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{{#Wiki_filter:Tennessee Valley Authority, Post Office Box 2000, Soddy Daisy, Tennessee 37384-2000 November 3, 2016 Mr. Robert Alexander Tennessee Department of Environment and Conservation Rosa L. Parks Blvd. 11th Floor, William R. Snodgrass Tennessee Tower Nashville, Tennessee 37243 | {{#Wiki_filter:Tennessee Valley Authority, Post Office Box 2000, Soddy Daisy, Tennessee 37384-2000 November 3, 2016 Mr. Robert Alexander Tennessee Department of Environment and Conservation Rosa L. Parks Blvd. | ||
11th Floor, William R. Snodgrass Tennessee Tower Nashville, Tennessee 37243 | |||
==Dear Mr. Alexander:== | ==Dear Mr. Alexander:== | ||
TENNESSEE VALLEY AUTHORITY (TVA) -SEQUOYAH NUCLEAR PLANT (SQN) -NPDES PERMIT NO. TN0026450 | TENNESSEE VALLEY AUTHORITY (TVA) -SEQUOYAH NUCLEAR PLANT (SQN) - NPDES PERMIT NO. TN0026450 - REQUEST FOR BIOCIDE/CORROSION TREATMENT PLAN (B/CTP) | ||
-REQUEST FOR BIOCIDE/CORROSION TREATMENT PLAN (B/CTP) REVISION APPROVAL Sequoyah Nuclear Plant plans to add Flogard MS6237 to our Biocide/Corrosion Treatment Plan. This chemical will replace Flogard MS6236 for corrosion prevention. | REVISION APPROVAL Sequoyah Nuclear Plant plans to add Flogard MS6237 to our Biocide/Corrosion Treatment Plan. | ||
The SDS for MS6237 is attached. | This chemical will replace Flogard MS6236 for corrosion prevention. The SDS for MS6237 is attached. As shown in the SDS, the active ingredients are phosphoric acid, zinc chloride, and zinc bis(dihydrogen phosphate). MS6237 will be applied at a maximum feed rate of 2.4 ppm. The maximum effluent concentrations will be 0.2 ppm phosphate and 0.2 ppm zinc. | ||
As shown in the SDS, the active ingredients are phosphoric acid, zinc chloride, and zinc bis(dihydrogen phosphate). | * The site would like to begin using the new chemical in mid-December, therefore we are requesting written approval by December 9, 2016. If you have questions, or need additional information, please contact Millicent Garland at 423-843-6714, of Sequoyah's Environmental staff. | ||
MS6237 will be applied at a maximum feed rate of 2.4 ppm. The maximum effluent concentrations will be 0.2 ppm phosphate and 0.2 ppm zinc. | I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. | ||
* The site would like to begin using the new chemical in mid-December, therefore we are requesting written approval by December 9, 2016. If you have questions, or need additional information, please contact Millicent Garland at 423-843-6714, of Sequoyah's Environmental staff. I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. | ~~.t Gregory A Boersc:ig Site Vice President (Interim) | ||
Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. | |||
I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Gregory A Boersc:ig | |||
Sequoyah Nuclear Plant Enclosures cc (Enclosures): | Sequoyah Nuclear Plant Enclosures cc (Enclosures): | ||
Chattanooga Environmental Field Office Division of Water Pollution Control 1301 Riverfront Pkwy, #206 | Chattanooga Environmental Field Office U.S. Nuclear Regulatory Commission () | ||
Division of Water Pollution Control 1301 Riverfront Pkwy, #206 Attn: Document Control Desk Washington, DC 20555 | |||
~ ,.., | |||
Do not eat. drink or smoke when | _.l--1 v | ||
If in eyes: Rinse | \ | ||
Chattanooga, Tennessee 37402 | |||
Version: 3.0 Effective Date: Mar-18-2016 Previous Date: Jun-12-2015 GEPower Water & Process Technologies SAFETY DATA SHEET FLOGARD* MS6237 | |||
: 1. Identification Product identifier FLOGARD MS6237 Other means of identification None. | |||
Recommended use Once-through system treatment Recommended restrictions None known. | |||
Company/undertaking identification GE Betz. Inc. | |||
4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (8001877 1940 | |||
: 2. Hazard(s) identification Physical hazards Corrosive to metals Category 1 Health hazards Acute toxicity, oral Category 4 Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Germ cell mutagenicity Category 2 Reproductive toxicity Category 2 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation OSHA defined hazards Not classified. | |||
Label elements Signal word Danger Hazard statement Moy be corrosive to metals. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. May cause respiratory irritation. Suspected of causing genetic defects. Suspected of damaging fertil ity or the unborn child. | |||
Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep only in original container. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat. drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. | |||
Response If swallowed: Rinse mout h. Do NOT induce vomiting. If on skin (or hoirl: Take off immediately all contaminated clothing. Rinse skin w ith water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously w ith water for several minutes. Remove contact lenses. if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Wash contaminated clot hing before reuse. Absorb spillage to prevent material damage. | |||
Page: 1 /9 | |||
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Store in corrosive resistant container with a resistant .in liner. | |||
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. | |||
Dispose of contents/container to approved local facility. | Dispose of contents/container to approved local facility. | ||
Hazardlsl not otherwise classified None known. (HNOCI Supplemental information None. 3. Composition/information on ingredients Mixtures Components CAS# Percent Phosphoric Acid 7664-38-2 20-40 Zinc chloride 7646-85-7 20-40 Zinc bis(dihydrogen phosphate) 13598-37-3 2.5-10 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our assessment of the potential hazards of this formulation. | Hazardlsl not otherwise classified None known. | ||
: 4. First-aid measures Inhalation | (HNOCI Supplemental information None. | ||
: 3. Composition/information on ingredients Mixtures Components CAS# Percent Phosphoric Acid 7664-38-2 20-40 Zinc chloride 7646-85-7 20-40 Zinc bis(dihydrogen phosphate) 13598-37-3 2.5-10 | |||
Call a POISON CENTER or doctor/physician if you feel unwell. Take off immediately all contaminated clothing. | *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. | ||
Rinse skin with water/shower. | Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our assessment of the potential hazards of this formulation. | ||
Call a physician or poison control center immediately. | : 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. | ||
