ML062850148: Difference between revisions

From kanterella
Jump to navigation Jump to search
StriderTol Bot change
StriderTol Bot change
 
Line 18: Line 18:


=Text=
=Text=
{{#Wiki_filter:RichaW Emch - air emissions inventory report for 2005 and MSbS for Nalco H-550                   Page 1 Paqe 11 IRicha~dErnch - air emissions inventory report for 2005 and MSDS for Nalco H-550 From:               "DeWald, Lynn" <ldewald@entergy.com>
{{#Wiki_filter:RichaW Emch - air emissions inventory report for 2005 and MSbS for Nalco H-550 Page 11 I Richa~dErnch - air emissions inventory report for 2005 and MSDS for Nalco H-550 Paqe 1 From:  
To:                 "Richard Emch" <RLE@NRC.GOV>
"DeWald, Lynn" <ldewald@entergy.com>
Date:               Mon, Sep 18, 2006 12:58 PM
To:  
"Richard Emch" <RLE@NRC.GOV>
Date:
Mon, Sep 18, 2006 12:58 PM


==Subject:==
==Subject:==
Line 27: Line 30:
Lynn Lynn DeWald Entergy Nuclear Vermont Yankee, LLC 320 Governor Hunt Road Vernon, VT 05354 802-258-5526 (phone) 802-258-5865 (fax) 802-380-4493 (cell)
Lynn Lynn DeWald Entergy Nuclear Vermont Yankee, LLC 320 Governor Hunt Road Vernon, VT 05354 802-258-5526 (phone) 802-258-5865 (fax) 802-380-4493 (cell)


I c emn\GW)00001.TMP                                                                                       Pag PacieelIil 1ii c:\ternn\GWIOOOOl .TMP Mail Envelope Properties       (450ED012.1ED :20: 29165)
I c emn\\GW)00001.TMP Pag elIil c:\\ternn\\GWIOOOOl.TMP Pacie 1 ii Mail Envelope Properties (450ED012.1ED :20: 29165)


==Subject:==
==Subject:==
air emissions inventory report for 2005 and MSDS for Nalco H-550 Creation Date            Mon, Sep 18, 2006 12:56 PM From:                    "DeWald, Lynn" <Idewald@entergy.com>
Creation Date From:
Created By:              ldewald@entergy.com Recipients nrc.gov OWGWPO02.HQGWDOO1 RLE (Richard Emch)
Created By:
Post Office                                                               Route OWGWPOO2.HQGWDOO1                                                       nrc.gov Files                             Size                 Date & Time MESSAGE                           675                 Monday, September 18, 2006 12:56 PM TEXT.htm                         5044 Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf       556268 H550.pdf                         65385 Mime.822                         1 Options Expiration Date:                 None Priority:                         Standard ReplyRequested:                   No Return Notification:             None Concealed  
air emissions inventory report for 2005 and MSDS for Nalco H-550 Mon, Sep 18, 2006 12:56 PM "DeWald, Lynn" <Idewald@entergy.com>
ldewald@entergy.com Recipients nrc.gov OWGWPO02.HQGWDOO1 RLE (Richard Emch)
Post Office OWGWPOO2.HQGWDOO1 Route nrc.gov Files Size Date & Time MESSAGE 675 Monday, September 18, 2006 12:56 PM TEXT.htm 5044 Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf 556268 H550.pdf 65385 Mime.822 1
Options Expiration Date:
Priority:
ReplyRequested:
Return Notification:
Concealed  


==Subject:==
==Subject:==
No Security:                         Standard Junk Mail Handling Evaluation Results Message is eligible for Junk Mail handling This message was not classified as Junk Mail Junk Mail settings when this message was delivered Junk Mail handling disabled by User Junk Mail handling disabled by Administrator Junk List is not enabled Junk Mail using personal address books is not enabled Block List is not enabled
Security:
None Standard No None No Standard Junk Mail Handling Evaluation Results Message is eligible for Junk Mail handling This message was not classified as Junk Mail Junk Mail settings when this message was delivered Junk Mail handling disabled by User Junk Mail handling disabled by Administrator Junk List is not enabled Junk Mail using personal address books is not enabled Block List is not enabled


mch - Final 2005.emissions inve-'nt-ory_&#xfd;epgrtto&#xfd;Eq&#xfd;&#xfd;gyYX.1_.&#xfd;&#xfd;.2qpp.pdf                                                     _ &#xfd;age&#xfd;_&#xfd;,J Pag~i~~
mch - Final 2005.emissions inve-'nt-ory_&#xfd;epgrtto&#xfd;Eq&#xfd;&#xfd;gyYX.1_.&#xfd;&#xfd;.2qpp.pdf
Richaki Emch Final 2005 emissions inventory report for Entergy VY 126 2006.pdf Entergy Nuclear Northeast Entergy Nuclear Operations, Inc.
_ &#xfd;age&#xfd;_&#xfd;,J Richaki Emch - Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf Pag~i~~
Entergy Nuclear Northeast Entergy Nuclear Operations, Inc.
Vermont Yankee 322 Governor Hunt Rd.
Vermont Yankee 322 Governor Hunt Rd.
Vernon. VT 05354 Tel 802.257-7711 26 Janiiary 2006 Mr. Daniel Riley, Environmental Engineer Vermont Agency of Natural Resources Department of Environmental Conservation Air Pollution Control Division Building 3 South 103 South Main Street Waterbury, VT 05671-0402
Vernon. VT 05354 Tel 802.257-7711 26 Janiiary 2006 Mr. Daniel Riley, Environmental Engineer Vermont Agency of Natural Resources Department of Environmental Conservation Air Pollution Control Division Building 3 South 103 South Main Street Waterbury, VT 05671-0402
Line 46: Line 58:


==Dear Mr. Riley:==
==Dear Mr. Riley:==
Enclosed is Entergy Nuclear Vermont Yankee's air emissions inventory report for 2005.
Enclosed is Entergy Nuclear Vermont Yankee's air emissions inventory report for 2005.
Total air emissions from significant activities, which includes the house heating boilers and the waste oil burners, was 9.07 tons for the year. Vermont Yankee does not include emissions from the emergency diesel generators (A and B), the John Deere diesel, or the emergency diesel fire pump toward the total tonnage in this inventory report as these emergency generators, each of which operate less than one hundred hours per year, are considered insignificant activities under the State regulations.
Total air emissions from significant activities, which includes the house heating boilers and the waste oil burners, was 9.07 tons for the year. Vermont Yankee does not include emissions from the emergency diesel generators (A and B), the John Deere diesel, or the emergency diesel fire pump toward the total tonnage in this inventory report as these emergency generators, each of which operate less than one hundred hours per year, are considered insignificant activities under the State regulations.
The cooling tower particulate emissions calculations for the mechanical draft cooling towers are based on the drift and drift rate, and as in 2004, remain conservatively high.
The cooling tower particulate emissions calculations for the mechanical draft cooling towers are based on the drift and drift rate, and as in 2004, remain conservatively high.
The cooling towers operated for 2,149 hours during 2005. The operating hours were utilized in calculating the 2005 PM emissions.
The cooling towers operated for 2,149 hours during 2005. The operating hours were utilized in calculating the 2005 PM emissions.
PM Emissions (TPY)     = Drift gpm x 8.33 lbs/gal x TDS x 60 min/hr x hrs/yr of operation x 1 ton/2000 lbs 72.0 gpm x 8.33 lbs/gal x (62 lbs/1000000-lbs) x 60 min/hr x 2149 x I ton/2000 lbs The calculations for the 2005 emission data for cooling tower hazardous air contaminants (HAC) consider the miscibility of the product constituent and the water circulated through the cooling towers versus percentage of water loss through evaporation when the towers are running.       The circulating water flow through the cooling towers is approximately 360,000 gallons per minute (gpm), and based on the FinalEnvironmental Statement Related to the Operation of Vermont Yankee Nuclear Power Corporation 4
PM Emissions (TPY) = Drift gpm x 8.33 lbs/gal x TDS x 60 min/hr x hrs/yr of operation x 1 ton/2000 lbs 72.0 gpm x 8.33 lbs/gal x (62 lbs/1000000-lbs) x 60 min/hr x 2149 x I ton/2000 lbs The calculations for the 2005 emission data for cooling tower hazardous air contaminants (HAC) consider the miscibility of the product constituent and the water circulated through the cooling towers versus percentage of water loss through evaporation when the towers are running.
The circulating water flow through the cooling towers is approximately 360,000 gallons per minute (gpm), and based on the Final Environmental Statement Related to the Operation of Vermont Yankee Nuclear Power Corporation 4


                                                                                                .............                  i mch - Final 2005 emissions inventory report Lor&#xfd;&#xfd;n&#xfd;ergy=VY 1 26 2006-pdf                                       -Page 2 Page2~
mch - Final 2005 emissions inventory report Lor&#xfd;&#xfd;n&#xfd;ergy=VY 1 26 2006-pdf i
IRichaM Ernch - Final 2005 emissions inventory report for Entergy VY 126 2006.pdf published by the Nuclear Regulatory Commission, 5,000 gpm is lost through cooling tower evaporation. The HAC emissions from the cooling towers are insignificant and do not exceed any action levels outlined in Appendix C of the Vermont Air Pollution Control Regulations.
-Page 2 I RichaM Ernch - Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf Page2~
Cooling Towers Pollutant                 Tons lbs/8 hours     Action level (bs/8hrs)
I published by the Nuclear Regulatory Commission, 5,000 gpm is lost through cooling tower evaporation. The HAC emissions from the cooling towers are insignificant and do not exceed any action levels outlined in Appendix C of the Vermont Air Pollution Control Regulations.
I                      Particulate Matter                   2.4 Dodecylguanidine Hydrochloride 0.001           0.002         0.025 Ethyl Alcohol                         0.0004 0.001           2,330 Glutaraldehyde                       0.008   0.015         340 Isopropyl Alcohol                     0.0005 0.001           63 Total 2.41 This submittal'does not include additional hazardous air contaminant (HAC) emissions inventory, as those would be associated with routine maintenance activities, such as painting and cleaning, and are therefore not subject to any State reporting requirements.
Cooling Towers Pollutant Tons lbs/8 hours Action level (bs/8hrs)
Particulate Matter 2.4 Dodecylguanidine Hydrochloride 0.001 0.002 0.025 Ethyl Alcohol 0.0004 0.001 2,330 Glutaraldehyde 0.008 0.015 340 Isopropyl Alcohol 0.0005 0.001 63 Total 2.41 This submittal'does not include additional hazardous air contaminant (HAC) emissions inventory, as those would be associated with routine maintenance activities, such as painting and cleaning, and are therefore not subject to any State reporting requirements.
Please do not hesitate to call if you have questions or concerns with the enclosed information.
Please do not hesitate to call if you have questions or concerns with the enclosed information.
Sincerely, Entergy Nuclear Vermont Yankee, LLC Lynn DeWald                                           Samuel A. Wender IV Environmental Specialist                              Chemistry Superintendent 802-258-5526                                          802-258-5650 2
Sincerely, Entergy Nuclear Vermont Yankee, LLC Lynn DeWald Environmental Specialist 802-258-5526 Samuel A. Wender IV Chemistry Superintendent 802-258-5650 2


M.)
Supporting Calculations A. SPECTRUS NX-1104 Tsopropyl Alcohol (400 gals/yr) x (8.24 lbs/gal) x (2.4%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm) 0.0005 tons/yr Ethyl Alcohol (400 gals/yr) x (8.24 lbs/gal) x (1.8%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm)= 0.0004 tons/yr Dodecvlauanidine Hydrochloride (400 gals/yr) x (8.24 lbs/gal) x (5%) x (I ton/2,000 Ibs) x (5,000 gpm/360,000 gpm) = 0.001 tons/yr B. NALCO H-550 Glutaraldehyde (50% Solution)
                                                                                                                                  ,~3 0
(250 gals/yr) x (9.4 lbs/gal) x (50%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm) = 0.008 tons/yr M.)
Supporting Calculations                                                   CD 3
,~3 0
(n A. SPECTRUS NX-1104                                                                                                               O/)
CD 3
                                                                                                                                  =3 Tsopropyl Alcohol CD (400 gals/yr) x (8.24 lbs/gal) x (2.4%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm)     0.0005 tons/yr Ethyl Alcohol                                                                                                                   0 M9 CD (400 gals/yr) x (8.24 lbs/gal) x (1.8%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm)= 0.0004 tons/yr t,0 Dodecvlauanidine Hydrochloride (400 gals/yr) x (8.24 lbs/gal) x (5%) x (I ton/2,000 Ibs) x (5,000 gpm/360,000 gpm) = 0.001 tons/yr                       CD B. NALCO H-550 0)
(n O/)
Glutaraldehyde (50% Solution)
=3 CD 0
(250 gals/yr) x (9.4 lbs/gal) x (50%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm) = 0.008 tons/yr 3
M9 CD t,0 CD 0) 3 K  
K       .4J;A.....CaN  .y.':...
.y.':...  
                                                                                                          .. . .... y..........
.4J;A.....CaN y..........


