ML062850148
| ML062850148 | |
| Person / Time | |
|---|---|
| Site: | Vermont Yankee File:NorthStar Vermont Yankee icon.png |
| Issue date: | 09/18/2006 |
| From: | Dewald L Entergy Nuclear Vermont Yankee |
| To: | Emch R NRC/NRR/ADRO/DLR |
| References | |
| %dam200611, TAC MD2297 | |
| Download: ML062850148 (28) | |
Text
RichaW Emch - air emissions inventory report for 2005 and MSbS for Nalco H-550 Page 1 Paqe 11 IRicha~dErnch - air emissions inventory report for 2005 and MSDS for Nalco H-550 From: "DeWald, Lynn" <ldewald@entergy.com>
To: "Richard Emch" <RLE@NRC.GOV>
Date: Mon, Sep 18, 2006 12:58 PM
Subject:
air emissions inventory report for 2005 and MSDS for Nalco H-550 Rich, I don't seem to have kept Sam's email address and although I think it is SHQ@nrc.com, I wasn't positive and didn't want someone to get this who wasn't expecting it. Can you please forward to Sam?
As discussed, we no longer use Nalco H-550 but even when we did, any product that was not consumed in the service water system had to be maintained below 2.0 ppm as a discharge to the CT River and as such was well below Vermont's action level for gluteraldehyde in cooling tower drift.
Lynn Lynn DeWald Entergy Nuclear Vermont Yankee, LLC 320 Governor Hunt Road Vernon, VT 05354 802-258-5526 (phone) 802-258-5865 (fax) 802-380-4493 (cell)
I c emn\GW)00001.TMP Pag PacieelIil 1ii c:\ternn\GWIOOOOl .TMP Mail Envelope Properties (450ED012.1ED :20: 29165)
Subject:
air emissions inventory report for 2005 and MSDS for Nalco H-550 Creation Date Mon, Sep 18, 2006 12:56 PM From: "DeWald, Lynn" <Idewald@entergy.com>
Created By: ldewald@entergy.com Recipients nrc.gov OWGWPO02.HQGWDOO1 RLE (Richard Emch)
Post Office Route OWGWPOO2.HQGWDOO1 nrc.gov Files Size Date & Time MESSAGE 675 Monday, September 18, 2006 12:56 PM TEXT.htm 5044 Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf 556268 H550.pdf 65385 Mime.822 1 Options Expiration Date: None Priority: Standard ReplyRequested: No Return Notification: None Concealed
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mch - Final 2005.emissions inve-'nt-ory_ýepgrttoýEqýýgyYX.1_.ýý.2qpp.pdf _ ýageý_ý,J Pag~i~~
Richaki Emch Final 2005 emissions inventory report for Entergy VY 126 2006.pdf Entergy Nuclear Northeast Entergy Nuclear Operations, Inc.
Vermont Yankee 322 Governor Hunt Rd.
Vernon. VT 05354 Tel 802.257-7711 26 Janiiary 2006 Mr. Daniel Riley, Environmental Engineer Vermont Agency of Natural Resources Department of Environmental Conservation Air Pollution Control Division Building 3 South 103 South Main Street Waterbury, VT 05671-0402
Subject:
2005 Air Pollutant Emissions Inventory Report for Entergy Nuclear Vermont Yankee, LLC. Facility ID WM 2335.
Dear Mr. Riley:
Enclosed is Entergy Nuclear Vermont Yankee's air emissions inventory report for 2005.
Total air emissions from significant activities, which includes the house heating boilers and the waste oil burners, was 9.07 tons for the year. Vermont Yankee does not include emissions from the emergency diesel generators (A and B), the John Deere diesel, or the emergency diesel fire pump toward the total tonnage in this inventory report as these emergency generators, each of which operate less than one hundred hours per year, are considered insignificant activities under the State regulations.
The cooling tower particulate emissions calculations for the mechanical draft cooling towers are based on the drift and drift rate, and as in 2004, remain conservatively high.
The cooling towers operated for 2,149 hours0.00172 days <br />0.0414 hours <br />2.463624e-4 weeks <br />5.66945e-5 months <br /> during 2005. The operating hours were utilized in calculating the 2005 PM emissions.
PM Emissions (TPY) = Drift gpm x 8.33 lbs/gal x TDS x 60 min/hr x hrs/yr of operation x 1 ton/2000 lbs 72.0 gpm x 8.33 lbs/gal x (62 lbs/1000000-lbs) x 60 min/hr x 2149 x I ton/2000 lbs The calculations for the 2005 emission data for cooling tower hazardous air contaminants (HAC) consider the miscibility of the product constituent and the water circulated through the cooling towers versus percentage of water loss through evaporation when the towers are running. The circulating water flow through the cooling towers is approximately 360,000 gallons per minute (gpm), and based on the FinalEnvironmental Statement Related to the Operation of Vermont Yankee Nuclear Power Corporation 4
............. i mch - Final 2005 emissions inventory report Lorýýnýergy=VY 1 26 2006-pdf -Page 2 Page2~
IRichaM Ernch - Final 2005 emissions inventory report for Entergy VY 126 2006.pdf published by the Nuclear Regulatory Commission, 5,000 gpm is lost through cooling tower evaporation. The HAC emissions from the cooling towers are insignificant and do not exceed any action levels outlined in Appendix C of the Vermont Air Pollution Control Regulations.