Chemical burns must be treated by a physician. | Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse. | ||
Wash contaminated clothing before reuse. Rinse immediately with plenty of water for at least 20 minutes Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. | Eye contact Rinse immediately with plenty of water for at least 20 minutes Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. | ||
Call a physician or poison control center immediately. | Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. | ||
Rinse mouth. Do not induce vomiting. | Most important Burning pain and severe corrosive skin damage, Upper respiratory tract irritation. Causes serious eye symptoms/effects, acute and damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye delayed damage including blindness could result. | ||
If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Burning pain and severe corrosive skin damage, Upper respiratory tract irritation. | Indication of immediate medical Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water attention and special treatment immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. | ||
Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Provide general supportive measures and treat symptomatically. | needed Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. | ||
Chemical burns: Flush with water immediately. | General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. | ||
While flushing, remove clothes which do not adhere to affected area. Call an ambulance. | S. Fire-fighting_ measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (C02). | ||
Continue flushing during transport to hospital. | Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. | ||
In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. | Specific hazards arising from the During fire, gases hazardous to health may be formed. | ||
Symptoms may be delayed. IF exposed or concerned: | chemical Special protective equipment and Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand precautions for firefighters breathing apparatus, protective clothing and face mask. | ||
Get medical advice/attention. | Fire fighting -In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider equipment/instructions the hazards of other involved materials. Move containers from fire area if you can do so without risk. | ||
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. | Cool containers I tanks with water spray. | ||
Water fog. Foam. Dry chemical powder. Carbon dioxide (C02). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. -In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider the hazards of other involved materials. | Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. | ||
Move containers from fire area if you can do so without risk. Cool containers I tanks with water spray. Use standard firefighting procedures and consider the hazards of other involved materials. | : 6. Accidental release measures Personal precautions, protective Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low equipment and emergency areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or procedures - vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. | ||
: 6. Accidental release measures Personal precautions, protective | Material name: FLOGARD* MS6237 Page: 2 /9 Version number: 3.0 | ||
Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. | Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up possible. Cover with plastic sheet to prevent spreading. Absorb spillage to prevent material damage. | ||
Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. | Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. | ||
Ensure adequate ventilation. | Small Spills: Wipe up with absorbent material !e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. | ||
Local authorities should be advised if significant spillages cannot be contained. | Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. | ||
For personal protection, see section 8 of the SDS. Page: 2 /9 Methods and materials for | Environmental precautions Avoid discharge into drains, water courses or onto the ground. | ||
: 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist or vapor. Do not get this material in contact with eyes. Do not get this material in contact with skin. Do not taste or swallow. Avoid contact during pregnancy/while nursing. | |||
Cover with plastic sheet to prevent spreading. | Avoid prolonged exposure. Do not get this material on clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. | ||
Absorb spillage to prevent material damage. Absorb in vermiculite, dry sand or earth and place into containers. | * Conditions for safe storage, Store locked up. Store in corrosive resistant container with a resistant inner liner. Store in original tightly including any incompatibilities closed container. Keep only in the original container. Use approved containers only. Protect from freezing. If frozen, thaw completely and mix thoroughly prior to use. Store in a cool, dry place out of direct sunlight. Store away from incompatible materials !see Section 10 of the SOS). Store in accordance with local/regional/national/international regulation. | ||
Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material !e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. | |||
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. | |||
Do not breathe mist or vapor. Do not get this material in contact with eyes. Do not get this material in contact with skin. Do not taste or swallow. Avoid contact during pregnancy/while nursing. Avoid prolonged exposure. | |||
Do not get this material on clothing. | |||
Provide adequate ventilation. | |||
Wear appropriate personal protective equipment. | |||
Observe good industrial hygiene practices. | |||
When using, do not eat, drink or smoke. Wash hands thoroughly after handling. | |||
* Store locked up. Store in corrosive resistant container with a resistant inner liner. Store in original tightly closed container. | |||
Keep only in the original container. | |||
Use approved containers only. Protect from freezing. | |||
If frozen, thaw completely and mix thoroughly prior to use. Store in a cool, dry place out of direct sunlight. | |||
Store away from incompatible materials | |||
!see Section 10 of the SOS). Store in accordance with local/regional/national/international regulation. | |||
* 8. Exposure controls/personal protection Occupationa.1 exposure limits US. OSHA Table Z-1 Limits for Air Contaminants 129 CFR 1910.1000) | * 8. Exposure controls/personal protection Occupationa.1 exposure limits US. OSHA Table Z-1 Limits for Air Contaminants 129 CFR 1910.1000) | ||