Al yt~'t)I
--.- ~
                                                                                                                              --.- ~
Al Rir6"hW Emch-Final 2005 ermnissions inventory report for EntergyVYl 26_2006-Pdf&#xfd;
Rir6"hW Emch- Final 2005 ermnissions inventory report for EntergyVYl 26_2006-Pdf&#xfd;                                         -~
-~
CERTIFICATION OF DATA ACCURACY For Purposes of Emission Calculations This form Inust be signed by an individual responsible for the completion and certification of the data contained in the forms attached which are intended to meet both the requirements of State Statute {10 V.S.A. 555 (c) and 3 V.S.A. 2822 (j)(1)(B)) and the requirements for"Ermission Statements" contained in the Federal Clean Air Act as amended in 1990. Certification indicates that the signatory takes legal responsibility for the accuracy of the information on the form.
yt~'t)I CERTIFICATION OF DATA ACCURACY For Purposes of Emission Calculations This form Inust be signed by an individual responsible for the completion and certification of the data contained in the forms attached which are intended to meet both the requirements of State Statute {10 V.S.A. 555 (c) and 3 V.S.A. 2822 (j)(1)(B)) and the requirements for"Ermission Statements" contained in the Federal Clean Air Act as amended in 1990. Certification indicates that the signatory takes legal responsibility for the accuracy of the information on the form.
The datapresented herein representsthe best available informationand is true, accurate,and complete to the best ofmy knowledge.
The data presented herein represents the best available information and is true, accurate, and complete to the best of my knowledge.
Print Full Name                   Print Full Title Sigture"                          Date of Signature SPl)       5phneNk e
Print Full Name Sigture" Print Full Title Date of Signature SPl) 5phneNk e
Telephone Number Received JAN     4 2006
Telephone Number Received JAN 4 2006


Richaed Emch - Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf                                             Page"5Il Vermont Agency of Natural Resources                                 Combustion Source 2005 Air Pollutant Emissions Inventory                             For Criteria Pollutants The Information displayed on this form is that which Is currently on file for your.
Richaed Emch - Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf Page"5Il Vermont Agency of Natural Resources 2005 Air Pollutant Emissions Inventory Combustion Source For Criteria Pollutants The Information displayed on this form is that which Is currently on file for your.
facility. It is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please revievw the Information contained in the boxes. If there is no value In a box, write in the correct 2005 value. If there Is a value, but it Is incorrect for 2005, cross out the value and in its place write the correct value.
facility. It is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please revievw the Information contained in the boxes. If there is no value In a box, write in the correct 2005 value. If there Is a value, but it Is incorrect for 2005, cross out the value and in its place write the correct value.
If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.
If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.
Facility Name:       ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form                   ir     be...b "I          I ci                       5 Facility ID       WM2335 Source
Facility Name:
ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form ir "I
be...b I ci Facility ID WM2335 Source


== Description:==
== Description:==
house heating boilers (2)
house heating boilers (2)
Stack Number:
Stack Number:
Source Number:                       I Segment Number:
Source Number:
Source Classification Code:     1-03-005-01 Operational Data:
I Segment Number:
5 Source Classification Code:
1-03-005-01 Operational Data:
Hours Per Day:
Hours Per Day:
                                                  ~fl                 Winter Throughput (%) : [i               40 Days Per Week: LIZiI                  Spring Throughput (%):         [I       30 Weeks Per Year: LZ~I1                  Summer Throughput (%)::I                   0 Hours Per Year:      5;                Autumn Throughput (%) :l               30 (Over)*
Days Per Week:
Weeks Per Year:
Hours Per Year:
~fl LIZiI LZ~I1 5;
Winter Throughput (%) : [i 40 Spring Throughput (%): [I 30 Summer Throughput (%): :I 0
Autumn Throughput (%) :l 30 (Over)*


'Riclail E.nch - Final 2005 emissions inventorreport for EntergyVY1 262006.pdf                                                       Page 61l Combustion Source (continued)
'Riclail E.nch - Final 2005 emissions inventorreport for EntergyVY1 262006.pdf Page 61l Combustion Source (continued)
Fuel Type:             FUEL OIL (#2) 2005 Fuel Consumption: (supply units):                   ,
Fuel Type:
* 4   ,
FUEL OIL (#2) 2005 Fuel Consumption: (supply units):
Av. Sulfur Content of Fuel (%):               J         Ash Content of Fuel (%):
4 Av. Sulfur Content of Fuel (%):
(Pleasesupply a current estimateof mid-range sulfur contenO Maximum Heat Input (million BTU/hr):
J Ash Content of Fuel (%):
Burner Rating:                             Boiler Rating:             L                     -
(Please supply a current estimate of mid-range sulfur contenO Maximum Heat Input (million BTU/hr):
Maximum Actual Firing Rate (million BTU/hr):
Burner Rating:
Percent Space Heat:           I00     [.
Boiler Rating:
Percent Process Heat:     j     0j Stack Parameters:
L Maximum Actual Firing Rate (million BTU/hr):
Percent Space Heat:
I00
[.
Percent Process Heat: j 0j Stack Parameters:
Stack Number:
Stack Number:
Stack/Duct Discharge Height (feet)                         87.9 Stack/Duct Inner Diameter at Exit (inches) :             I   27.6Z Exit Gas Temperature (deg.F:     F                           151i       1 Flow Rate at Exit (actual FT3/min) :119,915 If an air pollution control, device for the source exists Inspect the following information and correct if necessary:
Stack/Duct Discharge Height (feet) 87.9 Stack/Duct Inner Diameter at Exit (inches) :
TSP Control Device:     none                                           Theoretical Efficiency:
I 27.6Z Exit Gas Temperature (deg.F:
S02 Control Device: none                                               Theoretical Efficiency:
F 151i 1
NOx Control Device: none                                               Theoretical Efficiency:       '
Flow Rate at Exit (actual FT3/min) :119,915 If an air pollution control, device for the source exists Inspect the following information and correct if necessary:
VOC Control Devicei none                                               Theoretical Efficiency:[
TSP Control Device:
CO Control Device: I none                                             Theoretical Efficiency:. I 0 If an estimated emission rate exists, please supply the information below:
none Theoretical Efficiency:
S02 Control Device:
none Theoretical Efficiency:
NOx Control Device: none Theoretical Efficiency:
VOC Control Devicei none Theoretical Efficiency:[
CO Control Device: I none Theoretical Efficiency:. I 0
If an estimated emission rate exists, please supply the information below:
Estimated Emission Rite* :
Estimated Emission Rite* :
Basis of Estimate:
Basis of Estimate:
* If test data 4 years old or less is available.
* If test data 4 years old or less is available.
                                                                                                                                  -.U
-.U


I Riclha ,mch- Final 2005 emi ssions inyentorreport.for Entergy vY1 262006,pdf                                           -~ Page 711 Vermont Agency of Natural Resources                                 Combustion Source 2005 Air Pollutant Emissions Inventory                             For Criteria Pollutants The Information displayed on this form is that which is currently on file for your facility. It Is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review the Information contained In the boxei. If there is no value In a box, write In the correct 2005 value. If there is a value, but It is Incorrect for 2005, cross out the value and In its place write the correct value.
I Riclha  
,mch-Final 2005 e mi ssions inyentorreport.for Entergy vY1 262006,pdf
-~
Page 711 Vermont Agency of Natural Resources 2005 Air Pollutant Emissions Inventory Combustion Source For Criteria Pollutants The Information displayed on this form is that which is currently on file for your facility. It Is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review the Information contained In the boxei. If there is no value In a box, write In the correct 2005 value. If there is a value, but It is Incorrect for 2005, cross out the value and In its place write the correct value.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
Facility Name:       ENTERGY NUCLEAR VERMONT YANKEE l
Facility Name:
* Person Completing Inventory Form           [ LL-"r"v%VYe uI,   We (Jt                     I Facility ID       WM2335 Source
ENTERGY NUCLEAR VERMONT YANKEE l
Person Completing Inventory Form [ LL-"r"v% VYe We uI, (Jt I
Facility ID WM2335 Source


== Description:==
== Description:==
vipte oil furnace (2)
vipte oil furnace (2)
Stack Number:                         2 Source Number:                       2 Segment Number:                       I Source Classification Code:     1-02-004-01 Operational Data:
Stack Number:
Hours Per Day:                           Winter Throughput (%)                 5 Days Per Week:                            Spring Throughput (%):                 0 Weeks Per Year:                            Summer Throughput (%):
Source Number:
Hours Per Year:      1-7 CV 077          Autumn Throughput (%)     :LI3           [
Segment Number:
2 2
I Source Classification Code:
1-02-004-01 Operational Data:
Hours Per Day:
Days Per Week:
Weeks Per Year:
Hours Per Year:
1-7 CV 077 Winter Throughput (%)
5 Spring Throughput (%):
0 Summer Throughput (%):
Autumn Throughput (%) :LI3
[
(Over)
(Over)
* Einch - Final 2005 emiss-vans inKefy&#xfd;&#xfd;! &#xfd;epq&#xfd;&#xfd;tq!&#xfd;&#xfd;q&#xfd;&#xfd;rgyVY 1 26 2006.p(                                                 Page 8.
* Einch - Final 2005 emiss-vans inKefy&#xfd;&#xfd;! &#xfd;epq&#xfd;&#xfd;tq!&#xfd;&#xfd;q&#xfd;&#xfd;rgyVY 1 26 2006.p(
RichaiU Emch - Final 2005 ernis~lons inventory report for Entergy VY 1 26 2006.pdf                                               Pa ge8~
Page 8.
RichaiU Emch - Final 2005 ernis~lons inventory report for Entergy VY 1 26 2006.pdf Pa ge8~
Combustion Source (continued)
Combustion Source (continued)
Fuel*Type:       .      FUEL OIL (#6)                                 I 2005 Fuel Consumption: (supply units):               g, 55
Fuel*Type:
* ty.1 (o'i5 Av. Sulfpr Content of Fuel (%):             1 / --          Ash Content of Fuel (%)           1 (Pleasesupply a currentestimate of mid-range sulfur content)
FUEL OIL (#6)
I 2005 Fuel Consumption: (supply units):
g, 55
* ty.1 (o'i5 Av. Sulfpr Content of Fuel (%):
1  
/
Ash Content of Fuel (%)
1 (Please supply a current estimate of mid-range sulfur content)
Maximum Heat Input (million BTUlhr):
Maximum Heat Input (million BTUlhr):
Surner Rating:         j3 JBoiler Rating:                       .
Surner Rating:
j3 JBoiler Rating:
Maximum Actual Firing Rate (million BTU/hr):
Maximum Actual Firing Rate (million BTU/hr):
Percent Space Heat:             W Percent Process Heat:
Percent Space Heat:
W Percent Process Heat:
Stack Parameters:
Stack Parameters:
Stack Number:                 2 Stack/Duct Discharge Height (feet) :                             21.0 Stack/Duct Inner Diameter at Exit (inches) :7.9 Exit Gas Temperature (deg.F:                                 -    250 Flow Rate at Exit (actual FT3Imin) :                         [   1,992 If an air pollution control device for the source exists inspect the following information and correct if necessary:
Stack Number:
TSP Control Device: I none                                                   Theoretical Efficiency:
2 Stack/Duct Discharge Height (feet) :
S02 Control Device: [none                             .Theoretical                       Efficiency:
21.0 Stack/Duct Inner Diameter at Exit (inches) :7.9 Exit Gas Temperature (deg.F:
NOx Control Device: none                                               . .]TheoreticalEfficiency:
250 Flow Rate at Exit (actual FT3Imin) :
VOC Control Device       none                                               Theoretical Efficiency: j CO Control Device:     I none                                               Theoretical Efficiency:   "
[
1,992 If an air pollution control device for the source exists inspect the following information and correct if necessary:
TSP Control Device: I none Theoretical Efficiency:
S02 Control Device: [none  
.Theoretical Efficiency:
NOx Control Device: none  
..]Theoretical Efficiency:
VOC Control Device none Theoretical Efficiency:
j CO Control Device: I none Theoretical Efficiency:
If an estimated emission rate exists, please supply the information below:
If an estimated emission rate exists, please supply the information below:
Estimated Emission Rite* :
Estimated Emission Rite* :
Basis of Estimate         .
Basis of Estimate
* If test data 4 years old or less is available.
* If test data 4 years old or less is available.


Richardl Emch - Final 2005 emissions inventory report for Entergy VYi 262006.pdf                                               Page 911 Vermont Agency of Natural Resources                         Process Source 2005 Air Pollutant Emissions Inventory                     For CriteriaPollutants The Information displayed on this form is that which is currently on file for your facility. It is based on inventory forms completed for calendar year 2004 or the most recent year available. The Information must be updated to calendar year 2005. Please review the Information contained in the boxes. If there is no value in a box, write in the correct 2005 value. If there is a value, but It Is Incorrect for 2005, cross out the value and In its place write the correct value.
Richardl Emch - Final 2005 emissions inventory report for Entergy VYi 262006.pdf Page 9 11 Vermont Agency of Natural Resources Process Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The Information displayed on this form is that which is currently on file for your facility. It is based on inventory forms completed for calendar year 2004 or the most recent year available. The Information must be updated to calendar year 2005. Please review the Information contained in the boxes. If there is no value in a box, write in the correct 2005 value. If there is a value, but It Is Incorrect for 2005, cross out the value and In its place write the correct value.
If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.
If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.
Facility Name:     ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form: I LT)--
Facility Name:
I     f,,I                                   I Facility ID:       WM2335 Source
ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form: I LT)--
I f,,I I
Facility ID:
WM2335 Source


== Description:==
== Description:==
Particulate Emissions from Cooling Tower Stack Number:           5 Source Number:           5 Segment Number:           I Source Classification Code:         3-85-001-01 Operational Data:
Particulate Emissions from Cooling Tower Stack Number:
HoursPerDayi:                       Winter Throughput (%):
Source Number:
DaysPerWeek:        Ill]            Spring Throughput (%)                         ma WeeksPerYear: 1113]                  Summer Throughput (%):           '656"         aKf -F   D "
5 5
HoursPerYear::2,,tf                  Autumn Throughput (%): [             )*o4X,-       ;ioS-W       (OCP (Over)                        t (Z.b p
Segment Number:
I Source Classification Code:
3-85-001-01 Operational Data:
HoursPerDayi:
DaysPerWeek: Ill]
WeeksPerYear: 1113]
HoursPerYear: :2,,tf Winter Throughput (%):
Spring Throughput (%)
ma Summer Throughput (%):  
'656" aKf -F D
Autumn Throughput (%): [  
)*o4X,-  
;ioS-W (OCP t (Z.b (Over) p


Richard Emch - Final 2005 emissions inventory repoqrfor Entergy VY 1_26 2006.pdf                             Page 1.9j .....
Richard Emch - Final 2005 emissions inventory repoqrfor Entergy VY 1_26 2006.pdf Pag Page 1.9j Process Source (continued)
Pag Process Source (continued)
Raw Materials Input*:
Raw Materials Input*:
Type                                 Quantity Product Materials Output*:
Type Quantity Product Materials Output*:
Type                                   Quantity
Type Quantity
                          *Information in this section only necessary If accurate figures for stack flow rate and hours of operation cannot be supplied.
*Information in this section only necessary If accurate figures for stack flow rate and hours of operation cannot be supplied.
                          *StackParameters:
*Stack Parameters:
Stack Number:           5 Stack/Duct Discharge Height (Feet) :II                               o~o   1 StackfDuct Inner Diameter at Exit (Inches):
Stack Number:
Exit Gas Temperature (Deg F):                             [         0Z Flow Rate at Exit (Actual FT3/Min) ,                       I0I If there is an air pollution control device on this source inspect the following information and correct if necessary:
5 Stack/Duct Discharge Height (Feet) :II o~o 1 StackfDuct Inner Diameter at Exit (Inches):
PM Control Device:           none Theoretical Efficiency (%):       [I           0I [
Exit Gas Temperature (Deg F):
[
0Z Flow Rate at Exit (Actual FT3/Min),
I0I If there is an air pollution control device on this source inspect the following information and correct if necessary:
PM Control Device:
none Theoretical Efficiency (%): [I 0I [
If available, supply theoretical efficiencies for:
If available, supply theoretical efficiencies for:
PMIO Efficiency (%):     III         j PM2.5 Efficiency ()
PMIO Efficiency (%): III j
PM2.5 Efficiency ()
(NOTE: This Information will not affect the Air Registration Fee Estimate).
(NOTE: This Information will not affect the Air Registration Fee Estimate).
If an estimated emission rate exists for PM, supply the information below Estimated Emission Rate*                                               [
If an estimated emission rate exists for PM, supply the information below Estimated Emission Rate*
[
Basis of Estimate:
Basis of Estimate:
                            *.If test data 4 years old or less Is available.
*.If test data 4 years old or less Is available.