Cooling Towers Pollutant Tons lbs/8 hours Action level (bs/8hrs)
I Particulate Matter 2.4 Dodecylguanidine Hydrochloride 0.001 0.002 0.025 Ethyl Alcohol 0.0004 0.001 2,330 Glutaraldehyde 0.008 0.015 340 Isopropyl Alcohol 0.0005 0.001 63 Total 2.41 This submittal'does not include additional hazardous air contaminant (HAC) emissions inventory, as those would be associated with routine maintenance activities, such as painting and cleaning, and are therefore not subject to any State reporting requirements.
Please do not hesitate to call if you have questions or concerns with the enclosed information.
Sincerely, Entergy Nuclear Vermont Yankee, LLC Lynn DeWald Samuel A. Wender IV Environmental Specialist Chemistry Superintendent 802-258-5526 802-258-5650 2
M.)
,~3 0
Supporting Calculations CD 3
(n A. SPECTRUS NX-1104 O/)
=3 Tsopropyl Alcohol CD (400 gals/yr) x (8.24 lbs/gal) x (2.4%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm) 0.0005 tons/yr Ethyl Alcohol 0 M9 CD (400 gals/yr) x (8.24 lbs/gal) x (1.8%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm)= 0.0004 tons/yr t,0 Dodecvlauanidine Hydrochloride (400 gals/yr) x (8.24 lbs/gal) x (5%) x (I ton/2,000 Ibs) x (5,000 gpm/360,000 gpm) = 0.001 tons/yr CD B. NALCO H-550 0)
Glutaraldehyde (50% Solution)
(250 gals/yr) x (9.4 lbs/gal) x (50%) x (I ton/2,000 lbs) x (5,000 gpm/360,000 gpm) = 0.008 tons/yr 3
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Rir6"hW Emch- Final 2005 ermnissions inventory report for EntergyVYl 26_2006-Pdfý -~
CERTIFICATION OF DATA ACCURACY For Purposes of Emission Calculations This form Inust be signed by an individual responsible for the completion and certification of the data contained in the forms attached which are intended to meet both the requirements of State Statute {10 V.S.A. 555 (c) and 3 V.S.A. 2822 (j)(1)(B)) and the requirements for"Ermission Statements" contained in the Federal Clean Air Act as amended in 1990. Certification indicates that the signatory takes legal responsibility for the accuracy of the information on the form.
The datapresented herein representsthe best available informationand is true, accurate,and complete to the best ofmy knowledge.
Print Full Name Print Full Title Sigture" Date of Signature SPl) 5phneNk e
Telephone Number Received JAN 4 2006
Richaed Emch - Final 2005 emissions inventory report for Entergy VY 1 26 2006.pdf Page"5Il Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The Information displayed on this form is that which Is currently on file for your.
facility. It is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please revievw the Information contained in the boxes. If there is no value In a box, write in the correct 2005 value. If there Is a value, but it Is incorrect for 2005, cross out the value and in its place write the correct value.
If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.
Facility Name: ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form ir be...b "I I ci 5 Facility ID WM2335 Source
Description:
house heating boilers (2)
Stack Number:
Source Number: I Segment Number:
Source Classification Code: 1-03-005-01 Operational Data:
Hours Per Day:
~fl Winter Throughput (%) : [i 40 Days Per Week: LIZiI Spring Throughput (%): [I 30 Weeks Per Year: LZ~I1 Summer Throughput (%)::I 0 Hours Per Year: 5; Autumn Throughput (%) :l 30 (Over)*
'Riclail E.nch - Final 2005 emissions inventorreport for EntergyVY1 262006.pdf Page 61l Combustion Source (continued)
Fuel Type: FUEL OIL (#2) 2005 Fuel Consumption: (supply units): ,
- 4 ,
Av. Sulfur Content of Fuel (%): J Ash Content of Fuel (%):
(Pleasesupply a current estimateof mid-range sulfur contenO Maximum Heat Input (million BTU/hr):
Burner Rating: Boiler Rating: L -
Maximum Actual Firing Rate (million BTU/hr):
Percent Space Heat: I00 [.
Percent Process Heat: j 0j Stack Parameters:
Stack Number:
Stack/Duct Discharge Height (feet) 87.9 Stack/Duct Inner Diameter at Exit (inches) : I 27.6Z Exit Gas Temperature (deg.F: F 151i 1 Flow Rate at Exit (actual FT3/min) :119,915 If an air pollution control, device for the source exists Inspect the following information and correct if necessary:
TSP Control Device: none Theoretical Efficiency:
S02 Control Device: none Theoretical Efficiency:
NOx Control Device: none Theoretical Efficiency: '
VOC Control Devicei none Theoretical Efficiency:[
CO Control Device: I none Theoretical Efficiency:. I 0 If an estimated emission rate exists, please supply the information below:
Estimated Emission Rite* :
Basis of Estimate:
- If test data 4 years old or less is available.
