lj g%/_1 J HLet h-r dG -R 14 Aa e B Y I a Chain of Custody Form No. 2006-00380 CD Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 o 860-267-2556 2 Project Name: Haddam Neck Decommissioning Analyses Requested
':LabYfUse Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Z Priority:
Z 30 D. D 14 D. E 7 D. Container Sample Size-Media Type &Type, C .La S" Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID ,1 9106-0009-016F 5/15/06 13:28 SE C BP x x Transferred from COC 2006-00352 p 9106-0009-016FS 5/15/06 13:28 SE C BP X X Transferred from COC 2006-00352 9106-0009-017F 5115/06 14:03 SE C BP X X Transferred from COC 2006-00352 9106-0009-01 IF 5/15/06 08:05 SE C BP x Transferred from COC 2006-003519106-0009-013F 5/15/06 08:35 SE C BP X X Transferred from COC 2006-00351
_5 "9106-0009-013FS 5/15/06 08:3_ 5 SE C BP X x Transferred from COC 2006-00351 P 9106-0009-014F 5/15/06 08:59 SE C BP X Transferred from COC 2006-00351 9106-0009-015F 5/15/06 09:36 SE C BP X X TransferredfromCOC 2006-00351 NOTES: PO #: 002332 MSR #: 06-O/S4 SSWP# NA Z LTP QA D] Radwaste QA E] Non QA 1) Relinquis~ed By Date/Time
- 2) RecV d y Date/Time 3) Relinquished By Date/Time
- 4) Releive By Date/Time Samples Shipped Via:[ Fed Ex IZUPS H Hand E] Other Bill of Lading#-rq1_1 /- I ? 6 Internal Container Temp.: __ Deg. C Custody Sealed?YD NO Custody Seal Intact?Y[7 Nfl Health Physics Procedure/ 1~-/ $ 1 I GPP-GGGR-R5104-003-Attachrnent B-CY-001 Major e- I- I or C LU Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00381 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D. E] 14 D.E] 7 D. Container Sample Size-M e d ia T y p e & T y p eC o m n , P e e v t oL a S m p e I Sample Designation Date Time CodeC Comment, Preservation La Sample ID 1' 9106-0009-001F 5/11/06 13:22 SE C BP x x TransferredfromCOC2006-00347) 9106-0009-002F 5/11/06 13:46 SE C BP x X TransferredfromCOC2006-00347 9106-0009-003F 5/11/06 14:06 SE C BP X X Transferred from COC 2006-00347 9106-0009-004F 5/11/06 14:30 SE C BP X X Transferred from COC 2006-003479106-0009-005F 5/11/06 14:55 SE C Bp X x Transferred from COC 2006-00347 j.. 9106-0009-007F 5/12/06 07:44 SE C BP X X Transferred from COC 2006-00348 9106-0009-008F 5/12/06 08:16 SE C BP X X Transferred from COC 2006-003489106-0009-009F 5/12/06 08:35 SE C BP X X Transferred from COC 2006-00348 ( 9106-0009-01OF 5/12/06 09:07 SE C BP XX Transferred from COC 2006-00348 o0 0(J 01 NOTES: PO #: 002332 MSR #: 06-SSWP# NA Z LTP QA EJ Radwaste QA F1 Non QA 1) Relinquished By Date/Time
- 2) R'ecee y Date/Time 3) Relinquished By Date/Time
- 4) Received by Date/Time Samples Shipped Via:[ Fed Ex LUPS EHand L] Other Bill of Lading #4q Il /7 /ýr'Internal Container Temp.: _ Deg. C Custody Sealed?YE] NO0 Custody Seal Intact?Y E N17 Connecticut Yankee Statement of Work for Analytical Lab Services I " -P5iX; F4 (2. .ILI)-CY-lsC-sOw-o00 Figure 1. Sample Check-in List Date/Time Received:
---0 k, SDG#: _\S RJ.ýk CA, --0 Work Order Number: Shipping Cdhtainer ID:. -1. Custody Seals orf shipping container intac 2. Custody Seals dated and signed?3. Chain-of-Custody reord present?4. Cooler temperature
.AIQor.5. Vermiculite/packing materials is: 6.' Number of samples in shipping container:
- 7. Sample holding times exceeded?L01~f I It Chain of Custody# .- ., a t?.. Yes D4 No[]Yes*[ ]No [Yes M No t I Wet [].Dry*Yes [)( No [I).8. Samnple~s have:itapc .hazad labels"< custody seals -...appropriate sample labels 9. Samples are:'* ,-in good condition
.leaking-bmken i.ihave air bubbles 10.11.Were any anomalies identified in sample receipt? Yes [] No.Description of anomalies. (include sample numbers): Sample Custodian/Laboratory:
.Date: ..- 71ýTelephoned to" : On By_. _ " Page 39 of 105 Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00349 362 Injun Hollow Road, East Hampton, CT 06424 4 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones co Priority:
Z 30 D. El 14 D. E] 7 D. Container Sample Size-/ /O.Media Type &Type Saample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID a 9106-0010-001F 5/04/06 10:49 SE C BP X X Transfmred from COC 2006-00321 6tO 9106-0010-002F 5/04/06 11:12 SE C BP x x Transferred from COC 2006-00321 Olt 9106-0010-004F 5/04/06 12:48 SE C BP X X Transferred from COC 2006-00321 9106-0010-006F 5/04/06 13:34 SE C BP X X Transferred from COC 2006-00321 9106-0010-007F 5/04/06 13:21 SE C BP X x Transferred from COC 2006-00321
-9106-0010-009F 5/04/06 14:01 SE C BP X X Transferred from COC 2006-00321 9106-0010-OIOF 5/04/06 14:21 SE C BP X X Transferred from COC 2006-00321
-9106-0010-012F 5/04/06 14:44 SE C BP X X Transferred from"COC 2006-00321 9106-0010-013F 5/04/06 15:06 SE C BP X Transferred from COC 2006-00321 NOTES: PO #: 002332 MSR#: 06- 070" SSWP#NA SLTP QA El Radwaste QA E] Non QA 1) RelinquishelBy Date/TF e 2) Received y Date/Time 3) Relinquished By Date/Time
- 4) Received By I Date/Time Samples Shipped Via:[ Fed Ex[]UPS[] Hand F] Other Bill of Lading II.ý q04 -3 1;Internal Container Temp.: Z7Deg. C CustodSealed?
Yff" NO Custody Seal Intact?YVN 0 Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-O01 Figure 1. Sample Check-in List Date/T'ime Received:
9L/7 S / .0 6 SDG#,: 1. O 0~7j2 -7 Work Order Number: Shipping Cdftainer ID: -O7 3110 55 ?l Chain of Custody#'
6- 3,/7 I. Custody Seals oni shipping container intact?.. -Yes. [" No [1 2. Custody Seals dated and signed? Yes [j] No []3. Chain-of-Custody record present? " Yes No[].4. Cooler temperature (7* C 5. Vermiculite/packing materials is: Wet ] Dry ]6.* Number of samples in shipping container:
._:_ _ _7. Sample holding times exceeded?
Yes I No PJ 8. Samples have:_tape -_hazard labels_.._ custody seals -.appropriate sample labels 9. Samples are:_._n good condition
_Vleaking-broken .have air bubbles 10. Were any anomalies identified in sample receipt? Yes [] No IXQ 11....Description of anomalies (include sample numbers):
.__,.Smple. Custodian/Laboratory:
.. Date.: .--- " Telephoned to: On By.Page 41 of 105 I, 111l -11111 SAMPLE RECEIPT & REVIEW FORM 00 J ro0R 0-" P'M ueonly Client: rlt y £6g SD/ROCW Ordr Date Received:
5'- -ob PM(A) Review ( I items are resolved prior to signing): Received By: *Lk-. .Sample Receipt Criteria Z Z Com ents/Qualifiers (Required for Non-Conforming Items)Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) and sealed? I Samples requiring cold Circle Coolant # ice bags blue ice dry ice jjtZne other describe)2 preservation within (4 +/- 2 C)?Record preservation method. ..Chain of custody documents included with shipment?4 Sample containers intact and Circle Applicable:
seals broken damaged container leaking container other (describe) sealed?5 Samples requiring chemical Sample ID's. containers affecled and observed pH: Preservation at proper pH?6 VOA vials free of headspace Sample ID's and containers affected: (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory) 8 Samples received within holding Id's and tests affected: time?Sample ID's on COC match ID's Sample ID's and containers affected: on bottles?10 Date & time on COC match date Sample ID's affected:& time on bottles?Number of containers received Sample ID's affected: match number indicated on COC? O COC form is properly signed in 2 relinquished/received sections?4 Air Bill ,Tracking
- 's, & h/'I Additional Comments 7 YI/ 3 " -' RSO RAD Receipt #S*If > x2 area background is observed on samples identified as "non-Suspected Hazard Information r Z , a regulatedlon-radioactive".
contact the Radiation Safety group for further A investigation.
A BRadiological Classification?
Maximum Counts Observed*:
BB IMp Regulated?
HaCardonts:
rShipped as DOI' Hazardous C fMaterial?
If yes, contact Waste Hazard Class Shipped:lManager or ESH Manager. !.UN#: PM (or PMA) review of Hazard classification:
Initials Date: /7,,4 Page 42 of 105 List of current GEL Certifications as of 15 August 2006 State Alaska Arizona[. ~ ~Arkansas
'-_." CLIA!California
--.-... .. ... .C olo~rado .. .[ _.. .['.Connecticut Dept. of Navy -EPAj Florida/NELAP Georgia Idaho Illinois Indiana Kansas Kentucky Maryland Massachusetts Michigan Nevada--New Jersey New York North Carolina North Carolina Drinking W North Dakota Oklahoma Pen ns yl vania South Carolina Tennessee Texas U.S. Dept. of Agriculture US Army Corps of Engineer Utah Vermont Virginia---Washington Certification UST-062*_ _ -AZO_6_68_._-
.7 [ -7 88-0651 42D0904046 01I51CA....-GenE-ngLabs
..... ., PH-0_169------
-NFRSC 413 E87 156 __E87156 (FL/NELAP)
NIA 200029 C-SC-01I E-10332 90129 270 M-SCO12 9903 SC12 11501 233_45_7097 R-15 994 68-485 -10120001/10585001/10120002 02934 213 S-52597 N/A 8037697376 GEL N/A 00151 C223 Page 43 of 105 RADIOLOGICAL ANALYSIS Page 44 of 105 Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)Work Order 168404 Method/Analysis Information Product: Alphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 555696 554650 554649 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404011 168404012 168404013 168404014 168404015 1201153129 1201153130 1201153131 1201153132 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-01OF 9106-0005-014F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-00 1F 9106-0010-012F Method Blank (MB)168340011(9304-01-005C)
Sample Duplicate (DUP)168340011(9304-01-005C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Page 45 of 105 Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340011 (9304-01-005C).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Sample 168404003 (9106-0003-004F) was recounted due to high MDA.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Page 46 of 105 Product: Alphaspec Am241, Cm, Solid ALL FSS DOE EML HASL-300, Am-05-RC Modified Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 557837 554650 554649 Sample ID 168404009 168404010 1201158316 1201158317 1201158318 1201158319 Client ID 9106-0006-005F 9106-0008-006F Method Blank (MB)168404009(9106-0006-005F)
Sample Duplicate (DUP)168404009(9106-0006-005F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168404009 (9106-0006-005F).
QC Information Page 47 of 105 All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: AIphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu-I -RC Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 555697 554650 554649 Page 48 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201153133 1201153134 1201153135 1201153136 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-01OF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-OO1F 9106-0010-012F Method Blank (MB)168340011(9304-01-005C)
Sample Duplicate (DUP)168340011(9304-01-005C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340011 (9304-01-005C).
QC Information All of the QC samples met the required acceptance limits.Page 49 of 105 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- I1-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 1 555698 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Page 50 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201153137 1201153138 1201153139 1201153140 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-OIOF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-OOIF 9106-0010-012F Method Blank (MB)168340011(9304-01-005C)
Sample Duplicate (DUP)168340011 (9304-01-005C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QCQ Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340011 (9304-01-005C).