kchard Emc6h- Final 2005 6msp           n!&#xfd;qetory reportforEnter&#xfd;gyKV         12 206pdf                                 Page 11 i Vermont Agency of Natural Resources                               Combustion Source*
kchard Emc6h-Final 2005 6msp n!&#xfd;qetory reportforEnter&#xfd;gyKV 12 206pdf Page 11 i Vermont Agency of Natural Resources 2005 Air Pollutant Emissions Inventory Combustion Source*
2005 Air Pollutant Emissions Inventory                             For Criteria Pollutants The Information displayed on this form Is that which Is currently on file for your' facility. It Is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review; the information contained in the boxes. If there Is no value in a box, write In the correct 2005 value. If there Is a value, but it is incorrect for 2005, cross out the value and in Its place write the correct value.
For Criteria Pollutants The Information displayed on this form Is that which Is currently on file for your' facility. It Is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review; the information contained in the boxes. If there Is no value in a box, write In the correct 2005 value. If there Is a value, but it is incorrect for 2005, cross out the value and in Its place write the correct value.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
Facility Name:         ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form         I                 bew,~c     Ij-                 I Facility ID       *WM2335 Source
Facility Name:
ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form I
bew,~c Ij-I Facility ID  
*WM2335 Source


== Description:==
== Description:==
Emergency Diesels (2). 1675 hp Stack Number:                         3 Source Number:                       3 Seement Number:*
Emergency Diesels (2). 1675 hp Stack Number:
Source Classification Code: 2-02-004-01 Operational Data:
Source Number:
Hours Per Day:               0         Winter Throughput (%): [                 f 25 Days Per Week: '              0]        Spring Throughput(/):         Ii       25i .
3 3
Weeks Per Year:                        Summer Throughput (%):             ]
Seement Number:*
Hours Per Year:        ': 9            Autumn Throughput (%).       :LiI       5 L.j7,    kr-.      (Over)
Source Classification Code:
2-02-004-01 Operational Data:
Hours Per Day:
0 Days Per Week: '
0]
Weeks Per Year:
Hours Per Year:
': 9 L.j7, kr-.
Winter Throughput (%): [
25 f Spring Throughput(/): Ii 25i.
Summer Throughput (%):  
]
Autumn Throughput (%). :LiI 5
(Over)


tl A
m J
Jm
A tl
&#xfd;Yiqh&#xfd;r&#xfd;(E&#xfd;&#xfd;nch - Final 2005 emissio&#xfd;&#xfd;.inye&#xfd;ntW_&#xfd;epor&#xfd;t&#xfd;&#xfd;,&#xfd;&#xfd;qrgyy&#xfd; 1_?6_?QO&#xfd;.p&#xfd;f                                                     J&#xfd;age _y4_q Richard Emch Final 2005 emissions inventory report for Entergy VY 1 262006.pdf
&#xfd;Yiqh&#xfd;r&#xfd;(E&#xfd;&#xfd;nch - Final 2005 emissio&#xfd;&#xfd;.inye&#xfd;ntW_&#xfd;epor&#xfd;t&#xfd;&#xfd;,&#xfd;&#xfd;qrgyy&#xfd; 1_?6_?QO&#xfd;.p&#xfd;f J&#xfd;age _y4_q Richard Emch - Final 2005 emissions inventory report for Entergy VY 1 262006.pdf  
                                                                                                                                  -~ Page 12t1 Combustion Source (continued)
-~
FuelType:               FUEL OIL (#2) 2005 Fuel Consumption: (supply units):               *          .  ,
Page 12t1 Combustion Source (continued)
Av. Sulfur Content of Fuel (%):             .          Ash Content of Fuel (%):
FuelType:
(Pleasesupply a currentestimate of mid-rangesulfur conteno Maximum Heat Input (million BTUlhr):
FUEL OIL (#2) 2005 Fuel Consumption: (supply units):
Burner Rating:                             Boiler Rating:
Av. Sulfur Content of Fuel (%):
Maximum Actual Firing Rate (million BTU/hr):               [
Ash Content of Fuel (%):
Percent Space Heat:         "0 Percent Process Heat:
(Please supply a current estimate of mid-range sulfur conteno Maximum Heat Input (million BTUlhr):
Burner Rating:
Boiler Rating:
Maximum Actual Firing Rate (million BTU/hr):
[
Percent Space Heat:  
"0 Percent Process Heat:
Stack Parameters:
Stack Parameters:
Stack Number:               3
Stack Number:
                                  *Stack/Duct Discharge Height (feet)                       j 29.8j     j Stack/Duct Inner Diameter at Exit (inches).:               27X Exit Gas Temperature (deg. F)                             *180             .
3
Flow Rate at Exit (actual FIn/min)                         63,983 If an air pollution control device for the source exists inspect the following information and correct if necessary:
*Stack/Duct Discharge Height (feet) j 29.8j j Stack/Duct Inner Diameter at Exit (inches).:
TSP Control Device: I none                                           I Theoretical Efficiency:   0 -1 S02 Control Device: I none                                             Theoretical Efficiency:
27X Exit Gas Temperature (deg. F)  
NOx ConirolDevIce:Inone                                              ]
*180 Flow Rate at Exit (actual FIn/min) 63,983 If an air pollution control device for the source exists inspect the following information and correct if necessary:
                                                                                              * -Theoretical Efficiency:
TSP Control Device: I none I Theoretical Efficiency:
VOC Control Devicef none                                              'Theoretical Efficiency:
0-1 S02 Control Device: I none NOx ConirolDevIce:I none VOC Control Devicef none Theoretical Efficiency:
LI E I
* ] -Theoretical Efficiency:
CO Control Device:       none                                       I Theoreticsl Efficiency:
' Theoretical Efficiency:
L I E I
CO Control Device:
none I Theoreticsl Efficiency:
If an estimated emission rate exists, please supply the information below:
If an estimated emission rate exists, please supply the information below:
Estimated Emission Rate* :"
Estimated Emission Rate* :"
Basis of Estimate:
Basis of Estimate:
IIf test data 4 years old or less Is available.
I If test data 4 years old or less Is available.


1 I 1&#xfd;icha&#xfd;o Emch - Final 2005 emissions inveqtory_&#xfd;epo&#xfd;jq&#xfd;_&#xfd;q&#xfd;gy \T_&#xfd;&#xfd;22&#xfd;qq.pqf                                                       - &#xfd;agq P g 111q,11
1 I 1&#xfd;icha&#xfd;o Emch - Final 2005 emissions inveqtory_&#xfd;epo&#xfd;jq&#xfd;_&#xfd;q&#xfd;gy \\T_&#xfd;&#xfd;22&#xfd;qq.pqf
........ a. d...... -Fna .00.....          .      i.n.r.rp         rtfo.ntry.Y           1.6.0     6.d Vermont Agency of Natural Resources                                 Combustion Source 2005 Air Pollutant Emissions Inventory                             For Criteria Pollutants The information displayed on this form is that which is currently on file for your facility. It Is based on inventory forms completed for calendar year 2004 or the most recent year available."The Information must be updated to calendar year 2005. Please revlevs the information contained In the boxes. If there is no value In a box, write In the correct 2005 value. If there Is a value, but It is incorrect for 2005, cross out the value and in its place write the correct value.
- &#xfd;agq 1 q,11
........ a. d...... -Fna 00..
i.n.r.rp rtfo.ntry.Y 1.6.0 6.d P g 11 Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The information displayed on this form is that which is currently on file for your facility. It Is based on inventory forms completed for calendar year 2004 or the most recent year available."The Information must be updated to calendar year 2005. Please revlevs the information contained In the boxes. If there is no value In a box, write In the correct 2005 value. If there Is a value, but It is incorrect for 2005, cross out the value and in its place write the correct value.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
Facility Name:         ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form                       a.                                   ..I Facility ID       WM2335 Source
Facility Name:
ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form a.
..I Facility ID WM2335 Source


== Description:==
== Description:==
235 hp John Deere Diesel Stack Number:                         4 Source Number:                         4.
235 hp John Deere Diesel Stack Number:
I1 Seement Number:
Source Number:
Source Classification Code: 2-01-001-02 Operational Data:
Seement Number:
Hours Per Day:                         'Winter Throughput   (%):
4 4.
Days Per Week:                          *SpringThroughput/(%):           I     25 Weeks Per Year:                          Summer Throughput (%)2:     Z           5Z Hours Per Year:                          Autumn Throughput (%)       :[         2j (Over)
I1 Source Classification Code: 2-01-001-02 Operational Data:
Hours Per Day:
Days Per Week:
Weeks Per Year:
Hours Per Year:
'Winter Throughput (%):
* SpringThroughput/(%):
I 25 Summer Throughput (%)2: Z 5Z Autumn Throughput (%) :[
2j (Over)


Richard Emch -Final 2005 emissions inv"ryf&#xfd;pgqlp&#xfd;,&#xfd;qergyYY.&#xfd;&#xfd;"OQP-Pq&#xfd;,                                                                     Pge1 Richard. Emc - Fina 200   emsson.ivetoy.eprt.o.Ete..   ...                              2.....d Combustion Source (continued)
Richard Emch -Final 2005 emissions inv"ryf&#xfd;pgqlp&#xfd;,&#xfd;qergyYY.&#xfd;&#xfd;"OQP-Pq&#xfd;,
Fuel Type:               FUEL OIL (#2)                 .
Richard. Emc  
2005 Fuel Consumption : (supply units):           jj" :fj'l               $
- Fina 200 emsson.ivetoy.eprt.o.Ete..
Av. Sulfur Content of Fuel (%):
2.....d Pge1 Combustion Source (continued)
* Ash Content of Fuel (%):           0.00' (Pleasesupply a currentestimate of mid-rangesulfur content)
Fuel Type:
FUEL OIL (#2) 2005 Fuel Consumption : (supply units): jj" :fj'l Av. Sulfur Content of Fuel (%):
Ash Content of Fuel (%):
0.00' (Please supply a current estimate of mid-range sulfur content)
Maximum Heat Input (million BTU/hr):
Maximum Heat Input (million BTU/hr):
Burner Rating:                 j           Boller Rating:                 [Z Maximum Actual Firing Rate (million BTU/hr):               LI0 Percent Space Heat:       ir     0i*
Burner Rating:
Percent Process Heat:             0o Stack Parameters:
j Boller Rating:
Stack Number:                 4 Stack/Duct Discharge Height (feet)                           12.5~
[Z Maximum Actual Firing Rate (million BTU/hr):
Stack/Duct Inner Diameter at Exit (inches)                       3.9iI Exit Gas Temperature (deg. F)                                     180~
LI0 Percent Space Heat:
Flow Rate at Exit (actual FT3/min)                             '4,30 If an air pollution control device for the source exists inspect the following information and correct if necessary:
ir 0i*
TSP Control Device:       none                                             TTheoretical Efficiency:
Percent Process Heat:
S02 Control Device: I none" Theoretical Efficiency:       0 NO Control Device:Inon Theoretical Efficiency:
0o Stack Parameters:
VOC Control De vicei on                                                 ] The;retical Efficiency:     EZ~
Stack Number:
CO Control Device:     F none                                             Theoretical Efficiency:       0 If an estimated emission rate exists, please supply the information below:
4 Stack/Duct Discharge Height (feet)
Estimated Emission Rate*           T                                     I.
Stack/Duct Inner Diameter at Exit (inches)
Exit Gas Temperature (deg. F)
Flow Rate at Exit (actual FT3/min) 12.5~
3.9iI 180~
'4,30 If an air pollution control device for the source exists inspect the following information and correct if necessary:
TSP Control Device:
none TTheoretical Efficiency:
S02 Control Device: I none" Theoretical Efficiency:
NO Control Device:Inon VOC Control De vicei on Theoretical Efficiency:
] The;retical Efficiency:
CO Control Device: F none Theoretical Efficiency:
If an estimated emission rate exists, please supply the information below:
Estimated Emission Rate* T 0
EZ~
0 1*
Basis of Estimate :
Basis of Estimate :
I*f test data 4 years old or less is available.
I* f test data 4 years old or less is available.
1*
I.
_". ' .A
.A


I Richard Emch -_H550.pdf___                                                                                                             Page 1 1i Richard Emch H550.pdf Page 1 ii MATERIAL SAFETY DATA SHEET N"NALCO                                          PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
I Richard Emch -_H550.pdf___
(800) 424-9300 (24 Hours)   CHEMTREC
Page 1 1i Richard Emch - H550.pdf Page 1 ii N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
: 11.         CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME:                                     H-550 APPLICATION :                                     MICROBIOCIDE COMPANY IDENTIFICATION:                           Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S):                     (800) 424-9300 (24 Hours)     CHEMTREC NFPA 704MWHMIS RATING HEALTH : 3/3             FLAMMABILITY : 1/1             INSTABILITY :     0/0     OTHER:
(800) 424-9300 (24 Hours)
0 = Insignificant   1= Slight " 2 = Moderate 3=High 4=Extreme r2.       I COMPOSITION/INFO RMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
CHEMTREC
Hazardous Substance(s)                                   CAS NO                 % (w/w)
: 11.
Glutaraldehyde                                                                111-30-8              30.0- 60.0
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME:
: 13.       1HAZARDS IDENTIFICATION
H-550 APPLICATION :
                                                                  -EMERGENCY       OVERVIEW DANGER Corrosive. Causes irreversible eye damage. Causes skin bums. Harmful if inhaled. May be fatal if swallowed.
MICROBIOCIDE COMPANY IDENTIFICATION:
Harmf ul if absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Causes asthmatic signs and symptoms in hyper-reactiv e individuals.
Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S):
Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Do not swallow. Wear goggles, protective clothing, and rubber gloves. Wash thoroughly with soap and water after handing. Remove contaminated clothing and wash before reuse.
(800) 424-9300 (24 Hours)
Not flammable or combustible. May evolve oxides of carbon (COx) under fire concitions.
CHEMTREC NFPA 704MWHMIS RATING HEALTH :
3/3 FLAMMABILITY :
1/1 INSTABILITY :
0/0 OTHER:
0 = Insignificant 1 = Slight " 2 = Moderate 3=High 4=Extreme r2.
I COMPOSITION/INFO RMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
Hazardous Substance(s)
CAS NO 111-30-8 Glutaraldehyde
% (w/w) 30.0- 60.0
: 13.
1HAZARDS IDENTIFICATION
-EMERGENCY OVERVIEW DANGER Corrosive. Causes irreversible eye damage. Causes skin bums. Harmful if inhaled.
May be fatal if swallowed.
Harmf ul if absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
Causes asthmatic signs and symptoms in hyper-reactiv e individuals.
Do not get in eyes, on skin, on clothing.
Avoid breathing vapor. Do not swallow. Wear goggles, protective clothing, and rubber gloves. Wash thoroughly with soap and water after handing. Remove contaminated clothing and wash before reuse.
Not flammable or combustible.
May evolve oxides of carbon (COx) under fire concitions.
PRIMARY ROUTES OF EXPOSURE:
PRIMARY ROUTES OF EXPOSURE:
Eye, Skin, Inhalation HUMAN HEALTH HAZARDS -ACUTE:
Eye, Skin, Inhalation HUMAN HEALTH HAZARDS -ACUTE:
EYE CONTACT:
EYE CONTACT:
Corrosive. Will cause eye bums and permanent tissue damage.
Corrosive.
Will cause eye bums and permanent tissue damage.
Nalco Company 1601 W. Diehl Road
Nalco Company 1601 W. Diehl Road
* Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access S1/12
* Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access S1/12


