ML063400438
| ML063400438 | |
| Person / Time | |
|---|---|
| Site: | Haddam Neck File:Connecticut Yankee Atomic Power Co icon.png |
| Issue date: | 11/13/2006 |
| From: | Newson C Connecticut Yankee Atomic Power Co |
| To: | NRC/FSME |
| References | |
| 9106-0005 | |
| Download: ML063400438 (299) | |
Text
Final Status Survey Final Report Phase IV Appendix A5 Survey Unit Release Record 9106-0005, Discharge Canal November 2006 CYAPCO FINAL STATUS SURVEY RELEASE RECORD DISCHARGE CANAL SURVEY UNIT 9106-0005 Prepared By: Reviewed By: FSS Engineer Date: #( -/Q -Oa Date: ' /Date: _///_:/O FSS eiineer Approved By:________________
Technical Support Manager Revision 0 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD TABLE OF CONTENTS 1. SURVEY UNIT DESCRIPTION
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3 2. CLASSIFICATION BASIS ........................................................................
3 3. DATA QUALITY OBJECTIVES (DQO) ....................................................
5 4. SURVEY DESIG N .....................................................................................
8 5. SURVEY IMPLEMENTATION
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11 6. SURVEY RESULTS ...............................................................................
12 7. QUALITY CONTROL .............................................................................
14 8. INVESTIGATIONS AND RESULTS ......................................................
14 9. REMEDIATION AND RESULTS .............................................................
15 10. CHANGES FROM THE FINAL STATUS SURVEY PLAN .....................
15 11. DATA QUALITY ASSESSMENT (DQA) .................................................
15 12. A NO M A LIES ...........................................................................................
16 13. CO NCLUSIO N .......................................................................................
16 14. ATTACHM ENTS ..........................................................................
...........
17 14.1 Attachment 1 -Figures (10 pages including cover)14.2 Attachment 2 -Sample and Statistical Data (271 pages including covers)Revision 0 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD SURVEY UNIT DESCRIPTION Survey Unit 9106-0005 (Discharge Canal) is designated as Final Status Survey (FSS) Class 2 and consists of approximately 9,632 m2 (2.38 acres) of water covered sediment in an area located approximately 0.55 miles from the reference coordinate system benchmark used at the Haddam Neck Plant (HNP)(see Attachment 1, Figure 1). The Discharge Canal is a man-made mile long waterway that runs parallel to, and ultimately communicates with the Connecticut River. The Discharge Canal is subdivided into fifteen (15) survey units including two (2) permanent wetland areas for FSS purposes.
The survey unit is bounded as follows: Discharge Canal Survey Unit 9106-0004 is to the north (called north as orientated with the north to south flow of the Connecticut River), Survey Area 9528 is to the east, Discharge Canal Survey Unit 9106-0006 is to the south and Survey Area 9530 is to the west. The survey unit comprises the canal sediments to the depth of three (3) feet from the top of the sediment layer or the original construction depth and it extends up the canal banks to the mean high water level.This survey unit is bounded by reference coordinates EO 17 through E023 and by S100 through S115 (refer to License Termination Plan Section 5.4.4). The reference coordinates provide the maximum dimensions of a rectangle containing this survey unit. Some areas contained in this rectangle may not be part of this survey unit. The boundary of the survey unit was defined using a Global Positioning System (GPS) based on the Connecticut State Plane System North American Datum (NAD) 1927.2. CLASSIFICATION BASIS The survey unit was classified in accordance with Procedure RPM 5.1-10,"Survey Unit Classification. " The historical information, scoping analyses and characterization results provided sufficient data to designate Survey Unit 9106-0005 as Class 2 in May 2006.The "Classification Basis Summary" conducted for this survey unit consisted of: a) A review of the 1OCFR50.75 (g) (1) database, b) A review of the "Initial Characterization Report" and the "Historic Site Assessment (HSA) Supplement, " c) Historic and current survey records review, d) Visual inspections and a "walkdown." e) Formal or informal interviews with cognizant personnel.
A review of the 1OCFR50.75(g)(1) database report identified a number of events that may have impacted this survey unit. Several events indicated the potential for plant related contamination in the survey unit. These included a number of primary side system to secondary side system leakage events, Revision 0 3 Revision 0 3 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD contamination found to be present in secondary side systems and components, and unmonitored spills that drained to the discharge canal. In 1986, samples were taken from the legacy dredge spoils removed in 1979 dredged spoils area and from recently dredged canal sediment.
The sample analyses indicated that the concentrations of Cs-137, Co-60 and other radionuclides were a small fraction of the DCGLs for those nuclides that could be identified by gamma spectroscopy. (refer to NE-86-RA-1142 dated 11-13-86).
None the available historical information reviewed would support a conclusion that any residual activity in this survey unit is likely to be present at concentrations greater than the respective DCGLs.Additional information was provided by several historical documents, including the "Results of Scoping Survey", (completed 9/1/98), the "Historical Site Assessment", and the HSA Supplement (dated 6-30-00).
These documents presented the results of several sediment samples taken in 1997. These sample results indicated concentrations of 0.5 pCi/g for Co-60, 0.024 pCi/g for Cs-134 and 0.722 pCi/g for Cs-137.An initial characterization survey of the Discharge Canal was performed during April and May of 2004. However, none of these samples were taken from within the footprint of survey Unit 9106-0005.
A final characterization was performed by Site Closure personnel in April of 2006 to obtain the necessary data of sufficient data quality for Final Status Survey (FSS) planning purposes.
Six (6) 3-foot core sediment samples were taken from six (6) locations.
All of the samples were analyzed by gamma spectroscopy.
Since Hard-to-Detect (HTD) analyses were not performed and since Sr-90 was found to be a nuclide of concern in an adjacent discharge canal Survey Unit (SU 9106-0006), for conservatism it was included as a nuclide of concern in Survey Unit 9106-0005.
The Sr-90 concentration statistics were also.included in the variance calculations to determine the size of the sample population for FSS. Although no additional HTD testing was performed for characterization; four (4) of the fifteen (15) samples taken to demonstrate compliance with the release criteria during FSS were tested for the full suite of HTD nuclides to provide additional assurance that all of the radionuclides of concern were appropriately addressed.
As a result of characterization, the radionuclides of concern identified for FSS planning purposes were Cs-137, Co-60 and Sr-90 (refer to Table 1).Revision 0 4 Revision 0 4 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Minimum Value: 6.64E-02 1.16E-01 1. 14E-OY Maximum Value: 2.79E-01 5.59E-01 7.16E-02 Mean: 1.73E-01 3.08E-01 4.17E-02 Median: 1.63E-01 2.64E-0I 3.94E-02 Standard Deviation:
8.09E-02 1.52E-01 2.50E-02 NOTE: The Operational DCGLs are 6.01 pCi/g for Cs-137, 2.90 pCi/g for Co-60 and 1.18 pCi/ g for Sr-90; these are used in conjunction with the unity rule to achieve nineteen (19) mremn/yr TEDE The FSS Engineer performed a visual inspection and walkdown during May 2006 to assess the physical condition of the survey unit, evaluate access points and travel paths and identify potentially hazardous conditions.
Based upon the historical information and the results of radiological surveys performed during characterization, it was concluded that there was a low probability for residual radioactivity to be present in this survey unit in concentrations greater than the Operational DCGLs justifying a final survey unit classification of Class 2 (refer to Section 3).3. DATA QUALITY OBJECTIVES (DQO)FSS design and planning is based on the Data Quality Objective (DQO) process as described by the LTP, Procedure RPM 5.1-11, "Preparation of Final Status Survey Plan, " and the "Multi-Agency Radiation Survey and Site Investigation Manual" (MARSSIM).
A summary of the main features of the DQO process are provided herein.The DQO process incorporates hypothesis testing and probabilistic sampling distributions to control decision errors during data analysis.
Hypothesis testing is a process based on the scientific method that compares a baseline condition to an alternate condition.
The baseline condition is technically known as the null hypothesis.
Hypothesis testing rests on the premise that the null hypothesis is true and that sufficient evidence must be provided for rejection.
In designing the survey plan, the underlying assumption, or null hypothesis was that residual activity in the survey unit exceeded the release criteria.
Rejection of the null hypothesis would satisfy the release criteria objective of the FSS.The primary objective of the Final Status Survey Plan (FSSP) was to demonstrate that the level of residual radioactivity in Survey Unit 9106-0005 did not exceed the release criteria specified in the LTP and that the potential dose from residual radioactivity is As Low As Reasonably Achievable (ALARA).Revision 0 5 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD A fundamental precursor to survey design is to establish a relationship between the release criteria and some measurable quantity.
This is done through the development of Derived Concentration Guideline Levels (DCGLs). The DCGLs represent the concentration of radioactivity above background, equivalent to a dose-based release criterion and is presented in terms of surface or mass activity concentrations.
Chapter 6 of the LTP describes in detail the modeling used to develop the DCGLs for soil (called Base Case Soil DCGL), for existing groundwater radioactivity and for future groundwater radioactivity that will be contributed by building foundations and footings.As described in detail in the LTP, the dose model applied to the discharge canal presumes that the canal sediments are dredged to a depth of three (3) feet below the top of the sediment layer and spread for the planting of crops per the Resident Farmer Scenario.
Consequently, the soil DCGLs are directly applied to the canal sediment media.The DCGLs presented in Chapter 6 of the LTP were developed for exposures from three (3) components, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity.
Equation I shows the mathematical relationship between the three (3) components and the total dose.Equation I.HTotal=Hsoil (sediment)
+ HExisting GW +/- HFuture GW The total dose under the LTP criteria is twenty-five (25) mrem/yr TEDE from all three (3) components.
The allowable total dose under the Connecticut Department of Environmental Protection (CTDEP) radiological remediation standard for Connecticut Yankee (CY) is nineteen (19) mrem/yr TEDE. To satisfy both the LTP and CY CTDEP criteria, the dose from -soil must be reduced when using the groundwater dose values discussed above.This survey unit is not affected by existing groundwater or by future groundwater (reference CY memo ISC 06-024). Therefore, dose contribution from existing and future groundwater is zero (0) mrem/yr TEDE, based on field data.Equation 2: 19 mrem/yrTotaI=
19 mrem/yrsoi 0+0 mrem/yrExisting GW+0 mrem/yrFuture GW The allowable dose for soil in this survey unit is nineteen (19) mrem/yr TEDE as shown by Equation 2 above. The concentration of residual radioactivity resulting in nineteen (19) mrem/yr TEDE is designated as the Operational Revision 0 6 Revision 0 6 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD DCGL, and has been established for the radionuclides of concern as provided in Table 2.Note: The survey design used a much smaller value for investigation than the Operational DCGL provided by Table 2 to conservatively account for the contribution to the total dose from existing and future groundwater which had not been established at the time of planning the FSS.C-14 5.66E+00 4.30E+00 2.26E-01 Mn-54 1.74E+01 1.32E+O1 6.96E-0 I Fe-55 2.74E+04 2.08E+04 1.1OE+03 Co-60 3.81E+00 2.90E+00 1.52E-01 Ni-63 7.23E+02 5.49E+02 2.89E+0 I Sr-90 1.55E+00 1.18E+00 6.20E-02 Nb-94 7.12E+00 5.41 E+00 2.85E-01 Tc-99 1.26E+01 9.58E+00 5.04E-01 Ag- 108m 7.14E+00 5.43E+00 2.86E-01 Cs-134 4.67E+00 3.55E+00 1.87E-01 Cs-137 7.91 E+00 6.01E+00 3.16E-01 Eu-152 1.01E+01 7.68E+00 4.04E-01 Eu-154 9.29E+00 7.06E+00 3.72E-01 Eu-155 3.92E+02 2.98E+02 1.57E+01 Pu-238 2.96E+O1 2.25E+01 1.18E+00 Pu-239/240 2.67E+O 1 2.03E+01 1.07E+00 Pu-241 8.70E+02 6.61E+02 3.48E+01 Am-241 (5) 2.58E+01 1.96E+O1 1.03E+00 Cm-243/244 2.90E+0 I 2.20E+O 1 1.1 6E+00 (1) Bold indicates those radionuclides that are considered to be Hard to Detect (HTD)(2) The Base Case Soil DCGLs for soil are specified by the LTP in Chapter 6 and are equivalent to twenty-five (25) mrem/yr TEDE (3) The Operational DCGL is equivalent to nineteen (19) mrem/yr TEDE (4) The required MDC is equivalent to one (1) mrem/yr TEDE (5) Americium-241 can be analyzed by gamma and alpha spectroscopy and is considered to be Easy to Detect (ETD). The preferred result is the alpha spectroscopy's when both analyses are performed.
Revision 0 7 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Another important facet of the DQO process is to identify the radionuclides of concern and determine the concentration variability.
The radiological data that was used to support the DQO process, was provided by the characterization surveys performed in 2004 and 2006, as discussed in Section 2. Cs-137, Co-60 and Sr-90 were found to be the predominate radionuclides of concern., The basic statistical quantities (i.e., mean, standard deviation, median) for Cs-137, Co-60 and Sr-90 are provided in Table 1.As part of the DQOs applied to laboratory processes, analysis results were reported as actual calculated results. Results reported as less than Minimum Detectable Concentration
(<MDC) were not accepted for FSS. Sample report summaries included unique sample identification, analytical method, radionuclide, result, and uncertainty to two (2) standard deviations, laboratory data qualifiers, units, and the required and observed MDC.4. SURVEY DESIGN The level of effort associated with planning a survey is based on the complexity of the survey and nature of the hazards. Guidance for preparing FSS plans is provided in Procedure RPM 5.1-11, "Preparation of Final Status Survey Plans ".This survey was initially designed to ten (10) mrem/yr TEDE. At the time when the survey was designed, the dose contribution for existing and future groundwater had not yet been determined.
Consequently, a conservative value was chosen for the Operational DCGL. This approach is no longer required as the total dose from existing and future groundwater has been established.
The dose for soil used for this survey unit to demonstrate compliance with the LTP criteria is nineteen (19) mrem/yr TEDE, as discussed in Section 2 of this Release Record.The DQO process determined that Cs-137, Co-60 and Sr-90 were the radionuclides of concern (refer to Section 3). The sum of fractions or unity rule was used with the individual Operational DCGLs because multiple radionuclides (Cs-137, Co-60 and Sr-90) were considered in the survey design.Surrogate DCGLs were not required for this survey unit based on process knowledge from FSS of nearby adjacent areas and via screening process described in LTP Section 5.4.7.3, "Gross Activity DCGLs". Sr-90 concentrations in sediment and soil were ascertained by direct analysis.Radionuclide screening or de-selection is a process, described in LTP Section 5.4.7.2, where an individual radionuclide or aggregate may be considered insignificant and eliminated from the FSS. The criteria for de-selection are concentrations less than 5% for individual radionuclides and less than 10% for the aggregate of all radionuclides de-selected.
This process was applied to analysis data for this survey unit.Revision 0 8 Revision 0 8 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD The Elevated Measurement Comparison (EMC) did not apply to this survey unit since it is a Class 2 area and discrete, elevated areas of contamination were not expected.The Sign Test was selected as the non-parametric statistical test to demonstrate that the null hypothesis was rejected.
The use of the Sign Test did not require the selection or use of a background reference area, which simplified survey design and implementation.
In addition, this approach is conservative since it includes background Cs-137 as part of the sample set.The number of sediment samples for FSS was determined in accordance with Procedure RPM 5.1-12, "Determination of the Number of Samples for Final Status Survey. " The Lower Bound of the Gray Region (LBGR) was set to 0.78 in accordance with Procedure RPM 5.1-11 to maintain the relative shift (A/o) in the range of 1 and 3. The resulting relative shift was 2.0. A Prospective Power Curve was generated using COMPASS, a software package developed under the sponsorship of the United States Nuclear Regulatory Commission (USNRC) for implementation of MARSSIM in support of the decommissioning license termination rule (10 CFR 20, Subpart E). The result of the COMPASS computer run showed adequate power for the survey design. This indicates that the survey unit has a high probability of rejecting the null hypothesis, assuming that the characterization data are representative of the FSS results. Survey design specified fifteen (15) sediment core samples for non-parametric statistical testing.The grid pattern and locations of the sediment samples were determined using Visual Sample Plan (VSP) in accordance with Procedure RPM 5.1-14,"Identifying, and Marking Surface Sample Locations for Final Status Survey. " Visual Sample Plan was created by Pacific Northwest National Laboratory (PNNL) for the United States Department of Energy. A systematic triangular grid pattern with a random starting point was selected for sample design, which is appropriate for a Class 2 area.Judgmental sampling was included as a feature of this survey design to account for any anomalies potentially identified in the field.Sample locations were identified using AutoCAD-LT, a commercially available plotting software package with coordinates consistent with the Connecticut State Plane System. These coordinates were integrated with a GPS to locate sample locations in the field. Sample Measurement Locations for the design are listed with the GPS coordinates in Table 3.Revision 0 9 Revision 0 9 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Table 31 -,ample Measurement Loc'ationis N~ith Associated
(,S Coiordinates&
Designatiofn
~ Nprthing Easting 9106-0005-00IF 235695.70 670974.93 9106-0005-002F 235618.98 670930.64 9106-0005-003F 235618.98 671019.23 9106-0005-004F 235618.98 671107.82 9106-0005-005F 235618.98 671196.41 9106-0005-007F 235542.25 671152.11 9106-0005-008F 235542.25 671240.70 9106-0005-009F 235542.25 671329.29 9106-0005-OIOF 235542.25 671417.88 9106-0005-01 IF 235542.25 671506.47 9106-0005-013F 235465.53 671373.59 9106-0005-014F 235465.53 671462.18 9106-0005-015F 235465.53 671550.77 9106-0005-017F 235576.64 671402.01 9106-0005-018F 235550.83 671137.60 The sample location designations of Table 3 are not sequentially inclusive because of the necessity to relocate some samples due to the accessibility of the original sample locations.
Sample locations 9106-0005-006F and 9106-0005-012F were found to be on dry land. Consequently, they were randomly re-located using the VSP software to two (2) new locations designated as 9106-0005-017F and 9106-0005-018F.
Since sample 9106-0005-012F was randomly selected as a Quality Control (QC) split sample, sample 9106-0005-018F was designated as the replacement QC sample. Any location(s) identified by biased methods, were not included in Table 3.One (1) biased sample was required by the sample plan. This sample was designated as sample location 9106-0005-016F.
Sample results for sample location 9106-0005-016F are presented in Section 6, "Survey Results" and are also provided in Table 6.Four (4) sediment samples were analyzed for the full suite of radionuclides specified in Table 1, exceeding the requirement to analyze 5% of the sample population for HTD analysis specified in procedure RPM 5.1-11. Two (2) of the four (4) samples were randomly selected using the Microsoft Excel"RAND" function.
The two (2) samples exhibiting the highest observed radionuclide concentrations by gamma analyses were also selected.The implementation of quality control measures as referenced by Procedure RPM 5.1-24, "Split Sample Assessment for Final Status Survey, " required the collection of two (2) soil samples for "split sample" analysis by the off-site laboratory.
These locations were selected randomly using the Microsoft Excel Revision 0 10 Revision 0 10 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD"RAND" function.
The number of quality control samples exceeded the 5%requirement as specified by the LTP.Section 5.7.3.2.6 of the LTP specifies that scanning is not required for the FSS of the Discharge Canal. Table 4 provides a synopsis of the survey design.Survey Unit Land Area 9,716 m 2 naseu on IuLoukiAu-L 1 anu v isuai Sample Plan calculations Type 1 and Type 2 errors were 0.05, Number of 15 sigma was 0.143 the LBGR was set to Measurements 0.78 to maintain Relative Shift in the range of I and 3, Relative Shift was 2.0 Grid Spacing 27.4 m Based on triangular grid 3.16 pCi/g Cs-137 Design DCGL 1.52 pCi/g Co-60 To achieve ten (10) mrem/yr TEDE 0.62 pCi/g Sr-90 6.01 pCi/g Cs-137 To achieve nineteen (19) mrem/yr Operational 2.90 pCi/g Co-60 TEDE (2) to demonstrate compliance with DCGL 1.18 pCi/g Sr-90 Equation 2 of this Release Record Scan Coverage N/A The LTP exempts this area Sediment 6.01 pCi/g Cs-137 The Operational DCGL meets the LTP Investigation 2.90 pCi/g Co-60 criteria for a Class 2 survey unit Level 1.18 pCi/g Sr-90 (1) The survey design used a much smaller value for investigation than the Operational DCGL provided by Table 2 as the total dose from existing and future groundwater had not been established at the time of planning the FSS (2) The allowable dose for soil in this survey unit is nineteen (19) mrem/yr TEDE as the bounding dose from existing and future groundwater has been established based on field data (reference CY memo ISC 06-024.)5. SURVEY IMPLEMENTATION Final Status Survey field activities were conducted under Work Plan and Inspection Record (WP&IR) 2006-0021.
The WP&IR package included a detailed FSSP, job safety analysis, job planning checklist and related procedures for reference.
Daily briefings were conducted to discuss the expectations for job performance and the safety aspects of the survey. The "Daily Survey Journal" was used to document field activities and other information pertaining to the FSS.Measurement locations were identified in North American Datum (NAD) 1927 coordinates that were supplied to the sampling vendor, Ocean Surveys, Inc.(OSI) of Old Saybrook, Connecticut.
Discharge Canal sampling was accomplished using direct push technology to collect composite samples of Revision 0 I1I Revision 0 11 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD bottom and mean high water mark sediments.
Sediment cores from the Discharge Canal were obtained by OSI using a vibrating corer that is platform mounted on a sampling vessel. The core barrel was a three (3) inch diameter thin-walled aluminum tube which also served as a core liner (ten (10) feet or less). A core catcher was available to prevent the sample from sliding out of the bottom of the tube. Vessel positioning and the determination of sample locations were accomplished using a GPS interfaced with a navigation and data logging system.After extraction, water was drained from above the sample by drilling holes above the sediment.
The liner was cut, capped, sealed, labeled and turned over to site personnel who processed and controlled the samples under Chain of Custody (COC) protocols in accordance with procedure RPM 5.1-5, "Chain of Custody for Final Status Survey Samples. " Rinsing of the barrel and associated equipment was performed between sampling events. New aluminum tubes were used for each sample to prevent cross-contamination of subsequent samples.The fifteen (15) sediment samples were collected and packaged in accordance with Haddam Neck Plant (HNP) Procedure RPM 5.1-3, "Collection of Sample Media for Final Status Survey" and FSS design. Samples were controlled, transported, stored, and transferred to the off-site laboratory using COC protocols.
Four (4) samples (9106-0005-005F, 9106-0005-009F, 9106-0005-OIOF and 9106-0005-014F) were selected for HTD radionuclide analysis by the off-site laboratory.
The implementation of quality control measures included the collection of two (2) split samples at locations 9106-0005-003F and 9106-0005-018F for comparative analysis by the off-site laboratory.
- 6. SURVEY RESULTS The off-site laboratory employed for the radiological analyses of samples was General Engineering Laboratories (GEL) -Charleston, South Carolina.
The laboratory analyzed the fifteen (15) samples taken for non-parametric statistical testing and the associated duplicates using gamma spectroscopy.
Sr-90 was analyzed by gas flow proportional counting.
All analyses were performed to the required MDC.Cesium-137 was identified in twelve (12), Co-60 was identified in eight (8) and Sr-90 in four (4) of the fifteen (15) samples.Several other radionuclides which were positively identified (i.e., a result greater than two (2) standard deviations uncertainty) could be de-selected or excluded using the 5% and 10% rule described in Section 5.4.7.2 of the LTP.Revision 0 12 Revision 0 12 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD The off-site laboratory also processed four (4) samples for full HTD analysis as required by the sample plan. The requested analyses included alpha spectroscopy and liquid scintillation depending upon the radionuclide and the measurement method. All analyses were performed to the required MDC. Four (4) of the HTD radionuclides met the acceptance criteria for detection (i.e., a result greater than two standard deviations uncertainty) in more than one (1)sample; however, each of the positive results for HTD radionuclides could be de-selected based on the 5% and 10% rules.None of the sample results exceeded the Operational DCGL or required further investigation.
A summary of the sample results is provided in Table 5.9106-0005-001 F 2.88E-02 1.91E-02 5.1OE-03 1.57E-02 9106-0005-002F 6.60E-02 8.95E-02 8.79E-03 4.93E-02 9106-0005-003F 3.09E-01 3.15E-01 1.15E-02 1.70E-01 9106-0005-004F 1.63E-01 2.1 OE-01 6.21 E-03 1.05E-01 9106-0005-005F
-2.55E-02 9.87E-03 9.56E-03 7.28E-03 9106-0005-007F
-5.19E-04
-7.92E-03 5.15E-03 1.55E-03 9106-0005-008F 1.86E-01 1.69E-01 -1.56E-03 8.80E-02 9106-0005-009F 1.81E-01 2.14E-02 1.30E-02 4.85E-02 9106-0005-010F 2.60E-0 1 1.38E+00 1.34E-02 5.31 E-0 1 9106-0005-01 IF 5.76E-02 0.OOE+00 1.49E-02 2.22E-02 9106-0005-013F 5.3 1E-02 1.55E-02 -1.93E-03 1.25E-02 9106-0005-014F 4.73E-01 1.12E+00 3.27E-03 4.68E-01 9106-0005-015F 7.09E-02 2.78E-03 6.68E-03 1.84E-02 9106-0005-017F 1.39E-01 3.43E-01 -8.59E-04 1.41E-01 9106-0005-018F 3.39E-02 4.19E-02 5.37E-02 6.57E-02 (1) The Operational DCGLs from Table 2 are 6.01 pCi/g for Cs-137, 2.90 pCi/g for Co-60 and 1.18 for Sr-90; these are used in conjunction with the unity rule to achieve nineteen (19) mrem/yr TEDE The sample location designations of Table 5 are not sequentially inclusive because of the necessity to relocate some samples due to the accessibility of the original sample locations.
Sample locations 9106-0005-006F and 9106-0005-012F were found to be on dry land. Consequently, they were randomly re-located using the VSP software to two (2) new locations designated as 9106-0005-017F and 9106-0005-018F.
Since sample 9106-0005-012F was randomly selected as a Quality Control (QC) split sample, sample 9106-0005-018F was designated as the replacement QC sample.One (1) biased sample was required by the sample plan. This sample was designated as sample location 9106-0005-016F.
Sample results for sample location 9106-0005-016F are presented in Table 6 below.Revision 0 13 Revision 0 13 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Tabihe 6 -Biasei SampleResults C-17 Co-60 Sr-9O0 Fraction of the Sample Number p>i,- 1&p1/g_ pCi/g, Operational 9106-0005-016F
-1.86E-02 2.07E-03 9.07E-04 -1.61E-03 The Operational DCGLs from Table 2 are 6.01 pCi/g for Cs-137, 2.90 pCi/g for Co-60 and 1.18 for Sr-90; these are used in conjunction with the unity rule to achieve nineteen (19)mrem/yr TEDE.7. QUALITY CONTROL The two (2) split samples taken for QC were analyzed by the off-site laboratory.
The data were evaluated using USNRC acceptance criteria specified in Inspection Procedure 84750 and as detailed in HNP Procedure RPM 5.1-24,"Split Sample Assessment for Final Status Survey. " One (1) split-sample (9106-0005-018F/S) did not meet the comparison criterion for Co-60. A possible cause for this anomaly could be the presence of Co-60 in the form of discrete particles.
Such a physical form does not lend itself to homogenous mixing in a sediment matrix and, therefore, is not necessarily an indicator of inadequate sampling or sample preparation methodology.
In this sample, K-40, a natural radioisotope, was found to be present at an acceptable level of agreement, therefore, the comparison was determined to be acceptable.
For the other QC split samples, there was an acceptable level of agreement between the samples for all other detectable radionuclides.
The sample analysis vendor, GEL, maintained quality control and quality assurance plans as part of normal operation.
Refer to Attachment 2 for data and data quality analysis results.8. INVESTIGATIONS AND RESULTS One (1) sample result was found to exceed the design DCGL, but was below the nineteen (19) mrem/yr operational DCGL, as specified in Table 4. Confirmatory samples were collected to determine the extent of contamination.
The extent was bounded by taking four (4) confirmatory samples, one (1) in each major compass direction (i.e., North, East, South, West), two (2) meters distant from the elevated sample location.
The gamma spectroscopy results are included in Table 7.Revision 0 14 Revision 0 14 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD 01OF O0OA 4.63E-02 7.70E-02 0.00442 3.80E-02 010B 9.08E-02 1.15E-01 -0.00561 5.01E-02 010C 1.92E-01 5.22E-01 0.00471 2.16E-01 010D 6.30E-01 2.24E+00 0.0219 8.97E-0I (1) The investigation of sample 01OF was initiated upon a sample result greater than the original design dose often (10) mrem/yr, prior to finalization of the dose contribution due to groundwater.
Final results were evaluated against an Operational DCGL which considered the groundwater dose contribution.
(2) The Operational DCGLs are 6.01 pCi/g for Cs-137, 2.90 pCi/g for Co-60 and 1.18 for Sr-90; these are used in conjunction with the unity rule to achieve nineteen (19)mrem/yr TEDE.The confirmatory results demonstrated that no measurements exceeded the nineteen (19) mrem/yr Operational DCGL, indicating that no further actions are warranted.
- 9. REMEDIATION AND RESULTS Historically, no radiological remedial action as described by MARSSIM Section 5.4 was performed in this survey unit prior to or as a result of the FSS. Health Physics TSD BCY-HP-0078, "ALARA Evaluation of Soil Remediation in Support of Final Status Survey, " determined that remediation beyond that required to meet the release criteria to be unnecessary and that the remaining residual radioactivity in soil was ALARA.10. CHANGES FROM THE FINAL STATUS SURVEY PLAN The survey was designed to ten (10) mrem/yr TEDE which was conservative and necessary at the time of FSS planning.
It is no longer required as the total dose from existing and future groundwater has been established.
The dose for soil used to demonstrate compliance with the LTP and CTDEP criteria is nineteen (19) mrem/yr TEDE as discussed in Section 2 of this Release Record.11. DATA QUALITY ASSESSMENT (DQA)The DQO sample design and data were reviewed in accordance with Procedure RPM 5.1-23, "Data Quality Assessment. " The sample design had adequate power as indicated by the Retrospective Power Curve. The Sign Test was performed on the data and compared to the original assumptions of the DQOs.The evaluation of the Sign Test results indicates that the survey unit passes the unrestricted release criterion, thus, the null hypothesis is rejected.Revision 0 15 Revision 0 15 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Documentation was complete and legible. Surveys and sample collection were consistent with the DQOs and were sufficient to ensure that the survey unit was properly designated as Class 2.The preliminary data review consisted of calculating basic statistical quantities (e.g., mean, median, standard deviation).
The standard deviation was slightly more than the value used for the survey design. This is represented by the shift in the retrospective power curve as shown in Attachment 2f. This would indicate a need to change the original LBGR in order to maintain the number of samples at fifteen (15) to meet the Operational DCGL. However, the value of LBGR is not a critical issue as the survey unit has passed the statistical test, and the mean and median values are well below the Operational DCGL when used in conjunction with the unity rule. Also, the retrospective power curve shows that a sufficient number of samples were collected to achieve the desired power.Therefore, the survey unit meets the unrestricted release criterion with adequate power as required by the DQOs.The range of the data, about 3.23 standard deviations, was not unusually large.The difference between the mean and median was 40.8% of the standard deviation which indicates some skewness in the data. The data was represented graphically through posting plots, a frequency plot, and a quantile plot. The frequency plot shows some positive skewness as confirmed by the calculated skew of 2.01.All data, assessments, and graphical representations are provided in Attachment 2.12. ANOMALIES The anomalies associated with the disagreement between the field splits has been discussed in Section 7. The source of the disagreement for Co-60, was likely due to Co-60 being present in the form of discrete particles.
Such a physical form does not lend itself to homogenous mixing in a sediment matrix.No other anomalies were identified in this survey unit.13. CONCLUSION Survey Unit 9106-0005 has demonstrated compliance with the dose based, unrestricted release criterion.
The sample data passed the Sign Test and the null hypothesis was rejected.
The ALARA criteria for soils as specified in Chapter 4 of the LTP were achieved.
Reclassification and remediation of this survey unit was not required.Graphical representation of data indicates some positive skewness that is probably due to localized differences in particulate deposition rates, hydraulic velocity and sedimentation rates. The Retrospective Power Curve generated using COMPASS shows adequate power was achieved.
The survey unit was properly designated as a Class 2 survey unit.Revision 0 16 Revision 0 16 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD The dose contribution from sediment in this survey unit is 2.2 mrem/yr TEDE based on the average concentration of the samples used for non-parametric statistical sampling.This survey unit is not affected by existing groundwater (reference CY memo ISC 06-024). It has been determined that the dose contribution from existing groundwater sources is bounded by zero (0) mrem/yr TEDE.This survey unit is not considered impacted by future groundwater radioactive contamination, as there are no concrete foundations or footings containing residual radioactive material within the groundwater saturated zone in the area (reference CY memo ISC 06-024). The dose contribution from future groundwater, the third dose component is, therefore, zero (0) mrem/yr TEDE.The average total dose from residual radioactivity in this survey unit, including exposures from the three (3) components as described in Section 3, that is, residual radioactivity in soil, existing groundwater radioactivity, and future groundwater radioactivity from the burial of concrete foundations or footings from site buildings containing residual radioactivity, will not exceed 2.2 mrem/yr Total Effective Dose Equivalent (TEDE).14. ATTACHMENTS 14.1 Attachment I -Figures 14.2 Attachment 2 -Sample and Statistical Data Revision 0 17 Revision 0 17 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Attachment 1 Figures (9 pages)
ýý ý =ek,... -= .mr1VER.[r Reference Coordinate Sj~ten Benchmark Northing -236594.38
/ Lasting -668136.14 FiguCe 1 StoMnnecticut Yankee Atomic Power Company 9 -o o By~~ 1 Site Map With Reference To Survey Unit9106-0005 Octobffr 206 E.S.
14 9 9 9~)Sample Location sIaccwsble Sample Locaton WeWds 0 35 70 Feet Connecticut Yankee Atomic Power Company 9106-0005 Final Status Survey Design 911~) Samle Location hmkws~aAiy Sample Lowaton-_ Wetlands 0 35 70 , MC : Feet Connecticut Yankee Atomic Power Company 9106-0005 Final Swvy Design Investigation Sample Locations K 0.473 0 0.181 0 Location& Inxessblc Sample Locaton Wetlnds 0 34 66 PcF,, Note.Cesum-137 embfire w given mg wlts ofpcilk.onncticut Yankee Atomic Power Company 9106-0005 Final Status Survey Design Cesium-137Posting Plot Sample Location 4L-- Wedlams 9106-0005-01OF 0 34 69 MC== =Feet 0.26 Note.Cesiwn-137 masufta are given in units OfPcilkg Connecticut Yankee Atomic Power Company 9106-0005 (South End) Final Status Survey Investigative Samples Cesium-137Posting Plot 0O.1.12 0 0.0214 0&)Sample Lomaton&wLuccew7,le SaMPle Lomaton 0.0021 Wetlands 0 34 69 , Feet Note.Cobaft-60 ivsuft~ am givwi in unite ofpWi/g Connecticut Yankee Atomic Power Company 9106-0005 Final Status Survey Design Cobalt-60 Posting Plot
'9106-0005-010B 0.115 Sample Locadon 9106-0005-010C WetLand 0.522 9106-0005-010C 15 30 Connecticut Yankee Atomic Power Company 9106-0005 Final Status Survey Design Investigatory Samples Cobalt-60 Posting Plot 0.0149 4-0.0033 6 0.013 0 sawjle Loca~on 0.0009&)InC=]csll Sample Lomaton Wetlaads 0 34 68 Note.S&Wntium-90 mgzlty am ginunig~t~
ofPMilg Wnecicdut Yankee Atomic Power Comp 9106-0005 Final Status Survey Design Suontium-9 oPosting Plot
ý106-0005-010B
-0.0056 Location Locatioo 9106-0005-010C 0.0047 Wetands 9106-0005-0101 0 17 34 0.0134 Note: S&trotiw-90 g~bweni mt gim ill Units of tc/g.Connecticut Yankee Atomic Power Company 9106-0005Final Status Survey Investgatoy Samples Stontum-90 Posting Plot DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Attachment 2 Sample and Statistical Data DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Attachment 2a Sample Data (247 Pages)
Table of Contents G eneral Narrative
..................................................................
