Information Notice 1998-29, Predicted Increase in Fuel Rod Cladding Oxidation

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Predicted Increase in Fuel Rod Cladding Oxidation
ML003730714
Person / Time
Issue date: 08/03/1998
From: Roe J
Division of Systems Safety and Analysis
To:
References
IN-98-029
Download: ML003730714 (3)


N,4K_. iniormation Notice !-2Z:

rreclicted Increase in -uel Rod Cladding Oxidation

UNITED STATES

NUCLEAR REGULATORY COMMISSION

OFFICE OF NUCLEAR REACTOR REGULATION

WASHINGTON, D.C. 20555-0001 August 3, 1998 NRC INFORMATION NOTICE 98- PREDICTED INCREASE IN FUEL ROD CLADDING

29:

OXIDATION

Addressees

All holders of operating licenses for nuclear power reactors, except those licensees who have

permanently ceased operations and have certified that fuel has been permanently removed from the

reactor vessel.

Purpose

The U.S. Nuclear Regulatory Commission (NRC) is issuing this information notice to inform

addressees of recent Westinghouse experience with one of its reactor fuel designs which has

exhibited higher than expected rates of oxidation of zircalloy cladding at high burnups . It is expected

that recipients will review the information for applicability to their facilities and consider action as

appropriate, to avoid similar problems. The material and discussion contained in this information

notice are not NRC requirements; therefore, no specific action or written response is required.

Description of Circumstances

On October 28, 1997, Westinghouse notified NRC that modification of its fuel cladding corrosion

model in its fuel rod design code, PAD, to reflect new data on Zircaloy-4 oxidation at high burnup

may create compliance issues for its Integral Fuel Burnable Absorber (IFBA) fuel with Zircaloy-4 cladding. The modified code may predict higher fuel temperatures and internal pressures at high

burnup conditions. This, in turn, may lead to code results that do not meet the Westinghouse criterion

prohibiting gap reopening and that do not meet the loss-of-coolant accident (LOCA) criterion in 10

CFR 50.46(b)(2).

The Westinghouse criterion prohibiting gap reopening was approved by the NRC staff for steady

state operation when internal pressure in the rod exceeds reactor coolant system pressure. The staff

approved this criterion in lieu of a criterion requiring that the internal pressure of the fuel rod not

exceed reactor coolant system pressure. Both criteria have the same purpose, which is to not allow

separation between the fuel pellet and the cladding late in life; this limits temperature difference

between fuel and clad and therefore minimizes maximum fuel temperature.

The acceptance criterion in 10 CFR 50.46(b)(2) requires that the calculated maximum total oxidation

of the cladding not exceed 0.17 times the total thickness of the cladding before oxidation. Total

oxidation includes both pre-accident oxidation and oxidation occurring during a LOCA. If this total

oxidation limit were to be exceeded during an accident, the cladding could become embrittled. The

cladding could then fracture and fragment during the reflood period and lose structural integrity. This

in turn could compromise the structural soundness and coolable geometry of the core and ultimately

the ability to keep the core cooled.

Historically, the focus of compliance with 10 CFR 50.46 has been on 10 CFR 50.46(b)(1), "Peak

Cladding Temperature," which usually is most limiting at the beginning of fuel life. Because the

oxidation rate is known to be dependent on temperature, total oxidation was also deemed most severe

http://www.nrc.gov/NRC/GENACT/GC/IN/1998/in98029.html

Pagel1 of 3

08/20/1999

NRC Information Notice 98-29: Predicted Increase in Fuel Rod Cladding Oxidation at the beginning of life (BOL). The contribution of preaccident oxidation to the calculated total

oxidation had not previously been thought to be significant, but as measured cladding oxidation

thickness in the later stages of assembly service life increased faster than had been predicted, it

" became so.

On November 6, 1997, the NRC staff, Westinghouse, and the Westinghouse Owners Group (WOG)

met in a public meeting to discuss this matter. At that meeting, the WOG stated that it would provide

a list of affected plants, the projected dates when each might become vulnerable to potential non

compliance, and details of its plans to address the issue. The WOG also stated that each affected plant

would take appropriate individual actions in terms of reporting pursuant to 10 CFR 50.46(a)(3)ii

before the plant reached its projected date of vulnerability.

Westinghouse stated that it planned to perform more detailed assessments for individual plants and to

make timely recommendations to each licensee for compensatory actions with regard to the

compliance issue. In the longer term, Westinghouse will correct its model in PAD to better account

for recent higher burnup oxidation data and will begin using the revised model by August 1998.