I Richiird Eriich - H550.pdf                                                                                                                         Page 2 Paqe 21111 I Richard Emch H550.pdf MATERIAL SAFETY DATA SHEET N"NALCO                                            -PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
I Richiird Eriich - H550.pdf Page 2 11 I Richard Emch - H550.pdf Paqe 211 N"NALCO MATERIAL SAFETY DATA SHEET
(800) 424-9300 (24 Hours)     CHEMTREC SMUN CONTACT:
-PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
(800) 424-9300 (24 Hours)
CHEMTREC SMUN CONTACT:
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered.
Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
INGESTION:
INGESTION:
Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach.
Not a likely route of exposure.
Corrosive; causes chemical burns to the mouth, throat and stomach.
INHALATION:
INHALATION:
Irritating, in high concentrations, to the eyes, nose, throat and lungs. Inhalati on of product mist or vapors may cause respiratory allergy.
Irritating, in high concentrations, to the eyes, nose, throat and lungs.
Inhalati on of product mist or vapors may cause respiratory allergy.
SYMPTOMS OF EXPOSURE Acute A review of available data does not identify any symptoms from exposure not previously mentioned.
SYMPTOMS OF EXPOSURE Acute A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic :
Chronic :
Line 273: Line 439:
HUMAN HEALTH HAZARDS -CHRONIC:
HUMAN HEALTH HAZARDS -CHRONIC:
Prolonged inhalation of product can increase lung injury in persons with emphysema, asthma, or other lung disorders.
Prolonged inhalation of product can increase lung injury in persons with emphysema, asthma, or other lung disorders.
: 14.           FIRST AID MEASURES EYE CONTACT :
: 14.
FIRST AID MEASURES EYE CONTACT :
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open.
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open.
SKIN CONTACT:
SKIN CONTACT:
Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large splash flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.
Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes.
For a large splash flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.
INGESTION:
INGESTION:
Get immediate medical attention. DO NOT INDUCE VOMITING. Ifconscious, washout mouth and give water to drink.
Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink.
INHALATION Remove to fresh air, treat symptomatically.       If symptoms develop, seek medical advice.
INHALATION Remove to fresh air, treat symptomatically.
IF IN EYES:       Immediately flush with plenty of water for at least 15 minutes. Get immediate medical attention.
If symptoms develop, seek medical advice.
IF IN EYES:
Immediately flush with plenty of water for at least 15 minutes.
Get immediate medical attention.
IF ON SKIN: Immediately wash with plenty of soap and water. Get medical attention.
IF ON SKIN: Immediately wash with plenty of soap and water. Get medical attention.
IF INHALED: Remove to fresh air. If breathing is difficult, administer oxygen. If symptoms persist, call a physician.
IF INHALED: Remove to fresh air. If breathing is difficult, administer oxygen. If symptoms persist, call a physician.
IF SWALLOWED:         DO NOT INDUCE VOMITING. Do not give anything to drink. Seek medical advice with urgency.
IF SWALLOWED:
DO NOT INDUCE VOMITING. Do not give anything to drink. Seek medical advice with urgency.
Nalco Company 1601 W. Diehl Road
Nalco Company 1601 W. Diehl Road
* Naperville ,Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/12
* Naperville,Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/12


I Richard Enich - H550.pdf                                                                                                                       Page I Richard Emch H550.pdf Pacie 33t111 MATERIAL SAFETY DATA SHEET AWNALCO                                              PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
I Richard Enich - H550.pdf Page 3 11 I Richard Emch - H550.pdf Pacie 3t1 AWNALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC NOTE TO PHYSICIAN :
(800) 424-9300 (24 Hours)
CHEMTREC NOTE TO PHYSICIAN :
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical concition.
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical concition.
: 15.         1FIRE FIGHTING MEASURES FLASH POINT:                               None EXTINGUISHING MEDIA:
: 15.
1FIRE FIGHTING MEASURES FLASH POINT:
None EXTINGUISHING MEDIA:
This product would not be expected to bum unless all the water is boiled away. The remaining organics may be Ignitable. Use extinguishing media appropriate for surroundng fire.
This product would not be expected to bum unless all the water is boiled away. The remaining organics may be Ignitable. Use extinguishing media appropriate for surroundng fire.
FIRE AND EXPLOSION HAZARD :
FIRE AND EXPLOSION HAZARD :
Not flammable or combustible. May evolve oxides of carbon (COx) under fire conditions.
Not flammable or combustible.
May evolve oxides of carbon (COx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressur e self contained breathing apparatus and protective suit.
In case of fire, wear a full face positive-pressur e self contained breathing apparatus and protective suit.
: 16.       1ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
: 16.
Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended In Section 8 (Exposure Controls/Persona I Protection). Notify appropriate government, occupational health and safety and environmental authorities.
1 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material.
Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended In Section 8 (Exposure Controls/Persona I Protection).
Notify appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP:
METHODS FOR CLEANING UP:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Dilute the glutaraldehyde to 5% or less with water. Add sodium bisulfite (2-3 parts by weight per part glutaraldehyde). This will typically reduce the glutaraldehyde concentration to 2 ppm or less in 5 minutes at room temperature. The remaining solution can be disposed of via appropriate means. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container.
Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Dilute the glutaraldehyde to 5% or less with water. Add sodium bisulfite (2-3 parts by weight per part glutaraldehyde). This will typically reduce the glutaraldehyde concentration to 2 ppm or less in 5 minutes at room temperature. The remaining solution can be disposed of via appropriate means. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
This pesticide is toxic to fish. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified In writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/12
This pesticide is toxic to fish. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified In writing prior to discharge.
Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/12


[ F:Vicha&#xfd;d Em9h - H550.pdf                                                                                                                     Paige
[ F:Vicha&#xfd;d Em9h - H550.pdf Paige 4,11
[Richard. Emch H550.pdf Page 4,11 41 MATERIAL SAFETY DATA SHEET NNALCO                                            PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
[Richard. Emch - H550.pdf Page 41 NNALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours)   CHEMTREC
(800) 424-9300 (24 Hours)
: 17.         I HANDLING AND STORAGE HANDUNG :
CHEMTREC
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containe rs closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
: 17.
I HANDLING AND STORAGE HANDUNG :
Do not get in eyes, on skin, on clothing.
Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containe rs closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
STORAGE CONDITIONS:
STORAGE CONDITIONS:
Store the containers tightly closed. Store separately from oxidizers. Store in suitable labelled containers.
Store the containers tightly closed. Store separately from oxidizers. Store in suitable labelled containers.
SUITABLE CONSTRUCTION MATERIAL:
SUITABLE CONSTRUCTION MATERIAL:
Compatibility with Plastic Materials can vary; we therefore* recommend that compatibility is tested prior to use.
Compatibility with Plastic Materials can vary; we therefore* recommend that compatibility is tested prior to use.
: 18.         1 EXPOSURE CONTROLS/PERSONA L PROTECTION OCCUPATIONAL EXPOSURE UMITS:
: 18.
1 EXPOSURE CONTROLS/PERSONA L PROTECTION OCCUPATIONAL EXPOSURE UMITS:
Exposure gidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.
Exposure gidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.
ACGIH/TLV:
ACGIH/TLV:
Substance(s)
Substance(s)
Glutaraldehyd e               CEIUNG: 0.05 ppm, 0.2 mg/m3 0.05 ppm , 0.2 mg/m3 OSHNPEL :
Glutaraldehyd e OSHNPEL :
Substance(s)
Substance(s)
Glutaraldehyde                 CEIUNG: 0.2 ppm, 0.8 mg'm3 ENGINEERING MEASURES :
Glutaraldehyde CEIUNG: 0.05 ppm, 0.2 mg/m3 0.05 ppm, 0.2 mg/m3 CEIUNG: 0.2 ppm, 0.8 mg'm3 ENGINEERING MEASURES :
General ventilation is recommended.       Use local exhaust ventilation if necessary to control airbome mist and vapor.
General ventilation is recommended.
Use local exhaust ventilation if necessary to control airbome mist and vapor.
RESPIRATORY PROTECTION:
RESPIRATORY PROTECTION:
If significant mists, vapors or aeros ols are generated an approved respirator is recommended. A dust, mist, fume cartridge may be used. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection Is required, institute a compiete respiratory protection program including selection, fit testing, training, maintenance and inspection.
If significant mists, vapors or aeros ols are generated an approved respirator is recommended.
A dust, mist, fume cartridge may be used. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection Is required, institute a compiete respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
HAND PROTECTION:
BUTYL GLOVES, NEOPRENE GLOVES, Viton# gloves SKIN PROTECTION :
BUTYL GLOVES, NEOPRENE GLOVES, Viton# gloves SKIN PROTECTION :
Line 328: Line 515:
Wear a face shield with chemical splash goggles..
Wear a face shield with chemical splash goggles..
Nalco Company 1601 W. Diehl Road
Nalco Company 1601 W. Diehl Road
* Naperville , Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/12
* Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/12


IF&#xfd;ichw--d-E' ITch --I-155b-Pdf                                                                                                               Page 5 ;
I F&#xfd;ichw--d-E' IT ch --I-155b-Pdf Page 5 ;
Page 5;I I Richard Ernch   - H550.pdf MATERIAL SAFETY DATA SHEET AWNALCO                                            PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
I Richard Ernch - H550.pdf Page 5;I AWNALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours)   CHEMTREC HYGIENE RECOMMENDATIONS :
(800) 424-9300 (24 Hours)
CHEMTREC HYGIENE RECOMMENDATIONS :
Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.
Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.
: 19.       1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE                 Uquid APPEARANCE                     Colorless ODOR                           Aldehyde SPECIFIC GRAVITY                           1.11 -1.13 @ 77&deg;F/25&deg;C DENSITY                                   9.4 Ib/gal SOLUBIUTY IN WATER                       Complete pH (100 %)                               3.1 -4.5 0      0 VISCOSITY                                 21 cps @ 68 1F/20 C FREEZING POINT                           -5.8 &deg;F/-21 &deg;C BOIUNG POINT                             213 F/ 100.5 &deg;C VAPOR PRESSURE                             16 mm Hg VAPOR DENSITY                             1.1 VOC CONTENT                               54 % EPA Method 24 Note: These physical properties are typical values for this product and are subject to change.
: 19.
: 10.     1 STABILITY AND REACTIVITY STABIUTY :
1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Uquid APPEARANCE Colorless ODOR Aldehyde SPECIFIC GRAVITY 1.11 -1.13  
@ 77&deg;F/25&deg;C DENSITY 9.4 Ib/gal SOLUBIUTY IN WATER Complete pH (100 %)
3.1 -4.5 VISCOSITY 21 cps @ 68 01F/20 0 C FREEZING POINT  
-5.8 &deg;F/-21 &deg;C BOIUNG POINT 213 F/ 100.5 &deg;C VAPOR PRESSURE 16 mm Hg VAPOR DENSITY 1.1 VOC CONTENT 54 % EPA Method 24 Note: These physical properties are typical values for this product and are subject to change.
: 10.
1 STABILITY AND REACTIVITY STABIUTY :
Stable under normal conditions.
Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
HAZARDOUS POLYMERIZATION:
Line 344: Line 537:
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.
HAZARDOUS DECOMPOSITION PRODUCTS:
HAZARDOUS DECOMPOSITION PRODUCTS:
Under fire conditions:               Oxides of carbon
Under fire conditions:
: 11.     1 TOXICOLOGICAL           INFORMATION The following results are for the product.
Oxides of carbon
: 11.
1 TOXICOLOGICAL INFORMATION The following results are for the product.
Nalco Company 1601 W. Diehl Road
Nalco Company 1601 W. Diehl Road
* Naperville , Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/12
* Naperville, Illinois 60563-1198  
* (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/12


