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{{#Wiki_filter:CalvertCliffsCalvert CliffsChemical Effects in k fd Ris k-In f orme d GSI-191ResolutionResolution SihDiiWihNRCSff Si xt h Di scuss i on Wi t h NRC S ta ffNovember 13, 2013 AgendaIntroductions ObjectivesforMeetingObjectives for MeetingDiscuss Preliminary Autoclave Test ResultsDiscussion of Chemical Effects PIRT Items Discussion of Alkyds Autoclave Test PlanDiscussion of Integrated Chemical Effects Testing Topics
{{#Wiki_filter:Calvert Cliffs Chemical Effects in Risk-Informed k f               d GSI-191 Resolution Si h Di Sixth Discussion i WiWith h NRC SStaff ff November 13, 2013
-Zinc and Marinite Debris
 
-Chemical Effects Head Loss Loop DesignDiscussionofSmall
Agenda
-ScaleDebrisBypass/PenetrationTestPlan Discussion of SmallScale Debris Bypass/Penetration Test PlanSchedule for future periodic meetings CCNPP AttendeesTom Konerth -Supervisor Mechanical DesignKenGreeneLicensingEngineerKen Greene -Licensing EngineerJohn Swailes -Project Manager GSI-191CraiSellersProjetManaerRIGSI 191Crai g Sellers -Proje c t Mana g er RI GSI-191Steve Kinsey -Chemical Effects TestingJhWChilEffTiJ os h Wargo -Ch em i ca l Eff ects Test i ngJon Cavallo -Coatings Consultant Objectives of MeetingDiscuss Preliminary Autoclave Test ResultsContinue to Work Towards Agreement on Chemical Effects PIRTI CCNPP CHLE 003PIRT I ssues -CCNPP-CHLE-003Review & Work Towards Agreement on Chemical Effects Testing TopicsAlkdAlTPl CCNPP CHLE 007-Alk y d Autoc lave Test Pl an -CCNPP-CHLE-007-Considerations for Zinc -CCNPP-CHLE-008
 
-Considerations for Marinite -CCNPP-CHLE-009IntegratedChemicalEffectsHeadLossLoopDesign
===Introductions===
-Integrated Chemical Effects Head Loss Loop DesignReview & Work Towards Agreement on Small-Scale Strainer Bypass Test Plan -CCNPP-BPPlan-002PresentProposedScheduleforFutureMeetingsPresent Proposed Schedule for Future MeetingsCapture Staff Issues and Concerns Preliminary Autoclave Test ResultsCCNPP-CHLE-006 -Metals
Objectives for Meeting Discuss Preliminary Autoclave Test Results Discussion of Chemical Effects PIRT Items Discussion of Alkyds Autoclave Test Plan Discussion of Integrated Chemical Effects Testing Topics
-Insignificant Concentrations
  - Zinc and Marinite Debris
*Cr, Fe, Ni
  - Chemical Effects Head Loss Loop Design Discussion of Small-Scale Small Scale Debris Bypass/Penetration Test Plan Schedule for future periodic meetings 2
-Very High Ca Concentration
 
*Influenced Revised MariniteScaling Methodology
CCNPP Attendees Tom Konerth - Supervisor Mechanical Design Ken Greene - Licensing Engineer John Swailes - Project Manager GSI-191 Crai Sellers - Project Craig          Proje t Manager Mana er RI GSI-191 GSI 191 Steve Kinsey - Chemical Effects Testing J hW Josh Wargo - Chemical Ch i l EffEffects TTesting i
-Very High Zn Concentration
Jon Cavallo - Coatings Consultant 3
*Pure Zinc >> Galvanized Steel
 
*Influenced Revised Zinc Modeling Methodology
Objectives of Meeting Discuss Preliminary Autoclave Test Results Continue to Work Towards Agreement on Chemical Effects PIRT Issues I       - CCNPP-CHLE-003 CCNPP CHLE 003 Review & Work Towards Agreement on Chemical Effects Testing Topics
-Preliminary Data Insufficient for Additional InsightsCCNPP-CHLE-005-HighTemperature CCNPP CHLE 005 High Temperature
  - Alkyd Alk dAAutoclave l  TTest Pl Plan - CCNPP-CHLE-007 CCNPP CHLE 007
-No Results to Date Chemical Effects PIRT IssuesPIRT Item 2.5 Additional Debris Bed Chemical Reactions
  - Considerations for Zinc - CCNPP-CHLE-008
-Fiberglass & Metals Insensitive
  - Considerations for Marinite - CCNPP-CHLE-009
-Irradiation is not expected to have a chemical effects impact on coatingsPIRT Item 3.9 Concrete Material Aging
  - Integrated Chemical Effects Head Loss Loop Design Review & Work Towards Agreement on Small-Scale Strainer Bypass Test Plan - CCNPP-BPPlan-002 Present Proposed Schedule for Future Meetings Capture Staff Issues and Concerns 4
-Using concrete from Original Plant Construction
 