1 Chain of Custody and Supporting Documentation
...........
4 Radiological Analysis ..........................................................
9 Sample Data Summary ......................................................
29 Q uality C ontrol D ata ...........................................................
69 General Narrative 1 CASE NARRATIVE For CONNECTICUT YANKEE RE: Sediment PO# 002332 Work Order: 162485 SDG: MSR #06-0675 June 7, 2006 Laboratory Identification:
General Engineering Laboratories, LLC Mailing Address: P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address: 2040 Savage Road Charleston, South Carolina 29407 Telephone Number: (843) 556-8171 Summary: Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC, (GEL)in Charleston, South Carolina on May 9, 2006. All sample containers arrived without any visible signs of tampering or breakage.
The chain of custody contained the proper documentation and signatures.
The laboratory received the following sample(s):
Sample ID Client Sample ID 162485001 9106-0005-OOIF 162485002 9106-0005-002F 162485003 9106-0005-003F 162485004 9106-0005-003FS 162485005 9106-0005-004F 162485006 9106-0005-007F 162485007 9106-0005-008F 162485008 9106-0005-OIOF GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.P.O. Box 30712
- Charleston, SC 29417 ° 2040 Savage Road (29407)Phone (843) 556-8171 -Fa 2 (843) 766-1178
- www.gel.com Sample ID 162485009 162485010 162485011 162485012 162485013 162485014 162485015 162485016 162485017 162485018 Client Sample ID 9106-0005-01 IF 9106-0005-013F 9106-0005-014F 9106-0005-016F 9106-0005-015F 9106-0005-017F 9106-0005-018F 9106-0005-018FS 9106-0005-005F 9106-0005-009F Items of Note: There are no items of note.Case Narrative:
Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures.
Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.
Analytical Request: Sixteen sediment samples were analyzed for FSSGAM and Sr-90.Two sediment samples were analyzed for FSSALL.Internal Chain of Custody: Custody was maintained for the sample(s).
Data Package: The enclosed data package contains the following sections:
Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.
I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.
Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP INC.P.O. Box 30712
- Charleston, SC 29417
- 2040 Savage Road (29407)Phone (843) 556-8171
- Fa)5843) 766-1178 -www.gel.com Chain of Custody and Supporting Documentation 4
Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Health Physics Procedure GPP-GGGR-R5 104-003-Attachment B-CY-001 Major Chain of Custody Form Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 I 6.aAS5 /k'roject Name: "aaaam Neck i~ecommisslo Contact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
0 30 D. [ 14 D. R] 7 D.Date--.I Samples Shipped Via: Z Fed Ex LI ups nI Hand3 lOther Bill of Lading #7f go '?15s" Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Health Physics Procedure GPP-GGGR-R5 104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested " Use Contact Name & Phone: ----Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories
, 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones r(n Priority:
9 30 D. E] 14 D. [17 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservatin c2 9106-0005-OIOF 5/02/06 13:16 SE C BP x x Transferred from COC 2006-00314 QM 9106-0005-01 IF 5/02/06 13:39 SE C BP x X Transferred from COC 2006-00314 Q 9106-0005-013F 5/02/06 14:35 SE C BP x x Transferred from COC 2006-00314 9106-0005-014F 5/02/06 15:04 SE C BP x X Transferred from COC 2006-00314
! 9106-0005-016F 5/02/06 13:59 SE C BP x X Transterred from COC 2006-00314 5 9106-0005-015F 5/03/06 08:03 SE C BP X X Transferred from COC 2006-00316 U 9106-0005-017F 5/03/06 08:13 SE C BP X X Transferred from COC 2006-00316
)5 9106-0005-018F 5/03/06 09:09 SE C BP x X Transferred from COC 2006-00316
- 9106-0005-018FS 5/03/06 09:09 SE C BP X X Transferred from COC 2006-00316 NOTES: PO #: 002332 MSR #: 06-0675 SSWP# NA [ LTP QA [] Radwaste QA El Non QA Samples Shipped Via: El FedEx EiBUPS LI Hand 1)
Date/Time 2 [atc/Time
[3)
By '@
o E [ Other 3) quished By Date/Time 4),Received&'y Date/Time
_ _____Bill of Lading #79z6' q19S '~
Connecticut Yankee CY-ISC.SON-0OI Statement of Work for Analytical Lab Services .Y, Figure 1. Sample Check-in List Date/Time Received: Work Order Number: \J"- I.Shipping Cdntainer ID:. o , Chain of Custody n ,. L- Lc O -l I. Custody Seals od shipping container intact?.. -Yes No 2. Custody Seals dated and signed? Yes F'fNo I ].3. Chain-of-Custody record present? Yes f No [ I 4. Cooler temperature Cg C., I C C.S. Vermiculite/packing materials is: Wet ,]Dry U, ]6.: -.Number of samples in shipping container:
- -t 7. Sample holding times exceeded?
.Yes [ I No 8. Samples have: "//tape Whazard labels-/-custody seals appropriate sample labels 9. Samples are" i in good condition
.... leaking ..)-broken -have air bubbles 10. Were any anomalies identified in sample receipt? Yes ' ] No Il.. Description of anomalies (include sample numbers): Sample Custodian/Laboratoay:-
Date: /g .O .g"-Telephoned to: -On By .7 SAMPL RECEIPT & REVIEW FORM 0P e'+4 roR Itc" PM use only Client: Q\/A 4 b ]f7/6jSDG/ARCOC/Work Order: (,7- q285 Date Received:
IPM(A) Review (ensure non formi items are resolved prior to signing): Received By: j___________________
Sample Receipt Criteria z Comments/Qualifiers (Required for Non-Conforming Items)Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) a sealed?Samp requiring cold Circle Coolant # ice bags blue ice dry ice none other describe)2 preservati within (4 +/- 2 C)?Record preserv *on method.Chain of custody do ns included with shi mn?_____________________________
4 Sample containers intact and Circle Applicable:
seals broken damaged container leaking container other (describe) 5 Samples requiring chemical Sample ID's, containers affected and observed pH: preservation at proper pH? S s n a VOA vials free of headspace Sample ID's and containers affected: 6 (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory) 8 Samples received within holding Id's and tests affected: time?9 Sample ID's on COC match ID's Sample ID's and containers affected: on bottles?10 Date & time on COC match date Sample ID's affected:& time on bottles?Number of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in 12 relinquished/received sections?Air Bill ,Tracking
- 's, & Fi(- 7q2-iw 71095 4?52-- > /75: --14Additional Comments iR)( 4. & --:> [o c , RSO RAD Receipt #Sse dgar nrm in *jf > x2 area background is observed on samples identified as "non-Suspected Hazard Information
- '= = .., W al regulated/non-radioactive", contact the Radiation Safety group for further 04 cd EE investigation.
SRadiological Classification?
r Maximum Counts Observed*:
PC Regulated?
Comments: Shipped as DUT Hazardous " C C JMaterial?
If yes, contact Waste UN#:[Manager or ESH Manager.PM (or PMA) review of Hazard classification:
Initials Date: " o 8 0 RADIOLOGICAL ANALYSIS 9 Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)Work Order 162485 Method/Analysis Information Product: Alphaspec Am241, Cm, Solid ALL FSS DOE EML HASL-300, Am-05-RC Modified Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 533471 528491 528487 Sample ID 162485017 162485018 1201101117 1201101118 1201101119 1201101120 Client ID 9106-0005-005F 9106-0005-009F Method Blank (MB)162485017(9106-0005-005F)
Sample Duplicate (DUP)162485017(9106-0005-005F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
10 Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162485017 (9106-0005-005F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information 11 Product: Alphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- 11-RC Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 533472 528491 528487 Sample ID 162485017 162485018 1201101121 1201101122 1201101123 1201101124 Client ID 9106-0005-005F 9106-0005-009F Method Blank (MB)162485017(9106-0005-005F)
Sample Duplicate (DUP)162485017(9106-0005-005F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 I REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162485017 (9106-0005-005F).
QC Information All of the QC samples met the required acceptance limits.12 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu- 11-RC Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 533473 Prep Batch Number: 528491 Dry Soil Prep GL-RAD-A-021 Batch Number: 528487 13 Sample ID Client ID 162485017 9106-0005-005F 162485018 9106-0005-009F 1201101125 Method Blank (MB)1201101126 162485017(9106-0005-005F)
Sample Duplicate (DUP)1201101127 162485017(9106-0005-005F)
Matrix Spike (MS)1201101128 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162485017 (9106-0005-005F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis The tracer yield for sample 1201101127 (9106-0005-005F) was recounted due to poor resolution.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from 14 referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Gamma,Solid-FSS GAM & ALL FSS Analytical Method: Prep Method: Analytical Batch Number: Prep Batch Number: Sample ID 162485001 162485002 162485003 162485004 162485005 162485006 162485007 162485008 162485009 162485010 162485011 162485012 162485013 162485014 162485015 162485016 162485017 162485018 1201092332 1201092333 1201092334 EML HASL 300,4.5.2.3 Dry Soil Prep 529776 528487 Client ID 9106-0005-001F 9106-0005-002F 9106-0005-003F 9106-0005-003FS 9106-0005-004F 9106-0005-007F 9106-0005-008F 9106-0005-OIOF 9106-0005-01IF 9106-0005-013F 9106-0005-014F 9106-0005-016F 9106-0005-015F 9106-0005-017F 9106-0005-018F 9106-0005-018FS 9106-0005-005F 9106-0005-009F Method Blank (MB)162485001(9106-0005-001 F) Sample Duplicate (DUP)Laboratory Control Sample (LCS)15 SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-013 REV# 11.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162485001 (9106-0005-001F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Samples 162485002 (9106-0005-002F), 162485003 (9106-0005-003F), 162485014 (9106-0005-017F) and 162485015 (9106-0005-018F) were recounted due to high MDAs.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.16 Qualifier information Qualifier UI Reason Data rejected due to interference.
Analyte Europium-155 UI Manganese-54 Data rejected due to low abundance.
Cesium- 134 Cobalt-60 Sample 162485006 162485015 1201092333 162485008 162485001 162485002 162485008 162485011 162485012 162485013 162485014 162485015 162485017 162485018 1201092333 162485016 162485009 U'Data rejected due to no valid peak.Method/Analysis Information Product: Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: GFPC, Sr90, solid-ALL FSS EPA 905.0 Modified Ash Soil Prep Dry Soil Prep 535512 528491 528487 17 Sample ID 162485001 162485002 162485003 162485004 162485005 162485006 162485007 162485008 162485009 162485010 162485011 162485012 162485013 162485014 162485015 162485016 162485017 162485018 1201105909 1201105910 1201105911 1201105912 Client ID 9106-0005-001F 9106-0005-002F 9106-0005-003F 9106-0005-003FS 9106-0005-004F 9106-0005-007F 9106-0005-008F 9106-0005-01OF 9106-0005-01IF 9106-0005-013F 9106-0005-014F 9106-0005-016F 9106-0005-015F 9106-0005-017F 9106-0005-018F 9106-0005-018FS 9106-0005-005F 9106-0005-009F Method Blank (MB)162335018(9106-0003-008F)
Sample Duplicate (DUP)162335018(9106-0003-008F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QCQ Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162335018 (9106-0003-008F).
18 QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS DOE EML HASL-300, Tc-02-RC Modified Analytical Method: Analytical Batch Number: 531704 Sample ID 162485017 162485018 1201096867 1201096868 1201096869 1201096870 Client ID 9106-0005-005F 9106-0005-009F Method Blank (MB)162583001 (NOL-02-02-005-F-S)
Sample Duplicate (DUP)162583001(NOL-02-02-005-F-S)
Matrix Spike (MS)Laboratory Control Sample (LCS)19 SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162583001 (NOL-02-02-005-F-S).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.20 Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-1, Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 531618 528491 528487 Sample ID 162485018 1201096631 1201096632 1201096633 1201096634 Client ID 9106-0005-009F Method Blank (MB)163173001 (9304-0000-063RACR)
Sample Duplicate (DUP)163173001(9304-0000-063RACR)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC0 Information:
Blank Information The blank volume is representative of the sample volume in this batch.21 Designated QC The following sample was used for QC: 163173001 (9304-0000-063RACR).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: Prep Method: DOE RESL Fe-1, Modified Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 535483 528491 528487 22 Sample ID Client ID 162485017 9106-0005-005F 1201105872 Method Blank (MB)1201105873 162335018(9106-0003-008F)
Sample Duplicate (DUP)1201105874 162335018(9106-0003-008F)
Matrix Spike (MS)1201105875 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162335018 (9106-0003-008F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Samples were reprepped due to low/high carrier/tracer yield.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this 23 SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Ni63, Solid-ALL FSS Analytical Method: DOE RESL Ni-1, Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 531622 528491 528487 Sample ID 162485017 162485018 1201096644 1201096645 1201096646 1201096647 Client ID 9106-0005-005F 9106-0005-009F Method Blank (MB)163173001 (9304-0000-063RACR)
Sample Duplicate (DUP)163173001(9304-0000-063RACR)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
24 Quality Control (00 Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 163173001 (9304-0000-063RACR).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: LSC, Tritium Dist, Solid-HTD2,ALL FSS Analytical Method: EPA 906.0 Modified Analytical Batch Number: 531705 25 Sample ID Client ID 162485017 9106-0005-005F 162485018 9106-0005-009F 1201096877 Method Blank (MB)1201096878 162583001(NOL-02-02-005-F-S)
Sample Duplicate (DUP)1201096879 162583001(NOL-02-02-005-F-S)
Matrix Spike (MS)1201096880 Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 11.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 162583001 (NOL-02-02-005-F-S).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Sample 1201096877 (MB) was recounted due to high MDA.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from 26 referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint C14, Solid AII,FSS EPA EERF C-01 Modified Analytical Method: Analytical Batch Number: 534984 Sample ID 162485017 162485018 1201104745 1201104746 1201104747 1201104748 Client ID 9106-0005-005F 9106-0005-009F Method Blank (MB)163173001 (9304-0000-063RACR)
Sample Duplicate (DUP)163173001 (9304-0000-063RACR)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.27 Designated QC The following sample was used for QC: 163173001 (9304-0000-063RACR).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Samples were reprepped due to low/high recovery.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Certification Statement Where the analytical.
method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator.
In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.The following data validator verified the information presented in this case narrative:
Reviewer/Date:" M 28 SAMPLE DATA
SUMMARY
29 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co.Client SDG: MSR#06-0675 GEL Work Order: 162485 The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification ND The analyte concentration is not detected above the reporting limit.The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures.
Please direct any questions to your Project Manager, Cheryl Jones.Reviewed by 30 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: 9106-0005-OO1F Project: YANKO 1204 Sample ID: 162485001 Client ID: YANKOOl Matrix: SE Vol. Recv.: Collect Date: 02-MAY-06 Receive Date: 09-MAY-06 Collector:
Client Moisture:
13.9%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium-137 U Cobalt-60 U Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U -Potassium-40 Radium-226 Silver-108m U-0 Thallium-208 Rad Gas Flow Proportional Counting GFPC, S90, solid-ALL FSS Strontium-90 U 1.69 0.064 0.887 1.15 0.00 0.0288 0.0191-0.0115-0.0146 0.0293 1.62 1.36 0.0112 0.00247 11.3 1.15.000679 0.495+/-0.251+/-0.113+/-0.313+/-0.147+/-0.0385+/-0.0259+/-0.0235+/-0.0595+/-0.0717+/-0.0678+1-0.145+/-0.154+/-0.0236+/-0.0192+1- 1.05+/-0.147+/-0.0191+/-0.0669 0.0613 0.0919 0.147 0.0343 0.0269 0.020 0.0194 0.053 0.0515 0.0581 0.0311 0.035 0.021 0.0168 0.148 0.0343 0.0167 0.0186+/-0.251+/-0.113+/-0.313+/-0.147+/-0.0385+/-0.0259+/-0.0235+/-0.0595+/-0.0717+/-0.0678+/-0.145+/-0.154+/-0.0236+/-0.0192+/-1.05+/-0.147+/-0.0191+/-0.0669 0.131 0.188 0.310 0.072 0.0561 0.042 0.0418 0.110 0.111 0.119 0.0639 0.0728 0.0443 0.0353 0.326 0.072 0.0349 0.0391 0.0162 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/02/06 1701 529776 1 BXFI 06/06/06 2315 535512 2 0.0051 +/-0.00834 0.00785 +/-0.00834 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 31 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-OOIF Proiect: YANK01204 Sample ID: 162485001 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Fracer Recovery GFPC, Sr90, solid-ALL FSS 84 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.32 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-002F 162485002 SE 02-MAY-06 09-MAY-06 Client 24.4%Proiect: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europiurn-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting 1.01 0.0239 0.970 0.596 0.00 0.066 0.0895 0.00476-0.094 0.0792 1.12 0.709 0.0279-0.011 19.7 0.596-0.0068 0.351+/-0.158+/-0.128+/-0.334+/-0.0898+/-0.040+/-0.028+/-0.0523+/-0.0525+/-0.0729+/-0.0731+/-0.0645+/-0.0806+/-0.0326+/-0.0193+/-1.00+/-0.0898+/-0.0174+/-0.0455 0.0602 0.0948 0.131 0.0351 0.0245 0.0183 0.0192 0.0426 0.054 0.0478 0.0247 0.033 0.0165 0.0154 0.165 0.0351 0.0146 0.0182+/-0.158+/-0.128+/-0.334+/-0.0898+/-0.040+/-0.028+/-0.0523+/-0.0525+/-0.0729+/-0.0731+/-0.0645+/-0.0806+/-0.0326+/-0.0193+/-1.00+/-0.0898+/-0.0174+/-0.0455 0.128 0.195 0.276 0.0732 0.0512 0.0383 0.0414 0.0885 0.116 0.0983 0.0511 0.0684 0.035 0.0323 0.358 0.0732 0.0304 0.038 0.0241 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/06/06 2111 529776 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.00879 +/-0.0124 0.0116 +/-0.0124 BXF1 06/06/06 2315 535512 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXM1 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 33 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-002F Proiect: YANKO 1204 Sample ID: 162485002 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr9O, solid-ALL FSS 77 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.34 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-003 F 162485003 SE 01-MAY-06 09-MAY-06 Client 18%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium- 137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver- 108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.799 0.0143 0.576 0.558 0.0211 0.309 0.315-0.036-0.031 0.049 0.770 0.591 0.0053 0.00488 11.1 0.558 0.00339 0.241+/-0.140+/-0.0558+/-0.223+/-0.0789+/-0.025+/-0.0378+/-0.0352+/-0.0336+/-0.0389+/-0.0404+/-0.0726+/-0.072+/-0.0138+/-0.0117+/-0.839+/-0.0789+/-0.0112+/-0.036 0.0393 0.0479 0.0854 0.0206 0.0143 0.0108 0.0107 0.0288 0.0304 0.0382 0.0187 0.0223 0.0123 0.0106 0.090 0.0206 0.010 0.00999+/-0.140+1-0.0558+/-0.223+/-0.0789+/-0.025+/-0.0378+/-0.0352+/-0.0336+/-0.0389+/-0.0404+/-0.0726+/-0.072+/-0.0138+/-0.0117+/-0.839+/-0.0789+/-0.0112+/-0.036 0.0827 0.0981 0.179 0.0428 0.0297 0.0227 0.0228 0.0598 0.0648 0.0783 0.0384 0.046 0.0257 0.0221 0.195 0.0428 0.0208 0.0209 0.0116 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH 1 06/07/06 0542 529776 1 BXFI 06/06/06 2315 535512 2 0.0115 +/-0.00646 0.00552 +/-0.00646 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXM1 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description 1 2 3 EML HASL 300, 4.5.2.3 EPA 905.0 Modified EPA 905.0 Modified 35 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-003F Proiect: YANK01204 Sample ID: 162485003 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrierf/racer Recovery GFPC, Sr9O, solid-ALL FSS 80 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.36 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-003FS 162485004 SE 01-MAY-06 09-MAY-06 Client 19.2%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANKOO I Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.820 Americium-241 U -0.213 Bismuth-212 0.487 B3ismuth-214 0.660 Cesium-134 U 0.0563 Cesium-137 0.331 Cobalt-60 0.618 Europium-152 U -0.0624 Europium-154 U 0.00151 Europium-155 U 0.0473 Lead-212 0.789 Lead-214 0.663 Manganese-54 U 0.0192 Niobium-94 U -0.00129 Potassium-40 11.6 Radium-226 0.660 Silver-108m U -0.00245 Thallium-208 0.272 Rad Gas Flow Proportional Counting+/-0.171+/-0.112+/-0.330+/-0.096+/-0.0303+/-0.0533+/-0.0738+/-0.0613+/-0.0757+/-0.0801+/-0.0601+/-0.099+/-0:0257+/-0.0203+/-0.876+/-0.096+/-0.0201+/-0.0448 0.0681 0.0853 0.145 0.0359 0.027 0.0191 0.0204 0.0496 0.0543 0.058 0.0292 0.0392 0.0232 0.0176 0.156 0.0359 0.0169 0.022+/-0.171+/-0.112+/-0.330+/-0.096+/-0.0303+/-0.0533+/-0.0738+/-0.0613+/-0.0757+/-0.0801+/-0.0601+/-0.099+/-0.0257+/-0.0203+/-0.876+/-0.096+/-0.0201+/-0.0448 0.146 0.175 0.308 0.0759 0.0569 0.0406 0.0445 0.104 0.119 0.120 0.0606 0.0816 0.049 0.0372 0.349 0.0759 0.0355 0.0462 0.0171 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/02/06 1705 529776 1 GFPC, S90, solid-ALL FSS Strontium-90 U 0.00413 +/-0.0087 0.00819 +/-0.0087 BXFI 06/06/062315 535512 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 37 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-003FS Project: YANKO 1204 Sample ID: 162485004 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 63 (25°/-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.38 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Qualifier Result 9106-0005-004F 162485005 SE 02-MAY-06 09-MAY-06 Client 15%Proiect: YANK01204 Client ID: YANKOO Vol. Recv.: Parameter Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium- 137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-5 4 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting 0.988 0.0868 0.795 0.652 0.0438 0.163 0.210 0.0114 0.0148 0.0299 0.971 0.802 0.00298-0.0158 9.40 0.652-0.016 0.283 Uncertainty
+/-0.223+/-0.102+/-0.406+/-0.118+/-0.042+/-0.040+/-0.0451+/-0.0904+/-0.069+/-0.0714+/-0.110+/-0.122+/-0.0268+/-0.0251+/-0.987+/-0.118+/-0.0227+/-0.0535 LC TPU MDA Units DF Analyst Date Time Batch Mtd 0.0833 0.0899 0.158 0.044 0.0264 0.0208 0.0199 0.0574 0.0549 0.0676 0.0343 0.0413 0.0209 0.0187 0.171 0.044 0.0189 0.0232+/-0.223+/-0.102+/-0.406+/-0.118+/-0.042+/-0.040+/-0.0451+/-0.0904+/-0.069+/-0.0714+/-0.110+/-0.122+/-0.0268+/-0.0251+/-0.987+/-0.118+/-0.0227+/-0.0535 0.167 0.180 0.316 0.088 0.0527 0.0416 0.0398 0.115 0.110 0.135 0.0687 0.0826 0.0417 0.0373 0.342 0.088 0.0378 0.0464 0.0139 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/04/06 2031 529776 1 GFPC, SO9O, solid ALL FSS Strontium-9 0 U 0.00621 +/-0.00726 0.00668 +/-0.00726 BXF1 06/06/062315 535512 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Dry Soil Prep Ash Soil Prep, GL-RAD-A-021B Dry Soil Prep GL-RAD-A-021 LXM I LXM2 05/10/06 0855 528491 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 3 EPA 905.0 Modified 39 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-004F Project: YANK01204 Sample ID: 162485005 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90,. solid-ALL FSS 81 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.40 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of AnalysisT i T Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-007F 162485006 SE 02-MAY-06 09-MAY-06 Client 22.7%Project: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium-137 U-C Cobalt-60 U -Europium-152 U -Europium-154 U Europium-155 UUI Lead-212 Lead-214 Manganese-54 U -Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.864-0.0181 0.624 0.550 0.0386.000519-0.00792 0.00987 0.0388 0.00 1.01 0.568 0.00574 0.0306 15.8 0.550-0.0145 0.328+/-0.211+/-0.123+/-0.357+/-0.117+/-0.0448+/-0.0237+/-0.0276+/-0.0594+/-0.0715+/-0.101+/-0.110+/-0.109+/-0.025+/-0.0288+/-1.48+/-0.117+/-0.0187+/-0.0609 0.0703 0.0875 0.151 0.0353 0.0249 0.0194 0.0221 0.0468 0.0622 0.0505 0.027 0.0352 0.0198 0.0179 0.166 0.0353 0.015 0.0184+/-0.211+/-0.123+/-0.357+/-0.117+/-0.0448+/-0.0237+/-0.0276+/-0.0594+/-0.0715+/-0.101+/-0.110+/-0.109+/-0.025+/-0.0288+/-1.48+/-0.117+/-0.0187+/-0.0609 0.150 0.180 0.320 0.0744 0.0524 0.0411 0.0479 0.0979 0.134 0.104 0.0559 0.0734 0.0421 0.0377 0.370 0.0744 0.0317 0.0389 0.0221 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/02/06 1814 529776 1 BXFI 06/06/06 2315 535512 2 0.00515 +/-0.0113 0.0106 +/-0.0113 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 41 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 lnjun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-007F Project: YANK01204 Sample ID: 162485006 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 56 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.42 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-008F 162485007 SE 02-MAY-06 09-MAY-06 Client 32.4%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 0.561 Americium-241 U 0.0421 Bismuth-212 0.707 Bismuth-214 0.454 Cesium-134 U 0.0398 Cesium-137 0.186 Cobalt-60 0.169 Europium-152 U -0.00962 Europium-154 U -0.0777 Europium-155 U 0.0611 Lead-212 0.622 Lead-214 0.505 Manganese-54 U 0.0275 Niobium-94 U -0.0153 Potassium-40 10.4 Radium-226 0.454 Silver-108m U 0.00991 Thallium-208 0.210 Rad Gas Flow Proportional Counting+/-0.225+/-0.116+/-0.249+/-0.107+/-0.0588+/-0.0582+/-0.0693+/-0.0639+/-0.0922+/-0.0741+/-0.0943+/-0.129+/-0.0446+/-0.0267+/- 1.09+/-0.107+/-0.0259+/-0.0495 0.0839 0.0954 0.146 0.0407 0.0274 0.0245 0.0213 0.0552 0.0673 0.0675 0.0431 0.0406 0.0233 0.0207 0.223 0.0407 0.0229 0.0263+/-0.225+/-0.116+/-0.249+/-0.107+/-0.0588+/-0.0582+/-0.0693+/-0.0639+/-0.0922+/-0.0741+/-0.0943+/-0.129+/-0.0446+/-0.0267+/-1.09+/-0.107+/-0.0259+/-0.0495 0.185 0.200 0.325 0.0883 0.0597 0.0532 0.0491 0.118 0.152 0.141 0.0899 0.0868 0.0512 0.0451 0.510 0.0883 0.0488 0.0564 0.0144 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCig pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/02/06 1815 529776 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00156 +/-0.00706 0.00692 +/-0.00706 BXF1 06/06/062315 535512 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXM1 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 43 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-008F Project: YANKO 1204 Sample ID: 162485007 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier[Fracer Recovery GFPC, Sr90, solid-ALL FSS 80 (25%/o-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.44 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com CDrfifp.2fD nf A nahrci SLI1I~..~L~
~Ik £~LI~4R V ~YI~Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Project: YANKO 1204 Client ID: YANKOOl Vol. Recv.: Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-01OF 162485008 SE 02-MAY-06 09-MAY-06 Client 24.2%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid FSS GAM & ALL FSS Actinium-228 1.07 Americium-241 U 0.106 Bismuth-212 0.847 Bismuth-214 0.606 Cesium-134 UUI 0.00 Cesium-137 0.260 Cobalt-60 1.38 Europium-152 U -0.026 Europium-154 U 0.00723 Europium-155 U 0.0255 Lead-212 1.10 Lead-214 0.667 Manganese-54 UUI 0.00 Niobium-94 U 0.00799 Potassium-40 19.5 Radium-226 0.606 Silver-108m U 0.00878 Thallium-208 0.381 Rad Gas Flow Proportional Counting+/-0.262+/-0.119+/-0.369+/-0.101+/-0.044+1-0.0501+/-0.116+/-0.0529+/-0.0668+/-0.0705+/-0.107+/-0.104+/-0.0364+/-0.0213+/-1.58+/-0.101+/-0.0183+/-0.062 0.0751 0.0922 0.139 0.0329 0.0243 0.0189 0.0195 0.0437 0.055 0.0421 0.024 0.0308 0.0196 0.0175 0.162 0.0329 0.0155 0.0159+/-0.262+/-0.119+/-0.369+/-0.101+/-0.044+/-0.0501+/-0.116+/-0.0529+/-0.0668+/-0.0705+/-0.107+/-0.104+/-0.0364+/-0.0213+/-1.58+/-0.101+/-0.0183+/-0.062 0.156 0.189 0.291 0.0684 0.0504 0.0393 0.0414 0.0901 0.117 0.0862 0.0494 0.0637 0.0409 0.0363 0.348 0.0684 0.032 0.0332 0.0167 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/02/06 1816 529776 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.0134 +/-0.00904 0.00803 +/-0.00905 BXF1 06/06/06 2315 535512 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 45 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010F Project: YANKO1204 Sample ID: 162485008 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits CarrierlTracer Recovery GFPC, Sr90, solid-ALL FSS 70 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.46 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Frtfpofjti nf A nAl cie k M J.Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-011 F 162485009 SE 02-MAY-06 09-MAY-06 Client 21.6%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium-137 U Cobalt-60 UUI Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 1.04-0.0209 0.798 0.761 0.0368 0.0576 0.00 0.0149 0.101 0.0805 0.965 0.696 0.0519-0.0229 13.2 0.761 0.017 0.307+/-0.322+/-0.0723+/-0.698+/-0.207+/-0.0558+/-0.053+/-0.0718+/-0.126+/-0.0992+/-0.125+/-0.128+/-0.181+/-0.0609+/-0.0502+/-1.63+/-0.207+/-0.046+/-0.106 0.158 0.0605 0.370 0.0856 0.0494 0.0486 0.0351 0.106 0.136 0.0965 0.0608 0.0702 0.054 0.0406 0.372 0.0856 0.0389 0.0478+/-0.322+/-0.0723+/-0.698+/-0.207+/-0.0558+/-0.053+/-0.0718+/-0.126+/-0.0992+/-0.125+/-0.128+/-0.181+/-0.0609+/-0.0502+/-1.63+/-0.207+/-0.046+/-0.106 0.342 0.125 0.793 0.182 0.107 0.104 0.0803 0.223 0.298 0.201 0.127 0.149 0.115 0.087 0.844 0.182 0.0825 0.102 0.028 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/02/06 1816 529776 1 BXF1 06/06/06 2315 535512 2 0.0149 +/-0.0147 0.0134 +/-0.0147 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 47 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-01 IF Proiect: YANK01204 Sample ID: 162485009 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr9O, solid-ALL FSS 58 (25%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.Ul Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.48 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-013F 162485010 SE 02-MAY-06 09-MAY-06 Client 28.7%Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS Actinium-228 0.845 Americium-241 U 0.0182 Bismuth-212 0.534 Bismuth-214 0.502 Cesium-134 U 0.022 Cesium-137 U 0.0531 Cobalt-60 U 0.0155 Europium-152 U 0.0486 Europium-154 U -0.0487 Europium-155 U 0.00245 Lead-212 0.953 Lead-214 0.522 Manganese-54 U -0.0151 Niobium-94 U 0.0023 Potassium-40 14.6 Radium-226 0.502 Silver-108m U 0.0221 Thallium-208 0.308 Rad Gas Flow Proportional Counting+/-0.370+/-0.0393+/-0.723+/-0.163+/-0.0811+/-0.0476+/-0.0421+/-0.0961+/-0.128+/-0.0732+/-0.0988+/-0.113+/-0.044+/-0.0308+/-1.53+/-0.163+/-0.0309+/-0.0757 0.118 0.0327 0.226 0.0695 0.0372 0.0334 0.0365 0.0732 0.0981 0.0575 0.0376 0.050 0.0338 0.0254 0.277 0.0695 0.0278 0.0286+/-0.370+/-0.0393+/-0.723+/-0.163+/-0.0811+/-0.0476+/-0.0421+/-0.0961+/-0.128+/-0.0732+/-0.0988+/-0.113+/-0.044+/-0.0308+/-1.53+/-0.163+/-0.0309+/-0.0757 0.260 0.0687 0.500 0.149 0.0817 0.0728 0.0826 0.157 0.222 0.121 0.080 0.108 0.0744 0.0561 0.652 0.149 0.0598 0.0626 0.0183 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/02/06 1816 529776 1 GFPC, SO9O, solid-ALL FSS Strontium-90 U -0.00193 +/-0.00896 0.00878 +/-0.00896 BXFI 06/06/062315 535512 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXM1 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 49 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-013F Project: YANKO 1204 Sample ID: 162485010 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 69 (25%,- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria* Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier* QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.50 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: 9106-0005-014F Project: YANK01204 Sample ID: 162485011 Client ID: YANKOO Matrix: SE Vol. Recv.: Collect Date: 02-MAY-06 Receive Date: 09-MAY-06 Collector:
Client Moisture:
22.8%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM& ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium- 137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 0.767 0.00567 0.678 0.568 0.00 0.473 1.12-0.0376-0.0403-0.0272 0.752 0.520-0.0183 0.0317 10.6 0.568 0.00517 0.240+/-0.372+/-0.0503+/-0.625+/-0.137+/-0.123+/-0.101+/-0.136+/-0.092+/-0.128+/-0.0791+/-0.097+/-0.136+/-0.0478+/-0.0391+/-1.36+/-0.137+/-0.0328+/-0.0841 0.142 0.0456 0.288 0.0579 0.0505 0.0326 0.027 0.0787 0.103 0.0682 0.0449 0.0599 0.0378 0.0351 0.285 0.0579 0.028 0.0342+/-0.372+/-0.0503+/-0.625+/-0.137+/-0.123+/-0.101+/-0.136+/-0.092+/-0.128+/-0.0791+/-0.097+/-0.136+/-0.0478+/-0.0391+/-1.36+/-0.137+/-0.0328+/-0.0841 0.308 0.0945 0.621 0.125 0.108 0.0707 0.0629 0.167 0.231 0.143 0.0942 0.127 0.0819 0.0753 0.660 0.125 0.060 0.0735 0.015 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/02/06 1817 529776 1 BXFI 06/06/06 2315 535512 2 0.00327 +/-0.00761 0.00719 +/-0.00761 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 51 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-014F Project: YANK01204 Sample ID: 162485011 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 73 (25%-125o)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.52 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact:.
Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-016F 162485012 SE 02-MAY-06 09-MAY-06 Client 36.9%Project: Client ID: Vol. Recv.: YANKO 1204 YANKOO Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium-137 U Cobalt-60 U Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U C Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 0 0.892 0.036 0.921 0.623 0.00-0.0186 0.00207 0.011 0.0157 0.00321 1.03 0.733 0.0111.000839 17.2 0.623 0.00106 0.336+/-0.211+/-0.0698+/-0.305+/-0.110+/-0.032+/-0.0188+/-0.019+/-0.0492+/-0.0583+/-0.0586+/-0.099+/-0.119+/-0.0205+/-0.0174+/-1.29+/-0.110+/-0.0164+/-0.0543 0.0546 0.0577 0.118 0.0294 0.0203 0.014 0.0155 0.041 0.0481 0.0472 0.0244 0.0269 0.0175 0.0146 0.129 0.0294 0.0134 0.0152+/-0.211+/-0.0698+1-0.305+/-0.110+/-0.032+/-0.0188+/-0.019+/-0.0492+/-0.0583+/-0.0586+/-0.099+/-0.119+/-0.0205+/-0.0174+/-1.29+/-0.110+/-0.0164+/-0.0543 0.115 0.118 0.247 0.0612 0.0422 0.0294 0.033 0.0848 0.102 0.0967 0.0502 0.0559 0.0365 0.0305 0.279 0.0612 0.0278 0.0317 0.0168 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 06/02/06 1817 529776 1 BXFI 06/06/06 2316 535512 2'.000907 +/-0.00836 0.00805 +/-0.00836 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXM1 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 53 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-016F Project: YANK01204 Sample ID: 162485012 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 69 (25%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.54 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-015F 162485013 SE 03-MAY-06 09-MAY-06 Client 11.9%Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 0.779 Americium-241 U 0.0415 Bismuth-212 0.716 Bismuth-214 0.693 Cesium-134 UUI 0.00 Cesium-137 0.0709 Cobalt-60 U 0.00278 Europium-152 U -0.0239 Europium-154 U -0.0182 Europium-155 U 0.0206 Lead-212 0.762 Lead-214 0.764 Manganese-54 U -0.0066 Niobium-94 U -0.00534 Potassium-40 10.6 Radium-226 0.693 Silver-108m U 0.000726 Thallium-208 0.275 Rad Gas Flow Proportional Counting+/-0.111+/-0.0889+/-0.201+/-0.0601+/-0.0256+/-0.0212+/-0.0149+/-0.0383+/-0.0424+/-0.0452+/-0.0411+/-0.0661+/-0.0146+/-0.0121+/-0.537+/-0.0601+/-0.0125+/-0.0298 0.0398 0.0568 0.0882 0.0215 0.0163 0.0112 0.0126 0.0328 0.0343 0.0394 0.0201 0.0228 0.0123 0.0104 0.0994 0.0215 0.0108 0.0109+/-0.111+/-0.0889+/-0.201+/-0.0601+/-0.0256+/-0.0212+/-0.0149+/-0.0383+/-0.0424+/-0.0452+/-0.0411+/-0.0661+/-0.0146+/-0.0121+/-0.537+/-0.0601+/-0.0125+/-0.0298 0.0838 0.116 0.185 0.0448 0.0337 0.0234 0.0269 0.0677 0.0729 0.0803 0.0411 0.0471 0.0258 0.0218 0.215 0.0448 0.0224 0.0228 0.0141 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/04/06 2021 529776 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.00668 +/-0.00736 0.00679 +/-0.00736 BXF1 06/06/06 2316 535512 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 55 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-015F Proiect: YANKO 1204 Sample ID: 162485013 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 88 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.56 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-017F 162485014 SE 03-MAY-06 09-MAY-06 Client 16.1%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 1.34 +/-0.186 0.074 +/-0.123 0.895 +/-0.265 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 1.01 UUI 0.00 0.139 0.343 U -0.0397 U -0.0218 U 0.0712 1.60+/-0.0975+/-0.0273+/-0.0335+1-0.0511+/-0.0485+/-0.0616+/-0.0622+/-0.0709+/-0.094+/-0.0263+/-0.0185+/-0.878+/-0.0975+/-0.0168+/-0.0422 0.0567 0.0919 0.121 0.0317 0.0211 0.0184 0.0168 0.0403 0.049 0.0548 0.0252 0.0289 0.0165 0.0154 0.140 0.0317 0.0141 0.0162+/-0.186+/-0.123+/-0.265+/-0.0975+/-0.0273+/-0.0335+/-0.0511+/-0.0485+/-0.0616+/-0.0622+/-0.0709+/-0.094+/-0.0263+/-0.0185+/-0.878+/-0.0975+/-0.0168+/-0.0422 0.118 0.188 0.253 0.0656 0.0437 0.0381 0.0355 0.0832 0.103 0.112 0.0518 0.0597 0.0344 0.0319 0.299 0.0656 0.0292 0.0336 0.0173 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/07/06 0543 529776 1 BXF1 06/06/06 2316 535512 2 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U-C 1.29 0.0295 0.00962 22.8 1.01 0.00158 0.487 1.000859 +/-0.00856 0.00834 +/-0.00856 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 57 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-017F Project: YANK01204 Sample ID: 162485014 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 81 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.58 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-018F 162485015 SE 03-MAY-06 09-MAY-06 Client 17.6%Project: YANKO 1204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UUI Cesium-137 U Cobalt-60 U Europium-152 U Europium-154 U Europium-155 UUI Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 1.02-0.134 0.808 0.608 0.00 0.0339 0.0419-0.0249-0.0153 0.00 1.09 0.665 0.0255 0.0151 18.6 0.608 0.00395 0.381+/-0.245+/-0.127+/-0.337+/-0.117+/-0.0567+/-0.0308+/-0.0323+/-0.0653+/-0.0841+/-0.0972+/-0.121+/-0.127+/-0.0288+/-0.0247+/-1.71+/-0.117+/-0.0202+/-0.0688 0.0737 0.0923 0.155 0.038 0.0308 0.0238 0.0295 0.0503 0.0681 0.0544 0.0297 0.0364 0.0246 0.0209 0.203 0.038 0.0167 0.0206+/-0.245+/-0.127+/-0.337+/-0.117+/-0.0567+/-0.0308+/-0.0323+/-0.0653+/-0.08 41+/-0.0972+/-0.121+/-0.127+/-0.0288+/-0.0247+/-1.71+/-0.117+/-0.0202+/-0.0688 0.158 0.191 0.330 0.0803 0.0646 0.050 0.0631 0.105 0.147 0.112 0.0616 0.0762 0.0521 0.044 0.447 0.0803 0.0353 0.0436 0.023 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/06/062355 529776 1 BXFI 06/06/06 2316 535512 2 0.0537 +/-0.0144 0.011 +/-0.0145 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description 1 EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 59 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-018F Proiect: YANKO 1204 Sample ID: 162485015 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 49 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.60 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis... .... ... ...... A a vT --s Company -Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-018FS 162485016 SE 03-MAY-06 09-MAY-06 Client 24.2%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 U Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 UUI Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U-C Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U 1.15 0.0465 0.509 0.740 0.0988 0.105 0.00 0.0375-0.0127 0.0362 1.25 0.924 0.0155.000986 20.1 0.740 0.00684 0.389+/-0.407+/-0.0698+/-0.589+/-0.172+/-0.0652+/-0.0796+/-0.145+/-0.119+/-0.171+/-0.105+/-0.117+/-0.192+/-0.0534+/-0.0449+/-1.60+/-0.172+/-0.0501+/-0.104 0.148 0.0523 0.330 0.0759 0.0488 0.0395 0.0515 0.0988 0.122 0.0853 0.048 0.0659 0.0446 0.0372 0.375 0.0759 0.035 0.0401+/-0.407+/-0.0698+/-0.589+/-0.172+/-0.0652+/-0.0796+/-0.145+/-0.119+/-0.171+/-0.105+/-0.117+/-0.192+/-0.0534+/-0.0449+/- 1.60+/-0.172+/-0.0501+/-0.104 0.313 0.107 0.693 0.159 0.103 0.0829 0.109 0.205 0.260 0.175 0.0995 0.137 0.0936 0.078 0.812 0.159 0.0729 0.0839 0.0168 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 06/04/06 2022 529776 1 BXF1 06/06/06 2316 535512 2 0.00484 +/-0.00859 0.00803 +/-0.00859 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 3 EPA 905.0 Modified EPA 905.0 Modified 61 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-018FS Project: YANK01204 Sample ID: 162485016 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 69 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.62 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-005F 162485017 SE 02-MAY-06 09-MAY-06 Client 17.4%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 Curium-242 Curium-243/244 U -0.0415 U -0.00755 U 0.00112+/-0.0591+/-0.0634+/-0.0607 0.055 0.0358 0.0636+/-0.0591+/-0.0634+/-0.0607 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U Plutonium-239/240 U Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 UU1 Cesium-137 U -Cobalt-60 U I Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U 0.Niobium-94 U -Potassium-40 Radium-226 Silver-108m U -1 Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U I Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL F Tritium U Liquid Scint C14, SolidAll,FSS 0.0261 +/-0.0511 0.00 +/-0.0512 0.0459 +/-0.0733 0.0297 +/-0.0734-8.66 +/-8.72 7.70 +/-8.77+/-0.304+/-0.121+/-0.459+/-0.188+/-0.0421+/-0.0345+/-0.0303+/-0.0944+/-0.112+/-0.0964+/-0.170+/-0.181+/-0.0388+/-0.0275+/-1.29+/-0.188+/-0.0289+/-0.078 0.0844 0.0993 0.190 0.0487 0.0364 0.0274 0.0263 0.0728 0.0779 0.0839 0.0432 0.0528 0.029 0.0234 0.222 0.0487 0.0248 0.0254+/-0.304+/-0.121+/-0.459+/-0.188+/-0.0421+/-0.0345+/-0.0303+/-0.0944+/-0.112+/-0.0964+/-0.170+/-0.181+/-0.0388+/-0.0275+/-1.29+/-0.188+/-0.0289+/-0.078 0.185 0.157 0.203 0.0707 0.130 16.0 0.169 0.199 0.380 0.0974 0.0728 0.0547 0.0526 0.145 0.156 0.168 0.0864 0.106 0.0579 0.0467 0.443 0.0974 0.0495 0.0507 0.0172 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g LCW1 05/30/06 1156 533471 1 LCW1 05/30/06 2129 533472 2 LCW1 06/03/06 0541 533473 3 MJHI 06/02/06 1826 529776 4 BXF1 06/06/06 2316 535512 5 NXPI 05/28/06 0323 531705 7 0956 +/-0.00903 0.00831 +/-0.00904 3.49 +/-6.18 5.06 +/-6.18 10.5 pCi/g 63 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: 9106-0005-005F 162485017 Proiect: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Rad Liquid Scintillation Analysis Liquid Scint C14, SolidAllFSS Carbon- 14 U 0.048 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -5.82 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -2.31 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.298 Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.107 0.0885 +/-0.107 0.183+/-15.5 11.7 +1-15.5 24.6 pCi/g pCi/g ATH2 06/03/06 1732 534984 8 AFI 06/05/06 1626 535483 10 SLNI 05/26/06 2217 531622 12 SXEI 05/30/06 2126 531704 13+/-4.11 3.49 +/-4.11 7.11 pCi/g+/-0.271 0.218 +/-0.271 0.450 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021lB LXMI 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 EPA EERF C-01 Modified 10 DOE RESL Fe-I, Modified 11 DOE RESL Fe-1, Modified 12 DOE RESL Ni-I, Modified 13 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýRecovery%96 91 82 Acceptable Limits (15%-125%)
(15%-125%)
(25%- 125%)64 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-005F Project: YANKO 1204 Sample ID: 162485017 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 80 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 94 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 90 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 72 (15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.65 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Ce-rtifirnate nf Annivdi.Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-009F 162485018 SE 02-MAY-06 09-MAY-06 Client 14.4%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U Curium-242 U Curium-243/244 U Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -Plutonium-239/240 U Liquid Scint Pu241, Solid ALL FSS Plutonium-241 U Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS Actinium-228 Americium-241 U Bismuth-212 U Bismuth-214 Cesium-134 UUI Cesium- 137 Cobalt-60 U Europium-152 U Europium-154 U -Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U 0 Potassium-40 Radium-226 Silver-108m U 0 Thallium-208 Rad Gas Flow Proportional Counting 0.0451 0.0375 0.0173+/-0.104+/-0.0735+/-0.0689 0.0757 0.00 0.0537+/-0.104+/-0.0736+/-0.0689 0.0133 +/-0.0575 0.0447 +/-0.0575 0.0211 +/-0.0559 0.0316 +/-0.056-4.2 +/-9.77 8.38 +/-9.78 0.558 0.0512 0.288 0.541 0.00 0.181 0.0214 0.0156 0.0435 0.079 0.569 0.445 0.0259'.00303 10.5 0.541'.00846 0.156+/-0.165+/-0.0953+/-0.274+/-0.106+/-0.0381+/-0.0535+/-0.0242+/-0.0758+/-0.0786+/-0.116+/-0.0793+/-0.109+/-0.0233+/-0.0254+/-1.11+/-0.106+/-0.0219+/-0.058 0.0655 0.0797 0.224 0.0381 0.0252 0.0218 0.0239 0.0566 0.0615 0.0597 0.031 0.038 0.0226 0.0218 0.182 0.0381 0.0198 0.0188+/-0.165+/-0.0953+/-0.274+/-0.106+/-0.0381+/-0.0535+/-0.0242+/-0.0758+/-0.0786+/-0.116+/-0.0793+/-0.109+/-0.0233+/-0.0254+/-1. 11+/-0.106+/-0.0219+/-0.058 0.241 0.102 0.197 0.165 0.138 17.5 0.131 0.159 0.447 0.0762 0.0504 0.0435 0.0478 0.113 0.123 0.119 0.062 0.0759 0.0452 0.0435 0.364 0.0762 0.0396 0.0376 0.0152 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g LCWI 05/30/06 1156 533471 1 LCW1 05/30/06 2129 533472 2 LCWI 06/03/06 0557 533473 3 MJH1 06/02/06 1827 529776 4 BXF1 06/06/06 2316 535512 5 NXPI 05/28/06 0354 531705 7 GFPC, Sr90, solid-ALL FSS Strontium-90 U 0 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS 1.013 +/-0.00829 0.00722 +/-0.0083 6.86 +/-6.34 5.06 +/-6.34 10.5 pCi/g 66 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: June 8, 2006 Client Sample ID: Sample ID: 9106-0005-009F 162485018 Proiect: YANKO 1204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Liquid Scintillation Analysis Liquid Scint C14, SolidAlFSS Carbon-14 U C Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U -0 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U C.043 +/-0.0961 0.0793 +/-0.0961 0.164 35.7 1.25 +/-22.5 17.0 +/-22.5 pCi/g pCi/g pCi/g pCi/g ATH2 06/03/06 1934 534984 8 SLN1 05/29/06 1526 531618 10 SLNI 05/26/06 2318 531622 11 SXEI 05/30/062142 531704 12+/-4.99 4.21 +/-4.99 8.57.333 +/-0.298 0.239 +/-0.298 0.494 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Ash Soil Prep Ash Soil Prep, GL-RAD-A-021B LXM1 05/10/06 0855 528491 Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 05/09/06 1829 528487 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EML HASL 300, 4.5.2.3 5 EPA 905.0 Modified 6 EPA 905.0 Modified 7 EPA 906.0 Modified 8 EPA EERF C-01 Modified 9 EPA EERF C-0I Modified 10 DOE RESL Fe-I, Modified 11 DOE RESL Ni-l, Modified 12 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýGFPC, Sr90, solid-ALL FSS 87 85 77 71 (15%-125%)
(15%-125%)
(25%-I125%)
(25%-125%)
67 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: June 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-009F Project: YANKO 1204 Sample ID: 162485018 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 72 (15%- 125°%)Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 67 (25%6-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 65 (15%- 125%)Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.68
.1 QUALITY CONTROL DATA I 69 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Client : Connecticut Yankee Atomic Power 362 Injun Hollow Rd Renort Date: June 8, 2006 Page 1 of 9 East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder:
162485 Parmname NOM Sample Oual QC Units RPD%REC% Range AnIst Date Time Rad Alpha Spec Batch 533471 QC1201101118 Americium-241 Curium-242 Curium-243/244 QC1201101120 Americium-241 162485017 DUP U -0.0415 Uncert: +/-0.0591 TPU: +/-0.0591 U -0.00755 Uncert: +/-0.0634 TPU: +/-0.0634 U 0.00112 Uncert: +/-0.0607 TPU: +/-0.0607 LCS Curium-242 Curium-243/244 QCI201101117 Americium-241 Curium-242 Curium-243/244 QCI201101119 Americium-241 MB 12.2 Uncert: TPU: Uncert: TPU: 14.9 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: U -0.00249+/-0.0219+/-0.0219 U 0.0283+1-0.0555+/-0.0556 U 0.0131+/-0.0521+/-0.0521 10.8+/-0.975+/-1.73 U -0.0056+/-0.047+/-0.0471 12.4+/-1.04+/-1.95 U -0.00902+/-0.019+/-0.019 U 0.0399+/-0.0638+/-0.064 U 0.0392+/-0.0626+/-0.0628 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 89 (75%-125%)
05/30/06 11:55 pCi/g 177 pCi/g 346 pCi/g 168 (0% -100%) CWI (0% -100%)(0%- 100%)83 (75%-125%)
05/30/06 11:55 05/30/06 11:55 162485017 MS Curium-242 12.7 Uncert: TPU: Uncert: TPU: 15.5 Uncert: TPU: U -0.0415+/-0.0591+/-0.0591 U -0.00755+/-0.0634+/-0.0634 U 0.00112+/-0.0607+/-0.0607 U 12.5+/-1.06+/-1.96 0.00+/-0.0517+/-0.0517 12.6+/-1.06+/-1.98 98 (75%-125%)
05/30/06 11:55 Curium-243/244 81 (75%-125%)
Batch 533472 QC1201101122 162485017 DUP Plutonium-238 U 0.0261 U 0.00 pCi/g (0%- 100%) .CW1 05/30/06 21:29 70 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162485 Page 2 of 9 Parmname Rad Alpha Spec Batch 533472 NOM Sample Qual QC Units RPD%REC% Range Anist Date Time Plutonium-239/240 QC1201101124 LCS Plutonium-238 Plutonium-239/240 QC1201101121 MB Plutonium-238 Plutonium-239/240 QC1201101123 162485017 MS Plutonium-238 Uncert: +1-0.0511 TPU: +/-0.0512 U 0.0459 Uncert: +/-0.0733 TPU: +/-0.0734 Uncert: TPU: 11.3 Uncert: TPU: Uncert: TPU: Uncert: TPU: U 0.0261 Uncert: +1-0.0511 TPU: +/-0.0512 11.7 U 0.0459 Uncert: +/-0.0733 TPU: +/-0.0734 U -8.66 Uncert: +/-8.72 TPU: +/-8.77+/-0.0498+/-0.0498 U -0.00609+/-0.0511+/-0.0512 0.216+/-0.181+/-0.182 10.3+/-1.21+/-1.76 U -0.00623+/-0.0692+/-0.0693 U -0.0274+/-0.100+/-0.100 pCi/g 261 (0%- 100%)(75%-1 25%)pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 05/30/06 21:29 91 (75%-125%)
05/31/06 07:44 U 0.0634+/-0.0787+/-0.079 10.7+/-0.971+/-1.52 (75%-125%)
05/30/06 21:29 Plutonium-239/240 92 (75%-125%)
Batch 533473 QC1201101126 162485017 DUP Plutonium-24 I QC1201101128 LCS Plutonium-241 QC1201101125 MB Plutonium-241 QC1201101127 162485017 MS Plutonium-241 Rad Gamma Spec Batch 529776 QC1201092333 162485001 DUP Actinium-228 U-6.36+/-6.79+/-6.82 106+/-12.3+/-16.4 pCi/g 0 (0% -100%) LCWI 131 Uncert: TPU: Uncert: TPU: U -1.18+/-9.02+/-9.02 pCi/g pCi/g pCi/g 81 (75%-125%)
06/03/06 07:35 06/03/06 08:07 06/03/06 07:18 06/03/06 07:51 135 U Uncert: TPU:-8.66+/-8.72+/-8.77 146+/-14.7+/-20.1 108 (75%-125%)
1.69+/-0.251 Uncert: 1.64+/-0.254+/-0.254 pCi/g 7 (0%- 100%) MJHI 06/04/06 20:23 71 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162485 Page 3 of 9 Parmname Rad Gamma Spec Batch 529776 NOM Sample Qual OC Units RPD%REC% Range Anlst Date Time Americium-241 Bismuth-212 Bismuth-214 Cesium- 134 Cesium- 137 Cobalt-60 Europium-152 Europium-154 Europium-155 TPU: +/-0.251 U 0.064 U Uncert: +/-0.113 TPU: +/-0.113 0.887 Uncert: +/-0.313 TPU: +/-0.313 1.15 Uncert: +/-0.147 TPU: +/-0.147 UUI 0.00 UUI Uncert: +/-0.0385 TPU: +/-0.0385 U 0.0288 U Uncert: +/-0.0259 TPU: +/-0.0259 u 0.0191 U Uncert: +/-0.0235 TPU: +/-0.0235 u -0.0115 U Uncert: +/-0.0595 TPU: +/-0.0595 u -0.0146 U Uncert: +/-0.0717 TPU: +/-0.0717 U 0.0293 UUI Uncert: +/-0.0678 TPU: +/-0.0678 1.62 Uncert: +/-0.145 TPU: +/-0.145 1.36 Uncert: +/-0.154 TPU: +/-0.154 U 0.0112 U Uncert: +/-0.0236 TPU: +/-0.0236 U -0.00247 U Uncert: +/-0.0192 TPU: +/-0.0192 11.3 Uncert: +/-1.05 TPU: +/-1.05 1.15 Uncert: +/-0.147 TPU: +/-0.147 U -0.000679 U Uncert: +/-0.0191-0.0181+/-0.0823+/-0.0823 0.973+/-0.274+/-0.274 1.17+/-0.142+/-0.142 0.00+/-0.0358+/-0.0358 0.0105+/-0.0211+/-0.0211 0.00611+/-0.0196+/-0.0196-0.0143+/-0.0523+/-0.0523-0.0672+/-0.0591+/-0.0591 0.00+/-0.100+/-0.100 1.68+/-0.148+/-0.148 1.39+/-0.153+/-0.153 0.0321+/-0.0318+/-0.0318 0.0167+/-0.0171+/-0.0171 10.7+/-0.964+/-0.964 1.17+/-0.142+/-0.142 0.0103+/-0.017 pCi/g 137 pCi/g 21 pCi/g 4 Lead-212 Lead-214 pCi/g 25 pCi/g 78 pCi/g 18 pCi/g 1550 pCi/g 515 pCi/g 153 pCi/g 5 pCi/g 6 pCi/g 282 pCi/g 54 pCi/g 9 pCi/g 4 pCi/g 19 (0%- 100%)(0%- 100%)(0%- 20%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0% -20%)(0% -20%)(0%- 100%)(0%- 100%)(0%- 20%)(0%- 100%)(0%- 100%)Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver- 108m 72 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162485 Page 4 of 9 Parmname NOM Sample Qual OC Units RPD%REC% Range Anist Date Time Rad Gamma Spec Batch 529776 Thallium-208 TPU: +/-0.0191 0.495 Uncert: +/-0.0669 TPU: +/-0.0669+/-0.017 0.525+/-0.0635+/-0.0635 pCi/g 2 (0%- 20%)QC1201092334 Actinium-228 Americium-241 LCS Bismuth-212 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Uncert: TPU: 23.4 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: 9.64 Uncert: TPU: 15.1 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: U 0.508+/-0.559+/-0.559 21.0+/-3.45+/-3.45 U 0.361+/-1.07+/-1.07 U 0.102+/-0.286+/-0.286 U -0.0467+/-0.181+/-0.181 9.06+/-0.729+/-0.729 15.9+/-1.18+/-1.18 U -0.0491+/-0.335+/-0.335 U -0.249+/-0.328+/-0.328 U 0.077+/-0.360+/-0.360 U -0.0006 I+/-0.196+/-0.196 U 0.0856+/-0.227+/-0.227 U -0.0065+/-0.133+/-0.133 U 0.101+/-0.118+/-0.118 U 1.38 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 94 (75%-125%)
106 (75%-125%)
90 (75%-125%)
06/03/06 15:39 Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 73 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162485 Page 5 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 529776 Radium-226 Silver- 108m Thallium-208 QC1201092332 Actinium-228 Americium-241 MB Bismuth-212 Bismuth-214 Cesium- 134 Cesium- 137 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU:+/-1.23+/-1.23 U 0.102+/-0.286+/-0.286 U 0.0169+/-0.119+/-0.119 U 0.0217+/-0.131+/-0.131 U 0.0231+/-0.0503+/-0.0503 U -0.0485+/-0.0565+/-0.0565 U 0.100+/-0.114+/-0.114 U -0.00311+/-0.0254+/-0.0254 U 0.00344+/-0.0146+/-0.0146 U 0.0114+/-0.0135+/-0.0135 U 0.00208+/-0.0154+/-0.0154 U 0.0236+/-0.0367+/-0.0367 U -0.0158+/-0.0399+/-0.0399 U 0.00786+/-0.0328+/-0.0328 U 0.0278+/-0.0312+/-0.0312 U 0.0263+/-0.0251+/-0.0251 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pci/g 06/04/06 20:22 (75%-125%)
Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 74 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162485 Page 6 of 9 REC% Range Anist Date Time Parmname NOM Samole Oual QC Units RPD%Rad Gamma Spec Batch 529776 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver- 108m Thallium-208 Rad Gas Flow Batch Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: U 0.0016+/-0.015+1-0.015 U -0.000762+/-/-0.0129+/-0.0129 U 0.145+/-0.122+/-0.122 U -0.00311+/-0.0254+/-0.0254 U -0.00522+/-0.0117+/-0.0117 U 0.00116+/-0.0158+/-0.0158 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 535512 QC1201105910 162335018 DUP Strontium-90 QC1201105912 LCS Strontium-90 QC1201105909 MB Strontium-90 QC1201105911 162335018 MS Strontium-90 Rad Liquid Scintillation Batch 531618 QC1201096632 163173001 DUP Iron-55 QC1201096634 LCS Iron-55 QC1201096631 MB Iron-55 U 0.00669 Uncert: +/-0.00923 TPU: +/-0.00923 1.43 Uncert: TPU: Uncert: TPU: U 0.012+/-0.00902
+/-0.00902 1.19+/-0.081+/-0.0854 U 0.0107+/-0.00663
+/-0.00664 1.54+/-0.107+/-0.115 pCi/g 0 (0% -100%) BXFI pCi/g pCi/g pCi/g 83 (75%-125%)
06/06/06 23:16 06/07/06 10:08 06/06/06 23:16 06/07/06 10:08 1.54 U Uncert: TPU: 0.00669+/-0.00923
+/-0.00923 100 (75%-125%)
U 10.3 Uncert: +/-20.1 TPU: +/-20.1 437 Uncert: TPU: U 5.38+/-18.0+/-18.1 428+/-40.6+/-62.3 pCi/g 0 (0% -100%) SLNI pCi/g 98 (75%-125%)
05/31/06 12:49 05/31/06 13:22 05/31/06 12:32 U 3.58 pCi/g 75 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162485 Page 7 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Liquid Scintillation Batch 531618 Uncert: TPU: QC1201096633 163173001 MS Iron-55 569 U Uncert: TPU: 10.3+/-20.1+/-20.1 Batch 531622 QC1201096645 163173001 DUP Nickel-63 QC1201096647 LCS Nickel-63 QC1201096644 MB Nickel-63 QC1201096646 163173001 MS Nickel-63+/-24.7+/-24.7 544+/-39.3+/-69.3-5.49+/-4.33+/-4.33 301+/-7.49+/- 11.1 pCi/g 96 (75%-125%)
05/31/06 13:05 U -6.64 Uncert: +/-7.30 TPU: +/-7.31 U pCi/g 0 (0% -100%) SLNI 362 Uncert: TPU: Uncert: TPU: 460 U Uncert: TPU: U -1.66+/-3.41+/-3.41 pCi/g pCi/g pCi/g 83 (75%-125%)
05/28/06 01:38 05/28/06 03:40 05/28/06 00:37 05/28/06 02:39-6.64+/-7.30+/-7.31 Batch 531704 QC1201096868 162583001 DUP Technetium-99 QC1201096870 LCS Technetium-99 QC1201096867 MB Technetium-99 QC1201096869 162583001 MS Technetium-99 U 0.161 Uncert: +/-0.254 TPU: +/-0.255 U 395+/-9.22+/-14.9 0.239+/-0.273+/-0.273 11.1+/-0.474+/-0.545 86 (75%-125%)
pCi/g 0 (0% -100%) SXEI 12.5 Uncert: TPU: Uncert: TPU: 13.1 U Uncert: TPU: U 0.163+/-0.214+/-0.214 pCi/g pCi/g pCi/g 89 (75%-125%)
05/31/06 00:27 05/31/06 01:00 05/31/06 00:11 05/31/06 00:44 0.161+/-0.254+/-0.255 11.6+/-0.583+/-0.649 89 (75%-125%)
Batch 531705 QC1201096878 162583001 DUP Tritium QC1201096880 LCS Tritium U 1.17 Uncert: +/-4.09 TPU: +/-4.09 U 6.01+/-4.70+/-4.70 pCi/g 0 (0% -100%) NXPI 05/28/06 09:10 05/28/06 10:14 41.4 Uncert: TPU: 44.8+/-5.68+/-5.73 pCi/g 108 (75%-125%)
76 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www gel.com QC Summary Workorder:
162485 Page 8 of 9 Parmname NOM Sample Qual QC Units RPD%REC% Range Anist Date Time Rad Liquid Scintillation Batch 531705 QC1201096877 MB Tritium Uncert: TPU: U 0.0641+/-0.533+/-0.533 pCi/g pCi/g 06/03/06 05:11 05/28/06 09:42 QC1201096879 162583001 MS Tritium 45.7 U Uncert: TPU: 1.17+/-4.09+/-4.09 Batch 534984 QC0201104746 163173001 DUP Carbon- 14 QC1201104748 LCS Carbon- 14 QC1201104745 MB Carbon-14 QC1201104747 163173001 MS Carbon- 14 U 0.00714 Uncert: +/-0.0996 TPU: +/-0.0996 U 52.3+/-6.44+/-6.50 0.00246+/-0.103+/-0.103 11.3+/-0.855+/-0.873 pCi/g 0 114 (75%-125%)
(0%- 100%) ATH2 06/05/06 03:00 12.1 Uncert: TPU: Uncert: TPU: 12.9 U Uncert: TPU: U -0.0368+/-0.101+/-0.101 pCi/g pCi/g pCi/g 94 (75%-125%)
06/05/06 05:20 06/05/06 00:57 06/05/06 05:02 0.00714+/-0.0996+/-0.0996 Batch 535483 QC0201105873 162335018 DUP Iron-55 U -15.8 Uncert: +/-16.9 TP1J: +/-17.0 U 12.1+/-0.917+/-0.936 0.079+/-20.4+/-20.4 492+/-39.7+/-61.9 94 (75%-125%)
pCi/g 0 (0%-100%)
AFI QCI201105875 LCS Iron-55 QC1201105872 MB Iron-55 485 Uncert: TPU: Uncert: TPU: 655 U Uncert: TPU: U 5.04+/-22.8+/-22.8 pCi/g pCi/g pCi/g 101 (75%-125%)
06/05/06 17:00 06/05/06 17:33 06/05/06 16:43 06/05/06 17:16 QC1201105874 162335018 MS Iron-55-15.8+/-16.9+/-17.0 628+/-39.8+/-71.2 96 (75%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported 77 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
162485 Page 9 of 9 Parmname NOM Sample Qual QC Units RPD% REC% Range> Result is greater than value reported A The TIC is a suspected aldol-condensation product BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.** Indicates analyte is a surrogate compound.A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of-+/- the RL is used to evaluate the DUP result.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.Anlst Date Time 78 Table of Contents General Narrative
...................................................................
I Chain of Custody And Supporting Dpcumentation
...........
5 Radiological Analysis ...........................................................
12 Sample Data Summary .......................................................
18 Q uality C ontrol D ata ..........................................................
.60 General Narrative I.
CASE NARRATIVE For CONNECTICUT YANKEE RE: Soil PO# 002332 Work Order: 170256 SDG: MSR #06-1160 September 6, 2006 Laboratory Identification:
General Engineering Laboratories, LLC Mailing Address: P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address: 2040 Savage Road'Charleston, South Carolina 29407 Telephone Number: (843) 556-8171 Summary: Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC, (GEL)in Charleston, South Carolina on August 25, 2006. All sample containers arrived without any visible signs of tampering or breakage.
The chain of custody contained the proper documentation and signatures.
The laboratory received the following sample(s):
Sample ID Client Sample ID 170256001 9106-0006-005A 170256002 9106-0006-005B 170256003 9106-0006-005C 170256004 9106-0006-005D 170256005 9106-0005-0IOA 170256006 9106-0005-0IOB 170256007 9106-0005-OIOC 170256008 9106-0005-OIOD 170256009 9106-0014-033A GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.P.O. Box 30712 -Charleston, SC 29417 -2040 Savage Road (29407)Phone (843) 556-8171 ° Fax 243) 766-1178 -www.gel.com 170256010 9106-0014-033B 170256011 9106-0014-033C 170256012 9106-0014-033D 170256013 9106-0004-013A 170256014 9106-0004-013B 170256015 9106-0004-013C 170256016 9106-0004-013D 170256017 9106-0004-005A 170256018 9106-0004-005B 170256019 9106-0004-005C 170256020 9106-0004-005D Items of Note: There are no items of note.Case Narrative:
Sample analyses were conducted using methodology as outlined in General Engir eering Laboratories (GEL) Standard Operating Procedures.
Any technical or administrative problems during analysis, data review, and reduction are listed below by analyticail parameter.
Analytical Request: Twenty soil samples were analyzed for FSSGAM and Sr-90.Internal Chain of Custody: Custody was maintained for the sample(s).
Data Package: The enclosed data package contains the following sections:
Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.
I certify that this data package is in compliance with the SOW, both technically aid for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager orla designee, as verified by the following signature.
Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP INC. T P.O. Box 30712 -Charleston, SC 29417 -2040 Savage Road (29407)Phone (843) 556-8171 -Fax 43) 766-1178 -www.gel.com List of current GEL Certifications as of 06 September 2006 State Alaska Arizona Arkansas CLIA California
,-.Colorado
--Connecticut Dept. of Navy _EPA Florida/NELAP Georgia Idaho Illinois Indiana Kansas Kentucky Maryland Massachusetts
--Michigan Nevada New Jersey New York North Carolina North Carolina Drinking W North Dakota Oklahoma Pennsylvania Certification UST-062 AZO668 88-0651 42D0904046 0115 ICA GenEngLabs PH-0169-NFESC 413.W6-1J ..E87156 E87156 (FL1NELAP)
N/A 200029 C-SC-0I E-10332 90129 270 M-SCO12 SC-2-SC002 11501 233 45709 R-158 9904 68-48-5_~1 South Carolina 10120001/10585001/1 0120002 Tennessee
-02934 Texas TX213-2006A U.S. Dept. of Agriculture S-52597 US Army Corps of Engineer N/A Utah .. .-8037697376 GEL Vermont Virginia Washington N/A 00151 C223 4 Chain of Custody And Supporting Documentation 5
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00511 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 0 843 556 8171. Attn. Cheryl Jones cc Priority:
E] 30 D. 0 14 D. [] 7 D. Container I/Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comnment, Preservation Lab Sample ID 9106-0006-OOSA 8/8/06 14:35 SE C BP X X Transferred from COC # 2006-00488 9106-0006-005B 8/8/06 15:08 SE C BP X X Transferred from COC # 2006-00488 9106-0006-005C 8/9/06 07:46 SE C BP X X Transferred from COC # 2006-00307 9106-0006-005D 8/9/06 08:18 SE C BP X X Transferred from COC H 2006-00307 NOTES: PO#: 002332 MSR#: 06-11iO SSWP#NA SLTP QA El Radwaste QA 13 Non QA 1) Relinquished By Date/Time
- 2) Rec *ved By Date/Time 3) Relinquished By Date/Time
- 4) 4ceived By Samples Shipped Via:[ Fed Ex mUps[]Hand 13 Other Bill of Lading #V7-OO f 64 L Custody Sealed?YD- NO]Custody Seal Intact?YE NO Internal Container Temp.: ___ Deg. C V.Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major (1 Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00512 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddarn Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 , 843 556 8171. Attn. Cheryl Jones rA Priority:
[] 30 D. M 14 D. [] 7 D. Container Sample Size.Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0005-OIOA 8/9/06 09:03 SE C BP X X Transferred from COO # 2006-00489 9106-0005-0IOB 8/9/06 09:33 SE C BP X X Transferred from COC # 2006-00489 9106-0005-01OC 8/9/06 10:04 SE C BP X X Transferred from COC # 2006-00489 9106-0005-010D 8/9/06 10:56 SE C BP x x Transferred from COC # 2006-00489 NOTES: PO #: 002332 MSR #: 06- IlS0 SSWP# NA SLTP QA El Radwaste QA El Non QA 1) Relinquished By DatI/T ime of- Z4 4-0 1'71t34-0 2) ceivedB Samples Shipped Via:[ Fed Ex E] ups El Hand El Other Bill of Lading #ýqO 4 63 J Internal Container Temp.: __ Deg. C Custody Sealed?No Custody Seal Intact?YIJ NO D te/Time 3) Relinquished By Date/Time 49eceived By /DateTne Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-00 1 Major , Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00513 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones C n Priority:
E] 30 D. 0 14 D. Li 7 D. Container Sample Size-Media Type &Type Comment, Preservation Lab Sample ID Sample Designation Date Time Code Code Code , C 9106-0014-033A 8/11/06 07:58 SE C BP X X Transferred from COC # 2006-00493 39106-0014-033B 8/I 1/06 08:24 SE C BP X X Transferred from COC # 2006-00493 9106-0014-033C 8/11/06 08:45 SE C BP X x Transferred from COC # 2006-00493 9106-0014-033D 8/11/06 09:16 SE C BP X X Transferred from COC # 2006-00493 NOTES: PO #: 002332 MSR #: 06-1160 SSWP# NA SLTP QA[] Radwaste QA[] Non QA 1) Relinquished By Da~e/Time
- 2) ived By Date/Time 3) Relinquished By Date/Time
- 4) l ed DBy ate/Time Samples Shipped Via: Z Fed Ex El UPS Li Hand ...Li Other Bill of Lading #9?wo 40q Internal Container Temp.: _ Deg. C_Custody Sealed?YO NO Custody Seal Intact?Yo NO]
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00520 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-3924 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones r c C/Priority:
[] 30 D. 1Z 14 D. E] 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0004-013A 8/9/06 12:53 SE C BP X X Transferred from COC 2006-00490 9106-0004-013B 8/9/06 13:27 SE C BP X X Transferred from COC 2006-00490 "9106-0004-013C 8/9/06 13:57 SE C BP x x Transferred from COC 2006-00490 9106-0004-013D 8/9/06 14:28 SE C BP X X Transferred from COC 2006-00490 9106-0004-005A 8/9/06 14:58 SE C BP X X Transferred from COC 2006-0G490 91 06-0004-005B 8/10/06 07:41 SE C BP X X Transferred from COC 2006-00491 9106-0004-005C 8/10/06 08:09 SE C BP X X Transferred from COC 2006-00491 9106-0004-005D 8/10/06 08:49 SE C BP X X Transferred from COC 2006-00491 NOTES: PO #: 002332 MSR#: 06-1) C' SSWP# NA SLTP QA] Radwaste QA E Non QA l)-Relinquished By Date/,ime
- 2) Re ived By -Date/Time 3) Relinquished By Date/Time 4&ceived By Date/Time Samples Shipped Via: Z Fed Ex[3 UPS[] Hand LI Other Bill of Lading #7900 4 67 61444f Internal Container Temp.: _ Deg. C Custody Sealed?YVE N D Custody Seal Intact?YD NO Connecticut Yankee Statement of Work for Analytical Lab Services Figure 1. Sample Checkin List Date/Time Received: SDG#: Y 0 W Work Order Number:b, j.i j Shipping Cdatainer ID:7Y&D A43 4y Chain of Custody#I. Custody Seals. on shipping container intact?..2. Custody Seals dated and signed?3. Chain-of-Custody record present? ".4- Cooler temperature
- 5. Vermiculite/packing materials is: 6.' -Number of samples in shipping container:
AZ, 7. Sample holding times exceeded?-CY-isc-sow-001 CY-ISC-SOW-OOl
- Yes I.j1~o I(I Yes A' [IýYesJ-M [jb HýWet -'Yes 8. Samples have:'Sl.hazard labels_.:.:fwtody seals .appropriate Sample labels 9. Samples are-.'ood condition -leaking"broken .' have air bubbles H 10.11.Were any anomalies identified in sample receipt? , ' Yes [ ] No [-r, Description of anomalies (include sample numbers): Telephoned 10
-CY-ISC-SOW-001 Connecticut Yankee Statement of Work for Analytical Lab Services L L CY-ISC-SOW-OOl Figure 1. Sample Check-in List Date/Time Recved:.SDG#: I Work Order Nurnber: -Shipping Cdntainer ID: 0 I hi of Custody # Zetý 6 -taQ 1. Custody Seals od shipping container intact?. Yes t.-jr 1N 2. Custody Seals dated and signed? Yes -1,, 0o [" 3. Chain-of-Custody record present? Yes K,,N"o 4. Cooler temperature
,,2 5. Vermiculite/packing materials is: Wet ]6' Number of samples in shipping container:
_ _ _ __.7. Sample holding times exceeded?
Yes L.-]" 2 o [I]-8. Samples have:.-'.." hazard labels-6ustody seals -appropriate sample labels!I-I5 9. Samples are::. -in goqd condition&-e.Z roke -hav aibng* have air bubbles!10.11.I Were any anomalies identified "i sample receipt? Yes frNo i.Description ofanomalies, (include sample numbers): -.~ -O / .La y/"i, 11 RADIOLOGICAL ANALYSIS 12 Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)Work Order 170256 Method/Analysis Information Product: Analytical Method: Prep Method: Analytical Batch Number: Prep Batch Number: Sample ID 170256001 170256002 170256003 170256004 170256005 170256006 170256007 170256008 170256009 170256010 170256011 170256012 170256013 170256014 170256015 170256016 170256017 170256018 170256019 170256020 1201171525 1201171526 1201171527 Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived EML HASL 300, 4.5.2.3 Dry Soil Prep 563436 562444 Client ID 9106-0006-005A 9106-0006-005B 9106-0006-005C 9106-0006-005D 9106-0005-01OA 9106-0005-OIOB 9106-0005-OIOC 9106-0005-OIOD 9106-0014-033A 9106-0014-033B 9106-0014-033C 9106-0014-033D 9106-0004-013A 9106-0004-013B 9106-0004-013C 9106-0004-013D 9106-0004-005A 9106-0004-005B 9106-0004-005C 9106-0004-005D Method Blank (MB)170256001(9106-0006-005A)
Sample Duplicate (DUP)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this 13 narrative has been analyzed in accordance with GL-RAD-A-013 REV# 12.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (Q0 Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 170256001 (9106-0006-005A).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Samples 170256007 (9106-0005-010C), 170256016 (9106-0004-013D) and 170256019 (9106-0004-005C) were recounted due to high MDAs.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information 14 Qualifier UI UI Reason Data rejected due to high counting uncertainty Data rejected due to interference.
Data rejected due to low abundance.
U'Analyte Bismuth-212 Europium-155 Bismuth-214 Cesium- 134 Europium-155 Sample 170256009 170256003 170256009 170256019 170256020 170256008 170256005 170256007 170256008 170256012 170256013 170256019 1201171526 170256018 Method/Analysis Information Product: Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: GFPC, Sr90, solid-ALL FSS EPA 905.0 Modified Ash Soil Prep Dry Soil Prep 562563 562478 562444 15 Sample ID 170256001 170256002 170256003 170256004 170256005 170256006 170256007 170256008 170256009 170256010 170256011 170256012 170256013 170256014 170256015 170256016 170256017 170256018 170256019 170256020 1201169421 1201169422 1201169423 1201169424 Client ID 9106-0006-005A 9106-0006-005B 9106-0006-005C 9106-0006-005D 9106-0005-01OA 9106-0005-010B 9106-0005-OIOC 9106-0005-OIOD 9106-0014-033A 9106-0014-033B 9106-0014-033C 9106-0014-033D 9106-0004-013A 9106-0004-013B 9106-0004-013C 9106-0004-013D 9106-0004-005A 9106-0004-005B 9106-0004-005C 9106-0004-005D Method Blank (MB)170256002(9106-0006-005B)
Sample Duplicate (DUP)170256002(9106-0006-005B)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 170256002 (9106-0006-005B).
16 QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Samples were recounted due to low/high recovery.Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator.
In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.The following data validator verified the information presented in this case narrative:
Reviewer/Date: 6 17 SAMPLE DATA
SUMMARY
18 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co.Client SDG: MSR#06-1160 GEL Work Order: 170256 The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification ND The analyte concentration is not detected above the detection limit.The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures.
Please direct any questions to your Project Manager, Cheryl Jones.Reviewed by 19 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005A 170256001 SE 08-AUG-06 25-AUG-06 Client 15.8%Proiect: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.966 +/-0.192 Americium-241 U 0.0375 +/-0.0387 Bismuth-212 0.366 +/-0.306 Bismuth-214 0.650 +/-0.135 Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 U 0.0366 0.0666 0.104 U 0.00636 U -0.0788 U 0.0672 0.871+/-1-+1-+1-+1-+1-+1-+1-0.0355 0.0355 0.0726 0.0728 0.0938 0.0554 0.0971 0.0743 0.0329 0.175 0.042 0.0288 0.0236 0.0286 0.0538 0.0718 0.0518 0.0305 0.0379 0.0232 0.0223 0.201 0.042 0.018 0.0212+/-0.192+/-0.0387+/-0.306+/-0.135+1-0.0355+1-0.0355+/-0.0726+/-0.0728+/-0.0938+/-0.0554+/-0.0971+/-0.105+/-0.0319+/-0.0244+/-0.986+/-0.135+/-0.0208+/-0.0618 MDA 0.149 0.0658 0.350 0.0839 0.0576 0.0472 0.0573 0.108 0.143 0.104 0.061 0.0757 0.0465 0.0445 0.403 0.0839 0.036 0.0423 0.0298 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1057 563436 1 Units DF Analyst Date Time Batch Mtd Lead-214 0.727 Manganese-54 U -0.00916 Niobium-94 U 0.0101 Potassium-40 11.3 Radium-226 0.650 Silver-108m U -0.0067 Thallium-208 0.283 Rad Gas Flow Proportional Counting+/-0.105+/-0.0319+/-0.0244+/-0.986+/-0.135+/-0.0208+/-0.0618 GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.0254 +/-0.0193 0.0126 +/-0.0193 KSDI 09/07/06 1742 562563 2 The following Prep Methods were performed Method Description Dry Soil Prep Dry Soil Prep GL-RAD-A-021 Analyst Date Time Prep Batch LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 20 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0006-005A Project: YANK01204 Sample ID: 170256001 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 96 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.21 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005B 170256002 SE 08-AUG-06 25-AUG-06 Client 14.4%Project: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.606 Americium-241 U 0.101 Bismuth-212 0.685 Bismuth-214 Cesium-134 Cesium-137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m Thallium-208 0.435 U 0.0313 0.114 0.436 U -0.0448 U -0.0186 U 0.0423 0.643 0.462 U -0.0167 U 0.00909 11.1 0.435 U -0.00194 0.243+/-0.152+/-0.114+/-0.232+/-0.0852+/-0.0286+/-0.0348+/-0.0586+/-0.0525+/-0.0685+/-0.0579+/-0.0623+/-0.0885+/-0.0261+/-0.0195+/-0.983+/-0.0852+/-0.0168+/-0.0457 0.0599 0.0861 0.134 0.0332 0.0238 0.0206 0.0151 0.0416 0.0562 0.0552 0.0268 0.033 0.0174 0.0173 0.179 0.0332 0.0149 0.0176+/-0.152+/-0.114+/-0.232+/-0.0852+/-0.0286+/-0.0348+/-0.0586+/-0.0525+/-0.0685+/-0.0579+/-0.0623+/-0.0885+/-0.0261+/-0.0195+/-0.983+/-0.0852+/-0.0168+/-0.0457 0.131 0.179 0.290 0.0708 0.0507 0.0438 0.0345 0.0882 0.124 0.114 0.056 0.0696 0.0377 0.0369 0.399 0.0708 0.0317 0.0377 0.0278 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1220 563436 1 KSD1 09/07/06 1742 562563 2 Rad Gas Flow Proportional Counting GFPC, S90, solid-ALL FSS Strontium-90 U 0.00501 +/-0.0149 0.0117 +/-0.0149 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 The following Analytical Methods were performed Method Description LXM2 08/27/06 1545 562444 1 2 EML HASL 300, 4.5.2.3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 22 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0006-005B Proiect: YANKO 1204 Sample ID: 170256002 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 101 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.23 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005C 170256003 SE 09-AUG-06 25-AUG-06 Client 31.7%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.07 Americium-241 U 0.0251 Bismuth-212 0.684 Bismuth-214 0.673 Cesium-134 U 0.0516 -Cesium-137 0.317 Cobalt-60 0.821 -Europium-152 U -0.049 -Europium-154 U 0.0883 -Europium-155 UI 0.00 -Lead-212 1.01 -Lead-214 0.828 Manganese-54 U -0.0228 Niobium-94 U -0.0353 Potassium-40 12.4 Radium-226 0.673 Silver-108m U 0.00475 Thallium-208 0.382 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.00738+/-0.284+/-0.0367+/-/-0.424+/-0.121+/-0.0548+/-0.0544+/-0.09l I+/-0.0652+/-0.0913 F/-0.0926ý/-0.08 19+/-0.117ý/-0.0296ý/-0.0279+1-1.15+/-0.121 F/-0.0263 F/-0.0567 0.101 0.0332 0.178 0.0445 0.0344 0.0247 0.0294 0.0539 0.0839 0.0506 0.0329 0.0423 0.0238 0.0205 0.189 0.0445 0.0227 0.0242+/-0.284+/-0.0367+/-0.424+/-0.121+/-0.0548+/-0.0544+/-0.0911+/-0.0652+/-0.0913+/-0.0926+/-0.0819+/-0.117+/-0.0296+/-0.0279+1-1.15+/-0.121+/-0.0263+/-0.0567 0.215 0.0683 0.383 0.0947 0.0729 0.0528 0.064 0.114 0.182 0.105 0.0685 0.089 0.0513 0.044 0.431 0.0947 0.0477 0.0515 0.0255 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/01/06 1221 563436 1 KSDI 09/07/06 1745 562563 2+/-0.0142 0.0107 +/-0.0142 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 24 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: 9106-0006-005C 170256003 Project: YANKO 1204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Carrier/Tracer Recovery Recovery%
Acceptable Limits GFPC, Sr90, solid-ALL FSS 104 (25%- 125%)Notes: The Qualifiers in this report are defined as follows*A B BD A quality control analyte recovery is outside of specified acceptance criteria Result is less than value reported Result is greater than value reported The TIC is a suspected aldol-condensation product Target analyte was detected in the associated blank Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.25 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Project: YANK01204 Client ID: YANKOO Vol. Recv.: Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005D 170256004 SE 09-AUG-06 25-AUG-06 Client 28.2%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.01 +/-0.197 Americium-241 U 0.0605 +/-0.132 Bismuth-212 0.534 +/-0.328 Bismuth-214 0.594 +/-0.105 Cesium-134 U 0.0478 +/-0.046 Cesium-137 0.103 +/-0.0401 Cobalt-60 0.148 +/-0.0644 Europium-152 U 0.00143 +/-0.0589 Europium-154 U 0.0154 +/-0.0766 Europium-155 U 0.0625 +/-0.0643 Lead-212 0.900 +/-0.0831 Lead-214 0.854 +/-0.106 Manganese-54 U -0.013 +/-0.0244 Niobium-94 U 0.0144 +/-0.022 Potassium-40 11.6 +/-0.886 Radium-226 0.594 +1-0.105 Silver-108m U 0.0118 +/-0.0187 Thallium-208 0.310 +/-0.0591 Rad Gas Flow Proportional Counting 0.0659 0.088 0.168 0.0384 0.0253 0.0181 0.0204 0.0517 0.0653 0.0586 0.0345 0.0372 0.0203 0.0192 0.177 0.0384 0.0169 0.0199+/-0.197+/-0.132+/-0.328+/-0.105+/-0.046+/-0.0401+/-0.0644+/-0.0589+/-0.0766+/-0.0643+/-0.0831+/-0.106+/-0.0244+/-0.022+/-0.886+/-0.105+/-0.0187+/-0.0591 0.143 0.182 0.358 0.0813 0.0537 0.0389 0.045 0.109 0.142 0.121 0.0714 0.078 0.0434 0.0408 0.396 0.0813 0.0357 0.0422 0.0376 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/01/06 1221 563436 1 GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.000446 +/-0.0198 0.0166 +/-0.0198 KSDI 09/07/06 1740 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 26 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0006-005D Project: YANK01204 Sample ID: 170256004 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 50 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.27 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-010A 170256005 SE 09-AUG-06 25-AUG-06 Client 60.7%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.22 +/-0.394 Americium-241 U 0.0503 +/-0.0522 Bismuth-212 0.628 +/-0.547 Bismuth-214 0.834 +/-0.160 Cesium-134 UI 0.00 +/-0.0832 Cesium-137 U 0.0463 +/-0.0542 Cobalt-60 U 0.077 +/-0.0516 Europium-152 U 0.00822 +/-0.0958 Europium-154 U-0.000512
+/-0.129 Europium-155 U 0.0659 +/-0.115 Lead-212 0.933 +/-0.111 Lead-214 0.787 +/-0.146 Manganese-54 U -0.0199 +/-0.0442 Niobium-94 U -0.0359 +/-0.0364 Potassium-40 20.0 +/-1.50 Radium-226 0.834 +/-0.160 Silver-108m U -0.00415 +/-0.0338 Thallium-208 0.347 +/-0.0918 Rad Gas Flow Proportional Counting 0.120 0.0424 0.277 0.0633 0.0429 0.0333 0.0472 0.0766 0.0917 0.0674 0.0593 0.0602 0.0342 0.0275 0.288 0.0633 0.0282 0.0332+/-0.394+/-0.0522+/-0.547+/-0.160+/-0.0832+/-0.0542+/-0.0516+/-0.0958+/-0.129+/-0.115+/-0.111+/-0.146+/-0.0442+/-0.0364+/-1.50+/-0.160+/-0.0338+/-0.0918 0.255 0.0872 0.584 0.133 0.0903 0.0703 0.100 0.160 0.199 0.139 0.122 0.125 0.0725 0.0583 0.634 0.133 0.0591 0.0698 0.0274 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1I 09/01/06 1221 563436 1 KSDI 09/07/06 1745 562563 2 GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.00442 +/-0.0146 0.0116 +/-0.0146 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 28 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010A Proiect: YANKO 1204 Sample ID: 170256005 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 103 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.29 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-0IOB 170256006 SE 09-AUG-06 25-AUG-06 Client 61.3%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANKOO0 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.10 +/-0.245 Americium-241 U -0.00576 +/-0.0366 Bismuth-212 0.760 +/-0.351 Bismuth-214 0.576 +/-0.139 Cesium-134 U 0.0332 +/-0.0438 Cesium-137 0.0908 +/-0.0468 Cobalt-60 0.115 +/-0.0522 Europium-152 U 0.00833 +/-0.068 Europium-154 U -0.0828 +/-0.106 Europium-155 U 0.0871 +/-0.0591 Lead-212 1.08 +/-0.0778 Lead-214 0.812 +/-0.0928 Manganese-54 U 0.0145 +/-0.0313 Niobium-94 U 0.00876 +/-0.0271 Potassium-40 19.3 +/-1.35 Radium-226 0.576 +/-0.139 Silver-108m U -0.00887 +/-0.0232 Thallium-208 0.282 +/-0.0641 Rad Gas Flow Proportional Counting 0.0778 0.0263 0.189 0.0442 0.0314 0.0231 0.0225 0.0546 0.0808 0.0504 0.0306 0.0385 0.0262 0.0226 0.236 0.0442 0.0191 0.0224+/-0.245+/-0.0366+/-0.351+/-0.139+/-0.0438+/-0.0468+/-0.0522+/-0.068+/-0.106+/-0.0591+/-0.0778+/-0.0928+/-0.0313+/-0.0271+/- 1.35+/-0.139+/-0.0232+/-0.0641 0.168 0.0543 0.402 0.0936 0.0665 0.0493 0.0499 0.115 0.175 0.104 0.0636 0.081 0.0557 0.0479 0.521 0.0936 0.0403 0.0475 0.0368 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1221 563436 1 GFPC, SO9O, solid-ALL FSS Strontium-90 U -0.00561 +/-0.0185 0.0162 +/-0.0185 KSDI 09/07/06 1746 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 30 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010B Proiect: YANK01204 Sample ID: 170256006 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 89 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.31 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-010C 170256007 SE 09-AUG-06 25-AUG-06 Client 49.2%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GainmaSolid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.05 +/-0.196 Americium-241 U 0.00111 +/-0.108 Bismuth-212 0.539 +/-0.392 Bismuth-214 0.626 +/-0.101 Cesium-134 UI 0.00 +/-0.0318 Cesium- 137 0.192 +/-0.0408 Cobalt-60 0.522 +/-0.0639 Europium-152 U -0.0379 +/-0.0596 Europium-154 U -0.0318 +/-0.0732 Europium-155 U 0.0641 +/-0.0925 Lead-212 1.14 +/-0.0696 Lead-214 0.753 +/-0.0911 Manganese-54 U 0.0134 +/-0.0217 Niobium-94 U 0.0073 +/-0.0216 Potassium-40 17.9 +/-1.02 Radium-226 0.626 +/-0.101 Silver-108m U 0.00496 +/-0.0191 Thallium-208 0.354 +/-0.0504 Rad Gas Flow Proportional Counting 0.0698 0.0862 0.142 0.0371 0.025 0.0197 0.0211 0.0464 0.0585 0.0488 0.0264 0.0337 0.0193 0.0181 0.190 0.0371 0.0165 0.0183+/-0.196+/-0.108+/-0.392+/-0.101+/-0.0318+/-0.0408+/-0.0639+/-0.0596+/-0.0732+/-0.0925+/-0.0696+/-0.0911+/-0.0217+/-0.0216+/-1.02+/-0.101+/-0.0191+/-0.0504 0.148 0.177 0.300 0.0775 0.0524 0.0414 0.0453 0.0966 0.126 0.100 0.0544 0.070 0.0408 0.038 0.412 0.0775 0.0344 0.0384 0.027 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/05/06 2124 563436 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.00471 +/-0.0144 0.0114 +/-0.0145 KSDI 09/07/06 1758 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 32 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010C Proiect: YANKO 1204 Sample ID: 170256007 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, SrO0, solid-ALL FSS 101 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.33 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-OIOD 170256008 SE 09-AUG-06 25-AUG-06 Client 58.1%Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamnnia,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.920 +/-0.431 Americium-241 U 0.159 +/-0.0868 Bismuth-212 0.975 +/-0.615 Bismuth-214 U! 0.00 +/-0.170 Cesium-134 UI 0.00 +/-0.0619 Cesium- 137 0.630 +1-0.105 Cobalt-60 2.24 +/-0.161 Europium-152 U 0.0801 +/-0.100 Europium-154 U 0.159 +/-0.180 Europium-155 U 0.0923 +/-0.117 Lead-212 1.10 +/-0.108 Lead-214 0.707 +/-0.194 Manganese-54 U 0.0291 +1-0.050 Niobium-94 U 0.0114 +/-0.0446 Potassium-40 16.4 +/-1.57 Radium-226 0.761 +/-0.170 Silver-108m U 0.00643 +/-0.0377 Thallium-208 0.396 +/-0.103 Rad Gas Flow Proportional Counting 0.163 0.0423 0.310 0.126 0.0563 0.037 0.0361 0.0874 0.124 0.0649 0.0414 0.0578 0.0419 0.0367 0.341 0.0744 0.0316 0.0362+/-0.431+/-0.0868+/-0.615+/-0.170+/-0.0619+/-0.105+/-0.161+/-0.100+/-0.180+/-0.117+/-0.108+/-0.194+1-0.050+/-0.0446+/-1.57+/-0.170+/-0.0377+/-0.103 0.345 0.0871 0.654 0.259 0.118 0.0784 0.0793 0.182 0.267 0.134 0.086 0.121 0.0886 0.0774 0.753 0.156 0.0662 0.0763 0.0315 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1222 563436 1 GFPC, SO9O, solid-ALL FSS Strontium-90 U 0.0219 +/-0.0196 0.0135 +/-0.0196 KSDI 09/07/06 1805 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description.
I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 34 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010D Project: YANK01204 Sample ID: 170256008 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 97 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.35 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0014-033A 170256009 SE 1 I-AUG-06 25-AUG-06 Client 26.2%Proiect: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.28 +/-0.272 Americium-241 U 0.0199 +/-0.0632 Bismuth-212 UI 0.00 +/-0.484 Bismuth-214 0.920 +/-0.139 Cesium-134 U 0.0188 +/-0.0338 Cesium-137 0.709 +/-0.0983 Cobalt-60 0.697 +/-0.0935 Europium-152 U -0.0119 +/-0.0643 Europium-154 U 0.0763 +/-0.0741 Europium-155 UI 0.00 +/-0.0951 Lead-212 1.13 +/-0.134 Lead-214 1.04 +/-0.151 Manganese-54 U -0.0049 +/-0.0275 Niobium-94 U 0.014 +/-0.0236 Potassium-40 14.3 +/-1.30 Radium-226 0.920 +/-0.139 Silver-108m U3.080E-05
+/-0.0263 Thallium-208 0.405 +/-0.066 Rad Gas Flow Proportional Counting 0.0796 0.0541 0.171 0.0421 0.0298 0.0246 0.0267 0.0538 0.0675 0.052 0.0457 0.0416 0.023 0.0211 0.185 0.0421 0.0202 0.0235+/-0.272+/-0.0632+/-0.484+/-0.139+/-0.0338+/-0.0983+/-0.0935+/-0.0643+/-0.0741+/-0.0951+/-0.134+1-0.151+/-0.0275+/-0.0236+/-1.30+/-0.139+/-0.0263+/-0.066 0.171 0.112 0.363 0.089 0.0628 0.0519 0.0577 0.113 0.147 0.108 0.0938 0.0871 0.049 0.0446 0.412 0.089 0.0424 0.0495 0.0291 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/01/06 1223 563436 1 GFPC, Sr90, solid-ALL FSS Strontium-90 0.0366 +/-0.0205 0.0124 +/-0.0205 KSDI 09/07/06 1807 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 36 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis.Company:
Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0014-033A Project: YANKO 1204 Sample ID: 170256009 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr9O, solid-ALL FSS 99 (25%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria.< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.37 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis..... i Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0014-033B 170256010 SE 11-AUG-06 25-AUG-06 Client 16.3%Proiect: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamnma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 Americium-241 U Bismuth-212 Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, SrOO, solid-ALL FSS Strontium-90 U 1.03 0.037 0.897 0.681 0.062 0.862 0.944 0.00733 0.00812 0.0592 0.896 0.773-0.0465 0.00334 11.6 0.681 0.00313 0.278+/-0.272+/-0.0519+/-0.563+/-0.143+/-0.0748+/-0.117+/-0.113+/-0.118+/-0.115+/-0.0677+/-0.109+/-0.141+/-0.0487+/-0.0333+/-1.25+/-0.143+/-0.0324+/-0.0682 0.113 0.0353 0.237 0.057 0.0371 0.0301 0.0281 0.0695 0.0959 0.0595 0.0377 0.0491 0.032 0.029 0.247 0.057 0.0274 0.0296+/-0.272+/-0.0519+/-0.563+/-0.143+/-0.0748+/-0.117+/-0.113+/-0.118+/-0.115+/-0.0677+/-0.109+/-0.141+/-0.0487+/-0.0333+/-1.25+/-0.143+/-0.0324+/-0.0682 0.225 0.0705 0.473 0.114 0.0742 0.0601 0.0562 0.139 0.192 0.119 0.0754 0.0981 0.0639 0.0579 0.494 0.114 0.0548 0.0592 0.0268 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1559 563436 1 KSD1 09/07/06 1807 562563 2 0.00794 +/-0.015 0.0113 +/-0.015 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description 1 EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 38 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0014-033B Project: YANKO 1204 Sample ID: 170256010 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 103 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.39 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: 9106-0014-033C Project: YANK01204 Sample ID: 170256011 Client ID: YANK001 Matrix: SE Vol. Recv.: Collect Date: 1 I-AUG-06 Receive Date: 25-AUG-06 Collector:
Client Moisture:
14.2%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma, Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.841 Americium-241 U 0.028 Bismuth-212 0.476 Bismuth-214 0.628 Cesium-134 U 0.0398 Cesium-137 0.609 Cobalt-60 0.916 Europium-152 U -0.0803 Europium-154 U -0.0175 Europium-155 U 0.0335 Lead-212 0.710 Lead-214 0.810 Manganese-54 U -0.0149 Niobium-94 U -0.00772 Potassium-40 11.0 Radium-226 0.628 Silver-108m U 0.0295 Thallium-208 0.237 Rad Gas Flow Proportional Counting GFPC, SO9O, solid-ALL FSS Strontium-90 U -0.0326+/-0.277+/-0.048+/-0.345+/-0.128+/-0.0385+/-0.0698+/-0.0989+/-0.0732+/-0.0895+/-0.0642+/-0.0819+/-0.110+/-0.0338+/-0.0304+/- 1.00+/-0.128+/-0.0254+/-0.0761 0.100 0.0331 0.223 0.0439 0.0344 0.0277 0.0255 0.0581 0.0738 0.0553 0.0392 0.0428 0.0272 0.0254 0.220 0.0439 0.0239 0.0244+/-0.277+/-0.048+/-0.345+/-0.128+/-0.0385+/-0.0698+/-0.0989+/-0.0732+/-0.0895+/-0.0642+/-0.0819+/-0.110+/-0.0338+/-0.0304+/- 1.00+/-0.128+/-0.0254+/-0.0761 0.212 0.068 0.468 0.0928 0.0721 0.0581 0.0552 0.121 0.159 0.114 0.0808 0.0895 0.0575 0.0533 0.484 0.0928 0.0499 0.0513 0.0359 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1829 563436 1 KSD1 09/07/06 1842 562563 2+/-0.013 0.0158 +/-0.013 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 40 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0014-033C Project: YANK01204 Sample ID: 170256011 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 90 (25%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.Ut Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.41 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0014-033D 170256012 SE 1 I-AUG-06 25-AUG-06 Client 11.9%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.800 +/-0.169 Americium-241 U -0.00757 +/-0.0849 Bismuth-212 0.514 +/-0.239 Bismuth-214 0.496 +/-0.079 Cesium-134 UI 0.00 +/-0.0333 Cesium- 137 0.240 +/-0.0466 Cobalt-60 0.329 +/-0.0616 Europium-152 U -0.0221 +/-0.047 Europium-154 U -0.0277 +/-0.0651 Europium-155 U 0.0409 +1-0.050 Lead-212 0.618 +/-0.0549 Lead-214 0.582 +/-0.0773 Manganese-54 U 0.0209 +/-0.0191 Niobium-94 U 0.0124 +/-0.0174 Potassium-40 10.8 +/-0.796 Radium-226 0.496 +/-0.079 Silver-108m U -0.00363 +/-0.0168 Thallium-208 0.222 +/-0.040 Rad Gas Flow Proportional Counting 0.0584 0.0733 0.125 0.0289 0.0215 0.0172 0.0159 0.0418 0.0444 0.0464 0.0246 0.0304 0.0165 0.0157 0.144 0.0289 0.0148 0.0156+/-0.169+/-0.0849+/-0.239+/-0.079+/-0.0333+/-0.0466+/-0.0616+/-0.047+/-0.0651+1-0.050+/-0.0549+/-0.0773+/-0.0191+/-0.0174+/-0.796+/-0.079+/-0.0168+/-0.040 0.125 0.151 0.265 0.0614 0.0454 0.0365 0.0349 0.0875 0.0974 0.0959 0.0511 0.0635 0.0352 0.0331 0.320 0.0614 0.0312 0.033 0.0276 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/05/06 0531 563436 1 KSDI 09/07/06 1842 562563 2 GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.020 +/-0.0174 0.0117 +/-0.0174 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 42 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0014-033D Project: YANK01204 Sample ID: 170256012 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 103 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.43 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-013A 170256013 SE 09-AUG-06 25-AUG-06 Client 17.1%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.15 +/-0.162 Americium-241 U 0.0596 +/-0.0865 Bismuth-212 0.731 +/-0.295 Bismuth-214 0.959 +/-0.0845 Cesium-134 UI 0.00 +/-0.0287 Cesium-137 U -0.00113 +/-0.0196 Cobalt-60 U -0.00569 +/-0.0174 Europium-152 U -0.0275 +/-0.0539 Europium-154 U -0.0292 +/-0.0495 Europium-155 U 0.0375 +/-0.0594 Lead-212 1.19 +/-0.0671 Lead-214 1.08 +/-0.090 Manganese-54 U 0.0199 +/-0.0202 Niobium-94 U -6.020E- +/-0.0164 05 Potassium-40 14.3 +/-0.771 Radium-226 0.959 +/-0.0845 Silver-108m U -0.00566 +/-0.0152 Thallium-208 0.423 +/-0.0539 Rad Gas Flow Proportional Counting 0.0511 0.0665 0.115 0.0284 0.0195 0.0162 0.0139 0.0402 0.0385 0.0534 0.0261 0.0305 0.0165 0.0143 0.130 0.0284 0.0128 0.0142+/-0.162+/-0.0865+/-0.295+/-0.0845+/-0.0287+/-0.0196+/-0.0174+/-0.0539+/-0.0495+/-0.0594+/-0.0671+/-0.090+/-0.0202+/-0.0164+/-0.771+/-0.0845+/-0.0152+/-0.0539 0.109 0.136 0.242 0.0597 0.041 0.034 0.0301 0.0837 0.0835 0.110 0.0537 0.0634 0.0347 0.030 0.283 0.0597 0.0268 0.030 0.0304 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/06 1830 563436 GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.00331 +/-0.0151 0.0131 +/-0.0151 KSDI 09/07/06 1842 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified 44 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013A Project: YANKO 1204 Sample ID: 170256013 Client ID: YANK001 Vol. Recv,: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrierf[racer Recovery GFPC, Sr90, solid-ALL FSS 101 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.45 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-013B 170256014 SE 09-AUG-06 25-AUG-06 Client 19.6%Project: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.23 +/-0.302 Americium-241 U 0.0581 +/-0.0456 Bismuth-212 0.606 +/-0.361 Bismuth-214 0.990 +/-0.154 Cesium-134 U 0.0447 +/-0.0383 Cesium- 137 0.0831 +/-0.037 Cobalt-60 0.196 +/-0.0645 Europium-152 U 0.0248 +/-0.116 Europium-154 U 0.0401 +/-0.106 Europium-155 U 0.067 +/-0.0826 Lead-212 1.32 +/-0.136 Lead-214 0.989 +/-0.153 Manganese-54 U -0.00696 +/-0.0306 Niobium-94 U 0.00306 +/-0.0256 Potassium-40 9.89 +/-0.996 Radium-226 0.990 +/-0.154 Silver-108m U -0.017 +/-0.0253 Thallium-208 0.456 +/-0.084 Rad Gas Flow Proportional Counting 0.0948 0.0383 0.199 0.046 0.033 0.0286 0.0258 0.061 0.0809 0.0584 0.0337 0.0431 0.0262 0.0228 0.207 0.046 0.0211 0.0253+/-0.302+/-0.0456+/-0.361+/-0.154+/-0.0383+/-0.037+/-0.0645+/-0.116+/-0.106+/-0.0826+/-0.136+/-0.153+/-0.0306+/-0.0256+/-0.996+/-0.154+/-0.0253+/-0.084 0.190 0.0765 0.399 0.0919 0.066 0.0571 0.0515 0.122 0.162 0.117 0.0674 0.0862 0.0523 0.0455 0.414 0.0919 0.0422 0.0505 0.0316 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHl 09/01/062110 563436 1 GFPC, SO9O, solid-ALL FSS Strontium-90 U 0.00221 +/-0.0172 0.0143 +/-0.0172 KSD1 09/07/06 1843 562563 2 The following Prep Methodswere performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 46 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013B Project: YANK01204 Sample ID: 170256014 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 103 (25%-0125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.47 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-01 3C 170256015 SE 09-AUG-06 25-AUG-06 Client 17.3%Project: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.07 Americium-241 U -0.00337 Bismuth-212 0.808 Bismuth-214 0.614 Cesium-134 U 0.0481 Cesium-137 0.0789 Cobalt-60 0.074 Europium-152 U -0.0203 Europium-154 U -0.0129 Europium-155 U 0.0479 Lead-212 0.903 Lead-214 0.651 Manganese-54 U -0.0163 Niobium-94 U -0.022 Potassium-40 12.9 Radium-226 0.614 Silver-108m U 0.00256 Thallium-208 0.248 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U -0.00157+/-0.236+/-0.0367+/-0.311+/-0.118+/-0.0502+/-0.0569+/-0.0564+/-0.0622+/-0.0828+/-0.0527+/-0.0714+/-0.103+/-0.0298+/-0.0284+/-1.11+/-0.118+/-0.0199+/-0.0569 0.0703 0.034 0.157 0.0422 0.033 0.0226 0.0239 0.0547 0.0688 0.0529 0.0332 0.0431 0.0235 0.0226 0.250 0.0422 0.0177 0.0239+/-0.236+/-0.0367+/-0.311+/-0.118+/-0.0502+/-0.0569+/-0.0564+/-0.0622+/-0.0828+/-0.0527+/-0.0714+/-0.103+/-0.0298+/-0.0284+/-1.11+/-0.118+/-0.0199+/-0.0569 0.154 0.0701 0.341 0.0899 0.0699 0.0484 0.0531 0.115 0.152 0.109 0.069 0.0904 0.0506 0.0481 0.553 0.0899 0.0378 0.0508 0.0289 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/01/062118 563436 1 KSDI 09/07/06 1845 562563 2+/-0.0143 0.0123 +/-0.0143 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 48 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013C Project: YANK01204 Sample ID: 170256015 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 98 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.U! Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.49 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Qualifier Result Uncertainty 9106-0004-013D 170256016 SE 09-AUG-06 25-AUG-06 Client 25.9%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 1.03 Americium-241 U 0.0216 Bismuth-212 0.420 Bismuth-214 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U Potassium-40 Radium-226 Silver-108m U -Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid ALL FSS Strontium-90 U 0.689 0.0488 0.170 0.566 0.0265 0.0628 0.0541 0.958 0.784 0.00917 0.0056 12.6 0.689 0.00656 0.314+/-0.160+/-0.0981+/-0.350+/-0.0898+/-0.0307+/-0.0491+/-0.0694+/-0.0524+/-0.0639+/-0.0561+/-0.0653+/-0.0896+/-0.0221+/-0.019+/-0.931+/-0.0898+/-0.0175+/-0.0426 0.0664 0.0845 0.142 0.0339 0.0247 0.019 0.0198 0.0453 0.0591 0.0528 0.0265 0.0297 0.019 0.0164 0.166 0.0339 0.0151 0.0189+/-0.160+/-0.0981+1-0.350+/-0.0898+/-0.0307+/-0.0491+/-0.0694+/-0.0524+/-0.0639+/-0.0561+/-0.0653+/-0.0896+/-0.0221+/-0.019+/-0.931+/-0.0898+/-0.0175+/-0.0426 0.142 0.174 0.301 0.0715 0.0519 0.0402 0.0431 0.0946 0.127 0.109 0.055 0.0623 0.0403 0.0347 0.367 0.0715 0.0318 0.0398 0.0265 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/05/06 0521 563436 1 KSD1 09/07/06 1846 562563 2 0.00738 +/-0.0147 0.0112 +/-0.0147 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 The following Analytical Methods were performed Method Description LXM2 08/27/06 1545 562444 1 2 EML HASL 300, 4.5.2.3 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 50 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-013D Proiect: YANK01204 Sample ID: 170256016 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 106 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.U1 Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.51 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis..... i Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 91 06-0004-005A 170256017 SE 09-AUG-06 25-AUG-06 Client 17.9%Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Ganmma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.975 Americium-241 U 0.0504 Bismuth-212 0.804 Bismuth-214 0.647 Cesium-134 U Cesium-137 Cobalt-60 Europium-152 U Europium-154 U Europium-155 U Lead-212 Lead-214 Manganese-54 U Niobium-94 U -Potassium-40 Radium-226 Silver-108m U Thallium-208 Rad Gas Flow Proportional Counting GFPC, Sr9O, solid-ALL FSS Strontium-90 U -0.0288 0.249 0.682 0.0893 0.0167 0.00619 0.912 0.747 0.0235 0.00608 10.5 0.647 0.00189 0.322+/-0.164 f-I-0.0306
+/-0.393+/-0.112+/-0 .02 88+/-0.049 1+/-0.0884+/-0.0683+I-0.0707+/-0.0524+/-0.0658+/-0.0939+/-0.0494+I-0.0244+/-0.910+/-0. 112+/-0.0202+/-0.0462 0.0814 0.030 0.165 0.0371 0.0271 0.0255 0.0206 0.0526 0.0611 0.0476 0.0281 0.036 0.0228 0.0201 0.155 0.0371 0.0178 0.0209+/-0.164+/-0.0306+/-0.393+/-0.112+/-0.0288+/-0.0491+/-0.0884+/-0.0683+/-0.0707+/-0.0524+/-0.0658+/-0.0939+/-0.0494+/-0.0244+/-0.910+/-0.112+/-0.0202+/-0.0462 0.174 0.0616 0.351 0.0787 0.0574 0.0537 0.0453 0.110 0.134 0.0982 0.0584 0.0755 0.0486 0.0426 0.351 0.0787 0.0376 0.0442 0.0286 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/01/06 2119 563436 1 KSDI 09/07/06 1857 562563 2 0.00262 +/-0.0137 0.012 +/-0.0137 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 52 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005A Proiect: YANKO 1204 Sample ID: 170256017 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 92 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.53 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005 B 170256018 SE 10-AUG-06 25-AUG-06 Client 14%Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Gamma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.787 +/-0.187 Americium-241 U 0.0759 +/-0.0649 Bismuth-212 0.403 +/-0.233 Bismuth-214 0.636 +/-0.108 Cesium-134 U 0.0378 +/-0.0274 Cesium-137 0.181 +/-0.0421 Cobalt-60 0.710 +/-0.0716 Europium-152 U 0.0183 +/-0.0466 Europium-154 U 0.0204 +/-0.0516 Europium-155 UI 0.00 +/-0.0804 Lead-212 0.722 +/-0.086 Lead-214 0.832 +/-0.115 Manganese-54 U 0.0204 +/-0.0232 Niobium-94 U 0.0129 +/-0.0173 Potassium-40 9.30 +/-0.895 Radium-226 0.636 +/-0.108 Silver-108m U 0.0081 +/-0.0194 Thallium-208 0.299 +/-0.0505 Rad Gas Flow Proportional Counting 0.0725 0.0382 0.139 0.0306 0.0229 0.019 0.0155 0.0421 0.0449 0.0458 0.0317 0.0288 0.0192 0.0161 0.130 0.0306 0.0154 0.0157+/-0.187+/-0.0649+/-0.233+/-0.108+/-0.0274+/-0.0421+/-0.0716+/-0.0466+/-0.0516+/-0.0804+/-0.086+/-0.115+/-0.0232+/-0.0173+/-0.895+/-0.108+/-0.0194+1-0.0505 0.153 0.0789 0.294 0.0647 0.0482 0.040 0.034 0.0881 0.0982 0.0944 0.0651 0.0605 0.0406 0.0339 0.291 0.0647 0.0324 0.0332 0.0293 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJHI 09/02/06 1713 563436 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.0109 +/-0.0167 0.0123 +/-0.0167 KSDI 09/07/06 1857 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 54 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005B Proiect: YANK01204 Sample ID: 170256018 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 95 (25%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL hI Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.55 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005C 170256019 SE 10-AUG-06 25-AUG-06 Client 24.6%Proiect: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis GammaSolid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.810 +/-0.116 Americium-241 U 0.0147 +/-0.0176 Bismuth-212 0.365 +/-0.171 Bismuth-214 0.623 +/-0.0633 Cesium-134 Ul 0.00 +/-0.0297 Cesium-137 0.113 +/-0.0242 Cobalt-60 0.268 +/-0.0379 Europium-152 U -0.00617 +/-0.0317 Europium-154 U -0.0248 +/-0.0417 Europium-155 UI 0.00 +/-0.0407 Lead-212 0.840 +/-0.0404 Lead-214 0.686 +/-0.0505 Manganese-54 U 0.00306 +/-0.0143 Niobium-94 U 0.0053 +/-0.013 Potassium-40 10.2 +/-0.535 Radium-226 0.623 +/-0.0633 Silver-108m U -0.0071 +/-0.0113 Thallium-208 0.288 +/-0.031 Rad Gas Flow Proportional Counting 0.0431 0.0169 0.099 0.0212 0.0166 0.0124 0.012 0.0284 0.0337 0.0265 0.0162 0.0197 0.0127 0.0112 0.0857 0.0212 0.00971 0.0115+/-0.116+/-0.0176+/-0.171+/-0.0633+/-0.0297+/-0.0242+/-0.0379+/-0.0317+/-0.0417+/-0.0407+/-0.0404+1-0.0505+/-0.0143+/-0.013+1-0.535+/-0.0633+/-0.0113+/-0.031 0.090 0.0345 0.206 0.044 0.0343 0.0257 0.0254 0.0585 0.0714 0.054 0.0332 0.0406 0.0265 0.0232 0.186 0.044 0.0201 0.0239 0.0284 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/05/06 2143 563436 1 GFPC, Sr9O, solid-ALL FSS Strontium-90 U 0.0082 +/-0.0158 0.012 +/-0.0158 KSDI 09/07/06 1857 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 56 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005C Project: YANK01204 Sample ID: 170256019 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits CarrierFTracer Recovery GFPC, Sr90, solid-ALL FSS 96 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.57 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: September 8, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005D 170256020 SE I 0-AUG-06 25-AUG-06 Client 19.1%Proiect: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Gamma Spec Analysis Ganmma,Solid-FSS GAM & ALL FSS 226 Ingrowth Waived Actinium-228 0.995 +/-0.411 Americium-241 U 0.0557 +/-0.0479 Bismuth-212 0.635 +/-0.589 Bismuth-214 0.760 +/-0.165 Cesium-134 U 0.0627 +/-0.0504 Cesium-137 0.503 +/-0.0894 Cobalt-60 1.72 +/-0.132 Europium-152 U 0.00265 +/-0.0988 Europium-154 U 0.0538 +/-0.114 Europium-155 UI 0.00 +/-0.119 Lead-212 1.09 +/-0.126 Lead-214 0.802 +/-0.135 Manganese-54 U 0.0185 +/-0.0434 Niobium-94 U -0.0168 +/-0.0366 Potassium-40 10.7 +/- 1. 11 Radium-226 0.760 +/-0.165 Silver-108m U -0.021 +/-0.0301 Thallium-208 0.343 +/-0.0887 Rad Gas Flow Proportional Counting 0.146 0.0365 0.261 0.0601 0.0463 0.0338 0.0307 0.0745 0:0996 0.0591 0.0386 0.0517 0.0383 0.0309 0.276 0.0601 0.0247 0.0298+/-0.411+/-0.0479+/-0.589+/-0.165+/-0.0504+/-0.0894+/-0.132+/-0.0988+/-0.114+/-0.119+/-0.126+/-0.135+/-0.0434+/-0.0366+/-1.11+/-0.165+/-0.0301+/-0.0887 0.291 0.0729 0.521 0.120 0.0926 0.0676 0.0614 0.149 0.199 0.118 0.0772 0.103 0.0766 0.0618 0.551 0.120 0.0494 0.0595 0.0299 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g MJH1 09/02/06 1725 563436 1 GFPC, SO9O, solid-ALL FSS Strontium-90 U -0.00322 +/-0.0146 0.0127 +/-0.0146 KSD1 09/07/06 1857 562563 2 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/27/06 1545 562444 The following Analytical Methods were performed Method Description I EML HASL 300, 4.5.2.3 2 EPA 905.0 Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits 58 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: September 8, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-005D Proiect: YANKO 1204 Sample ID: 170256020 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Carrier/Tracer Recovery GFPC, Sr90, solid-ALL FSS 99 (25%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.59 QUALITY CONTROL DATA 60 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Client : Connecticut Yankee Atomic Power 362 Injun Hollow Rd Report Date: September 8, 2006 Page 1 of 5 East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder:
170256 Parmname NOM Sample Qual QC Units RPD%REC% Range Anist Date Time Rad Gamma Spec Batch 563436 QCI201171526 Actinium-228 Americium-241 Bismuth-212 Bismuth-214 Cesium- 134 Cesium- 137 Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 Manganese-54 Niobium-94 170256001 DUP 0.966 Uncert: +/-0.192 TPU: +/-0.192 U 0.0375 Uncert: +/-0.0387 TPU: +/-0.0387 0.366 Uncert: +/-0.306 TPU: +/-0.306 0.650 Uncert: +/-0.135 TPU: +/-0.135 U 0.0366 Uncen: +/-0.0355 TPU: +/-0.0355 0.0666 Uncert: +/-0.0355 TPU: +/-0.0355 0.104 Uncert: +/-0.0726 TPU: +/-0.0726 U 0.00636 Unceri: +/-0.0728 TPU: +/-0.0728 U -0.0788 Uncert: +/-0.0938 TPU: +/-0.0938 U 0.0672 Uncert: +/-0.0554 TPU: +/-0.0554 0.871 Uncert: +/-0.0971 TPU: +/-0.0971 0.727 Uncert: +1-0,105 TPU: +/-0.105 U -0.00916 Uncert: +/-0.0319 TPU: +/-0.0319 U 0.0101 Uncert: +/-0.0244 TPU: +/-0.0244 1.01+/-0.200+/-0.200 U 0.0258+/-0.075+/-0.075 0.592+/-0.276+/-0.276 0.690+/-0.0955+/-0.0955 U1 0.00+/-0.035+/-0.035 0.0611+/-0.0415+/-0.0415 0.159+/-0.0325+/-0.0325 U -0.00858+/-0.0624+/-0.0624 U 0.00919+/-0.0602+/-0.0602 U 0.0817+/-0.0557+/-0.0557 0.847+/-0.0867+/-0.0867 0.699+/-0.102+/-0.102 U -0.00665+/-0.0225+/-0.0225 U -0.00339+/-0.0176+/-0.0176 pCi/g 4 pCi/g 37 pCi/g 47 pCi/g 6 pCi/g 56 pCi/g 9 pCi/g 41 pCi/g 1350 pCi/g 253 pCi/g 20 pCi/g 3 pCi/g 4 pCi/g 32 pCi/g 402 (0%- 100%) MJHI 09/02/06 17:26 (0%- 100%)(0%- 100%)(0% -100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 100%)(0%- 20%)(0%- 20%)(0% -100%)(0%- 100%)61 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
170256 Page 2 of 5 Parmname NOM Samnle Oual OC Units RPD%REC% Range Anist Date Time Rad Gamma Spec Batch 563436 Potassium-40 Radium-226 Silver- 108m Thallium-208 11.3 Uncert: +/-0.986 TPU: +/-0.986 0.650 Uncert: +/-0.135 TPU: +/-0.135 U -0.0067 Uncen: +/-0.0208 TPU: +/-0.0208 0.283 Uncert: +/-0.0618 TPU: +/-0.0618 QC12O1171527 Actinium-228 Americium-241 LCS Bismuth-212 Bismuth-214 Cesium- 134 Cesium-137 Uncert: TPU: 23.4 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: 9.58 Uncert: TPU: 14.5 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: 11.7+/-1.03+/-1.03 0.690+/-0.0955+/-0.0955 U 0.000104+/-0.018+/-0.018 0.283+/-0.048+/-0.048 U 0.254+/-0.565+/-0.565 24.1+/-1.28+/-1.28 U 0.575+/-0.944+/-0.944 U 0.0248+/-0.213+/-0.213 U 0.00032+/-0.147+/-0.147 9.84+/-0.487+/-0.487 14.7+/-0.660+/-0.660 U 0.125+/-0.292+/-0.292 U 0.0779+/-0.277+/-0.277 U -0.0876+/-0.277+/-0.277 U 0.0524'+/-0.155+/-0.155 U -0.103+/-0.212 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 09/03/06 22:31 pCi/g 3 pCi/g 6 pCi/g 206 pCi/g 0 103 (75%-125%)
(0% -20%)(0%- 100%)(0%- 100%)(0%- 100%)103 (75%-125%)
101 (75%-125%)
Cobalt-60 Europium-152 Europium-154 Europium-155 Lead-212 Lead-214 Uncen: 62 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
170256 Page 3 of 5 Parmname NOM SamDle Oual OC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 563436 TPU: Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m Thallium-208 QC1201171525 MB Actinium-228 Americium-241 Bismuth-212 Bismuth-214 Cesium-134 Cesium- 137 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU:+/-0.212 U 0.0306 pCi/g+/-0.135+/-0.135 U -0.0513 pCi/g+/-0.115+/-0.115 U 0.769 pCi/g+/-1.10+/-1.10 U 0.0248 pCi/g+/-0.213+/-0.213 U 0.0782 pCi/g+/-0.105+/-0.105 U 0.180 pCi/g+/-0.177+/-0.177 U 0.0216 pCi/g+/-0.0479+/-0.0479 U -0.0654 pCi/g+/-0.0396+/-0.0396 U 0.110 pCi/g+/-0.0705+/-0.0705 U 0.00843 pCi/g+/-0.0317+/-0.0317 U -0.00203 pCi/g+/-0.012+/-0.012 U -0.00757 pCi/g+/-0.0117+/-0.0117 U -0.00589 pCi/g+/-0.0128+/-0.0128 U -0.0169 pCi/g+/-0.0308+/-0.0308 U 0.00802 pCi/g+/-0.0305+/-0.0305 U -0.00342 pCi/g (75%-1 25%)09/02/06 17:16 Cobalt-60 Europium-152 Europium-154 Europium-155 63 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
170256 Page 4 of 5 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time Rad Gamma Spec Batch 563436 Lead-212 Lead-214 Manganese-54 Niobium-94 Potassium-40 Radium-226 Silver-108m Thallium-208 Rad Gas Flow Batch Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU:+/-0.0294+/-0.0294 U 0.0151+/-0.028+/-0.028 U 0.00738+/-0.0252+/-0.0252 U .0.0127+/-0.0111+/-0.0111 U -0.00293+/-0.012+/-0.012 U 0.112+/-0.173+/-0.173 U 0.00843+/-0.0317+/-0.0317 U 0.00354+/-0.0115+/-0.0115 U -0.011+/-0.0157+/-0.0157 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 562563 QC1201169422 170256002 DUP Strontium-90 QC1201169424 LCS Strontium-90 QC1201169421 MB Strontium-90 QC1201169423 170256002 MS Strontium-90 U 0.00501 Uncert: +/-0.0149 TPU: +/-0.0149 U 0.00534+/-0.0155+/-0.0155 1.57+/-0.140+/-0.147 pCi/g 0 (0% -100%) KSDI 1.74 Uncert: TPU: Uncert: TPU: 1.74 U Uncert: TPU: U 0.0172+/-0.0185+/-0.0185 pCi/g pCi/g pCi/g 90 (75%-125%)
09/07/06 18:59 09/07/06 19:16 09/07/06 18:59 09/07/06 19:16 0.00501+/-0.0149+/-0.0149 1.32+/-0.124+/-0.130 76 (75%-125%)
Notes: The Qualifiers in this report are defined as follows: 64 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
170256 Page 5 of 5 OC Units RPD% REC% Ranue Anist Date Time Parmname NOM Sample Qual* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike con R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concen Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5 h Preparation or preservation holding time was exceeded centration by 4X or more ning this qualifier X the RL N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.** Indicates analyte is a surrogate compound.^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.65 General Narrative Page l of 105 CASE NARRATIVE For CONNECTICUT YANKEE RE: Soil PO# 002332 Work Order: 168404 SDG: MSR #06-0652, 06-0675, 06-0687, 06-0688, 06-0707, 06-0743, 06-0755 August 15, 2006 Laboratory Identification:
General Engineering Laboratories, LLC Mailing Address: P.O. Box 30712 Charleston, South Carolina 29417 Express Mail Delivery and Shipping Address: 2040 Savage Road Charleston, South Carolina 29407 Telephone Number: (843) 556-8171 Summary: Sample receipt The sample(s) for this Project arrived at General Engineering Laboratories, LLC, (GEL)in Charleston, South Carolina on May 5, May 9, May 12, May 17, May 26, June 2, June 8, 2006. All sample containers arrived without any visible signs of tampering or breakage.
The chain of custody contained the proper documentation and signatures.
The laboratory received the following sample(s):
Sample ID Client Sample ID 168404001 9106-0002-007F 168404002 9106-0002-01 IF 168404003 9106-0003-004F 168404004 9106-0003-015F 168404005 9106-0004-005F 168404006 9106-0004-015F 168404007 9106-0005-01 OF 168404008 9106-0005-014F 168404009 9106-0006-005F GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.P.O. Box 30712
- Charleston, SC 29417
- 2040 Savage Road (29407)Page 2 of 105 Phone (843) 556-8171
- Fax (843) 766-1178
- www.gel.com 168404010 9106-0008-006F 168404011 9106-0008-008F 168404012 9106-0009-002F 168404013 9106-0009-017F 168404014 9106-0010-001F 16840401.5 9106-0010-012F Items of Note: At the request of Dale Randall on July 20, 2006, GEL analyzed the above samples according to the spreadsheet in the attached email.Case Narrative:
Sample analyses were conducted using methodology as outlined in General Engineering Laboratories (GEL) Standard Operating Procedures.
Any technical or administrative problems during analysis, data review, and reduction are listed below by analytical parameter.
Analytical Request: Seven soil samples were reanalyzed for FSSALL, except gamma and Sr-90.Four soil samples were reanalyzed for FSSALL, except gamma and Ni-63.Two soil samples were reanalyzed for FSSALL, except gamma.Two soil samples were reanalyzed for FSALL, except gamma, Sr-90 and Ni-63.Internal Chain of Custody: Custody was maintained for the sample(s).
Data Package: The enclosed data package contains the following sections:
Case Narrative, Chain of Custody and Supporting Documentation and all analytical fractions.
I certify that this data package is in compliance with the SOW, both technically and for completeness, for other than the conditions detailed above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or a designee, as verified by the following signature.
Cheryl Jones Project Manager GENERAL ENGINEERING LABORATORIES, LLC a Member of THE GEL GROUP, INC.P.O. Box 30712 ° Charleston, SC 29417
- 2040 Savage Road (29407)Phone (843) 556-8171
- Fax (843) 766-1178 -www.gel.com Page 3 of 105.I I!
Additional HTD analyses
Subject:
Additional HTD analyses From: "Dale Randall" <randall @cyapco.com>
Date: Thu, 20 Jul 2006 11:04:54 -0400 I I U&Lfowlt To: "Cheryl Jones" <cj @gel.com>CC: "Clyde Newson" <Newson@CYAPCO.com>, "John McCarthy" <McCarthy@
CYAPCO.com>
Cheryl: Per our earlier discussion, attached is a list of samples that we would like to have analyzed to the FSSALL protocol.
I have included a list of test protocols performed on each sample to date. Once you have had an opportunity to determine our options for each sample please call or e-mail me at your convenience.
Thank You, Dale (860) 267-3133 Content-Description:
GEL FSSALL analyses request.xls GEL FSSALL analyses request.xls
! Content-Type:
application/vnd.ms-excel Content-Encoding:
base64 Page 4 of 105 I oflI 8/2/2006 7:04 PM Done To be done Previous GEL ID CY sample location IDs FSS Gam Sr-90 Ni-63 Am Pu Sr9O Pu241 Fe55 Ni63 Tc99 H3 C14 7164220008 9106-0002-007F x x x x x x x x x X 164220012 9106-0002-011F x x x x x x x x x x c 162335004 9106-0003-004F x x x x x x x x x x 162335014 9106-0003-015F x x x x x x x x x x 162832015 9106-0004-005F x x x x x x x x x x 162832009 9106-0004-015F x x x x x x x x x x 162485008 9106-0005-01OF x x x x x x x x x x 162485011 9106-0005-014F x x x x x x x x x .x 162850014 9106-0006-005F x x x x x x x x x x 163741005 9106-0008-006F x x x x x x x x x x 163741009 9106-0008-008F x x x x x x x x x x 164542008 9106-0009-002F x x x x x x x x x x 164542003 9106-0009-017F x x x x x x x x x x 163105009 9106-0010-001 F x x x x x x x x x x 163105016 9106-0010-012F x x x x x x x x x x Chain of Custody and Supporting Documentation Page 6 of 105 kV61 Health Physics Procedure o !Eýff q ')LýGPP-GGGR-R5104-003-Attachment B-CY-001 Major SChain of Custody NoForm007 Connecticut Yankee Atomic Power Company No. 2006-00371 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 4 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones co i, Priority:
X 30 D. E] 14 D. [] 7 D. Container ZO:<Sample ." ..Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0002-OO1F 5/17/06 10:42 SE C BP x x -"_Transfesred from COC 2006-00357 9106-0002-002F 5/18/06 09:43 SE C BP x Transferred from COC 2006-00361 9106-0002-003F 5/18/06 10:14 SE C BP X X Transferred from COC 2006-00361 9106-0002-004F 5/18/06 10:39 SE C BP X X Transferred from COC 2006-00361 9106-0002-005F 5/18/06 12:49 SE C BP X x Transferred from COC 2006-00364 9106-0002-006F 5/18/06 13:14 SE C BP x x Transferred from COC 2006-00364 9106-0002-006FS 5/18/06 13:14 SE C BP x x Transferred from COC 2006-00364 9106-0002-007F 5/18/06 13:37 SE C BP x x Transferred from COC 2006-00364 9106-0002-008F 5/18/06 14:04-M SE C BP X x Transferred from COC 2006-00364 NOTES: PO #: 002332 MSR #: 06- SSWP# NA [ LTP QA 0 Radwaste QA LI Non QA Samples Shipped Via: Internal 05 Fed Ex Container 0-1 UPS Temp.: Deg. C E] Hand Custody Sealed?I R h quDate/Time
- 2) =ived By Date/Time Custody Seal o~~( 0C$) Other Intact?ýrgelinquishled BJ Date/Time
- 4) Received By Date/Time YO__ NC Bill of Lading #5) Relinquished By Date/Time
- 6) Received By Date/Time 7C i951 ,
Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-00 I Major~Chain of Custody Form No. 2006-00372 M Connecticut Yankee Atomic Power Company ChinofCutoy3or (0 00 362 Injun Hollow Road, East Hampton, CT 06424 O 860-267-2556
, 5 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 0 843 556 8171. Attn. Cheryl Jones Cn V)Priority:
N 30 D. E] 14 D. [] 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0002-009F 5/18/06 14:28 SE C BP -x Transferred from COC 2006-00364 9106-0002-01OF 5/18/06 14:50 SE C BP x X TransferredfromCOC2006-00364 9106-0002-01IF 5/19/06 08:10 SE C BP X X Transferred from COC 2006-00365 9106-0002-012F 5/19/06 08:31 SE C BP X X Transferred from COC 2006-00365 9106-0002-013F 5/19/06 09:00 SE C BP X x Transferred from COC 2006-00365 9106-0002-014F 5/19/06 09:58 SE C BP X x Transferred from COC 2006-00365 9106-0002-014FS 5/19/06 09:58 SE C BP X X Transferred from COC 2006-00365 9106-0002-015F 5/19/06 10:29 SE C BP x x Transferred from COC 2006-00365 9106-0002-016F 5/19/06 13:19 SE C BP X x Transferred from COC 2006-00365 NOTES: P0 #: 002332 MSR #: 06- SSWP# NA [K LTP QA 0 Radwaste QA El Non QA Samples Shipped Via: Internal C?5S [Z Fed Ex Container ED UPS Temp.: Deg. C fl Hand Custody Sealed?SlRelin ishe Date/Time
- 2) Re ived By DatpTime Custody Seal/6ý X__ _ _ _ _ _ _ _ _ _ _ _ _ _f Other Intact?3)"Ielinquished By Date/Time
- 4) Received By Date/Time BillofLading_#___
xY ' N 0 Bill of Lading #5) Relinquished By Date/Time
- 6) Received By Date/Time
'1 " 7 79 Connecticut Yankee Statement of Work for Analytical Lab Services -.CY-ISC-SOW-001 Figure 1. -Sample Check-in List DateiTime Received&
-V : (0 SDG#: 0(o-0 "-6S Work Order Number: , ( , t_[ 'Z .Shipping Cdatainer IDnYIO_ LU (559/O Chain of Custody# 0 ( r /I. Custody Seals on shipping container intact?. Yes D\1"No [ ]2. Custody Seals dated and signed? Yes No[]3. Chain-of-Custody record present? Yes No [4. Cooler temperature
._"" 5. Verniiculite/packing materials is:. Wet [ ] Dry t\ ]6 " Number of samples in shipping container:
__7. Sample holding times exceeded?
Yes 11 No VI 8. Samples have'tape __ hazard labels_i custody seals -appropriate sample labels 9. Samples are:-_ ia good condition
.leaking._._broken .have air bubbles 10. Were any anomalies identified in sample receipt? Yes [ ' NoX ]11. .Description of anomalies (include sample numbers): Sample Custodia Laboratory:
Date : Telephoned to: On By-. " .., Page 9 of.105 Connecticut Yankee Statement of Work for Analytical Lab Services-CY-ISC-SOW-001
.I -lC-owoo Figure 1. Sample Check-in List Datefrime Receive&d",f)
& .2 f SDG#: 6&~#(-Or Work Order Number: ( 1.Shipping Cdntainer ID <P " ..Lt5 .59 "f Chain of Custody #.)2ov C, v 3/2 I. Custody Seals. oii shipping container intact?,.
Yes 'No I 2. Custody Seals dated and signed? Yes No [ ].3. Chain-of-Custody record present? Yes I Not]4. Cooler temperature .P , 5. Vermiculite/packing materials is: W et [] Dry I ', 6: Number of samples in shipping container
__ _7- Sample holding times exceeded?
Yes [ No 1 8. Saj lesth e._vape -hazard labels-cstody seals -appropriate sample labels 9. Sam ples are-..n$ii'good condition 2eln-broken .have air bubbles 10. Were any anomalies identified in sample receipt?.
Yes [ ] No... ..Description of anomalies, (include sam ple num bers): Sample Custodian/Laboratory: ' ,A.Date. , -o b Telephoned to: On By fJ.Page 10 of:105 ;.7 SSAMPLE RECEIPT & REVIEW FORM 7P7 01P ^ t Mueol I7Clnt -- up 4.'a A ~ _ SDGIARCOC/Work Order: I (Date Received:
& a .'Q10 PM(A) Review (ensure non-conrormi'ng items are resolved prior to sigaing);Received By: Uk Sample Receipt Criteria Z Z CommentslQualifiers (Required for Non-Conforming Items)Shipping containers received intact Circle Applicable:
seals broken damaged lear g container other (describe)
I and sealed? /Samples requiring cold Circle Coolant # ice bags blue ice dry ice none other describe)2 preservation within (4 +/- 2 C)?_ Record preservation method. ....Chain of custody documents 3included with shipment?
__ _Sample containers intact and ircle Applicablesdas broken damaged container leaking container other (describe) 4 sealed?1-5 Samples requiring chemical ýSa !,1 ID's. containers affected anid observed pH: p reservation at proper pH?-prservtionat poperpHSample ID's and containers affected: 6 VOA vials free of headspace (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory) 8 Samples received i holding td'a and tes, affectred time?9oSample ID's COC match ID's Sample ID's and containers affected:-on bottles?.______________________________
Date & me on COC match date Sample ID's affected-& tiYon bottles?Nu her of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in relin2uishedlreceived sections?
2,0" 0e 14 Air Bill ,Tracking
- s, &Additional Comments T RSO RAD Receipt# #_'S t zt *If > x2 area background is observed on samples identified as "non-Suspected Hazard Information
.regulated/non-radioactive-, contact the Radiation Safety group for further_____ i: (A )Radiological Classification?
Maximum Counts Obserd*.B PCB Regulated?
i Comments: Shipped as DOI Hazardous C Material?
If yes, contact Waste Hazard Class Shipped: Manager or _SH Manager. N#: PM (or PMA) review of Hazard class.iticaion
- Initials Date: Lo Z'7 10(,'U Page 11 of 105 ze,0 SAMPLE RECEIPT & REVIEW FORM 0 PM use onlyV Cliet: ~ (C' SDGIARcCOCIWOrk Order: Al Date Received:
c C:v" ,PM(A) Review ereslved prior to signing).Received By:. _Sample Receipt Criteria Comments/Qualifier leq'uired for Non-Conforming Items)Shipping containers received intact Circle Applicable:
seals broke damaged container leaking container other (describe) 1 and sealed? 1_____ _ooant _______________bue
__edy__e none_ other__escrib Samples requiring cold Circ Colant # I1ags blue ice dry ice none other describe)2 preservation within (4 +/- 2 C)? /Record preservation method. -ii 3 Chain of custody documents included with shipment?Sample containers intact and Cire plifcable:
seals broken damaged container leaking container other (describe) 4sealed? -Samples requiring chemical Sample IDs. containers affected and observed pH: preservation at proper pH? A 6 VOA vials free of headspace Sample ID' and containers affected: (defined as < 6mm bubble)? /Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory)
Samples received within holdin Id' and tests affected;8.time? /Sample ID's on COC matc ID's Sample IDs and containers affected: on bottles?7_
10 Date & time on COC tch date Sample ID's affected: 10& time on bottles?f Number of containe received Sample ID's affected: match number indic/ted on COC?COC form is prop rly signed in 1 12 relinquished/rIgived sections?
CoC." Z.oOCP -4), .... j- Air Bill ,Tracking Fs, &Additional Comments T RSO RAD Receipt #S e H a I *If > x2 area background is observed on samples identified as "non-St -regulated/non-radioactive", contact the Radiation Safety group for further__ __ investigation.
A Radiological Classification?
-,/ Miximum Counts Observed*:
W, c Pi/n B PCB Regulated?
Comments: Shipped as DOT Hazardousm-c Material?
If yes, contact Waste Hazard Class Shipped: r Manager or ESH Manager.B UNN: PM (or PMA) review of Hazard classification:
Initials -Date: -Page 12 of 105 C/
Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 1 Major~Chain of Custody Form Connecticut Yankee Atomic Power Company No. 2006-00312 362 Injun Hollow Road, East Hampton, CT 06424 4 /43 324/C 860-267-2556 01 5" Project Name: Haddam Neck Decommissioning
' Analyses Requested Lab Use Only Contact Name & Phone: COments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories
" 2040 Savage Road. Charleston SC. 29407 1 I".843 556 8171. Attn. Cheryl Jones rV) V CA Priority:
0 30 D. ] 14D., 71D. Container Sample Size-Media Type &Type C , rL m Sample Designation Date Time Code Code Code Comment, Preservation t._ab Samp__i_ .9106-0003-001F 4/24/06 14:13 SE C BP X Transferred from COC2006-00221 it 9106-0003-002F 4/24/06 14:39 SE C BP x Transferred from C0C2006-00221 91- 9106-0003-003F 4/24/06 15:01 SE C BP X Transferred from COC2006-00221 0 9106-0003-004F 4/25/06 08:41 SE C BP X Transferred from COC2006-00223 9106-0003-004FS 4/25/06 08:41 SE C BP X Transferred from COC2006-00223 9106-0003-005F 4/25/06 09:241 SE C BP x Transferred from COC2006-00223 9106-0003-006F 4/25/06 09:46 SE C BP x Transferred from COC2006-002239106-0003-007F 4/25/06 10:28 SE C BP X Transferred from COC2006-00223 9106-0003-008F 4/25/06 11:15 SE C BP X " Transferred from COC2006-00223 NOTES: PO #: 002332 MSR #: 06- SSWP# NA Zj LTP QA FJ Radwaste QA U Non QA Samples Shipped Via: AnternaCl."o tCter..Combined samples 9106-0003-003F taken on 4/25/06 @08:19 and 9106-0003-003FB taken on 4/25/06 @ 08:19 in order to have sufficient sample for counting.
Fed Ex bT. Deg .C ED ups ,. : -: -:: E Hand Custody.Sealed.
- 1) Relinquished By Date/Time
- 2) /ec ived By iDate Time .Custody Se1l Intact?.-JA " tu4 t .5-4"-c /,..,[] (d / ,g 1 Other 3) Relinquished By Date/Time
- 4) Received By DatýTime q___-____._____.__.
Nf.Bill of Lading # J 5) Relinquished By Date/Time
- 6) Received By Date/Time
- .7. 0 2- ?'i;0- 0 2 4 "
GPP-GGGR-R5104-003 -Attachment B-CY-00 I Major Health Physics Procedure Health Physics Procedure GPP-GGGR-RS 104-003-Attachment B-CY-00 I Major CD 0%Otc 0~0*01 Chain of Custody Form No. 2006-00313 Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 /(o2-3-5o/.
860-267-2556 "Z:3_,___.