I I Richitrd Emch - H550.pdf                                                                                                             Page 6 11 Paqe 611 I Richard Emch I
I I Richitrd Emch - H550.pdf Page 6 11 I Richard Emch - H550.pdf Paqe 611 I AWNALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
                - H550.pdf MATERIAL SAFETY DATA SHEET AWNALCO                                            PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours)
(800) 424-9300 (24 Hours)   CHEMTREC ACUTE ORAL TOXICITY:
CHEMTREC ACUTE ORAL TOXICITY:
Species               LD50                           Test Descriptor Rat                   1,300 mg/kg                     Product Glutaraldehyde Rat                   1.2 mVkg                       45% Active Ingredient Rat                   1.54-1.87 mt/kg               25% Active Ingredient Rat                   1.07 - 1.62 mVkg               10% Active Ingredient Rating : Harmful ACUTE DERMAL TOXICITY:
Species LD50 Rat 1,300 mg/kg Rat 1.2 mVkg Rat 1.54-1.87 mt/kg Rat 1.07 - 1.62 mVkg Rating : Harmful ACUTE DERMAL TOXICITY:
Species             LD50                             Test Descriptor Rabbit               897 mg/kg                       Product Glutaraldehyde Rabbit                 2.00 - 2.71 ml/kg             45% Active Ingredient Rabbit                 8.0- 12.8 mVkg                 25% Active Ingredient Rating : Harmful ACUTE INHALATION TOXICITY:
Species LD50 Rabbit 897 mg/kg Rabbit 2.00 - 2.71 ml/kg Rabbit 8.0- 12.8 mVkg Rating : Harmful ACUTE INHALATION TOXICITY:
Species               LC5O                             Test Descriptor Rat                 0.48 mg/I 0                     Product Rating : Very Toxic PRIMARY SKJN IRRITATION: At 10% or greater, glutaraldehyde solutions may cause moderate to severe irritation, with possible necrosis after prolonged contact.
Species LC5O Rat 0.48 mg/I 0 Rating : Very Toxic Test Descriptor Product Glutaraldehyde 45% Active Ingredient 25% Active Ingredient 10% Active Ingredient Test Descriptor Product Glutaraldehyde 45% Active Ingredient 25% Active Ingredient Test Descriptor Product PRIMARY SKJN IRRITATION: At 10% or greater, glutaraldehyde solutions may cause moderate to severe irritation, with possible necrosis after prolonged contact.
PRIMARY EYE IRRITATION : At levels of 0.2% and below of glutaraldehyd e, no eye irritation was noted. Levels above 0.2% of glutaraldehyd e produced moderate to severe irritation and comeal irjury.
PRIMARY EYE IRRITATION : At levels of 0.2% and below of glutaraldehyd e, no eye irritation was noted. Levels above 0.2% of glutaraldehyd e produced moderate to severe irritation and comeal irjury.
SENSITIZATION :
SENSITIZATION :
Line 360: Line 556:
CARCINOGENICITY :
CARCINOGENICITY :
None of the substances in this prod uct are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
None of the substances in this prod uct are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
HUMAN HAZARD CHARACTERIZATION Based on our hazard characterization , the potential human hazard Is: High 112.         1 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS :
HUMAN HAZARD CHARACTERIZATION Based on our hazard characterization, the potential human hazard Is: High 112.
1 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS :
The following results are for the product along with results on the active substances.
The following results are for the product along with results on the active substances.
ACUTE FISH RESULTS :
ACUTE FISH RESULTS :
I Species                             I Exposure       LC50                 I Test Descriptor I Bluegil Sunfish                     I 96 hrs       I 22.4 mg/I           I Product IFathead Minnow                         96 hrs         10.8 man               rouc Sheepshead Minnow                     96 hrs         64 mg/I               Product Nalco Company 1601 W. Diehl Road
I Species I Exposure LC50 I Test Descriptor I Bluegil Sunfish I 96 hrs I 22.4 mg/I I Product IFathead Minnow 96 hrs 10.8 man rouc Sheepshead Minnow 96 hrs 64 mg/I Product Nalco Company 1601 W. Diehl Road
* Naperville , Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/12
* Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/12


I Richard Emch - H550.pdf                                                                                                                     P Pag~e 7 !
I Richard Emch - H550.pdf PPag~e 7 !
MATERIAL SAFETY DATA SHEET N"NALCO                                          PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours)     CHEMTREC Rainbow Trout                   196 hrs         (24 mg/I                 Product ACUTE INVERTEBRATE RESULTS :
(800) 424-9300 (24 Hours)
Species                         [ Exposure       I LC50             EC50           Test Descriptor Daphnia mana                       48 hrs           11.5 m__I                         Product Shore Crab                           96 hrs           930 m_/I                           Product Grass Shrimp                         96 hrs         82 mg/I                             Product Mysid Shrimp (Mysidopjis           96 hrs           14.2 mg/I                         Product bahia)
CHEMTREC Rainbow Trout 196 hrs (24 mg/I Product ACUTE INVERTEBRATE RESULTS :
American Oyster                     96 hrs                             1.56 mg/I       Product Acartia tonsa                       48 hrs                           1 0.22 mg/I       Product AQUATIC PLANT RESULTS :
Species
Species                             Exposure       EC50/LC50             Test Descriptor Marine Algae (Skeletonema           72 hrs         1.22 mg/I             Product costatu-n)
[ Exposure I LC50 EC50 Test Descriptor Daphnia mana 48 hrs 11.5 m__I Product Shore Crab 96 hrs 930 m_/I Product Grass Shrimp 96 hrs 82 mg/I Product Mysid Shrimp (Mysidopjis 96 hrs 14.2 mg/I Product bahia)
Algae (Scenedesmus                 72 hrs           1.7 mg/I               Product subspicatus)                     I AQUATIC MICROORGANISM RESULTS:
American Oyster 96 hrs 1.56 mg/I Product Acartia tonsa 48 hrs 1 0.22 mg/I Product AQUATIC PLANT RESULTS :
ISpecies        rta               I Exposure       I EC50/LC50           ITest Descriptor Sewage Microornisms               I96 hrs         134 mo                 Active Substance AVIAN RESULTS:
Species Exposure EC50/LC50 Test Descriptor Marine Algae (Skeletonema 72 hrs 1.22 mg/I Product costatu-n)
Species                             Exoue           L5                   Test Descriptor Bobwhite Quail                       8 Days           10,000 ppr           Active Substance Mallard Duck                       1 8 Days           10,000 ppn         I Active Substance Mallard Duck                       I               L933 mcftg           150% Active Ingredient MOBIULTY :
Algae (Scenedesmus 72 hrs 1.7 mg/I Product subspicatus)
The environmental fate was estimated using a level IIIfugacity model embedded in the EPI (estimation program Interface) Suite TM , provided by the US EPA The model assumes a steady state conrdt ion between the total Input and output. The level III model does not require equilibrium between the defined media. The information provided Is Intended to give the user a general estimate of the environment al fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soiVsediment In the approximate respective percentages; Ar                       Water         I     SoiVSediment
I AQUATIC MICROORGANISM RESULTS:
                                      <5%                     30-50%1o                 50- 70%1o The portion in water is expected to be soluble or dispersible.
I Species rta I Exposure I EC50/LC50 ITest Descriptor Sewage Microornisms I96 hrs 134 mo Active Substance AVIAN RESULTS:
Species Exoue L5 Test Descriptor Bobwhite Quail 8 Days 10,000 ppr Active Substance Mallard Duck 1 8 Days 10,000 ppn I Active Substance Mallard Duck I
L933 mcftg 150% Active Ingredient MOBIULTY :
The environmental fate was estimated using a level IIIfugacity model embedded in the EPI (estimation program Interface) Suite TM, provided by the US EPA The model assumes a steady state conrdt ion between the total Input and output. The level III model does not require equilibrium between the defined media. The information provided Is Intended to give the user a general estimate of the environment al fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soiVsediment In the approximate respective percentages; Ar Water I
SoiVSediment
<5%
30-50%1o 50- 70%1o The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL This preparation or material Is not expected to bioaccumulate.
BIOACCUMULATION POTENTIAL This preparation or material Is not expected to bioaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURIE CHARACTERIZATION Based on our hazard characterization , the potential environmental hazard is: Moderate Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/12
ENVIRONMENTAL HAZARD AND EXPOSURIE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Moderate Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/12


Richa-r-d--E'm-"ch - H550. pdf                                                                                                                       Pa"e8 Pa~je8~
Richa-r-d- -E'm-"ch - H550. pdf Pa"e8 I Richard Ernch - H550.pdf Pa~je8~
IRichard Ernch      - H550.pdf MATERIAL SAFETY DATA SHEET N"NALCO                                          PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 in Section 15. CHEMTREC (24 Hours) see CERCLA/SUPERFUND If released into the environment, If released into the environment, see CERCAINSUPERFUND           in Section 15.
(800) 424-9300 (24 Hours)
113.       I DISPOSAL CONSIDERATIONS                                                                                     I If this product becomes a waste, It Is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characted stics of Subpart C, nor is it listed under Subpart D.
CHEMTREC If released into the environment, see CERCLA/SUPERFUND in Section 15.
As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handing, treatment or disposal requirements. For disposal, contact a property licensed waste treatment, storage, disposal or recycling facility.
If released into the environment, see CERCAINSUPERFUND in Section 15.
A<B>CONTAINER DISPOSAL<B> Metal Containers or Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or reconditionin g, or puncture and dispose of in a sanitary landfill, or other procedures approved by state and local authorities. Plastic Containers: May be incinerated, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. Metal Containers: Must not be incinerated. Do not cut or weld on or near metal containers.
113.
114.       I TRANSPORT INFORMATION                                                                                       I The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shippi ng Name / Hazard Class may vary by packaging, properties, and mode of transportatio n. Typical Proper Shipping Names for this product are as follows.
I DISPOSAL CONSIDERATIONS I
If this product becomes a waste, It Is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characted stics of Subpart C, nor is it listed under Subpart D.
As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handing, treatment or disposal requirements.
For disposal, contact a property licensed waste treatment, storage, disposal or recycling facility.
A<B>CONTAINER DISPOSAL<B> Metal Containers or Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or reconditionin g, or puncture and dispose of in a sanitary landfill, or other procedures approved by state and local authorities.
Plastic Containers:
May be incinerated, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. Metal Containers:
Must not be incinerated.
Do not cut or weld on or near metal containers.
114.
I TRANSPORT INFORMATION I
The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shippi ng Name / Hazard Class may vary by packaging, properties, and mode of transportatio n. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT:
LAND TRANSPORT:
Proper Shipping Name:                         CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
Proper Shipping Name:
Technical Name(s):                             GLUTARALDEHYDE UN/ID No:                                     UN 3265 Hazard Class - Primary:                       8 Packing Group:                                 II Flash Point :                                 None AIR TRANSPORT (ICAO/IATA) :
Technical Name(s):
Proper Shipping Name:                         CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
UN/ID No:
Technical Name(s) :                           GLUTARALDEHYDE UN/ID No:                                     UN 3265 Hazard Class - Primary:                       8 Packing Group :                               II IATA Cargo Packing Instructions:             812 IATA Cargo Aircraft Umit:                     30 L (Max net quantity per package)
Hazard Class - Primary:
Packing Group:
Flash Point :
CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
GLUTARALDEHYDE UN 3265 8
II None AIR TRANSPORT (ICAO/IATA) :
Proper Shipping Name:
Technical Name(s) :
UN/ID No:
Hazard Class - Primary:
Packing Group :
IATA Cargo Packing Instructions:
IATA Cargo Aircraft Umit:
MARINE TRANSPORT (IMDG/IMO):
MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name:                         CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
Proper Shipping Name:
Technical Name(s):                            GLUTARALDEHYDE UN/ID No:                                      UN 3265 Nalco Company 1601 W. Diehl Road
Technical Name(s):
* Naperville , Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8112
UN/ID No:
CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
GLUTARALDEHYDE UN 3265 8
II 812 30 L (Max net quantity per package)
CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
GLUTARALDEHYDE UN 3265 Nalco Company 1601 W. Diehl Road
* Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8112


                                                                                                                                            -Page 9 I Rich&#xfd;&#xfd;Eiiich - H550.p'df I Richard Emch H550.pdf Page 9 ~I MATERIAL SAFETY DATA SHEET P1NALCO                                          PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
I Rich&#xfd;&#xfd;Eiiich - H550.p'df
(800) 424-9300 (24 Hours)   CHEMTREC Hazard Class - Primary:                       8 Packing Group :                               II 115.     1 REGULATORY INFORMATION NATIONAL REGULATIONS, USA:
-Page 9 I Richard Emch - H550.pdf Page 9 ~I P1NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours)
CHEMTREC Hazard Class - Primary:
8 Packing Group :
II 115.
1 REGULATORY INFORMATION NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 Based on our hazard evaluation, the following substance(s) in this product Is/are hazardo us and the reason(s) Is/are shown below.
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 Based on our hazard evaluation, the following substance(s) in this product Is/are hazardo us and the reason(s) Is/are shown below.
Glutaraldehyde : Corrosive, Sensitizer CERCLNSUPERFU ND, 40 CFR 117, 302:
Glutaraldehyde : Corrosive, Sensitizer CERCLNSUPERFU ND, 40 CFR 117, 302:
This product contains the following Reportable Quantity (RO) Substance. Aso listed Is the RQ for the product.
This product contains the following Reportable Quantity (RO) Substance. Aso listed Is the RQ for the product.
RQ Substance                                                 RO Methanol                                                     5,000 lbs SARANSUPERFUND       AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:
RQ Substance RO Methanol 5,000 lbs SARANSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARD OUS SUBSTANCES (40 CFR 355):
SECTION 302 - EXTREMELY HAZARD OUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appen dx A and B as an Extremely Hazardous Substance.
This product does not contain substances listed in Appen dx A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following Indcated EPA hazard categories:
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following Indcated EPA hazard categories:
X               Immediate (Acute) Health Hazard X               Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
X Immediate (Acute) Health Hazard X
Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - UST OF TOXIC CHEMICALS (40 CFR 372) :
SECTION 313 - UST OF TOXIC CHEMICALS (40 CFR 372) :
This product contains the following substance(s), (with CAS # and % range) which appear(s) on the Ust of Toxic Chemicals Hazardous Substance(s)                                 CAS NO                       % fw/w)
This product contains the following substance(s), (with CAS # and % range) which appear(s) on the Ust of Toxic Chemicals Hazardous Substance(s)
Methanol                                               67-56-1                       1.0 -5.0 TOXIC SUBSTANCES CONTROL ACT (TSCA):
CAS NO  
% fw/w)
Methanol 67-56-1 1.0 -5.0 TOXIC SUBSTANCES CONTROL ACT (TSCA):
This product Is exempted under TSCA and regulated unde r FIFRA The inerts are on the Inventory List.
This product Is exempted under TSCA and regulated unde r FIFRA The inerts are on the Inventory List.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For adclitional copies of an MSDS visit www.nalco.com and request access 9/12
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For adclitional copies of an MSDS visit www.nalco.com and request access 9/12


I Richard Emch - H550.pdf                                                                                                           Page Paqe 10 101111 I Richard. Emch H550.pdf MATERIAL SAFETY DATA SHEET N"NALCO                                              PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
I Richard Emch - H550.pdf Page 10 11 I Richard. Emch - H550.pdf Paqe 1011 N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours)   CHEMTREC FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):
(800) 424-9300 (24 Hours)
CHEMTREC FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):
EPA Reg. No. 464-704-1706 In all cases follow instructio ns on the product label.
EPA Reg. No. 464-704-1706 In all cases follow instructio ns on the product label.
This product has been certified as KOSHER/PAREVE             for year-rou nd use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL FEDERAL WATER POLLUTION CONTROLACT, CLEAN WATER ACT, 40 CFR 401.15 /formerly Sec. 307, 40 CFR 116.4 / formerly Sec. 311 :
This product has been certified as KOSHER/PAREVE for year-rou nd use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL FEDERAL WATER POLLUTION CONTROLACT, CLEAN WATER ACT, 40 CFR 401.15 /formerly Sec. 307, 40 CFR 116.4 / formerly Sec. 311 :
None of the substances are specifically listed in the regulation.
None of the substances are specifically listed in the regulation.
CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :
CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :
This product contains the following substances listed in the regulation:
This product contains the following substances listed in the regulation:
ISubstance(s)                                   ICitations
ISubstance(s)
* Methanol                                     Sec. 111, Sec. 112 CALIFORNIA PROPOSITION 65:
ICitations Methanol Sec. 111, Sec. 112 CALIFORNIA PROPOSITION 65:
This product does not contain substances which require warning under California Proposition 65.
This product does not contain substances which require warning under California Proposition 65.
MICHIGAN CRITICAL MATERIALS :
MICHIGAN CRITICAL MATERIALS :
Line 429: Line 670:
STATE RIGHT TO KNOW LAWS:
STATE RIGHT TO KNOW LAWS:
This product is a registered biocide and is exempt from State Right to Know Labelling Laws.
This product is a registered biocide and is exempt from State Right to Know Labelling Laws.
Methanol                                         67-56-1 Glutaraldehyde                                   111-30-8 NATIONAL REGULATIONS, CANADA:
Methanol 67-56-1 Glutaraldehyde 111-30-8 NATIONAL REGULATIONS, CANADA:
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
Line 437: Line 678:
The substances in this preparation are listed on the Domestic Substances Ust (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.
The substances in this preparation are listed on the Domestic Substances Ust (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.
INTERNATIONAL CHEMICAL CONTROL LAWS Nalco Company 1601 W. Diehl Road
INTERNATIONAL CHEMICAL CONTROL LAWS Nalco Company 1601 W. Diehl Road
* Naperville .Illinois 60563-1198 - (630)305-1000 For addtional copies of an MSDS visit www.nalco.com and request access 10/12
* Naperville.Illinois 60563-1198 - (630)305-1000 For addtional copies of an MSDS visit www.nalco.com and request access 10/12


