ML071900442

Orise Interim Report for Completed Analyses for Samples from Set Eighteen, from the Indian Point Power Station, Buchanan, Ny, Dtd 03/30/07

ML071900442
Person / Time
Site:	Indian Point
Issue date:	03/30/2007
From:	Condra D Oak Ridge Institute for Science & Education
To:	Kottan J NRC Region 1
References
IR-06-007, RFTA 06-001
Download: ML071900442 (10)

Text

OAK RIDGE INSTITUTE FOR SCIENCE AND EDUCATION Distribution approval and concurrence

Technical Management Team Member Quality Manager March 30,2007 InitiabA Mr. Jim Kottan U.S. Nuclear Regulatory Commission Region I 475 Allendale Road IGng of Prussia, PA 19406

SUBJECT:

INTERIM REPORT FOR COMPLETED ANALYSES FOR SAMPLES FROM SET EIGHTEEN, FROM THE INDIAN POINT POWER STATION, BUCHANAN, NEW YORK [INSPECTION REPORT NO. 050-247/2006-0071

[RFTA NO. 06-0011

Dear Mr. Kottan:

The Oak Ridge Institute for Science and Education (ORISE) received set 18, consisting of seven water samples, associated with the Indian Point Power Station on December 7 and 8,2006. Sample analysis was initiated based on your previous direction for handling samples from ths licensee. Sample identification and collection data for the samples addressed in ths report are presented in Table 1. Gamma spectroscopy, the hard-to-detect betas (iron-55, nickel-63, and tritium), technetium-99, total radiostrontium, alpha spectroscopy, plutonium-241, and carbon-14 data are provided in Tables 2 through 8, respectively.

The pertinent procedure references are provided in each specific table. ORISE's Quality Control (QC) requirements were met for these analyses.

The QC fies are available for your review upon request. Additional reports wdl follow after the completion of the requested analyses.

ORISE has removed the Ni-59 data due to problems with the calculation associated with the concentration of thls radionuclide.

ORISE is discontinuing the reporting of Ni-59 data und ths problem can be resolved.

My contact information is listed below. You may also contact Wade Ivey at 865.576.9184 with any questions or comments.

Dale Condra, Manager Laboratory RDC:wPI:km Enclosures C: T. Carter, NRC/FSME/DWMEP 7518 E. IOlox-Davin, NRC/FSME/TWFN 8A23 M. Roberts, NRC Region I File 1697 E. Abelquist, ORISEg S. IGk, ORISE v7 J. White, NRC Regiony Voice: 86 5.24 1.3242 Fax: 865.241.3248 E-mad Dale.Condra @orau.org TABLE 1 ORISE Sample ID 1697W0116" 1697M006bb 1697W0117 1697M0067 1697W0118 1697M0068 SAMPLE IDENTIFICATIONS AND COLLECTION DATA INDIAN POINT POWER STATION BUCHANAN, NEW YORK NRC Region I Collection Collection Sample ID Date Time RO-543-95' 12/5/2006 11:45 1697W0116 filter 12/5/2006 11:45 P-1217 12/6/2006 10:45 1697W0117 filter 12/6/2006 10:45 Ft. Montgomery 12/5/2006 900 1697W0118 filter 12/5/2006 900 1697W0119 1697M0069 1697W0120 1697M0070 1697W0121 1697M0071 1697W0122 1697M0072 RO-18 12/5/2006 10:25 1697W0119 filter 12/5/2006 10:25 RO-543-50 12/5/2006 11:30 1697WO120 filter 12/5/2006 11:30 Mw-51-(011) 12/6/2006 11:45 1697W0121 filter 12/6/2006 11:45 MW-40-(010) 12/7/2006 9:37 1697W0122 filter 12/7/2006 937 Indian Point Power Station projects/l697/Data Tables/2007-03-30 Data Tables Set 18 TABLE 2 ORISE Sample ID BJ NRC Region I Radionuclide Concentrations Sample ID CO-58 CO-60 cs-134 CONCENTRATIONS OF SELECTED GAMMA EMITTING RADIONUCLIDES IN WATER SAMPLES GAMMA SPECTROSCOPY CP1, REVISIOF INDIAN POINT POWER STATION BUCHANAN, NEW YORK 1697W0121 MW-51-(011)

-0.6 f. 2.7 1.1 f. 2.3 1.5 f. 2.5 1697W0122 MW-40-(010)

-0.3 f. 1.7 0.3 f. 1.7 0.1 k 1.9 15 -1.0 f. 4.5 0.2 f. 1.8 1697W0116 1697W0117 1697W0118 1697W0119 b RO-543-95'