-.U
I Riclha ,mch- Final 2005 emi ssions inyentorreport.for Entergy vY1 262006,pdf -~ Page 711 Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The Information displayed on this form is that which is currently on file for your facility. It Is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review the Information contained In the boxei. If there is no value In a box, write In the correct 2005 value. If there is a value, but It is Incorrect for 2005, cross out the value and In its place write the correct value.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
Facility Name: ENTERGY NUCLEAR VERMONT YANKEE l
- Person Completing Inventory Form [ LL-"r"v%VYe uI, We (Jt I Facility ID WM2335 Source
Description:
vipte oil furnace (2)
Stack Number: 2 Source Number: 2 Segment Number: I Source Classification Code: 1-02-004-01 Operational Data:
Hours Per Day: Winter Throughput (%) 5 Days Per Week: Spring Throughput (%): 0 Weeks Per Year: Summer Throughput (%):
Hours Per Year: 1-7 CV 077 Autumn Throughput (%) :LI3 [
(Over)
- Einch - Final 2005 emiss-vans inKefyýý! ýepqýýtq!ýýqýýrgyVY 1 26 2006.p( Page 8.
RichaiU Emch - Final 2005 ernis~lons inventory report for Entergy VY 1 26 2006.pdf Pa ge8~
Combustion Source (continued)
Fuel*Type: . FUEL OIL (#6) I 2005 Fuel Consumption: (supply units): g, 55
- ty.1 (o'i5 Av. Sulfpr Content of Fuel (%): 1 / -- Ash Content of Fuel (%) 1 (Pleasesupply a currentestimate of mid-range sulfur content)
Maximum Heat Input (million BTUlhr):
Surner Rating: j3 JBoiler Rating: .
Maximum Actual Firing Rate (million BTU/hr):
Percent Space Heat: W Percent Process Heat:
Stack Parameters:
Stack Number: 2 Stack/Duct Discharge Height (feet) : 21.0 Stack/Duct Inner Diameter at Exit (inches) :7.9 Exit Gas Temperature (deg.F: - 250 Flow Rate at Exit (actual FT3Imin) : [ 1,992 If an air pollution control device for the source exists inspect the following information and correct if necessary:
TSP Control Device: I none Theoretical Efficiency:
S02 Control Device: [none .Theoretical Efficiency:
NOx Control Device: none . .]TheoreticalEfficiency:
VOC Control Device none Theoretical Efficiency: j CO Control Device: I none Theoretical Efficiency: "
If an estimated emission rate exists, please supply the information below:
Estimated Emission Rite* :
Basis of Estimate .
- If test data 4 years old or less is available.
Richardl Emch - Final 2005 emissions inventory report for Entergy VYi 262006.pdf Page 911 Vermont Agency of Natural Resources Process Source 2005 Air Pollutant Emissions Inventory For CriteriaPollutants The Information displayed on this form is that which is currently on file for your facility. It is based on inventory forms completed for calendar year 2004 or the most recent year available. The Information must be updated to calendar year 2005. Please review the Information contained in the boxes. If there is no value in a box, write in the correct 2005 value. If there is a value, but It Is Incorrect for 2005, cross out the value and In its place write the correct value.
If you have questions, or desire assistance with completing the inventory, please call Dan Riley at (802)-241-3858.
Facility Name: ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form: I LT)--
I f,,I I Facility ID: WM2335 Source
Description:
Particulate Emissions from Cooling Tower Stack Number: 5 Source Number: 5 Segment Number: I Source Classification Code: 3-85-001-01 Operational Data:
HoursPerDayi: Winter Throughput (%):
DaysPerWeek: Ill] Spring Throughput (%) ma WeeksPerYear: 1113] Summer Throughput (%): '656" aKf -F D "
HoursPerYear::2,,tf Autumn Throughput (%): [ )*o4X,- ;ioS-W (OCP (Over) t (Z.b p
Richard Emch - Final 2005 emissions inventory repoqrfor Entergy VY 1_26 2006.pdf Page 1.9j .....
Pag Process Source (continued)
Raw Materials Input*:
Type Quantity Product Materials Output*:
Type Quantity
- Information in this section only necessary If accurate figures for stack flow rate and hours of operation cannot be supplied.
- StackParameters:
Stack Number: 5 Stack/Duct Discharge Height (Feet) :II o~o 1 StackfDuct Inner Diameter at Exit (Inches):
Exit Gas Temperature (Deg F): [ 0Z Flow Rate at Exit (Actual FT3/Min) , I0I If there is an air pollution control device on this source inspect the following information and correct if necessary:
PM Control Device: none Theoretical Efficiency (%): [I 0I [
If available, supply theoretical efficiencies for:
PMIO Efficiency (%): III j PM2.5 Efficiency ()
(NOTE: This Information will not affect the Air Registration Fee Estimate).