QC Information All of the QC samples met the required acceptance limits.Page 51 of 105 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: GFPC, Sr90, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 556350 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Page 52 of 105 Sample ID 168404003 168404004 168404012 168404013 168404014 168404015 1201154644 1201154645 1201154646 1201154647 Client ID 9106-0003-004F 9106-0003-015F 9106-0009-002F 9106-0009-017F 9106-0010-001F 9106-0010-012F Method Blank (MB)168404003(9106-0003-004F)
Sample Duplicate (DUP)168404003(9106-0003-004F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168404003 (9106-0003-004F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Page 53 of 105 Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Samples 1201154644 (MB), 1201154645 (9106-0003-004F), 1201154646 (9106-0003-004F), 1201154647 (LCS), 168404003 (9106-0003-004F), 168404004 (9106-0003-015F), 168404012 (9106-0009-002F), 168404013 (9106-0009-017F), 168404014 (9106-0010-001F) and 168404015 (9106-0010-012F) were dried and reweighed due to low matrix spike/laboratory control sample recovery.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 554580 Page 54 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201150561 1201150562 1201150563 1201150564 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-OIOF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-00 1F 9106-0010-012F Method Blank (MB)168340012(9304-02-003C)
Sample Duplicate (DUP)168340012(9304-02-003C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (OC Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340012 (9304-02-003C).
QC Information All of the QC samples met the required acceptance limits.Page 55 of 105 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-1, Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 555722 554650 554649 Page 56 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201153222 1201153223 1201153224 1201153225 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-01OF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-001F 9106-0010-012F Method Blank (MB)168340012(9304-02-003C)
Sample Duplicate (DUP)168340012(9304-02-003C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340012 (9304-02-003C).
QC Information All of the QC samples met the required acceptance limits.Page 57 of 105 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-1, Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 555723 554650 554649 Page 58 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 1201153226 1201153227 1201153228 1201153229 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-01OF 9106-0005-014F 9106-0006-005F Method Blank (MB)168340012(9304-02-003C)
Sample Duplicate (DUP)168340012(9304-02-003C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340012 (9304-02-003C).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Page 59 of 105 Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: LSC, Tritium Dist, Solid-HTD2,ALL FSS Analytical Method: EPA 906.0 Modified Analytical Batch Number: 554582 Sample ID Client ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-01 OF 168404008 9106-0005-014F 168404009 9106-0006-005F 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-001F 168404015 9106-0010-012F 1201150569 Method Blank (MB)1201150570 168340011(9304-01-005C)
Sample Duplicate (DUP)1201150571 168340011(9304-01-005C)
Matrix Spike (MS)1201150572 Laboratory Control Sample (LCS)Page 60 of 105 SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 12.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340011 (9304-01-005C).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Sample 168404010 (9106-0008-006F) was recounted due to high MDA.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Page 61 of 105 Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint C14, Solid AII,FSS Analytical Method: Analytical Batch Number: Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201150573 1201150574 1201150575 1201150576 EPA EERF C-01 Modified 554583 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-OIOF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-001F 9106-0010-012F Method Blank (MB)168404003(9106-0003-004F)
Sample Duplicate (DUP)168404003(9106-0003-004F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Page 62 of 105 Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QCQ Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168404003 (9106-0003-004F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator.
In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.Page 63 of 105 The following data validator verified the information presented in this case narrative:
Reviewer/Date: : Page 64 of 105 SAMPLE DATA
SUMMARY
Page 65 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co.Client SDG: 168404 GEL Work Order: 168404 The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.ND The analyte concentration is not detected above the detection limit.The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures.
Please direct any questions to your Project Manager, Cheryl Jones.Reviewed by Page 66 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: 9106-0002-007F Project: YANK01204 Sample ID: 168404001 Client ID: YANK001 Matrix: SE Vol. Recv.: Collect Date: 18-MAY-06 Receive Date: 02-JUN-06 Collector:
Client Moisture:
20.9%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.(Curium-242 U Curium-243/244 U -0.0(Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0 Plutonium-239/240 U 0.1 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon- 14 U 0.t Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0 0762 0.00 0853.199 0341 10.0 4.17 0813 9.90 7.02.139+/-0.102+/-0.0995+/-0.0717+/-0.228+/-0.129+/-6.64+/-6.67+/-0.0797+/-48.1+/-6.39+/-0.213 0.00 0.00 0.0405 0.181 0.120 5.08 5.28 0.0634 32.0 5.18 0.173+/-0.102+/-0.0995+/-0.0717+/-0.229+/-0.129+/-6.72+/-6.67+/-0.0797+/-48.1+/-6.40+/-0.213 0.0956 0.138 0.177 0.444 0.323 10.7 11.4 0.132 65.9 10.6 0.360 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXL1 08/11/06 1336 555696 1 BXLI 08/11/06 1633 555697 2 BXL1 08/16/06 1220 555698 3 DFAI ATH2 MXPI MXPI EGD1 08/09/06 1128 554582 08/09/06 0324 554583 08/12/06 1633 555722 08/11/06 0738 555723 08/11/06 2027 554580 4 5 6 7 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-1I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified Page 67 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0002-007F 168404001 Proiect: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty 5 EPA EERF C-01 Modified 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Americium-243 Alphaspec Am241, Cm, Solid/Plutonium-242 Alphaspec Pu, Solid-ALL FSS Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL LC TPU MDA Units DF Analyst Date Time Batch Mtd Recovery%
Acceptable Limits ALL LF5 FS FS FS 80 100 98 75 76 74 (15%-/125%)
(15/o-I125%)
(25%-i125%)
(15%-/125%)
(25%-I125%)
(15%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 68 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Report Date: August 21, 2006 9106-0002-011F 168404002 SE 19-MAY-06 02-JUN-06 Client 17.4%Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Ri Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U (Curium-242 U -0.Curium-243/244 U -0.Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.Plutonium-239/240 U 0.Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -0 Liquid Scint C14, SolidAll,FSS Carbon-14 U C Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0 esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd).120 0146 0103 0121 0254 6.72 1.521 1.023 3.93 7.52 I.173+1-0.154+/-0.122+/-0.0861+/-0.125+/-0.0675+/-7.02+/-7.03+/-0.0828+/-47.7+/-5.81+/-0.203 0.0683 0.0692 0.0487 0.127 0.0381 5.56 5.94 0.0685 31.9 4.68 0.164+/-0.155+/-0.123+/-0.0862+/-0.125+/-0.0675+/-7.05+/-7.03+/-0.0828+/-47.7+/-5.81+/-0.203 0.251 0.303 0.213 0.344 0.167 11.7 12.8 0.143 65.7 9.60 0.341 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1336 555696 1 BXL1 08/11/06 1633 555697 2 BXLI 08/16/06 1237 555698 3 DFAI ATH2 MXP1 MXP1 EGD 1 08/09/06 1143 554582 08/09/06 0426 554583 08/12/06 1649 555722 08/11/06 0825 555723 08/11/06 2043 554580 4 5 6 7 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-1 I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified Page 69 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0002-01 IF Project: YANK01204 Sample ID: 168404002 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 76 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 100 ( 15%- 125%)Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL Fý 88 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 72 (15%- 125%)Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 76 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 79 (15%/-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 70 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Report Date: August 21, 2006 9106-0003-004F 168404003 SE 25-APR-06 05-MAY-06 Client 23.5%Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.027 Curium-242 U 0.112 Curium-243/244 U 0.0217 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.061 Plutonium-239/240 U 0.0551 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 8.31 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00343 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.603 Liquid Scint C14, SolidAlLFSS Carbon-14 U 0.0937 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 7.68 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 5.74 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0643 Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.117+/-0.315+/-0.206+/-0.189+/-0.103+/-5.73 0.153 0.245 0.205 0.176 0.0584 4.40+/-0.117+/-0.315+/-0.206+/-0.189+/-0.103+/-5.78+/-0.0203 0.0172 +/-0.0203 0.488 0.781 0.594 0.449 0.215 9.25 0.036 14.8 0.134 70.4 13.6 0.351 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXL1 08/13/06 0819 555696 1 BXL1 08/11/06 1633 555697 2 BXLI 08/16/06 1253 555698 3 BXFI 08/14/06 0834 556350 4+/-8.25+/-0.0813+/-51.2+/-7.12+/-0.198 6.87 0.0642 34.2 6.58 0.169+/-8.25+/-0.0813+/-51.2+/-7.13+/-0.198 DFA I ATH2 MXP1 MXP I EGD 1 08/09/06 1159 554582 08/09/06 0529 554583 08/12/06 1706 555722 08/11/06 0912 555723 08/11/06 2059 554580 5 6 7 8 9 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified Page 71 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0003-004F 168404003 Project: Client ID: Vol. Recv.: YANK0 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 3 4 5 6 7 8 9 DOE EML HASL-300, Pu-I I-RC Modified EPA 905.0 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-I, Modified DOE RESL Ni-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýGFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%42 92 113 59 71 83 76 Acceptable Limits (15%-125%)
(15%-125%)
(25%-i125%)
(25%-6125%)
(15%-125%)
(25%-125%)
(15%-,125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded Page 72 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Ci-rtifirntP of Annlvqir Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0003-004F 168404003 Proiect: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd The above sample is reported on a dry weight basis.Page 73 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Report Date: August 21, 2006 9106-0003-015F 168404004 SE 25-APR-06 05-MAY-06 Client 22.5%Proiect: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0456 Curium-242 U 0.113 Curium-243/244 U 0.180 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0196 Plutonium-239/240 U 0.0326 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 6.63 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.00477 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 1.03 Liquid Scint C14, SolidAllFSS Carbon-14 0.156 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -9.99 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 0.939 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.237 Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.155+/-0.181+/-0.239+/-0.121+/-0.0639+/-6.19 0.139 0.0733 0.181 0.118 0.00 4.86+1-0.155+/-0.182+/-0.240+/-0.121+/-0.064+/-6.22+/-0.0216 0.0179 +/-0.0216 0.387 0.321 0.472 0.324 0.0884 10.2 0.0375 12.6 0.146 59.2 21.6 0.353 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1309 555698 3 BXFI 08/14/06 0834 556350 4+/-7.06+/-0.0912+/-42.7+/-10.1+/-0.213 5.85 0.0699 28.7 10.3 0.170+/-7.06+/-0.0913+/-42.7+/-10.1+/-0.213 DFA I ATI-12 MXPI MXPI EGD1 08/09/06 1215 554582 08/09/06 0632 554583 08/12/06 1722 555722 08/11/06 1001 555723 08/11/06 2115 554580 5 6 7 8 9 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I 1-RC Modified Page 74 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0003-015F 168404004 Project: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter 3 4 5 6 7 8 9 Qualifier Result Uncertainty DOE EML HASL-300, Pu-I I-RC Modified EPA 905.0 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-I, Modified DOE RESL Ni-1, Modified DOE EML HASL-300, Tc-02-RC Modified LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Test Recovery%
Acceptable Limits Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 78 94 101 58 75 62 75 (15%-125%)
(15%-125%)
(25%-/125%)
(25%-125%)
(15%-125%)
(25%-/125%)
(15%/,125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded Page 75 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0003-015F 168404004 Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd The above sample is reported on a dry weight basis.Page 76 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005F 168404005 SE 03-MAY-06 12-MAY-06 Client 15.4%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier R Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -Curium-242 U -0 Curium-243/244 U -0 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0 Plutonium-239/240 U -0 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon- 14 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.123+/-0.033+/-0.227 0.157 0.080 0.247+/-0.123+/-0.0331+/-0.227 0.437 0.350 0.619 0.444 0.337 pCi/g pCi/g pCi/g pCi/g pCi/g+/-0.163 0.181 +/-0.163+/-0.0791 0.128 +/-0.0795 9.52 +/-6.00 4.57 +/-6.07 0.854 +/-5.88 4.87 +/-5.88 0.347 +/-0.097 0.0674 +/-0.0972-1.57 +/-46.0 30.7 +/-46.0 6.39 +/-7.62 7.40 +/-7.62 0198 +/-0.187 0.156 +/-0.187 9.61 pCi/g 10.5 pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1326 555698 3 DFA1 08/09/06 1231 554582 4 ATH2 08/09/06 0734 554583 5 MXPI 08/12/06 1738 555722 6 MXPI 08/11/06 1017 555723 7 EGD1 08/11/06 2131 554580 8 0.141 63.2 pCi/g pCi/g 15.5 pCi/g 0.324 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 3 4 5 DOE EML HASL-300, Pu- I 1-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 906.0 Modified EPA EERF C-01 Modified Page 77 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005F Proiect: YANKO1204 Sample ID: 168404005 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-1, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 65 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 95 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Pu24 1, Solid-ALL FS 105 (25%-/125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 78 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 80 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 80 (15%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 78 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-015F 168404006 SE 03-MAY-06 12-MAY-06 Client 26.5%Proiect: YANKO 1204 Client ID: YANKOOl Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.Curium-242 U -0.Curium-243/244 U -0.Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.Plutonium-239/240 U -(Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon-14 U 0.Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.+/-0.203+/-0.0301+/-0.251 0.178 0.0729 0.300+/-0.203+/-0.0302+/-0.251+/-0.213 0.210 +/-0.213+/-0.108 0.191 +/-0.109 0.469 0.319 0.713 0.521 0.483 10.8 14.2 0.149 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 6.64 +/-6.53 5.16 +/-6.57-2.9 +/-7.59 6.60 +/-7.59 0352 +/-0.0868 0.0713 +/-0.0868 1.88 +/-46.8 31.3 +/-46.8 3.88 +/-7.46 7.40 +/-7.46 0894 +/-0.198 0.163 +/-0.198 BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1342 555698 3 DFAI 08/09/06 1247 554582 4 ATH2 08/09/06 0837 554583 5 MXPI 08/12/06 1754 555722 6 MXPI 08/11/06 1033 555723 7 EGD1 08/11/06 2147 554580 8 64.4 pCi/g 15.5 0.338 pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534. 554649 The following Analytical Methods were performed Method Description 1 2 3 4 5 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-I l-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 906.0 Modified EPA EERF C-01 Modified Page 79 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-015F Project: YANK01204 Sample ID: 168404006 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 72 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 72 (15%-9125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL F5 94 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 73 (159-125%)
Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 80 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 78 (15%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 80 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Report Date: August 21, 2006 9106-0005-01 OF 168404007 SE 02-MAY-06 09-MAY-06 Client 56.2%Proiect: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier R4 Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -(Curium-242 U -0.Curium-243/244 U -0.AIphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.Plutonium-239/240 U 0.Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon-14 U 0.'Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 1.128 0115 0333 0548 0195 10.4 0.00 0636 36.1 7.26 0.05+/-0.0939+/-0.128+/-0.122+/-0.169+/-0.121+/-6.89+/-6.86+/-0.0801+/-44.1+/-10.2+/-0.199 0.142 0.147 0.149 0.158 0.117 5.27 5.76 0.0644 28.7 10.0 0.169+/-0.0942+/-0.128+/-0.122+/-0.170+/-0.121+/-6.97+/-6.86+/-0.0801+/-44.1+/-10.2+/-0.199 0.385 0.450 0.401 0.403 0.322 11.1 12.4 0.135 59.0 20.9 0.351 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1358 555698 3 DFA1 ATH2 MXP1 MXPI EGD1 08/09/06 1303 554582 08/09/06 1017 554583 08/12/06 1811 555722 08/11/06 1049 555723 08/11/06 2203 554580 4 5 6 7 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA ERRF C-01 Modified Page 81 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0005-0IOF 168404007 Project: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter 6 7 8 Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd DOE RESL Fe-l, Modified DOE RESL Ni-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%85 91 92 81 64 77 Acceptable Limits (15%-125%)
(15°/-125%)
(25%-/125%)
(15%--125%)
(25%-125%)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 82 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Certificateo T ...... 1----s Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-014F 168404008 SE 02-MAY-06 09-MAY-06 Client 32.3%Proiect: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier R Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0 Curium-242 U -Curium-243/244 U 0.Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.Plutonium-239/240 U -0.Liquid Scint Pu 2 41, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon-14 U 0.Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -C esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.219+/-0.0554+/-0.261 0.231 0.134 0.249+/-0.219+/-0.0557+/-0.261 0.608 0.494 0.646 0.434 0.369 13.6+/-0.106 0.160 +/-0.106+/-0.098 0.127 +/-0.0981 pCi/g pCi/g.pCi/g pCi/g pCi/g pCi/g 4.68 +/-8.01 6.48 +/-8.02 6.02 +/-6.38 4.90 +/-6.38 0892 +/-0.0827 0.0655 +/-0.0827 19.8 +/-46.3 30.6 +/-46.3 5.41 +/-7.91 7.77 +/-7.91 1.134 +/-0.192 0.167 +/-0.192 BXLI 08/11/06 1434 555696 1 BXL1 08/11/06 1633 555697 2 BXLI 08/16/06 1415 555698 3 DFA1 08/09/06 1319 554582 4 ATH2 08/09/06 1424 554583 5 MXPI 08/12/06 1827 555722 6 MXPI 08/11/06 1106 555723 7 EGD1 08/11/06 2218 554580 8 10.6 pCi/g 0.137 62.9 pCi/g pCi/g 16.2 pCi/g 0.346 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 3 4 5 DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 906.0 Modified EPA EERF C-01 Modified Page 83 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-014F Proiect: YANK01204 Sample ID: 168404008 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALl 50 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 61 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 74 (25%- 125%)Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 76 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 76 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15%-1125°01)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier* QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 84 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com
¢*f A nhri SLIRI~.i*LL, ~JR 1~IIUI V ~Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005F 168404009 SE 28-APR-06 12-MAY-06 Client 16.5%Project: YANKO 1204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis AIphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.0851 Curium-242 U -0.0253 Curium-243/244 U -0.0479 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0183 Plutonium-239/240 U 0.00122 Liquid Scint Pu241, Solid-ALL FSS+/-0.136+/-0.0495+/-0.0542 0.106 0.120 0.131+/-0.136+/-0.0496+1-0.0545 0.390 0.525 0.443 0.303 0.221 9.82 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g+/-0.113 0.110 +/-0.113+/-0.0662 0.0694 +/-0.0662 Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -Liquid Scint C14, Solid AIlFSS Carbon-14 (Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 4.43 +/-5.83 4.67 +/-5.85 2.02 +/-6.67 5.76 +/-6.67 1.142 +/-0.0798 0.061 +/-0.0799 12.6 +/-47.6 31.7 +/-47.6 7.70 +/-9.56 9.31 +/-9.56 BXL1 08/16/06 0949 557837 1 BXLI 08/11/06 1633 555697 3 BXLI 08/16/06 1431 555698 4 DFAI 08/09/06 1335 554582 5 ATH2 08/09/06 1719 554583 6 MXPI 08/12/06 1843 555722 7 MXPI 08/11/06 1122 555723 8 EGDI 08/11/06 2234 554580 9 12.4 pCi/g 0.127 65.3 pCi/g pCi/g 19.5 pCi/g Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.00659 +/-0.185 0.156 +/-0.185 0.323 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 3 4 5 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu- 11-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 906.0 Modified Page 85 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0006-005F 168404009 Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 7 8 9 EPA EERF C-01 Modified DOE RESL Fe-I, Modified DOE RESL Ni-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%76 93 105 72 64 81 Acceptable Limits (15°/.-125%)
(15%-125%)
(25%-125%)
(15%-.125%)
(25%-125%)
(15%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 86 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0008-006F 168404010 SE 05-MAY-06 26-MAY-06 Client 34.8%Proiect: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier R Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U Curium-242 U Curium-243/244 U -0 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0 Plutonium-239/240 U 0.C Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C04, SolidAll,FSS Carbon-14 U Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.195+/-0.202+/-0.0316+/-0.0711+/-0.113 0.0758 0.00 0.0766+/-0.196+/-0.203+/-0.0317 0.332 0.280 0.335 0.275 0.317 9.75 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 0.0967 +/-0.0712 0.118 +/-0.113 14.9 +/-6.37 4.64 +/-6.51 0.00 +/-6.06 5.09 +/-6.06 0.107 +/-0.0846 0.0664 +/-0.0846 15.1 +/-41.4 27.5 +/-41.4 0.258 +/-0.225 0.179 +/-0.225 BXLI 08/16/06 0949 557837 1 BXLI 08/11/06 1633 555697 3 BXL1 08/16/06 1447 555698 4 DFA1 08/10/06 2150 554582 5 ATH2 08/09/06 1822 554583 6 MXPI 08/12/06 1900 555722 7 EGD1 08/11/062251 554580 8 10.7 pCi/g 0.139 56.6 0.373 pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 5 6 7 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-I, Modified Page 87 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Proiect: YANK01204 Client ID: YANKOO Vol. Recv.: Client Sample ID: Sample ID: 9106-0008-006F 168404010 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Test Recovery%
Acceptable Limits Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýLiquid Scint Fe55, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 77 94 103 72 71 (15%-125%)
(15%-125%)
(25%-125%)
(15°/-125%)
(15%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UT Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 88 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: 9106-0008-008F Project: YANKO 1204 Sample ID: 168404011 Client ID: YANKOO Matrix: SE Vol. Recv.: Collect Date: 08-MAY-06 Receive Date: 26-MAY-06 Collector:
Client Moisture:
35.7%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF. Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U C Curium-242 U -(Curium-243/244 U -(Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -c Plutonium-239/240 U -c Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FS,'Tritium U Liquid Scint C14, SolidAllFSS Carbon-14 U -C Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0+/-0.192+/-0.142+/-0.202 0.152 0.132 0.240+/-0.193+/-0.142+/-0.203 0.426 0.446 0.603 0.328 0.353 pCi/g pCi/g pCi/g pCi/g pCi/g+/-0.096 0.125 +/-0.096+/-0.114 0.137 +/-0.114 11.5 +/-6.72 5.08 +/-6.80 0.00 +/-5.92 4.97 +/-5.92 1.0238 +/-0.0745 0.0636 +/-0.0745-10.7 +/-40.9 27.5 +/-40.9'.0956 +/-0.211 0.174 +/-0.211 10.7 pCi/g 10.7 pCi/g BXLI 08/11/06 1434 555696 1 BXL1 08/11/06 1633 555697 2 BXLI 08/16/06 1504 555698 3 DFA1 08/09/06 1407 554582 4 ATH2 08/09/06 1924 554583 5 MXP1 08/12/06 1916 555722 6 EGDI 08/11/06 2307 554580 7 0.133 56.8 0.361 pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 5 6 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-1, Modified Page 89 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of An'alysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0008-008F 168404011 Proiect: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 7 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýLiquid Scint Fe55, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%65 98 96 76 74 Acceptable Limits (15°-125°%)
(15%/-125%)
(25%-/125%)
(15%-125%)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 90 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0009-002F 168404012 SE 11-MAY-06 08-JUN-06 Client 33%Project: YANKO 1204 Client ID: YANKO0I Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.0 Curium-242 U 0.Curium-243/244 U I Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0 Plutonium-239/240 U 0.Liquid Scint Pu241, Solid-ALL FSS Plutonium-24 I Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon- 14 U Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U+1-0.155+/-0.145+/-0.268 0.166 +/-0.155 0.135 +/-0.145 0.281 +/-0.268+/-0.0493 0.0279 +/-0.0494+/-0.0492 0.0278 +/-0.0493 13.6 +/-6.90 5.13 +/-7.01 0151 +/-0.0146 0.0114 +/-0.0146 4.12 +/-8.36 6.70 +/-8.36).046 +/-0.0755 0.0613 +/-0.0755 12.9 +/-40.6 26.8 +/-40.6).078 +/-0.203 0.168 +/-0.203 0.458 0.455 0.687 0.122 0.122 10.8 0.0242 14.5 0.128 55.2 0.348 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1434 555696 1 BXL1 08/11/06 1632 555697 2 BXLI 08/16/06 1520 555698 3 BXFl 08/14/06 0834 556350 4 DFAI 08/09/06 1422 554582 5 ATH2 08/09/06 2027 554583 6 MXPI 08/12/06 1932 555722 7 EGD1 08/11/06 2323 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-11 -RC Modified DOE EML HASL-300, Pu-11 -RC Modified EPA 905.0 Modified Page 91 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -wwwgel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0009-002F Project: YANK01204 Sample ID: 168404012 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 61 (15/-1125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 98 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 94 (25%-125%)
Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 69 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 81 (150/-125%%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15%o7-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 92 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Parameter Qualifier Result Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0755 Curium-242 U 0.0957 Curium-243/244 U -0.073 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00629 Plutonium-239/240 U 0.0262 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 13.3 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.0205 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.583 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0271 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -61.9 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0628 9106-0009-017F 168404013 SE 15-MAY-06 08-JUN-06 Client 28.4%Project: Client ID: Vol. Recv.: YANK01204 YANKOO I Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.242+/-0.220+/-0.214 0.230 0.171 0.256+/-0.243+/-0.220+/-0.214 0.574 0.509 0.627 0.131 0.0709 pCi/g pCi/g pCi/g pCi/g pCi/g+/-0.0529 0.0299 +/-0.0529+/-0.0513 0.00 +/-0.0514+/-6.66 4.95 +/-6.77+/-0.0151 0.0116 +/-0.0151+/-7.98 6.65 +/-7.98+/-0.0759 0.0625 +/-0.0759+/-150 102 +/-150+/-0.200 0.165 +/-0.200 10.4 .pCi/g 0.0246 pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1632 555697 2 BXLI 08/16/06 1536 555698 3 BXFI 08/14/06 0833 556350 4 DFAI 08/09/06 1438 554582 5 ATH2 08/09/06 2129 554583 6 MXPI 08/12/06 1949 555722 7 EGDI 08/11/062338 554580 8 14.4 pCi/g 0.131 210 0.343 pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 3 4 DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 905.0 Modified Page 93 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0009-017F Project: YANK01204 Sample ID: 168404013 Client ID: YANKOOl Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 64 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 91 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 96 (25%-125%)
Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 72 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 73 (15/-,125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 79 (15%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria* Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 94 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0010-OO1F 168404014 SE 04-MAY-06 17-MAY-06 Client 27.3%Proiect: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, SolidALL FSS Americium-241 U 0.00677 Curium-242 U 0.0854 Curium-243/244 U 0.0361 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.173 Plutonium-239/240 U -0.0342 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 13.0 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.0128 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.548 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0555 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -18.1 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.134+/-0.227+/-0.167+/-0.242 0.238 +/-0.227 0.00 +/-0.168 0.241 +/-0.242 0.628 pCi/g 0.231 pCi/g 0.634 pCi/g+/-0.181 0.143 +/-0.182+/-0.0865 0.0951 +/-0.0866+/-6.44 4.78 +/-6.54+/-0.0141 0.0125 +/-0.0141+/-7.50 6.25 +/-7.50+/-0.0809 0.0655 +/-0.0809+/-47.6 32.3 +/-47.6+/-0.205 0.167 +/-0.205 0.331 0.235 10.0 0.0262 13.5 0.137 66.6 0.347 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1434 555696 1 BXL1 08/11/06 2250 555697 2 BXLI 08/16/06 1553 555698 3 BXFI 08/14/06 0833 556350 4 DFA1 08/09/06 1454 554582 5 ATH2 08/09/06 2232 554583 6 MXPI 08/12/06 2005 555722 7 EGDI 08/11/06 2354 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300.