-All Original Concrete Made On-Site with Same MaterialsPIRT Item 6.4 Coatin gs Dissolution and Leachin g gg-Epoxy Coatings Not Sensitive
Preliminary Autoclave Test Results CCNPP-CHLE-006 - Metals
-Zinc Coatings Used in Tests
  - Insignificant Concentrations
-AlkydCoatingstobeaddressedinAutoclaveTestAlkyd Coatings to be addressed in Autoclave TestOthers Alkyds Autoclave Test Plan -CCNPP-CHLE-007Investigate Chemical Effects from Alkyd Coatings
* Cr, Fe, Ni
-Apply Alkyd Coatings to SS Coupons
  - Very High Ca Concentration
-Include LOCA Debris and Exposed Reactive Materials
* Influenced Revised Marinite Scaling Methodology
-Submerge in Borated Water
  - Very High Zn Concentration
-DissolveBufferat195
* Pure Zinc >> Galvanized Steel
°FDissolve Buffer at 195 F-Expose to LOCA Temperature Profile for 7 Days
* Influenced Revised Zinc Modeling Methodology
-Vacuum Filtration for Head Loss Implicationslfb/-Visua l Examination f or De b ris / Precipitates
  - Preliminary Data Insufficient for Additional Insights CCNPP CCNPP-CHLE-005 CHLE 005 - High Temperature
-Chemical Analysis for Potential Precipitants & OrganicsSection-by Section Review Zinc Considerations -CCNPP-CHLE-008Failed Inorganic Zinc Coatings Historically Treated as 10 µm S pheres for H ydraulic CharacteristicsµpyModeling as such in Chemical Effects Testing Results in Very Large Surface Area of Surrogate MaterialCalvert Cliffs Proposed Approach
  - No Results to Date 5
-IOZ in ZOI and Unqualified Zinc-Rich Coatings Tested using SmoothZincPlateSurrogatewithSameSurfaceAreaas10 Smooth Zinc Plate Surrogate with Same Surface Area as 10 µm Spheres  
 
-Degraded Qualified IOZ Tested using Cured/Aged IOZ CoatedCoponsith2SrfaceAreaofDegradedCoated Co u pons w ith 2 x S urface Area of Degraded Coatings Marinite Considerations -CCNPP-CHLE-009Marinite Fines Debris Historically Treated as 10 µm SpheresforHydraulicCharacteristicsSpheres for Hydraulic CharacteristicsModeling as such in Chemical Effects Testing Results in V e r y L a r ge Su rf ace Ar ea o f So li d M a rini teeyageSuaceeaoSodateCalvert Cliffs Proposed Approach
Chemical Effects PIRT Issues PIRT Item 2.5 Additional Debris Bed Chemical Reactions
-Marinite Fine Debris Tested usin g 1/2" Thick Marinite Board gwith 25% of the Surface Area as 44 µm Spheres
  - Fiberglass & Metals Insensitive
-Marinite non-Fines Tested using 1/2" Thick Marinite Board ithPtltdSfASbdSd w ith P os t u l a t e d S ur f ace Area S u bmerge d or Spraye d Integrated Chemical Effects Head Loss Test LoopVertical Head Loss Column Primary Reaction Chamber(Showing Clearance for Coupons)Heat Exchanger Loop Initial Preparation ChamberLoop Heating & Cooling Small-Scale Bypass Test Plan-CCNPP-BPPlan-002Sensitivity TestsWaterChemistry
  - Irradiation is not expected to have a chemical effects impact on coatings PIRT Item 3.9 Concrete Material Aging
*Design of Experiments
  - Using concrete from Original Plant Construction
-Water Chemistry-Water Temperature
  - All Original Concrete Made On-Site with Same Materials PIRT Item 6.4 Coatings  g Dissolution and Leachingg
-Fiber MixtureRunFiber TypeWater ChemistryTemperature°°Prototypical Strainer
  - Epoxy Coatings Not Sensitive
-Fabricated from Similar °°°°Perforated PlateContinuous Filtration°°°°Section-by Section Review Schedule for Future Periodic MeetingJanuary 2014
  - Zinc Coatings Used in Tests
-ChemicalEffectsBench
  - Alkyd Coatings to be addressed in Autoclave Test Others 6
-TopTestResultsChemical Effects BenchTop Test Results-Final Chemical Effects Screening Test Protocol}}
 