-1.5 f. 2.2 0.4 f. 2.2 -0.2 f. 2.1 P-1217 1.2 f. 2.4 0.8 f. 2.2 -0.1 f. 2.3 Ft. Montgomery 1.1 L- 1.7 0.9 k 1.7 1.0 f: 1.7 RO-18 -1.0 f. 2.4 0.9 f. 2.4 -0.7 f. 2.5 -1.8 f. 4.3 -1.6 f. 2.0 2.3 k 2.5 0.2 k 3.1 -0.4 f. 2.1 11 "The range of MDCs for the selected radionuclides is 2.8 pCi/L to 4.4 pCi/L. bUncertainties represent the 95% confidence level, based on total propagated uncertainties Indian Point Power Station projects/l697/Data Tables/2007-03-30 Data Tables Set 18 TABLE 3 ORISE Sample ID 1697W0116 1 69W0117 1697W0118 CONCENTRATIONS OF HARD TO DETECT BETA EMITTING RADIONUCLIDES IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide Concentrationsa (pCi/L) NRC Region I Sample ID Fe-55b Ni-63" H-3d RO-543-95' 8 k 20' , 33 -5.0 k 5.5 9.7 200 k 210 , 360 P-1217 -4 k 19 33 2.3 & 5.7 9.7 80 & 200 360 Ft.Montgomery 4 & 20 , 33 0.4 ? 5.6 . 9.7 50 k 200 . 360 1697W0120 1697W0121 1697W0119 I RO-18 I 1 k 19 . 33 I 1.9 k 5.7 . 9.7 1 110 k 210 . 360 11 360 360 I MW-51-(011)

-2 k 19 , 33 0.2 k 5.6 , 9.7 70 & 200 . RO-543-50

-5 f. 19 , 33 1.4 k 5.7 9.7 260 t 220 1697W0122 I MW-40-(010)

I 13 & 20 , 33 I 1.8 k 5.7 9.7 I 290 k 220 , 360 "The MDCs for each radionuclide are after the comma. "e-55 analyzed using procedure AP13, Revision 4. 'Ni-63 analyzed using procedure AP17, Revision 0. d11-3 analyzed using procedure AP2, Revision

15. eUncertainties represent the 95%

confidence level, based on total propagated uncertainties.

Indian Point Power Station projects/l697/Data Tables/2007-03-30 Data Tables Set 18 TABLE 4 ORISE NRC Region I Sample ID Sample ID 1697WOl16 RO-543-95' 1697W0117 P-1217 1697W0118 Ft. Montgomery 1697W0119 RO-18 1697W0120 RO-543-50

1697 WO 12 1 MW-5 1-(011) 1697W0122 MW-40-(010)

CONCENTRATIONS OF TECHNETIUM-99 (Tc-99) IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP5, REVISION 16; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide Concentrationsa (pCi/L) 14.0 5.0 t 8.3 , 3.4 k 8.2 , 14.0 2.7 2 8.2 , 14.0 -1.8 k 8.1 , 14.0 6.4 t 8.3 , 14.0 -2.7 +_ 8.1 , 14.0 5.2 ? 8.3 , 14.0 b Indian Point Power Station projects/l697/Data Tables/2007-03-30 Data Tables Sct 18 TABLE 5 ORISE Sample ID NRC Region I Radionuclide Concentrations, Sample ID TPUs, and MDCS" @Ci/L) 11 1697\)(10116 I RO-543-95' I 0.29 ? 0.36b . 0.60 11 1697W0118 1697W0119 1697W0120 11 1697W0117 I P-1217 I -0.09 k 0.39 , 0.69 11 Ft. Montgomery