Am-05-RC Modified 2 3 4 DOE EML HASL-300, Pu- 1l-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 905.0 Modified Page 95 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0010-OOIF Proiect: YANK01204 Sample ID: 168404014 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-1, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 50 (15°%o- 125%)Plutonium-242 Alphaspec Pu, Solid-ALL FSS 85 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Pu24 1, Solid-ALL Fý 99 (25%- 125%)Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 74 (25°/o- 125%)Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 70 (15%-9125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 96 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0010-012F 168404015 SE 04-MAY-06 17-MAY-06 Client 28.1%Project: YANK01204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.110 Curium-242 U -0.0547 Curium-243/244 U -0.126 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.00157 Plutonium-239/240 U 0.0867 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 8.31 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00771 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.896 Liquid Scint C14, Solid All,FSS Carbon-14 U 0.0162 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 23.3 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0577+/-0.184+/-0.141+/-0.184 0.140 0.192 0.245+/-0.184+/-0.141+/-0.185+/-0.126 0.122 +/-0.126+/-0.0869 0.0406 +/-0.0872+/-6.16 4.77 +/-6.21+/-0.0144 0.0124 +/-0.0144+/-6.17 5.11 +/-6.17+/-0.0763 0.0633 +/-0.0763+/-49.3 32.5 +/-49.3+/-0.206 0.171 +/-0.206 0.386 0.544 0.597 0.291 0.128 10.0 0.0263 11.0 0.132 67.0 0.354 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXL1 08/11/06 1434 555696 1 BXL1 08/11/062250 555697 2 BXLI 08/16/06 1609 555698 3 BXF1 08/14/06 0833 556350 4 DFAI 08/09/06 1510 554582 5 ATH2 08/09/06 2334 554583 6 MXPI 08/12/06 2021 555722 7 EGDI 08/12/06 0010 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-I 1-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 905.0 Modified Page 97 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0010-012F 168404015 Project: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 6 7 8 EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-i, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery'Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL F5 GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%81 91 99 68 74 75 Acceptable Limits (15%-/125°%)
(15%-125%)
(25%-/125%)
(25%- 125%)(15%-/125%)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 98 of 105 QUALITY CONTROL DATA Page 99 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Client : Connecticut Yankee Atomic Power 362 Injun Hollow Rd Report Date: August 21, 2006 Page 1 of 6 East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder:
168404 NOM Rad Alpha Spec Batch 555696 QC1201153130 168340011 DUP Americium-241 Curium-242 Curium-243/244 QC1201153132 LCS Americium-24 I Curium-242 Curium-243/244 Sample Qual QC Units RPD%REC% Range Anlst Date Time U -0.000522 Uncert: +/-0.0385 TPU: +/-0.0385 U 0.00 Uncert: +/-0.0756 TPU: +/-0.0756 U -0.0177 Uncert: +/-0.0764 TPU: +/-0.0765 12.8 Uncert: TPU: Uncert: TPU: 15.5 Uncert: TPU: U 0.0578+/-0.278+/-0.279 U -0.0405+/-0.0562+/-0.0565 U -0.0517+/-0.257+/-0.257 12.8+/-1.84+/-2.70 U -0.0328+/-0.0454+/-0.0457 14.3+/-1.94+/-2.92 U 0.0471+/-0.157+/-0.157 U -0.0469+/-0.0459+/-0.0464 U -0.00385+/-0.210+/-0.210 pCi/g 204 pCi/g 200 pCi/g 98 pCi/g (0%- 100%) BXLI 08/11/06 14:34 (0%- 100%)(0%- 100%)100 (75%-125%)
QC1201153129 MB Americium-241 Curium-242 Curium-243/244 QC1201153131 168340011 MS Americium-24 l Curium-242 Curium-243/244 Uncert: TPU: Uncert: TPU: Uncert: TPU: pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 92 (75%-125%)
13.3 U -0.000522 Uncert: +/-0.0385 TPU: +/-0.0385 U 0.00 Uncert: +/-0.0756 TPU: +/-0.0756 16.1 U -0.0177 Uncert: +/-0.0764 TPU: +/-0.0765 U 12.0+/-1.38+/-2.08 0.0427+/-0.0837+/-0.0839 15.9+/-1.58+/-2.61 91 (75%-125%)
99 (75%-125%)
Batch 555697 QC1201153134 168340011 DUP Plutonium-238 U -0.0155 U 0.0237 pCi/g 956 (0%- 100%) BXLI 08/11/06 22:51 Page 100 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 2 of 6 Parmname NOM Sample Qual QC Units RPD%REC% Range Anist Date Time Rad Alpha Spec Batch 555697 Plutonium-239/240 QC1201153136 LCS Plutonium-238 Plutonium-239/240 QC1201153133 MB Plutonium-238 Uncert: +/-0.0215 TPU: +/-0.0216 U 0.0414 Uncert: +/-0.0934 TPU: +/-0.0935 Uncert: TPU: 11.8 Uncert: TPU: U+/-0.0465+/-0.0466-0.0489+/-0.124+/-0.124 pCi/g 2410 (0%- 100%)(75%-125%)
U 0.155+/-0.141+/-0.142 11.5+/-0.856+/-1.32 U 0.0552+/-0.186+/-0.186 U -0.0978+/-0.0892+/-0.0899 Plutonium-239/240 QC1201153135 168340011 MS Plutonium-238 Plutonium-239/240 Uncert: TPU: Uncert: TPU: pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 98 (75%-125%)
08/11/06 22:50 u -0.0155 Uncert: +/-0.0215 TPU: +/-0.0216 12.3 U 0.0414 Uncert: +/-0.0934 TPU: +/-0.0935 U 7.28 Uncert: +/-6.30 TPU: +/-6.35 U 0.0539+/-0.112+/-0.112 10.3+/-0.796+/-1.19 (75%-125%)
08/11/06 22:51 84 (75%-125%)
Batch 555698 QC1201153138 168340011 DUP Plutonium-241 QC1201153140 LCS Plutonium-241 QC1201153137 MB Plutonium-241 QC1201153139 168340011 MS Plutonium-241 137 Uncert: TPU: Uncert: TPU: 138 U Uncert: TPU: U 10.1+/-6.39+/-6.46 145+/-12.5+/-19.9 U 8.57+/-6.93+/-6.98 142+/-12.4+/-19.7 pCi/g 0 (0% -100%) BXL I pCi/g pCi/g pCi/g 106 (75%-125%)
08/16/06 16:41 08/16/06 17:14 08/16/06 16:25 08/16/06 16:58 7.28+/-6.30+/-6.35 103 (75%-125%)
Batch 557837 QC1201158317 168404009 DUP Americium-241 Curium-242 U -0.0851 Uncert: +/-0.136 TPU: +/-0.136 u -0.0253 U U 0.167+/-0.220+/-0.221 0.241 pCi/g 616 pCi/g 247 (0%- 100%) BXLI 08/16/06 09:49 (0% -100%)Page 101 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 3 of 6 Parmname NOM Sample Qual QC Units RPD%REC% Range Anist Date Time Rad Alpha Spec Batch 557837 Curium-243/244 QC1201158319 Americium-241 Uncert: +/-0.0495 TPU: +/-0.0496 U -0.0479 Uncert: +/-0.0542 TPU: +/-0.0545 24.5 Uncert: TPU: LCS Curium-242 Curium-243/244 QC1201158316 Americium-241 Curium-242 MB Uncert: TPU: 29.7 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU:+/-0.334+/-0.335 U 0.0761+/-0.149+/-0.149 25.4+/-2.47+/-4.16 U 0.0477+/-0.127+/-0.127 27.0+/-2.54+/-4.38 U 0.234+/-0.275+/-0.277 U 0.00+/-0.152+/-0.152 U -0.0551+/-0.0624+/-0.0628 pCi/g 879 (0% -100%)pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 91 (75%-125%)
104 (75%-125%)
Curium-243/244 QC1201158318 168404009 MS Americium-241 Curium-242 Curium-243/244 26.4 U -0.0851 Uncert: +/-0.136 TPU: +/-0.136 U -0.0253 Uncert: +/-0.0495 TPU: +/-0.0496 32.4 U -0.0479 Uncert: +/-0.0542 TPU: +/-0.0545 U 29.1+/-2.97+/-5.01 0.126+/-0.247+/-0.248 31.7+/-3.12+/-5.39 10 (75%-125%)
98 (75%-125%)
Rad Gas Flow Batch 556350 QC1201154645 168404003 DUP Strontium-90 QC1201154647 LCS Strontium-90 QC1201154644 MB Strontium-90 U -0.00343 Uncert: +/-0.0203 TPU: +/-0.0203 1.56 Uncert: TPU: U -0.00637+/-0.0152+/-0.0152 1.30+/-0.0563+/-0.0881 U 0.0176+/-0.018+/-0.018 pCi/g 0 (0% -100%) BXFI 08/14/06 08:33 pCi/g pCi/g 83 (75%-125%)
Uncert: TPU: Page 102 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 4 of 6 Parmname NOM Sample Qual QC Units RPD%REC% Range Anist Date Time Rad Gas Flow Batch 556350 QC1201154646 168404003 MS Strontium-90 Rad Liquid Scintillation Batch 554580 QC1201150562 168340012 DUP Technetium-99 QC1201150564 LCS Technetium-99 QC1201150561 MB Technetium-99 QC1201150563 168340012 MS Technetium-99 1.58 U Uncert: TPU:-0.00343+/-0.0203+/-0.0203 1.29+/-0.0535+/-0.0813 pCi/g 82 (75%-125%)
U 0.0338 Uncert: +/-0.192 TPU: +/-0.192 U 0.266+/-0.226+/-0.226 13.6+/-0.496+/-0.599 pCi/g 0 (0% -100%) EGDI 13.1 Uncert: TPU: Uncert: TPU: 13.0 U Uncert: TPU: U 0.0311+/-0.177+/-0.177 pCi/g pCi/g pCi/g 103 (75%-125%)
08/12/06 00:42 08/12/06 01:14 08/12/06 00:26 08/12/06 00:58 0.0338+/-0.192+/-0.192 12.0+/-0.523+/-0.602 92 (75%-125%)
Batch 554582 QC1201150570 168340011 DUP Tritium QC1201150572 LCS Tritium QC1201150569 MB Tritium QC1201150571 168340011 MS Tritium Uncert: TPU: U 1.77+/-8.20+/-8.20 U 1.62+/-7.47+/-7.47 pCi/g 0 (0% -100%) DFA I 68.3 Uncert: TPU: Uncert: TPU: 61.3 U Uncert: TPU: 76.2+/-14.0+/-14.1 U 0.586+/-8.01+/-8.01 pCi/g pCi/g pCi/g 11 (75%-125%)