I Richard Ench - H550.pdf                                                                                                             Mape11 lRichar~Emch H550.pdf Paqe ii] 1 MATERIAL SAFETY DATA SHEET PRODUCT 4NALCO                                        H-550 EMERGENCY TELEPHONE NUMBER(S)
I Richard Ench - H550.pdf Mape11 1 lRichar~Emch - H550.pdf Paqe ii]
(800) 424-9300 (24 Hours) CHEMTREC AUSTRAIJA All substances In this product comply with the Nation al Industrial Chemicals Notification & Assessment Scheme (NICNAS).
4NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours)
CHEMTREC AUSTRAIJA All substances In this product comply with the Nation al Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing Chemical Substances China (IECSC).
CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing Chemical Substances China (IECSC).
EUROPE The substances In this preparation have been reviewed for compliance with the EINECS or ELINCS Inventories.
EUROPE The substances In this preparation have been reviewed for compliance with the EINECS or ELINCS Inventories.
Line 447: Line 690:
NEW ZEALAND This product complies with Parts Xl - XV of the HSNO Act (1996).
NEW ZEALAND This product complies with Parts Xl - XV of the HSNO Act (1996).
THE PHIUPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS).
THE PHIUPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS).
116.       1 OTHER INFORMATION This product material safety data sheet provides health and safety Information. The product is to be used in applications consistent with our product literature. Individuals handing this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handing practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further Information.
116.
1 OTHER INFORMATION This product material safety data sheet provides health and safety Information. The product is to be used in applications consistent with our product literature.
Individuals handing this product should be informed of the recommended safety precautions and should have access to this information.
For any other uses, exposures should be evaluated so that appropriate handing practices and training programs can be established to insure safe workplace operations.
Please consult your local sales representative for any further Information.
REFERENCES Threshold Umit Values for Chemical Substances and Physical Agents and Biological Exposure Indces, American Conference of Governmental Industrial Hygienists, OH., (Adel Insight# CD-ROM Version), Adel Research Corp.,
REFERENCES Threshold Umit Values for Chemical Substances and Physical Agents and Biological Exposure Indces, American Conference of Governmental Industrial Hygienists, OH., (Adel Insight# CD-ROM Version), Adel Research Corp.,
Bethesda, MD.
Bethesda, MD.
Line 454: Line 701:
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Nalco Company 1601 W. Diehl Road
Nalco Company 1601 W. Diehl Road
* Naperville , Illinois 60563-1198 - (630)305-1000 For addtional copies of an MSDS visit www.nalco.com and request access 11/12
* Naperville, Illinois 60563-1198 - (630)305-1000 For addtional copies of an MSDS visit www.nalco.com and request access 11/12


[ Richar-j Em-ch - H550.pdf                                                                                                                 Page Page 12!1 i2~I
[ Richar-j Em-ch - H550.pdf Page 12!1
[Richakl Emch H550.pdf MATERIAL SAFETY DATA SHEET N"NALCO                                          PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
[Richakl Emch - H550.pdf Page i2~I N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Annual Report on Carcinogens, National Toxicology Progr am, U.S. Department of Health and Human Services, Public Health Service.
(800) 424-9300 (24 Hours)
CHEMTREC Annual Report on Carcinogens, National Toxicology Progr am, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Adel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Adel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Line 465: Line 713:
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Micromedex, Inc., Englewood, CO.
Prepared By: Product Safety Department Date issued: 04/21/2006 Version Number : 1.10 Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For adcitional copies of an MSDS visit www.nalco.com and request access 12/12}}
Prepared By: Product Safety Department Date issued: 04/21/2006 Version Number : 1.10 Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198  
* (630)305-1000 For adcitional copies of an MSDS visit www.nalco.com and request access 12/12}}

Latest revision as of 05:53, 15 January 2025

Email: (PA) Air Emissions Inventory Report for 2005 and MSDS for Nalco H-550
ML062850148
Person / Time
Site: Vermont Yankee File:NorthStar Vermont Yankee icon.png
Issue date: 09/18/2006
From: Dewald L
Entergy Nuclear Vermont Yankee
To: Emch R
NRC/NRR/ADRO/DLR
References
%dam200611, TAC MD2297
Download: ML062850148 (28)


Text

RichaW Emch - air emissions inventory report for 2005 and MSbS for Nalco H-550 Page 11 I Richa~dErnch - air emissions inventory report for 2005 and MSDS for Nalco H-550 Paqe 1 From:

"DeWald, Lynn" <ldewald@entergy.com>

To:

"Richard Emch" <RLE@NRC.GOV>

Date:

Mon, Sep 18, 2006 12:58 PM

Subject:

air emissions inventory report for 2005 and MSDS for Nalco H-550 Rich, I don't seem to have kept Sam's email address and although I think it is SHQ@nrc.com, I wasn't positive and didn't want someone to get this who wasn't expecting it. Can you please forward to Sam?

As discussed, we no longer use Nalco H-550 but even when we did, any product that was not consumed in the service water system had to be maintained below 2.0 ppm as a discharge to the CT River and as such was well below Vermont's action level for gluteraldehyde in cooling tower drift.

Lynn Lynn DeWald Entergy Nuclear Vermont Yankee, LLC 320 Governor Hunt Road Vernon, VT 05354 802-258-5526 (phone) 802-258-5865 (fax) 802-380-4493 (cell)

I c emn\\GW)00001.TMP Pag elIil c:\\ternn\\GWIOOOOl.TMP Pacie 1 ii Mail Envelope Properties (450ED012.1ED :20: 29165)

Subject:

Creation Date From:

Created By:

air emissions inventory report for 2005 and MSDS for Nalco H-550 Mon, Sep 18, 2006 12:56 PM "DeWald, Lynn" <Idewald@entergy.com>

ldewald@entergy.com Recipients nrc.gov OWGWPO02.HQGWDOO1 RLE (Richard Emch)

Post Office OWGWPOO2.HQGWDOO1 Route nrc.gov Files Size Date & Time MESSAGE 675 Monday, September 18, 2006 12:56 PM TEXT.htm 5044 Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf 556268 H550.pdf 65385 Mime.822 1

Options Expiration Date:

Priority:

ReplyRequested:

Return Notification:

Concealed

Subject:

Security:

None Standard No None No Standard Junk Mail Handling Evaluation Results Message is eligible for Junk Mail handling This message was not classified as Junk Mail Junk Mail settings when this message was delivered Junk Mail handling disabled by User Junk Mail handling disabled by Administrator Junk List is not enabled Junk Mail using personal address books is not enabled Block List is not enabled

mch - Final 2005.emissions inve-'nt-ory_ýepgrttoýEqýýgyYX.1_.ýý.2qpp.pdf

_ ýageý_ý,J Richaki Emch - Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf Pag~i~~

Entergy Nuclear Northeast Entergy Nuclear Operations, Inc.

Vermont Yankee 322 Governor Hunt Rd.

Vernon. VT 05354 Tel 802.257-7711 26 Janiiary 2006 Mr. Daniel Riley, Environmental Engineer Vermont Agency of Natural Resources Department of Environmental Conservation Air Pollution Control Division Building 3 South 103 South Main Street Waterbury, VT 05671-0402

Subject:

2005 Air Pollutant Emissions Inventory Report for Entergy Nuclear Vermont Yankee, LLC. Facility ID WM 2335.

Dear Mr. Riley:

Enclosed is Entergy Nuclear Vermont Yankee's air emissions inventory report for 2005.

Total air emissions from significant activities, which includes the house heating boilers and the waste oil burners, was 9.07 tons for the year. Vermont Yankee does not include emissions from the emergency diesel generators (A and B), the John Deere diesel, or the emergency diesel fire pump toward the total tonnage in this inventory report as these emergency generators, each of which operate less than one hundred hours per year, are considered insignificant activities under the State regulations.

The cooling tower particulate emissions calculations for the mechanical draft cooling towers are based on the drift and drift rate, and as in 2004, remain conservatively high.

The cooling towers operated for 2,149 hours0.00172 days <br />0.0414 hours <br />2.463624e-4 weeks <br />5.66945e-5 months <br /> during 2005. The operating hours were utilized in calculating the 2005 PM emissions.

PM Emissions (TPY) = Drift gpm x 8.33 lbs/gal x TDS x 60 min/hr x hrs/yr of operation x 1 ton/2000 lbs 72.0 gpm x 8.33 lbs/gal x (62 lbs/1000000-lbs) x 60 min/hr x 2149 x I ton/2000 lbs The calculations for the 2005 emission data for cooling tower hazardous air contaminants (HAC) consider the miscibility of the product constituent and the water circulated through the cooling towers versus percentage of water loss through evaporation when the towers are running.

The circulating water flow through the cooling towers is approximately 360,000 gallons per minute (gpm), and based on the Final Environmental Statement Related to the Operation of Vermont Yankee Nuclear Power Corporation 4

mch - Final 2005 emissions inventory report Lorýýnýergy=VY 1 26 2006-pdf i

-Page 2 I RichaM Ernch - Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf Page2~

I published by the Nuclear Regulatory Commission, 5,000 gpm is lost through cooling tower evaporation. The HAC emissions from the cooling towers are insignificant and do not exceed any action levels outlined in Appendix C of the Vermont Air Pollution Control Regulations.

Cooling Towers Pollutant Tons lbs/8 hours Action level (bs/8hrs)

Particulate Matter 2.4 Dodecylguanidine Hydrochloride 0.001 0.002 0.025 Ethyl Alcohol 0.0004 0.001 2,330 Glutaraldehyde 0.008 0.015 340 Isopropyl Alcohol 0.0005 0.001 63 Total 2.41 This submittal'does not include additional hazardous air contaminant (HAC) emissions inventory, as those would be associated with routine maintenance activities, such as painting and cleaning, and are therefore not subject to any State reporting requirements.

Please do not hesitate to call if you have questions or concerns with the enclosed information.

Sincerely, Entergy Nuclear Vermont Yankee, LLC Lynn DeWald Environmental Specialist 802-258-5526 Samuel A. Wender IV Chemistry Superintendent 802-258-5650 2

Supporting Calculations A. SPECTRUS NX-1104 Tsopropyl Alcohol (400 gals/yr) x (8.24 lbs/gal) x (2.4%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm) 0.0005 tons/yr Ethyl Alcohol (400 gals/yr) x (8.24 lbs/gal) x (1.8%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm)= 0.0004 tons/yr Dodecvlauanidine Hydrochloride (400 gals/yr) x (8.24 lbs/gal) x (5%) x (I ton/2,000 Ibs) x (5,000 gpm/360,000 gpm) = 0.001 tons/yr B. NALCO H-550 Glutaraldehyde (50% Solution)

(250 gals/yr) x (9.4 lbs/gal) x (50%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm) = 0.008 tons/yr M.)

,~3 0

CD 3

(n O/)

=3 CD 0

M9 CD t,0 CD 0) 3 K

.y.':...

.4J;A.....CaN y..........

--.- ~

Al Rir6"hW Emch-Final 2005 ermnissions inventory report for EntergyVYl 26_2006-Pdfý

-~

yt~'t)I CERTIFICATION OF DATA ACCURACY For Purposes of Emission Calculations This form Inust be signed by an individual responsible for the completion and certification of the data contained in the forms attached which are intended to meet both the requirements of State Statute {10 V.S.A. 555 (c) and 3 V.S.A. 2822 (j)(1)(B)) and the requirements for"Ermission Statements" contained in the Federal Clean Air Act as amended in 1990. Certification indicates that the signatory takes legal responsibility for the accuracy of the information on the form.

The data presented herein represents the best available information and is true, accurate, and complete to the best of my knowledge.

Print Full Name Sigture" Print Full Title Date of Signature SPl) 5phneNk e

Telephone Number Received JAN 4 2006

Richaed Emch - Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf Page"5Il Vermont Agency of Natural Resources 2005 Air Pollutant Emissions Inventory Combustion Source For Criteria Pollutants The Information displayed on this form is that which Is currently on file for your.

facility. It is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please revievw the Information contained in the boxes. If there is no value In a box, write in the correct 2005 value. If there Is a value, but it Is incorrect for 2005, cross out the value and in its place write the correct value.

If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.

Facility Name:

ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form ir "I

be...b I ci Facility ID WM2335 Source

Description:

house heating boilers (2)

Stack Number:

Source Number:

I Segment Number:

5 Source Classification Code:

1-03-005-01 Operational Data:

Hours Per Day:

Days Per Week:

Weeks Per Year:

Hours Per Year:

~fl LIZiI LZ~I1 5;

Winter Throughput (%) : [i 40 Spring Throughput (%): [I 30 Summer Throughput (%): :I 0

Autumn Throughput (%) :l 30 (Over)*

'Riclail E.nch - Final 2005 emissions inventorreport for EntergyVY1 262006.pdf Page 61l Combustion Source (continued)

Fuel Type:

FUEL OIL (#2) 2005 Fuel Consumption: (supply units):

4 Av. Sulfur Content of Fuel (%):

J Ash Content of Fuel (%):

(Please supply a current estimate of mid-range sulfur contenO Maximum Heat Input (million BTU/hr):

Burner Rating:

Boiler Rating:

L Maximum Actual Firing Rate (million BTU/hr):

Percent Space Heat:

I00

[.