Components Type Phosphoric Acid (CAS PEL 7664-38-2) | Components Type Value Form Phosphoric Acid (CAS PEL lmg/m3 7664-38-2) | ||
Zinc chloride ICAS 7646-85-7) | Zinc chloride ICAS 7646-85-7) PEL lmg/m3 Fume. | ||
US. ACGIH Threshold Limit Values Components Type Value Form Phosphoric Acid ICAS STEL 3 mg/m3 7664-38-2) | |||
Zinc chloride ICAS 7646-85-7) | TWA 1 mg/m3 Zinc chloride ICAS 7646-85-7) STEL 2 mg/m3 Fume. | ||
TWA lmg/m3 Fume. | |||
Zinc chloride ICAS 7646-85-7) | US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Phosphoric Acid ICAS STEL 3 mg/m3 7664-38-2) | ||
TWA lmg/m3 Zinc chloride ICAS 7646-85-7) STEL 2 mg/m3 Fume. | |||
TWA lmg/m3 Fume. | |||
!typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. | Biological limit values No biological exposure limits noted for the ingredient(s). | ||
If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles. Skin protection Hand protection | Appropriate engineering controls Good general ventilation !typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. | ||
Use of an impervious apron is recommended. | Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles. | ||
Page: 3 /9 Respiratory protection | Skin protection Hand protection Chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. - | ||
or to an acceptable level !in countries where exposure limits have not been established!, an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI 288.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Wear appropriate thermal protective clothing, when necessary. | Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. | ||
When using, do not eat. drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. | Material name: FLOGARD* MS6237 Page: 3 /9 Version number: 3.0 | ||
: 9. Physical and chemical properties Appearance Colar Physical state Odor* Odor threshold pH (concentrated product) pH in aqueous solution Melting point/freezing point Initial boiling point and boiling range_ Flash point | |||
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable! or to an acceptable level !in countries where exposure limits have not been established!, an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI 288.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. | |||
Thermal hazards Wear appropriate thermal protective clothing, when necessary. | |||
General hygiene considerations When using, do not eat. drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. | |||
: 9. Physical and chemical properties Appearance Colar Colorless Physical state Liquid | |||
* Odor* None Odor threshold Not available. | |||
pH (concentrated product) 1 pH in aqueous solution 1.4(5% SOLi Melting point/freezing point < -20 °F (< -29 "Cl Initial boiling point and boiling Not available. | |||
range_ | |||
Flash point > 213 °F (> 101 "Cl P-M(CCI Evaporation rate < 1 (Ether = 11 Flammability (solid, gasl Not available. | |||
Upper/lower flammability or explosive limits Flammability limit- lower 1%1 Not available. | |||
Flammability limit- upper Not available. | |||
lo/ol Explosive limit- lower lo/ol Not available. | |||
Explosive limit- upper 1%1 Not available. | |||
Vapor pressure 18mm Hg Vapor pressure temp. 70 "F (21 "Cl Vapor density < 1(Air=11 Relative density 1.58 Relative density temperature 70 °F(21°CI Solubilityliesl Solubility lwaterl 100% | |||
Partition coefficient Not available. | |||
ln-octanol/waterl Auto-ignition temperature Not available. | |||
Decomposition temperature Not available. | |||
Viscosity 34cps Viscosity temperature 70 °F (21 "Cl Other information Percent volatile O (Estimated) | |||
Pour point < -20 °F (< -29 "Cl Specific gravity 1.58 | |||
: 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. | |||
Chemical stability Material is stable under normal conditions. | |||
Possibility of hazardous reactions Contact with strong bases may cause a violent reaction releasing heat. Contact with metals may cause a reaction releasing heat and toxic gas. Hazardous polymerization does not occur. | |||
Material name: FLOGARD* MS6237 Page: 4 / 9 Version number: 3.0 | |||
Conditions to avoid Contact with incompatible materials. Protect from freezing. | |||
* Incompatible materials May react with bases and metals. | |||
Hazardous decomposition Hydrogen chloride, oxides of carbon and phosphorus evolved in fire. | |||
products | |||
: 11. Toxicological information Information on likely routes of e>eposure Inhalation Prolonged inhalation may be harmful. May cause irritation to the respiratory system. | |||
Skin contact Causes severe skin burns. | |||
Eye contact Causes serious eye damage. | |||
Ingestion Causes digestive tract burns. Harmful if swallowed. | |||
Symptoms related to the physical, Burning pain and severe corrosive skin damage. Upper respiratory tract irritation. Causes serious eye chemical and to>eicological damage. Symptoms may include stinging, tearing, redness. swelling, and blurred vision. Permanent eye characteristics damage including blindness could result. | |||
Information on to>eicological effects Acute to>eicity Harmful if swallowed. May cause respiratory irritation. | |||
Prolonged inhalation may be harmful. Species Test Results FLOGARD MS6237 ICAS Mixture) IC25 Ceriodaphnia | Product Species Test Results FLOGARD MS6237 ICAS Mixture) | ||
* Estimates for product may be based on additional component data not shown. Bioaccumulative potential No data available. | Acute Dermal LD50 > 2000 mg/kg, !Calculated according to GHS additivity formula) | ||
Mobility in soil No data available. | Oral LD50 1367 mg/kg, !Calculated according to GHS additivity formula) | ||
Other adverse effects | Components Species Test Results Phosphoric Acid ICAS 7664-38-2) | ||
: 13. Disposal considerations Disposal instructions | Acute Dermal LD50 Rabbit 2740 mg/kg Zinc bisldihydrogen phosphate) ICAS 13598-37-3) | ||
Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 1260 mg/kg Zinc chloride ICAS 7646-85-7) | |||
Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 350 mg/kg | |||
* Estimates for product may be based on additional component data not shown*. | |||
Dispose of | Skin corrosion/irritation Causes severe skin burns and eye damage. | ||
Serious eye damage/eye irritation Causes serious eye damage. | |||
Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization. | |||
Empty containers or | Skin sensitization This product is not expected to cause skin sensitization. | ||