08/09/06 15:42 08/09/06 16:14 08/09/06 15:26 08/09/06 15:58 1.77+/-8.20+/-8.20 Batch 554583 QC1201150574 168404003 DUP Carbon- 14 QC1201150576 LCS Carbon- 14 U 0.0937 Uncert: +/-0.0813 TPU: +/-0.0813 U 61.8+/-12.2+/-12.3 0.0422+/-0.075+/-0.0751 7.14+/-0.508+/-0.520 101 (75%-125%)
pCi/g 0 (0% -100%) ATH2 08/10/06 01:39 08/10/06 03:00 7.27 Uncert: TPU: pCi/g 98 (75%-125%)
QC1201150573 MB Page 103 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 5 of 6 REC% Range AnIst Date Time Parmname NOM Sample Qual OC Units RPD%Rad Liquid Scintillation Batch 554583 Carbon- 14 QCI201150575 168404003 MS Carbon-14 Uncert: TPU: U -0.0315+/-0.0776+/-0.0776 pCi/g pCi/g 15.1 U Uncert: TPU: 0.0937+/-0.0813+/-0.0813 13.8+/-1.00+/-1.03 92 (75%-125%)
08/10/06 02:43 Batch 555722 QC1201153223 168340012 DUP Iron-55 QC1201153225 LCS Iron-55 U -26.5 Uncert: +/-65.1 TPU: +/-65.1 U 5.83+/-36.9+/-36.9 pCi/g 0 (0%- 100%) vIXPI QC1201153222 MB Iron-55 QC1201153224 168340012 MS Iron-55 Batch 555723 QC1201153227 168340012 DUP Nickel-63 QC1201153229 LCS Nickel-63 QC1201153226 MB Nickel-63 QC1201153228 168340012 MS Nickel-63 641 Uncert: TPU: Uncert: TPU: 717 U Uncert: TPU: U Uncert: TPU: 512 Uncert: TPU: Uncert: TPU: 530 U Uncert: TPU: 660+/-56.2+/-67.2 U 18.2+/-39.6+/-39.6-26.5+/-65.1+/-65.1 688+/-60.2+/-71.6 pCi/g pCi/g pCi/g 103 (75%-125%)
08/12/06 20:54 08/12/06 21:27 08/12/06 20:38 08/12/06 21:11 96 (75%-125%)
3.79+/-5.39+/-5.40 U 6.68+/-7.43+/-7.43 479+/-22.4+/-27.1 U 15.7+/-9.92+/-9.93 pCi/g 0 (0% -100%) vIXPI pCi/g pCi/g pCi/g 94 (75%-125%)
08/I 1/06 11:55 08/11/06 12:27 08/11/06 11:38 08/11/06 12:11 3.79+/-5.39+/-5.40 511+/-23.5+/-28.7 96 (75%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported Result is greater than value reported Page 104 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 6 of 6 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more.** Indicates analyte is a surrogate compound.A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.Page 105 of 105 Table of Contents General Narrative
................................................................
1 Chain of Custody And Supporting Documentation
..........
5 Radiological Analysis ..........................................................
14 Sample Data Summary .....................................................
28 Quality Control Data ..........................................................
32 General Narrative 1 CASE NARRATIVE For CONNECTICUT YANKEE RE: Soil PO# 002332 Work Order: 172071 SDG: MSR #06-0688 September 27, 2006 Laboratory Identification:
General Engineering Laboratories, LLC Mailing Address: P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address: 2040 Savage Road Charleston, South Carolina 29407 Telephone Number: (843) 556-8171 Summary: Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC, (GEL)in Charleston, South Carolina on May 12, 2006. All sample containers arrived without any visible signs of tampering or breakage.
The chain of custody contained the proper documentation and signatures.
Sample 9106-0004-013F was relogged for additional analyses at the request of Dale Randall via email on September 19, 2006.The laboratory received the following sample(s):
Sample ID Client Sample ID 172071001 9106-0004-013F Items of Note: There are no items of note.I.
Case Narrative:
Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures.
Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.
Analytical Request: One soil sample was analyzed for Carbon-14, Tritium, Americium, Plutonium, Plutonium-241, Iron 55, Nickel-63, and Tc-99.Internal Chain of Custody: Custody was maintained for the sample(s).
Data Package: The enclosed data package contains the following sections:
Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.
I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.
Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.P.O. Box 30712 ° Charleston, SC 29417
- 2040 Savage Road (29407)Phone (843) 556-8171
- Fax (843) 766-1 17
- www.gel.com List of current GEL Certifications as ofZ, September 2006 State Alaska Arizona Arkansas* " CCalifornia........
..Dept. of Navy EPA Florida/NELAP
.Georgia ..Hawaii Idaho Illinois Indiana kansas Kentucky Louisiana Maryland Massachusetts Michigan Nevada New Jersey" New Mexico New York North Carolina North Carolina'Drinking W-Certifiation UST-062 AZ066&89s-0651 42D0904046 01 15,1CA GenEngLabs PH-0169 NFiSC 413 WGt-I J E87T56 E87156 (FLINELAP)
N/A N/A..... NiA.........
C-SC-OI B.-10332-90T29 03046 27/0 M-SCOt12 9903 SCI2 SCO02._. LA-E87I56.
11501 233 45709 North Dakota R-158 Oklahoma 9 90 Pennsylvania 68-00485 South Carolina 10 1200011 -585001/1b12-002 Tennessee 02934 Texas TX7l3-2006A Texas NELAP T1047fl4235-06-TX U.S. Dep. of Agriculture S-52597 -Army Corps of Engineer NIA Utah .8037697376 GEL Vermont 'V1T87156 Virginia Washington 00151-C164t1 -.4 Chain of Custody And Supporting Documentation 5
'Health. Physiý edure GPP-GGGR-R5104-003 -Attachment B-CY-00 I Major Cqnn cocul Yankee Atomic Power Company.ijun Hollow Road, East Hampton, CT 06424 860-267-2556 Name: HaddamiNeck Decommissionin2 I1 Contact Name & Phone: Jack McCarthy-'
860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road.. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones fRelbg samrple 91 06-0004-01 3F per th~e request of Dale Randall on 9/19/06. See attached email.Priority:
Z 30 D.E] 14 D. 0 7 D.Samples Shipped Via: (9 Fed Ex 0I uPs LI Hand El Other Bill of Lading #
GPP-GGGR-R5104-003-AffachmeiitB-CY-001 Major Health Physics Procedure HelhPyic rcdreGPGl 510-0-ttcmnI-C-0 ao Chain of Custody Form no. 2006-00336 Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested
..Contact Namne & Phone: -en, Jack McCarthy 860-267-2556 Ext. 3024 ...Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 ; " 843 556 8171. Attn. Cheryl Jones .V) Tr Priority:
Z 30 D.l 14 D.[] 7 D. Container Sample Size- " "- .',"-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation La, Sample ID 9106-0004-O0IF 05/3/06 09:37 SE C BP x x Transferred from COC 2006-00316 9106-0004-002F 05/3/06 09:56 SE C BP X X Transferred from COC 2006-00316 9106-0004-003F
-05/3/06 10:28 SE C BP x x Transferred from COC 2006-00316 9106-0004-004F
' 05/3/06 10:48 SE C BP X X Transferred from COC 2006-00316 J 9106-0004-004FS
-05/3/06 10:48 SE C BP X X Transferred from COC 2006-00316 9106-0004-005F 05/3/06 11:07 SE C BP X X Transferred from COC 2006-00316 9106-0004-006F 05/3/06 12:46 SE C BP x x Transferred from COC 2006-00317"'
9106-0004-007F 05/4/06 07:55 SE C BP X X Transferred from COC 2006-00320 9106-0004-017F 05/4/06 09:27 SE C BP X X Transferred from COC 2006-00320
,__ ,,__.,,,....-
NOTES: P0 #: 002332 MSR #: 06- SSWP# NA Z LTP QA[E Radwaste QA El Non QA 1) Relinquished By Date/Time
- 2) Received By *Pate/Time 1 , e," -4ý ,Q'L MW Samples Shipped Via: 21 Fed Ex MI uPs 0I Hand El Other Bill of Lading #e&n~Cna IT Vu~dSa nat 3) Relinquished By Date/Time 4) Received By r Date/Time L J ~ 1'.
Connecticut Yankee Statement of Work for Analytical Lab Services .CY-ISC-SOW-f01 Figure 1. -Sample Check-in List.Date/Time Received:
.,.. .SDG#: .-Work Order Number: G ' ." -:-, 1.Shipping Cdbtainer ID:j. --E3 *Chain of Custody# 33qO( -." .. Custody Seals o0ishipping container intact?::.
- Yes t Noje 2- Custody Seals dated and signed? Yes [ j No ( " 3. Chain-of-Custody record present? " Yes No ]* * -.4. Cooler.temperature
- 5. Verniculitelpacking materials is: Wet [WDry (j" 6": Number of samples in shipping container-.
__"" 7. Sample holding times Yes [ J No.8.. Samples have:.S -...k2tape " hazard labels" -.A2custody seals " -.appropriate sample labels 9. Samples are:-in good condition 2Cileaking
."..broken " ""- have air bubbles 10. :Were anY anomalies identified in sarnplo Yes. No[]i.: Description ofanomalies(includes O Sampe I ICustodian/Laboratory
.Telephonedo:
On o a ..--.
SAMPLE RECEIPT & REVIEW FORM PM use only Client: 4-1 nl V/6 SDG/ARCOC/Work Order: /6 z rgZ t Date Received:_ " 5-1-al (-An _ _ __ Review (esre
'tem r resolved prior to sng): Received By:_ C Ir-lexf 1i Sample Receipt Criteria V Comments/Qualifiers (Required for Non-Conforming Items)!Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) and sealed? ,,la...,p-
_Samples requiring cold Circle Coolant # ice bags blue ice dry ice (2f) other describe)2 preservation within (4 +1- 2 C)?Record preservation method. _ .C._..-__Chain of custody documents ,CO Us o-,v Z V t-included with shipment?