_.. ____ __* / _ _-" 5 7 , o/Project Name: Haddam Neck Decommissioning Analyses Requested Contact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories
.< " 2040 Savage Road. Charleston SC. 29407 b , 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D. L14 D. ] 7 D. Container Sample Size-Media Type &Type 1". 'Sample Designation Date Time Code Code Code Comment, Preservation .i, IP 9106-0003-009F 4/25/06 13:00 SE C BP X Transferred from COC 2006-00236
,.9106-0003-01OF 4/25/06 13:23 SE C BP X --Tnsferredfrom COC 2006-00236 9106-0003-010FS 4/25/06 13:23 SE C BP X TransferredfromCOC2006-00236
__._.._____._.._.
9106-0003-012F 4/25/06 15:12 SE C BP X Transferred from COC 2006-00236 9106-0003-013F 4/25/06 14:21 SE C BP X Transferred from COC 2006-00236 9106-0003-014F 4/25/06 14:48 SE C BP x Transferred from COC 2006-00236
-.. ., 9106-0003-015F 4/26/06 08:16 SE C BP x Transferred from COC 2006-00237 9106-0003-016F 4/26/06 09:41 SE C BP x Transferred from COC 2006-00237
.9106-0003-017F 4/26/06 09:18 SE C BP x Transferred from COC 2006-00237
., ,9106-0003-018F 4/26/06 08:59 SE C BP Transferred from COC 2006-00237 NOTES: PO #: 002332 MSR #: 0 6SSWP#NA SLTP QA[]I Radwaste.
Q)A E] Non QA 1) Relinquished By Date/Time
- 2) Received By Date/lTime
- 3) Relinquished By Date/Time
- 4) Received By Date/Time Samples Shipped Via: N Fed Ex F1 uPs[] Hand El Other Bill of Lading #-02a1 ,rer.0tbdy SialtC.y j Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Check-in List Date[/Time Received:
101 -$Work Order Number: -I (Z---3 -S Shipping Cdotainer ID: "']VL0 I'L OZ. ChainofCustody# 9 (30o "- '" ' O1 o 00o 13 1. Custody Seals or shipping container intact?.- -Yes No *2. Custody Seals dated and signed? Yes [ I No 3. Chain-of-Custoly record present? Yes No [ ].4. Cooler temperature C C., 5. Vermiculite/packing materials is: Wet [ Dry n 1 /-6 Number ofsamples in shipping container:
[i r .]. '7- Sample holding times exceeded?
Yes j I No 8 amp~eps-tape -hazard labels__Zcutody seals _appropriate sample labels 9. Samples are:-good condition
...2-lIeaking-broken
- have air bubbles 10. Were any anomalies identified in sample receipt? Yes [] No 11. .Description of anomalies (include sample numbers): S'ampleCustodian/Laboratory:-
.((' 1/4 rcpft'Telephoned to: BOn By_ _ _ _Page 15 of 105*1 SAMPLE RECEIPT & REVIEW FORM 0 PM oeant 00YI( 21 Client: 'SDG/ARCOC/Work Order:f Dat Rceve: o- M 1 64oPM(A) Review (ensure no-o! F g items are resolved prior to signing): Received By: ( C a _ _ _ _ _ _ __ _ _ _ _ _ _Sample Receipt Criteria Z Z Comments/Qualiflers (Required for Non-Conforming Items)1 Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container oder (describe) and sealed?Samples requiring cold Circle Coolant # ice bags blue ice dry ice none 2 preservation within (4 +/- 2 C)?Record preservation method. _ _ _n__ _ _ _ _ _ _ _s Chain of custody documents included with shipment?__=_
4 Sample containers intact and Circle Applicable:
seals broken damaged container leaking container other (describe) sealed?Samples requiring chemical Sample ID's. containers affected and observed pH: 5 preservation at proper pH? .. .... .. ......6 VOA vials free of headspace Sampl ID's and containers affected: (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory)
,_, Samples received within holding Id's and tests affected;time?Sample ID's on COC match ID's Smpl ID's and conaiers affect: on bottles?Date & time on COC match date Sample ID's affected:& time on bottles?Number of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in 1relinquished/received sections?Air Bill ,Tracking
- 's, & F-' d to % I Additional Comments % k z..V -RSO RAD ReceiptI # __________
SfInformation
.f> x2 area background is observed on samples identified as 'non-dm regulated/non-radioactive", contact the Radiation Safety group for further ,_ investigation.
~ ailgclCasfctoMaximum Coulnts Observed*:
B' PCB Regulate?
Conzritents:-hipped as trot Hazardous C Material?
If yes, contact Waste Hazard Class Shipped:_Manager or ESH Manager. UN#: PM (or- PMA) review of Hazard classification:
..-'.Date:,,!I Page 16 of 105 Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 1 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Name: Haddan Neck m, ,Contact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones I Priority:
ER 30 D. E 14 D. E] 7D.Samples Shipped Via:[ Fed Ex El uPs El Hand El Other Bill of Lading #
Health Phys,, Proedure GPP-GGGR-R5104-003-Attachment B-CY-00 1 Major*,; Cquntn Yankee Atomic Power Company" n " un Hollow Road, East Hampton, CT 06424 860-267-2556 ProjectName:
Haddarn Neck Decommissic Contact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road, Charleston SC, 29407 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D. [] 14 D. [17 D.Samples Shipped Via:[ Fed Ex El uPS C] Hand El Other Bill of Lading #
Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Check-in List Datc/Time Received:
-- i-2. 20 SDG#: A4,5R:t-LO 0,R F Work Order Number: /-'32 I Shipping ContainerID:
M714 9315 Chain ofCustody#
ooG- 6oS.'y 1. Custody Seals on shipping container intact? Ycs No J 2. Custody Seals dated and signed? Yes No [J 3. Chain-of-Custody record present? Yes No [J 4. Cooler temperature
- 5. Venniculite/packing materials is: Wet J4 Dry [6. Number of samples in shipping container:
9 7. Sample holding times exceeded?
Yes [] No 10.11.Were any anomalies identified in sample receipt? Yes No N o Description of anomalies (include sample numbers): Sample Custodian/Laboratory:
Telephoned to: On Date: ý 0a. , 6(, daq, By__________.By Page 45 of 56 Page 19 of 105 Connecticut Yankee Statement of Work for Analytical Lab Services cy-ISC-SOW-001 Figure 1. Sample Check-in List.Date/Time Received':
'i,(& ( (q " " SDG#: W Oc-Work Order Number:--Shipping Cdhtainer ID_ Chain of Custody# -&O&( --0()334 1. Custody Scals oni shipping container intact?. Ye -Y No 2. Custody Seals dated and signed? Yes[ ] No 3. Chain-of-Custody record present? Yes 'V No [ " 4. Cooler temperature
)1 3 C -S. VermiculitcePacking materials is: Wet f,/Dry tDr ]-Number ofsamples in shipping container:
_ _"_"_;__" 7. Sample holding tiMes exceeded?SYes ]Na &a 8. Sample-, have.'~.k2.ape-hazard labels A2.custody Seals -appropiate sample labels 9.Samples arei!-In good condition..-.have a"r bubbles 10. Were any anomalies identified in sample rewipt? Yes No [.Pag 2oescription ofaO4alles(include sample numbers).Sample CustiAaborar, .- , On__________
to -L Page 20of 105-SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM-127,0 QF ?- (
R A.oo ry .r<>,-r, 0, IS 3 A-((vl a~0t~- L33)(u v u (n55 A OO3 6 C 09 5i3_-_--__ _ _ _ 3 UMc- 5 (00--) n(, ti5 secL ble haf~d nl o ~ e (CC, G Aso_______A J __v__.,->-,H__
- JI Page 21 of 105) 1! 1 0 SAMPLE RECEIPT & REVIEW FORM PM use only Client: C'" , .SDIARCOC/Work Order: /4, 2e 3 Date Received:
PM(A) Review (ensure non-conforming items are resolved prior to signing): kReceived By: eA. I: j Sample Receipt Criteria Comments/Qualifiers (Required for Non-Conforming Items)I Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) land sealed? x-Samples requiring cold Circle Cool ant # ice bags blue ice dry ice nw other describe)2 preservation within (4 +/- 2 C)?Record Preservation method.Chain of custody documents included with shipment?
n C 4 Sample containers intact and Circle Applicable:
seals broken damaged container 1< "atr (decrib)sealed? .' .' 9o(1 ooo( -000 o-- -5Samples requiring chemical ISmple ID's, containen affected and obsered pHS:.preservation at proper pH?__________________________
6 VOA vials free of headspace Sample ID's and containers affected: 6 (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory)
_ ____.Samples received within holding Id's and test affectd: 8time?______________________
___9 Sample ID's on COC match ID's Smle ID's and containers a2feted: on bottles?Date & time on COC matchdate " ID's'affected:
10 & time on bottles? __ I Number of containers received 1 Sun* 's afeted: " match number indicated on COC? __COC form is properly signed in-relinquishedreceived seetions?
l AoL. el Air Bill ,Tracking
- s, &Additional Comnments_ _ _ .._ _ _ _ _ _ _ __._"_ .. .h3.. ..., Suspected*I1a0rd Information I rEal s t IK t(AtD Receipt #_ _ _ _-*If > x2 area background is observed on samples identified as "ton-regulatedinon-radioactive", contact the Radiation Safety group for further 4 jinvestigatiro.
I I I =A IRI ilgcalfigc~ikii?
I a I B IPCB Regulate~
? .SWM as l" Hazardous
-C Materiat?
If yes, contact Waste-Manager or jSH Manager. -VWximum Counts Observed:
<, .a.ýOrnments:
c-iazard' Class Shipped: Initials Date:5 .- 7z I'fp~t~f~I7~.yTCYtcw of Hazard clasitifi~atinn PM4( laftik1creview of Hazard classification: (I 0 SAMPLE RECEIPT & REVIEW FORM 01 PM use only iClient: ,J n Vp U SDARCOC/Work Order: /(2r37-., Date .J- n" , PM(A) Review (waure oma-coormbraq ftm,- resolved prior to signing): Received By: J____________________________
Sample Receipt Criteria A Comments/Qualirmirs (Required for Non-Conforming Items)Shipping containers received intact Circle AppW~kble:
seals broken damaged container leaking conmimar olber (describe) and sealed? -N=Q-Samples requiring cold Circle Coolanl # ice bags blue ice dry ice odier describe)2 preservation within (4 +/-- 2 C)?Record preservation method. l1¢'-, Chain of custody documents CO U's CY C> v' k+-included with shipment?
ant Sample containers intact and V,.,iruk=e sealit damaged couincr leaking aodiaer sealed? (e .-s27cb Samples requiring chemical Sample IDI,. containers affected and observed pH: preservation at proper pH?VOA vials free of headspace Sample ID's ard ontainers affected:_(defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory)_
8 Samples received within holding Id's and sens affected: time?Sample ID's on COC match ID's Sample ID's and oaminers aftected: on bottles?Date & time on COC match date Sample ID's affected: 10 1& time on bottles?Number of containers received Sarrie 11's affeteld: match number indicated on COC?COC form is properly signed in AC) C -)G5 .at..., V .L OU i 7-relin uished/received sections?
--_I__e_______
Air Bill ,Tracking
- 's, & _
f0 .hiL Additional Commnts 0 RAD Receipt S e *af > x2 area background is observed on samples identified as 'non-S eo regulated/non-radioactive*.
contact the Radiation Safety group for further OX CA investigation.
A Radiological Cassification.
Maximum Counts Observed*:
PB m Regulated?
Conunents:
IShi-ppW as 001~ Hazardous
i ..c Material?
If yes, contact Waste I Hazard Class Shipped: PManager or ESH Manager. iaONs:.PM (or PMA), nereview yof_ classification:, ,, _.'" nitials .... n '. Date: & %J V*r Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major Health Physics Procedure GPP-GGGR-R5 104-003 -Attachment B-CY-O0 1 Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556)ject Name: Haddam Neck Decommissioning
--Contact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
Ig 30 D. [] 14 D. [ 7 D.Samples Shipped Via:[ Fed Ex LI UPS Hand E] Other Bill of Lading #I'7q"c '71,6 '3:S
- Connecticut Yankee Statement of Work for Analytical Lab Services Figure 1. Sample Check-in List.Dateime R ived: 5 3 SDg# -:*Work Order Number: --- LA "J, Shipping Cdntainer ID: 5-'z, '6 3 Chain of Custody L. Custody Seals onishipping container intact?2. Custody Seals dated and signed?3. Chain-of-Custody record present?' 4. Cooler temperature jC , q 5. Vermiculite/packing materials is: 6.' -Number ofsamples in shipping container:
- 7. Sample .holding times exceeded?.CY-ISC-SOW-O01
- .Yes /No[.Yes' ,fNo (1 Yes JANo [ ].Wet [W.Dry j-ý]Yes [ ] No 10. Were any anomalies identified in sample receipt? Yes [ No <11. .Description of anomalies (include sample numbers):
"_-a numbers):-Page 25 of 105 111 1 9 SAMPLE RECEIPT & REVIEW FORM ff PM use only Client:I , SDG/ARCOC/Work Order: IGZLt85 DPM(A) Review (ensure non-confo items are resolved prior to signing): Received By: 19p /'- ....Sample Receipt Criteria , Z Comments/Qualifiers (Required for Non-Conforming Items)I Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe)
Samp requiring cold Circle Coolan, # ice bags blue ice dry ice nmne other describe)Spreservati
~dthirn (4 +1- 2 CQ?Record reserv n method.-Chain of custody d -n" included with shipment?4 ISample containers intact and CircIc Applicable:
seals broken damaged container leaking container other (describc) sealed?.lSamples requiring chemical Sample ID's. containe-, affected and observed pH: preservation at proper pH?6VOA vials free of headspace NSamle ID's and containers affected: 6 (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, immediately deliver to VOA laboratory)
I ad 8 Samples received within holding and test affect: lime?9oSample ID's on COC match ID's Sampl ID's and containe affected: 9on bottles?10 Date & time on COC match date Sample ID's affected:& time on bottles?11 Number of containers received Sample ID's affected: match number indicated on COC?COC form is properly signed in 12 relinquished/received sections?14 Air Bill ,Tracking
- 's, & F' 1q2- ' 19 4" -- 17t.Additional Comments a' --" (1'6>-T RSO RAD Receipt #t -if > x2 area background is observed on samples identified as *non-Su u a regulated/non-radioactive", contact the Radiation Safety group for further'L' investigation.
A lRadiological Classification?
/ Maximum Couns. Observed*:
_ PCB Regulated?
_ Comments: Shipped as Do'r"Hazardous C Material?
If yes, contact Waste Hazard Class Shipped: Manager or ESH Manager. UN#: PM (or PMA) review of Hazard classification:
Initials Date: Fa- t 40 ,0 1 IUD::'U Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 I Major Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424-860-267-2556 iect Name: HaddamýContact Name & Phone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones Priority:
Z 30 D. [] 14 D. [] 7 D.Samples Shipped Via: 9 Fed Ex El ups LI Hand DI Other Bill of Lading #92,o- ?.lo- 6Wyf
.Connecticut Yankee CY-ISC-SOW-O01 Statement of Work for Analytical Lab Services C C W Figure 1. Sample Check-in List Datetaime, Received:
~2 ( ~ (Work Order Number. -shipping Cdhtfiferl Cf+ C infutd# S (V?{S"-1. Custody Seals onishipping container intact?,.. -Yes tINo[ 4)2. Custody Seals dated and signed? Yes*[ ( No 3. Chain-of-Custody record present? Yes WL)No [1]: 4. Cooler temperature
_ i l5. Vermiculite/packing materials is: .Wet VC) Dry [6: Numbcr of samples in shipping container.' )t". cc) -" 7. Sample holding times cxceeded?
Yes [ No.8. Samples have.toja e -hazard labels* ýcustody seals -appropriate sample labels 9. samples are.., A1-ngood condition leak ng broken -have air bubbles 10. Were any anomalies identified in sample receipt?'
Yes []No )I I. :.Description of anomalies (include sample nurber)Samplek Custodiail~abomratzy:
2 ~~j~ .ae./L2/5 Telephoned to:_________
___B .Page 28 of f05 SAMLERECEIPT
& REVIEW FORM P4r e 70iu $SML I'm we onl Client:. 1,7 SDGIARCOC/Work Order: ,, Date Receied: PM(A) Review (esure nou-ionfurin items are resolved prio to sgunhg): ,eceived By: Ctrle cd(-I__., ._ ..._ __ _ _ _ _ _Sample Receipt Criteria CommentslQualifris (Required for Non-C oforming Items)Shipping containers received intact urde Aplicable:
wals broken damged conmter leaking container oder (descrie)and sealed? I r Samples requiring cold Circle Caoam # ice bags blue ice dry ice Q otrdribe)2 preservation within (4 +/- 2 C)?Record preservation method. 0 C Chain of custody documents
/0COus o.*x , \ LA-included with shipment?
I-Sample containers intact and S daraged comaier leaking coma..erud sealed? txx(A V" !I Samples requiring chemical in"i ID's. conitaimS affected and obscrved pH: preservation at proper pH? r VOA vials free of headspace Sample ID'S and cotaiens affecd: (defined as < 6mm bubble)?Are Encore containers present?7 (If yes, inunediately deliver to VOA laboratory)
.... .......9 Samples received within holding id's and ,et affected: time?Sample ID's on COC match ID's Sample ID'S and coanainems affected: on bottles?Date & time on COC match date Sampe ID's affected:& time on bottles?Number of containers received Sampl I'S afeced match number indicated on COC?COC form is properly signed in no "-'L, v.LU I 3 .d relinquished/received sections?Air Bill ,Tracking
- 's, & .CC'CI+/-)LL6uk- (i JI.--Additional Comments V RSO RAD Receipt I__e- as *f > x2 area background is observed on samples identified as -non-Suspected Hazard Information regutd/non-radioactive contact the Radiation Safety group for further logad i investigation.
A JRadiological Classification?
Maximum Counts Observed*:
4' Id r.-'[B IP'C Regulated?
Comments:[Shipped as DOU" Hazardous C Material?
If yes, contact Waste , Hazard Class Shipped:lManager or ESH Manager.PM (or PMA) review of .Hazard classification:
Initials Date: 1 T 0o D , in Ir .I)-ari%; 0t) U V ,)11 .11. 11, 9 SAMPLE RECEIPT & REVIEW FORM CONTINUATION FORM kl", k 1, 7-/, F32 'S, coolp ci4#~ uw?4 Ann+((flsr u( I IM k 0(--') ( il-gq'qt __,_____, ___O _ (1 ) SzeJvq-qqifCl Sq:5 <:6-% 1{t % AniZL,--- op 30') ( Cf') n.i ( i4 cjev-v h ad m_'btsfe ..cl* ' pm ni~ a A c.4' __ _ _ _ _ ___"_ _ __ _ _ _ _ _Page 30 of 105 11 [IT Health Physics Procedure GPP-GGGR-R5104-003 -Attachment B-CY-001 Major C 0 (J~Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00367 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 163-746e'Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones C *.z Priority:
Z 30 D. E] 14 D. 1] 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code code Comment, Preservation Lab Sample ID 9106-0008-001F 5/05/06 11:13 SE C BP x x x Transferred from COC # 2006-00324 9106-0008-003F 5/5/06 13:35 SE C BP X X X Transferred from COC # 2006-00325 9106-0008-004F 5/5/06 13:51 SE C BP X X X Transferred from COC # 2006-00325 9106-0008-005F 5/5/06 14:17 SE C BP X X X Transferred from COC # 2006-00325 9106-0008-006F 5/5/06 14:36 SE C BP X X X Transferred from COC # 2006-00325 9106-0008-006FS 5/5/06 14:36 SE C BP x x x Transferred from COC # 2006-00325 9106-0008-007F 5/5/06 15:03 SE C BP x Transferred from COC # 2006-00325 9106-0008-002F 5/5/06 13:10 SE C BP x x x Transferred from COC # 2006-00325 NOTES: PO #: 002332 MSR #: 0 6--0 7q3 SSWP#NA Z LTP QA E Radwaste QA E] Non QA 1) jRelmq~in Date/Time to/Time Samples Shipped Via:[ Fed Ex Eups EHand E Other Bill of Lading #P 2? 515z1//(v2-Internal Container Temp.: __ Deg. C Custody Sealed?YO NO Custody Seal Intact?YO NO 3) keinquished By Date/Time 4) Redeive~iry v I I~ateiTime Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 1 Major Chain of Custody Form No. 2006-00366 (D Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 1637 L. 7 860-267-2556 11o3-7 ____ V_Project Name: Haddamn Neck Decommissioning Analyses Requested Lab Use Only C)Comments:
V Contact Name & %hone: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories 2040 Savage Road. Charleston SC. 29407 '843 556 8171. Attn. Cheryl Jones W Z Priority:
Z 30 D. [] 14 D. El 7 D. Conainer Sample Size-Media Type &Type .. ...Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 1 jp 9106-0008-008F 5/08/06 08:01 SE C BP X X X Transferred from COC # 2006-00327 0 9106-0008-009F 5/08/06 08:32 SE C BP X X x Transferred from COC #2006-00327 01i 9106-0008-01OF 5/08/06 09:09 SE C BP X X X Transferred from COC # 2006-00327 01*/ 9106-0008-010FS 5/08/06 09:09 SE C BP X x X Transferred from COC # 2006-00327)l 9106-0008-01 IF 5/08/06 09:30 SE C BP x X X Transferred from CC #2006-00327)g 9106-0008-012F 5/08/06 09:53 SE C BP X Transferred from COC # 2006-00327)R 9106-0008-013F 5/08/06 10:16 SE C BP X X x Transferred from COC # 2006-00327 N 9106-0008-014F 5/08/06 10:47 SE C BP X X X Transferred from COC # 2006-00327 NOTES: PO #: 002332 MSR #: 06-6 73 SSWP# NA SLTP QA Fl Radwaste QA E] Non QA Samples Shipped Via: 0 Fed Ex El UPS 0 Hand D Other Bill of Lading #Internal Container Temp.: Deg. C Custody Sealed?YO0 Custody Seal Intact?Y5 NO 1) Relinquished By Date/Time
- 2) Received By Date/Time 3) Relinquished By Date/Time
- 4) Received By Date/Time
.Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW--001 Figure 1. Sample Check-in List DatefTime Received:
AQ14t)U _C1)A26J SDG#: Work Order Number:.Shipping Container ID:.r. I Chain of Custody #. OO'D (4 f')1. Custody Seals. on'shipping container intact?. Yes [-r-o [1 2. Custody Seals dated and signed? Yesj[ I No [3. Chain-of-Custody record present? Yes [-j]'Jo [I.4. Cooler ýtmperature
- 5. Vermiculite/packing materials is: Wet [IDry %. A)iAI 6' Number of samples in shipping container:
f'7. Sample holding times exceeded?
Yes [ ] No 8. Samples have:'Zitape labels-custody seals Y_.Zappropriate sample labels 9. Samples are-....good condition -leaking broken -have air bubbles 10. Were any anomalies identified in sample receipt? Yes [' No 11.,. .Description.
ofanomalies,(include sample numbers): Telephoned to:___ _ "_By._._._'
Page 33 of 105 sellAMPLE RECEIPT & REVIEW FORM 1 PM -eol ber of containers received h number indicated on COC?form is properly signed in puished/received sections?I Bill ,Trarking
- 's, &litional Comnmems S 6(4 1 k 0 RAD Reeipt __"___ ______> x2 area background is observed on samples identied as non uiatedlnon-radioactivel, contact the Radiation Safety group for findher Observed*:
c3p' h-~-- ) -pa&- k~5c lazard Clas Shipped: NI: Initials .l2/-~~ Date: F-Page 34 of 105 SAMPLE RECEIPT & REVIEW FORM"POOR1r,.t PM U Oly Client: Van kee& SDIR0f O rd /~37i e, Date Received: IU- PM(A) Review (ensure non1-corormiug items are resolved or to signing): Received By: C ¢ott) __ ____Sample Receipt Criteria Z CommentslQualiflers (Required for Non-Conforming Items)Shipping containers received intac! Circle Applicable:
seals broken damaged container leaking container other (describe) and sealed? _Sample requiing cod --Circei Coolant # ice bags blue ice dry icc ole ecie iSamples reqluiring cl d ecie 2 preservation within (4 +/- 2 C)?Record preservation method. ._/ I Chain of custody documents included with shipment?4Sample containers intact and Circle Applicable:
seals broken darmaged container leaking container other (describe) sealed?_______________________________
Samples requiring chemical Sample ID's. containers affecled and observed pH:-preservation at proper pH?6 VOA vials free of headspace Sanmle ID's and continers affected: (defined as < 6mm bubble)?_Are Encore containers present?7(If yes, immediately deliver to VOA laboratory).
8 Samples received within holding Id'sand s affeced.time?SSample ID 's on COC match ID 's Sam ple ID's and commurs affectei: on bottles?Date & time on COC match date Sample ID's affected:& time on bottles? I Number of containers received Sample ID's affected: match number indicated on COC?12COC form is properly signed in t o 4" Isfl'L4/Jku d relinquished/received sections?14 Air Bill ,Tracking
- s, & -41 " 3-/'5-. /5 Additional Comments--Z RSO RAD Receipt #Suspected Hazard Information
= *if> x2 area background is observed on samples identified as 'non-0 regulated/non-radioactive".
contact the Radiation Safety group for further Ix 9 investigation.
A lKaG 0logiCal futassiticatlont
!¶" -v I B PCB Regulated?
-Shipped as W T Hazardous C Material?
If yes, contact Waste L Manager or ESH Manager.Maximum Counts Observed*:
, Comrents: Hazard Class Shipped: UNI: Initials c) Date:/ /PM (or PMA) review of Hazard classification:
Page 35 of 105 Connecticut Yankee Statement of Work for Analytical Lab Services cY-iSC-soW-001 Figure 1. Sample Check-in List Date/Time Received:
0"/ t. ,G @ O " SDG#: Work Order Number: Shipping Cdntainer ID:, 71 Z 5 6 4 n i 7 Chain of Custody.#
"* ip " (a., 1. Custody Seals oni shipping container intact?. -Yes f'0 ]2. Custody Seals dated and signed? Yes Lý. o [I -3. Chaia-of-Custody record present? 'Yes [-o [4. Cooler temperature
[/" 5. Vermiculite/packing materials is: Wet VDry [1%6.' ;Number of samples in shipping container:
h 7. Sample holding times exceeded?
Yes-[ ] No.8. Samples have: '"tpe ______hazard labels custody seals ____appropriate sample labels 9. Samples are:in good condition -leaking-broken -have air bubbles 10. Were any anomaliesidentified in sample receipt? Yes [] No E-<11. Description of anomalies, (include sample numbers):
'Sample Custodian/Laboratory: ( _2"4 ,f , -. Date:__________________
Telephoned to: On- By_Page 36 of 105" .11 rý Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-00 I Major iI 1~I5qg 1'9~~~~ .-DI 0~Chain of Custody Form Connecticut Yankee Atomic Power Company No. 2006-00380 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556" Project Name: Haddam Neck Decommissioning Analyses Requested LaUse, Only#1 Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories
<2040 Savage Road. Charleston SC. 29407 <843 556 8171. Attn. Cheryl Jones V)Priority:
Z 30 D. E] 14 D. [] 7 D. Container Sample Size-Media Type &Type m I Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0009-016F 5/15/06 13:28 SE C BP x x Transferred from COC 2006-00352 9106-0009-016FS 5/15/06 13:28 SE C BP x x Transferred from COC 2006-00352 9106-0009-017F 5/15/06 14:03 SE C BP X x Transferred from COC 2006-00352 9106-0009-01 IF 5/15/06 08:05 SE C BP x Transferred from COC 2006-00351 9106-0009-013F 5/15/06 08:35 SE C BP X X Transferred from COC 2006-00351 9106-0009-013FS 5/15/06 08:35 SE C BP X X Transferred from COC 2006-00351 1 9106-0009-014F 5/15/06 08:59 SE C BP x Transferred from COC 2006-00351 9106-0009-015F 5/15/06 09:36 SE C BP X X Transferred from COC 2006-00351 NOTES: PO #: 002332 MSR #: 06-OS/' SSWP# NA 1) Relinquised By Date/Time
- 2) Re Z LTP QA EI Radwaste QA ED Non QA M c ' d y Date/Time Samples Shipped Via:[ Fed Ex LIUPS HI Hand El Other Bill of Lading #-q71-/f ?6- 2AI Internal Container Temp.: __ Deg. C Custody Sealed?YO] NO Custody Seal Intact?YE] NE!3) Min uhh A By -L 11 1 1 uate/ fime 4) Ke eive~I By/Date/Time Health Physics Procedure/ W1'd-J 5-4.1 -/.GPP-GGGR-R5104-003-Attachment B-CY-001 Major , , , -l -", I ... ..0ýCtChain of Custody Form No. 2006-00381 Connecticut Yankee Atomic Power Company 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use OnlyName & Phone: -Comments:
Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories rn 2040 Savage Road. Charleston SC. 29407 0 rn 843 556 8171. Attn. Cheryl Jones 0 z Priority:
Z 30 D. [] 14 D.V] 7 D. Container Sample Size-Media Type &Type Sample Designation Date Time Code Code Code Comment, Preservation Lab Sample ID 9106-0009-001F 5/11/06 13:22 SE C BP x x Transferred from COC 2006-003479106-0009-002F 5/11/06 13:46 SE C BP x x Transferred from COC 2006-00347 9106-0009-003F 5/11/06 14:06 SE C BP X x Transferred from COC 2006-00347 1 9106-0009-004F 5/11/06 14:30 SE C BP x .x Transferred from COC 2006-00347 It 9106-0009-005F 5/11/06 14:55 SE C BP x X -. Transferred from COC 2006-003479106-0009-007F 5/12/06 07:44 SE C BP x X Transferred from COC 2006-00348 3 9106-0009-008F 5/12/06 08:16 SE C BP X X Transferred from COC 2006-00348 ( 9106-0009-009F 5/12/06 08:35 SE C BP X x Transferred from COC 2006-003489106-0009-01OF 5/12/06 09:07 SE C BP x x Transferred from COC 2006-00348 o4 ot 00 0(NOTES: PO #: 002332 MSR #: 06-SSWP# NA Z LTP QA 71 Radwaste QA E Non QA 1) Relinquished By Date/Time
- 2) Rece y Date/Time J) ReiC ouis By Datc/Tim 4) R , FLO ( m V 6 3) Relinquished By Date/Time
- 4) Received t by Date/Time Samples Shipped Via:[K Fed Ex El UPS M Hand fl Other Bill of Lading #:!¢lf Internal Container Temp.: _ Deg. C Custody Scaled?YO ND Custody Seal Intact?YO ND Connecticut Yankee Statement of Work for Analytical Lab Services.cY-1SC-SOw-ooI Figure 1. Sample Check-in List Date/Time Received:
--0 (eWork Order Number: Shipping C.ntainer ID: ,' -'I' -1. Custody Seals. oti shipping container intact?2. Custody Seals dated and signed?3. Chain-of-Custody record present?.4. Cooler temperature
.0 , 5. Vermiculite/packing materials is: 6. "Number of samples in shipping container:
- 7. Sample holding times exceeded?VV 1~, o~~i~<Chain of Custody# -c-Yes Di No (1 Yes[ l No Yes No t ]B Wet [1Dry Yes K No [ ].8. Samples have'Stape " ___hazard labels ( -custody seals -appropriate sample labels 9.9 Samples arc:'i in good condition
.. "leaking.broken have air bubbles 10. Were any anomalies identified in sample receipt? Yes [] No 11....Description of anomalies (include sample numbers):
-.Sample Custodian/Laboratory:-,.2 Date: -,t 0, Telephoned to: On By_Page 39 of 105 Health Physics Procedure GPP-GGGR-R5104-003-Attachment B-CY-001 Major Connecticut Yankee Atomic Power Company Chain of Custody Form No. 2006-00349 362 Injun Hollow Road, East Hampton, CT 06424 860-267-2556 Project Name: Haddam Neck Decommissioning Analyses Requested Lab Use Only Contact Name & Phone: Comments: Jack McCarthy 860-267-2556 Ext. 3024 Analytical Lab (Name, City, State)General Engineering Laboratories
<2040 Savage Road. Charleston SC. 29407 843 556 8171. Attn. Cheryl Jones 00 z Priority:
Z 30 D. [] 14 D. E] 7 D. Container Media Type &Type Sample Desigation Date Time Code Code Code Comment, Preservation Lab Sample ID l 9106-0010-OOIF 5/04/06 10:49 SE C BP X X Transferred from COC 2006-00321 51O 9106-0010-002F 5/04/06 11:12 SE C BP X X Transferred from COC 2006-00321 01 9106-0010-004F 5/04/06 12:48 'SE C BP x X Transferred from COC 2006-00321 p1( 9106-0010-006F 5/04/06 13:34 SE C BP X X Transferred fromCOC_200"-0321 9106-0010-007F 5/04/06 13:21 SE C BP X X Transferred from COC 2006-00321 9106-0010-009F 5/04/06 14:01 SE C BP X X Transferred from COC 2006-00321 9106-0010-019F 5/04/06 14:21 SE C BP X X Transferred from COC 2006-00321
-9106-0010-012F 5/04/06 14:44 SE C BP X X Transferred from COC 2006-00321 9106-0010-013F 5/04/06 15:06 SE C BP X Transferred from COC 2006-00321 NOTES: PO #: 002332 MSR #: 06- 0707 SSWP# NA[9 LTP QA El Radwaste QA[I Non QA 1) RelinquisheoBy Datefr e 2) cve Dy Date/Time 3) Relinquished By Date ime 4) Received By Date/Time Samples Shipped Via:[ Fed Ex EUPS E] Hand[] Other Bill of Lading #3 904.-3 iI5-g1 Internal Container Temp.: /7Deg. C Custody.Sealed?
YF', N 0 Custody Seal Intact?Y 0N 0 Connecticut Yankee Statement of Work for Analytical Lab Services CY-ISC-SOW-001 Figure 1. Sample Check-in List ,t" -~ I I -Date/Time Received:
(714 : [0/ 0 o Work Order Number:.Shipping Cdntainer ID: ?1O'1 1I? b3 'l 1. Custody Seals ori shipping container intact?.2. Custody Seals dated and signed?* 3. Chain-of-Custody record present?.4. Cooler temperature (7 C 5. Vermiculite/packing materials is: 6.' Number of samples in shipping container:.
- 7. Sample holding times exceeded?-07, *7 Chain of Custody# .-6,-Yes "No[]Yes[.No N]Yes [~ No j ]Wet Pq Dry I"t Yes [ I No P 8. Samples have:-tape -hazard labels_._custody seals -appropriate sample labels 9. Samples are:._ n good condition
_ aking-broken have air bubbles 10.11..Were any anomalies identified in sample receipt?Description of anomalies (include sample numbers): Yes [ J No PQ Sample Custodian/Laboratory:.Date:
"-)'1-- 4 Telephoned to: On By.Page 41 of 105 k.-t1ý,,.,I t 0 SAMPLE RECEIPT & REVIEW FORM ff 6#64vL-PM use only Date Received:
PM(A) Review ( e g items a resolved prior to signing): ,Received By: A -rsle , , ~ -Sample Receipt Criteria Couments/Qualifiers (Required for Non-Conforming Items)Sae Ra Z I Shipping containers received intact Circle Applicable:
seals broken damaged container leaking container other (describe) and sealed? I Samples requiring cold Circlc Coolant # ice bags blue ice dry ice M other describe)2 preservation within (4 +/- 2 C)?Record preservation method.Chain of custody documents included with shipment?
__4 Sample containers intact and Circle Applicable:
seals broken damaged container leaking container other (describe) sealed?5 Samples requiring chemical Sample ID's. containers affected and observed pH: preservation at proper pH?6 VOA vials free of headspace Sample ID's and containers affected: (defined as < 6mm bubble?Are Encore containers present?7 (If yes, immediately deliver to-VOA laboratory) 8 Samples received within holding ld~s and tests affected: time?9 Sample ID's on COC match ID's Sampie ID's and containers affected: 9 on bottles?10 Date & time on COC match date Sample ID's affected:& time on bottles?Number of containers received Sampk ID's affected: match number indicated on COC?12 COC form is properly signed in relinquished/received sections?14 Air Bill ,Tracking
- 's, & 7 0%Additional Comments 1 , -RSO RAD Receipt At;5 *ff> x2 area background is observed on samples identified as "non-S H I i regulated/non-radioactive", contact the Radiation Safety group for further*PCBRegul
? Cinvestigation.
A fRadiological Classification?
Maximum Counts Observed*:
6 16 B ]PB Reulatd?