If an estimated emission rate exists for PM, supply the information below Estimated Emission Rate* [
Basis of Estimate:
- .If test data 4 years old or less Is available.
kchard Emc6h- Final 2005 6msp n!ýqetory reportforEnterýgyKV 12 206pdf Page 11 i Vermont Agency of Natural Resources Combustion Source*
2005 Air Pollutant Emissions Inventory For Criteria Pollutants The Information displayed on this form Is that which Is currently on file for your' facility. It Is based on Inventory forms completed for calendar year 2004 or the most recent year available. The information must be updated to calendar year 2005. Please review; the information contained in the boxes. If there Is no value in a box, write In the correct 2005 value. If there Is a value, but it is incorrect for 2005, cross out the value and in Its place write the correct value.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
Facility Name: ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form I bew,~c Ij- I Facility ID *WM2335 Source
Description:
Emergency Diesels (2). 1675 hp Stack Number: 3 Source Number: 3 Seement Number:*
Source Classification Code: 2-02-004-01 Operational Data:
Hours Per Day: 0 Winter Throughput (%): [ f 25 Days Per Week: ' 0] Spring Throughput(/): Ii 25i .
Weeks Per Year: Summer Throughput (%): ]
Hours Per Year: ': 9 Autumn Throughput (%). :LiI 5 L.j7, kr-. (Over)
tl A
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ýYiqhýrý(Eýýnch - Final 2005 emissioýý.inyeýntW_ýeporýtýý,ýýqrgyyý 1_?6_?QOý.pýf Jýage _y4_q Richard Emch Final 2005 emissions inventory report for Entergy VY 1 262006.pdf
-~ Page 12t1 Combustion Source (continued)
FuelType: FUEL OIL (#2) 2005 Fuel Consumption: (supply units): * . ,
Av. Sulfur Content of Fuel (%): . Ash Content of Fuel (%):
(Pleasesupply a currentestimate of mid-rangesulfur conteno Maximum Heat Input (million BTUlhr):
Burner Rating: Boiler Rating:
Maximum Actual Firing Rate (million BTU/hr): [
Percent Space Heat: "0 Percent Process Heat:
Stack Parameters:
Stack Number: 3
- Stack/Duct Discharge Height (feet) j 29.8j j Stack/Duct Inner Diameter at Exit (inches).: 27X Exit Gas Temperature (deg. F) *180 .
Flow Rate at Exit (actual FIn/min) 63,983 If an air pollution control device for the source exists inspect the following information and correct if necessary:
TSP Control Device: I none I Theoretical Efficiency: 0 -1 S02 Control Device: I none Theoretical Efficiency:
NOx ConirolDevIce:Inone ]
- -Theoretical Efficiency:
VOC Control Devicef none 'Theoretical Efficiency:
LI E I
CO Control Device: none I Theoreticsl Efficiency:
If an estimated emission rate exists, please supply the information below:
Estimated Emission Rate* :"
Basis of Estimate:
IIf test data 4 years old or less Is available.
1 I 1ýichaýo Emch - Final 2005 emissions inveqtory_ýepoýjqý_ýqýgy \T_ýý22ýqq.pqf - ýagq P g 111q,11
........ a. d...... -Fna .00..... . i.n.r.rp rtfo.ntry.Y 1.6.0 6.d Vermont Agency of Natural Resources Combustion Source 2005 Air Pollutant Emissions Inventory For Criteria Pollutants The information displayed on this form is that which is currently on file for your facility. It Is based on inventory forms completed for calendar year 2004 or the most recent year available."The Information must be updated to calendar year 2005. Please revlevs the information contained In the boxes. If there is no value In a box, write In the correct 2005 value. If there Is a value, but It is incorrect for 2005, cross out the value and in its place write the correct value.
If you have questions, or desire assistance with completing the Inventory, please call Dan Riley at (802)-241-3858.
Facility Name: ENTERGY NUCLEAR VERMONT YANKEE Person Completing Inventory Form a. ..I Facility ID WM2335 Source
Description:
235 hp John Deere Diesel Stack Number: 4 Source Number: 4.
I1 Seement Number:
Source Classification Code: 2-01-001-02 Operational Data:
Hours Per Day: 'Winter Throughput (%):
Days Per Week: *SpringThroughput/(%): I 25 Weeks Per Year: Summer Throughput (%)2: Z 5Z Hours Per Year: Autumn Throughput (%) :[ 2j (Over)
Richard Emch -Final 2005 emissions inv"ryfýpgqlpý,ýqergyYY.ýý"OQP-Pqý, Pge1 Richard. Emc - Fina 200 emsson.ivetoy.eprt.o.Ete.. ... 2.....d Combustion Source (continued)
Fuel Type: FUEL OIL (#2) .