O Sample containers intact and irlc Appbeale:
seals brjkcn damaged container leaking container sealsed? c:,oNt vq/ c s]Samples requiring chemical Sample ID's. containers affected and observed pH: preservation at proper pH? I VOA vials free of headspace Sample IO's and containers affected: (defined as < 6mrm bubble)? I_ , Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory) 8 Samples received within holding Id's and teast affecited:
time? s Sample ID's on COC Satch ID's Sample 11's and containers affected: on bottles? _ __._ __, 1Date & time on COC match- date Sample iD's affected:& time on bottles?Number of containers received L/ Sample ID's affected: match number indicated on COC?COC form is properly signed in CbG5 0t c-'V, vLU .irVw tic d A relinquished/received sections?
__,_ , Air Bill ,Tracking
- 's, & di.& CE(\U 1 Ies-1Additional Comments Tu .U RSOnRAD Receipt #Sa o *f > x2 area background is observed on samples identified as *non-Suspected Hazard Information fZ regulatedinon-radioactive".
contact the Radiation Safety group for further 6Zi investigation.
A Radiological Classi fication..
Maximum Counts Observed*:
B PCB Regulated?
___ Comments: Shipped as DOI Hazardous C Material?
If yes, contact Waste Hazard Class Shipped: Manager or ESH Manager. I N#: PM (or PMA) review of Hazard classification:
Initials Date: .7- .c V 44j-7'tip 010A .SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM alc Y-c Rot C0G,4:r ol ontra (a 1.Q55J (0ý) I (4hi5 Ccoý):ei Yccd a __________
b Lsp c1Z 5 CL M r~046 f,/0:
0 SAMPLE RECEIPT & REVIEW FORM r PM use only Client: (7< q/4.,-K .SDG/ARCOC[Work Order: I4' ZI .....Date Received:
<V. ,,q C, PM(A) Review (ensure non-conforming items are resolved prior to signing): Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforming Items)I Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) and sealed? -I Samples requiring cold Circle Coolant # ice bags blue ice dry ice none other describe)2 preservation within (4 +/- 2 C)?Record preservation method. __._ .3 Chain of custody documents included with shipment?
Y C 4 Sample containers intact and Circle Applicable:
seals broken damaged container lq<1ther11ascribe) sealed? -.4. , 90A): ao 6001 a 1 'f-.Samples requiring chemical Sample ID's, containers affected and observed pH: preservation at proper pH? --6 !VOA vials free of headspace Sample ID's and containers affected: 6(defined as < 6mm bubble)?_.
Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory)
-8 Samples received within holding I a tssafce: time? iSample ID's on COC match ID'S Sample lbs and contains affected: on bottles? , 10 Date & time on COC match date Sample ID'3 affected:& time on bottles? -1 U Number of containers received Sample lD's affected: match number indicated on COG? 1 COC form is properly signed in relinquished/received sections?
-o ! re-/.' -14 Air Bill ,Tracking
- 's, & -61 .-,. -, -Additional Comments u " *P AD Receipt #___________
Suspected Hazard Information
- If > x2 area background is observed on samples identified as'non.Sn regulated/non-radioactive", contact the Radiation Safety group forfurther i' investigation.
A Radiologieal .Clagsification?
-Maxim .u.a ..nta Observedl*:
" B JP Regul a a tLed? x axirm < 'Shi'ppe as D5M.Hazardous c-sa, c jMaterial.? -if yes, contact Waste Hazard Clas Shipped:[Manager or .ESH Manager. N#./,.PM (or PMA) review of Hazard classification:
Initials Date: 1. o.U/A Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-o01 Figure 1. Sample Check-in List-j ,,?Datc/Timc Rcceived: L'. 0of 0(8 'SDG#: /K4c -06 1?Work Order Number: /(Z " Shipping Container ID: -'I 5 8&7Z Chain of Custody #I. Custody Seals on shipping container intact?2. Custody Seals dated and signed?3. Chain-of-Custody record present?4. Cooler temperature A//s 5. Vermiculite/packing materials is: 6. Number of samples in shipping container:.
- 7. Sample holding times exceeded?a oeo ., 1. 1. -6 0 Yes No (Yes NO Yes No [wet 9 Dry [3]Yes [] No 8. Samples have: Y, tape hazard labels_,rcustody seals appropriate sample labels 9. Samples are: in good condition
_4_,eaking broken have air bubbles 10. Were any anomalies identified in sample receipt? Yes ( No [3 11. Description of anomalies (include sample numbers): Sample Custodian/Laboratory
.Telephoned to: On-Date: , 'ý /.? "6 f 9 g'o By- __Page 45 of 56 12 One additional Sample that needs to be measured to FSSALL
Subject:
One additional Sample that needs to be measured to FSSALL From: "Dale Randall" <randall@cyapco.com>
Date: Tue, 19 Sep 2006 09:14:28 -0400 To: "Cheryl Jones" <cj@gel.com>
CC: "Clyde Newson" <Newson@CYAPCO.com>, "John McCarthy" <McCarthy@CYAPCO.com>
Cheryl: We need to add sample 9106-0004-013F to our list of samples at GEL requiring further analyses to the FSSALL protocol.
It has already been measured for FSSGAM and Sr-90. Once you have had an opportunity to verify that you have enough sample aliquot and can estimate the turn around time (TAT) please call or e-mail me at your earliest convenience.
Thank You, Dale (860) 267-3133 I oflI 13 9/25/2006 1:29 PM RADIOLOGICAL ANALYSIS 14 Radiochemistry Case Narrative Connecticut Yankee AtomiePower Co. (YANK)Work Order 172071 Method/Analysis Information Product: Aiphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 570544 Prep Batch Number: 570368 Dry Soil Prep GL-RAD-A-021 Batch Number: 570366 Sample ID Client ID 172071001 9106-0004-013F 1201187914 Method Blank (MB)1201187915 172071001 (9106-0004-013F)
Sample Duplicate (DUP)1201187916 172071001 (9106-0004-013F)
Matrix Spike (MS)1201187917 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geon-tty as the calibration standards.
15 Quality Control (OC Information:
Blank Information The blank volume is representative of the sample volumes in this batch.Designated QC The following sample was used for QC: 172071001 (9106-0004-013F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Batch was recounted due to a high Matrix Spike recovery.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual.
documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analvsis Information 16 Product: Alphaspec Pu, Solid-ALL FSS Analytical Method: DOE IEL HASL-300, Pu- 1 I-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 570545 Prep Batch Number: 570368 Dry Soil Prep GL-RAD-A-021 Batch Number: 570366 Sample ID Client ID 172071001 9106-0004-013F 1201187918 Method Blank (MB)1201187919 172071001(9106-0004-013F)
Sample Duplicate (DUP)1201187920 172071001(9106-0004-013F)
Matrix Spike (MS)1201187921 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14..Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 172071001 (9106-0004-013F).
QC Information All of the QC samples met the required acceptance limits.17 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS DOE EML HASL-300, Pu- 11-RC Modified Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 570546 570368 570366 18 Sample MI Client ID 172071001 9106-0004-013F 1201187922 Method Blank (MB)1201187923 172071001(9106-0004-013F)
Sample Duplicate (DUP)1201187924 172071001(9106-0004-01;3F)
Matrix Spike (MS)1201187925 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (OC Information:
Blank.Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 172071001 (9106-0004-013F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Tine All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this 19 SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 570909 Sample ID Client ID 172071001 9106-0004-013F 1201188720 Method Blank (MB)1201188721 172071001(9106-0004-013F)
Sample Duplicate (DUP)1201188722 172071001(9106-0004-013F)
Matrix Spike (MS)1201188723 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (0C1 Information:
Blank Information The blank volume is representative of the sample volume in this batch.20 Designated QC The following sample was used for QC: 172071001 (9106-0004-013F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for-this sample set.Qualifier information Manual qualifiers were not required.MethodlAnalysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-I, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 573887 Prep Batch Number: 570368 Dry Soil Prep GL-RAD-A-021 Batch Number: 570366 21 Sample ID Client ID 172071001 9106-0004-013F 1201195366 Method Blank (MB)1201195367 172071001(9106-0004-013F)
Sample Duplicate (DUP)1201195368 172071001(9106-0004-013F)
Matrix Spike (MS)1201195369 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 172071001 (9106-0004-013F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Sample 172071001 (9106-0004-013F) was recounted due to ihe quench number being outside the calibration range. Samples were reprepped due to low/high recovery.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from 22 referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-1, Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 570908 Prep Batch Number: 570368 Dry Soil Prep GL-RAD-A-021 Batch Number: 570366 Sample ED Client ID 172071001 9106-0004-013F 1201188716 Method Blank (MB)1201188717 172071001 (9106-0004-013F)
Sample Duplicate (DUJP)1201188718 172071001(9106-0004-013F)
Matrix Spike (MS)1201188719 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
23 Quality Control (OC') Information:-
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 172071001 (9106-0004-013F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Gualifier information Manual qualifiers were not required.Method/Analysis Information Product: LSC, Tritium Dist, Solid-HTD2,ALL FSS Analytical Method: EPA 906.0 Modified Analytical Batch Number: 570910 24 Sample ID Client ID 172071001 9106-0004-013F 1201188728 Method Blank (MB)1201188729 172071001(9106-0004-013F)
Sample Duplicate (DUP)1201188730 172071001(9106-0004-013F)
Matrix Spike (MS)1201188731 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 13.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 172071001 (9106-0004-013F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this 25 SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint C14, Solid AII,FSS Analytical Method: EPA EERF C-01 Modified Analytical Batch Number: 570914 Sample ID Client ID 172071001 9106-0004-013F 1201188734 Method Blank (MB)1201188735 172071001(9106-0004-013F)
Sample Duplicate (DUP)1201188736 172071001(9106-0004-013F)
Matrix Spike (MS)1201188737 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 172071001 (9106-0004-013F).
26 QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis.None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator.
In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.The following data validator verified the information presented in this case narrative:
ReviewerfDate:
CU-IA. k , I 10 12-10 (27 SAMPLE DATA
SUMMARY
28 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Report for YANK00 I Connecticut Yankee Atomic Power Co.Client SDG: MSR#06-0688 GEL Work Order: 172071 The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.ND The analyte concentration is not detected above the detection limit.The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures.