Shipped as DUT Hazar ouas C Material?
If yes, contact Waste Hazard Class Shipped: Manager or ESH Manager. UN/: PM (or PMA) review of Hazard classification:
Initials Date: V" 7 .P" /Page 42 of 105 List of current GEL Certifications as of 15 August 2006[ ... ... ..State ....Alaska SArizona Arkansas CLIA California Colorado Connecticut Dept. of Navy EPA Florida/NELAP Georgia Idaho Illinois Indiana Kansas Kentucky Maryland Massachusetts
-Michigan Nevada New Jersey New York+ North Carolina North Carolina Drinking W North Dakota Oklahoma Pennsylvania South Carolina Tennessee Texas U.S. Dept. of Agriculture US Army Corps of Engineer Utah Vermont Virginia Washington Certification UST-062 AZ0668 88-0651 42D0904046
-01151ICA.... Ge_ .. ...PH-0169 NFESC 413 E87156 E97 156 (FIJNELAP)
N/A 200029-C-SC-0 I E- 10332 270 9903 SC012 SCO02 11501 233 45709 R-158 9904 68-485 101 20001/i 0585001/l0120002 02934 TX213-2006A S-52597 N/A-8037697376 GEL 00151 C223 A--I Page 43 of 105 RADIOLOGICAL ANALYSIS Page 44 of 105 Radiochemistry Case Narrative Connecticut Yankee Atomic Power Co. (YANK)Work Order 168404 Method/Analysis Information Product: Alphaspec Am241, Cm, Solid ALL FSS Analytical Method: DOE EML HASL-300, Am-05-RC Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 555696 554650 554649 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404011 168404012 168404013 168404014 168404015 1201153129 1201153130 1201153131 1201153132 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-OIOF 9106-0005-014F 9106-0008-008F 9106-0009-002F 9106-0009-0117F 9106-0010-001F 9106-0010-012F Method Blank (MB)168340011(9304-01-005C)
Sample Duplicate (DUP)168340011(9304-01-005C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Page 45 of 105 Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340011 (9304-01-005C).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Sample 168404003 (9106-0003-004F) was recounted due to high MDA.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Page 46 of 105 Product: Alphaspec Am241, Cm, Solid ALL FSS DOE EML HASL-300, Am-05-RC Modified Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 557837 554650 554649 Sample ID 168404009 168404010 1201158316 1201158317 1201158318 1201158319 Client ID 9106-0006-005F 9106-0008-006F Method Blank (MB)168404009(9106-0006-005F)
Sample Duplicate (DUP)168404009(9106-0006-005F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (Q0 Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168404009 (9106-0006-005F).
QC Information Page 47 of 105 All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Alphaspec Pu, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Pu-11-RC Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 555697 554650 554649 Page 48 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201153133 1201153134 1201153135 1201153136 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-OIOF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-001F 9106-0010-012F Method Blank (MB)168340011(9304-01-005C)
Sample Duplicate (DUP)168340011(9304-01-005C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-01 1 REV# 14.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Guality Control (OC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340011 (9304-01-005C).
QC Information All of the QC samples met the required acceptance limits.Page 49 of 105 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Pu241, Solid-ALL FSS DOE EML HASL-300, Pu- 11-RC Modified Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 555698 554650 554649 Page 50 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201153137 1201153138 1201153139 1201153140 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-01OF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-OO1F 9106-0010-012F Method Blank (MB)168340011(9304-01-005C)
Sample Duplicate (DUP)168340011(9304-01-005C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-035 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Ouality Control (0C) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340011 (9304-01-005C).
QC Information All of the QC samples met the required acceptance limits.Page 51 of 105 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Manual Integration No manual integrations were performed on data in this batch.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: GFPC, Sr90, solid-ALL FSS Analytical Method: EPA 905.0 Modified Prep Method: Ash Soil Prep Dry Soil Prep GL-RAD-A-021 Method: Dry Soil Prep Analytical Batch Number: 556350 Prep Batch Number: 554650 Dry Soil Prep GL-RAD-A-021 Batch Number: 554649 Page 52 of 105 Sample ID 168404003 168404004 168404012 168404013 168404014 168404015 1201154644 1201154645 1201154646 1201154647 Client ID 9106-0003-004F 9106-0003-015F 9106-0009-002F 9106-0009-017F 9106-0010-001F 9106-0010-012F Method Blank (MB)168404003(9106-0003-004F)
Sample Duplicate (DUP)168404003(9106-0003-004F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-004 REV# 10.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168404003 (9106-0003-004F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Page 53 of 105 Chemical Recoveries All chemical recoveries meet the required acceptance limits for this sample set.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Samples 1201154644 (MB), 1201154645 (9106-0003-004F), 1201154646 (9106-0003-004F), 1201154647 (LCS), 168404003 (9106-0003-004F), 168404004 (9106-0003-015F), 168404012 (9106-0009-002F), 168404013 (9106-0009-017F), 168404014 (9106-0010-001F) and 168404015 (9106-0010-012F) were dried and reweighed due to low matrix spike/laboratory control sample recovery.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Tc99, Solid-ALL FSS Analytical Method: DOE EML HASL-300, Tc-02-RC Modified Analytical Batch Number: 554580 Page 54 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201150561 1201150562 1201150563 1201150564 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-OIOF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-001F 9106-0010-012F Method Blank (MB)168340012(9304-02-003C)
Sample Duplicate (DUP)168340012(9304-02-003C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-005 REV# 13.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Guality Control (0C0 Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340012 (9304-02-003C).
QC Information All of the QC samples met the required acceptance limits.Page 55 of 105 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint Fe55, Solid-ALL FSS Analytical Method: DOE RESL Fe-1, Modified Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Ash Soil Prep Dry Soil Prep 555722 554650 554649 Page 56 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201153222 1201153223 1201153224 1201153225 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-OIOF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-001F 9106-0010-012F Method Blank (MB)168340012(9304-02-003C)
Sample Duplicate (DUP)168340012(9304-02-003C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-040 REV# 3.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340012 (9304-02-003C).
QC Information All of the QC samples met the required acceptance limits.Page 57 of 105 Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Analytical Method: Prep Method: Dry Soil Prep GL-RAD-A-021 Method: Analytical Batch Number: Prep Batch Number: Dry Soil Prep GL-RAD-A-021 Batch Number: Liquid Scint Ni63, Solid-ALL FSS DOE RESL Ni-1, Modified Ash Soil Prep Dry Soil Prep 555723 554650 554649 Page 58 of 105 Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 1201153226 1201153227 1201153228 1201153229 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-01OF 9106-0005-014F 9106-0006-005F Method Blank (MB)168340012(9304-02-003C)
Sample Duplicate (DUP)168340012(9304-02-003C)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-022 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340012 (9304-02-003C).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Page 59 of 105 Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Analytical Method: Analytical Batch Number: Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201150569 1201150570 1201150571 1201150572 LSC, Tritium Dist, Solid-HTD2,ALL FSS EPA 906.0 Modified 554582 Client ID 9106-0002-007F 9106-0002-01 IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-OIOF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-OO1F 9106-0010-012F Method Blank (MB)168340011(9304-01-005C)
Sample Duplicate (DUP)168340011(9304-01-005C)
Matrix Spike (MS)Laboratory Control Sample (LCS)Page 60 of 105 SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-002 REV# 12.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (QC) Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168340011 (9304-01-005C).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis Sample 168404010 (9106-0008-006F) was recounted due to high MDA.Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Page 61 of 105 Qualifier information Manual qualifiers were not required.Method/Analysis Information Product: Liquid Scint C14, Solid AII,FSS Analytical Method: Analytical Batch Number: Sample ID 168404001 168404002 168404003 168404004 168404005 168404006 168404007 168404008 168404009 168404010 168404011 168404012 168404013 168404014 168404015 1201150573 1201150574 1201150575 1201150576 EPA EERF C-01 Modified 554583 Client ID 9106-0002-007F 9106-0002-01IF 9106-0003-004F 9106-0003-015F 9106-0004-005F 9106-0004-015F 9106-0005-01OF 9106-0005-014F 9106-0006-005F 9106-0008-006F 9106-0008-008F 9106-0009-002F 9106-0009-017F 9106-0010-OO1F 9106-0010-012F Method Blank (MB)168404003(9106-0003-004F)
Sample Duplicate (DUP)168404003(9106-0003-004F)
Matrix Spike (MS)Laboratory Control Sample (LCS)SOP Reference Procedure for preparation, analysis and reporting of analytical data are controlled by General Engineering Laboratories, LLC as Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with GL-RAD-A-003 REV# 8.Calibration Information:
Calibration Information All initial and continuing calibration requirements have been met.Standards Information Standard solution(s) for these analyses are NIST traceable and used before the expiration date(s).Page 62 of 105 Sample Geometry All counting sources were prepared in the same geometry as the calibration standards.
Quality Control (0C Information:
Blank Information The blank volume is representative of the sample volume in this batch.Designated QC The following sample was used for QC: 168404003 (9106-0003-004F).
QC Information All of the QC samples met the required acceptance limits.Technical Information:
Holding Time All sample procedures for this sample set were performed within the required holding time.Preparation Information All preparation criteria have been met for these analyses.Sample Re-prep/Re-analysis None of the samples in this sample set required reprep or reanalysis.
Miscellaneous Information:
NCR Documentation Nonconformance reports are generated to document any procedural anomalies that may deviate from referenced SOP or contractual documents.
A nonconformance report (NCR) was not generated for this SDG.Additional Comments Additional comments were not required for this sample set.Qualifier information Manual qualifiers were not required.Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator.
In addition, all data designated for CLP or CLP-like packaging will receive a third level validation upon completion of the data package.Page 63 of 105 The following data validator verified the information presented in this case narrative:
Reviewer/Date:
I§ % , Page 64 of 105 SAMPLE DATA
SUMMARY
Page 65 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Report for YANKOO Connecticut Yankee Atomic Power Co.Client SDG: 168404 GEL Work Order: 168404 The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.ND The analyte concentration is not detected above the detection limit.The above sample is reported on a dry weight basis except where prohibited by the analytical procedure.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis.This data report has been prepared and reviewed in accordance with General Engineering Laboratories, LLC standard operating procedures.
Please direct any questions to your Project Manager, Cheryl Jones.Reviewed by Page 66 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: 9106-0002-007F Proiect: YANKO 1204 Sample ID: 168404001 Client ID: YANK001 Matrix: SE Vol. Recv.: Collect Date: 18-MAY-06 Receive Date: 02-JUN-06 Collector:
Client Moisture:
20.9%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0 Curium-242 U Curium-243/244 U -0.0 AIphaspec Pu, Solid-ALL FSS Plutonium-238 U Plutonium-239/240 U 0 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U.0762 0.00 10853 0.199.0341+/-0.102+/-0.0995+/-0.0717 0.00 0.00 0.0405+/-0.102+/-0.0995+/-0.0717 0.0956 0.138 0.177 0.444 0.323 pCi/g pCi/g pCi/g pCi/g pCi/g+/-0.228 0.181 +/-0.229+/-0.129 0.120 +/-0.129 10.0 +/-6.64 5.08 +/-6.72 4.17 +/-6.67 5.28 +/-6.67 10.7 pCi/g 11.4 pCi/g BXLI 08/11/06 1336 555696 1 BXLI 08/11/06 1633 555697 2 BXL1 08/16/06 1220 555698 3 DFAI 08/09/06 1128 554582 4 ATH2 08/09/06 0324 554583 5 MXPI 08/12/06 1633 555722 6 MXPI 08/11/06 0738 555723 7 EGD1 08/11/06 2027 554580 8 Liquid Scint C14, SolidAlI,FSS Carbon-14 U 0.0813 +/-0.0797 0.0634 +/-0.0797 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 9.90 +/-48.1 32.0 +/-48.1 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 7.02 +/-6.39 5.18 +/-6.40 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.139 +/-0.213 0.173 +/-0.213 0.132 65.9 10.6 0.360 pCi/g pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-1 I-RC Modified EPA 906.0 Modified Page 67 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0002-007F Project: YANK01204 Sample ID: 168404001 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 EPA EERF C-01 Modified 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-I, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 80 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 100 (15%--125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 98 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 75 (15°/w--125%)
Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 76 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 74 (15%-/125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 68 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Report Date: August 21, 2006 9106-0002-01 IF 168404002 SE 19-MAY-06 02-JUN-06 Client 17.4%Project: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.120 Curium-242 U -0.0146 Curium-243/244 U -0.0103 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0121 Plutonium-239/240 U 0.0254 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 6.72 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -0.521 Liquid Scint C14, Solid All,FSS Carbon-14 U 0.023 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 3.93 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 7.52 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.173 Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.154+/-0.122+/-0.0861+/-0.125+/-0.0675+/-7.02+/-7.03+/-0.0828+/-47.7+/-5.81+/-0.203 0.0683 0.0692 0.0487 0.127 0.0381 5.56 5.94 0.0685 31.9 4.68 0.164+/-0.155+/-0.123+/-0.0862+/-0.125+/-0.0675+/-7.05+/-7.03+/-0.0828+/-47.7+/-5.81+/-0.203 0.251 0.303 0.213 0.344 0.167 11.7 12.8 0.143 65.7 9.60 0.341 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1336 555696 1 BXL1 08/11/06 1633 555697 2 BXLI 08/16/06 1237 555698 3 DFAI ATH2 MXP1 MXPI EGD1 08/09/06 1143 554582 08/09/06 0426 554583 08/12/06 1649 555722 08/11/06 0825 555723 08/11/06 2043 554580 4 5 6 7 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-11-RC Modified 3 DOE EML HASL-300, Pu-11-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified Page 69 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0002-011F 168404002 Proiect: YANK01204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 7 8 DOE RESL Fe-1, Modified DOE RESL Ni-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýLiquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%76 100 88 72 76 79 Acceptable Limits (15°16-12501.)
(15%-125%)
(25%o-125°%)
(15 'o-125%)(25/-,125%)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 70 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Report Date: August 21, 2006 9106-0003-004F 168404003 SE 25-APR-06 05-MAY-06 Client 23.5%Project: YANKO 1204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.027 Curium-242 U 0.112 Curium-243/244 U 0.0217 AIphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.061 Plutonium-239/240 U 0.0551 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 8.31 Rad Gas Flow Proportional Counting GFPC, So9o, solid-ALL FSS Strontium-90 U -0.00343 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.603 Liquid Scint C14, SolidAllFSS Carbon-14 U 0.0937 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 7.68 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 5.74 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.0643 Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+/-0.117+/-0.315+/-0.206+/-0.189+/-0.103+/-5.73 0.153 0.245 0.205 0.176 0.0584 4.40+/-0.117+1-0.315+/-0.206+/-0.189+/-0.103+/-5.78+/-0.0203 0.0172 +/-0.0203 0.488 0.781 0.594 0.449 0.215 9.25 0.036 14.8 0.134 70.4 13.6 0.351 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXL1 08/13/06 0819 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1253 555698 3 BXFI 08/14/06 0834 556350 4+/-8.25+/-0.0813+/-51.2+/-7.12+/-0.198 6.87 0.0642 34.2 6.58 0.169+/-8.25+/-0.0813+/-51.2+/-7.13+/-0.198 DFA1 ATH2 MXPI MXPI EGDI 08/09/06 1159 554582 08/09/06 0529 554583 08/12/06 1706 555722 08/11/06 0912 555723 08/11/06 2059 554580 5 6 7 8 9 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I 1-RC Modified Page 71 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0003-004F 168404003 Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter 3 4 5 6 7 8 9 Qualifier Result Uncertainty DOE EML HASL-300, Pu-I1-RC Modified EPA 905.0 Modified EPA 906.0 Modified EPA EERF C-0I Modified DOE RESL Fe-I, Modified DOE RESL Ni-I, Modified DOE EML HASL-300, Tc-02-RC Modified LC TPU MDA Units DF Analyst Date Time Batch Mtd Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Recovery%
Acceptable Limits Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 42 92 113 59 71 83 76 (15%-125%)
(15%-125%
)(25%- 125%)(25/.- 125%)(15%-125%)
(25%-I125%)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded Page 72 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0003-004F 168404003 Project: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd The above sample is reported on a dry weight basis.Page 73 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Report Date: August 21, 2006 9106-0003-015F 168404004 SE 25-APR-06 05-MAY-06 Client 22.5%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Rad Alpha Spec Analysis Alphaspec Am241, Cm, SolidALL FSS Americium-241 U 0.0456 Curium-242 U 0.113 Curium-243/244 U 0.180 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.0196 Plutonium-239/240 U 0.0326 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U 6.63 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.00477 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 1.03 Liquid Scint C14, SolidAllFSS Carbon-14 0.156 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -9.99 Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U 0.939 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.237 Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd+1-0.155+/-0.181+/-0.239+/-0.121+/-0.0639+/-6.19 0.139 0.0733 0.181 0.118 0.00 4.86+/-0.155+/-0.182+/-0.240+/-0.121+/-0.064+/-6.22+/-0.0216 0.0179 +/-0.0216 0.387 0.321 0.472 0.324 0.0884 10.2 0.0375 12.6 0.146 59.2 21.6 0.353 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1309 555698 3 BXFI 08/14/06 0834 556350 4+/-7.06+/-0.0912+/-42.7+/-10.1+/-0.213 5.85 0.0699 28.7 10.3 0.170+/-7.06+/-0.0913+/-42.7+/-10.1+/-0.213 DFA1 ATH2 MXP1 MXP I EGD1 08/09/06 1215 554582 08/09/06 0632 554583 08/12/06 1722 555722 08/11/06 1001 555723 08/11/06 2115 554580 5 6 7 8 9 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-lI-RC Modified Page 74 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Project: YANK0 1204 Client ID: YANK001 Vol. Recv.: Client Sample ID: Sample ID: 9106-0003-015F 168404004 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 3 4 5 6 7 8 9 DOE EML HASL-300, Pu-I I-RC Modified EPA 905.0 Modified EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-I, Modified DOE RESL Ni-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Test Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%78 94 101 58 75 62 75 Acceptable Limits ( 150/o- 1250/6)(150-125%)
(25%- 125%)(2 5/- 125%)(15%-125%)
(25%-1250/o)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded Page 75 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis T ~ ~ o T .. T -.. ...lv -- -Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0003-015F 168404004 Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter
- Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd The above sample is reported on a dry weight basis.Page 76 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-005F 168404005 SE 03-MAY-06 12-MAY-06 Client 15.4%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty.
LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U Curium-242 U -Curium-243/244 U -Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -Plutonium-239/240 U -Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis-0.036-0.0169-0.0129+/-0.123+/-0.033+/-0.227 0.157 +/-0.123 0.080 +/-0.0331 0.247 +/-0.227 0.437 0.350 0.619 0.444 0.337 pCi/g pCi/g pCi/g pCi/g pCi/g-0.0217 +/-0.163 0.181 +/-0.163-0.0708 +/-0.0791 0.128 +/-0.0795 9.52 +/-6.00 4.57 +/-6.07 9.61 pCi/g LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.854 Liquid Scint C14, SolidAllFSS Carbon- 14 0.347 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -1.57 Liquid Scint Ni63, Solid ALL FSS Nickel-63 U 6.39 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0198 BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1326 555698 3 DFAI 08/09/06 1231 554582 4 ATH2 08/09/06 0734 554583 5 MXPI 08/12/06 1738 555722 6 MXPI 08/11/06 1017 555723 7 EGDI 08/11/062131 554580 8+/-5.88 4.87 +/-5.88+/-0.097 0.0674 +/-0.0972+/-46.0 30.7 +/-46.0+/-7.62 7.40 +/-7.62+/-0.187 0.156 +/-0.187 10.5 0.141 63.2 15.5 0.324 pCi/g pCi/g pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 3 4 5 DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 906.0 Modified EPA EERF C-01 Modified Page 77 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Client Sample ID: Sample ID: 9106-0004-005F 168404005 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 7 8 DOE RESL Fe-I, Modified DOE RESL Ni-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Test Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýLiquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%65 95 105 78 80 80 Acceptable Limits (15%-125%)
(15%-125%)
(25%-0125%)
(15%-125%)
(25%o- 125%)(15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 78 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company : Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd Contact: Project: East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0004-015F 168404006 SE 03-MAY-06 12-MAY-06 Client 26.5%Project: Client ID: Vol. Recv.: YANK01204 YANK001 Parameter Rad Alpha Spec Analysis Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.1 Curium-242 U -0.(Curium-243/244 U -0.'Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.1 Plutonium-239/240 U -0 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAll,FSS Carbon-14 U 0.1 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.(0823 0154 0994+/-0.203+/-0.0301+/-0.251 0.178 0.0729 0.300+/-0.203+/-0.0302+/-0.251 0466 +/-0.213 0.210 +/-0.213).142 +/-0.108 0.191 +/-0.109 6.64 +/-6.53 5.16 +/-6.57-2.9 +/-7.59 6.60 +/-7.59 0352 +/-0.0868 0.0713 +/-0.0868 1.88 +/-46.8 31.3 +/-46.8 3.88 +/-7.46 7.40 +/-7.46 0894 +/-0.198 0.163 +/-0.198 0.469 0.319 0.713 0.521 0.483 10.8 14.2 0.149 64.4 15.5 0.338 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1342 555698 3 DFAI 08/09/06 1247 554582 4 ATH2 08/09/06 0837 554583 5 MXPI 08/12/06 1754 555722 6 MXP1 08/11/06 1033 555723 7 EGDI 08/11/06 2147 554580 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 5 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 906.0 Modified EPA EERF C-01 Modified Page 79 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0004-015F Project: YANKO1204 Sample ID: 168404006 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-1, Modified 7 DOE RESL Ni-1, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 72 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 72 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 94 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 73 (15%-/125%)
Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 80 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 78 (15%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 80 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd Contact: Project: East Hampton, Connecticut 06424 Mr. Jack McCarthy Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0005-OIOF 168404007 SE 02-MAY-06 09-MAY-06 Client 56.2%Project: Client ID: Vol. Recv.: YANKO 1204 YANKOO Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -'Curium-242 U -0 Curium-243/244 U -0 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0 Plutonium-239/240 U 0 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.128.0115.0333.0548.0195+/-0.0939+/-0.128+/-0.122 0.142 +/-0.0942 0.147 +/-0.128 0.149 +/-0.122 0.385 0.450 0.401 0.403 0.322 pCi/g pCi/g pCi/g pCi/g pCi/g+/-0.169 0.158 +/-0.170+/-0.121 0.117 +/-0.121 10.4 +/-6.89 5.27 +/-6.97 0.00 +/-6.86 5.76 +/-6.86 11.1 pCi/g 12.4 pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXL1 08/16/06 1358 555698 3 DFAI 08/09/06 1303 554582 4 ATH2 08/09/06 1017 554583 5 MXPI 08/12/06 1811 555722 6 MXPI 08/11/06 1049 555723 7 EGD1 08/11/06 2203 554580 8 Liquid Scint C14, SolidAllFSS Carbon-14 U Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0636+/-0.0801 0.0644 +/-0.0801 36.1 +/-44.1 28.7 +/-44.1 7.26 +/-10.2 10.0 +/-10.2-0.05 +/-0.199 0.169 +/-0.199 0.135 59.0 20.9 0.351 pCi/g pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 3 4 5 DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-] I-RC Modified EPA 906.0 Modified EPA EERF C-01 Modified Page 81 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-010F Project: YANK01204 Sample ID: 168404007 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-I, Modified 7 DOE RESL Ni-1, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 85 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 91 (15%-/125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 92 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 81 (15°/-125%)
Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 64 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 77 (15%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 82 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Report Date: August 21, 2006 9106-0005-014F 168404008 SE 02-MAY-06 09-MAY-06 Client 32.3%Proiect: Client ID: Vol. Recv.: YANKO 1204 YANKOO I Parameter Qualifier Rt Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0'Curium-242 U -Curium-243/244 U 0.Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.Plutonium-239/240 U -0.Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon- 14 U 0.(Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0 esult Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 0591 0.04 0634 0694 0287 4.68 6.02 0892 19.8 5.41'.134+/-0.219+/-0.0554+/-0.261+/-0.106+/-0.098+/-8.01+/-6.38+/-0.0827+/-46.3+/-7.91+/-0.192 0.231 0.134 0.249 0.160 0.127 6.48 4.90 0.0655 30.6 7.77 0.167+/-0.219+/-0.0557+/-0.261+/-0.106+/-0.0981+/-8.02+/-6.38+/-0.0827+/-46.3+/-7.91+/-0.192 0.608 0.494 0.646 0.434 0.369 13.6 10.6 0.137 62.9 16.2 0.346 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1633 555697 2 BXLI 08/16/06 1415 555698 3 DFA 1 ATH2 MXPI MXPI EGDI 08/09/06 1319 554582 08/09/06 1424 554583 08/12/06 1827 555722 08/11/06 1106 555723 08/11/06 2218 554580 4 5 6 7 8 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I 1-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified Page 83 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21,2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0005-014F Project: YANK01204 Sample ID: 168404008 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 DOE RESL Fe-1, Modified 7 DOE RESL Ni-1, Modified 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 50 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 61 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL FS 74 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 76 (15%-/125%)
Carrier/Tracer Recovery Liquid Scint Ni63, Solid-ALL FS 76 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 75 (15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 84 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0006-005 F 168404009 SE 28-APR-06 12-MAY-06 Client 16.5%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -0.Curium-242 U -0.Curium-243/244 U -0.1 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U 0.4 Plutonium-239/240 U 0.04 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U -Liquid Scint C14, SolidAllFSS Carbon-14 0 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Ni63, Solid-ALL FSS Nickel-63 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U -0.01 0851 0253 0479+/-0.136+/-0.0495+/-0.0542 0.106 +/-0.136 0.120 +/-0.0496 0.131 +/-0.0545 0183 +/-0.113 0.110 +/-0.113 0122 +/-0.0662 0.0694 +/-0.0662 4.43 +/-5.83 4.67 +/-5.85 2.02 +/-6.67 5.76 +/-6.67 p.142 +/-0.0798 0.061 +/-0.0799 12.6 +/-47.6 31.7 +/-47.6 7.70 +/-9.56 9.31 +/-9.56 0659 +/-0.185 0.156 +/-0.185 0.390 0.525 0.443 0.303 0.221 9.82 12.4 0.127 65.3 19.5 0.323 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g BXL1 08/16/06 0949 557837 1 BXL1 08/11/06 1633 555697 3 BXL1 08/16/06 1431 555698 4 DFAI 08/09/06 1335 554582 5 ATH2 08/09/06 1719 554583 6 MXPI 08/12/06 1843 555722 7 MXP1 08/11/06 1122 555723 8 EGDI 08/11/06 2234 554580 9 The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 5 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-11-RC Modified DOE EML HASL-300, Pu-11-RC Modified EPA 906.0 Modified Page 85 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0006-005F 168404009 Project: YANKO 1204 Client ID: YANKOO Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 6 7 8 9 EPA EERF C-Ol Modified DOE RESL Fe-I, Modified DOE RESL Ni-I, Modified DOE EML HASL-300.
Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Ni63, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%76 93 105 72 64 81 Acceptable Limits (15%-125%)
(15%-125%)
(25%-125%)
(15%-125%)
(25%--125%)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 86 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0008-006F 168404010 SE 05-MAY-06 26-MAY-06 Client 34.8%Project: YANK01204 Client ID: YANKOO Vol. Recv.: Parameter Rad Alpha Spec Analysis Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U (Curium-242 U (Curium-243/244 U -0.Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.'Plutonium-239/240 U 0.01 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon- 14 U C Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0+/-0.195+/-0.202+/-0.0316+/-0.0711+/-0.113 0.0758 0.00 0.0766+/-0.196+/-0.203+/-0.0317 0.332 0.280 0.335 0.275 0.317 9.75 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 0.0967 +/-0.0712 0.118 +/-0.113 14.9 +/-6.37 4.64 +/-6.51 0.00 +/-6.06 5.09 +/-6.06 1.107 +/-0.0846 0.0664 +/-0.0846 15.1 +/-41.4 27.5 +/-41.4'.258 +/-0.225 0.179 +/-0.225 BXL1 08/16/06 0949 557837 1 BXL1 08/11/06 1633 555697 3 BXL1 08/16/06 1447 555698 4 DFAI 08/10/06 2150 554582 5 ATH2 08/09/06 1822 554583 6 MXPI 08/12/06 1900 555722 7 EGD1 08/11/062251 554580 8 10.7 pCi/g 0.139 56.6 0.373 pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Am-05-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 DOE EML HASL-300, Pu-I I-RC Modified 5 EPA 906.0 Modified 6 EPA EERF C-01 Modified 7 DOE RESL Fe-I, Modified Page 87 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0008-006F 168404010 Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 8 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýLiquid Scint Fe55, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS 77 94 103 72 71 (15%-I125%)
(15%-125%)
(25%-.125%)
(15%-/125%)
(15%-I125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GCIMS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 88 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address: 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: 9106-0008-008F Proiect: -YANK01204 Sample ID: 168404011 Client ID: YANKOOI Matrix: SE Vol. Recv.: Collect Date: 08-MAY-06 Receive Date: 26-MAY-06 Collector:
Client Moisture:
35.7%Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0969 Curium-242 U -0.0482 Curium-243/244 U -0.0576 Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.0397 Plutonium-239/240 U -0.0315 Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 11.5 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U 0.00 Liquid Scint C14, SolidAllFSS Carbon-14 U -0.0238 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -10.7 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0956+/-0.192+/-0.142+/-0.202 0.152 0.132 0.240+/-0.193+/-0.142+/-0.203 0.426 0.446 0.603 0.328 0.353 10.7 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g+/-0.096 0.125 +/-0.096+/-0.114 0.137 +/-0.114+/-6.72 5.08 +/-6.80+/-5.92 4.97 +/-5.92+/-0.0745 0.0636 +/-0.0745+/-40.9 27.5 +/-40.9+/-0.211 0.174 +/-0.211 BXLI 08/11/06 1434 555696 1 BXL1 08/11/06 1633 555697 2 BXL1 08/16/06 1504 555698 3 DFA1 08/09/06 1407 554582 4 ATH2 08/09/06 1924 554583 5 MXPI 08/12/06 1916 555722 6 EGDI 08/11/06 2307 554580 7 10.7 pCi/g 0.133 pCi/g 56.8 pCi/g 0.361 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300.Am-05-RC Modified 2 DOE EML HASL-300, Pu-11-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 906.0 Modified 5 EPA EERF C-01 Modified 6 DOE RESL Fe-l, Modified Page 89 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Report Date: August 21, 2006 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Client Sample ID: 9106-0008-008F Proiect: YANKO 1204 Sample ID: 168404011 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 7 DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Test Recovery%
Acceptable Limits Americium-243 Alphaspec Am241, Cm, Solid ALL 65 (15%-125%)
Plutonium-242 Alphaspec Pu, Solid-ALL FSS 98 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Pu241, Solid-ALL Fý 96 (25%-125%)
Carrier/Tracer Recovery Liquid Scint Fe55, Solid-ALL FS 76 (15%-125%)
Carrier/Tracer Recovery Liquid Scint Tc99, Solid-ALL FS 74 (15%- 125%)Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 90 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Qualifier Result 91 06-0009-002F 168404012 SE 11-MAY-06 08-JUN-06 Client 33%Proiect: YANK01204 Client ID: YANKOOI Vol. Recv.: Parameter Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U -(Curium-242 U Curium-243/244 U Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -(Plutonium-239/240 U Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 Rad Gas Flow Proportional Counting 0.00144 0.0192 0.013+1-0.155+/-0.145+/-0.268 0.166 0.135 0.281+1-0.155+/-0.145+/-0.268 0.458 0.455 0.687 0.122 0.122 pCi/g pCi/g pCi/g pCi/g pCi/g 0.00587 +/-0.0493 0.0279 +/-0.0494 0.0186 +/-0.0492 0.0278 +/-0.0493 13.6 +/-6.90 5.13 +/-7.01 10.8 pCi/g GFPC, Sr90, solid-ALL FSS Strontium-90 Rad Liquid Scintillation Analysis U 0.0151 +/-0.0146 0.0114 +/-0.0146 0.0242 pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1632 555697 2 BXLI 08/16/06 1520 555698 3 BXFI 08/14/06 0834 556350 4 DFAI 08/09/06 1422 554582 5 ATH2 08/09/06 2027 554583 6 MXPI 08/12/06 1932 555722 7 EGDI 08/11/06 2323 554580 8 LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U Liquid Scint C14, SolidAllFSS Carbon-14 U 0 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0 4.12 +/-8.36 6.70 +/-8.36.046 +/-0.0755 0.0613 +/-0.0755 12.9 +/-40.6 26.8 +/-40.6.078 +/-0.203 0.168 +/-0.203 14.5 pCi/g 0.128 55.2 0.348 pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Dry Soil Prep Dry Soil Prep GL-RAD-A-021 Analyst Date Time Prep Batch LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-i 1-RC Modified DOE EML HASL-300, Pu-1 1-RC Modified EPA 905.0 Modified Page 91 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0009-002F 168404012 Proiect: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 6 7 8 EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FýGFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%61 98 94 69 81 75 Acceptable Limits (15°/-125%)( 15%-/125%)
(25%-/125%)
(25/-I125%)
(15%-125%)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 92 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -ww.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0009-017F 168404013 SE 15-MAY-06.