Germ cell mutagenicity Suspected of causing genetic defects. | |||
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP. or OSHA. | |||
IARC Monographs. Overall Evaluation of Carcinogenicity Not available. | |||
154 Page: 6/9 | Material name: FLOGARD* MS6237 Page: 5 I 9 Version number: 3.0 | ||
* IATA UN number UN proper shipping name | |||
OSHA Specifically Regulated Substances (29 CFR 1910.1001-10501 Not listed. | |||
US. National Toxicology Program INTPI Report on Carcinogens Not available. | |||
Reproductive toxicity Suspected of damaging fertility or the unborn child. | |||
Specific target organ toxicity - May cause respiratory irritation. | |||
: 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. | single exposure Specific target organ toxicity - Not classified. | ||
repeated exposure Aspiration h.azard Based on available data, the classification criteria are not met. Aspiration of this product may cause the same corrosiveness/irritation impacts as if it were ingested. | |||
Chronic effects Prolonged inhalation may be harmful. | |||
: 12. Ecological information Ecotoxicity Product Species Test Results FLOGARD MS6237 ICAS Mixture) | |||
IC25 Ceriodaphnia 1.3 mg/L, Chronic Bioassay, 7 day Fathead Minnow 2.7 mg/L, Chronic Bioassay, 7 day LC50 Ceriodaphnia 2.5 mg/L, Static Renewal Bioassay, 48 hour Fathead Minnow 7.8 mg/L, Static Renewal Bioassay, 96 hour NOEL Ceriodaphnia 5 mg/L, Static Renewal Bioassay, 48 hour Fathead Minnow 1.25 mg/L, Static Renewal Bioassay, 96 hour | |||
* Estimates for product may be based on additional component data not shown. | |||
Bioaccumulative potential No data available. | |||
Mobility in soil No data available. | |||
Other adverse effects Not available. | |||
* Persistence and degradability No data is available on the degradability of this product. | |||
: 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the material under controlled conditions in an approved incinerator. Dispose of contents/container in accordance with local/regional/national/international regulations. | |||
Local disposal regulations Dispose in accordance with all applicable regulations. | |||
Hazardous waste code D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel] | |||
D006: Waste Cadmium The waste code should be assigned in discussion between the user, the producer and the waste disposal company. | |||
Waste from residues I unused Dispose of in accordance with local regulations. Empty containers or liners may ret~in some product products residues. This material and its container must be disposed of in a safe manner !see: Disposal instructions). | |||
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. | |||
: 14. Transport information DOT UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. IPHOSPHORIC ACID, ZINC CHLORIDE), RQ Transport hazard class(es) | |||
Class 8 Subsidiary risk Packing group Ill Special precautions for user Read safety instructions, SDS and emergency procedures before handling. | |||
ERG number 154 Material name: FLOGARD* MS6237 Page: 6/9 Version number: 3.0 | |||
Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOL for exact container | |||
. classification. | |||
* IATA UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PHOSPHORIC ACID, ZINC CHLORIDE! | |||
Transport hazard class(esl Class 8 Subsidiary risk Packing graup Ill Environmental hazards No. | |||
ERG Code 154 Special precautions for user Read safety instructions, SDS and emergency procedures before handling. | |||
IMDG UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PHOSPHORIC ACID, ZINC CH LORI DEi, RQ MARINE POLLUTANT(ZINC CHLORIDE!, MARINE POLLUTANT Transport hazard class(es) | |||
Class 8 Subsidiary risk Packing group Ill Environmental hazards Marine pollutant Yes EmS F-A.S-B Special precautions for user Read safety instructions, SDS and emergency procedures before handling. | |||
DOT IATA;IMDG Marine pollutant Material name: FLOGARD* MS6237 Page: 7 /9 Version number: 3.0 | |||
: 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. | |||
TSCA Section 12(bl Export Notification (40 CFR 707, Subpt DI Not regulated. | TSCA Section 12(bl Export Notification (40 CFR 707, Subpt DI Not regulated. | ||
CERCLA Hazardous Substance List (40 CFR 302.41 Phosphoric Acid (CAS 7664-38-2) | CERCLA Hazardous Substance List (40 CFR 302.41 Phosphoric Acid (CAS 7664-38-2) Listed. | ||
Zinc bis(dihydrogen phosphate) (CAS 13598-37-3) | Zinc bis(dihydrogen phosphate) (CAS 13598-37-3) Listed. | ||
Zinc chloride (CAS 7646-85-7) | Zinc chloride (CAS 7646-85-7) Listed. | ||
SARA 304 Emergency release notification Nat regulated. | SARA 304 Emergency release notification Nat regulated. | ||
OSHA Specifically Regulated Substances (29 CFR 1910.1001-10501 Not listed. | |||
Chemical name Zinc chloride Zinc bis(dihydrogen phosphate) | Superfund Amendments and Reauthorization Act of 1986 (SARAI Hazard categories Immediate Hazard - Ves Delayed Hazard - Ves Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. | ||
SARA 311/312 Hazardous Ves chemical SARA 313 (TRI reporting) | |||
Chemical name CASnumber %bywt. | |||
Safe Drinking Water Act | Zinc chloride 7646-85-7 20-40 Zinc bis(dihydrogen phosphate) 13598-37-3 2.5-10 Other federal regulations Clean Air Act (CAAi Section 112 Hazardous Air Pollutants (HAPsl List I | ||
Not regulated. | |||
High priority Inventory status Country(sl or region | Clean Air Act (CAAi Section 112(rl Accidental Release Prevention 140 CFR 68.1301 Not regulated. | ||
Safe Drinking Water Act Not regulated. | |||
A "No" indicates that one or more components of the product ore not listed or exempt from listing on the inventory administered by the governing country(s). | ISDWAI FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace Phosphoric Acid ICAS 7664-38-2) High priority Inventory status Country(sl or region Inventory name On inventory (yes/no)* | ||
Canada Domestic Substances List (DSL) Ves Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Ves | |||
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) | |||
A "No" indicates that one or more components of the product ore not listed or exempt from listing on the inventory administered by the governing country(s). - | |||
US state regulations US - Massachusetts RTK - Substance List Phosphoric Acid (CAS 7664-38-2) | |||
Zinc chloride (CAS 7646-85-7) | Zinc chloride (CAS 7646-85-7) | ||
US -Pennsylvania RTK -Hazardous Substances Phosphoric Acid (CAS 7664-38-2) | US - Pennsylvania RTK - Hazardous Substances Phosphoric Acid (CAS 7664-38-2) | ||
Zinc chloride (CAS 7646-85-7) | Zinc chloride (CAS 7646-85-7) | ||