Alkyds Autoclave Test Plan - CCNPP-CHLE-007 Investigate Chemical Effects from Alkyd Coatings
  - Apply Alkyd Coatings to SS Coupons
  - Include LOCA Debris and Exposed Reactive Materials
  - Submerge in Borated Water
  - Dissolve Buffer at 195°F 195 F
  - Expose to LOCA Temperature Profile for 7 Days
  - Vacuum Filtration for Head Loss Implications
  - Visuall Examination ffor Debris b / Precipitates
  - Chemical Analysis for Potential Precipitants & Organics Section-by Section Review 7
 
Zinc Considerations - CCNPP-CHLE-008 Failed Inorganic Zinc Coatings Historically Treated as 10 µµm Spheres p      for Hydraulic y          Characteristics Modeling as such in Chemical Effects Testing Results in Very Large Surface Area of Surrogate Material Calvert Cliffs Proposed Approach
  - IOZ in ZOI and Unqualified Zinc-Rich Coatings Tested using Smooth Zinc Plate Surrogate with Same Surface Area as 10
    µm Spheres
  - Degraded Qualified IOZ Tested using Cured/Aged IOZ Coated Co Coupons pons with ith 2 2x SSurface rface Area of Degraded Coatings 8
 
Marinite Considerations - CCNPP-CHLE-009 Marinite Fines Debris Historically Treated as 10 µm Spheres for Hydraulic Characteristics Modeling as such in Chemical Effects Testing Results in Very e y Large a ge Surface Su ace Area  ea of o Solid So d Marinite a te Calvert Cliffs Proposed Approach
  - Marinite Fine Debris Tested usingg 1/2 Thick Marinite Board with 25% of the Surface Area as 44 µm Spheres
  - Marinite non-Fines Tested using 1/2 Thick Marinite Board with ith P Postulated t l t d SSurface f   A Area SSubmerged b      d or SSprayed d
9
 
Integrated Chemical Effects Head Loss Test Loop Primary Reaction Chamber (Showing Clearance for Coupons)
Vertical Head Loss Column Initial Preparation Chamber Heat Exchanger Loop Loop Heating & Cooling 10
 
Small-Scale Bypass Test Plan-CCNPP-BPPlan-002 Sensitivity Tests
* Design of Experiments
    - Water Chemistry Run Fiber Type  Water Chemistry    Temperature
    - Water Temperature           1  Nukon      Tap                90°F
    - Fiber Mixture              2  Cocktail    Tap                90°F 3  Nukon      Borated Buffer      90°F Prototypical Strainer         4  Cocktail    Borated Buffer      90°F 5  Nukon      Tap                180°F
    - Fabricated from Similar    6  C kt il Cocktail    T Tap                180°F Perforated Plate            7  Nukon      Borated Buffer      180°F 8  Cocktail    Borated Buffer      180°F Continuous Filtration          9  TBD        TBD                135°F 10            TBD (Repeatability Test)
Section-by Section Review 11
 
Schedule for Future Periodic Meeting January 2014
  - Chemical Effects Bench-Top Bench Top Test Results
  - Final Chemical Effects Screening Test Protocol 12}}

Latest revision as of 12:14, 4 November 2019

Ri GSI-191 November 2013 Meeting with NRC Rev 0
ML13319A939
Person / Time
Site: Calvert Cliffs  Constellation icon.png
Issue date: 11/13/2013
From:
Constellation Energy Group, EDF Group
To:
Office of Nuclear Reactor Regulation
Morgan N
Shared Package
ML13319A601 List:
References
Download: ML13319A939 (12)


Text

Calvert Cliffs Chemical Effects in Risk-Informed k f d GSI-191 Resolution Si h Di Sixth Discussion i WiWith h NRC SStaff ff November 13, 2013

Agenda

Introductions

Objectives for Meeting Discuss Preliminary Autoclave Test Results Discussion of Chemical Effects PIRT Items Discussion of Alkyds Autoclave Test Plan Discussion of Integrated Chemical Effects Testing Topics

- Zinc and Marinite Debris

- Chemical Effects Head Loss Loop Design Discussion of Small-Scale Small Scale Debris Bypass/Penetration Test Plan Schedule for future periodic meetings 2

CCNPP Attendees Tom Konerth - Supervisor Mechanical Design Ken Greene - Licensing Engineer John Swailes - Project Manager GSI-191 Crai Sellers - Project Craig Proje t Manager Mana er RI GSI-191 GSI 191 Steve Kinsey - Chemical Effects Testing J hW Josh Wargo - Chemical Ch i l EffEffects TTesting i

Jon Cavallo - Coatings Consultant 3

Objectives of Meeting Discuss Preliminary Autoclave Test Results Continue to Work Towards Agreement on Chemical Effects PIRT Issues I - CCNPP-CHLE-003 CCNPP CHLE 003 Review & Work Towards Agreement on Chemical Effects Testing Topics