2005 Fuel Consumption : (supply units): jj" :fj'l $
Av. Sulfur Content of Fuel (%):
- Ash Content of Fuel (%): 0.00' (Pleasesupply a currentestimate of mid-rangesulfur content)
Maximum Heat Input (million BTU/hr):
Burner Rating: j Boller Rating: [Z Maximum Actual Firing Rate (million BTU/hr): LI0 Percent Space Heat: ir 0i*
Percent Process Heat: 0o Stack Parameters:
Stack Number: 4 Stack/Duct Discharge Height (feet) 12.5~
Stack/Duct Inner Diameter at Exit (inches) 3.9iI Exit Gas Temperature (deg. F) 180~
Flow Rate at Exit (actual FT3/min) '4,30 If an air pollution control device for the source exists inspect the following information and correct if necessary:
TSP Control Device: none TTheoretical Efficiency:
S02 Control Device: I none" Theoretical Efficiency: 0 NO Control Device:Inon Theoretical Efficiency:
VOC Control De vicei on ] The;retical Efficiency: EZ~
CO Control Device: F none Theoretical Efficiency: 0 If an estimated emission rate exists, please supply the information below:
Estimated Emission Rate* T I.
Basis of Estimate :
I*f test data 4 years old or less is available.
1*
_". ' .A
I Richard Emch -_H550.pdf___ Page 1 1i Richard Emch H550.pdf Page 1 ii MATERIAL SAFETY DATA SHEET N"NALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
- 11. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: H-550 APPLICATION : MICROBIOCIDE COMPANY IDENTIFICATION: Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S): (800) 424-9300 (24 Hours) CHEMTREC NFPA 704MWHMIS RATING HEALTH : 3/3 FLAMMABILITY : 1/1 INSTABILITY : 0/0 OTHER:
0 = Insignificant 1= Slight " 2 = Moderate 3=High 4=Extreme r2. I COMPOSITION/INFO RMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s).
Hazardous Substance(s) CAS NO % (w/w)
Glutaraldehyde 111-30-8 30.0- 60.0
- 13. 1HAZARDS IDENTIFICATION
-EMERGENCY OVERVIEW DANGER Corrosive. Causes irreversible eye damage. Causes skin bums. Harmful if inhaled. May be fatal if swallowed.
Harmf ul if absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Causes asthmatic signs and symptoms in hyper-reactiv e individuals.
Do not get in eyes, on skin, on clothing. Avoid breathing vapor. Do not swallow. Wear goggles, protective clothing, and rubber gloves. Wash thoroughly with soap and water after handing. Remove contaminated clothing and wash before reuse.
Not flammable or combustible. May evolve oxides of carbon (COx) under fire concitions.
PRIMARY ROUTES OF EXPOSURE:
Eye, Skin, Inhalation HUMAN HEALTH HAZARDS -ACUTE:
EYE CONTACT:
Corrosive. Will cause eye bums and permanent tissue damage.
Nalco Company 1601 W. Diehl Road
- Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access S1/12
I Richiird Eriich - H550.pdf Page 2 Paqe 21111 I Richard Emch H550.pdf MATERIAL SAFETY DATA SHEET N"NALCO -PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC SMUN CONTACT:
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
INGESTION:
Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach.
INHALATION:
Irritating, in high concentrations, to the eyes, nose, throat and lungs. Inhalati on of product mist or vapors may cause respiratory allergy.
SYMPTOMS OF EXPOSURE Acute A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic :
A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS:
A review of available data does not identify any worsening of existing conditions.
HUMAN HEALTH HAZARDS -CHRONIC:
Prolonged inhalation of product can increase lung injury in persons with emphysema, asthma, or other lung disorders.
- 14. FIRST AID MEASURES EYE CONTACT :
Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open.
SKIN CONTACT:
Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large splash flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.
INGESTION:
Get immediate medical attention. DO NOT INDUCE VOMITING. Ifconscious, washout mouth and give water to drink.
INHALATION Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.
IF IN EYES: Immediately flush with plenty of water for at least 15 minutes. Get immediate medical attention.
IF ON SKIN: Immediately wash with plenty of soap and water. Get medical attention.
IF INHALED: Remove to fresh air. If breathing is difficult, administer oxygen. If symptoms persist, call a physician.
IF SWALLOWED: DO NOT INDUCE VOMITING. Do not give anything to drink. Seek medical advice with urgency.
Nalco Company 1601 W. Diehl Road
- Naperville ,Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/12
I Richard Enich - H550.pdf Page I Richard Emch H550.pdf Pacie 33t111 MATERIAL SAFETY DATA SHEET AWNALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC NOTE TO PHYSICIAN :
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical concition.
- 15. 1FIRE FIGHTING MEASURES FLASH POINT: None EXTINGUISHING MEDIA:
This product would not be expected to bum unless all the water is boiled away. The remaining organics may be Ignitable. Use extinguishing media appropriate for surroundng fire.