US -Rhode Island RTK Phosphoric Acid (CAS 7664-38-2) | US - Rhode Island RTK Phosphoric Acid (CAS 7664-38-2) | ||
*Zinc bis(dihydrogen phosphate) (CAS 13598-37-3) | *Zinc bis(dihydrogen phosphate) (CAS 13598-37-3) | ||
Zinc chloride (CAS 7646-85-7) | Zinc chloride (CAS 7646-85-7) | ||
US. California Controlled Substances. | US. California Controlled Substances. CA Deportment of Justice (California Health and Safety Code Section 111001 Not listed. | ||
CA Deportment of Justice (California Health and Safety Code Section 111001 Not listed. Material name: FLOGARD* MS6237 Version number: 3.0 | Material name: FLOGARD* MS6237 Page: 8 /9 Version number: 3.0 | ||
Candidate Chemicals List Safer Consumer Products Regulations (Cal. Code Regs, tit 22, 69502.3, subd. lall Phosphoric Acid (CAS 7664-38-2) | |||
US. California. Candidate Chemicals List Safer Consumer Products Regulations (Cal. Code Regs, tit 22, 69502.3, subd. lall Phosphoric Acid (CAS 7664-38-2) | |||
US. New Jersey Worker and Community Right-to-Know Act Phosphoric Acid (CAS 7664-38-2) | US. New Jersey Worker and Community Right-to-Know Act Phosphoric Acid (CAS 7664-38-2) | ||
Zinc bis(dihydrogen phosphate) (CAS 13598-37-3) | Zinc bis(dihydrogen phosphate) (CAS 13598-37-3) | ||
Line 180: | Line 212: | ||
US. Pennsylvania Worker and Community Right-to-Know Law Phosphoric Acid (CAS 7664-38-2) | US. Pennsylvania Worker and Community Right-to-Know Law Phosphoric Acid (CAS 7664-38-2) | ||
Zinc chloride (CAS 7646-85-7) | Zinc chloride (CAS 7646-85-7) | ||
US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US -California Proposition 65 -CRT: Listed date/Carcinogenic substance ARSENIC (CAS 7440-38-2) | US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. | ||
Listed: February 27, 1987 Cadmium (CAS 7440-43-9) | US - California Proposition 65 - CRT: Listed date/Carcinogenic substance ARSENIC (CAS 7440-38-2) Listed: February 27, 1987 Cadmium (CAS 7440-43-9) Listed: October 1. 1987 LEAD (CAS 7439-92-1} Listed: October 1. 1992 US - California Proposition 65 - CRT: Listed date/Developmental toxin Cadmium ICAS 7440-43-9} Listed: May 1, 1997 LEAD (CAS 7439-92-1} Listed: February 27, 1987 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin LEAD (CAS 7439-92-1) Listed: February 27, 1987 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Cadmium (CAS 7440-43-9} Listed: May 1, 1997 LEAD (CAS 7439-92-1} Listed: February 27, 1987 | ||
Listed: October 1. 1987 LEAD (CAS 7439-92-1} | : 16. Other information, including date of preparation or last revision Issue date Dec-11-2014 Revision date Mar-18-2016 Version# 3.0 List of abbreviations CAS: Chemical Abstract Service Registration Number TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. | ||
Listed: October 1. 1992 US -California Proposition 65 -CRT: Listed date/Developmental toxin Cadmium ICAS 7440-43-9} | ACGIH: American Conference of Governmental Industrial Hygienists NOEL: No Observed Effect Level STEL: Short Term Exposure Limit LCSO: Lethal Concentration. 50% | ||
Listed: May 1, 1997 LEAD (CAS 7439-92-1} | TWA Time Weighted Average BOD: Biochemical Oxygen Demand COD: Chemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code LOSO: Lethal Dose, 50% | ||
Listed: February 27, 1987 US -California Proposition 65 -CRT: Listed date/Female reproductive toxin LEAD (CAS 7439-92-1) | NFPA: National Fire Protection Association | ||
Listed: February 27, 1987 US -California Proposition 65 -CRT: Listed date/Male reproductive toxin Cadmium (CAS 7440-43-9} | |||
Listed: May 1, 1997 LEAD (CAS 7439-92-1} | |||
Listed: February 27, 1987 16. Other information, including date of preparation or last revision Issue date | |||
50% TWA Time Weighted Average BOD: Biochemical Oxygen Demand COD: Chemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code LOSO: Lethal Dose, 50% NFPA: National Fire Protection Association | |||
==References:== | ==References:== | ||
* Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge. | * No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge. information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. | ||
information and belief at the date of its publication. | unless specified in the text. The information in the sheet was written based on the best knowledge and experience currently available. | ||
The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. | Revision information Hazard(s) identification: Response Hazard(s) identification: Storage Fire-fighting measures: Fire fighting equipment/instructions Fire-fighting measures: Special protective equipment and precautions for firefighters Exposure controls/personal protection: Respiratory protection Toxicological information: Respiratory sensitization Transport Information: Material Transportation Information HazReg Data: North America Prepared by This SOS has been prepared by GE Water & Process Technologies Regulatory Department (1-215-355-3300). | ||
The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. unless specified in the text. The information in the sheet was written based on the best knowledge and experience currently available. | |||
Revision information | |||
Response Hazard(s) identification: | |||
Storage Fire-fighting measures: | |||
Fire fighting equipment/instructions Fire-fighting measures: | |||
Special protective equipment and precautions for firefighters Exposure controls/personal protection: | |||
Respiratory protection Toxicological information: | |||
Respiratory sensitization Transport Information: | |||
Material Transportation Information HazReg Data: North America This SOS has been prepared by GE Water & Process Technologies Regulatory Department (1-215-355-3300). | |||
*Trademark of General Electric Company. May be registered in one or more countries. | *Trademark of General Electric Company. May be registered in one or more countries. | ||
Material name:.FLOGARD* | Material name:.FLOGARD* MS6237 Page: 9 /9 Version number: 3.0}} | ||
MS6237 Version number: 3.0 |
Latest revision as of 22:37, 4 February 2020
ML16342A976 | |
Person / Time | |
---|---|
Site: | Sequoyah ![]() |
Issue date: | 11/03/2016 |
From: | Boerschig G Tennessee Valley Authority |
To: | Ryan Alexander Office of Nuclear Reactor Regulation, State of TN, Dept of Environment & Conservation |
References | |
TN0026450 | |
Download: ML16342A976 (10) | |
Text
Tennessee Valley Authority, Post Office Box 2000, Soddy Daisy, Tennessee 37384-2000 November 3, 2016 Mr. Robert Alexander Tennessee Department of Environment and Conservation Rosa L. Parks Blvd.