- Alkyd Alk dAAutoclave l TTest Pl Plan - CCNPP-CHLE-007 CCNPP CHLE 007

- Considerations for Zinc - CCNPP-CHLE-008

- Considerations for Marinite - CCNPP-CHLE-009

- Integrated Chemical Effects Head Loss Loop Design Review & Work Towards Agreement on Small-Scale Strainer Bypass Test Plan - CCNPP-BPPlan-002 Present Proposed Schedule for Future Meetings Capture Staff Issues and Concerns 4

Preliminary Autoclave Test Results CCNPP-CHLE-006 - Metals

- Insignificant Concentrations

  • Cr, Fe, Ni

- Very High Ca Concentration

  • Influenced Revised Marinite Scaling Methodology

- Very High Zn Concentration

  • Pure Zinc >> Galvanized Steel
  • Influenced Revised Zinc Modeling Methodology

- Preliminary Data Insufficient for Additional Insights CCNPP CCNPP-CHLE-005 CHLE 005 - High Temperature

- No Results to Date 5

Chemical Effects PIRT Issues PIRT Item 2.5 Additional Debris Bed Chemical Reactions

- Fiberglass & Metals Insensitive

- Irradiation is not expected to have a chemical effects impact on coatings PIRT Item 3.9 Concrete Material Aging

- Using concrete from Original Plant Construction

- All Original Concrete Made On-Site with Same Materials PIRT Item 6.4 Coatings g Dissolution and Leachingg

- Epoxy Coatings Not Sensitive

- Zinc Coatings Used in Tests

- Alkyd Coatings to be addressed in Autoclave Test Others 6

Alkyds Autoclave Test Plan - CCNPP-CHLE-007 Investigate Chemical Effects from Alkyd Coatings

- Apply Alkyd Coatings to SS Coupons

- Include LOCA Debris and Exposed Reactive Materials

- Submerge in Borated Water

- Dissolve Buffer at 195°F 195 F

- Expose to LOCA Temperature Profile for 7 Days

- Vacuum Filtration for Head Loss Implications

- Visuall Examination ffor Debris b / Precipitates

- Chemical Analysis for Potential Precipitants & Organics Section-by Section Review 7

Zinc Considerations - CCNPP-CHLE-008 Failed Inorganic Zinc Coatings Historically Treated as 10 µµm Spheres p for Hydraulic y Characteristics Modeling as such in Chemical Effects Testing Results in Very Large Surface Area of Surrogate Material Calvert Cliffs Proposed Approach

- IOZ in ZOI and Unqualified Zinc-Rich Coatings Tested using Smooth Zinc Plate Surrogate with Same Surface Area as 10

µm Spheres

- Degraded Qualified IOZ Tested using Cured/Aged IOZ Coated Co Coupons pons with ith 2 2x SSurface rface Area of Degraded Coatings 8

Marinite Considerations - CCNPP-CHLE-009 Marinite Fines Debris Historically Treated as 10 µm Spheres for Hydraulic Characteristics Modeling as such in Chemical Effects Testing Results in Very e y Large a ge Surface Su ace Area ea of o Solid So d Marinite a te Calvert Cliffs Proposed Approach

- Marinite Fine Debris Tested usingg 1/2 Thick Marinite Board with 25% of the Surface Area as 44 µm Spheres

- Marinite non-Fines Tested using 1/2 Thick Marinite Board with ith P Postulated t l t d SSurface f A Area SSubmerged b d or SSprayed d

9

Integrated Chemical Effects Head Loss Test Loop Primary Reaction Chamber (Showing Clearance for Coupons)

Vertical Head Loss Column Initial Preparation Chamber Heat Exchanger Loop Loop Heating & Cooling 10

Small-Scale Bypass Test Plan-CCNPP-BPPlan-002 Sensitivity Tests

  • Design of Experiments

- Water Chemistry Run Fiber Type Water Chemistry Temperature

- Water Temperature 1 Nukon Tap 90°F

- Fiber Mixture 2 Cocktail Tap 90°F 3 Nukon Borated Buffer 90°F Prototypical Strainer 4 Cocktail Borated Buffer 90°F 5 Nukon Tap 180°F

- Fabricated from Similar 6 C kt il Cocktail T Tap 180°F Perforated Plate 7 Nukon Borated Buffer 180°F 8 Cocktail Borated Buffer 180°F Continuous Filtration 9 TBD TBD 135°F 10 TBD (Repeatability Test)

Section-by Section Review 11

Schedule for Future Periodic Meeting January 2014

- Chemical Effects Bench-Top Bench Top Test Results

- Final Chemical Effects Screening Test Protocol 12