The NRC staff found that this approach was adequate to address in the near term the specific

problems reported by Westinghouse and that plants with Westinghouse IFBA fuel could continue to

operate in compliance with 10 CFR 50.46. The staff noted that the burnup related phenomena, which

could result in noncompliance with the oxidation requirements of 10 CFR 50.46, may not be limited

to Westinghouse IFBA fuel but might affect any Zircaloy fuel used in high burnup applications. The

staff also notes that the oxidation-related phenomena discussed in this information notice may affect

licensees' compliance with the reporting requirements of 10 CFR 50.46(a)(3), as well as the

performance criteria of 10 CFR 50.46(b).

Discussion:

"Westinghouse employs the NRC-approved PAD computer code to evaluate fuel performance. In

-

1996, Westinghouse found that two cladding-related models in PAD were nonconservative in

analyses of fuels at high bumup. It has recently been shown that the effects of these non

conservatisms in the models could lead to nonconservative calculation of post-LOCA cladding

oxidation. These analyses are used to show compliance with 10 CFR 50.46 (b), criterion (2).

The first deficient model deals with fuel rod gap pressure. For the last several years, Westinghouse

plants have used high-duty fuel rods, with IFBA and Zircaloy-4 cladding in their core designs. The

IFBA rods have a boron coating on the U02 pellet surface. Westinghouse discovered that for higher

burn up IFBA fuel, the rod internal pressure buildup attributed to helium released from IFBA was

higher than the buildup previously modeled by the PAD code. Westinghouse revised the PAD model

to account for increased helium release from IFBA rods and the increased rod pressure buildup

resulting from this helium release.

The second deficient model is the Zircaloy- 4 cladding oxidation calculation in the PAD code.

Westinghouse corrected the corrosion model for Zircaloy- 4 cladding material to address the

accelerated levels of corrosion actually being measured for high burnup fuel rods. The measured

corrosion levels were higher than had been calculated using the previous oxidation model. Using the

corrected corrosion model, Westinghouse interpreted the PAD results to indicate that the degraded

thermal conductivity of the cladding due to the higher oxidation levels produced an increase in fuel

cladding temperatures and consequent higher clad creep rates. These higher creep rates could, in turn, lead to gap reopening, which would be contrary to a Westinghouse design criterion. In addition, Westinghouse concluded that with potential gap re-opening, degraded thermal conductivity of the

fuel pellets due to high bumup further elevated the local fuel temperature.

The accompanying higher stored energy level and the high pre-LOCA oxidation level could, as early

"as the second half of the second duty cycle, make this higher burnup fuel more limiting with respect

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08/20/1999

NRC Information Notice 98-29: Predicted Increase in Fuel Rod Cladding Oxidation

to the LOCA criterion of 10 CFR 50.46(b)(2) than the analysis of record for BOL fuel. Westinghouse

further indicated that the gap reopening is a concern not only for IFBA rods, but also for gadolinia

rods which contain gadolinia powder mixed homogeneously with U02 pellets. The gadolinia

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degrades the thermal conductivity of the fuel pellets, resulting in a higher operating temperature of

the fuel.

Westinghouse stated that exceeding the criterion prohibiting gap reopening did not directly lead to

clad failures. However, fuel rods with gap reopening could be more vulnerable to swelling and

rupture during LOCAs and could challenge the 17 percent oxidation limit. Therefore, high burnup or

high duty-fuel rods with a tendency toward gap reopening would be more vulnerable under LOCA

conditions. Licensees and fuel vendors with other types of Zircaloy clad fuels may wish to consider

the relevance of this information to the oxidation models in use for their specific fuels in light of this

new experience, which suggests that oxidation levels at high burnup may be more severe than

previously expected.

This information notice requires no specific action or written response. If you have any questions

about the information in this notice, please contact one of the technical contacts listed below or the

appropriate Office of Nuclear Reactor Regulation (NRR) project manager.

orig /s/'d by

David B. Matthews FOR

Jack W. Roe, Acting Director

Division of Reactor Program Management

Office of Nuclear Reactor Regulation

Technical contacts: Kulin Desai, NRR

301-415-2835 E-Mail: kddpnrc.gov

Frank Orr, NRR

301-415-1815 E-Mail: froanrc.gov

Edward Goodwin, NRR

301-415-1154 E-Mail: efgpnrc.gov

(NUDOCS Accession Number 9807290129)

http://www.nrc.gov/NRC/GENACT/GC/IN/I 998/in') 5O2)9.html 08/20/1999