11th Floor, William R. Snodgrass Tennessee Tower Nashville, Tennessee 37243
Dear Mr. Alexander:
TENNESSEE VALLEY AUTHORITY (TVA) -SEQUOYAH NUCLEAR PLANT (SQN) - NPDES PERMIT NO. TN0026450 - REQUEST FOR BIOCIDE/CORROSION TREATMENT PLAN (B/CTP)
REVISION APPROVAL Sequoyah Nuclear Plant plans to add Flogard MS6237 to our Biocide/Corrosion Treatment Plan.
This chemical will replace Flogard MS6236 for corrosion prevention. The SDS for MS6237 is attached. As shown in the SDS, the active ingredients are phosphoric acid, zinc chloride, and zinc bis(dihydrogen phosphate). MS6237 will be applied at a maximum feed rate of 2.4 ppm. The maximum effluent concentrations will be 0.2 ppm phosphate and 0.2 ppm zinc.
- The site would like to begin using the new chemical in mid-December, therefore we are requesting written approval by December 9, 2016. If you have questions, or need additional information, please contact Millicent Garland at 423-843-6714, of Sequoyah's Environmental staff.
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.
~~.t Gregory A Boersc:ig Site Vice President (Interim)
Sequoyah Nuclear Plant Enclosures cc (Enclosures):
Chattanooga Environmental Field Office U.S. Nuclear Regulatory Commission ()
Division of Water Pollution Control 1301 Riverfront Pkwy, #206 Attn: Document Control Desk Washington, DC 20555
~ ,..,
_.l--1 v
\
Chattanooga, Tennessee 37402
Version: 3.0 Effective Date: Mar-18-2016 Previous Date: Jun-12-2015 GEPower Water & Process Technologies SAFETY DATA SHEET FLOGARD* MS6237
- 1. Identification Product identifier FLOGARD MS6237 Other means of identification None.
Recommended use Once-through system treatment Recommended restrictions None known.
Company/undertaking identification GE Betz. Inc.
4636 Somerton Road Trevose, PA 19053 T 215 355 3300, F 215 953 5524 Emergency telephone (8001877 1940
- 2. Hazard(s) identification Physical hazards Corrosive to metals Category 1 Health hazards Acute toxicity, oral Category 4 Skin corrosion/irritation Category 1B Serious eye damage/eye irritation Category 1 Germ cell mutagenicity Category 2 Reproductive toxicity Category 2 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation OSHA defined hazards Not classified.
Label elements Signal word Danger Hazard statement Moy be corrosive to metals. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. May cause respiratory irritation. Suspected of causing genetic defects. Suspected of damaging fertil ity or the unborn child.
Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep only in original container. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat. drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.
Response If swallowed: Rinse mout h. Do NOT induce vomiting. If on skin (or hoirl: Take off immediately all contaminated clothing. Rinse skin w ith water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously w ith water for several minutes. Remove contact lenses. if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Wash contaminated clot hing before reuse. Absorb spillage to prevent material damage.
Page: 1 /9
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Store in corrosive resistant container with a resistant .in liner.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Dispose of contents/container to approved local facility.
Hazardlsl not otherwise classified None known.
(HNOCI Supplemental information None.
- 3. Composition/information on ingredients Mixtures Components CAS# Percent Phosphoric Acid 7664-38-2 20-40 Zinc chloride 7646-85-7 20-40 Zinc bis(dihydrogen phosphate) 13598-37-3 2.5-10
- Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
Composition comments Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our assessment of the potential hazards of this formulation.
- 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or poison control center immediately. Chemical burns must be treated by a physician. Wash contaminated clothing before reuse.
Eye contact Rinse immediately with plenty of water for at least 20 minutes Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important Burning pain and severe corrosive skin damage, Upper respiratory tract irritation. Causes serious eye symptoms/effects, acute and damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye delayed damage including blindness could result.
Indication of immediate medical Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water attention and special treatment immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance.
needed Continue flushing during transport to hospital. In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
S. Fire-fighting_ measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (C02).
Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from the During fire, gases hazardous to health may be formed.
chemical Special protective equipment and Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand precautions for firefighters breathing apparatus, protective clothing and face mask.
Fire fighting -In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider equipment/instructions the hazards of other involved materials. Move containers from fire area if you can do so without risk.
Cool containers I tanks with water spray.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
- 6. Accidental release measures Personal precautions, protective Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low equipment and emergency areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or procedures - vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Material name: FLOGARD* MS6237 Page: 2 /9 Version number: 3.0
Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up possible. Cover with plastic sheet to prevent spreading. Absorb spillage to prevent material damage.
Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material !e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
- 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe mist or vapor. Do not get this material in contact with eyes. Do not get this material in contact with skin. Do not taste or swallow. Avoid contact during pregnancy/while nursing.
Avoid prolonged exposure. Do not get this material on clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. When using, do not eat, drink or smoke. Wash hands thoroughly after handling.
- Conditions for safe storage, Store locked up. Store in corrosive resistant container with a resistant inner liner. Store in original tightly including any incompatibilities closed container. Keep only in the original container. Use approved containers only. Protect from freezing. If frozen, thaw completely and mix thoroughly prior to use. Store in a cool, dry place out of direct sunlight. Store away from incompatible materials !see Section 10 of the SOS). Store in accordance with local/regional/national/international regulation.