Please direct any questions to your Project Manager, Cheryl Jones.Reviewed by 29 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: October 2,2006 Client Sample ID: 9106-0004-013F Proiect: YANK01204 Sample ID: 172071001 Client ID: YANK001 Matrix: SE Vol. Recv.: Collect Date: 03-MAY-06 Receive Date: 12-MAY-06 Collector:
Client Moisture:
25.4%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mti Rad Alpha Spec Analysis Alphaspec Am24J, Cm, Solid ALL FSS Americium-241 U 0.0475 +/--0.105 0.064 +/-0.106 0.207 pCi/g TCI 09/30/06 0836 570544 1 Curium-242 U 0.0419 +/-0.111 0.0495 +1-0.111 0.248 pCi/g Curium-243/244 U -0.104 +/-0.106 0.127 +/-0.106 0.334 pCi/g Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.114 +/-0.111 0.0319 +1-0.112 0.132 pCi/g TCI 09/28/06 0937 570545 3 Plutonium-239/240 U 0.0883 +/-0.0997 0.0318 +/-0.100 0.132 pCilg Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U -4.69 +/-9.90 8.51 +1-9.90 17.8 pCi/g TCI 09/29/06 1603 570546 4 Rad Liquid Scintiliation Analysis LSC, Tritiumn Dist, Solid-HTD2,ALL FSS Tritium U -1.6 +1-6.64 5.69 +"-6.64 12-3 pCi/g DFAI 09/23/060750 570910 5 Liquid Scint C14, Solid All, FSS Carbon-14 0-265 +1-0.0958 0.0684 +"--.0959 0.144 pCi/g AXD2 09/23/06 1841 570914 6 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 16.4 +/-40.0 27.9 +/-40.0 58.3 pCi/g MXPI 10/02/06 1453 573887 7 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 0.712 +1-10.1 8.44 +1-10.1 17.3 pCi/g MXP1 09/26/06 1504 570908 l1 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.147 +/-0.259 0.213 +W-0.260 0.441 pCi/g KXR1 09/27/06 1734 570909 11 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 09/21/06 1329 570366 The following Analytical Methods were performed Method Description 2 3 4 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-1I1-RC Modified 30 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: October 2, 2006 Client Sample ID: Sample ID: 9106-0004-013F 172071001 Project: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mt, 5 6 7 8 9 10 II EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-I, Modified DOE RESL Fe-I, Modified DOE RESL Fe-1, Modified DOE RESL Ni-l, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FK Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%
Acceptable Limits 94 (1596-125%)
90 (15%-125%)
89 (25%-125%)
65 (159o-125%)
64 (25%-125%)
77 (15%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy-Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.31 QUALITY CONTROL DATA 32 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Client: Connecticut Yankee Atomic Power 362 Injun Hollow Rd Reuort Date: October 2, 2006 Page 1 of 5 East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder:
172071 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 570544 QC1201187915 172071001 DUP Americium-241 Curium-242 Curium-243/244 QC1201187917 LCS Americium-241 Curium-242 Curium-243/244 QC1201187914 MB Americium-241 Curium-242 Curium-243/244 QC1201187916 172071001 MS Americium-241 Curium-242 Curium-243/244 U 0.0475 U 0.0677 pCi/g Uncert: +1-0.105 +1-0.129 TPU: +/-0.106 +/-0.129 U 0.0419 U 0.0444 pCi/g Uncert: +/-0.111 W--0.118 TPU: +/-0.111 +/-0.118 U -0.104 U 0.104 pCilg Uncert: +/-0.106 +/-0.142 TPU: +1-0.106 +1-0.143 11.0 11.5 pCi/g Uncert: +/-1.13 TPU" +/-1.80 U '-0.0143 pCilg Uncert +1-0.0198 TPU: +1-0.0198 13.2 13.8 pCi/g Uncert: +/-1.24 TPU: +/-2.09 U -0.0325 pCi/g Uncert: +/-0.0788 TPU: +/-0.0789 U 0.0258 pCilg Uncert: 0.0727 TPU: +/-0.0728 U 0.0173 pCi/g Uncert: +/-0.127 TPU: +/-0127 11.0 U 0.0475 12.4 pCi/g Uncert +1-0.105 +1-1.26 TPU: +/-0.106 +1-2.02 U 0.0419 U 0.0176 pCi/g Uncert: +/-0.111 +1-0.133 TPU: +/-0.111 +"-0133 13.4 U -0.104 13.1 pCil/g Uncert: +/-0.106 +/-131 TPU: +1-0.106 W-2-13 35 (0% -100%) TCI 09/30/06 08:36 6 (0% -100%)0 (0%-100%)105 (75%-125%)
105 (75%-125%)
113 (75%-125%)
98 (75%-125%)
Batch 570545 QC1201187919 172071001 DUP Plutonium-238 U 0.114 U 0.0215 pCi/g 137 (0% -100%) TCI 09128/06 09:37 33 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Chareston SC 29407- (843) 556-8171 -www.gel.com QC Summary Workorder:
172071 Page 2 of 5 Parnname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Alpha Spec Batch 570545 e Plutonium-239/240 QC1201187921 LCS Plutoriium-238 Plutonium-239/240 QC12011 87918 MB Plutonium-238 Plutonium-239/240 QC1201187920 172071001 MS Plutonhim-238 Plutonium-2391240 Uncert: +/-0.111 TPU: +/-0.112 u 0.0883 Uncert: +1-0.0997 TPU: +/-0.100 Uncert: TPU: 10.1 Uncert: TPU: Uncert TPU: Uncert: TPU: u 0.114 Uncert: +/-0.111 TPU: +/-0.112 10.! U 0.0883 Uncert: +/-0.0997 TPU: +1-0.100 U -4.69 Uncu-t +/-9.90 TPU: +/-9.90+/-0.0796+/-0.0796 U 0.0278+/-0.0783+/-0.0784 U 0.0774+1-0.0812+/40817 9.41+1-0.863+1-1-36 U -0.0052+1-0.0436+/-0.0437 U 0.0338+1/0.0776+/-0.0777 pCi/g 104 (0%-100%)pCi/g (750/o-125%)
09/28/06 09:37 PCi/g PCi/g 93 (75%-125%)
09/28/06 09:37 U 0.0355+/-0.0666+1-0.0667 10.8+4.981+I-1.58 PCi/g PCi/g (75%-125%)
09/28/06 09:37 107 (75%-125%)
Batch 570546 QC1201187923 172071001 DUP Plutonium-241 U QC 1201187925 Plutonium-241 LCS-0.734+/-9.49+1-9.49 119+/-16.4+1-21.0 pCi/g 0 (0% -100%) TCI 09/29/06 16:35 QC1201187922 MB Plutonium-241 QC1201187924 172071001 MS Plutonium-241 Rad Liquid Scintillation Batch 570908 QC1201188717 172071001 DUP Nickel-63 134 Uncert: TPU: Uncert: TPU: U -136+/-8.76+1-&76 p(7i/g pCi/g pCi/g 89 (75%-125%)
09/29/06 17:07 09/29/06 16:19 09/29/06 16:51 136 U Uncert TPU:-4.69+1-9.90+/-9.90 121 W-16.3+1-21.2-3.16+"-835+14-35 89 (75%-125%)
U 0.712+/-10.1 U pCi/g 0(0% -100%) VXPI 09/26/06 16:08 Uncert: 34 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Workorder:
172071 Parmname Rad Liquid Scintillation Batch 570908 QC1201188719 LCS Nickel-63 QC1201188716 MB Nickel-63 QC1201188718 172071001 MS Nickel-63 Batch 570909 QC1201188721 172071001 DUP Technetium-99 QC1201188723 LCS Technetium-99 QC1201188720 MB Technetium-99 QC1201188722 172071001 MS Technetium-99 Batch 570910 QC1201188729 172071001 DUP Tritium QC1201188731 LCS Tritium QC1201188728 MB Tritium QC1201188730 172071001 MS Tritium Batch 570914 QC1201188735 172071001 DUP NOM TPU: 530 Uncert: TPU: Uncert: TPU: 572 U Uncert: TPU: U Uncert: TPU: 13.1 Uncert: TPU: Uncert TPU: 13.1 U Uncert: TPU: U Uncert: TPU: 51.0 Uncert: TPU: Uncert: TPU: 52.1 U Uncert: TPU: QC Summary Sample Qual 4-/-10.1 Page 3 of 5 Units RPD% REC% Ranve Artist Thte Time 0.712+/-10.1+/-10.1 0.147+/-0.259+1-0.260 0.147+1-0.259+/-0.260-1.6+/-6.64+/-6.64-1.6 W-6.64+/-6.64 487+/-17.1+1-233 U -4.05+/-9.33+/-9.33 526+/-18.1+/-25.4 U 0.117+"-0.269+/-0.269 13.4+1-0.550+/-0.629 U 0.163+/-0.244+/-0.244 13.5+/-0.606+1/0.680 U 2.28+/-6.40+1-6.40 42.0+1-8.08+1-8.11 U 0.215 W-5.20+1-520 48.1+1-8.61+t-8.65 pCilg pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g.pCi/g pCi/g pcr/g 92 (75%-125%)
92 (75%-125%)
0 (0% -100%) KXRI 103 (75%-125%)
103 (75%-125%)
0 (0%- 100%) DFAI 82 (75%-125%)
92 (75%-125%)
09/26/06 17:11 09/26/06 15:36 09/26106 16:39 09/27/06 18:06 09/27/06 18:38 09/27106 17:50 09/27/06 18:22 09/23106 08:22 09/23106 08:55 09/23106 08:06 09/23106 08:39 35 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407- (843) 556-8171 -www.gel.com QC Summary Workorder:
172071 Page 4 of 5 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Liquid Scintillation Batch 570914 Carbon-14 QC1201188737 LCS Carbon-14 QC1201188734 MB Carbon- 14 0.265 Uncert: +/-0.0958 TPU: +1-0.0959 0.260+/-0.0933+1-0.0933 6.46-W-0.443+1-0.454 pCi/g 2 (0% -100%) kXD2 09/23/06 20:16 6.77 Uncert: TPU: Uncert: TPU: 7.13 Uncert: TPU: QC1201188736 Carbon-14 172071001 MS 0.265+/-0.0958+/-0.0959 Batch 573887 QC1201195367 172071001 DUP Iron-55 QC1201195369 LCS Iron-55 QC1201195366 MB Iron-55 QC1201195368 172071001 MS Iron-55 16.4 Uncert: +1-40.0 TPU: +1-40.0 637 Uncert: TPU: Uncert: TPU: U -0.0248+/-0U0842+/R0.0842 6.69+1-0.466+/-0A78 U 11.8+/-41.4+/-41.4 601+/-52.5+/-66.2 U -19.2+/-32.4+/-32.4 769 W/-64.2+1-83.8 pCi/8 pCilg pCi,/g 90 (75%-125%)
95 (75%-125%)
09/23/06 21:21 09/23/06 19:28 09/23/06 21:03 pCi/g 0 (0% -100%) MXPI 10/02/06 09:34 pCi/g pCi/g pCi/g 94 (75%-125%)
10/02/06 10:07 10/02/06 09:17 10/02/06 09:50 734 Uncert: TPU: 16.4+/-40.0+/-40.0 105 (75%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more 36 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
172071 Page 5 of 5 Parmname NOM Sample Qua] QC Units RPD% REC% Range Arist Date Time N/A R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +I-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike cone. by a factor of 4 or more.** Indicates analyte is a surrogate compound.A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.37 DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Attachment 2b Split Sample Assessment Forms (2 Pages)
Connecticut Yankee Decommissioning Project Health Physics Procedure 24265-000-GPR-GGGR-R5124-000 Attachment A Split Sample Assessment Form Survey Area Survey 0004 Survey Discharge Canal 90 Unit #: Unit Name: Sample Plan or WPIR#: 2006-021 SML #: 9106-0004-004FS Sample
Description:
Comparison of split samples collected from sample measurement location #04 and analyzed using gamma spectroscopy by an off-site vendor laboratory.
The standard sample was 9106-0004-004F the comparison sample was 9106-0004-004FS.
STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable (Y/N)Value Error Range Value Error Ratio Cs-137 1.59E-01 1.53E-02 10 0.6 1.66 2.16E-01 2.10E-02 1.36 Y Co-60 2.63E-01 2.OOE-02 13 0.6 1.66 3.OOE-01 2.50E-02 1.14 Y Sr-90 -7.59E-03 8.65E-03 -1 NONE 3.86E-03 8.15E-03 -0.51 N/A Uomments/Corrective Actions: in consideration ot Sr-vu results, guidance for agreement ranges, obtained from USNRC Inspection Procedure 84750, does not address resolution ratios less than 4, therefore, a determination of acceptability for such rations cannot be made. Since other radionuclides of concern were found to be present at an acceptable level of agreement, therefore, no further action is warranted.
I ale is proviaedi to snow acceptance criteria used to assess split samples.Resolution Agreement Range 4 7 0.50 2.00 8 15 0.60 1.66 16 50 0.75 1.33 51 200 0.80 1.25> 200 0.85 1.18 Performed By: (ýýa Reviewed By: Date: WPIR -Work Plan and Inspection Record SML -Sample Measurement Location designation Page l of I Connecticut Yankee Decommissioning Project Health Physics Procedure 24265-000-GPR-GGGR-R5124-000 Attachment A Split Sample Assessment Form Survey 9106 Survey 0004 Survey Unit Discharge Canal Area#: I Unit #: Name: Sample Plan or WPIR#: 2006-0021 SML #: 9106-0004-OIOFS Sample
Description:
Comparison of split samples collected from sample measurement location #10 and analyzec using gamma spectroscopy by an off-site vendor laboratory.