Percent Process Heat: j 0j Stack Parameters:

Stack Number:

Stack/Duct Discharge Height (feet) 87.9 Stack/Duct Inner Diameter at Exit (inches) :

I 27.6Z Exit Gas Temperature (deg.F:

F 151i 1

Flow Rate at Exit (actual FT3/min) :119,915 If an air pollution control, device for the source exists Inspect the following information and correct if necessary:

TSP Control Device:

none Theoretical Efficiency:

S02 Control Device:

none Theoretical Efficiency:

NOx Control Device: none Theoretical Efficiency:

VOC Control Devicei none Theoretical Efficiency:[

CO Control Device: I none Theoretical Efficiency:. I 0

If an estimated emission rate exists, please supply the information below:

Estimated Emission Rite* :

Basis of Estimate:

  • If test data 4 years old or less is available.

-.U

I Riclha

,mch-Final 2005 e mi ssions inyentorreport.for Entergy vY1 262006,pdf

-~

Page 711 Vermont Agency of Natural Resources 2005 Air Pollutant Emissions Inventory Combustion Source For Criteria Pollutants The Information displayed on this form is that which is currently on file for your facility. It Is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review the Information contained In the boxei. If there is no value In a box, write In the correct 2005 value. If there is a value, but It is Incorrect for 2005, cross out the value and In its place write the correct value.

If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.

Facility Name:

ENTERGY NUCLEAR VERMONT YANKEE l

Person Completing Inventory Form [ LL-"r"v% VYe We uI, (Jt I

Facility ID WM2335 Source

Description:

vipte oil furnace (2)

Stack Number:

Source Number:

Segment Number:

2 2

I Source Classification Code:

1-02-004-01 Operational Data:

Hours Per Day:

Days Per Week:

Weeks Per Year:

Hours Per Year:

1-7 CV 077 Winter Throughput (%)

5 Spring Throughput (%):

0 Summer Throughput (%):

Autumn Throughput (%) :LI3

[

(Over)

  • Einch - Final 2005 emiss-vans inKefyýý! ýepqýýtq!ýýqýýrgyVY 1 26 2006.p(

Page 8.

RichaiU Emch - Final 2005 ernis~lons inventory report for Entergy VY 1 26 2006.pdf Pa ge8~

Combustion Source (continued)

Fuel*Type:

FUEL OIL (#6)

I 2005 Fuel Consumption: (supply units):

g, 55

  • ty.1 (o'i5 Av. Sulfpr Content of Fuel (%):

1

/

Ash Content of Fuel (%)

1 (Please supply a current estimate of mid-range sulfur content)

Maximum Heat Input (million BTUlhr):

Surner Rating:

j3 JBoiler Rating:

Maximum Actual Firing Rate (million BTU/hr):

Percent Space Heat:

W Percent Process Heat:

Stack Parameters:

Stack Number:

2 Stack/Duct Discharge Height (feet) :

21.0 Stack/Duct Inner Diameter at Exit (inches) :7.9 Exit Gas Temperature (deg.F:

250 Flow Rate at Exit (actual FT3Imin) :

[

1,992 If an air pollution control device for the source exists inspect the following information and correct if necessary:

TSP Control Device: I none Theoretical Efficiency:

S02 Control Device: [none

.Theoretical Efficiency:

NOx Control Device: none

..]Theoretical Efficiency:

VOC Control Device none Theoretical Efficiency:

j CO Control Device: I none Theoretical Efficiency:

If an estimated emission rate exists, please supply the information below:

Estimated Emission Rite* :

Basis of Estimate

  • If test data 4 years old or less is available.

Richardl Emch - Final 2005 emissions inventory report for Entergy VYi 262006.pdf Page 9 11 Vermont Agency of Natural Resources Process Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The Information displayed on this form is that which is currently on file for your facility. It is based on inventory forms completed for calendar year 2004 or the most recent year available. The Information must be updated to calendar year 2005. Please review the Information contained in the boxes. If there is no value in a box, write in the correct 2005 value. If there is a value, but It Is Incorrect for 2005, cross out the value and In its place write the correct value.

If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.

Facility Name:

ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form: I LT)--

I f,,I I

Facility ID:

WM2335 Source

Description:

Particulate Emissions from Cooling Tower Stack Number:

Source Number:

5 5

Segment Number:

I Source Classification Code:

3-85-001-01 Operational Data:

HoursPerDayi:

DaysPerWeek: Ill]

WeeksPerYear: 1113]

HoursPerYear: :2,,tf Winter Throughput (%):

Spring Throughput (%)

ma Summer Throughput (%):

'656" aKf -F D

Autumn Throughput (%): [

)*o4X,-

ioS-W (OCP t (Z.b (Over) p

Richard Emch - Final 2005 emissions inventory repoqrfor Entergy VY 1_26 2006.pdf Pag Page 1.9j Process Source (continued)

Raw Materials Input*:

Type Quantity Product Materials Output*:

Type Quantity

  • Information in this section only necessary If accurate figures for stack flow rate and hours of operation cannot be supplied.
  • Stack Parameters:

Stack Number:

5 Stack/Duct Discharge Height (Feet) :II o~o 1 StackfDuct Inner Diameter at Exit (Inches):

Exit Gas Temperature (Deg F):

[

0Z Flow Rate at Exit (Actual FT3/Min),

I0I If there is an air pollution control device on this source inspect the following information and correct if necessary:

PM Control Device:

none Theoretical Efficiency (%): [I 0I [

If available, supply theoretical efficiencies for:

PMIO Efficiency (%): III j

PM2.5 Efficiency ()

(NOTE: This Information will not affect the Air Registration Fee Estimate).

If an estimated emission rate exists for PM, supply the information below Estimated Emission Rate*

[

Basis of Estimate:

  • .If test data 4 years old or less Is available.

kchard Emc6h-Final 2005 6msp n!ýqetory reportforEnterýgyKV 12 206pdf Page 11 i Vermont Agency of Natural Resources 2005 Air Pollutant Emissions Inventory Combustion Source*

For Criteria Pollutants The Information displayed on this form Is that which Is currently on file for your' facility. It Is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review; the information contained in the boxes. If there Is no value in a box, write In the correct 2005 value. If there Is a value, but it is incorrect for 2005, cross out the value and in Its place write the correct value.

If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.

Facility Name:

ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form I

bew,~c Ij-I Facility ID

  • WM2335 Source

Description:

Emergency Diesels (2). 1675 hp Stack Number:

Source Number:

3 3

Seement Number:*

Source Classification Code:

2-02-004-01 Operational Data:

Hours Per Day:

0 Days Per Week: '

0]

Weeks Per Year:

Hours Per Year:

': 9 L.j7, kr-.

Winter Throughput (%): [

25 f Spring Throughput(/): Ii 25i.

Summer Throughput (%):

]

Autumn Throughput (%). :LiI 5

(Over)

m J

A tl

ýYiqhýrý(Eýýnch - Final 2005 emissioýý.inyeýntW_ýeporýtýý,ýýqrgyyý 1_?6_?QOý.pýf Jýage _y4_q Richard Emch - Final 2005 emissions inventory report for Entergy VY 1 262006.pdf

-~

Page 12t1 Combustion Source (continued)

FuelType:

FUEL OIL (#2) 2005 Fuel Consumption: (supply units):

Av. Sulfur Content of Fuel (%):

Ash Content of Fuel (%):

(Please supply a current estimate of mid-range sulfur conteno Maximum Heat Input (million BTUlhr):

Burner Rating:

Boiler Rating:

Maximum Actual Firing Rate (million BTU/hr):

[

Percent Space Heat:

"0 Percent Process Heat:

Stack Parameters:

Stack Number:

3

  • Stack/Duct Discharge Height (feet) j 29.8j j Stack/Duct Inner Diameter at Exit (inches).:

27X Exit Gas Temperature (deg. F)

  • 180 Flow Rate at Exit (actual FIn/min) 63,983 If an air pollution control device for the source exists inspect the following information and correct if necessary:

TSP Control Device: I none I Theoretical Efficiency:

0-1 S02 Control Device: I none NOx ConirolDevIce:I none VOC Control Devicef none Theoretical Efficiency:

  • ] -Theoretical Efficiency:

' Theoretical Efficiency:

L I E I

CO Control Device:

none I Theoreticsl Efficiency:

If an estimated emission rate exists, please supply the information below:

Estimated Emission Rate* :"

Basis of Estimate:

I If test data 4 years old or less Is available.

1 I 1ýichaýo Emch - Final 2005 emissions inveqtory_ýepoýjqý_ýqýgy \\T_ýý22ýqq.pqf

- ýagq 1 q,11

........ a. d...... -Fna 00..

i.n.r.rp rtfo.ntry.Y 1.6.0 6.d P g 11 Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The information displayed on this form is that which is currently on file for your facility. It Is based on inventory forms completed for calendar year 2004 or the most recent year available."The Information must be updated to calendar year 2005. Please revlevs the information contained In the boxes. If there is no value In a box, write In the correct 2005 value. If there Is a value, but It is incorrect for 2005, cross out the value and in its place write the correct value.

If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.

Facility Name:

ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form a.

..I Facility ID WM2335 Source

Description:

235 hp John Deere Diesel Stack Number:

Source Number:

Seement Number:

4 4.

I1 Source Classification Code: 2-01-001-02 Operational Data:

Hours Per Day:

Days Per Week:

Weeks Per Year:

Hours Per Year:

'Winter Throughput (%):

  • SpringThroughput/(%):

I 25 Summer Throughput (%)2: Z 5Z Autumn Throughput (%) :[

2j (Over)

Richard Emch -Final 2005 emissions inv"ryfýpgqlpý,ýqergyYY.ýý"OQP-Pqý,

Richard. Emc

- Fina 200 emsson.ivetoy.eprt.o.Ete..

2.....d Pge1 Combustion Source (continued)

Fuel Type:

FUEL OIL (#2) 2005 Fuel Consumption : (supply units): jj" :fj'l Av. Sulfur Content of Fuel (%):

Ash Content of Fuel (%):

0.00' (Please supply a current estimate of mid-range sulfur content)

Maximum Heat Input (million BTU/hr):

Burner Rating:

j Boller Rating:

[Z Maximum Actual Firing Rate (million BTU/hr):

LI0 Percent Space Heat:

ir 0i*

Percent Process Heat:

0o Stack Parameters:

Stack Number:

4 Stack/Duct Discharge Height (feet)

Stack/Duct Inner Diameter at Exit (inches)

Exit Gas Temperature (deg. F)

Flow Rate at Exit (actual FT3/min) 12.5~

3.9iI 180~

'4,30 If an air pollution control device for the source exists inspect the following information and correct if necessary:

TSP Control Device:

none TTheoretical Efficiency:

S02 Control Device: I none" Theoretical Efficiency:

NO Control Device:Inon VOC Control De vicei on Theoretical Efficiency:

] The;retical Efficiency:

CO Control Device: F none Theoretical Efficiency:

If an estimated emission rate exists, please supply the information below:

Estimated Emission Rate* T 0

EZ~

0 1*

Basis of Estimate :

I* f test data 4 years old or less is available.

I.

.A

I Richard Emch -_H550.pdf___

Page 1 1i Richard Emch - H550.pdf Page 1 ii N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC

11.

CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME:

H-550 APPLICATION :

MICROBIOCIDE COMPANY IDENTIFICATION:

Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S):

(800) 424-9300 (24 Hours)

CHEMTREC NFPA 704MWHMIS RATING HEALTH :

3/3 FLAMMABILITY :

1/1 INSTABILITY :

0/0 OTHER:

0 = Insignificant 1 = Slight " 2 = Moderate 3=High 4=Extreme r2.

I COMPOSITION/INFO RMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).

Hazardous Substance(s)

CAS NO 111-30-8 Glutaraldehyde

% (w/w) 30.0- 60.0

13.

1HAZARDS IDENTIFICATION

-EMERGENCY OVERVIEW DANGER Corrosive. Causes irreversible eye damage. Causes skin bums. Harmful if inhaled.

May be fatal if swallowed.

Harmf ul if absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

Causes asthmatic signs and symptoms in hyper-reactiv e individuals.

Do not get in eyes, on skin, on clothing.

Avoid breathing vapor. Do not swallow. Wear goggles, protective clothing, and rubber gloves. Wash thoroughly with soap and water after handing. Remove contaminated clothing and wash before reuse.

Not flammable or combustible.

May evolve oxides of carbon (COx) under fire concitions.

PRIMARY ROUTES OF EXPOSURE:

Eye, Skin, Inhalation HUMAN HEALTH HAZARDS -ACUTE:

EYE CONTACT:

Corrosive.

Will cause eye bums and permanent tissue damage.

Nalco Company 1601 W. Diehl Road

  • Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access S1/12

I Richiird Eriich - H550.pdf Page 2 11 I Richard Emch - H550.pdf Paqe 211 N"NALCO MATERIAL SAFETY DATA SHEET

-PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC SMUN CONTACT:

May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered.

Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.

INGESTION:

Not a likely route of exposure.

Corrosive; causes chemical burns to the mouth, throat and stomach.

INHALATION:

Irritating, in high concentrations, to the eyes, nose, throat and lungs.

Inhalati on of product mist or vapors may cause respiratory allergy.

SYMPTOMS OF EXPOSURE Acute A review of available data does not identify any symptoms from exposure not previously mentioned.

Chronic :

A review of available data does not identify any symptoms from exposure not previously mentioned.

AGGRAVATION OF EXISTING CONDITIONS:

A review of available data does not identify any worsening of existing conditions.

HUMAN HEALTH HAZARDS -CHRONIC:

Prolonged inhalation of product can increase lung injury in persons with emphysema, asthma, or other lung disorders.

14.

FIRST AID MEASURES EYE CONTACT :

Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open.

SKIN CONTACT:

Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes.

For a large splash flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.

INGESTION:

Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink.

INHALATION Remove to fresh air, treat symptomatically.

If symptoms develop, seek medical advice.

IF IN EYES:

Immediately flush with plenty of water for at least 15 minutes.

Get immediate medical attention.

IF ON SKIN: Immediately wash with plenty of soap and water. Get medical attention.

IF INHALED: Remove to fresh air. If breathing is difficult, administer oxygen. If symptoms persist, call a physician.

IF SWALLOWED:

DO NOT INDUCE VOMITING. Do not give anything to drink. Seek medical advice with urgency.

Nalco Company 1601 W. Diehl Road

  • Naperville,Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/12

I Richard Enich - H550.pdf Page 3 11 I Richard Emch - H550.pdf Pacie 3t1 AWNALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC NOTE TO PHYSICIAN :

Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical concition.

15.

1FIRE FIGHTING MEASURES FLASH POINT:

None EXTINGUISHING MEDIA:

This product would not be expected to bum unless all the water is boiled away. The remaining organics may be Ignitable. Use extinguishing media appropriate for surroundng fire.

FIRE AND EXPLOSION HAZARD :

Not flammable or combustible.

May evolve oxides of carbon (COx) under fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:

In case of fire, wear a full face positive-pressur e self contained breathing apparatus and protective suit.

16.

1 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:

Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material.

Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended In Section 8 (Exposure Controls/Persona I Protection).