- 8. Exposure controls/personal protection Occupationa.1 exposure limits US. OSHA Table Z-1 Limits for Air Contaminants 129 CFR 1910.1000)
Components Type Value Form Phosphoric Acid (CAS PEL lmg/m3 7664-38-2)
Zinc chloride ICAS 7646-85-7) PEL lmg/m3 Fume.
US. ACGIH Threshold Limit Values Components Type Value Form Phosphoric Acid ICAS STEL 3 mg/m3 7664-38-2)
TWA 1 mg/m3 Zinc chloride ICAS 7646-85-7) STEL 2 mg/m3 Fume.
TWA lmg/m3 Fume.
US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Phosphoric Acid ICAS STEL 3 mg/m3 7664-38-2)
TWA lmg/m3 Zinc chloride ICAS 7646-85-7) STEL 2 mg/m3 Fume.
TWA lmg/m3 Fume.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering controls Good general ventilation !typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles.
Skin protection Hand protection Chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. -
Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.
Material name: FLOGARD* MS6237 Page: 3 /9 Version number: 3.0
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable! or to an acceptable level !in countries where exposure limits have not been established!, an approved respirator must be worn. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI 288.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations When using, do not eat. drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
- 9. Physical and chemical properties Appearance Colar Colorless Physical state Liquid
- Odor* None Odor threshold Not available.
pH (concentrated product) 1 pH in aqueous solution 1.4(5% SOLi Melting point/freezing point < -20 °F (< -29 "Cl Initial boiling point and boiling Not available.
range_
Flash point > 213 °F (> 101 "Cl P-M(CCI Evaporation rate < 1 (Ether = 11 Flammability (solid, gasl Not available.
Upper/lower flammability or explosive limits Flammability limit- lower 1%1 Not available.
Flammability limit- upper Not available.
lo/ol Explosive limit- lower lo/ol Not available.
Explosive limit- upper 1%1 Not available.
Vapor pressure 18mm Hg Vapor pressure temp. 70 "F (21 "Cl Vapor density < 1(Air=11 Relative density 1.58 Relative density temperature 70 °F(21°CI Solubilityliesl Solubility lwaterl 100%
Partition coefficient Not available.
ln-octanol/waterl Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity 34cps Viscosity temperature 70 °F (21 "Cl Other information Percent volatile O (Estimated)
Pour point < -20 °F (< -29 "Cl Specific gravity 1.58
- 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous reactions Contact with strong bases may cause a violent reaction releasing heat. Contact with metals may cause a reaction releasing heat and toxic gas. Hazardous polymerization does not occur.
Material name: FLOGARD* MS6237 Page: 4 / 9 Version number: 3.0
Conditions to avoid Contact with incompatible materials. Protect from freezing.
- Incompatible materials May react with bases and metals.
Hazardous decomposition Hydrogen chloride, oxides of carbon and phosphorus evolved in fire.
products
- 11. Toxicological information Information on likely routes of e>eposure Inhalation Prolonged inhalation may be harmful. May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Ingestion Causes digestive tract burns. Harmful if swallowed.
Symptoms related to the physical, Burning pain and severe corrosive skin damage. Upper respiratory tract irritation. Causes serious eye chemical and to>eicological damage. Symptoms may include stinging, tearing, redness. swelling, and blurred vision. Permanent eye characteristics damage including blindness could result.
Information on to>eicological effects Acute to>eicity Harmful if swallowed. May cause respiratory irritation.
Product Species Test Results FLOGARD MS6237 ICAS Mixture)
Acute Dermal LD50 > 2000 mg/kg, !Calculated according to GHS additivity formula)
Oral LD50 1367 mg/kg, !Calculated according to GHS additivity formula)
Components Species Test Results Phosphoric Acid ICAS 7664-38-2)
Acute Dermal LD50 Rabbit 2740 mg/kg Zinc bisldihydrogen phosphate) ICAS 13598-37-3)
Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 1260 mg/kg Zinc chloride ICAS 7646-85-7)
Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 350 mg/kg
- Estimates for product may be based on additional component data not shown*.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye damage/eye irritation Causes serious eye damage.
Respiratory or skin sensitization Respiratory sensitization This product is not expected to cause respiratory sensitization.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity Suspected of causing genetic defects.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP. or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity Not available.
Material name: FLOGARD* MS6237 Page: 5 I 9 Version number: 3.0
OSHA Specifically Regulated Substances (29 CFR 1910.1001-10501 Not listed.
US. National Toxicology Program INTPI Report on Carcinogens Not available.
Reproductive toxicity Suspected of damaging fertility or the unborn child.
Specific target organ toxicity - May cause respiratory irritation.
single exposure Specific target organ toxicity - Not classified.
repeated exposure Aspiration h.azard Based on available data, the classification criteria are not met. Aspiration of this product may cause the same corrosiveness/irritation impacts as if it were ingested.
Chronic effects Prolonged inhalation may be harmful.
- 12. Ecological information Ecotoxicity Product Species Test Results FLOGARD MS6237 ICAS Mixture)
IC25 Ceriodaphnia 1.3 mg/L, Chronic Bioassay, 7 day Fathead Minnow 2.7 mg/L, Chronic Bioassay, 7 day LC50 Ceriodaphnia 2.5 mg/L, Static Renewal Bioassay, 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> Fathead Minnow 7.8 mg/L, Static Renewal Bioassay, 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br /> NOEL Ceriodaphnia 5 mg/L, Static Renewal Bioassay, 48 hour5.555556e-4 days <br />0.0133 hours <br />7.936508e-5 weeks <br />1.8264e-5 months <br /> Fathead Minnow 1.25 mg/L, Static Renewal Bioassay, 96 hour0.00111 days <br />0.0267 hours <br />1.587302e-4 weeks <br />3.6528e-5 months <br />
- Estimates for product may be based on additional component data not shown.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects Not available.