FIRE AND EXPLOSION HAZARD :
Not flammable or combustible. May evolve oxides of carbon (COx) under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive-pressur e self contained breathing apparatus and protective suit.
- 16. 1ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS:
Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended In Section 8 (Exposure Controls/Persona I Protection). Notify appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP:
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Dilute the glutaraldehyde to 5% or less with water. Add sodium bisulfite (2-3 parts by weight per part glutaraldehyde). This will typically reduce the glutaraldehyde concentration to 2 ppm or less in 5 minutes at room temperature. The remaining solution can be disposed of via appropriate means. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS:
This pesticide is toxic to fish. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified In writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/12
[ F:Vichaýd Em9h - H550.pdf Paige
[Richard. Emch H550.pdf Page 4,11 41 MATERIAL SAFETY DATA SHEET NNALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
- 17. I HANDLING AND STORAGE HANDUNG :
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containe rs closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
STORAGE CONDITIONS:
Store the containers tightly closed. Store separately from oxidizers. Store in suitable labelled containers.
SUITABLE CONSTRUCTION MATERIAL:
Compatibility with Plastic Materials can vary; we therefore* recommend that compatibility is tested prior to use.
- 18. 1 EXPOSURE CONTROLS/PERSONA L PROTECTION OCCUPATIONAL EXPOSURE UMITS:
Exposure gidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.
ACGIH/TLV:
Substance(s)
Glutaraldehyd e CEIUNG: 0.05 ppm, 0.2 mg/m3 0.05 ppm , 0.2 mg/m3 OSHNPEL :
Substance(s)
Glutaraldehyde CEIUNG: 0.2 ppm, 0.8 mg'm3 ENGINEERING MEASURES :
General ventilation is recommended. Use local exhaust ventilation if necessary to control airbome mist and vapor.
RESPIRATORY PROTECTION:
If significant mists, vapors or aeros ols are generated an approved respirator is recommended. A dust, mist, fume cartridge may be used. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection Is required, institute a compiete respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION:
BUTYL GLOVES, NEOPRENE GLOVES, Viton# gloves SKIN PROTECTION :
Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is recommended if gross exposure is possible.
EYE PROTECTION:
Wear a face shield with chemical splash goggles..
Nalco Company 1601 W. Diehl Road
- Naperville , Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/12
IFýichw--d-E' ITch --I-155b-Pdf Page 5 ;
Page 5;I I Richard Ernch - H550.pdf MATERIAL SAFETY DATA SHEET AWNALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC HYGIENE RECOMMENDATIONS :
Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.
- 19. 1 PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Uquid APPEARANCE Colorless ODOR Aldehyde SPECIFIC GRAVITY 1.11 -1.13 @ 77°F/25°C DENSITY 9.4 Ib/gal SOLUBIUTY IN WATER Complete pH (100 %) 3.1 -4.5 0 0 VISCOSITY 21 cps @ 68 1F/20 C FREEZING POINT -5.8 °F/-21 °C BOIUNG POINT 213 F/ 100.5 °C VAPOR PRESSURE 16 mm Hg VAPOR DENSITY 1.1 VOC CONTENT 54 % EPA Method 24 Note: These physical properties are typical values for this product and are subject to change.
- 10. 1 STABILITY AND REACTIVITY STABIUTY :
Stable under normal conditions.
HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.
CONDITIONS TO AVOID:
Freezing temperatures.
MATERIALS TO AVOID:
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.
HAZARDOUS DECOMPOSITION PRODUCTS:
Under fire conditions: Oxides of carbon
- 11. 1 TOXICOLOGICAL INFORMATION The following results are for the product.
Nalco Company 1601 W. Diehl Road
- Naperville , Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/12
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- H550.pdf MATERIAL SAFETY DATA SHEET AWNALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC ACUTE ORAL TOXICITY:
Species LD50 Test Descriptor Rat 1,300 mg/kg Product Glutaraldehyde Rat 1.2 mVkg 45% Active Ingredient Rat 1.54-1.87 mt/kg 25% Active Ingredient Rat 1.07 - 1.62 mVkg 10% Active Ingredient Rating : Harmful ACUTE DERMAL TOXICITY:
Species LD50 Test Descriptor Rabbit 897 mg/kg Product Glutaraldehyde Rabbit 2.00 - 2.71 ml/kg 45% Active Ingredient Rabbit 8.0- 12.8 mVkg 25% Active Ingredient Rating : Harmful ACUTE INHALATION TOXICITY:
Species LC5O Test Descriptor Rat 0.48 mg/I 0 Product Rating : Very Toxic PRIMARY SKJN IRRITATION: At 10% or greater, glutaraldehyde solutions may cause moderate to severe irritation, with possible necrosis after prolonged contact.
PRIMARY EYE IRRITATION : At levels of 0.2% and below of glutaraldehyd e, no eye irritation was noted. Levels above 0.2% of glutaraldehyd e produced moderate to severe irritation and comeal irjury.