-0.08 & 0.34 , 0.60 RO-18 -0.10 k 0.37 , 0.66 RO-543-50 0.18 k 0.39 . 0.66 .1697W0121 1697W0122 MW-51-(011) 0.37 ? 0.36 , 0.61 Mw-40-(010) 0.61 k 0.35 , 0.56 Indian Point Power Station projects/l697/Data Tables/2007-03-30 Data 'Tables Set 18 F TABLE 6 a 9 -. CD --. 8 --. 2 2 + U \ 7J' g n 1697W0119 RO-18 0.11 f: 0.18 , 0.31 0.00 f 0.09 , 0.20 0.07 f: 0.17 , 0.30 0.02 k 0.08 , 0.16 1697M0069 1697W0119 filter 0.01 f 0.02 , 0.04 0.00 f 0.01 , 0.02 0.00 f: 0.02 , 0.04 0.01 k 0.01 , 0.01 1697W0120 RO-543-50 0.17 k 0.21 , 0.34 -0.02 f 0.10 , 0.23 0.06 f 0.16 , 0.30 -0.02 f 0.08 , 0.20 1697M0070 1697W0120 filter 0.02 f 0.02 , 0.04 0.00 f: 0.01 , 0.02 0.01 f 0.02 , 0.03 0.00 k 0.02 , 0.06 1697W0121 nnXr-51-(011) 0.09 f: 0.15 , 0.26 0.05 f 0.08 , 0.13 -0.05 f: 0.11 , 0.26 -0.06 k 0.10 , 0.26 16971110071 1697W0121 filter 0.01 f 0.02 , 0.04 0.01 f 0.01 , 0.02 0.00 f 0.02 , 0.04 -0.002 f 0.005 , 0.02 1697W0122 MW (0 1 0) 0.23 f: 0.21 , 0.33 0.02 f 0.09 , 0.19 -0.02 f: 0.13 , 0.28 0.06 k 0.07 , 0.06 1697M0072 1697W0122 filter 0.01 k 0.02 , 0.04 0.00 f 0.01 , 0.03 0.00 f 0.02 , 0.04 -0.01 f 0.01 , 0.03 CONCENTRATIONS OF SELECTED ALPHA EMITTING RADIONUCLIDES IN SUSPENDED AND DISSOLVED FRACTIONS OF WATER SAMPLES AP11, REVISION 3; CP2, REVISION 12 INDIAN POINT POWER STATION BUCHANAN, NEW YORK TABLE 6 (Continued)

CONCENTRATIONS OF SELECTED ALPHA EMITTING RADIONUCLIDES IN SUSPENDED AND DISSOLVED FRACTIONS OF WATER SAMPLES AP11, REVISION 3; CP2, REVISION 12 INDIAN POINT POWER STATION BUCHANAN, NEW YORK 5 %e MDCs are after the comma. 8 buncertainties represent the 95% confidence level, based on total propagated uncertainties.

$ 'Zero values are due to rounding.

U N dSignificant figures expanded tn avoid repnrting a TPLT of 7ero at the request of the inspector E 2 F B E + W TABLE 7 ORISE Sample ID 1697W0116 1697M0066 1697W0117 1697M0067 CONCENTRATIONS OF PLUTONIUM-241 IN SUSPENDED AND DISSOLVED FRACTIONS OF WATER SAMPLES BY LIQUID SCINTILUTION ANALYSIS AP10, REVISION 2; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK Radionuclide Concentrationsa

@Ci/g of sediment in 100 mL or pCi/L for water) NRC Region I Sample ID RO-543-95'

-1 3 f. 35b , 60 1697W0116 filter 1.6 & 4.5 , 7.6 I?-1217 8 k 33 , 57 1697W0117 filter 1.6

• 4.5 7.7 1697W0118 1697M0068 1697W0119 1697M0069 Ft. Montgomery 8

• 33 , 56 1697W0118 filter

-2.6 f. 4.9 , 8.5 RO-18 3 f. 35 Y 61 1697W0119 filter 3.5 k 4.5 7.4 11 1697W0120 I 1697M0070 1697W0121 1697M0071 1697W0122 1697M0072 RO-543-50 1697W0120 filter 1 f. 10 , 17 MW-51-(011) 23 & 34 , 57 1697W0121 filter

-0.3 k 4.3 , 7.4 MW-40-(010) 14 & 35 9 60 1697WO122 filter -0.2

• 4.2 7.2 "The MDCs are after the comma. 'Uncertainties represent the 95% confidence level, based on total propagated uncertainties Indian Point Power Station projects/l697/Data Tables/2007-03-30 Data Tables Set 18 TABLE 8 ORISE Sample ID 1697w0116 CONCENTRATIONS OF CARBON-14 IN WATER SAMPLES BY LIQUID SCINTILLATION ANALYSIS AP9, REVISION 3; CP4, REVISION 3 INDIAN POINT POWER STATION BUCHANAN, NEW YORK NRC Region I Radionuclide Concentrations, Sample ID TPUs, and MDCS" (pCi/L) RO-543-95' 4 k 1 2b . 20 1697W0117 1697W0118

1697W0119 1697W0120 P-1217 4 t 12 Y 20 Ft. Montgomery 6 k 12 Y 20 RO-18 0" k 12 Y 20 RO-543-50 4 t 12 . 20 1697W0121 1697W0122 "MDCs are after the comma. buncertainties represent the 95"/0 confidence level, based on total propagated uncertainties.

'Zero values are due to rounding.

MW-5 1 -(011) 0 k 12 Y 20 Mw-40-(010) 1 k 12 . 20 Indian Point Power Station projccts/l697/Data Tables/2007-03-30 Data Tables Set 18