- Persistence and degradability No data is available on the degradability of this product.
- 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Incinerate the material under controlled conditions in an approved incinerator. Dispose of contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
D006: Waste Cadmium The waste code should be assigned in discussion between the user, the producer and the waste disposal company.
Waste from residues I unused Dispose of in accordance with local regulations. Empty containers or liners may ret~in some product products residues. This material and its container must be disposed of in a safe manner !see: Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied.
- 14. Transport information DOT UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. IPHOSPHORIC ACID, ZINC CHLORIDE), RQ Transport hazard class(es)
Class 8 Subsidiary risk Packing group Ill Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
ERG number 154 Material name: FLOGARD* MS6237 Page: 6/9 Version number: 3.0
Some containers may be exempt from Dangerous Goods/Hazmat Transport Regulations, please check BOL for exact container
. classification.
- IATA UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PHOSPHORIC ACID, ZINC CHLORIDE!
Transport hazard class(esl Class 8 Subsidiary risk Packing graup Ill Environmental hazards No.
ERG Code 154 Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PHOSPHORIC ACID, ZINC CH LORI DEi, RQ MARINE POLLUTANT(ZINC CHLORIDE!, MARINE POLLUTANT Transport hazard class(es)
Class 8 Subsidiary risk Packing group Ill Environmental hazards Marine pollutant Yes EmS F-A.S-B Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
DOT IATA;IMDG Marine pollutant Material name: FLOGARD* MS6237 Page: 7 /9 Version number: 3.0
- 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(bl Export Notification (40 CFR 707, Subpt DI Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.41 Phosphoric Acid (CAS 7664-38-2) Listed.
Zinc bis(dihydrogen phosphate) (CAS 13598-37-3) Listed.
Zinc chloride (CAS 7646-85-7) Listed.
SARA 304 Emergency release notification Nat regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-10501 Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARAI Hazard categories Immediate Hazard - Ves Delayed Hazard - Ves Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed.
SARA 311/312 Hazardous Ves chemical SARA 313 (TRI reporting)
Chemical name CASnumber %bywt.
Zinc chloride 7646-85-7 20-40 Zinc bis(dihydrogen phosphate) 13598-37-3 2.5-10 Other federal regulations Clean Air Act (CAAi Section 112 Hazardous Air Pollutants (HAPsl List I
Not regulated.
Clean Air Act (CAAi Section 112(rl Accidental Release Prevention 140 CFR 68.1301 Not regulated.
Safe Drinking Water Act Not regulated.
ISDWAI FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace Phosphoric Acid ICAS 7664-38-2) High priority Inventory status Country(sl or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Ves Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Ves
- A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product ore not listed or exempt from listing on the inventory administered by the governing country(s). -
US state regulations US - Massachusetts RTK - Substance List Phosphoric Acid (CAS 7664-38-2)
US - Pennsylvania RTK - Hazardous Substances Phosphoric Acid (CAS 7664-38-2)
US - Rhode Island RTK Phosphoric Acid (CAS 7664-38-2)
- Zinc bis(dihydrogen phosphate) (CAS 13598-37-3)
US. California Controlled Substances. CA Deportment of Justice (California Health and Safety Code Section 111001 Not listed.
Material name: FLOGARD* MS6237 Page: 8 /9 Version number: 3.0
US. California. Candidate Chemicals List Safer Consumer Products Regulations (Cal. Code Regs, tit 22, 69502.3, subd. lall Phosphoric Acid (CAS 7664-38-2)
US. New Jersey Worker and Community Right-to-Know Act Phosphoric Acid (CAS 7664-38-2)
Zinc bis(dihydrogen phosphate) (CAS 13598-37-3)
US. Pennsylvania Worker and Community Right-to-Know Law Phosphoric Acid (CAS 7664-38-2)
US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance ARSENIC (CAS 7440-38-2) Listed: February 27, 1987 Cadmium (CAS 7440-43-9) Listed: October 1. 1987 LEAD (CAS 7439-92-1} Listed: October 1. 1992 US - California Proposition 65 - CRT: Listed date/Developmental toxin Cadmium ICAS 7440-43-9} Listed: May 1, 1997 LEAD (CAS 7439-92-1} Listed: February 27, 1987 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin LEAD (CAS 7439-92-1) Listed: February 27, 1987 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Cadmium (CAS 7440-43-9} Listed: May 1, 1997 LEAD (CAS 7439-92-1} Listed: February 27, 1987
- 16. Other information, including date of preparation or last revision Issue date Dec-11-2014 Revision date Mar-18-2016 Version# 3.0 List of abbreviations CAS: Chemical Abstract Service Registration Number TSRN indicates a Trade Secret Registry Number is used in place of the CAS number.
ACGIH: American Conference of Governmental Industrial Hygienists NOEL: No Observed Effect Level STEL: Short Term Exposure Limit LCSO: Lethal Concentration. 50%
TWA Time Weighted Average BOD: Biochemical Oxygen Demand COD: Chemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code LOSO: Lethal Dose, 50%
NFPA: National Fire Protection Association
References:
- No data available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge. information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process.
unless specified in the text. The information in the sheet was written based on the best knowledge and experience currently available.
Revision information Hazard(s) identification: Response Hazard(s) identification: Storage Fire-fighting measures: Fire fighting equipment/instructions Fire-fighting measures: Special protective equipment and precautions for firefighters Exposure controls/personal protection: Respiratory protection Toxicological information: Respiratory sensitization Transport Information: Material Transportation Information HazReg Data: North America Prepared by This SOS has been prepared by GE Water & Process Technologies Regulatory Department (1-215-355-3300).
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Material name:.FLOGARD* MS6237 Page: 9 /9 Version number: 3.0