SENSITIZATION :
Levels of greater than 0.2% of glutaraldehyd e produced allergic contact dermatitis in human studies. May cause sensitization by Inhalation and skin contact.
CARCINOGENICITY :
None of the substances in this prod uct are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH).
HUMAN HAZARD CHARACTERIZATION Based on our hazard characterization , the potential human hazard Is: High 112. 1 ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS :
The following results are for the product along with results on the active substances.
ACUTE FISH RESULTS :
I Species I Exposure LC50 I Test Descriptor I Bluegil Sunfish I 96 hrs I 22.4 mg/I I Product IFathead Minnow 96 hrs 10.8 man rouc Sheepshead Minnow 96 hrs 64 mg/I Product Nalco Company 1601 W. Diehl Road
- Naperville , Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/12
I Richard Emch - H550.pdf P Pag~e 7 !
MATERIAL SAFETY DATA SHEET N"NALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Rainbow Trout 196 hrs (24 mg/I Product ACUTE INVERTEBRATE RESULTS :
Species [ Exposure I LC50 EC50 Test Descriptor Daphnia mana 48 hrs 11.5 m__I Product Shore Crab 96 hrs 930 m_/I Product Grass Shrimp 96 hrs 82 mg/I Product Mysid Shrimp (Mysidopjis 96 hrs 14.2 mg/I Product bahia)
American Oyster 96 hrs 1.56 mg/I Product Acartia tonsa 48 hrs 1 0.22 mg/I Product AQUATIC PLANT RESULTS :
Species Exposure EC50/LC50 Test Descriptor Marine Algae (Skeletonema 72 hrs 1.22 mg/I Product costatu-n)
Algae (Scenedesmus 72 hrs 1.7 mg/I Product subspicatus) I AQUATIC MICROORGANISM RESULTS:
ISpecies rta I Exposure I EC50/LC50 ITest Descriptor Sewage Microornisms I96 hrs 134 mo Active Substance AVIAN RESULTS:
Species Exoue L5 Test Descriptor Bobwhite Quail 8 Days 10,000 ppr Active Substance Mallard Duck 1 8 Days 10,000 ppn I Active Substance Mallard Duck I L933 mcftg 150% Active Ingredient MOBIULTY :
The environmental fate was estimated using a level IIIfugacity model embedded in the EPI (estimation program Interface) Suite TM , provided by the US EPA The model assumes a steady state conrdt ion between the total Input and output. The level III model does not require equilibrium between the defined media. The information provided Is Intended to give the user a general estimate of the environment al fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soiVsediment In the approximate respective percentages; Ar Water I SoiVSediment
<5% 30-50%1o 50- 70%1o The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL This preparation or material Is not expected to bioaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURIE CHARACTERIZATION Based on our hazard characterization , the potential environmental hazard is: Moderate Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/12
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IRichard Ernch - H550.pdf MATERIAL SAFETY DATA SHEET N"NALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 in Section 15. CHEMTREC (24 Hours) see CERCLA/SUPERFUND If released into the environment, If released into the environment, see CERCAINSUPERFUND in Section 15.
113. I DISPOSAL CONSIDERATIONS I If this product becomes a waste, It Is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characted stics of Subpart C, nor is it listed under Subpart D.
As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handing, treatment or disposal requirements. For disposal, contact a property licensed waste treatment, storage, disposal or recycling facility.
ACONTAINER DISPOSAL Metal Containers or Plastic Containers: Triple rinse (or equivalent). Then offer for recycling or reconditionin g, or puncture and dispose of in a sanitary landfill, or other procedures approved by state and local authorities. Plastic Containers: May be incinerated, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke. Metal Containers: Must not be incinerated. Do not cut or weld on or near metal containers.
114. I TRANSPORT INFORMATION I The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shippi ng Name / Hazard Class may vary by packaging, properties, and mode of transportatio n. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT:
Proper Shipping Name: CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
Technical Name(s): GLUTARALDEHYDE UN/ID No: UN 3265 Hazard Class - Primary: 8 Packing Group: II Flash Point : None AIR TRANSPORT (ICAO/IATA) :
Proper Shipping Name: CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
Technical Name(s) : GLUTARALDEHYDE UN/ID No: UN 3265 Hazard Class - Primary: 8 Packing Group : II IATA Cargo Packing Instructions: 812 IATA Cargo Aircraft Umit: 30 L (Max net quantity per package)
MARINE TRANSPORT (IMDG/IMO):
Proper Shipping Name: CORROSIVE UQUID, ACIDIC, ORGANIC, N.O.S.
Technical Name(s): GLUTARALDEHYDE UN/ID No: UN 3265 Nalco Company 1601 W. Diehl Road
- Naperville , Illinois 60563-1198 - (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8112
-Page 9 I RichýýEiiich - H550.p'df I Richard Emch H550.pdf Page 9 ~I MATERIAL SAFETY DATA SHEET P1NALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Hazard Class - Primary: 8 Packing Group : II 115. 1 REGULATORY INFORMATION NATIONAL REGULATIONS, USA:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 Based on our hazard evaluation, the following substance(s) in this product Is/are hazardo us and the reason(s) Is/are shown below.