08-JUN-06 Client 28.4%Project: Client ID: Vol. Recv.: YANKO 1204 YANK001 Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.Curium-242 U 0.Curium-243/244 U -(Alphaspec Pu, Solid-ALL FSS Plutonium-238 U -0.C Plutonium-239/240 U 0.Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U 0.Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium U I Liquid Scint C14, Solid All, FSS Carbon-14 U 0.Liquid Scint Fe55, Solid-ALL FSS Iron-55 U -Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.+/-0.242+/-0.220+/-0.214+/-0.0529+/-0.0513 0.230 +/-0.243 0.171 +/-0.220 0.256 +/-0.214 0.0299 +/-0.0529 0.00 +/-0.0514 0.574 0.509 0.627 0.131 0.0709 pCi/g pCi/g pCi/g pCi/g pCi/g+/-6.66 4.95 +/-6.77+/-0.0151 0.0116 +/-0.0151+/-7.98 6.65 +/-7.98+/-0.0759 0.0625 +/-0.0759 10.4 pCi/g 0.0246 pCi/g BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 1632 555697 2 BXLI 08/16/06 1536 555698 3 BXFI 08/14/06 0833 556350 4 DFAI 08/09/06 1438 554582 5 ATH2 08/09/06 2129 554583 6 MXPI 08/12/06 1949 555722 7 EGD1 08/11/06 2338 554580 8 14.4 pCi/g 0.131 pCi/g-61.9 +/-150 102 +/-150 0628 +/-0.200 0.165 +/-0.200 210 pCi/g 0.343 pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I I-RC Modified 3 DOE EML HASL-300, Pu-I I-RC Modified 4 EPA 905.0 Modified Page 93 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0009-017F 168404013 Project: Client ID: Vol. Recv.: YANKO 1204 YANKOOI Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 6 7 8 EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu24 l, Solid-ALL FýGFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%
Acceptable Limits 64 (15%-125%)
91 (15%-125%)
96 (25%-125%)
72 (25%-/125%)
73 (15%-125%)
79 (15%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 94 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: Qualifier Result 9106-0010-001F 168404014 SE 04-MAY-06 17-MAY-06 Client 27.3%Proiect: YANKO 1204 Client ID: YANKOOI Vol. Recv.: Parameter Rad Alpha Spec Analysis Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Alphaspec Am241, Cm, Solid ALL FSS Americium-241 U 0.0 Curium-242 U 0.Curium-243/244 U 0.Alphaspec Pu, Solid ALL FSS Plutonium-238 U (Plutonium-239/240 U -0.Liquid Scint Pu241, Solid ALL FSS Plutonium-241 Rad Gas Flow Proportional Counting GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.Rad Liquid Scintillation Analysis+/-0.227+/-0.167+/-0.242 0.238 0.00 0.241+/-0.227+/-0.168+/-0.242+/-0.181 0.143 +/-0.182+/-0.0865 0.0951 +/-0.0866 0.628 0.231 0.634 0.331 0.235 10.0 0.0262 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 13.0 +/-6.44 4.78 +/-6.54 0128 +/-0.0141 0.0125 +/-0.0141 BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 2250 555697 2 BXLI 08/16/06 1553 555698 3 BXF1 08/14/06 0833 556350 4 DFAI 08/09/06 1454 554582 5 ATH2 08/09/06 2232 554583 6 MXPI 08/12/06 2005 555722 7 EGD1 08/11/06 2354 554580 8 LSC, Tritium Dist, Solid-HTD2,ALL FSS Tritium L Liquid Scint C14, SolidAllFSS Carbon-14 L Liquid Scint Fe55, Solid-ALL FSS Iron-55 L 0.548+/-7.50 6.25 +/-7.50 13.5 pCi/g 0.0555 +/-0.0809 0.0655 +/-0.0809-18.1 +/-47.6 32.3 +/-47.6 0.137 66.6 0.347 pCi/g pCi/g pCi/g Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.134 +/-0.205 0.167 +/-0.205 The following Prep Methods were performed Method Description Dry Soil Prep Dry Soil Prep GL-RAD-A-021 Analyst Date Time Prep Batch LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description I DOE EML HASL-300, Am-05-RC Modified 2 DOE EML HASL-300, Pu-I 1-RC Modified 3 DOE EML HASL-300, Pu-11 -RC Modified 4 EPA 905.0 Modified Page 95 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0010-00IF 168404014 Proiect: YANK01204 Client ID: YANKOOI Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 6 7 8 EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-1, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL F5 GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%50 85 99 74 70 75 Acceptable Limits (15%-/125%)
(15°-/125%)
(25%- 125%)(25%-125%)
(15%-125%)
(15%-125%)
Notes: The Qualifiers in this report are defined as follows* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 96 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: Matrix: Collect Date: Receive Date: Collector:
Moisture: 9106-0010-012F 168404015 SE 04-MAY-06 17-MAY-06 Client 28.1%Proiect: YANKO 1204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd Rad Alpha Spec Analysis AIphaspec Am241, Cm, Solid ALL FSS Americium-241 U Curium-242 U Curium-243/244 U AIphaspec Pu, Solid-ALL FSS Plutonium-238 U -(Plutonium-239/240 U Liquid Scint Pu241, Solid-ALL FSS Plutonium-241 U Rad Gas Flow Proportional Counting 0.110-0.0547-0.126+/-0.184+/-0.141+/-0.184 0.140 0.192 0.245+/-0.184+/-0.141+/-0.185 0.00157 +/-0.126 0.122 +/-0.126 0.0867 +/-0.0869 0.0406 +/-0.0872 8.31 +/-6.16 4.77 +/-6.21 0.386 0.544 0.597 0.291 0.128 10.0 0.0263 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g GFPC, Sr90, solid-ALL FSS Strontium-90 U -0.0 Rad Liquid Scintillation Analysis LSC, Tritium Dist, Solid HTD2,ALL FSS Tritium U 0 Liquid Scint C14, SolidAlLFSS 0771 +/-0.0144 0.0124 +/-0.0144 BXLI 08/11/06 1434 555696 1 BXLI 08/11/06 2250 555697 2 BXL1 08/16/06 1609 555698 3 BXF1 08/14/06 0833 556350 4 DFAI 08/09/06 1510 554582 5 ATH2 08/09/06 2334 554583 6 MXPI 08/12/06 2021 555722 7 EGD1 08/12/06 0010 554580 8 1.896+/-6.17 5.11 +/-6.17 11.0 pCi/g Carbon-14 U 0.0162 +/-0.0763 0.0633 +/-0.0763 Liquid Scint Fe55, Solid-ALL FSS Iron-55 U 23.3 +/-49.3 32.5 +/-49.3 Liquid Scint Tc99, Solid-ALL FSS Technetium-99 U 0.0577 +/-0.206 0.171 +/-0.206 0.132 67.0 0.354 pCi/g pCi/g pCi/g The following Prep Methods were performed Method Description Analyst Date Time Prep Batch Dry Soil Prep Dry Soil Prep GL-RAD-A-021 LXM2 08/03/06 1534 554649 The following Analytical Methods were performed Method Description 1 2 3 4 DOE EML HASL-300, Am-05-RC Modified DOE EML HASL-300, Pu-I I-RC Modified DOE EML HASL-300, Pu-I I-RC Modified EPA 905.0 Modified Page 97 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com Certificate of Analysis Company: Connecticut Yankee Atomic Power Address : 362 Injun Hollow Rd East Hampton, Connecticut 06424 Contact: Mr. Jack McCarthy Project: Soils PO# 002332 Report Date: August 21, 2006 Client Sample ID: Sample ID: 9106-0010-012F 168404015 Project: YANK01204 Client ID: YANK001 Vol. Recv.: Parameter Qualifier Result Uncertainty LC TPU MDA Units DF Analyst Date Time Batch Mtd 5 6 7 8 EPA 906.0 Modified EPA EERF C-01 Modified DOE RESL Fe-I, Modified DOE EML HASL-300, Tc-02-RC Modified Surrogate/Tracer recovery Americium-243 Plutonium-242 Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Carrier/Tracer Recovery Alphaspec Am241, Cm, Solid ALL Alphaspec Pu, Solid-ALL FSS Liquid Scint Pu241, Solid-ALL FS GFPC, Sr90, solid-ALL FSS Liquid Scint Fe55, Solid-ALL FS Liquid Scint Tc99, Solid-ALL FS Recovery%
Acceptable Limits 81 (15%-125%)
91 (15%-125%)
99 (25%-0125%)
68 (25%-125%)
74 (15%-0125/%)
75 (15%-/125%)
Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported> Result is greater than value reported A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded The above sample is reported on a dry weight basis.Page 98 of 105 I~. I QUALITY CONTROL DATA Page 99 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Client: Connecticut Yankee Atomic Power 362 Injun Hollow Rd Reoort Date: August 21, 2006 Page 1 of 6 East Hampton, Connecticut Contact: Mr. Jack McCarthy Workorder:
168404 PnrmnasmP Srnmnle A nil A)C Units RPD%REC% Range Anist Date Time Parmname NOM Sam le Oual r Rad Alpha Spec Batch 555696 QC1201153130 168340011 DUP Americium-241 Curium-242 Curium-243/244 QC1201153132 LCS.Americium-241 Curium-242 Curium-243/244 QC1201153129 MB Americium-241 Curium-242 Curium-243/244 QC1201153131 168340011 MS Americium-241 Curium-242 Curium-243/244 U -0.000522 Uncert: +/-0.0385 TPU: +/-0.0385 U 0.00 Uncert: +/-0.0756 TPU: +/-0.0756 U -0.0177 Uncert: +/-0.0764 TPU: +/-0.0765 12.8 Uncert: TPU: Uncert: TPU: 15.5 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU: 13.3 U -0.000522 Uncert: +/-0.0385 TPU: +/-0.0385 U 0.00 Uncert: +/-0.0756 TPU: +/-0.0756 16.1 U -0.0177 Uncert: +/-0.0764 TPU: +/-0.0765 U 0.0578+/-0.278+/-0.279 U -0.0405+/-0.0562+/-0.0565 U -0.0517+/-0.257+/-0.257 12.8+/- 1.84+/-2.70 U -0.0328+/-0.0454+/-0.0457 14.3+/- 1.94+/-2.92 U 0.0471+/-0.157+/-0.157 U -0.0469+/-0.0459+/-0.0464 U -0.00385+/-0.210+/-0.210 pCi/g 204 pCi/g 200 pCi/g 98 pCi/g (0%- 100%) BXLI 08/11/06 14:34 (0%- 100%)(0%- 100%)100 (75%-125%)
pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 92 (75%-125%)
U 12.0+/-1.38+/-2.08 0.0427+/-0.0837+/-0.0839 15.9+/-1.58+/-2.61 91 (75%-125%)
99 (75%-125%)
Batch 555697 QC1201153134 168340011.
DUP Plutonium-238 U-0.0155 U 0.0237 pCi/g 956 (0%- 100%) BXLI 08/11/06 22:51 Page 100 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 2 of 6 Parmname NOM 5Samnle 011al OC UJnits~ RPD%REC%Range Anist Date Time Rad Alpha Spec Batch 555697 Plutonium-239/240 QC1201153136 LCS Plutoniurn-238 Plutonium-239/240 QC1201153133 MB Plutonium-238 Plutonium-239/240 QC1201153135 168340011 MS Plutonium-238 Uncert: +/-0.0215 TPU: +/-0.0216 U 0.0414 Uncert: +/-0.0934 TPU: +/-0.0935 Uncert: TPU: 11.8 Uncert: TPU: Uncert: TPU: Uncert: TPU: U -0.0155 Uncert: +/-0.0215 TPU: +/-0.0216 12.3 U 0.0414 Uncert: +/-0.0934 TPU: +/-0.0935 U 7.28 Uncert: +/-6.30 TPU: +/-6.35 U+/-0.0465+/-0.0466-0.0489+/-0.124+/-0.124 pCi/g 2410 (0%- 100%)(75%-125%)
U 0.155+/-0.141+/-0.142 11.5+/-0.856+/-1.32 U 0.0552+/-0.186+/-0.186 U -0.0978+/-0.0892+/-0.0899 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 98 (75%-125%)
08/11/06 22:50 U 0.0539+/-0.112+/-0.112 10.3+/-0.796+/-I.19 (75%-125%)
08/11/06 22:51 Plutonium-239/240 84 (75%-125%)
Batch 555698 QC1201153138 168340011 DUP Plutonium-241 U 10.1+/-6.39+/-6.46 pCi/g 0 (0% -100%) BXL I QC1201153140 LCS Plutonium-241 QCI201153137 MB Plutonium-241 137 Uncert: TPU: Uncert: TPU: 138 U Uncert: TPU: 145+/-12.5+/-19.9 U 8.57+/-6.93+/-6.98 pCi/g pCi/g pCi/g 106 (75%-125%)
08/16/06 16:41 08/16/06 17:14 08/16/06 16:25 08/16/06 16:58 QC1201153139 168340011 MS Plutonium-241 7.28+/-6.30+/-6.35 Batch 557837 QC1201158317 168404009 DUP Americium-241 Curium-242 142+/-12.4+/-19.7 0.167+/-0.220+/-0.221 0.241 103 (75%-125%)
U -0.0851 Uncert: +/-0.136 TPU: +/-0.136 U -0.0253 U u pCi/g 616 pCi/g 247 (0%- 100%) BXLI 08/16/06 09:49 (0%- 100%)Page 101 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 3 of 6 Pa.rmnnme NOmI'-amnle 012al QC Units RPD%REC% Range Anist Date Time Rad Alpha Spec Batch 557837 Curiumn-243/244 QC1201158319 Americium-241 Uncert: +/-0.0495 TPU: +/-0.0496 U -0.0479 Uncert: +/-0.0542 TPU: +/-0.0545 LCS Curium-242 Curium-243/244 QC1201158316 Americium-241 Curium-242 MB 24.5 Uncert: TPU: Uncert: TPU: 29.7 Uncert: TPU: Uncert: TPU: Uncert: TPU: Uncert: TPU:+/-0.334+/-0.335 U 0.0761+/-0.149+/-0.149 25.4+/-2.47+/-4.16 U 0.0477+/-0.127+/-0.127 27.0+/-2.54+/-4.38 U 0.234+/-0.275+/-0.277 U 0.00+/-0.152+/-0.152 U -0.0551+/-0.0624+/-0.0628 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 879 (0%- 100%)91 (75%-125%)
104 (75%-125%)
Curiumn-243/244 QC1201158318 168404009 MS Americium-241 Curium-242 Curium-243/244 26.4 U -0.0851 Uncert: +/-0.136 TPU: +/-0.136 U -0.0253 Uncert: +/-0.0495 TPU: +/-0.0496 32.4 U -0.0479 Uncert: +/-0.0542 TPU: +/-0.0545 U 29.1+/-2.97+/-5.01 0.126+/-0.247+/-0.248 31.7+/-3.12+/-5.39 110 (75%-125%)
98 (75%-125%)
Rad Gas Flow Batch 556350 QC1201154645 168404003 DUP Strontium-90 QC1201154647 LCS Strontium-90 U -0.00343 Uncert: +/-0.0203 TPU: +/-0.0203 1.56 Uncert: TPU: U -0.00637+/-0.0152+/-0.0152 1.30+/-0.0563+/-0.0881 U 0.0176+/-0.018+/-0.018 pCi/g 0 (0% -100%) BXFI 08/14/06 08:33 pCi/g pCi/g 83 (75%-125%)
QC1201154644 MB Strontium-90 Uncert: TPU: Page 102 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 4 of 6 Parmname NOM Sample Oual (C Units RPD%REC% Range Anist Date Time Rad Gas Flow Batch 556350 QC1201154646 168404003 MS Strontium-90 Rad Liquid Scintillation Batch 554580 QC1201150562 168340012 DUP Technetium-99 QC]201150564 LCS Technetium-99 1.58 U -0.00343 Uncert: +/-0.0203 TPU: +/-0.0203 1.29+/-0.0535+/-0.0813 pCi/g 82 (75%-125%)
U 0.0338 Uncert: +/-0.192 TPU: +/-0.192 13.1 Uncert: TPU: U 0.266+/-0.226+/-0.226 13.6+/-0.496+/-0.599 U 0.0311+/-0.177+/-0.177 pCi/g 0 (0% -100%) EGDI QCI201150561 Technetium-99 MB pCi/g pCi/g pCi/g 103 (75%-125%)
08/12/06 00:42 08/12/06 01:14 08/12/06 00:26 08/12/06 00:58 Uncert: TPU: QC1201150563 168340012 MS Technetium-99 13.0 U Uncert: TPU: 0.0338+/-0.192+/-0.192 12.0+/-0.523+/-0.602 92 (75%-125%)
Batch 554582 QC1201150570 168340011 DUP Tritium QC1201150572 LCS Tritium QC1201150569 MB Tritium QC1201150571 168340011 MS Tritium U 1.77 Uncert: +/-8.20 TPU: +/-8.20 68.3 Uncert: TPU: Uncert: TPU: U 1.62+/-7.47+/-7.47 76.2+/-14.0+/-14.1 U 0.586+/-8.01+/-8.01 61.8+/-12.2+/-12.3 pCi/g 0 (0% -100%) DFA I pCi/g pCi/g pCi/g 111 (75%-125%)
08/09/06 15:42 08/09/06 16:14 08/09/06 15:26 08/09/06 15:58 61.3 U Uncert: TPU: 1.77+/-8.20+/-8.20 101 (75%-125%)
Batch 554583 QC1201150574 168404003 DUP Carbon- 14 QC1201150576 LCS Carbon- 14 U 0.0937 Uncert: +/-0.0813 TPU: +/-0.0813 U 0.0422+/-0.075+/-0.0751 7.14+/-0.508+/-0.520 pCi/g 0 (0%- 100%) ATH2 08/10/06 01:39 7.27 Uncert: TPU: pCi/g 98 (75%-125%)
08/10/06 03:00 QC1201150573 MB Page 103 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.corn Workorder:
168404 Parmname Rad Liquid Scintillation Batch 554583 Carbon- 14 QC1201150575 168404003 MS Carbon- 14 Batch 555722 QC1201153223 168340012 DUP Iron-55 QC1201153225 LCS Iron-55 QCI201153222 MB Iron-55 QC1201153224 168340012 MS Iron-55 Batch 555723 QC1201153227 168340012 DUP Nickel-63 NOM Uncert: TPU: 15.1 Uncert: TPU: Uncert: TPU: 641 Uncert: TPU: Uncert: TPU: 717 Uncert: TPU: QC Summary Sample Qal QC U -0.0315+/-0.0776+/-0.0776 U 0.0937 13.8+/-0.0813
+/-1.00+/-0.0813
+/-1.03 U -26.5 U 5.83+/-65.1 +/-36.9+/-65.1 +/-36.9 660+/-56.2+/-67T2 U 18.2+/-39.6+/-39.6 U -26.5 688+/-65.1 +/-60.2+/-65.1 +/-71.6 U 3.79. U 6.68 Page 5 of 6 Units RPD% REC% Range Anist Date Time pCi/g pCi/g 92 (75%-125%)
08/10/06 02:43 pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g pCi/g 0 (0% -100%) vIXPI 103 (75%-125%)
96 (75%-125%)
08/12/06 20:54 08/12/06 21:27 08/12/06 20:38 08/12/06 21:11 08/11/06 11:55 08/11/06 12:27 08/11/06 11:38 08/11/06 12:11 0 Uncert: +/-5.39 +/TPU: +/-5.40 +/QC1201153229 LCS Nickel-63 512 Uncert: +/TPU: +/QC1201153226 MB Nickel-63 U Uncert: +/TPU: +/QC1201153228 168340012 MS Nickel-63 530 U 3.79 Uncert: +/-5.39 +/TPU: +/-5.40 +/Notes: The Qualifiers in this report are defined as follows:* A quality control analyte recovery is outside of specified acceptance criteria< Result is less than value reported Result is greater than value reported-7.43-7.43 479-22.4-27.1 15.7-9.92-9.93 511-23.5-28.7 (0% -100%) vAXPI 94 (75%-125%)
96 (75%-125%)
Page 104 of 105 GENERAL ENGINEERING LABORATORIES, LLC 2040 Savage Road Charleston SC 29407 -(843) 556-8171 -www.gel.com QC Summary Workorder:
168404 Page 6 of 6 Parmname NOM Sample Qual QC Units RPD% REC% Range Anist Date Time A The TIC is a suspected aldol-condensation product B Target analyte was detected in the associated blank BD Results are either below the MDC or tracer recovery is low C Analyte has been confirmed by GC/MS analysis D Results are reported from a diluted aliquot of the sample H Analytical holding time was exceeded J Value is estimated N/A Spike recovery limits do not apply. Sample concentration exceeds spike concentration by 4X or more R Sample results are rejected U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.UI Gamma Spectroscopy--Uncertain identification X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Y QC Samples were not spiked with this compound A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL h Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.** Indicates analyte is a surrogate compound.A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptence criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result.For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary.Page 105 of 105 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Attachment 2b Split Sample Assessment Forms (2 Pages)
Comiecticut Yankee Decommissioning Project Health Physics Procedure 24265-000-GPR-GGGR-R5124-000 Attachment A Split Sample Assessment Form Survey Area Survey 0005 Survey Discharge Canal#:9106 Unit #: Unit Name: Sample Plan or WPIR#: 2006-021 SML #: 9106-0005-003 Sample
Description:
Comparison of split samples collected from sample measurement location #03 and analyzed using gamma spectroscopy by an off-site vendor laboratory.
The standard sample was 9106-0005-003F the comparison sample was 9106-0005-003FS.
STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable (Y/N)Value Error Range Value Error Ratio Cs-137 3.39E-02 1.89E-02 2 NONE- 3.31E-01 2.67E-02 9.76 N/A Co-60 3.15E-01 1.76E-02 18 0.75- 1.33 6.18E-01 3.69E-02 1.96 N Sr-90 1.15E-02 3.23E-03 4 0.50- 2.00 4.13E-03 4.35E-03 0.36 N/A K-40 1.11E+0I 4.20E-01 26 0.75 1.33 1.16E+01 4.38E-01 1.05 Y Comments/Corrective Actions: In consideration of Cs- 137 results, guidance for agreement ranges, obtained from USNRC Inspection Procedure 84750, does not address resolution ratios less than 4, therefore, a determination of acceptability for such rations is not appropriate.
Since Co-60 has a likelyhood to be present in the sample matrix in particulate form, one would not neccassarily expect it to be Table is provided to show acceptance criteria used homogenuously mixed from processing of the sample-split aliqot. to assess split samples.Regarding Sr-90 results, the guidance is primarily intended for use with gamma spectroscopy (Sr-90 was measured using liquid scintillation).
Resolution Agreement Range Consequently, a much smaller quantity of media was used for the 4 7 0.50 2.00 analyses from the sample and its split (on the order of 1 gram). A much 8 15 0.60 1.66 higher level of sample homogenization than is routinely performed 16 50 0.75 1.33 would be required to achieve consistent agreement.
While the measurement and sample preparation methodology is appropriate for 51 200 0.80 1.25 FSS purposes, the cited guidance considers that the sample > 200 0.85 1.18 methodology may not be well suited for sample analyses by means other than gamma spectroscopy.
As K-40 was found to be present in both samples at an acceptable level of agreement, no further action is warranted.
Performed By: Date: Reviewed By: Date: WPIR -Work Plan and Inspection Record SML -Sample Measurement Location designation Z I Page I of I Connecticut Yankee Decommissioning Project Health Physics Procedure 24265-000-GPR-GGGR-R5124-000 Attachment A Split Sample Assessment Form Survey SSurvey 0005 urvey Unit Discharge Canal Area#: 90 it #: Name: Sample Plan or WPIR#: 2006-0021 SML #: 9106-0005-018 Sample
Description:
Comparison of split samples collected from sample measurement location #18 and analyzed using gamma spectroscopy by an off-site vendor laboratory.
The standard sample was 9106-0005-018F, the comparison sample was 9106-0005-018FS.
STANDARD COMPARISON Radionuclide Activity Standard Resolution Agreement Activity Standard Comparison Acceptable (Y/N)Value Error Range Value Error Ratio Cs-137 3.39E-02 1.54E-02 2 N/A 1.05E-01 3.98E-02 3.10 N/A Co-60 4.19E-02 1.62E-02 3 N/A 0.OOE+00 7.25E-02 0.00 N/A Sr-90 5.37E-02 7.20E-03 8 0.60- 1.66 4.84E-03 4.30E-03 0.09 N/A K-40 1.11E+01 4.20E-01 26 0.75- 1.33 1.16E+01 4.38E-01 1.05 Y C.omments/Corrective Actions: In consideration ot Cs-13'7 and Co-60 results, guidance for agreement ranges, obtained from USNRC Inspection Procedure 84750, does not address resolution ratios less than 4, therefore, a determination of acceptability for such rations is not appropriate.
K-40 was found to be present in both samples at an acceptable level of agreement.
Regarding Sr-90 results, the guidance is primarily intended for use with gamma spectroscopy (Sr-90 was measured using liquid scintillation).
Consequently, a much smaller quantity of media was used for the analyses from the sample and its split (on the order of 1 gram). A much higher level of sample homogenization than is routinely performed would be required to achieve consistent agreement.
While the measurement and sample preparation methodology is appropriate for FSS purposes, the cited guidance considers that the sample methodology may not be well suited for sample analyses by means other than gamma spectroscopy.
No further action is warranted.
1 4 1 Table is provided to show acceptance criteria used to assess split samples.Resolution Agreement Range 4 8 16 51 7 15 50 200> 200 0.50 0.60 0.75 0.80 0.85 2.00 1.66 1.33 1.25 1.18 Perfonned By: ,5ý X'Zee'WPIR -Work Plan and Inspection Record SML -Sample Measurement Location designation
/Page I of I DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Attachment 2c Preliminary Data Forms (2 Pages)
Health Physics Procedure GPP-GGGR-R512 1 -001 Attachment B, Rev. CY-00 I MAJOR Health Physics Procedure GPP-GGGR-R5121-001 Attachment B, Rev. CY-001 MAJOR Preliminary Data Review Form -Samples for the Sign Test Survey Unit: 9106- 0005 Survey Unit Name: Discharge Canal Classification:
Survey Media: Type of Survey: Type of Measurement:
Number of Measurements:
Operational DCGL: 2 Soil Final Status Survey Radionuclide Specific 15 1 BASIC STATISTICAL QUANTITIES Cs-137 Co-60 Sr-90 Minimum Value: -2.55E-02
-7.92E-03
-1.93E-03 Maximum Value: 4.73E-01 1.38E+00 5.37E-02 Mean: 1.33E-01 2.49E-01 9.79E-03 Median: 7.09E-02 4.19E-02 6.68E-03 Standard Deviation:
1.34E-01 4.25E-01 1.33E-02 RADIONUCLIDE CONCENTRATION (pCi/g)NUMBER 9106-0005-001F 9106-0005-002F 9106-0005-003F 9106-0005-004F 9106-0005-005F 9106-0005-007F 9106-0005-008F 9106-0005-009F 9106-0005-01OF 9106-0005-01 IF 9106-0005-013F 9106-0005-014F 9106-0005-015F 9106-0005-017F 9106-0005-018F Cs-137 2.88E-02 6.60E-02 3.09E-01 1.63E-01-2.55E-02-5.19E-04 1.86E-01 1.81E-01 2.60E-01 5.76E-02 5.31 E-02 4.73E-01 7.09E-02 1.39E-01 3.39E-02 Co-60 1.91 E-02 8.95E-02 3.15E-01 2.10E-01 9.87E-03-7.92E-03 1.69E-01 2.14E-02 1.38E+00 O.OOE+00 1.55E-02 1.12E+00 2.78E-03 3.43E-01 4.19E-02 Sr-90 5.10E-03 8.79E-03 1.15E-02 6.21 E-03 9.56E-03 5.15E-03-1.56E-03 1.30E-02 1.34E-02 1.49E-02-1.93E-03 3.27E-03 6.68E-03-8.59E-04 5.37E-02 Identified?
Y Y Y Y N N Y Y Y Y Y Y Y Y Y Identified?
N Y Y Y N N Y N Y N N Y N Y Y Identified?
N N Y N Y N N Y Y Y N N N N Y Performed By: Date: .-Date: /6-0D(
Health Physics Procedure 24265-000-GPP-GGGR-R5123-000-Rev.CY-000 Attachment B Health Physics Procedure 24265-000-GPP-GGGR-RS 123 -000-Rev.CY-O00 Attachment B Preliminary Data Review Form -Judgemental Samples Survey Unit: Survey Unit Name: Classification:
Survey Media: Type of Survey: Type of Measurement:
Number of Measurements:
Operational DCGL: 9106- 0005 Discharge Canal 2 Soil Final Status Survey Radionuclide Specific 1 1 BASIC STATISTICAL QUANTITIES Cs-137 Co-60 Sr-90 Minimum Value: -1.86E-02 2.07E-03 9.07E-04 z Maximum Value: -1.86E-02 2.07E-03 9.07E-04 Mean: -1.86E-02 2.07E-03 9.07E-04 Median: -1.86E-02 2.07E-03 9.07E-04 Standard Deviation:
1.36E-01 4.55E-02 3.01E-02 NUMBER 9106-0005-016F RADIONUCLIDE CONCENTRATION Cs-137 Co-60 Sr-90-1.86E-02 2.07E-03 9.07E-04 N (pCi/g)Identified?
N N Performed By: Independent Review: Z,, _ _.,"_Date: /a -2, -4ý9 Date: 6 0 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Attachment 2d Graphical Representation of Data (6 Pages)
Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Quantile Plot For Cesium -137 Survey Unit: 9106-0005 Survey Unit Name: Discharge Canal Mean: 1.33E-01 pCi/g 5.OOE-01 4.OOE-01 L 3.OOE-01 0 2.OOE-01 Q 1.OOE-01 0 o O.OOE+00-1.OOE-01 Percentage Cs-1 37 Rank Percentage
-2.55E-02 1 3 %-5.19E-04 2 10 %2.88E-02 3 17 %3.39E-02 4 23 %5.31 E-02 5 30 %5.76E-02 6 37 %6.60E-02 7 43 %7.09E-02 8 50 %1.39E-01 9 57 %1.63E-01 10 63 %1.81E-01 11 70 %1.86E-01 12 77 %2.60E-01 13 83 %3.09E-01 14 90 %4.73E-01 15 97 %Prepared By: Reviewed By: f/ i Date: -d Date:
Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Quantile Plot For Cobalt -60 Survey Unit: Survey Unit Name: Mean: 9106-0005 Discharge Canal 2.49E-01 pCi/g 1.60E+00 1.40E+00 , -1.20E+00 o 1.OOE+O0 o 8.OOE-01._ 6.OOE-01 --4' 4.OOE-01 o0 2.OOE-01 , -O .O O E + 0 0 4 0 0 0- _-2.OOE-01
--2--n -6)80I Percentage Co-60 Rank Percentage
-7.92E-03 1 3 %0.OOE+00 2 10 %2.78E-03 3 17 %9.87E-03 4 23 %1.55E-02 5 30 %1.91E-02 6 37 %2.14E-02 7 43 %4.19E-02 8 50 %8.95E-02 9 57 %1.69E-01 10 63 %2.10E-01 11 70 %3.15E-01 12 77 %3.43E-01 13 83 %1.12E+00 14 90 %1.38E+00 15 97 %z9e-y Prepared By:* --,-'-". A Reviewed By: Date: la- 2e-01=, Date: / -0 ld-4 -V Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Quantile Plot For Strontium
-90 Survey Unit: 9106-0005 Survey Unit Name: Discharge Canal Mean: 9.79E-03 pCi/g 6.OOE-02 5.OOE-02 4.OOE-02 S3.00E-02 0.2.OOE-02 -t.,-C 1.OOE-02 -- --0.00E+O0 I-1.OOE-02 2 jýj 8 iO Percentage Sr-90 Rank Percentage
-1.93E-03 1 3 %-1.56E-03 2 10 %-8.59E-04 3 17 %3.27E-03 4 23 %5.10E-03 5 30 %5.15E-03 6 37 %6.21E-03 7 43 %6.68E-03 8 50 %8.79E-03 9 57 %9.56E-03 10 63 %1.15E-02 11 70 %1.30E-02 12 77 %1.34E-02 13 83 %1.49E-02 14 90 %5.37E-02 15 97 %Prepared By:-Reviewed By: Date: /2-Date: 4/2 --,e6O0 Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Frequency Plot For Cobalt-60 Survey Unit: 9106-0005 Survey Unit Name: Discharge Canal Mean: 0.249 pCi/g 10 8-I Cr L.L.6 t 4 2 0 0) .1.I¸-I 0.00 0.25 0.50 0.75 1.00 1.25 1.50 Upper End Value (pCilg)Upper End Observation Observation
%Value Frequency Frequency 0.00 2 13%0.25 9 60%0.50 2 13%0.75 0 0%1.00 0 0%1.25 1 7%1.50 1 7%Total 15 100%Prepared By: Date: /0- 30-601 Reviewed By: Date: / 4)- 3-0 -6 6, Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Frequency Plot For Cs -137 Survey Unit: 9106-0005 Survey Unit Name: Discharge Canal Mean: 0.133 pCi/g Upper End Observation Observation
%Value Frequency Frequency 0.10 8 53%0.20 4 27%0.30 1 7%0.40 1 7%0.50 1 7%Total 15 100%Prepared By: Date: /10-30Q-Q)
Reviewed By: Date: /0- -7 Health Physics Procedure GGGR-R5123-Rev.CY-001 Attachment C Frequency Plot For Sr -90 Survey Unit: 9106-0005 Survey Unit Name: Discharge Canal Mean: 0.010 pCi/g 12 10-S6-"m4 U-2-0.01 0.02 0.03 0.04 0.05 0.06 Upper End Value (pCi/g)Upper End Observation Observation
%Value Frequency Frequency 0.01 10 67%0.02 4 27%0.03 0 0%0.04 0 0%0.05 0 0%0.06 1 7%Total 15 100%,rý, Prepared By: Date: Reviewed By: Date: {oi .
DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Attachment 2e Sign Test Calculation (1 Page)
Health Physics Procedure GPP-GGGR-R512 1 -000 Attachment A, Rev. CY-00 I MAJOR Sign Test Calculation Sheet For Multiple Radionuclisdes Survey Unit Number: 9106-0005 Survey Unit Name: Discharge Canal WP&IR#: 2006-021 I TYPE I (c error):0.05 TYPE I (3 error):0.051 Classification
- 2 Radionuclides:
Cs-137 Survey Design DCGL (pCi/g): 6.0116 Co-60 2.8956 Results Cs-137 2.88E-02 6.60E-02 3.09E-01 1.63E-01-2.55E-02-5.19E-04 1.86E-01 1.81E-01 2.60E-01 5.76E-02 5.3 1E-02 4.73E-01 7.09E-02 1.39E-01 3.39E-02 Results Co-60 1.91E-02 8.95E-02 3.15E-01 2.1 OE-0 I 9.87E-03-7.92E-03 1.69E-0 I 2.14E-02 1.38E+00 0.OOE+00 1.55E-02 1.12E+00 2.78E-03 3.43E-01 4.19E-02 Weighted Sum (W,)1.57E-02 4.93E-02 1.70E-0 1 1.05E-01 7.28E-03 1.55E-03 8.80E-02 4.85E-02 5.3 1E-0I 2.22E-02 1.25E-02 4.68E-01 1.84E-02 1.41 E-01 6.57E-02 DCGL-Result 9.84E-01 9.5 1E-01 8.30E-01 8.95E-01 9.93E-01 9.98E-01 9.12E-01 9.5 1E-01 4.69E-0 I 9.78E-01 9.87E-0 I 5.32E-01 9.82E-01 8.59E-01 9.34E-0 I Sign I 1 1 Number of Positive Differences (S+): 15 Critical Value: 11 Survey Unit: Meets Acceptance Criterion Performed By: Independent Review: Date: Date: />v Page 1 of 1 DISCHARGE CANAL SURVEY UNIT 9106-0005 RELEASE RECORD Attachment 2f COMPASS DQA Surface Soil Report with Retrospective Power Curve (3 Pages)
DQA Surface Soil Report Assessment Summary Site: Planner(s):
Survey Unit Name: Report Number: Survey Unit Samples: Reference Area Samples: Test Performed:
Judgmental Samples: Assessment
==
Conclusion:==
9106-0005 (19 mrem/yr)Dale Randall 9106-0005 1 15 0 Sign Test Result: Not Performed 0 EMC Result: Not Performed Reject Null Hypothesis (Survey Unit PASSES)Retrospective Power Curve g.4-U I.I-I.'-I='S 1~.1 1 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0 I ______-1 1. ______ _____ ~ZZE~-! I ______ -I--v _ ziz21______ 4i___ ______ -~---1--: I______ _____ -k-i ______: L_ -A= ~ zzi ______ ______ ______ ______0.0 0.2 0.4 0.6 0.8 1.0 Unity Rule Sum-of-Rados, including backgruund
--Prospective Power U 1-beta ....Actual Power-LBGR --Estimated Power DCGL ---- Retrospective Power 1.2 COMPASS vl.0.0 110131112006 Page 1 DQA Surface Soil Report Survey Unit Data NOTE: Type = "S" indicates survey unit sample.Type = "R" indicates reference area sample.Sample Number 9106-0005-001 F 9106-0005-002F 9106-0005-003F 9106-0005-004F 9106-0005-005F 9106-0005-007F 9106-0005-008F 9106-0005-009F 9106-0005-01OF 9106-0005-011 F 9106-0005-013F 9106-0005-014F 9106-0005-015F 9106-0005-017F 9106-0005-018F Survey Unit Data NOTE: Type = "S" indicates survey unit sample.Type = "R" indicates reference area sample, Type S S S S S S S S S S S S S S S Co-60 (pCi/g)0.02 0.09 0.32 0.21 0.01-0.01 0.17 0.02 1.38 0 0.02 1.12 0 0.34 0.04 Cs-137 (pCi/g)0.03 0.07 0.31 0.16-0.03 0 0.19 0.18 0.26 0.06 0.05 0.47 0.07 0.14 0.03 SrY-90 (pCilg)0.01 0.01 0.01 0.01 0.01 0.01 0 0.01 0.01 0.01 0 0 0.01 0 0.05 Modified Data (Unity Rule SOR)NOTE: Type = "S" indicates survey unit sample.Type = "R" indicates reference area sample.Sample Number 9106-0005-001 F 9106-0005-002F 9106-0005-003F 9106-0005-004F 9106-0005-005F 9106-0005-007F 9106-0005-008F 9106-0005-009F 9106-0005-01OF 9106-0005-011 F 9106-0005-013F 9106-0005-014F 9106-0005-015F 9106-0005-017F 9106-0005-018F Modified Data (Unity Rule SOR)NOTE: Type = "S" indicates survey unit sample.Type = "R" indicates reference area sample.Type S S S S S S S S S S S S S S S Sum-of-Ratios (SOR)0.02 0.05 0.17 0.1 0.01 0 0.09 0.05 0.53 0.02 0.01 0.47 0.02 0.14 0.07 COMPASS vI.0.0 10131/2006 Page 2 IDQA Surface Soil Report Basic Statistical Quantities Summary Statistic Survey Unit Background DQO Results Sample Number 15 N/A N=13 Mean (SOR) 0.12 N/A 0.17 Median (SOR) 0.05 N/A N/A Std Dev (SOR) 0.16 N/A 0.06 High Value (SOR) 0.53 N/A N/A Low Value (SOR) 0.00 N/A N/A COMPASS vl.O.0.P 10/3112006 Page 3