Notify appropriate government, occupational health and safety and environmental authorities.

METHODS FOR CLEANING UP:

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container.

Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Dilute the glutaraldehyde to 5% or less with water. Add sodium bisulfite (2-3 parts by weight per part glutaraldehyde). This will typically reduce the glutaraldehyde concentration to 2 ppm or less in 5 minutes at room temperature. The remaining solution can be disposed of via appropriate means. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).

ENVIRONMENTAL PRECAUTIONS:

This pesticide is toxic to fish. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified In writing prior to discharge.

Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/12

[ F:Vichaýd Em9h - H550.pdf Paige 4,11

[Richard. Emch - H550.pdf Page 41 NNALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC

17.

I HANDLING AND STORAGE HANDUNG :

Do not get in eyes, on skin, on clothing.

Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containe rs closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.

STORAGE CONDITIONS:

Store the containers tightly closed. Store separately from oxidizers. Store in suitable labelled containers.

SUITABLE CONSTRUCTION MATERIAL:

Compatibility with Plastic Materials can vary; we therefore* recommend that compatibility is tested prior to use.

18.

1 EXPOSURE CONTROLS/PERSONA L PROTECTION OCCUPATIONAL EXPOSURE UMITS:

Exposure gidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.

ACGIH/TLV:

Substance(s)

Glutaraldehyd e OSHNPEL :

Substance(s)

Glutaraldehyde CEIUNG: 0.05 ppm, 0.2 mg/m3 0.05 ppm, 0.2 mg/m3 CEIUNG: 0.2 ppm, 0.8 mg'm3 ENGINEERING MEASURES :

General ventilation is recommended.

Use local exhaust ventilation if necessary to control airbome mist and vapor.

RESPIRATORY PROTECTION:

If significant mists, vapors or aeros ols are generated an approved respirator is recommended.

A dust, mist, fume cartridge may be used. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection Is required, institute a compiete respiratory protection program including selection, fit testing, training, maintenance and inspection.

HAND PROTECTION:

BUTYL GLOVES, NEOPRENE GLOVES, Viton# gloves SKIN PROTECTION :

Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is recommended if gross exposure is possible.

EYE PROTECTION:

Wear a face shield with chemical splash goggles..

Nalco Company 1601 W. Diehl Road

  • Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/12

I Fýichw--d-E' IT ch --I-155b-Pdf Page 5 ;

I Richard Ernch - H550.pdf Page 5;I AWNALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC HYGIENE RECOMMENDATIONS :

Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.

19.

1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Uquid APPEARANCE Colorless ODOR Aldehyde SPECIFIC GRAVITY 1.11 -1.13

@ 77°F/25°C DENSITY 9.4 Ib/gal SOLUBIUTY IN WATER Complete pH (100 %)

3.1 -4.5 VISCOSITY 21 cps @ 68 01F/20 0 C FREEZING POINT

-5.8 °F/-21 °C BOIUNG POINT 213 F/ 100.5 °C VAPOR PRESSURE 16 mm Hg VAPOR DENSITY 1.1 VOC CONTENT 54 % EPA Method 24 Note: These physical properties are typical values for this product and are subject to change.

10.

1 STABILITY AND REACTIVITY STABIUTY :

Stable under normal conditions.

HAZARDOUS POLYMERIZATION:

Hazardous polymerization will not occur.

CONDITIONS TO AVOID:

Freezing temperatures.

MATERIALS TO AVOID:

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.

HAZARDOUS DECOMPOSITION PRODUCTS:

Under fire conditions:

Oxides of carbon

11.

1 TOXICOLOGICAL INFORMATION The following results are for the product.

Nalco Company 1601 W. Diehl Road

  • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/12

I I Richitrd Emch - H550.pdf Page 6 11 I Richard Emch - H550.pdf Paqe 611 I AWNALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC ACUTE ORAL TOXICITY:

Species LD50 Rat 1,300 mg/kg Rat 1.2 mVkg Rat 1.54-1.87 mt/kg Rat 1.07 - 1.62 mVkg Rating : Harmful ACUTE DERMAL TOXICITY:

Species LD50 Rabbit 897 mg/kg Rabbit 2.00 - 2.71 ml/kg Rabbit 8.0- 12.8 mVkg Rating : Harmful ACUTE INHALATION TOXICITY:

Species LC5O Rat 0.48 mg/I 0 Rating : Very Toxic Test Descriptor Product Glutaraldehyde 45% Active Ingredient 25% Active Ingredient 10% Active Ingredient Test Descriptor Product Glutaraldehyde 45% Active Ingredient 25% Active Ingredient Test Descriptor Product PRIMARY SKJN IRRITATION: At 10% or greater, glutaraldehyde solutions may cause moderate to severe irritation, with possible necrosis after prolonged contact.

PRIMARY EYE IRRITATION : At levels of 0.2% and below of glutaraldehyd e, no eye irritation was noted. Levels above 0.2% of glutaraldehyd e produced moderate to severe irritation and comeal irjury.

SENSITIZATION :

Levels of greater than 0.2% of glutaraldehyd e produced allergic contact dermatitis in human studies. May cause sensitization by Inhalation and skin contact.

CARCINOGENICITY :

None of the substances in this prod uct are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).

HUMAN HAZARD CHARACTERIZATION Based on our hazard characterization, the potential human hazard Is: High 112.

1 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS :

The following results are for the product along with results on the active substances.

ACUTE FISH RESULTS :

I Species I Exposure LC50 I Test Descriptor I Bluegil Sunfish I 96 hrs I 22.4 mg/I I Product IFathead Minnow 96 hrs 10.8 man rouc Sheepshead Minnow 96 hrs 64 mg/I Product Nalco Company 1601 W. Diehl Road

  • Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/12

I Richard Emch - H550.pdf PPag~e 7 !

N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC Rainbow Trout 196 hrs (24 mg/I Product ACUTE INVERTEBRATE RESULTS :

Species

[ Exposure I LC50 EC50 Test Descriptor Daphnia mana 48 hrs 11.5 m__I Product Shore Crab 96 hrs 930 m_/I Product Grass Shrimp 96 hrs 82 mg/I Product Mysid Shrimp (Mysidopjis 96 hrs 14.2 mg/I Product bahia)

American Oyster 96 hrs 1.56 mg/I Product Acartia tonsa 48 hrs 1 0.22 mg/I Product AQUATIC PLANT RESULTS :

Species Exposure EC50/LC50 Test Descriptor Marine Algae (Skeletonema 72 hrs 1.22 mg/I Product costatu-n)

Algae (Scenedesmus 72 hrs 1.7 mg/I Product subspicatus)

I AQUATIC MICROORGANISM RESULTS:

I Species rta I Exposure I EC50/LC50 ITest Descriptor Sewage Microornisms I96 hrs 134 mo Active Substance AVIAN RESULTS:

Species Exoue L5 Test Descriptor Bobwhite Quail 8 Days 10,000 ppr Active Substance Mallard Duck 1 8 Days 10,000 ppn I Active Substance Mallard Duck I

L933 mcftg 150% Active Ingredient MOBIULTY :

The environmental fate was estimated using a level IIIfugacity model embedded in the EPI (estimation program Interface) Suite TM, provided by the US EPA The model assumes a steady state conrdt ion between the total Input and output. The level III model does not require equilibrium between the defined media. The information provided Is Intended to give the user a general estimate of the environment al fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soiVsediment In the approximate respective percentages; Ar Water I

SoiVSediment

<5%

30-50%1o 50- 70%1o The portion in water is expected to be soluble or dispersible.

BIOACCUMULATION POTENTIAL This preparation or material Is not expected to bioaccumulate.

ENVIRONMENTAL HAZARD AND EXPOSURIE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Moderate Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/12

Richa-r-d- -E'm-"ch - H550. pdf Pa"e8 I Richard Ernch - H550.pdf Pa~je8~

N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC If released into the environment, see CERCLA/SUPERFUND in Section 15.

If released into the environment, see CERCAINSUPERFUND in Section 15.

113.

I DISPOSAL CONSIDERATIONS I

If this product becomes a waste, It Is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characted stics of Subpart C, nor is it listed under Subpart D.

As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handing, treatment or disposal requirements.

For disposal, contact a property licensed waste treatment, storage, disposal or recycling facility.

ACONTAINER DISPOSAL Metal Containers or Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or reconditionin g, or puncture and dispose of in a sanitary landfill, or other procedures approved by state and local authorities.

Plastic Containers:

May be incinerated, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. Metal Containers:

Must not be incinerated.

Do not cut or weld on or near metal containers.

114.

I TRANSPORT INFORMATION I

The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shippi ng Name / Hazard Class may vary by packaging, properties, and mode of transportatio n. Typical Proper Shipping Names for this product are as follows.

LAND TRANSPORT:

Proper Shipping Name:

Technical Name(s):

UN/ID No:

Hazard Class - Primary:

Packing Group:

Flash Point :

CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.

GLUTARALDEHYDE UN 3265 8

II None AIR TRANSPORT (ICAO/IATA) :

Proper Shipping Name:

Technical Name(s) :

UN/ID No:

Hazard Class - Primary:

Packing Group :

IATA Cargo Packing Instructions:

IATA Cargo Aircraft Umit:

MARINE TRANSPORT (IMDG/IMO):

Proper Shipping Name:

Technical Name(s):

UN/ID No:

CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.

GLUTARALDEHYDE UN 3265 8

II 812 30 L (Max net quantity per package)

CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.

GLUTARALDEHYDE UN 3265 Nalco Company 1601 W. Diehl Road

  • Naperville, Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8112

I RichýýEiiich - H550.p'df

-Page 9 I Richard Emch - H550.pdf Page 9 ~I P1NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC Hazard Class - Primary:

8 Packing Group :

II 115.

1 REGULATORY INFORMATION NATIONAL REGULATIONS, USA:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 Based on our hazard evaluation, the following substance(s) in this product Is/are hazardo us and the reason(s) Is/are shown below.

Glutaraldehyde : Corrosive, Sensitizer CERCLNSUPERFU ND, 40 CFR 117, 302:

This product contains the following Reportable Quantity (RO) Substance. Aso listed Is the RQ for the product.

RQ Substance RO Methanol 5,000 lbs SARANSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:

SECTION 302 - EXTREMELY HAZARD OUS SUBSTANCES (40 CFR 355):

This product does not contain substances listed in Appen dx A and B as an Extremely Hazardous Substance.

SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):

Our hazard evaluation has found this product to be hazardous. The product should be reported under the following Indcated EPA hazard categories:

X Immediate (Acute) Health Hazard X

Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.

The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.

SECTION 313 - UST OF TOXIC CHEMICALS (40 CFR 372) :

This product contains the following substance(s), (with CAS # and % range) which appear(s) on the Ust of Toxic Chemicals Hazardous Substance(s)

CAS NO

% fw/w)

Methanol 67-56-1 1.0 -5.0 TOXIC SUBSTANCES CONTROL ACT (TSCA):

This product Is exempted under TSCA and regulated unde r FIFRA The inerts are on the Inventory List.

Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For adclitional copies of an MSDS visit www.nalco.com and request access 9/12

I Richard Emch - H550.pdf Page 10 11 I Richard. Emch - H550.pdf Paqe 1011 N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):

EPA Reg. No. 464-704-1706 In all cases follow instructio ns on the product label.

This product has been certified as KOSHER/PAREVE for year-rou nd use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL FEDERAL WATER POLLUTION CONTROLACT, CLEAN WATER ACT, 40 CFR 401.15 /formerly Sec. 307, 40 CFR 116.4 / formerly Sec. 311 :

None of the substances are specifically listed in the regulation.

CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :

This product contains the following substances listed in the regulation:

ISubstance(s)

ICitations Methanol Sec. 111, Sec. 112 CALIFORNIA PROPOSITION 65:

This product does not contain substances which require warning under California Proposition 65.

MICHIGAN CRITICAL MATERIALS :

None of the substances are specifically listed in the regulation.

STATE RIGHT TO KNOW LAWS:

This product is a registered biocide and is exempt from State Right to Know Labelling Laws.

Methanol 67-56-1 Glutaraldehyde 111-30-8 NATIONAL REGULATIONS, CANADA:

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

WHMIS CLASSIFICATION :

Pesticide controlled products are not regulated under WHMIS.

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):

The substances in this preparation are listed on the Domestic Substances Ust (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.

INTERNATIONAL CHEMICAL CONTROL LAWS Nalco Company 1601 W. Diehl Road

  • Naperville.Illinois 60563-1198 - (630)305-1000 For addtional copies of an MSDS visit www.nalco.com and request access 10/12

I Richard Ench - H550.pdf Mape11 1 lRichar~Emch - H550.pdf Paqe ii]

4NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC AUSTRAIJA All substances In this product comply with the Nation al Industrial Chemicals Notification & Assessment Scheme (NICNAS).

CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing Chemical Substances China (IECSC).

EUROPE The substances In this preparation have been reviewed for compliance with the EINECS or ELINCS Inventories.

JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry Ust (MITI).

KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals Ust (ECL)

NEW ZEALAND This product complies with Parts Xl - XV of the HSNO Act (1996).

THE PHIUPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS).

116.

1 OTHER INFORMATION This product material safety data sheet provides health and safety Information. The product is to be used in applications consistent with our product literature.

Individuals handing this product should be informed of the recommended safety precautions and should have access to this information.

For any other uses, exposures should be evaluated so that appropriate handing practices and training programs can be established to insure safe workplace operations.

Please consult your local sales representative for any further Information.

REFERENCES Threshold Umit Values for Chemical Substances and Physical Agents and Biological Exposure Indces, American Conference of Governmental Industrial Hygienists, OH., (Adel Insight# CD-ROM Version), Adel Research Corp.,

Bethesda, MD.

Hazardous Substances Data Bank, National Ubrary of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Nalco Company 1601 W. Diehl Road

  • Naperville, Illinois 60563-1198 - (630)305-1000 For addtional copies of an MSDS visit www.nalco.com and request access 11/12

[ Richar-j Em-ch - H550.pdf Page 12!1

[Richakl Emch - H550.pdf Page i2~I N"NALCO MATERIAL SAFETY DATA SHEET PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)

(800) 424-9300 (24 Hours)

CHEMTREC Annual Report on Carcinogens, National Toxicology Progr am, U.S. Department of Health and Human Services, Public Health Service.

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Adel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.

Adel Insight# (An Integrated guide to industrial chemicals covered under major regulatory and advisory programs),

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Adel Insight# CD-ROM Version), Adel Research Corp., Bethesda, MD.

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),

Micromedex, Inc., Englewood, CO.

Prepared By: Product Safety Department Date issued: 04/21/2006 Version Number : 1.10 Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198

  • (630)305-1000 For adcitional copies of an MSDS visit www.nalco.com and request access 12/12