Glutaraldehyde : Corrosive, Sensitizer CERCLNSUPERFU ND, 40 CFR 117, 302:
This product contains the following Reportable Quantity (RO) Substance. Aso listed Is the RQ for the product.
RQ Substance RO Methanol 5,000 lbs SARANSUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313:
SECTION 302 - EXTREMELY HAZARD OUS SUBSTANCES (40 CFR 355):
This product does not contain substances listed in Appen dx A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370):
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following Indcated EPA hazard categories:
X Immediate (Acute) Health Hazard X Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - UST OF TOXIC CHEMICALS (40 CFR 372) :
This product contains the following substance(s), (with CAS # and % range) which appear(s) on the Ust of Toxic Chemicals Hazardous Substance(s) CAS NO % fw/w)
Methanol 67-56-1 1.0 -5.0 TOXIC SUBSTANCES CONTROL ACT (TSCA):
This product Is exempted under TSCA and regulated unde r FIFRA The inerts are on the Inventory List.
Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For adclitional copies of an MSDS visit www.nalco.com and request access 9/12
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(800) 424-9300 (24 Hours) CHEMTREC FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA):
EPA Reg. No. 464-704-1706 In all cases follow instructio ns on the product label.
This product has been certified as KOSHER/PAREVE for year-rou nd use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL FEDERAL WATER POLLUTION CONTROLACT, CLEAN WATER ACT, 40 CFR 401.15 /formerly Sec. 307, 40 CFR 116.4 / formerly Sec. 311 :
None of the substances are specifically listed in the regulation.
CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) :
This product contains the following substances listed in the regulation:
ISubstance(s) ICitations
- Methanol Sec. 111, Sec. 112 CALIFORNIA PROPOSITION 65:
This product does not contain substances which require warning under California Proposition 65.
MICHIGAN CRITICAL MATERIALS :
None of the substances are specifically listed in the regulation.
STATE RIGHT TO KNOW LAWS:
This product is a registered biocide and is exempt from State Right to Know Labelling Laws.
Methanol 67-56-1 Glutaraldehyde 111-30-8 NATIONAL REGULATIONS, CANADA:
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
WHMIS CLASSIFICATION :
Pesticide controlled products are not regulated under WHMIS.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):
The substances in this preparation are listed on the Domestic Substances Ust (DSL), are exempt, or have been reported in accordance with the New Substances Notification Regulations.
INTERNATIONAL CHEMICAL CONTROL LAWS Nalco Company 1601 W. Diehl Road
- Naperville .Illinois 60563-1198 - (630)305-1000 For addtional copies of an MSDS visit www.nalco.com and request access 10/12
I Richard Ench - H550.pdf Mape11 lRichar~Emch H550.pdf Paqe ii] 1 MATERIAL SAFETY DATA SHEET PRODUCT 4NALCO H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC AUSTRAIJA All substances In this product comply with the Nation al Industrial Chemicals Notification & Assessment Scheme (NICNAS).
CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing Chemical Substances China (IECSC).
EUROPE The substances In this preparation have been reviewed for compliance with the EINECS or ELINCS Inventories.
JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry Ust (MITI).
KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals Ust (ECL)
NEW ZEALAND This product complies with Parts Xl - XV of the HSNO Act (1996).
THE PHIUPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals & Chemical Substances (PICCS).
116. 1 OTHER INFORMATION This product material safety data sheet provides health and safety Information. The product is to be used in applications consistent with our product literature. Individuals handing this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handing practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further Information.
REFERENCES Threshold Umit Values for Chemical Substances and Physical Agents and Biological Exposure Indces, American Conference of Governmental Industrial Hygienists, OH., (Adel Insight# CD-ROM Version), Adel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Ubrary of Medicine, Bethesda, Maryland (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Nalco Company 1601 W. Diehl Road
- Naperville , Illinois 60563-1198 - (630)305-1000 For addtional copies of an MSDS visit www.nalco.com and request access 11/12
[ Richar-j Em-ch - H550.pdf Page Page 12!1 i2~I
[Richakl Emch H550.pdf MATERIAL SAFETY DATA SHEET N"NALCO PRODUCT H-550 EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC Annual Report on Carcinogens, National Toxicology Progr am, U.S. Department of Health and Human Services, Public Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Adel Insight# CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS# CD-ROM Version), Micromedex, Inc., Englewood, CO.
Adel Insight# (An Integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Adel Insight# CD-ROM Version), Adel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS# CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Prepared By: Product Safety Department Date issued: 04/21/2006 Version Number : 1.10 Nalco Company 1601 W. Diehl Road - Naperville, Illinois 60563-1198 * (630)305-1000 For adcitional copies of an MSDS visit www.nalco.com and request access 12/12