The standard sample was 9106-0003-010F, the comparison sample was 9106-0003-01 OFS.STANDARD COMPARI SON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable (Y/N)Value Error Range Value Error Ratio Cs-137 2.46E-03 1.18E-02 0 NONE 3.26E-02 1.59E-02 13.25 N/A Co-60 7.39E-03 1.20E-02 1 NONE 2.54E-02 1.48E-02 3.44 N/A Sr-90 -1.75E-03 8.05E-03 0 NONE -9.25E-03 8.95E-03 5.29 N/A K-40 1.20E+01 4.24E-01 28 0.75 1.33 1.32E+01 5.10E-01 1.10 Y Comments/Corrective Actions: In consideration of Cs- 13 7, Co-60 & Sr-90 results, guidance for agreement ranges, obtained from USNRC Inspection Procedure 84750, does not address resolution ratios less than 4, therefore, a determination of acceptability for such rations cannot be made. Since none of the radionuclides of concern were in a comparable range, K-40 was used to make the comparison and was found to be present at an acceptable level of agreement, therefore, no further action is warranted.
Table is provided to show acceptance criteria used to assess split samples.Resolution Agreement Range 4 8 16 51 7 15 50 200> 200 0.50 0.60 0.75 0.80 0.85 2.00 1.66 1.33 1.25 1.18 Performed By:&1! xlord WPIR -Work Plan and Inspection Record SML -Sample Measurement Location designation 6ý'Page I of I DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Attachment 2c Preliminary Data Forms (1 Page)
Health Physics Procedure GPP-GGGR-R5]2 1 -001 Attachment B, Rev. CY-00 I MAJOR Health Physics Procedure GPP-GGGR-R5121-001 Attachment B, Rev. CY-0O1 MAJOR Preliminary Data Review Form -Samples for the Sign Test Survey Unit: 9106- 0004 Survey Unit Name: Discharge Canal Classification:
Survey Media: Type of Survey: Type of Measurement:
Number of Measurements:
Operational DCGL: 2 Sediment Final Status Survey Radionuclide Specific 15 1 BASIC STATISTICAL QUANTITIES Cs-137 Co-60 Sr-90 Minimum Value: -7.91E-03 0.OOE+00 -7.59E-03 Maximum Value: 5.49E-01 1.8 1E+00 2.62E-02 Mean: 2.07E-01 5.08E-01 5.3 1E-03 Median: 1.59E-01 2.56E-01 3.01 E-03 Standard Deviation:
1.79E-01 6.07E-01 9.82E-03 RADIONUCLIDE CONCENTRATION (pCi/g)NUMBER 9106-0004-OO1F 9106-0004-002F 9106-0004-003F 9106-0004-004F 9106-0004-005F 9106-0004-006F 9106-0004-007F 9106-0004-008F 9106-0004-009F 9106-0004-01 OF 9106-0004-01 IF 9106-0004-012F 9106-0004-013F 9106-0004-014F 9106-0004-015F Cs-137 4.51E-01 1.71E-01 3.55E-01 1.59E-01 3.99E-01 1.12E-01-5.61 E-03 1.55E-01 2.09E-02 2.46E-03 2.12E-01 1.59E-01 5.49E-01-7.91 E-03 3.77E-01 Co-60 9.53E-01 1.41E-01 9.45E-01 2.63E-01 1.74E+00 2.23E-01 1.16E-03 2.56E-01 0.OOE+00 7.39E-03 3.66E-01 1.37E-01 1.81E+00 2.85E-02 7.44E-01 Sr-90 6.33E-03-9.37E-05 1.62E-02-7.59E-03 5.86E-03 1.01E-02-6.09E-03 2.62E-02 2.16E-02-1.75E-03 9.13E-04-1.72E-03 3.01 E-03 8.27E-03-1.53E-03 Y Y Y Y Y Y N Y N N Y Y Y N Y Identified?
Y Y Y Y Y Y N Y N N Y Y Y N Y N N N N N N N Y Y N N N N N N Performed By: ( 7C Independent Review: e 4 Date: Date:
DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Attachment 2d Graphical Representation of Data (6 Pages)
Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Quantile Plot For Cesium -137 Survey Unit: 9106-0004 Survey Unit Name: Discharge Canal Mean: 2.07E-01 pCi/g Cs-1 37 Rank Percentage
-7.91 E-03 1 3 %-5.61E-03 2 10 %2.46E-03 3 17 %2.09E-02 4 23 %1.12E-01 5 30 %1.55E-01 6 37 %1.59E-01 7 43 %1.59E-01 8 50 %1.71E-01 9 57 %2.12E-01 10 63 %3.55E-01 11 70 %3.77E-01 12 77 %3.99E-01 13 83 %4.51 E-01 14 90 %5.49E-01 15 97 %Prepared By: X",/ýReviewed By: Date: lo -2 S -OZ Date: -
Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Quantile Plot For Cobalt -60 Survey Unit: 9106-0004 Survey Unit Name: Discharge Canal Mean: 5.08E-01 pCi/g 2.00E+00 1.80E+00 ---- -1.60E+00 CL. 1.40E+00 r 1.20E+00 0 1.OOE+O0 , 8.00E-01 u 6.OOE-01 o0 4.00E-01 -2.00E-01 --*O.OOE+O0 ..-0 20 40 60 80 100 Percentage Co-60 Rank Percentage 0.OOE+00 1 3 %1.16E-03 2 10 %7.39E-03 3 17 %2.85E-02 4 23 %1.37E-01 5 30 %1.41E-01 6 37%2.23E-01 7 43 %2.56E-01 8 50 %2.63E-01 9 57 %3.66E-01 10 63 %7.44E-01 11 70 %9.45E-01 12 77 %9.53E-01 13 83 %1.74E+00 14 90 %1.81E+00 15 97 %Prepared By: -.14L2 Reviewed By: .V Date: / 2 ,-Date: Xerr--!5ý eh-Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Health Physics Procedure GGGR-R5123-Rev.CY-OO1 Attachment C Quantile Plot For Strontium-90 Survey Unit: 9106-0004 Survey Unit Name: Discharge Canal Mean: 5.31E-03 pCi/g C, 0.0 0 3.OOE-02 2.50E-02 2.OOE-02 1.50E-02 1.OOE-02 5.OOE-03 O.OOE+00-5.OOE-03-1.OOE-02 Percentage 0 Rank Percentage
-7.59E-03 1 3 %-6.09E-03 2 10 %-1.75E-03 3 17 %-1.72E-03 4 23 %-1.53E-03 5 30 %-9.37E-05 6 37 %9.13E-04 7 43 %3.01E-03 8 50 %5.86E-03 9 57 %6.33E-03 10 63 %8.27E-03 11 70 %1.01E-02 12 77 %1.62E-02 13 83 %2.16E-02 14 90 %2.62E-02 15 97 %Prepared By: Reviewed By: Date: /o- Date:
Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Frequency Plot For Cesium -137 Survey Unit: 9106-0004 Survey Unit Name: Discharge Canal Mean: 0.207 pCi/g 6 C)U-5 4-3-2-1-0-11 i==-F-I IF-K i i 0.1 0.2 0.3 0.4 0.5 0.6 0.8 1 Upper End Value (pCilg)Upper End Observation Observation Value Frequency Frequency 0.1 4 27%0.2 5 33%0.3 1 7%0.4 3 20%0.5 1 7%0.6 1 7%0.8 0 0%1 0 0%Total 15 100%Prepared By: Reviewed By: Date: /a-2.9-Q1 Date: 2SK/
Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Frequency Plot For Cobalt -60 Survey Unit: 9106-0004 Survey Unit Name: Mean: 0.508 pCi/g 1., LL 6 5 4 3 2 1 0 0.1 0.3 0.5 0.7 0.9 1.1 1.3 1.5 1.7 1.9 Upper End Value (pCi/g)Upper End Observation Observation Value Frequency Frequency 0.1 0.3 0.5 0.7 0.9 1.1 1.3 1.5 1.7 1.9 Total 4 5 1 0 1 2 0 0 0 2 15 27%33%7%0%7%13%0%0%0%13%100%Prepared By: Date: /0 -2 Date: " Reviewed By: I./
Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Frequency Plot For Strontium
-90 Survey Unit: 9106-0004 Survey Unit Name: Discharge Canal Mean: 0.207 pCi/g Observatio Observatio Upper End n n Value Frequency Frequency 0 0.005 0.01 0.015 0.02 0.025 0.3 Total 6 2 3 1 1 1 1 15 40%13%20%7%7%7%7%100%Prepared By: 65le6 A, "",/, /,001, Date: 6-Date: 1/ 5 Reviewed By: Reviewed By: 6 ~
DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Attachment 2e Sign Test Calculation (1 Page)
Health Physics Procedure GPP-GGGR-R512 1 -000 Attachment A, Rev. CY-00 I MAJOR Health Physics Procedure GPP-GGGR-R5121-000 Attachment A, Rev. CY-001 MAJOR Sign Test Calculation Sheet For Multiple Radionuclisdes Survey Unit Number: 0004 Survey Unit Name: Discharge Canal WP&IR#: 2006-021ýYPE I (ca error):0.01 TYPE I (P3 error):0.05 I Classification
- 2 Radionuclides:
Survey Design DCGL (pCi/g): Cs-137 Co-60 Sr-90 1.05 5.38 2.59 Results Cs-137 4.5 1E-01 1.71E-01 3.55E-01 1.59E-01 3.99E-0 1 1.12E-01-5.61E-03 1.55E-01 2.09E-02 2.46E-03 2.12E-01 1.59E-01 5.49E-0 1-7.91 E-03 3.77E-01 Results Co-60 9.53E-01 1.41E-01 9.45E-01-2.63E-01 1.74E+00 2.23E-01 1.16E-03 2.56E-0 I 0.OOE+00 7.39E-03 3.66E-01 1.37E-01 1.81E+00 2.85E-02 7.44E-0 1 Results Sr-90 6.33E-03-9.37E-05 1.62E-02-7.59E-03 5.86E-03 1.0 1E-02-6.09E-03 2.62E-02 2.16E-02-1.75E-03 9.13E-04-1.72E-03 3.01 E-03 8.27E-03-1.53E-03 Weighted Sum (W,)(includes C-14 component) 5.27E-01 1.47E-01 5.07E-0 I 1.85E-01 8.42E-01 1.77E-01 5.45E-02 2.14E-01 8.54E-02 6.25E-02 2.42E-0 I 1.42E-01 8.73E-01 5.22E-02 3.96E-01 DCGL-Result 4.73E-01 8.53E-01 4.93E-01 8.15E-01 1.58E-01 8.23E-01 9.45E-01 7.86E-0 I 9.15E-01 9.37E-01 7.58E-01 8.58E-01 1.27E-01 9.48E-01 6.04E-01 Sign Number of Positive Differences (S+): 15 Critical Value: 11 Survey Unit: Meets Acceptance Criterion Performed By: 4:2 Independent Date: /0 S -0/Date: I .,,
DISCHARGE CANAL SURVEY UNIT 9106-0004 RELEASE RECORD Attachment 2f COMPASS DQA Surface Soil Report with Retrospective Power Curve (4 Pages)
DQA Surface Soil Report Assessment Summary Site: Planner(s):
Survey Unit Name: Report Number: Survey Unit Samples: Reference Area Samples: Test Performed:
Judgmental Samples: Assessment
==
Conclusion:==
9106-0004 w/C-14 Dale Randall 9106-0004 2 15 0 Sign Test Result: Not Performed 0 EMC Result: Not Performed Reject Null Hypothesis (Survey Unit PASSES)Retrospective Power Curve U;=L.C, A-[-1 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 ZZZD_, __ _ __ m'I- I_ _ *I _ _li- , -i__ --,* _ _ " __"- -i--0.0 0.2 0.4 0.6 0.8 1.0 Unity Rule Sum-of-Ratios, including background
--Prospective Power U i-beta ....Actual Power-LBGR --Estimated Power DCGL ---- Retrospective Power 1.2 COMPASS vl.0.0 10/2512006 Page1I